SCIENTIFIC ABSTRACT ZELENSKAYA, M.G. - ZELENSKIY, A.I.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001964230007-9
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• Document Creation Date: November 2, 2016
• Document Release Date: March 15, 2001
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Investigations in the Field of Lactonan and Laotameas 62-11-24/29
6.Report.PzOVbx&tjon of Pb3YTVWjt=jjAbj~e vith Protnoted Action.
oolution has highor advantageB than suoh"in a blook"i 1) T~Iiia
procaaa taken plaue at relatively lowur tofal)-arature, 2) the
product output becomes higher, 3) the polymeride doveloping is
colourle93 and has no odour. In the physiological experiments
at the 1. Moscow Institute for Ledicine (reference 3) it was
ascertained that the samples with a rolative viscosity of -a 3~
aquooua solution of 3-7 to 4-0 are the most ofi!uctive as "pru-
longator". The best sample showed a relative viscosity of 3,74,
an osraotic pressure of. 27o moi water coluian and an average molar
weigth 0f--450 ooo. There are 1 table, 3 refererices,l of which is
Slavic.
ASSUC1,01ON-t-1n-stitute for Crganic Chuiniatrj imeni 11.1).Zeliziskiy of the AN
U~21R--~-Inri.titut organicheakoy khimii iiii.N. D. Zalinakotero Akadeuiii
nauk
SUBMITTED t June 2ij 1957
AVAILABLE: Library of Congress..
..Card 2/2

AUTHORSs Shostakovay, K.F., Sid'ell1r:ovskaya, F.F., 62-12-5/20
Zelenakaya, X.G.
TITLE; Investigations Carried out in the Fields of Lactones and Laotams
(Issledovaniye v oblasti laktonov i lalctamov). Information 9. The
Synthesis of the Vinyllaotama and Some of Their Properties
(Soobshohaniye 9. Sintez vinillaktmov i ikh nekoto*-ye ovoyntva).
FMIODICAL- Izvestiya All SSSR Otdelen4e Xhimicheakikh Nauk, 1957, Nr 12,
pp. 1457-1464 (USSR)
ABSTRACT: In publications dealing with chemical problem much attention has re-
cently been paid to the synthesis and polymerization of nitrogen-con-
taining vinyl compounds, Among these methods, there is the reaction
of ftrect vinylization suggested by Favorskiy and Shostakovskiy,
-.,&ich was carried out vrith alcohols and phenols. Further working out
of this reaction made it possible to synthesize a nunber of valuable
preparations. The authors gave a report about the vinylization of
lactams by using pyrrolidone, piperidone and capro-lactam as exam-
ples. The catalyzers of vinylization are alkaline salts of laotams.
It was shown that the most simple method of preparing the salts is
Card 1/2 the direct interaction between lactams and alkaline metals. It ivas

Investigations Carried out in the Fields of Lactones and 62-12--5/20
Lactams. Information 9. The Synthesis of the Vinyllactaw
and Some of Their Properties
further shown that vinylperidone as well as other vinyl lactams
must be hydrolyzed in an aoid medium. Optimwn conditions of hydro-
lysis viere found. The polymerization of vinyl lactwra vma carried
out under the influence of dinitryl of azoiso-butyric acid as well
as under the influence of H202 in an aqueous solation. The authora
then describe a simultaneous Polymerization of Vhe vinyl peridone
with the methyl cater of metbaorylioaoi~. There exe 7 tables, and
17 references# 11 of which are,Slavio.
ASSOCIATICTT: Institute for Organic Chemistry AN USSR imeni N.D.Zelinskiy
Institut organioheakoy k-himii im. IT.D.Zelinskogo Akademii nauk
SSSR).
SUBMITTED:
AVkIIM4Et
Card 2,12
July 3P 1956
Library of Congress
1. Lactones-Vinylization 20 Lactams-Vinylization 3. Alcohols
40 Phenols 5. Pyrrolidone
-77777177F77;~~

SIDELIKOVSKAYA, F.P.; Zl-,*JM-,SKAYA, 1-11PAYM A, I.N. j, W1110I.-YrAr.0roKlY, X.F.
lactones and lactams. Report Ilo.24.' Reactivity of p~rrrolidony-
lethyl eaters of acrylic acids. Izv. 21 SSSR Ser. khIm. no.11:
2061-2063 IT 164 (MUM 18:1)
1'. Institut organicheakoy khimii im. N.D. Zelinakogo AN SSSR.

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i~-- 1. - - .. 1-1.

SID-ELIKMSKAYA# F.,P.; ZELENSKAYAp M*0,1; SHOSTAKOVSKIYI -M.F.;_IoOPATIfl,-B.V&-

3499j-
S1190V621004100310111023
B I I Olf~B 144
IT. 2 0
AUTHORS: Sidellkovskaya, F. P., Zelenskaya, M. G. , ShostaRovskiy, M. F. ,
Lopatinp B. V.
TiTLE: New acrylic and mathacrylic acid caters
PERIODICAL: Vysokomolekulyarnyye ooyedinaniya,v- 4, no. 3, 1962, 389-392
TEXT: A synthesis of a,p-unsaturated esters with lactam rings
0
CH.= CdCOCHCH,,N (CHWD; -CHI=C- HCH2N (CH2JO
~~CH3
was developed to produce ne w monomers and polymers and to study the effect
of the lactam ring on the acrylic ester double bond.and on polymer
properties. The lactam ring is introduced into saturated esters by the
action of IT-(P-hydroxyethyl)-pyrrolidone (P) ozi fatty acids or their acid
chlorides. Esterification ofacrylic and methacrylic acid (AA, IMA) with P
is more difficult than that of saturated acids. AA and MA chlorides and P
form esters with 55 % yields (optimum conditionsi 1.5 lhrs, 700c, CHC13
Card 1/2

S/190/62/004/003/011/'023
N e acrylic and methaarylic acid esters B1 10-11,114
and CCl- as solvents, soda (or ITH ) to bind HC1) and sometimes additional
4 3
of hl.gh-boil
,imall amount,,3 ing producta of unknown titruature. Tho (n3toril I
and Il are rnobile liquida oolublo in water, othanol, methariol, aaijton-~' and
benzene, saponifiable in alkali, insoluble in ether and petroleum ether.
They polymerize at 400C, but withatand long-time storage at room temperature.
IR spectra taken with an WKC-14 (IKS-14) SDectrophotometer (NaCl prism)
showed two carbonyl grouDs and one =CH double..bond. Solid polymers
2
insoluble in organic substances and water, are obtained with azoisobut-ric
acid dinitrile. 'With benzoyl peroxide, only polymers from I insoluble in
organic substances and watercould be produced within 12 hrs at 80-820C.
There are 1 figure, 1 tablef.and 4 references: I Soviet and 3 non-Soviet.
The most important reference to English-languagre publicatioza reaes ,
ts
follows: G. 11. Stempel ot al. J. Amer. Chem. Soc., 72, 2299, 1950.
ASSOCIATION: Institut organicheskoy khimii AN SSSR im. N. D. ZL-linskoco
(Institute of Organic Chemistry AS USSR imeni 14. D. Zelinskiy)
SUBA4ITTED: February 23, 1961
Card 2/2
V

31192
3/079/61/031/012/011/011
1)204/D301
AUTHORS: Sidellkovskaya, F* P,j Zelenskayat M. Goo and Shosta-
kovskiy, M. P.
TITLEs The preparation of acrylone and methacrylone pyrro-
lidones
PERIODICAL: Zhurnal obshchey khimii, v. 31, no. '12, 19619 4060
4061
TEXT: The work was carried out in view of the recent interest in
the amides of acrylic and methaorylic aoids as potential starting
materials for the synthesis of new polymers. 0H2 CH.OON(CH2) 00
31
CH3
(I) and CH = C.CON(CH ) CO (II) were prepared in 20 and 40% yields
2
respectively by_the -action of the appropriate acid chlorides on Na
pyrrolidone at 100 >-150C. Propyl gallate was used as an inhibitor
and structures of the products were confirmed by infrared spectro-
scopy. Acrylone pyrrolidone (I) polymerizes very readily, forming a
Card 1/2

.33-192
B/079/61/031/012/011/011
The preparation of acrylone D204/D301
hard polymer, insoluble in water or ornnic solvents, during its
prepareCtion and distillation. Monomer II) polymerizes in 20% yield
on heating for 30 hours at 600C, in the presence of 5% azo-iso-
butyric dinitrileg to form a white powder (m.p.--2700C) soluble in
dimethyl formamide. Properties.of the. above two monomers and the
preparation of acrylone and methycrylone lactrams based on piperi-
done and caprolactam are now being investigated.
ASSOCIATION: Institut organicheakoy khimii imeni No Do Zelinakogo,
Akademii nauk SSSR (Institute of Organic Chemistry im.
N. Do Zelinskiy, Academy of Sciences USSR)
SUBMITTED: July 10, 1961
Card 2/2 40

~- - -.. . Ic ~~* ~'] -.
=1 - - --- Il'l 04111W,1~16~11~~ I.. I . .1 .

5-3610.5-3100 77ce2
SOVA2_59-2~-26/43
AUTHORS: Shorysin, P. P., ShkUrIna, T. N., 5ho3'&kovBkiy, X. P.,
Sidal4kovskayal Pa P., Zeler.-Akaya. K. a.
Spectroscopic InveattgatLon or T71z=taras and

PERIDDICALz Izvestiya Akadevall h*uic SSSR. Otdclenlye SchLticheakitzh
2
naulc 1959, Nr 12. pp, 22OB-2-11 (USSR)

AMTRACT:
anilide3 were studied. and
Spectra or N-vinyllactams and
s
the ""tual Influence of- Zr-oup was Investigated. Vinyl-
lactam3 contain Me 10t," C==C--q-C=-O; the exa=lnatlon
of the Int r ctlon of atome and groups tan be simplified,
to the by considering the effect or
the N-atovi on C=C and C=:=0 bonds, as well as the rrutul
interaction or the double bonds. Ra=-n and UV-*Pectra
of vinylpyrrolidone. vUylpiperldone. vinyloaprolactan,
or Irarlous Antlidea (rorma-1111de, acetanilide, etc.).
and or alaplar =Iecules containing an N-atom and a
carbonyl group (Pyrralldzne, N-butyllpyrrolidone.
Cord 1/~ caprolactan, dime thylaceza=1da were taimn.
Spectrogrg
~ph
,

ISP-51 and PRK nercury lar;) were used to obtain RarAn
spectra. and 3pectrograpn SP-4 to obtain UV-spectra.
Spectra of VLnyllacta.=3 Im the double bonds region
Showed, lines choracterintic for ~=C and C=O bonds.
It waS Csun4 that the presence Of the H-atom at the
double bond in.'Juenced conalderably --ha spectral
characteristLcsi: tne freq=ency of the C-_O tord was
lowered nearly AS tr=h 83 in molecules cantaIninz
bonds. Values of the ext--ctiin -COarfl-Clent
Or C.--O bond line = Tinylpiperldw=
lactan were quite high. AL-2d Close to those or
The -intensity or Q=C~11_-,e of vinylpy-rolidone wus
substantially ftlghcr~ amd that of C=:=0 line In all
three vinyllacta=3 was =rzy ti=3 than in ccm~
POundz with > IF- ^-'D bcads, This a==Iy In the
intensity or the 0--4% bccd in Ramin spectrum was the
most peculiar el-Aracter.!AZIC or V:JV11ActA=3 which
distinguished tl%wn fr-= w2ocules utrz C=C-N-C and
>11--C-0 bonds. It can be explalnel- by the influence
Of tho
C--C bond, through the N-ato=. an the cart~onyl
Card 2/3 group In the bond 3y3t*= f--C-b1--==O). Sirdlar
(
erv;'
relationships were also ob's d anilide spectra.
it was noted that %~*,ft allillstion of N In anilides
weakened the indications or conjugation of N with the
benzene ring, arA strengthened th~ or conjugation
with the carbonyl SrouP. It can t4 sam=ed' therefore.
that a C6SNRCO" "'*"as 1.... rr~ coplanarity of the
"Y"t"" C6N.N-C and the system C~_ );-COX becomes rAro
planar. There are -3 tables; 1 rigurt, and 6 references,
I u.s.. I U.K., 1 3 Soviet. The U.S. and U.K
;
-
references are R. E. Braude. E. Xoneai, J. Chtl
194,6, 948; Z. Corey. J. A=er. Cnam. Soc., 75. 2301
Soc.
(295
i)
ASSOCIATION, kly Lnstitute of Org&*1!c Chemistry, Academy
N. D. Zelin
a 3clanots USSR (Zrat_'tut organIc!,,eSkOY khlMli !=ant
'
:
sssa)
r nauw
H. D. Zelin3kc~go Akad~--
SUBKITTEDi April 7, 195d
card 3/1

r7,

4
N

M~V4.
.
.%.LZt Investigation in the Pielt of La*tonea and 7.acts-
1841 slovenly. v ohlao ti I "k teen, I Itn~- I z; %. 3 ft
15. p"p-ration. of
=olecxamr Wa%E:hts and Their
"
ana
(Soobehafteniya 15. Preparety polivinilui--rcl.
0*1ek~,IyarnaZo *an I ikh
PMCDZ=l 11M.Stile. Lked4iii rtAuk ZSSR. OT191 niya "LIM-c~Mu%~-:14
1959. 3r 5. vp DIC-900 ('J.13:1)

MAC-,
s,
A
Block polymeri.Atlo f vinylpyrrolldons =d.r -Zfiot
of asoLaoll.to actd. ax.'
sn' of,dinitril
of ~PZ
~
in aqueous solutions (Refs 3. 5) had been nt Oh,~
Institute zentionO Under %.XociatiDa. :A c=%actz= 'rith it
the phplIco-chtaical Vroparttea of vri."
(?V?) .*re IavestiC-ted- " Vr~- wer'.
because theme properties Are very tz"riteaz far thm,
investigation or the bi*l~ZtO activity
t~~X' jan Us obtained to
they .%hjhLt alight deviations fr.,, tn-lr ~h~.-
chemical ch~tarlvticm. (Table
haract.riatics of (P") *a1utions.as pro4-4tx -4ous
co=t-.12s). The volyzeri*stion conAitions 'or '-,*a
slueous solutions In the presence of 30 f SiO2 aza -.%ft
c.s-a.s A concentrations at this initiator am x*===A.%*4 In
table 2. The characteristics of *&It water *zl=z1.=a 1e (M)
bgLse used ma a plasmasub2tituto tro shasm, La t*bzr '~-. R*24tive
viscosity# ammotic pr*uxuret and the maloc%&Z~ of the
varleav preparations were daterntned. A Z;T the
charsateriatica shove th%t those or CPVP) V7v eff-- ve"00%1"
th" those of the plemacoubst4tuto. $A ;t ~202 hat zz be used
initiator In order %a obt~tn A~ highjj-~ w,'fectl" r47nsr.
The determination of tbo ol.cul.r
Levee tieAtion or the tr xaverm~'
showol that the block polynerm have a hign- d'L~p -of
card Z1, rolydisporeity than those obtained 1.

tw exit vtt*~
a mteth*d for,obtainlnj biolcgla4lly "tt" 3tzx~
*&IuU na of the,preF~,rations "3 been =%art are
i
Pso::.' I tables, %,.I " references. 12 f ~.ro
2 ,
Soviet.
AS3GC-'=CU. Institut or quiclioeko7 khtxtt in. i. U. ZAZ!=kzrz Arad*-ait
a,- 3MR (Institute of Ors'nic Monimtry Iven!
z.II"19t7 of the toni.-V of 3.itaa..' t342)

SUBIC--
:-Ir Ill. 1937

7MT,
mm IEEVRW
rives tigat ione of,lactones and lactasso. Report No.13.*Alkoxyotbyl-
idenspyrroltdones. lzv.AN SSSR-Otd.khim.nauk no P516-52o
Mr 159. iMIRA 12:5)
7 khimii im. Aellnskogo AN SSSR-
I Institut organicheakc N.D
(Pftrolldinone)

50)
AUTHORS: Shostakovskiyl M. F., Sidellkovskaya, SOV/62-59-4-29/42
F. P., Zelenskaya9 M. G.
TITLE: Reaction of Propylene Oxide With a-Pyrrolidone (Reaktsiya okisi
propilena s a-pirrolidonom)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 4, Pp 738-740 (USSR)
ABSTRACT: Thin in a briof report on the invontigation of tho reaction
of a-pyrrolidono with propylono oxida. In thin once the oxido
ring opens in a way no that a secondary alcohol is formed:
C H FH C_H___+Iimco(CH CH CH(OH)CH iCO(CH 2)
3 2 2 3 3 2 3
The, structure of-the N-(p-oxypropyl~4-pyrrolidone obtained
was proved by the synthesis of yrbutyrolactone and amino-
isopropariol. The aminoisopropanol required was obtained from
ammonia and propylene oxide (Ref 3)- upon interaction of
IT-(P-oxypropyl)od-pyrrolidone with thionyl chloride the
hydroxyl group was substituted by chlorine and
If-(P-chloropropyl) *pyrrolidone obtained. Upon heating with
Card 1/2 nqivioun alkali thij ohloride it, hydrolyzod (Tablo)l

Reaction of Propylene Oxide With a-Pyrrolidone SOV/62-59-4-29/42
although, more slowly than the N-(chloramethyl),*pyrrolidone
obtained earlier (Ref,4) which saponifies quantitatively at
room temperature evd,n in the absence of.alkali. Upon heating
of K-(P-chloropropyl) *pyrrolidone with caustic potash in
benzene solution, 1ICl was separated and N-(propenyl)(4-pyrroli-
done formed. The position of the double bond was determined
by spectroscopy. This investigation was carried out by
T.-N. Shkurina. There are I table and 6 references, 3 of
which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogc Akademii
nauk SSSR.(Inatitute of Organic Chemistry imeni ff. D. Zelinskiy
of the Academy of Sciences, USSR)
SUBMITTED: July 24, 1956
.Card 2/2

50)
AUTRORSs Sidelikovokayap F. P.1, Zelenskaya, M. G., SOV/62-59-5-21/40
Shostakovskiy, M. F.
TITLEs Invostigation In tho Viold of Laotones and Laotamos
(Iaisledavaniye Y.ablasti,laktonov i laktamov).
Report 16. N-Methylol-laotames (Soobahchenive 16.
N-Metilollaktamy)
PERIODICALt Izvestiya Akademii nauk SSSR.,Otdeleniye khimicheskikh nauk,
1959, Nr 5, PP 901-903 (USSR)
ABSTRACT: In this paper the synthesis of N-methylol-lactames of the
following structure was investigatedt Methylol pyrrolidone M
CH CONCH OR and N-methylol caprolaotame (II) CH CONCH On,
2)3 2 2)5 2
and some of their properties were detormined. The authors of
the present paper showed in a previous one that in the case
of an action of a 30 % formaldehyde solution upon pyrrolidone
and caprolaotame the following is produced in an alkali
medium with a yield of 70 90 % (1) and (II)t
OH- I i
Card V2 ~(CH 2). Coh + CH20 '(CH 2)n 'O'CH20' (Ref 3).

Investigation in the Field of Lactones and Lactames SOV162-59-5-21140
Report 16. H-Methylol-lactames
This scheme is to be proved. For this purpose, the reaction
of these compounds with thionylahloride
ORCH 2'4
(01~12)6 +SOC12 ClCH 2rCO(CH2 )~n + Hol + SO2
L
was investigated, and the compounds N-chloromethyl
pyrrolidine and N-(hlorQmethyl oaprolactame were obtained
with a yield of 60 %. The chlorina content of thona
oompounda wan datermined by titration according to the
method developed by Volhardt (table)f and it wao shown that
the chlorine atom in these oompoundo is easily saponified.
Both synthesis and investigation are described separately
in the experimental. There are 1 table and 6 referencesi
2 of which are Soviet.
ASSOCIATIONs Inetitut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of Sciences, USSR)
SUBMITTEDs July 26, 1957
Card 2/2

SIDBLIOVSTAYA, TiP.; ZELENMYA. No SHDSTAEDVSKIr, X.FS
lacton6s and lactams. Report No.12,- Vinyl Other of
~-( /3-oxyethyl)pyrrolidinone. AN SSSR,,Otd. khim. nauk no.9:1111-1118
S. 158o (NIRA 11:10)
1*lnetitut organicheakoy khimil iment. N.Ds Zelinskoge AN SSSR.
(P~rrolidinone)

_50)
AUTRORS: Shostakovskiy, M. F., Sidellkovskaya, SOV162-59-3-20137
F. P.,-Ze_lenskaya, 1A. G.

TITLE- Investigation in-the Pield of Lactones and Lactams (IsBle-
dovaniye v oblasti. laktonov i laktamov). Communication 13.
Alkoxyethylidene-pyrrolidoneB (Soobahcheniye 13. Alkoksi-
etilidenpirrolidony)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
19599 Nr 37 pp 516-520 (USSR)
ABSTRACT: In order to obtain vinylpyrrolidone, in the present paper
alkoxyethylidene-pyrrolidones were synthesized and their ther-
mal decomposition investigated. Several methods of synthesis
were applied: The interaction of vinylalkylethers with
pyrrolidone, the reaction of vinylpyrrolidone with alcohol
and the reaction of the u-chloroethylalkyletlier with pyrrolido-
ne. The beat results were obtained in the maction of pyrroli-
done with a-chloroethylalkylether. The character and the yield
of the resulting producto chiefly depend on the reaction con-
ditiono2 eupecially on temperature and Initial compononto
(Table), A lower temperature and oxoenn pyrrolidone favor
Card 1/3 the formation of pyrrolidone hydrochloride (Experiments 1,3,4).

Investigation in the Pield of Lactone.! and Lactams. SOY/62-59-3-20/37
Communication.15. Alkoxyethylidene-ryj?-rolidorir-v,
Card 2/3
An increase in temperature up to 850 providon a good yield of
ethylidene-bis-N-NI-pyrrolidone (Experiments 6sio). Experi-
ment 2 shows optimum conditions for the formation of butoxy-
ethylidene pyrrolidone and experiment 9 for the formation of
isopropoxyethylidene pyrrolidone. The most comfortable method
of synthesis of alkoxy-ethylidene pyrrolidonen as well as of
alkoxyethylidene caprolactams is the interaction of u-chloro-
ethylalkylethers with lactamS. This reaction,--ho'ytever, exhi-
bits a number of peculiar features for pyrrolidone. The yield
of alkoxyethylidene pyrrolidones,,for instance, is small,
further, in addition to them ethylidene-bis-11-NI-pyrrolidone
is always formed. Certain differences may be observed also on
the thermal decomposition of these two compounds. On thermal
decomposition of alkoxyethylidene c--prolactams viny1caprolactam
in obtained in high yield (70-80 ~)- On the other hand it is
not alwaya potinible to obtain vinylpyrrolidono on decompoijition
of alkoxyethylidene pyrrolidones. On decomposition of butoxy-
ethylidene pyrrolidone vinylpyrrolidone in a -40 % yield and
butanol were obtained. On decomposition of iscpsropoxyethylidene-
pyrrolidone iBopropyl alcohol, pyrrolidone, and ethylidene-

Investigation in the Field of Lactones and Lactans. sov/62-59-3-20/37
Communication 13. Alkoxyethylidene-pyrrolidones
-bis-U-NI-pyrrolidone were separated. The thermal decomposi-
tion of ethylidene-bis-N-NI-pyrrolidone takes place at con-
siderably higher temperature than the decomposition of
alkoxyethylidene lac'tams. As result.of this decomposition
pyrrolidone and a resinous residue were separated. There are
I table and,8 references, 5 of which are Soviet.
ASSOCIATION: In3titut organicheakoy khimii im. V. D. Zelinnkogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelin-
skiy of the Academy of Sciences, USSR)
SU13MITTED: June 21, 1957
Card 3/3

AUTHORS: Sidellkovskaya, F. F., Zelenskaya, 11. G., SOV/0-2-,a8-9-1:z/26
Shostakovokiy, M. P.
TITLE: Studies inthe Field of Lactones and Lactams (Issledovaniye
v oblasti. laktonov i lsktamov) Communication-12: Vinyl
Ether of N-(P-Oxyethyl)Pyrrolidone (Soobshcheniye 12.
Vinilovyy efir N-(P-ok!3ietil)pirrolidona)
~PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimricheskikh nauk,
1958~ Nr 9, pp 1111-- 1118 (LISSR)
ABSTRACT: During the last year various nitrogen-containing vinyl
compounds with remarkable properties were synthesized.
The authors of this paper attempted to prepare the
vinyl ether of N-(P-oxyethyl) lactam in order to study
its properties and in order to compare the properties
of the vinyl ethers of N-substituted P-ethanolamine with
those of the vinyl lactams. The vinyl ether.of IT-(P-oxy-
ethyl) pyrrolidone was synthesized. In addition the
authors investigated'the reaction between & -valerolactone
and P-thanolamine at 2000 C. Under the reaction conditions
Oard 1/3 ~he 6-membered ring apparently opens. Using-the example

Atudies in tbe Field, of Lactones and Lactams. SOV/62-58-9-1;/26
Cbmmunication 12: Vinyl Ether of IT-(P-Oxyethyl)Pyrrolidone
of thereaction of th0compound with butanol it ivat3
shown that the vinyl other of IT-O-o xyethyl)pyrrolidone
combines with alcohols. Di-If-(etliylpyrroli(loilyl),~tcetaI
and butyl-N-(ethylpyrrolidonyl) acetal were isolated.
The thermal decomposition of butyl-lf-(othylpyrrolidoilyl)
acetal was investigated. ~It was shown that the vinyl
ether of N-(P-oxyethyl)pyrrolidone combines with hydrogen
chloride. The product formed is unstable and upon
standing is tranformed into the chlorohydrate of N-(P-Oxy-
ethyl)pyrrolidone. It was found that the vinyl ether of
F-(P-oxyethyl)pyrrolidone polymerizes under the influence
of.the dinitrile of icooutyric acid-vaporand hydrogen
poroxido. It tends to polymerize thermally, but in
the proaarice of 0,21,5 bahzoyl poroxido (at 600 C) it- dooo
not polymerize. There are 2 tables and 9 referenceE;,
6 of which are Soviete.
ASSOCIATION: Institut organicheskoy khimii im.N.D.Zolinskogo Akademii nauk
SSSR (Institute of Organic Chemistry imeni IT.D.Zelinskiy )AS USSR)
Card 2/3

SHAPIRO, S.Ye.,- KONSTANTINOV, A.A.; 21-MENSKAYA,__~.I.; CIIAPOVSKAYA, L.G.;
STAROSTINA, I.S.
Clinical and immunobiochemical parallels in typhoid-paratyphoid
patients. Report No. 1:.Effect of the severity of the course, the
type.of pathogen and the age factor'on the protein composition of
the blood serum of typhoid-paratyphoid patients. Trudy Khab.med.
inst'-,no.20:38-42 16o.
(MIRA 15:10)
1. 1z kliniki infektsionnykh bolezney (zav. dotsent S.Ye.Shapiro)
Khabarovskogo medltsinskogo instituta i biokhimichoskoy laboratorii
(zav. dotsent A.A.Konstantinov) Khabarovskogo nauchno-issledovatell-
.skogo institute, epidemiolo ii i gigiyeny (dir. A.M.Krupnikova).
(BLOOD PROTEINS) ~TYPHOID FEVER) (PARATYPHOID FEVER)

LENKINAt M, S.,- SHOIRo, s.ya.; ZELENSKAYA. m.l.; KULUSHEVA, N.K.
Characteristics of the isolation of bacterioph,,ge In ty-11oid and Fars-
typhoid patients in a light clinical course of the disease and treatment
with antibiotics. Zhur.mik-obiol.,opid.i imun. 40 no.12:115-ii6 D 163.
(MIRA 17:3-2)
Iz Khabarovskogo instituta japidemiologii i mikrobiologii i kliniki
infektsionny,kh bolezney 1[habarovskogo meditsinskogo instituta.

KONSTANTINOV, A.A.; SHAPIRO, S.Ye..; STAROSTINA, I.S.; CHAPOVSKAYA, L.G.;
ZEIM4SKAYA, M.I.
Clinjoal and ijumanobioebomloal'. parallels In typhoid-paratyphoid
patients, Report No. P;,~ffeci~ of antibiotic therapy on the
protein componition of,tho. blood a6rum and WidaVs.reaction; the
interrolation between Widalln,roution and tho. individual blood
serum protein fractions. Trudy Khab.med.inst. no.20:43-48 160.
(MIRA 15:10)
l.- Iz-.kliniki infektsionnykh 'bolezney Uav. dotsent S.Ye.Shapiro)
Khabarovskogo m6ditainskogo,instituta i biokhimicheskoy laboratorii
Nav. dotsent A.A.Konstantino-v) Khabarovskogo nauchno-issledovatell-
skogo instituta Iepid emiologii I gigiyeny (dir. A.M.Krupnikovo.
(BLOOD PROTEINS) (ANTIBIOTICS) (TYPHOID FEVERI

77
7
GIDALEVICH, H. G.; DULINEVA, I. P.; Z&S'LAVSKIr, A, S. jULITMIKIN., M. G.;
GIDALLM
Prinimali uchasti7e., SHCHELOKOVA, 1. M.;
DANILOV M. A' I SHVEW, A. G.
Investi ating the offioionoY Of gmpa wn(thIng. Tnidy HNTIPP 13
39-44 161. (MIRA 1611)
(Moldavia-Grape, juice)

SHAPIRO, S.Ye.; KATXMOVA, A.D.; KLIMINO, O.T.; ZELENSKAYA, M.I.; TIMOFEYEVA,
A.A.; GARBUZOV, M.M.
Incidence of tulnremln in Xnabornvnk region. Zhur.mikrobiol.opid. I
immun. 29 no.2:2.1-24 F '5~i. WRA 1i:4)
1. 1% kliniki lnfektsionVWi bole7mey MiOnrovakorp meditsinnicogo
Instituta i Khabarovakoy protkvochUmnoy OtAntUil.
?M IA e
(TULARL , pidemiology,
in Russia (Rus)

IV35R /.Microbiology. lUcrobes Pathogenlo to Man F
and Animals. Tularemia Microbe.
Abs Jour : Ref. Zhur - Biol., No. 21, 1958, No. 95187
Author : Shapiro, S. Ye.; Kalmykova, A,D.; Klimenko,
0., 1,;J~lenokaya, U.I.; Timofeyeva, A.A.;
Garb z v,--Mv-*r-
Tact
Title : on Tularemic Diseases In the Region of
Khabarovsk.
Orig Pub : Zh. mikrobiol., epidemiol. i immunobiol..,
1958, No. 2, 21-24
Abstract No abstract.
Card 1/1

W MW M -
Hr a zw' fnvr~r ith
in FhfihnrowA nnd cl-tskirts.ll T). 12(--.
T~izs- n fn.w, Z')G
Mft,ynh-ryn I?Fi9 e-. (Tef-+;,'-- ,rO'rrnrir~ on
Z7

SUPIR09 S.Yet dotsentIAORSTANTINOVp A.A.f dotsent; ZHDANGVv
Med.Muk; ;ELEMKAYAp M.I.? kaud.med.ui~k
Dat4'of clinicalp epidemiological, and biochemical otudies on
hetdorrhagic 'nephrosonephritis. Sov.med. 25 no.lt64-70'Ja 161.
(HIRA 14:3)
1. Iz Ithabarovskogo institute, opidemiologii i mikrobiolo#i
(direktor A,H.Krupnikova) i kliniki infektoionnykh bolezney (zal,
dotsent S.Yeo Shapiro) MeditainBkogo instituta (dirloor - prof.
(EPID341C HEMOIMUGIC FWHR)

MLFIIMV~,-A, I-,. T.
of typhoid. B40ad Qn ma..
fron the clinic of Inractious diseases, Khabilrovalt 1A&Jie7-jI Inots"
rhab~.rovsk-State Kedical Inst. Khabarovsk, 1955- (Dissez-U- tions
fbr the Decree of Candidate in Hedlealc8cience)

YEPIFANOV, P.V.; YEROFFLEV, A
Removal of, excess -potassium bitartrate in the grape Juice
flow. Trudy WGIPP 5-47-50 t64, (MA 19ti)
Iz

L 27618-66 ENT(I)p _ JK-----.--
SOURCE
C NR. AP601&418 CODE t UR/ 16~/066[0-i,2/009670091
AUTHORt -Shapiro, So Yool Zelenskan. H& 14
ORGt Clinic of Infectious D iIa4dgeid-, KhIl!g-ovsk Kedidal UdtitutA (K11n1ka Infaktaloni
nykh bolazney Khabarovskogo rnditsinskogo instituta)
TITLE: Cases of botulisn n the Mxbarovsk region
SOURCSt Gigiyona i sanitariya# noo 32, 1965, 90-91
TOPIC TAGSi botulAsm, thorapeutiesi sertun, opidoidologF
ATISTRAM The author presents case histories of inhabitants of tho Khabarovsk
regiai Ao contractod botulism following consimption of fi9h products infected
idtii Cl. botitlintun. The illness waa In all canoe traced to persons who flahed
for chum rind pike for personal consumption as well as for ma,--,-ot oale to others#
Time canea Ind either a lethal outcome or resulted in intosbinal paroniap
diplopla, accommooation paresis. Treatment consisted of the admWstration of
antibotulin serum'V(typo A and B) cordDlined with transfusion of blood pla3ma,
saliyie sol-uTT~on3, and other means of pat holronatic therapy. Bacteriological
analysis of the remins of chum and pilce confirmad the presence of Cl. botu-
linum. Thus, opidamiolopjcal observations indicate that the region of
Khabarovok adjoining th,3 Amur River Is unfavorable from the standpoint of
botulism. The sources of this food poisoning were chum and pike, i.e. fish
tnDC1 616 ?811553~03-6

in Khabarovsk is -processed (cured)
,harbored chiefly in the consumption of home
fish products. LJPRS7
SUB CODES 06 SUM DATEt 26Dec64 OPJG REFS 002

KORZHN, A.A., inzb.; ZELENSKAYA, M.L., lnzb.; FMSEYvV'-rR.G,, inzh.
~Safet7 measures in using radioisotopes. 13ozop.truda v prom*
13 no.4:15-17 (Ap 159. (14IR& 12:6)
Ra 4
dioisotopea-Safay measures)

ZE411SKAYA,- H.O.;BRIGADIROY, II.G.; BLINOV, A.I.. tekhnicheoki7 redaktor.
(Orijin of man; material to aid the dissemination of scientific
information among the rural populativn] -VrOiekhoxI#enie chelo-
veka;*~materialy v pomoshch' estestvenno-nauchnoi propagar4e
aredi ael'skogo naselaniia.,4sto-na-Donu, 1956. 15 P.
(.;IIaA 10;6)
1. R.ostov.on the Don,Gosudarstvannaya nauchnaya, bibliateka.
(Bibliograpb7--Man--Origin)

ACCESSION NR: AP4042906 9/0040/64/028/007/1220/1228
-Ab"MOR- Zolenskaya, H.S.: SmIrnov,'.!ru.F.
7 77.
TITLE: Concerning vow features of the'quaolelostlo nucleon and deuteron knock-out
reactions on Id-2a shell nuoloi fftepoii,j4th Annual Conference on Nuclear Spectra-
soapy held In Tibilisi 14-21 Feb. loog
SOURCE: AN SSSR. Izv. Seriyi Azichaskaya, v-28, no*7, 1964p'1220-12i8
P n
ITOPIC TAGS: nuclear reaction, proton,reaction
ABSTRACT: In brder to dbtain inf4armation con6crAing'direct kn.cc-o~t reactions of, -
6 and WO
.:-~ld-2a shell nuclei between the cross aections for the fo~lcwing reac-
tions were calculated: Mg24(pj2p)Na23, G*128(p.*Fp)Aj27 and Mgp4(p#pd)Na22. Tho cal-
11culationo were performed with tho.unif.iod modal in tho momentum approximation with
the use of plane waves. The reduced nucleon widths were taken from the work of,S#.
Yoshida'(Prog.Theorot.Pbys.JL2,141#1954).,Tbo results are presented graphically and
are discusseds An a function of iheid'ent*proton energy, the cross-section for the,
(p,2p) readticin*shows a number 62 iteilseparated maxima. These are.dw primarily to
1P. the difference-between'.the 1pugitudinal,* and transvers4 fre uencies In these defo=~
L

P
1ACCESSION NR, AP4042968
ed- nuclei, which. also gives rise to the splitting of the giant,dipqle resonance.
Pairing forces also co'ntributo,.however, and the effect is marked in Sj28 as we 11
i 24
as in h19 . The cross section depends strongly on the angle between the two scat-
otons, but the maxima are still clearly separated when,.the gross section is
:averaged over the angle. The protdn'movientum distribution in rAther.complex because
of interference between osc .L46tor :otates with differentt. e effective iber
Th nur
h1g24 was f consido.rably less.
;of devtorons in otind.to.be approximately 0.5. This is
!than.in p-shell nuclei. The..(p'pd) cross section depends more strongly on the angle
.~!than does the (p,2p) cross section; ihii is due to'the,fact that the deuteron wave
:if unction is not a harlmonic.osc*illato'r'eigenfunction. As a function of the -incident
1-_-~proton energy, the cross section shows.a. number of peaks ihich,,however,* are not so!~._-'
well separated &s those of /the'(p.,2p) cross- -section. 'The probabilities- were calcu-
of by the 017(ppn)016'
"lated for the excitation of a number of .odd Iparity states -016
'reaction. Not only are the probabilities.lor-the excitation of the odd levels of tbo
onance quit different than-in the dase of excitation by photon ab-
giant dipole ros
~sorption, but many other odi stateb-aid:strongly excited.- Jt Is noted that many
-states can be excited and investiga'ted.-bi-means; of direct knock-out reactions that
ar that.~'
14 4- Wguld be difficult to oxoito.',otherwise j,an4jt4s suggested In partioul
iif

"The Stopping Abtorption, of-d'M56118 in C
repo-et, r;ubmi,--,,+,cd -for All-Union Conf on Nucloar Spectroucopy) 12biliol) 14-22
Feb 64.
MU (Mbscow State Univ)

-790
S/056/61/041/006/040/054
B109/B102
AUTHOM: Zelenskaya, N. S.,,Shirokov, Yu IT.
3
TITLES Relativistic.corrections to the~magnetic moments of H and
3
He
r, mentallnoy i teoretioheekoy fiziki, v. 41P
-RIODICALt Zhurnal ekaperi
P
no. 6(12)j 1961, 1934-1937
TEXTt AIgoneral expression io derivad 101' tho rolativilitia aorroationo
to the nuclear magnetic moments arising as a result of non-Galilean
relativistic,corr6atione.to the Hamiltonian of nucleon-nucleon interaction.
_Aocording,to F.. A. 7,hivopietsev, A. I. Perelomov, and Yu. It. Shirokov
(ZhETF, 3_6j 476, 1959), thetion-Galilean correction to nucleon-nucleon
interaction ha's the form
Gard 1/4

8/056/6i/041/006/040/05,1
Relativistic corrections to the ... B109/BI02
(3) haz been oalculated for the 51/2 tato of mirror nuclei by using
the 'Wave function of the harmonic o9cillator and the expression
(W + I'm + BP6. + ' Pj),.) V(r) (V(r) - Gauss or Yukawa potential).
Mn X
The result's are shown in a table. Conclusionst A) The relativintic
non-Galilean correction exceeds considerably the correction of the
spin-orbital interaction; B) the correction terms have the correct sign;
the maximum value of 0.086 explains only 30A of the discrepancy between
theoretical and experimental valu
es...The'difference.is attributed to
the ef5ect of exchange mesonst which has been discussed by S. D'i Drell
and, J. D. Walecka (Phys. Rev., 120, 1069,.196o). Thoreare I table and
'13 reforenaeot 4 Soviet and 9 non-Soviot. The four most recent
roferencea to English-language publications read ari followat L. D. -
Rearlstein~ J. C. Tong, K. Wildermuth. Nucl. Phya., 18, 23, 1960; A. 0.
Butchory J..M. Mo Hamce. Proo. Phys, Soc.f 74, 529, 1959; R. A. Ferrel,
W.11.'Viescher,,Phyti. Rav.t 1-0-2t 4501 19561 J. M. Berger. Phys. 410~v$
2239 1959-
Cara 3/4

31790 - ------ -------
S/056/61/041/006/040/054
Relativistic corrections to th e... B109/B102
Mo'skovskiy gosud arstvennyy universitet (11oscow state
University)
-SUBMITTED s :July 12, 1~61
Legend to the Tab 1 e 1 (.1 shape

13 and parameter of V(r) (V is given in
0
Mev and a in 10 cm)$: (2) Gauss potential; (3) Yuk4wa potential.
'I'
Opma it "OpameTpu Vjr)
W. a MCV, a a
$
A It (He
)
MeHILIM G
I
a=i,'73
to] -
0
-0,0/j8
O,Ot4
-0,014
1'--15, a=1,94 I , .. 0 -01032 0 009 -0,009
Va--68,8, a=i,55 0, -0,018 0:005 -0,005
nOMHUHafi 1OKaBa 0
V~~68 a=1,17 0 -0,086 0,026 -0,026
Vo=46.48, a=1 8 0 -01056 0,017 -0,017
Card 4/4

WR7 -ApGool.147 SOURCE CODE: LTR/03,37/65/002/003/0427/0432
AUTHOR: Zel2M~M~, N. S.; Mayling, L., Neudachin, V. G. ; ST!rrtp Yu. F. (.0
ORG: Nuclear P~yslcs Ins!ltute, MosSaw State University (Institut yadernoy flz'IkI
moskovskogo gosudarstvennoge univerEd
TITLE: Selection rules for nuclear reactionl t'n'vo4ving nucleon associatiotis in the SU(3)
scheme
SOURCE, Yaddrttaya ftzlka, v. 2, no. 3, 1006, 427-432
TOPIC TAGS: nuclear reaction, nucleon Interaction, selection rule, quantum number,
radioactive decay scheme, alpha particle, alpha decay
ABSTRACT- The authors examine selection rules according to approximate models of
quantum numbers in the SU(3) scheme. Selection rules are formulated for nuclear reactions
Involving associations according to quantum numbers In the SU(3) scheme, widely used in
light nuclei spectroscopy. it Is shown that-these selection rules in some cases lead to very
rigid restrictions, which makes it easy to check them experimentally. For example, the
reaction of quasi-eiastic knock-out of an Alpha-particle from the nucleus 016 by a fast
particle a: & (a, aa)C*, accompanied by a-decay of &1*43a, is possible only through
the - 12- t4e V leve T 11%41P0 144414+ > of the nucleus C"2. Furthermore, In the stripping
actions &'(LI6 d)Ne 2 * the oWy levels of the configuration (id-2s)' which can be exg#-_d
are those of the lowest rotational serter, 04, 2', based on the ground state of Ne
Z_71

-7A
ACC NRi
Orig. arL has: 6 formulas.
SUB CODM 18/ SUBM DATE: MUMS/ ORIG REFi 004/ OTH REP-, 010
2/2

.ACC NR: AP6019619 SOURCE CODE: UR/0048/66/030/002/0278/0284
Jl~<
A=OR: Zelonskaya, H.S.; Smirnov, Yu.F.
ORG: Scientific Research
Institute of Mcloar Physis~L -MOEC-OW State Univorsity im
11I.V.Lomonosov (N-auctino-issiodovatol'skiy,inatitut yadornoy fiz4aki Moskovskogo
gosudarstvonnogo univorsiteta)
TITLE: On taking into account spin-dependent effects in quasi-elastic knockout re-
actions /Report, Fifteenth Annual Conference on Nuclear Spectroscopy and Nuclear
Structure, hold at Minsk, 25 Januag to 2 February 1965/
SqURCE: AN SSSR, Izvostiya. Seriya fizichoskaya, v. 30, no, 2, ~966, 278-284
nuclSg
TOVIC TAGS;. c$jou,_jnuclear spin, spin orbit coupllngrhn=b=t=~~,
F4, gp,
approxima'iiMc~'%p~'~e'j`
A]3�TRACT: The impulse approximation calculations of V,V.Balashov, A,N.Boyarkina,
and I,11ottor (Nucl. Phys., 59, 417 (1964)) and P.Boregi, N,S,Zolonskaya, VIG,
Noudachin, and Yu.F.Smirnov (Nucl. Phys,, 660 613 (1965)) of tho cross section of
the quasi-elastAlc knockout reaction (n,aX) have been generalized to take into sc-
count the spin-dopendent terms in the interaction between the incident particle a
and the knocked out particle or cluster X. The tonsor forces between a and X are
neglected, but the central forces, the spin-orbital coupling, and the spin-spin
Card 1/2

L 41296-66
ACC NRj
interaction aro:taken into account. The spin-dependent factor In the expresalon for
the cross section is simplified for the case in which the spin of the incident-
particle a is 1/2, and expressions are given for the cross section and for the~polar-
izations of the scattered particle a and the knocked out cluster X (in the impulse
approximation the recoil nucleus is not polarized. Men the spin of the knocked out
cluster X is 0 or 1/2 the correction to the cross section (with the tensor forces . .I
ne lected) is rigorously zero. Computations for specific cases, in particular for the
(p,pd) reaction, showed that the spin corrections to the cross section-are small-
and that the formulas derived In the references cited above without taking spin Into
account are adequate. It is suggested that m9asurements of the polarizations of
knockout reaction products might provide information on the structure of the target
nucleus, and that measurements of the polarization of the recoil nucleus might give
an indication an to the limits of validity of the impuls6 approx'imation. The authors
thank V.G.Neudachin for discussions and valugible remarks. Orig6 Art. has:.
35 formulas.
SUB CODE: 20 SUBU DATE: 00 ORIG. REF: 002 OM REF: 003
i Card 2/2

JDIJH
-ACC-NRi-.-AP6O1962O__ --SOURCE CODE: -UR/0048/66/030/002/0285/0291
AUTHOR: Zolenskaya, N.S.; Smirnov' Yu.F.
ORG: Scientific Research institute ol Ku clear Physics, Moscow State Universit im.
M.V.Lomonosov (Nauchno-issledovatellskiy institut Vadernoy fiziki Moskovskogo
gosudarstvonnogo universiteta)
TITLE: Energy spoctra of tho final nuoloi in (jp,2p) reactions on ld-2s shell nuplei
/Report, Fifteenth Annual Conference on Nucloo7r- Spectroscopy and Nuclear Structure,
hold at Kinsk, 25 January.'to 2 February 1965/
SOURCE: AN SSSR, Izvostiya. Seriya.fizicheakaya,v. 300 no. 2, 1906, 285-291
~TOPIC TAGS: nuclear reaction, fwe-h Coriolis force, nuclear shell model,
deformed nucleus, magnesium, aluminum, silicon, phosphorus
ABSTRACr: The authors have extended their earlier unified model calculations of
quasi-elastic proton and deuteron knockout reactions on deformed ld-2s shell nuclei-;.
(Izv. AN SSSR, 28,. 1220 (1964)), to take into account the effect of rotational band
mixinzi:~.e., of the coupling between the single-particle and rotational motions. The
calculations wake motivated by the appearance of the'experimental excitation;curves
of G.Tibell, O.Sundber , ang.R.U.Renfierg (Arkiv fys., 25, 443 (1964)) for the (p,2p)
reactions on Mg24 A125 Si and P which disagreed with the authors' earlier
#&h
calculations in'bucF_a1L77_aW1t0 slig-gedt that rotational band mixing might be signi-
r,,4 1/2
I WIN

ACC NR: AP6019620
ficant. The calculations of A.K.Xerman (Xgl. danske vid. selskab. Mat.-fya. medd. 30
No. 15 (1056)) of the effect of Coriolis forces on the rotational level energies an~
the nuclear wave functions are employed to calculate the changon in the spectroscopic
factoru In tho roduced widthol and thoOO Are omployod to correct tqq earl or cglcu-
Intiono of the excitation lunctiond for tho (p,2p)~ 4 'Sizu
roactiona on Mu p ML ' , , And
P31. Rather good agroomont with experimont in achiovod, Tho poouliar teaturon of
each of the reactions are discussed. It Is concluded that the strong coupling9chemo,
In its pure form cannot account for the features of (p,2p) reactions on deformed Id-2t'
shell nuclei, but that rotation band mixing must be taken into account. In the case
of slightly deformed Id-29 shell nuclei, rotation band mixing duo to Coriolis forces
not only shifts the nuclear levels but also alters the probabilities for their exci- "I
tation In (p,2p) reactions. By taking rotation band mixing into account, good agree-,~
ment with the'experimontal data of Tiboll, Sundbergo and ;%endber9-(loc,cit,) can be
achieved.. It is suggested that experimental da.t a0 on the (p,2p) reactions on the
lightest*ld-2s shell nuclei (not heavier than No ) as well as an analysis of the
levels of those nuclei on the basis of the SU3 scheme of J.P.Elliott (Proc.Roy.Soc.,A,
245,128,562,(1958)) would be desirable. The authors thank V.G.KGudachin for dis-
cussions and.valuablo remarks. Orig. art* has: 4 formulas and 3 figures.
SUB CODE: 20 SUBM DATE: 00 ORIGo X-EF; 004 OM WW: 010
Card 2/2

LI 3531-66 EPA(-s)-2/F-'IIT(raWE17P41)/,EPr-(n) -2/HAP(t)/jEpP(b~ JMA"',
A-ME=L N NR: AP5015454 0101 /65/0Q~03/0038/0044-
!AUTHORS: )(qpAayev, A. 14..,,~ Zelenskaya N V Khalmuradov
~TITLEz Spatial distribution of atom"a fluxes when metals are
~evapcrated by the spark-arc method
iSOURCE: AN UzSSR. Izvestiya. Seriya fiziko-matematicheskikh nauk,
;no. 3, 1965, 38-44
ITOPIC TAGS: metal coating, metal vapo4eposition, metal film
IABSTRACT: The spark-are method for the evaporation of metals in
;vacuum was described by the authors earlier (DAN UzSSR, no. 12)!
1 1964
The present study was undertaken to determine the distribution of the.
,metal produced by a single evaporation source, so as to permit an
;ultlinate arrangement of several sources in such a way that a thin
film of uniform thickneas is pr-oducod. The experimental 13 tu dy con-
t3lated of locating flat glaaa platea at varloua diatances from the
t~vaporatlon center and determining the thicknes's distrtbutIon of the
deposited metal air by wasuring its t>ransparency. The experlwntal
Card 1/2

L 3.531-66
ACCESSION NR: AP5015454
japtup and dotaila of the Anstallation
[are-,. bri?~ e-uc-ribe-M--
of the toot meaourqmento
or, .-the--det#ri&ffati-ofi-
--.zubs tr-at
---lASSOCIATION: Fiziko-tekhnicbeskly institut'Am*UzSSR (Physicotechnical
~Institute, AN UzSSR)4~
ISUBMITTED: O7Oct64 ENCM 00 SUB CODE: IS
.NR REF SOV., 003 OTHER: 004
Card 2/2
- - --------
Im

YAGUDAYEVI A.M.j ZELEKSKAYA, N.V.; KHALMURADOV. R.S,;-"
Spatial d1stribution, of atomic fluxes in the vaporizzation
of metals by the sparking-arc method. Izv.AN Uz.SSR.
Ser.fiz.-mat.nauk 9 no.308-44 165.
(14TRA l9rl)
1. Fiziko-tekhnI-chqakIy Institut AN UzSSR. Submitted
October ?, 1964.

GALIFERINO H.U.; T-19 INSKIY, A,P.; -ZNLPNSXAYAO Et G
Knock testing of automobile engines. Trudr lab.dvig. no.1:61-87
(Automobiles-~-%ginae) 919)
M- E

PUCHKaV, BOROVAYA, HS.; ZEMSXkYA. R.G.; MMUNCEIMOVA, G.P.
Performance of winter notor oilo from eacten sulfur-bearing
crudes, Xhim,i tekh.topl.i masel 4 no,2:10-18 F '59.
(MIRA 12-.2)
1. Voesovuznyy nauchno-iseledovatellskiy institut po pererabotke
nefti i gaza i polucheniyu iskusetvannogo topliva..
(Lubrication and lubricante-Testing)
41

SOV/65-58-8-1Z14

AUTHORS: -,
Puchkov, N, G; Borovayal M., 3. and Zelenskaya,
TITLE: Useful Properties ofl~ubricating Oil's for Cars from

Eastern Sul --troleuwv Mlcapluatatsionnyyo
phur Po
svoystva av tolov.iz vostochnfth aernintykh neftey).
PERIODICAL: Khimiya i'Tekhnologiya Topliv i Masel, 1958, Nr.8,
pp. 1 - _9. (USSR).
ABSTRACT. Dur ing tasts by - the 140vokuybyshevsk Petroleum Refinery
' (iiovokuybyaheVsldyneftepererabatyyayu8hohiy zavod)
carried out by TsIAT1IM,.VNIITneft , TTAMI and VNII NP
it was found that.the properties of oils prepared accord-
in~ to-StanC:ixd GOST 8581-57 are unsatisfactory. Detailed
investigations Wereo thereforep carried out on the:.chemi-
Cal compositionand physico-chemical properties of these
oils. From.characteristics of thesesamples (Table 1),
-it can be sben that oils from sulphur petroleums d-Iffer

from Bakft .
petroleums by their low magnitudes cr'drisitybnd-
low refraction coef-ficientsg but they have better viscosity-
temperature properties, show low corrosion and a fhigh
tendency to lacquer formation. Data on the effect of
the addition of various additives on the properties of
lubricating oils NX NPZ was evaluated by laboratory
Card 1/3 methods (Table 2) In a Pinkevich apparatus. The smallest

Useful Propertieo of
Petroleums.
Card 2/3
SOVA35-58-9-1/14
Lubricating- Oils for Cars from Eastern Sulphur
anti-c -orrodive action was shown by the additive Paranoks
apd Tsiatim-339. The additive AzNII-4 and Santolube proved
tifisatisfaotory. The additive Dr,!rl Paranoks and Santolube
was most effective in reducing.lacquer formation. Analogous,
data were obtained when dete-nnirft the detersive properties
according to PZV (GOST 5726-53). The oil Iff-IlTZ could
hot be tested on the engine GAZ-51 because of insufficient
putification. Table 3: results of tests of oils on the
engine GAZ-51 (time of test = 100 hours). As these
laboratory analyses proved to be insufficient, pure and
used oils were d1vided into hydrocarbon fractions (Tables
4,.5 and 6) and tooted (Refs-31 4 and 5). A comparative
evaluation of the chemical oomposition of these oils
showed that after 150 hours of work the chemical group
composition of the oils changed only to a slight extent.
However, the viscosity of the aromatic fractions of ".-he
oils from Baku . petroleum altered considerably, Some
additional characteristics of the changes of the oils
after 100 hours.of work were obtained during the analysis
of tars (Table 7) and during analysis of deposits on
filters (Table 6). The lower degree of carbonisation

SOV/65--.58-9-1/14
Useful Properties of Lubricating Oils for Cars from Eastern Sulphur
Petroleums.
,of oxidation products was less dependent on the chemical
L
composition of the oils than on the presence of sulphur
in the oil NK-11N. Further tests were -Mrried out on
the oxidation of five samples of pils under laboratory
conditions (in the apparatus DK-2 NATJI) at 180o, 2000
and 2200C during fifty'hours.. The viscosity at 500C was
determined every ten hours, as well.as the quantit7 of
insoluble deposits,'tar and the amount. of forced asphaltenes
and hydroxy acids - 4). Table 9: data oA the
content of sulphur in,the oils. At high temperatures
(2200C and higher) the stability.of -Baku '.' and Eastern
olls equalises. Oxidation products of Eastern oils
are less pure and contain a larger amount of tars. asDhal-
tenes, hydroxy acids, but no a arbene s
,or carboids. There are 9 Tablest 4 Figures and 5 Referen-
ces: 4 Soviet and 1 English.
1. Lubricat;ing oiis--Test results 2.. Lubricant additives--Effectlve~
ness 3. Sulfur--Chemical effects
Card 3/,3

UMMM
32531
ZIA s/o65/62/000/001/002/002
E19VE135
AUTHORSi Puchkov, N.G., Dorovnyek, M.S,l Belynnehihov, G.P.,
ZelenA1ta_y-a-,_P_a., and Savarov, Ya.G.
TITLEs Service performance of basic lubricants refined in
different ways
PERICODICALi Khimiya 1 tekhnologiya topliv i masel no.1, 1962,
53 59
TEXT: -Engine tests at the VNII NP showed that engine oils
derived from Eastern high sulphur crudes caused ring-sticking.
in this respect alone they were worse than Baku oils, being equal
or better in all other respects. Accordingly, a study was made
of hydrocarbon group and ring structure and other properties of
various lubricants before and after engine testing. Eastern and
Baku oils were found to be generally very similar but differ in
the content of sulphur compound and in hydrocarbon structure.
Because of their constitution Eastern oils oxidise to form
oxyacids and asphaltenes which promote ring sticking. Even-
though the oil-resin contents of the initial base oils were
Card 1/ 3

32531
Service performance of basic ... s/o65/62/000/001/002/002
E-19VE135
similar, tho-oils from Eastorn crudes-produced more lacquer in
the engine and in a laboratory oxidation test than did Baku oils.
Oils deeply refined by solvent, acid or adsorbents were-more
stable, but whereas the Baku oils so refined deteriorated at a
steady rate the Eastern oils displayed an induction period, being
initially the more stable, but later oxidising more rapidly.
Adsorption refining was particularly effective in improving the
stability of the oils and reducing ring sticking with oils of
Eastern crudes, giving satisfactory performance even without the
use of additives. Work is in progress on hydrofined Eastern
oils and preliminary indications are that this treatment gives
somewhat higher VI than solvent treatmont. However, hydrofined
Eastern oils. have inferior additive susceptibility, particularly
to sulphonates, though their properties were much improved by
additive %14XII Hil-36o (VNII NP-36o). Hydrofined oils with this
additive behaved well in 100 and 600 hour gasoline engine tests
and in 800 hour diesel engine tests. A simple comparison of
certain physical properties of hydrofined Eastern oil with those
of Essolube, and Shell Rimula oils, indicates that the Soviet
Card 2/3

R531
Service performa nee of basic ... s/o63/62/000/001/002/002
E194/E135
base oils.can be as good as foreign ones. The need to match
additive to base oil is emphasised.
There are 5 figures, 9 tables and 4 Soviet-bloc references.
ASSOCIATION: VNII NP

7-.
DI
ACC NR: AP6018624 (A) SOURCE CODE: UR/0065/66/000/006/0048/0052
!AUTHOR: Grigor'yev, H. A.; Pimenov, A. M.; Zelenskaya, R. G.
ORG: NAMI, VNII NP
TITLE: Evaluation of ser vice qualities of automotive oili by engine tests
SOURCE: Kbimiya i tekbnologiya topliv..i masel, no. 6, 1966, 48-52
TOPIC TAGS- lubricant, lubricating.oil
ABSTRACT: In order to provide appropriate equipment for the testing of automotive
motor oils in the Soviet Union the NAMI-1 Lest unit was developed and uned at NAMI for
comparative engine tests, evaluating the test results by the UIM-6 method, US method
344-T (USA Standard No. 691, March 1959), and also by the PZV method. The unit in-
cludes a single cylinder engine, corresponding to a section of engine ZIL-130. The
unit permits rating of piston deposits, varnish, piston ring coking, wear of the
cylinder-piston section, low-temperature deposits, and the oxidizability of oils anq
bearing corrosion. Lubricants type A, B, and C were rated, represented by oil Aq--L'57
with admixtures of 0.7, 0.7, and 0.25% additive Santolub .193, and of 0.7, 1.5, and 4%.
additive Monto 613, respectively. Standard asoline A-7611was used in 100-hr runs.
Method UIH-6 gave higher ratings for ring mobility than method 344-T, and the latter.
permitted a differentiation by points of piston grooves and seals, although the final,,
results for both methods were similar. The types of deposit, however, may differently
Card 312 UDC- _.k65.521.5

- - - - - - - - - -
L 41031-66
ACC N.R.. AP6018624
affect engine performance and correspond to different serviceproperties of motor oils.1
Method 344-T is-employed by various organizations in the Soviet Union and is widely 4sed
in other countries. Thus, an important modification of the method without suitable
research is hardly expedient. Orig. art. has: 1 table and I figure.
SUB CODE: ll/ SUBM DATE: none/ OTH REF: 001
Jis

Ct~l rZt 44tr

5.3300
82 "
7 3.L
SOV/80-33-3-32/47
AUTHORS: Garber, Yu. N., Zelenevskaya, S. I., Rabukhina, G, G.

TITLE: Concerning.ttie-Azeotropic-Rectifidatton for the
Separation of Isomers With Close Boiling Points
(System m-Xylene-p-Xylene)
'PERIODICAL:: Zhurnal prikladnoy khimii, 196o, Vol 33, Nr 3,
pp 694-7oo (ussR)
ABSTRACT: The investigation of the phase equilibrium as well as
the rectification of paraldehyde-m-xylene and paraldehyde-
-p-xylene systems showed that paraldehyde does not
form azeotropes with either of the xylene Isomers, and
therefore cannot be used for the separation of the
xylene isomers mixture. Similar study of 1,2-ethyl di-
bromide mixtures with xylene Isomers showed that the
former gives an azeotrope with p-xylene only. The
.5-95.0'molar % of 1,2-ethyl
contains 92
,
dibromide and its boi ling point Is 131,00 C. However,
Card 1/2 due to the low p-xylene content in the mixture of the

the Azeotropic Rectification 78231
forI-the Separation of'Isomers With Close SOV/80-33-3--32/47
Boiling Points (Systems m-Xylene-p-Xylene)
isomers, 1,2-ethyl dibromide cannot be used as an
azeotropic agent for their separatlon. There are
4 tables; 6 figures; and 8 references, 2 U.S., I Belgian,
and 5 Soviet. The U.S. references are: D. F. Othmer,
Ind. Eng. Chem., Analyt. Ed., 4, 232 (1932); Eviell
and others, Petroleum Eng., 15, 255, 259, 319 (1944).
ASSOCIATION: Dnepropetrovsk Metallurgical Institute (Dnepropetrovskiy
metallurgicheskiy Institut)
,.SUBMITTED: November 15, 1959
Card 2/2

W-0
22iDPNOV, Yu.A.; DOROFEYENKO, G.N.; WANSKAYA, S.V*--
Thin-layer chromatography of carbohydrates on gypsum. Dokl. AN SM
149 no.6.-1332-1333 Ap 163. (MIRA 160)
1. Ros tovskiy-na-Donu gosudarstvennyy universitet. Predstavleno
akademikom M.M.Sh6mvakinym.

- - - - - - - - - - - - -
ZELF118KAYA, T.M. [Zelenslka, T.14.]
Morphological changes. in the orvaries of white rats under the
effect of large doses of antiovarian cytotoxic serum. Fiziol.
zhur. (Ukr.] 11 no.6:816-819 N-D 165. (1,111RA 19 . 1)
1. Laboratoriya imicheniya. biolo,gichoski aktivnykh vasheliestv
inatituta fiziologil Im. Dogoiriolitsan AN Uki-SSR., Klyov.

-0-0 4
a e a IF -0
OW411,15 AN* pecotsilts Ant I
The c"MW COMPWOM of buRSO (P-411 fusitIVA)
Pront. 1039, No. 4.,
fruits. ~ E~,Z 00
oo . 42-3; Kkisi. ni_tZ. Zhar. 1940. o. 1, M.-The mi-. -0*
40 tents ot plar, acid, =,and, tannic substwxts wtrr
00 dvd, In fruits of 23 . proomr ittsilitia. -Tbe
jifittl mraml of toctow (in the red fruits) W citric acid
an't the *bwmv of tatt"k auh-lancro make bultace a 0
VISIUAble fruit. The to"11W I be t1wd (or ptmfilr-
0 rit xlat;k mai, of the oily
1419 ritfk *A he "WtV rk. Re 16 1 P, coo
W. It. lien"
to QtO 40
to 0
coo
goo
V boo
L A I
tsoo
414.1 woo
gold" it "I C*t
tsimc ]psi A I an any it 9
U -a a to it! is 0 3, 9 V
ttit~ov frva scot, ct
0-* W 0 0 _o o 0 0 it 0 4-0. s-, 0. 0 0 9 0 0010 0 6 000 0 0 0 0
"e6- *W 0 SAA 0 : I W a a 0
10A ~ 4 MkIep ~ ~00 0

a1avi;,t,hv,h lt,,.VvcAl chAtips fit,
too !,u
*
'NailUji;i. 1'. 1, bekiii-I 14, Sol- [0, 41.1
Pill ilill m vull-C 4 a it aro 11 mill'if Woo 1.1 sil A I vs III I fit.
its Ifir "rly mapIr Ot vroirHIIIIII. Thk% I,
A Ald i1"411 lit all 011#01111 1114,
st.11, III the itild-th, o4 ill- mimm,r M, timill,-1 frco~-
Wil..Ul 111~ 614".14 ill the .41"1 lit Ifir 1,411 lit....
ill the ro't
CA

1. YB.: D. UMSKAYA
2. 058it (600)
4, APP10
7. Seasonal dynamics of ash constituents and nitrogen in various organs of young
apple trees. YE. D. Zelenskaya. Dokl. Ak. sel(khoz. 18 no. 11. 1952.
9. Monthl List of Russian Accessions, Library of Congress, April .1953, Uncl.
aw amo--
t iu~ a

Ya
It -Z

- ;~; , - -* I ", c, I .- -I ". ", . ~., , - . , ~
m

Zolenskiy, A. Fq, "Ma te rl als on the conditions of blood circulation in newborn
1nfa7n,FF-,Fr-u-rT1,r V1 IM!"0-I" - t; I Y" d1a (3-t. vraclv~y, j-.osvya,,.hch. paziyati prof.
Filatova, 1948, P. 1123-28
SO: U-3264, 10 April 1953, (Letopis 'Zhurnal Inykh Statey, No. 3, 1949)
-1~ -A

ZZLINSKITS A*F*
Fanctional peculiarities of the cardiovascular system in evaluation of
general development of nevborn. Pediatrila, Moskva No.6:13-19 Nov-Dac
51. (CIRL 21:4)
1. Of the Division for New-Born Infants (Head-A.F. Zelenskiy), Scien-
tific-Research Institute of Obstetrics and Gynecology, Ministry of
Public Health USSR (Director-L.G. Stepanov; Scientific Supervisor-
Prof. X.N. Zhmakin).
1_, =,-z

HEM
ZS19BSKIY#---A -.F.
.--~~Inrlttonc* of B.-P.Botkin on the development of Soviet pediatrics;
on tho 12~th artalvorwy of hie birOl [with auwOry In xnigwa.
Pudintrila 36 no.IM-85 Ja 158. (MIRA 11:2)
1. 1z kafadry datskikh boleznoy (zav. Ad-Zelanskir) Dnepropetroy-
akago moditainakogo inctituta (dir. -prof. D.P.Ohukhriyonko)
'TROVICH, 1632-1889)
(BOTKIII, SIMMI M
(FgDIATRICS)

Elactoencephalography In neuroses in children. Vop.psikh.i nevr.
no,7062-~66 161. (MIRA 15;8)
1. Kafedra nervnykh bolezney (zav..- Prof. Ye.F.Davidenkova)
Leningradakogo pedlatricheakogo meditainskogo lnatl~uta (dir.
Prof. N.T.Shutova).
(NEUROSES) (ELECTROENCEPHALOGRAM)

X19MYLOV
,, O.V., k4rid. tnklira. wlvk~ ZUEREBTSOV M.P.j. izizli.4
Effact of renidual stri)mvin rctmilLing from welding on tbe
ahrinkago of concrelit bi joliiLtj o.C I)vo-,-.jjnt colim-na, Prom.
stroi. 43 no.10:25-.30 165. (MIRA 18.11)