SCIENTIFIC ABSTRACT ZHELUDEV, I.S. - ZHELUDEV, I.S.
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CIA-RDP86-00513R002064710011-9
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S
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100
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Publication Date:
December 31, 1967
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SCIENTIFIC ABSTRACT
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e adkiyt Vo Vo I SOV/48---22--12--14/33--
Ruaakov L. Z. Rez, 1. So
TITLEt on Non-Linear Properties of Single Crystals of-BaT103.With
Additions of Pb and Single Crystals of Triglycine Sulfate in
a Strong Electric Field (0 nelineynykh evoystvakh monokristallov
BaTiO3 a dobavkami Pb i monokristallov triglitsinsul!fata. v
silinom e"ektricheqkom pole)
PERIODICAM Iz.vestiya Akademii:nauk SSSR, Seriya tizicheekayao,1958t
Vol-,22y NY 12, (USSR)
~ABSTRACTt The hyste'resis-interrelation between electric voltage and charge
I acharacteria,tic..'Of a pi6ioelectric condenser. Assujhing that
this interrelation is determined.by the idealized lqop shown in
figure 1, a.conneation between various harmonics of.charget of
Voltage of the alternating and the constant field and',the
geometrical characteristics of,the loop can be,found in
accordance with.Mezon's method (Ref 1). The triglyoine sulfate
and 139,T-j.0 single crystals investigated have shown a strong
..ndn-linearity (for trxiglyci4e sulfate N 80, for BaTiO N %W30)
d:A/2 3
C ar
On Non-Linear Properties-of Single Crystals of SOV'/46-22-12,14/33
BaTiO With Additions of, Pb,and-Single Crystals of Tr1g2ycine Sulfate in a
-3
Strong Electric Field
in the strong electric field (E >Ek) and high values of the
m
loss angle t- g(for triglycine'suilfate t94. 3-8 for
max
BaTio t .2). In,triglycine sulfate single cirystals a
3 gS in
m
considerable divergence of the curves illustrating the
dependence of.the'-dielectric constant e on the field tension
(,oflbotht the-alternating and the constant field), whichwere
~plotted at an increase and decrease of the voltages wasobserved*
This divergence-of a curves indicates a good electric "memory"
of triglycine sulfateo There are 6 figures and 2 references,
I of which is Soviet.
ASSOCIATION: Institut~.kristallografii Akademii nauk SSSR (Institute of
Crystallographyp Academy of Sciencest USSR).ToIJILP Komiteta po
radioelektronike.Soveta Ministrov SSSR (TaNILP of the Committee
..of Radioelectronics of the Council of Ministers, USSR)
Card 2/2
I lilfl IPHI 41., 01
24(3)
AUTHORS: Shuvalovp L. A. PXachkacheva, It. M., SOV/48-22-12-27/33
RusakovP L. Z., Zholudev, is S.
-----------------
TITLE:. !On Low-Temperature,,,Polarization of Ceramics From Barium Titanate
(flizkotemperaturnaya polyarizatsiya keramiki iz titanata bariya)
PERIODICAL:, Izvestiya,.Akademii nauk ZSSR Seriya, fizicheakayag 19513,
Vol 22, 11r. 121 ~RP 1516 -.1519 (USSR)
ABSTRACT: The present-paper deals with tests of the polarization and
the.aub:--polarization of. BaTiO ceramics in rhombic phase#
3
This polarization,has been called the low-temperature pola-
r12ation. These tests were,made on the assumptio-A that it might
be possible',to obtain.bigher values of piezomoduli of ~eramice
in the jrhombia and tetragonal phase by such a polarization in~
relatively..smail'fields. The low-temperature sub-polarization
in-the.rhombic phase causes an increaae of the values of the
piezomoduli of.ceramics in the tetragonal phase. On heating
under the field the subpolarization cauceD an increase of the
.:Card d31 by an average 15',fo- In apite of the noticeableageing- the d31
-7
On.~Low-Temperature Polarization of Ceramics From Barium 5011/413-22-12-27/33
Titanate
value ramaina,oby -more than 10% above the initial value. Heating
under the field after polarization in the rhombic phase pre-
~Vents thed from'becoming.smaller during the transition into
~the tetragonal phase. The polarization in the rhonibic,phase
with heating uinder,the field requires smaller fields than a
polariza.tion,at-room temperature , The d Al values do not become
.-smallcr,~-butAn:numerous cases even hig er than with hot pola-
.....rization.,Por thic,reason thelow-temperature poloxization
can be used-along with hot polarization, particularly when tht
latter is not,,feasible, for example on account of strong-con-.
in tho.proximity of the Curie (Kyuri) point. The
author's thank .,V,. G. Zatevakhina for his collaboration. There are
1~figurep 3 tablesp and 5 references, 4 of which are Soviet.
ASSOCIATION: Inatitut.kristallografii Akademii Pauk SSSR (Institute of Cry-
stallograpbyoAcademy of Sciences'USSR) TaNILP Komiteta po radio-
elektronike Saveta Ministroy SSSR (TeRILP of the Committee.on
Radioelectronies, Cabinet Council, USSR)
Card .2/2
24(3) SOV/2o-122-1-14/44
'AUTHORS: Spivak, Of V., Igrao N. , Zkoludev I. S.
-.'TITLE: On the Poculiaritiop.of the Domain Structure of Ferroelectrics,
~Made Apparent by Electron Microscope Visualization (0b
oLsobennostyakh -domennoy struktury negnetoelektrikov,
vyyavlyayemjkli pri. elektronnomikroakopichankoy vizualizateii)
PERIODICAL: Doklady Akademii nauk SSSRI 1956, Vol 122, Irr 1, pp 54-5T
(USSR)
'ABSTRACT: if the extraordinarily important r6le of the domains of the
forroeleotrioflL for the understanding of their physical
properties and of the nature itself.of the ferroelectrical
phenomena is Ltaken Linto aocount~ the application of electron
microscopy for.the purpose of completing the laws concerning
the orientation of the domains (of the characteristic features
of their boundaries and of their dimensions) offer many poe-
sibilities. According to the authors' investigationst the
domain itructure of the ferroeloo,trics may be visualized by
of a translucent microscope according to the method
of the imprints. These imprints must reproduce the fine struc-
Card 1/4 ture of the electric field. This was possible because of the
SOV/20-122-1-14/44
Onthe Peculiarities of the Domain Structure of Perroelectrical Made Ap-
parent' by Electron Microscope Visualization
existence of a natural raised profile (rellyef) of the ferro-
electric~poly-domain crystal. This raised profile of the
surface ielcaused by mechanical tensions on the boundaries
of the domains which, in turn, are caused by the interaction
of their electric dipoles. The use of a translucent electron
microscope and of colloid and coal imprinta permitted the
-detection of the domain structure on cryatals of barium ti-
and potassium sodium tartrato enlarged 25 000-fold.
The.domain'structure of the ferroelectrica may be observed
on imprints taken immediately from non-procensed crystals
and from etched.orystals. The authors etched crystals of
BaTiO in concentrated hydrochloric acid for 5 - 10 minutes.
3
The processing-of the samples is described in a few lines#
The authors then,describe the results of the preliminary in-
estigation of the domain structure by meano of an optical
microscope. J&ccording to the clectron nicroacopic inveatiga-
tiont the domain structure of the natural (not etched .) faces
of BaTiO in sufficient for the taking of very qualitative
Card 2/4 imprints. This natural profile is caused by spontaneous do-
BOY/2o-122-1-14/44
On'the,Peculiarities of the.Domain Structure of Ferroslectricap Made Ap-
_parent'~ by Electron Microscope Visualization
formations (which are connected with electrostriction]$momena)of
the domains. A figure shows a typical picture of the domain
structure of BaTiO in 1000-fold enlargement. With an 8000-
fold enlargement, 1he authors detected details of the shape
of a single domains In the case of still greater enlargements
(25 000-fold) the details of the boundary.between the domains
and some details of the structure of the individual domains
may be discerned..The domains detected by electron micro-
scopical inveatigation are smaller by one order of magnitude
than the, optically observed domains. This oubdomain structure
is very interesting for the detection of some properties of
the ferroelectrice. The reaults-ofthis paper concern single
crystals of BaTiO and potaasium,sodium tartrate. The authors
3
tharkV. I. Osokina and T. F. Pilippova for their help and
V* A,..Timofeyeva who placed the single crystals of BaT-iO3
at the authors' disposal. There are 4 figures and 7 references,
Card 3/4 4 of which are Soviets
SOV/70-4-1-23/26
'AUTHORS: Igras, E., Spivak7 G.V. and 'Zheludev
TITLE-.. Microrelief and.Domain Structure on the Surface ofa
Single Crystal-of Barium Titanate (Mikrorellyef i
domennaya struktura na poverkhnosti monokristalla
titanat-a'bariya)-
PERIODICAL: ' Kristallograftya, 1959, Vol 4,.Nr 17 pp 121-123
+ I'plate (USSR),
ABSTRACT: The surface structure of a single crystal of.~BaTiO has:
b&en studied-above and below the Curie point by optical
reflection microscopy and by stereo-electron microscopy,
Surface deformations.of two types were found: 1) elastic.
2) inela tic,
disappearing above theCurie point and e_ s
remaining-above the Curie point.' Crystals made in
various-vays behaved differently. Electron microscope
stereopairs were measured photogrammetrically and gave
a value of 600 A for the depth of the relief bands in a
quasi-elastic".example. Tn an inpla6tic sp6cimen
the.corresponding depth was 2 000 The form of the'
relief waves appeared rectangular. The relief seems'to
Cardl/2
SOV/70-4-1-24/26
AUTHORS: Spivak, G.V#j Igras, E., Pryamkova, I.A. and
-TITIS: Observations of-the Domain Structure of Barium Titanate by
Means of an Electron.Mirror (0 nablyudenii domennoy
struktury titanata bariya.pri pomoshchi elektronnogo
PERIODICAL;-~Kristallografiya, 1959, Vol 4, Nr 1, pp'123 125
+ -1 plate (USSR)
'ABSTRACT: It hasbeen-shown that it is possible toobtain by me an s
of.an electron mirror a qualitative representation of
domain structure of a ferroeleetric with a magnifi-
cation'of up to'several hundred times. The mechanism of
image-formation differs'from that in optical polarisation,
...microscopy. Earlier devices (Ref 2) used a magnetic
field for the''Imagnetic contrast effect" but this caused:..
instability. An electron beam from a gun is accelerated...
by.20 kV and:passes through a hole in a fluorescente
screen to the specimen where it is reflected. The s
ystem
.is roughly analogous to that of an ordinary microscope
with-incident Illumination supplied through the eyepiece.
Cardl/2
SOV70-1~_1-24/26
Observations of the Domain.Structure of Barium Titanate by Means
an, Electron. Mirror
Examples arereproduced of -images from BaTiO single
3
crystals,at 800X and 150X and a resolution of about
200,lines/ma~was':achieved. The reflection of the slow
electrons is due to -the fringing field between the
domains There are 5 figures and 10 references, 6 of
which ;~'e Soviet,:3 Englishand 1 French.
~A.SSOCIATION: Moskovskiy.~gosudarstvennyy univer6itet imeni
M. V. Lomonosova,,(Moscow State University Imeni
M.V. Lomonosov)
SUBMITTED- August ios-~1958
Card 2/2
of
- ------- -------------
SOV/70-4-1-26/26
AUTHORS. Shuvalov,.L.A.,~Aleksandrov, K.S. and Zheludev,, I.S.
TITIE: On them Question of the Domain Structitre,of'Ob Y6tals~ ~of
Trislycine - Sulphate (K voprosu o domennoy-strukture.
kristallo,v-triglitsinsul-...Ifata)
PERIODICAt: Kristallografiya, 1959, Vol 41 Nr 1, pp 130 132 (USSR)
, -
ABSTRACT: (NH2PH2C0OH)i.H.;,SO4 is isomorphous with the selenate
. and-the-fluoberyllate and several other.terroal
ectries
.-: .
which pass from the class . 2/m 2 at -the Curie point,
Possible ways in which thedomains can be twinned are.'
discussed here. Besides the symmetry of the transibioa
2/m 2 the-only other assumption is that in the
-ferroelectric state with no i, the mosaic
-mposed field,
crystal has no overall moment. Two and only two
mutual orientations of the domains are found, These
are:
SOV/70-4-,2-25/36
AUTHORSI _'Yurizi,~ V.A. and,Zholudev, X.S.
TITLE t The Influence of Thermal Troatmont on the Electric,
Properties of Rochelle Salt,Containing Impurities
(Vliyaniye termichoskoy obrabotki na elektrichaskiye
avoystva segnetovoy soli, soderzhashchey primesi)
PERIODICAL: Aristallograftya, 1959t Vol 4, Nr 2, pp 253-255,(USSR)
Rochelle. salt crystals damaged by y-radiation and alio
crystals gro -from solutions containing impurities have
Crystals were grown from'a solution
-containing.2% CuCO It was found that an abnormal loop
was obtaPed which 3returned to normal after annealing
at 401-45 -for some hours with slow cooling -~1-2 hours)
to room temperature. After some 200 hours "rest" at
room temperature,the abnormal loop returned. Measure-
ments were-madeon an X---ut crystal at 50 c.p.s. A
minimum field strength is needed to,establish the
abnormal double loop and this deperlds on the times of
exposing the specimen at different temperatures. It
follows that the arising in the crystal of the state in
Cardl/3 which a double hysteresis loop is observed takes place
SOV/70-4-2-25/36
The Influence of Thermal Treatment on the Electric Properties of
Rochelle Salt Containing-Impuritles,
only i the presence of a domain structure the domains
being in a state of rest. If tile specimen in exposed to
t m ratur lying outside the Curie interval (where
e pe
a
the domain structure is present) then the state in which
the iiormal hysteresis loop is pbserved can be ietained as
long as necessary. If the specimen Is at a temperature
between the Curie point but a'constant or alternating
electric field in applied to it,~under the action of which
the drystaX either becomes a iingle domain or undergoes a
of reorientation of the domains, then
''the state with the normal hysteresis loop:is also retained.
Graphsof the temperature dependence of dielectric
:susceptibility/i%cimens under different conditions are
given. ThereLare,5 references, 4 of which are Soviet and,
1 Japanese and 3 figures,
Card.2/3
SOV/70-4-3-26/32
AUTHORS: Zheludev' I.S. and Sonin
A.S.
TITLE: Rotation of.Plane' of Polarisatio In of Light and the
Symmetry of.Crystals
PERIODICAL: Kristallografiya, 1959, Vo 1 4,, Pir 3, pp 425-429 (USSR)
ABSTRACT: The changes in the . symmetry of crystals conditioned,.
in the general case, by tho changes (appearance, chango
of.sign,.change,of magnitude) in the specific rotation
Rf the plane of polarisation of light are investigated.
The specIfic.rotation in one direction is described by
an axial.tensor of symmetry 00 2 . The gyration
surface of a crystal can belong to one of the-four.'symmetry:
'groups 2.-2, 46ml 00: 2 and 0oloo The morphological
d~ symmetry groups of.crystals which show rotation 'either
coincide with these groups or their sub-Sroups. Point
'groups which can show rotation are 1,2 394,6, 2, 3.-2$
4:2-,. 6:'20 M, 2.m, 4-M, 3/4, 3/2,
A 6hange in the' point symmebry of a crystal on phase
transition conditioned by a change in the rotation can be
found from 'Curie's principle (A.V. Shubnikov Ref 4)
Cardl/2
SOV/70-4-:1-26/32
'Rotatioh.of Plane.of Polarisation of Light and the Symmetry, of
Crystals
to this principle the symmetry of the crystal
on bliange,ofrotatkon can be determined an the highest COM-.
monsub-group of the point'group to which the crystal
~belongs in its.initial state and the symmetry group of
the gyration sur-fac,e for the given disposition of the
-symmetry elements of both groups. Hence, for any of the
32 classes the change in.symmetry connected with a change
in rotation can be found. This is tabulated for all
classes and for the 4 symmetries of gyration surface.
There are 5 tables and 4 Soviet references.
ASSOCIATION: Institut krintallografii AN'SSSR (Institute of
Crystallography ofthe Ae.Sc., USSR)
SUBMITTED: March 171 1959
Card 2/2
SOV/70-4-4-5/34
AUTHORS: Sonin, A.,S. and-Zheludev T
Spatial Symmetry and Ferroolectric Phase Tran itions
PERIODICAL: Kristallografiya, 1959, Vol-4, Nri 4, pp 487-497 (USSR)
~ABSTRACT: Tables are given showingl for each of the 230 Space
groups, the space,groups which result when a crystal
of the initial space group undergoes a ferroalectric
transition.developing a spontaneous polarisation
along one of the axes-