SCIENTIFIC ABSTRACT YEVDOKIMOV, V. D. - YEVDOKIMOV, V. M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001963010003-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Radiation Polymerization of Isoprene, T, 1/64/1021
W0061 82076
gaiwa rays of C06r) whose yield 1-3 dire-.fly rvi)porlionstl to the
radiation dose, with small fluctuations -,f tte rqAiat-i,!n tnten!-,ity.
The microstruiture of the polymer in ~ho -~iaperat,~ire rangp 40 ~- 20--~c
Jf "he do-se and irtqn-:i~v f rad.i-ttlou, atd c-f thp
Is independent d 1. .1 10, 1 1 .1
prp5snce c4.' a 1:izer (5 mole-1Z Md,"., Th~-- averagnt mol cculir vr~~igh~
of 'he polymer riz-4 when the radiitior int"gri3ity ii de,~r-~aqed, The
a0hors thank 0, S. Denisov for advice vvi h:-.-Ip In tak'rig vhr-~ infrared
ipe:-.tra. There are table and A 4 US
ASSOCIATION: Ler i ng-ad ski ygo-iudar- z4 r_q v e- t ~L,~ln~ingrad
sta~'4~? Vnive;nuy)
4-TTED . July 7. 1959
-?12

83466
S/1461'60/003/004/006/010
~BOWBO56
AUTHORS: Yevdokimov, V. D., Radchik, A. S.
TITLE: An Apparatus for the Investigation of Friction Processes
by the Method of "Thin Plates". -LID
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Priboroatroyeniye,
1960, 401. 3, No. 4t PP- 4131-52
..TEXTL; Friction processes act only upon a thin surface layer of the materi-
al..Therefore, the authors investigated such processes by means of lamel-
lae over which a heavy slider was pushed, Fig, I shows the sag of a uni-
laterally clamped copper lamella as a function of the number of slider
passages (rate: 0-T:2 m/min; load: 75 kg/MM2). The initial deformation again
&icreases during the following passages. The resulting curve characterizes
the conditions under which friction occurs. The authors constructed a
portable measuring apparatus (Fig. 2), the function of which is describe4l-
The clqmped .1amella (0-3-0-5 9 5 x 100 mm) is pulled through underneath
a load, after which it is'-lifted in a perpendiculardirection, and the
amount of sag is recorded by breaking a low-voltage contact at 4 height
Card 1/2-

P466
An Apparatus for the Investigation of Friction S/146'60 003/004/006/010
Processes by the Method of "Thin Plates" B004Y2056
corresponding to the sag. By means of a multiplioator it is possible to
record the diagram on different scales. An organic glass rim allows to
fill.in lubricants. The apparatus makes it possible to investigate the
action of oils and various admixtures. By this method it is possible to
investigate, on a model, the surface layer which has been changed by
friction processes. These changes may be investigated on the samples, so
Ahat thephenomena occurring as a result of friction, cuttingt or drawing
may be studied. The high sensitivity of method and apparatus make it pos-
sible to~test finished products in the laboratory as well as in operation.
This paper was recommended by the kafedra detaley mashin (Chair of Machine
Elements), There are 2 figures and 2 Soviet references.
politekhnicheskiy institut
(Odessa Polytechnic Institute)
SUBMITTED: Pebruary 20, 1960
Card 2/2

S/020160/134/003/009/020
B019[Bo6o
AUTHORS: Radchiks A* Se.9 Yevdokjj2xj D.
TITLE: The Bauachinger Effect in Sliding Friction
PERIODICAL: Doklady Akademii nauk,SSSR, 1960, Vol, 134, No. 3,
Pp. 571 - 573
TEXT: If asample is first stretched beyond its vield polnVi-th-en-
heavily pressed, and again stretched, the limit of elasticity is lower-
ed9 and the material is weakened instead of toughened. This is defined
as the Bauschinger effect. The authors of the present paper studied the
effect of sliding direction on the character of the elastic-plastic de-
formations in the surface layer. The authors applied a method which they
had already described in Ref- 4, by which the friction of a thin sheet
(Cu) on a solid base (steel) was measured. The sheet dimensions were
0-3-5-100 mm, and the sliding rate was 0.72 m/sec. Results showed that
the surface deformation caused by friction on one side gives rise to a
hardening of the.surface. The contrary happens with reversive aliding.In
the authorst opinion, the hardening of the surface layer as a result of
Card 1/2

The Bauschinger Effect in Sliding Friction 8/020J60/134/003/009/020
B019/Bo6o
plastic deformation through friction is dependent on the sliding direo-
tion. The-surface hardening estimated after the microhardness is higher
with unidirectional than with reversive sliding. The authors correlate
this fact with the Bauschinger effect. K, V. Savitskiy is mentioned.
There are 4 figures and 5 Soviet references.
L/
PRESENTED: April 272 196-0, by P.A.,_-Rebinder, Academician
SUBMITTED: April 25, 1960
Card 2/2

S/020/60/135/003/0118/039
BO19/B077
AUTHOR: Yevdokimov.---Y--D,
TITLE: On the Wear of Friction Surfaces o., Different Sizes
PERIPDICALI. Doklady-Akademii nauk SSSR,- 1960, Vol-:,135, No. 3, PP, 573-576
TEXT: Tests about'vear of friction aurfaces showed that the surface with
a larger area will experience the greater wear even if both have the same
surface characteristic, This phenomenon is explained by stating that the
larger surface shows a higher number of starting defects than the smaller
surface if the number of defects per unit area is equal. The author used
a modellto test his theory, For the friction surfaces he used plaster
discs where steel balls were imbedded. The ,se steel balls represented
"Weak-spots" in the.plaster discs, It is mentioned briefly that the above
theory for the larger wear of-big-g-er-surfaces-does not-hold. Tests on
rock-salt-single-crystale-showed that the increase of the number of-start-
ing defects on larger friction surfaces is-not the-dominating-factor for
the wear of both surfaces. The author thinks that the main cause of the
Card 1/2

On the Wear of Friction Surfaces of Different S/020/60/',35/003/018/039
Sizes B019/BO77
diffei~entvwear of surfaces with dIfferent areas can be found in the
or 43 of
dynamics of friction. After-extensive tests the auth the opinion
tha-t- the smaller friction surface experlences.more cold hardening than th
larger surface of the same material if the rate of friction is small and
the temperature is low, if the rate of friction increases the temperature
will influence the wear of both surfaces, An inversion of the wear ratio
can occur if the materlal is similar and the size of the friction sur-
faces is not equal. This inversion depends on the physico-mechanical
sizes and on the cooling conditions during the experiment, too; It was
found that the wear of friction surfaces is determined by many factors
whose influence depends on various conditions, There are 3 f-.gures,
2 tables, and 2_2 Soviet references.
ASSOCIATIONs Odesakiy politekhnicheskiy institut (Ode"sa Polytechnic
Institute)
PRESENTEDi June 9, 1960, by P. A. Rebinder, Academician
SUBMITTED: June 6, 1960
Card 2/2

I
a

Detachable ring mandrel for fastening samples to the friction machine.
Zav. lab. 27-12o.3.-347-348 161. (HIM 14:31"
l.-Odesakiy politekhnichookii imuk~t,
(Testing machines) (Friction)

S/020/6",/136/001/013/037
9_7
AUTHOR-
TITLE: Sliding Direction and Cold Hardening of a Surface
PEPT ODICAL; Doklady Akademii nauk SSSR, 1961, Vol. 136, No. 1, PP- 74-76
TEXT: The author investigated the effect of sliding directed to one side
.----------and -of -the reversible --- sliding--produced--upon-the- distribution- of-- cold----
'hardening over the contact.surface-and..on its boundaries. A steel ring
rotated in the experimental arrangement at a rate of 0.2 m/min The micro-
hardness in the-slicting zone and on its boundaries on an Al sp;oimen for
the two kinds of sliding are shown in Fig. 1. As may be seen from the
diagram la, in the case of one-sided sliding, no particularly strong cold
hardening occurs in one half of the conl"act zone, whereas in the case of
reversible sliding a cold hardening exists in the entire contact zone
(Fig. 1b). The maximum cold hardening in one-sided sliding is greater than
that in the case of reversible sliding. Similar studies were made with a
rock-salt crystal. The manner in which the microhardness is distributed
over the sliding zone and also on its boundaries is quite analogous to that
Card 1/3

Sliding Direction and Cold Hardening of $10201611136100110131037
a Surface B019/BO56
in the case of aluminum. From these results and a study of the concentra-
tions of dislocations, the author concludes that the plastic deformation
in the transition zones decreases due to cold hardening, that the sliding
direction produces an effect upon cold hardening, and the latter outside
the sliding zone indicates a condensation of the material by its sliding
in this region. There are 3 figures and 7 references: 6 Soviet F-id I US.
ASSOCIATION: Odesskiy politekhnicheskiy ins-titut (Odessa Polyteohnic
Institute).
PRESENTED: June 10, 1960, by A. N. F-mimkin, Academician
SUBMITTED: June 9, 1960
Card 2/3

//loco
AUTHOR:
TITLE:
32835
9/020/62/142/OQ2/014/021
B104/B138
Yovdokimov, V. D
Effect of a surface-active lubricant on frictional deforma-
tion with unidirectional and reversing applications of force
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 142, no. 2, 19629 322-325
TEXT-. Results of Soviet papers published between 1934 and 1960 on fric-
tion between metals and crystals, related deformations, and the effect of
lubricantaq especially surface-active ones, are condensed in the present
synopsis* The-papers-show--that--adsorption processea play an important
part in friction and in the mechanical working of metals.' The addition of
oleic acid to spindle oil considerably reduces the frictional forces
between aluminum and steel. The elastic deformation outside the contact
faces of the two metals is reduced by this addition both it the frictional
force is unidirectional and if it is reversing. These phenomena are
qxplained by theories of P. A. Rebinder, V. I. Likhtmaa, and S. Ya. Veyler
(Deystviye amazok pri obrabotke metallov davloniyem, Izd. AN sm, ig6o).
Work-hardening of rock-ealt crystals, aluminum, and steel$ both inside and
Card I

32835
S/020/62/142/002/014/029
Effect of a surface-active ... B104/B138
outside of the contact facep depends on whether the frictional force is
unidirectional or reversing, regardless of the presence of a lubricant
(Fig. 1). Lesswork is required in unidirectional than in reversing
operation. Academician P. A. Rebinder is thanked for advice and interest
displayed. There are I figure, 2 tables, and 15 Soviet references.
ASSOCIATION: Odeaskiy politekhnioheskiy institut (Odessa Polytechnic
Institute)
PRESENTED: September 7P 1961, by P..A. Rebinder, Academician
SUBMITTED: July 1, 1961
Pi g. !. Distribution of work-hardening inside and outside the contact
zone in the case of sliding friction of a steel ring on an aluminum
sample.
Legend: (a) sliding one way; (b) sliding with reversing motion;
(1) contact zonel (2) microhardneso in kg/mm2. (1) (indicating curves)
-----lubrication.-with- spindle- oil-.---- (-2-)---(indicating -curves) __O.1%_oleic_acid--in---
spindle oil.
Card 2/

5/020/62/143/001/015/030
B1.04/Al t) a
ATJTHOR: Yevdokimov, V. D.
TITLE: litaiat(tiloo to -wear of the ourfaoe layer under alternating
shear deformation during sliding friction
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 143Y no. 1, 1962, 84-66
TEXT: In previoun studies (K. V. Savitskiy,-Fiz- met. i metal"oved.p At
no. 3 (1957); V.. D. Yevdokimov, Sborn. Issledove;iye dotaley ma'shinp
Odessa, 1959; Fiz. met. i metalloved., 10, no. I (ig6o)l DAN, 6
07rdifferences
(1960); A. S. Radchik, V. D. Yevdokimov, _DAZT, 134, no. 3 (196
were shown to exist in the stresses on surfaces exposed to unilateral
or- alternating deformation with sliding friction. The extent to which
this difference*in surface stress--affects-the-resiatance to wear is
--increase
investigated. Alternating sliding friction is shown to wear and
to reduce the cold hardening of working surfaces. In order to increase them
resistance to wear, the direction of slide must coincide with that of shear'
deformatic,a from previous machining, Slide conditions are also improved in
this case. Special'attention must be paid to this condition when aseemblin&
Card 1/2

S/020/62/143/001/01,',/070
Resistance to wear of the
B104/B108
new sliding Parts and servicing machines. There are 1 figure', 1 table, and.
3 Soviet references.
ASSOCIATION: Odesskiy politekhnicheskiy inatitut (Odessa Polytechnic
Institute)
1961-9 'by-P.- A. Rebind et Aoademician
SUBMITTED! July 7, 1961

42107
S/179/62/000/003/011/012
E194/EI35
AUTHOR: Yevdokimov, V.D. (Odessa)
TITLE. Shear strains and resistance to wear of surface layers
in friction
PERIODICAL: Akademiya, nault SSSR. Izvestiya.*Otdcleniye
tekhnicheskikh nauk., Mckhanika i.mashinostroyeniye.
no.5, 1962, 167-170
TEXT: It is known that alternating frictional shear stress
alters the properties or the surface layers, and so a study was
made of the influence of the direction of shear strain of the
surface layers on the resistance to wear ih sliding friction against
steel of aluminium, steel, brass and common salt specimens. Tests
were-made on a friction machine with both reciprocating and
repeated uni-directional motion; the number-of strokes was the
same in both cases. Wear was greater with reciprocating motion and
.tiie effect is most marked in more plastic materials.~_Similar
results were obtained in another machine with a shaft rotating in
a sleeve'- reciprocating motion gave more wear and about less
Card 1/2

Shear strains and resistance to ... 5/179/62/ooo/o.o5/oll/012
E194/E135
work hardening than uni-directional. urnan steel sleeves were
worked by pressure of lubricated rollers in a lathe t-made-no-
J_ k
difference whether su ie--cvi~o-iiia_! wear tests were
bs e-qu e nt-u iri-&i-)~, nade V
--im--thie -same' direct. ion as the rol,ling'or in the opposite direction,'
probably because the-shear strain was small. However, when
working in the lathe was .against fixed rollers or-balls, -a.
directional effect was observed in-subsequent triction tests
against-steell With friction in the opgosite direction to work
hardening, wear was much greater-than when It was in,the same
direction and nearly as great as on an unworked specimen. The
wear scars had a rougher surface when the direction of friction
was opposite to that of working.
There are 2 figures and 2 tables.
SUBMITTED;- February 19,-1962
Card 2/2

x Mq.

A004/A101
AUTHOR; Yevdokimav, V.
T MIS Effect ofsurfAce-active lubricants, on the efficacy of alternating
metal punching'~
PERIODICAL: Referativnyy zhurnal, Mashinostroyenlye, no. 16, 1962, 1, abstract
16VI ("Mauchn. 'zap. Odessk. politekhn. In-t"I 1961, V. 35, 79 - 82)

TEXT, The effect of surfacd-active lubricants on the nature of plastic de-
formation of metal was investigated by unilateral and alternating punching of steel
balls (hardened, with ground surface) 7.9 mm in diameter through hole3 'J.775 run In
diameter In a red-copper cylinder 38 mm in diameter and.17 mm high. The ball sur-
and rubbed;with absorbent cotton
prior
face,and hole surface were washed with CCI
.
I
to the tests. The tests were carried out without, lubtication (1), with spindle oil
without additives (II) and with the same oil with a 0.5,19 oleic acid addition (III).:
The presented F versus n graphs (P - punching stress in kg, n - number of ball
show in particular, that on the curVes III In unilateral and alternating
Iderably-less-than -ourves-1 and-11-at correspond-_
puric ng-P--ma --are:7cons
gnitu es
Ing n,_and that the reduction of down.to 6 constant magnitude-takes place-at-a
Card 1/2

YMOKO14DVP D. (Odessa)
Shif t deformpt ions - and wear -resistance of . suWface layers - aubj acted to
friction. Izv.b SS5_R.0td.tekh,nauk.%khA =shinostrno.5:167-170
3-0 162, (MM 15:10)
(Sarfaces (Technology)) (Friction)

4
YFIVOOKIMV-) VD., kaiid, tckhn. nauk; MEZENTSEV, S~A., inzb.- BUIRVA,
a-
KOIUW
n I.V., inzh.
BurnishIng holes in steel parts. Yfamhinostroen4n no.3~-41-1,2
MY-JO 165~ (MIRA 1826)

A:j Yev6okimov, V, 0.
TOP T C ll"AGS ela3tic deformation Fri -t Ic, 1 .-1.! ar rx
9,7 1

-5u L 'S!uLal-~Ce ur un ccois Lant a n-w I e nip A h
ces. Tdfameter 9'mm, length 14 mr rigic~ly affixed
to holder is oressed undar a Rnorl fir Instei n~n4,-v ~4
Ioutaide tho- tant"-t fa

III L i P ~f
-1-svi-rut, Odessa

A. ! - I I IJTI '~ N - ~T
". .1 1. L
, 14.
W - "

YmCKLmal, V.D.
Directivity effect-of deformations in rock ealt crystals due
to friction. Vokl. AN BSSR 165 no-3951*5-547 11 165.
(MIRA 18:11)
1. Odeaskiy elektrotakhnichaskiy inatitut avyazi. Submitted
J~ ...

TITUt Device for mea u
5 ri-rig torque and ,jxial forrea, -laas 42, N 1.76532
,I~r
Sj-'!E - '. -~ ez - ric -w
p~07rj9t'i el C--lZ'.3 ~:73. i nak
'AO;%Of
3
'71~s Author Certificate pre$
ABSTWTf -;A'ItS A deVICO for Teasi.Aring tor-que and axial
element for measuring the axialforces, and two inductive transducers for trans?.
5
C UX-3- .3
card 1 2 UDGt 53jo781t621.317.712

ACC
bir
-7p
Inc- c. r
SUB GMBt-'0,13/' SUBM DATE? Una-V-63

ACC NRt AP502891'1 2 ;r
rN nrl', CODE:
AUTHOR: Yevdokimov, V. D.
.ORG: Od6ssa'Electrotechnical Inst1tute of Contmunicatiori~jb~esskiy
elektrotekhnicheskiy Institut avyazi
TITLE: On the effect of strain directivity in friction of rock-salt
crystals
SOURCE: AN SSSR. Doklady, v. 165, no. 3, 1965, 545-547
TOPIC TAGS: crystal surface,, nodlum chlorlde, strain hardening,
Friction
ABSTRACT: The purpose-of- the _ s tudywas to check on the-experime, n tally----
of smrfaoe hardening produced by unilateral
friction. The author investigated to this end the effect of directiv-
ity of the strain connected with the plastic deformation in surface
lavers wAen NaCl crystals are In frIction, and the resultant- lattice
--dafp c t s . --%
-j -The tests were based on the fact that volume-deformed rock
ealt crystrd-Ts become phosphorescent when exposed to x-rays and can thus
produce an image on a photographle plate. The samples were 25 x 20 x
1:2 mm in size and were tented In a friction machine described by the
LCard 1/2 UDC: 539.621

1 30705-46
MUM.,
ACC NRs AP5028911 I
author earlier (witb I. V. Kozubskiy,, Mashinostroyeniye (Kiev), No. 4..
4., 1964). The test procedure waB also described earlier-by the authorl
?Fiz. met. i metalloved. v. 10, No. 10 131, 1960). The.pbotography
procedure is described in detail. The photography results were checked
by observation under a microscope. The diractivity of the.strains is
found to manifest itself during friction In different manners to cause
an uneven degree of plastic deformation, an increased amount of energy
margin in the compression zone, and an increased dislocation density.,
The ;3ign reversal of the shear deformations during friction gives rise
to a redistribution of the dislocation fields. This report was pre-
sented by Academician P. A. Rebinder. Orig. art.,bas: 4 figures.
SUB CODE: 20/ SUBM DATE: 1414ar65/ NR REF'SOV: 007
Card 2/2

EVI)OKIPOVI 11-P,.; LEONOVp E.A.
-de-lo-
(ICRA 17:,,,)

r. ry
all - I 1j; ii
gin
WE WE-
it
gln
g. P~, "a9
1 4 1
rj
:
ZT - Z.;
IF

TVAITOV, V.S.; SOKOWTA, N.A.; AURITANOV,
GURLYAND, I.S-.
Radiation polymerization of isoprene. Tvookon.soGd. 2 no.l*,
35-37 Ja '60. (MIRA 13:5)
1. Leningrad"kiv dosudarstvannyy universitst.
(Isoprfta) (Gamm rays)

AVERIYANOVo S.V.; YZ DOKIMOV, Vd-
KJOJOKI-1, H.A.; KUZTGHVAp f Ev
A,Ctjo.,j or ultrasonio waveq and -rays of CO 60 on polyvinyl
C.1:105~-106 960. (MPA- 24:4)
---alcohol-
1. Institut ovolyutgionnoy fiziolocrii imord Saahonova At
(Viny-l alcohol) JWtrasonio uavas)
(Gamma r4~)

3/020/60/135/002/0351'036
B016/BO52
AUTHORS: Khenokh, M. A., Kuzichava, Yes A., and Yevdokimov, V. F.
6o
TITLE: The Action of Gamma Rays of cc on Dry Carbohydrates
-PMODICkL:--- Doklady Akademii nauk SSSRI-1a.6ot vol.-135, No. 2p
pp. 471 474
TEXT; The authora report on their experiments concerning the action of
h1-g!Fkiim-jia-*-db-Ws-(Co-
-di - ried-glucose, -frud ose, a
and',-polysaccharid-ea.- Dry- and r-d
3.*affinOSe, mannite, and starch wIer e.exposed to radiation in a vacuum.
The resulting products were examined by the analytical methods described
in Ref.l. The action of y-rays was revealed by the strong smell of the
above carbohydrates, and by the fact that they turned increasingly brown
as the dose was increaaed. The analysis of the products revealed that
under the action of y-rays of Co 6o , dry carbohydrates undergo chemical
transformations which are closely related to those of aqueous radiolysis
Card 1/3

The Action of Gamma Ra .ys of C.060 on Dry S/02()/60/135/002/035/036
Carbohydrates B016/BO52
(Ref.1): They also undergo oxidative destruction under Vie formation of
H2COl dioxyace,tons, and organic-acids;-.the-glucoside-bonda.of--di-.,.tri-,-
and c har-Ides are ruDtured It was found that equal products are
-polysa-c. - , - I &
f ormed under -the dii.-ect and indirect-gamma action on-saccharose and-
------inannite-.--The-ultrav,!-.o-let--abs-ori)t-ion---sDe-ctra-of,-g-luc-~_%e_, fructo,qe,___________
raffincee, and star;lh solutions exposed to radiation (Pigs-1-3) differed
7 f rom -those- of aqueous~ -carbohydrate-, solutions- -expoPed to--radiolysis-i - This
indicatea that in the latter case the mechanism of chemical transforma-
tion-differs from that of,direct gamma action. The authors' data only
-,.partly provethe scheme according to which.1the reaction of the dis-
solved substances with the OH radicals yields the same products as
:formed.by direct gamma,action-(Ref-5).,The radiochemioal transformation-
in dilute solutions depends on the reAction of dinsolved substances and
H atomat OH and H02 radicals, Ionizing radiation, on the other hand,
causes ark ionization and excitation of molecules which decay under the
formation of free radicals. The recombination of free radicals formed
in dry sugars (Ref.6) is difficult due to slowed-down diffusion. Long-
Card 2/3

The Action.of Gamma Rays of Co 6o on Dry 3/020/60/135/002/035/036
Carbohydrates B016/B052
and other compounds when-reacting with water. In solid carbonhydrates
exposed to radiation, these radicals form intermediarj stages of the
radiolytic decay of molecules. Howevers it in difficult to detect these
radicals during aqueous radiolysis, since the addition of the elements
of water takes place rapidly.__jt is -WQped tha-t--thip- irork- will contribut
to--a-.bii-~lWr:-und-ers-tanding of the chemical destruction of carb-onhydrates
by ionizingradiation. They thank Professor I. Ya. Poddubnyy who nade
the experimeata possible.1. V. Antuflyev-assisted.in this work. There
are 3 figures and 6 references: 3 Soviet and I US.
ASSOCIATION: Institut ts itologii Akademii nauk SSSR (Institute of
Cytology of the Academy of Sciences USSR)
PRESENTED: June 2, 1960, by A. F. Ioffe, Academician
SUBMITTED. May 30, 1960
'Card 313

VOTINOV, M.P.; LAPIlaKAYA, Ye.M.; kUlElIO101, !l.A.j_jMQKIMOV V.F
ANTUFfYEV, V.V.; STAFEEM, AN.
Electron paramagnet~q resoriance spectra of hippuric acid Irradiated
by gamma rays of Cow. Radiobiologiia 1 no.1:149~-150 161.
OIRA 14:7)
1. Politekhnicheskiy institut im. M.I.KELlifiina I Instit~t taitologii
kN SSSR, Leningrad.
(HIPFURIG,ACID)
(GAJl%'RAYS-PlffSIOLOGICAL EFFECT)

LAPINSKAY-A, Ye.14.; KIGUOKH, K.A.; )MORPOV, V.F.
Raidiochemical transformation pf phonylelp-nine. Re&obiologiia I
no.5,:69,4-700 161. 3-4:11)
1. Institut tsitologii All SSSR~~.Lan~ngrad.
(ALANTIZ) (UDIOGI.!44ISTRY)

94044
t5 JYJ 0
3/02Y61/138/003/016/017
B
BI 03 208
AUTHOR8s Sokolov, V. N. Poddubnyyp I, Ya.#
Yovdokimov V. F..
TITLEt Polymerization nP nitroethylene under the action of y-radi-
ation
PERIODICAL: Doklady Akademii nauk SSSRI v. 138t no. 3, 1961, 619-620
TEXT: The authors devised methods for theindustrial production of high-
molecular nitroethylene under the action of y-radiation since in.this case
products are obtained which are as pureas the initial monomers. Other
methods with initiator and solvent yielded 68o far only powdery products
contaminated by initiator and solvent. Cc was use& as radiation sourcel
the apparatus is described by A. Kh. Breger et al. (Ref. 9: Deystviye
ioniziruyushchikh izlucheniy na neorganicheskiye i organichaskiye polimer-
nyye sistemy (Effect of ionizing radiation on inorganic and organic poly-
mer systems), Izd. AN SSSR, 1958). The initial nitroethylene was obtained
by dehydration of 1-nitro-ethanol-2 with phthalic anhydride. Fractions
with a boiling point of 360C/100 mm Hg were isolated from the monomer by
Card 1/5

24044
S/020 017
~Polymerization of nitroethylene ... /61/138/003/016/
B163/B208
repeated fractionation. Hot nitrogen was bubbled through-glass ampule
which-were then filled with freshly distilled nitroethylene. The oc-
cluded atmospheric oxygen was removed by the usual freezing up and melt-
ing. The ampule sealed in vacuo were irradiated at 200C, and the monomer
was distilled off in vacuo after opening. At the beginning of irradiation
(dose 1 - 106r), a turbidity was observed in the monomer which had hi,her-
to been as clear as water. At a dose of 5 - 10 6r a white precipitate re-
sults which is identical with the polymer resulting under the action.of
organic bases. On-further irradiationt ihe pasty monomer-polymer mixture
-is converted to a transparent, pale-yellow polymer block. This is appar-
ently relatea to secondary addition reactions of growing polymer chains
to the polymer already formed, and is accompanied by an increase of its
molecular weight. At doses > 0.3 Mr1hr no block polymer is formed. In
this case the polymer remains powdery up to a 100fo conversion, and turns
light-brown. The formation of the block polymer being a very complicated
physico-chemical process depending on many factors, a powder is formed in
some cases even with a 100% conversion. The polymerization of partly
Card 2/5

Polymerization of nitroethylene
44
A002 0761/138/003/016/017
B103/B208
polymerized samples continues also after irradiation is finished, This
suggests the formation of rather long-live polymer radicals under the ac-
tion of I-radiation (Fig. 2). Also in I this case block-polynitroethylene
results. The polymerization is inhibited by hydroquinone and oxygen which
confirms the,radical nature of-this process., The-polymer is insoluble in
common solvents, well soluble in N,N-dimethyl formamide. Its intrinsic
viocosity in. thic solvent is-0.38 which corresponds to a molecular weight
of 38,000. Its density is d 1-535, the decomposition temperature 1500C.
20
No denitrification (- CH - CHNO-) takes place during irradiation. The
2 2 n
crystalline phase is absent (X-ray data by S. G. Strunskiy). An intense
narrow halo and a weak-broad halo oor4l'!espond to the parameters of the
short-range order 5-15 i-and 3-73 R,, Under--the action of-y-radiation
nitroethylene may be copolymerized with other unsaturated nitro compounds
such as 1,4-dinitro-butadiene-1.3. There are 3 figures and 9 references:
3 Soviet-bloc and 6 non-Soviet-bloc. The two most important references to
English-language publicatione read as followst Ref- 41 D- Vofsi,
A. Katohalsky. J. Polym. Sai., L6, 127 (195'01 Ref, 'ts G. Buckleyt
Card-~3/5

24044
S/020J61/138/003/016/017
Polymerization of nitroethylene.... B103/B206
C. Scaife. Brit, Pat- 595282, 19471 Chem. Abstr., 42, 37775 (1948).
PRESENTED: December 20, 1960, by N. N. Semenov, Academician
SUBMITTED: December 17, 1960
Card 4/5

R
32317
4, 4 o o
AUTHORS: yevdokimov, V~ P., Poddubnyy J. Ya., andF Ku-z-'* n. 1. A~
TITLE., Titanium and tin tet.ra~,hlorides as acceptors of radic-a'1Z 4~n
the radiolysis of hydrocarbons
09 .1 -
FSRIODICAL~: Akademiya nauk SSSR, Doklady, v~ 141)-no, 5,
TEXT, The radiochemi6al reduction of TIM 4 and SnC1 4 dissolved in hl-dn~-
:arbons by Co 6o gamma radiation and the possibiliti'As of usin6 th'i
tion. for initiating the polymerization were studied, The
mixtures were irradiated in glass ampullas; (1) T3.Cl - n-o,~~tanr-,-
4
(2) TiCl benzene; (3) SnCl - n-ootane; and (4) SnCl
4 4
lotet
cyc I-rasiloxane. The oolutions were degassed; then, the ampullas wer~-
.-evatuated and sealed. After removal of thr? liquid products of radiolys"'S
a.nd-drying-in.vacuo at 1200C the subchloride prefipitations wi~re. ana_'yzed
-by 4I.J.,Dmetric titratior. with-silver chloride and platl_urv. el r-,,, t r r6
poter n
The quantity of the energ-jabsorbed was -termined-.by Iferrous sv 1 f -a
dosimetry.. The yield of the rea,~tion-was assumed to be 1526
Card 1/ 5

32317 /0 8
(I tin
Vi rL ribed Pro' jL r1i Y~l 5., -
lias bCC2 tviye f
atu
The W`Pa' '
I i ..j,p,3k! Ye 5 k5 ,ss:,
100 Ix I y e jz, d- -I
as., IP o all C (3 r.,
C. risk i r
BV )rgani C s"
-ar a
ino,.rp, nll~' -h,
a ~~A, n rlx br OIJ r - , - 5
v
fur
~ ~ j,
Tl
fill
power
G c, by
T',
:5r
Ons T 4 J, 4-,h I
r 1
ber-, zer-p- 5 t 5~1 ~i ~_ r
:7 P-gr f C-:r7~'
,, PI
_.aches
a] -hat th"
n.al,.YS-L .7~ ig 1.
i I, i 7, 4)
T, al Y'!i
tp,ly
A
0 M:p c du, 11 ~:L~
an(l
_Od~
Cy,7
an-1.
Oerstea
I tras Tll ,ar,
Card

3231*1
S/02 611/141/1005/010/016
Titanilum and tin tetrachlorides BI 03XI 10
picryl hydrazyl. The intensity of the spectruni Aincreases_ linearly with
increasing TiOl concentration. AtIthe same time, the existence 'of-the-
4
epr spectrum of the hydrogen atom stabilized on the quartz surface was
confirmed SnCl-2 is precipitated by irradiation of the mixturps (3) and (4).
GSnCl is shown in Fig. I (curve I)-, -Since it was shown-by,X,,A.
4
Andrianov, S. Ye. Yakushkina (Ref, 13: Vysokomolek. soyed. v. 10, 1503
(1960)), that the polymerization of octamethyl cyclote'vrasiloxane is
0~
effected by SnCl 4 at 120-150 V with simultaneous breaking of the ring,
this reaction was performed under the effect of ionizing radiation at room
temperature. Simultaneously the polymer formed was chlorinated by reduc-
tion of SnC1 4 'to SnCl 2' The C1 content in the polymer reached 3 mole-~3
with radiation doses of about 30,000,000 r. The molecular weight of the
polymer increases with increasing SnC1 4 concentration. The CH 4/H2 ratio
in the gases escaping on irradiation of octamethyl cyolotetrasiloxane
remains constant in a wide range of doses up to 45,000,000 r. Addition of
SnCl4 increases the CH 4/H2 ratio in this rane of doses. Thus, the 11 atom
Card 3/5

32317
S/02 61/1 41/005/010/018

Titani~,jrn and -tin te.tract _B1 0" _:I 0
radical in
i r, mor.--, active than the CH redliction. effented by
SnCl
3 4
irradiaticn. The followiri- ~)ossible t ypes of init-i-al rpacticns a e.
i n d i ca +I- e d'
R IH
R.
RHM-* H + C H
2 r 2n (3'
2H ~ C if
2
2
2
n n-
The frep, radicala formed according to (1) and (2) may irt~-rar+, wifli TiCl 4
, TiCl
- H T i C 1
-t HCI.
and SnCl + R* T I CI RCI
TiCl
4
4
3 4

a redis t ri bu t , on of ~h e e-ner6y alhis, orbc-d i.,~ no t i r; Poss i 1,11 e
JT
-- n the
relevant two-component system, if the tetrachl~,rld~~ c,~rcew:rat~ons are
increased. There are 4 figures and 14 0 SOV "et a rd 4 r. 0 n
Soviet, The three most recent referer,,.~7!s t,:) pu b I i c a t i ons
read as follows; H~ A, S3hwaPz, J. Acid Chem, Soc ; 79, (1957'~
f) Krehz,
De-ahurs t , j. Chem, Phys. 1-7 3,77 949" C, H~ 77~mf-~.rd. A. D.
Jenkins, R. Johnst-r, Pro-.!' _~Oy_ sl:'_'
Caxd 4/5

-32317
5/020/61/1,11/00/cAO/018
ntanium and tin tetrachlorides ... B103[BIIO
ASSOCIP310"11: -Nauchno-isaledovatellskiy institut
kauchuka im..S. V. Lebedeva (scientific r"T::~, '171t-
of Synthetic Rubber imeni S. V. Lebe4ev)
PRESEINTED: July A 4, 1961 , by S. S. Medvedevj Aco44gIt4qj4n
SUBMITTED: July 14, 1961
Fig.-1: Radiochemical yield of the reduction of SnCl and TiCl diasolvc?d
4
-in n-octane
Legend: (1i Sn Cl 4; (2 TiC12; (3) molar Ifecl component-.
4
t
Card 5/5

h3231
3/844/62/000/000/057/129
D204/D307
AUTIMS.-- Votinov, M. 2*t Khenokht D1. A. 9Kuzicheva, Ye.A9 Yev-
dokimov, V. F. and Antuflyev, V. V.
TITLE: The BPR spectra of r irradiated solid carbohydrates'
~OURCB: _Tr_udy__II-Vsesoyuznogo--soveahchaniya po radiatsipnnoy khi-
mii. Ed. by L. 60 2olak. Moscow-,-Azd-vo___AN,SSSR, 1962,
TEXT: The iQR spectra of some dryl-crystalline, mono-, di-, and
triaaccharides and other high-molecular weight carbohydrates were
studiod in an effort to determine the radiochemical changes tak-
ing place. Tho spectra of (1) gluooae,-(2) fructo.se (3) saccha-
rose, (4)-galactose, (5) raffinoue, (6) mannite, (7~ celluloa6,
and (8) cellobioee are illustrated$ described and discuosed. Thus,
e.g . (1) two tydes of radicals were found, .Ozle of which correspon-
ded to a fission of a U-if bond; (2) evidene"e-was obtained of inter-
action between an'unpaired election and 3 equivalent protons - the
-radical present wau a aecorkdary one; (3) t4exadicala formed by
Card 1/3

6/844,,62/OUO/000/057/129
The BPA-spectra ... I L D204//D307
the fiasion~of a 1,2-glucoside bond-and by the splitting off of a
11 from a 0;~(4) the spectrL~m became symmetr.ical on storage in air
at room temperature; (5) ~'qo -types of radicals were present, for-
-by the.-fission of 1 2--,and 6,1-glucoside bonds and by-the
splitting off of if's boAd-64 directly to 0-atom6;- (6) ar. interaction
was evident between an unpaired electron wi~4 3 nonequivalent pro-
tons; (7) two types of ra44cals were detected, one of which was
formed by a fission of a 1,4-bond; (8) two 'radicals were present,
---one being secondary. No 101t signal was detected from r irradiated
stdrchf- The coacentrations- Pf radicals and the EPR-spectra rev
mained essentially unchanged over more than 6 monthso at room tem-
perature; the radicals disappeared when the carbohydrates were
me).' ted. Theintensity of th~~ SPR signals increased, slower than
linearly, with increasing doses of irradiation* It is concluded
that information concerning tiie radiochemical changes may be ob-
tained by the BPR method. There are 2 figures.
ASSOCIATION: Leningradakiy-politekhnicheskiy institut im. M. I.
Kalinina (Len'ingrad Folyttechnical Institute im. DI.I.
Card 2/3

5/84 62/OUG/000/070/129
D204%307
AUTHOR3: bapinskayaq Y,~ L. Khenokh, M. A., Votinov, M. P. , Yev-
dolkimov,. V. P. and Arituflyev, V. V.
60
TITLE: The action of radiation of Go on solid hippuric acid
0 U RC E Trudy II Vjesoyuznogo soveshchaniya po radiatsionnoy kiii-
~mii. Ed. by L. o. Polak. Moocow, Izd-vo &N SSSRV 1962,
403-408
TEXT: The ef -f cc ts of efradiation on hippuric acid,---benzoic acid,
-in the presence of air. MOM gave rise
,.d glycine were studied in
to PhCOO, only, and glycine was radiolyzed to NR 3 and (;H20, the ex-
k-,ent of decomposition increasing with increasing dose of irradiation.
Hipparic acid it~3elf turned pink on exposure to 6- rayo, but the co-
lor disavpeared on recrystallization or on heating to 13000. The
physical properties of hippuric acid remained unchanged after ir-
:radiation. The EPR sepctrum showed 5 lines which corresponded to a
H interacting with the Ii-nucleus and two other protons. The inten7
__,uity of the lines rose with increasing dose. On heating the irradia-
Card- 1/2

210~)OIOUOIO'1011 2~,_)
-"27
0
ted acid-to -128 C one line of the 1~21'(: Upectrum wash ucerlod j. 3 a
jq-at 1800C only tho con'tral doublot' remained, and, decompo~3itioll
pea
riot ill-at 2,10oc. rckyo- iohize and e.xci-,te t1w molecules of the
acid, which suboequently bi~eak up into stable free radicals. Thue
-the preuence of the aromatic rin6 6ivez otabilitqj to hippuric acid
e r (-,. 'r o 4 f i
radiation. Th a , urea.
ASSOCIATION: Inatitut tsiiologii '%N 63SR; Lening radskiy politekhj-~ 4
Kalinin~. Ow3tituto of Gy~_
cheskiy institut im. 11. 1.
y cc mic Inotitute im.
tology AS USSR. Leningrad eol ,t ha
M. 1. "alinin)
Card 212

h3 235
S/844/62/000/000/071/129
D204/D307,
AUTHORS; Khenokh, M. A., Kuzicheva, Ye. A. and Yovdokimov, V. F.
TITLE: The action of ionizing radiation on solid carbohydrates
SOURCE: Trudy II Voe3oyuzno-o soveshchaniya po radiatsionnoy khi-
0
mii. '~"d. by L. 6. Polak. Molacow, jzd-vo AN SSSR, 1962,
409741_4
T;:,%T: The influence of oxidation on solid glucose, galactose,
fructose,isucrose, lactose,,raffinose, mannite and starch was in-
vestigated. 6- rays ionize and excite the carbohydrate molecules,
which split into 6table free radicals. The monosaccharides decom-
pose to give HCHO and other compoundal.bui no new reducing sugars
are formed. Sucrose forms fructose, HCHO and dihydroxyacetonebut
lactose gives the monosacchar-Ade only, with high radiation doses.
Hence the-411-bond is more stable to rradiation than the 2,1-bond.
in raffinose the d"'rays break the 1,2-bondgiiiberate fructose and
form HCHO and a compound containing a chromatic group. Mannite de-
composes to give 11CHO, dihydroxyacetone, an organic acid and frue-
04rd-1/2

S/84,,4/62/OOU/OJO/071/129
The action of ... D204/D307
..tose, while-starch forms a'reducing~compound,' hCHO, and an organic
acid but no glucose or maltoBe.,Conductometric,titrations of 1%
.:-:-_'9olution8 of the irradiated saccharides showed that the amount of
NaOH required for neutralization decreased in the order starch >
glucoE3&,>sucrose> mannite> raffinose~, The acidity of any one solu-
tion is greater if the corresponding.carbohydrate was irradiated
inIO rather than in N la -in solid carbo-
2 2* !2he radioch mical changes
hydrates were similar to those obsernired in th,e corresponding aque-
ous,solutions. There are 5,figures,
ASSOCIATION: Institut tsitologii AN ZSSR (Institute of Cytology
AS USSR)
Card 2/2

YEVDOKIMOI~, PODDTJBI-IYY I.Ya.; ONN I.A.
Apparatus for mitomatic potandometri,~ and --onductomet,211
titration. 7av.lab. 31 no.10:1274-1275 165.
(MIRA 19: 1)
1. Vsesoyuznyy nauchno-issledovatel'skiy ibstitut
sinteticheskogo kauchuka.

Use off &-capacity pickap to neasure the moisture coutcnt of loose
materials. TSvet. 'met 33 no.7:&12 J1 160. (MMI 13:7)
1. Gintavatmet.
(Gran-alar materials) _(Hoisture-Heasurement) (Traneducera)

YEVD0KR40j,~-G.; IWAUIN, M.M.; WASSM, N.A., kand. fiz.-
"I---
matem.r.auk, otv. red.; LEBEDEVA, I.A., red.
Lphysica; textbook for students entering the Leningrad
Institute of Construction Engineers] Mika; uchebnoe
soble dlia postupaiushchikh,v LISI;-Lenlngrad,:Inzhen9rno-
stroite. in-tj, 1963. 154 p. (IAIRA 17:4)

IEVDOKIMOV, V.G.; ROZENBERGt.L.I.;..5KIHKOj S.F.; MAKER$ I.M.J,
(Physics textbook; collectiOn of-problems with solutions)
Uchebnoe posobie po fizike; sbnrnik zadach s resbpniiami.
Leningrado Leningr. elektrotekhrL. in-t svir- . 1964. 173 p.
(~JRA 18:7)

I YEVDOKII-I)VO V.G.
Ways for further automation iDf the production of fiberboard.
I , Der. prom. 14 no.7:13-14 JI 165. (MMA 29: 1)

KMMSOV. A.K.; SHUMAN, M.Ts.; KOPTONOVICH, IOGO; YEVIDOXIMOV,
Vol.
Brief reports. Zav.lab. 23 no.7:878-879 '57. (PLPA 10:8)
I.Kiyevskiy makhanicheakiy zavod for Shifman, Nononovich)
2.Institut obahchey i neorganichaskay khimit Akadamii nauk
SSSR (for Yevdokimov)
(Laboratories-Apparratus and supplism)

V FZ. 0 M 6 T-7
Yevdokimov~ V. 1. 76 - 3-- 5-30/39
TITLE; The Reaction *9 Germanium:-TetrachlorideWi+~hGalei,,~n Oxid~^

a
(Vzaimode tviyeohetyrekbkhloriatogo germaniya z olcialyu
kalltsiya~
PERIODICAL: Zhurnal Neorganicheakoy Xhimii, 1958, Vol 3, Ur 5,
pp 1232-1236 (TissR)
ABSTRACT: Investigations on the reaction between gormanium-!V-totra~,
chloride with calcium oxide were carried out. The beginning
of the temperature of reaction between GeC 14 and CaO could
be determined in a special devicewhich makes pos!jible the
investigation of the heterogeneousreac-tion botwevii vapox-
-phase and solid phase. Three exothermio effects were
determined at 395, 595 and 6500C from the curve of
temperature-reaction.
It was found that the action of GeCl on CaO takeE place
gradually. At 3350C 'the reaction bZins by an intenze
adsorption of GeCl4 1 at 6oo0C the composition of thq slims
of the formed bodies corresponds to 3 mol CaO arid 1 mol
GeCl A complete decomposition of the rpaction-products
i'
0
Card 1/2 take
place at 1200
C.

The Rea0tion 0e, Germanium-To trac hl orid.eWith Cal o i tun Oxide M-3 5-30/39
The X-ray analyses of the formed products of rea-~ti-n
~show that the compounds have different crystalline
structures.
The chemical interaction between GeCl and CaO presumably
takes place according to the followini equations:
GeCl 4 + 4 CaO -4 Ca 2GeO 4 + 2 CaCl2
3 Ca 2 GeO4+ GeCl4 4 CaGeO 3 + 2 CaCi2
5 CaGeO + GeCl 3 CaGe 0 + 2 CaCl
3 4*-----:. . 2 5 2
There are 5 figures, 2! tabl.es, and 4 references, none of which
are Soviet.
SUBUITTED: June 4, 1957
AVAILABLE: Library of Congress
1. Gormani-m-tetrikcblorJAe-,GhoxicaI reactions 2. Cola-,= oxide-
Chamical raactiona
Cara 2/2

5 .(0)
AUTHOR: YevdoKimov,__V. I. SOV/62-59-8-40/42
TITLE: Annual Plenary Sessi.on of thc Sectica of Chemical Sciences
of the Academy of Sciences, USSR on March 25, 1959
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
19599 Nr 8, PP 1506 - 1511 (USSR)
ABSTRACT,.-~ The -annual plenary eiesaion was hold at the Institut organi-
cheskoy khimii Akadomii nauk SSSR (Institute of OkKanic
Chemistry of the Academy of Sciences* USSR). The Secretnmry of
thc Seaticm., Academician N. N. Sem-enov, read a paper on
the reorganization of work in IV-he institutes according to the
decisions of the 21at Party Meeting and the May Plenary Ses-
sion of the TsK KPS;3,(Establishment of close contacts with
industry, new economical production processes, intensification-
of research). 11ore detaila concerning the individual items
follow.-There was an extended discussion on the problems spot-
lighted in the paper. Discussants:were Academicians A. Ye.
Arbuzov, B, A.. Arbuzov, A. P. Vinogradov, S. 1. Vollfkovich,
V. A *Kargino-V, N. Kondratty-ov$-8. S. Medvadev, P. A.
Rebinder, I. V. Taranayev, A. 4. Frumkin, and Aoltdemician of
Card 1 the Latvian SSR, A. I. Kalninsp as well as the Corresponding

Ajanual Plenary Session of thi- S ea toi r, r- r.-f Chemical SOV/62-59-6-40/42
Sciences of the Academy of Sciences, USSR on
MarGh 25, 1959
Members of the AS USSR S. N. Danilov, S. Z. Roginakiy, the
Doctors of Science V. I. Ivanov, A. V. Kiselev, A. B. Taubman,
A. P. Trapezi-,kov, and others. Academician V. I. SDitsyn crit-
icized the activity of the Bureau of the S ez +, 1 o -K, and an-.
nounced an intensification of physico--chemical reocarch in the
field of polymers. In future, the Institute would, he indicated,
carry outup-to-dateresearch-work orly. The article goes or.
to mention the contributions of the other participants in the
discussion. The following persons were elected directors of
the newly established institutes: B. A. Arbuzov, Director of
the Inatitut organicheskoy khJ.mij.; '(Institute of
Organic Chemistry-at Kazan), Academician A. P. Topohiycv,
Director of the Inatitut neftekhimicheskogo sinteza (Insti..
tute of Petroleum Chemical Synthesis), and Academician A, 11.
Frumkin, Director of the institut alaktrokhimii (Institute of
Electrochemistry).
Card 2/2

5.2200 78089
sov/62-6o-1-35/37
AUTHORS., _Xevdokimov, V.-I.., Mcrozov, I. S.
TITLE:, -Letter to the Editor, Synthesis of Stannous Chloride
From Elements
'PERIODICAL: Izvestlya Akademll nauk SSSR. Otdelentye khImicheskilh
nauk, 1960, Nr 1, p (USSR)
f
ABST CT:

s report that stannous chloride was obtained
The autho
for t,,,
first time by direct synthesis from the ~!lementa.
A good contact between the ga2eoLis chlorine and the
reacting surface df tin io Important. Two different
methods were used: (1) The process was conducted at
a temperature higher, than the bp of SnCl 2(6060),
thus -removing SnCl formed by evaporation. (2) The pro-
cess,was conducted at a temperature slightly higher
than mp of tin (235-3000) thus by constant renovation
Card
1/2 of'the reacting tin surface. The proposed methods
~
-
_ indus-trlal Impo rtance. They can be used for
.are of

;RIUM
_Letter to the Editor. Synthesis of 78089
Stannous'Chlcrtde From Elements sov/62-6o-i-35/37,
the,preparation of other.products.- Anhydrous titanium
trIchlorlde was obtained from tetr6chloride by the'
-Proposed methods.
ASSOCIATION; N. S- Kurnakov Institute of General and Inorganic
Chemistry Academy of 8,--iences USSR (Institut obschey
i neorganiche--koy khInAl Imehl N. S. Kurnakova
Akademil nauk SSSR)
SUBMITTED: October 20, 1959
Card 2/2

-9/078/60/005/012/011/016
BO17/Bo64
AUTHORS: Yevdokimov, V. 1. and Sokolovaj 1. G.
TITLE: X-Ray Pictures of Reaction Products of Germanium Tetra-
chloride With Calcium Oxide
_-5~--No -.-1
PERIODICAL; Zhurnal neorganicheskoy khimii, 1946, Vol.'
pp. 2798-2801
TEXT: The reaction products of germanium tetrachloride with calcium oxide
form according to the following equations:
4CaO + GeCl 4 ' Ca2GeO 4+ 2CaCl2 (1)
3CaO + GeCl - CaGeO + 2CaCl., (2)
'4
75CaO. 20001 GdGe~ 0 4daCli-
-Z 5 -
a~i,
--d t
he'-rOadtiohl pro U0 oriql e kwraX pictures
en C-i P. 1.6iULM- 4v (da-_ GOO--K-0). Table I-
were tak- 'a :gerad a-.;-
2
4 gives the Debye diagrom, and compares it with that of the hillebrandite
Card 1/2

X-Ray Pictures of Reaction Products of S/07 60/005/012/011/016
Germanium Tetrachloride With Calcium Oxide B017YBo64
mineral (CaSiO 40H 20). A comparison of the twoIDebya diagrams reveals that
oalcium orthcos-Maa-fe-show 9 mnar A-ray pic-
tures. Tables 6 and 8 show 'Who X-ray pictures of the reaction products
0 1 0
CaGeO and CaGe 0 forming at.600 and ('50 C, respoctively. The X-ray
~3 2 5
pictures are compared with those of wollastonite. The X-ray picture of the
product 5CaO-2GeCl is similar to that of barium disilicate. Table 9 V/
4
shows the Debye dia gram of the hydration produot of CaGe205* The structure
of the ortho-, meta-, and calcium digermanates is similar to the structure
of the ortho-, meta-, and calciumdisilicates. V. F. Zhuravlev is men-
--tioned.-Therre ---are-q--t-ablea-- and 5____ f _r___ -_ _72-Soviet -~'2:_US_ and-
~M a enoes:
4k___
SI"MITTEDf'. 0, 5
er
Card 2/2-

S/030/61/000/002/002/011
B105/B206
AUTHORS: Zevdoklmoy! V.I., Candidate of Chemical Sciences
Toy
. . ~j
Morozov, iftAidate of Chemical Sciences
Moro 0
v.
TITLE: Application of chlorine in tin metallurgy (Physicochemical
----------------.-,----fundamentals of chloridizing at low temperatures)
PERIODICAL: Vestnik Akademii nauk SSSR, no. 2, 1961, 44 - 47
TEXT: Chloridizing-of tin at low-temperatures, for the economic exploita-
tion of tin ores and concentrates with a tin content below 10%, was in-
vestigated by the authors. At present, such ores are not processed at all
or only with great losses of tin (up to 50%). A further progress in the
tin industry can only be made by applying completely new processes based on
newchemical reactions. A sufficiently high yield of tin from concentrates
containing less than 10% tin, as well as the separation of tin from all
residual comp-onentstfiust be warranted. The chloridizing of the powdery
V= -6 vra_turea=~120--to-l 809-C)__takes__j lace with the f ormat ion
nftid:tth orl,6
Card 1/5

3/030/61/000/00?/002/'Oll
Application of chlorine B105/B206
results, on the basis of which the chlorUizing method at low temperatures
vas elaborated, are checked next. Under usual conditions, the first stage
of the reaction,, the formation of SnCl 2' cannot be observed, since it is
very easily oxidized to SnCl by chlorine* ~Oxidation already takes place
at a Dressure of the chloring above the SnC1 2of jo-14mm Hg The authors
also investigated the kinetics of the process in the kinetic as well as
diffusion range. At an increase of the linear chlorine rate from 20 to 70
cm/min, the rate of chloridizing increases from 2 to 6 g tin per hour per
2
i1cm of the reaction area. An increase of the linear chlorine rate above
70 cm/min does not affect the rate of chloridizing, but the percentage of
the utilization of chlorine is reduced (Fig. 1). The chloridizing rate as
-.a-_,functi_on-_of__-.the_ temperature-is- ehown-in 1Rigq_2*- -The--t-qua-tion Sncl4+Sn
2SnO1 shows-t' a netics-.of the interaotion of stannic
2 mechanism nd ki
iq_-~rieiotion- d648 -not-
starVat 600 C--a-s previouslyasdumed,-Vut.at 23.0 C. --This -fact as well -as
Card 2A

3/030/61/000/002/002/011
Application of chlorine ..BlO5/B2o6
the determination of the reaction rate at various temperatures and pres-
sures of the SnC1 vapor made it possible to elaborate the method of di-
rect SnCl synthefis from chlorine and tin,, as well as the method of oblo-
2
rine-refining of the tin from lead. The losses of tin were considerably
reduced and the refining process was intenijified. At present, there exist
t-w-o-varian-t-s- for, the- prod uo.ti on of anhydrou a SnCl : at. a temperature above
6060C and at one slightly higher than the fusing temperature of tin. __0n______
the basis of this method, anhydrous SnCl oan be produced in great quanti-
2
ties and without losses. The new.method for tin production from concen-
trates with low tin content consists of the following: the charge of con-
centrate with low tin content, and coal is heated to 820 - 8600C in a re-
ducing atmosphere. The tin is thereby reduced to metal and remains in the
charge in the shape of smallest metal reguli. The reduced charge is cooled
and chloridized by means of chlorine gas at 120 to 180 0C. Pure metallic
tin is produced therefrom. The raw material deposits worth mining in-
crease by more than the double by using this method, and the tin yield in-
creases by 15 to 20%. The processes recommended may easily be automated.
Card 3/5

3/030~61/000/002/002/011
Application of,chlorine B105/B206
Since chloridizing proceeds at low temperature,.the apparatus can be built
from steel. Collaborators of the. Institut ~obahchey i neorfranicheskoy
khimii Akademii nauk SSSR (Institute of General and Inorganic. Chemistry of
the Academy of Sciences USSR), TsNITOLOVO ((Toontralinyy nauchno-issle-
dovatellskiy institut olova)(Central Scientific Tin Research Institute))
and Novosibirskiy olovozavod (Novosibirsk Tin Plant) conducted experi-
ments in enlarged installations. It is assumed that the introduction of
this method will permit to increase the amount of tin produced and reduce
the production conto conaiderably, There are 2 figures and 3 So~riet-blon
references,
7777
Car
d 4/5

000/002/002/011
~
Application of chlorine B105/B20
7. 70.
So

'"OROC.digo

e 46MMOR&AW 1-10M,
L
-so too-
r
fdyaevqWx, T
Legend to Pig.I: rate of-ohloridi- Fig.2 a) temperature in 0C;'
zing, a and c) percentage of chlorine b) rate of chloridizing in
utilization; a) linearchlorine rate /cm 2 hr

in am/min; b)-reduction of the tin .
g
weight in 9/CM2 of the are-a.-
Card 5/5.

S/025/62/000/010/001/002
D204/D307
AUTHORS: Semenov,, N.N., VotX-11 prize winner# Academician and
Yevdoltim6v, V.I., Caiadidate of Chemical Sciences
T1712: Forever'young
PERIODICAL: Niauka i zliiznl, no. 10, 1962,,
T M-M A few isolated aspects of madern inorganic chemistry~
are discLissed, which are at present in an early stage of development,
~~The following subjects are treated: 1) Inorganic polymers, particu-
Larly linear structuren bonded in Ali.3 direciions (but not through
every unit) to form a loose network, are thought promising. 2) Semi-
conductors, where an effort should be made'to sWdy the electrophy~~
si-cal,characteristics of a wide range of materials'; an important
characteristic is the long life'of current carriers, which is in
------ turn determined by purity, perfection of lattine and surface proper-
based e.g. on sul-
of- -new -semi c onductors is urged
ties. I
-materials,
phides and tellurides. 3) Ultra-purificat'6n f - ktvown
ec of
-ding to development of new properties and extended fields
l
Card lA

S102!V6210001010100110(12
D204/D307,
Forever young~
application. Research is: recatun ended into the- related subject of
h_a%-I_or_of-m ate ri als at high lire sroure s and -lowF
a poKt.7ant_.__
and -high temperatur ~i the
in e.g. the study of plasma. 5), Silicate's and related materials.
Particularly stressed are, orylinary-and crystalline glasses, zeolites
(possibly to be.ap;plied.as molecular sieves), protection of construc-.1
tional materials at hirh tbmperatures,.refractories, cements and con-
--cretes. 6) Extractive'~metallurgy involving the use of chlorine,
(!Spec pro ing for the-rare-earth-and-other non-ferrous metals.
underlining t e nee -for
Advantages of this method are listed,, 4 --addi
tional studies. The extraction of tin by chlorination in. -used as an
example. Other new directions in this field, such as electrothermal
inethods, electron-beam fusion, high temperature decomposition and
continuous reduction methods are mentioned. There are 15 figures.
C ard 2/2

.1 ... .- - ~ lif I Mimffl%

GOGOLITSYN., M.A.., kandetekhn.nauk; YEVD0KIMM, V.I.,, inzho. 140SHENSKIY, Yu,A,.,
inzh.,- FAVLICHKOi, N.Io.0 fizh.
Restoration of crankshafts by build-up weldinge Svare proizve no,
10:22-25 0 16j.- (MIRA 16:32)
1. Kazanskiy nauchno-issledovatol'okiy i proyektnyy inatitut avto-
mobillnogo transporta.

ACC NR' AP1001378 soncE. com.s uFt/o4i3/66/000/021/0052/0032
MENTORS: Yovdokimov, Vo I.; Poliyevakiy, G. Ao
013G: none
TITLE: Method for synchronizing self-excited generators of periodic or random
sequences of pulses with determined cycle interval. Class 21,, No, 187830
SOURCE: Izobreteniya, prorqshlennyya obraztsyp tovarnyya znaki, no. 21, 1966, 52
TOPIC TAGS: pulse generator, pulse sequence, pulse amplitude
ABSTRACT: This Author Cortificate preaonts a method for synchronizing self-excited
generators of periodic*or random sequenced of pulses with determined cycle interval.
To-insure- stable- operation-of-the -self-excited pneratorover-Attios range of pulse
arid. interval density variation, inpat pulses with constant. amplitude -are- su~plied__tol _7
a. cowrarter of interval length between pulses to pUse ampl-Itude directly proportional..
to tfie length of the preceding interval. The converted pulses are then supplied
through a.synchronization cirmdt to the self-excited generator*
.14-UB CODE: 09/ SYJBH PATE t03.Jul65,
Card 1A

MOISEYENKO, A.T., inzh.; YOSKALEV, N.M., kand, takhn.-nauk; KOSHKIN,
V.G., kand. takhn. nauk; YKERVALI, O*P.v inah., red.;
DIYACBKOV, G.D., Inzh.,-red.; inzh.,, red.;
STRASMKH, V.P., red. takhn. red.1
BOFDVNFV, N.K., tekhn. red.
.[Construction specifications and regulational Stroitellnya
normy i pravila. Moskva, Goastroiizdat. Ptla Sec.B. ch.3.
(Fundations and supports of piles and cylindrical shels;
precast construction (SNiP I-B.3-62)] Fundamenty i opory 1z
evai i tsilindricheakikh obolochek; sbornye konstruktsii
SNiP I-B.3-62). 1963. -7.p. Pt.l. Sec.T ch.15.(Polymer-
base materials and produe.ts (snp i-va5-62)]~M%~erialy i iz-
delila na osnove polimerov (SHiP 1-4.15-620.- ~1963- 26 P.
--(HIPA 16:6)
1. Russia (1923- U.S.S.R.).Gosudarstvennyy komitet po delam
stroitel.'stya-2. Gosstroy SSSR (for Mkirvalij Moiseyenko).
3. Mezhduvedomstvannaya komissiya po pemsmotru. stroitelln7kh
norm i pravil (for Dlyachkov Mskalev). 4., Gosudarstve4W-
institut po proyektirovanlyk osnovaniyA fundamento*
"Fundamentproyekt" Minister,6tva stroitolistva rSFSR (for
Yevdokimov). 5. Vaesoymnyy hauchno-issledovatellskly Insti-
tut no-wykh stroitelinykh dAarialov Akademii strottellstva i
arkhitektury SSSR (for Kbplidfi).
(Concrete -piling) (NAymers)

ACCOSSION NIt: AP40004GO S/0061/63/015/006/0772/0780
AUT1101h. Vasil'yev, A.M. ; Ydvdokimv, V,H,
-TITLE-. influence ofan electric field Cn ?MR in gases and liquids
SOURCE: Optika I spektrookoplyal v.15, no.6,-1963, 772-780
chemica"hift,-notppherical nucleus, quadrupole
--quad -mo 0
~j,momentr rupolo cdu7pring tant, 7-symmartr -cat top I near-mo
M."STRACT: The Influence of an external electric field on-the splitting of the nud-
car magnetic resonance spectrum of nuclei with a quadrupole moment has been consid-
orcd by one of the authors in an earlier paper (A.H.Vasil'yev, ZhETF,43,1526,1962).
I,a the present paper, the problem is treated quantum-mechanically taking into ac-
count the orientation of the molecules in the applied electric f Leld. It is as-
--sumed that, the nuolet have a non-zero quadrupole moment and are bourd in a moLecule
with an electric dipole moment. The initial equation Is the quadrupole interaction
Hamiltonian ot Landau and Lifshits (Kvantovaya mekhanika (Quantum mechanics ],M. -L.
1948). The wave functions are derived for an qxially symmetric top molecule. In
addition, the case of a linear molecule is considered. The final equations charac-

NR: ARK009460
terize the spectrum of resonance frequencies that should app ear In liou of "he sin-
gle KHR line. Tho possibility of measuring the splitting experimentally for the
purpose of evaluating the quadrupole coupling constant is discussed. It is can-
eluded that =c3surement. of the line broadening should he feasible under the appro-
priate experimental condittns. Orig.art.has: 65 formulas.

SV IRIDOV, S.A.; PERELIMAII, V.H.; YFVDOKDIOVA, V.M. (Moikva)
Diagnosis of imterstijjijj_-c~aj,6~dsjs ------ K3.i.n-j,-
0 med.- -/+I - 1-.0,4
110~-114 Ap 163. JMIRA 17:2)
L Iz 1-7 Icafedr7 rentgenologii i radialogii,Wentra;'nogo,
instituta usovershenstvovaniya vrachey zav. - zaaluzhenrqy
deyatell nauki prof. S.A. Reynberg) m baze bolinitay imeni
S.F. Botkina.

BOCHAROV, VX.; DUDAYEVA, L.M.; )LEVIX~KP~W,, LOSOV, A.F.;
-.Y. K,,; KO
KRASOVSKIY, V.P.; LIJKIYAIIOV, E.B.; NUSATOVA, VzA.; VOVIKOV,
M.S.; SUKHOVANCMiKO, G.P.; TABELEEV, V.V.; TOU.ACHEV, A.S.;
CHMTKO, V~F,(deceaaed]; 81ITPISKIY, V.A.; FAK~ G.V., red.;
SELESNEVA, A,D., mlad. red.
[Structure of capital inveatments in the U.S.S.R. and the
U.S.A,5 analysis and methods of comparison] Struktura kavi-
talInykh vlozhenil SSSR, i SShA; analiz i metody sopostav-
lenlia. 'Mosk-vap Ekon6mikaq . 1965. 2501p, -(14IRA 18 1:5)
1. Moscow. Nauchno-issledovateltskiy ekonomichoskiy insti-
tut.