SCIENTIFIC ABSTRACT YERSHOV, N.I. - YERSHOV, O.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001962910007-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 15, 2001
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

XTDUSO Ta,?.; PUZITSKIT, K.T.; TIRSH)TO V.I.; 11mysKly, B.A.
Catalytic polymerization of olefins, Report No.8: Folpterization
of etbVlene over a nickel - aluminasilicate catalyst, Isv,AN SM
Otd,khiu,wmk no-5*-920-925 MY 160. (KMA 1316)
1, Inotitut orgaulohoskoy Wall Imaul 1,,Ds Ulinokog* Almdemii
nauk Um,
(AWWlene) (Polyneritation) (CaUlysts)

Calculating the amonat of seeMe throuO b*Wzg eands.
Ayt,dors 23 noo?s23-25 JI 160.
(Boll percolation) (Road drainage)

82720
,/60/1.33/01/30/070
3/020
BO11/B003
AUTHOM Yershov, N. I., Eydus, Ya. T., YisrokhIns, V. P.
IMM, I I
TITLEt Oxygen-initiated Polymerization of Et ene by Beterogoneoun
_K!~Xl
Catalysis in the Presence of Eydrogen
PERIODICALs Doklady Akademii nauk SSSR, ig6o, vol. 133, No. 1,
pp. 108-111
TEXTt In a preceding investigation (Ref. 1) the authors have found that
ethylene is polarized on a Co-clu catalzat1during hydrogenation at
1001C. So far, such a polyme tion had not been observed if the gas did
not contain CO impurities. It was proved that polymerization at 1000C
is not initiated by CO but by oxygen. This reaction is reduced by a rise
in temperature, and is most vigorous between 100 and 12000. It is
additionally intensified by an increase in the oxygen content up to
It does not take place in the absence of oxygen an4 liydrollen. In the
article under review, the authorareport on some resulto of this new
reaction named in the title. The same apparatus and i)atalyat wore used
as in Refs 1 and 2~ Table 1 lists the experimental rasults obtained at 411
Card 1/3

81'120
Oxygen-initiated Polymerization of Ethylene by S/020~60/133/01/30/070
Heterogeneous Catalysis in the Presence of BOII/ ~'003
Hydrogen
a ratio of 113.2 between C 2H4 and H2* It may be seen that polymeriza-
tion yields a gaseous dimer and up to 35% of liquid products (referred
to the ethylene used). The waste gas contains 1-1.5% of 00. The authora
assume that the said reaetion is identical with the kiydropolymerization
of ethylene under the action of CO (Ref. 2). This wam, however, not the
case since the reaction did not give the highest yield between 190 and
2000C and was not intensified with rising CO concentTation. Table 2
proves that this is the case with C 2H4 1 H2a 1,1 and an 02 content of
2%. At the same time, the ethane yield rises from 45 to 79k. Experimental
results obtained at different temperatures, whioh show the effect of CO
addition upon polymerization and hydrogenation, are given in Table 3-
The presence of CO and B20 in the waste gas and the reaction water of
several experiments indicaie that 0 2 added to the reaction mixture
reacted vigorously with the main components.during the reaction. The
authors assume that active surfaces are thus formed, which initiate the
polymerization of ethylene. This is proved by the inoreasing quantity of
Card 2/3

8.1P00/1 33/01/30/070
Oxygen-initiated Polymerization of Ethylene, by 3/6"~ 6
1 B
Heterogeneous Catalysis in the Presence of BO11 B003
Hydrogen
reaction products with rising 0 2 content at; 1000C. From all this the au-
thors conclude that the reaction named in the title is initiated by 02'
Tho polymerization of ethylene in the presence of H is not
ido"tioal with tho hydropolymariviation undoir tho anijon of CO. Th,ro
are 1 figure, 3 tables, and 4 reforenceat 1) Soviet- aild i dorniftn~
ASSOCIATIONt Institut organicheakoy khimii im. N. D. Zolinakogo
Akademii nauk SSSR (Institute of Organic Chemistry Imeni
N. D. Zelinskiy of the Academy of Sciences, USSR)
PRESENTED: March 10, 1960, by B. A. Kazanskiy, Academician
SUBMITTEDt March 89 1960
Card 3/3
it!
j

XMS, Ta.T.; PUZITSM, X.V.; YUSHOV, N.I.; "IrAZA Ir, B.A.
Cataytic polymerization of olefins, Report Jro.10: Zffect of
the temperature and contact time on the course of etbyleas
polymerization on nickel catal"te, IST.Al SMOOtilekbim,
nauk no.6:ni4-ln8 ii 16o. (MINA :1337)
1. Institut organicheskoy khim:U imeal IsDaZelinskolgo
Akademii nauk SSSRe
(Ethylene) (Polymerization) (Catalyste. Nidkel)

13106~160100010OTIOI 5/0 ~'71V,
:8004/B064
AUTHORS.
TITLE-
PERIODICAL:
Eydus, Ya. T., Puzitskiy, K. V., Yershov N I
Guseva, 1. V., and Kazanskiv,-I_JC-4..~;~~
Catalytic Polymerization of Olefins,, Communication 11,
Tho EffQct of Impurities in the Initial Gas and of the
Material of the Toot Tubk) Wall. Upon tho Coljz,o~i of tho
Polymerization Rqaction of Ethylene n Rickel Cattily:iLA
Izvestiya Akademii nauk BSSR. Otdelen3e khtnicheskikh
nauk, 1960, No. 7, PP. 1291 - 1294
TEXT: The authors are concerned with studying the effects of all
reaction conditions upon the catalytic polymerization of olefins. In
the present paper, they report on the effect.of impirities in initial
ethylene, the influence exerted upon the catalyst by treating it with
various substances, and finally the effect exerted apon catalyai~s
by the material of the tube walls. Up to 5% propylerie or up to 10%
butylene were added to ethylene as impurities. Ethylene was polymerized
Card 1/3

Catalytic Polymerization of Olefins. S/062/60/000/007/015/017/XX
Communication 11. The Effect of Impuri- B004/BO64
ties in the Initial Gas and of the
Material of the Test Tube Wall Upon the Couroe of the PolymerIzation
Reaction of Ethylene on Nickel Catalysts
to butylene on a NIO-Al203 catalyst. While an addition of 0,5 to 3%
impurities showed no effect, the activity of the catalyst dicreased at
higher amounts of admixtures (yield without addition: 82%q with an
addition of 5%: 56.2%). An addition of 30 - 4.0% H2 or preliminary
treatment of the catalyst with H 2 (yield without- H2: 58~8%' With H2
23.0%) showed the same effect. The water vapor content of ethylene
also reduced the activity of the catalyst. On comparing the activity
of the catalyst in test tubes of gla8Bj brass, or stainless steel it
was found that in the steel tube the yield in polymers and the re-genera-
tion capacity of the catalyst decrease; maxim".1m y1old io thl-- ginfin.
and braaa tubou 71.2%, Iti th" atutl tuba? 64.7%. Tht~rn &i*tl I figure,
5 tables, and 2 Soviet references,,
Card 2/3

Catalytic Polymerization of Olefin-.. S106216010001007101510i7l'XX
Communication 11. The Effect of B0041BO64
Impurities in the Initial Gas and of the
Material of the Test Tube Wall Upon the Course of the Polymerizatica
Reaction of Ethylene on Nickel Catalysts
ASSOCIATION: Institut, organicheskoy khimii im, N, D. Zelinskogo
Akademii. nauk SSSR
(Institiate of; Organic Chemistry imeni N, D. Zelinskiy
of the Academy of Scionces USSR)
SU13MITTED: Novombor 12, 1956
Card 3/3

S/062/60/000/008/025/033/XX
B013/BO55
AUTHORS, Yerokhina,.V. R., and Eydus, Ya. T.
TITLE; Catalytic Iaomerization of Cycloprop~ne in MiTtures With
Olefins
PERIODICALi Izvestlya Akademii nauk SSSR. Otdeleniye khimichaskikh nauk,
1960, No. 8, pp. 1495-1499
TEXT: In the present paper, the authors studied the effect of admixing
cyclopropane to ethylene and prcpylene on their polymerization over various
catalysts. Cyclopropane was prepared by the methoa described by G. G.
Gustavson (Ref. 11). Quantitative determination of the propylene and cycle-
propane mixtures was carried out by a method based on Ahe selective ab.-
sorption of propylene in a KI--Br 2 solution (Ref. 13). The apparatus and
experimental technique was the same as in Ref. 15. The following catalysts
were applied: Cobalt on alumina (Ref. 16) (1), silica gel (II), cobalt/
silica gel (III), aluminum silicate (IV), and cobalt/aluminum silicate (V),
On catalyst (I), neither ethylene nor propylene formed liquid polymeriza-,
tion products at 300 0C and below. Addition of cyclopropano (7 - 30%) to
Card 1/3

Catalytic Isomerization of Cyclopropane S/062/60/000/00;3/02542/Xx
in Mixturea With Olefins B013/BO55
ethylene produced only slight formation of liquid polymerizates. The
yield was less than 1% of the initial ethylene and 9 - 43% of the added
cyclopropane. The latter was isomerized only up to 20% (Table 1). In ex,
periments with pro ylene (Table 2), the portion of reacted cyclopropane
was lower (5 - 15A. The data listed in the table show that liquid poly-
merizates are formed in small quantitiej,,or not at all, when oyclopropane
is added to ethylene or propylene. The cyclopropane is isomerized only
slightly, only up to 20%. In the presence of hydrogen, the yields of
liquid hydropolymerizates of ethylene, obtained with and without addition
of cyclopropane, did not exceed 4.1% of the initial alkene. The addition
of cyclopropane did not affect the yield. 33 -- 57% of the cyclopropane
entered into reaction, i.e., a much higher percentage than in the absence
of hydrogen. No liquid polymerizatea were formed In experimonts employing
catalysts containing silioa gel, (II) and (13:1). Neither propylene poly-
merization nor cyclopropane laomerization occurred. In tests employing
catalysts of propylene polymerization Phich iiire based or, synthetic alu-.
minum silioate, the cyclopropane in mixture vith olefinfl is isomerized
65 - 100%. It was stated that no final conclusions concerning the poly-
merizing effect of cyclopropane admixtures could be drawn from the ex-
perimental data, since the yields of liquid polymerizatos were lower than
Card 2/3

Catalytic Isomerization of Cyclopropane S1062160100010081025AZ31XX
in Mixtures With Olefins B013/BO55
ethylene produced only slight formation of liquid polymerizates. The
yield was less than 1% of the initial ethylene and 9 -43% of the added
cyclopropane. The latter was isomerized only up to 200jf. (Table 1). In ex-
periments with pro ylene (Table 2), the portion of reacted ayclopropane
was lower (5 - 15Z, The data listed in the table show that liquid poly-
merizates are formed in small quantities,or not at all, when cyclopropane
is added to ethylene or propylene. The cyclopropane is isomerized only
slightly, only up to 20%. in the presence of hydrogen, the yields of
liquid hydropolymerizates of ethylene, obtained with and without addition
of cyclopropane, did not exceed 4.1% of the initial alkene. The addition
of cyclopropane did not affec-. the yield. 33 -- 57% of the cyclopropane
entered into reaction, i.e., a much higher percentage than in the absence
of hydrogen. No liquid polymerizates were formed in experiments employing
catalysts containing silica gel, (II) and (III). Neither propylene poly-
merization nor cyclopropane isomerization occurred. In tests employing
catalysts of propylene polymerization which are based on synthetic alu-
minum silicate, the cyclopropane in mixture ivith olefina is isomerized
65 - 100%. It was stated that no final conclusions concerning the poly-,
merizing effect of cyclopropane admixtures could be drawn from the ex-
perimental data, since the yields of liquid polymerizates were lower than
Card 2/3

Catalytic Isomerization of Cyclopropane S/062/60 000/008/025/033/XX
in Mixtures With Olefins B01005~
the amount of reacted cyclopropane. It was, however, possible to determine
the activity of the various catalysts. Catalysts containing aluminum
silicate were found to be very active in isomerization of cyclopropane
in mixtures with ethylene and propylene. Cobalt on alumina was much leas
efficient. There are 4 tables and 22 refefenaes: 12 Sowiet, 10 US,
4 British, 7 German, and 1 French.
ASSOCIATION: Institut organicheskoy kh1mii im. N. D. Zelinakogo Akademii
nauk SSSR
(Institute of Organic Chemistry imeni N. D. Zolinskiy of the
Academy of Sciences USSR)
SUBMITTED: March 9, 1959
Card 3/3

8 111hq
s/b8:/jJ7c;DQ/022/0!6/Q- !6
AO05/AO0l
Translation fromi Referatiniyy zhurnal, Khimlya, 1960, No, 22, P. 571, # 91091
2 Ito c~
AU-IHO-RS: Eyd-.--s, Ya. T., Yershov, N. 1.
TITTLE: On the Role oi the Plane Chains in the Catalytic hqdropclymerization
Mechanism of Olefins Under the Action of Small Quantities of Carbon.
Monoxide in the Presence of.Hydrogen
PERIODICAL: Probl. kinetiki i kataliza, 1960, Vol. 10, pp, 4011-409
TF.XT- The radical-challn mechanism is proposed of thLt
-~al hydropolymerization reacticr- of olefins under the a~:tlon of small CO-suan-,itlz.~a
in H2-presence, proceeding in contact with a colvalt catalyst, at about 200 C and
atmospheric pressure. In the process mechanism are included the reactions of the
H-atoms and radicals connected with the surface, their reoombin!ttions and dlsso~,,J-a-
tions and the Interaotiono with the ab3orb,~rt olvfln
A. Litm~uiovie-1-
mranslator's note; This is the 'full trarslatiort of the original. Russian atstract
Card 1/1
fll IN Il!] 11111, 1; '1* 1 H , I

YERSHOV, N.I.; EYDUS, Ya.T.; YEROKHTIIA, V.R.
Catalytic hydrocondensation of carbon monoxido irith olefins and the
hydropolymerication of olefina under the effect of carbon monoxide
and hydrogen. Report No-32: Conversion of 1-octene. I:zv. AN SSSR.
Otd.khim.nauk no.9sl696-1702 S 161. (MIRA 14:9)
1. Institut organicheskoy khimii im. N.D.Zelinskogo All SSSR.
(Carbon monoxide) (Octene) (Hydrogen)

4~12 '61 /000/010/010/016
J~-'Zbo B106/B101
AUTHORS; Yershov, N. I., Eydu.99 Ya. T,,j and Yerokhina, V. R.
TITLE: Catalytic hydrocondensation of carbon monoxide with olefins
and their hydropolymerization under the action of carbon
monoxide and hydrogen. Communication 33. Formation of
higher hydrocarbons with a number of carbon atoms not being
an integral multiple of the initial olefin
PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 10, 1961, 1871-1874
TEXT: The catalytic hydropolymerization of olefins under the action of
carbon monoxide in the presence of hydrogen and the hydrocondensation of
carbon monoxide with olefins yield both real polymers and their hydro--
genation products, and a considerable quantity of highor hydrocarbons with
a number of carbon atoms not being an integral multiple of the initial
olefin, The authors clarified the reasons of formation of these higher
hydrocarbons. The yield of these hydrocarbons increases with increasing
Card 1/4

2! 2 7 3
S/062/61/000/010/010/018
Catalytic hydrocondensation of carbon... B106/B101
molecular weight of the initial olefin (double bond in I-position) while the
value of the mean multiple K m decreases for the whole higher-boiling frac-
tion of the condensate. Km - (La ini)/n (2) (ai = fraction of the il-th
hydrocarbon in the higher-boiling fraction of the condensate; n i - nunber
of carbon atoms in the i-th hydrocarbon; n = number of carbon atoms in the
initial olefin). The formation of larger amounts of higher hydrocarbons,
the carbon number of which is not an integral multiple of the initial
olefin, can be explained neither by hydrocracking of the initial olefin nor
by its hydrocondensation with carbon monoxide. Therefore, it is assumed
that the formation of the higher hydrocarbons mentioned is due to the
cleavage of carbon-carbon bonds during hydropolymerization or hydrocondensa-
tion, Radicals are formed which may lead to the forwition of higher
hydrocarbons with a carbon number not being an integral multiple of the
initial olefin. The authors conclude: In catalytic reactions of olefins
under the action of carbon monoxide and hydrogen, the hydrocarbon chains
grow less by molecular interaction of the initial olefin than by react'-on
Card 2/4

28273
S10621611000101010101018
Catalytic hydrocondensation of carbon... B106/B101
of the initial olefin with radicals formed by cleavage of carbon-carbon
bonds on the catalyst. Thereforeg the highe r-boiling reaction products
mainly yield hydrocarbons the carbon number of which is not an integral
multiple of the initial olefin. Hydrocarbons with fewer carbon atoms than
are present in the initial olefin are also J'ormed in fimall (juantity,, The
cleavage of the C-C bonds is facilitated by plane addition of the absorbed
olefin molecule to the catalyst surface and the resulting deformation.
This plane absorption only occurs at low carbon monoxide concentrations.
At higher concentrations, the carbon monoxide may displace, from the
catalyst surface, the carbon atoms of the olefin which do not lie at the
double bond. This eliminates the deformation of the olefin moleculet
Under such conditions, the hydrocarbon chain may grow rithout cleavage of
carbon-carbon bonds by hydrocondensation of the olefin with the carbon
monoxide according to the following scheme:
Q'H2-fjII 2 + CH2 C113CHxGH2
CH3CH-CH2 + CH2 0 CH3CH2CH-CH2, etc. (3).
Thus, the type of adsorption of the olefin molecule andq therefore, also
Card 3/4

2,1273
S/062/61/000/010/010/018
Catalytic hydrocondensation of carbon- B106/B101
the direction of the reaction may change ao dependent on the content of
carbon monoxide and hydrogen in the initial. gas mixtu-re and on the
capability of the olefin of being adsorbed. These reciprocal transitions
of the reactions of olefins under the action of carbon monoxide and hydrogen
will be thoroughly studied in the following communication. There are
8 references: 7 Soviet and 1 no-n-Soviet. The reference to the English-
language publication reads as follows: A. W. Pletcher, E. J. Gib3onj
Radioisotope Conf. 11, 41 (1954).
ASSOCIATION: Institut organicheekoy khimii im. IN. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic. Chemistry imeni
N. D. Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: April 8, 1961
Card 4/4

971,
28
Z,; 7
SIO 61/000/010/011/018
B106 B101
AUTHORS: Eydus, Ya. T., Yershov, N. I.p and Yerokhina; V. R.
TITLE: Catalytic hydrocondensation of carbon monoxide with olefins
and their hydropolymerization under the action of carbon
monoxide and hydrogen. Communication 34- Reciprocal
transitions of formation reactions of hydrocarbons from
mixtures of ethylene, hydrogen, and carbon monoxide
PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdelaniye khimicheskikh
nauk, no. 10, 1961, 1874 - 1879
TEXT: It had been assumed previously (Ref. 13 N. I, Yershov,
Ya. T. Eydus, Dokl. AN SSSR, 115, 1126 (1957); 119, 1062 (1958)) that one
stage of the synthesis of higher hydrocarbons from carbon monoxide and
hydrogen is a radically proceeding hydrocondensation of carbon monoxide
with olefins. In the subsequent stages of synthesis, this reaction may
change into a hydropolymerization of olefinsg which constitutes a radical
chain reaction, In the present study, the authors considered the
possibility of a similar transition of these reactions into each other on
Card 1/5 A

28 274
5/062/61/000/010/011/018
Catalytic hydrocondensation of... B106/11101
a catalyst that is efficient both in the reaction according to
Orlov-Fischer-Tropech, and in hydropolymorization reactions of olefine and
their hydrocondensation with carbon monoxide. Such a catalyst was obtained
by activating a Co-clay catalyst with addition of 18~0' Th02 (referred to
metallic cobalt). A Co-kieBelguhr catalyst is also catalytically active
in all reactiolno mentioned. The tests were conducted at 1900C and
atmospheric pr.essure in a flowing system. The volume velocity of the
initial gas mixture was close to 0100 hr -1 . Before the tests, the catalyst
was reduced with hydrogen at 450 C for 5 hr; the catalyst vas regenerated
in the same manner. Binary mixtures CO - H 2 (1.2) and ternary mixtures
C2H4 - H2 - CO of different compositions were used as initial mixtures.
No liquid hydrocarbons but mainly CH , CO,,, and H 0 were -formed in the
4 d. 2
tests with binary mixtures CO - H2 during the first 5-7 hr of the reactio!4
immediately after reduction of the catalyst. The same occurred
immediately after regeneration of the catalyst. The formation of lio.-did
hydrocarbons only begins after 6-7 hr contact time, their yield groys from
Card 2/5

28274
S/062/61/000/010/011/018
Catalytic hydrocondensation of ... B106/M101
one regeneration to the other (Fig. 1). Initial mixtures with 7-7-55 CO
.and with 25-35% CO were used in tests with C 2H4 - H2 - CO mixtures. At
lower CO concentrations under otherwise equal conditionag the yield of
liquid hydrocarbons was 2-3 timej the yield at high CO concentrations.
In the presence of small CO amounts the ethylene hydropolymerizes, at
higher CO concentrations hydrocondensation with carbon monoxide occurs.
Thus, it is possible to attain a transition from one reaction into
another, and vice versa, by changing the composition of the initial gas
in the presence of the catalyst. A reduction of the C 2H4/H2ratio in the
initial mixture favors hydrogenation of ethylene to ethane. It was found
that the molar ratios -at which CO, H 2 , and C2H4 react with formation of
liquid hydrocarbons are very similar to the molar ratios of these gases
in the initial mixture. Fig. I shows that hydropolymerization and
hydrocondensation in ternary mixtures also proceed in the first 5-7 hr
after reduction or regeneration of the catalyst, and even produce
maximum yields of liquid hydrocarbons in the period of regeneration. The
synthesis of hydrocarbons from CO and H 2, however, yields only methane
Card 3/5

Map-
21274 S/06 61/000/010/011/Cla
Catalytic hydrocondensation of... B 1 06YI31 01
at the same stage. This interesting fact may be explained an follows:
In the synthesis of hydrocarbons from CO and H 21 the reduction of carbon
monoxide produces radicals which either polymerize (methyl.ene radicals)
or condense, e.g., with cleavage of water (hydroxy methylene radicals).
During methane formation at the beginning of contact, the interactions
of radicals are apparently hindered so that the -radicals act on the
adjacent particles (hydrogen in binary CO - H 2 mixtures, olefin in
ternary olefin - CO - H 2 mixtures). Thus, the same factors that effect
methane formation in the synthesis from CO and H 2 favor, in the case of
ternary mixtures, the hydropolymerization of olefins under the action of
small CO amounts and the hydrocondensation of CO with olefins. In this
case, the methylene radicals do not associate but are preserved as
reaction centers and reaction initiators with tho help of olofinii. Thovo
are "I figure, 3 tables, and 10 referencea: 7 Soviet and 3 non-Sovlot,
The two references to English-language publications read as follows:
E. F. G. Herington, L. A. Woodword, Trans Faraday Soc, .25-, 958 (19/39);
S. R. Craxford, Trans. Faraday Soc. J~, 9~7 (1939).
Card 4/5

i~O;e 14 S/062/61/000/010/011/ola
IF -
Catalytic hydrocondensation of... B106/B101
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinakogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni
N. D. Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: April 6, 1961
Fig.l. Various types of formation reactions F1
of hydrocarbons and their reciprocal trane-
formition. Legend: (a) hydrocarbon yield,
(b) hours; (1), (la)p (1~)t and (18)
ml/m ;
synthesis of hydrocarbons from CO and H2;
(2) and (2a) hydrocordensatibn of CO
with C2H (initial mixture contained 25~4 CO); Voo-' P-No.
its
M
(3) and ~3a) hydropolymerization of C2H under*3 I
4
the action of CO (initial mixture contained
10 40 60 JOY04
7-7-5',.1 CO); the vertical broken lines
indicate the instant of catalyst regenera-
tion.
Card

'A, Migil HIM "I"'; IbIMMI'LA. -,1 t r I
IIIFLINIM~.' IMIMI 1AIMMINER."r, 1411. 10466~.Ikdi -1
S/062/62/000/Oo5/ooa/ooa
BlIO/B101
AUTHORSj Yershov, N. I., L)rdusy Ya. T., and Yerokhina, V. R.
TITLEs Catalytic hydrocondeneation of carbon monoxide with olefina
and their hydrbpolymerization under the action of carbon
monoxide and hydrogen. 36. Hydrocondensation and
hydropolymerization of olefins on the nickel c;ttalyst
PERIODICALs Akademiya nauk SSSR. Izvestiya, Otdeleniye khimicheakikh
nauk, no- 5. 1962, 911-916
TEXTt The specific character of the nickel oatalyst (as compared with the
Cc catalyst) was examined, and the hydropolyinerization of ethylene,
propylene, and butylene under CO action was tentativel performed on it".
The catalyst was Ni-Mn-Al 203 kieselguhr (100:20:10000~. However, the
synthesis of.liquid hydrocarbons from 1CO+2H,, (2000C) does not set in
3 /m3
until after 20 hro. The yield first attained 128 ml m , then 145 ml
while that of CO 2 and CH4 dropped to/v1O and 20-2 . With 15-18/.
addition of ethylene to ICO+2H liquid hydrocarbons formed in the
Card 1/4 2'

S106Y621000100 5/006/008
Catalytic hydrocondensation of carbon ... B11 0 B101
first hours already under -75% hydrogenation of ethylene. This is
brought about (1) by dilution of the initial CO-112 mixturo with vthylcno
which# in reducing the reaction ratel also reduoe6 the catetly8t heating,
and thus inhibito the methane formation; (2) by preferrod rothylona
advorption to the most active catalyst centers, at which tho methane
formation takes place.. Since the hydrocarbon formation from carbon
monoxide and hydrogen in the presence of ethylene takea place at thu
losa active catalyst centersi liquid hydrocarbons are immadlately formed.
-!hylene is cost readily hydrogenated on the catalysts at 1000C, the
0
process was almost as rapid as at 200 C, the yields of gaseous paraffin
hydrocarbons being 25-27% at 1000C.and 29-4~ at 2000C. At 190-2000C
on the Ni catalyst, ethylene chiefly reacts with hydro;zen, as the latter
cannot react with the proiucte of incomplete CO reduction. If, however,
this is made possibl4o ethylene can take part in the syntheai3 of hiEher
hydrocarbons. Thus, when a binary mixturo of 1CO+2H and athylene wa:j
alternatingly blown through for 3 and 6 min, respectively, the yield of
60-681a of reacting ethylenp is
liquid hydrocarbons was 240-260 ml/=3
Card 2/4

.3/062
I I /62/000/005/008/ooa
Catalytic hydrocondensation of carbon BIJO/Z101
hydrogenated to ethane. Vhen alternatingly blowing-through with
propylene (6 min) and 1CO+2H 2 (3 min), the hydrocarbon yield was raised
to 154-172 ml/m3, i. e., it rose by 60-79 mljim3 as bompared with the
binary mixture. The propylene hydrogenation was relatively poor in this
connection (17'5f- of initial propylene). Whon alternatingly blowing
through with butylene min) and 1CO+2H2 (3 min), the olefin yield rose
to 210 ml/M3, and the yield of gaseous paraffins droppod to 9-1010 04,
initial butylene. When blowing through with ternary mixtures of Co, H21
and olefin (ethylene, propylene, butylene) at 1900C and an atmospheric
pressure with -100 hr-1 volume rate on the Hi. catalyst, the olefin is
hydrogenated to the corresponding paraffin. The formation of higher
hydrocarbons from CO and H2 in the presence of ethylene and its homologs
takes place at 190-2000C on the catalyst surface which is free from olefin
molecules. This surface is the smaller the higher the olefin
concentration in the initial gaseous mixture. This causes the yield of
liquid hydrocarbons to decrease on olefin addition. If, however, the
olefin reacts with reduction products (methyleno and other radicals),
Card 3/4

!3/062/62/000/005/COB/008
Catalytic hydrocondensation of carbon B11O/B1Q1
hydropolymerization and hydrooondensation prevail over olefin hydrogenation.
There are 4 tables.
ASSOCIATIONt Institut organichesk0y khimii im. N. D. Zelinakogo
Akademii nauk SSSR (Institute of Organic Chemistry imeni
N. D. Zelinskiy of the Academy of Scienoen U33R)
SU.B=TTEDt December 16, 1961--
Card 4/4

EYDUS., Ya.T.; YWHOV, N.I,; YERONWAV V,R,; ANDRMV,, N.S.
... ...... . .........
Oxygen-initiated heterogeneous catalytic reacticia of comdensa-
tion of olefins in the presence of hydrogen. Part 2: Conversions
of ethylene. KinsA kat, 4 no,3:416-421 My-Je f,63-
(mnu 16.-,7)
1. Institut organicheekoy khimii imeni Zelinskogo AN SSSR.
(Ethylene) (Pol rization)
'L7
(cb7gen
a " =u,!;

'11 Jll w :1.,
YERSHGV, N.I.; EZDUS, Ya.T.; YEROKEINAO V.R.; ANEMEV, N.S.
Oxygen-initiated heterogeneous catalytic reactIon of con-
densation of olefins in the presence of hydrWan. Part 3:
Conversions of propylene. Kin. i kat. I+ no.6:8a9-834 N-D 163.
(W RA 17: 1)
1. Institut organicheskoy khimil imeni Zelinskogo AN SSSR.

YERSHOV, Nj!j EYDUS, Ya.T.; YEROMINA, V.R.; ANDRETEVv U.S.
oxygen-initiated heterogeneous catalytic reaction o'f condensation
of olefins In the presence of hydrogen. Part 5s Conv-arsl~)n of isobutylene.
Kin. i kat. 6 no.2%300-305 Mr-Ap f65. (MIRA 18t7)
1. Institat orgaricheskoy khirdi imeni Zelinskogo,)A SSSR.

EMIS, Ya.;-".; _17,RSHOV, N.I.
lnl~iateed reactionis. Dc.-~I,, AN SIISR .162- mc.~-
610-612 ~V 1~5. 18-,~ .,
1. Institut orgadche5koy khimil Im. N,,Melinskolgo All SS,13R.
Submitted Novernter 11, 1964~

SOURCE CODE: UR/0020/66/167/003/0583/058!
I
AUTHOR: Yershov,_N. I.; Eydus, Ya. T.; Guseva, 1. V.
ORG: Institute of Organic Chemistry im. N. D. Zelinskly, Academy of SclencesSSSR
(Institat organicheskoy khimil Akademii nauk SSSR)
"in
TITLE: The initiating effect of carbon monoxide during hydropo!ymerizaUon of ethylene
the presence of hydrogen
SOURCE: AN SSSR. Doklady, v. 167, no. 3, 1966, 51,13-585
TOPIC TAGS: polymerization Initiator, carbon mono;dde, ethylene, reaction mechanism
ABSTRACT: The report describes conditions for the hydropolymerization of ethylene at 190C,
during which the hydrogen reduction of carbon monoxide Is almost completely absent and the
monoxide is not detectable in the end products of the process. Preliminary exposure of the
reduced Co catalyst to the monoxide, or to a gas containing It, at 100C represents one method
of obtaining such conditions. The ratio of ethylene to hydrogen is especially significant in
the process and can serve to control the catalyst's ability to reduce CO. In such cases the
monoxide fimetions as the initiating agent through any, of the four described reaction variants.
Card 1/2
uDG: 66.097-13
77-77F7

ACC NR: AP6011657
The results Indicate that the growth of carbon chains during hydrqvlyrnerlaatlon,fpoiia,~ibly
also in the FIscher-Tropsch process with a Co catalyst) Is not a deJAyd-rvtJoa-.C~cwixfjOQ
process, but , .1
.F~ ~esen~l~~_a polymerization mechanism with correctitma fordentructioll prly-
Ceases. The paper was presented by Academician B. A. Kazanakly a". Mg. 415.
SUB CODE: 07/ ~b~DATE.- 02Jul66/ OXRIG REP: 009/ OTH REF: 012

i ; 1, '~ TNI
fl
all rlil
la

[p.j

lq,

111111 mill 1111111IM11,111111j

YERSHOVP NOMO
Studying ventilation systems by means of reconnalmnae. mrVeyso
Nauch. trudy KNIUI no.16sl46-163 '&~. (4RA 18:7)

Graphonalytical mthod of stu4ing the Joint opermtIcan of fans. Hatr-h.
trudy KNIUI z;o.l6t239-245 t64. (MIRA 180)
7-
,j