SCIENTIFIC ABSTRACT YEVDAKOV, V.P. - YEVDOKIMENKO, V.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001962920020-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 15, 2001
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

I " -"1 :1 ~ I - -i~ I i M! V, ~ I ~ U 1111, ; l,' I I-1; j, - I I I lff~ Mk 111 H owli. W, illvA. Is, .1".1" MWA AlliNWHAMI.Al ggnr gil!j 1 lAwfugglig & glij ~ !=I]
Elil:iiiAwl~Rl.~j)arF-,.IlLAMNIII:al"~,~!ia-1.1tizul-- ....... .!" I I - ".- Is-I......-I 1:1-.1'... 1....-. ...... 11-1- -... -I...... ... ...... ... I..- MIRMITIff"ITIll
PETROV, K.A.; NIFANTIY.W,. E.Ye.; LYSENKO) T.N.;
Synthesis of esters of phosphorous and ph9sphinic acids b7
alcoholysis of their amides. Zhur.ob.khim. 31 no,,7.-2377-2380
ji 161. (MIRA 14:7)
SPhosphorous acid) (Phosphinous acid)

PETROVP K.A.; YMAKOV, V.P.: SERGEYEVA, L.N,; MOVSKIM, V.A.
2p /*, 5-trichlorophen7l eatera of aM
mathylphouphinio doldn. Murtob.Phim, 31 no.1004,14-3417 0 161.
(,MIRA 14:10)
(Phosphinothioic acid) (Phoophinic acid)

-III mr, IIISMIUM1111 11111.1103 . !11~ I k It 1 :1
....... .. .... mm-
la F
PETRCVp K.A.;_gyqg9VlLl V.P BILEVICH, K.A.; RADCHENEO, V.P.; NIFANTIYEV,
--2F
E.Ye.
Properties of phosphorus acid amidev. Part 1; Renctions of
amidophosphites with phenols. 2bur,,ob.khim. 32 no.3:920-
923 Mr 162. (MIRA 15:3)
(Phosphoramidous acid) (Phenols)

PETROV; K.A.; YEVDAKOV,, V.P.; BILEVICH, K.A.; KOSO.EV, Yu.S.
Properties of phosphorus Acid amideb. Part Zi Phenolyvisp alcoholysis,
and hydrolysis of amidophosphonites, Zhurob:khim. 32 no.6:1974-1977
Je 162. (MIRA .15:6)
(Phosphonamidous acid)

PETROV, K.A.; YEVDAKOV V.P.- ABM-ITSEVA, G.I.; STRAUIRAIT, A.K.
~~~ .9
Properties of phosphorus acid amides. ?art 5: Peactfoon of
phosphoran,idous and phosphonamidous acids with thipphenol and
mercaptans. Zhur.ob.khim. 32 no.90070-3074 S '(p", (!L',IRA 15:9)
(Pfio-ophorafidAo4~jeW~~~(Pfi6ophonaifAoti~ Wd)4"
(Thiols)

PETROV, K.A.; )!~VDAKOV, V.P..-, MIZRAKII, L.I.; R01,10DIN., V.P,
Properties of phosphorus acid amides. Part 3: Neir rnethcd oP
synthesizing thiophosphites and thiophosphomites. Zhur.obekhime
32 no.9-3062-3065 S 162. (MIRA 15:9)
(phosphoramidothioic acid) (Phosphonamidothioic acid)
R

ACCESSM, 1?Rs AP4009143 9/0190/64/W6/Wl/OMO/OM2
11111,190M Patrovp No Ael YovdakOv, V. Po; Bilevich, K. A.1 Kboyft6vt I%* so;
Padchonko, V. Ps
TITLE: Properties of aTddes of phosphorus acids. 7. A now mothod.for the syntba-
sis of phoaptorus-containind polyesters
SCURCE: Vy*sokorolekv.1yskrr"e soyedinenlyap v# 6# no& It 1964.10-12
10FIC TAGSs phosphorus acids phosphinoun acicl, mtidca, polyesters polycondensetioas
hyd.kocluinones sull'Urs zqygezi, tetra*Vay1di=id6, hexwthey1t11=dda
:ABSTRACT: Polyesters of trivelent phosphorus acids ware obtained ty tbo reaction of
tatraetWdiazddes of phosphorous or ph~sphinous acids with bydroqvinone in a 1:1-
moler ratio. The ingredients are heated at 120C during the initial 3-2 hour pari6d,
:,then at 220C during the subsecruent 3 hours, vacuum being applied to remove the
,evolving dietbylamine. The resultiig products are yellowish transparent svbatUnces,
;the polvp~ospbinites being solid and the polypb6sphitas of rubber-lAke consistency,
~the lafter*poseasaing good adhesion to glass. The reaction product of hexaet1Vl-.
triamidopbospUte with hydroquinone yields a brittle trimeric polyester, The
:tCo.rd,

1rd-
ACCESSICH NR., AP4009143
-products Obt-ii-a-ed had a Specific ViscositY Of 0,04-0-25 (In a 2.15 oolutlan in
1%
dimotbylformssmide) and a deconvaition rango of 280-4%0. Upon trantm*nt with
aulAir or oxygant tho trivalent phoophoma of tho polyeators beciemd dollvarted to the
rAntnvolent form. In conclusion, the authors call attention to the fact that WI-ale
~,he rolyosters obtained by their technique had softening pointe vithin the 130c-1500
rnnge, tho corresponding products obtoined by the convontional wthod from phon-, I
phorus dihalid-39 and diatomic phenolo had -softening points whicJi wera 70-00C lower.
Orig. art. hiss 3 formulas and-1 table.
ASSOCIATMA none
SUB1.77TEDs 16Apr62 DATE ACQs 10P 064 ENCLs 00
SDB CODEs CH 110 YW~ SM 007 OTHERs 003
Card 2/2
77 ------ i-j --- Q-
T

YEVDAKOVY V. 1,-.; MIZRAKH, L. 1.
Interaction of mothylphosplilnic acid anhydride ulth bydroxyl-
containing compounds. Zhur. ob.Khim. 34 no.6:1848--1851 Je 164.
WIRA 17:7)

PETROV, K*,A.; IE VDAKOV, V.P.; DILEVICH, K.A.; CHEMM, V.I.
Properties of phosphorus acid amides. Part 4: Reaction of
aminolysis and phenolysis of amidophosph'Ltes and amidophosphonites.
Zhur.ob.khim. 32 no.9:3065-3069 S 162. (11IRA 15:9)
(Phosphoramidous acid) (Phosphonamidic acid)

PETROV., K. A. ;, ; 141ZI-LW-,, L. I.
Properties of amides of phosphorus acids. Part 6: Synthesis of
i..2,5-trimethyl-4-piperidyl eaters phosphorus acids. Phosphorus
analog of "promedol." Zhur.ob.khim. 33 no.4:1246-1251 Ap 163.
- (MIRA 16:5)
(Phosphorus acids) (PipBridinol)

PETROV, K.A.; BASYUK, A.A.; YEVDAKOV, V.P.; MIZRAKH, L.I.
Thiophoolibbiltdo. Mntr. ob. kidino 34 no*7I222tf!o-;U)2fI ii 0Q,
(MMA 17:8)

'17 F d,

nhLnoun acid w-TIN n-he)-anol Dr,2&uced the m-hen.-Vt iw-pe r-f r1l;wnyll~~,".
ar--.. has
T11

-,A M. jj;.~[ ll~`", 1: 1! N 1 1 =p-14111pal ap x
TT
All,
ji

YIN Dili KOV ) V. P. ; M I , Pi4i I, I. IA N I ~ALCV A, 1,. Yii
Synthesis of mixfd arld
anhydride3. Yhur. oh. khim. 34 no.9:3124
1. Institut azotnoy prony3lilennosti I produkto"i
sinteza.

V.
React, or rnenhylphocp'll" ar
and their salt.s. Zhur. 0). kh.,m. .14 no.3.20,52-39'.1,
'V%! RTIF I '111: 11' 1 H1.19 IN;

TL-:VDAKOI' V.P.; SHIlITYGITA, Ye.K.; i"5iil-,VICH, K.A.
Amides and anhydrides of vhosphonls acidis. Far-, 4:
tion of hydroxyl-conLaininir compounds with p-diethylamidc-p-
acethl-0-alkyl phosphites. Zhur. ob. khim. 35 no.4:728-73L Ap
165. (MIRA
1. Gcaudarstliennyy natichnc)-i.,isle(loviltellskiy i proyakLtlyy in~-,Titut
azotnoy promyshlerinosti 1 produktov orgrardelieskogo sinteza.

YEVDAKOV, V.P.; SHIINKOVA, Ye.K.
Amides and anhydrides of phosphorus acids. Part 5: Reactfon Of
amides of phosphorous and phosphinic acids with acetLc anhydride.
Zhur. ob. khim. 35 no.4:739-741 Ap 165.
(14IRA 18:5)
1. Gosudarstvennyy nauchno-issledovatellskiy i -proyektnyy institut
azotnoy promyshlennosti i produktov organichoskogo sinLeza.

!T, I I I P I
....... ..... .............
R e Lt c t on r, 1 1 ~-y p h r
"ihilr. (;b. kh'r. 31-1 no.7-1 314 .11 '65. 181811

YLVDAKOV, V.!,.; ALIFOVAY Ye.l.
Antlier, and anhydr!.-I--~s of phozphoruz qcJdn. -Fert 7. -~'f n tr - - --' 3
dnd sore convernicni of- rhc)spfjir;,c ii!~Jl '/:hij:-. ob.
klilm. 35 no.9.1584-1587 .':, 165. (XIIIA 1p!10",
1. Gosudarstve-nnyy nauctino-isslrjrirviatu.1liAki.y I
inst-Itut azotnoy promyshinnnost.1 I prcdukt,ov wrgar-ir:~-.skogo
sin',eza.

YPIDAMP
A_m,-ie8 dnd dnhyJrldcs nr pho3phomi
Or amidos of' I;hosphorru3 acid with carloxy
Zhur. ob. k,"Am. 35 no.9,1587-1~91 'Sl- 165.
1. Tns4-, tul; asol,ncy promyshli--nnontJ i nr,)'.'-Iktov
3inte-a.

1!1 1 - I. ,
YEVDAKOV, V.P.; KMAKII, L.I.; DA01 ,11,011A, I,Ya.
Reaction of dialkyl amides cT dialkylphosphorous acid with aldehydes.
Dokl. All SSSR 162 no.3:573-576 Yv 165. f%141RA 19:;,j
1. Gosudarstvennyy nauchnc-iisledovateltskiy i proyek'nyy institut
azotnoy promyshlennosti I produktov orp-nichenkcgo sinteza. Sub-
mitted November 14, 196/+.

-? T Vu
-PaT
:~cn

M'Ilil 0111HIMI HIM if MHOI ?P111111111,11
Ti

L 302!5..66
ACCESSION NR; APS022010 UR/0266/65/000/614/0078/0078
678.85
AUTHOR: Petrov K._A.*,
Yevdakov V. P.; Dilevich, K. A.; Mdchenka, Vo
Kosarev, Yu. S.
4
ganir,~ ghosphorus pobqqrsj~' Clo; 39, No. 172996
TITLE: A method for producing or
,SOURCE: Byulleten' Izobreteniy i tovamykh zriakov, no. l40 1965, 78
TOPIC TAGSi organic'phoophoruts compoun4, polymer, phospho.)Ivus McId
'ABSTRACT: This Author's Certificate introduces a method,Ay~ ptioducIng arginic phout
phorus polymers based an amides of phosphorous and phosplivious iicids- A wider ne- i
1 1
~Iecticn of raw materials is provided by using dihydroxyl-cantalgititig aryls an the
i
.second component for polymerization.
iASSOCIATION: none
ISUBMITTED: 310et6l ENCts: 00 SUB CODE: MT G-C,
!NO REF SOV.4 000 OTHER: 000
1~cordvi

111741111111141111 oll i
L 4959-66* E-"4T(M)/EPF(c)/ENP(J)/EWP(t)/EVIP(b) IJP(c) JD/RW;
ACC UR: AP5025678 SOURCF
0031 UB/0266/65/0011/%8/0025/0026
'AUTHORSt Toydakov, V. P.0- k-URqva't Ts. It
1 ORG: none
TlUgi A method for obtaining/tho anbj~rtde of 'Ali
Phan -113-112-nhl nd Its maid
eaters. Class 12, No. 174625 announced by State Scientif Lo jjgLe-&K.
0 Inc-
kt
nauchno-issledovatell s~ji i proyelctrW institut, azotnoy proavflh1e;~wati i prcdu ov
-aintezay -
organicheskogo
iSOURCEt Byulleten' iao'bretaniy i tovarnykh znakov, no# 169 19,65, 25-26
TOPIC TAGS: vinylphosphonic acid, anhydridej, phosphor organic compound, Rhos-phonic
acidj formic acid
ABSTRLCTt This Author Certificate presents a method for obtaining-tbe anhydri" of%
vinylphosphonic acid and its acid esters by reacting the dicliloroanhydride of
vinylphosphanic avid with wftdrous formic acid at 10C and by nubsequent heating
to 120-130G, The resulting anWride of vlaylphoaphonic acid. is than treated with
UDC1 5 ,419.X ig.q
L-Li LLPM
- rr~~
M1111141 Min

L 4959--66
tVdmVl-Qontainin& compounds ait a tompersture of 120-3,300*
SUB OIGD& 00/ WBM DATZ* 10ju164
167
Card 2
WE r- --, ~11, P,

Jt~_
souRWOE, 0 Ei 2 5j
AUTHOR: BlIevich, X. A.; Yevdakov, V. P.
ORG: State Scientific Research_Aqd and Products
of Organjj Sy_nthe_sis (Gosudarstvennyy nauchno-issledovatel9sIdy i'proyelctnyy institu
azotnoy promyshlennosti i produktoy organicheskogo sinteza)
TITLE: Alcoholysis and phenolysis of acetylphos-phi s t 00
SOURCE: Zhurnal obshchey khimii, v. 35, no. 2, 1965, 365-36B
TOPIC TAGS: phosphorylation, organic phosphorous compound, acetic anhydride,
alcohol, glycol, tertiary amine, phenol
ABSTRACT: Mild phosphorylation of various hydroxyl-containing compounds can
;be.aticcessrully carried out with acetyl phosphites, readily 4iYnthouized by
;reaction of dialiqlamides of diallqlphqsphorou3 acid with acotic anhydride.
(RO)2pN(C2H5)2 + O(OCCH3)2 - (RO)2POCOGH3 + CH C011(02H5 )2
3
;The reaction occurs andothermllv, and acety1dialkylphosphites aro formed
,at high yield. It was found that esteraoideis of.phosphoric acid react with
,acetic anhydride to'form mixed anhydrides. it was shoint that dia1lqrlacetyl-
phosphites phosphorylato prl=ry-,, secoadaz7,, 4nd tertiar7 alcohols, glycols.:
-and phenols in the presence of tertiary aminso or dialkylazaldos of dlialkyl-
phosphorus acid at room temperature. Orig. art.-has: 2 tables. [JPRSJ
SUB CODE: '07 / SUEM DATE: 05SeP63 / WIG W: oo5 am nEr. : ool
Card 1/1 not _UMM 546.18

Ft:,*5-76;-15-IOOiTll-,r~~T13;111,
ACC NRi ANJUIUJ97 SOTP,.a-; CONs U11.0075:
AUTHOR: K~v~dazir~,V,
T luatr7 ra-td Irodnats c-, 11' Ov gcirdr;
&reaL avo--,ition ~Q at 3 r~ 1T'I'a'aa (D P(V. J,: i 11. IAI
drides of monabasic carbwy4c acids to - foLna wryl. phexaphitcv - ala Cyl
lphosphites In the reaction of two malea ot tho wahydjI.doj waid(i,jIC,'jr1 PhWphi:~C:;
-~!in the reaction with one mole of' the anhydride, Diaa.`.kylwtiIdOa(:q,l pholsphitGo-
and amidoacyl phosphites are unstable! and decompose almost entij!aly to the
landde of thp_ corresp9nding acid ani meta hosph 'o whm husteds They are also
P.
J
CL dit IiJAIMA

It., Illuill! A Im I,
T
-ACC NRI--AP6016692
1h acoho 'a to orm diADq1
--effective phosphorylatL-ig agents,, reacting At
-!phosphite' and the diethylenade of the carboV#c acid., Phomplionrl.a1ion,of
of' "lie aviieloacyl
-E~-`clin--be 66Mucted ifi one stop without isoletion
[ky1diamide oT alk;jlrihosphoraug,;
osphites 'by aucwssive3,T treating the tetrad
acid h--z 1,,a maids
wit Ln acid anhyx1ride and an alcohol. Anliydrideei to Ed1bas
GOMMUM 40
iceinic) 0.1oo react idth amides qf,phiti id Orige ar t.
ht
P,
-b1: a~*-. fjtRJS
3
ta 9~
CODE 07, DATC-t ~30J=64 OUG '1101 F t 0.07 OTH 11mv, 001
Car
im upimm L
-6

681--fa&- MT(r,)/FaP(Wftr
rACC-R"_~6W(591 SOURC3. COX.- 5-5763-5-M 6 077 133 47-1 ~
AUT"O'1'
AUTHOR: Yevdakov, V. Et" td#oV--1 Ye. I*
ORG -. State Scientific Research and Plannixy, TnAitute, Nit
ORjG
'D Or T
of Organic Synthosis (GosLdarotvsr_r*-y nauchno-is.4ile-d-o _11ail2ly TroyRfArvy, Jjlr~rtitut 1
P
_z0
pror7shlonnosti i produlctov argrandchaskogto sii.,ttozm).
An-~he-*field`t-aridd !a
--1-_rT1F,--T~Mstigation 0 5- !an~id6i:a
a lid
ynthosis andsom, transforwations of arL
S lUdrides of *iospl.~i c aidds
SOURCE;: thurnal obsh-chey IdArdi, v.o 35, noe 9 1965,13"aw" ~587
TOPIC TAGS: phosphinic acid, organic synthatic jvococs, fc~fril-,ic holcl, (30tor,
'fluorinated organic compound
TRACT: - Continuing a study of anhydrides of phosphorus
oynthosizod anhydridoa of all[ql-p cycloalkyl-j, and arylpholf-phinic aci(H Irr
reaction of the corrospon(Ung dichloridoo wUh ardyjdmi~a fowd,c acid ok-
:with water. Tho corresponding ankydrides are produced in high ylioild at 130-
1W0 for the alkyl and cycloalkyl compoimds, and at 150-16(f for the aryl
derivative. The an*dride synthesis can also be condueted in the presence L
of solvents and organic compounds, which shaxlAy,reduces the reaction temp.- -
orature but makes isolation of the anfqdridd formed fm. Via hydivchloride
of the orRanic base and further isolation of: the acid ester difficulty#
Card UDC:' V-;6-lB.!H-547,261n8
IMMEMMIM Ifni 11111 110MM

I L 25681~66
ACC NR% R6o16691
Acid asters of phosphinic acids were producad:by hqatime, th~j anIMIrid-3a With,
primir7j secondary.. and fluorinated alcohols',~as IMI-1 ~Ls vith phpmwi'.~ form,
Ing monoalkyl (ar7l) phosphonattes ir. )d& yi;ld. The auth6itv p34-wae a nueloo-
YhMc sub3titution reaction at the tetrahedral phosphorus Am) vith the
qi, react, on o,
;phosphorva atcm pentavalent in the transition bt&Lo~ for th M 0 PhP
ihini -,Oci -an)Mdrides,idth Wr*iWI-conbaidqjg curspo"(W-: A, j-t 4, haot
SUB C=&-- 07 SM DATE#. 29Jun64 ORIG REFt 02 OM UF: 002-

L '364912-46 E..,'F(m
ACC NR: AP6027085
SOURCE CODE: Ull/0079/65/035/010/187---/1-876
AUTHORi Mizrakh, L. I.; Yovdakov, V. P.; 'S andalcrva, L., lia.
ORG: none
TITLE: Amides and anvdrides of phosphgus acid.s_./ Part 6: Mixed anhydrides of
acidt) of tri- n~_d pontavalent phosphorus. Synthesis and oome properties
SOURCE: Zhurnal obahchey khimli, v- 35, 110- lop 190, 1871-1876 1
TOPIC TAGS: phosphoru~3 compound,-organic amide, acetic anhydride, chemical synthasi5l'
chemical bonding, phosphoric acid, phosphinic acid, reaction mechanism, hydrolysis
~ABSTRAQT: The reaction of compounds containing a p I;I_N bondwith
!.`anhy&i1des of aoids. of epntavalant phosphox-us vras-s-t-u- des
Anhyd=1
bf phosphoric and ptiosphinio aelds (1, 11) react with amides of
;phosphorous and phoophinous acids to form mixed anhydrides of acids
Rf tri- and pentavalent phosphorus (III and IV)i
0
JR,
>P-0-1'-n
\P-N(C111J3+fi-P0j
MC2114h
0 0
IR, 11 11 Rp
2 P-MC1115h + P206 P-0-1-0-P-0-p/
(C21101N N(CA)%
Card 1/2 (IV)

36401! ... 66
ACC NRj AP602
.A simila; shift of the dialkylamide group and formation of a
!PII -0-Pv bond are observed when dl- and triamiden or acida of tri-,
Ivalent phosphorus are involved kn the reaction, The mechanism of
'formation of mixed anhydrides (M) and(W) most probably consists
in a nuolephille attack of the free elect on pair of nitrogen, fol-
lowed by-a heterolytio cleavage of the p111-N bdndt
0
%P-R
.,P-N ----P -R /P* Mprov)
0
Data of the analysis of the synthesized compounds (III) and (IV)
.and their constants are tabulated. Certain conversions (hydrolysis.
alcoholysis, eto.) were carried but In order to demonstrate the
structure ofthese compounds and to study their properties. The
mixed anhydrides were found to have good phosphorylating properties.
Orig. art# has: 2 tables. [JPRS: 36,3281
SUB CODE: 07 / SUBM DATE: 29jun64 ORIG REF: 005 CrTH RFF- 003
/)-/z
R 11

Q R., "111. '!W~W
ACC NRt Ap60211;2O SOURCE CODE: UR/O413/66/ooo/oii/oo,'-u/0o2i
INVENTOR: Yevdakov, V. P.; Shlenkova, Ye. K.
ORG: none
TITIE: Preparation of cyclic alkyl phosphites f~ Class 12, No. 182157 [announced by
State Scientific Research and Design Institute of the Nitrogen Industry and Products
of Organic Synthesi (Gosudarstvennyy nauchno-issledovatellskiy i proyektnyy institut
azotnoy prorryshlennosti i produktov organicheskogo sinteza)]
SOURCE: Izobreteniya, promyshlenrWye obraztsy, tovarnyye znaki, no. .11, 19050", 21
TOPIC TAGS: organic synthetic process, organic phosphorus compound, phosphorous acid
derivative, cyclization, cyclic ester
ABSTRACI!: The subject of this invention is a simplified method for the preparation
of cyclic alkyl phosphites from N,N,NIN1-tetraalkylphosphorous diamides which are
treated with acetic anhydride and glycols. [JKI
SUB CODE: 07/ SUBM DATE: 06Apr65
UDC: 547-419.1-07

E?IT(m)/E;WP(j) RH
ACC NRs AP6021677 SOURCE CoNg ur