SCIENTIFIC ABSTRACT ZIEBORAK, K. - ZIEGELHOEFFER

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002065110009-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 19, 2001
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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1-:ac~%ims',a, Azeatropli: -ml lyazeotropic pyste:-,,s.
IYUC. Z'ositive-negative azeotropen formed by 2, ace-tic acid,, and puraffinic
hydrocarbons. P. 7883-
C'1-71, Warsza%a, Vol 20 no. 2/3, 1955.
T r.
SO: !-,;ojjt~,j5, List of East Darsor-ean Acujaijons, (E.ZAI) Vol. 4, no. lO, Oct. 1955,
Uncl.
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ca".. the lk (151%) vitm wtmlhc~ with
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Imassible evvil with r"woetitatives of the 0"M farming npar4-
lasittent ilaubarp with the. Agent, Set*ratials by thstillation in
I-I'Acticolly imik ashitate %hen the Poixturr citations twat wrow all
totu4j" Statialitig Imussy alnutrijan wtth awk uUwc and Ltaitain
laig Aw-one at U"vamilsolue s4asota tallicil Inaly furm L-414 lei nat)
The 14-acidawfla #Awrvv%l duhns the chawlation -11 a tolittur"
..I V.1 I to'lliNk Implatore. Alta towel 6XIIIIS w1ance Illu%tr all,,
tlit' hatuallant all orady lAttgent Ast%itruIvm awl
Ipmtkj" Tlor 4.1 at luixiliff 441 1*1011, 1140.
Call;. AM 111%U4110 Altai 001110 LlWet-1*1411119
littall") III"* the clultioully at W rurmtion of 41111111,11var)
arrotrop" 4*1 Watures of nearly tangent, rectroM, The ftv.
ltvr,. Air "T.".V Of ter"Z am"i'vor" co"t"W, M011, 11,0~
an, P111wr C'l ~ tw Warr b1i Ing ticlat"" ze-14to c Militurvo of
quAlmnaly I* Irmary nearly faingrot amtknolwa am piartleall)
I,- -Jwd(~ toy ft&atima ilittillattlain , A tolit in form.
whato a tal.14" &NMI 110fittly I'AftflUlt ANUMIPIPS Willi
114111' load Of It olixtUtr of bOnw1kgam auld Mee
with the other pan, hadliti-m uf a third cullipme"t or e-en
11, "r. coMP0IMMt* h4%'Itlg I&tN* 110410tr0fliC (144ACIty Wdl Ulld I* tht'
I-mrAilan 01:4 tttwn number Id lernary tarquales'natly almilrOlwa,
OKI b it Of whwh will allows "airly, S. WMVIIICKA.

"I III, "'Ic hmm 1 111111;14111111100 1111111111411 A Wit I 1;IIMw--1. ...........
all 12,017 j hit 113 at
owtvlorIAWAl W,, VittyntnIt K, fluxteir"Arr Altall!'"Pe ~ C*mPtIrd 61
mment-RINnal-waler anti 110"Orline,
-0 RICotipille C2jeTt*kljjdojltjIWyM UtWOr,011'.11% it tfINAtRI111. AA-
nolu,%mrody I bo matmel. 1'r-einvA Chrmlesn7. No 1 0. 19A,pp.410-431.
2 Win.
The existence of the quaternary betermentrope romposed Or ben-
rr" - ethanol - water and W)octAne (2.2.4 - trilukhyl-pelli fine I
hits been demonstrnied, 7111- boiling, point Of tile hP1P.'M-tZC13;M3P1t at
one Wnimiphere 04,89,C', and the perrcritagem wrifilit ennapaillion
ns followc, bipivenp 01,5%, ethanol 17,11%, wuler 4.7~'Ccmd 1swictillid
Tbe dirn.-MIrs and the refractive Indoxes of b.)th Me liquids,
havir alto lxvn Arterminrit,

/7
541.110173 541.123,61,
dfixorak K. claiternary Arpotpipe Cinnis"Pol of
.0 am-ful-le Mrrosklidnikowym ulwarzonynt z tKOMWIM, Pill-
"Olu. Welty i pritt'nsyll che"llezur. 1,10. 1-8. 19-0.
OP 4:0. 3 t3bi.
Quaternary flarotrope comlxmW of ethanol- be n.-eiW-wat of, and
110MMI l1ristAlle has twen oblalned. It has beell chamctertzc4l bY
1WHIM temperature 64,711T and by the 1011OW1119 Pc(cf-1114" .0 'Might
r"11114t%it loft! brtl 41 tjol.1n,
(12.4, Ohnnol 1113, water 68 an ,I h,,_
in" 12 1. Composition. densities and the refractive indexes at boilii
jhr lower and the upper phases. arr rive$,, The 11creentage volume of
the lowcr phaw At ZC*C Is 17.2. which cormstmlids to 17.gs porprerk
of the 1wrCelliage Wright.,

Zd -
'tjSbo k_j.. quaternary Aseetrepr Campoird of Rriumv- hiliansil.-
litc, It it Im, rAviiiNklmlisikow,. its titAiwit-opit vt livittemi, 4,11-mlo.
Ill. Wotly I cylikIll. 1'r1rillyml (111.111k4ily. Nil, I A,: 111:10 pp, .121.
livitane tit the felloa Oil,- lierrinnintr wclpllt enivilwisit Ion, IK-.ije"e 215,
rthaiml 17.4. unter T1 mid cyclobvimir .14 0 Ond Wiling. Is
02191' Kus Ilveii W)HIllciV An mciArnple dolirrsilim vIttal 141 0.111C
wax (nund will% rcxpf*vt to ImIlItin Irtirip.,niture or mc iuw~Vvr IM111111tj
trtn.try n7rolrope retispoird of ethatiol water cycloill's'Itle.

The tr
1. T.
t. W. Chem. Research. Wsrmwl:-,
Mi., (34SM sti. walk., d no. Srr. A.- 1050. 9-12(ift
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was 172 TOIA
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h the azeatropic rAnVe Is dclined an th~ Catreme b P, lit ililts at,'-
.
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ower. t
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pban; t
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ew 17,95 wt.-% at 30' 0( the total and Cautallsoll 11.1 It the emespouding homolop which torm tangnt or umtly
tenmt ISON (i&.~ the upper and lower limits of A$'a.
11.9 11, $4.4 M. and 4.9 wt.-% IV', The u d1# 0.8m,
Pfir
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cont4fted 73
V IAW (rppyl. The forilutlod a( ternary ajecitropes of A and C
t h
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IV. The quatemary ax, was detd. a
diffetentlid ebullionleter will the -boWas terawy asto- with a lierka a
otuologs. 8, 11, 16, ett., or their Lximerv,de~
pirads upm the stuidler atoutropk lunge of A With 84
,
h B'
h
h
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i
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trope (11-M-tv) and adding Small Anits. of the bigber-boift
ternsury atootrope- detg. The bell&# and emilta- a:
w
t
s. alt
out
(
e trmary uzootrope r4i
ije UJAY
be soinewbat Luger thAn the alaller Nziary airollope rAnic
by virtue of the tirailY tangtant W)bir'; of the bbiArT system

s
ation temp.. and plotting avinA the canwa. of the usixt.
The quatemary altottoPe was sho PrePd- bY di"it- Lt. .
The fortrution of qu-stermiry altvtr;ipri 6 litnltcJ by the
'

The Isaftrolty AWM"V" watw4ftSelaw. atrotn4lic ralid"Ity of file Wiwi). 6V114,1114 (A 'A~ith 11
6~
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all 3
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form Alt0trq" Willi CaCh Othtt ARA Aith thr
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logs (9, 04, 81. tICA Within J curtain rancv, thcqUAtfftlaity
l
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nV 1XV, wo 17.0 Vol.-% or 17,14) w1A ol th# total Asro
rolse rarip inAy
w vourwhat Wrjur Min the %Mallv~t
binary lano lirvirtucof l1ratly I'lligrill iolmrbof thr IduAn
a t 20* and owtaitird I I A 1. 1.2 V. 34-111111. INAI 33.7 wt,
10 0 XI
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1
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biltus. K. Zleborith. IQ. WM-TM quid
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am. 10-28,8Y um of lit WAM Curm of an MW* ,
x4vat, A. with a wits of hortiolop. Be. . Aief
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rst-60US quaternary azootrope W(Mid he 'amill. V,
11"4y Want 1904TOPOS and their Influence an the formjs-~
doo of trimmT and quattriwy motropes and rectropm.*
VuAll ailo. of hydrtwught'llt. 11, Wl 1111)'. the lemp. vl.'~
mulpti. curve IW$ title --ttkill cuirrs1KNI-11119 III IN fix 111,014,41
U( nearly tAjjjVU( bilfaify a$CUftuIWft. W if.111-aillill JXjjjj( f(lan
Ilearly tangent lLjmrq" to newly tAllik111 Vellifillwi. A11.1
sectioti repmetifinS the dion. of the xrotrupr, ir to tite,
ternazy asmuope, 1-111MV. b. (34-85% is added irAsutitie
(Lvntg. Mostly 1WMCrk bCpt&Un Slid MUSICS). th 93- I(Xl*,
distri. will yield the quaternary ait"drolm alid thv temartr
alrutto1w. and a sonsewhat mimiLar di%in. curvc is Oil ait-I.:
dioll, 1.1 lwmilr.
Thin, there is m slmiUrity lictierris flik
tangent and newly tangent atrotlows al:d Irl'116,1K.. .41'.1
the distu. of ik complicAted poly"anixtur It ~Ystflll The i
Utowfuc rule wits deifmed: If sublitattv a (Orm nith I
put of a honuilatioluit seslet newly tangent aieutiolies and
with another newly tangent seu(f0ltirl. the itildn. ofa.'Iril or:
41h isitcotropic cumimment leutis to the fornwimi of Irtilary
or quaternary wrotrotwit. resit., uticAr Ix1il1tIg-tCnIP4.'
differ slightly fmu each other. These Wits. ultrinary itr~
quaternary azeutropes or zeotro ot be se;ki. by
Herman Skohlik

i All
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In (_.tjwc; 41jd~ 'It mwj; IL'a-thifl; tuipl. tbe
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tj ,)14 mw mi'lup-will ;.Iftl, fUll"I.-I 'ptellols, halm. mid
uni.,rd um IT 1*1-lt JmUlicrimA I cuimcm Le
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chlozul~Ltgul fi- 1 " ~Ilti Aral Lal~. al"t 2m
rcrtilimt iin 4aw 4m0fuaved I oman lv~ th-im
By %imnS I hi, chi .( I Ill mmiu~4 imt
ampual [it I I.XN-i; Ill", tw.'~'tlo 'it Owl dvoliplitt.. Ill NIX
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Zltbalak K., 7.10orakciwa M- Vosttlve-N*gaVve. tto-
W.
-,Trove Formed ~l n-11MER"Mr-tic Acid and [hrridillo. XVII
,0 etwolropie (lodatnio-uJumnlim n-helitar, - k-nas actawy -- pirl-
clyna**: XVII Ra