SCIENTIFIC ABSTRACT ZEMLYANSKIY, N.I. - ZEMLYANYY, N.G.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001964420008-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 19, 2001
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

67- ... ...
`EWP(J)/91j(M)_ RM
ACC-MI-AV7003108 SOURCE CODEt UR/0079/66/036/007/124 243(
AUTHOR: Zemly!~~siciy N. 1. - Chernaya, N. M.; Turkevichp V. V.; Krasnoshchek, V,
ORG: Llvov State University (Llvovskiy gosudarstvennyy universitet)
4.U. Esters of-selenothiophosp oric acid.1 III. Mixed eaters of OjO-dialkyl-
osphoric acid
-.,.I,SOURCE: Zhurnal obshchey khimii, v. 36) no- 7, 1966, 1240-1243
.~z:%~"-20PIC TAGS: organoselenium compound, ester, organic synthetic process, phosphoric_..-
a
cidl, IR spectroscopy) chromatography
ABG~fPACT: The authors s3mthosized for the first time the eotassium-salt of
-diqt sq _bp, Phorla-suid 7, and investigated its reactions with
_1!~p~Lthiop cil
alkylating agents- allcyl-bromides, alkenos, and alkynes. Reaction of une
potassium salt with certain alkyl bromides yielded new mixed eaters of
0.0-diothylsolenothiopho.~,phoric acid., the reacttion proceeding at the selenium
atom. The methods of infrared spectroscopy and thin-layer chromatography
.3-n-dicated that the aBWlation of the potassium salt results in the formation
primarily of the thione isomer. This was confirmad by synthesizing the
isomeric propyl and isoairql esters of 0,0-diethylsolenothiophosphoric acidivith,
a thiol structure by the reaction of 0,0-diet*nylehloroselenopho3phate with
potassium morcaptides. Xdxtures of the isomsers were obtained,, and their forma,
,tion was interpreted as'a partial rearrangement of the thione-isomor to the...j
thiol isomer during* its :,Lsolatioh. ' Orig. art. has;' 1 figure, 2-foximlas and
1 table. 9701
[JPRS: 38P
SUB CODE:. SUBM DATE: MaY65 ORIG REF: 002
Ca d 1/1

MIYANSMY N.I.; MJRAV7tYEV 1.v.
.9
Roaction of phoaphorus pentasulf1de with alcoholB in the presence of
bp-sos. Dakl~ All S3SR 163 noja654-655 JI 165. (MIRA 180)
1. 1.1voirskly gasudarstvenriyy utiveresitet im. Iv.Franko. Submitted
January 11, 19155.

ZEML~~ANSKIY, N, l.; GUE~FOVti, L.V-
y Jiltlopho3p'
-- I I t, fl
Synthesis of unsaturatM ecters of 0,0-dia-k-',
acids. Zhur, ob. khlm, 35 no~8~1481~,1483 Pa, '6-5.
18A)
L. Llvovskiy gosudarstvennyy urilversitet.

ACCESSICK IM: AP4021979 S/0O73/64/b3o/6oe/oi9o/ol94
AU1THOR:.Zemlyanqkiyp_N._I.j Turkevich,, v. v.j muravoyev, I. vt; Bary*lyukp V.W
TITLE: Spectral characteristic of the P&S bond in certain dithiophosphates
SOURCE: Ukrainsk.Ly khimicheskiy zhurnall v. 30, no. 2 1964 190 -194
TOPIC TAGS: vibrational spectrum, IR spectrum,ditbiophosphate, phosphorus sulfur,
double bond, alkyldithiophopphate,, aeyldithiophosphate, acyldithiophosphatej,
frequency shiftj, phosphorus sulfur bond frequencyp spectral analysis
ABSTRACT: The vibrational spectra of a number of dithiophosphates were studied i0i
determine the possibility of applying such physical methods to the determination'.
of molecular structures of these phosphorus organic compounds. The IR spectra in!,.-.
the 400-2400 cm-1 region of a series of alkyl and acyl derivatives of di4tio-
phosphoric said were examinadl the position of the frequency of the Pas Vibm.
tiona in these compaunda was determined to be in the 640-680 ca-1 ranges The
additional environment of the P atom affects the vibration of the PzS bonds. Thel
more electropooitive the C atom bound t6 the S., the greater Is the shift (vip to
1 /2

ZEMLYANSKIY, N.I.; TURKEVICH, V.V*; MURAVIYEV, I.V.; BARYLYUK, V.V. r
Spectral characteristics of the F'S bond in some dithiophosphates.
Ukr.khim.zhur. 30 no.2:190-194 164, (NIRA 17:4)
1. Llvovskiy, gosudarstvennyy universitat Imni I.Franko.

.ZEWANSKIY, N. I.; ILIMOVS Aq L. L(deceaead]; GALIBEY, V. I.;
MbHy B, .; MURAVIM, I. V.; TURKEVICH, V. V.
Synthesis of some derivatives of eaters of 0,,Ol-dialVIphm-
phorodithioic acids and theirAftfrared spectra. Zhur. ob.
khim. 32 no.1214066-4069 ID 162,, Wn 16: 1)
1. Livovokiy gosudarst7enrqy universiteto
(phospborodithioic acid-Spectra)

ZENLYA~ja&11.,I~I,j DRACH, B.S.; prinimali uchantiyo: GOLECIIEK., A.A.;
"~- YURVIENKO) S.A.
Synthesis of salts of some 0.0-diaryldithiophosphoric acids. Zhur,
ob.khim. 32 no,6:1962-1966 Je 162, (MIRA 15:6)
(Phosphorodithioic acid)
.1

ZIZILYANSKIY� IU PRIB,, O.A.; DRACH, B.S.
Reaction'of potassium 0.0-dialkyldith~aphosphates with aromatic
-sulfon chlorid6s. Zhur.-ob. khim. 31 no.3:880-883 Mr 161.
-Yl
(MIRA
1. L*1*67skiy gosudarstvennyy universitet.
4-rdnyl chloride) (Phosphorodithioic acid)

5.3630 77893
SOV/79-30-2-44/78
AUTHORS: OlIfirenko, S. P., 21'emlyanskiy, N. I., Lylyk, A. M.
~TITLE: Synthesis of Acyl Derivatives of O,O-Dibutylthio-
phosplioric.Acid
PERIODICAL: Zhurnal obshchey khimli, 1960, Vol 30, Nr 2, PP 579-580
(USSR)
ABSTRACT: The synthesis proceeds in the following stages: (1)
synthesis of' dibutylphosphite; (2) obtaining sodium
dibutylphosphite4)(3) synthesis of' 0,0-dibutyl-
Lhlopho8phate; ( t3yntheal.3 of acyl derivatives of'
0,0-d1butylthlophouphorle acid# Since the ijyntheql~
Card 1/3
oi' sodium 0,0-dibutylthiophoophate was not previously
described in literature, it Is g1ven below. Metallic
sodium In absolute benzene was otirred with 0,0-dibutyl-
phoophorous acid under water-free conditions. After 20
hr excess sodium was removed, and powdered oulfur was
added in small portions-with.vigoroua stirring and cooling.
After addition, the mixture wao heated for 30 min at 600 q

Synthesis of Acyl Derivatives of O,O-Dibutyl- 77893
thlophosphoric Acid SOV/79-30-2-44/78
and benzene was removed by dIstillation until crystals
started to f'orm. Final removal of' benzene and crystal-
lization were done under reduced preeaure. Acyl
derivatives of 0,0-dibutylthiophouphoric acid were
obtained by treating the sodium ualt with acid chlorides
of benzoic, succinic, glutaric) and adipic acids. Results
of the reaction and some physical constants are given in
the following table;
cylation of Sodium 0,0-Thiophosphate 1,-[ith Acid Chlorides
rOAMULA or Y1GLD 21 jai
ACYL DPMVATJVC ho
(q41VO),1, SOCOC4113.
C
(Cjt4O)A11SOCO(C111VO()SV( *
(r4j~Oh.
(C4)1j0).,VS(1CO(C1 10 SCOOSP
There are I table; and 10 references,
I U.S. The U.S. reference Is:
Card 2/3 Organophosphorous Compounds, N.
410 1.50M 1.066
a5:4 1.466
78,0 1,158
192
I Polish, 8 Soviet,
0. M. Kosolapoff,
Y.) 385 (.1956)_

Syr~thesis of Acyl Derivattlives of 0,0-Dlbuty-l- 7 7 82 9 -1
thiophosphoric Acid SOV/~9-30-2-44/~P,
ASSOCIATION: L'voV State University (Llvovskiy gosudarstvennyy
universitet)
SUBMITTED: May 15, 1959
Card 3/3

ZWILYA?ISXIY,. N. I.
Combustion of hydrocarbons chlorine. Ilauk. zap. Vviv. un- 13:
103-112 149. 1~ (KRA 12: 10)
l.Kafedra organicheakoy khimii Llvovskogo goeudarstvennogo universiteta
imeni I. Franko.
(methane) (Chlor".0

i i i ~ ~ - ~- /2r T
ZEMLYANSKIY, H.I.- MALINOVSKIY, M.S.
Synthesis of acyl derivati7es of 0,0-dialkylthiaphosphates. Zhur.
ob.khim. 26 no.6:1677-1678 Je 156. (MMA 11a)
l.Livovakiy gosudarstvennyy universitet.
(Chemistry, Organic--S7nthesis) (ThiDphosphates)

ZEMLYANSKIY,_U,L1,FRIB, 0., student IV kursa; SHARYPKINA, M., student IV
-----~kursa; KOSTSITKO, A., student III kursa; GLUSHKO, A., student III 1mrsa;
KOZOWNIKOVA, 0.. student III kursa; KRASILOVSKAYA, T., student III
kursa; SMODA, N., student III kursa; PIPTOVA, N., student III k-ursa;
TSERKEVICH, G., student III kursa; SHAM, V., student III kursa
Condensation of aromatic hydrocarbons vith halogen derivatives of
aldehydes. Nauk. zap. Lviv. un. 13-.129-135 '0.
(MIRA 12:10)
l.Kafedra organicheskoy khimii Llvovskogo gosudarstvennogo universiteta
im. I. Franko.
(Hydrocarbons) (Aldehydes)

PjLvOvj Ye-M.; MLYANSEY, N.N.; KOCIIESHKOV.. K.A.
. Study of the element-oxane bond. Lead oxanes. Dokl. Ul SSSR 143
no.3:603-605 Mr 162. .. (KM 15:3)
1. Fiziko-khimichaskiy institut im. L.Ya.Karpova. 2. Chlen-
korresponsent AN SSSR (for Kocheshkov).
(Lead organic co'mpounds)

im
ZEMLYANSKIY N.N.-, V.N.; PANOVO Yodi.; KOCHESHKOV, K.A.
Synthesis of plumtyumnes of the (RCCOPbAr2)20 tyPe- Zhur. ob.
khlm. 35 no.5:843-F45 My 165. (MITRA 1826)
1. Fizi.ko-khImicheakiy institut imenj Karpova, Moskva.

ZERLYA10MY II.N.- PIM11, YOA~ SHAMAGNII, O.P.; KocIff-SHKOV, K.A.
~ ~ : -- ~ - - - ~: ~7 - I I
Synthesis of tin oxanes RCCO(Sn(C4H2)2O1 OCR. Zhur. ob. khim.
35 no.6ilO29-1031. Jo 165. (M-IRA 18:6)
1. Fiziko-khholcheskiy institut imeni Karpc-.a.

S/020/62/146/006/010/020
B1061BI86
AUTHORSt jemIL Panov, Ye. M.t Kocheshkov, K.A.,
._ 4
Corresponding Member AS USSR
TITLEt Dialkyl tin
PERIODICALt Akademiya nauk SSSR. Doklady, v-
.146, no. 6, 1962, i335-1336
,
TEXT; As.no reliable method has so far been worked out for the synthesis
of tin dialkyls, the data published on these compounds differ greatly.
Referring to a reaction made by G. Wittigt F. I; Meyer, G. Lange (Ann.$
571, 167 (1951)) the authors of this article succeeded in synthesizing
anal.ytical-grade.di-n-butyl tin and diethyl-tin by reacting a suspension
of anhydrous SnCl 2 in a 1:4 mixture.of ether and benzene with an.ether'so-
jution of n-butyl lithium and with ethyl lithium, respectively (reaction
temperature, -10 0C; molar ratio between SnCl and alkyl lithium - it2).
Di-n-butyl tin is thus obtained in a yield oi 63.7% and in the form of a
dark cherry-red oil readily soluble in hexane, benzene, toluene, ether,
chloroform, and carbon tetrachloride, but poorly soluble in alcohol and
Card 1/2

S/020/62/146/006/010/020
Dialkyl tin B106 B186
acetone. Diethyl tin is obtained similarly in a yield of 40-0 in the'form
of a dark, cherry-red oil which is as soluble as di-n-butyl tin. Both
tin dialkyls oxidize in air and more quickly in solution. In the case of
di-n-butyl tin, a white, 8roduct is formed, which, together with HC1, gives
(C 4H912 SnCl 29 M.P. 42_43 C. The oxidation of diethyl tin is more complex,
Di-n-butyl tin reacting with bromine in CCI 4 gives (C4 H9)2 SnBr 2, m' P.
18.5-19.5, in a quantitati-te yield. Di-n-butyl tin heated in a sealed
ampoule with an argon atmosphere begins to precipitate metallic tin at
0
230 C. The tin dialkyls synthesized here are polymers. Their molecular
weights were determined by cryoscopy and ebullioscopy and were found to be
1780 and 1633, respectively, for diethyl tin, and 1921 and 1745, for
di-n-butyl tin. There is 1 table. The most important English-language
references are: T. Harada, Sci. Papers Inst. Phys. Chem. Res. (Tokyo),.
35, 290 (1939); S.F.A. Kettle, J. Chem. Soc.r 1959p 2936.
ASSOCIATION3 Fiziko-khimicheskiy institut im. L. Ya. Karpova (Physico-
chemical Institute imeni L'. Ya. Karpov)
SUBMITTED; July 9, 1962
Card 2/2

rEMLYANSKIY N.N.; PANOV, Ye.M.; SLOVOKHOTOVA, N.A.; SHAMAGINA, O.P.;
K. A.
Stepped formation of compounds with a stanno-oocane bond and reactive
terminal groups. D6kl. AN-SSSR 11*9 no.2012-315 Mr 163.
(MIRA 160)
1. Fiziko-khimichaskiy institut im. L.Ya.Karpova. 2. Chlen-k6rres-
pondent AN SSSR (for Kocheshkov).

.,gEMLYANSKIY. N. N.; GOWDSHTEYN, I. P.; GUFIIYIINOVA, Ye. N.; PANOV, Ye.
'----'~~fbVOKOTOVA,
N. A.; KOCHESHKOV, X. A.
M.;
Structure of compoinids with a stannoxane bond studied by means
of dipole moments and infrared spectra. Dokl. AN SSSR 156 no.
1:131-134 My 164. (MIRA 17:5)
1. Fiziko-khimicheskiy institut im. L. Ya. Karpova. 2. Chlen-
korrespondent AN SSSR (for Kocheskhov).

DaM "Fit 163
(MITRA 18:8)
0
------------- - ---------

SLOVOKHOTOVA, N.A.; FAYZI, N.A.; ZEMLYANSKIY, N.N.; PAROV, Ye.M.;
KOCHESHKOV, K.A.
Structure of some organotin salts of carboxylic acids. Zhur.
ob. khim. 33 no.8:2610-2613 Ag 163. (MIRA 16:11)

39170
5/062/61/000/012/011/012
00 B117fB147
AUTHORS; Kocheshkov, K. A., Panov, Ye. M., and Zemlyanskiy, N. N.
TITLE: Stepwise formation of the elementoxane chain in the presence
of diazo alkanes
PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 12, 1961, 2255
TEXT; In the present "Letter to the Editor"t the authors report on the
reaction of elemental arganic compounds with diazo alkane. The.- -2oint out
that the usually-practiced hydrolysis, etg., of R 2Sn (OOCR)21 rnenlts in a
mixture of organic tin compounds. In the case examined, an increase of
the elementoxane chain takes place whereby, during the individual stages,
pure products are isolated and the RCOO end groups ar8 preserved, , such as
for,(n-C4 H9)2 Sn(OOCCII3)2. Monomer (boiling point 142 - 145 ac (100 mm Hg))
dimer (melting 60'C) tetramer (melting point
0 point 580
1380 -- 139 C) ~o octamer (decomposition at above 2000C), eta. The
Card 1/3

30170
s/W/61/000/01'2/P~/012
stepwise formation of the... B117/B-147
reaction is shown by the example of two elements On, Pb). The authors
concluded, however, that the reactionmay be extended to o*&er elemental
organic compounds comprising at least two saponifiable groups itthe
element (e.g., R 2 Si(OOGR )2 or RM (OOCR)2 , etc.). With cliazomethane:
(a) 2R23nX 2 (1) ~ X(R)2 Sn-O-Sn(R )2X (")- (I') is 020H42 0 5Sn2 having
a molecular weight of 591. (b) 2X(R )2 Sn-O-Sn(R Y (I') 3~1
X(R) Sn- H 0 Sn , molec:z).r-,r weight
2 EO(R)Onl -X (I,,)' (III) is C36 78 7 4
1109. (c) 2X( R)2 Sn- lo?R)2SnJ,-X (111) 0 X(R )2 Sn-EO(R )2Sn]7-X (IV).
(IV) is C 68H150 011 SnVmolecular weight 2156. In each case, R - n-C 4H9
and X - OOCCH 3' (d).2R 2PbX 2 (1) ~- X(R)2 Pb-O-Pb(R Y (',)' In this
case, R - C6H5 and X w OOCCH (OH3)2' (I,) is C32H3405 Pb, decomposition at
240OC- (II) was also obtained with diazoothano and diazobutnno.
[Abstracter's notet Essentially complete translationj There is I Soviet
reference,
Card 2/3

33932
S/079/62/032/001/009/016
,57 D202/D302
AUTHORS: Zemlyanskiyg N.N9 Panov, Ye.M,, and KocheEtkov9 K.A.
TITLE: Synthesis of organostannic salts of organic acids
PERIODICAL: Zhurnal obshchey khimii, v~ 32, no. 1, 1962, 291-'Z,9`,
TEXT,~ The autho.-s describe a new method of preparing organosllannic
salts with organ:'c acids by an exchange reaction between organic
lead salts and organic halides of ting stating that this reaction
takes place easily with fairly high yieldsy e,,g~ (Bu) 2SnBr2 + Pb
(OOOC.Ch 3)2 ---> (Bu, )2 Sn(OOC.CH 3)2 + PbBr2o The lead salts of liquid
organ.4;c acids can be obtained by dissolving litharge in the corres.-
pondin6 a-lid and may be directly used for the reaction; organostan- V~
nio salts of dicarboxylic acids can be obtained by direct action
of th(, acid-on tin tetraothyl, The etarting Sn organic chlorides
were.lobtained by usual methods., The authers synthesized 6 known and
3 nE;w compound* and give full details of the Drocedure, 1) Triethyl
till a0etate Wdu obtalned in 7?,~8 % y1old by boiIJ&P.- lead acetatle
Card 1/3

335 32
S/07Y62/ 03 2/001/009/01 -0
Oynthealf) of organol3tannic salts ... D202 D302
W 1 th" tr-;'_%,tllvl -tin chloride. 2) Tributyl tin acetate fvom load Roo-
tate and tri-n-bu~yl tin chloride; yield -- 84.5 %. 3) Triethyl tin
methacrylate from PbO in methaerylic acid and triethyl tin.chlori-
de, yield - 58.7 %,, 4),Tri-n-buty-1 tin methac-ryl,,,,.te 'Lr-om PbO in me-
thacrylic acid and tri-n-butyl tin chloride; yield - 99.1 %. 5) Di-
n-butyl tin diaoetate fFom lead acetate and di-n-butyl tiz4z bro,4.e,
Field 85.4 %. 6) Triphenyl tin acetate from lea-d' acelk"ate and
chloride-, yield 84*5 %. Physical const'ants determined for
these products were in very good agreement with data given in 14.-te-
rature. 7) Diethyl tin adipate was obtained by heating te-1.1-aethyl
tin with adipic acidw yield - 90 %; m,-p. 143-1440C. The compound
is soluble in cold CH01 3 and, in hot bc~nzene~ toluene,, tylene, di-
chloethane and CC1,0 8) Diethyl tin azelate was obtained b7 heating
tetraethyl tin and azelaic acid,, The yield was 7q-.95 %~ m.D-- 121-
124-510C. Its solubility is similar to that of the adipate, 9) D1-
ethyl tine sebacate was obtained in the same way from tetrasthyl
tin and a slight ex!~*.ess of sebacic acid. The yield was 64,9 %-,- M~).
122-123M Its solubility is similar to that of the above compounds.
Card 2/3

S/020/62/143/003/018/02~
B110/B138
AUTHORS: Janov, Ye. M.f and Kocheahkovi K. A.,
Corresponding Member AS USSR
TITLE: Investigatioli.of the element-oxane bond. Lead oxanes
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 143t no- 3P 1962, 603-605
TEXT: A method is described for the synthesis of compounds with lead
oxane bond which'may also be used for other elements. The compounds
Ar2PbX 2 and ArPbX (where Ar is the aromatic radical and X is the residue.
3
of the organic acid) have low moisture resistance. When left standing in
air, their melting point drops and impurities insoluble in organici appear,
During recrystallization, even with the freshly precipitated compoundy
some drops of acid must be added to prevent hydrolysis. From a solution
of diphenyl lead diacetate in a mixture of acetone and water, 15-20% of
the substance will gradually separate in the form of (C H Pb(OH)-OCOCH
6 5)2 3
Hydrolysis of Ar Pb in the presence of diazoalkane produces the
2 (OCOR)2
lead-oxane bond:
1/3

/04
S/020/62/143/003 16/029
'Investigatiomof the element- BIIO/BI38
2(QHI),Pb(OCOCH3)3'-t-2HsO-*-2CH3N2--*2CH3COOCtio-~-2Ns
CsH& Colis
-i-MCOO-Pb-0 ~b - OCOCHs
After addition of water 1-2 ml ethereal diazoalkane to the acetone solution' 4
of Ar Pb(OCOR),, tetraphenyl diplu'mbo-oxane diacetate crystallizes out I ~1~
2
within a few minutes,, Excess diazomethane produces almost quantitative
yield. In the same wayp tetraphenyl diplumbo-oxane was obtained with a It
yield of 72~.- As th,a reaction does not take Place with dry eolventsp the 1
hydrolysis of the organo lead salt is the first reaction phase. Diazoalkane,
not participate in the synthesis of thq final product, but only binds'
the acid formed during hydrolysis, thus preventing reaction reversal. When
-heating with -organic acids) the lead-oxane bond,is t oken, and the initials
product is re.-formed, There are 5 references.-The moit important re ,fereme;
to English-language.publications is. W. T.Ieichlep -To Polya. Saio,
521 (1961).
Card 2/5
=old

WW/RH
IJP(
AUTHOR: Gellfman, Ya. A.; Zemlyansky, N. N.; Lauris, I. V.i Syutkina, 0. P.; Kuskova,
IV. P.; Paa__o_y_T_e. M. ........
ORG: none
TITLE: Stabilization of polyvinylchloride by oraanotinoxanesl~
S6URCE: Plasticheskiye massy, no. 9, 1966, 10-11
TOPIC TAGS: vinyl chloride, polymer, tin compound, organotin compound, o.rganometallic
compound, solid mechanical property, heat resistance
ABSTRACT: The effect of organotinoxane-type additives [CH3COO(C4H9)2SnO, to
CH3C0O1(C4Hq)2Sn0340CCH3, and [CjjH23CO0(C4H9)2Sn32O3 on the thermal stability of
polyvinylchloride was investigated. The aging characteristics of the stabilized PVC
was tested according to GOST 10226-62 and the decomposition temperature was tested
according to the GOST5960-51 standard. It was found that the PVC stabilized with
organotinoxanes had a therinal stability comparable to that of PVC stabilized with con-
ventional R2PbX2 stabilizers. It was also found that the organotinoxane stabilizer
based on acetic acid was as effective as that based on lauric, acid. Orig. art. has:
tables.
SUB COM 1l/ SUBM DATE: 00/ ORIG REF: 004/ OTH REF: 004.
Card 1/1 not UDC., 678.743.22:678.048.9

KOPANTM, H.H.; ZEKLYANSKIY, P.14.
Building sulfur dioxide exhauBt fans with facilities existing in
the enterprise. Bum.prom. 31 no.1:14-16 Ja '56. (K1,RA 9:5)
1. Vtoroy laliningradakiy teellyulozno-buma2hnyy kombinat.
(Woodpulp industry) (Exhaust systems)

99R
BEREZOVSKIY, V.A. [Berezovslkyi-, V.A.); ~~YAN~ IY,4,,~~Zomlianslkyi, S.V.)
Temperature variations in the gastric mucosa qaused by a'cetylAoline,
adrenaline, aad xoxiadrenaline. Fiziol. zhur. (Ukr.] 7 no.2:2.35-
21,2 Mr-Ap 161. (MIRA 1414)
I..Laboratory of th6 Physiology of Digestion of the A.A.Bogomolet,
fnstitute of Physiology of the Academy of Sciences of the UkraiAian
S.S.R.,-Kiev., and the Department-of General and Expqrimental Pathology
of W.arsa,4 Pathology of Warsa~r Medical Academy.
(BODY TEMPERATURE-) (STOM&CH)
(NERVOUS SYSTEM. AtTONCMIC)

ZMLYANSKIY. S.V. (Zemlianslkyi, S.V.]; BEREZOVSKIY~ V.Ya. [Derezovalkyi,
V.IA.]
Changes in the temperature of the gas.tric Ncosa due to the effect
of histamine. Fizlol. zhur.-[Ukr.j 6'no-3:))6-343 My-Je 160,,
(MIRA 13:7)
1. Institut fAziologii im. A.A.B~ogofholltsa All USSR, la~oratoriya
pishchevareniya i Varshavskaya 14ditsinakaya Akademiya'~ kafedra
obshchoy i eksperimentaltnoy patologii.
(STORACII-SECIMIONS) (BODY TUeERATURE)
(HISTMIIIIE)

bUU11f
j ;-CUDEf 105
UR/0420/65/000/002/00
ORi V8 TO 10 5
;TH(
AT;THOR: Zemlyanaki A. (Docent)
1'n
G.
ORG- None
F
TITLE: Investigation of the t1wee-dimensional kforn
Lation of a. metal subjected to_pM#1An
by a circular rotary cutter
SOURCE: Samoletostroyeniye i teldmilm vozduslinogo Rota no. 2t -1965~ 98-105
TOPIC TAGS: metal stress, metal cIatting, material deformation
ABSTRACT: The article describes an, investigation of thriee-dimensional deformation of a
metal chip being cut on a circulax rotary cutter. The study dealt with the region of optimal
conditions N = vd; where vc is the circular velocity of the cutting edge and vd Is the speed of.
descent of the chip). The following conclusions are reached. The longitudinal deformations
of the chip (compression and shear) are uniform and are determined by the angle'of Inclination
of the cutter axis X. The transrerse deformations of the chip depend on the cutting pattern,
the size of the static back-rake angle of the cutter, and cutting speed; the nature of this
relationship is analogous to similar relationships for standard cutters. - The most substantial 'J
decrease in the degree of -deformation is noted with an increase in angle A. The field of de-.
formation In the transverse cross section of the chip Is highly non-uniform. The metal under-
goes its greatest deformation not only on the surface'of contact with the front edge of the
cutter, but also on the chip-worked piece surface, which Is. never In contact with the back
I Card 1/2

ACC N': AP7005574 M SOURCE: CODE: Ull/0145/66/000/011/0120/0124
AUTHOR:-
V. A. (Docen' 0; Alekseyev, Yu. (Professor; Doctor of
technical sciences)
ORG: none
TITLE: The calculated basis of the wear resistance of round rotating cutting tools
SOURCE: IVUZ. Mashinostroyeniye, no. 11, 1966, 120-124
TOPIC T.:-IGS: wear resistance, cutting tool, rotating cutting tool, metal cutting
physical parameter
ABSTRACT: A theoretical evaluation is given of the reasons for extenaing the
period of wear resistance of the cutting tool by replacing. the standard cuttina tool
0 10
with a rigidly fixed cutting edge by a round rotating cutting tool. The effect appears,
to be due to the shortening of the path of a point on the rotating cutting edge in
material being machined and to decreasing the wear of its faces through a favorable.
change in the physical parameters in the cutting zone. The paper was presented by
Professor Alekseyev,- Yu., Doctor of technical sciences, Eharlkov Aviation Institute,
02Nov65. Orig. art. has: 2 figures and 12 formulas. (Translation of authors I abstract)
SUB CODE: 13/SUBM DATE: 02NCov65/ORIG REF: U13/ I
Card 1/1 UDC: 621. 90. 025 INT] I

L 27147~t J~IT~ &T
ACC NR:
AP6006141 SOURCE CODIE: UR/0420/65/000/003/0086/0091
AUTHOR: Zomlyanskiy_, V, A, (Docent)
ORG: none
TITLE, Wear 'of round rotating
_EuttiE& tools as a function of cutting edge path in
the machined material ILI
SOURCE: Samoletostroyeniye i tekhnika vozdushnogo flota, no. 3, 1965, 86-91
TOPIC TAGS: rotating cutting tool, cutting tool, tool wear
ABSTRACT: The wear of round rotating cutting tools (RRCT) as a function of cutting
edge path in the machined material was thoorotically and oxporimontally investigated.
Based on the special kinematics of PdICT's (V. A. Zemlyanskiy. Kinematika rezaniya
la-uglymi sa,movrashchayushchimisya reztsami. Sb. Samoletostroyeniye i tekhnika
vozdushnogo flota, vyp. 1, Izd--vo KhGU, 1964)jan expression for the tool life is
derived as h
AVVam~7 V P. C, D. T, L
H,
(where
V Cos
UDC: 6G
Cl~.l
Lqa-rd 1/2

ACC NRs AP0006"1 0
normal nomenclature). The average tool velocity %V is always lower for RRCT's
than for normal cutting tools. Based on these equations, the best cutting param-
eters for maximum productivity for rough cutting and finish cutting of materials
with RRCT's are derived. Experimental data for various cutting conditions are
presented to support the 'derived equations. It was found that the accumulated wears-.'
is directly-proportional to the cutting time, average cutting edge speed, and to
the cutting edge wear coefficient,, Orig, art. has: 3 tables, 4 figures, and 14.,,,,;;,:
formulas.
SUB CODE: 13/ SUM DAM none/ ORIG REF: 005
2 /2

/V1 L YA- M5 A-
?1UTHOR: None given 122-2-33/33
TITLE: Dissertations (Avto~aferaty-.dissertatsiy)
PERIODICAL: Vestnik Mashinostroyeaya$ 1958, No.2, p.86 (USSR)
ABSTRACT: N.F. Bocharnikov - Research into Ways of Substituting
Tin in Cast Copper Base Alloys ( Izyskaniye putey zameny olova
v liteynykh splavakh na mednoy osnove). submitted to TsNIITMASh.
As a result of laboratory research carried out by the author,
a copper base alloy has been obtained not containing tin and
possessing good mechanical and casting properties, as well as
satisfactory anti-friction properties and a good resistance
against corrosion and cavitation. It is noted in the conclusions
that the alloy so obtained can, in many instances, replace tin
bror,es and aluminium bronzes which have poor casting qualities.
V.A. Zemlyanslqy - Research into the Process of Chip Breaking by
_WT-0T1-ng T7o-ol ii-ro-vided with a Chip Breaking Device (Issle-
dovaniye protsessa drobleniya Btruzhki na reztse so struzhkolomom)
Submitted to the Moscow. Aviation Production Institute (Moskovskiy
aviatsionnyy tekhnologicheskiy institut). The' work contains an
analysis of the forces acting on the chip breaking device. A
procedure for designing the chip breaker dimensions is proposed
and verified. This'procedure is suitable for different con-
ditions of machining and does not require complicated computations
Card 1/2

Dissertations
122-2-33/33
or tables.
L-V. Khudobin - The Development and Zvalu~tLon of Novel
Production Methods with Cylindrical Grinding Machines
(Razrabotka i iseledovaniye novykh tekhnologicheskikh voz-
mozhnostey krugloshlifovallnykh stankov). Submitted to the
Moscow Machine Tool and Tool Institute imeni I.V. Stalin
(Moskovskiy'stankoinstrtimentallnyy institut imeni I.V. Stalina).
Possible methods of production using cylindrical grindinK,
machines provided with an automatic system of control, 11
monitored by the magnitude of the radial grinding force are
considered. Tests carried out on a cylindrical grinding
machine with longitudinal workpiece traversing were the basis
of the automatic control system described.
V-V- Zars - Research into Vibrations in Turning (Issledovaniye
vibratsiy pri tochenii). Submitted to the Leningrad Polytechnic
al Institute imeni M.I. Kalinin (Leningradskiy politekhnicheskiy
institut imeni M.I. Kalinina).
AVAILABIZ: Library of Congress
Card 2/2

ZEMLYAWSKIY, V.A. , kand. tekhn. nauk, dotsent, Yu.P., aspirant
Defuvrkttlon of the cuL.-off layer in out irietals with romid
self-retating cutting'tools. Izv. vys. uchob. zav.; rashiziosi.r.
no.3:151-157 164. (m I it A 17:
I. Khsxlkovskl.y aviatsionnyy institut.

GMBg T.V. [Horb, T.V.], doktor sellskokhoz.naulc; TMESHCHMO, F.K.,
kand.biolog.naiik; O.T. [Bohaievsflqri, O.T.J, kand.
vaterin.nauk; POTYCKMO X.D.'s- [Pot fomkin, M.D.Jiakademik;
KNIGA, M.I. [Knyha, M.I.1; FOPff, O.Ta., kand.BOllskokhoz.it~;
MIMIK, G.G. CHmelyk, H.H.1# kand.sel'skoihoi.nauk; WAM9 1 0P*0
kand.eellokokhoz.nauk [deceased]; KOPIL, A~M., k~tna.iellskokboz,
nauk; TSELYUTIN. V.K., kand.seliskokhoz.nauk; BOZHKO, P.Tu.,.doktor
sel'skokhoz.nauk; KROKIN, S,S., kand.sellskokhoz,,nauk, ZEMLTANSKITo
V.M. [Za-mlianalkvi, V.K], kand, eel lokokhoz.nauk; BORISHEKO, C.W-~
[Borysenko, A.M.1, kand.biolog.nauk; ZAZRAREWO, V.13., kand.biolog..
nauk; SMIRNOY, I.V. [SmyTnov, I.V.], kand.biolog.nauk; ENtABUSTOVSKIY,
I.F. [Xhrabustov's'kyi,'I.F.3, kand.biolog.nauk; TORSTYANMSKATA, K;N.,
M. N.
,[Trostianet,Oka' 1, assistent; ALNSHKO,, F.I.,.inzh.; VASIL.IYEV,
Tasylliev, O.F., kand.tekhn.nauk-, BUGAMMO. I.I. [Buhaianko, I.I.1,
starohiy propodavatell; TRAMOMIR07A, 0.0., kand.ekonominmuk-
BTJTKO, -S.D. kandoekonom.nauk; MUSHIK, E.G. [Teleshyk,
doktor ekonom.na~; TAROSRIWO, V.D.j kand.okonom,nauk; tISIT# LT.
CLYBY1, I.I.J., red4;_7XROSB=O, T.G.. CISroshenko, T.H.], tekhn.red.
[Handbook for sootechnicians] Dovidnyk,zootekhnika. 2., dopovuene
i poreroblene vyd.. . H~riv, Derzh.vyd-vo oil Is 1kohospodars Okoi- lit-ry
TJRSRp 1960.~:. 728 pe, (MIRA 15:2)
1. Vsosoyuznaya akadomiya ael'okokhoz, stvenuykh nauk imeni V.I.
ray
Lenina (for Potemkin). 2. Chlqu-korreopondent VsGsoyuznoy akadomii
yk1a nauL
eel skokhopgystvenu imani X,,I.Lsnina (for Kniga).
&,)took and stock bro eding)

X61.3-115 Obstet.&
0
--807... BLEPHANnAsis OF THE -VULVA (Runsian text) Zemlyansky V.,
ARKH. PATOL. - 1957,.19/7 (71-73) Illus. 2
Elephantlasis wilvae Is rare In Europe but more common in the Near East, India
and In Central America. Its aetiology has not been established but the condition
may be attributed to interference with lymphatic drainage. The author reports,2
cases of this disease. In the first case'a 33-year-old woman developed rA tumour
38 x 25 cm. in the left labium minus following tb of the inguinal lymph nodes. The
lesion was resectled and histological examination revealed connectivetissue hypera-
plasia, oedema, cnd marked proliferation and dilatation of the lymphatics. The
second patient a 38-year-old woman, had atumour of the left labium majus,
48 x 28 x 24 cm. in size. The enlarged labiurn was removed surgically and was histo-
logically very-aitnilar to the first case. In this instance the aetiology of the elephan-
tiasia could not be ascertained. Wilson - Dearborn, Mich.- (V. 10, 16)

UISOlFarn 11orscs.
s Jour: Re fZhur-Diol., N.-~ 20, 1958, 92568.
AuVior
..,_
Inst Y_,rhhav Zootcclmical Institute.
Title :'The Amplitude of *wcnert "in the Joints of the Extre-
idties in TrottinGlliarscs.
OriG Rib: S13b tr.1 Yjmr'3'Ovsl. zooteldm- in-tas 1.9 5 7., 10, 215-
227.
Abstract: T'lic pace in trottorb v a batudied., 1; (lescription In
L;ivon of the relative position -of the extreuLtiao.
during various stafys of mmarxi-it - at* a wnll:, a trot
cu-,d when racin6t - Illic AmIm,.ontal functions of the
extrevIties were studied in OLiversu sectors of nove-
mnt. The lenrth of the stride and sector in horses
Card
VP
47

ZEMLYANSKIY, V. N., Doe Biol Sci (diss) "On certain regu-
larities in the biomechanics of of the
horsex in terms of factors influencing its basic productivity."
Khartkov, 1958, 21 pp (Min of Agriculture USSR, nar1kov Vet
Inst), 160 copies (KL, 35-58, 106)
-20-
I". MEMIMFM

Yi
Z3HLYANSKZ.,,,'V,.N. (Leningrad)
Vulvar elephanthiasis [with summaz7 in linglishl. Arkh.pat. 19 n0,7:
71-73 '57. (KTRL 10:9)
1. Iz kefedry patologichaskoy anatomli (zav. - prof. P.V.Sipovskiy)
Goeudarstvennogo institute dlya usoversheastvovaniva vrachey i
Kologrivskoy gorodskoy bol'altsy.
(TIJBIMOULOSIS. MULF. GENITAL, complications,
vulvar elephanthiasts (Rrs))
(LYMPEMHA. etiology and pathogenesis,
vulvar elephanthiasis caused by tuberc. (Rus))

V. ".
t,
Zeml-ans',:1.y, V. u. - ItTlic ~,.loto(,raphlc rotliod In the olt-Aldy of tl,,r.- mcchani-lm r--Af
I/ . v, I I
liorso viovoronts", Sboimlk Trurlo , (Darl1c. nootall1in. III-Q, V01. Vi lonuo 1, 1949,
p. 93-142-, - Bibliog: 31 items.
SO: U-301v2, 11 March 53, (Letopis I Zhurnal I nyl-h Statcy, No. 8) ~ 1949) .

1 MMYANO'KIY) V. N.
2. USSR (6oo)
4. Water Supply, Rural
7. Mechanical method for watering horses. Konevodstvo 23, No. 5, 1953.
9. Monthly List of Russian Accessions, Library of Congress Aoril 1953. Unclassified.

ZU NS
MILYAN Krf) V. N.
Zemlyanskiy) V. N.
"Some la-,.is of the biomechanics of motion and footing of the horse as
factors influencimm. its basic productivity."- lliji Higher Education
Ukrainian SSR. Ukrainian Order of Labor Red Banner ACricultural.Acarlemy.
Kiev., 1956. (Dissertation for the Degree of Doctor in Agricultural
Sciences).
Knizhnaya latopist
No. 21, 1956. Moscow.

Onectitits AND Factcallif 11.019
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ZDMYANSKI,,' V.A inzhener.
.... ............... ....,
Designing chip breakers Vest.mash. 37 no.6:57-62 Je 157. MRA 10:7)
(;~chine tools--Attachments)

(Ilrollt"(11 (if Chi' Ilowkiltif.)
adrijbte"If. V. A. ZemlialAii. Vninik
jV "'.
M. 19. rkc. IM, '77-M
~aWujjfm of t,hfp lu_kjng procm; critMon, of its defonnation
whtO pmilitg s-epurmfw'a ofcurling gild hvm~iftg mues, Dia-
gr4nw, ~graplti, tab6. 20 ref,

Vq:L-jA -,qM -A -58-------
K4holo
2055 R"THIASIS Or, TIIE VULVA (Russian text) - Ze ml:,a no lay V. N.
E&PIN
ARKIL PATOL. 1057, 19/7 (71-73) Illus. 2
Elephantiasis vulvae is rare in Europe but more common in the Near East, India
and in Central America. Its actiology has not been established but the condition
may be ,attribuied to interference with lymphatic drainage. The author reports 2
calico of thJs disease. Jn the first case a 33~-year-old woman developed a tumour
38 x: 2 5 c m. in the left lablum mlnus following tb of the inguinal lymph nodes.' The
lesion was resected and histological examination revealed connective tissue hyper-,
plasia, oedema. -and marked proliferation and dilatation of the lymphatics. The
second patient, a 38-year-old woman, had a tumour of the left labium majus,
48 x H x 24 cm. In size. Tito enlarged labium was removed surgically and was
histologically very similar to the first case. In this instance the aetiology of the
elephanthissia could not be ascertained. Wilson Dearborn, Mich. (V, 10, 16)
7~4

ZEMLTANSKIT, Ya,G,, gornyy inqhener.
~~qate'r awAining vacuum wells" by S.V.Jtomissarov Reviewed b7 E.G.
Zemlianskii. U&oll 32 no.2:47-48 7 '57- (MLRA 100)
1, Trest Soyuza"toosusheniye.
Mine drainage) (Komis'earov, S,V,)

?,I[

ZEMLYANSKOVP V.De; CHEPLANOV, VOI,
Improvement of planning indices in ferrous metallurgy. Stalt
2) no-5:471-473 My 163. (WRA 16:5)
1. TSentralinyy nauchno-isaledovatellskiy institut chernoy
metallurgii -4
jIron and steel plants-Management)
(Index numbers (Economic a))

ZEMLWSKOV,, -V.-D..,
"Accounting and the.analysis of business transactions in
metallurgicil plants" by A.V. Valuev, A.A. Skorokhodov.
Reviewed by V.D. Zemlianskov. Stall 22 no.7:652 Jl 162.
(HERA 15:7)
(Steel industry"-Accounting)
(Iron industry-Accounting)
(Valuev, A.V.) (Skorokhodov, A.A.)

ZEMLYANSKOV, V.D.; MAKAROV,.M.P.
~
New developments in researoh. Stall 25 no-10:956 0 165.
(MM 18-.11)

ZEMYANSKOV, V.D.; YUDINA, L.D.; SHITIKOVA, A.A.; PRIKHODIKO, R.V.
Consumption of rolled ferrous metals in the U.S.S.R. during
the current seven-year period. TSNI1CHM no.45-.143-153, 165.
(MIRA 18:9)

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ZEMLYANUKHRI, A.A.; SIMONOVA, R.V.
Effect of presowing treatment of cornseeds with succinic
,acid on the-organic acid metaboliBm. Nauch. dokl, VS
shkoly; biol. nauki no.3tU7-134 164 MIRA 17--8)
1. Rekomendovana kafedroy fiziologii rasteniy Vormezhskogo
gosudarstvennogo universiteta.

ZEMLYAWITINI-A.A. ~
1.11ffr~ct, of ascorbic acid on water metabolism in plants. Fiziol.
rast. 11 no.6:1047-1055 N-D 164. (~JIRA 1.8.2)
1, Department of Plant Physiology, Voronezh University.

ZF-14LYANMIN, A.A.
----------------
Effect of mineral fortilizers on physiological and biochemical
processes in carns Fiziol.rast. 7 no-1:13-19 160.
(MIJUL 13:5)
1. Voronezh State University.
(Corn(Maize)-Fertilizers and manures)

TRY USSR
CATEGORT i Plant'PlYniolo&y. Hanpiration md Votsbolinm.' I
rP$. JOUR. RzhBiol... No. 6 1959,o No. 24,197
J AUTHOR
Academy of Sciences, USSR
'I TI'TLE t The Inhuenoe of Irrigation on Plant Metabolism
OPIGI PUB* I Biol. onnovy. oroshaypm. zemloa-, 1957, 552-564
ABSTRACT Two-year experiments in,irrigation by sprinkling
of sunmor wlioat.,G,ordoiform'910
and
Beta vulgaris
.
.
,
.
-maor6rhiza*wei-.O-.,6onductecl'in Voronezh9kaya. oblast'.
Irrigaiio'n.,c-au'ned"an in6rease,of aotivity,of
oataltLses an-a.'pp*roxidases..in..tho leaves anri seeas
of the wheat ana-in the leaves-(espeoially the,
young--lea4es)-6f.the.beets, a .n increase in the
content of.ascorbic acid and siigars. (especiany
glueocles), in the leaves-~ of,, the wheat, and an
inoreeme, in the 'rekO~ of the:flow of carbohydrates$
1/2 ngel-vurzei-7
2

ZIMLYAIWMIN A.A
The morphophirsiological characteristics of Agropyrum tonerum
wd A. fibmium and their bearing on the introduction of the latter
species into cultivation. Bot.zhur.42 ixo.2:230-239 F 157.
(MINA 10:3)
1. Voronezhakiy gosudarstyewly univermitat, Kafedra darvinisma.
(wheat grass)

GOLITSYN, S-V., WMAHMIN, LA.
Some recent data on the chemical composition of chixfa hay and
tubers* Trudy VGU no-3:23-36 158*' (MIRA 13:8)
(Chufa)

Z134LY"MM, A.A.
Effect of irrigation on phosphorus metabolism In wheat. Trudy
VGU no-3~27-j2 158. WU 13:8)
(Oheat-Irrigation) (Phosphorus metabolism)

ZAGYANUKHIN, A. A.
Effect of irrigation on the bioche mical activity of the soil and
plants. Trudy VGU56 -na-l'il3-16 159, (MIRA 13:8)'
(Irrigation) (Biochemistryj

USSR/Plant Physioloa- Respiration and Metabolism 1-2
Abs Jour 1bf Zhur Biol., No 19, 1958, wo 86624
Author
Inst ronezh University
S c or'llatrat Vo
Title The Effect - of Soil Hur4dity .,od 1.11atabolism in Pea Seedlings
Orig Pub Djul. Obshchestva YaSteBtVOiSp~rt. pri Voronazhsk. U11-te)
10, 35-37, 1956
Abstract Vegetation experiments were conducted on pea of the Eamonslziy-
77 variety for soils with differaifag hwnidity - 70 to 20 par-
cent of the total moisture capacity. An increase in coil
humidity involved an increase in the rrowth and the (Iry and
natural veight of the plant and a pronounced increace in the
content of ascorbic acid (3.5-fDld greater content, of that
acid at 1 70-parcont humidity of the soil compared with 20-
percent humidity), incraaso in the content of aaccharose
and particularly glucose, v.,id rice in the accumulation of P
(by appror-4matelY 30% compared with original content). It is
Card 1/2
8
H Zrd

ZEMLYANMIN, A.A.
in leaves in relation to the individual growth
of plant a. Dokl. akad. sellkhoz. 23 no.9:14-16 '58. .(MIRA 11:10)
I.Voroneshakiy gosudarstvannyy universitat. Proistavlena akadelmikom
I.V. Yakusbkiuym.
(Plants-Absorption of water) (Leaves (Botanv))

ZE24LYANUKOIN. A. A.. USSR)
"Ascorbic Acid and AcIds frDm the Di- and Tri-Carbo.Vl:Lc
Acid Cycle as MetaboUem, ActiVatorse
Report presented at the 5th Int'l, Siodlmmlsti~~r Wngress,
Moscow, 10-16 Aug 1961.

ZEMLYANUKHIN, A.A
Physiological characteristics of two Voronezh varieties
of corn.Nauch.zap.Vor.otd.VBO za:23-26 164. (MIRA 18111)

za-ly~*Jjuyliifly A.A.; AIIISOYEVA, O.V.
Murnal. d,,m-ami(,.,j of organic, ac-ld corton;L In the ot'
aunrlower. Nauch. dokl. vys. shholy; biol.
181 166. j~,t jej : I
1. Rel-omendovana kafedroy fiziologli rastcniy Vorono.-tw1rogo
p,o,-,-udarot,.-ennc,go universiteta. Slubmi.tuted lflovorllb,~-r 1-7, "'A4.

VEYSBERGp K.G., insh.; NADTOCHIY, W., inzh.; ZEMLYANUKEN., A.G., inzh.;
TOVp SqM*p Whe
Faading of mine face mechanisms in development workings by means
of a pomihon cable. Ugol.prom. no.5t7O-72 S-0 162.
(MIRA 15: 11)
1. Giproniselaktroshakht.
(Coal mining machinery-Electric driving)

Determining the second frequency of natural vibrations of
ffpindle in internal grinding machines. Stan.i instr- 31
no*8:32-33 Ag 1604 (MIRA 1318)
(GrindiDg machines-Vibrations)

VDOVEITKO. V.M.; Z194LYANUKRIN, V.I.
Ratio of the quantitative distribution of uranyl nitrate and
watt:-: in ether solutions saturated with water. Trudy Radiev.
inst.AJU SSSR. 8:30-37 158. (MIR& 12:2)
(Uranyl nitrate) (Ethyl other)

SOV/78-4-2-23/40
Ryskin, Ya. I., Zemlyanukhin, V. I., Solov'yeva, A. A.
Derbeneva, No A.
TITLE: Investigation of the State of Water in Anhydrous Solutions of
Uranylnitrate by the Method of Infrared Spectroscopy
(Izuehen:Lye sostoyaniya vody v nevodnykh rastvorakh uranil-
nitrata jaetodom infrakrasnoy spektroskopii)
PERIODICAL: Zhurnal neorganicheskoy khimiiq 1959, Vol 40 Nr 22
PP 393-396 (USSR)
ABSTRACT: The paper under discussion describes the investigation of
the state of water in anhydrous solutions of uranylnitrate by
infrared spectroscopy. The following frequencies of the watar
spectrum were used in the determinations: frequency of the
deformation vibration -) 2 1645 cm-1 (A= 6.
Ni + ~)3) = 6882 am- (.A 1-45,,,,) and (-02+ V3) = 5110 cm-
(A= 1.96
,1,,).-dj-. frequency of the symmetrical valence
vibration of the water moleculeii) 3**' frequency of the asym-
Card 1/2 metrical valence vibration of the water molecule.

SOV/78-4-2-23/40
'Inventigation of the State of Water in Anhydrous Solutions of Urany1nitrate
by the Method of Infrared Spectroscopy
The spectra were recorded on the infrared spectrometer-D-209 by
quartz avd NaCl-prisms. The solutions to be examined were
produced by the dilution of hexa, trig and dihydrates of
uranylnitrate in suitable solvents, as ether, acetone, and
meihylethylketone. The infrared absorption spectra of-the
hexa) trig and dihydrates of uranylnitrate in ether were re-
corded in the zone 1.3-2*2,u.The results show that two molecules
of water~are complexly bound in uranylnitrate and are con-
siderably deformed. The deformat*.Lon degree depends on the.
nature of the solvent. The remaining water molecules of.uranyl-
nitrate in organic solvents are bound less complexly to uranyl-
nitrate and show a comparatively slight degree of deformation.
The spectra of uranylnitrate in acetone and methylethyl-ketone
show analogou 's phenomena. There are 4 figures and 5 references,
2 of which are Soviet.
SUBMITTED: December 12, 1957
Card 2/2

al, 4'a P
/26603
s/186 61/003/004/002/007
EjL41/El64
AUTHORS: ~khin, V.I., and Savoskina, G.P.
TITLE: The extraction of Americium with Tributyl phosphate
PERIODICAL: Radiokhimiya, 19611 Vol.3, No.4, pp. 411-416
TEXT: The authors carried out investigations on the
extraction of Am from HN03 solutions. Quantities of Am (< 0.1 mg/f)
containing not more than 2% of other a-emitters were extracted in
cylinders at room temperature 20 1 20 . The tribu*j.,yl phosphate
was first washed with a 5% NaCl solution, then with water and
distilled under vacuum; concentrated HNOz was prepared according
to the Erdman method (Ref.7: Yu.V. Karyak-Ing Chistyye khimicheskiye
reaktivy ItPure chemi,~al.reagentsll, 233. Goskhimizdat, M.,(1947)).
The Am-content in both organic and aqueous phase was determined
radiometrically; the concentration of HN03 by volumetric titration
with alkali with methyl orange. The coefficient of distribution
aAm was calculated as the ratio of the equilibrium concentration
of Am in the organic and aqueous phase. It was found that the
coefficient of distribution of Am, in the presence of non-extracted
nitrates increases with increasing concentration of nitrate and
Card 1/4

266o3
The extraction of Americium with .... S/186/61/003/004/002/007
E14_1/E164
decreases on increasing the.concentration of HN03. The authors
also calculated the equivalents.of salting-out of a number of
nitrates and found that the degree of extraction of Am increases
on raising the !on-potential of the cation and the coefficients of
activity of Am we well as that of the salting-out agent.
Investigations on the mechaniBm of distribution of Am indicate that
complexes of the type Am (N03)3.n(TBP.m HN03) are formed in the
organic phase during extraction from very.acidicsolu~.Uona-
(HN03 ';),8M).and that nastable co mplexes of Am are formed'with HN03
in aqueous,solutions. At high concentrations of the nitrate it
was observed that the curves of the coefficients of activity are
approximately parallel and are only slightly affected by J
W = ionic strength) of the solution. Average values of the
equivalents of salting-out of nitrate of monovalent cations in the
relation to IM LiNo3 and coefficients of activity of Am in the
,sa-1-11-ing-out agent when J = 4 are given% see Table 5. It can be
seen that the salting-out effect is greater thehigher the
coefficient of activity of Am and of the salting-out agent, which
Card 2/4

L3313
s/186/62/004/005/005/009
E075/E135
AUTHORS: Zemlyanukhin, V.I** Savoskinal G.P., and Push lerikov, M. F.
TITLE: Investigation of the complex formAtion of americium
with neutral 1)hosphoroorganic compounds. 1.
PERIODICALi Radiokhimiya, v.11, no.5, 1962, 570-575
TEXT: The authors investigated the extraction of Am-with.
tri-n-butylphosphate (TBP), di-n-butyl.ester of n-butylphosphorous
acid (DBEBP), n-butyl ester of di-n-butyl phospi7orous acid
(BEDBP) and Cri-:n-butylphosphine ox-1-de (TBPO). This was done in
view of the lack of data in the literature on the extraction of
trivalent elements with neutral P compounas, with the exception of
tributyl and trioetylphospliates (TBP and TOP). Am was used in
quantities below 0.1 mg/litre dissolve7d in 5M NaN03. Kerosene was
used as diluent for the extractants. The procedure used was
described previously (V.I. Zemlyanukhin and G.P. Savoskina,
Radiokhimiya, V.3, no.4,.1961. 411). The extraction of Am increnses
when TBP is replaced by TBPO. When the concentration of the latter
is above 0.01 M ~ third phase is formed. The distribution
coefficients (a Am ) incrense rapidly with the concentration of IINO 3
C ar d 1/ 2

.Investigation of the complex s/186/62/004/005/005/009
E075/E135
and reach maximum values (2.16 and 13.3 for DBEBP and BED13P
respectively) in approximately 2M HN03- In general, Am(N03)3
interacts with the extractants M:
Am 3+ + 3 NO3- + 3T P~ Am (NO 3)3 '3T
The equilibrium constants for this reaction are:
KTBP ~ 0.4; K DBEBP = 7.4; KBEDBP !~ 112; KTBPO 1710.
The activity coefficients of Am decrease with the increasing
concentration of HNO 'the departure from ideality increasing in
the order TBP, DBRP, BEDBP, TBPO.
There are 7 figures and 3 tables.
SUBMITTED: July 7, 1961.
Card 2/2
7

s/186/62/ook/oo6/oo3/O09
t075/,E433
AUTHORS: Zemlyanukhin, V.I., Savoskina, G.P., Pushlenkov, M.F.-
TITLE: A study of the formation of complex compounds of
americium with diisoamyl ester of methylphosphinic
acid (DAMP)
PERIODICAL: Radiolchimiya, v.4, ?no.6, 1962, 655-66o
TEXT: The results of the experimental extraction of americium
with DAMP from nitric, perchloric, hydroch1gic, sulphuric and
a4;etic acid solutions are described. The 2 lAm used contained no
mqre than 2'/'* of admixtures emitting a radiation. It was shown
that the formation cf complexes of aviericium with DAMP follows the.
same. relationships as the formation of complexes with
trlbutylphosphate. Americium Is comparatively well extractable
wAh DAMP from nitric and parchlorate solutions and weakly
extractable from hydrochloric, sulphuric and acetic solutions.
Jonf3 amoricium'is extracted in
From nitric and perchlorate solut
the form of Am(N03) 63DAMP, tho constant for which was
calculated :(k = 8Y. There are 5 figures and 4 tables,
SUBMITTED: September 9, 1961
Card' 1/1
~~7F7~ r7

ZEMLYAN,11MIN, V.I.; SAVOSKINA, G.P.; P11,311LENKOV, M.F.
...
Complex formation of americiwn with acid organophosphrus
compounds. Radiokhimiia 5 no,. 6%0'74-679 163.
(MIRA 17:7)

ZEMLYAMIMIN, V.I.; SAVOSKINAL, G.P.; PUSHIENKOV, M.F.
d I I - I-
Complex formation of americium with neutral organophosphorus
compounds. Part 2. Radiokhimiia 6 no.6:694-701 164.
(MIRA 18:2)

N.N.; ~7NANUXIIINA, M.P.
Chrmking the jr-arformance of induatrial packed nauun-r6c""Ification
apparatus. Trudy VNIISN'DV no.6.-l,,l-Uj6 viS3. rFJ~R-k 17-.4)
3

SAVICH-ZA13LOT.5KIYI BA, (Savyoh-Zablotalkyi, B.K.]v inzh.-olaktrik;
W.-IMAIMP I.M. fZemlianyi, I.M.], inzh.-olektrik
Operating transformers with automatic tension regulation. Mekh.
oilt. hoop. U no.5:23-24 Yq 160. (MIRA 146)
(Ele#rio transformers)

KAZANTSEV, Yevgeniy Ivanovich. Prinimali uchasUye:_M1UYAM,_
Y.P..,,. inzh.; KATSEN, L.G., kand. tekhn. naukj SDIIKIN,
I.D., prof., retsenzent; STEPANOV, Ye.S., red.;
SHKLOVSKAYA, I.Yu., red.iz&-va; KOROVINA, N.A., tekhn.red.
[Industrial furnaces; handbook for their calculation and de-
sign] Prorgstaenrye pechi; spravochnoe rukovodstvo dlia rasche-
tov i proektirovaniia. Moskva,, Izd-vo "Metallur iia," 1964.
451 P. W11IRA 17:4)
1. Dnepropetrovskiy metallurgicheskiy institut (for Semikin).