SCIENTIFIC ABSTRACT YERUSALIMSKIY, B.L. - YERYKALOVA, O.K.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001962910019-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 15, 2001
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Reactions of the Free Radicals in Solutions. 3/062/60/000/009/014/021
Communication 17. Effect of the Viscosity of B023/BO64
the Medium on the Primary Recombination of
Free Radicals
4 Soviet and I US.
ASSOCIATION% Institut vysokomolokulyarnykb noyodinowiy Akndwil i. wauk S',")11
(Infitituto of Highmolocular Compoundu of thp Acadwy of
Sciences USSR)
SUBMITTED: April 7, 1959
Card 3/3

IVA I K It 115, L
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U-1~ I ill W i h.14141HUM I 1WHOWN HIMMUM Ill i 3,13 6B. I; I i0'! I jj;,1,'j I,,! 1' .-.1 1
DOLWPLOSK, B. A.Jv )LO~USA IMMIX, B, XROPUCHEVA, Ye. N.,
TINYAKOVA, Ye. L.
"Structure of Diene Polymers as a Function of the Plature
of Catalytic Systems"
Report presented at the Conference on International IS-ymposium
on Macromolecular Chemistry. Montreal, Canada, 27 July to 1 Augul3t 61.
/-Institute for higher "cular Compounds, Akademia
Nauk, SSSR, Leningrad, USSR.
1d:
11111111111111H11111111114 tii iiii'll I 11!

LYUBETSKIY., S.G.; DOLGOPLOSK, B.A.; YERUSALIMSKIY
Free-radical polymerization of ethylenee Part 1t Kinetica of
ethylene polymerization in a benzene and heptaw solution. VyBokom.
soed. 3 no.5:734-739 Vq 161. (DEIRA 34:5)
1. Institut vysokomolekulyarxqkh soyedineniy AN SSSR i Neuchno-
issledovatel'skiy institut, pollm izatsionnykh plast:Lkov.
(Ethylene) (Polymerization)

S/190J61/003/005/014/014
S110/3230
AUTHORSt Yerusalimskiy, B. L.p Morkurlyevs, A. V., Baykova, N. P.
TITLEs Polymerization of chloroprene under the influence of organo-
metallic compounds
PERIODICALi Vysokomolokulyarnyye soyedineniya# v. 3, no. 5, 1961, 798
TEXTs Data published on the polymerization of chloroprene by methods
other than initiation by free radicals disclose nothing about polymeriza-
tion in the presence of conventional organometallio compounds. The present
authors found the polymerization of chloroprens under the influence of
organolithium and organoma nesium compounds to be posmible. Butyl lithium
and the system [094 1 + IC4B9 ) 2 1f81 were used as initiators of polymeriza-
tion. This system, formed in the course of the organomagnesium. synthesis
in hydrocarbon, has already been applied together with other organo-
magnesium compounds for the polymerization of isoprene. Under the in-
fluenos of the system butyl magnesium iodide - dibutyl magnesium the poly-
mesization of ohloroprene takes place at a considerable rate between 40 and
60 C. it a concentration of the initiator of 0.012 to 0.025 and of the
Card 1/2

MUM, 11111110111"111111111"'I.
_22572-
S/190/61/003/005/014/014
Polymerization of... B110230
monomer of 2-5 moles/l, conversion amounts to-5 per cent per hour at 600 C
at the beginning of the reaction. Applying butyl lithium and a concentra-
tion of the initiator of 0.008 and 08 the monomer of 4.0 molse/l, con-
version is 2 per cent per hour at 35 C at the beginning of the reaction,
Polymers obtained in hexane under the conditions described are Bolublo in
benzene to a limited egtent (v50 per cent). Temperature of vitrification
varies from -46 to -50 C for the individual specimens. [Abstracterts note2
Essentially complete translation]. There are 4 referenoest I Soviet-bloc
and 3 non-Boviet-bloo.
SUBMITTED3 January 28, 1961
Card 2/2

'10i It H M.I 1111HVI 1141P H 11
2062 S/ 190/61/003 '/007/0(~6/1);~
B 15 1/3 ?0 G
ww~
AUWJOi1:j: Ly!;Ibet~,kiv, :3. G., Dolgop'Losk, B. it., 'iarii-gallimskiy, B. L.
T ITLE; Ethvitme ijcivmerizatior. urder the aclarin of free
;L, C-1-yicric! polymerization in t1w of benz,mo with
trie -y*tem -,olvent - mcnovj-i.,r beirif, nbt,~,v c,-Jtical .,,ninf
PERIODICItL: Vyiokomo1eku1yarnyye gcyedineniyal v. :5, 7, 19o1,
1 C);-,O- 1002
TU, XT I t Ili-w pijrponn of thil !JFU1()nt papor ~.* il jiyl-mn polp
merlzaf~lrjn At, ~Jie r`m--j-?rco of bonv:'-j~4 ari sc-l.vont ir-d .%zr~-iobvyric, iz,ii
dirill.rile vais The system tias abo-~rtn '10
, plint
it became c,,mp:,r,At-1e *~c- t homogenecue -.-iis !~arr-c!d
out at 701--'11. ne containeo aj imput. 0'.
t
11 ,artj:j] previ,urf? 411 tilt, "vite ~:Oravr? J.1': 0,1.1
;s
an xLo-jr~ir!y f alm by 1-seric-di n! grap.,ly. :11r-e
I-lie rnlyr,~,r t-.-tc; cfiter(rinc~d in a+ ~3~:,47- ir. t'w,~ "i!,-' (--xL-or4..mpnta1
sprie:~, ~.- r.-:o-,oure ,;hs vari~.-d betwv,~m I00 -irl -ho
Cztrd 1 /4

2C 62
,~onnentz-:0,ion vav kQ'ij~ scr!--tant af mol-ll
100 at m 0-3'~-O- 57- at '00 ','n -,nd
4 wove
TIvt,n in nt
9~`O at~:, 70CC. ~V tit -,aried 1-11P:Ii.-ne crn~~,jntva! ton. Oo ~ i,-', E! t.,,3 ncf
~cnzenv fr.-iven, )%o i,, II civor val ue. of -, n t ri n:A a vl.z c-~ ~. i ~ v ,, nd Ivm~iri -.a-
ticn rate. 9C2,/~- of t1-- polyethylene obtained was -, ry s t a L 'I i r. t- -.1. no o o -n b I ed
tb,- low-preosure eth,rIe-no ulso in cf-her resLent:,- The awhcr- to
fi,re -IJ'qr!3 by ijuti"1011S. TI.?rr? are 21 +1111)1~:,7 and
I Soviet-bIcc and 6 nf~n-Soviet-bloc, The "5 rpf-i,enres tv Engltsh-
language publications read as follows: Z.Laita. j.Polympr Sci, ",P,
459,1959; W.Padgett, E.Perry, J.Polymer Sci ~7. 543~ 1959: R.Laird,
A.1-ilorell, L.'Seed, Dig:. Faraday Soc., 22, i~61,;*7956; R.Heines, W.Bi,vant.
A.Larchar, Industr. and Engng. Chem., 49, 1071, '1957; S.Kcdama,
V.14atsushima, A-Ueyoshi, T.Shimidzu, J.Polymer Sci., 41, 89, 1999.
Card 2/4

; q%1 ! 111 & iI -I I I I, I ., ,I
BOGOMOLINYY, V. Ya.; MMUSALMSX~Y_,. FOMOVSKIYp Yo.I.
Free radical reactionsin solutimso Part 18: Relative
activity of C113. and (CH3)3 CO. radicals in the reaetlon of
detachment of H-atom from hydrocarbons. Zhur.o~,khim. 31 no.8:
2675-2682 Ag 161. (MTRA 14:8)
(Radicals (Chemistry))

3 6 ~ 9. 1:1,
S/190/62/004/004/009/019
B117/B138
AUTHORS: Lyubetnkiy, S. G., Dolgoplosk, B. A., Y.2~s l_jmAk~y,_.jj. Lo
TITLE: Polymerization of ethylene affected by free radicals III.
Polymerization of ethylene with the monomer - polymer
system in a non-homogeneous state
PERIODICAL: Vysokomolekulyarnyye soyedineniya,, V. 4, no. 4, 1962,
533-539
TEXT: The polymerization kinetics of ethylene was studied in the presence
of azoisobutyric acid dinitrile and benzene between 100-600 atm at 700C.
The activation energy was determined by additional experiments at 60 and
BOOG and found to be 17 � 2 kcal/mole. At relatively low monomer conversion
at 100-300 atm, the rate of polymerization has a first-order dependerlae in
relation to monomer concentration. Here the degree of polymerization
changeu linearly with the monomer concentration. At pressures abovc
300 atm, the dependence of polymerization rate and molecular weight of the
polymer on the monomer concentration ahown a marked change after this.
The degree of polymerization does not change lineorly itith the concentration.
The dependence of rate and degree of polymerization on the volatility of
Card 1/3

3/19 62/004/004/009/019
Polymerization of ethylene... B117YB136
I
ethylene is similar. At 400-600 atm, the order of reaction in relation to
volatility approaches 1.9. In experiments of up to 20 hr duration, gradual
increase of the molecular weight of the polymer and constant polymerization
rate were observed. This confirms the concept of "live" polymer chains in
polymerization. Their existence was proved by direct experiments at 200C.
The increasing molecul&r weigM clearly showed that the polymerization of
ethylene at room temperature develops further on "live" polymer chains.
The change of the dependence of degree and rate of polymerization observed
at the beginning of the reaction at 300-400 atm is probably connected with
the development of an active solid phase. The aggregation of the growing
chains, which leads to accumulation of the "live" polymer, plays a decisive
role. The change of the polymerization mechanism setting in above 300 atm-
results in a functional depondence of general formt ka, M fospol) - Y(EW)",
fi
where ka is the constant of the rate of ageregation of "live" polymer
radicals, P is the mean degree of polymerization, and is the monomer
Pol 1!41
concentration. The deviation of the order of reaction in relation to the
ini'tiator concentrationg which becomes especially noticeable in the absence
of the solvent, points to a change of the polymerization mechanism. The
Card 2/3

S/190/62/004/004/009/019
Polymerization of ethylene ... B117/B138
order of reaction of 0.69 was ascertained without solvent, and of 0-53
-0-56 in the presence of benzene (0-14-0.28 mole/1). The increase of poly-
merization rate and molecular weight of the polymer observed in the presence
of small benzene amounts can also be traced back to the growth of "live"
polymer chains in the solid phase. There are 6 figures and 4 tables. The
two most important Enelish-language references aro: R. Buchdal, Disc.
Faraday Soc., Z2, 150, 1956; C. Bamford, A. Jenkins, M. Symons, M. Town3ed,
J. Polymer Sci., a, 181, 1959-
ASSOCIATIONs Inntitut vyvokomo1eku1yarnykh soyedinenly AN OSSR (1110titute
of High-molecular Compounds AS USSR), Itauchno-issledovatellskiy
institut polimerizatsionnykh plastmass (Scientific Research
Institute of Polymerization Plastics)
SUBMITTED: March 10, 1961
Card 3/3

S/190/62/004/009/005/014
B101/B144
AUTHO 3: Dolgoplosk, B. A., Yerusalimakiyp B. L., Kavunenko, A. P.,
Merkurlyeva, A. V.
TITLE: Polymerization of diene hydrocarbons tinder the action of
organomagnesium compounds
PERIODICAL: Vysokomolekulyarnyye-ooyedineniya, v. --~, no. 9, 1962, 1333-1337
TEXT: The polymerizo:ltion of butadiene (I 2,3-dimethyl butadiene (II), -
and chloroprene (III) by the system (C H was studied under
4 9 2M9 - 04H911g,
the same conditions as that of isoprene described previously Uysokomolek.
soyed., , 2, 541, 1q60). Renults: (1) A solution of ~5 - 30.mole'/'O~ I in hexane
yielded -10,,j polymer with 77 - 75% 1,4 bonds at 100 C. Under the same
conditions, II yijlded-40~j' polymer with 97~ 1,,! bonds. The poly.-,erizaticn
proceeds more slovly than that of isoprene. The polymers are completely
soluble in benzene and have lost 6-G.; of'their double bonds. It is
assumed., therefore, that an intr~uiolecular 0cyclization occurs. (2) The
polymerization of III in heiar-~: at 40 - 60 C yielded up to 20~'C'$.polymer.
The polymers had limited dolubility in benzene, and their glass transition
Card 1/2
F

S/190/62/004/009/005/014
Polymerization of diene... 11101/B144
Point Was -40' to L490C- (3) The consumption of organomaGnesium initiator's
during the polymerization of isop rene was studied. The content in C H
4 10
libera 1~ ed bj If2so4vas determined chromatographically. The continuous
.L
decrea in ~nitiator-concenuration and the continuous increase in
molecu~jrve ght during the 'reaction suggest a consecutive organometal
synthe s.1 tonomer addition to the C-Mg bond is compar'atively slow.
There 1 igure and 4. tables.
ASSOCIA Institut vysokomolekulyarnykh soyedinenily AN SSSR (Institute
of High-molecular Compounds AS USSR)
SUBMITT Ds May 20, 1961
T
C4rd ;2/4
.11 li'11RITU, WKNI I I'I'll i1 I
P ;41RHI 14, M11",J]

IAILOVSKAYA, Ye,B.; SOKOLOVA, O.V.; YERUSAIM4SKIYO B.L.
Transisomerization of dimothyl maleate under the im"'luence
of free radicals. Zhur.ob.khim. 32 no.2:621-626 F 162.
(MIRA 15:2)
(Maleic acid)
(Isomerization)
(Radicals (Chemistry))
f,

I , 11
YERUSALIMSKIY, B.L.
Modern concepts of the mechanism for the cation polymerization of vinyl
monomers. Usp.khim 32 no.12:1458-1487 D 163. (MIRA 17:2)
1. Institut vysokomolekulyarnykh soyedineniy All SSSR.

YERUSALDISKIY B.L.,-.KRASNOSELISKAYA,,,j.G., MAzUREK, V.V.
- - --, I... .....
P013merization of chloroprene In the presence of organometallic
compounds. Part 1:System chloroprene - butyllithian. Vysokom.
sood. 6 no.7tl294-1301 JI 164 OFIRA 18:2)
1. Institut vysokomolekulyarnykh soyedineniy AN SSSH.

111"'.tg I In
gamma=!, 1him.
ACCESSION NR: AP4045430 5/0190/64/006/009/1637/1641
AUTHOR: Krasnosellskaya, I.G., Yerusalimakly, B* Le
o-"Ze#8 under- the influence of dibutyl mi
TITLE: Polymerization of chlor prene agnesium and
butylmagnesium Iodide
SOURCE: Vy*,.sokomoIekulyarny*ye soyedinenlya, v. 6, no~ 9, 1964, 1637-1641
TOPIC TAGS: chloroprene, dibutyl magnesium,. buty1rnognesium iodide, organomagnestum
compound, chain termination, chain propagation, activAlon, initiator, polymerization
catalyst, polychloroprene
ABSTRACT: The kinetics of polymerization of the system chloroprenc-dibidyl magnesluin.;
buty1magneslum Iodide were Investigated by carrying out the polymerization In heptane
or a fraction of purified kerosene at a monomer concentration (M) of 2-8 mole/liter and
an initiator concentration (C). of 0. 01-0. 08 mole/liter. Under the given conditions, the
polymerization reached an almost constani rate in the inlUal state to slow down gradually
later and to stop completely an disappearance of the polymer. At 40C, (M) =.6 and (C)=0.08
mole/liter, the maximum yield was 55%. The plotter experimental data show that for the
Card jL/3

ACCESSION ~R: AP4045430
initial rate of polymerization, calculated from the conversion after the first 40 min., the
order of reaction was 0. 95 with respect to the initiator and 1. 09 with respect to the
monomer. After 0. 25 min., the reaction mixture contained only 10% of the starting
initiator, and in 0. 5 min. It completely disappeared. 7143 total content of organo-
magnesium cqmpounds after 0. 25 mim was 92% of the Initial. Then, the total concentra-
tion of organic magnesium compounds continued to decrease slowly. The decrease in the
initiator concentration can be attributed to the parallel reactions of initiation and destrue-
tion. The rate constants of the elementary reactions and the activation energien of chain1
propagation and ohWn termination wore detOrmined and We da a mm IOWA, Foi, obain
propagation, the constants were k, 1228.4andk it 0.82inin-1; fq chain ternitnation at
40, 50 and GOCthe constants were 0. 0018,. Q.-OOR and0 .0087 min-i, respectively. The
I activation energy of chain termination obtained from these values Is 17.9 + 0.5 kcl/mole.
i The average vimosimetric nwiecular weight of polychloroprene calculated from the
I formula ju = 1. 55 X 10-4 W. (in benteme) increased continuously In UW initial stage
of the polymerization. This confirm@ tfj3 Idnetic acheme according to which the chain
propagation kq a stepwine arganametalUo sytiffiesis. The results Indicate an anionic
A
CmW3.

............. ............... ... .. . . ....
I i it IL-.1 1,.I .
ACCESSION NR: AP4045430
mechanism for the reaction. The resulting polymers lose their solubility In benzene at a
certain degree of conversion (during polymerizati6a at 40C, at a polymer yield of about
40%). The microstructure of polychloroprene formed under the Influence of organo-
magnesium compounds practically coincides with the typical struettire of polymers ob
tained by the radical polymerization of chloroprene. "The authors are greatly Indebted to
A.A. Korotkov for his useful comments. The microstructural daW, on t1w polyfners were
provided by Ye. 1. Pokrovekiy and G. V. Lyubimova. 11 Orig. art, bas: 6 formulas,
5 figures and I table.
ASSOCIATION: Institut vy*.sokomolekalyarny*kh. soyeftenty AN S$SP% (insiltute of High-
Molecular Compounds, AN SSSR)
SUBMITTED: 260ot63 -ENCL-. 00 SUB CODE: OC
NO REF SOV: 004, OTHER: 002
3/3
Card

DUT0,41, V
* - "a' _Tlyl B.L.
~
of i8tj-,pene wl'b irlayl chlori
j(in~jj-~!j of coix,,Ir le. vysck-:~T-
ooed. 7 no.6.,.1075,-ICr19 j,~, 165. ('141RIS 18,9)
)., ()Rjjt,jTwksy '~(ipibfijnt, i Twititilt, v~sokoinclokulyarrjykh
s,:iyt~dineniy AN

L 376~~66 S4T(m)/04F(j)jT RM
ACC NR. Ap6o11237 [A), SOURCE CODE: UR/0413/66/000/006/0075/0075
INVENTOR: YerusA1jMgk1y,_B, L. -. Kulevekaya, 1. V.; anuilov, S. K.;
Frenkell, S. Yao
ORG: none
TITLE: Preparation Ylonitrile
of poilyacr ~N Class 39, No. 119925
announced by the J_nstitu~E_eof High-Molecular Com2ounds, -AN SSSR
nstitut vysokomolekulyarnykh soyedineniy AN SSSR)j
D
SOURCE: Izobretenlya, promyshlennyye obrazteyo tovarnyye znaki,
no. 6, 1966, 75
TOPIC TAGS: polyacrylonitrile, acrylonitrile, polymerization
ABSTRAM. This Author Certificate introduces a method of preparing
polyacylonitrile by polymerization4of ncryloniItril4lin a hydrocarbon
solvent at about -75C in the R-55-57ce 3f ;-rgir,~-agneslum catalyst%s.
To extend the variety of organomagnesium cataly-t:s,
C.1 .1 _9-omplexes,,of
magnesium alkyl halides or magnesium alkyls wit. limethylsulfoxide
are suggested. (LD]
SUB CODE: 11 07/ SUBM DATE: 13r-,-.,b6r-
Card 1 /1 vmb uDc: 678.745

T GMARK) N, N'. Y z"I i, !rK 8. L.
e of et'-,rlena under th3 et"frect. rY'
7 no.'f'sl,~1.3-1216 J-L '65.
(MIRA 1818)
kombinut i Institut vyaokoinolekalyarnykh
n'y AN 3,912M.
--cyadine

L ~3526-666 EWrfi)/T/S-WP(J)
ACC NRt AP601562 (A)
SOURCE CODE: UR/01901'66/008/005/0876/0881
413
AUTHOR: Kulevskaya, L!V.; Yerusallmskiy, B. L.; Mazurek, V. V.
ORG: Instttute--of Macramolecular Compounds, AN SSSR'(Institut vysokotoolekularnykh
soyedinenly AN SSSR)
TITLE: Polymerization kinetics of the crylonitrIlejunder the effect of
butylmagnesium chloride
SOURCE: Vyaokomolekulyarnyy* noyedinaniya, v. 8, no. 5, 1966, 876-881
TOPIC TAGS: polymer, monomer, po lymerizatlon kinetics, acrylonitrile, intgmmmdzw:~
chloride, toluene , motcAmclooat 0-rmPocP"o
ABSTRACT: The kinetics of polymerization in the system acrylonittile, toluene, and
butylmagnesium chloride at -75C has been investigated. A mecbanism of the
polymerization process Involving elementary stages through intermediate complexes
,was proposed. For the initial stage of polymerization, the first order of t e
catalyst and the second order of the monomer were shown. The nolecular weight of
the polymers exceeded 200,000. Orig. art. has: 7 figures, 9 formulas, and I table. 1-
SUB coDE.- 071 sm DATE: 13May65/ ORIG REF: 0061 OTH RFV: 012
Cad 1/1 UD Ci 66.095.26+678*745
IJP(d) WN/RM

L-44583-66 BIT
ACC NRs
AP6015672
SOURCE CODE;
UR/0413/6' 001009100
0/0 76/0076
IMNTOR: Yerusalimskiyj B. L.,, Krasnosel'skaya, 1,
ORG: none
TITLE: Method for obtaining polychloroprene Class 39. No. 18129315
(announced by institute of Micromolecular Com2ounds AN SSSR (Institut
vysokomolekulyarnykh soyedineniy AN SSSR)j
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki,, no. 9',
1966., 76
TOPIC TAGS: polychloroprenej chloroprene, polymerization, polymeriza-
t~on catalyst
I
ABSTRACT: An Author Certificate has Veen issued for a method of obtain-
ing polyohloroprene by DolvmerizatioWlof chloroprene in a medium of
inert organic colvent at-_roo~_~e-m_pardflura In the preaenoe of an orgsno-
metallic catalyst. To increase the polychloroprene yiold, a comple _of
1/2 uDc: 678.763.2

L 44583-66
ACC NRt AP601%72
l~II.Luiiiuutly.L-.L.LVII.LUIILLUU.LUC-U.LUU L,;(.LUIOF
metallic catalyst'l LTranslationj
SUB COM 1l/ SUBM DATE: 06F-eb65/
4o used as the orpno-

YEWSA-LIMSKIY., B.L.; KULEVSKAYAJ, I.V. -
Polymerization of acr7lonitrile under the effect of organ-agnesium
compounds. Vysokom.soed. 7 no.1:184-185 j& 165.
(MIRA 18:5)

BRESLER', Semen Yefimovich; YERUSALIMSKIY, Boris LIvovich;
PODDUBNYY, I.Ya.,, dokfrr-MTm-.--n-Mv-ra.'-**-'
[PIVsics and cbemistry of macromolecules) Fizika i khi-
miia makromolekul. Moskvap Nauka, 1965. 508 P.
(MIRk ISO)
~ ~ i i 1 " ~ --. i Li, ~ i d , i ,;, a ~ ."

LL
11.0
I IIIIIIIIIIHIM 1.11m ill B fl! I I I
li~ H 1 :1 1 L!, J I 1111111MIN1.111141ti 1111111 Ill 18113 1 1 1 .

MI-I IH
H Ili,

YMISALIMSKIY, B.N., doteent (KIyeT)
Carrying of dysentery bacilli by healthy persons and bacteria
secretion In subclinical forms of dysentery. Trach.delo n0-3;
299-302 Nr 160. (min 13:6)
1. Kafedra infektoionnykh bolesney (sav. - prof. G.I. Khomenko)
Klyevskogo inatituta unoverabLenetvovanlya vrachey.
(I)TSMARY)

Y-I;RLJSALIMKIY., B*M* I dotsent
Cortisone therapy as a method for the differential diagno3is of
JaUndices of varied etiology. Vrach. delo no.1:59-61 Ja 62.
(MIhA 15:2)
1. Kafedra Infektsionnykh bolezney (zav. - prof. G.I.Xhomenko)
Kiyevskogo instituta usovershenstvoyaniya vrochey.
(CORTISO11E) (JAUNDICE)
.111A 11
IIIIINI III IINIIII 11111,1MI I P 1111: 1

~ ; r . - 4-1 ~ ; Jil ht:11 h I F I I ! , 1' 11 , , I ! I
- I H i
YERUS.UnfSKly, L. 14.
"The Problem of Lym .phogranulomatosis of the Lungs% Arkhiv Patol.., 10, No. 2,, 1941.
Docent., Therapeutic Dept*, Oncology Clinic, Viev. Rengeno-Radiologiw-a Tnst., -1947--

YERVSATX,'4S'M. L.M.
Yerusalimskiy) L.M. "Hemd.:Vxedena", 7racheb. delo, 1949, Ilo. 1, paragnq)hs
SO: U-3042, 11 'I'larch 53, (Letopis Inykh Statey, No. 9, 1949)
'A

102
/132/05/41/069
"5: C2 B004 FV0 10 1
AUTHOM Beletokiy, M. S,., Yerusalimakilj,,M. I.
InITLE3 On the Mechanihm of the Protootion of ftA!j~o(IL~ A grfi i no t
, t. tl-
Oxidation
PERIODICALj Doklady Akademii nauk SSSR, 1960, Vol. '132, No~ 5,
pp. 1122-1124
TEXT% The authors discuss the easy oxidizability of magnesium due to the
structure of its electron sheath. The valence electrons of the magnesium
surface, which are in the 3s ground state, readily react with the
p-electrons of oxygen. These statements were confirmed by experiments.
By introducing neodymium into the magnesium surface, the 38 electrons of
Mg are raised to the higher p-level and, in compliance with the selection
rulep they are protected against bonding with the valence electrons of
oxygen. The experiments are described. In a vacuum ohamber (5 - 7-10-6to1r),
magnesium, magnesium-neodymium alloy (45% Hd), or pure Vg_qAXaLV&,,~re
sprinkled onto a collodium film by a molybdenum spiral vith a cuf ent
Card 1/2 41

On the Mechanism of the Protection of 61707
3/020/60/132/05/41/069
Magnesium Against Oxidation B004/BO11
impulse (7-8 a for Mg and Mg-Nd alloy, 18-20 a for Nd), Of the metal
films thus obtained, electron diffraction pictures were taken both
immediately and after long standing in the air. Fig,, I shows that in the
case of pure Mg, the interference rings of MgO grow more and more
intensive after standing in the air, while a amall addition of Nd
suppresses the formation of MgO still after one month of standing in
the air (Fig. 2). There are 2 figures and 2 Soviet references,
ASSOCIATIONs Vsesoy-uznyy nauchno-issledovatellskiy alyuminiyevo-
magniyevyy institut (All-Union Scientific Research Institute
of Aluminum and Magn2~
PRESENTEDa February 13, 1960, by G. V. Kurdjrumov, Academician
SUBMITTEDs February 6, 1960
Card 2/2

81859
S/020/60/133/02/28/068
S7,2130.0 BoWB060
AUTHORS: Beletskiy, M. S., Yerusalimskiy, M. I.
TITLEs Electron Diffraction Study of Reod1mium Oxides
PERIODICAL: Doklady Akademii nauk SSSR, 196o, vol. 133, No. 2,
pp. 355-358
TEXT: The authors discuss the rather scarce data contained in publica-
tions (Iost and others, Ref. 1, and also Refs. 3-5) concerning the oxides
of the rare earth elements. It follows herefrom that neodymium, sesqui-
oxide is present in hexagonal and cubic modification. A higher degree of
oxidation to NAO , has hitherto not been known. Oxidation conditions and
intermediary oxiges are not described either. For the purpose Of study-
ing the oxidation processes of neodymium, the authors made use of the
diffraction method of fast electrons on thin oxidized films of this
element. A special apparatus with a vacuum of 6-7-10- 6 torr served for
the purpose. As a protection against the "burning through" of the
collodium base, the authors used a copper not (60-130 mesh, electrolyti-
Card 1/3 1-r

81859
Electron Diffraction Study of S102016011331021281068
Noodymium Oxides B016/B060
cally prepared). Electron diffraction pictures of the nonoxidizad
neodymium were obtained by immediately placing the neodymium film in an
electron diffraction apparatus. A thermocouple was then fastened onto the
copper net mentioned, and the latter was heated in the furnace along with
the film.. At the same time, film fragments were kept at room temperature,
and oxidation on the air was studied on them. Fig. I a shows the electron
diffraction picture of the initial film. Table I supplies experimental
data, from which it appears that the thin neodymium film oxidizes with
relative rapidity at room temperature, giving rise to the cubic modifica-
tion of the sesquioxide. Oxygen diffuses in the film interior already at
room temperature with a certain intensity (Fig. 1b and Iv, respectively).
The blurred interference rings of the compound formed points to a con-
siderable distortion of its lattioe. Despite considerable spread of the
lattice constant value, the average value a . 11-36 A points to the
continued enlargement of the elementary cell of neodymium on longer
storing in the air and at room temperature. The authors therefore
believe that the oxygen diffusion0-rogresses in the lattice of the
p
sesquioxide, whereby the lattice is irregularly distorted. By a tempera-
ture rise up to 50000 there also forms a cubic lattice with a constant
Card 2/3 V~

Electron Diffraction Study of
Neodymium Oxides
S /0PRL08' (1E / 1/0 2 '2 1C 6 8~
B016 3060
a 11-05 A. The degree of ordering of the atoms in the lattice rives at
70;OC (Table 2). The authors reach the conclusion that an oxide Nd 203
and probably Nd 6011 results at temperatures up to 700 0C. The compound
corresponding to NdO2 forms with We oxidation of neodymium vapors only.
All of these compounds exhibit a cubic lattice. There are 1 figure,
2 tables, and 9 references: 3 Soviet, 1 French, and I American.
ASSOCIATION: Vsesoyuznyy nauchno-iseledovatellokiy alyumimiyevo-magniyevyy
institut (All-Union Scientific Research 1111titute---of
Aluminum and Magnesium)
PRESENTED: February 13, 1960, by G. V. Kurdyumov, Academician
SUBMITTEDs February 6, 1960 k1
Card 3/3

0:
IMLISAIM-ZKIY., 11. D.
IYERUSALIMSITly
See also IYERUSAM5=7, N. D.

T7-RITSL-T'.'SK=Y
Dv,-,. sluch*,.,~a Tnidy
8, 1949, .9. 383-87.
storv,~~tol. in-ta, 1,7,
SO: Letopis' /hurnp-IInykn 6tatey, Vol. 39, "Osk"a, 1949

j Y.E,-: ) -~' V '.I F'l i - I r~ ~t "i K, t - YV I.
~,~ KI * , P . I .r- r o ~p .
"A Gousal of 7-arly Tabes."
Vostnik vr-prolai7ii i dei,rz:bolo_-J.i (Bulletin of
- J)
].,*o 1 Jinuar,,--;-eiruar- 1951j, k',,,iou4pr?r),

IYZRUSALWKIY, P.I.-, prof.; DATSMVSKIY. B.M., kand. med. nauk.
diagnosis and therapyO by KRi Ast-vatsaturov. Reviewed
by P.T. lerusallmakii, B.N. Pat-sko-isk.iL. Sov, mod. ~21 n'o-7:157-158
OtM 12:3)
(SYPHILIS) (ASTVATSATUROY, K.Rj)

- rratubALIma-Kir,
Nashi avtomobili (Soviet automobiloo). Ris. V. Tsmbi i F,, Volukivillo. Moukvn, Dotgiz,
14.953- '112 p.
SO: Monthly List of Russian Accessions, Vol 7, So 9, Dec 19.44

IMUSAL114SXTY. V, A., Cgl.
A.. Cnl - Author of bror-hurop
Pi-obegs l~ (How to Increase the Iritt"Opale I agol )f V01140don 0 V11,1011
&ft=bll
was critically reviewed by Engr-Lt Col Yu. SEREMAKOV. (Voyennyy Vestnlky
No. 3t Mar 54)
SO: SUM 175,, 6 August 1954

41
HAUMOVSKIr. AoRoo tuthso ratoonzimit,;
red.; (TCFW, Tej:., red. ind-va,;
SMOMTA, O&T.. tekho. red.
CRacing cars] Gonochnya avtomobili. Moskva, Goo. nouchno-tokhn.
izd-vo mashinoetroit. lit-ry, 1958. 264 p. NMA 11-10)
(Automobiles, Racing)

. F- - -7- - . I
"The lrachinability of Alloyc~i Sfn-,r..turn.1
Stan',-.i i Instr-Trimtvoi. i5, "o. 1 101,1,
. I . .
steel.it

ZRAMENSKIT, H.S.9 prof.; Y3MUSALlMSKITj,,,YG4
(Frunze)
Iffectiveness of the signaling system In Ind%wtrlal traum. Sivadray.
18 no.lOt22-24 159. (MIRA 13-2)
1. Ix travmatologiohaakogo otdalaniya Kirgivakoy respOlilmnakoy kli-
nichaskoy bolinitay (glavnyy vrach K.S* RigmAtalln) I rrunzonakny
gorodakoy sanitarno-epidemiologicbeekoy stantaii (glavw vrach Z.P.
Grinberg). (ACCIDENS INDUSMIAL)

GRINBERGs Z*Pe; MMU"QIM4SKTYv__Y8-T'.
V.P
__ -"W,. ow_r
Effect of vanitary conditions in F=nza-. on -the. -decrease lit the
amount of atmospheric dust. Gig, j san. no. 10:74WI75 0 160*
(MM. 1302)
1, Iz Frunzenskoy gorodskoy oanitarno-epidemiologicheskoy stantsil,
(FRUNZE-DUST)

YERUSALIMKIY. Ye.l.
Type, character and localization of industria3 injuxlle3 in saw
industrial enterprises in Frunze. Sov. z&av. Kir. no.2:29-32
mr-Ap 162. (MIIU 15:5)
1. Iz Frunzenskoy gorodskoy sanitarno-opidemiologichaskoy stantsii,
(glavnyy vrach - N.I.Galushko).
(FRUNZE-INDUSTRIAL ACCILENTS)

ZNAI.MNSKIYO M.S.# prof.; YERUSALIMSKIYO Yo.I. (Fninze)
Evaluating the effectivenesu of the signaling nystem in Industrial
traumatism. Sov. zdrav. 21 no.5:59-62 162. (MIRA 15;5)
1. Iz kafedry operativnoy khirurgii I. topografichemkoy anatomii (zav.-
prof. M.S. Znamenskiy) Kirgizskogo meditainskoffo iq5tituta.
(INDUSTRIAL ACCIDENTS)

FOMINA, A., doktor khim.nauk; )MRUSENK0, V.
Oxidative decomposition of kerogan in dir-tyontma stAle by alka2lne
potasaiwa parmanganate. l7v. AN Ent. 3SR. Sor. fiz,-Mat. I te]eh.n_q&.
12 no.21189-197 163. (MIRA 16slo)
1. Academy of Sciences of the Estonian S.S.R., Inst!tute of
Chemistry.

SEMIOTROCH&V) V.,L',.; BARAK, Ts.m.; Sf'rISIN, M.P. p POPINUN, 1.0.;
YZRUSIIEVA L.F.; ILISJIL~Ap O.S.
Fasteurellosis in ran in Kazalinskiy District, of Kzyl-Crda Frov-ince.
Zhur. mikrobiol., epid. i immun. 42 no.EI:114,3-11+4 Ag 165. (MIRA 18:9)
1. Srednea7,iatskiy naucbm-issledovatellskiy protivochumnyy in-
stitut, Alma-Ata.

YERUSHKOVSKIY, Tu.S.
Strict enforaemt-nt of gorerms-ital regulatianu. vej6t.sviazi 25
no.2:21 F 165. (MIRA 18-.6),
1. Za7p-duyushchiy otdelom t7ansports i sv7azi Komitets partiy-no-
,osudarstvannogo kontrols Mosk6vskogu rodekogro kamitete
7 L. 90
Nommuds tieb a okay partii Sovttskogci Soyuzo I lloskwrskogo garodskogo
Sovets doputatov trudynshchikliftya.

-YERVANDYAN, S.G.
Pollen fertility and
artificial rrutrient
79-84 Jl 164.
the growth of pollen tubss in p-otataes on
media. lz*,r. fil, k-m. SS.R. -9ijI. n;--UkL 17 no 7;
OMIRA 17: 10)

YF-F-,JANDYAN-, S.G.
~ I ..-
*j, morn' --;zsnf-,tLc rr,~~c~3ses ir at --c- is .r ri. -411 Arr- SSR. Plsl.
nauki 18 no.335C-56 Yr 16154 ( M F2,A18,15)

YEERVANDYAN, S.G. -
.. . .... m ~ _. .-. .
Macrosporogenesis and development of the female gametophy-te
in pot.-.toes, Izv. AN A=. SSR. Biol. nauki IP no.21:76.-E!
N 165. (MIRA 19:1)

MVAVTOV) Goj.inzh-v
For the defense of clear skies. Tekh. ml. 31 no.6-.:LP~-Zi 163.
(14IRA 16-7)
(Anti.-aixoraf t gima)
."
~~i I

TNRVK'STAN, I,.N.
'r,.1- .
Plastic revair of ertensive cranial defects with polyvethylmeta-
cr7lats, Sovet,med. No.2:22 lob 31. (OUIL 20:6)
1. Candidate Medical Sciences. 2. Leningrad.

SEROV, N.A.; YERYAGINA.. Vp.Aj
1 ,
lxperim4mtal stability testing of conieal cooling, tawnre.
~6ucb.dokl.vy9.sbkoly; stroi. no-1:153-158 159.
(MIRA 12:10)
1. RekoTlendovana kafedroy stroitelinoy "ekhanlki Laningradskogo
inzhenerno-stroltel4no& Inatituta.
(Cooling-towers-Tenting)

YERYAMKIN, G.I.
Cystography by double separate administrations of contrast media.
Urologiia 25 no. 4:31-35 JI-Ag 160, WDU 14:1)
(BLADDER-RADIOGRAPHY)

BALAMATOV, N.N.; YER'YEVO B.A.
System for exact regulation and stabilization of the-alectron
energy In a betatron, Prib. I tekh. ekap. 8 no.,4:24-2?
Jl-Ag 163.- (MIRA 16:12)
1. Nauchno-issledovatal'okly inotitut yadernoy Miki.
Moskovskogo gosudarstvennogo universiteta.

"l-t I:',,; j ~LIIRI "MLIMR, , mwlu laq! tila I rwllC; IUll 11 4 1~;, , ., ". -ad. 1.4--r#3111
. -At', Fl,~, , ".,-1.1- .1 -.1, - M- MOR ... IMINININ R................. ............... ....... " "i ii ~ - ~ i.. I.gm. ~ ~ lLfUl-! -
.1 "1, -- ----- ri~
YERYGIN, D.P. (Moscow)
4WAWW'-~tF-,"ZI;~M30,.
Acquainting students with the manufacture of glass and cauent.
Xhim. v shkole 9 no.4:28-34 Jl-Ag 054. (MLRL ?--8)
(Glass mamdacture) (Cement)

YERYGIN, D.P. (Koakwa)
Industrial training of students in a chemical plant. Xhim. v shkole
11 no.4:65-67 JI 156. Wn 9: 9)
(Industrial edueation)
I i-4

TIMIN, D~P,,(Mookva)
Industrial excursions carried out by chemistry teachers. Xhim. v
shkole 13 no,1:63-65 Ta-7 158. (MIRA 10:12)
(Chamistry-Study And teaching) (School excurmlone)

YMGIN, D.P.
Methods of acquairting students with some concepts of polymers.
Uch.zap.'IGPI no.225:164-174 164- (IIIIIPA 18:32)

YERYGIN. D.P.
Production practice in chemical technology in pedagogical
institutes. Uch.zap.MGPI no.2251256-264 164- (MIRA 18:12)
II'Vilild ii-II:!IIIET 'flPh 1;1~1 I

TMOIN, D.P.
Industrial training of chemistry teachers, Pollt ekh.obuch. ro.3:
78-80 Nr 159. (MIRA 12:4)
1. Hookovskly gorodskoy inatitut usovershenotvovanlya uchitele7.
(Chemistry-Study and teaching)

16111 '1044 1 1 ~11; 11
YM7~GIN
School club at the PodagogicAll Xhin. V Ohk;OXP 26
3 ' 3;
no. 66-43 My-Je !61. 0111:4 14 5)
1. Pedagogicheskiy institut imeni V.I. Lenina, Moskva*
(Chemistry--Study and teachizg)

7. TO 7
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M, [ I
............
21-859 ~~ftYGIIJ, P. S. vliyaniye ovodnennosti pochvy na dylkhanilre
korney risa. Trudy Krarnodarsk. in-ta --fAshch. pror.,~-stij,
,rip. 7. 1949, S. -1--6-
SO: Letopis' Zhurnallnykh S'U-atay,, 1,,o. 219, 1!oc,!'va,, 1949
~ - -- ; ; i ~~; E i~ 1.

USSR / Cultivated Plants. Grains. M-3
Abs Jour: Ref Zhur-,Biol., 1958, No !6, 72935.
n
Author : Aleahin, Yo. P.; Yaryt~i A k q__.-
Inst : Kuban Hice Experihiental Station
Title : Preplanting Treatment of Seeds for the Purpose of
Obtaining Thick Rice Sprouts.
Orig Pub: V sb.: Kratkiye ito6i nauchno-issled. raboty (Kub-
ansk. ris. opytn. st.) za 1956 g. Krasnodar, "Sov.
Kuban"', 1957, 37-41.
Abstract: Soaking seeds in a solution of 2,4-D and potassium
salt of hetero-auxin (140 mg/1) increases germina-
tion when sprouting on unflooded soil. Germination
of seeds in anaerobic conditions with temperature 2
and ~-':-?O increases the stability of the rice --prouts
during deep floodin.. Treatment of the seeds with
(NH8)2SO4 guarantees thicker and more viable sprouts.
V. Yakushk-ina.
Card 1/1

USSR/Cultiv.--itad Plants, Grains,
Abs Jour : Rof Zhur-Biol., No 15, 1958, 63135
grain moisture increases in the fiald~ the
0 rice quality decreases. 0. V. Yalmshkina
Card : 2/2
TI
38

CMITAY
CAT_L'*01VZ
ABS. JOUR.
AUTHO
INW.
T ITL:~
ussa M-4
RZBiol., No. 1959, NO. 81034
Yerygin, P. S.
'A Fla-Z-1MI-T-0 I- I. =Ce n c e s
Physiological Substantiation of irrigation
I'
Of Rice by Ploodiiig.
0711 G . PUB.:Sb.: B.Lol0 asnovy oroshayem. zeinled. ~.oscow,
AN SSSR. 1C,
571 lfl,-171
ABMIIACT : Data of the All-Union Rice Lxperinrent 6tation.
In the producluio.n of rice the water conditions o~' the soll
vary during the growing period. During, them perlod. OIL' Seed
germination a soil that iz;,~ not flooded is favo_--able to the
development of a den-se, stard of seedlings. WIth ii soil
moisture contert In excess of PO-~O~u of zapillary water-
holding capacity, gf;rmtnation of riCe 3eedo is InItibitea
the- naturp of germin'ation Is laltei-ed (.LristetAd or tiie
Cel thO 00100ptyl I)OR1119 tO d0VL-'1-,')P) I J*1~31)1;ViAtAon r0,(~ I.$
decreased, ano also t1,(j activity of catala_,;e, wid :-achr~ra::C,.
On tbe other hand, by t:he end of 'the period of emerging of
seEdlings, flooding provide-s conditions, that are more
CAaD- 112
2/2

-Y3RYGIEI-,--P,S,;-VOLODARSKrY, 9.1-0
low
Ivan Sergeovich rosenkols 60th birthdar. Bot.shur. 42 no.6:960-961
Je 157. (KIRA 10:7)
1. iubanskly sel'skokhozyFqstvennyy institut.
(losenko, Ivan Sergeevich, 1996- )

20-5-49/54
AUTHORS: Yerygin, P.S., Ryabchun, 0. 1.
TITLEs The Root Structure of the Rice Plant as Dependent on the Water
Regime of the Soil (Zavisimost' stroyonlya korney rina ot vod-
nogo rezhima pochvy)
PERIODICAM Doklady Akademii Nauk SSSR, 1957, Vol. 115, Nr 5, PP. 1020-1030
(USSR)
ABSTRACT: Rice is known to be cultivated at different olkological con--
ditions. On rice fields which are 2 - 15 cm wider water,, nearly
80 -it of the entire rice is cultivated. The remainder is either
flooded 20 cm and more or is harvested on f:blds that are hardly
flooded at all during the entire period of vegetation. With
such excess and insufficient degree of moistening the yields
of crops are only half those obtained by more shallow layers.
The broad dispersion of conditions of growth has since long
caused research workers to study the anatomy of the rice root.
Among other things, the schlerenzyma cylinders of the rice
root quickly lignifies in the case of dehydration and a drying
of the soil. The absorbing surface of the roots is increased by
Card 1/3 the formation of lateral roots and little hair-like formations.

20-5-49/54
The Root Structure of the Rice Plant as Dependent on the Water Regime of the
soil
anatomioal atructure of the root (table 1). The main causes of
the difference In root structure in the case of floods as com-
pared with moistening were processes of growth. They were in-
tense in the case of flooded roots, and therefore the number
of radial cell series as well as of their cycles inside the
root increase. In the central cylinder a larger number of meta-
xyclem vessels was formed. The increqse of the diameter of the
central cylinder is also due to the thickening of the cell valls.
When moistening they are from 1 1/2 to twice as thick as wher
flooded. All this tends to show that moistening does not modi-
fy the anatomical structure of rice roots to auch an extent that
this might be called a change of its hygrophytic nature. There
are I figure. I table and 8 Slavic references.
ASSOCIATIONs KubanPRice Testing Station (Kubanskaya risovaya opytnaya
PRESENTED: by A.L. Kursanov, Academician , Aprii 6.- 1957
SUBMITTEDs April 5, 1957
AVAILABLE: Library of Congress
Card 3/3

YEIMIN, P.S.; AIESHIN, Ye.P.; SAUTICH,, M.A.; FENELONOVA,, T.14.
I . Effect of gibberelic acid on rice. Fiziol. ramt. 8
no.4,.460-1+66 t6l. (MMA 24.-.11)
:Le Kuban Experimental Rice Ratio% Krasnodar,
Gibbere3Uc ',ac4d)
~'Riee) I

A, A.
Collective Firms
Inspection can, mittee of the collective farm at work. Ko!A. proiz. ~2 ~ro. 6 19~2.
Yont~nly List of Russian Accessions, ibrary of Congress, Octobr-r, 1952,
.. !... Im
. :

LUZGACHIIV, I.M.; YFARYKALIH, V.N.
,qMUWAM",
bgKft~&"
Compressed air device for extmeting piles. Ratsiftebr.predl.
v stroi. no.58:18 153, (MIak 7:2)
(Pile driving)

t~-ACC-Mgz AP6001698
AURTHOR.- Y
erykalov, A.
ORG-. none
I
E CODE-.
TrrLE: An estimate of the accuracy of the variational method
SOURCE: Atomnaym eaerglya.. v. 19, no. 5, 1065. 462-463
TOPIC TAGS: w-1clear reactor charactertatto, varlattonalmethbit
ABSTRACT: In many reactor proble= It [a impdrtant to find Plevriti-MAI dintettntowi,, kvithout
a detailed atudy of neutron distribution. The presimt lettar diamwittas orle of the exi,- T
I f.1 11,
approximate methods which parmitz the estimate of the uppler as Nvr;~,U a.9 o~, the lower I i r'. A-9 fo r
the c1genvtflue of the self-adjoint operator, The neutron flwt V' In 11je ret~jctor Uidescribvd "'~y
the sinTle group diffusion equation with the time constant
L4)=K"v.
and the accuracy of the. eigenvalue Is estimated by a method analogaus to Ahe one usmi by
G. Temple (Proc. Roy. Sao., 211A, 204, 1952). - T~e elkenv~dua ;L 0 Iso in the one aide bounded
by
-qL. -1; 0
(2)
ccrd 1/2 MAP: 62~ -39,fil

ACC NR& AP6001698
Y"o, (rj Is a trial solation), and on the other by
X4 < Q +6q,
where
(41p
For a reactor in the critical state the relailve errdr in readtor afte, &,eIj ixot e=eed 0.3%.
The author thanks Yu. V. Petrov. G. q,_kangoy, =d Ye,_ _A, r their valuiible
_qLMApy fbi
advice =d disausai~n-of-th-e-i-es~its. OTt& aLt. has: 9 formulas.,
SUP 90DE: 19, 20 SUBM DATE-r 13FebGS

W.A.
13MTKAW
Kicrodetermination of protherombin in blood; Ltibe"4elo 6 Ei.e; 41
noi4sl&19 J3,-Ag '58 (NM 11:9)
(PROTHROtani)
y

U68R/ Analytical Chemistry - Vitl, s1t3 of Orgunic Substancea a-3
Abs Jour : Referat Zhur - Xhimiya, Ho 4, 1957, 12156
Author : Spryskov A.A., Yerykalov Yu.G.
Title : Quantitative D6tenhinatlon_77'lsomers of Dichlorobenzenes
Orig Pub' Zh. analit. khimii, 1956, 11, No 4, 492-494.
Abstract After determinatioii of p-dichlorobenzene (I) by thermal
method, and in-dichloroben--ene (II) by the bromide-broma-
-%-.e method developed b,., the authors specifically for II,
o-dichlorobenzene (III) can be determined, in ini:ccures
of the three isomers, by difference. After ascertaining
the content in 1, from the solidification point of the
nixture unde;.- investigation, this mixture is subjected
to nitration and reduction, in order to determine T-I by
bromination. SwVlc of the substance being aralyzed
( - 1-5 9) is mixed with an equal weight of water, the-
re are added, after coaling, dropwise and within 30 Mil-lu-
tes, 15 g RNO (Sp. Gr. 1-5), after -1 hour the mixture
3 2
Card 1/3
?
I If 1111111111111 ill F-1 F~011 71117

USSR/ Analytical Chemistry - Analysis of Organic Substances G-3
Abs Jour Referat Zhur - Xhimiya, No 4, 1957, 12156
mixture is allowed to stand for 30 minutes in a sealed
vessel. Thereafter 2 g KI are added and after 5 minutes
the 12 is titrated with 0.1 N solution Nn 2SO in the
presence of starch (to determine the amount o.~ dichlora-
niline formed from I and III) (S ). ilanount of dichloraiii-
line formdd from U-is Sl- S 25/300 - S2, hence the con-
tent of II in the raixture in: (in %) S1 100 / S , 100/25-
Since the content of I in the mixture is known from the
solidification point The content of III can be calculated
as the difference. Error in determination of each inomer
is - 1% of the sum of isomers. The described procedure
has been checked with compounded mixtures.
C"rd 3/3

SOV/ 79-2~8-647/63
AUTHORS: Spryskov, A. A., Yerykalov, Yu. G.
TITLE: On the Crientation of the Sbu3titution Ln 'Uh-e Lroratic
(K oriyentatsii Prii zameshchenii v arorrtti&eskori ryadu) III.
The Isomerization of Dichlorobenzenes (III. Izomerizatsiya
dikhlorobenzolov)
PERIODICAL: Zhurnal obshchey kh:Lmii, 10581 Vol. 28, Nr 6,
pp. 1637 - 16h2 (USSIR)
ABSTFUCT: The aim of the present paper is to investigate t1he isomerizaticn
of dichlorobonzenen and to obta-hi states of equilibrium among
Ls , from tn~ lichloro-
the I omers on various conditions. Proceedinp a i (
benzene a state of equilibrium ainong the lsorrrs was obtained
on its heating with aluminum chloride at 16-00. -In the equilibrium
mixture were 16Z ortho-, 30,'0" Para- and 5h% metiiisomers foiind. The
velocity of the isorierization procoss depends on thl-~ amount of
aluminxim chlorido. Bot0doo this i.'jo1YY1)"-v)1AO)1 SI-so A dU11)'-O-'No1-tJO11-
ing, takes place which in the experimetitt, on t. henting- up to
1600 for 5b hours, yielded aboui 1,6'"" monochlorobenzene and Up to
2,8' of a resinous product. The results of the e.,q)erirrents tend
to show that on the heating with aluminu:,n chloride a dehalogenation
of dichlorobenzene takes place under the formation of 1ronochloro-
benzene as well as a formtion of chlorine. rhe latter chlori-nates
monochlorobenzene and forms a rd-cture of dichloro-substitutents.
Card 1/2

~)Ji the Orientation of the Sbustitution in the Aroma-tic SOV 79-2~-il-L,"T/163
Series. TIJ. The Tsonerization of Dichlorobenzenes
Tha r)rocesq of dehalogenation Is represented Iry Uie 1,11.ven scheme.
Hydrogen chloride forms in this slystem by conversion of alumLn,,;,-.i
chloride with a small amount of air hunidity. ThiLq ',;nis chlori-na-
tion reaction in the presence of a catalys:t is reversible. Hour-
ever, the velocity of the counnterreaction at low tenpi~ratun2s is
so low that the halogenation reaction can practically rint b-, re-
versed. ilith incr-ased temperature 4ilno tiic vclncity of tho rev-.~rs-
ible conversion increases. It becomes an isomeri:,ation Pnd it
becomes possible to obtain a state of equilibr-hot. T'here arc-, 1
figure, h tables and 11 ref-nrencps, It of it6iich are Sovilet.
ASSOCIATION: Ivanovs1cLy khimiko-tekhnologicheskiy Institut (Ivanovo ("herilcal
-Technological institute)
SURNITTM: May 11, 1957
1. Ghlorobenzenes--Isomerism.
Card 2/2

5 3)
A6THORS: Spryskov, A. A., Yerykalov, Yu. G.
_~_ 1. 4 J"
TITLEt On the Orientation in the Substitution of the Aromatic Series
PERIODICALt Zhurnal obahchey khimii, 1959, Vol 29, Nr 8,
pp 2798 - 2803 (USSR)
ABSTRACTi The authors carried out earlier (Rof 1) a number of experi-
ments concerning the isomerization of diatilorobenzenes at
12o and 16oo. At 1600 a state close to the balance between
the isomers was reached and the composition of the mixture
in the state of equilibrium was found. However, the balanced
0
state could not be achieved at 120 . In the present paper the
further attempts at isomerization at 120 0 are described, the
results of the isomerization experiments at 100 and 1800 and
of the experiments in which hydrogen chloride was introduced
into the reaction mixture are discussed. An investigation was
made of the isomerization of the o-, m- and p-dichlorobenzenes
at 120 and 1800 in the presence of aluminum chloride. In 0
order to achieve the equilibrium between the isomers at 120
many more than 1000 hours are needed. The mixture which is
in a state of equilibrium contains 12% o-isomer, 33/o p-isomer,
Card 1/2 and 53% m-isomer. At 1600 a state close to equilibrium is

On the Orientation in the Substitution of the SOV/79-29-8-791/81
Aromatic Series
reaohed after 20 houre no matter fror" whioh iaomer onet had
started. It was found that the isomerization rate decreaseu
at the introduction of hydrogen chloride into the reaction
vessel in proportion to the quantity introduced. The removal
of small quantities of HC1 from the system also reduces the
rate of isomerization according to the reaction mechanism
previously suggested (Ref 1). From the experimental data the
constants of the isomerization rate of dichlorobenzenes at
1600 were computed. More on this computation is found on
page 26ol. The retarding effect of large amounts of hydrogen
chloride on the isomerization may be explained according to
the scheme given in the experimental part. There are 1 figure,
3 tables and 3 Soviet references.
ASSOCILTIONt Ivanovskiy khimiko-tekhnologioheskiy inatitut (Ivanavo Chemo-
technological Institute)
SUBUITTED: June 2o, 1956
Card 2/2

SPRYSKOVj A.A.; YERYKAWTV lu.G.
Orifttation Ln substitution in the &rmatir, series, Part 7t Catalyats
of the isomerization of dichlbrobenzenes. Zhur. 0b,, khim. 31 no.l:
2.92-296 Ja 161. (KUIA 142 1)
1. Ivanovskiykhlmiko-tekbnologichookly inatitut.
(Benzene) (Izomerization)

YERTOWV, Yu.G.,- SPRYSKOV, A.A.
Orientation in the substitution in the aromatic series. Part 9:
Equilibrium between isomers of dichlorobenzene. Zhur. ob. khim.
31 no. 110721-3722 N 161. (MIM 14: 1-1)
1. Ivanovskiy khimiko-tekhnologicheakiy institut.
(Benzene) (Substitution (Chenistry))

T14 INA Yu. G.,- SPRYSKOT, A. As
Preparation of zeta-.4fichlorobanzene, and 2.4-disuhloramEtro-
benzene* Izve vyse ucheb. sav.; khim. I Min. tekb. no.5:
763-765 162. (MMk 16: IL
1. Ivanovskiy khimiko-takhnologichemkLy institut.. kafedra
organichaskuy khimii.
(Benzene)

,l12MKgffj,_,Yv.-G.; SPRrSKOV, A. A.; YEMOVAO R. M.
Orientation duridg subatitution in the aromatic serinig.
Part n: Zqcwrization of trichlorobehaersa, Zlaw. ob. khim.
32 no.22.*4M5-4028 rD 162, (MRA 16:3.)
1. Ivanovskiy khindko-takhnologichookiy institut.
(Banze'ne) (Isomerization)

YERYKALOV, Yu.G.; SPRYSKOV, A.A.; MATYASH, V.K.
Orientation during the substitution in the aromatic series. Pan LI.:
Isomerization of trichlorobenzenes in the presence of complex cata-
.. lysts. Zhur.ob.khim. 34 no.1:237-240 Ja 164. (MIRA 17:3)
1. Ivanovskiy khimiko-tekhnologichoskiy institut.

jj,Fl I- mnr A% t IT Sr, v
y-, ,pin,c.XOV, PA. A, T. A
C- ientatirn ir -!ubstityition in the arcmatvi(' Part;
pbonanlara of' dichIcro~nivWne iS0,-jl?rizftticn., Mur. Oit'g-,
1 r~w).J-.21L-24 Ja 165-~ t,, I ll A

YEWIXALGIVY
enz~a-' on sn'r,3- ~jt,'-on in zn
(14TRA 18W,
van o,: 5-. m,
oiganichesi".cy kltt-'..-nl~'.

KOPTYUOp V#Aoj ISAYSTp LS-) YERYKAI-OV, AI*G, SPRY.)KOVp A.A,
36
Isomerization of o-dichlorobenzene in the prenerice of UC1 3 1
Mmr. org. khim. I no. 12t2081-2083 D 165
(DIIRA 19il)
1. Novosibirskiy institut organicheskoy kbimii Sibirskogo A-
deleniya AN SSSR i lVanovskiy khimiko-tekbnologicheskiy in-
stitat. SUbmitted November 9., 19649

TERYKALOVA, 0. K.
"Changes in Hemopoiesis During Chronic Poisoning With Tetraethyl- Lead",
Military-Medical Journal, No. 8, p 29,, Aug 1955.
.; - ~v:IH--?-6,,M.-'I
I I : ~:~, pf ?. -~
!!: , i, RT~T;~, . 1;~-t ".
, ~ ~ A". ~m--V "... N:I-~

y 0 V
USS/Mmn atd Animl r~yvlology (B~rmal and Pathological). T-3
Bloodip Mood Diseas"I
Abe Jour Ref Zhur - Biol*,, Yo, 16, 1958o 74702
Author JOUdybdyjo'P F.V;., :Yerykalova, O'Ke
inst
Title On the Problem of BLypoplastic OXA7 Ajilastic Anenias
Orig Pub Proble gemstolo L perelivaniya, krovi,, 1957P 2.. No 3, 14-
17.
Abstract 10 patients with aplastic anemia (AA) and 6 with hypoplas-
tic anemia OW were examinade The Ulness: developed due
to long effects of vapors of othy2ate4 benzine, dyes ard
other reeksons, Ma some cases of AA.. aigne were observad
of megaleblast hewpoicsis (mgmloblaits In the bone =r-
raw, meaulo- and macrocytes, the colored irAicator hi&har
than the unit)* In the beginning stage of AA specimen of
the bone mrrov by oterrA puncture shwed the number of
nuclear cells increased and the erythropoiesis stren(,tthened.
Card 1/2
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GEMRO~I- '-4.8. flotsrmt; -1,0.; YFeRYNAUVA VY!7-UDF;,NR(.'), SI,
9
~"-- 1. . -1., -'-- -.4 . .....
L f .! -, i f. - ~ ~: r.: -. -
Direc' tranaCus'on z~' tlie biccd I.n P-rn7~- "!,a Ir E -
I -- - .
the synd-rcue of acutit fibrinoly3f s. Vcen.-med.zhul,. I C~I, .