SCIENTIFIC ABSTRACT ARAYS, YE.A. - ARBUZOV, M.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002200210013-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

I I pjq~tj I I I I ai I II!. I q
u S!S
AE", Y S-3 , Y e . A 1 -7, T A.
"In'~erpretation System for Solving Large Proble-IS11
V sb. VoLr. T-;-of7r-rT=f-. av'o-atiz. rroveltir. (Frobl,-- of' Desi-
n
grar.m.ing and of -W01'r-s') , Tcms,~-,
1971, PP 3743 No 1, Jan '(2, Abstract. .,o 1"Tic.1(
Translation: The authors describe the "Rea6er" intcrnretaticn
sueciali--ed for solution of large problems on the BESN-I, co-.uuter. ~-he
component parts of thc Readr--r system. are: E.) a lilrary Of
ators; b) a table 04' characteristics; c) the i-m-kin- bcard; d' `-.e-
interp,retaticii progra-m- The characteristic of eech operatcr appc-arinr-
the library o--,- standard operat-
ors is comprised of: tLe cc~al n? ~-,, b e r c
the operator, the instruction for use of- the orcrator, and I-Is-descri-r-Itic,-
s I1 11
The table of characteristics contains in-forrmtion on each C.-c-rator jr 'he
11-Crary olF' uDerato-~s. The -,-crking ccard Is a s~--c--icn of ccr-
store in which the standerd cnerators are locatc,di. it is not-c-l', ',hai:
giVQII SyStUM dOo-'S 1101, C-lil"li !--!' T t'
conventional !,S-2
1/3

USS~R TJDC: 7)1
1 v
ARA
"Solution of Problems of Linear Al~gebra in the Auto-Aralitik Syste-11,
V sb. Vo-or. avrc..--a-t-JZ.__T1rovf--ktir. (Problerns of Desi= --,2-o-
gramrdng and Autoint,-Licn-collection o-f works), Tomsk, Tc!r.sb- Univer:74.+-y,
1971, IDP 191-1.96 (-fro:n 1:o 1, jan '1 .,0, Al Etracz No
Translaticin: An is descrii-bed for solut'iCn C_ foljC,41~j~-
matrix problens of linear algt~bra -,n symbolic
- - - -.. 1. - .1 -m
system: 1) a matrix iS Oven who,,;e r-2cinenr,3 nay bc botli and
analytical ex--pressions. D~, is to tho LI-d cl(-
terminant of the ratrix; 2) t-he r.-,atriy of coe,"ficientr of some sYstem of
linear equations is given. It is necessary to solve this zystc-!~,1; 3) "
J U:le
initial gives a system of m'x n-a-irenslanal 1rectors. It is 110-
auired to isolate an 4ndenendent subsystem of vec4-(,,rs P-i -i-en
system, 4) it. is required to write out -with respect to t-e nrcdeter:nir,~-~.
number a systern off equations whoS(.. sat--*~~-',icz-cn results in
vandshing of all deter,,.,inants of order k in the '! I iE, 7 -:, 4 5) 41, is
112

USSR
ARAYS, Ye. A. V., Vo-pr. 1)rotrr
Tomsk, Tomsk University, 1971, pp 191-196
recuired to find a matrix Tw,hich is the inverse of t"C.
The principal cycle of transformations for -solving the problems enumeratcd
above is reduction of the matrix to triangular form. A mod--fied metrod
(the equivalent matrix method) is used as the reduction procedure. It is
noted that the program which realizes the described algorith-un can be ;sed
with matrices of order (70 x 70). The procrar- for formula-'~-i-,S- tre sf:ven
problems is made up, in the form of an operator in the Auto4-.naliti', system,
(BESM-6) under ue g(!neral Litle PAL (Progrtimr of Alj.-.~Rwrt,
V. Mikheyev.
2-2
50

F . . . . . . . . . . .
USSR
ABAYS 'Ye.
"Program for Modeling nn.] Analysis of Radio Electrome CI-cuits
De.
V sb. Vopr. urof-,ranin-Ir. i avtcmatiz. m-cyc-:tir. (Prob-iems o~' Pro-
gram-ming and AulLemar ion-C oil f-%C t ion 01, -wor'!:S), omsk, I rs~ ~:niverszity,
1971 , pF. 65-79 (,-ro- irernetilva , N"o 1 J a 2 , Ab s tr~i T 70 -1
.Or ~'rj;.
Translation: The authcrs describe rrirci-oles end alF -for
the characteristics of' C and TC circuits, including cal-
culating sensiHvity and find-ing the frequency responsc~s of.
and statistical analysi-ZI, of clectron-ic circuit---. A. DcruS~-- rk. o .

USSR UDC:
O'."'S-31 Yl
Froaram for Modelillng aen4 a, allysis of Radio Electronic C-L
C~ -
C-:na sign L'-o-
V sb. V tiz. -,roye!-i-. ('Probl-a,:,.s
.A_U4- r,,- a- wor"s), Tcrisk, Toms4 University,
grwarr-riing E-nd ion--collec-'icn 07,
19-Cl, pp 4,1-6h Jan 72, Abstrac-t '.o
Translation: A proErEim is described for modelin- and analvsis of elec-
tronic radio circuits by means of a comimter desigred to aid the planner
with the analytical rar-. Ofl 1:4 S-,.ork. The "casic purpose of the progr_m
is to predict, the ba-havcr of an electronic circuit modi'iceticrl cc.--_-ct4F%d
by the desil.-,ner on t-ho lr,,,.,!~is of its mzdel. Thc- rro-
vides for: 1) arialyzing Clectronic circuit,,, lij Ow cow;t,ariL afid
-state rnode; 2) analyzin:r trpnsient m-rocecQ=s in the -circid L; 3)
out ve--iouz stati5tical studies (evaluatin_~ the effect of .scatter -in
parameters and aging of elements, analyzirF. circuit reliability, analyzing
the sensi t iv l'' ty of t1h e - irc-a-i t to variaticn, s in i It s int raramAcrs
In addition to circuits with DC tlnc- pro~7am car, be used fcr ana-
lyzing circuits whose supply source is a trapezoidal pulse, a sinusoidal
1/2
- 55 -
M,

fEtill1iillif~"t--,~vtlil~11--lrl~r.11111WRe;~I I Mi. kN;iI I M" I I I I ~'r- II I $III I".I. IM.-,
u S S i I
AFLIky-S, 'Ye. .41.
Tomsk, Tomsk Univ-L-_rsity, 1971, U
signal, a linearly acat.-L-atcUd S-L--usoild'al si~;nal, a d ==~cd
nal, or a signal vIncse sl-.ape is given in tabular form. Tl'.~~ MARS-1 pro-
occ_ra*T_1CT: DC r-ciels and -,.-_`,h lincar A%,,'
gram is designed f", W~
steady-sLate nodels, ircludin':~ pulsc circuJ -he
based oil metnods of circuit analysis: the, method of loop c-u.2-rentc, the
method of junction potent"i-aig, the SrfCtjor.~! methc-, Pnd a c-r.,,'Oiraticn
J-
method. The LwIA'RS-11 uro=- is formulated on th- of
interpretation systen- for solution of larEe pro-L-le-ms. DiblicFrar.hy of
ten titles. V. 1-likheyev.
2/2
I P-1 TIMMM I MN IsIfilry'r, 1,111 1"TIN TRIMM HIRRI MIM ]CLOM RIMIT RIMM9,91 FiTTITT'.1. M: 'fF '41' r~ 9111 11.1~ !1 -41 1

2 1)4 6 55 366 3
IN'STRUCTION' ON EXPERT MEDICAL EVALUATION OF VISA51LITY AT MEDICAL INSTITUICES
1,1,10 ItZSTITU'VES FOR TjjF. 01.10CED MiANING OF PIRMCtANS
jArtICIL by Yo.D. Arbatskavak(I.J.. 6,,1;1',.v'n' a,
Xj!-,~,Aj Ch a I r v f Ex pe r t
lie 6 1 coil D I n -.z% 2 1 M. (h ii 0 C en - YU. 1~. N,h k :~tl L t " I
Trimt1tute for the ArIvanced TraininF, of rhy-4-l"ns
-L,witij; Xa.,,co-, Sov,r-~~-ve Uravookhriment,v, RN-sian. No 10, 14,71. sIbmitted
2;- April 1971, pp 45-51)
It iu of great. national importance w improve the. qualivy of vedtcni
ion of diability under presunt T'he succes, of ~or;~ jwv-
A!::) -"I"'t Z
tni, tng to prtavention of d0eane and 4kabillry, of ratt-inal sp!mdinz of
23 in I Insit-ance fundri, mid of Preserving ble-illed personnel in ind-astr-i rullL-
on proper ~~xpert e-luation or t~~p,,rary LMd 1.~ting dls.,ibilltv. Hcevei
prnetLc, 11411, that lAv";I.Lunn often ma'~e nwy errors in ft-m1,tni exp,rt
.!vatuaticat 01 divablUty, For ex-plo, tn 10.2 porcvmt of the pativntr
wi,re referretl to VrKY I.MedLLal Comnii3tilon for L~etemtnatlcm of W~4.~-Illtyj
ithout juntific-atton, and In nome oblaqts and the r.nrhl~ I
T1,(- ichLe1'CTCnL4 of ',0Vtet p.blic health car, are clo5.il-f Un-ed I 'I
currprvhetwlv~! and proper training of ritudc-nt,; ~i- rredical For A~1~
oil(! of thL forris of advanced trainin,~ of phv!;i~ians tit -,jr 1~ngtjtute
ar~eueminar, for thr pro(4,siors and instrect-rs of n~di~al tlLch
hav born held ar a part of the curriculum sil."! '965. we that qualified
tt"Ining of inc4tructottl Ju vt-ry impartant. 111--te ar, I 1111mb--r -d or~-q dealing
i of 1-il se i a b
with orpmlizatin", vwthodz of conducting, nn~ w , n n r
(H.D. govrij?,ina; M.V, Mtjrav'yt!v and L.A. V.S. Pogw.- and N,11, Shul'-
%~L pina; V,B. Antanovich: V.N. BULrovt M.YL. S.kh.reva; A.P. nd A.U.
Shvina; M.O. Kra~uov ot al. ; 1%.Yv, VLterEon et 11. , VIN, and (AI)prs).
A very special place belongs to Heminarti rind uymposiunw lor instructorn
-t hight!r m-lical itintitutionu and infititutes ior the advanceA training of phy-
nicinns (M.D. KovrlV~inn, 196D) at our Institutr. The W110 paya much attc-rition t~)
the training of 111tiLitictnra who teach future ne,ltcs, so- thtit thl. us. di"Cuan.-d
But rov ,
extena!wly In 1969, in Geneva, tit a meting of WHO terrenentatives (V.N.
1.970).
13

!;L~tIL-2L S RWI (A I, III: A I I P I If A I I L~T I ON A IX0 It I I I I H I' Y 1111- "M, CU j o"
kit I 1100 11 IF ~ro --I ~m ;-.,-W i `F:J i IC T i.-i -(Hrf-f I P. 1-i-I
of th":
method of' -,tochnsttC approxii.tation is an.1,ze-.1 t*Or the
of results of observatiort; is finite, jj~t IA-,,; of the vectol- of lint c,
effici,vnts B are CUlCUI.3tCd Using the formnla:
It t 1) - ii..
where fi 7.41 15 Un e5tillllitt Of thQ Vector i,CiPht CV~ffil.ient 11
ii,put, signal; ;:"Ji) - Mi"
Or
,(i) is tilt output r, e
of the input rignal; zz ignal ohserved .,t!I 1104st
z(i) - x(i) 4 n(i); n(i) is the noise at the output of the object; is
a series of positive numbers, :;titisfying th, Condition 2:~(I)
I is the iteration number, I is the nuir,ber of cumponunts of vector it an" F.
A Sufficiently pl"iSe estimate Of VL~tor ii !. Iby the ITICtl'od uf , t~n.s-
tic approximation, particularly with a high noise level , cwi be pro'hictd only
aftilr a number of lter:ititnim- 1`11.14-1105) .The i
great inimber of points of realizutions.of Input and output signals rvq-~-.rf~ a
great deal of tire. Therefore, the possibility is stu"~ed of using 4
listing algorithm, the theoretical basis of uhich was provided by B. St.
Litvakov.
The accnracy of rc%toration of a Itarazeter in a limited nurber of 4era~
tions depends on the statistical characteristics of the itiput signal f,,i' ,
noise level it(!) and the selection of :I tuning step length Y(i) . Oxilv p1r.1-
meter YO) call be changed freely.
investigation by the Munte Carlo method alk-ed certain specifics f thr
Igo, ithn with repeated listing to be established. The influetwe L,f v-,
llowing factors oil the accuracy of estimation as &tvrmined: ") Iii;:~t sgnal
2coorrelati on function; b) noise at Lite uutput of the object; c) "wint-er ci re.
Cz
CT-
C9
cc
Ct_

USSR UDC: 51
TRUFA~
SYROV, Yu. P. , CHURKEIDZE, Sh. S., ARBATSKIY,_q..J1, TOV, V. V.
"On Optimizing Intersectorall apd Interregional Coi-Taunications in Planning
the Development of a United Nationall Economic System"
Sb. tr. in-t mat. Sib. otd. PJI SSSR (Collected Works. Institute of Mathe-
matics, Siberian Department, Academy of Sciences of the USSR), 1971, VY-0.
2(19), pp 138-168 (from RZh-Kibernetika, No It, Apr 72, Abstract No 4V501)
[no abstract]

M; A
M-1
MIR.In
USSR UDc 621.319.L-.002.15
rSj[ErjIjC'~ UD;:It', T
,!"VIr, T. S. NIKITP,11, V. A. YAKUSH-El" S. A.,
ALEKSEYEV, V. L. , A?,ISU70~!, A. D.
nA Device for Applying Silver Pazte to Ceramic Disc Cnn)acitt~r B 1
Moscow, izobreteniya. rrcnyshllenn~~:-ye obraz-,Sy. tolarnlFre znnki,
Patcrit. I'To 28 112, class 2-1, filed 8 !1- 6._~,
1970, No 33, Soviet t 5
29 Oct 70, P-_58
"hor
Translation: This Ai s Certificate introduces a device -for
silver paste to cera-mic disc capacitor bi-anks. The wnit contains a rotating
disc for trp_ns-nortin~7 the blwiks. Around th,~ pera-rr',en ol' disc a-re
P1111tiple-pli, ace with -ockrtr, for the 'Tic.- dl~vice n1CO
contains a .-::echanis-.. for applying the paste to the blw!'--. -,"c 4 ',,1
with punches. jUso included in the device are a drying chaz!d)er and a
drive mechu.-isti. As a disting-uishing feature of the pa-tcr-it, the Pr~_,CiF_Cln
uroducti-,7-itv of de-,ni'ce -erc innroved t-
and sul
Placing . 2 -lit sleevr--s
vith spring-_',.oadu6 luir~- -in the cartridge pockets. Rods f,-*" -into t-se
hollow slet-2ves a.,-.-d onnn thc-m, and the punches aro ioca!,~--d cr 'both sidez, (n'
the cartric~,--s.
2 5
a " ~Mwll 1, W fammg.

USSR 17DC 542 - 9 1: 5 'It 7/ 111-19
AR Ye. (deceased), VALITOVA, F. G., GAZETIMNOVA, N. G.,
X111 BEN N -
and PETROVA, L. P. , Instittite of Or-anic and Physical C11011tistry
imeni A. Ye. Arbuzov, Academy of Sciences LISSR, Kazan'
"Alplia-Phenyl-beta-dictlivl(dipliciiyl)phosplioiioct),draziiies'I
Moscox-,,, Izvestiya Akadcriii Nauk SSSR, Scriva "Chinnichesicava, No 7,
Jul 73, pp 1646-16,tS'
Abstract: Upon the reaction in dry benzene of tho chlorides of
diethyl and diplienyl phosphate v.,ith unsymmetric soclium phcw..1*-i-,-dra-
zinc, a 1 p] 1,1- phe 11 Vl-b Ct a- d iethyl pho S p] lono) iydrn zin c (1) and aipha-
phenyl-b eta- dip] i cnyl I-)' io s phono hy dra. zinc (11), respecLively., 11."CrIc
obtained instead of the expected (di-
phcriyl) phosphonohydr-azincs. The reaction of T~and 11 v,~ith
phthalic acid dichloride in dry benzone in Lhe presence Uf 1`11-1~,N
led to the formation of and 2-ph(6.nyl-
3-diplicn3,].pliospliorio-1,4-1)iif,lialaziti(,-ctione, respectively.
1/1

USSR UDC: 632-95
ARBUZOV, A. Ye., VALITOVA, F. G., and BAYGIL'DINA, S. Yu., Institute of Organic
anc
'rP*tic&l7 Chemistry im. A. Ye. Arbuzov)
IIA Method for Preparing Diphenylthiophosphoi-i-:iydrazine.,:"
USSR Author's Certificate No 256761, filed 3 May 67, published 13 Apr 70 (from
RZh-Khimiya No 22, 25 Nov 70, Abstract No - 22 N651 P by G. V. Kuznetsova)
Translation: These substances with the fonaula R P(S)WINN(I) (R=a-lkosyl,
aryloxy group oi, aryl.) we obtained from the rellc?ion of (X=halide)
With Ph NNII2(11) in a madittm of polar solvonW. A solutl~ql Of 9." C ot,
(EtO)2P?S)CI in 25 rpl of MeGN is added to a solution of 18 g o-P II in 15 rLI
of MeCN after which the mixture is left to stand for several days, The re-
cip--tated kyrd-rochloride of II is filtered out and the solution is evaporated
to an oil which is treated irith ether. The residue of I! hydrochloride is
separated and after the ether evaporates an oil is obtained which crystallizgs
at - 100. The -,-ield of I (R=OEt), C 15 H, 2N202PS' is 61%, melting point.69-70
i (R=OPh), C24H2102PS, are prepared in a similar fashion, yield 66%, oil; and
1/2
23

USSR
ARFjWV, A. Ye., et al, USSR Author's Certificate N
to.:256761, filed 3 May 67,
pAIished-13,Apr 70 (from RZh-Khimiya, No 22, 25 Nov 70, Abstract No 22 N651 P
by G. V. Kuznetsova)
I (R2Ph)j C24H21N 9PS, yield 21e., melting point 153-40 (absolute alcohol),
along with 65% LTh 2(S)22 0, C2020OP2'921 melting point 200-20 (PW-Te). I can
be used as physiologically active substances.
212

USSR UDC 547.-26'11
VIZEL', A. 0., KRUMOV, V. K., ARBUZ01. 8. A , and FADEYEVA, L. M., Institute
of Organic and Phvsical Chemistry imeni A. Ye. Arbuzov, Acadeniv of Sciences
USSR
"Production of 1-Halophospholenes With a Trivalent Phosphorous Atom and
Syntheses Based on These Compounds"
Lenin-rad, Zhurnal Obshchey Khimii, Vol 43 (105), No 10, Oct 73, pp 2137-
2143
Abscract: A simple, one stage synthesis of 1-halophospholenes wiLh a tri-
valent phosphorus has been described based on the reaction of a conjugated
diene hydrocarbon with phosphorus trihalide and white phosphorus, best
results being obtained with the reagent ratio of 3:1:2~ The products are
very reactive compounds which could be used in synthesis of novel phos-
pholene derivatives: ethers, thioethers, and amides with trivalent
pF,osphorU!3; they also react easily with conjugated dienes via a 1-4
cycloaddition, yielding novel spirophosphonium salts. The cyclic phW.3-
phonates obtained undergo easily the Arbuzov and Perkav rearrangement
reactions.
1/1

RIM
USSR UDC 542.91:547.1,118
ARBUZOV, B. A., NOVOSEVSKAYA, A. D., and VINOM00M, V. S., Chemical
Institute imeni A. M. Butlerov, Kazan' State University i-..ieni V. 1.
Ul'yanov-Lenin
"Reaction of Some Vicinal Dihalide Compounds With One Flectron Accepting
Group Containing Sodium Triethyl Phosphite and Diethyl Phosphite"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 12, Dee 732 pp 2604-2608
Abstract: The reaction of methyl esters and nitrates of a,5-dichloro- and
a,B-dibromapropionic acids with sodium triethyl phosphite and diethyl phosphitee
was studied at several temperatures [-7', to -10', + 7', +20', +1100 and
+150'j as well as the reaction of a,P-dibromodiethyl ester with triethyl
phosphite at room temperature. The intermediate and final producus were
isolated and identified by means of IR spectral data and comparative
analysis of physical properties.
lit
aj

USSR bDC 661.718.1+547.38+547.514
-A,'? 3 . I
K, _Z() V , 3 .'-ember Academy of Sciences USSR; FUZHENKOVA, A. V., ZIN-
KOVSKIY, A. F., and SAVCHENKO, L. Ya., Scientific Research Chemical Insti-
tute imeni A. M. Butlerov at Kazan' State University imeni 11. 1. Ul'yanov-
Lenin, Kazan'
"The Interactions of Trimethyl Phosphite and Dimethylphospharous Acid
With Phencyclone"
Moscow, Doklady Akademii Nauk. SSSR, Vol 199, No 2, 1971, pp 339-341
Abstract: A thermographic study of the addition of to phencyclone
showed that this reaction proceeded at a higher temperature (beginning of
the exo-effect at 58-62', maximum at 85-90') than the addition of (!-IeO)3P
to retracvclone. The reaction also took place with an Arbuzov rearrange-
=enr, but not-by a nucleophilic attack on the oxygen of the C=O group, as
in the case ot tetracyclone, but by a nucleophilic attack on the carbon
atom of C=O with a subsequent rearrangement into a bipolar ion 1, which
then rearranc-ed -.ntc a bi.Dolar ion II with final iso-merization into tha
end-product dimethyl ester of 2-nethoxy-1,3-iliplienyl-4,5(0,0'-bipheny-
acid (111), or by a direct attack
on the 5-C atom adjacent to C=O with the fornation of 11. A proof of
1/2

~--! il~~-' 4~1114R~-IMUIMTM~111'
USSR
ARBUZOV, B. A., et al., Doklady Ak-ademii Nauk SSSR, Vol 199, No 2, 1971,
pp 339-341
the formation of II was the conversion of II into 1,3-diphenyl-4,'5-(O,O'-
biphenylene)-4-cyclopentenone-phosphonic acid (IV) by the action of proton-
donor reagents, i.e., acetic acid and MeOH. IV could also be obtained by
the hydrolysis of III with 1:1 11C1. The addition of dimethylphosphorous
to phencyclone resulted in the formation of IV.
2/2
31
MIMI
I U

USSR UDC 661.718.1' + 547.77
ARBUZOV,__B. A., VIZEL', A. 0., BTANOVSKAYA, K. M., and GOL'DFARB, E. I.,
Institute of Organic and Physical Chemistry imeni A. Ye. Arbuzov, Academy
of Sciences USSR
"Reaction of 2-Oxo-2-chloro-3,3,5-trimethyl-1,2-oxaphospholene-4 With
Ethylene Glycol"
Leningrad, Zhurnal Obstichey Khimii, Vol 43 (105), No 10, Oct 73, pp 2134-2137
Abstract: The reaction of 2-oxo-2-chlaro-3,3,5-trimethyl-1,2-oxapliospholene-
4 with ethylene glycol was studied under various conditions:. with or without
solvent, different ratios of the reagents, with or without triethylamine.
In all cases only one acyclic product was obtained: 2-oxo-2-(1,1-dimethyl-3-
oxobutyl)-1,3,2-dioxapho4holane, b.p. 140-141'/0.01 mm, n20 1.4727, d2O
D 4
1.2221. Formation of a cyclic dioxaphospholane structure requires more
vigorous reaction conditions.
1/1
23

, Ble.
rga nopnosphoroua Compound!
USSR UDC 661.718.1 + 547.38 + 547.514
ARBUZOV, B. A., FUZHENKOVA, A. V., ZINKOVSKIY, A. F., and KOLOSKOVA, T. N.,
Scientific Ghemical Research Institute imeni A. M. Butlerov at the Kazan,
State University
"Reaction of Trialkyl Phosphites With Indanocyclone"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (.105), No 10, Oct 73, pp 2129-2133
Abstract: The reaction of trialkyl phosphites with indaziocyclone goes alon.0
the Arbuzov rearrangement route, forming 1:1 bipolar type addition compounds
at the first stage. If the reaction is carried out in presence of acetic
acid or acetic anhydride, a series of enols is formed. An intermediate
product is a bipolar ion whose presence was shown by thermographic and
spectral data. An analogous addition product forms in a reaction of
-4ndanocyclone W4 th tris(direthylamino)-phosphine.
1/1

USSR UDC 542.91:5.147.1'118
ARBUZOV, B. A., MUSLINKIN, A. A., VIZEL', A. 0., KOVALENK0, V. I., VYRDIA,
N. N., and KAPUSTMA, N. M., Institute of Organic and Physical Chemistry
imeni A. Ye. Arbuzov, Academy of Sciences USSR
"Phospholene Glycolacrylates and Some of Their a-Substituted Analogs"
Md5cow, Izvestiva Akademii Nauk SSSR, Seriya Kbimicheskaya, Nlo 8, Aug 73,
pp 1828-1833
Abstract: Experimental results are reported on the synthesis of new acrylic
derivatives containing organophosphoric heteroring -- phospholeneglycolacrylates
and some of their a-substituted analogs. These products were obtained by re-
aCLing l-chloro-l-oxophospholenes with glycolmonoacrylate and a-substituted
acrylates in inert organic solvents, in presence of triethylanine as an
acceptor of I[Cl. Several synthetic routes have been proposed for the syti-
thesis of pliospliolene,,,Ivcol-a-fluoroacrylatei;.
WIM E-1 M-11 W,

USSR UDC 542.91:547.1'118
ARBUZOV, B. A., NURETDINIOVA, 0. IN., NIKONOVA, L. Z., GOLYDFARB, E. 1.7
Institute of Organic and Physical Chemistry imeni A. Ye. Arbuzov of the
Academy of Sciences of the USSR
"Reaction of Phosphorous Acid Chlorides With Oxetanes"
Izv. AN SSSR: Ser. Khimiche Mar 73, pp 627-632
skaya, No 3,
Abstract: A study is made of the reaction Of FC13 and alkylphosphorous
acid dichlorides with 2-methyloxetane and 3,3-dimethyloxetane in other
than 1:1 reagent ratios. The equations of 18 reactions are given together,
with the experimental details of eight reactions and physical constants
of 23 synthesized phosphorous acid derivatives.
92
W.-M,
121
.... ........ ..

USSR UDC 542.91:547.1'118
ARBUZOV, B. A DLMNOVA, E. N., and VINOGRADOVA, V. S., Chemical Institute
Imeni A. M. Butlerov, Kazan' State University Imeni V. I. Ul'yanov-Lenin
"Reaction of 2,5-Dipenyl-3,4-diazacyclopentadien-l-one-3,4-diaxide ~-,Iith
Trialkyl Phosphites"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No 6, Jun 73,
pp 1422-1424
Abstract: Trimethyl- and triethyl phosphite react With 2,5-diphenyl-
3,4-diazacyclopentadien-l-one-3,4-dioxide yLelding I-alkyl-3,5-diphenyl-
pyrazolyl-4 dialkyl phosphates.

USSR UDC 542.91:547.1'113
ARBUZOV, B. A, im,.O%Tow~, L. Z., NURETDINOVA, 0. N., Institute of OrGanic and
Physical Chemistry imeni A. Ye. Arbuzov of tKe Soviet Academy of Sciences
"Some Properties of Oxaphospholans"
Moscow, Izv. AN SSSR: Ser. Khimicheskaya, No 3, Mar 73, pp 648-650
Abstract: Some reactions of compounds with the oxaphospholan ring were
studied, Di-(l-methyl-3-chloropropyl) ester -of ethylphosphonous acid at
100-IIOOC was converted to two phosphorus-containing products which separate
fairly readily an distillation.
Pure 2-oxo-2-phenyl-5-rietliyl-1,2-oxaohospholan (lb) was synthesized by
additional heating of the mixture of (1b) and (IIb) at 200-220% for 1.5-2
hours. Compound (1b) reacts with PC15 in CHC13 with formation of the cor-
responding acid chloride. Reacting compounds (1a) and (1b) with P2S5 it'
boiling Ibenzene produces the thiouxaphospholan compounds (IIII) and (111b)
which upon further heaclrig with P2S5 without a solvent at 120-130% replace
the oxygen in the oxaphospholan ring by a sulfur atom. The constants of the
synthesized compounds are summarized in a table.

USSR UDC 542.91+541.6.547-431.2'118.3
JJAKAROVAY N. -A., NABIULLINY V. F. MWENOV, 13. T. , and AqA`UZ0V".BL.J9
Institute of Organic and Physical Chemistry imeni A. Ye. Arbuzov, Academy of
Sciences USSR
"The Behavior of 2-Ethoxy-4-chloromethyl-1,3,;!-dioxaphospholane on Heating"
Leningrad, Zhurnal Obshchey KbirLti, Vol 43, No 11, Nov 73, pp 2373-2378
Abstract: Re-esterification of triethyl phosphite with 1-chloro-l-deoxy-D,L-
glycerol (I) led to the formation of 2-ethoxy-4-chloromethyl-1,3,2-di-oxaphos-
pholane (II). Study by the methods of gas-liquid chromatography and 31P nuclear
magnetic resonance showed that the cyclic phosphite II consisted of a mixture
of a cir, and it trans-isomer with boiling points that ware close to each other.
The trans-isomer predominated in the mixture. On heating of Il for 6 hrs at
175-900, EtCl was evolved and a P-containing ciligomer forned, epparently as a
result of an inter-molecular Arbuzov rearrangement. II was also pre-oared by
reacting I with ethyl dichlorophosphite EtOPG12 in the presence of NEt3'
Similarly, the 2-beta-ch-loroethoxy and 2-isobutoxy analcgs of I! (III and IVI
were synthesized by the reaction of I with CICH2~F42C`;~C` 2 and i-BuOF'] 2, respec-
tively. The 2-phonoxy nnaloft (V) of II was alno prepared. 'rho 6,!1invior and
properties of compounds IIT-V, including, the predomin'ance of the trans-iscmer
1/2

6 p, --t-n-lu ibn4i i "i M 44A I!-,.
USSR
MAKAROVA, N. A., et all., Zhurnal Obshchey Khinii, Vol 43, No 11, Nov 73,
pp 2373-2378
in them, were consistent with the assumption of an intermolecular rearrangement.
The authors thank V. V. Ponazanov, N. P. Imoshina, and E. I. Golldfarb for
carrying out instrument measurements.
2/2
"117-19MOM. flMOMMMM, 4.9 a 0 0 M Q; 9 20, M, OEM 9'. M -0 10;

USSR HC 541.63:547.111118
ARBUZOV. B. A., ARSFINOVA, R. P., VEREESHCHAGIN, A. M.) mid VULIFSON, S. G.Y
Institute of Organic and Physical Chemistry imeni A. Ye. Arbuzova, Academy of
Sciences, USSR, Chemical Institute imeni A. M. Butleroy, Kazakstan State
University imeni V. I. Ullyanova-Lenina
"Steric Configurations Containing Phosphorus Heterocyclics. 3. Gauche Confor-
mation. of the Alkoxy Group in 3-Alkoxy-l-thia-3-phosplietlianes'I
Moscow, Seriya. Khimicheskaya, 9i 1973, pp 1964-1967
Abstract: A four-membered ring containing two heteroatoms -- one of S and one
of P of the type below for the given sets of x and y~ was examined:
x W X OMO I Y 0
(II) x OFh, y 0
.CH (III)X Ole, Y
2 (IV)X Oph, y
S P (V)X OC6H4-p-N021 y S
Cil
y
1/2
MUM N "11111111rma~ 1~
34

2VM-~ _-'tF Emil
MMI'_
USSR
ARBUZOV, B. A., et al., Seriya Khimicheskaya, 9, 1973, pp 1964-10,67
The molecules cart have either a bent or a flat configuration. The dipole
moments and Kerr constants were determined for all five comt)ounds and showm both
as graphs and in tables. On the basis of these graphs it was shcwn that these
compounds occur in the bent configuration and have angles of less than 1140 to
1650. The phosphoryl or thiophosphoryl group occupies a pseudoequatorial
position while the methoxy and phenoxy groups have a gauche orientation.
2/2
lit. Vi,l~i..~ll~l'.11,ipll:"Ii!illfl.--~41;14;,Ilf"zl.-14iplli%l~,9.1:i;~4lt;i,1"4zll.~l, 1_1

10
USSR UDC 54-2-91:547.772.2:547.11118
ARBUZOV, B. A., SOROKINA, T. D., FUZHF7-TKOVA, A. V., VIROGRADOVA, V. S.
"Interaction of 1,2-diphenyl-4-benzalpyrazoli.dine-',,5-di-one uith Trimethyl-
phosphite and Tri(dime'thylamino)-phosphinelI
Moscow, Izvestiya Akadera-ii Nauk SSSR, Seriya Khimicheskaya, No 11, 1973,
pp 2577-2580
Abstract: A study was made of the effect of trimethylphosphite and tri(dimethy-
lamino)phosphine on 1,2-diphenyl-4-benzalpyrazc)lidine-3,5-dione (I). The
study was made using thermography and infrared spectroscopy.
Trimethylphosphite interacts with 1,2-diphenyl-4-ben~alpyrazolidi-ne-3,5-
dione via the bipolar ion stage with the formation of the methyl ether of the
enol form of the dimethyl ester of 1,2-diphonylpyrazolicline-3-5-dione-i,-I)enzy-I.-
phosphonic acid. On interaction of tri(dimenthylamino)phosphine with 1,2-
diphenyl-4-benzalpyrazolidine-3,5-dione, a stable adduct (1:1) was obtained
having the structure of the bipolar ion with the P-C bond.
HE
t r !Iff" 1111114:

USSR UDC 542-91:547.572:547.11118
ARBUZOV.,_ B. A., ZOROASTROVA, B. M., TUDRIY, G. A., FUZHEN-KOVA, A. V.
"Interaction of Dibenzal Acetone with Trimethyl. Phosphite and Dimethyl Fhos-
phorus Acid"
Moscow, Izvestiya Akadem-Ji Nauk SSSR, Seriya Khimicheskaya, No 11, 1973,
pp 2581-2585
Abstract: A study was made of the interaction of dibenzal acetone with tri-
alkyl phosphites. Trimethyl phosphite reacts with dibenzal acetone with the
formation of 2,2,-trimethoxy-3phenyl-5 5-(/3-I)henyl),.rillyl-l,"-Oxaphospholene-
4(11). When (H) is washed with water, the phosphorane ring breaks at the
P-0 bond with the formation of two keto phosphonates, probably S-cis- and S-,
transconformers. Phosphorane (II) reacts with dibenza-1 acetone by the diens-,
synthesis reaction, A thermogram is presonted for a mixturo of dibenzal
acetone with (CH 30)3P and the reaction of dibenzal acetone with (C"30)3p in
the presence of CH3CGO11.
1/1

fflmml&~- Rq.97WW-Mr RN 41 ENIIW~ Mlmgn,%Wh-~
USSR LI) C541.67047-879
Academician, ARSHINOVA, R. F., GURARIY, L. I., 1%V,&X1iEV,
Amuggy
E. T., Scientific Research Institute of Chemistry imeni A. 14. Butleroy
Affiliated with Kazan State University imeni V. I. Ullyanov-Lenin; Institute
of Organic and Physical Chemistry imeni A. Ye. Arbuzov, Academy of Sciences
of the USSR, Kazan
"Dipole Moments and Kerr Constants of 1,32-Dioxaphospholans"
Hoscow, Doklady Akademii Nauk SSSR, Vol 204, No 6, 21 Jun 72, pp 1149-1351
Abstracti The paper is a continuation of research on the stereostructure
of heterorings. The authorssLudy conformations of a series of 1,3,2-dioxa-
phospholans with the tricoordinate phosphorus atom. Four compounds of this
type were synthesized by reacting ethylene-1,2-propylene, 2-3butylene and
2,3-dimethyl-2, 3-butylene glycols with phosphorus trichloride and alkyl
dichlorophosphites. The dipole moments and Kerr con3tants were measured In
an atmosphere of dry arLon. The results show that the usual conformation of
the 1,3,2-dioxaphospholan ring is distorted by the spatial Interaction of
methyl groups which takes place in the case of meso-2-chloro-4,5-dimethyl
1,3,2-dioxaphospholan. This explains the contradictory data In the litera-
ture with respect to PNR and gas electronQ&rkphy determinations of the
stereostructure of these rings. The authors thank A. N. Vereshchlagin and

USSR UDC 542-91047xi18
ARB ZOROAST-ROVA, V. M. TUDRIY, G. A. , GUZUHENKU1A, A. V. ,
Chemical Institute imeni A. M. Butlarov of Kazan State University imeni
V. I. Ul'yanov-Lenin
"Interaction of 2-6-dibenzylidene-cyclohexanone with trialkylphosphite and
dialkylphosphorous Acids"
Moscow, Izvestiya Akademii Hauk SSR Seriya Khimicheskaya, No 11, 1972,
pp 2545-2549
Abstracti The interaction of tirmethyl and triethylphosphite with 2,6-
-dibenzylidenecyclohexanone was found to lead to the formation of cyclic
phosphorane (Ia), (Ib). The structure of the phosphoranes was checked
by the nuclear magnetic resonance and infran--d spectral data. The properties
of these spectra are discussed. The interaction of 2,06-dialkylphosphites
forms dialkyl esters of 2-(6-benzylidenecyclohexanone)benzylphosphonic acid
and also cyclic esters depending on the temperature. The experimental pro-
cedures and results axe given for the inter-action of 2,6--Denzylidenecyclo-
hexanone with trialkjlDhosphites, the saponification of the phosphoranes, the
interactions of phosphorane (Ia) with acetic anhydride, the interaction of
2,6-benzylidenecyclohexanone with trialkylphosphites in the presence of
1/2
53

USSR
ARBUZOII, B. A., et al., Izvestlya Akademii Nauk SSR Seriya Khimicheskaya,
No 11, 1972l pp 2545-2549
(CH the interaction of phosphorane (Ia) with CH COOR, the interaction
3CO)201 3
of 2,6-dibenzylidenecyclohexanone with triaLkylphosp-hites in the presence
of CH3COOOH, the interaction of 2,6-dibenzylidenecyclohexanone with (CH 30)2
FOH, z,6-dibenzylidenecyclohexanone with (a51420)2POH, 2,6-d-i ben zylidenecyclo-
hexanone with F(OCH3)3 in the presence of methanol, and thermographic analysis
of the enol derivative of phosphorane (Ib)a
2/2

urganopnosptiorous compounas
USSR UDC 542.91+661-718.1
ARBLPZOV, B. A. I SOROKINA, R. D. , and VINOGIWOVA, V. S. , Chemical Institute
iggffT."T.-R~ierov, Kazan' state University imeni V. I. Ul'yanov-Lenin
Kazan'
"The Reactions of 5-Benzalbarbituric Acid with Trimethyl Phosphite and
Tris(dimethylamino)phosphinall-
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskayap No 3, Mar 711
Pp 573-5?7
Abstracti At minus 14o trimethyl phosphite (I) added to 5-benzalbarbituric
acid (II) with the formation of a lil addition product (m.p. 80-50) that
had a bipolar structure, This product isomerized to the methyl ester of the
enol form of the dimethyl ester of barbiturYI-5-benzylphosphonle acid (IIII
m.p. 220-20). The latter compound formed directly when the reaction waa
carried out at room temperature. on treatment of III with HC1, the dimethyl
ester of barbit.uryl-5-benzylphosphonic acid (1V1 m.p. 2440) was obtained.
Dimethyl phosphite reacted with II to form a product which on recrystalliza-
tion from dioxan yielded the dioxanate of the enol form of the dimethyl
ester of barbituryl-5-benzylphoasphonic acid (a.p. 154-50). Treatment of the
dioxanate with HCl resulted in the formation of a product that proved to be
1/2

-----------
USSR
ARBUZZGB, B. A., et al., Izveettya Akademii Nauk SSSR, Seriya Khimicheskaya,
No 3, Mar 71, PP 573-577
identical with IV. In the presence of glacial acetic acid, I and II reacted
with the formation of IV, which vas isolated in the form of the enol dioxanate.
The reaction of tri(dimethylamino)phosphine with II yielded a !it addition
Product (M-P- 150-2u) which had the structure of a bipolar ion with a P-C
bond. The product was stable in the form of a bipolar ion in the crystalline
state.
2/2
47

M n
USSR uDc 661.,718-1:547.642
APPIZ I-%REfEV) YU. 1.I., VINCGIFIADOVA, V. S.) and SAI,';I'iOVl YU. YU.1
Chemical Inr~ltute imini A. M. Butlerov, Kazan' S'Uat--- University lm~ani
V. I. Ullyanov-Lenin
"S-Dirophosphoranes Based on Acrolein and Yethyl Esters of Ethylene-glycol-
and Btityleneglycol-1,3-pliosphorous Acid"
Yloscowy Doklady Akademii Nlauk SSSR, Vol 205, N o 4, Aut, 72j, PP 843-846
yclic phosphitc.5 was studied. A(1(11-
Abstract: The reaction of acrolein with c
tion of acrolein to the met!W1 ester of eth)-lenegl,,,col-olio--r)iioiolis acid in
absolute ether yielded 1,6,9-trA8,ct-[(5-methox,,,r)-5-pliosplia~.piro-(I~,l~)I
2-nonene., b-P. 55-560/1(j-3rn, n;~ 1.)020, dclo 1-3016. wher, -mit-flene-lycal-
D 4 tt
phosphorous acid methyl ester was used, the prmhict was I I )-' "rioxf,,-9 20
methyl-[(~-met.110~-T)-5-pliosr,haspiro-()t,5)1-2--decene, b.p. 61-62o/io-3 mm, n
-0 - D
1.4780, 41 1.2041. Addition of vniethyl vinyl- ketone to the met-Ilyl est~.-r of
acid yielded, after a someV11ftt 510W;-~r MfiCtloyi, 1,6,
").I)- Vj'-
740/10-3 UMI 20 1 01;t -wit"t'.
rrD -4745, dy Zhe runctions were Cftrr4V,,1j
exclusion of moisture ', under continuous stirrinrr, keepin,~- the
+250C. The products were found to hydrolyze easily im air but were stable eno,-I~-
to be distilled under hi,-h vacuum.
25
"Al

I t-ni rn~~ha M. YMM. ff"HIMFUM Hit W"i, W11 A 11,11 hd. TJI~4L 4,~ 1g 6cj-. 1.
USSR UDC: 54-r.26,118-'51171 .775
DIANOVA', Z. N., VINOGITINDOVA. V. S., C11011dCal 11-15titUtC il:lelli
A. 1-1. Butlerov Affiliated With Kazan' State University irf-mi V. I.
U1 ' yanov-Lenin
"ne Structure of Products of the Peaction of 1 -Phe nY1 3 -MC LYIv1 -4 - 1 sopropYlir -
denepyrazolone-5 With Dimuthylphosphorous Acid"
Leningrad, Z-hurnal (Toshchey KIiimiij Vol 42(lo4), tio 6, Jun 72, pp 12.12-1217
Abstract: The structure of dimethyl (1-pheriyl-2,3-dirieth,~..,I-pyi,azolone-5--,r'L-4)
isopropyl phosphonate and dimethyl
isopropyll phosphonate was identified by the addition of dimethl, -phos-pho_~~Dus
acid to 1-phel-,,'1-3-,-rethyl-li-isolrol)yl.idenep),rtzolone-5 followcd by allrylation.
Tautomerism of the a(Jduct of dimethylphosphorous acid with
4-isopropYltdone-D razolone is proved. The mithors Oiank Yu. Ya. Swiitov and
'Y
E. I. Gol'dfarb for taking the mrx spectra.

............
USSR UDC 5112.9l.:547.1'1133
All KRUFNOV V. K., and VIM', A. 0., Institilte of Or-anic and
Ph-y-sical Chemistry imieni A. Ye. ArbuzovY Academy of Sciences USSR
"Preparation of Acyl Bromides of Trivalent and Pentav.alent Phosphorus Acids"
Moscow, Izvesti,,,a Akademii Nauk SSSR, Seriva nimicheskaya, 110 5, 11 Y 72,
a
PP 1193-1194
Abstract: It is shown that acyl bromides of phosphoric ac.lds can be synthe-
sized by replacing chlorine with bromine in the corresponding acyl chlorides
in the presence of phosrhoras tribromide. PBr 3 can 'he used to obtain a wide
rangge of acyl bromides of D--ntavalent and trivalent phosphorus acids. Optimum
reaction temperature 1-10-1900.

USSi bl) C541.6:547.11118
RBUZO SO CKDA, T. D., VINOGRIWOVA, V. S., and SERGEYEVi'l, G. N. ,
e R Lca r &Ln ST3Kute Imeni A. !..(. Butlerov, KZMm State Universith Imeni V. !.
#
U11yanov-Lenin
"Structures of the Reaction Products of Somi -Un.,zaturated
Carbonyl COMDounds With TrImethylphosphite ami Tri(d:~xiethyl.~,-nino)-~Phospliine"
Moscow, Izvestiya Akadenii Nauk SSSR, Seriya Khimichesknaya, No 4, Apr 72,
pp 865-871
Abstract: Tr:Bwtkyl~phosphitr, reacts with
at -140 yielding a 1:1 addition product, writh bipolanr structure which isomer--
izes easily to a methyl ester of the enol form. of
benzykpliosphonic acid diviethyl ester (1). The latter forris the roactlolli
is carried out at room te-niperature. Hydrolysis of (1) yick~s an C-nol form of
a dinathylester of ck-(1,3-diohoziylbarbitua~yl-5)-bDri7,.yj.-)ho:,ijliotiie acid. Re-
action of tri(d:irethyl,.ir~.ino)phosphinewi-thl,3-dip'rlr--.qyl-5-benz.-ilb.,iz-bituric
acid yields a 1:1 crystalline addition product with a bipolar ionic ~;tructurfll.
Dipole momont values and W spectral parameters of a series o" bipolar ion-
obtairied 1'rom m-o ropnrti~:I,
47

7-
LISSR
V A. 20FOASTIROVA, V. M,
iY, g. ln--titute iroai A. '14"uLler-ov Cf
of or.-'anic
State University imerii V. I. Ull and I
Physical Chemizitry imeni A I Ye. Arbuzov of the Acad-n,,y, of Scicmuo USSYl
lcohol. 2. By, ifl, ri
"Derivatives of Phasrhoxus Acids an.1 A 4
of Nixed Dstem of Phosphoric Acid air! Son,) of il-hulr blulcC-~Ilcz~.l
ProT)erties"
Moscov, Izveatiya Alkadelaii Ilauk SS55R, 3erlya I:o 5, 1,"-Iy 72,
PP 1155-11559
Abatracti A previous article by the author3 d(,:;crlbvd ;-,wnc phorphorou-i,
phozphoric, thiophoaphoric P-rid phosphinic acid miturs an
allyl radical. A study of bioloriezil propertier. of tho syrlthozj.~'ce crif~-oDuy-.4.0
f3howed th-at they have a selective fun~~icidal urd antim.~.croblal eifect, Low
toxicity and si,,pificamt- activity towavzds th- don:.a.-LI-ophyte r cl-', -
Ll T I hophjton
gypseum and Epideimophyton 16auf mrin-llolf -rorc noticeable irl r.J~.-ud phosph;)Ac
acid estera contairiir4- onc C(-chlarc;~-Ilyl mdJcal. .1lowca
I ' y L
tir.t the fungicid,71 activity of thci rlxed estcv-; incr~--'Ls'z I,-itll
of tho hydr~~carll-(jn at the plwsphorv,~- ollc,,~iv w"W.1-,'-

USSR
ARBUZOV, B. A., et al. , Izve5tiya AkadeLOA Nauk 53SR' serflya Xhinij eh~!akaya'
Ho 5i May 72f pp 1155-1159
The present article gives a more det,%ilod study of the (',~Yflct of
this type of compound, The alkyl xwUcaJ- in tho se3--les of conpowids
I/Cl
(FOY(O) - OCF'2- - 0 was lengthened from C, to C6. An irprnvc.-.-!-a tit in
the synthesis, viz. corducting thp reaction letween w,'id
-, of
chlorides and C