SCIENTIFIC ABSTRACT ZALKIND, IN.S. - ZALMANOVICH, M.Z.

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Document Number (FOIA) /ESDN (CREST): 
CIA-RDP86-00513R001963710010-3
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RIF
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S
Document Page Count: 
100
Document Creation Date: 
November 2, 2016
Document Release Date: 
September 19, 2001
Sequence Number: 
10
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Publication Date: 
December 31, 1967
Content Type: 
SCIENTIFIC ABSTRACT
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ZALIKIND, In. S. Zal 'kind, In. S. and lreiwdze, N., On the addition of hydrogen to ocety2ene derivativos. MIX. The catalytic hydrogenation of the glycole of the diacetylene series. P. 1551, Mathyl-n-toliWl-acetylenyl carbinol was synthesized and from it diacetylene glycole-2, 7-di-n--toluYl-3, 5-octadiene-2, 7-diole were obtained. It is estab-lished that during catalirtic hydrogenation this diacetylene glycole behaves analogous to thc -rglycols of the acetylene series. The Stalin Lal-.. of Organic Chem. 7~f the Tbilisi State Llnivenc;ity. September 16, 1941 SO: Journal of General Chemistry (USSR) 1~,, (8o) No. 8 (1948) Is lot 601,11 POP 0 0.- C 0 p p v P~ I I -U I L 1 -1 AA 0 us f-- -9 . I .-I - - 60 004 1 71 00 00 00 Addition of hyttioglin to acetylene dellwativee. XXXIX. 00 a CatAlItli: urice. A I Cutil 1, Ittlussur. z up. Mils, kil Khipm. 18. 1534 P(WISI: c(. C-1. 43~ 1-00 11). Ill. 00 00 YlCarbitlisl (11) 011 CU,Clt. 11, Ill. 121-2', sim, vvih- ltited by pu.ing dry C,11, thruugh 57, g, politd. KOII in LNN) W. dry MOO, ct"cd to sibutit -10". aliff [I'Ming Giropwise. 11%rr 3 It"-, 1').S X. p-%trC.l1.C0,W its 3 V,41. 0 13 Py;-1. VIC 111tv 4 1-f 1. 0.1kIA mish- lit.74 I mi, 00 1:110 Ill$ milisiJil I'll (rharacirfigril fly v-11114vir 1101- 00 grilAtioll 'Wr (I,tpt Im )IV ill ~'Al lilt, 0 1.3011, 'A ith Is We. I'll. ill ~12 U1111.) iIICFV~WS is ith tIlV atilt. of I'd; thut the times in tuin.. uccrtsaty to add A). W. 00 Anif 1001.1 4 the final 1 If, vivirc, imith 4 nix. Psi, 11'.. ZU1. go* > .51; with 0 tug., 11, 21.42; %ith 8 stig,, M. 14,27; nith ::9 0 12 mg., 4, 8, 26; with 15 nig,, 3. 0,5. 12 miss, Th., prskluct Is 2.7-di-4. pt,iefic.illy 4o .... .... bVillm I" v.,IAyA, tht Pl black. 8 11 attitm we addo, rcstilting ill ditsilyl-2.7- 0 riots CL ASSit ICATICIS A .1i lAt tbf:i All. GO: V1 1-11 i ZW n I nj a -4 1 ill Of c' It OF U Is A, so 1, :t .6 ill R a CT rt 'jL0 ts 1 .4 ~ * Goo o 0 (b 0 0 00 4 f 0 iTq: : : : 0 :l* * 0 0 6,80 - -- 66 0 4D : : : : :P -WW/bha*i*try - Ac*tylWlb,- Avg Derivatives Chemistry -'Elynthesia "fte Addition of Hydrogen to Acetylene Doriva- lytic rqdrbgeWatian or Di - w4ools'" 'TU* W, Xr--=dza, lab Org Chemp ThUisi. State U hiani 1. V. atalin, 51 Pp Shur Obabzh nlynil" Vol Xnrr (L=)., So 8 mathyl-n-toL3rl-ArAtylen7l-eaxbiwI aid frca It the dlacetYlena-glycol 2,7-di-n- tOjY1-3,5-aatadiin-2,7-diol- Shove that duzqAg oatal~,tic b7ftosanation this diacetylexe glyea 3.9/49T23 VM/Chazi stry Acetylene$ Aug Derivatives (06nta behaves simi3jwly to Ole ed acetyle,", eariae. In ]presence of palledium it adcls'fovw latme of hydrogen vith conrersim of triple to double ban". With platinum, the raaatl6n pro* Ceeds szoothly until eight hydrogen atoms axe added and. simple bonds forned,-Notes that &I.- j190neTiMee achol solution vith a drop of h7drechloric acid. Research continues. Submitted 3.6 sep'417. :LqAM 3 W-4 it X, , .12 N I b is A N W ~V A.- A-7 V go CC W i I 4;T Ad&(&W of kydmgta k, t4allyletak CMFMdf. XL. t4 the niono-lin ether with A ing. I'd iiiiii,;4,17441i '71 T~ 3 *0 a!- CaWy* hyd-l- of ill rjLq,. Z12A trit. Ill 14) min.. while 0.11175 g. I't cau" IM Vu. S. 7AI'lund Still I. K *e:1. If tobe field ins Mile,, twob 7 fljlrp~ frillifted flit WMA, kief Kkifmi. (I. Gen: Chein.) 11', M354VISKS); Cf- C.A. 4J, 2H =4 fe,C(OlJ)(*.j COlegnif ethers (01104711:1,, h. 1911-1 ". dl.0 0.8475, mif 00.. (it AO 41111111 di-Hu. -nil 0101141-lits) W`cmis OM uwt Pit (OBOCII.Ju b. tOO-291) . it:: 0XV7, Sir LCT217. Mach) faster thAn site irrortion with the glycol itwIl (of M"C(Ofla)Clfl:CJJ('(UJJ)Mr,, b. 217-1111, d!: 0: 11, the pli-W.FlAro (1). Alld illipater faw di-Om rIAM (1111). 1. OW 1.4--.4%, and MrC(Ofiw) CJ1,CJJgc(OJ,Jk Ales. It. "Oelle 04 prefid. --coliding to lillt4ittlov it 4 .;1 1. Ut the firil =1-6% Jil 0.147-03, XV ]AZU41P, (it ih StAtOl that the S stirred 24 his. with -30 lot, hteoll Stitt 4 Mi. let Produces may Croft be COMPICtely AS WlY WnAJI &Mi*. '00 -~ %% *1,1. b. I (R-W. 4. OJ*579. mi? 1.42r, 7 (Purified by atte dealt witti, and close (pWj=IM was ise