SCIENTIFIC ABSTRACT ZAIKIN, YE. - ZAIKOV, R.

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SCIENTIFIC ABSTRACT
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- - - ------- ACG IIR t AP6021781 Fig. 1. 1 - narrow-band filter; 2 phase dotoctor; 3 - amplifier; 4 summator; 5 - low fre- 7 quoncy-filtor;_ 6 balanced modulator; 7 - phaso ohifter; 8 amplifior;- 9 - amplitudo dotoctor; M- low froquency. filtor Orig. art. has: 1 diagram. SUB GODEs 09/ SUBH D=: .'22Ja65 Card 2/2 SMIRHOVp G., podpolkovnik; ZAIKIN,, Ye., myqr - '! -T,*-;. r, - .. An air regiment retaMs conquered heights. Komm. VooruLf, Sil 4 noolls37-45 Je 064. (Hill. 17sq) DONWARIV) Y,T., 1:arid. tekim- nauk; MOAKOV, V*Ao p lnzh.; MKIIIAO A.A.,, Iml, Friv,--t;Ugating th,o composition and the nature sf chemio&L heterogenelties In industrial glazso Stek, I kero 22 no.8:13-15 Ag 165. (MIRA 18t9) 1. Zavod IlAvtosteklotto K,T.~ MINAKC113, -11AILF-1111A. A-A- 164 Q Nn r~: T--i 11;oo "I ZADLINA, 1. 11. CsLnd Agr Soi -~. (dies) "Selection of maple trees umlar oon&tLons .t4We-,A - -LAI) of Moskovskaya OblaLste Voronerh,'%'1959. 20 pp (Min of Agr ISPBR. Voronesh Forestry Lngineering Inst), 150 copies (KL, 49-59, 141) _68- Hotbods of produaing large-grained millet formp. Trudy 101P. OW,biol, 5t164-172 t62, (KmA l6 t 5) 1. Mavn" botanicheakiy sad AN SSSRp Moskva* (MILLET) (COWHICUS) (POLYPLOIDY) viph; m%LSROVICH. Anna yefluovnel ..yUCHIKOV, Valentin NikO1870 red. Eps alysis) Paralichi* IAroslavl, TAroolavokOG knishnos "d r 1958. 87 P. (PARALYSIS) ZAIKIN Veni inzh.; OBFAZTSOV, Vnevolod Vladimirovichp -I.tekhn.nauk.. dotBent Special features of the eynthesis. of multicyole relay systems with contactless asynchronous elemen's. rzv.vYs.ucheb.zav. elektromakh. 7 no,l2tl470-1474 164. IMIRA 18:2) 1. Gidrofizichaskly Inutitut Ali McrSSR (for Zaikin). 2. Kafed~-a avtomatiki i telemakhaniki, Novochorkasakogo politekhnichaskogo instituta (for Obrastsov). Ye.Vq UaTNA. VYGOVt UnIng- of hatrth blnckss~ ph aea trca 6fr,-:~~at ~,7, am--rtzits- 164. M ZATKTVA, Y. G- X^d. IWt-, -c191.9- Nor., In3t. Phy3iological ixa. L F. Favlov, LI-pt. Biol. Sci., Accd. Zci., "The Problem of Efferential Functic-mi of thin Dorsal florve:s: I. Fc,le of tho Ir!rv6s in Snmphathttic Crbcli-Gine Tsinnkiy Phenotiena in f;,01d Blocclei Dorn ~3 111 I~ni-nals," Fiziol. Zhnar. SSSR, 35, No. 191+9; d...Ii. Effect of Do-rial Mnrvez on tht -of 3~.m. -.alhelti-_ Cr:),.k11 Ginetstnskiy Phenor.!tna in Itlarm-Blooded Animals," ibid. r= MR". - 38290 ZAIKINA, M. T. Vllyaniye ezerim i atsetilkholina na siq*ticheakiy fe:aomn orbeli- Ginetainakogo. Sbornik trudov (Arkhang. gos. med. In-t)p v7p, 91, 191.90 s. W-23. - Bibliogrt 16 nazv YELIKOV, 9,p.) ZAIKINAJ,~ IAIIA. --j Some properties of Cell Oxtracte frm y"st ftngi. Blulokv- biol, i x6do 59 no.598244 065, (VI RA. 3.8: 11) 1. lAningradskiy khimiko-fm'Mt8svtich89kiY 'nstltut' j,,imitted February 4p 1964. YFLIfiCFV,, N.P.; FROLOVAj, M.A,; ZAIKINA, N.A. characteristics of the complem-ant fixation reaction in nandidlasis ta-eated Oy antibiotics and other preparations. Eksp, klin. lssl,, 'Xim 1525) po antibiot. 2:UG.U5 160. OLEY (COI LENT FIXATION) (MONILIASIS) WrIBIOTICS) -QpmAlr.MaW4 V. V. DOBRC),"ffSLOV V,V.; YELIWOV~, N.F.; ZAIXIIIA, N. KOIIDRATIYIVA, BYSTROVA A*,, A.A.; MXDVEDIKOVA, A.A.i SILUYAJIOVAP N.A.; MVX -0--9-T, Study-of the antifuzigal propertiesand chemotherapautle. actirity of antibiotio 26/1. Mcsp. i klin. ioul.-po-antibiots 2:2t~-~-295 160o (FIRA 15:5) -(ATITIBIOT.IGS) YELINOVS N, F. ; Z A I KI 11 N. I'll"ido, Vor.. med. 9 F7,-!T ( 1, /T .;r AR6022387 (N) SOURCE CODE: UR/01197/65/000/024/6065/W65 ATjTHOR: Felldman, I Kh,; Frankovskly,, Ch. 3 Yamshchikov, Vo P.; -Mordvlnovep Yes To; knryukbtap Yue &; Zalkinap.N.-46; Vito-rokays, G. o; Arkad'yevap 0, Ye, TITLE: Azo-derivatives of benzene as potential antlbsotqrial~compounde* SOURCE: Ref. zb. Formakologiya. Toksikologlye, Abs. 24-54-512 REF SOURCE: Tr. LeIningr, khim.-farmatsevt, vyp. 18, 1965o 171-17 TOPIC TAGS: benzene, chemical compounds rlicroorganism contaminations bacteria,, plant parasite ~ABSTRACTI An In vitro method of serial dilutions was used to test the activity of several syntbatic azo-compounds in relation to dermatophytess some gram positive and gram negative bacteria and two species of yeastlike molds. All the tested szo-compoundJ containing a carboxylic group proved inactive. The exception was 2.4-dichlor-3- carboxy-41-oxyazobanzolo The azo-compounds displayed highest activity in relation to Cro.nooformanap weaker activity in relation to dermatophytes* and the weakest in relation,to Candida. albioans, Only L c6rd lZ2 A.C NR- AR6022387 certain azo-compounda displayed antibe2aterial and antIvIrus action* The bigbe3t In vitro activity was displayed by 2.4-dieblor-41-mothyl-4- oxyazobenzol and 2p4-dichlor-41-oxyazobenzol which proved most effective in relation to yeastlike molds and dermatophytes.ond weakest in relation to bacteria, No Zabolotakayao 47ranslation of abstrac-t7o SUB CODE: 06,p 07 2/2 card L ZAIKINA, !.A.; YELINOV, N.P.; YAKIWVt P.A. Purifleation of waste waters Ar-the antAblotics industry. -Trudy Len,khim.-farm,inat, no-15t279-284 162. (MIRA 15;11) (ANTIBIOTICS) (lNULbTRIAl, WASTFS) ~,-ZAIKINA-, N.A.- Tojeting the nev ant(fungal antibiotic 26/1 an the CdMU& carrier state in white mice. Zxop. 1 L-1-4-n. isol. po antiblot. ;Zs296-299 160, (MIRA 1515) (CANDITA) (ANIBIOTICS) ZLIXIYA, M.G., kand-fiz,ko-matematicheekM nauk 3brpansion of eTen numbers of an imaginary quadratic field into - a sum of tvo Osemislople, summands* Veh. cap. Kalin. goo. peA. inst. no,5:88-117 158a (1KIP-413:10) (lumbers. Theorv of) I ~ IU.111VA. N.G. ~jnxry quadrstic field ConsistlAff . --1- - ..- " ~-. I - i, i1i of wobers of au 12N I -- itriblat deals. Vah. Ica? HDPI 108, 261-272 - '."?- (Ku 11112) -1 f Small simple i (1,=-ooro. Theorf Of) ZAIKINA N.O. 'Matribution of nonresidues of the power a along ths,:xodulus of ,simple ideal In an Iroginar7 quadratio flold. Vch.-%xp JGPI 10&. 273-;2E2 157, (MIRA Ili 12) (lumbers, Theor7 of) I I ZIMINA, N,G. ---- the soutYArn t ta 0 ic f.,jorj f'ro,% Quaternary rjedirAnts af digtor - pal,t of the maz Poninsula. Vesr, Mosk. -an. Sor. 5i Geo 19 A ~kRA 17:4) nc.l.-76-78 Ja-F 164. IdZSBINSKAYA, Z.V.; ZAI IIA MIRE, A.P., doktor geogr. ;Kl~ nauk,, red. (Guidebook for practical exercises in a course on "Quaternary geology"; method of diatom analysis] Ruko- vodstvo k prakticheskim zaniatilam po kur--u "Chetvertich- naia geologlia"; wtod diatorovogo analiza. Voskvap Eosk,, gos, univ., 1964. 74 P* (KIRA -18:5) ftEvi-i-U-aIti-en s of Munerical Irimcticus Conn6eted-Vith Swe Problems -in the Theary of Mraginary Quadratic Fields." Cand Pbys4kth Salt Moscow State Pelagogical xr-stp Moscov, 1953. (RZWAtv Jan 55) Survey of Scientific and Technical Diesertaticas Defended at USSR Higher Educaticnal Instiutions (12) SOt Sm. No. 556, 24 Jun 55 MKINA, R.O. (Kiyev, ul. Sakmaganskogo, d. 83, kv. 1); VOYSTATSMY, V.A. (Yiyev, '---------uT.-Chudnovskogo, d. 19, k-r. 12) Distribution of ethylene-substit-ated phosphoramines in c4irtain tiestAs and o-gans of animals, Top* o&c. 4 no*$.'557-561 158. (IIIAL 12:1) 1 Iz ukrainskogo nauchno-issledovatel'skogo sanitarno-IdAzicheakcgo I;stituta (dir. - dots. 11.1. biganskiy). (CYTOTOXIC DR=, metabolism b is (1-az ir idlayl)-phany lamina phosphina oxIda, distrilution in variwis organs In animals (1ha)) Work capacity of hyprtenaive patients before ej~d aftir treat- ment with RwMolfia proparations in -a polyclinic. gov,aosde 26 no.112104-107 11162 (IMA :L713) 11. Iz polikliniki imeni Dzarzhinskogo (gl&w,yy wach -- im- oluzhemyy vrach PSFSR T.G. Karakozzorv zave terapevti.-fteakim ot- deloniy(im B.A.Abanenov)p W)vkvao ZANDW, T.A. Atheroaclaro-tic-c ardlos clarosts vItlwut hypertension wid with It. Sbor,nauch.-prak.rab.Poliklin.1m.F.E.Dzersho ao.209-44' 161. (MIU 1614) (HEART-DISEASES) (HYPERTEISION) (ARTERIOSCLERNIVS) ZAINIM, T#A# I Treatment of ,"artension tV xms of Rawolfla serpent:40 . preparations In polyalluics. Sbor.nauch,,-prsk.rab,FblUUn. im,F,E.D%Grzh, no,245-52 l6le (MRk 164) (HrMTENSION) (RAUWOLFIA) BAUNNOT, A., lush.; ZAIKIN&* V., Insh.; IPPOLIWTA, I., Insh. Devica for erecting reinforced concrete columm. 1k awrol., Hosk. 2 -n0-8:30 Ag 159. (MIRA 12:.,:L2) 1. Stroitallnyy uchastok-19 tresta Roastroy 96.4. (Coluxtas. concrete) SUCHOGLO.VP -81.I.;_~~~V-,'D-* Effect of technolo~gical factors on the comwtlw - of rwor fap- - I -- sterite materials, Ogneupory 26 no*7;323-327 163.012U 16:9) L, Dnepropetrovskiy metallurgichaskiy inatitut, 3/137/61/000/lDll/008/123 A0601AI01 AUTHOR: Zaikina, V. D. TITLE; On the problem of slag-stability of fireproof articles PERIODICAL- Referativnyy zhurnal, Metallurgiya, no. 11, 1961, 2. abatract UB12 (113b. nauchn. tr. Dnepropetr, metallurg. In-t1f, 1959, no. 38,-85-90)- The best resistance at high temperatures and low slag Witions was demonstrated by Dinas brick and dense forsterite in the study of refractory-slag eq:jilibrium systems., At low temperatures and high slag additions the forsterite chamotte refractories have In all instances demonstrated a low duratility. The greatest destruction was undergone by Dinas.refractory and by porout synthetic forsterite on account of the formation of 1o% melting-point silicatca. Forstezite refractories, in contradistinction to DInas brlck ones, form with the slags an easily removed crust. Chamotte refractory i~i destroyed on account of the inter- action of the slag with the surface of the r(ifractory and the runof:.' of the reaction products from it. The greatest durability was shown by ma4pesitochrotaite refractory, dunite forsterite, and dense synthetic forsterite. The nature of their destruction Is: magnesitochromite and the dunite forsterite are Card 1/2 S/13 7/6 1 /ooc)/o 11/00 8/12---' On the-problem of-slag stability-,.... AoO/Aioi - impregnated with. slag, -and the dense -synthetic- forsterite is destroyed as a- result of corrosion, dissolution, and slag-saturation. V. Oparyshevc [Abstracter's note: Complete translation] Card 2/2 WSR/gngibaering Pover Plants, S&P ~q Electric Engineers, Pover *Kiev Interoblast, ]Department or VNI= (All-Tinion, Technical Society of Power Engineers)," A A. 1p- Wko, Engr, 1 2/4 pp 'Slektrichestvo" No 9 Oml the basis of results in socialistic cow- Petition of VNIM departments, Kiev Interoblast Dept vas awr-rded first prize and transferable Red Sumer for 1948. Contributing factors in the 11ev wacce as: (1) mass participation of society anabars in cnative I scieAtific fng" '64ie --r='n%'xp Slibetr e'L (ContdY activities, rendering aid in orgeanizational and Acientific engineering matters for improving qualift~ ettiona and expanding political vlevpoints; (2) originating measires to strengthen creative teawvork *f scientific and industrial vorlters, emphasizing . liv=tance of new techniques.; (3) aiding innovators sad efficiency experts of Industry. The Kiev society bas nearly 700 members. 77' USSR/Ilectricity Personalities Mov 51 wP-rafes-e-or-A.-T.- Orlovskly (HIs--50th-BIrthUy arA-24 Years-of Pedapirical- cad Public ActivitA" Prof A. D. Mesterenkos Corr Rem, Acad Sci Ukrainian SSR, !?~rof 1. 1. G-.!GberLl Dr Tech Set, Docent V. G. Xholmekiy, Cand Tech Set. X. V, Zubanov, C'hLef Inr . XLeven- ergo, Yu. V. Kartashavokly. Chief Znf-r. GI-mve:-targo, RM, Ukrainian STR, A. S. Taretsov, Dir, Kiev Heat and Pow*r Sta. A. A. Zayka, Ingr "Ilsk-trichestvO No 11, P 91 Orlovskiy has been he" of the Cbni.r of Centr&I Zlea Power stations, Kiev Polytech Inst since 1937, and Dean of the Mec Ragineering Taculty of the latter Institute since 1944. At present. he La directing work in the Kiev Polytech Inst on the problem of generating reactive power in mercury-converter units. Orlovakiy has trained more than 1,500 eloo engineers* 201TO I-- ---I ','a-w' Mr R.4, A., ZAVSSKIY, A0 M., lSktOY. V. P., vismmy, B. A.~ SRI-',RBTN, S. M., AMTJSCFLISKIY. F. K., BAUPGOL'TS, A. I., ZO,WTAIV,V, T. L., PUSHIMEV, M. I., PROSMYAKM V-, GURVICH. A. H.. ~F'SIMO, A. I., SHM-S, 7.'T., XONMATIM, G. H., IMOV. S. V., ALUS74M, A. TN., BOLOTOV. V. V., TMOIE M-, 1. M., GERASIKOV, 5. T., MONTI M, I L. A.. LMVIT,- GO. O.,-ORLOYSKIY, A. V., VZDIUiOV, V. M., STRIKOVICH, M. A., GIMMAM, L. K., NIKIYOBbV,- V. V., SOLODOMKOV, 0. S., SMIRNOV, S. P., ZOLOTA"WA,N. A., KALXXIITA, -9. H.. GOLIDICRSUZZYN, T. L., XTEBAROV, L. D., SALUYEV. N. F., ZAIKO, 4. AUL.MARIMS, H. F. A. S. ObituAry. Maktriabastvo, No. 2, 1952. SOI - Month List Of Russi8n ACCessionsp Library of congress, Tml,,r 1952 Una. ZAIKO, M., inzh.-pilot I Can weather be ordored? Grazhd.av. 20 no.11:22-23 N 63. (MIRA 17:2) RAZADVI A. T#~ and H MjIACIT2VAp`Oo A. S. . M. RATov chor"'Icrij. Tcchnolor!,icnl Inotitutc, Kazzin, and the K--ziii ll-~iccnl lrztitutc) "Estcr3 of fdl~ylplhosphoncus ard Dioll-Ilphosphinic Acids and Thei~- Bio- losicijl Activity," Kbimiva -4 Premencenic Socdinerii (Che-mistrly and Applicotions of Grgaroplicspharous C=p,:-unds) pp 205-217, 1c"57 fl*)O: A-3MI, fWl trv!wl.,9t!or. AMSKATAo L.8,; Urim=A, I.Y. Pharmacology of the paranitr*phwql aster of diethylphotqihorle acid [with summaz7 In English]. Pam. I toks. 22 no 1:66-69 "'~-P 159. (HDU 12:4) 1. lafedra famakologii (zav. - dots. ROA. Aluf) Xazanektgo madi- tainalcogo inatitata*' (PROSPHINIC ACID, role cpda. diethylphos Inic acid p-nitrophonyl aster. pharmacol. Rug)) ZAIXONHIK(YVAt Nibuphinq a nev cholinamlwtic drug. Faz. zed. zhura not 2:41-43 Mr --Ap 163. (11MA 14-4) 1, Kafadra farma,',-olcgii-(zav,-- dotsent T*V. Raspopova) lizanskogo maditainakogo.instituta, (PHOSPHINIC ACID) VLASNOVAI V.M..; ZAIIM41UNU-~V' flibuphinp a new antiglauccmatous drug, lUtz. =ad. zhur, =). 2:46-48 Mr-Ap 161. (I-ILRA 14:4) 1. Kafedra farmakologii (zav. - doteent T.V. Raspopova) Kizanskogo meditsinskogo instituta i kafedra g:Laznykh bolezney (zav. - prof. A,N, -Kruglov) I Kaza.askogo gosudarstvennogo instituta dlya usovershen- stvovaniya vrachey im6ni, V.I-.- - IAnins-,- (GLAUCOMA) (PROSPHINIG ACID) TONATTEVA, O.A., ZAIKM-IKOVA, I.V.1, AGONSKLYAv L.S. Antibacterial properties of organic compounds of phosphorus. arxi - - - application of organopImpIvrus comicands) &, IV,. AR~3=ir,, Ed, Publ. by Kazar &MI, Acad, Sei. USSR, Hoscow 1962, 6 1 32 Collection of co =late Papers prosanted at the 1959 Kazan Coaforance on Chardstry of XganoohosphoruB Comounds. 71. AM- , AM. YITIR CoR. BIC:PG1 ICU AC'.'!V:':! C, A,D DIA I 4 ?57 7Z -Z U rrI.TZrl . . , . l . . . 73. . f . . . . . . . . . . . . . . . . . . !~ ,U~:;. i. .. cc D.Niliu;l) OF TM~ 07 M12 YrC;:, U . . . . . . . . . . . . . . . . . . . . . 4L3 7A. MICIV V;'.1 6Y . . . . . . . . . . . . . 4 ~-41 75- Kil =-TA M' O.MANQ~)l . . . . . . . . . . . . . . . . . . . . . . . 4,;3 76. BICCYI',, AND :MPZ7:,;-, 0, 1 f:,.. m IA 11 'r., W t ',r . . . . . . . . . . . . . . . . . . . 418 77. TJ 5 F.' 0 P. PmoF03 Dvyr ~,, f. OF TAN e.) 1.1 11113 . V. N. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 472 71), UP, AV M.',Lt :J':; IN -ifS OV kliD I i4Uf;,-MAL ' I. ~, V. . . . . . . . . . . . . . . . . . . . . . . . . IU!Z0!-- 47G 79. IXXICo=! OF CIIGAVIIII~~:1141: . . . . . . . . . 60 POLIC.N[M. . . . . . 4CS . . . . . . . . . . . . . . . . . . . . . . . . ff.1,,.,-,*-,I;Y,~,,-!,) JOIN-MT ~XOPO!, . . . . . . . . . . . . . . . . . . . . . ... 430 62 K.A. . G,~ 7:- Ac A lii~&IAFAT~,-,:l 17".. . . . . . . . . . . . . . . . . . . . . 61. CLTNIC-41% V. 14. k;tt~ gm. E15 D T~, - 0 [ Ii 0 t, G %: 1 A GA C', WXC A. Z. 14. 03! , . . . . . . . . op GrAy 51Z 87 , ..: , - ;;G I luin-Arr TUIC17'-f OF T . A. 1. Colo,-`-, . . . . . . . . . . . . . . . . . . . . . . . . . sis ca. Al ir-li SICIZIEZ3 A.M 0 . . . . . . . . . . . . . . . . . . . . . 520 Eig Z~Isz:l CF ON pril 27.~, ", 524 . of Zdl clr~~ 't"IL -C, j KUDRYAVTSVA, N.P.; ZAIKONNIY.CIA, I.V. ; AM, KCA, L.S, -- Effectiveness of new phosphorus organic substances in I;Jie troatmont of diphtho'cime Ir4z *Mod. Zhur. no.6t4l-44 162. (MIRA 170) 1, Kafedra detskikh infoktsi) ~zav.-prof. N.P. Kudryavtseva) i kafedra,faravAologll (zav.-dotsont T.V. Raspopova) Kazanskogo meditsinskogo instituta. AFONSKAYA,, L,S*; ZAIKOIINIKOIIA,, I.V,; RZHEVSKAYAO O.F.; STUDFANTSOVAp I.A., Mechanism of the action of amin and nibufin, Fara. i toks. 26 no.2:184-189 Mr-Ap 163. (KIRA 170) 1. Kafedra farmakologii (zav. - dot-sent T.V. Raspopova) Kazanskogo gosudarstvennogo meditsinskogo instituta. AFOIBK"tyA~ ZAIKOI;Lk'I A love Search fcr Frote:ctive an! 4 p,J r with some cirganopho.-3phonin cof:pmrda. Ratich. tr .y a,,;,. -C n,7 red. in,-t. 1. K&iedna farvinkologii (,,-a%,,. - dot-,ent T.I.'.Ntjpi)j,,:~v Kazanskojo medl",fFinokogo In.9tituta. :IDUX.AM. A V G ZAIKONIIIKOVA,-I.v .- ll!-L ~xeating -'ri-7Jrr,-,-.;7r-.,a2!5 Ir 1. Kafedra farmakologil (-Lav. j 2--Tu kafedra 1 M shcharov) Kazanskofro me it Pleabanima of Lh" actl~,,r. of -1--ittifir. on I.,- i"vaxt -,7. acuto radiation. -~i.clalens in 4!d. nid. 9 nc,.2v5C-,:)- 'D 164. 1. Kafodra i rwiielogrli i luitedra farnzdlcl~Np"i Kazanskogo irieditnln-,lkogc~ Ar-st1ttit-ap -ZAIKONIIIKOVA,- -I V -, KADYROV,--M *-G~; -YARYGINA, - Go- - Experimental -- studies. of - the-- harr-,lees nature of epoyy caspoun.da as a dental filling mterlal. Nauch. trudy Yaz. goo. moil. inst. 14:173-17,4 164- (MIRA 18'.()*, 1. Kafedra terapevtichaskoy stomatologii (zav. - dotsent G.D. Ovrutskiy) i kafedra, farmakologii (zav. - dotsent T.V.Wkspopova) Kazanskogo moditsinskogo instituta. T. V. Ra=lta of the work of the Niarrviiological Departz~-..nt Iii study of organophosphorva co:~,jnuracm, I'lauch. trudy med, inst. 14:175-176 164. . (!,!,T i18:9) 1. Kafedra farmakologit (zav. - dot,Jont T.V.Ravpcq-.ova) YjA,Umakogo madiuinskogo inotitutao ARBU,7,()V j B.A., akademik; V12,ELI, A.O.; ZAIKONNIKOVA, IN.; 5RI)EIITSOVA, I.A.; DTJ','IAXEV, V.G.; ZVEREVA, M.A.; Oroganophosphorus compounds of low toxicilq-. Dak-I., 1.11 S,3-c7R 265 n0.1291-94 N t65- (MI RA 18: 10) 11, InBtitut organicheskay 1-hi-mii All SSSRI, Fazzan', i Fa:.panskiy gosudarstvennyy meditsinskly institut. ZAINONNIKOVA, T.I. - 14 xican ipeclos of UV ge*us flentzia Tlhunb. &tmt.Gort.. a'-155-161 t630 (MIRA 170) ZAIKOHHIKCNA T. 1. of the Bpeciea of the gemm Deutzist Tlvmb. belo&--, ging to -the oection 14esodautzla Schnaid. Bot.zhur. e,? w.2i2O2-- 212 F 162. (HIRA 15:3) (Deuttla) ZIAIKOV. AleMandr Matmeov ZAIKOV, Aleksardr Matveevich. Geroichcskaia 5hatura, pervenets sovetskoi elektrifiEntsii. Y,oskva, CDsizdat, 1928. 1-19 p. DLC: MI. ~z"6 - 5148 7,3 SO: LC,fl~viet Gec!graphy, Part 1, 1951, Uncl. 28674 8/92 0/61 /14 0/'002/019/023 Ll $ C)O BI 30/B1 10 JXTHORS: Zaikov, G. I., Mayzue, Z. K., and Emanuel, K. IA. , Corresp()rkd- Tn-g-M-e-m Fe-r -1-5 _'U S S R TITLE: Mechanism of chain ramificati one .-during - oxidati on of methyl -------ethyl ketone in-liquid phase PERIODICAL: Akademiya nauk SSSR., Doklady, v. 140, no. 2, 1~)61, 405-406 TEXT: The authors found that the degenerate chain ramificatic-n during oxidation of methyl ethyl-ketone (1) in liquid phase proceeds through the decomposition into radicals of two intermediate compounds, keto hydro-, peroxide and diacetyl. (I) was oxidized with atmospheric oxygen in an autoclave at 50 atm and 100-1450C. The oxidation products (acetic acid, ethyl acetate, diacetyl, ethanol, peroxides, 00, and C02) were analyzed chemically or by paper chromatography. Prom the course of the kinetic curve for the (I) consumption (Fig. 1) it may be concluded that the oxida- tion is a reaction of the first order. In fact, a complicated process takes place, which is suggeated by the chain reaction and the itnomalously low factor before the exponential funottoo in the aquation for the constant Card 11of 28674 ,/61/140/'002/019/023 S/020 Mechanism of chain ramifications ... B130/B110 of the reaotion rate k = 5.2-_1Q,exp(11,200/w) Geo-1. --The chain ---Character -of the~procesa was Froven by addition of a-naphthol-(II) as inhibitor* In the presence of (II), a noticeable induction period occurej the duration of which rises with increasing inhibitor concentration. Tne rate of formation of chains dvring oxidation of (I) gas deterzined from 1< the kinetics of inhibitor concumption: G)o - 1-5-10- mole/liter-sec at 1450C. During the process, the rate of initiation rises as c:,mpared with 1% due to the formation of degenerate ramifications. Ths rate of initiation during the reaction was determined by measuring thiB consumpt:Lor. of inhibi tor (11) freshly supplied at different time interviLla. Fig. 3 shows thi~t the oxidation of (1) proceeds like a chain reactioa. The ra".e of initiation, however, rises to double its value only~, Fordhe rate W of oxidation of (I) t it is written down; (j - (k2/"5)1RC 11tji j 12. k11 increasevof the reaction rate (j to-double its value changes the initiation .rate ci11/2 by the 1-3-fold Ionly, which leada to a linear dependence of the reaction rate on the-co=entration of (I)p i.a.g to a reaction of the firv: order. The rate of chain ramification during oxidation of (I) rises in proportion with the accumblding amount of keto hydroperoxide only at the Card 216 28614 8/020/61/140/()02/019/0211 mechanism of-c-ha-in ramifications S130/BIIO bsginning of the reaction. ~Latsr ont a higher total rate of formation o' ie7-observed- than- -corresponds -to- -the - deoompos it ion -o,.!-keto.- hydroperoxide into free radicals. This shows that, besides heto hydro.. peroxide$ other intermediates participate in the chain ramif:ioation -during oxidationof (1). The assump~icn of a cooperation ot diacet 1 (formed in this reaction and readily decomposable into two xadic&12~ W(LG- 13 oonf irmed by an increasing rate - of chain ramif Loation on 'add Ltion of diacetyl. - The dependence of the ramiflcation rate on the to-tal concentra, ti on of ke7tq__hy`d-r`6-p-(s_r`o%-UO- IPII ka Oal +. ? IPIII t Aler-O 0 is- -the rate -of initii~iicn at: -a certain instant -.ol Vqe reaction,- t- ------- ---- [D) and are, the.- concent rat ions -of- diacetyl- and keto hydroperoxide. On a mixture o an 4 -2) From (1) and obtain& '0 1/02 a ~rDll (+2) ~kw2/okj [P]II/f [,D]2 + (k2/k, IP1,1"k2/ki can easily. be L-J a d - 3/6 a 28674 /61/140/002/019/023 S/020 11 a c hr L,, of chiiii ramifications- B130/3110 ..calculated sinoe"ths, other data are-experimentally dete=1ned.i-_ he or-ki- at 1 -10-5 -sW-l for k,- 1-4910' fouhd7 f 0 sec.l. ~There are 4 figures and 14,references: 11 Soviet and 3 non-Soviet. The three referender, to Enel'ich-language publications r6ad ea follows-, W. D. Zdqons~ G, B. Lucas I J, A.m. Chem, Soo. 2267 (19501 J. S. F. Pode , W. A. Waterep. Jo Chams.Soa-$ 1556P.717i W, A. Watersp J. Chem* 806-P 1946, 1151. ASSOCIATION: Institut khi_mi_bh.es-koY firiki. Akadsmii- neuk 193P. (Iristitute' -Aca, Gmy o of---Chemi oar physiod~of th4 d f Sciences USSR) PBUITTED. llay~120j 19~1 Sl~i - I..- Kinstid ourvea for the ejonsumption of mothyl-ethyl'k4stone and the a cr lation -of --reactidn, products at T m 145 C_ 50 atm, and e.r ouinu 0 pressure .*4106ity -s*20-litb:~a/~r$~',,O.I)_Consudption of methylethyl ketanes (11) comi- -'anam6rphosis-of-curv e _16g~vithmid! ourarlation of aoet:.o acid, W-002i (4Y00# (5) ethyl aceta diacdtYl,~ (7) keto hy6roperoxide (righ't-hand iicale), -(8) ethanol (right-liand spal a) --Legsadi hr, (b) molsAb- Card, 4/6 ZAIXOVI GoIll, MAY14USI Z.K.-, MANUELIS Nome Mechanism-of chain- branching -in- the -liquid- phase oxidatian of Piethyl ethyl ketone. Dokl. Ali ESSR 140 no.2:405-4CZ 3 $61. (MIRA 14: 9) I.-Institut khimicheskoy Miki All SSSP. 2. Chlen-korrespondent AN SSSR (for Emanual'). (Ketone) (Oxidation) KOVALEVAj, Z*Ta.1 ZAJROV# G,K*j SAFONOVAt S,,Kh,, Therapautia offdai of msuAlrio, ProllstrAry nporto ThAy I-go MMI 34:434-439 164. 18111) 1, Kafedra psikhiatrii (zav. - zas-luzbennyy dayatelt muki Prof. V.M. Banshchikov) 1-go Moskovakogo ordena lAnina itedi- tainskogo inatituta imeni Seohenova. 88359 9/195/60/00-1/004/004/()1r BbIT/ 05'5 AUTHORS: Blyumberg, Es A.t Zaikov, G. re, Kayzas, Z. K., Emanuel', TITLE: Oxidation of Ethyl Alcohol in the Liquid- and 1he Gaseous Phase Under Comparable Conditions PERIODICAL: Kinetika i kataliz, 1960, Vol--I, No. 4, PP- 510-518 TEXT: The kinetics of ethyl alcohol oxidation in the liquid- and the gaseous phase were investigated at various temperatures and pressures. Oxidation of ethyl alcohol in the liquid phase was carried oat at 145-2300c-&nd 52-95 atu. The kinetic curres representing the ethyl alcohol consumption and the enrichment of the reaction-product during liquid-phase oxidation at 52 atm and 145, 200, and 2300C appe&r in fig. 1~ The reaction rate increases with temperature. The activation energy of othyl alcohol oxidation in the liquid phase is 10.2 koal/nole. The. reaction products of ethyl alcohol oxidation in the liquid phitse at 200 OC and 52 &t0 are tabulated. The main reaction products of oxidation in the liquid phase are acetic &aid and ethyl acetate. Fig. 2 shows the CazJ 1/3 88350 Oxidation of Ethyl Alcohol in the Liquid- and S/195/60/001/004/004/015 the Gaseous.Phase Under Comparable Conditions B017/BO55 kinetic curves of ethyl alcohol consumption and enrichment of reaction products during oxydation at 2300C and 52, 70, and 95 &to. ?ho corres- ponding curves for oxidation in the liquid phase at 52 eta aud 145 and 20000 over oobalt acetate are shown in Ifig, 3- Both the reaction kinetics and the composition of the roatition products in gaotame phase ozidation of ethyl sloohol differ from those in liquid phase oxidation. In gaseous phase oxidation, CO and acetaldehyde are the main reaction products. The kinetic curves of ethyl alcohol consumption and the enrich- ment of the reaction product during gaseous phase oxidation (2000C 20 atm) at ethyl alcohol concentrations (if 2.6 % 10-3 and 0.54 )00 %ole/cia'3" are represented in Fig. 4. Fig- 5 shows the corresponding curve@ for temperatures of 200, 230- 250, and 2600C and 20 eta at alcohol concentra.- tions of 2.6 .10-3 mole/c'a3. The influeace of temperature on the gaseous phase oxidation of ethyl alcohol at 200 and 28000 and 200 &to :,s illustra- ted in Fig- 5.~ The CO and M14contents of the reaction productis increase with temperature. The activation energy for the oxidation of ethyl alcohol in the gaseous phase is 18 kcal/mole. H, go Semenov is mentioned. There are 5 figures, 1 table, and 21 references; T Sovieto-8 British, Card 2/3 86359 Oxidation of Ethyl Aloohol in the LiquL4- and" S/195/60/001/004/004/01") the Gaseoun 11haoe Under Comparable Conditions S017/B055 3 USt 1 Italian, I Indian, and I Swiss. ASSOCIATION: Institut khlmicheakoy fizlki AN SSSR (institute Of Chemical Physics of the AS USSR) SUBMITTED; June 10, 1960 Card 3/3 BLIUKBM, N.A.;, ZAIKOT. G.Te. K&y2;JS. S.K.; INAMILI , 9.14. Differences in the Oxidation meclanismB Of OthYl &lcOh0I in the liquid and gaseous phases. Dokl.AIF SSSR 133 noel; 144-147 J1 160. Wu 13:7) 1. Institut kbimicheekoy fiziki AWemil muk 33SR. 2. "Ohlen- korrespondent AN SSSR (for Imnuell). (Zthyl alcohol) (Oxidation) 81726 8/020J60/133/01/40/070 B004/BOO7 S7 oozoo AUTHORSt Blyumberj[q E., A,, Zaikov, 0. Yevs Mayzusp Z* K*# Emanuel#$- N* M.0 Corrsi~;ch-dT-ng--Yemb*r of the AS USSR TITLEs The Differenoes in the Oxidation Mechanism of I!thyl Alooho~l In the Liquid and in the Gaseous Phase PERIODICAL: Doklady Akademii nauk 83SR9 19609 Vol, 133, No. 1. pp.-144 - 147 In the preceding papers (Refs. 1, 2) some of the authors found that the oxidation of n-butanelin the liquid state is more adva:atageous than in the gaseous state. In the liquid statef the reaction develops at lowe-- temperature and at a high rate, it is ikore selective and ouch products of an intensive oxidation as are characteristic of the reaction in the gaseous phase lack-nearly entirely. N. N. Semenov (Ref. 3) explained this differ- ence by a change in the ratio of-two competitive reaction3s ROj,--* R106 + R"OH (1) anii RO; + RH --4 R02H + R' (2). Low pressure and high temperature are-intended to promote the course of reaction M# high pressure and low temperature are expected to promote that of reaction (2). Card 1/3 LK 28 The Differencesin the Oxidation Mechanism of Ethyl SNNY060/1 33/01/40/070 Alcohol in the Liquid and In the Gaseous ?has* B004 B007 B -For-the-purpose-of ohocklng this a3sumptionp the gutho.re investigated .the oxidation of ethanol in the liquid phase (200 op 50 atm) and in the same autoclave also the oxidation in the gaseous phase at reduced pres- sure (20 ata). The results of both reactions are compared in Fig, I# The following-charaoteristic features for these two reactions were observed. 1) Liquid phases No induction period, high acetic acid- and elthyl acetate yield, low yield of CO, small quantities of acetic aldohyde, uhich appears only-as-an-intermediate product.-2) Gaseous-phases-Long inducition period (10 h), slow course of reaction, little acetic acid and ethyl. acetate, much CO, and acetic aldehyde as the main product. Formic acit and peroxide in both cases form in only small quantities, because they are not stable under the experimental conditions selected. The authors discutis these results on the basis of reaction equations. As the concentration of alco- hol under the experimental-conditions in transition from the Uquid to the gaseous phase is reduced only to 1/5, this alone cannot lie the cause of such a difference In the course of the reaction. By calcul.sting the ratio k2/k. I of the rate constants of the reactions (1) and (2), they find that k 2/k,, in transition from the liquid. to the gaseous phagie, does not Card 2/3 the Oxidation Mechanism 81798 The Difforewoo in of 8102QV6011 3!1,10 1 /40/OTCI Ethyl Alcohol in the Liquid and in-the Gaseous B004/ OOT Phase change by the five-fold.bat.a thousand-told. The main factor of the difference in the course of the reaction is therefore not the greater density of the liquid phase, but a specific behavior of the liquid phaseq which may be caused either by intermolecular hydrogen bonds or by the reaction of Ions laoking in the gaseous phase. There are 1 figurio and 4 Soviet.references. A330CIATIONt Inatitut khimioheskoy fiziki Akademii nauk SSSR (Institute of.Chomical Physics of the AoadeaZ of Sciences, IiMR)___ SUBMITTEDi March 29, 1960 Ca.rd 3/3 5.56oo 77758 SOV/'1'5-15-1-2'-'V~29 AUTHORi Zalkov, G. YU-. TITLEs Separation of Lower Aliphatic Alcohols ty Paper Chromatography and Tielr Quantitative Deteminatlon PERIODICALI Zhurnal anallticheolcoy khImil, 1960, Vol 15, Nr 1, pp io4-iog (USSR) ABSTRACTs The ol' methyl, ethyl, propyl, and butyl alcoholo werc detcmilned. To the mIxture o:-' alcohol,13 were added 0.5 ml. of pyrIdim-, arid a 3ati.u-~,ted benzene :.,Olution of ~~,5-dinitroben-zoyl The mixture was heated at 50-COO for 10-15 nlnuteL. Absolute methyl alco-..ol waj used ao the otatlonary phase and heyane, hej~tane, or rionane, az; the mobile phase. Ascending chromatography waj uoed In the majority of cajea. Tne solutlon, containIng esters of 3,5-dinitrobenzole acid, was depooitcd on the Otrip or acetylated paper (120 X 130 Im) 20 11u1, from the Card 1/4 Separation of Lower Allpliatic Alcohols by 7775~ Paper Chrcmatography and The~ir Quantitative SOV/7-5-15-1-201/29 Determination edge of the paper. Tcie~ paper was placed In achroma_ tography chamber after dryinrT. The metil'-d of the separation is descrillmed by D. F. (Nature, 16(j~ 7 Ob Yanov-;ki wap, u.-,ed a-s a developer. The ro~-Iulto of U10 tjUallt' I - d C~ I U r-111i L I'! L 10 r1 011 -10 13 V U are shoaii IiL 111,able 1. T;ie quarititativL? dt, i~,t Ion :).'L alcohols v1_-1,,-_; baoed on t1he ab.: o 1~ ot icnr, D-,;, 1_1 igh b-, comoounds fovimed after wr_~re spra,,,;,,~d Yrtnov,kj. reagerit. Thie, up-,Ical ("(,r,-,:Lty of alco1iol der' va-111'iv~.s, Itz directly' p,.,opDrtlorial !-,c! the c~oz~centrar -on. The ex-ror of the me- I _iod is Trie rjuant-Itat-iie det(,._rq;Ir-iatIon of alcolhols is pos"11ble in the presenc7~ of and hydroi,.a,bon oxI.dation product The 5 1'1jures; 3 and 2`1 Us . j referencen, T -"Dviet) 7 U-K,, (.1 U.S., 2 Japuiese, I Aus trA an. Tht- .1) rt~cent U.3. 1). , Hollr.,J, hl',L. W., Al,"t ,Iy G C -d 2/1i )52); Rt-1 ,e, 11. G ,, ~1,, J. G., a:r 2 1 1 C 1). J . , If Separation of Lower Aliphatic Alcohols by- 77758 Paper Chromatography and Their QUa-rititat.1ve SOV/15-15-1-20-29 Determination Table 1. (a-) The value of' R. for 3,5-din1,'1,-r1bePz--,ates of' alcohols on dIfferent oamfle;) of' acetylated paper; ~b) Type of paper; (c) Movin,,~ phase; (ct) Methyl alcoholl e) Ethyl alcohol; (fj Propyl alcohol .9 ; I ) n-Butyl alcohol; (h) Hexane; (i) Heptane; (J) blonane. Q.) tk) fit /j 4 C (b o,.-m o,m () 68 (),,77 If 0, 14 0,16 0,41 0,14 0,36 0,50 0:63 1) 0 iii 11 11; 0, 19 11,33 0,44, 0,,,2 0,1~1 (),10 0,71 11 11 (k] 0,26 0,31, 0,49 0,(2 0, 7 2. 11 2 -1:1 o"O v (1,33 11. 51 0, 7 2 0,E4 Card 3/4 Separatit-.'n of 7 7 T! 7)8~ D47 P G'I ~ N.Iji. L LV.1 lp! iY- aril i--T-rj e ~17 f-It _.,i t:L v, 0 i,f71-~ i - j Lj De tevinination Analyt . Che,,n., (1951); White, J. W., Drydea, E. C., Analyll. 20, 85,2 (10;13); Henze, P. E., Analyt. Chem., 27, 134c-) (1955); Y. W., Phill'iPs, Y. 1'.., AnIlYt. Chem, 2(M, '.`53 lip%). ASSOC!nTION:. Irl3t.1tute OC Of the, Ac.,tUdcilly of, fizilk! AN SUBMITTEDi November 20, 1(-1,58 Card 4/4 BLYUMBMG,, L.A.; ZAIKQ_~e.4--El4AVTJEL' ~ N.M. -GaB- and Uquid pbase oxidation of n-butane. lleftekhimiia I no.2:235-21i b-h,--kp 761. NlPd, 15:2) 1, Inntitut khimichenkoy fl2ikl. AN SSSR. (mane) (Oxidation) BLYUIVERG, E.A.; ZUKOVt Q.Ye.; EMANUEL' pN.M. Oxidation of n-butam In the poeous and liquid phasen, Pv4, All SWR 139 no.109-101 J1 161. WFA 14:7) 1. Institut khimicheskoy fiziki jW SSSR.,-2. Chlen-korrespdndent- AN SM (for (Butane) (Oxidation). UIKOVP G.Ye*j HAYZUSO Z.K. Wdation of methyl ethyl ketone in the liquid and gas phases. KinA kat. 3,no.6t&1+6-854 N-D 162. ~ (KMA 15112) 1. Institut khimichaskoy Miki All SSSR. (Butanone) Mcidation) ZAIKOV,, G.Te,; MAYZUS,, Z.X, Reasons for the difference in t1w mechanism of oxidation of organic substances In gas and liquid phases. Izv.All &SM.Otd. khim.nau no.7:U75-11% JI 1.62. (MIRA 15:~) 1. Institut khimicheskoy fiziki AN SSSR. (Organic compounds) (oxidation) S/062j62/000/001'/002/01) BM/Bleo AUTHORSs Zaikov, G. Ye-9 and Itaysuag Z. K. TITLEt Reasons for the different mechanism of oxidation of organic substances in gas or liquid phases PERIODICALs Akademiya nauk SSSR. Isvestfyo. Otdoleniye khimichookikh nauk, no. 7s 1962# 1175 - 1104 TEXT: M ethods described in previous papers (Be A. BlIumberg, 0. Ye. Zalkov, and N. M. Emanuel', Dokl. AN SSSR, 139, 99 (196i)1 Neftekhinlya 1, 235 (1961); E. A. Blyumberg G. Ye. Za*o% Z. K. Vhyzus9 and N. M. Emanuel', Dokl. AN SSSR 133P 144 6960); Kinetika i katalis 1, -510 (190); 0. Ye. Zsikov and Z. K. Maysus, Kinetika i katalis (1962)1 Be A. Blyumberg, Z. K. Mayzus, and N. U. Emanuel'# ob. "Okieleniye uglevodorodov z zhidkoy favell ("Oxidation of hydrocarbons in the liquid phaso")# Izd. AN SSSR, Mof 1959,.P- 125; 0- Ye- Zaikovo Zh. analit, khiaii 159 104 (1960); 15~, 639 (1960)1 17t 117 S1962))-vare used to stu4y the oxidation of ethyl alcohol and metbyl-athyrl ketone with different amouats of benzene. Experimentis with ethyl alcohols 20000p !j0 stool alcohol s benzene ratio Card 1/3 $1062J621000100-VO021013 ,Reasons for the different mechanism**# B117/B180 8 : 1, 2 1 1# 1 1 1_j I-s 2, and 1 t 3. :Sxperiments with methyl-ethyl ketone: 1450Ct 50 atm., ketone t benzene ratio -, I i It I 1 2,, 1 1 3. In both cases, an increase in benzene, which teduces the dielectz,J.c constant of the medium, was found to alter the comp3sition of reaction products. With ethyl alcohol, the amount of products obtained from the b,'.zolecular reaction of peroxide radicals was 20% at I 1 3, and 80% inpuro alcohol~. With methyl-ethyl ketone, (I 1 3) the reaction products had tho same composition as with oxidation in the gas phase. Differences in the oxide.- tion mechanisms of polar organic compounds in gas and liquid phases are due to the rate of the reaction between the peroxide radical and the oxidizing substance (bimolecular reaction), the dieleatric cowitant of the medium, and the formation of intermoleoular hydrogen bonde.. The bi-- molecular reaction between RO; and the.test materialt is between two dipoles and slows down as polarity deoroasles. Good agreement between experimental and calculated dipole moments confirms the structure assumed. for the activated complexes in the.case of methyl-ethyl ketonell,but not for ethyl alcohol. This shows that the re4action rate of ROi and ethyl alcohol is rot only dependent on the-polarity of the sodium b0; also on Card 2/3 179 r 3/062/62/000/001/002/QI3 Reasons for the different mechanism... B117/BI80 the'formation of intermolecular-hydrogen bonda. _It -to not the Individual molecules (RH-and RO;) which-rea-otg but aggregates consisting of five or more particles linked by hydrogen bonds, Thors, are 5 figures awl' 3 tables. ksSOCIATION& Institut khimiche.skoy fisiki-Akit6vaii -nauk 66SR--(IfIeltitute f o Chemio 1 Phys ice of the koadomy of Sciences USSVI SUBMITTEDt January 30# 1962 .Card 3/3 ZAIKOVO G.Te.; MATZUSq Z.K. ........... Polarity of-the medium as effecting the activation energy of the chain continuation reaction in the oxidation of 9thjI alcohol and wthyl ethyl katonr,. Dokl. AN SSSI 150 no,lt-116-119 Ky 10. KERA 16:6) IL. Inatitut khimichoskoy fiaiki AN SSSR. Predativlano nkadwdkom H.N.Seaenovym. _(Ethyl alcohol) (Butanone) (Oxiiaticn) (Activation energy) UIKOVJ Q.Ye. Effect of solvent on the liquid rli!lsa oxidation of etbyl al- cohol. and methyl ethyl ketone. lleftekhimiia 3 no.31381-389 Hy-Je f 63 044,4j, - (MILI 16t9) 1, Institut khImicheakoy fiziki .0.1 SSSR. (Sthyl alcoholl (Ketono) (W(lation) ZAIKOV, 0. Yo.; HAMS" Z#K.61 DWIM10j, N&14* of chains In tba -I lquid-phase oxidation of methyl othyl ketone and ethyl alcohol, Noftekht-W,.& 4 no.1991--91,16/+ (,M'IRA 17 t6) 1. Thatitut khimichookoy f isiki. AN SM. 120RUEL lril.32.ay Markovich" ERTRAV, Tovgenly Tlwfeyevich; XOVS, ZjrnOda r;-wAp,1j--vrw. Frlnlr4all uchastie; GAGARINA, A.13..~, GOLIDEERG. V.14.; ZAIKC,'Vg G.Ye.; DORIKOV, YuiD.; OBUKHOVA, 'L~K.; TSEPALOV, P. J-- SHLYAPRITOKV, V.Ya.2 SKIBIDA, I.F., reud. 1 . I -[OxidaTdon e-ha In renc t low,4 in the liquid 1,11im)d T.34-!pnyti ojoflilo~l!;i -,,jv'1qvodarodov v zhldkol faze. 1-11:)Avii, Nau~rk: 1965, 311, p. (141RA 18:9) 01075:160101 -1/005/025/0,26/kAK ~002/'BO56 AUTHOR: Zaikov, G, Ye. TITLE. The Separation of the Low Aliphatic Ald and Ketones b;r Means of the Method of Paper Chromato6-raphZ~, and rheir quantitative Determination 17 PERIODICAL: Zhurnal analiticheskoy khimii, 1960, Vol. 15, No. 5, pp. 639-642 TEXT: It was the purpcse of the present paper to develop a mathcd for the qualitative and quantitative analysis of carbonyl compounds in a mixture of aliphatic aldehydes and ketones (el - C4) formed in ti.e oxidaticn of n-butane. For this-purpo2e the -paper - --hromat Ograpbic separation rif the corresponding 2,4-dinitrophnnylhydrazone3- wa13 E,pplied, The ordinary chromatographic paper of the type (Laningradskaya bystraya) must, for this plir2ose, first be made hydrophobic by acetylation with acetic acid anhydride. T~,~ Rf-values are, to a conaidprable extent, dependent on the manner of this pre-ti-catment; Card 1/4 Tbe~ Separation of the Low ~Ii I~atic 3/07 60/Oir-/OO%/0r?5/O26/Yj: P Aldehydes and Ketones by Means of the Method B002YI3056 of Paper Ghromatography, and Their Quantitative Determination however,, the Rf-values are well, reproducible on papers o" one and the samB lo-t.-Good-separation was o -btai-nod with quantities of 101 g/mole; as a mobiIe phase, hexane, heptane or nonan6 wa3 used, the effect beirg approximately the same with all these solvents. Fig. I shows a schematical chromatographic patte:rn at 200C, where (1) denotes formaldqhyde, (2) at~etaldebyde, (3) propionaldeny-3o, (4) butyraldehyde,-W acet(Ine, (6) methyl ethyl ketone, and (1) a mixture of 'these substances.. 2,4-6~.nitrr- pben-jr1hydrazine always has Hr - 0, Oxidation products such as pej.-oxides, al-,ohnisi acids, ether, and cater do not affect the chromatographic determipation in quantities such as are usually formed in the oridat-Ion of the hydrocarbons. The spots were dyed by means of a 5% scluti)n of KOH in raethanol, out out, and the dinitropheryl hydrazcnes ar-a ex-tra.-ted and t,olorim,itrically determinied. The calibration curve practical!y takes the same course for all sub3tancea muritioned. An tinalysia of an artifinial mixt-are showa that the error in the determination of aldehy4os and a.-etones is less than 6%, and amounts to 10% on)y in the saaa of Card 2/4 '7 -he Low Aliphatic S/075/60/015/00!j/(J25/026/), The Separation.of t . 11 -Aldehydes and Ketones by Mearis of, the 7-Tathod B002/BO56 Of Paper C~hromatography, and Their e,Determination 4 (~tmrititatiq 111e-~thylothyllcetono~ The author thanks N. M. Emantiall and Z.- K. Mwrvaafor diovuosion'a. There are 2 figuroo, 2 ta=os, anJ 18 ioforoncoo: 4 Soviet, 7 13ritich,, 4 US, and 3 Czech. T 1-0.14 -Inst~itut -khimicheakoy- Tiziki AV -S,SSR,_ Mockva tlmtititute of- Chemical Physics AS USSR, Moscow) Sn:,IITT:-;D:, September 22, 1959 Card 4,14 ZAIROTI G Ye -0 - -~- Chromatographic determination of diace-tyl in the produ-.ts of liquiA phase oxidation of n-butane. Zhur.anal.kbim. 17 no.l-,117-120 Ja-F 162. ~(FUA 1512) (Butanedione) (ChromatograplAc analysis) ZAIKOV, G.Ye. Separation of 14wer maiphatic aMehydes and katows brr awax of paper chromtoaa", and their quantitative detersinstion. Zhur. anal kbim. 15 no.51639--642 S-0 160. WIL 13:10i 1* Institute of Chemical Pbysics, AAademy of Softences, UOS.S.R*9 Koscow. (AMehydea) (ratones) (C~romatographiq analysis) L 360-66 T ---72093! ACC NRt AP6027349 SWIM; COMS Bu/--- 5j0:[81E2f1695 AUT11011: Zaikov, R* ORGt now TITIZi Baryon classification and mansee SOUP-Cc, -. Bulgarsks *Ymdeadya na naukite,* Doldady., -,Vo -29. nao 12;, .710% 1095-IW3 TOPIC TAGS: baryon. particle pivoics ABSULACTt The author introduces -a now Urjvn -suporsRat4plat r4CUAA1VU,%Lt1on# . malols use of the FUto-Sternhaimar rass forada, pautulatea a.maft5 ldfrerolvl.~) 2-alationihip, I and establishes several empirical for=aas - 7,ae system lis ~testad:by a-Dquu-ing k~s resiats with knotm mass values 9 Fourteon, nwr baMns 4m -pree,.Utel * IMs, paper was presented by Academician H. Hristov on 21 Saptomber -1,965. r.Wif;. art. tl2az: 10 formulas and 3 Ubleso fo-rig. art. in. En&2TjJ-M3: j&;46~j SUBCODEs 20 SM.UTEs -21Sep65 ~OMIRHFs W~ WIF card t 383h5-66 EuT (m) /T ACC -Nito -APW7984 SOU111=_ COD-r'-. __ BU/O0n/66/Oi9_ 5 Tl j '00 1-7- FOO _9~ AUTHOR: ORG; ln~tuto of Pb Xgics. BM TITIBI C3AIMMOStion MA W3806 of SOURCE: Dulgarska akaderdya na nauldta., Doklady, v. 19, no. 1. 1906, 21-19 TOPIC TAGS: negon, olenentar7 particle, nuclear physics ADSMINCT: The author 1) introduces'a now schema for -the labeling of elementary particles; 2) introduCO3 now proscriptions; :5) pn.%poaea -now malls formulas substituting for the Gall-Man and Olwbo expression; 4).obtoins bettor values.for the equation -paromotars--oX and Al _than.th0ae__' from the Flato-Starnhaimor formula; and 5) astablichoo-1 table 01 itiotopio IPultiplots which exhibit an equality of the 0 and p parities for all 'resonance states while for basic mesons thay have opposite aizns. jhii; :pftP*'o::' was prosontod by Acadordcian H. Hristov on 21 Soptenbor 1~65--' -5rig. art. 1-i Cn~ rbiw: 36, iV~ff SUB CODE: 20 / San DATz: 2isop63 OTH 12F: 002 _J 1,6 V nu t,,iui~ itierfWcaj cluracteristles Raj. ob I rd t anrt Ice. n t an Inen 1e '71 1 (_~ I 57), 10, Y, der The schejrc fcFr 01111i'l-itcl aposed by Salam and PQ!kit, P , 6&5-6901 is extetld"41 t' ;(ILI) 2 (1955), ILI&I TILO. following eatphic al ftj,lLSsIjc)rmula,-~ for ions. ferr, Held rl is a sixcifir, illteger 0 [ for t)ious. 76 for llud(Ons- ~,O for AG etc.) ar"J I", tai"' tile 0, ZALTIM, R. OA sywastrical form of the quantum mechanics of nucleons," . IMTIIA. MM FIZICHESKA$ Sofiia, Bulgaria, Vol. 6,1 Jan./Dec. 1956 (published L957). - - --- - Montbly List of East European Accossions Inder. (VAI)# The-Library-of - -- - - --- -- - Congress$ Volum 8, No. 8x Argust 1959. - Unclassified BUIDARIA/Thooraticel physics - Quentun Theory of Fields B-6 Abe Jour if~of Zhur Fizikaj No 10, 1958, -No 22125 Author s ZaikRyjXAbk&- Inst Irhy~sics Institute, Bulgarian Acede-V. of Sciences, Title iOn the Syrnatrical Forn. of Quantum Mechanics for the Nucleon. Orig Fub tIzv. B01g. A 4d. Viz.-metem. i tokhno I. Sor. fiz., 1957, 16, 3-11 Abstrect ITo doscribo the nucle6n# it is proposed to use e 7-dinentionel spacul which is a combinetion of the Minkoirsky 4-spi!,,,o and the inotopic 3-spece. The wave function is consid-gred to be an 8-componont spinor, of which the first four c,x3pcnents corroopand to c cberged steto of the nucloonp end thD four 1 ast-c orpononts- to tho-noutral-steto-or - tho- nue loon GIn -a c------ cordance with the Sonerel theory of spinors# the matricos of eighth order 11 70 Pro derivodl analogous to the Dirac netrico" The principal equation for tho h I ?o nucloonp whic go o In he particular case Into t.ha Diree equation, is written in theform Card 1 1/1 BULGARIA/Thcorotical khyoios Quantum. Theory of Fields B-6 Abs Jour i -4of Zhur Fiziks, No 10, 1958, No 22125 j=1 whore(,,.j,(x) exp (ieOk ~), eo and a0 are conatents9 on! x and denote the first four in the loot three coordinates. Bi is nado up of pertiel derivativoa with roopoot to tho corresponding coordinntes end of o!.ghth-ordor tartrizis, which are 11noar oombinstions of 1, 11 1 () end /-I j ~, PIC P 1 - It in assuned thet tho cooffiaiontii In those Met c*3 cherw actorize the intarnetionn with rll types of fiolds, Including tho fiolds of difforont nesons, and that in the firat sp- proxi,lAtion they should bu linaar l'unctions of tho ainrao- ponding vector ond pseudo-vector ptitontials rnd of t.1-m-3 dori- vetives of the potantiels with respect to the four coordinates. For the particuler type of the intciraction# an explicit forn of Eq. (1) is given. At the and of the work the amhor de- terninos, with tho aid of tho first four metrices Pj,, in analogy with the Dirac equation, the vector of the mArrant, tbo pseudo-voctor of the spinp and the onorgy-taimentun 71 A BUMARU/Nue-16ar Physics Elementary Par.'iit-Liss C - Abs Jour : Hof Zhur - Fizikap No 5# 1958: No 10142 Author : Zaikov Fashko infit : ROW-Given Title : QMant= Mecbanical Characteristics and ElementAry Par+AcJAS Orig Pub : Dokle Bolgo Ali., 1957.. 10.9 fid-2p 101-103 --Abstract,-: - The - author- considars -the - classiftention of-elamentary paild.- cles in four di- asio"Al isotopic space.. All the heavy cktrig- ed mesons are considered as one pseudoscalar part,"..cLe. 11n neutrkl heavy mesons fom an in&jxin&a4'-# doublet. In tho classification variant proposed It is possible to dispense- Vith introducing the lepton charge. However: it becomes neces- sary to Introduce a hypothetical acalar neutral m-son Vitt. mass close to the mass of the experimentally observed aeix~,ral pion* Tile table is given for the classification. of 6lew_~r,4a:,.*y particlas and the types of their decay. Card 1/1 BULMM/Nuclear Pivoice - Elenotitary Particles. C Abe Jour Ref Zhur Fizika, No 10) 1959) 22005 in the version of the theory considered, etroa(; Interac- tions of the hype are fol'Ind to bo forbid- den; the wave Vinctions of the K tiesons arA ~hcdr anti- particles are comectc-d by -the relations K'td* i~ K-, kO* :~-- -RO. The WO ruesmi cannot decay rapidly into three pions, -- V.S, Barashenkov Card 2/2 BULMRIA/1111clear Mysics Elet:iei itriry Particles. C Abe Jour : Ref Zhur Fitika, No 110 1959, 24446 Author : Zaiko,v R Inst : Physics Institute, Bulgarian AcadcLW of Scioncei Title : Isotopic Bi-Spaco Theory. 11. Orig Nb : D:)kl. BoIG. All, 1958, 11, No 4) 259-262 Abstract : Using the formal-ism previously developed (Referat zhur rizika, 1959, No 10, 22005), the author writes nut, the interaction Lngrangl-nns for various types of particles, charge operators, a,,id baryon nwabers. Card 1/1 21 - . Zaikov, Hashko, starahl-muchen outrudnik. Substance and antisubstance. Rat I flz BuIg 3 no.2:5;3-59 lfr-Ap 162 1. Fizicheaki Institut BAN. ZAIKO rof. d-rj NIKLEV., S., inzh. 911~ Linear programing. Tekbnika Bulg 11 uo.10096-3r 162. f