SCIENTIFIC ABSTRACT ZHUKOVA, V.I. - ZHUKOVA, YE.N.

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• Collection: Scientific Abstracts
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• Document Creation Date: November 2, 2016
• Document Release Date: July 16, 2001
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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ROZENBLYMp Sergey Germanovichp-limd, tokbn. naukj 741UNOVAp V.I. g insbo #
red,; FOKCHEVy A.G,t red. imd-va; GMTS, 1.

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(wheAt-Har7ogting)
MMMIIII. "HIM: 110P.Mly"'IN

S/13 9/61/000/00 V017/023
E021/E48o
AUTHORS. Loskutov,, A.I., Kuznetsov, V.D., Zhukova, V.M~
--M-e microatructure,
TITLE: The influence of thermal cycling on
of cadmium,
PERIODICAL: Isvestiya vysshikh uchebnykh zavedexiiye. Pizika,
no.4, 1961, 134-139
TEXTs Investigations were carried out on commercially purt
cadmium. Samples of 70 mm length and cross seations:of 10-M 5V
10 x 2 and 10 x I mm, were rolled. Specimens were elactropoliihed
in a 50% aqueous solution of orthophos phoric acid. N I mm dl6metsr
region was marked on the specimens using a diamond. The changes in
relief of the surface were studied in*.this region.duringthermall : I .I
c.yclinf. Samples were held for I minute at 10'00 arid-for 3 min'ute*3
at 185 C. Changes were~follow4d, on a horizontal metallographIt
microscope and on an interference microscope. Mcrophotographa
were taken. Thermal cycling developed-a relief'lat the graln
boundaries. Grain boundaries, invisible at first, appeared after,
only 2 cycles and those boundaries which were initially Visible
became more marked. This indicates displacement of' grains"
relative to one another. Slip lines were also present in the
Card 1/3
.M-110101r,.-Km:

S/139/61/000/004/017/023
The influence of thermal 9021/9480
grains after only 2 cycles. With anincreasing number.of
the graln boundaries became much sharper and the numberof slip'
,lines increased and they became more marked. The difference
between the levels of several grains was measured after:varicus
times* In one case, after 20 oycles the displacement was
10 microns and, after 35 cycles, 12 microns. lt,'waa also 3howA
that after 20 cycles many fine graina'appear-ed-inladdition to the
original grains 04 The breaking-up of the grains Wais complete after,
about 300 cycles. The newly formed grains were associated ln~
groups and the botuldaries of the groups torresponded to the
boundartes of the original grains. The fact that the; origin-At,
grain boundaries were more strongly marked than the nair grain
boundaries,might be explained by higher thermal stresses in those-.-
regiona. Macro changes were also observed, The length of ~
samples int;rea3sd with the number of cyclesl afte~r 400 cycles. the;
Jength of I mm thick samples increased by about 2.5%, that of tha
2 mm on6s by about 1.2% whilst the 5 mm thick aamot& rtmained
essentially unchanged, There are 19 figures and ~ reterencea~-
2 Soviet and 5non-Soviet, The four moat recent refeilentas to
English language publications read as followa~;
Card'2/3

S/139/61/000/004/017/023
The influence of thermal E021/24801
Ref. 124, L.Lloyd and R.Mayfield. Trans of ASM,'Y,,5O*-954, 1958;
Ref.3: V. Boas, R. Honeycombe, Proc. Roy. SOC., A186' NO-1-004,57-71,
1946-, Ref.5: W. Boas, R. Honeycombe. Proc, Roy 0 S60,39 Ai889
NO,10159 289 19471 Ref.6.- W. Boast R. Honeycomfibe., Journ. Inst.i
met., 73,.No-7, 103, 1946-1947.
,ASSOCIATION:. Sibirskiy fiziko-tekhnicheskiy insiitut'pri Tomskom~
gosunlversLtete iment V.V.Kuybyshava
(Siberian Physicotechnical Institute at Tomsk State'
University imeni Y.V.Kuybyshev).
SUBMITTED: May 15, 1961
'Card 3/3

During DCn21fIC8tion of Cloyey Grounds," Gidr, orJin, rtro-vo, lip
PP 16-13, 1954
The authors develo 6 1~ jJ8.1%.ae-
p thin oseibillity of dearessing the: i t,
ability, -.X clcyey grounds by, vuy of dannificatiM of them duriney i rl~-
C11'eased wettine. They present experimental observationn ouli.'tho wilter
permeability of two elvyey grounde (soil contAining n&nd ;-butt. 25-50`0
clay) from which tntifiltretion ~creenu were canstructed, Ic-ld otAlle
bottom of experiuental constructiona. Tho Crounds wero built up to ti
2Z-cm layer, efter wetting and otending they were made denue by *heci,1113-
~foot rollers and by smooth roller* for various degrees of~utettiq*. From
the compacted layer samples of ground were tnken by mul.nB of steel cyl-
inderr, l9cm dirmeter and 6-10 cm. height and tested for filtration. in
a device 'of the y4jinenskiy type (for hyd.rmilic gradient frota 3 to 11).
The study demonstrEted th,~-t iermeability Lrestly decreases unde'. vet
com9acting. (RlhGpol, No 4, 1955)
Slim. 110. 601, 7 Oct 55

s/139/62/000/001/005/0~Z
E026/E435
AUTHORS: Kuznetsov, V.D., Loskutov, A.I., Zhukova- , V.M.
TITLE: The'effect of thermal cycling on th.e mi brostructure'i:
of Cd. II
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeni3r., Fizilca.
62 36-4o + 4 plates
no.1, 19
0
TEXT: The effects of plastic def rmation, set up by thermal
cycling over the range -196 to +80C, on the microstructuire of: Cd
are studied. Cross-slip is observed after only one cycle;
lip taking place in two and, with further cycling, -three
directions, usually at 60 to 700 to each others, Further
deformation up to~50 cycles sho-mrs that one of .:,t h eslip systems
tend5 to predominate over the others. Twinning is also
-te def orinati! n f
observed, the width of the twins increasing as~tl 0
increases. ~ Sub-grain formation ta'kes place,within the original
grains, the disorientation being shown up by microinterferometriC
studies. Micro-relief effects are also observed when complex
slip systems operate in two adjacent grains-..' This:behaviour is
different front that in the: temperature range:10 to 1850C, sinc~6
Card 1/2.

S/139/62/000/001/005/03Z.
The effect of thermal cycling.... F,026/c.4~5
the material is below the r4crystallization temperature and
grain-boundary migration is practically absent.' In the upper
temperature range only one slip system a
pparently operates and,
very little twinning is observed*, indicating that the strain
resulting from thermal cycling in this. tomp'eratare range must :.be
considerably loss than that from cycling in the'Jow-temperaturo

.42
1899. ZIIUKOV.1'L V. N. Filatov's Ukrain.ian,Exp. Odcssi,i 05511.
Ille IMMence of decompressive gu~rgery-. upon t an'6.
gioscotoma and intva-ocul'ar t)
PIIOC.FILATOV'SUKIIAINIAN Lxv.lN9T:EYEblS. 1955,3(210-2151 i
Twenty-six patients ( 30 eyes) subjecte -d to fiitulatio6 stirgery~wlere undcr
tion. Of 30 eyes. 13 were in.the early stage of glaucomi) and lit114 the gluIU60ina *38
in an a0vanced stage. Nine eyes were in thr mage in
the stage of decompensation. The majority of patients With early glaucioma iihowed
a normal diameter of scotoma (10,out of 16 eyes); livi). I -~ilh adyancediglauco-
ma this finding was rarely met with (2put of 14 eyes).: Im the first 10 days atter
operation signs of hypotonia weve prtsent,-, they were
aided by a grtater or
lesser widening of the angioscotomik. The widening of the angioscou--ima is cipaside'r.
Rol I ME --p-mmus L

ed by the author as a secondary phenomenon. bound up iv~th the disturbed tAo'od
circulation; this. Was caused ~by the sharp postoperative 4owering of lite ophthahnic
w
tone. The contracting of the angluscotoina appeared 2 A' ecks:x1ler operallm
The normalization of the ophthalmic toOo occu'rred at d4owt the icatne lime.: Thu
subsequent observation of ther patients over a perivd or IR inontha, showed that
once a stable normalization of the Intraocular presstire Nad taken place, further
widening of the angloscoloma after the operMion oc,:ur i'd in oifly 2 out of 30i eyes.
An oedematous scotoma or Uie appearance of a neuroscoitoma (!on occur as a rill-
sull of a stable derangement of the regulation of intra Oressure, or~' III the
event of a marked retinal oedema noticod before the alleration.' Bibliography' -
6 lilies.
-NIMMS I ON Room I

mall I
~~nzh., KHINSKIY p Pavel Dayldoidb:hs kand,
-~M~te=bn. zi=kj LJOp inzh.v reC;~: VA.-IlLtUrY,
ZJJF
lu.A,,, red, izd-va;.BELOGUIROVA, IdA.p takhn's rod,
(Relaxation resistance of pearlitic etruetu~ai steel.for
fasteners; practices of the Kirov Plant in LomingreAlRe-
lakeatsionnaia stoikost' korlstruktsionrWkh st~lei perlitnogo
klassa, dlia krepezhrykh detaleis- opyt Leningradskogo Kirov-
skogo savoda. Leningrad# 1962. 29 p. (Lani4radokildom
nauchno-tekhnicheskoi propagandy. Obmen perodovym,6p~tOM6
Seriia: Metallovedenle i termicheskaia. obrabbtkaq no.3'
(tan 15-0)
(Steel,# Structural-Testing). (Strains and stresses)

I I1 .1111 1 F! .1 :1-11 1 r: . 111 - 111111
S/129/62/000/002/009/014
E073/E335
AUTHORS: ~hukova,T;P., Engineer and Smirnov, NiS., Candidate
of Technical, Sciences
TITLE: 'Influence of small quantities of alloying elements on
the oxidation of.low-carbon steel:.
PERIODICAL: Metallovedeniye.1 termicheskaya obr.abotka metallov,
no4 2i 1962, 45:- 46
TEXT: Enamel coatings are frequently of,,'a poor-quality in
goods made of low-carbon steel with a high tondeii-cy to oxidation.
The authors investigated the speed of oxidation of.steel with, .
small contents of various alloying elementso~ 8 low-carbon steel
heats were produced in an induction furnace andtP each, small
quantities of Cul, Nil Co, Ti, Cr, V, All Si~and bin were added.
during the tempering. The first ingot%remained unalloyed.for:
each heat, then an alloying element was added,so that each.
successive ingot contained an increased quantity of the element.
The initial steel-of each heat contained 0.0~5 - o.o8j,a c,
o.16 - o.46% bin, 0.020 00070% Si, 0-014 0.03510' P,
Card IA

S/129/62/000/002/009/014.
Influence of ... ~E073/E335
0-015 0.046% S, 06029 0.19% Cr, 0.04 - O.b84% Ni,
0010 0.20%~Cu.,O.004 0.048% Al. Thequantity.of alloying.
-elements did not exceed 1%. The steel was rolled into 0-5-MM
thick sheet. The specimens 05 - x- 40 mm), were annealed at
0
700 ,C for 2 minutes, degreaied ina solution~of sulphurie acid,
s
(80.g/litre) for 10 minutes at 60 0Cj washed in wate r,
neutralized in a solution of Na CO '(5 g/litre) and Na PO
2 3 3 4 0
(4 g/litre) for 3 minutes at 50 OC and dried at 110 120 CD
The speed of oxidation was determined,by continuous weighingo,
0
Oxidation w-as at 860 C for 10 min, the specimens being weighed
every two minutes. The.mean square error 01 of the measuret~ent.
for various oxidation times (2 -.10 min),wasgon the average,
3o06%. It was determined by statistical analysis with the re,%ult
that an accuracy of7+ 3% could be achieved-by carrying out at
least three parallel measurements,, whereby the magnitude o,.
should have a maximum error of 3(rl,V-n The obtained data
show that, with the exception of-Mn, all the investigated
alloying elements reduce oxidation of low-carbon steel,, even
if added in insignificantly small quantitios. By comparing the
Card 2/4

S/129/62/00'0/002/06~/014
Influence of .... E073/2335
rates of oxidation of low-carbon steels alloyed with various
elements It was found that-Ti, Co, Al and Si-'~slowad down
appreciably the speed of oxidation. .,V',.Cu,'Cr and Ni slowei
down the oxidation process to.a lesser extent. Mi. brought'~about
a slight increase in the speed of.ox1dation of low-carbon steel.
The,surface oxide films.of the oxided specimens were subjected.
to electron-diffrabtion investigation (carried.out~by il
G.D. Susloparov and I.Ye. Bolotov). For.this puSpose specimens
were subjected to oxidation in. a furnace at 860 C for 30 sec
and then immediately dropped into cold water'for freezing tl~e
thus-formed oxides. It was found that the external layer of,
the oxide film consisted of magnetite.; this layer did not
contain alloying elements.'-The here given data.explain the
improvement in quality of enamel coatings of Ti-containing
steels, as well as the improvement in quality obtained by
treating low-carbon steels with solutions contalining'Ni and Co
prior to enamelling.
[Abstracter's note: this is a slightly abridged translation'.1
Card,3/4

ACCESSION NR: AR4015697
SOURCE: RZh. Xhimiya, Abs. 23MI64
AUTHORs Zhukov&#-Ti-P-4A$~K01Mog0Tov1 Va L84, ovetlovs VI, As; SMiTtWVj He B*
TITLE: Investigation of the mechanical durability'aM thekt:10'al OtAbility of 'a
and
glass coatings on the inner surface of steel pipes
-259
CITED SOURCE: Tr. Urallskogo n.,ij in,ta cherno met.9 v., 2,'. 19630' 248
TOPIC TAGS: enamel, glass, enamel coating, glass coating*-$ !steel pipe, pipe lining
ABSTRACT: It was established that with a decrease in the ~oefficLent of thermal
expansion of enamels and glass which are utilized In the coating of the inner:sur,
face of steel pipes, the mechanical durability and thermal stability of the cbat-
ings significantly increase. Addition of Fe oxides (up to 1014) to prime enamel
and the use of frittered ground glass, the properties of which are close to those
of the glass coatings, as the prime coating also have a favorable effect on the
properties of'the enamel and glass coatings studied* A method is developed for cj
~caluulating the stresses which appear in the coating under. the influence of for
which deform the pipe.. Authors' summary
Cord 1/1 DATE ACQ: '09Jan64 SUB' CODE HT MiCL., 00

Ell 197/"!ail
TH 7- Smirnov, Zhulcov-P, V. P. Oveatinni,co-rq, V. I.
T Lffect of docarbonivition of a staiDI. ourfiwe on thip stabililqr
of axi ortariel coatiziC,,
PERIODICA I-,. 1KhWY6Lt 4, iN~3, 4.40v bs4act
41,1146 (Tr.- Ve'alikaeo n.-i. iti-ta ahern. matillov, %#., 1, A961,
2-11 - 219
TEXT: The authors study tha factors that influenon tho adhesiveness of
an enamel coating on stGol. The optimum adhosiventiss (if the ena.134~ls '-')n
the metal in obtained at ,,.Ln orldation rat(:, of Lhe sitf-0), in It-r corres.-
pending to an increase ir, QreiMmt )f 5 - 7 mg/C=2 :;IA~r 10 .111-1 ~tt 860 - goo 0 C.
Alloying of low-ciLrbon steel with meta13 iihich rediwe i.lim oxidation ra te
to an optimum valua improves the adhaui7enessi of t1he ~?mtriielf% or, the ridital.
~In analogoun effect is achieved by the atrong roducezr!i alumintm ard
silicon. The adhesivenoms of the ennnels decrema-f-ti T;.O) increfts~n,,r --trbon
contant of the iiteel. ~'IlcytnF, Df tht-1 steel trith thorie metals t hat rjr--
,,ioro chron-ium)
- stable carbides than tron c~Lrbidp ti taniwa
C ax d 112

PEE,
F
00 04
all
_SPf ot of -:,deo
e arbbidzs,
resul ts ina better
14 M, i t-, - - It 1~ iI i -M V "-, -ortriespog U td'
- COMPlet e
ej
C -W-ffost rbadily r rmea: carbides of chote
0
metals. Removal of grease in the upper layers of the steel 'nereames
the adhesiveness of the enamels on tile steel baze. ~It Abvtrac.er's noto
Complete translation.]

9/03,2/6i/027/00i/909/037
S% -B.0.10054
AUTHORS: ZhU -1.1 and Smirnov, N.~ S.
Ovahinnikova, V.
TITLE: Determination OfAhe Coh Iesion of Enamel Coats to Met' 18
PERIODICAL: Zavodskaya' lab oratoriya,, 1961j Val- 27, No~' i, pp. 43-~45
TEXT: A new method of determining the cohesion of enqmel coats to~m'etals
has been developed. A simple attachment to the IT (P-." Tj) App aratu aa
used to determine the area.of free metal~S'urface formed inl:the destrUction
of the enamel by the punchV by measuring the amperag*e. The area is~
calculated from the equation:
QQI
V, - IR.
where Q electrolyte resistivityt q thickness of the eiamel layerin,
cm, I - amperage in a, V -terminal voltage,of the transf ormer in V~
R - resistance of the external circuit in ohms. Three typqs.of specimens
were examined. The first and secona typ .es consisted of cold- and hot-rolled
steel which had subsequently been enameled. The third type consistedtof
cold-rolled steel with acidproof enamel coat. Maximum error of the method
Card 1/2

ROZANOVA N. S. JZHUXOVA, To A
Affoot of enervation of the solsen on hemoodosis itt Une unrrowi,

15-1957-3-2627
Tra0slation from: Referativnyy zhurnal, Geologlya, 1957, Nr 3,.
P 12 (USSR~-
AUTHOR: Zhukova, Ye. A.

TITLE: The Albian Rocks in the Pitnyakska7a Group of Uplifts
(Ob allbskikh otlozheniyakh Pitnya",' uppy podn'atiy)
DY 9r
PERIODICAL: UzSSR fanlar akad. doklad-lari, Dokl,. AN UzSISR, 1956,
Nr 5. pp 7-9
ABSTRACT: Drill-hole data in the Sultan-Sandzhar and,Tyuya-A1u*yun-
regions'have been used to*subdivide t1he Lower Cretaceous
deposits. The beds, starting at the base,,,are light I
green sandstones, dolomitest siltstobes, Marls, pebble
conglomerates grading into cobble conglomerates and; in
the upper part, greenish-gray silty,61ays With fossil
plants. T he proposed age is Aptian-Neocomian. The's e
beds lie on variegated' Jurats-1-c deposits,' which ar'e~
separated from them by ajayer of pebble conglomerate
I at a de"pth of 477 to 500 m. Above the Aptian-Neocomian.
Card'1/3 bedd',there occurs a layer of fossiliferous Albian rocks

15_1957~3-2627
a Albian Rocks in the Pitnyaksk~
h ya Group of Uplifts (cont.
T
(180 to 250 m). These rocks are divided into three horizons,'
The lower consists of fine and medium-grained micaceous sands
and sandstones with poorly preserved pelecypods,: The middle
is dark gray sandy siltstones and silty clays with thin layers
of silty.sandstones, in which carbonized pl&nt remains occur.~
In the clays there occur pelecypods (Exogyra.arduennensis d'Orb.
var. zeravsehanica Mazaf. and Pholadomya favrinu:Agass
rim-
numerous forami ers (Proteonina herborTlanL (Chapman),-MM'
mina sp,, Discorbis vescus Bykova, D. aktagi Bykbva I Glomosp ra
gaultin Berthelin var. confusa zas5elova, Imodiscus Dlahus
Furssenko, Heterostomella alizade Djaff., UReramminoides~ op.
and Rotaiiatina asiatica Bykova),, and ostrao, ods (Protocyth6re-
rugosa Mandelstam, Protocythero)eteron concentricum (Reuss), and
Fo- P
cy-therella inclinata Mandelstam). Me upper rizon consists of
slitstones with. thin layers of fine-grained 'sandstone,. which
mains'. In the silts't6nes there~~occ'ur
contain carbonized plant re
poorly preserved pelecypods (Nucula,pectinata Sow.'and Corbula
ex gr. gaultina Piet and Comple-R-e7-aM roraminifers (ArGodiscus
lanus Furssenko, Gaudryina oblonga Zaspelova, Dorotnia fill-
Card

...... ... . .
The Albian Rocks in the Pitnyaksl:A Group of Uplifts (Cont.)
'YM
lormi9 (Berth.), and Discorbis vescus Bykov a). ~The lithoXogy of
the Albian deposits i ates that the beds: aro,,approximately
the same age as the rocks in Priunguzye and Ka;vakum. The group
of Albian poleoypods points to connections with~tfte marine ba-
sins of the European part of the USSR and with other parts of
Europe. The group of foraminifers suppo.-ts this relationship
and also indicates a connection with a marine basin in the Buk-
harskbyaregion.
Card 3/3

TOKIN, Boris Petrovich; PETROVICHEVA, O.L., red.; ZHUKOVA, Te.G.0
tekhn. red.
(Theoretical biology and the works of E.Bauer] Teoretichs-
skaia bf~logiia i tvorchestva.E.S.Sauera. Lehingrad, Izd-vo
Leningr. imivi 1963. 161 p. (MIU 16:8)
(BAUERw ERWINi 1890-1942) (BIOLOGY)

GOLIDMAN, A ON.,, kand.khimicheakiIkh nauks ZAYTSEV, A-104 0S';YW.Vp G.IO;
LkM1MANCHUK) LOS. 0-'L13BYANITSKIY,, I.Ya.., kand.1~khimic'h6skikh nauk;
PRE0BRAZ1fE1aKIY, V.A.; FURMAN, MOS., dolctor,khimicheAikh nauk*
PrinimaU uchastiyld-. ZHADIN, B.V.j VESELICHAKOVA., T.L.; SEDOVAJ, S.M.;
TRUBNIKCVA, V.I.; KUPIN' M.I.;~ZRKRA'-YAOI-q.
Preparation of adipio acid in a Continuous pilot xuAte
-323-3
Khim.prom. no.5. 27 My 162 i (MIR& 15.7)
(Adipic Acid)

. 1. 11 1 1 11 ! 11 ~ I,- I .~ - I - .. .1 -
-------
-- - ---

- V ; ! - '. wl, "--
. I I I ! I . lill il 1 ~
- -- - -- .- - - -------

I

IVANOVSKAYA, T.Te.,.MEOU. Ye.l. (Moskwu)
Congenital diseases of the excretory apparatus of the pancreast
[with su=ax7 In Inglidje Arkhepat* 20 U048$55-64 158 (MIRA11119)
1; ~ Is prozekt=7 (nauchM7 rukovodItelO - deyotritellmy chlazi
ANN SSSR prof. N.A. Skvortsov) Gorcdsko7 klinldhes]Wy detskoy bolinitsy
Noel (glavnn vrach - saslyzhenW vrach RSFSR Yelv.-Prokhoravich);
(SYSTIC FDR6SIS OF PANCRIAS, case repo:rts.'
congene. (Rus))
(PANCMSO abnorm;
hypoplaola# case, reports (Ituo)),

80V/51-4-6-0/24~
AUTHORs
Investigation of Intermolecular lateracti in Solations of;,
Organic Nitriles, Using Infrared Spectroaco~l~ Methods
(Issledovaniye m*zbmolekulyarnYkh vzaimodeystviy. Y mstvorakh
organicheskikh nitrilov Metodami. infrakrasnoy ispaktroskopli),
PERIOUIG&L i Optilm i Spektroakopi7a, 1958, Vol IV, Nr 6, pp 760-757 kUSSR
ABSTRACT: The author studied'organic nitx1jes. The a*:nubataInces possess high
dipole moment localized at the M grcup.; The 'atom of nitvop~i'p
bound+ by three valence bonds With carbon kas two eleotrons.at the
2S-leval which can be given to an acceptor, ttaLi forming four
equivalent valencies. For the3e two reasons strong Interactions
between nitrile molecules ean be assumed* ~ It -vas reported. that~' with
decrease of concentration
of acetanitrile:(CH W)'in volventa o:P the
benzene or OG14 type molecular polarization of the solution;; Incre&ffes
This is explained by assuming that the complexex present In, the
pare substance compensate the dipole moment of oach mole=19 entering
pure substance, but on solutics these c=~lex-Ds: are broken tip and
Ca rd 1/4 consequently the dipole moment Increases.. CH~,S= was dissol
yed Ins
.
I" Mal

SOV/51-4-6-0/24;
Investigation of Intermolecular Interactions in Solutions of' Dr&anic Nitriles
Us~ng Infrared Spectroscopic Methods p.
CG14,,GO&~GHG13 (03000- G41802,i(G2H5)jM- Acetonitrilia was
used In this inve;tigation because bratiolf'.4, of a' 11 groups
(GEN, G--G, OH3) of this molecule are simplit and tl"ir ONO:6itVA
bands lie in convenient portions of the spe*ltmz.~ For ccMpar4mi the
.author also studied the absorption band of the OUN group of
acrylonitrile (02113GN) which differs from acotoal-trile, by eftipling
of the GM- and G--G bonds. It vas found that vn~ diasolutAoxi on.
acetonitrile in 001' (Figs 1, 2), 06E and in other solvents th*~~
4; 6
intensity of vibration bands of ~ the GM groups decreazea'.
with decrease of solution concentration. It is ituggestad that thim
docreass is due to destruction of molecular: oompl4w4s which le,4at~; In
~xie acetonitrile. Based on this assumption, it $eini-qUantitstiro
calculation is.made of the degree of associ&tion of ~acetonitrilo
molecules at various solution.concentrations-'For pare aceteatrile
association Is of the order of .706 7Wn acetonitrile is dislialv64
in chloroform (Fig 3) a gradual displacement, of tlie:G&S bemd tomrds
higher frequencies, vithokAt a chango in lntensityf Is observed.
The C--G band of acatonitrile in chloroform ex.M.blim a diticontinuous
Card 2/4
M. r. VIM M

--------- -
SOV/51-4-6-6/24
Investigation of Intermolecular Interactiona in Solutions of Organic Nitrilea,
Uoing Infrared Spectroscopic Methods.
change of the absorption frequency ondllAi6a (Fig 4). lt~ is
suggested that association bet.woon acetonitrilo molecules Is
replaced by association between acatoaLtrile ani chloroform.
The C-_N group absorption is not affected vhen acatonitrile is, in
acetone (Fig 5). On the other hand the eff act of dioxane on a,cet o-
nitrile (Fig 6) results in a strong lowering of intensity. -Then* .
observations are, explained by pointing out that molecules of acetone
interact more strongly with one another than vd-bh.acetonitrilis.
Behaviour of acrylonitrile, in'the same six'slolvonts is very similar
to behaviour of acetonitrile. From the spectroscopic2data obtained
in this paperthe author suggests a model for intermolecular interaction
of acetonitrile molecules with one ~ another. ~ ~ This mad e1 (shown on.p-757)
assumes an interaction between S of one molecale v:i+,h I of another
molecule and conversely. The subject of this paper was suggested by
V.M. Chulanova kiy. The -work vas carried out us ing Arecord Ing
spectrophotometer 193-6 -with UF and NaG1 prisms. ; Precision of
-------A.- -.-- 4 A C - 1-1 -3 -~ A.- 17 _30%d A'-- &

AU MOR i Zhukova, Ye.L.
TITLB Investigation of.Intermolecular. Interaction',in 3o,Ultions of:
Organic Nitriles by the 11at-hods of infrarad,'Spec~ras copy
(Issledovanlye mozhmo1eUulyarnykh vzaimodeyhtviy v rastvora!di
organichas kikh nitrilov ineto4oa infrah-aano~ apoktroak.0pii)
FSHODIVAL: Optiks, i Spektros kopiya, 1953, Vol 5, Ur 3,: pp 276-275 (USSR)
BS MGT; The present paper deals with tho intmwola 'lar lyII d IIn a lut
M1 n v. a ions
of acotonitrile (CH501) in hydraryl-containing solvents: H20,
CH30H, GivjHo, and the following carboxylia~acils4 0013GOOH-P
GHzClCOOH, CH:,,GOM, HOOCK, M,3(CH2)4.(;OM. ~Tho Lw:Aoaltrilo; mol4cula
is sufficiently simple for them study of behtivioar of all the
of that molecule whan it is Pla cod in solu.tion - Acetoni-brile raacts
with sub~ta-nces which contain tho hydroxyl: Frmzp,- this 7as I the reason
for the choice of the solventa used by tb6 proser4t author. In thwe
solvents mixed 010--solvont =aplexoz aro~formod. A' recording
110-6 spectrcmetar vith UF and VaCl nrisia.3 vas uisad - The error iin
+ .5 ~a-l and 15-17% in measurements
detannination of frequen,--y 7jaB . 0
of intensity. . On solution of acatonltrilo In all the s olvonts used
Gard 1/3 new bands appear which are displaced with respect to tho absorption

invaat-igaUon of Intaraolocular Intaraction in BoiAioas of Organic 31itri :l6s by
t-ho 1:511h.~qla of Infrared Spectroscopy
''hands of pare GR30 torarda higftar froquono:le (Fig1a). The
position of tho now.band doeu not depend on the solution conceatralvion,
but Its intensity increases with decraaso oft-the concoatration.
This iuddicatois that acotonitrile molecules are bcrAind to GH304
molecules Fig lb shows the d O.p3nd once, of 1,tha inuaeral absorption,
coefficient of the complex nov band on concontration. This. aopndonco
is a straight line in the particular case of. tho Solution in OH3Q4.
Fig 2 shoris the departure fraA IbLoult's law for taie solution of
acatonitrile in mothyl alcohol. On solutiom of acotonitrila in acids a
new clear band is observed which Is displaced +tovkirds hlGhar, fro(luencies
vith respect -".o the position of absorption bands of pure acatonitrile
(Fig 3a) - The d apead once of the into-ral a ba orption coof f Went J of
n'.,
the coaplex band on the coace -a~ftoa lsahc4u im,Fie;,3b. This figure
shows that at low, concentrat-ions tho absorption is' incre is ad. due to the
a 'he deo dbnca
presenca of acetonitrile-acid complexes. Fig 6 a1v s t an
of the integral absorption coefficient of tho acadciutod band, (curve 1
a
n,
d of the spoa~ral displacanan' (carve 2) 01% -.110 -kt%~l or the
Card 2/3 ionization cons4"-nt of acids. 'Cho poiats I-V reprouaut solutions in
..... .... ............ .....

inves,Itigration of Intemolecular in taraction, irt Solutions of OroAtlic Vitril,)l by
the LoVacfls 'of Infrared SpactroacopY
&P 1; 0
GJ150H, CH3001i, Gjj2GlCOOH, G%GCCHand H0001,1-ro ocz1v 1y. Pig 5 1givou
the absorption band of E;roup of acetonitril,3 dissolved in
G~150H. Fig 6 shows tha absorption band of;1VIta 0-0 Orcrap t~f
CH3M on solution in acatonitrilei. 'the axp)Oaental reaults obtained
-nation of iiiixed ra-aplaxoj GH3CR -solv-33'
by ti-Le author suggests that inT for,
the carbon atom of the. 0 L, IT group of acetoultrilB, is joined:-t~o the
oxy-oa atoa of tho hydroxyl group of the sol-irent, vh1lo the riltrogan
atom of acatonitrile is joined to the hydrorqn a-bom of the solvent. The
author thanks V.M. Chulanovskiy aW his co-wo'rlcars for their advice.
There are 6 figures and 5 rekarel-Aces, 4: of which are GOVJOt.4
univy
'fitat
'=0GLkT1O1T: Leningradskiy gouudarstvenny;~~ zicneakly lnstitu~ (Lonin-radI BtaU'
University, Physics Inatitatel
SUB11ITZED: Septamber 13, 1957
-ard 3/3
1. Cyanide solutions--Spectra 2. Cyanide solutions--Molecular
structure i 3. Molecular association 4. Infrared spec-troscopy-..;
Applications

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