SCIENTIFIC ABSTRACT ZHIDKOVA, Z.V. - ZHIGACH, A.F.
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CIA-RDP86-00513R002064730001-8
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S
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100
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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MBININ, KX, akademik otvatetvenW redaktor- OAPOR T8.1 --GAKN'-
Ai;!, G. K:;
ZHIPAXHIIU# WHINUIT, V.V.; BAMIKAYA, I.M. 'illW
ROGINSKIT, SOZ.; UNOVSKIY N A -, KISIM, A# V.; IMU, L-to.
# #L; YMP so 0
SLWAKOTA, I.B.; runw, I" L; U)SOV I.P.; TROSffANSKATA, Te.B.;
TZnnUp A*Soo, MAVANKOVp-A*Be; BALDA X.M.; BRUXBM, Te. M
z Ye#; NAPOLISKIY, S.A.; XIMUYLOYA, Ye.A.; X&WojLL I
VI OV
CHIKOV, D.I.; SEWAKIN, V.L.,BUNDILI. A.A SA N
B.G VJM V#P.; VSHTSYN, Ta.A.
[Research In, the. field OfLeh,romatography transactiont of theLA11-Uniou
Conference on.ChromatopTaphv, November 21-24. 19501 Iseledovanlia v oblasti
khromatografli; trudy Yeasciasnogo soveshchanila po khromatografil, 21-24
noiabria 1950.g, Xoskva, Izcl,-vo AksAemii neak SSSR, 1952. 225 10,
(KUL& 6 -.3
1. Akademiya nm* SSSR. Otdolenle khimicheakikh nauk.
(Chromatographic analveis)
-4 "n t -u 21; E M .4111 1 'ILI, A 4r I' Iii f'.1
USSR/Physics Spectra- arA-Ysls
Card 1/1 Pub. 431 51/62
I--- , ''
Authors
I OT", ~ i. e ',!I ,A.
Title t bete m4.nat i or, of 1~ e L r,,e a:isc r7-
by ttie s,:ectruni -ieir rii I. f,-s
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Submitted t .............
of zerwOM s4 ftr4"fm, ths MAI Wrvw
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Ari, -..r-ftfs
AUTHOR: Zhidkova., Z., ve 48-114/13
TITLE: On the Determination of the True Absorptior of Adsorbed Substances
According to the Spectra of Diffuse Reflection (Ob opredelenii istin-
nogo pogloshcheniya adsorbirovannykh veshchestv po spektram diffuza
nogo,otrazheniya).
PERIODICAL: Izvestiya AN SSSR Seriya Fizicheskayal, 1957, Vol. 21, Nr 11,
pp*: 15oo-1501 (USSR).
MSTRACT; This is the summary of a conference which is a continuation of a rem
port by the author in ZhETE., 27, 459 (1954). The investigations on
the determination of the true absorption K(,X) of the substance being
in dispersed state are continued to be developed according to the
method of diffuse reflection. The Investigation-is extended on that
sphere of adsorption-phenomena where adsorbed powders, the particles
of which show only a painting 9f the surface.. serve as objects, The
problem, becomes more complicated by the necessity of additionally
evaluating and taking account of the physicalchemical factors acting
on the absorption spectrum of the adsorbed substance. Powders of mole
ten and unmolten glass- and quartz particles with dyes adsorbed were
Card 1/2 investigated. The following statements were made on the strength of
-F
on the-Determination of the True Absorption of Adsorbed Substances 48-11-5/13
hocording to the Spectra of Diffuse Reflection.
the testa: 1) The spectrum of the diffuse reflections i, e. the
spectrum - log R(,#%) of the adsorbed materia characterizes with ream
Peet to quality the absorption D of the film of the adsorbed
substance; The positions of maxima and minima coincide with the speco
tra - log II (J%) and Dl",(A). When the D (A) -spectra show some man
ximaj:theirrel,ative size will be marked by the relative size of the
maxima -log R(,X). 2) The form of log R(,%) curve is some-what chano
ged in comparison to the D %) absorption curve of the film of the
adsorbed substance in'view of the special way of the light passing
through the dispersed media.. 3Y In contrast to powders containing
particles permeated with dye,,the change of the geometric grain size
of the adsorbent does not form an optic factor for the adsorbed man
teria,whioh causes a change of the -log R (,A) spectrilm. 4) When
the physicalchemical properties of the "adsorbed" surface vary any-
how. with the variation of the adsorbent dispersion, the -log R(X)
-spectra can widely differ.-The variation of the -log R(.k) spectrum
represents in these cases the actual change of state of the dye adm
sorbed in the powder with the change of the grain-size of the powder.
There are 2 Slavic references.
AVAILABLE., Library of Congress.
Card 2/2
! i iHi, .~ ~ ! lt;-
1! 11 ~, i ilt 111 It i "' H `111,
I r il i .. It ~~ ~ I hits H !, ~, R I
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SOV/51-7-3-20/21
LUMOR.: Zhidkova Z.V.
TITLH s On -who Effect of Thickneps of the Adsorbed Layer on the Diffuse
Reflection Spectrum Olt Adsorbates
PERIMCAL.-Optika I spaktroskopiya, 1959, Val 7, Nr 3, pp 426-4b1 (USSR)
ABS TELACT t Adsorbed layers of various thicknesses of the following dyes were
red:
prepa
phanosafranine,
di,3thyl-506-dimethyl-B-chlorthia-4'-Vinocarbocyanine iodide (dye Hr Its)
I
1,3-di thyl-thia-2-cyanine, iodide, (dye Nr 4),
506'-dichloro 31 -wtriethylcarbocyanine bromide (dye Ir 6).
'These dyes were supplied by E.L. Potrushkina. Dimensions ~of the dye
raoloculas were taken from published data (Rots 9, 10). The dyes were
adsorbed -an powders of,glass TF-5, prepared as described earlier (Rof 11),
and -on pmvdars of silver chloride.. The adsorbed layer thickness was
deduced from theadsorption Isotherms. The absorption spectrum of the
alcohol solutions of the dye Hr 3 is shovm in Fig 3. Fig 4 shows the,
adsorption Isotherm for.the dye Yr 3 on silver chloride; the abscissa
represents the equilibrium concentration of the dye in mals par litre (0.4)
and the ordinate represents the amount (m) of the dye in grams adsorbed
Ga
SOV/51-7-3-20/21
On~the Effect of Thickness.of the Adsorbea Layer on the Diffuse Reflection Spectrum
of Adsorbates
on,1 gram of silver chloride or TF-5 glass. The results of Figs 4 and 5
refer to adsorption from alcohol-water solutions Fig-.5 shows that
Cq/m is a linear function of Ceq In the case of the dye Nr 3 adsorbed
on.A&Gl.. The dif fused reflection spectrum of the dye Nr 3 adsorbed on
Asel is shown in.Fig 6 for, different thicknesses of. the adsorbed layer.
Similar results were obtained for the other dye#. The author ends with
the coaclusion thRt the diffuse reflection spectra of adsorbed dyes are
not greatly disturbed -when the adsorbed-layer thickness is varied and
consequently the diffuse reflection spectra can be used for qualitative
determination of the absorption spectra. Acknowledgnent is made to
Prof. U.V. Savostlyanava for heradvice. There are 6 figures and
~21 references, 14 of vh1ch are Soviet, 4 English, 1 French, 1 Japanese
and 1 translation into,Russian.
SUEMTTZD s Au gus t20, 1958
Card 2/2
-777:- 24 nmal I BOOK Sur.01TATION SW/01)"
go spaktrom"U. t. li
Molskalyarnays. spsktmak,~Vlya (P"rs at the 10th A12-Volon
Coftf, as an Spsatriagap7. Vol. Is Molecular Spectroscopy)
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Iditorial Roavds LwAsters G.S., Academician (
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Karaltakti, V.G., Candidate Of Toa;Wa
CaM4i4AtV or ftgl*4 SM PA%h~M&%IW ..
al Sattat4s, Rayakir, S.
SateA000, nimovskly, L
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Candidate of h4tical and W.MmAtica l Sciendqs. Mlirwich" .
"
Candldat* of "104 " PlAtURAUGAI 8016AGOO and Clamberma,
A. Ye. Candidate of "toll end MALM801441 i4lenote.
we= 1/30
Nut4ov A.A. Spectral Study or the Colloidal
iZiUstim at ?-contors, In Alkali Raids Crystals 146
P141kovekaya, O.V. XRfr*z*d Absorption Opeetrs of
Anthractne
vartanymm, A.T. Absorption ftostra at Sublimated Dy*
Layers 154
Fislankhol1n. V.X. Absorption 5944tra of ThIsaim-6yo
crystal* 157
hlbytkovs, X.N., MA D.S. AgrosklA. Study of the
Optical Properti*6 of gas* Dyes In Large S&WI*s
by the Ya of lurr3r Renesclon 159
dkova and Yu. X. Buss. Study of tht Iffeat
of DIsparsion AM Veto" of Us A4-
662taht on
the apes ral Absorption Caryt at Absort"
t
So"141"d Dyes
"Y4 U/30
~
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-mom
131
Rfftl
Oil
if,
ab~sorption of light br adsorbed substances determined
or Wfusion, reflection of.adsorbents. Trudy kow.
spectra
I~hi* QS-110-114 158., (KIRL 11:8)
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Z~IDKOYA .,Z~.V
Spectral study of ion-exchange sorption of dyes on resins,
Part 2, Zhure.fize khIms )9 no,&184-1827 Ag 165
imIPA 1819)
Eli I &m Ilt-11111411111"IF"I I j-'T
ME
1" [ I TI
jig
85449
A/0-60/60/0330011/011/014
AOO_VAOOI
A Luchko, R. G.
ATMORS -,Shtraykhman, -0, A., Al shits, I M. Zhidobi:na: I
Tl=t Vhlxotropld Systems on the Bas!~ of the Unselurat-of-I TIN I ml- I
Polyester Res P red Silica Gel
iln a3id owdi
PERIODICAL zhurnal.prikladnoykhimii, 1965) Vol. 33, No. 11, 'pp. 2r-86-2593
t
MAN ..The thIxotrbpio-,p'roperU8r Oe susparf4ans were Jzlrestigated consis
ith a
ing of- unsabirated polyester re a 1n L-id . s omj_~ - t c4' poodgred sill,3a, gal w
m 9 as asti s-with
view to usir* them in the manufaoture of a::+.icles ad. of gI s pl a
vert -al and Inclinea six aces. Iii the -axperimeatt th-3 P. -1 resin was usad which
Ac N
ACHA (VTU'33024-59 LSM), Sevaral type
is pro&an-ed atoordingto M 33024-59 s
of pcwderied.silica gel like ths~typ4s 7.~-CA)__ ~-333 (U-333) and various exp-9ri-,.
:rmt-~i, samples were 6tudied~ , ltv" fc~~rd thatt for. the impragnatlen of glass
Iiabrlo's-,on'.Vertioal itU-faawdnly,Qne third ot b:Lnding mat;~rlal is nviaded to
prev ent oompared %0:6ther glass plastics prtductls. The efft oieney of
pands -.on a degr.--Y4 ot V's dispersion, Wi+-h an :Lvicreasa~
the IjAxotropio ~ filler, de th__
in. dispersica the efficiency inoreasto rapidly J~j tre begiming, then - the Inorease
ber.%omes slower a-ad, after' reaching a CA.-C&L-1 it has no apprtodabl?,effeet
C
CO
Hilt
-SHTRAYEWNP-G-.Af-;-ALISHITSI--Iol~~,L
Thixotropic systems baied on the unsaturated polyester resin
FN-I and powdered silica gel, Zhur. prikl, khim. 33 no.11912586~-
V f4n IMTRA Will
0.
.1 11 VtC I ,
: , I i,
I p i 11 '. .,
': i I -I I ~,Ii 1! i I
illi~ ~111[11 I' Ill fi"l 1~ ii ,
. I : I , ~- 1;
; I I I
:~ if, .11 ~4
:Ii11,11 - I i I
ININIIIIII: id ] !~~ iII7 P"I III, I fl, 114 ` ii' 1: ~
I : - ! . I Ac
!.[In
i r I T!"., ! ! I;, ..
I ~ . . 1 1 ~ 9 a .
"I'll I i H 1! 1111-1 Irl, , _ , - ~
. - ',~; ~j
I. . J lo I I '..p
I . ~ v!
*5 -a -Itb-4 I tO 0 110 0 a /0-2 1
BI 02/B214
AUTHORS: Aleksandrovt L V,p Zhidomirov,.G. M.
f.spin-;lattice relaxation time for radical
TITLIE: calculation a
in molecular Ia
rystals
akeperimentallnoy i teoreticheakoy fiziki-, V-.!'41 Y
PERIODICAL: zhurn~i'
..,no., IMt 1961t 127-137
TEXT:, It~ia shown'.in thid pe. per that the aiiiaotropy of the g factok' (or"',
the anisotropy of tko-byp4rfine structure) -intthe radicals of"molocular
crystals may lead to a spin-lattice relaxation time of the ord or. of
ea.. The authors considered the spin-lattice relaxation of'a radical
in a magnetically dilute molecular crystal, and based their study on a
epin,Hamiltonian of, the form P9 S H + A S I , where g and A
ay a Y, ay a Y Y ay
are the tensors bf.spin-orbit and hyperfine interactions (A summation, is'
to be made over the Greek indices). H is the component of the external-
a
magnetic field in.the.direction S and I are thwprojections.of the
CL a
I.___Cqrd._ 1/7
J;4
Calculation of 3piri-lattice 13102/B2-14-
spin operators.of the electron and the nucleus on the-o: axis (the electron
eui); and P:is:
spin is assumed to interact with the spin of only one nucl
orbit and hyperfine interactions are assumed to
the Bohr magneton. Spin
be,axially.sypme.tricl i.e.# the tensor and A ' are diagonal in a.
i:ig CLY
certain coordinate systemlill,y1f,z", T dly'AtAch~d to the radical.'aThe
orientational waves in the molecular crystal are assumed to be one
dimensional.(Of. A.I. Ansellm, N.N. Porfirlyeva. ZhETF, ill 4389'-1949).,
it is assumed that in,the equilibrium position of the principal axis-
iJ
agation, V.1, 0
z" the teneors g and A coincide with the direction of prop f
the vibrational wave. The deviations from the equilibrium position ILI
assumed to be, small. The angle between H and denoted by
lies in the plane of X~ and: H (the zly' plane in Fig. 1)p one obtain -for
,'the spin Hamiltonian
X Hg. ((p) S. + A ((p) S, 1. +H9,, (qs, S. + A(y, x) S,. 1,, +
+ A.s ((px) SA..
WO
9, M -.9 5in'(P +9 s, (v) -~ A.L sin' ip + A 1 coO
Ag Xcw2,p+% sin 29). Ao,(tp.%)-AAI--~-Xsin2q)+X!cos2(p) (4
g, (,F.,X)
As$ 4, %) AA 1% cos 2(p + %!sin 2rpl, Ag M g 191. AA MA AL,
:Card-2
J, d
L
`h cu at op n- attice-i.-.
B
2 4
OW
0
If,the direction of polarization of the wave is'rotated by 90 lieB4 in
;
the-z'
x1planel Fil, 2), one has
g,, (tp) SS + A,. (T) S#18 PHg,- S, + PHg, Sy + A. S.1. +
+A,rS.Ij,+A,.SI, +Aj,.,SjI, +AjjSjIj +A,,.Ssl,.
T Ant sin 2(p,
A 90 Ag% cos ip, A,, AAX! slrOlp.
A,, A,, -AA X sin tp, Aj -L,&AX! 4n2tp,
"e Ap -,&A% cos 1p.
A"
In both forms, the terms Thich are not important for the investlgatjone*-.~
have been neglected. ForIcaiculation of the probability of a relaxiatio
transition between any two levels of the spin system, the spin'Hamiltonian
in the form
+ 2H
PHg(q)S + A(Y)S I + R
2-
Z Z Z
can be used for either case. Here R, (q)' and are linear, combination's
R2
of-the spin operators With non-vanishing matrix elements for.the tran i
tion'(fonsidered. If the term linear in ~ (transition with abaorptioh o;
one orientational phonon) is considered, one obtains for the probability
Card
317
_-8/056
/6-1 /u 1 /oo t/oo-VOZ-1
a ion of ipin-littice .. B102/B214
f one: rel
0
axation transition per unit time
2n
W12 (1 2) (a)L) 11>g (&),t)
whore" 0 (R Jq).ie the matrii. element between the spit states 1 and
1/2
'(n
he nt h and: (.n+ 1
nin~iM ~112JW) is the matrix element betvieen t
'(whose moment of inertia is'j)j-
:.states of the-rotational oscillator
g(oj)dw is the number of the operational normal vibrations in the fro
nterval 61 to. t4ft; the oyjnbol denotes thq averaging over 'k., h equantum
number n, Is the distance. botween the magnetic lovele, I and 2. *,"-In Ahi
-,linear'model LJ + q: cooll in the freqtoncy of rotational
2
oscillations of an individual molecule, when all.the remaining'moleou W4
Ure.in the equilibrium position,, 0-1611 6 n. One has
quit)
P~H YT7 i qi < < as VT+ qj
ir
g
(10)
0 nPH 0 < as Y-1 N UPH C0>103y1+1q1-,
Card 4/7
il :A Itw: f
2642J
-
056
s-31056/61 041/001/008/0
'/00'/00
Calculation of
spin-laitice, ... B102/B214'
altl7oni
Finally; an astimhte is given for a specific case (trans
12,
ftion 1~2
1/2 1/2, - 1/2). It is found that 1/T 0 W 1-4 5. 10 T /V 5J 'Wh'eie .~-4 6
1 12
2 0
-40gocm T 200 K, one has 1
_2A' If J 10()'10
v
2/ /T1
'd
Ue 0 1,8':j
The result
t hgt. T1can be easentiallyumallor than the val .80 ~ec 0-
according to'Ref. 7, a,rees with the result obtained in the laborato'!X4.0f...
V.~V. Voyevodakiy at the Institut khimicheekoy fiziki AN SSSH (Instliute 'of
Chemical Physics, AS UOSR). The authore thank Professor A.S.- Kompaneyets',
and,~rofessor X. D. Sokolov for discussions. There are 2:figures'an* 7
refeiences: 4 Soviet-bloc and 3 non-Soviet-blo'e. Thb three references to.
Enelish-language publications read as follows- Ref.-I: H. M. MqConolf,
J.Chem.Yhys. 21, 709, 1956; Ref. 3:,D.I*E. Ingram. Tree Radicals as
studied by Blectron,Spin Resonance, Londont 1958; Ref, 5: 1 H. 'van Vl a ollt,
Yhys.Rev. 51, 4269 1-940-
ASSOCIATION: Institut khimichodkoy fiziki Akademii nauk BRSR (Institute
of Che;nlqal Phy'sios cif the Acadepy.of Scianoes.USSR)
UBMITTED: December 19,-1960
Car4 6/7
,, flf:~ .: .
' it 7 - i 1. - P~ I
i . , - ,
'; -fl I "Nit "llf"ll 1111" U-1 I "I I i !I
;I 1 1 H !-~ , :1
I I
i I !d i
I': ; t PIR11.1,F I INIM M
4'i 19 !4iff
S/1-92/62/003/00.5/001/003
D267/ 308
AUTHORS: Zilidomirov, G.M. Lebedev, Ya.S. and Tsvethov, Yu.D.
TITLE: Vorm of line in the electronic paramagnetic resonance
spectra of.peroxide type radicals' in oriented poly-
mers
Zhurnal att6ukturnoy Ichim. ii, v. 3, no. 5, 1962, 541-
545
TEXT: It was shown in an earlier pki?er that the spectrum
of peroxide radicals (ROj) iyi oriented specimens depends on the
orientation of the specimen 'In the magnetic field, To calculate the
line form in the e.p.r. spectrum for oriented'specimene the authors
assumed that (1) the peroxide radical has an axial oymqctry of the
g-factor and (2) the symmetry ajces*of this factor are distributed
randomly in the plane S at.right angles 'to the orientation directioni
of
,polymer c been the end
hains. , The calculation has carried out to
for the-case of an infinitely narrow individual linet when the ex-
ternal magne tic field is,parallel to the orientation axis. It has
-Card
5/192/62/003/005/001/00'3
Form of line D207/D.308
been shovm that the forn of the e.p.r. line can be used for deter-
mining the degree of orientation of the chains (such estimation has
"Me
be,en carried out for a Teflon. specimen oriented by stretching).
paper ends with a discussion of the structure of perdxide type radi
cals (on the strength of the data shox-Ang the temperature dependence.
of the form of e.n.r. lines). Thqrc are 3 figures.
ASSOCIATION: Institut khimicheskoy kinetiki i goreniya So AN
Novosibirsk SSSR (Institute of Chemical Kinetics
and Combustion, 'Siberian -Brandh of the AS Novosibirskt
USSR); Institut khimicheskoy fiziki All 5SSR Unsti-
tute of Chemical Physics, -AS USSR)
SMINITTED: June 17, 196.1
Card 2/2
NO
1i I !~ 111 111111114.1'. 1, 111 ii I ,I
jjl~
Ir
b535h
3/181/63/005/002/043/051
B102/B186
'7
AUTHORSt Kazanakiy, V. B.9 Fdriyakiy, G. B., Aleksandrov, I. V., and
TITLE# Investigation of the interaction of free radicals with the
surface of a solid (silica gel) by the apn epee tra
PERIODICALs Fizika tverdogo telat v- 5p no. 21 19631 649 659
TEM The authors give a detailed analysis of the e.p.r. spectra f atomi''
hydrogen, methyl# ethyl end polymer radicals adsorted on several types of
silica gels (specific surfaces 290# 300, and 700 M~flg). The studies were,
made in order to obtain information on the nature and the geometry of
binding and the motions in the deorbed states The eopor., spectra were
T
taken at ;1--3.2 am and a hf modulation frequeicy of I gas The W sped'
trum of adsorbed hydrogen is tharacterized by a hyperfine splitting constant
of A 1411�0-1 Me (for free hydrogen it is A 1420-40 Mc),and a great.-
0
asymmetry of the components* On the basis of the present authors 6arlier
results (Kinetika i kataliz I, no. 4# 539t 1960) the hyperfine splitting
Card 1/3
B/181/63/005/002/943/051
Investigation of the B102/B166
constants Aj. and A for L E4 and H4 11 E) are oniculatedi
47
A.,=A,,=A' -A-W
(4a)
47
A,
a3
30
(4b)
A ML (1'~- 15.5Xj Ao (I - 15.5xj
3 0 (4c
2
a E/e. The anisotropy of hyperfine splitting is obtained as
47 141
A Aj.== A V
20 a3 --.160 0
(5)) z. 11E and'perpendioular to 'the auggace. The"
tianisotropy of the g-fact.o.r, !dg -, g11 g.L # i a very weak (,,.10- ) and. not.
to be observed inexperiment. The polarization energy of the hydrogen
atom in the E field waa,obtained as -.I kcal/mole. The, apar. spectrum of
deuterium.atoms.adsorbed on SiO is consiaerably narrower snd.is.symmetr*i-'-
2
cal, with smaller amplitudes of the aide coSponentat The eperi, 1spectrum
0 )iyper&,,'
of the methyl radicals was measured at -196 C1 it consists f toux
fine structural lines with n distance of 23.1+0.1 oe and with an amplitudel~*'
ratio of 1 t 8.5 1 13 1 2.5. instead of I t'~_t 3 & 1. This can be ex-.~*~
Card ?/3
- - - - - - - - - -
8/iSi/63/005/002/043/05-11,
Investigation of the ... B102/,Bi66
plained by the loss of rotational,degrees of freedom Of.CH3'on adioiptiono
The e*ptro,spectrum of the ethyl radical consists of 12 lines and Oda be
considered as quadrupl6t arising on hyperfine interaction of the uipaired 01 1*
electron with the protons ofthe CH, group, each quadruplet line being ~"'~,'T
split into a triplet due to interaction with the CH protonso The e.p.r.
2
spectrum of the polymer radical consists of six broad poorly reeolvedoom".'': -
ponents ( -25 oe distance). The results show that the e.p.r. spectra of ad,*
aorbed radicals differ considerably from those of free radict~;Is'or of
Cale stabil!zed in solid polycrystalline matrices. Thesurface effect be..'a"'.
comes apparent in a reduction of the hyperfine eplitting'constant (for-.hydw~'
gen in a deformation of its electron shell).and in a change of the character
of motion due to losses of degrees of freedom or of equilibrium positionp
of the radicals in the matrices. There are 9 figures and 1,table,
ASSOCIATIONt Inatitut khimicheskoy fiziki AN SSSRt Moskva (I-astituts-'Of
Chemical Physics AS USSR, Moecow)
SUBMITTED% Soptember 27, 1962
Cdrd 3/3
7. --
Determination of the Integrals of dipole-dipalm hypWine fno-~
Aeraction of electron with nuc:ei# Zhure strukto kbim., 6 no@
'65
655456 Jl-Ag
L Tns4 Uut khimicheakoy kinatiki I gormiya Sibirskogo o d e1 efti
t
AN USSR, go Novosibirsk, Submitted May 27, 1965.
C
N
ZHID(14IRCJV, G.M.; SCHASTNEV, P*V.
Hyperfine ~nteractian of unpaired oleotrons with methyl group
nuclei inTpelectron radicals, Tooret. I eksper. khim. 1 no. 5t
61,9-654 S-0 165 (MIRA 19tl)
1. Thatitut kbimicheskoy kinetiki i goreniya "ibirskogo ot-
deleniya AN SSSR, Novosibirsk. &ibmitted June 23, 1965.
if
YuD-ovlcff-,Vd--;-x-!aBORODOV, A.D.; SOLMEVICH, Ye.A.,,, IFEEYTS, V,L.-,
PANOVI.F.S.; EELYAYEV, A.U.; ALADIIN, 0.1.; CSIF-OV, Y.F.;
VOROBIYEV, A*Io; PROKOFIYEV, Yu.Vs; SOW11YEV, Yu.A,;
KtIZIMINj A.V.; ZtjlDQNl0 V.'(U,') ZOLIN~ A.VI,,YAT'I!v Ye.P.
Yo.N.; DRYA
KCROLEV, V.F.; KERMOV, N,B.,, KRAVCHEINKO, A.8,; RYVLllf, V.A,-,-
GURCHENKG, A.P.; KRUGLIKOV, T.P.; CHEWIYAKOV, F,A.; Aillill~UvI..
N.K.
Authors' certificates Rnd ptonts. Mashinostrmnio nD.I!,101-
103 Ja-F 165. (1-111RA 18-4)
H 1101
M I Ii
Hill '1 1`11
OunwTrirlv, r,v,j a11UVMnVV,,,U.fq,
Isotropic hyperfine splitting on a fluorine nucleus in sle&,brda-
paramagnetic resonance spectra of free radicals, Zhur. strukt, xhim,
5 no.6:839-8/+4 N-D 164. (MIRA 1814)
1. Institut khimicheskoy kinetiki. i goreniya Sibirskogo otdoloniya
AN SSSR, Novosibirsk. J,
t~w I
H; HIM ?"I "Mill 111111'" "11
III I'm 11311,111 1 1!3 RI
j; f. ~IV;
ZHIDOMRO G M.; T
....................
Use of the electron paramagnetic revonance mn thod in studying
conformations of free radicals in somealicyclic compounds;gopt.
I spektr. 17 nb,D67-72 J1 'tV*. Ofd f(A 1,1
34M,
Lu
SCHASTNEVO F.Y..; ZHIMROV, G*M*
Samiempirical theory of isotopic superfine splitting in the
electron parawgnetic resonance spectra of free radicals,
DAL AN SSSR 153 no.ltl5l-153 N 163. (KRA ~17:1)
1, Inatitut khimichookoy kinetiki i gorenlya Sibirskogo
otdoleniya AN SSSR. Predetavleno akademikom V,N. Kondmtlyevym,
9 V -A
I. . I`.'~v'"I
J iyl 1;:.
49
511 4 111 M I M. q- IF! t I I f 9 11, 111 ", I I E-..
Fill 11~.' 11 ill
-i A.
L
4 f It Ji".
37054
5/032/62/028/005/008/009
B11-1/B101
AUTIIIORSt~ Vaaauskas, S. S., and Zhidonis, V. Yu.
TITLEt The hardness diagram and its application in determining the
strength characteristics of metals
PERIODICALs Zavodskaya laboratoriyap v. 28p no- 5t 1962, 605-6oa
TEXTt A m'ethod of testing,metal samples for their elastic limit# yield and
broaking points by using only Brinell's hardness test) no tensile tests
being required, is recommended. It is shown that the change in the hardness
numbert depending on the degree of plastic deformation, can be observed by
using conical indenting toolso(made of alloys with HRA up to-80) with
different point angles (0.A8 The deformationj which was found to
0
depend on the point angle of the cone, can be calculated and Is proportional
to the specific transverse contraction of the sample in tensile tests. A
diagram based on the ratio between the hardness number and the point angle
of the indenting *one shows that the critical value of hardness and strength
can be determined with one lidenting coj~e O'nlyr yield point of steels with
Card 1/2
S10321621020100)-10081009
The hardness diagram and its B117/BIOI
0
a cone whose point angle is 160 1 breaking point of steels and
commercial nonferrous metals with a cone of 1200# oto. Yield and
breaking points under elongation were determined. from the respective
hardness numbers, and the following relations were foundt 6 5 m 0.25 Us
and 6,B - G-30 N. (H S is the hardnese.number in the indentation of a cone
of 0 - 16oo, and RB the one for 1200). H and correspond to the
3 "B
critical values of the hardness numbers on the hardness diagram and -can be
found with in indenting tool of any shape. There are 5 figures.
ASSOCIATIONs Kaunasskiy politekhnicheskiy institut ~Kaunas PolytecbnI o
Institute)
Card 212
IN
KHODAS) M.Ya. (Moskva,# Krasnopresnenskaya nab.d.1/2,kv.163);
-ZHIDOVETSKAYA A.S.
PYATHITSKAYA) ..G.,Kh.;
NeutIralization of heparin by protamine sulfate during artificial
blood circulation. -KUn.khir. no.7t59-62 Jl 162. (MIRA 15:9)
i.-Laboratoriya iskusetvennogo krovoobrashcheniya (nauchnyy
rukovoditell,- deystviteltnyy chlen ANN SSSR prof. B,V.Petrovskiyj
zav. - koktor med.nauk G.M.Soloviyev) Nauchno-issledovatellskogo
instituta, eksperimentallnoy khirurgicheskoy apparatury i Instrumen-
tariya na baze gospitalln khirargicheskoy kl4niki.
(HEPARIN) (PROTANINES) OTBLOOD-GIRCULATION, ARTIFICIAL)
GALANOVI I.G., otvo rIed.j MATLAXHOV, S*Gop otv, red,; POLESIV,
Ta.L., red.; BOGOHOU)V, A.I.,, red.; ZHEUZNYAKOVA, M.A.p
red. ZZBHIWDUOVVJESTSKIY B V-red.; ZILIBERSHTErN, LA.,,
YOOP*.* red.; KOZWVA)
Te.l. red.; MAKAROVj A.D., red.; SAMARTSEV) A.I.j red.1
SOMPKOs A.P.' red.; TIKHONOV, V.A.$ redej VOIAOVA, V.A.s
.9
ved. red.
[Safety regulations in the gas industry; regulations
obligatory for all ministriesp departmentsp aW organi7A-
tions] Pravila bezopasnosti v gazovom khoziaistvej pravila
obiazatelIny dlia veekh ministerstvp vedomstv i organizateii.
Perer. i dop. izd. Moskva, Nedram 1965. 143 p.
(MIRA 18t3)
L Russia (1917- R.S.F.S.R.) Gosudarstvannyy komitet po nad-
zoru za bezopasnym vedeniem rabot v promyshlemosti i gorno-
. ~ '! ( 7 2,j t
! , . I
. Js t
(Bilk manufacture)
P".
I - a. . . ~ ',7! . 1 ,
': -, ; 3 v , R V .
;, . ; 9 ~' i , ;
I ! "11 ii i i ~ I - ~, ~` ! I i , I; ~ I I ! I ~ : I I I ~ I i, I i i 0 1; 1. , . I . I
1. -II :* 7, .! ~ 1, , I
, 11 1 r, I - 1 11 *; I ~ 1 1*1- 1 ,
JR 1 11 i t~ -,t!
i ~
i, �.
3 .1,
i 11.1 kii-IN U' "lillill Fliil rl~l If i 116 111, V11-11.1 I i!,
.! fl-~ 1 -'i I ~~ , t. , , 41,17: ~
:, "! -- I ~.
- r
. , V., ! i
fl: 1 11 li Ill 11 "--1- 1;
1 , . , i ~ I ~e~ -., i f ~1, .--
,.i -
;~! W 4,.;" w I : , ~' , ;~ i' , ; : ~
1,1 , i -Iffid I 3p, p 1 ~;~ - i it, I
1 - 1 1 r? - : :~ .
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Fla
i
7- -F, -
1", , W", I ~VT- ~~~
,7'i
If HIP
it
flit,
Till 7 -"1% I'M i I-"
Determination ofthe pover consmed by a roller bit, Ikuch.
zap, UkIrniiprookta no.3:37-41 160. (NIRA 14:12)
(boring)
ZH1DOVTS3Vj,~.N.A.;.OS1NCHUx, zfP*
zffeat of h~dros+Atic praeowe on dril-ling indicee of the Dolina
area, Wt.' i gaz. *,om, Ap-Je 162. WRA 15:6)
Gosudarstvennyy nauchno-isoledovatellskiy i proyektnyy
~~institut ugollnoy,, rudno3r, neftpnoy i gazovoy promyshlennosti.
(Dolina region (Stanislav Province)-4il well drilling)
inzh.1 YAREMIYCMM, R.S.,
inzhol TISHCHENKO, A.V., inzh.1 KRITSUK, A.A.p inah.
Gollapse of protective strings on the Zaluzh area, Nauch. sap.
Ukrniiproekta no.9t33-/,o 162. (KRA 160)
(Car,pathian.Miauntain region-Boring machinalry)
i V
KOLICHENKOP A.V.), kand.takhn.nauk; ZHIDOVTSEV,, NA., kand.tekhn.nauk
Results of' industrial testing and introduction of turbodrill
axial supporting elements with replaceable rubber parts. Nauch.
sap. Ukrniiproekta no.993-14 162. (MIRA 16:7)
(Turbodrills)
W-1
'k j~g7g,
-ri
I K'
PEI'; WMIT HE
,ly
-- h 1 11111 HIMI
iWE 9
P -,
j-,, I . ~ I 1~ I,-,, , E~; ; : I
!,~ l.., tnoj
f U~ -, I - ; I - p! , '~ ~
I - 1: i ~- I i -
: I !! - I i[l ~: - F~r :~ ~ 1" W" I U~H;, !. 7 .
lei .91'bl~-l.1,1~irilrl~-~4,~~~,-~;~lw~fl--I I 11PHIHIillill MIll!'I -ii.-?
11 ~i.. i ! 1! 1
T~r
WIN 11111f9 I'll, 11'"ll I`-
:_ !i ` V H 1; .7. ;
. :,. i 1.1 1 1 If. If.', I ~ -1 ~ I , -* - i~ lk
; . E 9 - 2 - -E
: , '. ", 1! ii I I "I", lfflf~ i I i , v . : I - . .
I I I - - - - i
, . !! 1, . J. ; I '. , , , j
N, Tr w I .. i *
ZHIDOVTSEV, II.A., kand. tekhn. nauk; KOLIGMIKO, AS., kand. tekhn, rauk
Wearing crut diamond bits in rotary drilLng. Neft. i gaz. prom*
no.2.-23-28 AP-Je 163. (HIRA 17. 11)
I, Gosudarstvennyy nauchno-issledovatellskiy i proyekt,nyy institut
ZHIDOVTSEV., U.A,; SIICIIUXIN# 14,V,
Comparison between theefficiency of deep turbodrilling and
deep rotary drilling in.the northwestern part of the Dnieper-
Donets Lowland. Neft. i Raz. vrom. 3124-27 J-1-6 165.
t
F1711,1 I --iili] 1 tri
~, - 1 A' i I 1-I '- .. .- i
-q -,! ; 11 ; ! . E
I I I i_ i !- i ~ ! : ! , ,.: . ..
T''HU"'Nik I
I ~; ~ 1 1 .; I- 1[ Ll, ~ E. -
'I I I I t ~ ji . !
..
I!: , - 1! .11 it A i
ZIIIDOVTSZVA, 14. 1.;. Haster Med Sci (dios~ -- ',!Evaluation of the functional
state of the liver and pancreas in various stages of hypertension". KharIkov,
1958. 14 pp (Khar'kov State Hed Inst), 200 copies (KL, No 6, 1959, 143)
IRRUKUHIM"
IL
URI
IN
IND
G*WH*~D__ti_itriy Leonidovlch~_- kind. tekbn -0 x1juk; KORYAVTSV., Fedor Alskor-n-
drovioh,'inzb.j MMMW.,, Alekoandr rantelaymonovich, inzh#l GERSETMl
Yu.S_j inzh., reteenzent;.ROXHLIN, A.G.p kand, takhn. nauk,, retsen-
zant;.ZH=A=',"O.A,, naucbWy red.; OZEROVA, Z.V., rod.; IWAKOVA,
(Modern methods -of assembling marine sbafti4l gowerconrVe mato4y
zontazha euAovykh valoprovodovltzd#2.p ispr. i dop. Leningradp
Goo. soiuznoe izd-vo oudostroit. prouWahl., 1961. 280 P.
(Shafting) (Shipo-Equipment and supplies)
3/003
B I 6b/'3 'it,
AUTHORS i Kalabina, A. V., Filippova, A. Kh., ikaenenko, R. L.,
La tys..eym , r- S - , 7 1 ncc ra-- ~ - vi , v - v . . Zh 10 ~aj evis , L.
T IT U 5tudies in the field of synthesis and ccrivers,,orui of P,,. . a ry
eat ero . 1110 . 22. S y r, t.~ e aa r. d -,, e r trr-( ~ir` ; ns
eaters and acetals of bromoph,~-ncls
PERIOD.~CAI,i Ref arat ivnyy zhurnal - Khimiya, no. 4, 11;6~, 256 - 25,j, at-
atract 4ZhI23 (Izv. Piz.-khim. n--i. 111-to pri Irkutij.Koz
V- 5, no. 1, 1961, 120 - 1)0)
TEXTs Vinylation of 2-bromophenol (I) and 4-bromophenril (11) by the Favor-
ski.( - Shostakovskly method (initial presgure of ncetyicne 'H 28 ata
210 - 2200C, 50 - 45 min) in the presence of 9 larep jj~Lntily Kl,ii :- - ~'4 a if'.
and with high dilution of 'the reaction mix~jr,~ wi'h *-i-r i. o;a z #-e r,
dioxanp added) made onsible the synthesis of the vinj. Of
40%, b-P- 93 - 940CA am Hg, n20D 1.5676, d 4" 1.45"9, t r
of Il.~III), yield 12 - '2*, b.p. 215 - 216OC/72B mm HR.
Hg, n D 1-5685, d 420 1.4366. The addition of I - 13 t-) ~;)n-q c ar,o
Card 1/3
9/043 1 14 k/00( 1004
Studies in the field of syntheste... 131603186
aromatic vinyl asters (with thorough R t I r r I n4g In the ji-aerwe of I irc,_,a
concentrated HCl) 6ave a ser-les ckf ('11 CH (Oil )GR IV). i.
ers givent the initial vinyl ether, quantity in molas , the initia,
quantity in moles, reaotion temp. in cC and the renoticn tiae ir, qrs, H an-11
RI Jn IV, yield %, b.p. in 00/= E[g, n20 D and d 4 20 1 vAnyletnyl. ether (V),
0.430, 1, 0-500, 65 - 90, 1.5, C211 5' O-BrC 69 41 4 0, 1 ~'i I -, , I . !~ -;' 5 , * . 5 4' 1 -'; 8 ;
V, 0.120, 11, 0.058, 70 - 75, 1.5. C211 5 0 n-Brr. 611 4 (Iva 124 - 125/8, .1,5o,9,
1-54831 vinylbutyl ether, 0.679, 11, 0.579, 75 - 86, 1, 4 a,, n-3r,'. 6H 4 ~ V b
38, 155 - 156/17, 1.5051, 1.23641 vinylphenyl ether, 0.167, 11, 0.167. 70 -
60, 2, C H n-BrC H 47. 1 , 171 - 173/6, 1 . 585 1 , I . 57titj ; I C . 1 1 1 T
6 5' 6 4'
0.104, 70 - 80, 2, n-BrC 6H 4 (Iva). 55, 216 - 2'17,1,3. 46': .661~
A study was made of substitution or th~ Br a-ai In 1-1 :7 .~ tr. :1.
ethoxyl groups. Experiments to hydrolyze lil and 'V rl '11 1 Bail qlicq t '~'
the respective vinyl esters of the phenols . ii, an a,il.~), ~a Y13, .: C- ~ - ' -,~' ':, n
the preaenoe of Ou 2 Cl 2 and Ou shavings) were unsucconfil-al To -1 5 moo i en
Iva in 20 ml oryosoopio C 6H 6 were added 0.08 moles C 211 5Br and 0.15 mo.eEi N.~ ,
Card 213
?
A
S /C)o '0-0--l ce, 1) 1
Studi,as in the field of syntheeis B " 6 6. 4S
whiCh watt thoroughly stirred for 2 hre at 6C - 69"' to thor t a, 1-..!
f or :1? hre, whereupon It was fil to? r ~-d th r-) uo~h g- ;t qj, v
2H , Rl- n-C 2 H 5 c 6 H 4 Pq a I (i S~M
Hg, n 20 D 1.5006, d ~ 0 0.9051. 5 g IV d a r. d 2 0 a, ;'04, )1 S e h "% P C. f
4 4
5 hr at , 1000C to give 4-ethylphenol IV:), y ,e L (1 98 D . ~ - ~ - 4 c . - ,,
0 1 . MM
H,g , 120T) 1.5240. In the optinum experiment C )')4 moleg :71). mc Ps
C HBrjand 0.15 males Na in 200 ml C H6 wore heatcd f -,r I It qrl,j
2 5 6
as stated above, IV were separated (R c HQ# R' "'R j 1- 1 d
140 - 1420C/17 mm 11g, n 20 -. i.496o, d 4~c C .9271,. 'Jn i & r -m j r.-d i -i-
k 85 - 9 0 ((; , 2 - 5 h re ) t h e v t wj I ea t (- r a f 71 -man pr,3ej.-A c P c v r:
?2 - 9 5 ' Z 0 = Rg , n 2 0 D 1 4 0 . A it
dry ~ 2 H5 ONa, 10 al C 6 R 6 and 50 it Cu ft iin6a vau xep-, A', r
was the n washed w ith IOA -ilka 11 and 4- et h o xy phe no I ~i i nj ca t er wrhq 3 IP4 -q '~A
4 0%, h - P - 10 1 - cr:, an lig , i
by distillation, yield
abstract 4Zh122. Abs t racter 'n n(A 1 t 7
Card 3/3
I N
C119MAK11Illp GA., prof.$ _VIDYAYEVA,. T.I.1 TSMALINAt T.A.; VOSMSMSKAYA.,
L. Ye. j- PIGOIMN
Prevention of ophthalmoblennorrhea in newborn infants by means of
a oynthmycin, emilsion, Sbor. naucb. rab. Kaf. akush. i gin. C2,11
no.ltll5.-ll9 160. (MIRA 15*-4.)
1. Is akashersko-ginakologichookoy kliniki Gorlkovskogo moditainskogo
instituta, zav.klinikoy - prof. G.K.Gherepakhin.
HUD, Dallas.* T.; BOLIN, L.Ye. [translator]; :~1LIGACH,_ profoosor,
doktor khimloheski* nanki redaktor; 0G11DZMMUT1-,-3.A., redaktor;
10VISTA, N.A., tokhnichemkiv redaktor
CAA introduction to ths chemistry of hydrideso Translated from the
Xnglish] Vvedenie v khtmiiu gidridoy. Perevod a angliiskogo L.X.
Berlinai Pod reds A.Y.Zhigachas Moskva, Izd-vo inostmanoi lit~-ry
1955i 238 pe (MLPA 19:81
(Hydrides)
~1r it
~KHIG~APH, A.Y., doktor khlmichesklkh nauk, professor; ANT(MOV, I.S., kandidat
'TAMchaskildi nnuk.
Use of hybrides In Industry, Khim.promeno#4:200-202 Ja 156. (MLRA 9110)
(Hydrides)
ra
A _F
V
6C11 /0
USSR/Inorganic Chemistry. Complex Compounds. C
Abs Jour : Ref Shur Xhimiyal No. 8) 19579 26449,
Author : Zhigach, A.F., Kochneva, L.N.
Inst :
Title i ~Nitrogen Pontaining Derivatives of Diborane.
Orig Pub Uspekhl khimli, 1956, 25, No. 101
1267 1281.
.Abstract Review. Bibliography with 61+ titles.
Card 1/1
USER/ Chemistry lle,ctlor f)rocenaea
rArd 12
Authors 9A K
ritle
Periodical Dok. AN
Abstraot
i- t--, in A :4 -jr, ey-i r I w I
-d"I I
At 1143 hPI I i1'1jl;fV3"_NI I i!! ilrf, i kf: P, VMR E*INAIW5tl_ITV_ U41TIFIFf I lam! it 141, 1 1 1! Ili _19 Vlil~iu 9,0 1ilL.
Periodical D* . AN r)6
Abstract
=777
71
IT %I
-gg"~'gmg
0
La
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4
I%.NL ~._
- N 111111
IN I lj~
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OR g, fA