SCIENTIFIC ABSTRACT ZHELUDEV, I.S. - ZHELUDEV, I.S.

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CIA-RDP86-00513R002064710011-9
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December 31, 1967
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SCIENTIFIC ABSTRACT
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e adkiyt Vo Vo I SOV/48---22--12--14/33-- Ruaakov L. Z. Rez, 1. So TITLEt on Non-Linear Properties of Single Crystals of-BaT103.With Additions of Pb and Single Crystals of Triglycine Sulfate in a Strong Electric Field (0 nelineynykh evoystvakh monokristallov BaTiO3 a dobavkami Pb i monokristallov triglitsinsul!fata. v silinom e"ektricheqkom pole) PERIODICAM Iz.vestiya Akademii:nauk SSSR, Seriya tizicheekayao,1958t Vol-,22y NY 12, (USSR) ~ABSTRACTt The hyste'resis-interrelation between electric voltage and charge I acharacteria,tic..'Of a pi6ioelectric condenser. Assujhing that this interrelation is determined.by the idealized lqop shown in figure 1, a.conneation between various harmonics of.charget of Voltage of the alternating and the constant field and',the geometrical characteristics of,the loop can be,found in accordance with.Mezon's method (Ref 1). The triglyoine sulfate and 139,T-j.0 single crystals investigated have shown a strong ..ndn-linearity (for trxiglyci4e sulfate N 80, for BaTiO N %W30) d:A/2 3 C ar On Non-Linear Properties-of Single Crystals of SOV'/46-22-12,14/33 BaTiO With Additions of, Pb,and-Single Crystals of Tr1g2ycine Sulfate in a -3 Strong Electric Field in the strong electric field (E >Ek) and high values of the m loss angle t- g(for triglycine'suilfate t94. 3-8 for max BaTio t .2). In,triglycine sulfate single cirystals a 3 gS in m considerable divergence of the curves illustrating the dependence of.the'-dielectric constant e on the field tension (,oflbotht the-alternating and the constant field), whichwere ~plotted at an increase and decrease of the voltages wasobserved* This divergence-of a curves indicates a good electric "memory" of triglycine sulfateo There are 6 figures and 2 references, I of which is Soviet. ASSOCIATION: Institut~.kristallografii Akademii nauk SSSR (Institute of Crystallographyp Academy of Sciencest USSR).ToIJILP Komiteta po radioelektronike.Soveta Ministrov SSSR (TaNILP of the Committee ..of Radioelectronics of the Council of Ministers, USSR) Card 2/2 I lilfl IPHI 41., 01 24(3) AUTHORS: Shuvalovp L. A. PXachkacheva, It. M., SOV/48-22-12-27/33 RusakovP L. Z., Zholudev, is S. ----------------- TITLE:. !On Low-Temperature,,,Polarization of Ceramics From Barium Titanate (flizkotemperaturnaya polyarizatsiya keramiki iz titanata bariya) PERIODICAL:, Izvestiya,.Akademii nauk ZSSR Seriya, fizicheakayag 19513, Vol 22, 11r. 121 ~RP 1516 -.1519 (USSR) ABSTRACT: The present-paper deals with tests of the polarization and the.aub:--polarization of. BaTiO ceramics in rhombic phase# 3 This polarization,has been called the low-temperature pola- r12ation. These tests were,made on the assumptio-A that it might be possible',to obtain.bigher values of piezomoduli of ~eramice in the jrhombia and tetragonal phase by such a polarization in~ relatively..smail'fields. The low-temperature sub-polarization in-the.rhombic phase causes an increaae of the values of the piezomoduli of.ceramics in the tetragonal phase. On heating under the field the subpolarization cauceD an increase of the .:Card d31 by an average 15',fo- In apite of the noticeableageing- the d31 -7 On.~Low-Temperature Polarization of Ceramics From Barium 5011/413-22-12-27/33 Titanate value ramaina,oby -more than 10% above the initial value. Heating under the field after polarization in the rhombic phase pre- ~Vents thed from'becoming.smaller during the transition into ~the tetragonal phase. The polarization in the rhonibic,phase with heating uinder,the field requires smaller fields than a polariza.tion,at-room temperature , The d Al values do not become .-smallcr,~-butAn:numerous cases even hig er than with hot pola- .....rization.,Por thic,reason thelow-temperature poloxization can be used-along with hot polarization, particularly when tht latter is not,,feasible, for example on account of strong-con-. in tho.proximity of the Curie (Kyuri) point. The author's thank .,V,. G. Zatevakhina for his collaboration. There are 1~figurep 3 tablesp and 5 references, 4 of which are Soviet. ASSOCIATION: Inatitut.kristallografii Akademii Pauk SSSR (Institute of Cry- stallograpbyoAcademy of Sciences'USSR) TaNILP Komiteta po radio- elektronike Saveta Ministroy SSSR (TeRILP of the Committee.on Radioelectronies, Cabinet Council, USSR) Card .2/2 24(3) SOV/2o-122-1-14/44 'AUTHORS: Spivak, Of V., Igrao N. , Zkoludev I. S. -.'TITLE: On the Poculiaritiop.of the Domain Structure of Ferroelectrics, ~Made Apparent by Electron Microscope Visualization (0b oLsobennostyakh -domennoy struktury negnetoelektrikov, vyyavlyayemjkli pri. elektronnomikroakopichankoy vizualizateii) PERIODICAL: Doklady Akademii nauk SSSRI 1956, Vol 122, Irr 1, pp 54-5T (USSR) 'ABSTRACT: if the extraordinarily important r6le of the domains of the forroeleotrioflL for the understanding of their physical properties and of the nature itself.of the ferroelectrical phenomena is Ltaken Linto aocount~ the application of electron microscopy for.the purpose of completing the laws concerning the orientation of the domains (of the characteristic features of their boundaries and of their dimensions) offer many poe- sibilities. According to the authors' investigationst the domain itructure of the ferroeloo,trics may be visualized by of a translucent microscope according to the method of the imprints. These imprints must reproduce the fine struc- Card 1/4 ture of the electric field. This was possible because of the SOV/20-122-1-14/44 Onthe Peculiarities of the Domain Structure of Perroelectrical Made Ap- parent' by Electron Microscope Visualization existence of a natural raised profile (rellyef) of the ferro- electric~poly-domain crystal. This raised profile of the surface ielcaused by mechanical tensions on the boundaries of the domains which, in turn, are caused by the interaction of their electric dipoles. The use of a translucent electron microscope and of colloid and coal imprinta permitted the -detection of the domain structure on cryatals of barium ti- and potassium sodium tartrato enlarged 25 000-fold. The.domain'structure of the ferroelectrica may be observed on imprints taken immediately from non-procensed crystals and from etched.orystals. The authors etched crystals of BaTiO in concentrated hydrochloric acid for 5 - 10 minutes. 3 The processing-of the samples is described in a few lines# The authors then,describe the results of the preliminary in- estigation of the domain structure by meano of an optical microscope. J&ccording to the clectron nicroacopic inveatiga- tiont the domain structure of the natural (not etched .) faces of BaTiO in sufficient for the taking of very qualitative Card 2/4 imprints. This natural profile is caused by spontaneous do- BOY/2o-122-1-14/44 On'the,Peculiarities of the.Domain Structure of Ferroslectricap Made Ap- _parent'~ by Electron Microscope Visualization formations (which are connected with electrostriction]$momena)of the domains. A figure shows a typical picture of the domain structure of BaTiO in 1000-fold enlargement. With an 8000- fold enlargement, 1he authors detected details of the shape of a single domains In the case of still greater enlargements (25 000-fold) the details of the boundary.between the domains and some details of the structure of the individual domains may be discerned..The domains detected by electron micro- scopical inveatigation are smaller by one order of magnitude than the, optically observed domains. This oubdomain structure is very interesting for the detection of some properties of the ferroelectrice. The reaults-ofthis paper concern single crystals of BaTiO and potaasium,sodium tartrate. The authors 3 tharkV. I. Osokina and T. F. Pilippova for their help and V* A,..Timofeyeva who placed the single crystals of BaT-iO3 at the authors' disposal. There are 4 figures and 7 references, Card 3/4 4 of which are Soviets SOV/70-4-1-23/26 'AUTHORS: Igras, E., Spivak7 G.V. and 'Zheludev TITLE-.. Microrelief and.Domain Structure on the Surface ofa Single Crystal-of Barium Titanate (Mikrorellyef i domennaya struktura na poverkhnosti monokristalla titanat-a'bariya)- PERIODICAL: ' Kristallograftya, 1959, Vol 4,.Nr 17 pp 121-123 + I'plate (USSR), ABSTRACT: The surface structure of a single crystal of.~BaTiO has: b&en studied-above and below the Curie point by optical reflection microscopy and by stereo-electron microscopy, Surface deformations.of two types were found: 1) elastic. 2) inela tic, disappearing above theCurie point and e_ s remaining-above the Curie point.' Crystals made in various-vays behaved differently. Electron microscope stereopairs were measured photogrammetrically and gave a value of 600 A for the depth of the relief bands in a quasi-elastic".example. Tn an inpla6tic sp6cimen the.corresponding depth was 2 000 The form of the' relief waves appeared rectangular. The relief seems'to Cardl/2 SOV/70-4-1-24/26 AUTHORS: Spivak, G.V#j Igras, E., Pryamkova, I.A. and -TITIS: Observations of-the Domain Structure of Barium Titanate by Means of an Electron.Mirror (0 nablyudenii domennoy struktury titanata bariya.pri pomoshchi elektronnogo PERIODICAL;-~Kristallografiya, 1959, Vol 4, Nr 1, pp'123 125 + -1 plate (USSR) 'ABSTRACT: It hasbeen-shown that it is possible toobtain by me an s of.an electron mirror a qualitative representation of domain structure of a ferroeleetric with a magnifi- cation'of up to'several hundred times. The mechanism of image-formation differs'from that in optical polarisation, ...microscopy. Earlier devices (Ref 2) used a magnetic field for the''Imagnetic contrast effect" but this caused:.. instability. An electron beam from a gun is accelerated... by.20 kV and:passes through a hole in a fluorescente screen to the specimen where it is reflected. The s ystem .is roughly analogous to that of an ordinary microscope with-incident Illumination supplied through the eyepiece. Cardl/2 SOV70-1~_1-24/26 Observations of the Domain.Structure of Barium Titanate by Means an, Electron. Mirror Examples arereproduced of -images from BaTiO single 3 crystals,at 800X and 150X and a resolution of about 200,lines/ma~was':achieved. The reflection of the slow electrons is due to -the fringing field between the domains There are 5 figures and 10 references, 6 of which ;~'e Soviet,:3 Englishand 1 French. ~A.SSOCIATION: Moskovskiy.~gosudarstvennyy univer6itet imeni M. V. Lomonosova,,(Moscow State University Imeni M.V. Lomonosov) SUBMITTED- August ios-~1958 Card 2/2 of - ------- ------------- SOV/70-4-1-26/26 AUTHORS. Shuvalov,.L.A.,~Aleksandrov, K.S. and Zheludev,, I.S. TITIE: On them Question of the Domain Structitre,of'Ob Y6tals~ ~of Trislycine - Sulphate (K voprosu o domennoy-strukture. kristallo,v-triglitsinsul-...Ifata) PERIODICAt: Kristallografiya, 1959, Vol 41 Nr 1, pp 130 132 (USSR) , - ABSTRACT: (NH2PH2C0OH)i.H.;,SO4 is isomorphous with the selenate . and-the-fluoberyllate and several other.terroal ectries .-: . which pass from the class . 2/m 2 at -the Curie point, Possible ways in which thedomains can be twinned are.' discussed here. Besides the symmetry of the transibioa 2/m 2 the-only other assumption is that in the -ferroelectric state with no i, the mosaic -mposed field, crystal has no overall moment. Two and only two mutual orientations of the domains are found, These are: SOV/70-4-,2-25/36 AUTHORSI _'Yurizi,~ V.A. and,Zholudev, X.S. TITLE t The Influence of Thermal Troatmont on the Electric, Properties of Rochelle Salt,Containing Impurities (Vliyaniye termichoskoy obrabotki na elektrichaskiye avoystva segnetovoy soli, soderzhashchey primesi) PERIODICAL: Aristallograftya, 1959t Vol 4, Nr 2, pp 253-255,(USSR) Rochelle. salt crystals damaged by y-radiation and alio crystals gro -from solutions containing impurities have Crystals were grown from'a solution -containing.2% CuCO It was found that an abnormal loop was obtaPed which 3returned to normal after annealing at 401-45 -for some hours with slow cooling -~1-2 hours) to room temperature. After some 200 hours "rest" at room temperature,the abnormal loop returned. Measure- ments were-madeon an X---ut crystal at 50 c.p.s. A minimum field strength is needed to,establish the abnormal double loop and this deperlds on the times of exposing the specimen at different temperatures. It follows that the arising in the crystal of the state in Cardl/3 which a double hysteresis loop is observed takes place SOV/70-4-2-25/36 The Influence of Thermal Treatment on the Electric Properties of Rochelle Salt Containing-Impuritles, only i the presence of a domain structure the domains being in a state of rest. If tile specimen in exposed to t m ratur lying outside the Curie interval (where e pe a the domain structure is present) then the state in which the iiormal hysteresis loop is pbserved can be ietained as long as necessary. If the specimen Is at a temperature between the Curie point but a'constant or alternating electric field in applied to it,~under the action of which the drystaX either becomes a iingle domain or undergoes a of reorientation of the domains, then ''the state with the normal hysteresis loop:is also retained. Graphsof the temperature dependence of dielectric :susceptibility/i%cimens under different conditions are given. ThereLare,5 references, 4 of which are Soviet and, 1 Japanese and 3 figures, Card.2/3 SOV/70-4-3-26/32 AUTHORS: Zheludev' I.S. and Sonin A.S. TITLE: Rotation of.Plane' of Polarisatio In of Light and the Symmetry of.Crystals PERIODICAL: Kristallografiya, 1959, Vo 1 4,, Pir 3, pp 425-429 (USSR) ABSTRACT: The changes in the . symmetry of crystals conditioned,. in the general case, by tho changes (appearance, chango of.sign,.change,of magnitude) in the specific rotation Rf the plane of polarisation of light are investigated. The specIfic.rotation in one direction is described by an axial.tensor of symmetry 00 2 . The gyration surface of a crystal can belong to one of the-four.'symmetry: 'groups 2.-2, 46ml 00: 2 and 0oloo The morphological d~ symmetry groups of.crystals which show rotation 'either coincide with these groups or their sub-Sroups. Point 'groups which can show rotation are 1,2 394,6, 2, 3.-2$ 4:2-,. 6:'20 M, 2.m, 4-M, 3/4, 3/2, A 6hange in the' point symmebry of a crystal on phase transition conditioned by a change in the rotation can be found from 'Curie's principle (A.V. Shubnikov Ref 4) Cardl/2 SOV/70-4-:1-26/32 'Rotatioh.of Plane.of Polarisation of Light and the Symmetry, of Crystals to this principle the symmetry of the crystal on bliange,ofrotatkon can be determined an the highest COM-. monsub-group of the point'group to which the crystal ~belongs in its.initial state and the symmetry group of the gyration sur-fac,e for the given disposition of the -symmetry elements of both groups. Hence, for any of the 32 classes the change in.symmetry connected with a change in rotation can be found. This is tabulated for all classes and for the 4 symmetries of gyration surface. There are 5 tables and 4 Soviet references. ASSOCIATION: Institut krintallografii AN'SSSR (Institute of Crystallography ofthe Ae.Sc., USSR) SUBMITTED: March 171 1959 Card 2/2 SOV/70-4-4-5/34 AUTHORS: Sonin, A.,S. and-Zheludev T Spatial Symmetry and Ferroolectric Phase Tran itions PERIODICAL: Kristallografiya, 1959, Vol-4, Nri 4, pp 487-497 (USSR) ~ABSTRACT: Tables are given showingl for each of the 230 Space groups, the space,groups which result when a crystal of the initial space group undergoes a ferroalectric transition.developing a spontaneous polarisation along one of the axes-