SCIENTIFIC ABSTRACT ZAKHAROVA, A. F. - ZAKHAROVA, F. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001963610008-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 19, 2001
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

PARKRUTIK, P.A., kand.tekhn.nauk; ZAKRAROVA, A.F.
Effect of heat treatment conditions on the characteristics of
AL9 alloy. Avt.prom. -20 no.2:34-36 F 16z. (MIRA 15:2)
1. Minskiy avtozavod. -(Aluminum alloys--.Heat treatment)

I ?. I-.-- _... .- S)Y~3~62/000/014/004/020
jai D A004/A101
AUT-46RS: Parkhutik, P. A., Zakharova, A. F.
TITLE: The effect of the heat-treatment conditions on the properties of
the AJ19 (AL9) alloy
PERfODICAL: Referativnyy zhurnal, '.Kashinostroyeniyep no. 14, 1962,-22, abstract
114A139 ("Avtomob. prom-st", 1962, no. 2, 34 - 36)
TEXT: The authors present the results of investigations for cutting down
the heat-treatment procedure of" the AL9 aluminum alloy on account of a reduction
in the holding time prior to hardening and of the ageing time. It is pointed out
that optimum mechanical properties of AL9 alloy specimens db- = 25 - 27 kg/mm2,
HB 85 - 90 and 8 - 1.5 - 2.0% are obtained with hardening at 5350C (holding time
4 hours) and ageing at 170 and 1850C (with 4 - 6 and 2 - 4 hours holding). The
cast AL9 alloy will harden without quenching. For parts which are of no special
importance and which do not require a particular surface finish, the foAlowing
heat-treatment conditions are recommended: tempering at-170 and 1850C in tho
course of 6 - 8 and 2 - 4 hours.
[Abstracter's note: Complete translation]
Card 1/1

S/129/62/000/005/006/011
E073/E535
AUTHORS: Parkhutilt, P.Jk,,- Candidate of Technical Sciences and
ZaLc ~-i~~t--,Znginoor
TITLE: Heat treatment of the alloy AJI 9 (AL9)
PERIODICAL: Metallovedeniye 1, termicheakaya obrabotka metallov,
no,5,,1962, ?,8-4cl
plis (200) cast into
1EXT: Standard specim earthen moulds
w4th various contents of silicon and magnesium (ifilthin the
limits of the specification r0GT (GOST) 1497-42) were investi-
gated for hardness and strength after the following heat treat-
~,-Ients (the skin was not machined off): 1) quenching after holding
at 5350C for four hours; cooling in water to 60-40OC; ageing at
150, 170, 185 and 200*C for 2, 4, 6 and 8 hours; 2) ageing of
specimens in the as-cast states at 150, 170 and 185*c with the
same holding times; 3) quenching in water from 535*C after
holding for 40, 60, 90, 120 and 180 min; ageing at 170*C for
2,4,6 and 8 hours. It was found that tempering at 1500C does
not ensure full utrengthening of the quenched alloy. The highest
strength is achieved after ageing for two hours at 170 and 185*C
Card 1/2

SfIELUCIIENKO, Valentin Rikliaylovicb. Prinimali uchant1jets-IZAKILAU110
dota,.,kand. tekhn. nauk; RW,&.'OVSKIY, Mop kand. tekhn. nauk;
-GOffAXSKIrq,'fu.V.# dots.., red.; SUTLERp N.V.., red. izd-va;
KOTLYAKOVAO 0.1., tekhn. red.
(ShipbtLilding materials and ship repairs) Sudoetroiteltriye ma-
terialy i sudoremont. IRningrad, Izd-vo "14orskoi transport#"
1961. 332 p. (MIRA 150)
(Shipbuilding-Equipmentand supplies)
(Ships-.Vaintenance and repair)

-ZkKHkROVA,-Aa.,-kand. tekhn. naukv red.; F%IICHEV9 A.G.9 red. izd-va;
GVIRTSq V.L.p tekhn, redo
(Smal.1 hard-alloy fomixqy, cutting tools made of plasticized blanks;
at+idged report of lectuxes delivered'in the Leningrad House of Sci-
entific and Teebnical.-Propaganda at the "Manufacture of cutting tools"
seminar] Tverdosplavnyi fasonnyi malogabaritnyi instrument iz plasti-
fitsirovanxqkh zagotovok;'sokrashchannala stenogram-a dokladov, pro-
chitamifth v LDNTP na seminare "Instrumentallnoe proizvodstvo.n Lenin-
grad, 1961. 26 p. (L6ningradskii'Dom naucbn6-tekhnicbeskoi propagan.-
dy. Seriiat Mekhanicb8BkaiA 6brab6tka metallov) (KMA 3-4:7)
(Metal-cutting tools)

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lone and a substance with formula C229 0 %
formed. When I is treated with 0oncen&t
hydrochloric acid in the presence of CuC12 and
MkCl, the win reaction product is a mixture of
chlorides. Submi-tted 20 Apr 1947.
9/4M6

-sert-buty1wAtykne. A.
ls.kruvA (A. A. ZhlI12vSutC Vniv., Lcoingrall)-.- 1kar.
061khtf MOM. (J. Gen. Cbctu,) 20,
Authralk- Jj,CjCC'J1vj islut pf"MI. as jolll-ws: 1'ri-thl.
CIC11, WAO peetwi. av.M4111C to Ivitakil Ad. IV741)
with IIu()II UK Owtod, Aturind it? ltt,e .14
Me; y1c1d. The hydrac.-Art"s treit"I with S;,j j&jjjjj
"fuler Ht'O fluddy Vve Me Na deisr., which Wax tfc~tal
wit It emlilig wit It 11c.5ck. then hem tell L' hrs., yk-lding ek)%
pit., 1.4051.
so'.* 1.4401. el'o' 1.4113 (the pscoticifit-4 ate -~mtijmitl "oh
Ilulocrults pvViqlas PIVIMS.; to wrteirtlerll. thl4mitll
,Aith 1% K161n0l gAve McjCCCh11 itust AcOll, whkh Atir
j1w) obtAitift] con usouolyzisl. The RAttun *In-virum ~Isuwvf
a line at "1'411 cm.-I chameteristil: at the C!C link. The
I)MIUCI IS WIA1110 Anil 15 URCIM115"I CHI 14419 -tUfAge Of 011
IrMing with life. MINI. (1. N1 91144,11MICI

a= of. by' m, A. 1. 7A.
Zkow MArktf Kkim.
(from pilwe.
sfklwrqf Itle
Rukumn till" (Inten%like on a &4walc) 21:041), 211119.5).
2WOU.N. 2HIM.5), itago.h), 1451(4), I:wp). 11tri(t).51,
irJA3). MG(2). 701(4), 37t~!!). 1WRI), 193(A).
Tbe Imiurr" 214M cm. -I cortropunds to the triple txxid.
The till" I;Mk5 an-I 1451 are rhanscirtWit- 4 Irtminal
IWAII.-hillc and of Me pout". l"p. N. I Islas

ZAKHaOVA, A.I.; SAPOZHNIKOVA, R.A.
.7 . I - -1-1 1-1--1---
Intrawlecular rsarraz4.poonts in the &cotylozw series. VII. A"OtIon
of an ae4tylanic chloride, 2,3,3-trinotb7l.-3-chlaro-"harl", With
organamagnesius compounds. Zhur. Obshcbay Khim. 22,1804-10 052.
(CA 47 no.14:6857 '53) (KlJb. 5:11)
1. Leningrad State Univ.

Imikamselander reeffampments In seetylsee series. V1.
Pjrj= jajmmft14",&6e and
ies I'lift ML,dt a Reactlas 01 2,2.3-tri-
y,,"dW%4Aez wift I&w Wetaft. A. I -
. . -Fee
;nd K. N. Mbrorayslova (A. Zh(tA11GV-STMV--
TIfthr.-.1.4iii restd). Asir. Obs"I Xhim. 0. Gen Chen..)
20, cf. C.A. 43, OIN11c; 44, 11011a. --Posi-
MV of Mtc-Cll through 410 ml. RtO and 21A) g. powd.
ws
KOH at W th a,ldn. of 110 X. %lftCAc in 1`390 KAVV. After
standing ov-1ght, 65% J1eCC.1fr(U11W:,C11 (1). tht
68'. d: RAW. d.'* O.WG, xj? is" 1.45111111. x,,'
lAwl (Cf. lotmskh. J. Russ. 11hys. (*AZ. -';-. 41. M11
09(19)). Treatmentol'25g. I with 4-5g. portionst)(diry
HCI gave a sts-ststancous irsup. fi--c in 70-5'. Yielding
tPi;sgdAy1-J-th1Pr&44exYxr (11). ts, "s. 21'. (1.,'
11.9275. #1:* xj,' 1AM111. #t.- I-ORKI-1, xl't' LOY.031%
this with 10,10 alk. K.%It%O. at Nt* 9AVe %lesCAc and ArOlf.
stiffing 10 11. If with 17 1. AjQAc In AcOll I firs. it (UP
-lPime1kyW-wdoxy-4-ktxyw (1111i.
gave 63%
d-, 0.9021. d" 0.9144. %1,* 1.44310. n'.' LOW. ma" 1.451N.
Relaxing 8 g. I with 40 S. AcO 13 Isrs. gave An ..ciats:
closely sirrWar to M, bs 62-3% d.9 0.9315. d.10 0.91-38.
Fortnatkm of the U from I procetd% by a tnonotno!, intchA-
nism. as shown by the case of rrplAcenjent cumartl by the in-
ductivt effect of the Me group. G. NI, KOWAAPOR -

USSR/Memistry - Acetyleme Series Jul 49
Rasrrangementg, Zatermolecular
"Intermolecular 'Rearrangemento In the Acetylene
Series: V. Interaction of Acetylev Chloride -
34hloro-3-XethYlhe.VU-4 With XWes:l'= Organic
Compounds," A. 1. ZalEbarova; Chair of Ora Chmi
Chem ratulty Le .1-3 0rd of Lenin State U
Imen! A. A. , 5 1/4 pp
"Zhur Obabah rnlm" Vol =, No 7
Reaction of initial coz~oundiith C245MgBr Is
ac-.amppjaied by an interm.olecul rearrangement,
am %'result, of vhich agi!~'produced! 3,,5~-dimethyl-
heptediene-3,4 and 5methyl-3-ethylberju-4.
2/5OT26
USSR/Chemistry - Acetylene Series (C=td) Jul 49
Resrrangements, Intezziolecular
Anomalous product, 3-methYl-5-.pheinrl-bexadiene-.1,
results 1rom. reaction of C6HPgBr.,v:Ith izdtidl
cov4cund. Discusses possib.1
me n-1- -f ~ theve
GOVIbmitted 7
2/5OT26

U=/chemifftry. - Acetylene Jan 49
Chemistry - Rearrangemente Intramolecular
lecular Rearrangements in the Acetylene
Intramo
Series: IT, Interaction of 3-ChlorO-34%tbYl-
-I-Beatyae azda. '5-Chloro-3-14etbyl-4-Hexauo With
Silver Acetate," A. I. ZakhELrova, Chair of
~~~Ctrg Chem, Chem Faculty, Ieningrail State Ord
of Lenin U imerLi A. A. Zhdanov, 8 I!P. PP
.""Zhur Cbahcb Eblyn" Vol No I
Intheraction of tertiary acetylene chlorides
-:-,vith silver acetate in glacial acetic acid
sives acetates of the initial alcohols from
58/49T19
I.TM/Chemistry Acetylene (Contd.) Jan 49
..vhich the chlorides were prepared, an unatable
allene, acetate.,_ formed by intramolecular re-
olefinic cuacetate. This
~e of one was demonstrated on
.:~:eubject compounds.
carbinol vaB prepared from methylacetylone and
Ln&thZl ethyl ketone and converted Into the core,.-.r
-reoponding chloridgby reaction with phosphorus
-trichloride or gaseous hydrogen chloride. T-bla
xeaction is accompanied by partial debydratj
1~,'formlng 3-metbyl-2-hexene-4-yne bp 107 - leb
1~11-.:iLt 737 =, d(2o/4) 0.7785, n (20/D) 1-41:5057.
,,~Sabmltted 20-Aii- 47. -
!,Jaw 58/49T-13

,A 'A 0 A -.J.
A 14LI A. -- - I7t, 0&
o
f
--U6:kLLL1W AX0 r1rXfWt-tS 4
o I-Frain r Bub Betty"" "Off.
M. Recedes a( in 0" dwwo, 2-cmairs-2-
Wift eirgame-dowd ,
00 A fri'J""Y '('.:
114vilueralf State t '00
(U S 4 R) r IM-M(11147)(In Rumskn); cf.
C.A. 44, 56W."' UeiJgHr (IMM 10 1. US Wild 62 E.
Ogg XeHr) iss 200 tv. 91q0 wm drvanted frost unused Me and
008 the man. sloorlty ,V d with 40 t. MeoCCICICMe; after
6 hn. at a 1. was decosupd. vith dil. IM amt
Got
the org. 14y" gave b. 1124% d. 19 it.
0.7311. d*41 0.7 1W, al: 1.42M. A shallar rvaction ming
rkmglk (froin a . NIS and M a. Ph1hr) Save WOMMY1..
omyWr~ (4Woll. bm 106-W, d: 0.(WW. 40 0.9X1. a**
00 is'.' 9.UI331 m" 1.6=74. mV 1.54703. The products In
Is anomakms and remit from arciarrafter-
0*0 1 both mves, me 1,14or Intrarmilecularly at the
"W"t. mthaNy takin
000 moawnt of tracth-m. tuder the rvactkm condhions, a
06 bound resonating taboolum imt
66 R
A A ,go
R/
x
R 00
C C4 - - R Image
41
It luillWAIWIts fwtkm with RMIX Arm flor for"Idik" 00
P-rallwis. 4111
11111ti(fierf 1111flivor lbeedviykiiiii typo g
IV, 00
1800
1100
glow ;it 0
.1. a.. Ogg a',
-0-11 -T a rw -0
Ktt~,-~ 0 a I v &I ') a -d -)v
MW a I
0 0,0 0 0 0 0 *
0 0 0 0 010 0-0 0 6_0 9 0 0 0 0 0-8 0 : : : : :i* 0 0 * 0 0 00 00 0 0 0 0 6 0 0 0 ei

isrs' A
11111141111A
so
00
00 it
094
00
IN
U :A
A -^

ON 11 !
I To
At AS M if 14; U It M a Is it At is a 41 tj
a A.
; I A f
J
L- IL a A I
V
V- L
i
st 41 A it Ie
, -
.
-
'
.
1ntr1IAW#ctsW reaffangements of ciawaads W the
IIC!Ti:*. rk4. 11. Road= of as it"nook chwMa
&-I
4u with lover least*
:
,
.
1. Ofol
Cke".
fters"I state Univ
Me 1
I
)
.
.
.
N~17. M41 tr22(l9I-.)(hi Rul%lan); 0. C.A. 40.
M 1.00
MAI.-INAwO. X011 (2M S.) amt 4M cr- alls. littO
*
d
h
i
-00
sit.
t
em
with McCICII an
were said. withslitringst 0
wav irrale'l whis 97 4. %fr,V0 in 311) ce. I?I,A) with ron. .00

"A' 101111 ire wairrand thr'llif4i'm 1. laver 14%r
4,41 till,111. 'W". Ijf.V(f pit) C~ ('310 (1). INA. P41-0, 414
0,M)II, dl' is KKI, x1.* 1.4441%j. ml: IACM -,thew values
&are with 113~ of lotsich (J. HMlq !sky$, CArm. Xv.
AM(Itkr, 1), but differ float thaw. ;4 Hurt and Cohen
Plepts. %xf I fly the larlhM sit IL anti C.
-
,
,
il
froat
411 it
I
Fird
th
11
ith 1
1
M
1
l
.
.
e"
w
4
4
4
:
11CI
a
"
ral
'
I
U
xi
;
wl kv. 14.0 was 0.1.1rcl lIfy
..
i
ll, a Filh, In
11
ls livistril at
ovet Ill InAt_ anti [tic r4oilowt wi
l
0. Willi ktiFfing With ro S. 161tiLo. 1111OWN 10 Blind 3
days, anti treated with ice. then with dil. 11113, to
1-0-
Main. a littl-.- C11j:C.%1eCjCJ1r. 45% 1. bill 81
~-
,t
14M). and a o6mall amt. of a instatances, lit. M
whivis f*ffv,i its show the lwrwncv o( vithee Oil or CO 2 see
PARIS". and which stas aplvartntly m6talionly "junt
thrilltuditivollbyll'andC. I (49f.) wits treated with
Ilet iffneratrd fly healins cancli. IKI (withsAmt drying) structurv by It. and C. (we show). 1 (15 g,) and t5 it. ase
wit Insti t coi-lant; at fitst, I ICI was striarbcd with j At . Acj0 Wrest heated ein a stand bath 0 Ism., dild. with 11,0,
5*
t
t
7
i l
x9e
0-
I AM
gorlu
oU4 trivill. fi~. lbril lit
it V
oo and the or
lave still 2 IA r" fort4u,l (generally 21-311 min. Snifired. layer selmi.. ws,,hel, 41ri~l, and di%ld. in gJVV
- I
p
. h. 91-2V. d:
It.. Ird.-46.11 still un MAIIIII, Ilse upIArr,1 Only th. 1011~2
'
""", 0-94M
M' 11-1113M
a" 1 4
17117
-11w parns,
.
,
.
.
I. jy.,jV.,,,.y. ;
cc, fifitt 'hptsK, isti, LI Yield 711, sto,filt-I W04 obtained "twit 42 it, SIOAr In M) i--
Ar0IIL
l
.
-4 0 017. w"
wv1AY1,I-Aej4'.YAvt, Ill), film (11 2'. it', (1.9472, dl
liedt"ll oVVf 0,5 lit. with Ifirrills 101th 29
- 11 ,, -,s
i

still, -
I'M 18, and a ApAxi
1.111113. R ,tv. A
4: "
, Off, then fir4ird 4 lit$, In fxl*. 411141, 1 ,,, .",
l
A
t
7
ties
tile hirtiv.
, ti
Clie. b. "ri, Il
1
tioutralifiell with 111% Na8C 04. exist, wit It Rlo
A
--
1
,
t
turr it( It fly vigntimlinn "ve AeOll a
.'
141 "I" it* 1441cr C11111. was reliesitell ining AAAVA
.:t; we 0
I
"
'wid (41SAIV8141 a, Ilse Vil "It). it is
1151iii1fle same le'llit w" ol-fallIM, Not wittitte a it.
4
41111,11 11)
-Ann'Y-r structure was detect I.
G. M. Ko-AIAIMR ~ t*
--Itx!
a
o ;
X

0*0
OOC
LA4,4060MILtakovd *eta 110110-fA
~Cu 'U.
Mwrj?:1rA,Ar.A I "Mer ud 50 oc. AcOH *We
Wk lk . with 25 K. &fe'Caclat is 33 cc.
AcOR; amvs*dhis 6w 4 hn- At 60' Ae Rligt-
tZested irittl ivratcr. amtrilized by XSM sad
UM &
with Rw. Dl~patm a mixt. ff*m
6
prodam gum tid-
d,- - 0. 9,W.
0.0444.
b=at Iaa ow Pt black ga-
bw 'd: 0,97,61.
1.46M (hydrornation as
Abu"! ga- j:,,im0Ac); And
-b, 115 X10
-17', b. WS'. d.0 LOW, d.
IA3174 (owulation p- iqfteo, Ac0l,
and Ac0Ci;r#qoji, -hL'c hydrogenation as above Ka"
,prCll(oAc)Clt.OAc, which on hydrolysis by Air-
dit.11(3 yf4jW 6o-PrCOMt by a -COM-Y M-fe-
lf:KOAc is used in the above rtaction no UUGG
occurs at 60 hile Increased tem leads to it wcMiaty
raIction M ("annatiou o( CifetifeCIC11 bc%Wcs the
satmally egpected amtste. Substitutim of BW fur
A.0" givd, awy the normal subefitutiou t, the
acttyleuic aretatc. G. M. Col.-Upoff
d(CALLONVII, LIT91RATM CLAtWKAVKN
a a a a a
to
lee
W
Cos
000
$00
Coo
ZOO]
me*)
!Zotv
9300
CIO*
$*logo .31 o#v got
7_7_7- aw ow"t
U-N-Al .0 is q
to If w or a a x a Cis L I a ad 0 a a 'I V IN a a 4 3 6
0 0 0 0 0 00 0 0 * 000 0 0 0 0 lee of so so e 0 a 0 0 0 0 0 a Is * 00000
000000 00 9 0 0 000 0 0 0 'o ib0 011, V IN 0 0

.4; 9-4~~4-164*"A I il-j~ ilipWVP 2ili.-illpi!~-li~~~~~l,~i,;IFI--!~,~~91,12Lti-ilp.5;i I I~A Piz

11 1A
NO AP O #T0 cWts
As* Otafferiti

ktim almm MOW kydtKUwk gdd oil foulmethyf.
b
f
"
A
1
Z
kh

it e
.
.
A
.
rm
drova uW 1. U. Str(Offoam (t*nW-

t W-SAR.) 15, 433-411
14 (71
I.) was H at t . ter
brs. to *1d 94 e. undtUed dic which were se
d
~
..
p
by dista. gm we*#. Into Z.S-di ' ' 04.4- 00

-
ACTOdiraf ImrobaW). bw W7% 1.01 , w' " IIA&M.
' 00
x)
IAMD. and 2.S4iftdAj4-1,S4irA&v#44#xyw, bw
' '
4 400
W -2 % d: It AV, d16 1.00, a
IIAWW. 4
1.4M. The 0046
004 structutesl the dichiurldes are unly provWmaf. bemum
3*0
004 identu"6 meart, 4'L was only
- - - - =
fi
ll
a
y
The lat to met

Xe only a ght -caction with Na in
K-COo 201V:d
nee
MOO '
dait a ounit. of nkW. wbik hosting with Zo
in kYton
ll
t
h
d w

4W
gave a stua
amt. a
a
rocarbon which
y
was spganady C(:CMes)j. The 2nd oampd. failed to
give an 4
vachlble amt
1
of deb
l
t
d
d
i
h e*

`06
0 .
a
ogema
1
e
ucts w
t
1
pro
either No or Za in the cold; heming in the latter cm W we*
to demumn. G. U. KowkWff 400

~

w
0o

I IL A 1"'f&LLWMAL LITIENATIM41
s I a see
.
'

SIVIII
'va Irmo 41",4w

SOICSO 01&P all dig 4e4& I @a Orr M
a a 9 1 W a 9 A 4 3 4 T
U W
e at a am
0 114

'a
:LLIOO
- 0 00 0

AUTHORS-. zakharozA.__-1,1., Illina, G. D. 7c9_12-6A3
TITLE: The Synthesis of Rairified Triacetylene !~ydrocarborz fSintc-z razvet=
vlennykh triatsetilenovykh uglevodorodov).
II* Production of 4,4,7,7-'Tetrarnethyl-Decatrii-nc!-2,5,8 and 3,3,6,6-
Tatra-methyl-1,8-Diphenyl-octatriine-I.,4,o7 (II- Polucheniye b.4,7,7-
tetrametil-dekatriina- 2j5
s8j- J. 3.3,6,6-tetrarif--til-1,8-d.,Lfenil-
.
olctatriina-1.4,7) -
PERIODICAL: Zhurnal Obshchey Khimii, 1957, Vol. 27, Nr 12, pP. 3201-3203 (USSR).
ABSTRACT: In a previous work the authors proposed a method for the synthesis
of triacetylene hydrocarbons with a P-position of the triple bin=
dines, by means of the propargylation of magnesium bromalkine-1 with
the help of tertiary acetyleriedichlorides (R2 C Cl_CSC_Z CL R2)'
This way the first representative of the completely P-tri-nes aao, ob-
tained. In the present work the authors continue the investigation
of the synthesis and properties of ramified triacetylene with a p-
position of the triple bindings and describe the synthesis of two
new representatives of this class. By means of propargylation of the
magnpelum bronalkine with tertiary acetylene-dichloride the synthesis
of two new ramified diacetylene hydrocarbons of the following formum
Card 1/2 lae was then carried outs'

The Synthesis of Ramified Tri-2cotylone liydrocarbons. 79-12-6/43
II. Production of 4j,4.,7,7-Teti7amethyl-Decat~-iine-2,,5.,8 and 3,3,6,6-Tetra-rac-thy2-11,
8-Diphenyl-octatriine-1,4,7.
a) 4,4,7-tetraniethyl-decatriine-2,5j8; b) 3,3,6,6-tetrzirr,,~tl)yl.,.I,B.,
diphenyl-octatriine-1.4~7. The structure of theso hydrocarbons wa.9
proved by the fact that on the occasion of the ozonization acetiu
acid and corresponding dimethyl malonic acid formed.
There are 6 refarences, 3 of which are Slavic.
ASSOCIATION.' Leningrad Agricu-Itural Institute (Leningradskiy sell skoirlozyaystvenn
nyy institut).
SUBMITTED'. November 2o, 1956,
AVAILABLE: Library of Congress.
1. Triacetylene Hydrocarbons - Synthesis
Card 2/2

J f
thesis of franc e
ration of
0,9-dodecamyne.
-A.1- 7.Ahargini, G. D. 11' na. and G M, Mijra-,hov f - -1
zhur. 00111chef-
4'-W-Ta EtMgHr (from 25 g. Nlg)
was; addcd in 7, firs. 82 5. 21cXC-.CH lit EciO and aftee 3f;
hrs. at room temp., followed by rtflu--mg until C,lf. evolu-
Ition ceased, cc6ling, addn, of 2 g. CutClo und I g. HzCls
followed by 90jr. (iCCIAUXJ~- in EttO, allowing to 5tand3tj 0,
lirs. and rcflux~ag 4 firs. and hydrolyzed with dil. TIC] gavc
aftcr 2 di.itits,lou%
41TINIM, lia-'46 471,,1.4 037, 0, ta'p'
0.01, Rallialk ~Pzettutil~gtll.-' 2&RI),
1112(111 3), 1343 '11, I.IJ7(3).
2==Vx~o(51' 0. ~Iy'sis of this g:lvc
Nfc:C(CO, dertiGed as the Ag salts- Oxidati-tti of the.
I~ydroclrb' tv tit K.) In 0. faillxl to o ke Placc, II'Mrn'tim-
lion ow d- 'act give. the
doJecave, tit. 3'-S'. G. N1, K')

.4111, MR11(i Vit-wl--lwirvma i~,_WAKJJ)i
W
-7! -------- - -----
t,.eSynthesis
ration of 2.2,5,5.8 A. L
3 4.*
and
MF 71 C, -,A .
JJQ littfMI, f)y_
Aprorargylation-of acttylenir Grignard reagents b-V conifids.
7 -A,f the type R,,CClC.CR in the prmucc of 110, nit d Cu,C1j.
KOH'in 200 mt; firy HtO wa!
To IJA5 g~ pmv-d. q R([Afl With
.:70 9CAd stirring at 0, in 4 i1r3 0.5 tnote NIC,CC -CII, 0.5 mole
Afe,co, and ta till. dry UL , after stirring: Ili hr:s. the inixt;
.0
vv:ts trx-ated with lfO " ith coiling imd the org, fayer yielded
1fe,MC7C,,1je,()11. fill 6~1,*, thy 62" in. 34", rilg
1.42118. it" L42100, it" 1.1-30,57, H1,1, 1.91TH. Theak.
trcatzd jaL5_10_V. p(jrtiong with dry I(Cl widi civAing gave
95.5% Afeacc, CcAfei n, (1). 1~;# 72", izj? 1.43598, ffl,?
1,4,13*,1'-1 m1jVIA-12S5, nV 1.11511~1; [cf. lluch awl St4sve,
W
EtBr, and 2"W mt. Ct.0, rwas treated over 4 irs. with 4 1. g.
TtIejCC:CEl in 50 till. EtjO with vx)ling and after 8 hri. in
tile coid the inixy:. Nvas rauxod until Cith evolution ceased.
171te tooltd Grignard rca~rnt was Oita treated with I C. Cu,
CII and I g. I tg;Clj followed by 40 g. I added with coating;
after Stirring 3 d;4yS tile inixt. was treated with dil. JICI art4
the org. layer ifa I I dktd-7 Yieldijig _2 productv
C tl, bt--z -58*1 Q, MS25, dn 0.7M,
2,11% Cir,:CAfe(,,,C V1
nV, 1.41N51. !!',? 1.4310. nlv' 1.417CY1, a',,' 1,4561,
Stwattifir AMMO, WO.7(1), MIA(r)), MQ),
(1), M37.3(l)) t,ud SO% Afe;CC CCAfr, C.-* CCAfe,, hu 82*.
). nl,? 1A1169, fsi~
h, 74% in. 4CV, do 0,7413, 1-41735
N3 JR2vaan spectrum in molten state:
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at SiSG 2M, amt I A. 'NT. KosoLpoff

AUTHORSt Zakharora, A. I., Efros, A. M. SOV/701-28-12--17/41
TITLE: On the Probll.)m of the Cyano-.Ethylation of Acetylene- Glycols
t
(K voprosu -.-aianeti1iro-.raniy& atsetilenovykh Y.-gli -
oy)
PERIODICAL% 'Zhurnal ol;shohey khimiii, 1958 , Vol 28, Ur 12, pp 3243-3245
(USSR)
ABSTRACT% Recently Efros (Ref 2) investigated the oyano-athylation
xeaction in the sexies of benzimidazole in the presence of
triethyl-benoyl ammonium hydroxide. It was interesting to
use this catalyat also in the oyano-e-thylation of unsaturated
hydroxyl--containing compounds, especially of acetylene-
glyao-'a. The authors. tharefore, cyano-othylated the
tetrameth,yl Pad terraphenyl butynediol in the presence of
this catalyet. With. t-he former this reaction takes place
vexy easily on the addition of the double amount of
aGrylonirrile to the solution of glycol in dioxane under
the formation of heat and slight resinification. After 24
holixs stsinding at room temperatlire and pouring the reaction
mLctuxe into water urystals of tetramethyl butynediol ether
are separated, which have a melting.-point of 37-380 (yield 65%).
Card 1/3 The yield of the monocyano-ethyl ether of this glycol obtained

VIP
On the Problem of the Cyano.-Ethylation, of SOV/79-28-12-17/41
Aootyli%no -Glycola
under the same conditions amounted only to 8-10%. Thus the
above catalyst can also be used efficiently in the cyano-
ethylatj~,n of tetramethyl butynediol, as this reaction takes
place easier than that suggested by Nazarov and his cooperators
(Ref 1), and the final product does not need tedious purifica-
tion. The cyano-ethylation of tetraphenyl butynediol M
carried out in the same was as mentioned above also takes
place easily, but with a somewhat large excess of acrylo-
nitrile. The final product is the di-(p -eyano-ethyl)-ether
of tetraphenyl butynetiol. (11), (melting-point 179-1800). Its
yield amounted to 52.6%. From the reaction mass remaining
the mono-9 -cyano-ethyl ether of glycol (III) was obtained
(melting point 68-690) (yield 26-5%). Both of these ethers
had been unknown before. There are 2 Soviet references.
ASSOCIATION: Leningrad8kiy sel'skokhozysystvennyy institut (Leningrad
Agricultural Institute)
Card 2/3

/A
A 1A
PHASE I BOOK KUWITATION SOV/4583
Leningrad. Universitst
Voprosy teorii stroyeniya organicheskikh soyedinenly (Problems in the Theory of
the Structure of Organic Compounds) [Leningrad] 1960. 239 P. Errata slip
inserted. 3,725 copies printed.
Sponsoring Agency: Leningradskiy ordena Lenina Gosudarstvennyy universitet im.
A.A. Zhdanova.
Resp. Ed.% T.A. Favorskaya; Ed.s V.D. Piastro; Tech. Ed.s S.D. Vodolagina.
PURPOSEs This collection of articles is intended for chemists and organic
chemists.
COVERAGE: The collection is concerned with the scientific legacy of. A.Ye. Favorskiy..
and includes discussions of his theoretical views and their'e~blution in eon-
nection with the development of theoretical organic chemistry,, The articles re-
view problems on the structure# reactivity and tranaformations of various classes
of organic compounds: unsaturated acyclic and cyclic hydrocarbonsp saturated
and unsaturated alcoholsp glycols and carbonyl compounds. No personalities
are mentioned. References accompany each article.
40rd 1/3

Problems in the Theory of the Structu. SOV/4583
re (Cont.)
TABLE OF CONTENTSt
From the Editors 5
Danilov, S.N. Evolution of A.re. Favorskiy's Ideas on the Course of Chemical
Reactions and Present-Day Understanding of the Mechanisms of Favorskiy
Reactions 7
_LA Development of A.Ye. Favorskiy's Work on Syn-
thesis and Conversions of Acetylene Hydrocarbons and Their Halogen Derivatives 52
Domnin, N.A.., R.C 'h. Kolinskiy, and V.A. Cherkasova. Development of A.Ye.
Favorskiyfs Work,.-in the Field of Polymethylene Cycles 68
Lebedeva, A.I. Development of A.Ye. Favorskiy's Ideas on the Synthesis of
Terpenes and Related Compounds by the Soviet School of Chemists 126
Yanovskayap L.A.p and V.F. Kucherov. Role of A.Ye. Favorskiy's Research on
the Synthesis of Isoprenoid Compounds 135
__Gm*_74~

ACC NR, AR6035271 SOURCE CODE: UROJO161i-/6-i-/0-60-/-009/GO12/GO12
AUTHOR; Zakharov
TITLE: Some results of the study of the mechanism of earthquake foci in the
Tashkent region
SOURCE: Ref. zh. Geofizika, Abe. 9G70
REF SOURCE: Sb. Geol. stratigr. i seysmol. Uzbekistana. Tashkent, Nauka.
1966, 90-108
TOPIC TAGS: seismology, earthquake, seismic wave, earth crust
ABSTRACT: The mechanism of the focus of 11 earthquakes of the 9-14 intensity
scale, has been determined in the area around Tashkent. Displacement signs in
straight, head and refracted longitudinal waves were used for the above determina-
tion. In the case of nearby stations, the emission angles of seismic rays were
calculated according to a model of the structure of the Earth's crust in the area
around Tashkent. Errors in drawing of nodal lines did not exceed an average of
10-15 degrees along the azimuth. The directions of compression and decom-
pression. stresses for most of the foci investigated, form small angles with the
1/2
UDC: 550. 341. 4

NA, AR6035271
horizon. Moreover, the decompression stresses are found to be oriented
parallel, and the compression stresses, at a right angle to the Chatkala
Mountain range. Possible planes of the fault are characterized by a fairly steep
occurrence. Displacement shifts predominate in the north-eastern part of the
region in the foci (10 earthquakes). Shifts In the direction of the fall of the fault
planes have been'determined in the case of the foci of two earthquakes investigated
in the south-western part of the region. 4 Balakhina. (Translation of abstract]
JGCJ
SUB CODE:. 081
2

DANILOV, S.N., gJav. red.; ZAHHARDVA,_A.I.., red.; ARBUZOV, A.Ye.,
rcd,,; Va'U-Z;:-DA?IILGVA, E.D., red.;
10M, I.S., red,7 NAMMZITEVA. Ye.D., red.; LUTSMINYO,
I.F., red.; MI J-110iIENKC, , K.P.,'red.; NEMTSEV, M.S., red.;
PETRbV, A.A,j red.: FREYDIIIIA, R.Kh., rod.; SHINYAKIN,
M.M., red., SIICHUK~RMI, S.A., red.; YURIYEV, Yu.K., red.
(Problems of organic synthesial Problemy organichaskago
3inteza. Moskva,. Nauka, 1965. 323 p. (FIRA 18-.8)

BUTIN.F.SKAYA, Yo.M.-i 'Z~AKHAROIIA, A.I.; AT-ABAYEV, Kh.A.; FLENOV, Yu.P.
rZf:g,-'--Lt5 of the application of specific hodographs for the
i!o'4armination of the epicenters of some regio.ris in Central Asia.
",I.ul.')-)v, po seism. no.15:101-111 1630 (RIRA 17:4)

ZAKHAROVA, A.I.
Specific hodographs based on earthquake data for the Tashkent area
and the central Chatkal Range. Trudy Inst. mat. AN Uz. SSR no.25t
147-160 162. (KM 16t8)
(Tashkent region--Seismometry) (Chatkal Range-Saismometry)
L

S/1067/62//0C0/GC4/CG2/G-02
D207/1)303
Al 1 TI i 0.1 i Zakha-ova A.I.
'21TL:-;: Or, the recurrent shocks following t*-,, 3rich-
mulla earthquake on October 24, 1959
12E.I~IODICAL: ..~kademiya nau'k UzbAzkoy SSR. Izvestiy--. Seriya.
tekhnicheskikh nauk, no. 4, 1962, 77 - 81
A strontgr earthquake occurred at 23.40 hours GVI-I
or, Oc-.ober 2L) 1959, near the village of Drichmulla about 90 km
rorth-east of the city of Tashkent. The intensity c~f the earthquake
was I = 4 - 5 and its TaL-,ni.tude was X - 5-0.. Purther shocks were
recorded in the region of Brichmulla dur-ino the next 18 months. 'Nine
stronG shocks (1,11 > 3) were recorded from November 1959* to I-lay 1960
by the re-ional scismic-station network. ~n 11'ay 1960 new sen-,itive
stations were establizhed neax Brichfaulla and theze -tatiors record-
ed about 100 shocks of X > 3 up to October 1961. An analyr,-43 of 9
stroiig shocks and 20' weak ones is ~;iven. by the auzhor, the follow-
Card 1/2

S/167/62/000/"04/002/002
On the recurrent shocks D207/D3GS
inz items bein.- tabulated. date, tine of the shock at th~~ focus,
dis-~ance fron the earthquake conter, depth of tho focua, c-,,jer,~-j
class of the zhock ( K = I o where --2 is in Joules), 34-atiorLs
which recorded the shock. r2he area ovQr which these shocks occurrr'd
co'le-ls 350 -M2 includinj the Chatkalo-Zurarninskiye IlidCes, cons
inj of paleozoic rocks, and the '-Iazhkc-rLt-Golodrostopsl,