SCIENTIFIC ABSTRACT ZHMUR, V.A. - ZHMUROVA, I.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002064830011-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 20, 2001
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

jI.
lei U
R;T

VIM ~l
i; full 1- 1
ME MWA H

. - :" [ - i. - .-I
; - ji I i I i i
9 * ~ I : : ,, i
- , ; 11 v I! -.11i I I !, ~ ,I ~ i i , -i IN 1 :4 111 ! ` I ! ~11
. i v , .: . I R I I i. , I ~ ~t

. i -11. ! :
: i I' ~ ;A I i,'O i". ii: I I. ~: 11. ;lf ~; "1 -1 , * .
", . ! 1 1
:. . : ii A - i
f *i ': : i, : ! 't 7,
?v i Ii . I I ;U

. . .,-: ~t*Jl!dlL.0:H.:- i , A I I
I !,:1 1 , ~,! ,,, h
: .~ : &, ~61 , i ; I ':
: ~! :I I i fl I I .

- : , -- '. i -i!l I ~ !it I ~. 1 1 ~'. -1, ..7:! .
. ~ . t~ : ~ 1 , !. : ~1.
. I -.I i.I!I ! I : : . I ; . - 4; .: i 7:
.. ~ , I P " I : , r
11i !; i i, R I I i . ;~ . -
.f, ~ I !; ! ! 1; , I T i

TT

P- , 1 1 R S -'I ~ I!! III i 1, i 1 ; I II,: ,~; I ;j :1 1 ) 119 i1 A -, ! , i F T , 7 ,

. I I " * I , I V :
.: - , N! I ii 411 I'll I I - i i I !:I i ; I f F11 I I ~ I ~
L i ~ I A - : . , .1 - - I r

I . t : i it i, , ~-~ I
t 1$ t , ~ i~
: ': il ... il-! I - i ~ -1 07-1 : ,I '! .; ,
i ~ - ~, i ~ i "'I V,
.- I % 1t ~:
.1 ;
ti
, . : 1 ~ ill. "ll I ! 11 ! 1,1 i H 7 ~1 ... ~: i -
R 'i i w I T: I ii:,lIrii 4 .1 1 , . ! i..

j ,

1: i~!, r , " . 1j, , I
:, " I - - - F. :I: 'I
.1 t .. I . I ~ ~ A 1 [;;, I Ill ; 1
f,~'f : I ~ I k,,: i i - I -- I
. : : j
.i ; I ~ ~ I 'i ~ 4 ~' . 1, .. .
11, 1 , ~ i: 1 - I , . . :, ( 1 1 th I , 1 7 T

W
1. 11 ~11. It! 1 w ~Jjr !f f I ~, I i - 1- i ;~ . , ~
: , , ~~Iw , i(
. . i~ t . . - 1' 11
4; F~ IM :~ "I i it " . -
1 - i, I m 1; ~ I ; f . I - a ~"!: i :
lp, i-; i I

USSR/Fnarn ixinn 16 Iforiaes
'J)s Jour:, Ref Zhur-Diol., No 20) 1953) 92551-
uor
i
ut.
Inut ;~J.Unic;hcientiflc 11cricarch Listituto for 11c:roc
RaisinG.
Title Data an the Luiciv.-;tior- of the Ovary, Folliclcs and
Corpua Lutaun in Horsca
Ori[; Pub: 13yul muchno-teMni. infrrn. Wes. n.-i. .4n-t konevodstva,
1957, No 33 14-16.
reparations using the ir.;
,bstnact: It was shown in 25 1) pre3riation
0~ j3il3jj0rsjci
method i-Gros as ncaified by, Kovpas that
a well developed nenrc apparatus existo iz., the ovary
which includer, bumUes -of mLlullatcd and non-nedulla-
ted nerve-fibero caid nerve c.,ncUiw_s. The area of the
ovulatory foolsa of ovaries isirnarved most inten-
Card 1/2
35
F1 _11111 _~'r 7, 1 T7,

-I! A
IF Ro

;-' ~-~ ~ L ~ F ~ ~01 I I , !j! 1 1: 1.
I I ~, 4 ~ f-:~ -
.';! 111 1 : 1,i'- , ~ r.
, , , . . . 1 -
1 ~ I I .: I ~ 1, ,
.p r i I I ; ifli j j ill *,,~` 1"111"I f 4
1 1 ; , ~ : . . : ~ - . " ..

& !, !1 1.
L ",
j- . 4 , V m i i
i ; i q ~ ; i t .4 L : - .
. I~! ~ - V. .1. , ,
.1 1 . f.-. it 1. 1 1 ;~ '111ii. 1 ~ 'i'i , C , k 1 4. . .
u 1", 11,11 . 1 4 H

-----------
~ar aso r S Wardized PD-L-in,ing. o
vDeta bri, the Zoohyg ic Ra ns r0 -,tar f FarraAng, Falis.

-ACC-NRt-AP601971-3 SOURCE-MDE-:--UR/0.128/061000/006/,0003/OOP~-.---I
AUTHOR: Korolev, V. M. (Candidate of technical sciences); Kolobashkin, B. M. (Candi-
date of technical sciences); Zhmurina, Yu.-,A. (Engineer); Maslov, A. D. (Engineer);
Malini~a, A. D. (Technician); Kuyanova, M.,M. (TechnicianY.
ORG., aone
TITLE: High-strength stainless steel VNL-l
SOURCE: Liteynoye proizvodstvo, no, 6, 1966, 3-5
r
TOPIC TAGS:, stainless steel, high stren th steel, austqnitic martensite steelp
precipitation hardenable atee l/ M-1 4-
ABSTRAM, A new. aust ,enitic-maitensitic cast stainless steel,designated VNL-1 has.
been developed. The steel contains 0.08% max C, 0.9% max Ma, 0.75% max Si, 14.07-
14.60% Cr, 6.45-7.50X Ni, 0.68-0083% Mo, 0.016- Y1.01M S, and 0.028-0.30% P. At
room temperature the steel has a tensIile strength %f 111-123 kg/mm7,.a yield strengtt
of 84-93 kj/mm2, an elongation of IL8-19.0%, a reduction.of area of 37-45%,,and a
notch toughness of 5-8 mkg/cm~. - The corresponding figures for -196C are 161-180
kg/mm2, 107-147 kg/mm?, 9-16%9 14-21% and 4-7Z. At 500C the steel has a tensile
strength of 65-80 kg/mm2, an elongation of 8-10Z, and a reduction of area of
20-40%. In cyclic tests under a stress of 77.5-88 kg/mm~, the steel withstood
Card- 1/2 UDC: 621,74:669,15-194.55
4

I
.I
I -
t
1~
4
I
- I
.i I
I I'll
a. Wfi
111.1. ff, . I
t "I . - .

- r
- q F ~ ]iHd I I I t 4 U . i - - I i 11, k t ~ , I I'. _-
i , i ! 'I :
.1 -.~n , I- . . , - I . , .
4 j., I :I !I !!,~i !!I 'I ~I I 1 !1* ,
. 1,
11 , : !:i,fl.- -ji I I : , - ~; i .
;~z -.,, ;'I . I , :.~j , I J I. ; t ! I t . . i

L
181/62/004/003/035/045
BIOB/BIO4
AUTHORS. Shneydert A.,D.t and Zhmurkqf -I# S#
TITLE;~ roperties of mercury-activated cadmium
Photoelectrical p
telluride layers
3, 1962 606-*607
PERIODICAL ~'Pizika tverdogo tela, v, 4, no
TEXT: Cd-Hg-Te layers-prepared by heating CdTe withmercury vapor were
studied under conditions-of "transversel.l.and.Illongitudinal'I illumination.
The ratio of photolcurrent to da,rk.current was somewhat greater in the case z
of "transverse" illumination whereas the absolute amount.of photocurrent
-thousandth of the photocurrent from
in th'i s case- was.onlyabout one.
"longitudinal" -illumination. The electrical and photoelectrical properti 8
were directly ~dependent onthe vapor pressure of the mercury in heating,
J e., on the~amount of mercury:diffused into CdTe. The photoconductivit
maximum which for CdTe lies at about 830 mA is shifted to longer waves
when mercury Iis added._Thia behavior is attributed to the formation of
ti
solid solu ons of the type xCdTe- I-x)HgTe.. There are 2 figures and 4
references: 3Soviet and 1 non-Soviet. The reference to the English-
Card -1/2
17
i'114 Ald 1 1 A
M 7

3/181/62/004/003/035/045
Photoelectrical proporties.of BIOB/B104
I
iz,

1 L:~tr T
----- ------
I' a
Tl 11 E The influence of admixtures on the photocorjductj,~,I a
n i:
of
~Mium telluride
PERIODICAL:
Ukrayins fizychnyy zhurnal, v. 8, no. 4, April !963. 487-4488
TEXT: Thin coatings of CdTe, applied in a vacuum on a hoi, sublayer and
heated in mercury vapors have considerably better photoconductivi-v tear.
untreated with mercury. The effect of other el ements in tie pn,) * 1,~ ty
of CdTe coatingswere studied. rhin CATe coatLrgswv:~ hea~e-~ i t :-n -~-utt-c;s Ot
the following elements- silver. indiu-m, 6-~.,mtitLit -sulfur, selentim and to'llu'r-
ium. -,ictst af 0-0 -the photoconductivity of CdTe
,coatings~'- Ho1weVd-r-d"T coatingsheated in bismuth vapors at 380"C have a phr)!~o-
conductivity 4-5 times greater than pure CdTe coatings. An assum; ton LI made on
the mechanism o! action of bismuth and aercury vapor3 ir, ~d-e
the electrical and photoconductivity- in tle -itz i-, so - 4 i),i
RgTe -CdTe 19 f r-ned: --:i the c a se of b *1 smu t h. C W-! 'i 'I i:a
zmpurlry which resul-s in a decreage -~ne a "Al it I
surfa,.-e of he sazzple.
tfl'k-,y
S 3v. ctober IG, 1962
Card 1/1

S C"F F I z i ka
A bs . 5E499
A II-) RShnejderj A. D. ; Zhmurko, I. S.
A
I
and ;xhotoelectric PrP 1&y-3
2
C:TF,D Nauk. zar). D:!~okjo 8, 1962 , 3-9
-de-rz-i. oed in7t,
T'AG6; cadmii= tellurlde, ohotoe'er-tri-: ~.,rn P" 7tj,e ectri r- nropert Y
photocori-i,icti.rtg film, photoconductivi-y
!TRANSLATION: The optimal oonditions for obtaining photoconducting CdTe films a-to
investigated. The beat results were obtained by condenBing high-resistance p--CdTe
from va~-,or on a quArtz or graphite substrate heated to 250--3000C, The snaaiment,
on a were characterized by a ratio I i_ = I;lr,. 7he opec-T-ens i-t
M~.-minR+ed thr-xh the -tit ei:!~trole
photocurrent (30-35) AA-a. Tne spectrai c.Iara-_t,?rIstIf, of tne p-Inotocn- j,-,
.1 . The 31one of tne *em-er%t-_irFi denen-
ity disp'n7s one mi,-imum af 940 m
1~ corresnonds to Z, F = 1. 5 ev. The -~hoto,-I%r:-ent vr,)wt* Iq - -.-a. tj-
a~ average valile t - 2 )r 10-'; sec, ar d ~he TP f' 'rc -ir, c.
A. Shne-
DAT2 .7-j M -CODE-. PH E$CL: ~00
CR;4 171

INK;I111,111"11 A-HE
Jill MENU;), 101IME Irt IN H I I I il i, ~ T 1, '41, ; -

7
N I , I I I fili 1 1, 11 n jo,-, ~.!
I.. I I ~,', 1 .1 , - if,
11 1! 1 ""; , "
i'~~ ; i -r. - -1
; ! 1: J . I Hf t, "..!,
- I E , . P.-..- :

13
d 1-

-, :~ ~! i~ I ~'i-Vi II'll I h , , ': I " ~ 3 ;
.... i '; Z; I , I R 0 1 ~;, I ~:9 1 1 f 1,
I~ f., , I I
: ~~, .; 1. ;; i.t ! hil. I h i i, L"'. A~ ~~ -
- i. :,*;, 9 11
; '-- :t I ~:" r i. -!-I ~, i 1: 1 1a ~j I I q w -. i I . - - I

:~ 1 ~ t
i ill *
I ~ I

I IIJ

'llli~ fill

`.- ': J~ -! '!IIA - -411
. t, ~ Hf 1 ~
1 11'.
- P"IN,1111,11 ill.
~t, -; ~: ~~ : ~ ~r ~ 1;I ' i " ,i ,
I I . . -- , ) I I P, I - !! I J I, 1 1 H

, f ,,-. i
. 1 ~
ll I ~, Ed I i I I-If tl',.11-70~,:~''2,;
~ ~ 1111. ~
.~ 'Afir m:11., il

1*.,:InotituIVorgmdchemkoy Ichildi AN Ukrainskoy SSRo
;-.,.-(Fh6sibAzo empoundo)
;F,

1L
R , -JiE
I W, MR.
,ir rij,

mi
m VIA

Jim
Mil
Hirwt MIMW 4

if W11 ;J' ~i t.
711-534.21
Wftt of tfit Dbetwomim Group and its Co Ah
'Pluslity w th,
A=.&9-JI- A.- 1. Kwitimmy and 1. N, Z Gm Chem.
1~, 1953, 23, 4UMUDY& J-
t k irm (if
dyt- of a &tllrhtcc, dri-clo wit ric risil f qf -,t- t-.- t hr f
w

j~ IT H: ji
-- , " I
Ufff-11 ff.,15fll'
IS

COPIAnadly of th-441 M=up ~vith !b! ben3ene rinr PiA

W 1114 fffect on the Cal or of
- _L,:EjL!ffiR_P_y and

1 X4
)II111x2vil . tip, vfttk
r)k M, ;I3
Mpand R1 Polip.) III fbe l~-1KAWWO 0 Ef
i
but A walk M
II f
b
t
1i
i
f
At
d
-
u
e),
#)I
ir n
fits.
e
l
rill
ffoillf
alliscm CoMpIrtely Mitrpk lite. ativilchrullite Action of fill-
.
pf"it), the mnie efrret 6 lind hy 2 Me grotit" in 8,,JR)-a-
t

o
Nc)~. I(Olitling .33 R. 'Ill-BrANW41111it ill 70
nil, F1011 2 11m.,with Ing, X. 4 unit WilO,
Moll flaw 21.5 which. IrtItte-I I
IM list, ArOll stith 42 x. Zn ihwt will 11(lial. roovA. IICI,'
TAiml It hr.~ fifirrO, 11M.', awl livule,j with N*OA,-. gavi, r~ I
wilb vicot--s-
pill
A0.0, [cave nil fit (At. a r
Thf4((1K.)t"fqj"l tip

4.8 mi. I MOA (if, 1. 11 mnl 12 ill[
Ir
evincit. 11,40.,

M
its on it woter bith. and Ifir:j"111to-t rfptd.~ frinis HIM
A
and tvid. froin MI. I ICI give IJ' K. kfill* (1), M.'

100~-2% and OA g. jt-mirts, ift-rip., ill. tj
ReMixing 11.3
DIV. 0.3 g. 1117(0110'. all't :1
t7.1954 ml. pyddinc 0.5 fir. gave AgWo ~rrrn
,

OrRerAo Wmi t
8 r7 ben.
in. :M-21, 61 t
n
FAS
i
ax.
s
m
ll.

McCiff.50A -1 hrq. nt 11110-70' gas-e,12 M. it
4 after at
~nziry salt, which, refluxt4 with 11C(Olith in filine, gave.

c1tv"onif '7111, ffroni::

EMU), ab I max, A a Fn#. I beal I V0111 h 2
Ij
br3. at 1000"unrl,thr rrqullirg ClOaternary salt trMiNvA in
d 1, violet bh(4-ntrlky?,1;-
pyri ine will% IIC(0110~ pre 30~4
'In atove 34X)%'htwwpttun max. 590 nio I trailing 0.2 r, 2- -
incibyl,54cri-imtyl4~-nitrolkniothtwole with 0- g. P.-
McCalUMM I fir. at IM-MI gayp 7514 wintrmnry wilt, i
Which, reffivicA 20 min. with 11c(Out), in
W%
Iit Mille dixJ1111P. 2"07, (frain
T(0111), air"POP" inax..NO mm. 3,-I-h1t4OsN)CJfjN1ft
(k1 4diazotized anct treated with 0.4 K. NfelUPh In -fit.
*
kbiaf after several Ism a tipt. which. divialwill in
Ila. y
110slad filptill. with N11.011, pve4O cnwePr*lwt.j"rrf-
"imoO
lantme-
OM by chrumstogmphy an Ah(h
k In
. y
l
g

Ow

6
HIM, Alf
ri-I mm
Ohl
Q
9~~' i - -;' t ,

1 , P,
I ; I
I ;
j ~ 1,
I i
i - 5
i L,
. : A
- I : k
. . .
; I I
: . . f
- . 9
: u

1. N.

'N
"Esters of,isocyanatophosphoric Acid and Their Derivo-
U'ves," by A* V. Kirsanov.and 1, N. Zbxurovaj'Institute of
Organic,Chemistry...
Academy of Sciences Ukrainian SSR, Zhurnal
11-*,~;, Obsh6hey.KhImiL, Vol 0 ;002-p06,":
N 4., APr 57., PP
E
ers o isacyar
at f iatophosphoria acid are prepared by the thermal de-
composition. of eaters 6f_uietbanphospboric acids. Certain new esters of
-*,urethanph6sp ric acid were,prepare
d from, the eaters of isocyanatophosphpi
ho
7

-I-. ! - i i,;! " ; . :~ i ,
.
. . I. . 1
. - t ..I ~, : ~ 11 1; 1 " ~ii I [-fll I -~ 1~ . i ~;v 1- , t,
i i ~i I i . ~ ; . ) -;~ ;
- " I ; 1"ll .i ; , jw 11 1 ~~ -
I : . I . 0 HIM II-EYMIAIV

.1 ..
1 1

T -~- .
, " ~: ' `
o I , ; . -
j . - , t
i. ;, I I

761-66 ENT(m)
NR: AP6012649
SM
~IC5 163
SOURCE CODE:
t. ..N

ACC NR' AF6016698 SOUME r-ODF,1 UR/0079/65/035/012/2197/22W
AUTHOR: Zbmurova, I# No; Voyteekhovskaya, 1. Yu.
utioof Organic4hemi ---AN-UkIz
(Instiiut organichee*.'.
rSS9
Imut
Ukism)
TITLE Phosphorus,.alkyltetra~hibri~~~:,
p
i zhur
-SOURCE
~,._v- 35, no. 32 ~1965 2197-409
i-TOPIC:
--chlbrinated org c-~66mpq d
T
GS un phdephori6, acid, eulw
_'Compo
MPO
A
2-A
BSTRACT i
t
W ith: ohiorine tit -M to 15 Isoprop.
Z!_ 0
b,
d -100amYldl Iehloropho y V1.
GbbUtSrLl amy an
Sphines' leld
un;
OCIPhbruil3b Is W_ h i 0__ h dooompose mhen heate
h
AabdVe _0o- At 26.300 bAtYlld l6bldropho sphine to ohlorinated to
.~diohlorobutyjtetraohloroph:o n
sphorus. a d propyldiohlorophosphine
!'is converted into Propyltetraohlorophosphorus. Alkyltetraohloro'.i
'Phosphoruses reaot with sultur dioxide or sueoinnio aold to Co3m
ith6 aoid d1ohlorldes of alkylphosphonio aolds, RPOC12o where R W!
;n- 180-C R 9# 190-C Hii or 140-C
C070 3 V CO 091 04H?C'26 CS 5KII
whose oharacteriatios are presented,
'The
allthdro'd is,thelr thanks to,'Ai V, bralmov for aid
V -and
C the
researcho
0Vjj0j on
T-7
_-d
-'REPt
UDCS

ACC NRi W5027772 Monograph
niqv
DeE~uhp GrifjOriy LUarionovich; Zbmurova 7rina NikolUM= Kirsa
1_4!e Ar
Vasillyevich; ShevchenkoA Venii~lin s nek, Alla Stanislavovna,
ljospha:Lo oppounas ~Fosfazoooyedinenlya) Kievp Izd-vo ",Naukova dumkax" 1965. :283 Pe
(At head f title: -Akademly-a nauk Ukr Inskoy SSR.-.1notitut.- -
illus. PbibliZ~* 0 a
organicheskay khimij) 2000 copies printed.
TOPIC TAGS: organic phosphorus compound,, nitrogen compound) organic ato compound
-PURPOSE = CGVMGEt The introduction contains a review of recent, research in tho
field and a discussion of the problems connected with inconsistencies in terminologya
.The nomenclature employed is that first proposed by A. Mikhaelia. The book deals
with data on the chemistry of phosphazo compoundsp published in the scientific press
up to 1 January 1964p and, presents lists of the phoupbazo compoundn'that are known,
atIthe prescAttime. It is Intended for scientists) industrial workers) tcachera$
and students Interested in modern progress in organic chemistry..' eBpecially those
working Lin the field of phosphor- organic compounds. Each chapter deals with a dif-
~fepent class of compounds,, for vhich the authors give the method of preparatioup the
chbmical properties) a list of compounds,, and-an appropriate bibl4ograpby,
T4BLE OF CONMTS fabridged]l
Cb. 1. Introduction 9,
~Che 2, Phoophazosulfolvis - 16
Ch. 3o Phoophazocarbacyla - 79
;47
A Card 11W. f I
--------------------- ---------- .. .... .

I I 11. . I I . i.
I i ! ~ 9 t I
?!,: 4. !;, ki ~ i ~ 11: 1~ -I
I I : - ~ .- - ~! a
I , I ~! 1 1
'lp I'l - i I

I -~ 9 * ; 7 i i ii! ii!- -
." ". i ~,L i ~ I 'i. I - i I ~ P I . .1
1 .1 :, 4 ~~ I ~-~ !, , ,
:;~ I I I , . :~
: ~~, ;u , 1 ~ ; I A I I . j
I F. ~ I ~ . .; 1~ i
.. .. ; I ~, !

..i r -1 4 ~j...
i : i
01,1111H i III 1~ I KI i, I ~ ir If.", "1
i! ! -
I I ; Ii::I, ZIT .:!!
J~,

dif * MM
0 i2a I

.11
i6 [. I i... .i ,
Vp,
1 1

i Or
P ip
4
III
I
rij, i
la

.1 ik~~ ~ ~t ,
r, .. %
r: .

-- -----------------
, , . 7 , , , .
. m c I , , . T " , I
, 6~~. ~ a, i'llli-i ~ I I ~ I I ~,:, , t I ';
- : ' . . . I , ,
4 1 ,, i , .
111,11 P" lo ,1 L

24. PROMMUS 15OCTMIATM. A. V. )~rvmvnv rt n1 . . . . . . . . . 6q

27, . . . . . . . . . . .
. .. . . . 175
28. .
PJAMON OF P1.10;M10MIa bTI(j,)MF WTJ1 AU',YL WMMM V. U. cnhl) s:t 141 . . . . . . . M()
OV CAU.U,;XYIEC ACIWJ (V;OIjMJPJiAZ(Y C-Cml 1) ij 0A),
. . . . . . . . . . . . . . . . . . . . . . . . . .
30. nr -I OF CI-1/11,1DF-3 WT"I ACIU AMUDE3. V. 1. 32heveherko ~!-, tLI . . . . WO
31- WMRS OF DrAMMINITIVNY1.1 ACV~;.,, I;. r. Tavetkov . ... . . . . . . . . . . 193
32., IrlUIZIMMIDE3 OF r. A. rui -I,o-f ttrA A. r. cAyzitom . . . . ... . . ... . 157

33. M-A, V. 0. Varon~,)v and D. X, InnIrt
TUAM, 03 OF DIAMYL MoViTITY3 147111 qu.I;;kTi . .
;; G 3,

34. -~wpoltv-% r-ldn .

108=10.1; OF DIAMI, wrPI P-111.14"al"IfIXINZ. R. a. 1,
07

M, -1 'MON',
M. AGYXIMMM Or T91 MIMI I~YL W7jM 0, P1,100PRORIC ArM AMIXIM X ACID3.
11. r. Cirlov r%rKi Y. 0. vor-=-~ko? . . . . . . . I . . . . . ... . 212
36i WrEX5,0F DtA[rYlAMr?ll-,-,IYIf~,!DJPhiiTC AM.- G. Y.- 14. th.tnov 217

37. IID AIM t!~=3 Or ACID.
ACTIOIf'OF CAPrO.*i IMMICHWAIDS Al
. . . . . . . . . . . . . . . . .
G. Kinal fn~ nl~ . . . .
33. .
PFACTION 01' D"M IC AXMS U"I I ", !~"!5n CIU00M, . L. V. Noi tarwr and It.A. &xbImm 2
~fp
39. REACTIOIN OF DIVILIOPIMPECRIC AMS 'WITH ARrIAk.,rIO DrAZO COIVOUNDIL A. F. CM;K)V . . . 2z8
40. u0IWW ACID WITa TRICULOBCAMM CHLOME. L. Z. Sobor-
MACTION OF F-IMM 0' FYOZ;iI
. .. ... . . . . . . . . . . . . . . . . . I
ovak~i ot oil. v i
2=
41. .
REACTION O,-~ viox"Imm, r~,:nACI!rDaIIV Urni MaOf, ACMAIV. t,Y. Int-jenko krid Y. KirIL-iv 237
42. SMIE.", OF G 11. V. YDrn)-A,, et al . . . . . . . . . .
Ii IL 242
43. UIMM15 OF DICrM=LIC ACM3 A110 M. IVNIATIOtl OF IIOLYAMMM

*
,
111W TIr V. V.: Ycrahalc 1.-t al. i . . . . . . . . . . v
2

44. *~~,o:
--D co au OF . -YL-
;I~ , i
SMIRESIS,~ romoulmTmI, A: rovyrrm=17.103 OF F--,r. ACID.
0. S. Fole!miltor L't . .. . . . . . . . . .. . . . . . . . . . . . . . . . . .

5.
rm, P11,013PiF).1113 )(OV0M3 AIM MMM3, X. A. Andr va et al.
'T10" -07 NE-4 =00
NFW Mh
263
SYNIMMTS or BrFVWIq0.IaL CrAITOU.",,." OF 110aPHORU31, ~D. A. Arbuzur., et al . . . . . . . 272,
'47. SYM."ItM13- AD APPLItWIPM1 OF 0.-,QM0FII4,5r%OfIu3 CM%MUs 13 TIM PUSTICS IrLvj="mT.
. . . . . . . . . .
'P.- A. Ywhkizvot al. . . . . . . 179
48. PMSPNO, 'AM R=43. K. A. Petroy et al . . . . . . .
WwCONWHM MUM= 285

49. M TO fATH sy -IIWZIS. K.A. Pctrov et a-1.
AYPLIZATIO5 OF.ATWIJWf FZAPWV~,E;~= raTZrLK)sPjjo. C92

SO. 4 XAN)a M100MM, E. V. Xurnotgav et 41.
mmariTtmVI) ORCALNOIO*P!,~ 1w

of a) A.7 Y6. Mvzov, Fit. pull. ty XiLumf Arfil, AuL Uncl.
0TewII*.ph*3phmw CVZ7~,Omil
IESR, Ywcou, 1562 63--~PP.
Concetton ef e=plot~ pnptrg. prv4cutAd at tho 1559 Katen Coaarenec, en Ch5clstI7 of
orgw9bosphorw COCT*"~ a.

A1,

! `., 115-111 'ill, 1, 0; 4 1, i 1 , - 4, P. ~ u ~' ~i ,-:,
i it ~.
.1 " q ~. ~ , ~ I e- i -~ ', . ;~ ~, 1
I - H
C

JI

5/079/60/030/012/017/027
j3ooi/Bo64
AUTHORSt Zhmurova, 1- 11. and.Kireanov, A. V.
TITLEs 'Hydrolysis and Acidolysis of Monomeric and Dimeric Trichloro-
phosphazoaryle
FERIODICALi Zhurnal obahchey.khimii, 1960p Vol-30, No. 12, PP-4048-4053
TEXTi The 'tjiChj~'j 0Lphosphazoaryls (ArN- PCY obtained in the previous,
paper- (Ref.1) are.:easily hydrolyzed~by air moisture. They acidolyse with
formic and ace,tic'aoid to aryl amilophosphoric acid dichlorides (I)'(IV)
(Table 1). In contras tL to monomeriIa trichloro.phosphazo aryls th eL dimeri3
compounds are not transformnd into aryl amidophosphoric acid dichlorides
during hydrolysis or acidolysis. Dichlorides of the arylamidophosphoric
acid,(V)-(XII) (Table 1) may be obtained by the method described in Ref. 1
under the action of formic acid on the solutions of monomeric trichloro-
phosphazoaryls a ccording to reaction (A). The letter are easily hydrolyzed
with water (some of,them even by-air moisture) 'Ftich renders their
purification diffioult. On.prolongWheating in Liissolved state or on
water bath without solvent, they-gradually decompose. The authors proved
Card

Hydrolysis and.Acidolysis of.Monomeric and 8/079/60/030/012/017/027
Dimeric Trichlorophosphazoaryls,' BOO1/BO64
the~identity of arylamidophosphoric acids which are mentioned by,
Michaelis (Ref.2). On reacting PC1 -with arylamidophosphoric acid di-
5
chlorides the-initial products were.obtained in high yields, i.e., the
monomeric and dimeric trichlorophospbazoaryls (Ref.1):
irNHPOGl ~+'Pcl 101POC1 +-01:4 ArN_ Pol
'72
3
2 ArNHPOCl + 2PCI 2POC1 + 2HCl + - PCI
21. -,,,,(ArN 3)2
5. -3
The_:structure of Aimeric -trickorophosphazoaryls~could be determined by~
~partial_fhydrolysis. only in four:-dimerso According tc the elementary
analysis,~,their molecular.weight and:the chemical prooerties,i the
reaction products, obtained in.this connection are acid chlorides of
N,Ni-dia'ryl-N-dichlorophosphinyl diamidophosphoric acid (Table 2). All
other dimers.gave only viscous resing. In.crystalline stete
..N,Nl-,diaryl-N-dichlorophosphinyl:diamidophosphoric acid chlorides are
ra. th er stablevon heating in or.ganic.solvents or POC1,0 they rapidly
decompose. Their structure was confirmed by converting them into the
dimeric initial trichlorophosphazo aryls with 2 mules PCI Thereare
Card 2/3

ii, Hf I -lit
-l ~,-,
IN 4
T

S/079/~60/030/009/011/015
.3001/B064
AUTHORS: Zhmurovat,I.,.N ,.Kirsanov, A.iV.
-TITLE: Triobloro-phoaphazo.
m Vol- 30, No. P7;PP-3044-3054
PERIODICAL.- Zhurnil obeho.hey.,khi 11, .1960,
TEXT: In continuation of Papers of Refs- 1-4 the authors studied the re--.,,
action of phosphorus pentachloride with a series of.aromatic amines and
some derivatives of aryl.amido phosphoric acide. Trichloro-phosphazo ac.,-Is
are obtained almost quantitatively on the action of PCI on acid amides
5
(Ref. 1). On the,reaction of aromatic aminee or their.hydrochloric salts
V, ith PC1 :in boiling carbon tetrau'"'loride compounds are obtained in,good
Yields, hich, in their compositionj1pracieell correspond.tochloro-phos -
phazo aryls (Table 1). ArNH + Pol -42RCI + ArN . FC1 (I)
2 5 3
ArNff Cl + PC15~---* 3HC1 + ArN - PCI (II)
3. ~_9' 13 3
Amines with basicity 10 10 give rise to triabloro-phosphazo
Y-0 as
aryle-in the form of dimers-, while low-basicity amines yield sitch in the
orm of monomers. Dimers of trichloro-phosp~azo aryls obtained from amines
f
C
Z'
IN

Aryls, P/07?/60/030/009/011/015
BOOI/BOI 4
Wi th Kb a s 10-9 107 10 are decomposed, on boiling, in benzene solutionst~
and not in monomers, whereas-dimers from,low-basicity amines are partly~
or wholly docomposed into monome_Es. Monomers of triahloro-phosphazo aryle
resulting from amines with basiaty Kb' -10-10 - 10-131. could be obtain-
as
ed in benzene solution only. When their solutions are evaporated, Ahe mono-,.
mere are I~converted into the reep ectivq dimers. Trichloro-phosphazo aryls
from amines,vith lo- 14, 1071-9 resemble the trichloro-phosphazo
acyls as to their physical and chemical properties. Again with respect Ao
these properties, the dimmers of trichloro-phosphazo aryls differ sharply
from trichloro-pho3phazo acyls and apparently possess a cyclic "bencoid
structure -.,eri Of , trichloro -phosphazo aryle . like vi as resu lt on . the
-of ~'PC I ''on a.series ,~.of aryl.smid.0 phosphoric
~Ctio acids. The divaers
a . n
of lrichloro.-~hosphazo ary'01derive their importance from the faot-that
thd.y are-aleo formed b Ithe'reaction of phosphorus pentachloride with.
y
various derivatives of aryl amido phosphoric acids (Table 2). There are
2 tables and'13 references: I Soviet, 6 US, 1 German, 3 British, and,
2 French.
card 2/3

- -
1 1.11 ", : ;III,- , V I f- -:-, F'- 1-1, , ~
4" 5 . T 7 : t -? I f 7 ~ : 1 1 -.~ C ~ ~ ~

~:-AUTHORS: Levcheako,. -Ye. $a I Zhmurovao I. N., SOV/79-29-7-34/83
Kirsanov
A. V.':
TIttE':' Realition of 'Phosphorus Pentaichloride With Acid:Dichl'oriden-and
:Diesters ofthe Aryl Sulphonamidophoaphoric Acids (Reaktsiya'
pyatikhloristogo fosfora a dikhlorangidridami i diefirami aril-
su.11fon.amidofoafornykh kislot
PERIODICAL:. Zhu'rnalobshchey.~khimii, 1959,:Vol 29, Nr 7, pp 2262.,r~2267

ABSTRACT.#
~Kirsanov succeeded -Anj an f i c hl or--.) phos 0
r a o ming the tri
Ikyl8 yla of:the~ty into the acid-.dis~
phona and ar, pe: R30 N' FC1
2 3
chlorides of:the corresponding alkyl- and:aryl su1ph=iA1d&vhoa;-`
-phoric acids according to. the scheme R30 N=MrCl +H 0 icl+
2 3 2
+RSO NHFOCI - by theaotion of water or formic acid (Ref it-,
72

neformation'.
.was of interest:to find out whether a reverse tra
was possible,,i.e. whether.the corresponding trichlorophosphaza
compoundscould be obtained according to the scheme RSO MOC1 +
+Pcl Hal +'POC1 + RSO N PC1 (I) from the acid dichlor-
3 2 3
Card 113
40 ~11 -f--

-------------
entachloride With Acid
_~Repction,:of Phosphorus P BOV/79-29-7-34/63
Diohlorides-and Diestere of the Aryl Sulphonamidophos-:
phoric Acids
idea of aryl,oulphonamidaphosphoric acids, The experiments'.
showect that the,roaction (1) for t,he-ao.id dichlorides of 0-1,
m-, and p-nitrophenyl:sulphohamidophoophoric acids takes place
at 130- 1350 within 10-15 min in yields of from 47 to 80% as
wall as for phenyl eater of the N-(dichlorophosphinyl)-mono-
amidb of p-benzene dioulphonic.acid at 115-1200 within 20-25
min in a yield of 49%. In all cases by-products of uaknown na-
ture are f ormed. Also in the reaction of PCI with the potas-
5
siu;n salts.of the.acid dic%lorides of nitrophonyl-oulphonamido-
phosphoric acids the.'same yields -were obtained.:In the action
of 11C1 on theacid dichlorides 'of aryl oulphonamidophd6phorio.-.
5
acids, the molecules of which contain no other substituents.in~
the aromatic nucleus, no corresponding trichlorophosphazo sul',
phonaryls..are formed. In the reaction of PCI with the diphenyl
5
eaters,ofthe above acids the diphenoxy chlorophosph -azosulpho-
naryle, irrespective of the nature and the position of.the-sub.-
are obtained in the aromatic nucleus o.flaulphonio-
Card 2/3

50) BOTI79-29-5-60175
AUTHORS: p jireanovy To
TITLE:, 'Extension of the Range of Applicability of the Phosphazo.
Reaction (Rasehireniye granite primenaniya foofasoreaktaii)
PERIODXCAL: Zhurnal obsbohqy.khimiit 1959t Vol 29j Nr 5t pp 1687-1694 (USSR)
ABSTRACT.: By the action,of. phosphorus pentaohloride on...triaryl phosphiie
one obtains triarozy'. phoophorus'd-lahlorldes. Not-ozily phos-,-
phorua pentachloride but-also pentaphenozy phosphorus -and 1. tr;L-
phenoxy phosphoras dichloride may.be_utilized~a's.phobphorus
containing components for phosphazo--raaotioxts..-.Triphanoxy
phosphazo aryle -are obtained by the.-za &alion_ ot..the.: ab ove-
mentioned compounds with aromettic amino s.- 2r.aduati on and
properties,of the following compounda.are given. Triphenoxjr
phosphorus,,diohloride, peniapbonoxy phosphorust triphonoxy
pho
Ar :phazo phenyll triphenoxy phoophazo nitrophanyle
ff P(OC H ) with the axyl radicals: 4-NO C
.6 5 3 2 04
2f4_00 0 H P M-00 P.1 2P496-(NO.2)3CA
2 6 3 2)2'6"3f N02
(Table 1), triphenoxy phosphazoacyls AcIT-P(OC H with the
6 5 3
acyl radicalsA .0 H so j so IN.P(OC6V3121 (c6H50)2pot
Card 1/2, 5 2 2

.1 :: .1 P -. . 3~ ,
- i I
It , T!
'", ; U ;l[:i ll~ H :, 111],
I - " Qj lj~,,-,~
A

Direct.Amidation'of,Carboxylio Acids 6009-29-6-67/72
'Amidee of thatype (RO) FOR and Ar FOIM and their N-aubeti-
2 2 2 2
tuted compounds..ver6 selected as samples to be analysed# The
amide and,the dimethyl amide of the diphenylphosphinic acid am-
idate the carb6xylic aoidal when heated in pyridine ordioxane
and are.very-easily'eaponified. The amidatiort capacity of the
amides of the d4~enylphosphinic and diphonylthiophoophinic &a-.
ids.corresponds totheir easiness of.saponification i.e. -to
th4ir capacity to combine with,hydroxyl..The amide, ..dimethyl-
amide and phenylamide of the diphenylthiophosphinic acid and,
the phenylamide of diphenylphosphinic acid do not amidize the
carboxylio acid under the same conditionsfand it in difficult
to saponify them. The mechanism of amidation of carboxylic.ao-,
ids with ailde and dimethylamide of the diphenylphosphinic ac-
id differs from the mechanism of amidation of the carboxylic
acids with amideo,of the sulphuric acid. Some amides of the
diphenylphosphinic and diphonylthiophoophinic acid were syn-
The'amidation with the amide of the diphenylphos-
.:phinic acidl according to the schemEt
RCOOR + (C H PONH ---->,RC ONK + (C
5 2 2 2 002POOR
~qard 2/3. takes place especially smoothly. In the table ami-_-~3s of both