SCIENTIFIC ABSTRACT ZHEREBKIN, G.P. - ZHEREBOV, L.P.
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CIA-RDP86-00513R002064720003-7
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RIF
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S
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100
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November 2, 2016
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March 20, 2001
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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0.0.; GURIKOVA.- V.G.-,-
*=LIX, Lis.; Rl~aOV, 1.1.; ..46- -; MIKOXAVIVA, I.V.;
ICUROBKO. V., redektor; IAFCHVUKU, K.. takhnichni7 redaktor
[Industry of.the Soviet Ulcratri during 40 yatirs, 191j-19571
1?romymlcvtstl Pzuians'kd Ultrainy in 40 kokiv (1917-1957). Xylve
Derzh.vyd-vo polit.lit-ry URSR, 195?o 330 p. (XLF4 10:10)
1. Akedemiya Dattle. UR4, Kiyev. lastitut ekonomiki.
(Ukreit~a-- Induc tries)
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'AUTHORS: Ginz-bur-, D. B.' Doctor
chaical 72-50-7-2
. ~ciencos, Zherebin
nTLE: 'Ration lization of the Fuel Economy of the
a Corlkiy Glass
Works (RataionalAxatsiys toplivnogo khozyayetva Gor1kovs*,1W:o.
stekollnogo zavoda)
PERIODICAL: Stoklo I koramika, .1958, 1ir 7, PP- 3-0 (USSR)
ABSTRACT:, Meaeures, ti.iolintroduction of which is intended within 2.to 3
years, are investigated, The Increase of the gas heating power,
as well as the 'suspension of the conduction of the phenol con
.gaining waste waters into the river Volga are considered-1o be
urgent. The gas heating power required for obtaining a certain
output of glass mass, as well as the dependence of the
ciency of the kiln on the output of glass mass are~given.in_
figure 1. It is intended to increase the heating power of1the
generator gas by the addition of propane-and butane gasi Some
properties of these gases are given in table 1 and are further
described. The scheme of a device for the storage and trans-
~portation of a propane-butane mixture is ohown in figure 2.
The dependence of the gas yield and its heating power on the
Card 1/3 humidity content of peat may be seen in figure 3. The quanti-
1J
naliz7ati-oii-of-tli-e-&el-Econo-my -,6_f__th6G6r1kiy SOM-58-7-2/19
Glass Works
tative ratio-.between.the propane.-butane -mixture and the Can-
erator gasat various schemes of gas purification and utili-
zation of tar in dependenc
e on the,humidity o6ntent of peat
and on the heating power required by the mixture is given
(Pigs 4 to-9). Furthermore, 4 variants of 4sing undried Las
are given and described. The possibility and suitability of
.the dryihg of
peat by means of exhaust gases.was found by
.tests carried out by.the Institute of Power Engineering AS of
t,
he BSSR (AS Belorussian OSR ) (1.A. Lyuboshits and I.T,
E1.1perin/Ref 1 ) and by, tha Tnztltute of Gas UtilizationAS
USSR (A.T.,Tishchenko / Ref 2).For conveying the tar to the
nozzle burner the'-us'e of an 611-pumping outfit developed by
TaffIlTMash 16).. is. considered. The constructioni,of the
nozzle burner in-which the fuel.is sprayed by highly cal-
otov
orific..gae#' fac.proposed by the metallurgists N.N. Dobrokh
d N (Aef, I),. It in also recommended to,try out the
an i rarp
nozzle bur'ne'r.developed by II.A..Zakharikov and A.I. Rozhanskiy.
at the.,' Ins'titute`6f Gas utilization AS USSR (Raf 1 Concludnnis-
The heating power of.peat-gencrator gas may be increased by
2/3 the addition of a. propane-butane mi- ture and by artif iait,.l jeat
oil
66362
SOV/120-59-5-5/46
AUTHORS: Zh erebin, Ye. A., Andreyev, L. Go and Timoshuk, D. V*
----------------
TITLE: Fast Neutron,~Spectrometer
tekhnika eksperimenta, 1959, Nr 5, pp 29-32:
(USSR)
ABSTRACT: The spectrometer is based on the.principle put forward by
Mozly and Shoemaker in Ref I and is illustrated
Bchematically:in Fig 1. The detecting system consists
of two.scintillation counters, a proton proportional
counter and a collimator. The detecting system is
placed in a common-jacket filled with methane,which is
the working gas-of the proton counter. The neutron
beam n is incident on a crystal phosphor 1 (tolane)
which is the source of recoil protonsin the spectrometer.
The collimator. 5 .-selects the recoil protons from the
crystal. 1 and lets them through into the proton counter
andthe crystal phosphor 2 (tolane) of the other
94
3
scintillation counter. The recoil protons spend almost
all their energy in the crystals of the two scintillation
counters# The sum of the pulse heights from the
scintillation counters is proportional to the energy of.
Cardl/3 theneutron which gives rise to the particular recoil
66362
Past NeutronSpectrometer SOV/120-59-5-5/46
--proton. The pulse, from the output of the proton counter
is used in a coincidence circuit to separate out the'y-rays.
Pulses from.the scintillation counters I and 2 and.the
proton counter are, applied to the. inputs of channels .1, 11
and.P,-of the cleetronic.scheme of the spectrometer (Fix 2),
Channels I and*II of the scintillation counters aro
identical* The wide-band amplifiers I have switches
giving two values of the amplification coefficient so that
the work may be carried out in two energy intervals. The
output cathode followers of these amplifiers feed.t.he
pulses into the -delay lines 2 so that the scintillation
pulses and the pulses from the proton counters are
brought to the same point in time. A part of the signal
is fed through the.amplifiers 3 into the triple coinci-
circuit 9. The pulses from the proton counter are
fed into the amplifier 7, are shaped by the fast trigger 8
and are then fed into the triple coincidence circuit 9.
'A pulse will Appear at the output of this circuit only if,
the recoil proton produced in the acittillator I (Fig 1)
passes through the collimator 5, the proton counter 3,4
Card2/3 and enters the sc.intillator 2. The remaining parts of
66362
Fast Neutron Spectrometer SOV/120-59-5-5/46
raot N e u t:',
''the.signal from.the delay lines 2 are fed through
the transmission circuits 4. The pulse froin the triple
Coincidence circuit 9 opens the transmission circuit4
for channels I and-JI. The total pulses are fed into
the amplifier 14 and then to the amplitude anaiyser.15.
The efficiency of the spectrometer is 1-31 x 10 -k for
14.5 MeV neutrons. Fig 3 gives the dependence of the
efficiency on energy. As can be seen, the relation is
linear. The resolution is 10% at 14.5 MeV. Fig 5
shows the neutron spectrum from a Po + Be source
The Po + Be source had an intensity of about 10 neutrons/
see. There are,6 figures and 4references, l,of
which Is.Soviet and 3 English.
SUBMITTEDt August 22, 1958
Card 3/3
10UMMICH, Anton Ivanovich [Konsievych, I.I.], kand.okonounauk; ZHK~M
GOP. [Zherebkid, H,P,10 kand.akonom.naukj, oty.red.,, GURIKKO, Tj,
V*A*1# redo'
[Carrying out the'resolutions on the development of alwokbreeding
as directed by the December Plenum of the Central Committee of the
CPWJ Vykonaismo rishennia, hrudnevoho Plenumm TeX IM v dell shomm
pidnesenni tvarynnytetva. Kyiv, 1960~ 39 pe (Tovarystvo dlia.
poshyrennia polityohnykh I naukovykh sna'A I Ukrainulkoi RM. Ser.6,
no.12)o (MM 13:9)
.,(Stock and steckbreeding)
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KUS(MM, Vasiliy Sargeyevich-, OBRA2TSOV, V.A., retsanMt; RAKOV,
A.F., retsenzent;.ZMMOV, I.V., red.; AERAMOVA, Ya.A.,
teklm.red.,
f
(Automatic. control_...,o production processes] Avtomatike pro-
izvodstvennykh:pro~'s saov.~ Rostov-na-Donug Rostovskoe
knishn izd-voS-'_.1960.:- 95:p,
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ARKSMOROV. Petr Xuzlmich; ZMMICOVt I.T., red.; PMWA, F.As p
tekhn.red.
(Aid for a young electrio welder] V pomoahch' molodomu
slaktroevershchiku. Rostovna-Donus Hostovskoe knishnoe
izd-Tot 1959s 59'p, (MIU 13:5),
welding)
F--X.
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AUTBORS.- Ginzburgi D* Boj,Dootor of Technical Soioncee SOV/72-59-7-9/19
Matveysylt Me A. Zherebin So 1.
TITLE: increase of-thwWorking Efficiency of Glass Kelting Furnaces by
Sealing the Regenerative and Recuperative Systems (PovyshwAye
offektivnosti raboty steklovarennykh pacbsy putem uplotneniya
regenerativnoy i rekuperativnoy oistem)
PERIODICALz Staklo ileramika, 1959, Nr 7t pp 26 - 30 (USSR)'
ABSTRACTs The'authors of this paper dnd 1. V. ~ebedsva(Footnote 1). . fe=d.
that the air excess in the tank furnace of the Gor*kir glassworks
amounts to 15% and of the Gusevo crystal works amounts to 23%0
found in -the glassworks
Do B. Ginaburg, M, Ya. Magidson (Footnote 2)
,
imeni Kalinin an air excess of aG a 1, 2. Therefore the authors of
this paper do not agree with the statement of V, A. Ireobmar and
M, Go Stepanenko (Footnote 4~ that the burning in the funaos in
the glassworks takes place.with an air excess of aL, * 1.5 till 1-7-
The amount of gas passing the regenerators is calculated by memo
of equativiis which are givenIand explained. These informations for
the GorOkiy-works were published already earlier, for the Ousevo
cryoW works they am represented in the figure. As it may be seen,
Card 1/2 from it it Is possible to attain considerable savings by making
g , ; '. .
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KOV-s-Seraf im -Kona tantinuri cbv;-BABU'uHKINA-i-S.-I-.-,--redakttr-F ORNZYIVAP
1:17, tekhnichookly redaktor
[The-holding power of resins applied to metals] Xreplenis raziny k
metallame Moskva, Goes nauchno-takhno izd-vo kbim. lit-r7, 1956.
.147 p* (MMA 9:8),
"C~
USSR/Chemistry of High Molecular SAbstaaces, F
Abs.Jour Referat. Zhunlal,Khimiya, no 6., 1957, 19423.
Author B.V. Deryagin, S.K. Zherebkov, A.M..Madvedeva.
Iwo
Inst.
Title Concerning the,Fart of Diffusion of Polymer Chains
in the Mechanism cf Adhesion and Autohesion (Stickinig
Together) of.Rubbers.
_-Orig Pub Kollod. Zh., 1956, 18, No 4, W4_412.
Abstract Wi th a view to study-the influence of relaxation or
diffusion processes on autohesion, the autohesion of
.,HK and SKB was investigated, using tne-method of
crosoed quartz threads covered with rubber filme
(Kolloid. zh., 1950, 12, 431; RZhKhim, 1956, 32140).
It was shown that the energy of nutoheeion sharply
increased in case of films from 0 to 0.1/"and above
0.5 thick, which was connected w1th the increase of
van der Waal's forces in the first case. and with the
facili,,tation offormation of platforms at easily de-
Card 1/3
:USSR/Chemistry of High Molecular Substances. F
AbS, Jour Referat. Zhurnal Khimiya, No 6~ 1957~ 19423.
formed thick films in the second case. In the thick-
nesslinterval from 0.1 to 0.5M, the autohesion
energy did-not depend cu the 'film thickness. The :Ln-
crease of the contaOt duration increazed the autobesion
energy only if the tilm thicluiess was>O.5At from
which it followed that the diffusion processes did
not play any part id the-autchasion of thin films.
During the study'of the correlation of the combinabIl.-
ity of various rubbers and their adhesion one to an-
other and autohesion, the measurement of the shear-
ing strength of rubber adhesion wns carried. out and
it was shown that in case of butyl rubber, the dif-
fusion processes did not~play a great part and that
its adhesion strength, was determined by the areu of
the true contact depending onLthe mechanical proper-
ties and by the influence of forces connected with the
double.electrical- layer, which played an essential
part at the measurement of the work of tearing by the
method of oxfollation. In case of NX, G 0, SKS-2
SKS-30,.SKS 2
-Card 2/3 -13-
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U MAN OV gA -a v-r-e- AjV-Y_ A T__K I N j,- -A Y er e dGAR BAR Y. I
red.; ZAYMOVSKIY., A.S.,red.j KARGIN, V.A., rod.;
KISHKIN, S.T.,,:red.1 KIARXINA-RATNEfty SOL, doktor tekhn.
nauk, red.1 PANSHIN, B.I.,, kand..tekhn. nauk, red.;
ROGOVIN, Z,A., red.; SAZHIN, N.P., red.; SKLYAROV., N.M.,.
doktor tekhn. nauk, red.;.FRIDLYANDER, I.N.9 doktor tekhn.,,
naukp red.; SMNIKOV$ A.V., red.; SHCHERBINA, V.V.., dokpr
nauk.. red.;ISHRAYBER, DOS.$ kand. tekhn. nabk,
red.; GMLI,, S.V.p.kand. tekhn, nauk, red.1 VINOGRADOV,,G.V.,
doktor khoz. naukp red.; NOVIKOV, A.S., doktor khoz. nauk.red.;
I.I.p daktor tekhn. nauky red.; 2RUAM-Y&K
kand. tekhn. nauk, red.; BOGATYREV., P.M., kand. telft. iiifuR-,",Fed.j
SANDOMIRSKIY,, DOM., D.M.j kand. tekhn. naukp red.i BUROVJ S.Vop
kand. tekhn. nauk,, red.; POTAKf Ya.M.) doktor tekhnonaukt red.1
KUM, G.N., doktor tokhn. nauks red.1 KOVALEV, A.L. kand.takhn.
nauk, red.; YAMANOV, S.A.,, kand. tekhn. nauk, red.; SUF7ELI,
IOA.0 kand. khoz* nauk,, St. nauchn. red.; BABERTSUH, A.S#, inzho,
nauabn. red.1 BRAZHNIKOVA, Z.L., nauchn. red,- KALININA, Ye.M.0
_~mlad. red.; SOKOLOVA, V.G., red.-bibliograf; &i~SELISKAYA, Ch.A.p
red.
(Building materials; anencyclopedia: of moiern technology] Kon-
struktaionnys materialy; entsiklopediia sovremennoi takhniki.
Glav. red. A.T.Tumanov. Moskva, Sovetskaia antaiklopediia.
Vol.l. Abliataiia - korrozila. 1963. 416 P. (MIRA 170)
1. Chlen-korrespondent AN SSSR (forKisbkin).
T, 11 ~(k 1. 0
F, (k )/E Aji'(c r!p/
)
-
cc NRt
HMIJDAN
-
Zlicreb1cov, Scrafim KonstOnt1ngx;kq
k
-
A Ocr AC
U-o mtal bond erloniy6 raziny I mtmll=) 2d ed.,, rev. and enl,
1
-bscov, lzd-vo "'Ah 11
& 66.. C~46 p, lUus,, biblio,, 1rAex, 5,300 coPies
13rinted,
:TO?IC TAGS,. wtal jointint-:,- -rwtal luing, =tal surfacing, nevural rubb
er.,
t
s
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b
di
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A
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-~c rub
on
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ing mterial,
na.., a
ing.. bon
-FL -.T
qPCSE AM COMAGE: This book dcacribes the zethoda of riZber to mal bonding
UZO& In the Illdu5try.' The naents of bomlings, the mathods doterirdnine the
StrenGth of rubber to mtal bondin," , and the modern theoretical conceptc or, the
=chanisms of bonding exe 'described., The book is intendcd for engineering arA
toccImical workers of the plantus m6mufactbrinG rubber to imtal bonded cxt A-clea,
it cari also be used by researchers working in the field of rubber to metal
bom1ing.
TABI.T." Cv. CO'Nums (6brldged):
Forevord
intxoduction
:Ch. 1. Basic informtion
.
Bibliography 15
I ccrdIJ3 t=621.792.4:678.o63
CC NRz
Ch. 11, As*hm-t inf&,Itation on basic materials used in bomUns 17
36
4.
Ch. 111. Prepora. n of mthl and rubber surfaces before bonding 38
ca. IV, Adhezlves)?Jsolvent~~, comnting 40
BibUoCj-a7-6h-y. -- 46
M. V. , I-bthods o.L '.esting 70
oz;r 12~
Bibli 1
CIII. V1. Rullber to metal bonding by mans of ebonite 114
126
Bibliou aphy
Ch. VII Rubber to rmtal borAing, b rwans of brrtqq IV
0
B:Iblio~Xa]~ny -- 17,
Ciao VIIL~ - Rubber to matal boridina,by means of latex albumen we thermopene
Gownt -.171
BIWAoaTaphy 4". 179
Ch, Z(, Bondirig rubber to)wtal, by. means of adhesivea rode from halol&rubber
rubber .. 180
Biblio&pkphy -- 205.
Ch. X. BoMIng rubber to mQtal by wans of adhesives made from isocymates
206
B:IbIio3rqpiW 225,,
Ch. XI. Bonding rubbet- to metalby rwarw off adhesives =de from Synthetic
resins -- 226
BiblioCraphy -- 235
Cho XII. Bonding of rntaU to riMer made from hiCh teMerature raw =ateriais
Card 21
.- I- K2"N~J-* t--L
TIVII,
OV, A.T. yrqlavv- red.;~ WATKI219 A.Yo., red.
tekWw-,UWc,, redoyMIADVSKIY K-8 jrrGd,j*KARGIN# V~A*#,:
redq K!SHKINi,.-S.-T-.# red.; KISHXIUJL-UTM, Ss'I daktor
tekb:w,vovkv-4ed-.j-PAvs=p Bier.'It.kando tekbno naukj-red,j
ROGOVINj.'ZO-Lg daktoilckox$ rAuk, red.; SAZHIVO X,Ps# red.;
SKLYAROV# N.IM#,,,46ttbr-tekhn.nauk,, red.; FT~IDLYANMR, I.N."
doktor tekbn, .ii6k)-,red.; SIIUBNIKOV, A.V.,, red.; SHCMMINA,,
V.V,j, doktor geol.-miner. nauks redej SIUMBER,. D.S.j, kadn.
~tekhn,naukj.red ; GENELI, S.V.p kand. tekh~.nauk., red.;
NOVIKOVs A.S.0 ~oktor khoz. nauk, red.; KITAYGORODSKlYt I.I.,
doktor tekhn. naukp red.; 4,1,R.MKW, S.K.s kand. tekhn. nauk,
1211- - --a
red.; BOGATYREV,'P.M., kand. tekhn.- A. p red.; BUROV, S.Vep
kand. tekbn. nauks red.; POTAKp Ya.M,j doktor tekhn, nauki,
red.; KUKIR, G.Hof doktor tekbn. naukj red.j KOVAIZV, A.Lp
kand. tekhn. nauk, red,; ZENTSELISKAYA, Ch.A.,j tekhn, red,,
(Building materials;~`an encyclopedia of modern technology]
Konstruktsion2We,-materialy; entsiklopediia savremennoi tekh,
niki. Glav. red*' Twmnov,, A.A. Moskvap Sovetakaia entaiklo-
pediia. Vol.1, Abliataiia - Korroziia. 1963. ~416 p.
(MRA 170)
-korroupondent KisWn).
L Chlen All SSSR (for
A_.D
B GROMN, -ye.M4; - CHELMDEYEV,
-Investigating. the' cheidual,etability of some natural rubbers
:and rubber goods, pr6ftew'--on -,their base. Kauch.1 rez, 21
nosl2sl1p.14 D 1620
Institut rezinovoy promphl meti,
Pubber-Testing)
I. j ~ 1, j" 1, ~ - :
-1111"t, I Ili 1:114 141,111111": 11"
!
S/191/62/000/005/008/012
BlIO/B101
AUT S
HOR Korolev, A. Ya Zherebkov-p-S K oriGova, F. X.,
Medvedeva, A. M.,76rozhan, Ye. M.
I~iE_ Gluing of ftoroplast-4 to rubbers
~PERIODICAL_.' Plasticheakiye.masay, no, 5P 1962Y 37-39
TEXT:: Ptoroplast-4,-(Polytetrafluoro ethylene) was glued to organofluorine
-and acrylonitrile rubbers.: For this purpose
the surface, degreased by
I- .,means of gasoline,.was modified with a sodium-naphthalene complex
activated by addition of 2 g-ato'm Na metal per mole naphthalene in I liter
tetrahydrofuran. After 46 sea treatment of the film, rinsing in acetone
and waterl and 30 min drying at 10OPCp the surface color turned from
milky white to gray-brown. The contact angleof wetting with water
dropped here from 106 to 45-550- Crude rubbers were pasted on using glue
on the basis of nitrile rubber and thermoreactive resin OD-H-1 (FEN-1)).
The strength of gluing,of organofluorine and acrylonitrile rubbers to
ftoroplast-4 with smooth surface was 0-56-0-92 kgf/cm, with rough
surface 2-55-5.66 kgf/cm.. The gluing of CKH-26 (SKN-26) rubber to
Card. 1 /2
.i i
m
~
: I i ! IT! ~
I ;, ,, ~!
11 I'l Hit ~' ~ H 141
I -, X ~ .1 i I - I ;
S/138/59/000/07/0a/000.
AuTwWs Kaluzhenina, K. ZherqtU%. S. K., SUkh tina, T. M
.-,Sergeyieheva, V. S.
TIM$ On the tropertlearof Mixtures andIVulcanizates Based on Bromobu~Z`
Rubber X
~MUODTCALi Kauchuk I Rezina,.: 1959,, 'No. 7, pp..13-18
The authorsloutline the.valuable properties of butyl rubber and
..'explain its Iapplication in the production of rubber articles. The chemical and
phyt':rc~al properties of Vulcanizaiia made of butyl rubber are due to their low
non-saturation an(i also to the presence of regularly distributed side methyl
groups, linked with thedensely packed linear chains, as deeori bed in Ref , 1, by
R. Thomas and L. King, The properties of the vulcanizatas made of the butyl
rubber are described, band howth6se properties are applied -in the production,of
'various rubberized articles.. However, the disadvantage of the butyl rubber mixtures
is the slow vulcanization and the incompatibility of the butyl nibber with other
r4on-saturated polymers, aa:well as lts.poor adhesion to various metals, Some of
these disadvantages could be eliminated by the use of bromobutyl rubber, Accord-
ing to the authors, there~are two methods for the production of bromobutyl
Card 1/3
31138/59/000/07/03/009
a Properties of Mixtures and Vuloanizates Based on Bromobutyl Fmbber
yl.-rubber'on the rollers with bromine
r.- 1): by brominating' the but 2) by
ating-the butyl-rubber with-
ethyl,bromine in.a. solution.of ethyl, chlorinej
.'m irisoxi Ai Made 1~of the properties of domestic bro.mobutyl rubber produced by-
6-:M'eth~ds~vith those of:the imported bromobutyl rubber of the HIker 09wka-r),
trad k and,the:possibillt h be
e mar- _y~of:combining t e._.bromobutyl,rub rwith
polymers. is shown.,: When combining the domestic bromotnityl rubber with
ral rubber', rubber.lo-obtainea with satisfactory properties, The oompati-
ty- of the, biomobutyl. rubber-wIth: other polymers makes It possible -to cement
. er onto met4a. The experimental. procedure undertaken Is outlined in. detail
. ;the.technolo-gi6al and physico--mechaniloal properties of the vuloanlz~tes are
rMined and given In:Table l.- Ths-highest stability
of-the sAh~i qft~s reached
eeh the 'Ply of natural rubber or butyl:rubber and a ply of a mixture of
,O,rted bromobutyl rubbers combinediwith natural rubberj- a somewhat lower
ility ,16 reached with a ply or's, Mixture based on the domestic bromobutyl
er., combined- with theonatural. 'rubber. Adhesion to metal of the rubber can
ocbmplished by, using the ply of, OL: mixtune based on the:bromobutyl rubber.
po, 6 ng'the.bromobutyl mixtures to Mtal,.ibV the hot method was.
9sibility- f fixi
led. -The results of:the test-45 are given in Table 7. The results of the
2/3
;SOV/81-59-w9-33450
-Translation1rom: Reforativnyy. zhurnal Kh-imiya, 1959, Nr 9, p 562 (USSR)
AUTHORS.--" Xaluzhenina, K. FL, Sku-ba, I.A., Zherebkov, S.K., Medvedeva, A.M.
TITLE s The Increase in the Adhesiveness of Rubber Mixtures and Olues Based
.,on Synthetio Rubbers
PERIODICAL- Tr.:N.-i. In-ta razin, prom-Eti, 1956, W 3, pp 47 - 55
AWTRACTt The possibilities of increasing the adhesiveness of.-~~es and glues
baudd.on butadiene-styrMa (ES),butadiene-nitrilet(EN) rubbers and
gluexbased on neopreneO(N) by means of oondensation realnot
rubrezina, B (I), -yarrezina A (II), yarrezina B (III) have been studied.
.-The optimum.dosls'of these resins for raw mixtures of BS and BN is 10
weight parts per 100 weight parts of.rubber. According tothe capacity
of Increasing the adhesiveness, of the raw mixtures of Mf,, 1, 110? 111 av
eauiv4lent. The Introduotlon of the## resift iat* tbk vtbb,~ru1tw*
I'dIi(I
69h6h
S/069/60/022/02/012/024
D034/DO02
AUTHORS: Med~redeva A. M. Deryagi B.V., Zherebkov, S.K.
TITLE:, Studies of Adhesion Phenomena in Rubber to Metal Bon-
ding With " Leykonat"6Glue,3. Interaction Between Sodi-
um Butediene Rubber and Triphenylmethane Trilsocyanate
.PERIODICAL
; Kolloidnyy zhurtal., 1960, Vol XXI19 Nr 21 pp 21?-222~
. (USSR)
'
.ABSTRACT:., ~The
authors report on. a study of.the interaction
between rubberand triphenylmethane triisop yanate in
olutions'and the-effect of the gogjapatel on rubber
as a vulcanizimg agent. The study was intended to
-
~verify.the assumption that'the cause of adhesion
at the boundary~ rubber - "Leykonat" film Meykon~at"
is-a gluerepresenting a 2096 solution of triphenyl-
methane trii
socyanate In dichloroethane) consists
.
in.1chemical interaction between the rubber and the
Card- 1,4
69464
S/069/60/022/02/012/024
.Studies,of.~Adhesion Phenomena in Rubber-to Metal Bonding With
",Uftonat", Glue, 3. Interae'tion.-Be'tween podium Butadiene Rubber
,.:,and.Triphenylmethane Triisocyanate*
isodyanate. Triphenylmethane.triisocyanate can ai-
multaneously interaot-with several rubber molecules,
which necessarily"must result in the formation of
a:structure similar_to thenetwork obtained by vul-
investigation the authors used
sodium butadiene.~.rubber of the type RShch. For
the"study of -the-formation-of three-dimensional
structures in the~solutions a.viscometer of the t
ype
PV-7-Z Ref:3,41 was used, which permit's investiga-
tion of the properties of highly viscous liquids and
conq,entrated-dis~-erse. systems. This device makes
possibleto'reveal-anomalous structural viscosity of
the systems and,to,determine simultaneously the ul-
timate defOrmation*.stress. The design of 'the device
Card 21/4_~.
Ar SOV/69-21-5-10/23
00)
AUTHORS: Deryagin, B.V.i Zherebkov, S.K. and.Medvedeva, A.M.
TITLE: A Study of Adhesion.Phenomena in Rubber to Metal
Bonding With Leykonat Cement. 2, Bonding of Metal
'and Unfilled Rubbers
TITLE: Kolloidnyy zhurnal, 1959, Vol 219 Nr 5, PP 558-563
(USSR)
~ABSTRACT: :This isa study.of the adhesion phenomena observed
inthe bonding of unfilled rubbers to metals with the
aid of the isoeyanate cement: Leykonat. Table 1,
gives a survey of the rubbers and -their ingredients$
The rubbers were bonded to metal plates (cleaned with
emery paper Nr 100) during the vulcanization process.
The bonding strength was cha:!aeterized by the re-
sistance to theseparation of the rubber from the
metal, and was expressed in kilograms per centimeter
2
of the width of the specimen (erg/cm, The results
Card 1/5 of preliminary experiments showed that in a number of
-- ----------
66200
SOV/69-21-5-10/23
A Study..of Adhesion Phenomena in Rubber to Metal Bonding with Ley-
_-,kondt Cements 2. Bonding of Metal and Unfilled Rubbers
cases the'bonding strength exceeds the strength of
the rubbers-themselves, and the rupture has a cohe-
sional character. In order to obtain in all cases
an adhesional character of rubber-metal separation,
the authors.reduced the thickness of the cement film.
The experiments revealed however, that this reduction
in thickness-affects differently the bonding strength
of,rubbers prepared on the basis of different natural
rubbers. The data given In table 2 and graph 1 shows
that with the aid of leykonat cement (on the basis
of,triisocyanate.triphenyl methane) it is possible
to bond to metal rubbers prepared on the basis of
polar as,well as non-polar natural rubbers. In pro-
portion to the growing of the chemical activity and
polarity of the natural rubbers, a growth in the in-
tensity.of interaction of the cement film can be
observed with rubbers prepared on the basis of these
natural rubbers, whereas the intensity of interaction
Gard'2/5 of the cement film with the metal remains constant
V, il I 1~ U "it t.
The experimental results however, show that in the
given case-the bonding strength does not-grow mono-
tonously in proportion.to the increase in chemical
activity and polarity,of the natural rubbers. After
an initial growth,it passes through a maximum, and
subsequently drops. The authors have shown that the
bonding strength of rubber to metal will be high o 'n 1y
in the case ofan approximate equality of the intensi-
ties of interaction at the cement-metal and cement-,
rubber interfaces. If.when one of the surfaces is
in contact with the cement film the intensity of in-
teractionAs considerably higher, the bonding strength
of tubber to metal will be.low. The authors already
showed In a preVious' public ation fRef 1_7 that there
is an increase in intensity in the interaction of a
m
cement fil with a sandblast reated metal surface.
Bonding of the mentioned rubbers to such siufaces
~Card 3/5 therefore,'will bring about a change. The authors
66200
~07/69-21-5-10/23
A.Study of AdhesionlPhenomena in Rubber to Metal Bonding with Ley-
konat Cement. 2. Bonding of Metal and Unfilled Rubbers
~ascertained,this phenomenon on the basis of two cha-
racteristic-examples.: bonding of unfilled rubbers pro-!
pared from'butyl rubber and SKN-40. Whereas the bond.
ing strength of the first rubber did not change, the
~bonding strength of the second rubber was increased
by approximately ten times. On the whole, the ex-
periments have shown that the strength of the rubber
to matal bonding, due to the cement film,,is controlled
by,the ratio of intensities of interaction of the
latter with~the~,contacting surfaces at the cement-
rubber and.cement-metal interfaces. in the case of
E~n approximate equality of.both intensities,.the
bonding strength,will be low. One of the factors af.,
f6eting the,intensity of interaction of the cement
film with the rubber is the reduction in thickness
of the cement film.' Such a reduction results in a
drop in the intensity of interaction of film and
Card 4/5 rubber, ivhich differently reflects on the strength
66200
SOV/69_21-5-10/2
3
'A Study:of Adhesion Phenomena in Rubber to Metal Bonding with Ley-
konat Cement. e_i 2. Bonding of Metal and Unfilled Rubbers
.of the rubbers tozetal bonding, this strength in-
creasing in some cases and decreasing in others. Use
of the isocyanate cement leykonat makes possible a
o
s
lid bonding to,metal of unfilled resins prepared
on the basis of most of the existing polar and non-
polar'natural.rubbers. It was ascertained that an
increase of polar,groups in natural rubber results
in an increase in the intensity of interaction of
the film with the rubber containing this natural
rubber. There,are 2 tables, 2 graphs and 2 Soviet
references.
ASSOCIATION: Nauchno-issledovatell.skiy inatitut rezinovoy promysh-,
Moskvai.(Scientific Research Institute of
the Rubber Industry, Moscow)
~SUBMITM: -Oct. 2, 1958
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1110) as a umii. fol '. (I fiq 4 Itm pwr The Wool #"Ohs
At a 42 3155. Ajawil im owsto-iby *voolol)
worlil of 441% Pulp, "volts, is 7% lianift. mild 0171p III $-.,I
Itud w4w vias III-taitio-J, lippolvo. fbv panic fro,tilt. '00
Aort w,hisined with votmoll Motto Me moafivorl Itartispol
valor age
Ior Chuniamford Show '4 pillilly With votooml o-hil" witlo,
'*0
CCIUSUF V3&d t0olU1101. The fittlill ChhWidt MtW )ICI air
14011 at 4U*. The -00
trnmvcd with t1,0 at M)' afoot 17,
I'lloilwt 14whrof with 1 -1 ; 1.1 patis Ili Ion. Of CI giv"
it I' toot I-I'vi" "mt*' 11 Pratt "al"[
JIM S
livot. IIN-44hing of firval"I t--mo 4.1.1 with &.I- C1
Inoduced idensir torsulu. 11111"i; 4t&**
so
so
'o0
pad. i's-4i6q.
I&Ajej * -- - ---1 -- - -.1 -- . - . :- . ~ - I - :4 too
it . ~Ili ;0*
4. - too I I o u4 avor
U, 0 AV IQ is , * 1A
'n ; in I 1 0 toot a
rm
0 ~ do is 'ev
0 0 90" if 0 0 0 * 4 - 0
0-0-0-0 0-0 0 0: 0
s 00
a IF Al I AIR ism IN teos-ad
4
A 0
010-4
-
-
as
- Imislivirtr
oit off $r.
as p
inks of UNW* lotination to b"If on thr diff,millml 44
"
Ca
M-
ffi
all
t
I
a
lam
ll
d d
l
"
.01 GO
at c
o
s
n
im iin
e
gli
At
,
procews of
p
JM
lin in dil-
l"
of U
m &W cmi
f th
t
d
h
.
e con
e
e exama, o
p
An
l
T
frmt martloW of OW and wintri-tyt Otilk at diffmilt
h
d
o o
s,
Ots" of grainh by Ill# slain and fluoirmnet met
The arculaulation of Ocala 14 a vrittlable flaut pracmIll
"W b
f
i
i
h
l
f
i
lot
- 4 or
o
unct
on twi
.
ys
y
diffemlly accord
ng to the p
tiffs fuld a Ittv lity"
ul
l
d ma
th
#
I
so ;
aw a
It.,
ate
a yo
p
n p
fit the Rtalk
yfrafrarAdittlept.c. moffignintsthemanw,
l
oface. lpkntthti nin vintent imes" continuous
y
y
.00
from arm to nonnal value of a ripe plant. In effailm flatl
cereals life primary Ilrda tripittalas no WO group*, the
h '00
e Max.
contents at wbkb vradually loc"aw. and reach t
400
0.
* at the fall alaturity of the pLant.
at Wgittahk tisaw b a pm,em of &M-Umulativa of hico ,
404
so
- - 4 Cvjp9mWmttbatofHgnIu~ Theallwocco(MCOPWPO
iti
t M
h
0.0
j on a
asora
e suppos
the Cray IlZaw tc* t
nin 1% firmed from a
t Lat Ii
gLO t
tr
I
I
m
d
a
o
g
coW"71 corapArx. The olwefv%-tl pf-rumm of is Wgr
hydrocuttions with MrO Ittoop4. gr& flatly
of
o
at th, the lactralling contents W Mto groolls in
4
USulu shows conclusively thit these hylknefulfung lake
pan ~s Ill* UtWo lomiation, Bots",studies showed
that she 11julfiailon of ctilt and lissome is not the RnA
PIM of Unt vowth. Tile cells, And dwiv A" capallit:
of deflinniin tion, whereby ligultil with W4 Mto tinmlis
"
bvioud
t
mt
h
diff
l
d
l
alp0
Is'
o
if ax
eren
.
o
n
ete
y to a
y
itratfirs Colup
p
0 formentallve decompa, of licalm, and Its rielfflodurtion in
r
fW 11
drRWIXG orwn
l
1
l
t jWjk
fi
n
a
of
0
an
$
Sont
ef
fi p
K
1y
part 0
and struetture of lignial, which under ex"iffnal canditiorm
I
114il a
of 4r. g, by the action 44 mro" mineral
Ald,ILA all4L&WMCA& tntg&Tw bcdO ~Sm 11vt emptig-of orontatic character. V.1A.
boo
moo
Samse map aft 49-- _141ii
144i
WfMLU 8 AV 10,11
4
9s0 0* 0
0, OLo_~ 0 0 f 0
toOOOO
000*000*0060004
0 0 0 0
_
W
4
O
Aiv i, -
4 J 4. ~.Z.y 4; j #A '04 C~ 4 ao all itu on k%U *hit
t~ is 1; 0 is a "e
.
k
6
0 ,
do bw sm-tts! Ili U" woo e41 fir
04 1 ke I Prom 1943
w /1
n
cw
h
0 14
or
1
oma
elm
y:
wasmaw,
Is, "th"r trPowc Of Itil Cl
N
j
I
o.
r
,
wg 11up salon d Cl an is 1woveM as 11S, A whemlic 110VINIPS If Ovest
to licults chitwille for the Profs
fivin (11), beraw C4 the vsr*g CI ctlatt"t. 111tviuds, nmtb%Uftt chloiblat4w. lie I In ddorisaw Wuw I.
vAt Me, bomuse It vauslot bn orlid. with 140 OW 4011
late It cffvctivdy wA tcoams
ast
t
11
Z= T.
m
Ins
.
Ing PWI14.7 by Oct. adw-trits; islut 91114
"Fustseresloul because Of faulty ponredurm
rats
l
M
F~i -409
.
e.
y.
01pokalkin depes"N In pwt DFWM #1he quanifty J 13 used, m bt WSAW Out Complete
nin the Cl "MIsost of this 2 "
ll '
th
bture cmtmt d
f the Ii
a
z
h
f
a
M
l
r
I e
xe o
w raw
A
e mu
o
t
m Twe
t
a
"
g
she wmi. It mrsall sots. of wotxl arm used in a large lit am is loosely ootobisseti. wal tabift
I M19%. The 1.1 ~ I 1.00
so-'
00
osami. tho bc*t fpf twartion h raotly diss4mW a
thimlisatilm tw-awds at a sloo, rate. The d"kah ex maJ drykV
ad the regivessm The twhaviordtimClim 100 In- -
k 1110 vental" AV, vam C 46.-45,11 4.t3.4QI 22.54 Imad 0
tit; khk
i
~
1
4b 0
-
putem I. thal tfuwd by the MI w%Usj UUM I
.1rder" with Floe pewtrafkm a the waw
hy At n
.2%14swl
N) In.
---
CA anil 4% "1. 'A I posp,604 14-1 1; its
M4 00
.
W a yn'
104AII(S in 41111tiatlov: ratheT Axis sh-vorlstift d the C1, A- rits" we 6 a in omjpkg SIA w
11% 0(fivoism"t f4varsatlk few the chictiamitiod. Undef &.Awft=y&t0 eavinfusibler-Imp-%
IT
Awhyde $W
(SVtw0b1t r"Isditkw"' the t`-t" IK004*1111 1111"T OW
In wrtam I MOIL
d
.
i
rwb*wyl grmv. The trimoc"ie asisms 91 the
(too
00
it ig A a is It -V a v I of 14 1 1
t;~ ('P' It ~t 'i v .1 K t
-
-
0 oo* 0 0 0
-
0 - 0 0 0,0 0-0
0 0 - o
0 4 to 0 0
0 0
.0 * 0
of, if 0 0 Id a a v a v 0 to 4
iap
004 '.M lot
Pt"01111, AS* POVOINYll WVRA
pOy=W La plad Ofimbafmailt. -00
din VyielfawkAidjop. SWI.
71'"y K-ld!n
ego Ak". Nealk J.S.S.N.. OVA Rkim. Nakk i
09C
pfutmam. *ad liant" do not tam dkwtly from beif -
es- agesi lkild p"tam. but lbrwch Ot latermwiale funnAllim
It. M. 1A."Itir
of
*90
(see
See
JIF
too
ISO. to-O.
Alml
tv ft$O mv 0-i
'I
0
9-160,09 0 0 *a fa 0-0~0 0-0 0 0 6 if g f Q 0 00
160
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v! A ~ V
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Q of 0 66 of 0 a it 4 a 4:
--A
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Mw* A Ow
it
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l S S IJ
1911w
;
f two .
I
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#
ismollom
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jj* 40
Sollt" "to 449 414
vgting-if
Ov 441
be
00
u a ~v so
1 MIT a9 a 3 1 9
S *If 0 0 f_0 0 0 $ 0 0 0 0-0
00 0 0 0-0- f
10 0.0.0 9 * 0 06 6 0 0 0 0 0
*VO-0410-0-0-0-0-0 & 0 Of *'* 6-# 0 0 0 0 0 0-0 0 0 41 0 0 0 * 06 0 0 * 0 9 0
11 *woo 1411
-17
411oze
Vo
00 tuawass So Ili* CROSUW dW*dl*Mi Ist the fignill clintlal dirtoplittl front ill* tbw 01 41M twoofth 4,
*0
I WOW, .0.144INY-8 Poll". 21. No.
~w
I42WI9kf6V-_M - Jwt (of this %a% a
- 3/4 11, "P. 11ASIMIlowto
1. U. ,r,
dxW pot 124 fit Ili*
hut Mod 3 at the twA too
I -,
00 d I ,
slope 1.14pad
loorostwh 0 Ott. UNIX lof* pinpl, tier. Thorl
-
e filwat 44 A drOw Istio-it wall tow 11110 l4st 911
In fl
(
l ill# rAll
M. (41w0 that Was I A-2 titaft . bv"
delliloilvil 60 thrilkirm.14h4n I" Ili* V"11
1 1
I
got
wail
s
o
y
0 j
1"his brossit'lo WAS dA*IYMI
i
l
i
it
1 *
. T
Ordi-140.
1119111so
TAII hi
tl
It
k
a.
s " Wr
ptw
s.-1114
N%
Its vep.6"o. like's I.Pols It.
'A4 bov%ally. Thr it-ill capicut t1wItAKA
VrJJtJAlIV 44 -
w,,
u
g
- ecstitmt ist %he dorsal p.,, .,I
*As 113 .16 at IIW tuse "ad tip of the "Mum
t NNW
0
ogo 43
.16,41a Ill. mini P&JUaly 110C to thor tip of the 13- 15 In it
11" "to"" Contmi wwM book Ape .
11", t-fit l-,Poittos Ili the, ftntral mrsd dairmil
k *11111it the 4%6 load an either "in of IL MAI -ad I&S;% in jU
wratr
l
*-
Itiff, vb a. 111.404k-Ally the AWHW "CVPt fW the 69t *Mt
IIw A,b swilcut 9.341fam-d top tip Miele live luip began a
and MMMU Ppolu, r-P- Ill 41WO, w1wolo AW 4M,
Mon"Ant kvuA-# Ploorlson, 0all Stamm. ludiviriba
lot
4r #114 Ib;-n. r p, livolly AP*tjt Ohr dor,st 2 no, lips,
plh
WFl* WWI Ili# 14111111
1.41AI
f
J
j 44 livike. vorthalope. boatiTgubow. fig.. k this brawk =x
detll Ill the Uled
fUrICUMIS I
bkb
k
qlio
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r;a jjk
1
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A,jj j,"jlFjj#
jj
I
4,119 1110 Will 9 M- it "41 hs"?f 1" 11"' lt-wml .
f
t
7 petfuromisj.. Th,
(Moctlotts of the "Mout- n3"IPIMMt$ WVoaapsmqI $0.
jullaod throt it WWWRIMI lixtt"brol ls) she it-* ~J Is"I .
low
Is
too
I low tw lia Ai
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tale*
00
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or
toy
fetals coolift of
0
Pram., 21, -No. 7/K 4)(
ths wurk o1jaym and Gr6nud (C.A.
l
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h
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