SCIENTIFIC ABSTRACT ZAKHARIYA, YE.A. - ZAKHARKIN, L.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001963520001-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 15, 2001
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

ZAPADNYUK) V.I.; ZLMIMUYA, Ye.A.
Desensitizing offeato o:! rhode=lne derivatives. Farmi toks.
24 no,ls33-,36 Ja-F 161. -OMA 1435)
1. Kafedra farmakologii (zav. - prof. A.A.Gavrilyuk) i lcafedra
patologicheako-v- fiziologii. --- prof.-I.I.Fedorav) Llvovskogo
gosud&atvennogo modits,'.nakogo l.n3tituta.
(THIAZOLM 101011ANINE) (AIMMY)

7&KHAIITYA# Ye A * WADNM, V.]:, (Llvov)
Spasmolytic effect of ncriocainig. Pat. fizlol. i eksp. terap. 3 no-3:
77 Mq-Je 159. ~(NIRA 12:7)
Ii kafedry patofizio.ogii (zav. - prof. 1.I. Yedorov) i kafedry
farmakologli (zav. - prof. A.A. Gavrilyuk) Llvovskogo moditainakogo
inatituta.
(PROGAIM, eff.
on exper. (jonvulaions (Rus))
(001;VMIONS, e.,.per.
eff. of procaine (Rua))

ZAMIM, Ye. A.
"The Effect of Strong Stix-mlation and Parabiotic Inhibition on the Znerggence
and Courze =1 Tnflannation (Experimentsl Taveatigation)." Cand Med Scl, VvoV
State Medical Inst, Lf-iov, 1953. (RZh2iol, No 4, Oct 54)
Survey of Scientific and Technical. Dissertations Defended at U33R Higher
Educational Tnstitutions (10)
Sol sum. No. 461., 5 Mv 55

ZAKHARIYAO Ye.A.; MOROV, I.I.
DialnUxicating effect of sodi= lactate In poisoning wIth narcotis,
Trach.delo no.4^a7l-75 F 163. (MIRA 1615)
1. Kafedra patologichookoy fiziologli (zav. - prof. I.L Fedorov)
Llvovehogo meditsinskogo inatituta.,
I (NARCOTICS) (BODMI LACTATE)

V' IK"i A ItY A
Rs prs-41,r.- ,c-n of aud' -g;~n!
admi nis"rat! r.-n c;l, Sn! Ml~ C",;
mf"J. 18
1. Yafenra baz -
uglur) I lmfpdra lLarminkc,!,.l-.k7.lkj, ~'nv. ~, prr,j, A,A. ~iv-ullvul,'t
L!vovukcgo MCdttoLn.:-,~cc.7o, P~pr!l 10,

-ZAKHARIYAk Yed..
Yeaiod of inducing ailelogf-n-1r; convulsions. Pat. N24101. i
eksp, tArap. 9 no.3;7R-?9 my-,Te 165, (MMA 18J9)
1. Kafedra patclagic-henkoy 071olcgil (zar.- d(asent V..P.
Bezuglov) Llvovskogo ineditm-nokogo Inatituta.

ZAPADNYUK, Ignatiy Pavlovich, prof. ; ZAPADIM-K, Vitaliy Ignatlyevich,
kand. med. nauk; ZAKHARIYA Yelcal~_LndrDyAwa, d.
? , kar
med. nwak; FEDOFJDV-,-T. prof,, doktor rzed. nauk, red.;
ZAPOLISKAYA, A.A., tel:hn. red.
(Laboratory animals, their breeding, keeping, and use in
experiments] Laboratornye zhivatnye, ikh razvedenie, soder-
zhanie i ispollzovenio v eksperimente; s predisloviem i pod
red. I.I.Fedorova. KI.ev, Cosm3dlzdat USSR, 1962. 349 p.
(MI RA 16:7)
(LABOILATORY ANIMA1,S)

ZAVPJUITIV~ ER.t kviri.med. nauk (Sofiya)
U-1-- 4 ~'17
SC,.-np,4,3. lleit. derm. ven. 37 no.
Trop.tirpent of F . I (RI IRA 17 19 !
0 163.

r rrjct It< h!

ABRASHKV, G.P.; RADEEV,, R.I.; TSENKOV, TS.G.; DIMOV, N.D.;-ZAM I.TS.;
TYJ__. 1. --
PFINCHEV, S.P.; TSONE7, M.D.; SHAVELISKIY, G.A.
Crude oil of the Dolni Dubnik "Ipld. KhIm-i tokh.topl.i zaasel 8
no.11:24-30 N 163. (MIRA 36:12)

ZAKHARIUVO N,; BAKRACHEVI N.; POPOV, 1. (Boleariya)
Acute poisoning b7 explosion gases. Gig. truda i prof. zab.
4 no.12:45-47 D 160, (MIRA 15:3)
1. Dimitrovskaya bclInitsa ctlya shakhterov.
('.4INE GU&S-TOXICOLOGY)
(ELASTIRG-HIMENIC ASFECTS)

GEGUCHADZP,,, H.A.; ZAKHARIYEV, A.I.
IMAking "ka briquete from weaUf caking 'lean Llu)garls-n acti-Is.
f,
Lrudy IGI 204155-158 '63. (MIRA 3.7t8)

ZAMURIYEV, V.I.; GODEV., ll;.G.
lawaorical 5cileme cf a forceast *~y a 6wo-lavel model Of Lhe
atmosphere on the Uisis of the siolution of tho comploto
system of hydrotheriaodynamic equations. Trudy I-'.,.',TS no.6:25-
32 165. (MIRA 18:12-)

MILL I
'NKOV, Kh.R.; KIRIIT, I.; AGOPYAN, K.; ZAKHARIYEVA, Z.
Influence of hemp dus,,, on som- body Amations. Gig. i fan. 26 no.4:
25-32 AD 161. (HIRA 15: 5)
1. 1z kafedr patologicheskoy anatomii,, patologichoskoy fiziologii
i fiziologii 116ditaintikogo inatituta imeni I.F.Pavlova, Plovdiv,
Bolgariya,
(HR.S.-PIE'SIOLOGICAL FFFX--OT)

ZAKHARIY&VA, M. (Zalrbarievas M.K.], d-r; SDLOWMA, K.
Stmmlardization of the tota= - anataxitto Pt. 1. Trudy 44miol
mikrobiol 8:83-439 161 bubl.16Z].
1. Chlen Redaktaionnoy kollegii, *Trud:r Ilaucluio-isaledoyatell-
akogo inatituta opidemiologii i mikrob:lologii" (for Zakharieva).

DAVITASIIVILI, L.Sh., akademik; ZAKIIARIMA-KOVACTIEVA, Kr.
Origin of the "Stone Fore3t" near Varna, Bulgaria. Soob. AN Graz.
SSR 30 no.4:441-446 Ap 163. (.%t1 RA 17: 9)
1. Institut palcobiol:)gii All GruzSSR, Ybillsi. 2. Alrademiya
.nauk Gruzinskoy SSR (for Davitashvili).
0

DAVITASHVTLI, L.Sh., prof.; ZUMRIYEVA-KOVACIIEVA, K.R.
Mystery of a "stane I'c)rest*Ain Bulgaria. Friroda 52 no.9:
90,91 '63. (MIRA 16:11)
1. inatitut paleobialogii AN GruzSSR (for Davitashvili).
2. Sofiyskiy gosudarstvennyy univeremitet, kafedra pale,mtologli
(for Zakhariyeva-Kovacheva).

7A MAR f YIN; -,KO VA ',,*I IfXA
One; :,-ore "Petrifled forest" in the of
Soob. AN Gruz. SSR 36 no.1:1;.13-126 0 'U..
1. Sr)fiyski,,r gosudar3tvpnryy urlw.91tet, Submitted
JUIY 10p .964,

--- - -- -- --ZAKHARIn.VAi-KOVACHEVAj Kr.-- --- -- - --
Seeond wetans forest* of Bul4garia.
114-115, 164,
--- -- ---- ---- - - - - -- --
Prlroda 53 no.10t
(KIRA 17:11)
1. Sofiyakly universitet, Bolgariye.,,

ZAKUR"VICH, I.P.1 BEM*KI71., A. Yuo
Mondor's diaease in general tuximoulosis and oxUlary 121&-a-
donitis. Zdrav. Bel. ~ no.7t85 Jlt63 (KIPA 17t/,)
1. Ir Kostyukovichskoy rayonnay bollnitay (glavnyy vraoli V.K.
Polevtsov)~.

ACC NP, AP6036102 SOURCE CODE: UP,/0256/66/000/011/0067/0070i
AUTHOR: Zakharkin, D. F. (Engineer,, Lt. Col.)
i ORG: none
TITLE: Amplitude velocity curve of a moving target selector
SOURCE: Vestnik protivovozhushnoy Dborony, no. 11, 1966, 67-70
TOPIC TAGS; radar signal, moving.target, radar tracking, computer application
I'ILBSTRACT: Method of differentiation between radar signals reflected by stationary
and moving tar8ets is being discussed under the conditions which occur when the two
coincide. Such a situation arises in the case of "blind velocities," i.e., such
radial velocities of moving targets with respect to the receiving stazions at which
the reflected signals are in constant phase Telationsbips and, therefore, are sup-
pressed by the computer of the moving target selector in the same manner as the sig-
nals reflected by stationary targets. The 1111,rs a-mplitude-velocity curves are useful
in mathematical calculations leading to the isolation of the signals derived from.
MTS. In order to eliminate the "blind velocities" within a sufficiently wide range
of Doppler frequencies a multiple sequential reading of the received signals is en-
p~lbyed simultaneously with the alternating frequency of the sounding radar impulses.
In' his manner the first segment of the amplitude-velocity curve, which corresponds
spectrum of the Doppler frequency of the interference, is sufficiently steep,
,,Cn'r-d 1/2

ACC NRi' AP 6036102
and the operational range of the target's velocities in sufficiently wide to minimize
the effect of "blind velocities." Orig. art. has: 5 foinulas and 4 figures.
SUB CODE: 17,.=/ SUM DATE: none
Card 2/2

-- -- - . I - --I I Moving target SOISC.,tion aLppmmtus_ in reLd" stational xateriaI
from foreign 1-itereture. Vent.pxotivowzd.obor. WOW4-26 F
161, (HIRA 14:2)
(Raclar)
~4

TUMINA, Ifaderhd& Vasil 'yma. n&whuyy Gotrudulk; ZAKHARKIN. ING.,
re4,t rAYDAWYA, N.D,, tekhnorsd,
[Golden-coral rnkmniza solotala. Khabarovsk; Khabarors'ims,
knithnoe ltd-vat 2959* 2? P. NmA 14w)
1, Btrobidxhanskaya. eal'skokhotirsYstvannaya opytmaya stamtstra
(for Teremina).
(Gorn (wts))

Is ZAKHARUN, 1.
2. us.,-)a (6oo)
4. Concrete Construction
7. Mechanized preparation of concrete, Eng. MAtit'.ugl. 2 no. 3, 1953.
9. Monthl List of Russian Accessions, Library of Congress, APRIL 1953, Uncl.

mom
ZAKHLRMO rdtp rop
U3.5jVChemistry - Pharmaceuticals Doc 50
Medicine, Ambic Dysentery
"New Synthesis of the Alkaloid Ewtine,,O R. P. Yorvati(MwIeva., R. 3, Uvahlta,, L# I.,
Zakharkin, M, S, Bqnova, 11. A. Precbrazhenskiy
"Dok Ak Nauk SSRI* Vol IM., no 4, PP 53-9-542
In addn to being opecific remedy against amoebic dysonter7, ematine is effective against
Trematodes and some bacteria which prcduce serious dLsnasen in man and animals. Most pr6bable
fonnula for emetine, advanced by authors, corresponds to R. Robinsoniz fo:,-Mula based on
the.,ory of p!Wsiological conditions (311'ature," Vol CLIII, No 524, 15.5, 1943.) Formula has
now been confirmted by authors, who ex-ried out complete synthesis of racenic emetine in
several different wWs. Two reaction schemes Ed-ustrate authors' complete s~mthesis.
Pa. 173T23

"Synthetic Investigations in the Fiel-d of the
Alkaloid Emetine." Thesis for degree of Cand.
Chemical Sci. Sub 3 Apr 50, Moscow Inst of Fine
Chemical Technolegy imeni (M.V.) Lomononov
Summary 71, 4 Sep 52, Dis?ertationo Presented
for Degrees in Science and Engineering in 14o,,3cow
in 1950. From Ytch9rMaya Mookya, Jon-Dee 1950

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YvIiIIj~'.4 th! Matti un md h t to4'2'a-5(i* with,
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-4*, x 2, 422. G. 11. x.

i., i s t
VA
ts Uinotine COMPOLmds. V. S:rnthesis of the natLrw
tme X-t~rul~.
tiae 2ii- M. A. Wv-., MFU777, 11
A4.1119113, _ JU
-cl DIM- U044"(11. J, 1,14. 1
S-, CA,
it. 1.11 jN1

ZAKHAFXnT, L.I.; PIMCBRAZHENSKIY, N.A.
IsoqtLinoline compound series. VI. STatmais ofO-[I-(broaomethyl)
propyll glutarlc acid andll-[l-hydro:qustbyl)propyllglutaric wid
lactons. Zhur. Obahchey Kh1m. 22, 11390-5 052. (KLRA 5:11)
(CA 47 no.15:7507 153)
1. N.V. Lomonosov Fine Cha-z. Teoh.In,3t., Hoscow.

zAKKU=,, L. 1. _
"Iso,quinoline compounds. Patt S. Condensation of a' -substittttod B -propyWutaric acids
with homoverstr7Ludmu. Zakhmt*IjIg L ~l and Prectrashenskii,, N. A* (p. 153)
80; Jgmal 21 giatml gamistry (Zhumal Obshchei Khtdl)e 1953,. Volumot 23, No. 1.

Ttl iil~, -)R
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A ithuro Zak ftsr~ lh-ly ~j
:hlbulittod August 23, 1953

T:--
psp
Periodical D-ki. ~"I ESSER 97 Ed. 91- 9~1- 1954
nn nf' t-ptrqc-h' orc- I kon-or0oanng
Tt-
,04--Itution Aced. of Sc. U&SR, irst-it, ~t- '-f Cov-rcftunds
Sub,-.Atteet I!a-y 12

Carld 1/1 Pub. 22 30/t*-'
LvIAa=- i ninm- Friofil ir%A Q KI Ame: Zj lehar'win T-, T
acld5
?eriodical 9 Dak - OF 3-5311? 99/5, 70!1-7R,33, Dec 11, i9'.,.
Abstraot I Anc-ther o f a'-Iyl rcgrou,),-ng in a dichloropropene sygte,- is presented.
5 i aJI .1 C, e L C 3
Ell I
OT S-~-i
OR

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_OOR and Cllo
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-r
EXlbv, at td 31,
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'R VW 5-24".4

aty J 2/2 ?-ub. -k - 6.,Z7

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Py
Ma

uSsWorganic chemistry Synthetic C' aLitic C*,61ry,, E-2
rs
Abet Journalt Refe:.Iat Zhur -KbimiA, No 1, 1957, 800
Author: Keemeyanov, A. N., Freydlina, R. Kh.p and Zakharkin, L. 1.
Institutions None
Titles The Investigatim of the &-%actiona of Po1,Yc1i1orohydroc&:rtj"8 and Re-
lated Ccopounds
Original
PeriodIcall Uspekhi khimii, 1956, Vol 25.. No 6., 665-7o4
Abstract: A detailed survey with a biblicgrdphy of 93 titleo-
Card 1/1

USSR/Orgp-nic Chemistry Theoretical and General questions E-1
on Organic Chez:istry
Abs Jour Referat Zhur - Kh1miya, No 2, 1957, 4228
Author Nesmeyanov, A.3., Freydlina, R.Kh., Zakharkin., L*I#.#
Belynvskiy, A.B.
TitD3 Action of Nucleophilic SubstEnces on Ccmpcunda of the
Structure CCI - CH = CRRI.
Orig Pub : Zh. obshchey khimii, 1956, 26, no 4j 1070-1082
Abstract : By dehydrobrortination of 1,1,1-trichloro-3-bromobutane
(1), 1,1,1-trlchloro-3-bi.-Omo-3-phunylpropane (11), 1)1,
1-trichloro-3-bromo-3-mel*.b;ylbutane (III) and 1,1,,l..tri-
cUoro-3-bromo-4, 4-dimp",hylbutane (IV) (synthesized by
addition of CBrCl to tivi cnrreepondin" olefins) were
prepared, respecthely: 1,1,1-trichloroobutene-2 IM,
1,1,1-trichloro-3-phanyl,,Drop(~ne-2 (VI), 1,1,1-trtchloro-
3-methylbutene-2 (VII) and l,1,l-trich1oro_4,4-diziethyl-
------pent ene-2_ _(VIII_)-. -Structure of VI was confirmed by
Card 1/14 -3

USSR/Ore.anic Ct.emistry - Theoretical and General Zuestions E-1
cn Crganic Chenictry
Abs Jour Leferat Zhur - Khimiya, No 2, 1957j 4228
ithich is attriDuted to spatial hinLrances. In an alcoho-
."Ac medium (C2ffr,)2M reactG with V and VI to form nixtu-
re* of alltoxy- find amino., derivativea, whilp with Vil and
'7111 only alkoxy-derivativcs are rormed. With
alone, without allcohol, V and VI form a=no-derivt,
tives, while VII does not react even at 1100. On action
:)f NH3and piperid-ine (Xj), in an alcoholic modiiua, VII
forms a small amount of tuaino-derivatives. The (siane
course of the reaction bas been ascertained on interac-
tion of V, VI and Vil with Na2S in alcoholic medium: V
and VI form mixtures of 0- and S-derivatives, while V11
yields only 0-derivatives. The authors draw the conclu-
sion that the reactivity of the investigated conijounda
depends to a large extent upon the nature of the! substi-
tuents at the center of action of the NP. With ~.ecrease
of the electrophilic nature (EP) Of the compound under
Card 3/14 5 -

- - - - - - - - - - - - - - - - - - -- - - - -
USSR/Organic Che;.iistry Theoretical and General Questions E-1
on Organic Chemistry
Abe Jour Rwl.'crat Zhur - Khimiya) No 2~ 1957, 4228
st,ady (V > VI > VIII > VII) the rate of alkylation
at the O-atom increases and that dt the N- or the .13,-atom
deoreasee. Fron previous ,rork, (see above-cited reVe_
re,.-ice), it follows that EF of 1,1,1-trichloropropa.,v- in
gr,!ater than that of V. A3 amlogy is traced betvz!;an the
reactions under study and -the alkylation of metal dariva-
ti-!es of tautom(,~ric system3, taking place with transfer
of the reaction center. In the former case,there L3 alky-
la-;ed a mixture of two substances comprising different
ce-iters of EP a-Aack, and in the latter case both tqese
ceaters are bound into a () system of -n' -conjugation
(k~Ao-enolic, lactim-lactamic). It is shown that V, VI
an:1 VII react vLth C6ff6 in the presence of ALC13) to
fo-.*m, respectiv,;Uy, 1,1-dichloro-3-phenylbutene-l (XII),
1,.L-dichloro-3,3-diphenylpropene-1 (XIII) and 1,1-dichlo-
ro-3-methYl-3-plaenylbutene-I (XIV). It was found that
Card 4/14 - 6

USSR/Organic Chcvdstry - Theoretical and General Questiona E-1
oit Orguaic Cherlistry
Abe Jour Ro-ferat Zhur Khimiya, No 2,, 1957) 4228
X Y i. C1 ~'(CH3)-CH2+X,, +YH
H c(CH3).-,.,H C-Cl 1 11 (2)
H 'Cl CH z CC12
t'ae NP -reagent an Ca , 'a' d' -conjugated- systen (see
eche=e 2). High yield of XV from X and its low yield from
VII are indicabive of the fact that VII reacts with NF-
reagents in ac,.ordance with scheme (1) vithout any isomQ~,
xUation. Noted is thQ jimilarity in behavior of the
C:13C-group of VI and of C6H5CM (hydiolysis by 901
flycoll, disproportionation with forzation of ClCHOCCCl
(in heating with CICH2COOH'). There is proposed a n
iiaheme (Cf ) Kharacch) J, Amer. Chem# Socs) 1947) O"Is
U00, 1105~j of alLralfne hydrolysis of the producto of
addition of CTrC13 to olc:Cins:
Card 6/14

USSR/Organic Ch~mistry - Theoretical and General Questions E-_
aa Crganic Memistry
Abs Jour Referat Zhur - Khimiya, No 2, 1957, 4228
(4%, BP 91-920/1 r,,m, n2LD 1-5710 ' d2C1 1 323 '7. On exhy-
drobromination vith alkali in CIX Ch VTreacts with al-
cohol, 153 g III in 50 ml alcohcioi treated with 45 1~ KOH
In 180 g alcohol. (00) to get XV, yield 3.5 9, BP 30-31o/8
z;r, n2OD 1,5027~ and '111, yiela 6(%5~%j BP 45-460/6
22, d'(' - 1 W. 7rom 63 g XV1 and 4" g M"Ll in
L26D 1.48 k, 1.21 1
1.50 ml CF CH (15-2CP I day) are obtained XV., yiell
3 ' - /I A.1 91
E~nd VII, yield 'jl%, DP 51-520/10 =" n20D 1.4628, 0
:..1418. In the same manner f--cm 50 9 Mrl, 35 g KOH and
..Go Ml C2H CH exe obtained 12 g XV and XVIII, yield 14 g,
13P 72-73 ~U --, n2CD 1.V16, d4O 1.uol. 17 g XVII and
,211 ONa (from 6 j; No.) in e0 ml absolute alcohol bciled 10
M~1, added 8 g KGH in 10 r-1 water and boiled 6 tcurs,
;
.:0 get (CH3)2-C-.CHC0R yicacj 4.2 g, RP 69-'10C (from water).
Into 39.5 9 XVII HC1 Laa'i is pasued for 2-5 hourvi stra-
tified liquid is poured i;ito HU, bottom layer is z)ejara-
ted,
Card 8/14 - 10 -

USSR/Organic Chemistry - Theoretical and General Questions E-1
oil Organic Chemistry
Abs Jour Referat Zhur - 11imiya) No 2, 1957, 4228
and therefrom ia obtained X, yield 30.1 9, BP 58-58,10
/15 rn,'n2GD, 1,4847, dfO 1.2527. X is also obtained by
plissing HCI (gas) ( -51t0 -70, 3 hours) into 14 g, XV in
p:renence of 1 9 ZnC12, yield 52%, 13P 640/25 an. From
26 g 4,4-d'nethylbutene-11 60 g CBrCl3 and 1 g of &ini-
tr-ile of azo-bis-isobutyric acid (autoclave, 100-1(;50,
6 hours) is obtained IV) rield 38 9, BP 9CP/5 m, rj20D
1.5030, d4o 1.4-792. Fror~ 0.11 role IV and 0,33 rx):.e
02H )2"H 1000, 18 hours) is synthesized Vill,
Yte.La 7C#jo, BF 64-650/10 mn, n4OD 1.4725, d4O 1.1403.
Ozonation of VXII yields -the cbloral. From 35,6 g V
and C1130Na (from 4.98 g Hi in 50 Ml CH30H) io obtsWorl
1000 -3-metl x-buteie I
2.5 hours) 1,1-dichloro 10T fL
~XX), yield 59,tj BP 640/57 m, n20D 1.4580, 1.: -1;2.
15.9 g V and 113-3 9 (C2H~)OH (boiled 8 hours furin
ill-dichloro-3-diethyldwdno-butene-1 (xxl), yield 5C~'
Card 9/14

USSR/Organic Chemistry - Theoretical and General Questions E-1
on Organic Chemistry
Abs Jotir Peforat Zhur - 10.,imiyal No 2, 1957, 4228
BP 79-5-8c0/14 Taii, n20D 1.4690, d~O- 1,0470; hydrochloride)
~T 1157,50- Same amunts of V and (C2H ) NH heated in 4o
ml Cif3OH, which 3ives 3c~ XXI and Xx, 5 2 Bp 4o-410/15 mm.
From 32 9 V, 32.8 g CH 3CMIa and 0-5 g Ki, in 50 9
CH COOH ( - 100), 18 Murs) is obtained I 1-dichlora-3-
.2201)
acatoxybutene-1 (XXII), yield 59%, BP 83-80/26 m, -
1-4590, d~O 1.2234. Structure of XXII Is establisbed
by converting it by the act-icn of alcohol into XIX, BF
63'/6 rri (in tho papor, 1,1,-dichloro-3-hydroxybutor,,Q-2).
ffeat'.ng of 30 g V find V9 g Na2S.91120 in 80 ml alcctx,l und
10 m:. water ( - 1000, 6 hours) gives bia-(l,1-dichj.oro-
3~mel;hylpropen~-1-yl)-sulfl.de, yield 4(Yp, BP lo40/,,i rm ,
n OD 1-5345, d 4 0'1-3156, arid 1,1-dichlorG-3-ethoxyl)ttt(!ne-1.
From 24.4 z V and, oodlum ywilonts enter- (from 4.6 1, un
and ",2 g mnIonic eater In 80 ml abijoluto alcohol) lit; ob-
tain'ed (boiling 3 hours) the ethyl aster of 5,5-dicbloro-
Card 10/14 - 12 -

USSR/Organic Chemictry - Theoretical and General Questions E-1
on Organio. Chemistry
Abs Jour Refe:nt Zhur - Khimiytt, Ik, 21 1957, 4228
a acid (XXII.T), 1rield
-3-ri(,,thyl-2-carbethoxvp,(,)ni;ene-4-ii
20
70~p, BP lor/l rn, ne 1,4605, d4 1-1829- :-)0"(
XXIE: are hydrolyzed (by boiling with HC1 and all COCII)
and decarboxylnted to 5,5--clichlor o '*A,!-'4-ic
-3-methylpente
acid, yield 85~7%, BP rm, n2QD 1.48oo, dFO
V
1,2739~ By interaction of 10 g V, 1.2 g A1013 anJ 25
MI. C06 (stirrad 30 millutes) ia obtained X~~) yieli 70,
BP 73-74o/ 1.5 irm, n20D 1-5423, dj~ 1-1702.
On a,:tion of C12 XII forms 1,1 1,2-teti-achloro-3-r!'onyl.-
butmae, BP 107-1060111~5 nin, n26~ 1.5568, d&O 1-3634.
From 36 g IX and 36.5 g (C2H-5)2M' lC'C'o' 16 hc-LL-s)
are Dbtained MI, yield 33,'6 9, Bp 64-6r/21 m,, E;nd
20.6 g IX. Interaction of 15 g VI and 5.5 g KNI 4n 25
ml absolute C'XrVj (15-200, 16 hours) gives 1,1-(Uchloro-
open .-
3-ethox -3-ph(in~lpr e 1 (XXIV)., yield 87%, BP 510-910/
I mm, n~OD 1.:5308, d~O 1.16M Y-.~-om 11 g VI and 12 g
Card 11/114

USSR/Organic Chemistry - Theoretical and General Questions E-1
on Organic Chemistry
Abs Jour Referat Zhur - Khimiya, No 2, 1957, 4228
(CP-H5)2NH in 25 zil absolut.:C2H5C-H (heating 8 hours)
are obtained XXIV, ---- yield 4.5 gy and
l~l-dict.loro-3-d-Lethylar4ino-3-.phenylpropeno-1, yiell
4.8 g, TIP 98-990/1 irn, n20p 1-5335, d&O 1,1116; hydro.
chloride MP 149--'1500 (from alcohol -petrolown cither).
From 11 9 V1, 3 9 UCl an~. 20 ml C6H6 synthesizell-10
xxii, Y'.eld '16%~ Dr 10-1,11jo/l raii, n -0
D 1-5951,
1.2180. By intE-raction. of 17 g V11 and 8#5 g KW irl
V11 CH 011 (15--20c', 16 hours) are obtained a srall ancunt
of Wand XVII, yield 8210, BP 47-480/7 m. Interaction
of 1-0 g VII ard 16 r, (C2H 5)2 NH in 30 ml CHCH (heatod
10 hOU-13) gives XV and XV11) yield ' M- :BP
57-58P/'-14 nm. Yrom 10 g M and 5 g NH in 40 ml absolu-
te alcc;aol (in =-Oule, 90-950, 4 hoursi is obtaineJ
XVIII, with a yield of 6 a, and 1,1-dichloro-3-amino-3-
methylbutene-11 yield o.9 g, Bp 64-650/12 =, n2Cr
Card 12/14 - 114

USSR/Orgunic Chemistry .. Theoretical and General Zuestions E-1
on Crganie Cheniotry
Abs Jour Referat Zhur - Khimiya, No 21 1957, 4228
petroleum ether). From 10 g VII and 4o mi C211 OR ('15-20P)
for noveral day.,) IE; obtained XVIII. IntaractKII (4 10
VIII an( -9
I CH Ofla (from 1,L5 g Na in 50 ml CH30R) 14"
on boiling f~r 30 hours) :~.,l-dichloro-3-mothoxy-4.,~-di-
t
I '0L,
mcthylpen~18ne-l (XXV), yield 50%, Bp 6o-610 9 rrn, 1&;
1.4620, d!; 1-0755. Fron '( g VIII and 5 r, ~C 21 rr-.
in 15 g M OR ( - 1000, lt) hourz) is obtainc.
XMI, )ielP 2.2 g.
card 14/14 - 16

USMYANOV, A.#., &)Wemik; UKHARK W, L.I.; YBXMINA, R*Kh,
The condensati.on of acid. J,j -dichlorocrotonic
uld and I -bromoc rot onto acid with benzene In the presence of alumi-
num chloride. DAIJA MM III no.1:114-116 N-D 156. MRA 10:2)
1, Institut eLexantoorganichaskikh soyedinenty Akademit, nauk SM.
(Crotonia aA:id: (Benzene)

WOW
"Ea

FFMLI?(Ap KOGTp Velf.
AS USSR
"Emolytic Isowerisation in Polyhalogenalkenes.," Mer submitted
at 16th Internations.1 Congress of Pure and Applied Chemistrr,, Paris,
18-24 JulY 1957

IT., VA31L_Y:,VA) Y-,
Z(dZWIKII'!j L. r.,ll;YDLII;A;, ?-
Emd A.
Of 0,"i,-
th telormers olld 0 rICAl
k 'N-GiC3 Of
11poly-marizatiOrl Of or 4.t~,c CII.,
i~rcaa I
-pc. rprecented fj'; t
u 10 _y ,arclr. Erst.
ac:idsp" 11 PC' V W r7 13 I'l 13 t
Hier, polynvro, ~18 inn-,-) Feb 57~

4. T.
AUTHORSt Zakharkin, L.I., Kornevat V.V* 62-11-7/29
TITLE: Allylic Rearrangnments of 1.1-Dichloro-3-PhOnYlpropene-1
and Related Compounds (Allilinyye peregruppirovki
1.1-dikhlor-3-fe:.Iilpropena.-I i blizkikh soyedineniy).
PERIODICALs Izvestiya AN SSSR, Otdelenie Khimioheakikh Vauk, 1957, Nr 11,
pp. 1344-1348 (USSR)
ABSTRACTs Here it is demonstrated that under the influenoo of the
sodium-alcoholate on 1.1-iliohloro-3-phenylpropene-1 an
allyl-prototropt) rearrangament to 1.1-dichloro-3-
phenylpropene-2 takes place. In a further reaotion with the
sodium-alcoholate diethylacetal of the ainnamaldehyde and
the diethylketal of the j,henylethinylketone develop. It is
demonstrated that under the influence of the sodium-alcoholate
on 1.1-dichlorc-3-gotoXY--3-phonylprope.-ie-I the diethylketal
of the phenolethinylketone is obtained. There are 12
references, 5 of which axe Slavic.
ASSOCIATIONt Institute for 3-lementorganic Compounds of the AN USSR.
vffl=l~w (Institut elem-antoorganicheakikh soyedineniy Akademii nauk SSSR)

Z-
IUTHORS; Zakharkin, L. I. and Okhlobystin, 0. Yu. 20-2-20/50
TITLE: The Utilization ol' Aluminum Trialkyls in tho Synthesis of
Clemental Organiq Compounds (Ispolizovaniytj alyiaminiytrialkilov
dlya sinteza elerientoorgonichaskikh soyedineniy).
PERIODICAL: Doklady AN SSSR, 1957o Vol. 116, Hr 2, pp. 236-236 (USSR)
ABSTRACT: In conneotlon v.,I;h the fact that organoaluminuo compounds
were easil~r acce~jsible in recent times the problem naturally
rises of their utilization in the synthesis of other
element-organic compounds. In patent publications production-
methods were described of organozinc, organocadmium and
organomercury ccmpounds of the type RMeX, as well as of trial-
kylborines from haloid compounds of the same alements and
from a mixture of alkylaluminum-halides which forms on the
action of appropriate haloidalkyls on aluminum;
3 RX + 2 Al ---> RAIX 2+R2AIX. As far as this reaction
only takes place with the lower alkyls (R not higher than
C3H7), this method can not be considered general enough. In
Card 1/4 the present pa-,.)er the authors studied the interaction of

The Utilization of Aluminum Tr--.alkyle in the Synthesis of 20-2-2o/50
Element Organic Compounds
bcron-, antimony-, arsenic-, phosphorus-, tin- and
mercury-halides with triethylaluminum and tri-isobutyl-
aluminum. In all cases investigated an exchange roaction
takes place under formation of an aluminum halide and of
alkyl derivativen of the elements taken. On addition of
trifluorboro-eth:rdrate to tri-isobutyl-aluminum,
triisobutylboron forms at 60-650C. The same forms on
blowing gaseous trifluorboron through a triethylaluminum
solution in decahydronaphthalene. The interaction of tri-
--isubu* -alunipu--etbyrate with a suspension of trifluor-
_yl just an. e,4 ly. The inter-
a- 6i i -6h -of - --t ^i~ I ~1` b- ui-q-4-4-1i i dA_VA V 14 k - W-A 9 1 - tr i c h 1 oxi d e
-ah
in ether does nrit lead
are, however: i:iobutyl-trichloroaraine and di-isolnitylmr-
chloroarsine. Tae interaction of tri-isobutyl-aluminum with
phosphorus tricaloride is more complicated. The formation
of a complex of 'the reaction products with chloroaluminum
takes place as the result of an energetic reaction (in-
dependently of the type of solvent). From the reaction mas3
Card 2/4

The Utilization of kluminum Trialkyle in the
Elemental Orpaic CompoundS
Synth -esis of 20-2-20/50
isobutyldichloro-ahosphirLe can be distilled off in a
vacuum. On further heating of the rest a radical
deconposition taies place under formation of volatile
products and elecientary phosphorus. The interaction
of equimolecular amounts of tri-isobutyl or tri-ethyl-
aluminum with m(rcuric bromide or sublimate ka ether or in
hexane chiefly 'leads to symmetric dialkyl deri*,*atives of
mercury: a) Dlivo-butyl-mercury and b) broma-isobutyl-
mercury. Diethy:.-meroury was obtained from sublimate and
triethylaluminur, in hexane. Stannic tetrachloride yields
tetra-isobutyl-';in en the action of tri-isobXLtYl-alUMinUM
in heptane at 49-480C (after decomposition by a NaOR-solution).
Besides, tri-is)butyl-tin-oxide can be isolated by distil-
lation of the rest over sodium, apparently by dehydration
of the correspoadine hydroxide. Thus (iso-C 4H ) and (iso-
C4R9)3 SnC1 for% in the case of interaction o? tri-isobutyl-
aluminum and stannic tetrachloride.
There are 14 r(ferences, I of which is Slavic.
Card 3/4

The Utilization of Aluminum Trn.Llkyls in the Synthesis of 20- 2- 20/50
Elemental OrgoAic Compoua4s
ASSOCIATION: Institute for Element Organic Compounds AN USSR
(Institut alementoorgdnicheakikh soyedineniy Akademii nauk
SSSR)
PRESENTED: By A. N. Nesmeyancv, Academician, May Op 1957
SUBMITTED: May 79 1957
AVAILABLE: Library of Congre~js
Card 4/4

of A3Aeh)rd9B bY Red" tOn The react,1011 corim
preduotion .,, Vjydride. ally PossiblO, ben%03-9 hepO a
alumin 80 to go 0/ -c So trier p ( &dvan
D i is O'buty a of the the0ret' 'Iyents V lv e s Man. 8 frolu
attain Tformed in larinu.sent,,,, vtat i.nvo er&tures frolu
cornf.,d c a-' be r e uc-h $Oj:'+,hg nitrilep temp i0e Of
8, 0.), a Ire Of f L,,St eq"IWIar rat
tane ) e case 0 ,,,-r reduced
t..... iccordilig to tr-e natl %eve ne of
0 to 00 were - hosen. in th arti,n, nitriles ransitiOn Product ed
~Jts in th,3 re ~ 011 of the to L,,o 5hould be carrl
nartlciP-3~ , decoWlltto the rjjtr1* of such readW
the alailie .18 case tro"t"'
both . S. Tbi jjA hydridc .,3,1.j4 in tv
up too I JaLlIL'Rin espee I.d-3hlde - Th' tilw
dji3obtitY- prerlautiony acid t be dis
th.e -,jth grealo as phenylacet'c caproni_ty3_ canno, of phe"
out AJH to yields
changeablB a]jllf the ki-Cog ion. c an be wcpjained
tion Product D "Jithout &,,,omr;oslt aldehydes , This
.1 mm v acukm I 'I dichlorhe%en-1,41
d In -nd of ) 11) Cf these ine j,
e e~hjde llaplotnenjye opherjy~hadraz
t
nylacet'c &U ..paction ( )f 2)4 - dl-nitr ldrazon 00aes
..-ti.11 C -Aition ( , d- n-LtrophenY imental
by the P - ied y 0 ng 2. 1 by an exPer
can be -remed ~te of co es 0, 0 r is folloff0d
5 The ab e re eh are Sla"c"
0 tht the The ab
80 and entio a . at none of 'Whi
to conv e ere ces,
part with to 1e:, and
Card 213 There are
Production of Aldehydes by Rettuction of Nitriles With
Diiaobutyaluminimn Hydride.
ASSOCIATION: Institute of E19mentia-40rogani-c Jompeunds AN U3SR (Institut elemento-
organicheskikh voyedineniy Akademii nauk SSSR).
HMENTM: May 8) 1957, by A. H. Kemlfteyanov~ Academician.
SUDMITTED: May 7, 1957.
AVAIUBLE: Library of Congress.
Card 3/3

ZiW11,4Rk11vj 4,
AUT11ORS: Zakharkin, L. I., Gavrilt:nko, V. V., Okhlobystin,O.Yu. 62-1-18/29
TITLE: Tho Action of Triethy-1 Alunintun and Dii-sobutyl AlulrL=a Hydride on
Jjotal. Cb loridou of Group VI In tho Presence of Cart-on Monoxide
' I , L~oiybaonu and Tuni-;ii Lun Oarhonylo
(Deyotvij ,0 tfiOtil1r1'ju,",ij1_'ya i Ciiizol)utiluljui.iiiiij,,~'Ldrida n-A
khloridy metallov VI gru,jpy v prisututvii okisi ugl_-roda.Sintez
karbonilov khroma, moliblexia i vollfrai;ia)
PERIODICALs Izveatlya Ali' Otdolosilya DOmichoakikh Fauk, 1956
Nr 1, pp 1oo - '1o2 (j5:311)
ABSTIUCT: The action of trietbylal~,Aziinun and diioobaty1_-1L1z.-zinu"-hydride on
the above mentioned chlorides was for the fivit time investigat-
ed by Jab and Caszal (reforence 1 ') . Both f ound, that c,-,rbonyl es
of chroraium, molybderun, and tungsten are formed in the reaction.
Later this methcO waa investigat-ed by means of 13agnes, iu -,-organic
compounds, i.e. inuifferont variants. The authors shuw in this
paper that for tho obtaining, of Cr(CO)6, i;10004 and CR(CO)6
triethylaluminu-i and diisobutylaluminumcliloride can bousad with
success, i.e. in,carrying out the reaction of the chlorides of
the metals of tae 6th rrroup with triethylaluminum in etheric
oollution. In the reaction under the same conditionj with diiso-
Card 112 butylaluoinumhydride Cj:(CO)6 and "JO(CO)6 were obtained (with a

The Action of Trie~thyl Aluminun and Diigobutyl Aluminum 11y'drido on
Metal Chlorides of Group VI in the Presence of Garton Momxide. Syrithesin
of the Chromluz:,,- tlolybdetuun-, ant.. TunZsts,-~n Carbonyls
yield of '73 - 75~j') The ny'athesis of thu triv thy laluminun and
triisobutylaluminim (of w~iich dii:iobutylaluiiinuui~iydride was
produced) was ca: '-ried out by the authors corre3poridinj to the
reaction of Zie.vler, Gellert, Zosel (ref~erence 5) i'rOLi alutinum,
hydrogen, and thE corces-I.onding ol~~fiii. There exe 5 refernnees.
AS.SOCIATION: Institute cf Mem!.-ntal-Org-anic OompoundqAS JSSR (InoUtut
elementoorganichoskikh soyedineniy Akademii nauk SSSR).
SUB1,"ITTED: Iruly 12, 1957
AVAILABLE: Library of Congress
1. Triethylalumirun-Synthesis 2. Trilsobutylalustinum-Synthesis
3, Chromium carbcnyl-Synthesis 4. Molybdenum carbonyi-Synthesis
5. Tungsten carbonylo-Synthesis 6. Dilsobutylabrdnunhydride-
Production ". Metal chlorides-Chemical reactions
S. Triethylalumijium-Chemical reactions 9. DiisOutylaluminumbydride-
Chemical reac-6ions 10. Carbon monoxide-App1i:ations
Card 212

AUTHORG: Zakharkin, L. J., Okhlobyatin, 0. Yu. ZOV/62-56-lo-21/25
TITLE: Regrouping of Liuminum Trialkylo(Porogruppirovka alyuminiy-
trialkilov)
PERIODICAL: Izvestiya AkacL!mii naul: SSSR. Otdoleniye khinicheshikh. nauk,
1958, ITr lo, pp 1278 - 1278 (USSrt)
ABSTRACT: The authors flouiid by t'ric example of triisopro,)Yl aluminum
and tri-sec.-tutyl aluminum that secondary al,.x!-,inum
trialkyls re.-roup into primary aluminum trialkyls on
heatinG. The eescribed nethod of the prodt~.ction of
triisopropyl aluminum from (i-C 3H7)2Hg and Al does not
only yield triisopropyl aluminumt as the authors suggested
(Hof 1), but al3o the mixture of triisopropyl aluminum
and tripropyl aluminum which can be ueparat,~d by
fractionatioi,. The triisopropyl aluminum prDduced in
this way can be completely converted to tripropyl aluminum
in a sealed empoule. Tri-sec.-butyl aluminum produced
in the reaction (see. C 4H9)2 Hg with aluminum can be
Card 1/2 converted un(er the same conditions by reGrouping into

RegroupinC of Aluminum Trialkyls SOV/52-5a-lo-21/25
tri-n.butyl aluxiinum. In thi.3 case P-butylene and di-n.
butyl aluminum hydride could partly form. Tri-n. butyl
aluminum could '~e identified by means of n.butyl
mercury, bromide: boiling point 1360. There is 1 reference.
ASSOCIATION: Inatitut elementooi,,:,.~.~i-i--Iienl,-i~h 9oyedineniy Aktidenii nauk SSSR
(Institute of Elementavy Orpac Cwpowids AS MR)
SUBMITTED: Juna 6, 1950
Card 2/2

5W SOV/62-58-12-7/22
AUTHORS: Zakharkin, L. I., Sorokina, L. P.
TITLE: Condensation of P,P-Dichloro Acrolein With Carbonyl Compounds
and the Conversion of Condensation Products Into a-Pyrone
Derivati7es (KondensatsLya P,0-dilkhlorakroleins, 3 karbon.11n),=i
soyedineniyami i prevra3hoheniye produktov kon~.ensatsii v
proizvodnyye a-pirona)
PERIODICAL: I.-vestiya Akadfimil nauk SSSR .. Otdelenlye khimir.~heskikh nauki
1958, 11r 12, pi, 1445-1451 (USSR)
ABSTRACT: In the present pa:,)er the authors investigated the condensation
of P,O-dichloro acrolein with some carbonyl compounds, which
leads to the production of dichloro diene ketenes. Besides,
they Invostig2tod tho possibility of a closing of the cycle
of the lattor into a-pyrotie derivative:j:
RCOCH R' - CROCH-CC1
2 2 -).- RCX C11-CH- Col2 Co
0
Card 1/3 With aliphati-, aromatic ketonon tho reaction mith 0,,q-d1vh1oro

SOV/62-50-12-7/22
Condensation of O)O-Dichloro Acrolein With Carbonyl Compounds mad the
Conversion of Condensation ProlLicts Into a-Pyrone Deriyati,~es
aerclein in the presence of hydrogen chloride takes place
easily. Thus, acetophenorie with P,P-dichloro acrolein yields
1 , -1-lichloro-5-phenyl-1 3 -pent adi ene-5-~on:
HCI
C6Hr)COCH 3 "CHOCH~CC12 ---p- 06H5COCH- C11-C11- 0012
1
p-chloro-a,_etop.'_-enone, p-oxy-acetophenone, proplophenone and
n-butyrophanone react In a similar wav. With respect to the
mechanism of the closure of the cycle of the dichloro penta-
dione system Into an a-pyrone a, 'totem the following consider-
ations moy be zade: It may be assumed that in ne.',d medium
originally a h~'drolyais takes place of the 110,lorovinyl group
into a carboxyl group with a subsequent closure of the cycle
of the formed keto acids* In this case an addition of the
proton to the 144C1 2. CH-group takes place. The aasumption, how-
ever, that the proton affiliates to the and of the conjugated
system, i.e. to the carbonyl oxygen, seemo more probable. The
process of cyclization can 'When be represented as follows-
Card 2/3

SOV/62-58-12-7/22
Condensation of 0,P-Dichlort) Acrolein '17ith Carbonyl Compounds w2d the
Conversion of Condensation PXGducts Into a-Pyrone Derivatives
H+ OOH
RCOCE-CH-'.H-C'.1 2- xb, R 6 ASH- C 11 JTHI C C 12
11
HC CH
R--C cei
2
+0 '1
OH H
H 0
2 P 0
0
There are 4 references, 1 of which is Soviet.
ASSOCIATION: Institut elerientoorgar.1cheskikh soyedineniY Akademii nauk SSSR
Institute of Elementorganic Compounds, Academy of Sciences,
USSR)
SUBMITTED: April. 5,1957
Card 31/3

ZAKHAR IN. L.I.; GAVRILZIMD. V.V.
c on of -carbon dictide, on aluminum trialkyls. Dokl. AN SSSR.
U8 no.4;713-715 7 158. (MIRA 11:4)
I.Institut elementoorganichaskikh soyedinenly Akadsvii nauk SSSR.
Prodstavlono akadecdkom A.N* Nesmeranovm.
(Aluminum organic compouzda)
(Carbon dioxide)
(Acide)

rlov/62-59-1-29/38
51~ORS:
A
Za-kharkint L. I., Gavrilenko, V. V.
'
, -
TITLE: -TT-1 F-ra-r-t-i-�rl-of
al o-ens With Alum inum Tria.*A.!~yls (Vzflimode,~7flt-
H
Mi)
,flottlov a alyrminiytrialkila
PERIODICAL: Izvestiya Akademil nauk ~)Wi))orilye Ithimicheskikh n,,.ul:,
1959, lir 1, pp 166 - 166 (misa)
ABSTRACT: In the present -corztunication the authors report on the
investig,Ltion of the effect of chlorine, bro.-I~Llje, iodide
on a number of aluminum trialkyls. Aluminum trialVyls react
very strongly with halogens nithout solvent even at low
temperatures (down to -780). The effect of.chlorine vas
investi,zated with triinobutyl aluminum, tri-n-but-j ~21uminum,
tripropyl aluminum and tri-n-hexyl aluninum. Thus irobutyl
chloride, 1-chloro butaneg 1-chloro pre)jane nnd 1-chloro
hexane were obtained accordin.gly. The chlorination wa3
carrieJ out at -35 and -200. The yield of alkyl chlori~les
amounted to 60-70;/o. Beoides monochlorine derivatives also
higher chlorine derivatives were obtained, -specially --t
an excess of chlorine. In addition to th,%t, the aluminur,
Card 1/ 2 trialkyl mixture synthesived from triethyl aluminum an,]

interaction of yalooena witi, Alurinum Trialky1a
ethylene was chlorinated. 1-chloro butane, I-e.-Horo hexane
and 1-chloro octane were separated therein. The reaction
with bromine was investigated with triisobutyl aluminum,
tri-n-butyl aluminum, tripropyl aluminum and tri-n-hexyl
aluminum. At -20 and -250 only 2/3 of the th-aoretically
required brouine quantity reacted. The yi(Ild of alkyl br.-jriiides
amounted to 60-M~- By the action of bromine on the
reaction product of trimethyl aluminum and i-sobut;flene nco-
pentyl bromide was precipitated in addition to methyl brom-;(~e.
The effect of iodide was investig-ated with tr--:ethyl- and
triisobutyl aluminum. The yield of alkyl iodides amounted
to ^j 60%. Under given 2onditionE! isomeri-nition of halide
alkyls wa8 not observeli in one of the canon Investi,i,,atrd.
There are 5 references, 2 of ahich Tire Oovict.
ASSOCIATION: institut clemeiitoorir,,.iricl,.e,3kikh r-oyedineniy Akaienii nrll.~k-
SSSR (Institute of E.1(4rental )rjanic Compounds of the Aczl~f~M-,,
of Sciences, US2,M)
SUBMITTED: June 6, 1956
Card 2/2

5(3)
AUTHORS: Zakharkin, L. I., Ok'.hlobyntin, 0. Tu.
TITLE: On the React-ion of Realkylation in the Aluminum and Boron
Trialkyl Series (0 r2aktsii perealkilirovaniya v ryadu
alyuminiy- i bortrialkilov)
PERIODICAL: Izvestiya Mrademii n;-iuk SSE-R. Otdclcnlye k:,i!.michft--1,ikh n-.11!~,
1959, Hr 1, pp 181 - 181 (UM321)
ABSTRACT: The authors write in -- letter to the editor: On heating tri-
alkyl or triaryl bor)n R E with trial!-yl r-,luminum 1111-`Al
3
a reaction of realkyLlation occurs. Thus RI 13, R,,Al and
5 .1
products of incomplete realkylation of initial trialkyl
aluminum are formed:
R3B+R I al -4 Ral + R,3B
al. 1/3 Al; R. n-C H C 11 - RI
4 9; i-C4Hqv 6 5f
Recauve of the high reaction temperature
fin in separated from th(! R Al forned in
Cnrd 1/3 conaidarable det~roe. CorloclilAorttly corronpondin,,-
CT',')IC2H5'
(120-1600) the cle-
cat-,es to a
(lialkyl

On the Reaction of Realkylation in tho Aluminum and Dor)n SOV/6 2 - 5n- 1 -,:"7/'78
Trialkyl Series
aluminum hydiidon :~re produced. In thv, interaction of
triisobutyl toron Yrith tri(-tiyl rltiminuri, f:~r inst:--nce,
triethyl boron and diisobutyl alumintin hytlride v1pre obt~airiel.
On gradual hentin~,- (up to 1800) of the nixture of tripherly!
boron with a double cunntity of triethyl ~-jlaminum triethyl
boron is slowly distilled in pure ni-tro,-,en -~rrrent. After
the distill,,tion of the mixture (C 2if5)2 AlC6115and
C2H5Al(C 6H, )2 in vacuum triphenyl aluminum remains in the
residue. Under equal conditions, trimethyl boron is synthe-
sized from (C611 5)-,B and (CH 3)3 Al with n, yield of 75'J'. Tri-
methyl boron is oiowly separated on h,,~atirg the mixture of
trimethyl aluninum a.nd tributyl boron up to the boili,-,6
point. The tributyl aluminum bein-- produced containa up to
25% dibutyl aluminum hydride. In the intcraction of tributyl
boron with triethyl aluminum trintYyl bornn an(l alno -.L
mixture of tribut,-,l alurlinun and dibutyl -Itirtintri hy,iride
is formed which contains 59;5o' of the latter.
Card 2/3

On the Reaction of Real kylzA..on in the Altiminum, arvil Eoror '70171(2-'-~~-!-" "7-,z
I ~'i -
Trialkyl Series
ASSOCIATION: Institut eliE-n(!ntoor,,:,,i,nievi4,rl-ikli ,3oyedineniy Alrale-.1ii nallk
. SSSR( Inctitute ofEjwrj;nj Jrganic Co-,ifjoin-do of the Acn,itrly
of Sciences,
SUBMITTED: September 9, 1958
Card 3/3

50)
AUT11011: ZakharkinlL. 1. SOV/62-1--, --9/37
-3
TITLE: Reaction Between 1,1-Dichlorohexene-I and Sodium Ethyl Mercap-
tide (Deyntviye c-tilmerkaptida natriya na 1,1-dikhlorgeksen-1)
PERIODICAL: Izvestiya, Akademil. nault SSSR. Otdeleniyo khimicheakikh nauk,
1959, Ur 31 Pp 437-443 (USSR)
ABSTRACT: In the present paper the action excrted by sodium ethylmercap-
tide on 1,1-dichlorohexone-1 as well an on 1,2-dichlorohexene-1
and 1-chlorohexino--l was invrotij-,ated. On the heatinC of' an
alcoholic solution of !iodium ethyl mercaptide with 1,1-dichloro-
hexene-1 2 compoundn were obtained: 1-cliloro-2-othyl mercapto
hexene-1 and 1,2-bitj-(ethyl mereapto)-hexene-1. The same
products were lik3rise obtained from 1,2-dichlorohexene-1 and
1-chlorohexine-I -.inder the action of ethyl mereqptide.
Investigating tha etructure of these two compounds the
following was found: On the action of 2,4-dinitro-phonyl hydra-
zine in the presence of sulphuric acid always the same 2,4-di-
nitro-plienyl hydrazone C14 11 20 IT4043 is formed. On the heating
of solutions of 1--chloro-2-ethyl mercapto hexene-1 and 1,2-bis-
Card 1/3 (ethyl mercapto)-ILexene-1 in hydrochloric and acetic acid

Reaction Between 1,1-Diohlorohexcite-I and Sodium SOV/62-',,9-3-9/37
Ethyl Keroaptide
mixture always the same I-ethyl mercapto hexene-2 results.
This yields the 2,4-dini.tro-phenyl hydrazone which is identi-
cal with the 2,4-dinitro-phenyl-hydrazone dircoluly obtained
from 1-chloro-2-ethyl mcrcapto hexene-I and 1,2-bis-(ethyl
morcapto)-hexene-1. As to the reaction of sodium ethyl
mercaptide with 141-dichloro hexe4e-l-it may te assumed that
.the first reaction -stage is the addition of C2H5SH to the
dichloro vinyl group and the following separation of HC1.
Apparently the separation of hydrogen chloride taken place
more readily than the addition of ethyl mercaptine. Such
an addition of ethyl mercaptane to the asymmetric dichloro
vinyl group is in contradiction with the addition of a number
of electrophilic reagents, if it proceeds by way of the
addition of the C 2n5S--anion. In the case of an action
exerted by nucleophilic reagents on the dichloro vinyl group
an induction effect of the chlorine atoms seems to occur which
produces a fractional positive charge at the seoond carbon
atom. The action of the nucleophi'lic r:?agents in directed to
Card 2/3 this carbon atoia. I;a t~e case of electrophilic reagents,

Reaqtion Between 1,1-Dichlorohexene-1 and Sodium SOV/62-59-3-9/37
'Ethyl Mercaptide
howoverp the determinative direction appears to be the
electromeric effect of chlorine atoms. It is not impossible
that the addition of ethyl mercaptane takes place according
to a radical mechanIsm although the reaction in the presence
of diphenyl amine in nitrogen atmosphere offers the same
results. There are 10 references, 4 of which are Soviet.
ASSOCIATION: Institut elementooriranicheskikh soyedineniy Akademii nauk SSSR
(Institute of Elemez;tal Organic Compounds of tha Academy of
Sciences, U30SR)
!IUBISITTED: June 11, 1957
Card 3/3

50)
AUTHORS: Zakharkin, L. I., S-vin.-., L, A.
TITLE: Effect of Trieth-,rl Y,luminum and
Some Allyl Compoundn (Deystviye
but ilalyuminiygidrida na nekotoryye
SoV/62-59-3-10/37
Diisobutyl Aluminumhydride on
trietilalyurniriiya i diizo-
allilInyye soyedineniya)
PERIODICAL: Izvestiya-Akademii nau!~ SSS11. Otdeleniye khimicheSkikh nauk,
1959, Nr 3~ P; 444-449 (USSR)
LBSTRACT: In the present paper tha effect of triethyl aluminum and
diisobutjl aluminunhydride on allyl compounds CH 2-CH-CH 2X,
X beinj; OR, SR, and ITR 2f was investigated. A clenvage of the
C-X-bond takes place and an unsaturated hydrocarbon and
corre-~ponding (C211 5)2 AIX are formed. The inability of triethyl
aluminum to react with the double bond of the allyl compounds
investigated may be explained by the decreasing electron
density at the heteroatom owine to the complex bond thatze-
duceB the activity of the double bond. In contrast with the
triethyl aluminum the Adition of tho dilcobutyl aluminum-
hydride to the double bond takes place comparatively eanily.
(i-C H N AlCH CH CH X are formed herein, whare X = OR, NR
Card 1/2 4 9/2- 2 2 2 V

9ffect of Triethyl Lluminum and DiisobutYl Aluminum- SOV/62-501-3-10/37
hydride on Some Allyl Compotuids
and SR..Further an attennt wan made tn allow the diisobutyl
al uminumhyd ride to r(act with tho double bond or the vinyl
butyl ether. As a recult of this reaction which proceeds with
self-heating, ethylere (already at 30-350) and -butoxy diiso-
butyl aluminum ivere obtained. Apparently the or,~anic aluminum
compound of the R2Al-.CH2cH2 OR type, rhich in in.itially formed,
in as-unat-,ible--as--siL.,-il.,4r-orgtai-c magnezium -on 'Pounds-
XMgCH2CH2X(Refs 6,7). It decomposest while ethylene is
eliminated and alcoholate (i.-C 49)2A111 + CH2'CH-CC4 H9
(i-C 4H9)2 AlCH2C11 20c 4EQ (i-C 4H 9)2AlO(,'4 TI9t C'. 12 -CIT2in
I
formed. There are 12 referencenv 1 of rhich is 3oviet.
ASSOCIATION: Institut elementoorgE.niche3kikh soyedineniy Aka,lemii nauk SSSH
(Institute of Elumentr,l Organic Cnmpounda of the Academy of
Oooionoerj, LIS'4111)
SUBMITTED: June 14, 1957
Card 2/2

50)
AUTPORS. Zakharkin, L, I., Khorlina, 1. M. SOV162--59-3-27137
TITLE: Thermal Decomposition of Adducts of Diisobutyl Lluminum
Hydride on Nitriles (rermicheakoye razlozheniyg? produktov
prisoyedineniya diizobutilalyuminiygidrida k nitrilam)
PERIODICAL: Izvestiya Akademii nauk 31,30R. Otdoleniye khimi-.hcf3kikh naukt
1959, Nr 3, pp 550-552 (USSR)
ABSTRACT: In the preceding paper (R(-f 1) the authors obtained the adducts
of diisobutyl aluminum hydride and the nitriles
RCH=N - Al (i-C 4if 9)2' In the present paper the behavior of
theoe products was irvestigated when they are h,iated. It was
foL,nd that a gas con&isting mainly of isobutylene is separated
if' the compounds RCII:=N - Al(i-C 4H9)2 are heated to tempera-
tures of from 220-24CO. In the hydrolysis of th.9 residue,
hovever, the correepcnding amine RCH2NH2 forms -with a yield
of up to 80 % of the theoretically computed val-ac. Thus# in
heating a reduction takes place due to the displacement of
isobutylene and the formation of new Al--N bonds. In this re-
duction products of the following linkage systems form:
Card- 1

Thermal Decomposition of Adducts of Diisobutyl SOV/6,?--59-3-27/37
Aluminum Hydride on Ifitriles
I I
- K - Al - N - Al - In adducts of diiBobutyl aluminum
I I
CH2R va2n
hydride and disubotituted amiden a reduction at the expense
of the displacement of isobutylene in possible In principal.
It is, however, only unimportant and furthermor.), is accompanied
by strong resinification. There are 8 references, 1 of which
it) Soviet,
ASSOCIATION: Institut elementoorE-anicheskikh soyedineniy Akademii nauk SSSR
(Institute of Elemental Organic Compounda of the Academy of
Sciences, USSR)
SUBMITTED: July 16, 1958
Card 2/2

SOV/62-59--5-32/40
MUM; L. F,
TITLE: Rearretngement -of - ~,I-Dichloro-5-OXY- Chloro)-5-A"YlPenta-
~
diene3-1,5 Into 5-krylp(intadiene Acids
Peregruppirovka 1,1-
dikhlor-5-oksi (khlor)-li-arilpentadiyenov-1,3 v 6-arilpenta-
diyfjnovyyo k1aloty)
PERIODICAL: Izveatiya Akadomii nauk SSSR. Otdeleniye khimic'noo'cikh nauk,
1959, Nr 5, pp 936-938 eUSSR)
ABSTRACT: In the present paper tha reduction of come lpl-dichloro-5-oxo-
5-phenyl pentadienes-1,3 into the corresponding oxide deriva-
tives was carried out, ind the allyl-anionotropic iaomerization
into 6-aryl pentadi-rz- icid was investigated acccrding to the
scheme H_ I H +
ArCOCR--CE-CH=CCI2 ArCH-CR-CH-CR--CC12
&H
ArC11-CR-CH=0WH-COOH.-Such a rui-grouping in pentadl.en,)a hao hither-
to not been investigated. The reduction of the following diene
ketones was carried aut wi-1h aluminum isopropylale! in isopropyl
Card 1/2 alcohol-.'ArCOCR-C11-CH=CC12 with 1) Ax = 0 6H59 R - H;

S07/62- 9-5-32/40
nearrangemnt of I'l-Dioliloro-5-oxy (Chloro)-5-arylpontadioni)e-1,3 Into
6-ArylpentualCLL Acids
2) Ar - 0611 51 R - CH.; 3) Ar-p-ClC6H4t R - H. 0:-' these three
oxide derivatives obtained only 1,1-dichloro-5-3XY-4-methyl-5-
phenylpentadiene-1,3 showed sufficient resistan-.e to heat, so
that it could be distilled without being changel. The other
two alcohols had to be converted into the correspondi:ng
chlorides for the purpose of vacuum distillatioa. In the ex-
perimental the -..ndividual reactions are described and the
physical characterisiics of the substances obtained are given.
There are 5 referencos, 2 of which are Soviet.
ASSOCIATION: Inatitut elementoorganicheskikh soyedineniy A ademii nauk SSSR
(In3titut, of Zlemental-organio Compounds of tho Academy of
Sciences, USSR)
SUBMITTED: October 24, 1958
Card 2/2

J, %,-7,
5 (3)
AUTHORSs
Zakha:rkin,-!",, GavrLlenko, V. V. sa7/62--,.,9-8-39A2
TITLES Anomalous Reaction Course in the Displacement of :[sobutyleue
by Means of Styrene From Triisotitylaluminum
PERIODICALS Izvestiya Akademii nauk SSSR. 0ij,delenlye khimiche;3kikh nauk,
1959, K;~.St P 1507 (USSR)
ABSTRACT: In the displacement reaction of.triisobutylalumin= and styrene
an affiliation of aluminum to b,-th the first and second carbon
atom could be observed contrartr to Ziegler' 's statements (Refs 1? 2).
The two isomers were cbtalned L-z a ratio - 7:3. The following
equation is given for the reactlon: C CH-CH + i-C H al 0
05 2 4 9
C C -al + 0 R CH al i-C H al -0 1/!; A-1. Af ter the
61,57 6 5. 2CH2 4
CH3
oxidation of the obtained mix-'.,Xo with chromic arlVdride in
acetic acid, acetopherone and~')henyl acotic acid were
precipitated under the influeu'je of carbon dioxAde-ethylbeazoic
and cinnamic acid. Sizilar re-ialte were obtained in the
in7estigation of the EXfiliatl= of diisobutylaluminum to
Card 1/2 styrene. There are 2 reforeno !s,

I e7 '5~4't: 31~;';~~ ~Zl't"-Z'm~'~4
AnomalTas Reaction Caurse in the Lisplaceml A of SOV/62..cg-a-39/42
Isobutylene by Means of Styrene From T..,i is r butyl aluminum
ASSOCIATION; atitut element oorgani,,-h(.-,-tkikh soyedineniy Ak,%domii nauk SSSR
IeInstitute of Elemental.-tx-ganio Compounds,- Aoadeta~- of Scienaes,
USSR)
SUBMITTKDt May 22s 1959
Card 2/2

5.3610 77071
sov/62-59-12-15/43
AUTHORS: Zakharkin, L. I., Khorlina, 1. M.
TITLE% Reduction of Substituted Amides to Aldehydes and
Amines With Diisobut~llaluminum Hydride
PERIODICALi Izvestiya Alcademii nfuk SSSR. Otdelenie khimicheskikh
nauk, 1959j Nr 12, pp 2145-2150 (USSR)
ABSTRAM Dialkylamides of aliphatic acids and amides of aromatic
acids are reduced wi-';h diisobutylaluminum hydride. The
yields-o,f-aldehydea-are given irt Table 1. The yields
of amines obtained bj redu6t-ib-ii-*Of-monc~--;aiid-disubE~ti-
tutedamides with ('a')-C4H9)2AlH are given in Table 2.
Card 1/5

Reduction of Substituted Amides to
Aldehydes and Amines With Diisobutylaluininum
Hydride 9, Cot) e- n4 w ro
(-M4P 0* R4 no Mfltf* 70 #/pAllpr
ep
4101c-
77071
sov/62-59-12-15/43
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Reduction of Substituted Amide's to -17071
Aldehydeu and Amineo With Diisobutylaluminum SOV/62-59-12-15/43
Hydride
RA na o.- Y/w
OF
4VAIS eZ A
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* -- picrate; b -- dihydtochloride; c -- hydrochloride
* Found for Icobornylbenzylamin e: 01 12,117
Card 3/5

Reduction of Substituted Amides to 77071
Aldehydes and A-mines With Diisobutylal.uminum sov/62-59-12-15/43
Hydride
Card 4/5
The reduction of disub;3tituted amidea to ablehydes
occurs as follows:
11C ONRIIII + (I-C"IIq)j Al 11 - It - CH - N11111, RCHO,
OA1 O-C-111h
The reduction of amides to amines occurs according.to
scheme: (1) + (i-C4IIq)s AIII - 11019NIllij, + (t-C411,), Alo~i (1-c"110jr
There are'5 tables; and 21 references, I Soviet,
5 German, 3 Frenchi 5 U-S-~, 7 U.K* The 5 most recent
U.S. and U.K. references are: V. M. Micovic, M. Lo
Mihailovic, J. Org. Chem.. 18 1190 (195D 0* D.
Johnson, J. Am. Chem. Soo., 46., 7543 1* 1- A-
Braude, R. LT. Jones, J. Chem. Soc., 4 ~J9
J. D. Roberts, Ch. Ox,een,, J. Am. Chem. SOO..'& -e14
(19116); R. E, Benson, F. L. Cairus, J. Ain. Chem. Soc.
70,, 2115 (1948).

Feductic,n of' Subztituted Amidea 77,571
Aldehydes and Amlnf-is Wt-h D1.1-obuty1al-t~rin,11r.
r I
A330CIAT-10N.- Institute of Elementoorgarde Compouncio, Academy c-f
Sclr-ncf~s LISSR ~Instltut elemen',-oorgi--in inhe.M