SCIENTIFIC ABSTRACT ZHDANOV, V.M. - ZHDANOV, YU.A.
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December 31, 1967
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SCIENTIFIC ABSTRACT
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ALEKSANYAN,,A.B., prof.; DEWENEVINUH I.S., doktor mod. naukj
BELYAKOV, V.D.p doktor med. nauk; BF,=,!ERTNYY, B.S.: dokt.
mad. nauk;,VASHKOV,.V.I.j prof.; GROMASHEVSKIY, L.V..
prof.; YUKIN,I.I., prof Prof.)
ZHMAYEVA,.Z.M., kand. biol* nauk; KOVARSKrY, kand,
med. nauk; NABOKOV,', V.A., prbf.1 NOVOGOIIODSKAYA, E.M.,
prof.; PAVLOVSKIY, Ye.N., akademik; PETRISHCREVA, P.A.#
prof.; PERVOMAYSKIY, G.S.) prof.; POGODINA,. L.N.; ROGOZIN,
I.I.) prof.; SUKHOVA, M.N., doktor biol. nauk; CIIASOVNIKOV,
A.A., kand. med. nauk; SHATROV, I.I.,, prof.; SHURABURA,
prof.,- YASHKULI., V.K., kand. med. nauk;
ZHUKOV-VEREZHNIKOV, N.N., prof., otv. red.; BOLDYRW,, T.I.,
prof., re.d.; ZASUKRIN, D,N,p doktor biol, nauk, red.;
KALINA, G.P.,, red.,
(Multivolume manual on the microbiologyp clinical aspects
and epidemiology of,communicable diseases] Mnogotomnoe ru-
kovodstvo po, mikrobiologii, klinike i opidemiologii. infek-
tsionnykh boleznei. Hoskvaj Meditsina. Vol.5. 1965.
548 p. (MIRA 18:3)
1. Deystvitellnyy chlen AMN SSSR (for Aleksarqan,
Gromashavskiy, Zbdanarv, Zhukov-Verezhnikov). 2. ^Ihler-
korrespondent.41N SSSR (for Rogo2in, Boldyrev). -
Zs4qy)-, !jfp;'ZBARSKIY~ I.B.- BUKRI31SKAYA, A.G.; FMOISKAYA., G'P.
Study. of, the ~llnitiil stage of interaoilon of Sendai virutwith
cells 210-ra the ailtoradiographic method* Ad* eksp. blol. t mbdo
56 no.7t67"72 Jlt63 OUU 17 23)
lo 1z.1aboratorii fiziologii virusov zav. deystvital Inn
chlen AM SSSR V.M.;Zhdencv) Thstituta virusologii Imeni D.I!.
lvanovskogo (diro - doyetviteltnyy chlen AM SSSR V-M. Zhdanor)
AM SSSRA laboratorii biokhimii kletoobnykh struktur (zav-s
doktor biologicheskikh naulc I.B. Marskly) Instituta morfologii'
(Agricultural machiner7--Safety measures)
i
LI 1585-66
5.05015051-
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Dorbun--A
q':ghlk!- E:,
EVIT(,l)/EWA(h). OW
BOW_-UPJ
UTM
_V ber&% Dubla-
U na-
:T",'Khareva, Be last M ~.F 5 5- 5_,~
Physical proportion of rocks and mineral rossources of tho USSR (Fizichaskilo evoy-
etva gornykh porod L polaznykh IskopayerVkh SSSR) Uoscow,. Tzd-wo 'NedrA",, IL964.
323 p. Illun., biblio. (At head of titles Gosudarstvenw goologich4skly k=i,.g
tat SI.IISR. V5esqYu3Mz institut).,ILJO
3000 copies printed. Und@r the aditorehip of 0. M.
Principal editors L A. Kaltvkava; Tecbn1cal editors A. S. Polosina; Proofreaders
X. 5, Toroptseve,
TOPM TAGS.' =gmatic rack,, mataaorphic rock,, m1neralogy, petrology, solamelopy
Ip'", s5
FURPCGE AND COVFMGZ: This book to the result of the genoralization of =tArlals
collected prImarily byrophysical trusts-and geologic agencies, as we3l in by the
institube DAMAd (Vs=. Principal attention Is paid to the basic laws goTerning
variations in the physical properties of rocks, various petrogmphic groups,, and
useful minerals of divers almeralogic compositiond The phyalctl paraasters to
~Crd 213
W 7'
AU5015051
2- -
-wbich-4pei a
Nj
-the: specific &in the rat* of propagation of longitudinal
3. d
and transverse wavoa, The compilers of the book are colleaVes #f the Laborator-
Iya fizichoaklkh ffyoysty gornykh porod ar4. the Mal petrIgrafil of VMML They
express their gratitude to Be A, Andra ~'jnG. I, Wartynavaly,-S. V.
YOVVI,A. A. Log!kS4~ ', I
Moskyaleva'J4 s. G.-Bo _Ik4vaZ-nRV. Fe
eAqj!!a e. Ut
Dyb~r;,"!B. K. L'yor;,V. 1, Mqqkv!k1Aya~4,,fj. Petroyaj,, Tu. Tq,. 1,
key ich,, d_oiar Sh
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TABLE OF CCIIT=t
Introductiom- - 3'
Part. L Physical proparties:-of Magmatic and moUsorphic rocks
Ch,~', Z- Physical properties. of rock4emlng mlneralr 9
Cho. 17, Denfilty'af rooki 33
Ch. 111. : kAgneltic, properties; I of rocko 93
Cho We ~Spsciflo electrical resistance of roo'kd 172-
Ch V pagation of-longitudInal. elastic waves- in rocks
0 -- , , Rato, of Prs 193
ChO VY, Ob-Pho In j*qsi"! properties of rocks# depending an manifold pressure
Card 2/3
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5h) 0-pasition to (lit MeO group. Similarly was obta
101-21 (from
eff
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.
11.
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'
ChentIcail Atint. ether), w Ich with lit
in Atoll gave W di-arderiv..M.-
150-60*,.Wlth the Ur atomfi located In o,o -poiltions to the
VoL 48
Noo 9 CtO group. O-Tttreacetyliylose (16 g.) 111' 20 ml. AeCI
~
PIVIO 1954' heated 10 min. with 15 C, PC$ and 5 g. AICIR on awaterl.,
bath gave, aftcr quenchisig in much coIrt 1120, 28% U.
Oreahic Chemistrv Chloretfifler 1x*se_m, I* An- petr, - ethcr)_TK%___.
__(ftT
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h
X
it
Ue C4IrtN
~4 ~ Y1 cdy
gI)r gave 14p n i )(r(a se,
x*
In. 129.5-30,5* (from ko-PrOl I Similarly obeidned Were-
cht(fropkejt)4)triaceiyl.rylose. m. 14 60.0,; (from
IX 941.) Imond-i"I drriv.) M. 161-31 16 Iso-MOH);
Br deria., m. 10-110* (from ivi-Proll)J; .39% I+Owew-
lri4crlylxylofe' M, 130"l-IM, (train ix:tr. COICO., Thc'fatter
(4 g.) in 28.8 mL Ac,O and 10." ml. AeOll miffed to 24 9.
Cu0N:O.)j..3Ih() hi 33.0 inl.~~r,() and 14.4 int. AcOtf, jmve.
3370 nitre deriv, In. 165.5-7,0* (frmil lio-PrOll) The
iinilarly ga"C 16~'
P-anisyl deriv. (above) in 46 fifiti. ut 115'.s
nitre dcriv, m, 1.5.1, 50V (frian NoTiOll), G. M.K.'.-I,
ussR,Xhemistry - Ertraction of ilaments
Caxd 1/1 Pub. 66 - 13/36
Authors i %hdanov, Yu. A.
- - aftswev-
Title I On utilization of biochemical concentrations of elements
Periodical i Priroda 44/6, 89 - 93, :un 1955
Abetrnat A study is made of the disversion of certain e2e-monts,
Institution
Submitted @sees q-1, 6
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I I
IfSSWChemical Technology. Chemical Products and Their Application Fertilizers.,
1-6
Abst Journal: Referat Zhur Xhimiya., No 2, 1957, 5064
..Author: Zhdanov, Yu. A.,,Azarov, K. P., Gorbatemko, V. Ye.
institution: Academy of Sciences USSR
Title: Glasses and Frits for Supplying Minor Elements to the Soil
Original
Publication: Dokl. AN SSSR, 1956, ioB, No 60 U29-1131
Abstract: To Improve the distribution of minor elem nts (ME) B, Kh, Cu, Zn, Fe,
Mo, Co,,within the soil, to decrease their.combining with other soil
cemponents and to reduce their leaching, It is advantageous to add to
the soil ME that have been fused or fritted with glass. Solubility of
the glass or frit is regulated by composition of the glass or by
changes in the procedure of its production. Growing experiments are
described which serve to determine the efficacy of minor element fer-
tilizers prepared from readily fusible 3- or 2-component Slasses,
window glass scrap or phosphate glass, containing also P, K, etc, by
Card .1112
f I
I
I
c/o
r Card -1 _
i
I
(Lonins Vladimir Illich. 1870-1924) (Science)
AUTHORSt Azarov, K~P*9 .26-10-12/44
Zhdanovp Yu, A
5RaIozub6v
F
M
.
,
p
TITLE; Perennial Mineral Fertilizers (Unogoletniye mineralInyye udobvw
re
PERIODICAL9 Priroda, October 19571 No 109 pp 84-86 (USSR)
ABSTRACT: To improve the nutrition of plants, fertilizers are used which
contain nitrogen# phosphorus$ potassium and so-called trace
elements as boron, copper, cobalt$ zinc ' mapganese and others.
Too large or too small quantities of such trace elements are
harmful to the plants, As soluble salts used as fertilizere
either wash out In the soil too fast or form compounds with
other components of the soil# which the plants cannot annimil-
ate, a new method has been developed by making fertilizers
perennial. It consists of introducing Into the soil chemical
trace elements fused with easily malting glass whioh Is then
pulveriz'e'd and used for fertilizing, Such frits spread out
well in.the soil.'aupplying plants steadily and for a long
time with trace elements. Experiments conducted with corn,
potatoest sugar beets'and cabbage over the period of a year
Card 112 gave very satisfactory Ancreases of crops.
AUTHOR ZHDANOV Yu.A., DOROVEYENKO G.N. PA 3155
TITLE --Fr-o_a_u_c_t_i`on__oT,0----C Derivatives of 1 -Arabinooe.
(Sint*zy.C-----C 'proizvodnykh I-arabinozy. .-Russian)
PERIODICAL Doklady Akademii:Nauk SSSR09579yol 113o Nr 3oPP 601-603
Recelved 6/1957- ~Raviewed 7/1957
ABSTRACT In previous works D019 2983,403 the winning of somemonoses (glu-
cose# galactose$ xylosa~ was described according to the method of or-
ganomagnesis. synthesis. This method has as yet not;b**A employed for
the synthesis of 0----C-derivatives of 1-arabinosso Here ths 0------C-
substitution products of this hydrocarbon was produced synthetically
an a result of the.interaotion of 6-ohlortriao9tyl-l-arabinoss and'
of the corresponding reagent. They contained ths following radioalss
phenyl, anisyl, nathtyl, phenathylg' o-tolyl# n-tolyl, thienyl,,buty'l
The general forlault of the compounds obtained Is the following;
0
Aco 00'.
0
In the course of the ohlorifiationp bromiz&tLonp iodation of anisyl-
and phen*thylarabinose the corresponding halide dervatives are a*-
Card 1/2 parated.
AUTHORS: Zhdanov, Yu. A., Dorofeyenko, G. N. 20-6-3-9/47
Md Zn1vog1Kz9v3p L, Ye.
TITLE: The Synthesis of Some Carbon-Carbon Derivatives of
Carbohydrates (Sintez nakotorykh uglerod-uglerodnykh
proizvodnykh uglevodov).
PERIODICAL: Doklady:AN SSSR, 1957P Vol. 117, Nr 6, pp. 99o-992 (USSR)
ABSTRACT: As,described earlier (references 1 - 4) the organomagnesium
method broughtabout good results in the synthesis of the
above-mentioned derivatives of d-glueosof d-galactose, d-
xylose and I-arabinoee which contain various "agluooneo",. In
the present work this method was employed for the production
of some new compounds: phonyl-tatraacetyl-galactose, 0-tolyl-
triscetyl-xyloaoI allyl-tatraacetyl-galactoBe and allyl-
-
triaostyl-arabinose. It was.found that the aoctylated allyl
sugars are capable of adding a chloro-j bromo- and dirhodane-
molecule at the double bond of the allyl residue. Haloid-
derivatives of the already earlier synthesized phenyl-
trlacetyl-xylose were also produced. Acetachlormonosacoharides
which serve as initial products in the synthesis of the C--C
Card 1/2 derivatives of hydrocarbons were obtained due to the treatment
The Syn thesis of -Some Carbon-Carbon Derivat vos o
Carbohydrates
of sugar acetates with phosph phosphorus pentachloride and
aluminum. chloride in a chloroform solution. An experimental
part with the description of the production methods of the
following compounds is given: P-chloro-triacetyl-l-arabinose,
di-broma-phonstyl-triacetyl-xyloseI di-ehloro-phenetyl-
triacetyl-xyloss, dibromo-mallyl-triacetyl-xylcsoj di-bromo-
mallyl-tetraacetyl-glucose, di-rhodone-allyl-te-traacetyl-
glucose and di-rhodane-allyl-triaostyl-xylose beside some
above-mentioned sugar derivatives together with constants.
There are 0 references, 5 of which are Slavic.
ASMIATMNt Rostov_n&_D=%x ELtAte Uhiversity- (Rostovskiy na-Donu
gosudarstvannyy'univerottet)
PRESENTED: July 23, 1957P by A. I. Oparin, Academician.
SUBMITTED; July 23# 1957
---AVAILABLE: Library,of Congress
Card 2/2
S
OV/ 30-53-6-3o/45
AUTHOR: .Sergiyenkol I. Z.
TITLE: The Chemistry and Metabolism of Carbohydrates in Animal and
Plant.Organisms,(Khimiya i obmen uglevodov v zhivotnom i
rastitel nom organizmakh) Conference in Moscow (Konferentaiya
v MoBkve;
PERIODICAL: Vestnik Akademii nauk SSSR1 1958, Nr 6, ppo. 1.12-M
(USSR)
ABSTRACT: This conference took place from January 28 to January 30.
If was organized by the L&boratory for Physiological Chemistry
of the AS USSR and was attended by about 2oo specialists,
among them organochemiats, biochemists, physiologists, pharma-
cologiste, histologists and physicians who represents& various
scientific institutions of the AS USSR, of the Academy of
Medical Sciences of the USSRt of the VASKhNIL of a number
of universities and other colleges, as well as of branch in-
stitutes from all,the country. It was opened by the Diroctor
of the Laboratory for ?4ysiological.Chemiatry B. N. Stepanenko.
He stressed in his detailed report among other things the
Card 1/5 great theoretical interest in the investigation of the ab-
3 o-5.3-- 6--36145
The Chemistry and Metabolism of Carbohydrates in Animal and Pldnt Organisms.
C
onference in Moscow
solute formation'of simple carbohydrates. Now and great success
was achieve&, in the'field of the O-and N-glyoosides. He re-
~ported on some,important results of the work in laboratories.
Furthermore the fol:,:7ing.reporte,were heard:
I) So No DanilovvOn the reaction ofthe simultaneous ox,i-
dation and regeneration in a group of carbohydrates.
2) Tu. A. Zhdanov: On the use of different methods of synthesis.
W13. ~N- Sitepa ~~L. X. Kryukova, 0. Go Berdyuk: On in-,
vestigations carried out in the field of some 0- and X-
glycosides.
4) 0. K., Orlova: On 2 now diphtheria bacilli.
5) Ye.,K.41imova: On carbohydrates in the structure of
diphtheria bacilli.
6) S. A.-Neyfakh and M. P. Mellnikova: On enzymatio members*
7) V. So Illin: On the importance of-hexokinase reaction,
Card 2/5
-----------
sov/ 30- 58-6-3o/45
The Chemistry and Metabolism of Carbohydrates in Animal and Plant Organisms,
Conference in Moscow
8) N. Ke Nagradova; On the properties of the effect of the
dehydrase of phosphorus-glycerin aldehyde.
9) A. Ps Barkhash: On the method of the conversion of glucose.
10),Ao N. Petrov$ On the'presenoe of a phosphorus-less method
of syntheois.in the liver
11) M, Is Prokhorova and Z. K. Tupikova: On the intensity of,
the oarbohydiatemetabolism in organs.
12) B. 1. Khaykina: On the velocity of the regeneration of
free and bound.glyoogene fractions.
13) Yee L#':Rozenfel'd:,On the funotion of animal organisms.
14) M- G.:Shubioh: On the results of the hintochemical investi-
gation"of the glycogens of muscular tissue.
15) R- A. Rutberg: Ontheimportance of polyeaccharides in the
investigation of the blood system.
.Card 3/5 16) G.
Ya.'Rozenberg and T. V. Polyshina: On the production2the
__SO7/ 30-5 3-6-30/45
The Chemistry and Metabolism of Carbohydrates in Animal and Plant Organisms.
Conference in Moscow
properties and characteristics of,Soviet dextrin.
17) A ff. Petrova: On the problems of the pathology of carbo-
~;drate metabolism.
18) So Me Leytes and No To Smirnova: On the effect of the
antidiabstio preparation BZ-55.,
19).A6-V..Xotellnikova and G.T. Xrechetova., On special problems
of the pathology of carbohydrate metabolism.
20) B. No Stepananko, Ye. M.,Afanaslyeva an& R. A. Baksova: On
the chemical nature of a new polyeaccharide.
21) 0. A. Pavlikova and M. V, Turkina: On conversions of sac-
charose in:p~ant tissues*
22) Do 1. Lisitaing, M. So Bardinskaya, M. I. Smirnova-lkonni-
kovay'lu. V. Peruanskiyq Go A. Lukovnikova and V. I.
Ivanov-t On carbohydrates of plant origin.
In the resolution the achievements as vell as the shortcomings
vere men-cioned. A commission for the coordination of
work'was founded.
Card 4/5
SOV/14-27-2-3/5
Zhdanov! Yu A Dorofeyenkoj 0. N.
AUTHORSt (Rostov -na-Dond):
Jy' 'Lu* A'
TITLEs (___~OnRe't~erocy~clic a bon-Carbon Derivatives of Carbohydrates
(Geterotaiklicheakiye uglerod-uglerodnyye proizvodnyye ugle-
vodov)
PERIODICALs Uspekhi Khimii,l 1958t Vol. 27, Nr 2p ppe 179 192 (USSR)
ABSTRACTs Compoundst in which a polyoxaldehjrde-p a polyoxyketone- or
a polyalcohol rest is connected with any organic radical
(aliphatiot alicyclic, aromatic or heterocyclic) by single
carbon-carbon bonds, are classed with the C-C-derivatives
of sugars.
In the present, article a survey is given on new experimental
data in-the,field of heterocyclic carbohydrate'derivatives* and
theattempt is made to generalize these data. Isopropylidene-9
benzylidene- and ethylidene derivatives of sugars,.different
oxides (glucosane) and imino sugarsp are not treated, because,
according to their properties, they rather belong to the
Card 1/2 acetalef anhydro-ougarat amino-sugarep respectively.
5(3)
~:AUTHORS: Zhdanov, Yu. A., Korollchenko,.G. A SO'!/2o-122-5-17/56
TITLE, Irew Carbo~n-Substituted Derivatives of Glu
cone (Novyye
ugle-rodzameshchannyye proizvodnyye glyukozy)
PERIODICAL: Doklady Akadoinii nauk SSSR) 1950t Vol 122, Ur 5,
PP 811 013, OUR),
ABSTRACT: In, the past. ~+,he authors -had produced different deri-
vatives'mentioned in th6~ title. They contained ouch
'
radicals
~as naphthylp tolyl, diphenyl, thienyl, phenetyl,
p-anisyl and.others (Ref 1). The oreanomagnesian
synthesis proved to be a general method of production
of 3uch compounds. The paper under review describes
the synthesis of o-anicyl-tetraacetyl-glucose and its
bromine and nitric derivatives. The nitroderivative
formerly produced of p-aninyl-tetraacetyl-glucoae
was reduced to the correopondin- amino. Hydration
in the precence of Haney nickel proved to be the beot
Card 1/2 method of reduction; other methods.(with zinc, iron
IfeW Ca----bon-Substituted Derivatives of rluCocle
SOV/2o-122-5-17/56
or tin) did no,t Yield any clear results. The
synthetized 3-a~qino-p-.inicyl-tetraacetyl-glttcot!o
was turned 'into the corrotponding banzo~rl and
diazotized product
had to underao, an azo-combination with aniline# phenol
and P-naphthol. A para3raph on experiments with
the uoual data was added. There are 2 referencest
which are Soviet.
ASSOCIATIO147: Hostovskiy-na-Do,nu goaudara-tvernyy universi-tat (Roctov-
-Donu State U.
nivernity)
PRESEUTED: June 4, 1956, by A.I.Oparint Academician
SUBMITTED: June, 2, 1958
Card 2/2
5 (3),
'LUTHORB;: Zhdanovp YU. ~A* Sholoyinp 09.. Yo. SOO 5 3 4 -I.J1 0131
ComplexCompounds-in the Series of Perinaphthindene
TITLE:
(Kamplokenyyo ioyedineniy v ryadu perinaftindona)
PERIODICAL: Izvestiya..Yysahikh uchobnykh zavedoniy. Xhimiya i khimicheakaya
takhnologiya, 1959-t Vol 2v Hr 21 pp 200 -.203 (USSR)
ABSTRACT: ~,.Perinaphthindenons W, like several other cyclic polynuclear
ketones, forms molecular compounds with metal halides (Refs 1,
2#4.),.The'authore succeeded in finding that 2-bromine peri-
~naphthindenone-l (II) forms firm 'nuclear compounds with 11 trong
aprotoniclacids (SbOl 'BACI ). 2-J-parinaphthindenone-1 (111)
5 4
forms an analogous:complex with tin tetrachloride. C H OBr.
13 7
lated. In
SbOl ~(C H .qnCl were iao
.-.5 " 13 4; (C13H70-J)2-3nCl4
'their crystalline state all complexes have precise melting tem-
:peratures and are easily soluble.in CH COOH, in alcohol and in
di6xane, butl.not easily soluble in other and bonzenel Their sol-
ubility"in"yetrole'um other is poor. Whan'boiled in water# the
hydrolysis destroys them completely, and they are completely
Card 1/2 hydrolyzbd when boiled with water ammonia and weak acids (Ref
Complex Compounds in the -Ser;iss of Perinaphthindeno 807/153-2-~4_10/31
.2). PerinAphthindenons hydrazone (IV) (Rof 3) also forms stable
complex compounds with metal.halides. They are all soluble in
pyridine and dioxans, but-their solubility in aloohol is poor.
Hydrazone-is Tegenerated with their hydrolysis. A, stable com-
plex ie-doyolopii-by a sublimate solution In absolute other.
Salts ofbivalent mercury n rmally oxidize hydrasones down.to,
diazone othane'derivatives Nef 7)- If mercury salts are ou-
perfluousp nitrogen separates.,and organic mercury compounds
develop (Ref 8). In the experimental part the production of
molecular.oompounds of halogen derivatives of perinaphthinde-
none andits hydrazone with halides of sovoral metals are do-
scribed# as well as the production of 2-J-perinaphthindenone-1
(III), not described up to now. There are 8 references, 5 of
which are Soviet.
-Rostovskip-na ra
ASSOCIATION, -Donu gosuaarstvannyy universitet; Kafed
organioheekoy khimii (Rostov-na-Donu Stat University; Chair
e
of Organic Chemistry)
-SUBMITTED: January 289 ~1958
Card.2/2,.-.
B/153/60/003/004/023/040/XX
B02O/BO54
AUTHORS.: Zhdanov" YU-,,& Dorofeyenko, G. N., Ivanchenko, N. V.
TITLE: Synthesis of.Some Indole and Hexachlorane Derivatives of
Monosaccharid.es
PERIODICAL: Izvestiya~vysshikh uchebnykh zavedeniy. Khimiya i
khimicheakaya tekhnologiya, 1960, Vol- 3, No- 4,
ppo 680 -~683
TEXT: :.The authors.study the:possibility of synthesizing some hetero-
.~,cyclicderivativeo.of Grignard reaction. For this
purpose, they investigated the reaction of acetohalogenoses with indolyl
magnesium bromide. It is known that organomagnesium compounds of the
indole series form, as a rule, 0-substituted indole derivatives under
.the action of alkyl- and acyl halides. The reaction of indolyl magnesium
bromide,with acetohalogenoooo proceeds similarly, and yields P --indole
4erivatives of monosaccharides.,The resulting P-indolyl augars were fur-
ther acetylated by acetic anhydride dissolved in pyridine, and isolated
in,the form of crystalline acetylated compounds. By means of the
Card:1/3
~-Synthesie of Some In.dole and Hexachlorane S/153/60/003/004/023/040/Xx
Derivatives of Monosaaaharides B0201BO54
Grignard reaction it was possible to synthesize P-indolyl tetraacetyl
glucose$ P-indolyl tetraacetyl galactose, and P-indolyl triscetyl xylose.
The resulting oompounds~are 0-- C derivatives, not N-glucooides, which
is confi'rm6d bylthe presence of aotive.hydrogeng and by -4he results of
.oxidation with.permanganate. The synthesis of heterocyclic derivatives
~with a pyrrole radical, was not possible in the way indicated. The au-
thors continued th,e,investigation of the halogenation of acetylated aryl
sugarso and found that phenyltstraseetyl galactose and phanyl tri-
acetyl xylooet as well as phanyl.tetraacotyl glucose (Ref-7), readily
add six chlorine atoms, thus forming hexachloro cyclohexanone derivatives
of carbohydrates which are isolated.in sirupy consistency. The authors
thoroughly describe thesyntheeis of P-indolyl tetraacetyl-d-glucoeei
P-indolyl tetraaoetyl-d-galactose, P-indolyl triacetyl-d-xylose,.and
hexachloro oyclohexyl. tetraacetyl-d-galactose, and study the reaction
of 2,4-dimethyl pyrrole magnesium bromide with at-chloro tetraacetyl-d-
glucose. There are 9 references: 5 Soviet, 2 USj and 2 German.
Card 2/3
-ACC-NR~06, W3-1----- V 7/6 61034-[007/12 /12 12~-~
Tr 0 SOURCE-GOIR.- f V/W1
AWI-011: Z11(lanov, Yu. A.; Uz1ova, L. A.
ORG: Rostov on the Don State University (Rostovskiy-na-Donu gosudarstvennyy
,unLversitet)
al~ I TI.E. Carbon chain of augara
SOURCE: Zhurnal obshchey khimii, v.-36, -1212
7, 1966t 1211
TOPIC TAGS: or ondonsation
ganic synthatic-proceas, organic phosphorus compound, c
reaction
-J AB ko. -,,othyl~.r-.*Lpheiiylphospho.-anor. were synthesized for the first
W MGT: A31 x0ayl
1.tima fro-m asters of brozmopyrvv~c aaid as poss:!:blo intormadiates for the synthesis'
1 of higher su-ars and their dcrivatpivos through the I.-littig reaction.
ti
Al"al.-hbxalylmetliylenaphosphorane was condonsed with 2).
3;1j,5,6-penta-O-acoty1-al-
the
,D-ralact,ose according to a mothod dovalopod previously by authors for the
,synthesis of al~ha,bata-unsatur.%tcd C-sWostilArted ketoses. The condensation
yielded, the methyl as Uar of an uwatura-ted kotonononoic acid: mothyl estorof
~,,3,4,-didehydro-3,4-dicieox.,f-5,6,7,8,9-ponta-0-acotyl-D-galacto-2-nonulo3onoic
aoid in 42% yiold. Tho roaction pormits tho,buildup of the car'bon chain of
carbohydrates on the basis of three carbon atoms. EJPRS: 38,9701
SUB CODE:'' 07 SUBM DATE: 1OMAY65 ORIG 1W 003 OTH HSF: 007
+
rd 1 UDC;
547.4 569 + 5 0 7*
.77n KZ
__ACC_NRta76_ff_616_7 ----SOURCE -CODE s-- UH/007 9/ 66/036/010/1742/ 1746-
AUTHORt _~~danM*_:Ojo_Ao; Alekseyevs Yu. Ye.; borofeyenko, Go No
ORG: Rostov on the Don State University (Rostovskiy-na-Donu gosudarstvennyy
universitat)
TITLEt Condensation of phosphoranes wi,.th 192-0-cyclohoxylidene-alihn-D-xylopentadial-
dose
SOURCE: Zhurnal obshchey MIMI v..36, not 10, 1966, 1742-1746
TOPIC
TAGS s. organic chemical synthesis, organic phosphorus'compound
'SUB CODEt, 07
ABSTRACT.- 1,2-0-Cyclohex~lidene-alpha-D-xylopentadialdose (1), a cyclobe)Wlidene
analog of 1,2-0-isopropylidene-elphs-D-xylopentodialdoi;e (a promising Intermediatar.
for the preparation of higher sugars with an oldehyde group at the first carbon
atom by the Wittig reaction),,vao synthesized in the form of a crystalline.0 non
hyg .roocopic powder. Ito Infrared spectrum and structure-revealing chemital re-
actions were studied. The'compound was found to react vith phosphorenes of the
second groupo forming unsaturated deriyativeo of sugars with a furanose ring,
Orig. art.-has: 3forvulss.~ RS t 0,35.9
_j F.
UDCt ~547,454,661071801
L 518,)b 6 SWT(mL/WPkJ) RH
AUVIOR t Zhdanov, Yus Ao; Dorofeyonko, Go No; Korol'ohenko, Go Aol Os~q gA, a
01.11IG: Rostov on the Don State University (RostovsMy-na-Donu goaudarstvanqq
univeraitIAT
TMIS% Condensation of D-g3yceraldehydelwith phosphoranes
Vo
5OURCE: Zhurnal obahchoy khindi, 36, no.,3, 1966o 492-494
TOPICTAGS: -condensationx-ea6tion, IV~ttic aldebyde, chemical synthesis, organio
phosphol us compound, qub~tituent, 05L orimetallic 'organic derivativP
ADMIACT A general mothod 6f.synthesizing I-C-aryl--aabstituted unsaturated
.pentulosos on the bauis of the eqndensation of glycoraldebyde with benzoy1motW-
enotrDphonylphosphorano and its derivatives is proposed** The preparation of four
ncnr uns atu atod pontulosos is describedo The otIV; ester of 4,5-D-dihydroxypontene-
2-oic acid as obtained in the, reaction of glycer&1dorwas With car5itho'VMWIone-
jylphosphorano Orige art. hast 2 formulas, fJ-PRJS
SUB CODSt 07 SUEM DATEs 05Feb65 ORIG RCM 006 OTH REF: 001
UDCt
Card 1/1 4'5- J