SCIENTIFIC ABSTRACT ZHAROVIN, N.A. - ZHATKANBAYEV, ZH.ZH.
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100
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December 31, 1967
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SCIENTIFIC ABSTRACT
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USSR/Cult ivatc-d Plauts -Potatmg, Melons,
'Lbs Juur,
][3 10, 1950, 41K)90
Z!,ur,- Biol:.,
Author iarovial II.A.
List D,;loruccimi II-wtitutc! J~'Qr t:...; People s Economy.
Title vac C.,t~mlxal Composit-io.'I .)I' Votato Varictios uC 1954
1955 Crops Divid,&. 'by Dictricto in thu, BU(vmw54.-,r,
Pub
Orig I
Uc:~ zan. Bclorusok. i-1- Id.-va,, 1957, v~,,P# 131-
j
187.
Lbstract Mir, 5 vUey, deals WIVI t*10 OLLtL111ination Of t4.,-, total
aviovul'- of dry rmttcr, stnrc'~. co-Acmt) suow-,
DOCCIwavocc), n1trogc-.1 .,,tbfjtn1-cuq cma protoin, as.1, rm.
cellu-100c, pentoean, acid, Bolmlin a,.; woll 'lc t1- a
acidi-L"y in the tul)4~-ri3 o2 .'A, 1:,~runt potato varictlos
No 1j Trudovoy, 7.av~vqky,
Card 1/2
USSR/Cultivat"Icd plwats lbtatoo's, I "aws.
Abi3 Jour Eaf M-ar Biol., ITD iO, 1,40W
d Darmlissia) x
Bk~:71J21ineQ21) Ostboto, Forrm all "mi V
ml,! 1055 craps M:wni by selectloa
entical so-il ane. ari-otc-chnical cinditixis. Mc
art-*cl-- c-l-tes tlic tlata .~n &,--nical analyses. 51:---
-t,::r, ut-,Lch, ascorbic aced n~-
co, cwitent of' dry mt
substruices was `n -I~ievaricticc
03tbo".z:.. GX. a c:I-Iiav
Card 2/2
lot,,
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til
Jubilee.Congreas of the American Society of Chemical Engineers SOV/63-4-3-16/31
Ir L~~a 7 :141i 1 , --.
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ip;,,qR/ Chemistry -Analy-tic-rd chemistry
G'q trd 1/1 Pub. 116 - 15/29
Authora _And,,Chernov, R. V.
TItle t Distribution of o-hydroxyquinoline and its combination with tron in a omter -
organic solvent system
Periodical t Mr. khiji. zhur. 21/6, 757-760, Dec 1955
Abstract v Analytical data are presented on the solubi litY of o-h;rdroxyquinoline in car-
~Lnd the ~Ia-tributlon
bon tetnichloride, chlorcfarm, d4i~nIoroe%rwtn" ne
coeffici,nt ~)` this reaeeTIL jet.t-a-, %h-5, 1,,Id C--iter ap. wejI
a3 aque-.),., F
3eries correiiorf~, t~ i;.,,
4overr,'P.4 brie -)rtv-n',at~ar nc C
wi Th t. fie i- T e.0- r a C ta bt Y
Table.
Institution Kiev State University Im. T. G. 'ihevcherko
Submitted June 4, 1955
137-58-5-11159
Translation from:.,Referativnyy zhurnalp Metallurgiya, 1958, Nr 5, p 3Z3 (USSR)
AUTHOR: 'Zharovskiy, F.G.
---------------
TITLE: Employment of Extraction Processes in Chemical Inspection of
:Materials of Metallurgical Production (Primeneniye ekstra-
girovaniya.v khimicheskom kontrole materialov metallurgiches-
kogo proizvodstva)
.PERIODICAL:. Tr,.-Nauchno-tekhn. o-'Va chernoy metallurgii. Ukr.~ resp.
pravl. 1956, Vol, 4, pp 138-148
ABSTRACT: A survey. A brief description of extraction methods and
separation procedures. -The author examines various methods
whereby metal is extracted with the aid of dithizon, diethy1d.i-
thiocarbarnate, 'ethylxanthogenate, cupferron, o-hydroxyquin-
oline, and other organic reagents; also examined are.the
methods in whichmetals are extracted in the form of inorganic
,complex compounds (halide and rhodanide), hetero poly acids,
and ternary complex compounds. A table was composed showing
th e compounds into which a number of elements can be extracted.
Bibliography: 85 references. 1. Industrial prod uc t ion--Ma teria 1s
Card 10 2.,Materials--inspection 3. Metals--Processing N.G.,
4. Chemical elements--Separation 5. Chemical compounds--Separation
7.~
I-etec-tron al
Lb--x..;YAA J. 6. 51tevuhezr6o atato. lj~ilv Kiev
KUM - Aw 22 '1132 "4 'Vsl'~ v- Rjt,~-Ln r,"
,net Ki a t M~Wi-
AUTHOR: Zharovskiy, F. G o, 78-3-19/35
TITLE: Distribution.of the Chloride Complex of Molybdenum,
in the System Hydrochloric acid - Organic Solvent.
(Raspredeleniye khloridnogo kompleksa molibdena
v sisteme solyanqya kislots. organichaskiy rastvoritell.)
PERIODICALi Zhurnal~,Neorganioheskoy Khimii,, Vol.II, No.3, 1957,
pp.623-627. AUSSR)
ARSTRACT: An account is given of the investigation of the
distribution ofmolybdenum chloride In the system
aqueous solution - organic solvent, with different
concentrationsof.,hydroehlorie acid and also of chlorides
of other metals And of phosphoric acid in the aqueous
solution. Ths1nvestigation Included thirteen oxygen-
containing organiesolvents. It was shown that vith
increasing hydrochloric acid concentration the solubility
of water in butanol, isobutanol) isoamylaleohol and
buty1formate rises. In the first two equal volumes of
5N hy drochloric acid dissolve$ and in butyl formats an
equal volume of 7N hydrochloric acid. Ethyl acetate and
Card 1/3 diethyl oxalate saponify on prolonged shaking. There is
Distribution, of.the.Chloride Complex of Molybdenum in-the
System Hy4rochloric acid Organic Solvent.
practically no ehange,in the volumes of the.phases
when ethyl-, isopropyll isobutyl- and isoamylbenzoates
and also,ethyl-~ and isoamyltsalieylates are mixed with
hydrochloric acid solution. As hydroahloric-acid
concentration is Increased the extraction of the
molybdenum-chloride complex by the above esters
increases. The greatest extraction-efficiency is
shown by the ester with the lowest molecular weight,
Diethyl ether extracts the complex with the formula
HEM0020131- The extraction of the complex is practically
insensitive to the partial replacement of hydrochloric
acid by equivalent quantities of calcium chloride or
aluminium chloride, but extraction of molybdenum
chloride by diethyl other decreases when ammonium
chloride or phosphoric acid are present. There are
Card 2/3 5 tables and 12 references, of which 8 are Slavic.
L
., * f-4 jt~l Z.) - - - - . _;
I t f , ~ -, K i -U' 7-
" , 4 -,-. - j ~ .
I i
i
111 F., 1.10111, in I I 1111 MH E 11, 11 M11111111 I I Ili., I 11.
A.T. 12-,T/ 71
TITLE: Zircclni~vit it!i'- het'i.
loc 'C; 3 P,
Zav(70j3'-,i.-,,-a Labcr"xtovi.,-a, 1.:57: Vol. 23, Nr 12, TT). 1JjC7-1 k -
AB
STWM:
la this pa-,~ur the ivrlicotion of -hanyl-flitcron tin a rcaLent in
gdven prufermce, e9 i -&,-,r. t1m colorimetrio determination of
er'.1-mimi as well as of W-1tijacri.- Eirconiun with nhenyl-fluomn
farms a compound of a light-red
color.,ihich is difftomlt V~Ainuclvc; at a lok% content of zirconii.=;
the color chanLea into rmrkri,,~;n. The :!--izL--tu;n of the li-,-ht absorrtlol'.
of zirconium is,located at 535 met. II.- this doiaqin of the mpectl 1
thc. reageat solution doe8 riot ab.-jorb the HITht.
fluoronate" is soluble in -.thri-x1s bM,-mol, i~tetf*,
aii~vl spirit, butyl fonwte avol but it is color-'Laqt
only in spirit solutions. Phosi-,111cm-s- owl hydrofluoric acid lrovc a
disturbing influence upon zircoUwa In tile orlse of phenyl-fluorzi-,
reactionn. In this case alac, 3.oils , ht:,vc a colog of, their o-.Arn.
as -.,ell az titanium, lead, antimn,.v.-, tmtalm;~, niobilum anc! hafnium
excrcise a disturbing influeric,-;. -zi ic-.11 ns U-4c ions;
k"olorimetrio 'Determination of Zirconitr,,. fith 32-12-Y71
-hc
-rwI!-FIuomn'I
r
4+ 2+ 2+ 2+ & 6+
3j3,, V5+
pe3+, Cr34 Ti Ni Cu Q t, o and 4
if their content exceeds the zirconium cm-itent by the 50,,2CO,
2CO, 5CO, 2CO, r0,: 3CO, ICO, 1 and 5-fold reqI)ectively. The incli-
nation of zirconium toaards hydrclynis b," also to Ire talcen intf?
acoount. There follomj a de2arintion of thr.. experivent and a cor-
responding table is:given. Another pronesa cf the exreriment of. tht;
to tt~e detcrAwition of zir-
t, nalyn is ,1~,ihich 1:3 given lwr~~, re-ii
menim or alutdijur, -wl P, table containing the
conim in metallic rnaf;
results is give . There are 3 figures, t.~ulw.,, rnid 6 referencen
n b
5 of Aich are Slavic.
-iya v S I
2-JOCIATION: I. State University imeni T.C;.Shevchenko
-darstverm~y universitet im. T.G,.ShPvdeAiD)
"PILABIZ.- Librr-ry of Congrese
C.~ rO, 2V 2 1. Zirconium-CAOMetric determinp-tion 2, Pherw1fluoron
3. Phosphoric acid 4. Hydrofluoric acid
AUTHORS: Zharovskiy F. 0., Pilipenko, A. T. BOY132-24-10-9170
TITLE: The Colorimetric Determination of the Phenylfluoronate of
Germanium (Kolorimetricheskoye opredeleniye fenilfluoronata
germaniya)
-PERIODICAL: Zavbd kaya Laboratoriya, 1058s Vol 24, Yr lo, pp 1192-1194
(USSR).
..ABSTRACT: The c.olorimetric determination of germanium is based upon.
the formation of yellow and blu a heteropoly acids as well
as upon a reaction of germanium with oxidized.hematoxyline
(gematoksilin), quinalizarin, purpurine, and phenyl-
fluoron. Since the composition of the compound of germanium.
with the last reagent,as well as the conditions of the-colori-
metric determinations have been investigated insufficiently,,
the present'paper deals *with this subject. Stipanist and
R
ech ist and Gek
t (Shtipan W (Ref 1) assumed an.easy die
solution of this compound in organic solvents. In the present
case it-wat observed that cyclohexanoneia a favorable solvent
-and that- the extraction of the germanium phenylfluoronate
by means of,chloroform is considerably worse. The experiments
Card 1/2 -carried out-'showed that the assumption of Stipanist and
SOV/32-24-10-9/70-
:The Colorimotric Determination of the Pheny1fluoronate of Germanium
'Hecht concerning the structure of the germanium phenylfluor,o_,
-nate.is not sufficiently substantiated. The method of iso,
molar-series was used for,the determination of the composi-.
tion of the germanium Phenylfluoronate using the solubility
of, the complex compound in cy6lohexanone. The resulto are-
represented graphically and the formula GeO(C 0 H ) is
19 5 .11 2
assumed..In the investigations which were carried out for
the determination*of Germanium with.phenylfluoron'it was
observed t1jat the re-extraction of germanium is better car-
ried out with a weak ammoniacal solution than with pure
water, An~analytical procedure in given. It is mentioned
among other things that an acid decomposition in the prenence
of.~chlorides is inadequate. There are 2 tables and 3 ref-
erences, 2 of.which are Soviet.
ASSOCIATION: Kiyevskiy gosudarstvennyy universitet im. T.G. Shevehenko
(?%rev, State University imeni T. C. Shevchenko).
'Card 2/2
0 SOY/32-25-1-21/51
bTHORS-., Babko, A. K. Z.harovskiy, F. G.
.TITLE, ~Application :of~Extraction in Inorganic Analysis (Primeneniye
ekstragirovaniya v neorganicheskom analize) survey (Obzor)
PERIODJtAL: Zavodskaya Laboratoriya 1959, Vol 25, Nr 1, PP 42-52 (USSR)
BSTRACT
A The analyses of materials port ining to the metallurgical
a
industry usually involve separation processes of either the
substance to be.determined or of its-impuritieso In this con-
nection~an,ample survey of the pertinent methods is given.
'The advantages offered by the extraction methods are described
as well as the factors influencing such extraction processes.
An enumeration of the inorganic complex compounds which may
- formed .in,suoh extractions is also giVen. The various
be
.
flucrides:, chloirides, bromides, iodides, thiocyanates, nitrates,
-ibed, and the
and.heteropolyacidB are..mentioned and desc,:.
respective references are indicated. Since organic solvents
are also often used in extraction processes, the respeqtive
organo-metallic compounds are enumeratedg: among them the di-
carbazonates, diethyl-dithio carbamates,-,ethyl
Card,1/2, xanthates, oupferronates, -quinolates, nickel dimethyl
OxY
S/073/~2/028/002/001/096
B101/B110
Zharove Sakhno, A. G.
AUTHORS:
*
molybdenum and tungsten In the system
TITLE stribution of
Di
.'hydrobromic aoid organic solvent
~.Ukrainskiy,khimicheskiy zhurnal, v. 28, no. 2, 1962p 145-150
TEXT: Astudy,waa made of the distribution of Mo and W (as sodium molybdate
and sodium tungetate, respectively) between an,aqueous solution of HBr and J-
oxygen-containing solvents: isoamyl acetate, isobutanoll butanol, isoamyl
alcohol, diethyl ethery n-amyl alcohol, iaobutyl acetate, and propyl acetatei,-~
After mixing the HBr solution containing a known quantity of-W or Mo with 'I
the organic solvent, the content of W or Mo in the aqueous phase was
~"i.-: determined colorimetrically, and the quantity of W or Mo gone over into theii
il organic phase was calculated-from the difference. The result was; M 10 mi
l
of I-Ot 2-0 3-0, 4.0':5-0 an-&6.0 X HBr hold 0.88, 0-571 0-44, 0-33,-0.29i
and 0.26 mg of W, res;eotivelyp in solution. At higher tungeten
concentra-1. 2L,
,
c ons ur cipitatede, m i
I t, LgBtiC,.acid is pre (2) 95-7qo of W is extracted fro
00-0.5 N:Hft*~ Accordinglyt the degree of extraction decreases with
Card.1/3
0
S/07 62/026/002/ooi/ o6
Distribution of molybdenum ... BI 01 Y131 10
increasing acidit (3):With increasing acidity, the degree of extraction
,6 of increases,86-97% of Mo in extracted from 5-6 N Dr. (4) This depen-
Mo
dence of the degree of extraction on the acidity is not influenced by the
kind of organic solvent. c
(5) As regards their capability of extra ting
-.:f from 1 H HBr, organic-solvents.can be arranged as follows-. iooamyl acetatol.j
'is amyl alcohol/-diethyl other