SCIENTIFIC ABSTRACT ZHDANOV, V.M. - ZHDANOV, YU.A.

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SCIENTIFIC ABSTRACT
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ALEKSANYAN,,A.B., prof.; DEWENEVINUH I.S., doktor mod. naukj BELYAKOV, V.D.p doktor med. nauk; BF,=,!ERTNYY, B.S.: dokt. mad. nauk;,VASHKOV,.V.I.j prof.; GROMASHEVSKIY, L.V.. prof.; YUKIN,I.I., prof Prof.) ZHMAYEVA,.Z.M., kand. biol* nauk; KOVARSKrY, kand, med. nauk; NABOKOV,', V.A., prbf.1 NOVOGOIIODSKAYA, E.M., prof.; PAVLOVSKIY, Ye.N., akademik; PETRISHCREVA, P.A.# prof.; PERVOMAYSKIY, G.S.) prof.; POGODINA,. L.N.; ROGOZIN, I.I.) prof.; SUKHOVA, M.N., doktor biol. nauk; CIIASOVNIKOV, A.A., kand. med. nauk; SHATROV, I.I.,, prof.; SHURABURA, prof.,- YASHKULI., V.K., kand. med. nauk; ZHUKOV-VEREZHNIKOV, N.N., prof., otv. red.; BOLDYRW,, T.I., prof., re.d.; ZASUKRIN, D,N,p doktor biol, nauk, red.; KALINA, G.P.,, red., (Multivolume manual on the microbiologyp clinical aspects and epidemiology of,communicable diseases] Mnogotomnoe ru- kovodstvo po, mikrobiologii, klinike i opidemiologii. infek- tsionnykh boleznei. Hoskvaj Meditsina. Vol.5. 1965. 548 p. (MIRA 18:3) 1. Deystvitellnyy chlen AMN SSSR (for Aleksarqan, Gromashavskiy, Zbdanarv, Zhukov-Verezhnikov). 2. ^Ihler- korrespondent.41N SSSR (for Rogo2in, Boldyrev). - Zs4qy)-, !jfp;'ZBARSKIY~ I.B.- BUKRI31SKAYA, A.G.; FMOISKAYA., G'P. Study. of, the ~llnitiil stage of interaoilon of Sendai virutwith cells 210-ra the ailtoradiographic method* Ad* eksp. blol. t mbdo 56 no.7t67"72 Jlt63 OUU 17 23) lo 1z.1aboratorii fiziologii virusov zav. deystvital Inn chlen AM SSSR V.M.;Zhdencv) Thstituta virusologii Imeni D.I!. lvanovskogo (diro - doyetviteltnyy chlen AM SSSR V-M. Zhdanor) AM SSSRA laboratorii biokhimii kletoobnykh struktur (zav-s doktor biologicheskikh naulc I.B. Marskly) Instituta morfologii' (Agricultural machiner7--Safety measures) i LI 1585-66 5.05015051- Y :t~ Dorbun--A q':ghlk!- E:, EVIT(,l)/EWA(h). OW BOW_-UPJ UTM _V ber&% Dubla- U na- :T",'Khareva, Be last M ~.F 5 5- 5_,~ Physical proportion of rocks and mineral rossources of tho USSR (Fizichaskilo evoy- etva gornykh porod L polaznykh IskopayerVkh SSSR) Uoscow,. Tzd-wo 'NedrA",, IL964. 323 p. Illun., biblio. (At head of titles Gosudarstvenw goologich4skly k=i,.g tat SI.IISR. V5esqYu3Mz institut).,ILJO 3000 copies printed. Und@r the aditorehip of 0. M. Principal editors L A. Kaltvkava; Tecbn1cal editors A. S. Polosina; Proofreaders X. 5, Toroptseve, TOPM TAGS.' =gmatic rack,, mataaorphic rock,, m1neralogy, petrology, solamelopy Ip'", s5 FURPCGE AND COVFMGZ: This book to the result of the genoralization of =tArlals collected prImarily byrophysical trusts-and geologic agencies, as we3l in by the institube DAMAd (Vs=. Principal attention Is paid to the basic laws goTerning variations in the physical properties of rocks, various petrogmphic groups,, and useful minerals of divers almeralogic compositiond The phyalctl paraasters to ~Crd 213 W 7' AU5015051 2- - -wbich-4pei a Nj -the: specific &in the rat* of propagation of longitudinal 3. d and transverse wavoa, The compilers of the book are colleaVes #f the Laborator- Iya fizichoaklkh ffyoysty gornykh porod ar4. the Mal petrIgrafil of VMML They express their gratitude to Be A, Andra ~'jnG. I, Wartynavaly,-S. V. YOVVI,A. A. Log!kS4~ ', I Moskyaleva'J4 s. G.-Bo _Ik4vaZ-nRV. Fe eAqj!!a e. Ut Dyb~r;,"!B. K. L'yor;,V. 1, Mqqkv!k1Aya~4,,fj. Petroyaj,, Tu. Tq,. 1, key ich,, d_oiar Sh q, TABLE OF CCIIT=t Introductiom- - 3' Part. L Physical proparties:-of Magmatic and moUsorphic rocks Ch,~', Z- Physical properties. of rock4emlng mlneralr 9 Cho. 17, Denfilty'af rooki 33 Ch. 111. : kAgneltic, properties; I of rocko 93 Cho We ~Spsciflo electrical resistance of roo'kd 172- Ch V pagation of-longitudInal. elastic waves- in rocks 0 -- , , Rato, of Prs 193 ChO VY, Ob-Pho In j*qsi"! properties of rocks# depending an manifold pressure Card 2/3 L o .. ..... SUB GCMt 93; WBUIV 22Sep64 Na Par wvt M MMt 044 v 0 0-0:0,0 a 0-00.04 OW low so 1 -00- II all a I* J~tl Flies Nv *.V& v Q u 0 OrIP t IA M FRI 0#001"St^0 0#04,90tiff 140cs Ij I M, loo's go 0 go A 0 00 a f 00 see 00 off bo 0 IL i iij~a i 4;i ~~vlt U AV 10 9 A 4 Is cw a 0 a I or im a 4 )--g" r it' N 19 9 x N t9 to K "a I 0, * 0 V N ZHDANOV ~-M A isfi, d Y AIldi . M ng C ti As f carboti On O Nauk'S.S.S.R. 90, MOM ad A ~43*i 71JO-4-Chlorcitetriwayllivew (5 0 with,- ' I C C, MRSHr front 31.0 1, RHr sa% r the IMW "t On t 40% 0' 40 0 t t f T 5 . . rea men o . Iii min, with 0.8.1 X. CI In CCII save aertylglarme. in. 180,6-1V (from Iso-PrOll); ftpparen!f Cl I r led 5h) 0-pasition to (lit MeO group. Similarly was obta 101-21 (from eff 1 . 11. p ' ChentIcail Atint. ether), w Ich with lit in Atoll gave W di-arderiv..M.- 150-60*,.Wlth the Ur atomfi located In o,o -poiltions to the VoL 48 Noo 9 CtO group. O-Tttreacetyliylose (16 g.) 111' 20 ml. AeCI ~ PIVIO 1954' heated 10 min. with 15 C, PC$ and 5 g. AICIR on awaterl., bath gave, aftcr quenchisig in much coIrt 1120, 28% U. Oreahic Chemistrv Chloretfifler 1x*se_m, I* An- petr, - ethcr)_TK%___. __(ftT -W L h X it Ue C4IrtN ~4 ~ Y1 cdy gI)r gave 14p n i )(r(a se, x* In. 129.5-30,5* (from ko-PrOl I Similarly obeidned Were- cht(fropkejt)4)triaceiyl.rylose. m. 14 60.0,; (from IX 941.) Imond-i"I drriv.) M. 161-31 16 Iso-MOH); Br deria., m. 10-110* (from ivi-Proll)J; .39% I+Owew- lri4crlylxylofe' M, 130"l-IM, (train ix:tr. COICO., Thc'fatter (4 g.) in 28.8 mL Ac,O and 10." ml. AeOll miffed to 24 9. Cu0N:O.)j..3Ih() hi 33.0 inl.~~r,() and 14.4 int. AcOtf, jmve. 3370 nitre deriv, In. 165.5-7,0* (frmil lio-PrOll) The iinilarly ga"C 16~' P-anisyl deriv. (above) in 46 fifiti. ut 115'.s nitre dcriv, m, 1.5.1, 50V (frian NoTiOll), G. M.K.'.-I, ussR,Xhemistry - Ertraction of ilaments Caxd 1/1 Pub. 66 - 13/36 Authors i %hdanov, Yu. A. - - aftswev- Title I On utilization of biochemical concentrations of elements Periodical i Priroda 44/6, 89 - 93, :un 1955 Abetrnat A study is made of the disversion of certain e2e-monts, Institution Submitted @sees q-1, 6 iIII I . -.)i- II . ttL- v =E~ "9== I.- ... p I I i~ I I , 41 . I i M. P, Ill I I ~ lmllllllfll~- ! I "I Illilill ! illimill, .1 0111ilill. I I IfSSWChemical Technology. Chemical Products and Their Application Fertilizers., 1-6 Abst Journal: Referat Zhur Xhimiya., No 2, 1957, 5064 ..Author: Zhdanov, Yu. A.,,Azarov, K. P., Gorbatemko, V. Ye. institution: Academy of Sciences USSR Title: Glasses and Frits for Supplying Minor Elements to the Soil Original Publication: Dokl. AN SSSR, 1956, ioB, No 60 U29-1131 Abstract: To Improve the distribution of minor elem nts (ME) B, Kh, Cu, Zn, Fe, Mo, Co,,within the soil, to decrease their.combining with other soil cemponents and to reduce their leaching, It is advantageous to add to the soil ME that have been fused or fritted with glass. Solubility of the glass or frit is regulated by composition of the glass or by changes in the procedure of its production. Growing experiments are described which serve to determine the efficacy of minor element fer- tilizers prepared from readily fusible 3- or 2-component Slasses, window glass scrap or phosphate glass, containing also P, K, etc, by Card .1112 f I I I c/o r Card -1 _ i I (Lonins Vladimir Illich. 1870-1924) (Science) AUTHORSt Azarov, K~P*9 .26-10-12/44 Zhdanovp Yu, A 5RaIozub6v F M . , p TITLE; Perennial Mineral Fertilizers (Unogoletniye mineralInyye udobvw re PERIODICAL9 Priroda, October 19571 No 109 pp 84-86 (USSR) ABSTRACT: To improve the nutrition of plants, fertilizers are used which contain nitrogen# phosphorus$ potassium and so-called trace elements as boron, copper, cobalt$ zinc ' mapganese and others. Too large or too small quantities of such trace elements are harmful to the plants, As soluble salts used as fertilizere either wash out In the soil too fast or form compounds with other components of the soil# which the plants cannot annimil- ate, a new method has been developed by making fertilizers perennial. It consists of introducing Into the soil chemical trace elements fused with easily malting glass whioh Is then pulveriz'e'd and used for fertilizing, Such frits spread out well in.the soil.'aupplying plants steadily and for a long time with trace elements. Experiments conducted with corn, potatoest sugar beets'and cabbage over the period of a year Card 112 gave very satisfactory Ancreases of crops. AUTHOR ZHDANOV Yu.A., DOROVEYENKO G.N. PA 3155 TITLE --Fr-o_a_u_c_t_i`on__oT,0----C Derivatives of 1 -Arabinooe. (Sint*zy.C-----C 'proizvodnykh I-arabinozy. .-Russian) PERIODICAL Doklady Akademii:Nauk SSSR09579yol 113o Nr 3oPP 601-603 Recelved 6/1957- ~Raviewed 7/1957 ABSTRACT In previous works D019 2983,403 the winning of somemonoses (glu- cose# galactose$ xylosa~ was described according to the method of or- ganomagnesis. synthesis. This method has as yet not;b**A employed for the synthesis of 0----C-derivatives of 1-arabinosso Here ths 0------C- substitution products of this hydrocarbon was produced synthetically an a result of the.interaotion of 6-ohlortriao9tyl-l-arabinoss and' of the corresponding reagent. They contained ths following radioalss phenyl, anisyl, nathtyl, phenathylg' o-tolyl# n-tolyl, thienyl,,buty'l The general forlault of the compounds obtained Is the following; 0 Aco 00'. 0 In the course of the ohlorifiationp bromiz&tLonp iodation of anisyl- and phen*thylarabinose the corresponding halide dervatives are a*- Card 1/2 parated. AUTHORS: Zhdanov, Yu. A., Dorofeyenko, G. N. 20-6-3-9/47 Md Zn1vog1Kz9v3p L, Ye. TITLE: The Synthesis of Some Carbon-Carbon Derivatives of Carbohydrates (Sintez nakotorykh uglerod-uglerodnykh proizvodnykh uglevodov). PERIODICAL: Doklady:AN SSSR, 1957P Vol. 117, Nr 6, pp. 99o-992 (USSR) ABSTRACT: As,described earlier (references 1 - 4) the organomagnesium method broughtabout good results in the synthesis of the above-mentioned derivatives of d-glueosof d-galactose, d- xylose and I-arabinoee which contain various "agluooneo",. In the present work this method was employed for the production of some new compounds: phonyl-tatraacetyl-galactose, 0-tolyl- triscetyl-xyloaoI allyl-tatraacetyl-galactoBe and allyl- - triaostyl-arabinose. It was.found that the aoctylated allyl sugars are capable of adding a chloro-j bromo- and dirhodane- molecule at the double bond of the allyl residue. Haloid- derivatives of the already earlier synthesized phenyl- trlacetyl-xylose were also produced. Acetachlormonosacoharides which serve as initial products in the synthesis of the C--C Card 1/2 derivatives of hydrocarbons were obtained due to the treatment The Syn thesis of -Some Carbon-Carbon Derivat vos o Carbohydrates of sugar acetates with phosph phosphorus pentachloride and aluminum. chloride in a chloroform solution. An experimental part with the description of the production methods of the following compounds is given: P-chloro-triacetyl-l-arabinose, di-broma-phonstyl-triacetyl-xyloseI di-ehloro-phenetyl- triacetyl-xyloss, dibromo-mallyl-triacetyl-xylcsoj di-bromo- mallyl-tetraacetyl-glucose, di-rhodone-allyl-te-traacetyl- glucose and di-rhodane-allyl-triaostyl-xylose beside some above-mentioned sugar derivatives together with constants. There are 0 references, 5 of which are Slavic. ASMIATMNt Rostov_n&_D=%x ELtAte Uhiversity- (Rostovskiy na-Donu gosudarstvannyy'univerottet) PRESENTED: July 23, 1957P by A. I. Oparin, Academician. SUBMITTED; July 23# 1957 ---AVAILABLE: Library,of Congress Card 2/2 S OV/ 30-53-6-3o/45 AUTHOR: .Sergiyenkol I. Z. TITLE: The Chemistry and Metabolism of Carbohydrates in Animal and Plant.Organisms,(Khimiya i obmen uglevodov v zhivotnom i rastitel nom organizmakh) Conference in Moscow (Konferentaiya v MoBkve; PERIODICAL: Vestnik Akademii nauk SSSR1 1958, Nr 6, ppo. 1.12-M (USSR) ABSTRACT: This conference took place from January 28 to January 30. If was organized by the L&boratory for Physiological Chemistry of the AS USSR and was attended by about 2oo specialists, among them organochemiats, biochemists, physiologists, pharma- cologiste, histologists and physicians who represents& various scientific institutions of the AS USSR, of the Academy of Medical Sciences of the USSRt of the VASKhNIL of a number of universities and other colleges, as well as of branch in- stitutes from all,the country. It was opened by the Diroctor of the Laboratory for ?4ysiological.Chemiatry B. N. Stepanenko. He stressed in his detailed report among other things the Card 1/5 great theoretical interest in the investigation of the ab- 3 o-5.3-- 6--36145 The Chemistry and Metabolism of Carbohydrates in Animal and Pldnt Organisms. C onference in Moscow solute formation'of simple carbohydrates. Now and great success was achieve&, in the'field of the O-and N-glyoosides. He re- ~ported on some,important results of the work in laboratories. Furthermore the fol:,:7ing.reporte,were heard: I) So No DanilovvOn the reaction ofthe simultaneous ox,i- dation and regeneration in a group of carbohydrates. 2) Tu. A. Zhdanov: On the use of different methods of synthesis. W13. ~N- Sitepa ~~L. X. Kryukova, 0. Go Berdyuk: On in-, vestigations carried out in the field of some 0- and X- glycosides. 4) 0. K., Orlova: On 2 now diphtheria bacilli. 5) Ye.,K.41imova: On carbohydrates in the structure of diphtheria bacilli. 6) S. A.-Neyfakh and M. P. Mellnikova: On enzymatio members* 7) V. So Illin: On the importance of-hexokinase reaction, Card 2/5 ----------- sov/ 30- 58-6-3o/45 The Chemistry and Metabolism of Carbohydrates in Animal and Plant Organisms, Conference in Moscow 8) N. Ke Nagradova; On the properties of the effect of the dehydrase of phosphorus-glycerin aldehyde. 9) A. Ps Barkhash: On the method of the conversion of glucose. 10),Ao N. Petrov$ On the'presenoe of a phosphorus-less method of syntheois.in the liver 11) M, Is Prokhorova and Z. K. Tupikova: On the intensity of, the oarbohydiatemetabolism in organs. 12) B. 1. Khaykina: On the velocity of the regeneration of free and bound.glyoogene fractions. 13) Yee L#':Rozenfel'd:,On the funotion of animal organisms. 14) M- G.:Shubioh: On the results of the hintochemical investi- gation"of the glycogens of muscular tissue. 15) R- A. Rutberg: Ontheimportance of polyeaccharides in the investigation of the blood system. .Card 3/5 16) G. Ya.'Rozenberg and T. V. Polyshina: On the production2the __SO7/ 30-5 3-6-30/45 The Chemistry and Metabolism of Carbohydrates in Animal and Plant Organisms. Conference in Moscow properties and characteristics of,Soviet dextrin. 17) A ff. Petrova: On the problems of the pathology of carbo- ~;drate metabolism. 18) So Me Leytes and No To Smirnova: On the effect of the antidiabstio preparation BZ-55., 19).A6-V..Xotellnikova and G.T. Xrechetova., On special problems of the pathology of carbohydrate metabolism. 20) B. No Stepananko, Ye. M.,Afanaslyeva an& R. A. Baksova: On the chemical nature of a new polyeaccharide. 21) 0. A. Pavlikova and M. V, Turkina: On conversions of sac- charose in:p~ant tissues* 22) Do 1. Lisitaing, M. So Bardinskaya, M. I. Smirnova-lkonni- kovay'lu. V. Peruanskiyq Go A. Lukovnikova and V. I. Ivanov-t On carbohydrates of plant origin. In the resolution the achievements as vell as the shortcomings vere men-cioned. A commission for the coordination of work'was founded. Card 4/5 SOV/14-27-2-3/5 Zhdanov! Yu A Dorofeyenkoj 0. N. AUTHORSt (Rostov -na-Dond): Jy' 'Lu* A' TITLEs (___~OnRe't~erocy~clic a bon-Carbon Derivatives of Carbohydrates (Geterotaiklicheakiye uglerod-uglerodnyye proizvodnyye ugle- vodov) PERIODICALs Uspekhi Khimii,l 1958t Vol. 27, Nr 2p ppe 179 192 (USSR) ABSTRACTs Compoundst in which a polyoxaldehjrde-p a polyoxyketone- or a polyalcohol rest is connected with any organic radical (aliphatiot alicyclic, aromatic or heterocyclic) by single carbon-carbon bonds, are classed with the C-C-derivatives of sugars. In the present, article a survey is given on new experimental data in-the,field of heterocyclic carbohydrate'derivatives* and theattempt is made to generalize these data. Isopropylidene-9 benzylidene- and ethylidene derivatives of sugars,.different oxides (glucosane) and imino sugarsp are not treated, because, according to their properties, they rather belong to the Card 1/2 acetalef anhydro-ougarat amino-sugarep respectively. 5(3) ~:AUTHORS: Zhdanov, Yu. A., Korollchenko,.G. A SO'!/2o-122-5-17/56 TITLE, Irew Carbo~n-Substituted Derivatives of Glu cone (Novyye ugle-rodzameshchannyye proizvodnyye glyukozy) PERIODICAL: Doklady Akadoinii nauk SSSR) 1950t Vol 122, Ur 5, PP 811 013, OUR), ABSTRACT: In, the past. ~+,he authors -had produced different deri- vatives'mentioned in th6~ title. They contained ouch ' radicals ~as naphthylp tolyl, diphenyl, thienyl, phenetyl, p-anisyl and.others (Ref 1). The oreanomagnesian synthesis proved to be a general method of production of 3uch compounds. The paper under review describes the synthesis of o-anicyl-tetraacetyl-glucose and its bromine and nitric derivatives. The nitroderivative formerly produced of p-aninyl-tetraacetyl-glucoae was reduced to the correopondin- amino. Hydration in the precence of Haney nickel proved to be the beot Card 1/2 method of reduction; other methods.(with zinc, iron IfeW Ca----bon-Substituted Derivatives of rluCocle SOV/2o-122-5-17/56 or tin) did no,t Yield any clear results. The synthetized 3-a~qino-p-.inicyl-tetraacetyl-glttcot!o was turned 'into the corrotponding banzo~rl and diazotized product had to underao, an azo-combination with aniline# phenol and P-naphthol. A para3raph on experiments with the uoual data was added. There are 2 referencest which are Soviet. ASSOCIATIO147: Hostovskiy-na-Do,nu goaudara-tvernyy universi-tat (Roctov- -Donu State U. nivernity) PRESEUTED: June 4, 1956, by A.I.Oparint Academician SUBMITTED: June, 2, 1958 Card 2/2 5 (3), 'LUTHORB;: Zhdanovp YU. ~A* Sholoyinp 09.. Yo. SOO 5 3 4 -I.J1 0131 ComplexCompounds-in the Series of Perinaphthindene TITLE: (Kamplokenyyo ioyedineniy v ryadu perinaftindona) PERIODICAL: Izvestiya..Yysahikh uchobnykh zavedoniy. Xhimiya i khimicheakaya takhnologiya, 1959-t Vol 2v Hr 21 pp 200 -.203 (USSR) ABSTRACT: ~,.Perinaphthindenons W, like several other cyclic polynuclear ketones, forms molecular compounds with metal halides (Refs 1, 2#4.),.The'authore succeeded in finding that 2-bromine peri- ~naphthindenone-l (II) forms firm 'nuclear compounds with 11 trong aprotoniclacids (SbOl 'BACI ). 2-J-parinaphthindenone-1 (111) 5 4 forms an analogous:complex with tin tetrachloride. C H OBr. 13 7 lated. In SbOl ~(C H .qnCl were iao .-.5 " 13 4; (C13H70-J)2-3nCl4 'their crystalline state all complexes have precise melting tem- :peratures and are easily soluble.in CH COOH, in alcohol and in di6xane, butl.not easily soluble in other and bonzenel Their sol- ubility"in"yetrole'um other is poor. Whan'boiled in water# the hydrolysis destroys them completely, and they are completely Card 1/2 hydrolyzbd when boiled with water ammonia and weak acids (Ref Complex Compounds in the -Ser;iss of Perinaphthindeno 807/153-2-~4_10/31 .2). PerinAphthindenons hydrazone (IV) (Rof 3) also forms stable complex compounds with metal.halides. They are all soluble in pyridine and dioxans, but-their solubility in aloohol is poor. Hydrazone-is Tegenerated with their hydrolysis. A, stable com- plex ie-doyolopii-by a sublimate solution In absolute other. Salts ofbivalent mercury n rmally oxidize hydrasones down.to, diazone othane'derivatives Nef 7)- If mercury salts are ou- perfluousp nitrogen separates.,and organic mercury compounds develop (Ref 8). In the experimental part the production of molecular.oompounds of halogen derivatives of perinaphthinde- none andits hydrazone with halides of sovoral metals are do- scribed# as well as the production of 2-J-perinaphthindenone-1 (III), not described up to now. There are 8 references, 5 of which are Soviet. -Rostovskip-na ra ASSOCIATION, -Donu gosuaarstvannyy universitet; Kafed organioheekoy khimii (Rostov-na-Donu Stat University; Chair e of Organic Chemistry) -SUBMITTED: January 289 ~1958 Card.2/2,.-. B/153/60/003/004/023/040/XX B02O/BO54 AUTHORS.: Zhdanov" YU-,,& Dorofeyenko, G. N., Ivanchenko, N. V. TITLE: Synthesis of.Some Indole and Hexachlorane Derivatives of Monosaccharid.es PERIODICAL: Izvestiya~vysshikh uchebnykh zavedeniy. Khimiya i khimicheakaya tekhnologiya, 1960, Vol- 3, No- 4, ppo 680 -~683 TEXT: :.The authors.study the:possibility of synthesizing some hetero- .~,cyclicderivativeo.of Grignard reaction. For this purpose, they investigated the reaction of acetohalogenoses with indolyl magnesium bromide. It is known that organomagnesium compounds of the indole series form, as a rule, 0-substituted indole derivatives under .the action of alkyl- and acyl halides. The reaction of indolyl magnesium bromide,with acetohalogenoooo proceeds similarly, and yields P --indole 4erivatives of monosaccharides.,The resulting P-indolyl augars were fur- ther acetylated by acetic anhydride dissolved in pyridine, and isolated in,the form of crystalline acetylated compounds. By means of the Card:1/3 ~-Synthesie of Some In.dole and Hexachlorane S/153/60/003/004/023/040/Xx Derivatives of Monosaaaharides B0201BO54 Grignard reaction it was possible to synthesize P-indolyl tetraacetyl glucose$ P-indolyl tetraacetyl galactose, and P-indolyl triscetyl xylose. The resulting oompounds~are 0-- C derivatives, not N-glucooides, which is confi'rm6d bylthe presence of aotive.hydrogeng and by -4he results of .oxidation with.permanganate. The synthesis of heterocyclic derivatives ~with a pyrrole radical, was not possible in the way indicated. The au- thors continued th,e,investigation of the halogenation of acetylated aryl sugarso and found that phenyltstraseetyl galactose and phanyl tri- acetyl xylooet as well as phanyl.tetraacotyl glucose (Ref-7), readily add six chlorine atoms, thus forming hexachloro cyclohexanone derivatives of carbohydrates which are isolated.in sirupy consistency. The authors thoroughly describe thesyntheeis of P-indolyl tetraacetyl-d-glucoeei P-indolyl tetraaoetyl-d-galactose, P-indolyl triacetyl-d-xylose,.and hexachloro oyclohexyl. tetraacetyl-d-galactose, and study the reaction of 2,4-dimethyl pyrrole magnesium bromide with at-chloro tetraacetyl-d- glucose. There are 9 references: 5 Soviet, 2 USj and 2 German. Card 2/3 -ACC-NR~06, W3-1----- V 7/6 61034-[007/12 /12 12~-~ Tr 0 SOURCE-GOIR.- f V/W1 AWI-011: Z11(lanov, Yu. A.; Uz1ova, L. A. ORG: Rostov on the Don State University (Rostovskiy-na-Donu gosudarstvennyy ,unLversitet) al~ I TI.E. Carbon chain of augara SOURCE: Zhurnal obshchey khimii, v.-36, -1212 7, 1966t 1211 TOPIC TAGS: or ondonsation ganic synthatic-proceas, organic phosphorus compound, c reaction -J AB ko. -,,othyl~.r-.*Lpheiiylphospho.-anor. were synthesized for the first W MGT: A31 x0ayl 1.tima fro-m asters of brozmopyrvv~c aaid as poss:!:blo intormadiates for the synthesis' 1 of higher su-ars and their dcrivatpivos through the I.-littig reaction. ti Al"al.-hbxalylmetliylenaphosphorane was condonsed with 2). 3;1j,5,6-penta-O-acoty1-al- the ,D-ralact,ose according to a mothod dovalopod previously by authors for the ,synthesis of al~ha,bata-unsatur.%tcd C-sWostilArted ketoses. The condensation yielded, the methyl as Uar of an uwatura-ted kotonononoic acid: mothyl estorof ~,,3,4,-didehydro-3,4-dicieox.,f-5,6,7,8,9-ponta-0-acotyl-D-galacto-2-nonulo3onoic aoid in 42% yiold. Tho roaction pormits tho,buildup of the car'bon chain of carbohydrates on the basis of three carbon atoms. EJPRS: 38,9701 SUB CODE:'' 07 SUBM DATE: 1OMAY65 ORIG 1W 003 OTH HSF: 007 + rd 1 UDC; 547.4 569 + 5 0 7* .77n KZ __ACC_NRta76_ff_616_7 ----SOURCE -CODE s-- UH/007 9/ 66/036/010/1742/ 1746- AUTHORt _~~danM*_:Ojo_Ao; Alekseyevs Yu. Ye.; borofeyenko, Go No ORG: Rostov on the Don State University (Rostovskiy-na-Donu gosudarstvennyy universitat) TITLEt Condensation of phosphoranes wi,.th 192-0-cyclohoxylidene-alihn-D-xylopentadial- dose SOURCE: Zhurnal obshchey MIMI v..36, not 10, 1966, 1742-1746 TOPIC TAGS s. organic chemical synthesis, organic phosphorus'compound 'SUB CODEt, 07 ABSTRACT.- 1,2-0-Cyclohex~lidene-alpha-D-xylopentadialdose (1), a cyclobe)Wlidene analog of 1,2-0-isopropylidene-elphs-D-xylopentodialdoi;e (a promising Intermediatar. for the preparation of higher sugars with an oldehyde group at the first carbon atom by the Wittig reaction),,vao synthesized in the form of a crystalline.0 non hyg .roocopic powder. Ito Infrared spectrum and structure-revealing chemital re- actions were studied. The'compound was found to react vith phosphorenes of the second groupo forming unsaturated deriyativeo of sugars with a furanose ring, Orig. art.-has: 3forvulss.~ RS t 0,35.9 _j F. UDCt ~547,454,661071801 L 518,)b 6 SWT(mL/WPkJ) RH AUVIOR t Zhdanov, Yus Ao; Dorofeyonko, Go No; Korol'ohenko, Go Aol Os~q gA, a 01.11IG: Rostov on the Don State University (RostovsMy-na-Donu goaudarstvanqq univeraitIAT TMIS% Condensation of D-g3yceraldehydelwith phosphoranes Vo 5OURCE: Zhurnal obahchoy khindi, 36, no.,3, 1966o 492-494 TOPICTAGS: -condensationx-ea6tion, IV~ttic aldebyde, chemical synthesis, organio phosphol us compound, qub~tituent, 05L orimetallic 'organic derivativP ADMIACT A general mothod 6f.synthesizing I-C-aryl--aabstituted unsaturated .pentulosos on the bauis of the eqndensation of glycoraldebyde with benzoy1motW- enotrDphonylphosphorano and its derivatives is proposed** The preparation of four ncnr uns atu atod pontulosos is describedo The otIV; ester of 4,5-D-dihydroxypontene- 2-oic acid as obtained in the, reaction of glycer&1dorwas With car5itho'VMWIone- jylphosphorano Orige art. hast 2 formulas, fJ-PRJS SUB CODSt 07 SUEM DATEs 05Feb65 ORIG RCM 006 OTH REF: 001 UDCt Card 1/1 4'5- J