SCIENTIFIC ABSTRACT YESAFOV, V.I. - YESAKOVA, R.

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CIA-RDP86-00513R001962920002-0
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December 31, 1967
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SCIENTIFIC ABSTRACT
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a INHUM111,01 Tf4 0 t do", "btat'll dcQ G C. 10 ~10A Soo. o 00 es goo 6w. bf. gee 00 Q 11 1 goo JL *am Ixes gee Igoe gee Kee U09 &$*.ILA 14T#AkWWdLU~C*A1wcG41wOtA WOO If SA 6 il 0 LI TIM.- - ~ww a a~i .9 1A -3 a v 00 0 0 0 0 4.16 0:0,0 0 0 a OID 0 Ma 0 0 a WO a fie so so 0 0 *ewe 6 0-0- 0, 0; 6-1 0 0 0 Co 0 0 * 0 A 0 0 0 40 mallfluffmill"irm. MIME VIM 11.1. EFF"11 111 1 IS It 11HMail I H I *0 Goo 6.00 11 11 It I T I 4t Jj #j F-6-111 L.11- i ~t i -0 is Cw ill's doldifft" god detOC111111111AIAN Of (U44241 -00 Illmd f-~llaltv j 4 1 ftl ('40 . IV, -k A. WI 14. 111, 41(11% lil)MI1,111i 11411441441 In Forloolm )WAS10"m 4 -144JUMI, IN, lilihmolu' kald"1611111 -00 (C. A, )a. MMI) caltmit be lism univerumv 1.0 on- litilli.4 diem hydrWAFIX"ll with coni"Alell (ImII& Zldc 1. lur -11W 10 ill" M40114111% 11(tht lkilylOrtilAtIC113 111 OlkWW X 11ifloir hifitfilkat Nill, *fv (644ijilpitntwil fliffit 1114"Sa*tm ltjl thr splu-1.41sim .4 'Illodi-1414C. 1111114. Ill 11111 wholl I'm- ittitwol fit it kiiii. of CCL Me hivillinvy method i~ 00 Estfaw still A V. ShImili, '00 Applosil Oww~ (11, 8. S. R.) 14. 10 Vl(ln IM, 114411 kfati%kirf ill f1mi'll.1 11m.40'"m 14A 9. ;vmi Al 0 ful(II041).- licagilindtical its CCI, Is SOVON, tier flia". cacbm with IrmJuptird doublit be", slid h, 14wim. PA*W by thic girmirlatio" of conskleraw amts. 44 h4kion wills. Hydirovabom deAlm with wpowed ifindsic brindo R" bl"IMIlutcd siull!"fT tO Okfm- with Min I"KI'lificstit w1m. a# bisluvra ", The mWilvity Limits of the No- tolillislill" firoiction (IV lWilts. of l4com with 1.34fic-Itel i. 1% 44 thr tollry, whilt, h* noills. 64 SAW. hysirlmoube".1 with dictwo IN% limit Is at (1,1070 01 Oirmns. The lee wrt'rearrIMIXII Willi finwrattil 401-1 milic 44CYvIlOwlitue, Ze 0 *nil dr,~4111sk, mitil *kill. kemw-* isnit deoAd*ne, fly the MvIllider ft"Ifuhl of &I[s. I noi. A. A. thwhillitigh UtfOATL46 C' I I I too o' Vo 1. V 4fill u a" 4!A I !)* A I a N it if 4 1 w it* Vitt" IIK 0 o ::Gooe VIM, I Idle to P1111ttr 11 w ts % Al''I UD &1'#l jill 140U 4 Q'Judbif wgg iv. V. I w, --L- A-0- VC a C C .640 1.60 -00 00 M 00 -x HOSIOV ml L 11- RAlkher, J. Gem, CAM. (U. S. H. R.) U. .00 sumanary); cf. C. A. 1; Was$ is 00 a J!"No -,if-Allmatil. ;Mllatecol 14 %V411MOCt with 11. jjtvouni~ 0 uAry hydiulytic deaVap of the latter tultsmuputictots- 00 a t MI. trat" W" n"471 Goakk lot the pft*MCQ of du - -00 00 a yklojal XV&U amu. of k"loldi"Awd" qua 40 k:%4mcmejiqo! #p& the kluer locin 04D 9 m iwkW its the! td owi*. M. [Is* (flum Moll), I'M lactwill welt 0 k1mostutted try Z010CM4411 LILAII411418 At AlKMj 10'. Withel bougal :00 00 PaCkOwAlcos Y bictwastollf the yiddistbellaythfamacatulle, Me.CO was ithm" to be lacrt W woolkneal lima ou to" tulto *0 with Pif-WAMO ma"tat Vool P"AMCM 11-111,49 OU oe slow, coo Wall; the samit remit was obWated wheme MvWCO w*4 411141111 is III used, 1lvwtrve;rOZ1C.Rd1#30 CVCOO i 1(U Joe coo itanowea". a. 4 1.8'. whilop, Ot 00 tyl 4641de fill 1,11-41, #04111 so '12 idetto am that attiolsbowslith. Thms, p4mMins sclatate to 0 mar lot moll ttlamfol for "hym-kettade condensational. ...... . too "00 bee or to o1 0 1 t& loo Lv 10 all a a it cc It 0 0 0 0 0 0 0 0 0 p oa 0 1 00 4111, 0 o0110111111111 M.A.,90 It 0 0 a a *a so M PION. F 411 IL 11 HFT 1 1 00 A 106 R, ... Cr at dou 0 = pcodwt ARM 00 a fro= CooloaW be tM pen= l il wth vjr4j, 64 00 gg !i zi C. cmmtbok a" 13 aftcr t1to 4".. Rob bmted fet 8 it".. cm koly= er" f e"A of I Na4% ad ftbi. to to", sit 1.4480. tw 1 yi" the mogma pad 11taisicAt by k. %04 , 3 chlitTatkm over K1 JAL A-A C_0_441 :~ ......... .. A. !..00 V. f. Ij 1. 8 11041 Z KlIsaikkigs S 1-00 - . . , . -00 RUM U94 Ifftit"flUch M A- 4, i th NA M lk e WAA C M ad M4,CO RA A 1% V0011. 6 " C1A4athYJdknt,- wtic "Mal We"". Assib -00 a 691m; 5 2. 1 tell'ot) WAR Q"" u 0 AV so At It It It III 1 1 00 0 0 0:; Os 19 joi 0-0-0 0-0 o 0 4664660 0 0 fit fl H q H I r!f1TV',T1i1T1TpM1 O 0 04 a st"ta W thl atia. vet I N. o .. pi. lotbile the we. -00 ow. drw ou- cocc(que. be 1(0- ce 7 S. The poodfict Liam.' Tbesvoct "Castiod"d afifif 9*10 wet disin. at 71 zoo be 0 tto: ~ to on& soup 0,0-10 Imitas etc 0 4 a 0 Go o fj.4 0 tb:*!:O.o 0 0 0 41 4) It 0 too *to : 0 : a a 0- *Wa 0-64 a it u 13 1. -A It 00 so 604 *0 0 .3 :9 00.4 . ............ gradtido 41 M#Ar hyd(Oww"s Mth 4 44pepill 410. IV, 6A I I W'a . 1. Ou wv, 14. S. Ksgothkim OOA A da. C". ku. S. S. R.) 11. 8l8-22(1q4~.(ffnglhb twainvy); cf. C. A. 39, 41W wW W4"ftg ~-Mtuxt (fluln W3 Vd) vu Gddvi &ww6a 4tw 3 hn. to t3.4 -IS*; &her sUnding orhrs4bt ilm"docompa. by (maw Mw,lb"W"obtalmll 16% bw 88% fsV 1.4492, d:6 ted for 20 bn. in a st=n balli in 119*" uk"t in tatome, yidded an oiducs, =Ural tk 1-liadr. wkkhl"-- "ba"ditmdto CrYXL d4rx. dm U=1 EMOr 4m" 4 of didwe. ba go-toO, t%V 1.4410. 140 OAM; beating with Aukk "Ityawe ttvft a A*t. 4 addom Cd tbA amomw dWo of Ow ky*wuboas~- fm the Fw= of it beavy wd tm Od. Am a* Igo-AMU Ur pm a Inhi. of t'j4=0M = xsg.- 2404slyt- . 0.78M. M. Kosiblmd bw 135-34% MV 1.4144.4. i 1;j Aid-$L4 "T4LLlVCXdA, tlrf*ltWC CLAISWKAMM k.)44.7 ~lr 9 AT PO Ll IV it 0 C 0 a It 0 ; ar 111 A p 96446 0 0 0 A 21p - I!; J T il ual CILL11 W: Q%v Itl 10 L 1 4 I'l 4 it I I T M 0 a 4 3 s 0 40 0;0 0 9-01"k-Al if, 0 0.01 41 a 4 0 0 a i a a 4e lot Bee 0 14 1- 004 00.4 -00 uh- -00 a a coal dwAk4 X.A.-Subr. I f. A, ON of C&O". (U.& & a.) 16 T ' I Ire* 41. C, A, $0. Md'..-AiMbe is* 11 im d"m thitit 1ho m4tku of v r-Up (w Woo dwome okk% irAve 1. (~Wfgl W4 *0 114 otmocted to VIAMN 4 im dw WON an owAlu .00 'abk H& 6vrom u1 Be la mW for then Wo nudicalm, ,NO trNiai- butykew an chuactui by this b0mvWr am=# the sod,),; akda hydnywacbma. TOot Witealm eftdido to goocUic for dko" cA wemal aml twatichc4 x4rAcIam W thim are a** tw-MA1001 10440 M hythr We ft"Mufte, di- od tof4lachutyknev fie dwactoiltd Ithow1w. The I me pwodwe il from-waff Is ok"t SOW IM 0 lose goo SOC co a are 0 as* woo OL A~1, kkee at toothilum cwwcufft IRS* o LV a 4X1, 000 0 Is *-Ole a a 0 9 0 log 0 0 0; 0 0:0 IN a a 0 a 4 0 0,0000*6040901 7i to It P 1 1 1 0 13 it to it 4 is 14 it 0 4 At a a Al a 440 -es -00 *00 I'I m ce a too go* goo CO 0 see we 0 09 tie 0 0 Iff4dift the ?."d toutka w1uk 0 kitcom. V. V, .1- udav, J. 00 14. -A-7(1944)(rackit suicintacy); d~ Ing 4txtr- 00 OlLkle (in EW) to 1940 lix" 104 1-15, il by On t 0 * s Uffial workitwop M04 &W k6 trwit, turilaty 'ak. WhIs C4%(CO)JOb$lv* am mV. lWa 60.0%,m-41. t tis sk*wfr4 Ituat, III of Gdvuw4 vitlit cv,pumtd. kgtoml the Me. 04 clopi"Imut of 14W tgcctp. flavors the ffxzrji raiction cotwo. Thomme -ON , mWaded at 15 It 17J% of crude acuAkaes, cantMall of C thyi-l, didwl, b. It 1-1121- Ill" 0.75M, mV 1.4424, and an a dd. sM. of rctl~ -wmc Awnw. Tin t of Lhe - 104 reactim wax atba 4110011:1 I rt. -the abo" pmtddk =.- I -w and the km, b. 114-15- it d." 0.760. aV 1.4M. The kouctum of tU wmldl. wcm dvA. by aziWk-A. 0. M. x1mupcd It G 0 ***ego 40 so 0 00 &-0w 6-00 *a*, .. . ..... ... q- i m AIO 0.01,10 a? 0-6 a 41 (11 0 0 N It. 0 t a *-a-*- I!: "1 141 1; NA I W, A "a 00 00 A 0 AttswpW KYWOHW9 40 d t4Wd* Of the Arks, 1. N'.11.0ftfav. J.6t". Chem. 14. :0 wousary).-Allcoill'tM CTIIL-A: 00 lood"I Im"aw 04 the eow 1=112"'0f Witt. Ifirowls. wom catstwwd ka !seew tILIMN III willp ((W pstAmcof itortimIR A fieVe OM& w4411 liftflaii on A 'Ifim"I 00 d lukth it's %4,411 go. on wl M 1)4111 at IM-W. 1160110 $Io- It oril* diosior 1% a cty%t. w4M. ta. CLS" Iftimit lwtr. ethet 1; to roither IrwIlIr hyd"Ayom, tht" Inowathic all 1111mill - 1111.111tace twtwrvn C stmi N*. 411,11 It prolidifillf tut. the ~trlwulo *0 J%N-.C PhN*ic 00 1 LA %W 1, 1 C-NPft rm"41%. G. M. K,W.JAC.)Jl 09 4 -ee -00 -00 0 .00 too goo too :zo 0 tie 0 fAtt"amraL WINATWO (LAMICArme aJ! Lee (in It" Ali (A AV 'a All AM -mv I IF 0.4; *I! goes 0 0 0 0 0 0 a 0 0 a 0 0 0 a 0 0 a goo a po ~~ 11 I Ili IN I 11 !;IRR NN I dip, I RM Ad 1111:11 Ills- Tr M H Tj ............ SlAve Ufdv.)~ J. cf. CA, 39. 47(14-g~ 40 ~12 'Y sort [UZI oil i'Ailic all. floss. iii reconunctulcif for 0* irtvc4lon of ii(rtw(utC-% at the qUILIMIAry C StOol basting ft 00 gi jdauble bond, such mus in ofelins or its dienct. Tbc amt. of such hydrocArImm-t in liquid-plume Lrackiaig ltimfucts k 00 %h4Mn IU hKIM-C With fi%ing b.p. 44 the firactiont. A ms~wv file halogenation and hypaujitiltuation Of 00 tall is lw(4K*Cd ISOCIA1414111 10 Which the MOCCILAtillil 00 mol. is firo fixed to the double bond, then the atm* sea bitinds are ckaved. And the hatogent are trandonned ftst* as* Itaftj majemai: this esipuills the txmibdity wo the high reaction fate of utch lukigras with other milerWi present intherractirprimixt. Iviantylenr (1.011 g.) and RMUMS. keftjqcnrftacikiavoithitxlittcno.t;)?"ctirmixkdiind4.70%3 gee it. e4 life r-An, siva- treated (tw 0.5 fit. with 2.3 1. freshly U09 004 90%0 Iffelms. Cl Willer, AM llw fog, layer waf, iselill" WVUW W1411 coo 'Id "i1 NA49.. flik'l. anil isnalygird got Ci and ustdim.; 0011 197. a the i1mmy1cut Cliff not etecr Into n=ti=, thus 00, Aj iihowing direct chlorination of imAiny1coft; extemom of A lL the reaction to I hr. gave unreacted bominyleve. 600 71W suptm%ition that hypochkirittation is occompartled by coo AAA fumt chlorinat'w" L"I aho -led by the higher CI Coss- tent than cakd. for all Im, giradict. Sc=t--. fee UM gee 04-2,0 htji. thoweil that SA-29X~ of trillat tailived at is, ve 0 for transfortrution into liar.. %9. Kosorm I !SON Lu7d' jj _&%@.ILA SETAL4,Vle.ACAI,Lfftit&TWECLAIUrCAIM Cleo -tam vid. spi5imilvir wtgaG -0 1 t411442 -it Cite ea door cti t Is. '44 1, m 1. '1 10 alp 4' a a Ir 0 9 d3 a 2 a a It li: oi .1 it it Ic R 0.00060000000000000 a 4 :1 a 6 0 4m 0 a 13) 0 OF a 0 0 Ill 0 a a 0 0000 go a a* Go* 0 0, *G0 :L 0 41 a) 0 Q Q) lji $ 0 ': I z I A I a 4 1 4 if a 11 ~A_ c a I F c if I K k, m 00 & so a fill 00000 0 006 toot all a- " 14 u a w a I a a III jr,134"V31 v lip -a- It 1. JL I I AA '"D .!~! total Itc-CI&III "Cvchv4s "mt. *CkUZ40A GU L GQJus vul 1. Isizo v 3.1il is, Pmnyukova. J, APOW Chm. (111.9 (1945),-The oil from wds of L, ukixwa can be umul in fonmuutbm C4 bish-r'nuit Irying vilv Among Ov vsm- Stitucuts them w" wnd a ucw form of lin.;Uvi~ iwid, whom kdjwbfvmid#, ai. 232-C. obtained by ctin. IA the mj& belauumida with ether. G. %l.-K.tr"Ajx,*A OCTALLUM"AL WCRAIW4 CLAW FWAT ON Will u Is AV to a 000004 um 119 Ruts MO 0 0 0 a 0 0 0 0 0 0 0(0 0 0 0 a a a 9 0 4 Im a is v to 4 A;LIq I '00 "60 j zoo roe A410 .. . ........ .. me IN 1%0 411411 ow mg All lot to No N w1wimsme 5f);-w V. A 4MC3 0 0 0 0 0 0 0 * 0 * a 0 0 0 0 a 0 G, 0 lei so 0 0 0 0 0 0 a 0 0 a 0 0 0 0 11 It lit II It. tit I in A-4 11 ',111 ql 463 4 1 1 Is off 11 11 -0 4 )) W Is I n 11:1 A IF 9; Is, a N As At 111111fli 41 -goomoved J is , . I _L its qjk Gas 0,41,01101,1111 W, fisitivii 1 *4# a dismiss of Adw did Quit 0 4mjv. 94arow , 1~cq fit CtXrrfjpIIiiI 94~f fi!~ ty 10 11-3 W111tit Ed 9;949M off ifissuhli; mr"etrt, I I'Ah'tuava WtAl Nc4tv 1'ruv.. Nvmllosi4i: J. noi 4, Ild-ol. b"Ittle In. dill At : ; ~ % - 41%TM its Ok I 1'eft. f-km. it' I I it list t1wits, (I c IR040. -with the hisportivorst cleigmtr4 (Crist-it'j" i C.A. of i's top ill. N'to fit 1410, Jk) 40, (111154 jovt14 Isil"Atily Ism trillp'. Idth is"Itisr 44 mpAilp folacts ill IV 10 ! .1161 , sold .;.m In too 101 0. No tilt 7% .1wiff, h0mooftmons %t$0 1-4110 its Wi4i. 0U 4, 11 In Ifill 00 9.1. it'"It ..'11 til-4fif, liv44.4- CW41,11h1tv. Littlitt" 4 hichitt %till k4mm 3 :1 a, Nig 41,11 17 it, "M I'l ;111 11"ll. off. Fjtv knoff YW1.14, awl Ili, ko-tva" ttvA I it." moot. litp wool. FAIA-4 ovet a Itth.. 11VOI1114111 as missive vhvs~ I&T ~01111 fly IhAn lit lovit."CO, so 141 a. thr mailluil Ivactim is min. '? fly 1*0 clornest, Arixuatic Gfirtard Ivagrut's f4low OtMind 1.4432 whik it do"Wrof sunt, a mit" I v 5,1 . we too ii, caurste of the reactions to a C"Ater evolut than He or Et Ifulf Plo-I.-AM,11 Adduct W 1114641 ,, . : ills tuA15* . r,4vr a 0 'rignmol trolzointol. In mutfudkikon tit Kohler (CA' a, AS Wit, Coasts. 33.01~, Af, ("U"t-opts is to the asiduct 0 G 11,1111 v 0 00 -3 PC41). 194 1411h, (from 3.8 g. &tj moss! 31 C. Eliths) its 40 cc. cif the qIjuter or to Iso I-..0 V. I'VOIXIMOme In V1.0 wisol Xi sovir (I It". r( - I V tit All C. 3-awthyt'l- 1011ce. RIM.C0*11 W -10" to -11% Milit(flklit (froxti a 4. 43 lei 111111 cv. lifill.). After warklag up Ai -it-- M11 olmt X14 g. IlIttlit) to #0 (v. 1410 omr-La sidyed linivir d 104. 000 so TtImml in C.A. JS, MKIA1. 62.91'~ to yicM. ulm dchyilmlimi as about, but at foskic"I 7 moo, kepi4idoomr, dl* 11.77,10, at' 1.4441A was M-uttat distTi. ovcr Na. WO 11milly a provourv. Knit toot. ro 44) ji 4-osviern-34mv. Into 1711:?J11.~14 0~111441, alp &-nin. ovrr Na, 2.2 C, :+I,.j4-I,34rjeoBmw, b# 234-7 '. -00 . '11* 0 44", in 1W rv. WOO, vqo" to litmoIltor (tmm tht tu.1"r alshilitritle sioldret 1 lit [10 In a) cv. Kst.0 sea,$ A-Mvil "we 211") Solve it AS vill. quittgs. 40.9 AS. 11.5 G. Mg mad dO it"; After StAtitfiltif UrVII'Might 4114141, dOCOMiM. With 1417111 211.11 0 fly Clow 10 K. ext.. trillatclif mi krittissimi Alualam of friv-4titit cm. dista. IN M Over 2 W. KH304 W4 a C. mmyd. CW4464 Go Immoyfoutso. VcrIc A. JJUkr Wkneral Momm N4.*&, And flosAlly purifiled by rptirtlited olmn. tover Nat MIMI. htivh.). 1. Amo, CArms. Sar. 69, I;G" this tdl'. it" 0.70-47. UM VIK4110 Of Cliff, h b-IJIMMI 1010 1 Intilt jr&m; the fortfoscattism 0 1.) " 3.3 C. Tmakir Ara- fitilf-RoU (1) joust 2 sq. Al." at -34% fill assets fit rato thist Age l'. hydritio. ht-Atcd tit to cc. Md'h its a malcoll toilat to f(W fba atliods - JERI if, nmil-5-tv, it" C.14. pkift off its, 2(1 hm. gxve on owid formium an AN asit with 2-4. 74% Ag. jk451 urr rectwAvilif and ZW41 Of it hitalsol 011(wilk too ... ..... .. A;j . ...... is opt; ;41 r 4, man a of, q 4-ft cc tt IS t to Itit still 4 1 0 no 0 #6 of I if N 0 a go-Ser ~f . I ), e,6:41 age memes 609tv 10 0 00 41`10 0 0 04 4! G OLAG) 0 41, 41 M 0 11 q1 lb qh 0 a. unimplivilm oll it 00 lee 00 00 o* 00 00 00 so so 00 00 00 00 ft4ctkn (11) i-s funmd. A cum oficwi Me't-AMI of 1;. IWO-1 t-P. &s-1 qmmliv td catalpt. Atmit 45% W 11 Is mmtxwd of It" tv- "cuk-t Is twiticqVultY With A mrAU qtuatstity of tbt 3-t1 *ma, Thm wctt Wait- fied by mc6in with thip Wgn&W magmt w4 tompoiwo fnKTOM and *tivs. With knoon knimikh. of the PhY%- rx The int I frWOM of tk hightf4miging ritist. ON. n falimm =twowl chiefir 4 4K~Vl chb"Ivt 06-11 *"e imp himber Metiff". At bishrr rcwomi frinpoi. and whels inner ratillya wit *Md. Ifiv frAtIss"I W4L* 11"We svio. 14%; the witt, cd H th-t-tratni and the 1winwy #Atti, Iwolut-I WAV CtMIMIM Witiciat extifely 40(o the MuTvASLA mitiort; the quantity ill highimi-bouitts PCWIK-t abiduchl the trutity 4A toovs-boili 9W-ccActkm ft prixtu"s bicimmm ftom a hV00W to a st"Itkut qt*Ln. tity. 2.3-DiInCthYI-3-pCnt&*A IWO A PAtMjd*TffAdM. tn. 49," Ad (tvin 4,4-diratthyl-2-Matatitif m. M-j C. Wf%f 0 0 0 0 a a o 0 0 0 0 0 0 0 0-0 0 0 a 0 0 0 0 0 0 111 0 0 0 0 0 0 40 OL a 0-0 0-0 0 0 0 0-0 01 0, 0 0 0 0: 0 0. ~O 0 0 0 0 * m 00 0 41 so 00 00 09 0411 00 00 09 so 00 00 00 00 00 00 00 0 0 0 0 0 0 a 4) 0 0.0 0 a a 0 0 111 0 4 lie ve 000 wwx Cost 11 4: 4 oft Ifthmadoft Of the VW4 .tarl(w Hydr OCRIrum V. i (in RUASIan.) V. 1. Eoafov. Zhurptal 0(johchei KAi_ a*-,3 inii (Journal of Ge6ffkl Chemistry), v. 17(19), Aug. 1947, p. 1453-1447. Prysents results of an experimental *nil thromd. Cal vestiration of the bromination of mono- tind !n djo flnx a the aliphatic wries and of tho stnijility of the products. via wa 4.v oat S.44 Alij __446052 .4 -ts to, 10 is M, too 4; a LIP WIF qv WIG 0 0 0 &-a 0_4b_Q_0 40 4p q1 so At -Cis ; ,a I I-a 0 __ ' claw 1C.LTY xt -1% so of to A P a a cl 3 00640 G 411 el'o 0 0) 0 M;W'O 0 04 j 4:041 "00 off coo 4x 0 0 coo &00 z*O we* ESSAFOV, V. 1. "On the Attempt to Synthetize the Ketones of the Cyclopentene Series. IV (P. 1518) SO: Journal of General CheM13tT'.Y, (Zhurnal Obshchei Khimii), xj~~/che-fia airy - B!"ne 87nthssis Jun ~ 49 chemi0try - G-rig=d React-ion %g-ew"In ting ancl Iodinating H4'Dlene 1~ydro- a&-bons Vith Conjuga-ta Do-dBlo Bl=ds,' V. 1. lab of Org Chem, Ural State U,'! ZZMsk, 14 pp mr Obahch Vol Ito 6 - F-"Obtp Far) W,11. 3-mathYloataaleae-2, 4; 2-tortiirv-butjyl-4J. A 2, 3- 4- ... .... . .. isiAnta ot 2, 6-d1=etbyloota&iene-4,6 are LU aare prec-i", &..a yleld. of 2~ e Synthesia _,p=E hemigqa-y Dien Tun 49 -4,L---)t-"IYlpecttuUene--I.,.3 la improved. Studies' & redeticin of throo, fbUcving eystema: 4 .113 3-zetbYlhoptana-3-ou-5 and CZ~W~* (2) criboa toridary alcohols, 2, 6-motbylo~tauv-:; ~-0-1-6 and 3, 4, 5-irimethylheptone-4-ol-3. iftova that in the 464dration of4~, in the Oik-tirateii tertdaty alcohols, baving 1*osenoe of carbinol the groups and C2 activity Is Oblefly cauml by the A-at= Othyl. SWm-1 a 9 Sop 47. C.4 The charactarladca of ale-wasstwated botmos, IV-4 V--I--FA-JUV. f- Gtll- CIMM. U-S-S-R- J9, 1100-1h (1049)(Engi. trgmJAtloo).---Sm C.A. 44,5703a. - E. J. V. of 0.0-ita"ttirawd kowm, IV. V- L RftfOV- ZANO. ObSkAell Nkin. (I. Gen. Chem.) 10, 31WO(INO); cf. C.A. 39, 91 8I.-Summarliat ion of the i privious data (C.A. 33. 3Mt. 40, t4tys), 44, I(Iolb) ah*" that the depre of conjugation of C:C and C:O Unb &U. the reactivity of unsaid. ketones; iocreased num ON R bound to the CO group decreases the extent of owlagatitio. and the same takes ptwe with the R attached totbe terminal C tif the C:C link, Two said. radiculs an the letter C Atom decTe2ft the conjugation even more, Md the action of a %fe-Et combination is greater than that of di-Me at ---' Me And kri-Bu. Introductiozi of a 1~14. R on the 2n4 C Atom. with 2 radic*6 on the Ist C atotti. givell the max. lowering of the conjugation. The iodicatim cf tL- unsaid. ketones may serve to show the SU'acturd types by incrmse of the Wine no. with inemAsed - so. of dde chains from the C atom, of the conjugated in, a '~tj I!n CC14 CAII Alto be used stmILU tot In. derrrtats urith an inm4q*d no. of nulicals bound to tbt conjujultd system, The tipper oceJuption licult to Sivtn toy vinyl littonu and the Ituver Umit Iles with the rooropilp. Itavin; 2 quattroi4rit C atoim% 41thec:clink. Tlic koput-I 11*0 (the methoolsoftorrim. win be give" in Lttr papet) wele: limlyluffam(flopir (1). No 163-5% d:* 0331). Of 1.4124; I-slyhdrmetnethy? ethyl kekw (0). by., 175-7*, d" O.M113. nt" 1.4471); balylidend- welAQWtopyl helow (11f), forts IIU4* 114 O-PZ40 ~V mif im 1.44 0; MI, h" IM-10" 41,0- 0,M73. Ri~' 1.4480; ijoj=y4JrsrneLinr (V). lot., IN -h', d:* 0.347 .0. XJ? 1.4w9; mesityl olkip IVD. t)r,i UN W* d" 0 8,;d.) nV IAM; (VII), bns'164 d'* 0"1, V 1.44"1; (VMI. bw 157-8 . d1o' OAZM. esir 1-411S; he mo-2-ow RX),*b,. 1117-91'. dJ* 0.954.1, mi.' 1.44.151); M, Imu 21Y.1 31, 0 0.11M. nAP 1.44411; licnitylieltnewrione IXI). In, 5 4 45'. and beasyWrilennithyl ttlivI kittitit (XII). in 40 The Inclination wai run by midn. of the ketont to 10 ~). EtOH, rinsing with 10 ml. MOILaddii. of 25 nil. EtOll-Wine soln. und, alirr shAinit, 21A ml. 1W). (0(10*W by 11141killit RILd letting stand 6 MfU. CC Woof. Will titntiots of The etcen iodirse with wt& III is ctled. from the reaction with 10 mi. 2% 910~ and a 2nd fivnUm with thioaWate, beoralwAtIous orwe 4ow in CCI#. the lubta. allowd to $"ad 30 min. Alta mixing, OW dw IIBC pnerated Caw. similarly flow the reaction withmandictch. InAmIa.1pveankxfiwvo.oI3.S- 3.9 with 0.9-6, 117o III formistion, Whitt a 1370-ada. reft- Um pve VA-M.2 antil MIA& resp.; U Its 5 tain. pve 6.4-4.1 Mine no. and 3".31401 [it while Man ado. Vtve 23.7-10.7 anti 07.3-78.817.. Wv.. hi I,, a tulm. Ove 3444.2 &M JOZ~18.07.. resp. (tortm run oat mittle); 11 in 5 * . pvc 3.1-3.0 ladift no. (HI not While 1350 min. gave 15.1-18.6 and 133- IM In 5 min. pvt 8.8-6.9 ant! 35.6-7116/0. gap-; P" in 5 min. 3.24.5 kpdtm no. and a* HI cited,-u . 1740 min.-gave-105.4 and 40.9% Hf._F"P.; a &M a am. gave 4A--6.1 towne no. am au.1-44M-k Ki- VU In S min. cave 36.0-4.6 wine no. and 92-".4 MuNk 17MIntin. pv* 136.7-3.5 and 50.2-66.0%. mp.; VM to 5 mia. pvc 95.3-0.2 and W 0-6 441 White In 1410 Mo. It pvw 1198.11-114.4 ' 'A' IX In 5 min. pint IC9.7-5.7 wo 92,11-72311o. in 3 min. Vsve 3D.6-93 anxi 40.2-2.01%. . 71 . tion cipts. pvc the following tm. Of gubwsUtutim Md S&M.. Mg. - I 17-n and 194 -4. a 21-7 MW I M 404 and 167-41: IV 17-14 ai;J 162-M. U -%an 161; IM 64 aM IM-6; VI 11-10 and 219-6* X 23-19 sall 114-16; VU 179-87 antl 119-141; VM 36-M and 19-18; IX 223-13 aM 50-64. The yl" of CIrlemard rowlim with the ahm ketow, died ( dO.O. #A eba, al='d Vy It'. the mults tattat bo taft pit 1111th w4 Slow IA4dft. is do pa"ek, dithavo tbd GOMM11 hkAff rkib am xMoL wM #no= bilifug a low degree with 1611,1walwev Iffliag mAde tor t1W tam of Ittlalitatitin. V, V. L R#qFOv And V. V. Sergo"Itars. DO. lidedeRvio"t (1) has the highest detim of Conjuguloll ~ notate. In the RCII: CHAc seeks, Le.. hocrease of R kuTexAft the indePrAdOnct of the ethylene band. I does mot teact in aq. a1c. Sain. with 0.1 N Iodine, Whitt Oith 02 ,y "n. the iodine 00. is but IA7% of the"Y'. and e- a 0.5 V arjln. aims but .2,W, Iodine Ito (a! theory), the butifidtfle ama?g tivro and i71V~ .1 & thtorelical iodine no. -det the *vnso 0004ftims. Hot of I &JO ffd Merco and 700 of. 1.4% aq. SaUl'umted 'at 0' wil 121) . AcH 11% 20 ad. 111.0. VC000011till to -2- Om 6 brO-- let o gt&" "itraillbt at 01. atutrifirt(l with AcOH. will uld. With NaCl gave on exta. swith Flo and ditin. in the a crystal of Wille. I4,A7, 4 the product. M.19-21 *, d$1 0 M14. RV 1.4319. firofnin-thm' -1 1 -at 0* in CCL ~10'98% of On theou-11021 uptake, rvvfl wAh twice tbe theore4kul unt. at 11r; no IOU is evelytd. G. M. Kosoiopoff USM/ChemistU - A-1COhOI9 49 Synthesis "The Synthesis of Tertiary Alcohols Using, Campbor Aqe, I'll vy. 1. '-V'esafov, N. I. -Novikov, Lsb- of Org Chem, Ur&I State U? Sverdlovak, (4 pp "ZbAir Obeh-ch- EhLi-m" Vol =- No T d of tert-lax-I me-thylb-orneo1j, synthesized by. a n In"tte-raction of campbr vp =6 high temperet-ares chiefly ecause of enol:Lza- #- hp Y" C=Tnp -'r- At 160C, enoll-zationn of camkthp. 7 1_11-accozDaw-Led by fbimasttbn of secon cu -., cout#lr-lng ca=z~hcr, latter reaction biing-chler ceI yield of tertiary alcohol of r. redu 2/50TV Alcohols Jul 49'.. Synthesis. (Contd) Iftet ayntbevie is carried out at -150 C. At,b4;h 4, chief secondary reaction Is redue- ttou of camphor into borneol. Submitted 29 Mar 48, Charaterflation of m.11-ummitura0d ket;0":-im. V. 9. EsaVjUral State Univ.. Svtrdkmkl. ZAmp. ObykbrK lm~m. (I. Gen. Chem.) ZO, IWO-7(19W); cf. C.A. 44, MI0d.-vrJt-Vnsatd, ketones with nornul "Fucturr me more trAdily hydrolyzed mith 0.01 N thin .ith 0.1 N NaOll; ketones similar to mesityll oxide be- have in the reversemanner. SibeligradAllonotreavivily way be uwd In the cbaracteritation of ketmes. Ketones analogous to trialkylvinyl ketatte, i.e. R%C:CCOR, Rre even more resistant to hydrolysis, In the Ist Wries 0,1-0.2-1. samples were heated In munpuls with JfjO, ().Of ~w OA N NaOli M ml.) 2 lits, at l(W. and the C1111 resction on 10-m1. aliquots uml as the relative measure ig iodine cvmuinpt Ion. cmled. on the star t Ing rnalcti3l. Inn 2nd scrics the alk. Wine satn. was allowed to react with the W-ml.aliquot for 15 sec., 1. 6, or 15 min. so 4-4 to give a measure of the An. Amts. of the reacted ketnum. The results follow. INCII:CHCONfe: in Itif) 01,331"; re- acted, in 0.01 X NiOlf 93.9117a. in 0.1 X 73.5%. C61118- CII:CIICO.Nfe,64.3.$IA,717117,,.reip. hiesity1mitle, 44.C.4, 75.43. 90.78%. EtChleX11CORt, VIZI, WAfl, 92.16%. EtC.Xfe:C]6feCOMe, 37.08. 31.0. 46.4411'0'. 71C Imtones with normal structure have a higher degree (4 conjuralion than acclum In branched-clumin analogs and thi-o is held it) be the reason for their mogt easy cleavage. #1 %1 V-1-fr ak use 61 tas, Wo(mm mcuan in the analysis of somt or- k CNIPOW41., " V . I. V #A Io v tj I Id N . 'NI . ftlhv~ ;6 1 A . It, lIff 00, StAt"06 ''''!WCAMMIA, C Aut. Aim. 61 11A ANXI11411). -Th't Woftwill traC11011, i.e.. the reactkm tit ccmqodi. contS. the group or CII.CM0111- with ' followed by ltyclrolygi-i and Mimi- fialk of Cliff Was Imm. MAO with a,$-unwd. ketoste% wid their timmpontlius krials 11.11 hAvi"t thr4r Xfoulm Ism ca- rblejoi,yielcift Amaltichysle tw sattP. mribyl krimm 1110m) avillt Irm, e.g., aml 4-morcer4i- IHIV. mvffAwr the drill, Imi'M flit C1111 [Torthm 44 41,0- 111owid, 111okJ161011w,4 al"I fit lbell if kP1140 'Ally 11 111i'm hVilr4il"It YkIll 2 iftl4c of ImId. ult-1110 6,11411. 1w ithif Ivilt 111111 itICINTI k0twe If I(Samitate. W 11-~Wh ~SSP,,;M-emietry - Diene Hydrocarbons Apr 52 --,rAtjon ard Iodoxidation of !,I-Dialkylbutadie- ,Sri-, 1. Me-0-7 ~' ?art VIII"' V. 1. YeGafov, Dab of Org Cb-em., Ur-II State U *'%h-1Z.~: Obsh-ch KbAm" Vol XXII, No 4, pp 6o4-6il of dialkyl allyl carbinols in presence procc--~dr in 2 direetiu.-E vith the forma- tA'c= of diene bydrocarbons both iilth bQ .- 4M;~ vith :4 canju8ated system of double bonds. Vhe- vie~~4 or the 11;~tte-r is the !over, the lower tbr deg cC tlyd-rogenation of the allrjl group to 4,Ite c--'t4pol C-atom-s. In 1,1-dimet4lbutadiene-1,3., in 224T36- c6nl-~t to dl-isoprophemyl and berxadieze-2,4 the dbu- IbU -bonds are- less strongly conjugated, and the brami- MUI -,m or iodotidatian proceeds more fuI3,Y. Tertlj:ary ales vith an aLlvl radical split at the bond betvpeen 423-j-1 radical and the C-atom of the carbomyl radical. UUFOV, V. 1. Hols, of Russian chemists in developing methods of synthesis by m4ane of zinc or&nto compounds. Trud,- In4t.1st.est.l. takh. val.6: 318-346 '55. ("M 9 (Zinc organic compounds) IIPA. I T T. ~.T~- I A I ~ 11, li-11 j- IIE- ILLU RM I i t . I : ! , *,, . i ii t, I 11m: i ... h?, , k'-- 11: 41,11,1111111111 INI: 111 1h.11., I li"i. ~11;i I ; I . I : : YESAFOV, V.I. Chemical structure of C H and synthesis of new -phanylated 12 14 1 diene (1,3) hydrocarbons. Part 7. Zhur.ob.khim,, 27 no.10:2667-2675 0 157. (MIRA 11:4) 1.Ural'skiy gosudarstvenny7 universitet. (Chemical structure) (H7drocarbons) AUTHOR: Yesafnv. V. 1. q T! ME': investipal'icn of' tte Thermal Peecmpos;,L:t!,n 71" 1. On thp Ch~-r?-jstry of Oxoniu!n Compourt,J!3 (T, K kbimi4 oksoniyevykil snyedineniy) PPMT,'A'rP~'! 7hurn!il -`~r-oanev K),..-mll, 195.8. Vol,~~ 28~ Nr 9~- P P,~, AMTRACT: Th,~ pver~,TO- investigation aimed at determining the degrep of the binding stability of the 0.1hor mriltickilen of .he w(in,ann,-d compoundsl for this n1so, th,~ method of th,~zf-tialt &.tcmpnei~lon was used which h,3,t3 t,) bi- loreferred. -'n ;n,? q-iven case to other purely cheirf7?-1 mF-thodci T a fi fc-urd tn.-ts the ethers form dietherr wtth mi3pnep-Jurr,iodide t~vrl rihim A-!vti f, viefor. binding of thf,. ivigne-o-im with tho r,f tne etw:-., mol.eculeo whereby into 7.0 MPjrne.I~:.,jm lnti-,e3e and v"he r, ,qhowed 1;hav trie ethers wl*~h Capabi!.ity 1.~, va-ic-,us kinas rF Vard etnexe I,r.!.In oni-- the !.:.-,;M,iodide Invi,-stip~atirr h-i Tri-rma, Tecompocition of Mr-.pr.P!7,. - un 7 Todidn, !. On tiie (`heir.*~~,-., r-1: Compounds eventhough -it vas formed-from magaesium. iodide yipld!i rr,,4jrnwqLtw Jodide of I I"f is obtwined of roi i the other ,) mixture of iodine rind mat,?ri_-:;[uin by from d-i ro'iacement -7,- th~, it ethew 'rom Mg,". V 11 V th e r c --.1i lipht primary nihorv wi it or ;;71., i .1 111,A). dec,-jmuw,31t!cn of the magries.1% iodide dletller6 of the decon-d ir 1- n ai, 10dide il, -o- etber,~l and ioA-ine b, C'M t,~.-,,tct:Lons.. The secc-id strorik4,jy hound to the mq-resium, It wal flir"her ;3ho;qn that :.n.th!: thermal. I , _,rn - he magnes- of thp second kind w i ~ it ft i,;' Aiatic ethers I!--- alkyls Oienoia and resinous form, One moiecill.e fat, ether separates in free state, *he Card 2/3 :,O~Iiv chemical bond of magnesium to the rxygen T n ve 9 t 1 za n - F 1 h f ~ Th,~- rma I rics c a fn r, r) s i t i o n na p-i eri lodi-i(.- "Lher'S. On the: of th - -:., eUrt I.n rht- rnpi-neriinv iodide diether of the wic.-or i p raves f tm. oxnnjum .j8tnvt,. Ir fc,r !.vo decompmiltion W thil maqw,~,:um iodide diether fir r.." #w: p.opr):f,!qj . Th", ZIA 1) fll! i% A S 8 C, 0 1 i~'!N-a :!j,. ari n! f. v i I r ;,I e rv 1 t F. t L9 FMM AUTHOR: Yesafov, V. I. TITLE: Investigation of the Thermal Decomposition of the Reaction Products of Dioxane With Magnesium lodide-Diether Ua6nesium- Iodide and the Mixture of Nagnesium, and Iodine (Izueheniye termicheskogo razlozheniya produktov vzaimodaystviya dioksana s diefiratom yodiatogo magniyap yodistym, magniyam i ameslyu magniya a yodom )II. On the Chemistry of Oxonium Compounds (II. K khimii oksoniyevykh soyedineniy) PERIODICAL: Zhurnal Obahchey Khimii, 1958, Vola 28, Nr 5, ppA 1218 - 1221 (USSR) ABSTRACT: After it was found that ethers with magnesiur, iodide yield compounds of the formula NgJ 2' 2ROR which on heating decompose again to their initial products, it was of interest to in- vestigate analogous compounds containing dioxane. Above all it was found that in the action of dioxane on MgJ 2' 2(C2H5)0 and RMgHal.2(C2H 5)0 (Reference 2) a complete analogy exists. The dioxaqe displaces equimolecul'arly the ethyl ether from Ca--d 1/3 these compounds. Different from the ethers/the compound 79-26-5-16/69 Investigation of the Thermal Decomposition of the Reaction Products of Dioxane With Magnesiur Iodide-Diether , 'Magnesiur Iodide and the 1.1,ixture of Magnesium and Iodine . II. On the Chemistry of Oxonium Compounds Mgj2 with di oxane, MgJ 2' 2C4H8021 on heating separates only half of the dioxane contained in it, the other half auffering decomposition. Thus the oxygen atoms of dioxane have a greater capability to form oxonium salts than the ethers, and they yield more stable oxonium compounds. The most typical oxonium compound of dioxane in obtained in it:n reaction with a mix- ture of magnesium and iodine. This product must be regarded as oxonium salt of symmetrical (formula I) or asymmetrical structure (II). The question if these salts form at the same time, or if first salt (I) is formed which then converts to salt (II) remains unsettled. It is only clear that in salt M if it remains unchanged on heating the P,P'-diiodine-dievher would have to be found among the docomposition-products, which was not observed. The experimental results speak fully in favor of structure (II). Among the decomposition products of Card 2/3 this salt there were found: dioxane$ ethylene, ethylene iodide. 79-26-5-18/69 Investigation of the Thermal Decomposition of the Reaction Products of Dioxane With Magnesium lodide-,DL ether j Magnesium Iodide and the Mixture of Magnesium and Iodine. II. On the Chemistry of Oxonium. Compounds ethyl iodide, acetic anhydride, iodine and mapesium. After all zhe results of the reaction of dioxmne with the mixture of magnesium and iodine prove that'the latter as well as the ethers in this case do not react according to the scheme C4H8O2+Ugj2___;:~C2H4J2+C2H 4Yg as a high-melting dioxonium salt is formed here instead of the low-melting ethylene Aadide. There are 2 Soviet references. ASSOCIATION: Urallskiy gosudarstvenny universitet ( Ural' State University) SUBMITTED: May 3, 1957 Card 3/3 i1gliff JM 5 (3) 3 07/7 9 -- 29 -20/6 AUTHORS: Yesafov-, V. I., Stashkov, L. I., Sirotlr-Ln,- L. 3.~ 9u--v-d-r-ov-,--1-.L., Novikov~ Ye. 0. TITLE: On the Characteriation of the %,P-Unnaturatod Xot3nes,. VII (K kharakteristike a,0-nepredel'nykh ke"Yonov. VII) PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, 1Tr 3, pp 845-849 (USSR) ABSTRACT: The present paper is issued as firat publication of experimental data on the hydrolytic cleavage of the aliphatic aromatic agp-unsaturated ketones containing an aryl radical ahich :.s directly combined with the carbonyl group. Ketcnes of this type were obtained by dehydration of the P.--kotals which had been synthesized according to the method of Grignardl- V. and Colonge, I. (Ref 2). CH3 H IT(CH CH 1 C6 5 3)Mgj (CH ) C-Cmu 4 CH 3 3 3k;uAr 0M. Experiments with respect to the hyd:rolytfc c1pavage of t1he P-ketols were carried out as well. The data of table 2 show Card 1/2 that the P-ket-ols are far more unstable than Lhe corresponding SOV/79 - 2 9-3 - 20/6 -1 On the Characteristics of the a;P-UnBaturated KetorL-,iB. VII ago-unsaturated ketones and prove to be more sensi'live to very weak hydrolysis reagents. Besides, the behavior of the 0-ketols in the hydrolysis differs from that of the a&-unsaturated ketones by the fact that a change of the NaOH-concentratior, exerts a slight influence upon the cleaYage intensity of the P-ketols whereas the hydrolytic cleavage of the a,P-unsaturated ketones is considerably influenced. The rate of hydrolysff.s of the aliphatic aromatic ketones investigated increases signi-fi-. cantly when the NaOH concentration is increaued from 0.01 to 0.1 n. 8 P-ketols hitherto unknown were syntliesized and dz--. scribed. It was determined how far the hydro' "ytJ _- cleava-ge of the 0-ketols and at the same tim. that 4)i thlb a,P--unsatnrated katonon dovolopa and it waa provod Oiat the It~%Lor b,j" little HBr on bromination. There are 2 tables and 4 refer(-.-.-.3es, 2 of which are Soviet. ASSOCIATION: Urallskiy gosudarstvennyy universitet (Ural State Univ6raity) SUBMITTED: February 18, 1958 Card 2/2 50) AUTHOR: Yesafov, V. 1. 30r/79-29-7-5/83 TITLE: Synthesis of the Phenylated Lx,A-Uneaturated Alcohols and the (1,3)-Diene Hydrocarbons.V1II (Sintez fenilirovannykh a,P- -nepredellnykh spirtov i diyenovykh (1,3) ujrlevodorodov.VIII) PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 7, pp 2129-2132 kUSSR) MTRAM In ordar to nolvo tho problomm oonoorti-Ent?, the oopi4rittion of HOIAgX from the fording magnesium halido carbinolaten (Ref's 1-3), the reaction of'2,2,3-trimethyl-5-p-arylpenten-3-ones-5 (Ar-C6H,, n= CHN H4, n-C 2H5U6H0 which may be present in cis- and trans-forms with RMgX (Ref 4), are described here. The experiments showed that among the three homologous ketones 2,2,5-trimeth3-1-5-p-tolylpenten-3-one-5 produces the best yields in tertiary alcohols. These alcohols can be dehydrated only with difficulties. In the Grignard reaction the other two ketones mainly yiblded diene hydrocarbons 0,3)- This particular behpvior might be explained also by the influence of a spatial factor. The phenylated diene hydrocarbons (1,3) of the siructure (III) and (IV) obtained show, compared to the similar aliphatic Card 1/2 compound kV) ~Ref 3), a stronger stability of the double bond IR "'LA1,19011, 19-1011WILUMIM1141111 1.16W41 .11A 1111 ui` 14161 '.W!Li.'.~ WON-A Synthesis of the Phenylated a,~-Unsaturated 307/79-29-7-5/85 Alcohols and the (1,3) Diene Hydrocarbons. VIII in pooition 3,4 and may be broininated t1iorerore only with the separation of a high amount of HBr. The following ob,tlunaciturated tertiary alcohols were newly synthesized and oharacterizedt. 2,2,3-trimethyl-5-P-tol.-flhexen,3-01-5 and 2,2,3-trimethyl-5-p- -tolyihepten-3-ol-5 as well as the phenylated diene hydrocarbons (1,3): 2-phenyl-4,5,:5-trimethylhexadienft-1,3 and 2-p-ethyl- phenyl-4,5,5-trimethylhexadiene-1,3. it is assumed that the stability of the halogen magnesium carbinolates formed by Grignard reaction depends on a,A-unsaturated ketones. There are I table and 4 Soviet references. ASSOCIATION: Urallskiy gosudarstvennyy universitet (Ural state University) SUBMiTTED. March 17, 195ts Card 2/2 p HIP TAUFOV, V. I. --------------- On the history of the origin of the stereocbealml. tbaery R%d the attitude of A.R. Butler and some of his contemporary West Xuropean chemists toward It. Trudy rnsta3t.eata tskh-3Ck-4-;- 135-174 160- (Stereochendstry) (MIRA 13:8) . (Butlerov. Alexandr Mikhallovich, 1828-1886) 86499 S/079//60/030/011/004/026 B0011 /B066 AUTHORSs ly~ lsafov~,V- wI. and Yakunina, G. I. TITLEs Chemistry of Onium. Compounds. III. Investigation of Thermal Decomposition of the Reaction Products of Te'urahydrofuran, a(-Methyl Furan, Pyrrole, Thlophene With (;he lUethorate of Magnesium Iodide and With Magnesium lodide PERIODICALs Zhurnal obshchey khimii, l1q,60, Vol- 30, No- 11, pp. 3572-3576 TEXTt V. 1. Yesafov (Refs. 1,2) showed in his papers that the etherate MgI2.2(C2H5)20 is a very convenient agent for the re4tive estimation of the degree of aromaticity of the five-membered 0-, F- and S-heterocyclic compounds. These heterocyclic compounds may be arranged in the followIng order on the basis of increasing difficulty in the release of the un- shared electron pair of heteroatoms with formation of "onium compounds"; and for silvan, pyrTole, and thiophene with respect to the degree of stability increase of the electron iixti~t of heterocycles: Card 1/4 86499 Chemistry of Onium Compounds. III. Inveetigatiod S1079J601030101110041026 of Thermal Decomposition of the Reaction BOOI/BO66 Products of Tetrahydrofuran, o(-Methyl Furanp Pyrrole, Thiophene With the Dietherate of Magnesium Iodide and With Magnesium Iodide This order is further.confirmed by the experimental data of thermal de- composition of the reaction products of the mentioned heterocyclic com- pounds with anhydrous magnesium iodide. Tetrahydrofuran forms with the latter a compound which decomposes on heating by cleaving the hetero- cycle (Ref- 5). Silvan and pyrrole give, only on heating with magnesium iodide, compounds which decompose at high temperature, also under cleavage of the heterocycles. Also on prolonged heating, thiophene does not react with magnesium iodide. It follows from thin that furan and pyrrolo, no woll. nn tholr nompoundal PlatntitIn t)l~ otnt'o of "If"C'U'Unri In the heterocycloij only tit low temperaturesi, with increfloing temperature, however, this state is diaturbedt in wh1oh connection the un- shared electron pairs of oxygen and nitrogen are cot fron, and otable onium compounds are formed with MgI: Card 2/4 8649P Chemistry of Onium Compoundsp IM Investidation 60/0)0/0100019 of Thermal Decomposition of the Reaction 06TSO" Produaii bf'Totr&hydrofur&no4t-Hethy1 Favah, Py e MoOme With Us Dietherate of Hagnf stun ladidq~' and With, M4V45E slide [ Q'f- Me. Nei which also explains the gooompa'sition of 0- and on heating$ It was thus shtvn that i) tatrahydroturaft &Opf4dds ths diethyl other from X912s* 2HO to-foft'Hj;ItM060 which t9 ddaaajorsA under oloaugs of a Oplecule of totrahydraturano that 2) silyth am pyrrold displAdo one 196196ul~'Of'othir f,~dm R#1242( 029')iOp and Stye adaysun.ds yfth-HpZg w1itch depom .pope under cleavage of the heterocycles; thot )), 1hioghone roaotm neither'with M42020235)20 nor with X6124 1 is Ansumad t at tho', partioiYaiion of hoterostami In the formation of hotoid orgles inorls,166 their: - capability of forming anium denjoundso This &P~%uhption is oupported by the fact that dioxano and to'trehydrofuran give,With 111Zg statlor!som- pounds than simple aliphatio others# Oo Zo gusnotoovas So Ve 8011ALF1 Card 3/4 Chemistry of Onlux casymdeo We 14'reoUldflob Ofsa 010 0041026 of The=911doompisition of ths'laa4fign, 94,6 /011/, 'Oofy ~i 4 Oroductis of TotishydiWimat ct-mothyl ftrant Fjrzrdlzfp DiOPWRO ft'sh Us Dletherate,of Napieflux Udid* ad With mspef4uo lodide and Of So felU srs, thafted for xakinatmiutls ths NAMPLOSS. IMF$ aim 11 referenaess 5 fiavisto 4 No 2 British# SM 2 damuss- ABOOCUUM gralf ekty sm"reftsusly U"Veslattot (1142 0$640 valverfiltyr wi=*-=$ AuPst I So ~ 1959 ftr4t 414 IMT YESAFOV V.I. Characteristica of dletertl=7 ~-glycolv. Pal-t 1. 7,bu--.,,b.kbJm. 30 no.10:3272-3275 0 161* OMA 14:4) 1, Urallskiy gosudarstve=yy universitet. ~Glpols) PHOW11111 ,W11 11;h; A 3 ?0 -,/190/62/004/006/002/026 P'l (11 AUTHOPS Tager, A., Suvorova, A. I., Goldyrev, L. N., Yesafov, V. I., Berestova, V. L. TITLE: Effect of the chemical structure of the plasticizer on the vitrification temperature of polymers. I. Placticizinc of polystyrene withdiphenic acid and naphthalic acid eaters PERIODICAL: Vysokomolekulyarnyye soyedinaniya, v. 4, no. 6, 1962, 803-808 TEXT: Thermomechanical curves were plotted for p6lystyrene (Pst) plasticized with 25 moleJ;o of: monomethyl-, monoeth-y'--, and monobutyl diphonatei'dimethyl-, diethyl-', ethyl-butyl-, d-.*b-,;-y.-, ethyl-octyl-, and dibut~l napi.,,halate. The diheptyl diphenate; dimethyl, diethyl, and synthesis of ethyl-butyl diphenate (b.p. 167-168 C/1.5 mm Hg, MR 91-69) and of ethyl-octyl diphenate NR 110-57), now produced for the first time, will be Dublished. The compatibility of the plasticizer with PSt was studied on the basis of the critical mixing temperature, which lay at 100-1300C with diphenic acid monoester, below room temperature (sometimes Card 1/2 .,,/62/CO4/006/CO2/C26 Effect of the cheirical structure ... ~'l o1 /.B1 10 at - -50 0C) witr- of t-his acid, and at room temperature with naphthalates. ..Js-uilts: (1) The vitrification temperature, TV, of plasticized PS-. drops with increasing compatibility. Pure PSt had TV = 1050c, PSt with monoesters had TV . 40-700C, PSt with diphenic acid diesters yielded the lowest TV. TV dropped with increasing length of the alkyl radical: ethyl-octyl diphenate yielded TV = -110 C; the naphthenates showed & low effect (TV . 9-480C). /2) With increasing content o0 CH2 J. links in the alkyl radical, T of diphenic acid dieaters approaches a minimum at n CH2 a 10-12, and then rises again. (3) The structure of the aromatic radical of the plasticizer affects T : diphenates (and phthalates) plasticize more intensively than n phthalates. There are 3 figures and 2 tables. ASSOCIATION: SUBMITTED; Card 2/2 'M.R~ Urallskiy Gosudarstvennyy universitet im. A. M. Gor1kogo (Ural State University imeni A. M. Gor'kiy) March 21, 1961 )P'277 s/iqq/62/004/GC06/003/026 Tager, 'Suvorova oldyrev, L. N., Yesafov, V. I., AUTHORS Topina,Ai. P. A I `G T II'LE: Effect of the chemical structure and z'-ie si"e of ~he plasticizer molecule o the vitrification trilmperature of polymers. 11. Plasti~czing of pol:fmethyl methacrylate with eaters of diphenic and naphthalic acids PERIODICAL: Vysokomolekulyarnyye soyedineniya, v. 4, no,'. 6, 1962, Bog-a14 TEXT: Thermornechanical curves were plotted for polynethyl zethacrylate (MU) plasticized with 25 rlole~a' of: monomethyl, monbethyl, and Monobutyl diphenate; dimethyl, diethyl, ethyl-butyl, dibutyl, and diheptyl diphenate; dimethyl, diethyl, and dil~utyl n' hthalato. 1110oults: (1) The n better the compatibility between polyner area plastic-4zer, the Greator the drop in the vitrification temperature, T,,' of pure (TV . 1600C).. (2) TV dropped with increasing length of the Ikyl radical3 of the diphenate down to a --iinimum (-90C). (3) ,on esters of diphenic acid and e naphthalates showad a lower plasticizing effect (T.,,,%j50oC)- (4) The Card 1/2 V S/1qG/62/V-G4,/G-C6/GG3/026 Effec-. of the chemical structure ... B101/3110 struc-.~;re of the aromatic radical affoct!j the plauticizing effact. The better Dlasticizing of dip~enates is explained by the ability of the compo-~nu to be turned round the C-C bond between the two benzene rings. In the cLie of monoesters, the free COOR reduces the compatibility. (5) The molar concentration rule does not apply to the polymer plasticizer systems investi,zated. There are 5 figures and 1 table. ASSOCILITION: Urallskiy gosudarstvennyy universitet im. A. V.. Gorikogo (Ural State University imeni A. M. GorIkiy) SUBMITTEM: March 21, 1961 Card 2/2 USAFOV V. 1. History of the discovery of organic reactl=s in the presence of anhydrous aluminum halidese Tmdy luste lst.esti tWrho 39tlO4-3.40 ?62,, (MA 1612) (11riedel-Grafts reaction) V-ZA-VIOV) VILL SHITOV, G.P. Characteristics of prirz-ry-tertiary IFI-93-Ytols, ;P(Lrt 3. Zhur.ob.- khim. 32 no.9:2819-2822 S 162. (MMI, 15:9) 1, Urallskiy osudarstvennyy univeraiteto ~Glycols) YESAFOV, V.I.; ZHUKOVA, L.P. Characterist-Jes of secondary-tortiar-,It-gi7cciiq. J'art Zhur.ob.khim. 32 no.9:2816-2819 S 162. (111W. 150) 1. Urallskiy gonudarstvennyy univorsitet. (QIYOOlv) i, Y-,-,SAFOV,-V.1s; DASHKO, V.I;.; 1-11A.FLEX, E.M. ~l racterlstic,!j Bricondary-tt-rtinry J."'17cohn. Part .b. Aim. 34 no.12:4094-4Cf,6 D 164 OIIMA -8*.-1) 1. Urallskiy gosudari3fvenn-.Ty universitet, A NINTIMIRIMI 11111 Irilill 131i~l 1111iii' MiliAll H,7: 11: 111i1 H 1WR HwoAn and Anizal. Phyalology (Nor mal and Patholaglcal.)6 T Lymph Circulation. Abe Jour :Ref Zhur - Biologiya, No 13, 1958, wo- 60370 Author :Yesakov, A. I. Inst I "o -j"Ir- Title Investigation of the "Automatic" Action of the Center of IMhatic Hearts Orig Pub Zh- obahch. biologii, 1957, 18~ No 3, 185-193 Abstract The contraction of the pooterior lMh hearto (M) in a frog waa recorded on a kywgraph. The warming of the spinal cord with a thermode on tho level of the III vertebrum, produced an increaeo in the contraction rate; the destruction of the cord on that level did not interrupt the rhythmical action of' IR. It was stopped only when the spinal cord was destroyed at the VII vertebrum. The rhythmic activity of LH originates in the Card 1/2 tl:i ti 0~ Z"; -)-t) (7:os i-:rd-.,r of I~ciAn .-.d C;rdpr o" -bor V.Lm-,ono!7ov) CG- ic;:7 YESAKOV, A.I. - --------------- Metabolic factors of automation (exe=pl!Lfied bv the cerebrospinal center of lymph hearts). Zhur.ob.biol. 20 no.1:28-34 --Ta-F '59- (MIRA 12:2) 1. Kafedra fiziologii shivotn7kh Kookovakogo gonudaretvannogo universiteta in, X.T.Lomonosova. (L7MMTICS) (SPINAL CORD) (PHYSIOLOGICAL COHISTRT) SNYAKIN#-F.G.2 prof.; YESAKCfVp A.I., kand.biologenaWc Muncular sense. Zdorovle 7 no.9:9-10 S 16L (MiA 14:9) (MCUIAR SEKSF,) YESAKOV Metabolic nature of the automatism of norva"ceLlz as r-Aemplifind In the spinal center of the lymph heart,, Zhur. 6b. biol. 22 no.2: 136-143 Mr-Ap 161. . (19RA 14: 5) 1. Department of Animal Physiology, Staliw University of Moscow. (HERVFS) YESAKOV, A.I. Problems of the efferent regulation of recoptoriv; baivod qn on crxWlo of lingudl chtmrooptom Mulokall- M01. I t',Wl. .51 110.3: .1-8 Mr 161. (MIRA .14: 5) 1. Iz laboratorii fiziologii i patologil. organov chuvst7 Nav. - prof. P.G.Snyakin) Institute normallnoy i patalogicheskoy fiziologii (dir. - deystvitellnyy chlen AMN SSSR V.V.Parin) ViN SSSR) Mo.skva. Predstavlana deystvitel'stva chlenom Mill SSSR P.K.Anokhinym, (RECEPTORS (NEUROLOGY)) (STORA.CH) (TONGUE) YESAKOV, A. I. %thodology of neurodynamic investigations and practical work 1n the p~qeiology of hwmn anal7soro" brr P. 0. Makaravo Reviewed by A. I. Boakov. Hauch. dokI. vys. shkoly; biol, nauki no-3: 208-209 162. (14IRA 15:7) (SENSES AND SENSATION) (PHYSIOLOGY--LABORATORY MANUALS) (MAKAROVS, P. 0.) fl j. MAKIN P. G. irof.; YESAKOV A. I. kand. biologicheskikh nauk .4 js P Our habits are stereotypes. Zdoravle 13 no.11:11-5 11 162. rMIRA 15: 1-0) YESAKOV, A.I. Effect of the sympathetic nervous 13ystem on the olectric, activity of tongue receptors* Tnidy Inst. norm* i pato fl- ziol. AMN SSSR 6:63-65 162-2 (MIRA 1-1-.1) 1. laboratori-ya fiziologii i patologii organov chuvsts (zwro- prof. P.G. Snyakin) Instituta normallnoy i patologicheskoy fiziologii AMN SSSR. YESAKOV _,A,I,; ZAYKO., N.S, .t~~ Effect of guanidine on the functional activity of taste receptoro. Fiziol. zhur. 49 no.8:984,.989 h- 163. '114111A V: 2) 1. From the laboratory for Phyajology and Patbology of Sense Organs, Instituto of Normal and Pathologio Phymiology, U.S.S.R. Academy of Medical Sciences,, Moscow. YESIKOV A.I. Rcf1ax regulation of mapontanscuo" activit7 of tongim cheno- receptors. Biul, ekop. biol. i med. 56 no.8:7-11 Ag '63. (MIRA 17-7) 1. 1z laboratoril fiziologii. i patologli organcrv chuvatv (zav. pof. P.G. Snyakim) Instituta normallnoy- i patclogicheskoy fisiologii (dir. - deystvitellnyy chlen AW1 SSSR prof. V.V. Parin) JW SSSR, Moskva. Predstavleno daystvitellnym ablenom ARN SSSR P.K. AnokhirWme YESAKOVO A.I. Efferent reactions in the hypoglosaal ner7e. Kul. eksp. b1:2. i med. 56 no.11:15-18 0 [i.e. 11 ] 163. (MIRA 1?: 11) 1. 1z laboratorili fiziologli i patologii organoy aknivotv (zav. - prof. F.G. Snyakin) Inst-4tuta normallnoy I patologiche3kay Viziologil (dir.- doystvitellnyy chlen AMN SSSR prof. V.V. Parin) M01 SSSR, Moskva. YE,SAKO V.. A. I Mpu-tr.)ph~rsialog-ical nnalys!s of the functional =b-;1ity and of processes rpgulating t~e tAsta rocitptor appovF3tus. 7~-udy Inst. norm.1 pat.fiziol. AM SSSR 7:0-44 'C'A. (Ia-RA !8t6) 1. Laborstorlya fiziologill i patoiciii organav chu-istv (zav. - p-,---l. P.G.Snyaidn) Initituta normsl noy i patologicheskay fiziclogii s ss R. YESAKOV, A.I. (Moskva) Role of different regulation levels of recepto:-.3 in the perception process. Vest. AMI SSSR 21 no.1:62-68 166. OmA 19: 1) YESAKOV A. .; FILIN, V.A. L___j I Physiological characteristics of the functioning of the taste receptor apparatus. Fiziol. zhur. 50 no).2:269-3.76 F 164. (MIRA 18:2) 1. Iaboratoriya, fiziologii i patologii organov d*tv Inatituta normallnoy i patologicheskoy fiziologi-.1 AMN SSSR, 14oskva. YESAKOV, A.I. Pocsible specific stimulus of the llautomtic" center of the heart. Biul. eksp. blol. i med. 57 n.o.6#19-22 Je 164, (MIRA 18.-4) 1. Kafedra fiziologii zhivotnykh Moskovskogo, gosudarstvennooo universiteta imeni Lomonosova. -14 El. MIYEV, YU.K.; BAZAH, V.I.; YESkF0VA,-AjLN -~-SELIVWWA,, S.31. AND CM0YAKH0VM, S.I. "The Catalytic Transformations of Haterocyclical Compounds" ftrt XV1. "Syntbesis of Certain Pyridine and Quinoline Derivatives of Pyrrolkine" Zhur Obohoh. Kh1m. 10$ No. 21; 1940. Moscow Order To Lenin State University imeni M.V.Lomonosova, Laboratory of Organic Chemistry imeni Academician N. D. Zellns)4~,, Received 26 1%7 1940. U-1612j, 3 Jan. 1952 ''IA :, :, ~ 1 . 1 i i !I i I!li:,, 1~ Fi 1 11111k1 1;11,; YZSAKOV, I.Sq YASHCHNIIKO, Z.G. Interpreting vertical electric sounding curves b7 the T method. Razved. i prom. geofiz. no,30:50-54 '59. (1,aRA 12:12) (Blectric prospecting) U04; I. S. YASHCMKO, Z.G..; TL Use of electric prospecting in studylag the elastic properties of Igneous rockso Razved.i prom.potive 110 23-29 '59. (61, 13: W (Rocks-41actria propertlos) (111astialty) TISAKOV. V.A. ; ;nc~p. N.S.Bodnarskii; obituary. lsv.Al SBISR Si9r.geog. no.1:0-96 Ja-F '54. (WLRA 7:2) (Bodnarskii, Hitrofan Sterpanovich, 1870-1953) USM/ Geagrai~hy Education Card t 1/1 Pub.-45 - 8/20 Authors t Esakov,, V. As t3 at Riassi n ti- e Title : History of the origireation or geoeraphy. fjeultin a Ur .'r 17C tiet, Abatract Institution Sifbiritted Izv. All SSSR. Ser, gt,.Oga ~4' 51 -!60$' ;Julr;- Aligblit JJI:54 t History of the establIahm-at of geovmphy taeulties 3t qu-svim-l uni vei-s i ties sirce the second h0f of tba 19th centurys Acad. af Sc. USSR, Institute of Natiiral History, and T'achnique rK 1% ~IM I USSR dphysics Moscow University FD-1152 Card 1/1 Pub. 129-16/23 Author Yesakov, V. A. Title the history geography In Moscow University (up to the establish- ment of the chair of geography in M) Periodical : Vest. Mask. un., Ser. fizikamat. i yeot. nauk,, 9, HO 7, 131-136, Oct 1954 Abstract : The Petersburg Academy of Sciences, founded in 1725, established in 1739 its Geographical Department. Th3 author lists the numerous studies and expeditions undertaken after this date. Institution : Submitted : may 22, 1954 ;' I I-;i-.. i~ - YZSAKOT, V.A.; SO=IYET, A.I., redaktor; VOIDDIM, N.I., redaktor; - - --MMMVAg T.A.,- tekbnlchpskiy redaktar (D.N. Anuchin and foundation of the Ru0nian academic geoe ,Taphical chool.] D.N. Anuchin I sondanie imenkal univermitetskoi googTafl- heakoi shkoly. Mookva, Izd-vo Akademii nauk SSSR, 1955. 180 P. : (Anuchin, Dmitrii Hikolaevich. 1843-1923) (HLRA 8:10) TESAKOV, V.A. ,- -, M.I. Veniukov's correspondence with N.M. Przbevallskii. Vop. ist.ent. I tekh. no.1:207-212 156. (WRA 9: 10) (Veniukov, Mikhail Ivanovich, 1832-1901) (Prshevel'skii, N.M.) 3(0) SOV/10-59-3-21/32 AUTHOR: Yesakov, V.A. TITLE: Scientific Contacts of A. Humboldt with Russian Scientists PERIODICAL: Izvestiya Akademii nauk SSSR, Seriya geograficheskaya, 1959, Nr 3, pp 124-130 (USSR) ABSTRACT: This i1streview of scientific contacts of A. Humboldt with Riissian s,;ientists. There is 1 photograph, and 16 referencesp of which 15 are Russian and 3 German. ASSOCIATION: Institut istorii yestestvoziianiya i tekhniki All SSSR (the Historical Institute of the Science of Natural History and "Tech- nology., AS USSR). Card 1/1 X 30 11/ 1C-~5-9 -4-2t'3/29 AUTHOR: Yesakov, V.A, TITLE: A. Humboldt's Anniversary in the USSR PERIODICAL: Izvestiya Akademii nauk SSSR,, Seriya geoGraficheslcaya 1959, Nr 4, p 158 (USSR) ABSTRACT: The article is concerned with the 100th anniversary of the death of A.v. Humboldt; in the USSR. The followinZ- personalities and organizations partici- pated in the commemoration of the great German scien- tist: Academician D.I. Shcherbakov, Cor:oespondin~; ,Tember AN SSSR (AS USSR)93.V. Kalesnik, Academ4cian _ A.A. Gri.-or'-ev, Corresponding Uember AS UISSR ~.V . Obruchev, the Akademiya nauk SSSR (Academy of Sciences USM, the Geograficheskoye c,bshchestvo SSSR (Geo- 0 CD graphical "ociety M33R)t tho Glavnaya goo.rizj.o~lorvaya observatoriZ-q im. A.I. Voyeykova tral GeoplWsical (COZL U Observatory imeni A.I, Voyeykov), the Astronomiches- Card 1/3 kiy institut imeni P.K. Shtevnberrra (Inotitute o_f' 0 SOV/10-59-4 -28/2-0, A. Humboldt's Anniversary in the USSR Astronomy imeni P.K. Shte:cnbero), the Vsesoyu--noye botaniches.zo-7 re obshchestvo (All-Union Botanical ;:)Ociety), the Otdeleniye Ire o loGo-,,je o6raf iche s'l,-likh nri~uk (Section of Geolo3ical and Georsraphical I-31ciences) AS U3SR, the Institut istorii yestestvoznaniya i tek- hniki (Institute of 11isto:7 of the N,,:ttural Sciences and Technology), the Sovet-skoye natsional'noye ob"- yed-ineniye istcrikov yestostvoznnniya i tuek-lani-ki (Soviet 11,ational Associatfon of 1Ustorians of IsTiatural Sciences and Technology), the Moskovskiy gosudars-u- vennyy universitet im. Uolf. Lomonosova (Moscow State University imeni M.V. Lomonosov) the Moskovslroyo obshchestvo ispytateley p:?irody ~Mosoow Socie'ty 01, Naturalists), Obshchestvo sovetsko-Sermanskoy druz- hby i nauchnykh svyazey (413oviet-German Society for the Promotion of Friendsh-11p and Scientific Connec- tions), the Gosudarstvenniry istoricheskiy muzey Card 2/3 (O)tal;o 11ii0rical Museum), t1io Gw:ii.tdiivr;t;v(,,j1rVy jatl,,ey -007/10-59-4-28/29 A. Humloold-bos -Anniversary in the USSR izobrazitel'n,ykh isleiasstv (State Muse-un, of Graphic Arts) , the IMuzey zem]_evedeniya IJGU (Geographical Liuseum IT.,10). the Gosudarstvennoye- izdatel"stvo geo- graficheskoy literatury (,")tate PublishinC House of Geo-raphical Publications)and the Ministerstvo svyazi SSSR (Ministry of Comminnio-ations USSR). There is 1 Soviet reference. Card 3/3 YESAKOV; V.A.; SOLOVIYEV, A.I.j FEDOSEYEVO I.A.v otv* red*; (Russian geographical explorations of Em-opean Russia and the Urals in the 19th and the beginning of the 20th century] Russkie geograficheskie iseledovaniia Evropeiskoi Rossii i Urals. v XIX - nachale XX v. Moskva, Naukav 1964. 177 p. (MIRA 17:11) f. ";i 1. I.L i .1 R H I! Hi .!=2 0 h R!""! 1R I H I mA .......................... . . . ..... . .................... .... ..... .....- NAUMOV, Guriy Vasillyevich; FEDOS=, LA.,, otv. red..LYFUA - 6" red.; SOLOVIYU, A.I.p red. 211, (RuBaian geographical explorations in Siberia in the 19th century) Rueskie geogreficheskie 'Looledovanlia Sibiri v XIX - nachale XX v. Moskva, Nauka., 1965. 146 p. (MIRA 19:1) V.A.; PLAIUIOTNIK, A.F.,- ALEKMEV, A.I.; FED0,13FUl-W, I.ik.l - red.; SOLOVIYEV, A.I.p red. (Russian ocean and sea studies In the Ic,-Lh to the bagJr- ning of the 20th centurj) Rusokia okesnicheskie I morskle iseledovaniia v XIX-nachale XX v. Mookvap Naukap 1964. 158 P- (m:111A vtl) _USAXOV,_,Vasiliy Petrovich~ PARFENOV, Eduard Yevgenlyevichl Pfld~oAd,v;, -V -n-tin Alekseyevichj LERNER, D.M,p rod, (Automated electric drive systems with regulated semi- conductor rectifieral SisterW avtomatizirovannogo olektro- privoda s upravliaemymi polupi,ovodnikovyini vyprlaniteliami. Leningrad,q 1964. 35 P. (MIRA 1731-1) ... if xLzhaner. ;~~1044A -, ,. i - - X Operating conditions of electric winchad on ships. Sudoetroania 23 no.3:34-35 Mr '57. (KIM 10:5) (Winches) (Blectricity on ship*) TESAKOV, T.P., kand.tekhn.nauk Systems for electric propelling units usine, steady current. SudoBtroenie 25 no.2:31-34 F 159. (MIRA 12:4) (Electricity an ships) 'A R~ L 33115-66 ACC NRl AP6024083 s6Wci--,-* d6bi. 6144/66/0001002/o235/o236 AlIT110RI Zav alov. A, Set Qjtlman As 421 gllchanov Ve Del Fams Mk lie I'll hue-r--, Ar,ranwovs Borger, Ae Yae; Greyor, Lo K.; Yi-s&--kov. V. Pd; Yoe V.1 Vya-tman, Ko- I.; Abr7utin VO flaf-G-Ubanov. V. Vo; OfAChoMy, K*--17f--Yov0eYov, He Yell -ffo-rUn-, ld-.-Efe; 6fW1Df1 V, Yoe IF.;, Avilov-Karn love go Net 1159usli, A. Gel Bolyayov, I-* P.; Pokkor, I. 1-.F~ ORG: none, TITIZ-s 0* Do Bron (on his 70th birUiday) SOURCF-t MZ. Elektrono~hardka, no. 2. 1966, 235-236 TOPIC. TAGS: aloctric onginooring porsonnol, circuit breakor AWITRACM Osip 13orioovich Bron uns born In 1896 in 1C.Untai. In 1920, hn griiehiabKl from thn phynics-mth faculty of KharlkovTochnological Inotitooo . lie bocano a pro- fosoor in 1930s He defended his doctorfs thosid"in 194& Dii~~ tho second world var. ho was In. tho navye After don. o*AUrAtion in 199),. Enginoor Colonol Bron iront to work towilii-nr, at the Lonin;Eed Indu4trial Corresp2ndonoe School* Ho bocamo tho head of thn Chair of Thoo ical Puns of Slootrioal Tsahn4loa in lio in olow)ly associatod with scientific and development work, and has cooporaktod closoly in thin area with the Leningrad "Elektrosils" plant sInco 194de His work has boon in tho reas of spark-daEsi~~~-~powr~M ;xsalwrti. Ho hsa published over 1110 M entific works and 19 inventionso f5hpi SUB CODEs 03, 09 SUBM DAM" SOL) J, 5.3300 77094 S0'1/62 -12 -_-rd/43 L AUTHORS: Zhuze, T. P., Zhurba, A. S., Yesalcov, Ye, A. TITLE: Brief' Commun icat tons. Investigation o7P-V-t7n1elation and Phase Equilibrium in Ethylene-Cyclohexane Syi;tei.~i PERIODICAL: Izvestiya AkademLl nauk. Ot~,ele~nLye IdiLmicheskikh nauk., 1959, Nr 12, pp 2251-2253 (USSR) ABSTRACT: Inve3tigation ol' binary- systems of unsaturated Ca.'302; -and pavafflno, naplithenes, and avorilatic hydrocarbons, pl'00010,13 pl',10tical intevest; 111 vl.,-!Vt of the 11ij,:h oolUbi -a lity 01' 'GhC1 1U01' III C0111pV(33!3(3d U1.3atAllat,ud (:-a;_,,cL;. P-V-i;-I,l relationship of' the ethylene-cyclohexane -,ystem was studied by the authors in a modified apparatu:3 described by Sage and Lacey (Trans. Amer. Inst. Minin Met. Engrs.., 19110, Nr 136, P 138). Isotherms V -- 1'(p~t were traced in the range from 30 to 1.500 for ethylorie- cyclohexane mixtures with 20 to 85 molar, % ethylene, at pressures ranging from 10 atm to pressures somewhat above the saturation point of each mixture. Saturation pressures and the corresponding specific volumes were determined from these isotherms, and dew point pvessu-2es Card l/N were established in a series of separate experiments. A1 1111111!111111"111 IT Brief Corr,,run.tcat;1c.;nL,,. Irive-st;igzitlon Of 7 7 P-V-t-11 Relation and Pha:jc., Equillbrium S ov/0, - in Etliylei-if-,-Cyc!loiif-,YLtii,-~ Sy:;teiri Data thtw obtained, served to i, race i5otherly,,.~ P :~ f(N)t (Villeve DT 113 the i!i,')Lar share of ut-hylene dis.,,olved In cyclohexane); i.3othermla of t.`ie con3tant fov ethylene anit K isotheviiie; of' rno1ar volurtiu:j VM of the binary sy,5t(!m Plotted ai.,;ainsl. molar, share 14 of ethylaric at 50 at.-~,. 2 In this mannev, the composition of' the coexistinE, phases, the equilibrium cons*~anto of ethylene and cyclohexarie at pressureo Lip 1,;o 100 atmand the riolar volunic3 of mixtures at their saturation pressures, were determined In the tenipevattire vange fron, 30 1250, Molar volume iaotherm,,3 at low temporatuves were practically linear tip to N,) = 0 65; at hif, -hor te.irtp~~vatUre,,3, the molar volume fiicreaoc~.; oharply St"IrLing N'.) = 0,50. There avc 3 fiCupes; and 3 rcf'erelicco, l-U.S., 2 Soviet- I.J..23. vor,,L-ence is: B. H. Sapl*e. W. 11. Lacey, Tvunn. Amen,. Iriz;t. Milnin~;. Card 2/N - w~t'. Engx.,. , .1-,6, 138 (.19110). L ,4, ZHUZE, T.P.; YUSHHEVICH G.N.,- USHAKOVA G.B.;,,,:(ZSAKOV Ye.A. Critical parazetera for oil and oil-gas pystemEi, Reft. khoz. 41 no.6.*25-31 Je 163. (MIRA 17:6) AFANASIYEVA, V. B.; ESAKOVA, N. 11. Relation between the snow cover and G. J. Wangeaheim's types of circulation. Trudy GGO no.151:77-80 161jo (MIRA 17:7) F I A 11 1!R ACCESSION NR: AT4046059 S/2531/64/000/166/0182/0188 AUTHOR: Yudin, M.L(Doctor of phyeico -mathematical sciencer,); Yesakova. N. Afanas 1yeva, V. B. TITLE: Preliminary evaluation of the prognostic significance *of the Information obtained, from meteorological satellites SOURCE: Leningrad. Glavnaya geofIzicheskaya observatoriya. Trudy*, no. 166, 1964. Voprosy* interpretatsil daany*kh moteorologicheakildi sputnikov (Problems In the of data of meteorological satellites), 182-188 IroPIC TAGS: meteorology, meteorological satellite, cloud, precipitation, weather forecasting, long-range weather forecastfng, snow cover, radiation balance t~BSTRACT:`The objective of this paper vras to develop a method for the preliminary ch"acterization of anomalies of cloud co~rer, the radiation balance of the underlying surface and the limits of snow and ice cover for subsequent use of such characteristics i in long-range weather forecasting. The authors establish statistical relationships between' such anomalies and the characteristics of future weather (temperature and precipitation);' certain direct characteristics of atinospherio circulation are also anitlyzed In relation to future weather. Determination of the characteristics of w-lomalles of the cloud cover, Card 1/3 ACCESSION NR.- AT4046059 the boundaries of the snow and Ice cover and the radiation balance was done using mean 10-day values, for the period Septeinber-Nuvember 1948-1957. These values were i mapped, after which the parameters characterizing the fields of individual elements i were determined. The method used for constructing the maps and defining the character- I Istics-of anomalies Is described briefly. The state of atmospheric circulation was deB- cribed using the zonal Index devised by Ye. N. Blinova, the M. 1. Yudin meridional index --and-the A. A.- Rozhdestvenskly hydrodynamic indices... These parameters were used to-sUpplement the 10-day means of temperature and precipitation for an analysis of these value- determined for a grid of points covering much of the European SSSR. Synchronous P j..statidtioal relationships werci established between the 10 mentioned parameters; ..,,a0hbhronoua prognostic rolationahIps also waro detormined. The ton considered para- 'iaeters,were correlated with temperature and precipitation for the 10 daya which fo I I owad. -T~0-jcbmputations of the correlation coefficients were performed on a "Ural-111 electronic I.-,2'q-9~iputer. Most of the results of the computations were plotted on maps, and 66 such maps wore constructed. In a considerable number of cases relationships were discovered which are characterized by quite high correlation, coefficients and with a stable Identical AIN ACCESSION NR: AT4046059 4 1 f 1: sign for the entire considered area. It was found that dio selected parameters generally give more information for prediction of temperature than for prediction of precipitation. Ilowever, an absence of prognostic relationships to noted on a number of maps. The method described made it possible to establish a number of parameters of the state of the atmosphere and the underlying surface which are quite closely related to the characteristic of future weather for 10 days In advance. The greater part of the parameters apply to -cept by use bf meteorological - those elements which cannot be determined globally ex satellites. This emphasi;es the great importance of satellite obs rvations for long-range forecasting. Orig. ait. has: 2 formulas, 6 figures and 1 table. Glavnaya geofizichookaya observatoriya. Leningrad (Maia Geophysical ASSOCIA710N. Observatorv) Ix AFANASIYEVA, V.B.; YESAKOVA, U.P. Statistical relations between the anomalies of cprt&ia weather characteristics. Trudy GGO no.1653105-113 '64- (MIRA 17:9) AFAlT!':_!lYViA) "T.B.; Y2-,SJ!KCVA) Ila, Re laticn of' t!~e !i !~_if t of the bowndar7 of sucw atner. tti t~e G, I ~rangen,_-itilrr typas cf circulation 1,ti the flpring litiriod. Trudy r,00 no. 168; 45- 43 165, MURI, YN,;AF,()VAy 11.1'. A 1-7% It! A3V U ~ .. 4' L niffc~ince of Prelizim-ry evaluatior cf tio preUncstic slt- information returned by ineteorolo'gical satellites. 7:1-L,,dy GGO no.166:182-188 t64. (14TRA Objective method for deterodnation of the lixting stage of aelatin stock. R. Gorodets',:aya., 14. Sheremet, 11. Shakhnazarova, D. Virnik, V. Smirnova, and R. Y~esakova. Myasnaya Ind. S. S. S.R. 25, No. 5, 52-4(1954). -The procedure for detg. the atatus of the Liming of gelatin stock is based on extg. a s.,,-,nple and detg. extd. gelatin colorimetri- cally by means of the biuret readtion. 'Results are given for extractable gelatin in bome stock ah 5-day intervals for LjO days of liming. Total extractablo gelatin is dotd. for vari- ous bones and other gelatin stock. M. M. Piskur GORMMTMYA6, R.V., kandidat khimicheskikh umik; SUMMUROU, H-Sh., mladshly nauchnyy sotrudnik-; SIMRIMM'. N.V.; YIRIrII, D.I.; SKIRNOTA, V-Te. ; UWMI, t%lxf- Reducing losses in gelatin production. Trudy VIFIIHP no-7:108-113 '55. (nu 9: 8) 1. Voesoyasan nauchno-IssledovatellftLy Institut mysenoy promyohlen- nosti (for GorodetskVs, Shakhaacarova. Sheremet); 2. Hookovakir zhelatinowyy zavod (for Virnik, Smirnova, Yeaskova). (Gelatin) GORMTMU, R.V., kandidat khinichaskikh aaWc; SETAXNAZAR , M. Sh. mladshly nauchan sotruftlk; SMUaM, N.V.; TIOU, D.I.; SHIBOVA, V.Te.; YMKOTA, a. Kethods of determining the degree of liming in galatigemous tissuos. Trudy VNIZIM Ao.7:114-122 155. (KM 9 18) 1. Vaesoyuznyy nanchno-inaledovatellakly- institut myssnoy prorq- shlonnosti (for GorodetskVa, SMkhnaxarove, Shertmet); 2. Modkov- skly sholatinovyy savod (for Virnik, Smirnova, Yesakova). (Gelating)