SCIENTIFIC ABSTRACT ZAKHARYEVSKIY, A. N. - ZAKHARZHEVSKAYA, M. N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001963610019-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 19, 2001
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

ZA19URIYEVSKIY-,, A.N.
L.Martin's book "Technical optics" [translated from the English).
Reviewed by A.Makharlevskii. Optbi spektr. 10 no.3:424,-425
Yx 161. (MMA 14:8)
(Optics) (Martin., L.)

IIKHARIYEVSKIY, A.N.; KUZNETSOVA, A.F.
Use of interference,=Lcroseopes in biology. TSitologiia 3 no.3:
245-253 My-Je '61. (MIRA 14:6)
1. Gosudarstvennyy optichesk.~y institut, Leningrad.
(INTERFEROHETRY) (MICROSCOPY)

7,MARIYEVSKIYP A.N.; KUZNETSC,VAo A.F.
Biological interference midroscopes. TSitologi-ia 3 no. 2,213-2Z~
Mr-Ap 161. NIFA 14..4)
1. Gosudarstvannyy opticheskiy institutp Leningrad.
(NICROSCOPE)

5011/51-6-5-26/34
24(4)
,WTFOR-3 Zakhar~ftvs.iciy. A.!,-. and Fedin, L-k.
TIM: Measurainent of Doublo Rofraction of Fibres (1=ereniya dvoynogo
lucheprelomleniya volokon)
PMTODML Optika I Spektraskopiya, 1~,,59, Vol 6, Nr 5, pp 701-703 (USSR)
ABSTIUM.- A iDolarization microncope suitable for measurement of double refraction
in fibre& is shown In Fig 1. 11. fibro F is placed in a suitible
inuarsion medium batmoon an objective Ob aa~ a condenser K. The other
parts of the microacope ares a polarizer P, An analysir A, an ocular Oc
and a 'Nollacton prisai 'It kplacod in the image plane). For 0.01-0.02 m
thick fibres the magnification Is 500 X. The system produces linear
interference tands at right-anglos to the fibre. A fibre displacos th-3
bands by an amountAY which is related to double refraction, definad as
the difference betwoon the refractive indices of volqrized rays
tnW - nL), by the follmving expression
a(n, n1)
17here a is the thickness of the fibre and A is the ravelength of tha
Card 1/3 light used. Fig 2 shows a microphotograph taken I n gree*n light

Measurement of Double Refraction of Fibres S OVI 5 1 - 6 - 5 -26/ 3 4
(546 MIL). The five fibres shown in Fig 2 tire: (1) caprone,
(2) "lavsan", (3) nitron, (4) cuprammonium rayon, (5) viscose rayon.
The strongest double refraction occurs in "lavsan" (fibre 2) and the
weakest (it is also of the opposite sign) in cuprammonium rayon (fibre
In order to measure &T precisely it is convenient to use a screw
micrometer with its hair-line in the image plane. For tMs purpose
the scheme of Fig tz a
, I is roplacod by one of the two varian- h ovin i n
Fig 3- two JVollaston prisms Yll and IN2 are used and the micrometer
hair-line is placed in the image plane q. This idea is due to
L.A. Fedin (authorlu certificate ?:.,'o. 60-1720/26 dated July 25, 19,58).
Doublo rofraction (iij, n.L) of a uniform fibre io now calculated from
RA
(nil - n.L) -_ , (7)
S ~f-z
where R is the area kruoasurod microphotometrically) bourx1ed by the
curved interforarico band in the fibro and tho original r,)ctilinear band
Card 2/3 ti

A casurement of Doubla Refrartion of Fi-res
Ill
(c.f. Fig 4, part A), S 2. 1
11 is the magnification of
area of the fibro. Thero
is German and I English.
SUBMITT-N; December 4, 1955
tho separation botv".n undisplaced bands ,
the m-Acroscope and 5 io the crooo-se~itional
aro -1 figuros and 2 roforenevs, I of vhi~~h
Ga rd 3/3

zAkItARf5my, B.
f~-'= (Maintenance and operation of Jet-propelled airplanes) Praktika tekhnicheskogo
obsluzhivaniia i ekspluatatsii reaktilrnykh samoletov.
Vestnik Ygafdohnom FlotA (9): 45-48p 191+7o

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- am" M - - % ', Y~I; NIKOLISKIT, B.P., prof., otv.red.;
YCHIN, D.P., kand.3chim.nauke otv.red.; SHCHEMMIYA, Ye.V., red.;
ZM OVA, Te.G., tekhn.red.
[Kinetics of chemical reactions] Kinetika khimichaskikh reaktaii.
Leningrad..Izd-vo Leningr.univ., 1959. 165 P. (KIRA 12:12)
1. Chlen-korrespondent AN SSER--(for Nikoliskiy).
(Chemijoal-reaction, Rate of)

5 (4) SOV/54-59-3-21/21
AUTHOR: Zakharlyevskiy, N. S.
TITLE: The State of t .he Theory of Heterogeneous Catalysis
PERIODICAL: Vealnik Leningradakogo universiteta. Seriya fiziki I khimil,
1959, Nr 3, pp 141-144 (USSR)
ABSTRACT: The present paper gives a survey on the present state of
catalysis. For somo time a tendency has been observed of
going over from homogeneous to heterogeneous catalysis as
the latter yields nuch purer products In contrast to homo-
geneous catalysis. Heterogeneous catalysis displaces also
the fermentative one because of the much simpler production
of the catalysis raw materials. The theory of heterogeneous
catalysis, which iii important for Industrial purposes and
production, is ati]Ll somewhat contradictory. In general,
it is assumed that catalysis is due to a formation of inter-
mediate compounds of a special nature (Boreakov, Refs 1, 2).
Roginakly observed a variation of the catalytic properties
by traces of gas, Robozey observed a difference in the oata-
lylic properties of single atoms and a monoatomic layer.
Roginakiy developed the theory of overeaturalion (Ref 3)
Card 1/3 and Balandin the multiplet theory (Refa 5, 6P 7, 8). The

BOV/54-59-3-21/21
The State of the Theory of Heterogeneous Catalysis
following phenomena were observed: a reaction of the atoms.
of the crystal surface with gaseous moleculeat a reaction of
an amorphous colloidal surface layer with gaseous molecules n,
a reaction of a surface solution (surface hydrides- and oxides)
with gaaeoUs molecules and finally, a reaction of single
atoms adsorbed on the surface with gaseous molecules.-Here-
from the existence of various regions of reaction is concluded:
1) The physical region in which a Van der Waals adeorptibn
takes place. Only little solid bonds form. Reaction energy
amounts to 1 kcal. 2) Region of chemisorption. i close aur-
face bond forms overcoming the energy bairrier. Activat Lon
energy is equal to that of ordinary chemical reactions.4
frozen activated complex is formed. Multiplet theory provides
explanation@ of the processes in this region. Excited states
develop (transition states)# but only in geometric and energy
agreement vith the reacting atoms and molecules. The value
axI+ so occurs In calculating the activation energy which do-
p6nds only on the catalyst. Roginakiy's theory of overeatura-
tion is especially taken into account. Were are various con-
Card 2/3 cepts on the nat'ure of the surface. (1) existence of an energe-

SOV/54-59-3-21/21
The State of the Theory of Heterogeneous Catalysis
tically uniform surface (Boreakov). Phenomena of surface con-
tamination are in contradiction with this concept.(2) existence
of active cent 'era. The third region comprises the boundary
case of chemiaorption. Single atoms or radicals form due to
the tearing of bonds In the adsorbed bound molecule. Balandin's
multiplet theory and Roginskiy's and Vollkenshteyn's electron
theory (Refs 9, 10, 11, 12) may be well applied to this re-
gion, as well as the theory developed by Semenov and Voyevodskiy
as regards radical formation. The fourth mentioned region Is
the plateau, in which spatial phases are formed between cala-
lyst and gaseous molecule. This field does not participate
in catalysis. There are 1 figure and 21 referenoeBp 20 of
which are Soviet.
SUBMITTED: may 15, 1958
Card 3/3

PALICHEVSKIYJ, V.V.; Z-AKHARIYEVSKIY, M.S.; KALIVARSKAYA$ T.M,
Methylorange absorption spectra in concentrated salt solutions.
Vest. LGU 17 no.16:125-330 162. (MIM 15:9)
(Methyl orange-Spectra)

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