SCIENTIFIC ABSTRACT ZHUZE, T.P. - ZHUZE, V.P.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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24-12-19/24 Compressed hydrocarbon gases as solvents of oil and oil residues. Part 11. 0 ethylene at 105 0. The ability of these gases.to dissolve petroleum products increases in the following sequence: ethylene propane, propyleue mixture of propane with propylene; only products with a higher quantity of paraffin-naphthene hydrocarbons are dissolved more easily.by propane than by propylene. There are 3 figures, 5 tables and 1 Slavic reference'. SUBMITTED: May 3, 1957. AVAILABLE: Library of Congress. Card 2/2 lo, - t~ -. -2/-= AUTHORS: Safronova, T.P. and Zhuzes T.1~4 165-12. -7/12 TITLE: An Investi tion of the Sol~bility,*Iof Gases In Crude Petroleum ils at"Increase d Ptessures and Temperatures. (Izuoheniye rastvorimosti gaz6v v neftyalch.pri. povyshennylch davleniyakh i te4eraturakh). PERIODICAL: ',Thimiya-i T6khnalo iya Topliv I masels 1958,,Nri2. pp. 41 - 46.-(USSRI. ABSTRACT: The solubIlitly of gases in petrr)leum is influenced by~ the pressure, temperature and~properties of the!gas, and the'nature of.crude petroleum oils. The'solubility of gases (methane., propaAep ethylefie, 002 and nitrogen) in RomasWkinsk and Tuymazlnslci~etc~ crudes at,pressures, 300,- 350 atms. and.temperatures of 20, 50,,and'10000)', was investigated and the apparatus for this is shown in Fig.10- -Methane and propane,i7ere selected awthey are-the components of natural'gasp~and also to define the Inter-relationship between them solubility of a gas and Its molecular weight., Nitrogen and 002 are~also components In natural gasi eth7lenb Is not contained in natural gas, but was tested to clarify the solu- bility of unsaturated hydrocarbons. Pare ethylene, which 3ontained no Impurities, ~,was used. Table 1 give's Card 1/3 the properties of the di&erent types of crudes which, 65-2-7/12 An Investigation of the-Solubility of Gases in Crude -Petroleum Oils at Increased Pressures and Temperatures. were tested., ~Figs.' 2 5 show results obtained, in the form of graphs., The quant Iilty of nitrogen,di6solved in the crude petroleum oils increases when the pressure. is increased, and at the same time the coefficient of solubility of nitrogen decreases. 4n increase in the temperature gives higher solubility of nitrogen* The solubility of methane In orude.petroleum oils is con- siderabI7 higher than that of nitrogen at the same temperature and under-the same:pressure conditionse Table 2 gives comparative data for solubility ooegficients of nitrogeh,.methane, and other gilses-at 100 0. Propane shows better solubility than methane# Gurves of the interdependence of the* 'solubility coeffic- ient of propane and the pressure are.~oharaoterlstio and show a sharp maximum at pressure interval of 50 - 75 atms. The solubility of.ethylene,i *n petroleum is considerably higher than that ofmothane,but not as high as that of propahe.- At pressures between 50'.- 100 atms..th~ solubility of propane increases rapidly with Card 2/3 pressure; at 50 atms (2000) and 100 atms (50 and 1,0000) 6.5-2-7/12 An Investigation of the Solubility of Gases in Crude'.Petroleum Oils at Increased--Pressures and-1emperatureso the form of isotherms changes. 002 isvery soluble in crude petrolew oils; it is more.~soluble than methane. but not so scluble as ethyleneand propane. In all cases the solubility coefficient's for the various types of orude.petroleum oils are given. Th6re are 2 Tables and 5 Figures, 12 References.* 8 Russian and 4 English. ASSOCIXTION: Petroleum Institute AS USSR. (Institut nefti AN SSSR). A,VAIIABLE.- Library of Congress. Card 3/3 SOV/24-58-11-ri3/42 AUTHORS: Zhhuz_e_,__~~afronova, T. P. and Yushkevich, G. 11. zm~os ~ow) TITLE: Extraction of Ozokeri'e from Ozokerite'"Ores~by Means~of' Compressed Gases (Ekstraktsiya ozoker;ita iz ozokeritovykh rud szhatymi gazami) PERIODICAL: Izvestiya Akademii Nauk SSSR, Otdelleni~e_Tekhnicheskikh Nauk', 1958, Nr1l, pp 123-125 (USSR) ABSTRACT: The here described method, developed at the Oil Institute, Ac.Sc. USSR, is based on the ability of a number of hydrocarbon gases to dissolve satisfactorily hydrocarbons if these gases are compressed to some pressure at a temperature exceeding their critical~temperature. :It i's also known that the dissolving ability of gas, increases.'at a conbtant temperature with increasing pressure; _~ 'at higher pressures the gases begin to disso.Lve not only hydrocarbons but also asphalt-resin com]~ounds. The test- rig on which the extraction experiments were carried out consisted of a.column, a s .eparator, alreceiver and a: compressor. The colilmn consisted of a 1500.mm lon6v 45 mm. inner dia. tube scheduled to withstand 150 atmi. Cardl/4 The colimn was fitted with external electric heatinE.,and SOV/24-158-11-33/42 Extraction of Ozokerite from OZokerite Ores b- Means of Compressed Gases inside it the temperature was measured.by means of a 'by means o 4" ' ~ 3-point thermocouple and the pressure, a pressure gauge. The column was joined-bymeans of':a throttling.' valve with a separator, a 0.5~1_itre ve~ssel,'rated fo 'r a. pressure of 70 atm and fitted with external electric... : heating. The separator was joined by means of a vslve~to the receiver. The:operation was as.follovis: at th*bottom of the column a few layersof the substance wa 'd to s place serve as a filter and ore was loaded into th~ collimn, Following that, the column was heated to 100,JC , then, gas,,%ras passed through it which was prelim-1-narily compressed to:the selected extraction pressure. After~passing through:the ore, the gas dissolved the hydrocarbons contained in the, ore and passing through the filter which 1. retained the ore dust, it flowed through a throttling valvelinto the separ&tor' where the pressure was reduced to 40-50 atm.. The tempera- ture in the separator was Raintuained~dt the' same level as in the column, i.e. at 100 C. * Since at. these pressures the Card2/4 gas no longer acts as a solving agent, the~products, dissolvid in it sepai keri aw ,ate out (i e. ozo -to r material), SQV/24-58-11-33/42 Extraction of Ozokerite from Ozokerite Ores by Means of Compressed Gases the regenerated gas is drawn off by the compressor,en-d is additionally compressed to theinitial pressure and is then again directed into.the~coliim-n for further~or.e extraction. Thus, the extraction process was effected with a continuous circulation of the gaseous solvent. On . accumulation of the raw ozokerite in the separator it was transferred into the receiver where it wasmaintain- ed at atmos,Dheric pressure by means of a'throttling vaive. Thereby, gas separated out from the raw ozokerite vi 'hich became dissolved in it in the separator in a quantity., corresponding to the respective temperature and pressure; this gas was removed into a gas containe:~. The characteristic of the ores which were subjected to such extraction are entered in Table:l. 1 The:ore was~charged in the collimn in the as-delivered state Ity-ithout additional breaking up or drying, it consisted'.of a~,mixture of pulverised particles with bits of~valriousi dimensions. between,2 and 10 mm. The extraction of the~ozokerite~- from the ores was eff6ated by meanslof propane-propylene fractions the composition of which~Is entered in,Table 2 Card3/4 I which also contains 1r)formation on the conditions of the I IN 86439 q 5/181160/002/011/026/042 77 0 6 00 I'> 412) B006/B656 /0 AUTHORS: Sergeyeva, T met and: ~helykh, Ae I TITLE: Electrical Properties of the In 2Te D.ef e.o' .-;type, Semiconduc-' tor PERIODICAL: Fizika vVerdogo, tela, 196o, vol. 2, NoA.- 11 :pp. 2656-2071 TEXT: The authors give a report or the results obtsi,ned b~k :in.vestigat,ions of the electrical properties (conductivity4 thermo-emft, Hall effect) of ihe Te semiconductor which has a high concentration of lattice vacan 813LI, I n,, Nntrinsic" deiaots - cationio vacancies) and uause &.disturbance of the periodicity and a distortion of the'potentiail rield of ~ tho~: crystal. They greatly affect the motion and scattering~ of carriersland p~hononB. The'--- -type seinic6nductor Ii ni ;i he authors chose In Te because this defeot es i 2 middle of the isoelectronic series AgI - CdTe - InSb a-Sn1whoae elelotri- of tWS cal and thermal properties are known, and also because the structure;. i compound has already been investigated and some ind cations an to the ar- rangemoant of cationic vacancies are available; thirdly, data on electr io al Card 1/ 7 86439 Electrical Properties of the In Te Defect-type S/181 60/Co~/311/026/642 2 3 'Boo6 B056 Semiconductor r; hile- photoconductivity as woll as optioal:absorption a e available w there are no data on galvanomagnetic, thermoelectrical-and~':thermal proper_~ ties. In Te was synthesized from the elementary components in quartz: 2 3 ampoules by fusion at 700-750OC- As shown by.A. 1. Zaslavski, and V.iM. .y Sergeyeva, this compound exists in the a'- and P-phasea, the latter being 0 stable above 550 C. Some properties of these two forms are.given in T 1. Fig. I shows the temperature dependence of the electrical conduotiTity, of-stoichiometric a-In Te In the range of -70 - +400.C there is intrinsic conductivity; the inclination of the straight line logo . f (1/T) does': not;: change up to melting temperature (66 OC).- Pig. 2 shows the: irreversible 7 0, - I I - II C in change in electrioal conductivity by beating up to more than 490-500 r (1) or by continuous evacu ti (2). Fig- 3 shows'the change in elec-4 ai a on tribal cunductivity in the P-* a transition. The HalIeffect was measured ion With direct current and in a constant magne Itic field,using~a compensat method. Fig. 4 shows thi Hall coefficient R within the range of intrinsic conductivity as a function of temperature; the diagram also contains th~!! mobility as r. function of temperature. Fig- 5 shows analogous diagrams for other specimens vith.different degrees of orientation. Also Fig.'6 Card 2/ 7 86439 Electrical Properties of the In Te Defect-typ6 B/181/60/002/011/026/P42 3 Semiconductor B006/BO56 shows a and R as temperature functions of stoichiometric In' Be within'; 2 1 3 7- t the range of intrinsic conductivity, the degree of ori *entation risiagjn the Sequence 3, 20 1. Also the thermo-emf, a - W/T),'is a~s traight :'line (Fig. 7). The numerical values obtained for the.paramet ere 0of hig4-purity In Be are given in Table 2. The forbidden band width at 0 K.was deteimin~d 2 3 to be 1.12+0.05 ev. Furtheri the impurity conductivity was!investigated. It could bT shown that Bi impurities induce n-typej and iodine p-type* conductivity, whereas other atoms (Mg, Cd, Cul Rg, Sbt' Sn I bi i ~ Si, aild Go in-quantities of 1 at% cause no impurity conductivity.' Fig*: 0 shown logcr - f(I/T) for In Be with 1 at% Sb, Cu, Hg, and Sn (pa:~allel stra~ig~ht' 2 3 lines). Fig. 9 shows thelemperature dependence of o,.R, and u n on n-types in Be and Fig. 10 shows the same-for p-type In Be !Furthermore detail; 2 2 3 of chemical binding are discussed (Scheme, Fig. 11).:The refractive 1n'*dex, n, (measured by M. I. Kornfelld) was,found to be 3-4.�bi3 f or: X = 2.2: V,_ and the dielectric constant, E , was equal to 16. The results of the'se investigations are discussed in detail, especially with respect to mobility. ..On account of the carrier scattering cationic vacancies, the mobility, Card 3/7 86439 Electrical Properties,of the In2Te 3 Defeat-type S/181/60/002/011/W/0421- Semiconductor 'BO06/BO56 III IV mut in other semiconductors of the group A B, ~;'see table) is oh. 2 smaller than in neighboring isoelobtronia.binary compounds'of perfeo.t; ivi detemperature ~ra go. tructure. The carrier mobility is constant within a~ n. whtah is explained by the predominance of scattering by elec.trically. neutral cationic vacancies. V. A. Petrusevich, I. Z.: Fisher, ~V. N. Bogovolov, and A. F. Ioffe are mentioned. Ye. L. Shtrum.' is thanked for chemical di-S.- oussions, and ff. F. Shvartsenau for help in measuremehis. There are 11 figures, 3 tables, and 27 references; 9 Soviet, 9 German, 4 US, 1 Dutch-, and 3 Japanese. ASSOCIATION: Institut poluprovodnikov AN SSSR Leningrad (institute of Semiconductors of the ASIUSSR', Leningrad), SUBMITTED: July 15, 1960 Card 4/7 86439 181 /60/00~/Oi 02 3006/BC56~ i : Ta6Ax a 3 q _: I VI A . 11 vi ~Ijt vt v A 8 IYA'V- 7 - A.E a ,CuBr znSe.- Ca CAM , X.- 2-9 . .8 2 .95 juj 1-50 1 O 78 9anoerb. 5.08 -542 1 ' 563 l 5.65 ' "Y Vt. cm A s 16 7 01 ~ , E.O. . . . . . . cq ZnTv. : 2 a2Te., (3nsb 3. Ca- sn 6 o' . 0.81 - 6-08 5.87 6.09 go, cX2/jI cex: 13 r.: : 11 5 5000 - sit Ajrj CdT. nSb 0. a'.A 2.8 &47 1-80 '' 1.12 0. 08 H 081fo"', - 6.46 6.14 6.44 .46' 0 21 a* ccK So 16 1600 13 ' 17- 0 7 .15- 0 80000 34600- t; Card .7 1W I 1 9 it v 11 w Is low fVDAVAIN b J? 1) 10 w a #I ip a A A a L-J" t,.x..JL 4 'A-R-J. 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OIW a" I M - led b Obs" of thq stmoms dwo, #a O"th 41W d#Cay"WAS In hiltmou-MV4510410 F n4W op beitbrardwadMIX 'oa)WA*AtwR m4 N=tw Leuvp( Ilk bugno I whW with 4(dkke. coot.) - 10 wkj ipsi-mbilme.urviok Uchi,i 's Am-om.- &4"s - 10-0 ow.. aw wkk a a Ift I"*, Imotarm" J41 (A - I,W. 't dicW4144 I. Abw a t4lo . - full wt. J'9 4PMMIIAWA gftkigy 0 6% Wool. a". true at 0 kwW 4, , h With A SUVOtOr 4. U; toolt, 0 - Ndt to - AV./#wt,. *hav &f. awl p an meuwW W In fornow doo- to VdAbliShru W1014 ft dUMMOR Of M 1AW'. 9-codw S& b"Pubes. &W a It taloom, kow da, coW. Salloorto tot.0*04"m I HO COMI. IN Ad S" WSOAMS. Ike 1, to IN$ ~~41 rob" of lit'W" Into oft. Ofterm:+30, impubm 01 a h*..Stb auk *ammos hr 4% faitw; f$ M no tMelik" e= up. mituo cwtolmmids to IN I &V .b"W"m on a bw the Pak iapphum-Wout-044-107 trip. of ;;~- i tin At :* r ad &I -C (a 1. AO- Ado, Wc=s 14~r" bba". Foor In Okpolujim - vdth :4o- - 4oAlb - coulac to r Allo. 101010"All wo 96114 smed &at Istemb-of OQMI losock is 4e V. am to O'w faw" Ilemp. accowhis to 0 101' wwas " dim 2 1 Aw~lWvrs. U. ~ .-Ndho mom out. JS - 0.43 ev.- in U 'm- dou"wo &w =0113001 -wof V., F. "d & M. RYTHM. JW. IM-U. cf. C.A. mommommots to mom So -the temp. b am~:=x"t (')J* cv.; at 3U*.:r Ow I CwO of a - 3 X 10-4 okv-ocm.- vcrpub~ ddkrmt walplas Packs x I - wd A 10 vskUtWo at pbm of orkdmWic Coo at I ait Into me. '.e WIN);, imemsm orkh the tantp. qxpautliallyt I a In rolav 1. IPA Yuktitiosyrith the tomp. IWA ...... as Is 1 tww for hr theontw6wis. 1:11 mur- a. 4#, ywits MAP CIA rke MI dwacw a P1040100MAIWIky, V. P. Zhu" i" M .14 grad Phyi.-Tecls. 1wirr-Vamly Abw.,V*,A, ,and. of C040 241-4(1951).-Tht COUCIL14- 0-t tlw PW- is of an impurity character, established by mvious C22d., ark (iW. 60. WOW; Zkmr, FAsw Tterd. Fit. 18.1321(111M). 19. MOO); 20, IMIM); C-A- 41- 4MU; ". 28429) MW Mfirtned by o4savations Of 0113" anal Una (C.A. IV. W979) lbat. in the Vidaltir of $Jav fink of the abmorptk-,~ bond at 0.63 0, the PWOVD"d- bwrftw$- with'the Content of elms 0, Involves tM diMcWIY thati in thk range. tbe abtarlztjou is atueb too higA to be at-. tributed w the very small nu. of decho" an the k-upwity 11"Coor k-wels. This difikwltY It MCIVOIJ. wilbout C I of the previously awatmad Sane scheme. by abwukmtwn fro= the inapurily attributing the tMM90011 Of tlactnMA kvd M to th, cq"dWtJCM t"c, &K ta direct actw a the light quanta on the fralmety attlaw, Wt to &KOWI&M sbsmvdqn of light by the main crystal kuke. Tk cidtoo - thu odulml t.4 eftliff MMUM OF raset - looked jmwly. center " trunindt, its caM97. th- WOS an EIKUM from the impurity level to the cooductiols YOM; this constitum a son of "Mitan eoaWw of tho 2W kind." At low tC= the Comm. of electrons I* M h StUall. and t' brw dDly all the excitom will matubbar. -d the twC quantum yield will be truall, At a suffocintlY, Irmp,. be no. at electrilot, to M will lie high. and\ iletcall all I i~4tons'iiiu ilia in OA10to1w Oi kile Ailig - in M, WU a Masi quantuas ykid. - U the tw~ P of earitatis l"locid in UMC Val, Per Mait *7 1, lk*W to OK Hoist tivargr bf ilbmarbtll, .4 . on". *6CM the radar tip".S46 kke 'exC404: Yield. With V, and T, dc"xh;ff. MP., lh~, "leatt life, of the ncitoo unill i callbiiM e of The 2nd kind not$ a rr"hInation. and at w.coom of looked I -vurhr atom (eketrou In Af~ V -~ velocity'll( Ow excil . I - C3 as aectia" for tw collision b" IIMV: 1-~! t4will lit? in recorabilnropla slat &&-Jmt of the 2ad Mac# aw s~gajkzjlt il r - +~ ~r,*), and I be: am P, of excit*4 V&CV(j;4 in fliflaggle"ratis Into, the cotcludion awe is h a), Wbere 8 -,1 (rlr* ar dually #L From the kinetic w-b'kmA# + M thi kveb Ware mevigabir, anti the pbatocomi. laoru"r bit! I jkL.. t inn tho otmrnl quantiala yinid ii found it - (W2*14 + 4), wbM a - Own, of jk I"t. haki- At low tetirp... xqCs. and 0 - ("1s)a ~j 1141,, *L"V%XL &I h1kh tfgnk%~, W" is can C;Q 1. 0 tvpj - coust. This ~ temp. de- p!adeft" of A hi Ill wCeamt witb previous obicrvm~n.. live Uwe "lechaniun Of p1loloc'M4. way buki: in alwi 111didt Crystals. and the Internal pbotockc. e" my be contingent an collisims of the 2nd kind bctwtm Cuitiml. and lmlmd F "nten. It W not ablevtd lit ardittuy tcatias, la, tbot it-lion of Ik, kbiorplian, bqt stmtM o"car an "uttantout Illuminathin with the %mvt l"t ktb of The IN. 11M I IZ~ '. 14, 4 !i I p;v , t',7 IT Z-valk-InIcarrs, V. P. ZT~ -.;!,I --.rc mvic- Iilmd m mc, alethixt Li sug- Vs~_j fQr smic !tr-vut,~b aw ~w;lilkr with m - d;4ut:lm*e ihrrjtt ;A VASQ. 77 io 1: 7 t!_: HIM USSF,,Physics Elentrical properties FD-3103 Card 1/1 Pub. 153 2/24 Author DIU20. V. P.~ Regel. A. R. Title Electrical properties of &Uoys in the systexn.Ni.re-NiTe2 Periodical Zhur. tekh. fiz-, 25, No6 (june), 1955, 9781983 Abatract The authors.investigat* electrical conducti-vity, :Lts, teme,-ra ure t coefficient thermoelectromotive force, and temperature.conduc- tivity of the system of alloys with composition froin NiTe to,riTeo. They note that the problvm of clarifying theirelation between~ electrical propertien of chemical compounds and tlieir.crystallo- chemical characteristics is presently a pressing one. They a6- knowledge helpful discussions with Academician A. F..Ijoffe, arid help of scientific associates V. M. Sergeyev and Ye. L. Shturm and laboratory assistant V. M. Medvedev. Nixie references. Institution Submitted February li 1955 .............. . .. 9(6) PHASE I BOOK LXPLOITA,TION- SOV12506 Zhuzes Vladimir.,Panteloymonovioh ---------- Poluprovodnikqvyye materialy;, elementy po,luprovodniki, I(Sexii- conductor Materials, Elemonts of Semiconductors) Leningrixd, Leningradskiy dom nauchno-tekhnicheakoy propagandy, 1957,~ 101 p. (Series: Obshchestvo p0 rasprostraneniyu politiches- kikh i nauchn)rkh znaniy RSFSR, Soriya "Poluprovodniki," vyp. 17) 15,000 copies prlnted.~ Sponsoring,Agenciest Akademiya nauk SSSR,.' -Institut polupro,..; vodnikov, and Leningrad. Dom nauohno-t~khnicheskby propagandy. Tech. Ed.: D. P. Freger; Editorial Board': A. F. Ioffexi,Ac~dem- ician (Chief Ed.); M. S. Sominskiy,, Candidate of,Ph~61cal and Mathematical Sciences (Deputy Chief Ed.:'); Yu. P. Mas'Iak6vets,-. Doctor of Physical and Mathematical Sciences; 0. A.!Smolenskiy, Doctor of Physical and Mathematical Sciences. S. S.'Shalyt,, Doctor of Physical and Mathematical Sciences;, A. R. ~egellp Candidate of Physical and Mathematioal'Sciehoess- V:; K. Sub- ashiyev,, Candidate of Physical and Mathematical Sciences,- K. A. Shagurin, Engineer; and Sh. D. Achkinadze, Engineer. Card 1/4 ._-fifififijjffi~111 III MY Semiconductor Materials; (Cont.) SOV/25,06 PURPOSE: This book is intended for engineers and technologists who have occasion to use semiconductor materials. COVMAGE: The book is 17th in a series of A published,by Lenin- gradskiy Dom nauchno-teknicheBkoy propag andy (Leningrad House of- Scientific and Technical Propaganda) aind'the In's titut: Poluprovod.-.. rlikov AN SSSR (Semiconductor Institute, Aoadem~ of Scienceso USSR) undex~ the_general title, Poluprovodniki.(Semiconductors).: It is also the revised and supplemented second:edition of an:iBsue en- titled Poluprovodniki i ikh tekhnicheskoye primeneniye (Semicon- ductori and Their Technical Application)i This book deals with the semiconductor properties of elementsand:'gives bao1c data on their structural, eleatrioal, themoelectrioal., galvanomag- netio, and optical properties. No personalities are mentioned. 'there are 104 references: 44 Soviet, 56 English, 1 Swedish and 3 Geman. TABLE OF CONTENTS: Int'roduction .3 Card 2/4 11R1 11111J jj 1111 11,11 ~Semiconductor Materials; (cont.) SOV/25o6 :Ch. I. Chemical Bond in.Semiconductors 5: Ch* U. Elements of the III-B Subgroup 10 1. Boron 10, Ch.-III. Elements of the IV-B Subgroup 12' 1. -Diamond 14 2. Silicon 16. 3. -_,Germanium 37- 4. Germanium-silicon alloys 65 5. -Gray tin 67 6. 'Silicon carbide 70_ Ch. IV. Elements of the V-B Subgroup 75 1. Phosphorus .75 2. Arsenic 77~ Ch.,V. Elements of the VI-B Subgroup 78 1. Selenium 81 2. Tellurium 87 ~Card 3/4 r U 1. 11111 HII 11 1 1111 111111 If IV I I III &EIIIII. III III I I III I I I I III I I I II I'l Lit I I Iug IF. I I Ws I H -I I till IM I NI I IM I] Ul Is I ITIME I Iff 11 Ifil I 1141 Z 6 11 tat lip llummml -A Lu"-,a,-,lu y -ULM IL 9 d, F TT I ;lIMIllql-I;ll;p d th Llk;i, -j 111111 1. 1 1 1 Ohl' HIPM-1111 '4LIlp i 4E. li~ I I .Off til''ll'Ma, 3 i~d NIP H art, V I PA C.Ao will q*o: fill Rill,v; ol, toll)( 'all ''kV 5. i I-Kill it 1F P- 44 It, 04i III lilt it, All. : I . . p. it j. ifi 114 AUNI :F! Li -fill slows IV di i'tr.1,11111 fir, Sim EHIE fill -ii 111V HIT 11F111HIMM111111 M Rill HVI U -USSR-/-PHYSICS GARD-1-/-2__PA --1992- 'AUTHOR hzE'V.P.',PIKUS,G.E., SOROKIN,O.V. PITLE On the Problem of the Influence exercised,,by an Exterior Electro- static Field on the Velocity-of Surface Recombination in Germanium. PERIODICAL iurn.teohn.fis, 27, faso.1, 23-.29 (1957) Issued; -2 / 1957 Experimental method and results: The velocity of surfs~ce recombination was measured by the methods developed.by O-V.SOROKIN, Zurn.techn.fis.26,11:0556)._ On this occasion the effective diffusion lengths L were experimentally-, do- a termined, and from the values found in this way the velocities of surface.re- combination were computed. Investigatione-were carried:out with rectangular plates made of monoorystalline u- and p-germanium. The'upper boundary BurfaG6 of the sample served forthe mounting of metal probea:~phosphorus bronze for n-gerctanium and tungsten for p-ge=anium. On the upper boundary surface of the sample a rectilinear.stripe of - o,005 cm widthq which was vertical to ths, longitudinal axis of the sample, was illuminated. A mica plate which was coated with silver on one side and had a thickness of from 0,0022 - 0,0030 cm was pressed or pasted on to the lower boundary surface. An elec,tric voltage of up .to 6 kV was applied to this silver coating. The block, :scheme of the measuring, device is shown in form of a drawing. I diWam illustrates the typical curve which is obtained on,the screen of the ozoillograph by bringing #robe into contact with the sample. When applying an exterior electric field to the sample the curve partly changed its:shapep p 1 1111 jil 10111, BII fasc.1, 23 CARD 2 2 PA -~1992 Z,urn. o 2, -29 (1957) apparently because of various transition processes in the radiotechnical, do- irice. After less than 10 see the curve again assumed its previous shape which indicates that the velocity s 2 of surface recombination on the lower' boundary surface is constant. This constance of 02 was,observed in connection with all methods of working the surfaoe. A -ftrther diag:ram shows typical ourves for A p - f (z), where - A p is the zoi~.neatration 'of the oh airge carriers which are not in equilibrium. Conolusions: At steadied conditions the velocity of the surface recombination not change u 'der the effect'.ol' 1 of the current carriers in germanium does n an exterior electrostatic field. This is true up to concentrations of. 1013 cm-2 of the current carriers induced on the germanium surf aoo.; Con-I duotivity of the sample on this occasion remaiz~v practically: Unchanged.: The induced current carriers essentially fill 'the l,urface levels:? ~their dinsity 13/0M2. Is considerably more than 10 The outer levels play nolilmportant. part in surface recombination which takes place on the interior levels. Xn4emi-, conductors there apparently are several interior levels'wat different heights. INSTITUTION: Institute for Semiconductors of the Academy of Science in the USSR9 LENINGRAD. XUTHOR 'VITLE ZHUZEJ V*PO. PjKUSj G.Ye. SOROKIN, O.V. 57--6,3/36 The Determination of the Surfaoe Recombination'Rate by 116ains of a. Change of Semicanductorf Resistance in the '%g,,etic Fieldi, (11etod izmer-niya skorosti poverkhnostnoy rek=1b'.natsii po ism6n- eniyu, soprotirleniyq~ pol-aprovodnika v mag.,,itnoa pole _Ruiiain) PERIODICAL Zhurnal Tekh.,Fiz.,1957,Vol 27,,Nr 6, PP 1167-1173 OJ -5 104 A3STRLCT A now method for the measurement of the valocitylofeurfade re- combination is described. It is based on the dependence o'f the resistance of a semiconductor sample in a~;magnptic field on the 'recombination velocity on its surfaces. Tho results of,experi'Pen- tal chekings of this method are given. They agree well w1ith theo- Tetical predictions; i.e. they fully prove the theoretical final conclusions mentioned in the work of one of the author's (d.u. Pikus, T,M6,Vol 26ppages 22-50) with regard to, the depei'494*oe of the seaiconductor-resietance in'the magnetic field on'the.1ve- locities of the surftee-recombinations,the voltage and the fre- quency of the electric field, as well as~on the voltage-bf the magnetic field. The method presented can be used for the~~investi- gation of the influence of an exterior electrostatic field and of the outer medium on the velocity of surface recombination6 At pre- sent such experiments are carried out and will be published Is- ter An various works. (1 table, 6 illustrations and 3 Slavic referencea). AUTHORS: ZjMzej V. P.# Taidillkovskiy -1. M., SO-V/57-581 4/37 Bartnitskayat S. TITLE: Thermomagnetic Phenomena~ in Silver Telluride (Termomagnitnyye , yavleniya v telluride seiebra) PERY60DICAL:. Zhurnal tekhnicheskoy fi'ziki, 1958, Nr 8, pp. 1646 -i650t (USSR). ABSTRACT: This is a study of the Nernst-Ettinghauenlieffect, of'the; thermo e.m.ffp of the electric oondu6tstvity and of the, Hall-(Kholl) effect in Ag Teand AgTe in the.temperatu Ie interval 1:~ ~'F- - 0 of 12o-6oo K. The measuring methods are described in;referience 5. The nature of the variations of the temperature d6pandence of d and R agrees with observations made by, Appel(Ref 8). Diagrams showing the temperature dependence of the dimensionless~ fields of the tranav f th 1 Nernst- ol e 6ngitudinal .Vrae an ' ~ r- Ettinghausen effect and I respeciivelyp and the.te mpe k ature coefficient a of the thermo e.m.f. are given. Tlie~ 'of ~ at temper- negative sign and the great absolute V alue Card 1/4 , , y atures below 2000K oan be explained by the.effect of.phon6nL Thermomagnetic Phenomena in Silver Tellurid* :SOV/57-58-8-4/37 drag C'.~-Thls. indicates a.oonsiderabl~ 'affect exerted x by the.pbonon'drat upon the 16njitudi6al Nirnst-,Et-cinghausen effect at low tempe Iratures. In the ra6ge of 200-4200k: > 0. about as T 295 and ~ence.als y va ries 0 u it is assura~)d that n 0 that is to saythat a carrier soattlerirle on acoustic low-frequency Oscillation's corresponding to a covalent type of binding is prevalent. The:relation I a-JT-295 can be explained by a multiple phonan:scattering of the carriers. Around 4200K the field decreases marke dly and changes its sign. At a further temperature-rise of up to T -`4900K it first increases again, depreasing su*b- sequently and passing through a minimum at-T::Z::b 5500K. The jump-like variation of A occurs at:a temperature near the fly phase transition temperature. The inversion*of the signin the longitudinal Iternst-Ettinghausen: Ieffect. in the point;of phase transition undoubtedly indicatead change in the type of binding. The negative zign of above.4.200K indicates Card 2/4 that a-Ag2Te is a semiconluotor with,a pre4ailing ion Ibinding Thermomagnetio Phenomena in Silver Telluride SGV/57-58_46~_4/3,7 the Debye temperature,of'which is less'than-420"K. The.~ as not conv: no n theory of Howarth-Sondheimer (Ref 15) 7 f-gly substantiated bj experimenta.-According to the opinion~ofl the authors,it is unsuited for the computatidn.of the. parameters of semiconductors. The section of-the thermo eLm.f. versus temperature curv,e~shows a peculiar course in the range of, high temperature. a is p Iositive at T'64 3950K,~ reaches ~ maximum 0 at 490 K (320pV/degree). At a further.rise.of temperature,' it decreases a little. This behaviour;of a(T) can.be,explained by the.assumption of.a superposition of the eiectron~thermo e.m.f. by a relatively~great thermo e.m.f.:ca~used,by the mobiles silver ions(Ludwig-Soret.-effect) at high temperaturei. The- experimental 'results obtained from AgTe are given in short. The electric conductivity and the Rall-(Khoill) corstant of AgTe vary continuously, whereas R decreases with a rise temperature above 2500K,and d inareas'se, in! the same Cemperature. z range. Contrary to evidence obtained by Appel-I inver.searit sign. The modification of the sign in the Hall-offeot, at':a tempera:ture rise suggests a transition into the range of:, mixed conductivity. The repeated inversion of the sign(from, Card 3/4 minus to plus) at 4550K is apparently determined by:the Ludwig-' q. i ThermnmptD-nAtin PhAnnMATIA in Ailvar MalliiriAa qnV )1;7-9;.q-A;-A /97 ~AUTHORS: Zhuze, V. P.,,Kontorovaq 2. A. ~Oyl/ 157-58-,87,2o~3 TITLE., Correlation of Strength.and of Beat do'hductivity of Non Metallic Crystals (0 korrelataii M02U6 tveridostlyu i tieplop'rovod-: nostlyu nemetallicheskikh kristallov) PERIODICAL; Zhurnal tekhnicheskoy fizikip 1958, Ni 8, P.P. 1727 -;1733~(USSR , ABSTRiOT: This paper presents- a5cbmparison of th: properties of_.Ahe~ group of ternary-semiconduct'ar compounds with the general; formula ABX f and with a chalkopyrite;~!:structure exhibiting the properties of such non-metallic crystal s. Such.crystals ' are produced by'the elem 'ents~of the'IV-B column of th6 periodic, s,.ratem and by the binary compounds of an AIII: By type's imhich e ahibit the same covalent binding anCthe same,lattice st!ructure. A comparison of the data bearing on the strength and,the hriat conduotivity of these three groups,shows that the micro- sbrength~ffl and the heat ~oonductivityr of these substahce's are correlated in a definite! way.' k deoreases as H. On thin other hind, H showe a definite decrease with therincrease of interatomic distancei Such a correlation between H a4dw~ Card 1/2 however, is also found in the halide: compounds of alk~ali:metalB.l -T .............. ... .... Correlation of Z`;trength and of the Heat conduct ivit 5 1,50V/57- 8-~64o/37 of,Non-Metallic Crystals although theee'-dompounds'exhibit a differe t 'type of ~icheml; Cal n binding, mainly of an ionic kind and a_ different crys'~tal lattice (N&Cl structure). The considerations Goncernin~g this correlation advanced are:by no meana:intend6d to be-& consistent thojory.to these phenomena* The transition fr omi, li,;ht to heavier elements or Compounde~~ in the homolo&Lts se'.ries in question (inorease'of 11) is' accomp~'ani'ed by a 1; reduction of the lattice'energy U and an increase of~ bhe 0 ' I lattice constant r o As specified,by formula (8) for.tT~the, hent conductivity gust de 'crease systematically in accolrdantle with the experiment, Since$ however, this tiansition is~alillo accompanied by a reduction.of the coefficient a of the~~quaiii- elt.stic binding, which determines H a~definite correlation'. between R and K must exist# There are ~ figures, 2 tables?,: and 6 referenceat 5 of which are Soviet. ASSOCIATION: Institut poluprovodnikov AN SSS11R lening-rad (Institutel~of. Semiconductorw,AS USSR.Leningrad) SUBMITTED: Dec(aber 12, 1957 Card 2/2 Q z. E.) AUTHORS; Zhuze, V. P., Sergeyeva, V. M., Shtrum, Ye. L. -2-3/32 57 -tITM. New.-Semic3nducting Compounds (Movkye poluprovodnik~ovyye soyedineniya~`. Ni ~2 pp: 2 3-23F6 (USSR)~%, PERIODICAL: Zhurnal Takhnicheskoy Fiziki, 1958, Vol. 28, 3 ABSTRACT.* In the irrrestieation of binary semiconducting-compounds with the': general stoichiomotric formula ABX2 the authors syntheti6ally~produced 4. new. t*om-- I VIII VI Pounds of the,follo,~ing composition-,A B where A is eith~ri.Culor J, asw xpec". Ag., B Fo and X either Se or Te. All fourcompounds a.. to 1)6~e ted, are semiconductors. The analysis of the natu~r'e of the chemicil lirv= ndicates the -6 of ~ 3 kage in these compounds i possibili 7' asp _hybrie4zation (mixture of valence states)~of the electron-state's in.the.,-rystal. . i-r6m' the schemo given here is to be see ,n that'the~chemical linkageIin!comp ounds of this t3Te probably takes place by means of electrons being in,the sta- 3. and AgFeTe were pro- te of sp -hybridization. CuFeSe2, CuFaTe2, AgFeS02 2 duced by e.irect melting of the components as well a& ft-om. corresponding binary compounds (which were previously produced~by a direct synthesis of the coriponents), The radiographic analysis (performad by R. A; Zvinchuk ;A5 in the Latoratory for Radiography in the Institu~e' for~Semiconductors.!: Card 1)4t-, USSR)proved that the samples were monophase. The".east samples of,ftFeSe 2 ilium New Semiconducting Compounds. 57_2_3/32!~ and AgFel?e2 were more closely examined. The photographs were taken in thet case of YeX -radiation. The roentgenograms were indicated under.thb asa~ sumption of a tetrao-onal-lattice symmetry. The great: deviation of the -1 eal rorithe chalcopyrite-structure, c/a-valves from the quantity (c/.v' 2), id as well,as-the occurrence of.indice.s.of the tyke h +'k. +. 1 - 2n +~ 3-.'(for- bidden for the spacezaroup Dia ' I 42d) exclud6s: the; possibility to ~ucri.w ~j- 2d be to Uese compounds the fof the chalcopyrite-structure (to which. type- the analogue of these compounds AgFeS,,belongs). The volume relation of the 6lerientary cells in AgFeSe and AgFeTeq (dementary cells),agrees with 2 the relation of their molecular veis;hts and the' relation of the third,po-~ Wer of f;he radii of Se" and Te4-. This can dnjiy irdicate a similarity 'with the of the ohemical linkagre and an exact aGree-ment'of the structurOs conceptLLons from the theory of the densest packine.'The mel',Ing tempera- tures T,neiti, the microstrength H in ke/ma, the electric conductivit in' ohm cm the Hall constant:R in cm3/C and' the ihermo-eleotromotive force a in 66 V/OC with regard to Vb for all compounds, were determin6d. For several compounds the activation-energy of the 6urrent-cairiers, in eV was determined according to the.dependence of,the B611 constant on tempe- Car' rature. It is shorn that the compounds (which,'were investigated here) A New Semiconducting Conpounds. 57-2-3/32 III V like, those of the A ..B type in the case of,ja deviation of their~'comw position from the stoichiometry do not change the type of conductivity. The elei-,tric properties of the AgFeTe -compound'-werei. more close4 investi-,i~' 2 gated hiiree In samples with a current_aarrier_~oncen'tration of.the order of magaltude loll ce3 the mobility of the alec'tron,*~As higher than 2000 cm4/V.s1.-c. The dilatometric analysis of AgFeTe'~at 146-4oOC shows: an 3.i o thermal jump of the volume Yfnich indicates the%ccurrenoe of a first-orm der phaie transition, The modification of the4olume in;the phase ti- ans in tion~ Vie -modification of the volume in the phase transition.is very high and amomits. to O.,5501o. The activation-energy'lof the current.-carriers, also uniergues i,-;reat changes,at;the-point of transitiont Until, the tran- sition-bemperature 0.,28 eVO afterwards VA s58:iV11 Lt the.authorls request P. V. Gulltyayev measured the course.of temperature of the ther-. mal - and AgFe rys conductivity in-the AgFeTe2 Se2"samPlesr' with large c tals. The coefficient of thermal conductivity in both compounds at room tempe- rature approaches OoOO7 cal/emodegre .asseco There are 5 figures, 2 tables, and 9 reference7s, 5,df which are Slavic. ASSOCIATION: Instittte for Semiconductors AS USSR. LenincTad (Institut poluprovodnikov AIN SSSR. Leninarad). C BOV/57-28-10 1/40 -24(6). AUTHORSt Zhuze V. P., Sergeyeva, V. M. Shtrumi,t! Ye. L., TITLE: Sem1conductor CompoundaTtth:thi e n 6riai 1,,';r' mlu~'Ia. ABX 2 ~(P b ey Forklul6y.-OX o1uprovodnikcvyye~,so edibeniya s 9 s o 2 PERIODICALt Zhurnel tekhnicheskoy f iziki, Val g$,,Nr 1,1,01 p~ 209 3 -2168, (USSR) ABSTRACT: :Ternary compounds with the general formula ABX2 ;crystallize.in a chalkopyrite struicture. ~,They were foa'nd for..the.fir t t ime: synthetized by H. Hahn (Kfian) and coworkers Ili 1953 (Ref~l)- f the- '3 _e' In kBX compounds a,formation o hyb'r'id~~stat a and'the 2 q'R tetrahedrio dia-tribution*of atoms corr pond'in*g:;to this type of compound is according to the scheme.describing the formation of chemical compounds.only possible iWi'such.'Oase's, where in-the ip jof.- the compound one of the~elemsnta of the third gr',ot* odio! to system, or-iron,,represents the trivalent elem.en.VB. Antimony- and bismuth are incapablelof entering,such &~Oompound.~ Punda- mental facts, a description of the method, and of thelaynthesis are presented. Investieations. carried: oat in the X-ray labor&- tory IPAN by.R. A. Zvinchak showed that the samples of, the Card 1/4 8emiconductor Com,ounds With the General Formula, ABX SOV/ 7-~28-10-IiO 5 2~: I III VI gro-ap of A B ~ X compounds are all of'tmonophase com o~itfon 2. P,- p and a chalkopyrite structure. The compounds CuTlTe and AgTlTe were for the first,time produced;eynthetica.~.ly;, The 2 I Yin V1 'd - 1.9'o of X-ray analysis showed that ~A B X a, mpoundB are a,, 2 monophase nature. Cast samples of*AgFeSe and-AgPeTe r 2 2~we e: examined more closely-with the help of~FeK radiation.: The CoR. AIBV X VI compoundat CuSbSe', CuMiSe , AgSbSej, AgSbTe 'AgBiSe 2 2 2 2. -.2 and AgBiTe also proved to be of a moqophas,e.nature.1ith6ut 2 exoeption the compounds investigated were found~to be!eemi.- cor.ductors. In compounds with the~'ele mejnts oif~,the.V. #6up~ t he ,in the cht-mical bond is very likely not realiZed by electrons.! hy~;.-rid state sp3j but by electrons, th6.:gtate of,which,can~be. expressed by a pure p-func'tion. Anoctahedron near-ran8elorder' of the atoms is cheract eristic of su6h a band, as p-bonds" lie in three directions orthogunal to dach other. The~crystal. structure of the compounds of the V. group confirms the fact Card 2/4 that the tetrahedron distribution of atoms distinctivia:O'~ s'p3 Semiconductor'Compounds With the General Formula ABX~,; SOVb7-28,--10-1/40 bond.s is not found in these.compounds.'W-ith this group~only~ the octahedron distribution is realized~ The,compounds,pr'oduced-~ synthetically are subject to the gefieral~ rules which, Mike it poscibleto separate substances with int.rinsiol,semicondu~ctioln from such with a metall io condtiotivity.,The deoision between. theve two alternatives is b.ased upon the conception of;th6 pos-. sib.f.lity of the formation of covalent bonds.,The,A B x 2 Pom- pounds satisfy the octet rule by Kossel~,(Kossell) and the rule by Hooser. (Mozer) and.Pearson .(Pirson). (Ref 19)i Finally the' participation oftthe d-electrons of-th.e!iron~contained'in the I Viii VI "d A B ~ x2 comp6u,fids in the formation of thechemical bond An in .he semiconductivity is' investigated:4 The~absen!~e of metallic conductivity gives iise to, the asaiimpt.i6fi that the d-electrbne of -.he atoms of the transition'metal a're.existing in ci~so'reet states in these compounds andthat they'tform'a completely 00- cupied d-'zone. It may be assumed that the gre~at distances Ve- tween the atoms of the transition metal~in the crystal are: hindering the formation of an incomplet6ly occupied zone. This Card 3/4 problem will be thesubject of another, paper. A. F. lo ff e, gillf U 1511 Wil IMINIIIIIII 1111011141 OR till' lilt 11 IIIH I III 111111111141 IUN![illBiji!illilll!IPIIIIIIII[Illlnntlh,liaI 11111 11 lilt I III M1.13,91111 -,.kand.fiziko-matemat.nauk,- GUSMIKOVA, YO.I., bibliograf; BUBROVA, K.L. I bibliograf; ARON, G.M., red.izd-va; ~BOCHEVXR, V#T*q tekhnorede .[Scientific works on semiconductor electro nic in struments (detectors and transistors); bibliogimphy 1943-19551 Nauchns.is. literatnra po poluprovodnikovym elektron"m~prihiram (datekto'ry i timmisiory); bibliografiia 1945-1955. M6sk-wa, Izd-vo Akad. naul: SSSR, 1959. 326 p. (MIRA 12:8) 1. lOmdemiy& _uauk SSSR. Inetitut poluprovadnikov*.~ (Bibliography-Trandstors) (Bibliograpby--Hlectronic instraments)[ (Bibliography"Somiconduoto're) - - - - - - - I 11gowilr[IIIII] I i "M Hit I M It I; III I 11r, III I, . ......... ... 67395 -240), e4i(&~ ;SOV/ 61-1 9-'7A AUTHORSs Zhuzo. V. P Pikus, 0. Ye., Sorokin, 0.4. ' ~TITLFt to~the Application of the Ma netoeiiiation Sffect Invc)tigation of the Surfsoe of Semiconductors PMIONCAL: Fizillca tverdogo tela' 1959,! vol. I't r 9, j! pp 1, 20 N (bSQR) ABSTRACTs J The-,authors,used-the''i4eth kof surfs. a rb comb iriA tic 0 a . measurement by mea no ~ of the resistance Aingelof 'a semt condactor. in the magnetic field to investigate th:e energy surface structure .of german .ium. This investigation is rei.~ ported here in all.details. The method applied to measure the surface recombination rate is new and.was,~introduced!'by' the authors themselves. A.description thereof~iq n4h give references 4 and 5. The aim of the investigation under're- view was that of demonstrating the-appii*atioh of this method, with two samples of n- and p-geraanium being Used for th'a 'pur- pope. Figure I shows.the block diagram of the. us~ed setup,. The msthod is based on the application of a formula. describing ge of a t n, -.la e the relation between the resistance chan hi n . Card 1/3 sample in the magnotic'field H and,the:recombination rates a 67395 Application of the MagnetostAotion if f ect! to the SOV/j 17/31 Investigation of thit Surface of Semiconductors 1 2 2'A, 2 on their opposite faces sA Q R/Q 0 V a +8 2 where d is the sample thickness thei v'oltali" of !the main:~; 9 frequency th t f vhich, is. incident , upon e.Anveatiga ed part o the samplei is the resistivity without,. magnetic . field:'., A.Ax 0 an 6/1r, (1+b)(14yb)pn d given by A ~ih re;~ W7 (n+p)(n+pbT :and'p deh.ot e the equilibrium.conoentrations:of electrons band ho'es, /An ah d ,tu . p their drift mobility,, aen;~nd.Ap~ their Hall,.mobility,:and; p 1 the length.of the investigated part of the sample. It4;ie now described how it is.possible, by means of the instriiiient + II . I ,I to obtain direct osoillograme reprodUo lnig. the dependence of:- 1. 2 the quantity -on! the:applied Ieldol~ Figures 9~5*show such osaillograms,for the two.samples iniestigatedo whose, Card 2/3 chaxacterietics, are given.i The next section discusses the IK 67395 Ap lication of the 11agnetostriction Effect: to the :;:.130V/181- -9-176 Investigation of the Surfaoe of Semiconductors interpretation of, measuring results in deAailj~ the resulis are given in the form of diagrams, and the nume~rical valuesi are.jiven in two tables. The, method.described:"is very ex- pedient for a quick and fairly accurate determination of:the' fiela-bound change 6f a'., k.i V. Rzhanov,. 1. A.']Arkhipova', and V. N. Biduly -(ReU12)-i'applied this.method to:investigate the modulation of a through a 'n outer eleo tri6 field. Their re- , sult;30 however', did not fit those by the"authdrs in two... points. This is discussed in the final'part of the..paper.~ There are,10.figures, 2 tables, and-15 references-, 8 of which are 3oviet. A350CIATIONt Institut poluprovodnikov AN SSSR Lening'~d (I of~ ra ~stiiute _ 3emi-oonduotdre of the AS USSR$ Leningrad) SUBMITTED: Febr-aary 16,_ 195~ _Card 3/3-- I titillf JU &ICA ii lim Ifflefin III Mull! 11VIIIIIII 11 HUM III r-1011111 1111111111111 IN 11411101 111111111111111M ;or w6h 4sfdl'ct m t im-c 6r 41. lug 91 IILVI MIN =,a= I IMP! -- - ------ - ---- - ------- -------- ------ - Ace-WSION uRt APW13500 S/0181/641006/002/00*435 --yatkovag, To. Del Zhuze, V Sorgeyevaj': K I AUTHORSt Dev Golubkov, A V. I Smirnov, Is As tITLEs The thermal conductivity of Sm, P., and their simpl.echalcbgen compIounde- SOURCit Fizika tv'rdogo, t a elay v. 6. no.:2. 1964., 00-W TOPIC, TAGS: thermaA conductivity, samarium,, praseodymiumli'tcha cgpn,, O'r7stal 1~ttice conductivit-,r,, rare earth ABSTRACT t This pap-L~ stems from a lack of thermal-conductivity information:on rare-earth compounda and their compounds that have been recently studied in considerable detail for other propertlos, The Compounds studied (PrS$*PrSej Met and SmS) were synthooized. from the~constitfxent elements by~~tho w4hod described in Rare Earth Resesa-ch. (p. 135,p 223., Ed. by H. V. Kleber ii. Y.$' 1963.). anct the: thermal conductivity was measured on the "All setup of Ye,~Do~Dev~qtkovaj A V. Petrov, 1. A. Smirncm, and B. Ya. Moyzhes (FTTj 2p 7.38.# 1960) * Measurements on Sm. Pr, and the indi,cated compounds were made in the ten"rature, inberval; 80-460K. Card 1/2 V- ~j k 1ACC. NRi --A 10,38 c Fla To Zh -V Sha oval A :,:ORG:~.-.~ Institutei-:Of a w dkov'r emii nauk Ss R) till I- i~ TITLE: i~- Superconductt~rit~ ..o J'~ f ~Scm' MUrjjal.~ *3erimentallno-- -te6retic :A !~i ini r .0. 13ril. w: lie oz n YC J304 171?219 c~o'r 6 -t e '11311! a olc~ ommet, *'r C tic c a.* mag~-.tic field _point, authdrs- th&t- a C ith -ABSTMGT: -The. -show- 6M4 I ILL: T04'Ji:-&i9q r6dndubt6l Al ar t~ the 11 r, Ir it props IA33e.j and TA354j~ if rece,htly-.- Yhey -also show that--,t -e-- gvVer-condtidtir) r S1 t6iji e. s- u-b- -s' t a- n- c ede-pends b Ahe tecbhology~' it )r atlo~ bib, of: B" I , onnpit pid ~r. i! c eviation from` th6 -std 6 --C.0rivos on c -0t -th 0 t 4 Atfil um~-te bik 'A was isynthesized f~roni ~the'- componei~ s.~,b E e Ri a --proc;!,~~c --cle-isexibed In'-- o e 'ardehe "'Mye ma erialy, Inorganic! Materials 2~ 116 1~ Pt i:'Oz te~te li-,oreb;sed-1"i-om:previolli)3.y,~fusdd-:*AtiatI I "bt ~~nzd bt er Vr~v -peratur tvo - omples ah -e 6.1,'.~Tlwco ea- F. -.tfiL'-- de-stru,~.tibn- of erc6n 'a itli6ej---b ectively. Mgrielk--ic memswemeuts,h&ve:.sh6;wn t6t at: 1.1' he: ne =R- 1/2 _j!j I III At I I J I 13111 V I II fir I It -i I Oki blqo In 1110 1 IF! 1,9311 kit ir :,i 7r+- 17 0 1 it t T`~ -i,7 rip 6 cO PUTAS-0, -T~ACC-Iffi Ty" T AMOH: 2aluzeil NO: hWq ill 71 iji- 091.:~ institutd, -of,,,, 78emicondu+drs' SSSR' I Le~lzkraki~ ut A 1~ SE lift) Aw FTTM+ Rall: effei~; 6rysiaj: 41 do _Su z Avordogo tela;~ VO, JIM. Ai_:! j, 6~9 IV M. ?IC -TAGS CO _;_COMP .cryptai sfq Ule b 1j I ~~cii i~Ti~~-_`-~1_,!~."!` ity, -_ Neel'te#erab ire,-~ carrier ~Ae4i*.. crjatvAi de i t3r, Ch a tal$.-~ Hall, mobility. w Iill 71 j J, ft o i-ele co6du ty.~~i I -T To chech . an- the - mec~is'm- f! ctric -that exped~ _4: on. i i biL I whose.6 MU6~:J.~: MvLals, ondfictivIty Is- Uan-, e -Wil ~authoxo measur BLPch son-,model' the U-i ~ COO: Wqtle cry,oteilp e4 t6i ietb-- it t, cc) d -gi rpoi al a J~q s--v e-;In- W, orm: 0 0 w 1~ wit i6d fi duiAivity w wet ib fi T_ of~23,900 e~-Hall effe t -'cov1d*,be! WISUrld In' ~t t I IN _ie~perat! Me 0 t 0' ine thdlfeellom I be--.- I (JO/T -1 2--~X) Abovi f -A iT AI 4::: 11h 9 !11 J t L 2289846.': f: q, f7kil :_jJ66666 o a- b s- t strong incridasi, cai-rier dens ftl~ iiciviiii- ''t in&', empem- nduct vity, .1 Z hd:'it W Lne-, q c r I th~ stal- ii ;;p, e a ~a ei, _1~ ductor. )e v -The domintMig-Aefects: iiLIA'e'-lat ii t t --- Iductivity et i9d 4hich ifi: a - 0 C OM ry~p O~Ve Ca j I :'q jTh nized ii! ei -d'ata'; cAn b _-i iidci~ibed_. e. th pigly and doubly 1.9 th I-Pl"r-~of--quasi-chemical-pro~essiB~'~-,~hi,ch=leaci-,t"he, e cei~- fileiec r ers in a ionic cr7itals' mde h issum that the-! e. T- , e-.1 ption Xt - h les i.~. f: :.del)ends-on nO erlhe-.-L~mpem ure--r 0 e ith t i6r -the idenpit~.~-f~~* I*g noreases: rid O.L _.:~~m 6 Ud ..V '0, 7-7 teriperatum. at Idgl' --t- C _to emem ura.s pera urei.--.-and - ftIewhaV--"3.owexv' tb,-,n,- jr)tjj~ t d6 ------------- -A *~ ;Qf kelhom d6e not contradict theliconclusidns'ofth6 existi~ ''t 11g. heory.~:df iidrd~ A,6is C '10 th; mol The dri t -mo ilityz'of- a m ~Iure~s per, t~sjLned by the auth~ is i-Atat onal:.~medsur f - b6 '~~t erWgM'V th 10 t is C10j; t~ th in~,Co% e e- WI mob iorik.'arti_ SMI CODr mW9 OMM DV 2D/ 06, -j T T! ;i Cant.2/2 61 IJI) RDW/JD/JG 115n1-66 E',Tr W A!jft8/EWP'(-t)/ET1- c ACC NN AF603B53T SOURCE'CODS: -MVO.'81/66/008/006/1761/17TJ AUTROR: Golubkov, -DbiYi "re. P. Zhu e,, V. P. Oergaye*&~ V. M.'; Smirnw..' I, A.* ORM, Institute of Simiconductors, AN SSSR, Leninp-ad (Institut poluprovodn ikov AN SSSB TITIE: Thermal conductivity of Iantbex= and its monochal~~en!tei SOURCE: Fizika tverdogo tela.. v. 8j no. 6, 1966., IT61-1TTJL,~ TOPIC TAGS: lanthanitm,' lanthanum compound, thermal conduction, rare'earth 6etal: cryntal lattice, the3mal emf, temperature dependence, phono''n scattering., electron' scattering ABS7RACT,. This is a continuation of earlier~research by the. authors v vt~6, 430' 1964) on the thermal conductJ:vity of rare-earth metals andktheir~com*unds,~ and is devoted to a separa ...n of the'e-lectro' V pic and'lattice:covponents~:of the the~r~'con- ctivity of La., Le~Tp "MaSe and LaSY( The linthanum monoclisiccgenites veii syn, tesized from the constitutent elements by-a method described in'detail in the' gterature (Rare Research., 223- Ed. by E. V. Kleber., !NY, 1961;,A. v. Golubkow Irr aleip Neorgo mt. v. 2j, 7T., 1966) and were pressed into briquettes;at'high pressure fOllowed by annealinj ;. The measurement apparatus was . described by* the authors - ear-s Aer (M Ve 2P Mo 1*)* The theoreticaLrxpressions four thewtwo thermal-, Conduqivity -ccmonm its are derived. -mmhi'analysis of the expe Irimenta.137 measured 1i 2 ACC KR~ AP6026689 SOURCE CODE: UR/0181/66/008/008/2390/23947 - !AMHOIRI. :Bogorolov, V. X.; Zhu-- of Semiconductors, AN~SS a (Ins it v ORG: SRI) Leningra ut poluprovodnik,o J%X~ SSSR) MTLTE: 7he mechanism oE,conductivity in rutile SOURCE: Fizika, tverdo&5 tela* v. 8, no.8, 1966, 2390-2394 TOPIC TAGS: titanium crcide, rutile, Hall constant Hall effect ABSTRACT:~ ~Setslof data on the anisotrwq of electrical conductivity -constant, py Hall and piezoresistance of rutile, obtained by variolus authors, .'are analyzed as functions .of Temperature and currunt carrier concentrations.',The presently-decepted zone scheme of rutile is inadequate to explain:-zhe cggregatd of~exparlmetiql daia'ov'er a broad tem perature rango.~ If it 1z assumed that the current carrier concentration.is tempera- ture independent above 1,1000K in,the samples iniri~~igated, thd'electrical,conductivity and Hall effeat data may be described by the, equations of the mall Iradius polaron theo ry. A qualitative estivate of a ulumbor of parameters from the,~ttheoriy also yields rea- sonablo values. The authors thank M. I. Klinger and Yu. A. Firsov for valuable discus- sions. Orig. art. has:. 2 figures. SUB CODE: 20/ SUBM DATE. 13Jan66/ ORIG REF: 006/ OTH REr; 007 Card 1/1 ..... ....... . -W4 ':~J.;!~f I it I! t I: I I' F !!~!'V! U 1'_-~E~r!]Vpj A W; I '.1U.! I EN IR;",; U I 14111 1: 11*LW 4t~" i'4e" I tl I fl: 11C1 1: jill ~ft tat i!4 it tO Ell ii~ -1