SCIENTIFIC ABSTRACT AZARYAN, D.T. - AZHIYEZER, I.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002200220017-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

/2___ cl 18 __6 xt, 'PROCESSING DATE--3DDCT70
AS fiki
_J,.'TLE-STATE OF THE SURFACE,LAYER7DURING ADSORPTION COMPLICATEDBY A
CHEMICAL-REACTION -U
~.~AUTHOR-102)-LYCHKIN, I.P., AZjtRyANv D.T.
r.,CQUNTRY OF INFO-USSR
,.;SOURCE-ZH. PRIKL. KHIM. (LENINGRAD) 1970, 4313), 687-90
-DATE PUBL ISHED---70
_~SUBJECT AREAS-CHEIMISTRY
-TOPIC TAGS- ADSORPTION, CARBON DIOXIDE* ETHYLENEDIAMINE, CHEMICAL
REACTION, AMINE
_~CGNTRCL MARKING-NO RESTRICTIC14S
"DOCUMENT CLASS-UNCLASSIF[ED
PROXY REEL/FRAME-2000/1635 STEP iNO--UR/0080/70/043/003/0687/0690
61 RC ACCESSICN NG-A001.25257
UNCLAS!;IFIED

~2/2 018 UNCLASSIFIED PkIOCESSING DArE--30OCT70
C.IRC ACCESSICN NU--AP0125257
--ABSTRACT/EXTRACT-W) GP-0- ABSTRACT. ABSOR.PTION,OF SO SUB2 P.~ESENr IN
AIR, BY AQ. SOLNS. OF ETHYLENEDIAMINE AND ETHANOLAMINE CAUSED
.-DISTURBANCES oF rfiE SURFACE LAYER wHICH WERE TRANSFORMED INTO CONVECTIVE
~_..STREAMING INTO THE CE,'4TER OF THE SOLN. A LINEAR RELArIGN EXISFS BETWEEN
THE, RELATIVE AMT. OF ADSORPTION ON THE PHASE 3UUNDARY GF THE GAS SOLN.
.,iAND 1-TAU, 6HERE TAU IS THE TIME OF APPEARANCE oF,jHE DISTURBANCES.
FACILITY: KASP. VY.SSH. ViDENNO-MORSK. KRASNDZNAMEN14UE UCHILISHCHE IM.
KIRCVA, USSR.
UNC LA SSJ F IED

USSR 539.4:624.012
B.ABAYAN, A. A., AZA-TRYAN, R. G.
"Concerning the Question of Crack Resistance and Strength of Oblique See-
tions of Bendable Light Ferroconcrete Elements"
Sb. nauch. tr. Yerevan. Dolitekhn. in-t (Collected Scientific Works. Yerevan
Polytechnical Institute), 1970, 25, PP 74-70, (from RZIi-Mekhanika, No 5, May
72, Abstract No 5V398)
Translation: Me paper describes the testing of 16 ferroconcrete girders
with concretes of grades 250 and 350 on.a stone-and-pumi-ce filler. The
-girders measured 200 x 21; x 15 [sic]. Class A-II rein' orcement 14 and 16 r3r.,
f
in diameter was used. Bending tests were done b., syr.Tetric loading in two
sections. Flexures, the.width of opening of sloping cracks, and deformations
of the concrete and the reinforcement were ineasured., it was found frorm the
results that the crack resistance of supporting sections of the girders is
ensured with fulfillment of the condition
Qq - H + if deteiinined by the propooed method, in 7-9-
13 e 16 2 5'
10 xp (-96M RT) cjr,3,jj-l.sec- it was possible to acco~Xnt for reactions of
bLI1 typed of' aCLIN'd Colittra of chtfl,lin with tjio j0d,I)it.or wheri studyini., the
kinetics of reextions of H atoms b,! the ignition liwitla; mi)t-hod.
2 te
4

UNCLASSIFIED! DATE--iOOCT70
112 021
-T-ITLE--CALCULAT ION OF REACTIONS FOR~ALL TYPES OF ACTIVE CENTERS REACTING
WITH MOLECULES, OF ~AN ADDITIVE USING ~A FLAMMABILITY LIMIT METHOD -U-
~~~.-AUTHOR~--AZATY~it-Y-I-V-9!-
ZOUNTRY OF INFO--USSR
~.,~'SOURCE
-KINET. KATAL. 1970, ll(L)v 239-41.
DATE PUBLISHED ------- 70
~:_~,SUBJECT AREAS--CHEMISTRY
TOPIC TAGS--CALCULATION, FLAMMABILITY LIMIT, CHEMICAL REACTION RATE,
~,~:-_-.HYDROGEN, HYDROXYL RADICAL
'~CONTROL MARKING--NO RESTRICTIONS
::,.00CUMENT CLASS--UjNCLASSIFIED
:,`~PROXY REEL/FRAME--1997/0832 STEP:NO-UR/0195/70/OIL/001/OZ39/0241
CIRC ACCESSION NO--AP0119736
UN C L AS S I F I E 0

W2 "021 UNCLASSIFIED' "PROCESSING DATE--30OCT70
-~~CIRC.ACCESSION NO--AP0119736
w-.ABSTR.ACT/EXT,P.ACT--(U) GP-0- ABSTRACT. AN IMPROVED VARIANT OF THE
.,~FLAMMABILITY LIMIT METHOD IS PROPOSED WHICH ALLOWS THE PROCESS H PLUS RH
'EQUALS H SUB2 Rt A140 THE REACTIONS 0 PLUS RH EQUALS:OH PLUS R AND OH
i.~PLUS.iRH EQUALS H SUBZ 0 PLUS R TO,aE CONSIDEREDJIN THE MECHANISM. IT IS
NOT NECESSARY TO KNOW THE RATE CONSTS* OF: THE~,LAST 2 REACTIONS TO DET.
RATE CONST. OF THE 1ST PROCESS. IF.CHAIN TERMINATION TAKES PLACE
IN A DIFFUSION REGION OF TH&REACTION, THE CALCI~. OF~THE RATE CONST.
DOES NOT INVOLVE THE COEFF,. OF HETEROGENIOUS RECOMBINATION OF H ATOMS.
FACILITY: INST. K'HIM. FIZ., MOSCOWp USSR~
UNCLASSIFIED

USSR UDC 621-371-029.6
RZ=PVSKIY, V. V., KOREITBERG, Ye. B. , OIRLOVSKAYA, B. D. , and
AZBELI, M. D.
"Propagation of Broad-Band UHF Signals in Tuannels and Shaft,
Mo-~ow, V sb. X Vses. k_onf..Po ra-sDrostr. radiovoln. Tezisy dokl.
Sek.s. 6 (Tenth All-Union Conference on the Propagation of Radio
Waves; Report Theses; Section 6--collection of works) "Naulka,"
.1972, ]PP -4-67 (from RZh--Radiotekhnika, No 10, 1972, Abstract
No 1OA392)
Translation: Experiments investigating the passage of pulse signals
in the tunnels of the Moscow subway are desci-ibed. Triangular
"radio pulses 0.08 8 wi Ie at half value were'used, with a period
of repetition at POO W,on a carrier frequency of 2200 MHz. To
detect distortions of broad-band signals, television images ,'!ere
transmitted along shafts and in ("he tuvannel of the subway. Results
of,the experiments showed that the distortion of the pulse fron-us
did not exceed 0.02 ps; the multibeamnature of the -ropagation
has no effect on, the accuracy of TIM signal transmission; the qua-
lity of the TV transmission is good., Three illustrations, bib-
liography of one. N. S.

USSR UDC 621-371.029.6
RZHZVSKIY, V. V., KORENBEERG, Ye. B., ORLOVSKAYA, E. D., and
AZBEL I, I-1. D.
"Experimental Investigation,of the Propagation of U11F Radio Laves
in Tunnels and Mine Shafts"
Moscow, V sb. X Vses. konf. po ras-prostr. radiovoln. Tezisy dokl.
Sakts. 6 (Tenth All-Union Conference on the Propagation of Radio
Waves; Report Theses; Section 6--collection of works) "Nauka,"
1972, pp 68-72 (from RM--Radioteldinika, No 10, 1972, Abstract I-To
1OA393)
Translation: The investigation was conducted iii tunnels of the sub-
way, lined with tubing (circular cross section) and in minu shafts
(rectangular cross section), ounk in gypsum strata. Results of the
measurements showed that in rectilinear paths, the at-tenuation is
waves for the transmis-
comparatively low; this permits use of UHr
sion of information along shafts. In paths vith turns, there is a
substantial addition to liheveakening of the field, and retransla-
tors are needed for the transmissions of information. Fo-LLr illus-
trations. N. S.
58

-2:621."71.1
U33R UDC: 62.1-396.
,IZB-L-L 14. D.
"Using Broad-Band Si~7nals for Co~-.imunicaticn in ne-s at UH,"
'ur 'I _11-ction
V sb. Shakhtn. radicsv~vazl (I Nining Hadio Ccinj_ _j_CLZ1O~ --CC.--,.
of vorks) 1--loscow, 1970, pD 5-10 (from
248)
March "l, Abstract 1'0. 3;1
Translation: Distortions are studied in t1he i n -_F'o rma t i o n t ra n si t -
ted in coiwr~unications systems inside mines. ---n analysis is made
of methods o-- reducing ~Lhose distortions conniicted with the
'he advantare.1 o~
multibeata nature of the propagation.
broad-band sir4lia-ls (on the e-2--ample of industrial tel~~vision) are
demonstrated. !I. S.
70

USSSR UDC 5 17. 925 .-I-A ;5 _17.92C,
AZB-I'=- V, V.
"Zero Solutions of a Second-Crder -Linear Differential Equation
writh Delayed- Argument"
Minsic, DiTferentgiallnvye Uravne-niya, No. 7, vol. 7, jUlY 1971,
Pp 1147-1157
Abstract: This article finas the con(13.-caons uraer ine -me-
orems of Stur_- and de la Va3_I4e-.PC)ussj_n apply to equ---Lions
n'. These theorems are o.zen the tha~ouTh
delaved argv-72e
-ial eouations -ield rosvilts.
which j_mre,-,ti La-tions of different
The fiP.-t of t-heoe theorems deals wita them se.,;uration o.-C ,x,~ro
solution-v; tj-.Ie second deals with the differentia-L. in,,:,,quality
space the
t,.,hich vermi-(',-s the len,,-th of the non-oscill,,ation
distance bet,,.;een adjacent zeros of the solution -- to be esti-
nic Jia conce-rned, f- in
rMtCd ~,T, rr_~ -t delayed arjv::~e. era, 1 Y cpea~
%:.U4-hor _es
these ckmle theove.,irs orr:. no lorc;-Cr
his oa, a consideration of t-I-Le
1/2

USSR
AZBELEV, N. V., Differentsial'nwe Urayneniva No. 7, vol. 7, July
1971, pp 1147-1157
m
L x 1 t, Ju- +p (t)x(hi (t)) o, tElo,oo),
x(t) o if t< 6
-hat uhe pi(t) can be,s=ed for el-ch
under the assumptions 11
S
hj(t) is mea urable in 10,00); pi (t) ~, 0, hi(-LI),4 -6
t > 0 (i m) , where the s olut ion o the
for a-most a!! U
equation if-, a fwiction x(t) writh an absolutely continuous deri-
vative th,:tt -~ a 41- i ~~ -f ies th,:, eauation practic-!,Illy in lo,*,
I -h I - u k I
The author is associated wi the Taij~.ov ~n4:ti'ute o~ Chertical
Machine Construction.
2/2
3

USSR uDc: 621-396.6.Ol7.7P(088.8)
PELITSMOV I. D., NEZHINSKIY, T. I., KHASPEKOVA, Ya~ N. , A~~L-LL' ,Z. A.
"A Drying Installation for Radio Components"
USSR Author's Certificate No 267488, filed 3 oct 66 Published 27 Jul 7-
(from RZh-Padiotekhnika, No 1, Jan 71, Abstract No 1V232 P)
Translation: This Author's Certificate introduces a drying installatic-
for radio comDonents such as microelements which have a flat base. 'Pic-
installation contains a rotating disc for moving the components from a
-er. To im~
batching device to the unloading port, and an in rared heau
Ing quality and simplify the design, the heater is made in 'he
prove dry 1
-form of a flat plate located over the disc, and the:disc is equipped wit,,
radial chutes so that the comDonents can be -moved one step by rakes when
the chutes match up with the loading device and the unloading port.
the laterall cylindrical surface of the disc between,the grooves are dri-.---,
uuled t--O a mechanis-- for turning a system of levers and springs
P2- c0
to turn the disc by steps and fix its position.

corrosion
USSR UDC 669.265'24.018.44:620.196
GORBAKON' A. A. PARSHIN, A. 11.
"Increasing the High-Temperature Strength and Resistance to Intercrystalline
Corrosion of P120111745 Alloys"
V sb Metallovedeniye (Physical Metallurgy -collection of works), No 15, Lenin-
N
grad, Sudostroyeniye Press,_1971, pp 92-100 (from Rzh-Metallurgiya, No 4, Apr 72,
Translation: The properties of the Kh2ON45 alloy mastered by industry are ana-
lyzed from the point of view of the suitability of using this alloy in thermal
power engineering. It was demonstrated that, this alloy, which has high resist-
ance to chloride stress-corrosion cracking, has comparatively low-temperature
strength and extremely unstable resistance. to corrosion. 4 A study was made of
.the effect of stabilizing additions of Ti and 11h ard of the conditions of aus-
tenitizing and additional provocation heating in the 500-8500 range on the stress-
rupture strength. Mhe possibility of increasing the high-teurperature strength
(stress-rupture streng
gth and deformtion capacity) of alloys of this type by
additional alloying with molybdenum and their resistance to corrosion by limit-
ing the C content- and increasing the Nb content (I;b:C -:_1 24) is demonstrated.
'Three illustrations, four tables, and an 18 -entry bibl I ogTaphy.
1/1

USSR UDC 582.285.2:634.746.(571.6)
AZ8aIXL-Z- M.
"Rust Fungi That Develop Accia on Far Eastern Species of the Berberidaccae"
Leningrad, Mikologiya i Fitopatologiya, No 5,1971, pp~420-425
Abstract: Two groups of rust fungi on species of* the barberry family, Ber-
beris amurense and Caulophyllum robustum, are described. The first group
includes species with telia invariably concealed under the epidermis and
teleospores with very short stems, Puccinia brachypodli Otth and Puceinia
niels. The second group includes species in which the. epidermis tears over
the telia and the teleospores rest on more or less short stems, Puccinia
graminis Pers. and Puccinia culmicola Diet. P. culmicloln is found only in
Fast Asia, wbile the other three species occur throughout the temperate
zone of the Northern Ilemisphere. The synonymy of the. species and intra-
species taxa and their nomenclature are given in accordance with the rUles
~of the International CodeF of Botanical Nomenclature. The keys are arranged
to assist in identifying the fungi in the haploid and diploid stages.
1/1

USSR UDC 632.95
AZERBAYEV.-I. N., AYMOZHAYEVA, M. Zh., TSOY, li. A.
"Acetylene-Containing Ureas"
Alma-Ata, Khimiya atsetilena i tekhnol. karbida kal'tsiya sbornik (Chemis-
try of Acetylene and Technology of Calcium Carbide -- collection of works),
"Kazakhstan," 1972, pp, 157-160 (from RZh-Khimiya, No 9, May 73, abstract No
9N534 by M. G. Kaplun)
Translation: Substances of the formulas H2NCONHC(R)(R')CHC11 (I) and
m-XC6H4NHCONRC(R)(R)C-=Cli (II) (R and R' alkyls or RR' - cycloalkyl,
X - H or Cl) are synthesized in reactions of acetylene amines with
nitrourea (III), with PhNCO, or with m-ClC6B4NCO. Example. 0.01 mole of
-of III in 4 ml of distilled water
Me2C(NH2)C=CR (IV) is added to 0.0l.mole
at about 20*C, mixed for 30 minutes at.the same temperature, and then at
50-55% until gases are no longer given off, and then filtered. The fil-
trate is evaporated to 1/4 original volume, cooled, the precipitate is
separated and crystallized from water and then from heptane. 1.09 grams
of I (R = R' = Me) are obtained, C01020, yield 70.7%, melting point 151'C.
The following compounds of type I are synthesized by analogous methods
(given are R, R' or RR', molecular formula, yield in Z and melting point
1/2

USSR
AZERBAYEV, I. N., et al., &biuiya atsetilena J tekbnol. karbida kal'tsiva
sbornik, "Kazakhstan," 1972, pp 157-160
in *C): Me, Et, C7H12N20, 77.2 103; Me, Pr, C8Hl4N 20, 89.7, 64; cyclo-
C6H C OR -N20, 90.4, 129. 0.01 mole of PhNCO is gradually added with
coag lo P.01 mole of IV in 3 ml of absolute C-H . The mixture is held
0 6
for 40 minutes at 40-50'C, cooled, and evaporated until dry on the following
day. The residue is doubly crystallized from heptane giving 1.72 g of II
(R - R' = Me, X = H), C12H14N 0 yi-ld 85.1%, melting point 153'C. The
following compounds of type If 'are synthesized by analogous methods (g4-qen
a 'Q:
are R,.R' or RR', X, molecular formula, yield in %0 melting point i,
Me, P
Me, Et, R, CIP16N 0 86 1 111; r, H, ClOli,20, 99.6, 104,
c6a 16 1 26,'95.-~,2151; Me, Me, Cl, C12H13CIN20, 93.2, 141.--~~
11 C H 9N
H '20 99-8, 91;
Et, I C13H 15 C INT 20, 95.8, 123; Me, Pr, Cl, C14 17~LN
cyclo-~611u)- Cl, C1018CLN20, 98, 1, 133. The structur; of the synthe-
sized compounds I and I! is confirmed by the data of IR.spectra. The
compounds were produced in a search for mutagens, herbicides and soil
sterilizers.
2/2
43

USSR UDC 547.241
AZEUAYE-V _-N., DZHAYLAUOV, Yu. G., BOSYAKOV, K, B., YERZHANOV, K. B.,
SERIKBAYEV, K. S., and ALEKSEYEVA, N. N., Institute of Chemical Sciences,
Acad. Sc., KazSSR, Alma-Ata
"Reactions of Unsaturated Phosphites With Aldehydes,and Ketones"
Alma-Ata, Izvestiya Akademii Nauk Kazakhskoy SSR, Seriya Khimicheskaya No 1,
Jan-Feb 7 3, pp 5 1-5 7
Abstract: Condensation of dipropargyl phosphite with chloral and bromal yields
0,0-dipropargyl (1-hydrox-y-2,2,2-trichloroethyl)phospliotiate and its tribromo
analog even without any catalyst. In.the presence of sodium alkoxide the
reaction of diallyl phosphate with 2,5-dimethylpiperidone-4, 2,6-diphenyl-
piperidone-4, 2,6-di(2-hydroxyphenyl)-piperidone-4,,1,2,5-trimethylpiperidone-
-4 yields the respective 4-diallylphosphanepiDeridoles-4; with 2,2_-dimethyll-
tetrahydropyranone-4, 2,2-dimethyltetrahydrothiopyranone-4 and 2,5-dimethyl-
tetrahydrothiopyranone-4 the products are the respective 4-diallylphosphane-
The esters of a-hydroxyphosphinic acids of pyrone,
and thiapyrone series are unstable, decomposing an distillation.
1/1
- 23 -

USSR UDC 547.341.26'118.07
ZARIPOV, R. K., AZERBAYEV, I. N., and AYMAKOV, U. A., Chemical-Metallurgical
Institutei Academy of Sc3ences-, KazakhSSR
"Reaction of the Esters of Hydro%vmethylphosplionic Acid With Orthoformate
Estersit
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 4, Apr 73, pp 764-765
Abstract: A mixture of 29.6 g triethylorthoformate and 44.8 g di-n-butyl
ester of hydroxymethylphosphinic acid was heated in an oil bath to 130' for
30-35 min distilling over about 12 ml of ethyl alcohol. The residue was
vacuum distilled yielding di-n-butyl ester of diettioxymctliyl(hydro7yiqettlyl)-
phosphinic acid. A series of homologues was obtained in an analogous manner.
The products are colorlesb volatile liquids without it marked odor, soluble
in organic solvents.

USSR UDC: 547.241+547.653
KAM4Y, G. Mi., KI-N-SAIZOV, A. S.of A--. GABDUL-LIMA, N. Z.,.
Institute of Chemical Sciences, Academy of Sciences of the Kazakh SSR
"Products of the Reaction of Chloral With Dialkyl Naphthyl PhosT)hites"
Leningrad, Zhurnal Obshchey Xhimii, Vol 42(104), No,6, Jun 72, PP 1300-1302
Abstract": Continuing their work on the synthesis of dialkyl naphthyl phos-
phites, the authors studied the reaction of dialkyl C(-naphthyl and dialkyl
P-naphthyl phosphites with chloral and studied the'~Tjhysiological activity of
the resultant compounds. Chloral was added slowly to an ether solution of the
phosphite. The reactions yielded alkyl na-Dhthyl 15j, /3'-dichlorovinyl. phosphates
-and the corres-pondinS alkyl chlorides
C,,Ii,OP(Ofl)2-_..GI3CCIIO -> CJOI[701'(O)(Olk)OCII=--CCI..-P.RCI
The resu-Itant products are colorless liquids which gradually hydrolyze in air,
All the compounds are excellent insecticides with comparatively low toxicity
for warm-blooded animals. Because of their low toxic properties and their
curativo effect in treatm-ant of hypodermatosis.of cattle, alkyl naphthyl
-31-dichlorovinyl phosphates show promise for use in veterinary practice.
38
PH MIMIMMIMIM, M11, IMMINIORMORMU TIMM

USSR UDC 547.251541.641632-953
KOCHRIN, D. A., VORONKOV, H. A., VORONKOV, V. A., a
Institute of Physical Chemistry, Academy of Science~411 &,Hoosactw, "AT
my of Sciences KazSSR,, Alma-Ata
Institute of Chemical Sciences# Acade
"Biologically Stable Grafted Copolymers of Perchlorovinyl Resin and Organotin
~Aerylates and Formation of Films Based on,Then!,'
Alma-Ata, izvestiya Akademii Nauk KazSSR, Seriya XhLideheskaya, No 1,
Jan-feb 72, pp 78-80
Abstracti Copolymers of trialkylmetacryloxystannates with perchlorovinyl
QCV) resin were obtained by heating the components JP1 a mixture of acetone,
toluene, butyl acetate, in .. presence of isobisnitrylisobutyric acid. These
copolymers provide strong protective coverings with high antifungal activity.
Optimal tensiYe strength, heat conductivity and temperature conductivity
were obtained with content of organotin~metacrylates. PCV films modified
with 1-2% orgaaotin additives showed improved physico-mechanical properties
and higher heat stability. The new copolymers were tested ont Chaetomium.
globosum, Stachybotrys atra, Aspergillus niger, Aspergillus anstelodazy,
Pecylomyces variety, Penicillium cyclopitam, Penicillium brevicompactum.
.None of these cultures shoved any growth on samples protected by o)cperimental
copolymer films.

Nitrogen-Compourids
USSR UDC 5.42.91:547.824
AZERBAYEV, I. N., ESKAIROV, X. E., and KUATBEKOV, A.~ M.
"The Synthesis of Cyanoethyl Ethers of N-Alkyl-2,6-diphenyl-4-etliylpiperidin-
4-one"
Izvestiya AkadeM4i Nauk Kazakhskoy SSR, Seriya Khinticheskaya, No 2, Mar-Apr.
71, pp 68-70
Abstract: The addition of acrylonitrile to ethylpiperidones takes place in
40% aqueous potassium hydroxide. Acry,-onitrile adds to the hydroxyl group
to form $-cyanoethyl ethers of 1-allvl-2,6-diplienyl-4-etliylpiperidin-4-one.
The condensation oE freshly distilled acrylonitrile, in the presence of
stannic chloride, with 2,6-diphenylpiperi.diti-ti-otic, and 2,6-diphenyl-4-
ethylpiperidine-4-one yields 1-0-cyanoetiiyl-2,6-diulieiiyll>iDeridiiie-4-one
and 1-8-cyanoetliyl-2,6-diplienyl-4-ctliylpiperi(lin-4-one..
The structures of the compounds were confirrued bv infrared spectroscopy.
The products were separated and identified by thin layer chromatography.

Acc. Nr. AbstractinR Ser ice, Ref. Code
00041521 CHMICAL ABS
89995k Products of the reaction f cr-chloro-c-isonitrosoace-
rtone with aromatic amines. urmatisalieva.
K
a. 1. A.
T.;_.Poplavskava. 1. A r
). Zh. Org. 1970, 1), (56-S (Ruz;s). 'the reac-
L SS, R
tion of 'MeCOCCl:NOH (1) with RNH2 (R is 34%lecaRi, 2,4-
LeC4Hi, CIC6H3, 4-.NleOCH;, 2-MeOC6114 2-EtO-
C,Hl, 2-NleCj1t, 3-HOCeH4,~or 3- ,H2NErHO in the pre'sence of
XEta gave NleCOC(:.NOH).NHRAU)- Simnilarlv. treatinz I
with a-aminopyridine in pyridine soln. gave i 10-13510 cL-(2-
pyriiJy!atninr))-o-igoniyosoacerotie (111). The ~;'reaction of 11
with N113011 gave 34CC(: NOll)C(-N0H),NllR: JV); IV (R
4-CIC41141 was prepd. by treating TvIeQ:N6l-1)Q:NOH)Cl
with 4-ClCgHINH2 in the presence of NL-t4; Ul does riot react
with N11:0H. CPJR .J
REEL/FRAME
A(l

PROCESSING DATE--230CT70
1-12 009 UNCLASSIFIED
T.ITLE--PREPARATION OF PARTIALLY SULFONATED P3LYSTYRENE -U-
AUTHOR-(O2)-UE%jlAY_EV, I.N., ROMANOVA, D.M.
.CCUNTRY OF INFO--USSR
.~.-.SOURCE_-IZV.. AKAD. NAUK KAZ. SSRr SER- KHIM. 1970t 20(2), 80-3
DATE PUBLISHED ------- 70
AREAS--CHEM[STRYr MATERIALS
TAGS--POLYSTYRENE RESIN, CHLOROFORMt SULFONATION, SOLUBILITY
~.CONTROL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--'tl)!CLA SS f F f ED
,.PROXY REEL/FRAME STEP NO--UR/0360/70/020j/002/0080~00")3
--1999/1863
CIRC' ACCESSION NO--AP0123651
UNCLASSIFIED

2/2 009 UNCLASSIFIED, ;PROCESSING DATE-230CT70
~.-C IRC ACCESSION NO--AP0123651
-ABSTP.ACT/EXTRACT--(U) GP-0- ABSTRACT. BLOCK POLYSTYRENE (1) WAS
DISSOLVED IN CHCL SUB3 AND REACTED WITH 0.2-3.0~,PARTS HSO SUB3 CL AT 20
OR 50DEGREES. TiHE PR00UC-TS WERE PPTO. WITH G SUB7 H SUBlb. THE
INCREASE IN HSO SU33 CL,I RATIO GAVE PRGDUCTS WITH HIGHER ACID NOS. AND
C-GR;:r 'y! I T'
LOWER SOLY. IN OR.G. SOLVENTS. THE PRODUCTS OBTAINED T -50 0' --S 1-i
0.8-3:1 HSO SUB3 CLvI RATIOS WERE ONLY.PARTLY SOL. IN HCONME SUB2 AND
SWELLED IN MEOH. FACILITY: INST. KHIM. NAUtet ALMA-ATA, USSR.
UNCLASSIFIED

-1/2':- 009 UNCLASSI FIED.'-'-' !~PRDCESSING DATE--30OCT70
~.TITLE--SYNTHESIS OF HETEROCYCLIC ACETYLENIC ALPHAT~ ALPHA PRIMEt AND GAMMA
TR I OLS -U-
:AUTHOR-(03)-A7-ERBA I N., KUSAINOVAt ZH.ZH.t YERZHANOVt K.Be
COUNTRY OF INFO--USSR
f
SOURCE--IZV. AKAD. NAUK KAZ. SSRs SER. KHIM. 1970r~20(1)t 81-4
WDATE' PUBLISHED ------- 70
._.~SUBJECT AREAS--CHEMISTRY
'.-,TOPICJAGS--CON0ENSATION REACTIONt KETONE, ACETYLENE, HETEROCYCLIC
-NITROGEN COMPOUND, ALCDHOLr CHEMICAL SYNTHESIS
CONTROL ~MARK I NG
--NO RESTRICTIONS
".00CUAENT. CLASS--UNCLASSIFIED
REEL/FRAME--1997/062Z STEP NO--UR/0360/70/020/001/0031/0084
~ICJRC, ACCESSION Nt)'--AP0119534
UINCLASS IF LED

------------
2/2 .009
UNCLASSIFIED P~ROCESSING DATE--30OCT70
ClRC ACCESSION NO-AP011.9534
-ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE TITLE COMPOS. WERE PREPO.
CONDENSATION OF KETONES (SUCH AS SUBSTITUTED PIPERIOUNES) WITH
HEXYNEDIOL, OR BY CONDENSATION OF 4tVIYDROXYp4tET!iYNYLPIPEI~IDONP-S WITH
BETA KETOLS. THUS, L2.6 G 2,67DIPHENYL,4,PIPERIdONE AND 12.8 G
3tMETHYLrljHEA'YNE?3p5tDIOL (1) IN 100~ML TETRAHYDROFURAN (11) WAS .40DED
AT 0-2DEGREES TO 16.8 G KOH AND 150 ML It TO GIVE.52PERCENT
:,:-~..:2,6,DIPHENYL,4,(3tMETHYLt3,5,DIHYDROXYHEXYNYL),4t~PlPEPIDINOL (1111), M.
117-ISDEGREES (LIGROENE); HYDROCHLORIDE M. 262-40EGREES. SIMILARLYt
~'-~:.56PERCENT, 2,2,5rTRIMETHYLr4,(3,METHYL#
-~-~~::3t5pDlHYDROXYHEXYL)p4tPlPERIDINOLt Mo 132-30EGREES (LIGROINE)
.(HYDROCHLORIDE..'A. 160-IDEGREES) WAS PREPD. FROM 5.7 G
2t2,5rTRIMETlHYL,4,PIPERIOONE AND 7.6 G 1. ETMGBR~(FROM 1.93 G MG AND
G.ET8k IN 100 ML II) WAS TREATED WITH 6,68 G.BETA ISONEk OF
...:1,2,5,TRIMETHYL,4,HEXYNYL,4,PIPE.RIDINOL IN 5.0 ML II AND 4.1 G
IN 20 ViL 11 TO GIVE 35PERCENT I,2,5,TRIMETHYL,4,(3,
METHYL#3,5,DIHYDROXYHEXYNYL),4,PIPERIDI,40L M. 139-40DEGREES;
'HYDROCHLORIDE M. 227-80EGREES. SIMILARLY, 63.2PERCENT
212,E)I.'4ETHYL94t(3,METIIYLl3p5tDlfiYDROXYHEXYNYL)r 4*TETRAHYDROPYRANOL M.
78-90EGREES WAS OBTAINED FROM 6.15 G
-TR
2,2qDI#4ETHYL,4tETHYNYLr4tTE AIIYDROPYRANOL AND 4.4 G Ill.
..FACIL I TY: INST. KHIM. NAUKP ALt-lA-ATAs USSR,
U-NCLASSIFIED

USSR UDC 547.241+547.362+547.81+547.823
AZERBAYEV. I. N., DZHAYLAUOV, S. D., BOSYPYOV, Yu. G., YERZHANOV, K. B.2
and SERIKBAYEV, K. S., Institute of Chemical Sciences, Academy of Sciences
KazakhSSR
"Reaction of Dipropargy1phosphorous Acid With Heterocyclic Ketones"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 2, Feb 73, pp 288-292
Abstract: Reaction of dipropargy1phosphorous acid with ~-ketones of the
pyran, thiopyran, and piperidine series in presence of sodium alkoxide
leads to the formation of respective dipropargyl esters of heterocyclic
a-hydroxyphosphonic acids. It-was shown that nucleophilic addition of
dipropargyl phosphite to pyranone and thiopyranones,:in contrast to
piperidones, requires the presence of alkaline catalysts. It is assumed
that the aminoketone acts as a catalyst.
1/1
44

USSR UDC 632.95
KHASANOV, A. S., TSAREV, S. G., KAMAY, G. K%., AZERBAYtV N., GABDULLINA,
N. Z.
"Synthesis of New Chloral-Based Organophosphorus Insecticides"
Alma-Ata, IW:miya atsetilena i tekhnol. karbida kal'tsiya-sbornik (Chemisrry
of Acetylene and Technology of Calcium Carbide--collection of works)
"Kazakhstan," 1972, pp 359-361 (from RZh-Khimiya, No.9. May 73, abstract No
9N476.by T. Ya. Ogibina)
Translation: Agricultural insecticides are synthesized -- ethyl a-naphthyl
-0.0-dichloravinyl phosphate (1) and ethyl 5-naphthyl a.6-dichloro~rinyl
phosphate (11) . Example. 0,228 mole of C13CCHO diluted by an equal volume
of ether is gradually added with agitation and cooling~ to -10% to an ether
solution of 0.228 mole of diethyl a-naphthyl phosphite. The mixture is
kept for I hour at -,.,20*C, the ether is driven off, the residue is distilled
twice under vacuum giving compound I with a 3rield of 68% Cl4Hl3Cl2 04P, boil-
20 1.3370, n20D 1.5648. In a s milar procedure
ing point 150 1*/0 12, d4
compoutid 11 La produced with a yield of 73,37. C1013C1204F, boiling Point
161-30/0.1, d 20 1.3395, n20D 1.5030. Compounds.1 and, 11 are insoluble- in
4
water, and dissolve readily in ether, acetone and other organic solvenLs.
112

USSR
K[USANOV, A. S., et al., nimiya atsetilena i tekhnol. karbida kal'tsiva
"Kazakhstan," 1972, pp,359-361
sbornik
The insecticidal and toxic properties of the chemicals were studied as well
as their myotic and anticholinesterase effect and their curative action
when hypodermically injected in cattle. It is shown:that the toxicity of
I for warm-blooded animals is 1.5 times less than that of chlorophos, while
that of II is two times less, -~;,,hile the larvicidal effect on midge larvae
is ten times greater than that of chlorophos. The curative action of I in
hypodermic injection of cattle was studied in 1.5 and 3% concentrations.
The preparation was used externally in the form of an emulsion with OP-7
in. a dose of 200 ml. The animals were treated in,1111arch. Compound II in
this method of injection is used only in the form of a 32 emulsion with
OP-7. Observations showed that I is 100% lethal and II is 98% lethal, for
ox bot larvae.
2/2
40

USSR
46ZERV.AYEV N.,'AITKF'OZf1AYEVA, M. ZH., TSOY, L. A.
'Method of Producing Mono-or Disubstituted Ureall
USSR Author's Certificate No 281454, field 28/07/69, published 19/03/71.
(Translated from Referativnyy Zhurnal Khimiya, No 4, Moscow, 1972, Abstract
No 4NS92P by T. A. Belyaeva).
Translation: Substituted ureas with the general formula RNHC(O)Nf1CR1_RfC=
CH(I) (R=H, Ph, C6H4Cl; RI and R11 = lower alkyl or CRIR11=cyclical radical)
are produced by reacting nitrourea (II) or RNCO (III) with substituted acetylene
amine. 0-01 mOl %le2C(NH2)C=Cfl (IV) is added-to a solution of 0.01 mol II in
4 ml water at about 20% agitated 30 minutes at about,20', then at 50-55' until
gas bubbles stop evolving, filtered, evaporated in a Vacuum and I (R=11, RI=R"=
Me), is separated, yield 70.7%, mp 151* (from water). ' Similarly, I is produced
(R=H) (given are R1, R", yield in %, mp in 'Q: Me, Et, 77.2, 109; Me, Pr, 89.7,
64. Also vroduced is I [R=11, RIRIIC=cyclohexylidiene (CIID)], yield 90.4%,
mp 129*. 1.1 g III (R=Ph) is added to a solution of 0.88 g IV in 3 ml C6116
with cooling, heated 40 minutes to 40-50 cooled, evaporated and I is separated
W=R"=Me. R=Ph), yield 85.1%, mp 153" (heptane). A similar process produces
I (given are R, R1, R11, yield in %, mp in *C: Ph, Me, Et, 86.1, 111; Ph, Me, Pr,
99.6, 104; M-CIC6114, Me, Me, 93.2. 144; M-ClC6114, Me, Et, 95.8, 123; ni-ClC6114,
Me, Pr, 99.8, 91; Ph, R'R"C=Cf]D, 95.3, 151; m-ClC6H4, R'R"C=CHD 98.1, 133.
59

031-Jlssvi,jNn
Z6gOOlOdV--ON NOISS333V )813-
6900/1900/eoo/()OO/OL/1?1;0/6[)--ON d3lS L.ZOZ/~961--3WV)J3/I33ld AXO'dd
031JlSSVlDNn--SSVI3 IN3WMD-07.
,evw
SNGIIDlblSg'd ON-ONIN If
.LN13W-:'IDVNVW -OVIdiSlIONI I(IdVONVJLS. IVIUISnONI "10'dIND:) kiiIvno--s!)Vl 3 1 d9 I
S33N313S IV130S ONV I"OJAVH3B--SV3bV, ID3runs~1-
OL ------- (13HS] iond 31V.
:69-L9 dd 'Z UN 'OL61 'OAIS3HDVN I Al"ONVIS-3o)inas~.
USSn--DjNl 30 AIIINW3~'
9*0 'ADO
-n- ONlivaino jo V I'd3.1 I'd 0-3
.0.10-
OLd3SBI--31VO ONISS330'dd 031 =1.1 SSV.-IONn -:-~

-2/2 010 UNCLASSIFIED PPCCES,SrNG DATE--18SEP70
~-CIPLC ACCESSION NO--AP0100592
1,ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE QUANTITATIVE METHOD OF
~:--:ASSES54ENT OF THE CRITERION OF OUTDATING, SUGGESTED IN THE ARTICLE, Is
F.OUNDEDON A COMPARISON OF THF USE VALUE wirH THE TOTAL EXPENSES. A
~'~ORIEF CRITICAL REVIEW OF LITERATURE ON THE SUBJECT IS PRESENTED.:
UNCLASSIFIED

USSR
ADILOV., D. A. and AMINOV., B. M..9 Uzbek Scientific Research Institute of
Epidemiology, Mi(YF~6iology, -a-Ra-Tnfectious Diseases
"Clinical Picture of Anthrax in Recent Years"
Tashkent, Meditsinskiy Zhurnal Uzbekistana, No 9, 19721 PP 55-57
Abstract: Study of the case histories of k4k anthrax patients from 1938 to
1970 showed that the course of the skin form of the disease became more benign
after.1950. The number of severe cases and the mortality rate declined sharply
mainly because of the widespread use of sulfa drugs and antibiotics. Carbuncles
appeared more often on the hands -than on the face, possibly owing to change in
the made of transmission of the infection. The te-7.Derature reaction occurred
in about three-four-ths of the patients, or at about t4e~ samelyate as in the past,
but its intensity was less and the duration shorter due to early administration
of antianthrax-globulin combined with antibiotics..

USSR UDC 612,5-087.86
LOGUNOV, A. D., AZHAYEV. A. N., and KOSRELEVA, 0. S.
"Determination of the Coefficients of Mixing for Calculation of the Average
Temperature of the Human Body"
Moscow, Gigiyena Sanitariya,:No 3, Mar 73, pp 72-75
Abstract: In experiments on humans placed for 1-6 hrs into a chamber with
an air temperature of -40, -10, 5, 25, 30, 35, or 40', the heat flow be-
tween the body and the surrounding air, the temperature of the skin, and
the rectal temperature were determined. The subjects on whom the experi-
ments were carried out were nude or.dressed in summer, winter, or between-
season clothing. On the basis of the experimental data obtained, formulas
for the coefficients of mixing corresponding to.the temperature of the skin
and the rectal temperature under various conditions of heat exchange were
derived. Nomographs were plotted which indicate 1) the relation between
the coefficient of mixing for the skin temperature and the thermal insula-
tion of body tissues; 2) the relation between the insulation of body tissues
and the inner temperature gradient of the body; 3) the relation between the
coLifficienta of mixing for the recuil and skin temperatures and Lhe rectal-
skin temperature gradients and also between these coefficients and the
1/2

USSR
LOGUNOV, A. D,, et al., Gigiyena i Sanitariya, No 3, Mar 73, pp 72-75
thermal insulation of the body tissues. With an increasing differencebe-
tween the rectal and median skin temperature, the degree of thermal insula-
tion of the body tissues increased, while decreasing with a reduction of the
inner temperature gradient. At low outside temperatures the thermal insula-
tion of the body surface increased. lt~decreased at high outside temperatures.
2/2

USSR UDC 612.57
AQAY&Yda~ ~.N. Mosccrw
"Special Aspects of Heat Metabolism in Man at High Ambient Temperatures"
Leningrad, Fiziologicheskiy Zhurnal SSSR imeni,I. M. Sechenova, Vol 58, No 3,
1972, pp, 463-468
Abstract: On the basis of measurements performed on human subjects resting in
a thermal chamber at air temperatures ranging from 40 to 80% and a 11cra rela-
tive humidity (10-25%) for up to 60 min., physiological.reactions associated
with heat metabolism are divided into three stages of byperthermia. In the
first stage, body temperature rises slightly from 36.9 (control) to 37.3*C,
heat production decreases from 1.47 to 1.29 Cal/min, thermal:insulation by the
skin falls from 0.3 to 0.12 units, heart rate increasesJrom 69 to 79 beats/
min, arterial pressure is maintaincd, and the total. ace.umulation of heat is
12.1 Cal/mZ of body surface; thus, the body successfully copes with the high
ambient temperature. In the second stage, heat loss lags behind heat produc-
tion so that a large quantity of heat is accumulated (54.8 Cal/m2) and body
temperature rises to 38.8'C; hcrwever, the cardiovasculat system is functioning
efficiently. In the third stageof hyperthermia (body temperature 39.4*C),
circulatory decompensation begins, and a heat stroke becomes iminent.
1/1

:12 012 UNCLASSIFIED PPOCESSTNIG 0ATE--02')CT70
~J,lTLE-CCFANIC DEPTHS -U-
~.XUTHOR--AZF!AZHA, V.
~'COUNTRY OF INFO--USSR
SOURCE--VCDNYY TRANSPORT, MAY 30v 1970,~ P 3t COLS 1-4
PUELISHED--30MAY70
SUBJECT AREAS--MECH.t IND., CIVIL ANO MARINE ENGRt EARTH SCIE~4CES AN)
~-.~-,UCEANCGRAPHY
:,T,UPIC TAGS--SUBMARINE, UNDEPWATER RESEARCH LABORATORY
CONTROL MARKI,NG--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
RECL/FRAME--1989/0990 STEP NO--UR/9028/70/000/000/000310003
CIRC ACCESSION NG--AN0107511
UNE LAS S 1 F j'_E D

V -L --- --- 89

USSR UDC 546.882+620.172.24
AMONENKO, V. 'a., AZHAZHA, V. M.,.ZEYDLITS, M. P., and SHEVCHENKO, S. V.,
Physical-Ifechanical Institute, Academy of Sciences Ukrainian SSR
"Effect of Small Additions of Oxygen and Nitrogen on the Nature of tile
Mechanical Properties-Temperature Relationship in Niobium"
Kiev, Proble-my Prochnosti, No 6, 1973, pp 54-56
Abstract: The effect of oxygen and nitrogen impurities on the nature of the
temperature and strength-ductility properties of niobium was studied. Niobium
of 99.8% purity was used which contained metallic impurities of 0.0917. Ta and
5.10-3% W and Fe, and interstitial impurities of 2-10-3% H2, .10-3% 02 and
2.6-10-3% N2. The mechanical properties of niobium were studied in the 20-900
C interval where it was shown that at a strain rate of 1.6-10-3 sec, at 300,
400 and 550 C, maximum strength properties and minim= ductility are observed.
Height of tile maximums at 300 and 550 C depends on the concentration of oxygen
and nitrogen. The smooth change in the mechanical properties of niobium with
temperature is associated with the deformation dynamics of aging. 3 figures,
1 table, 9 bibliographic references.
80

0 4( ~( C
'jC) '7 2 t'a" ke (i 7
UDC SA9. 374
FEATURES OF TIM sTnucTURE AND PLASTIC. DEFORMATION
OF ZIRCONIUM SATURATED 13Y NITROGEN
AND OX YGEN
V 1'. ard V. A, Finkel'.
Fnxin-ri "g Intitut, of the Ac-d,-tn~
subitted to prose I February 1972 pages 12118-1300
Th, tyerpune of thie work i~ thr ~tutiy of -he rilect of the maturati"n
with nitrogt-n and oxygen at low pri-s-re on the mechanical properties,
feattires (if plailic deformation. mid ~Iructur~ (if rtirconium iodide and
a purcr metal obtained by the zone %melting nit-thod 01.
Specinwris with the given content of g,%4eous impurities were prepared
by saturation of the zirconiurn hands with a %hicimrss of 0. 3 millimeter.
heatt-il by alternating current in it vacuum chamber, a% a renult of the
feeding of nitrogt-a or oxylten through a measuring valve. The tempera-ure
of the specimens was 1200ocLniffrade. the saturation time Z rninutro. the
pressure- of the games 10-5--10- torr. The quantity of gas absorbed was
calculated according to data concerning the rate of abPorption L Z'] and -ao
controlled by chemical analyara. After saturation by gases. the zirconium
ribbons we re anticaled for the. purpose of homogern-m %on for 8 minuteo. at
the Ranic temperaturt- in o vaciturn of I x WE' tore.
The, mechanical propertien were ~todied at room, tempt-rature on
specimenn with dimensions of the working part of ZO x 50 x 0. 1 millimeter
at a conmtani rate of tenAlon 1. 6 x 10-3 secondft' 1. The load wA. mea.
ou red by the DF-0. I specimen dynamm-Ater.
For the study of the crystal structure of xirconiurn, a methodology
developed earlier for obtaining specimens with a temperaturr gradient was
used j 31 : a shaped specimen was heated by alternAting electric current,
and in this cant a temperature difference from 700 to 1400"C was created
105 -

i n i t .Iii, c~o,- if If.,- If ff,- r,- nt ra It, is[ abmt, rpt lust, I fit- I. it it c e it t r l I i oil of
,it t'r. ge n o t- ~ * VX,-o - r I e, I at o ng t he I e I, V t h -,f I he . pe , . . ~ , .; a - .,I,, f ron, t Is s
I, Is,- r-t a . I i of dir i I,,- ~ I rsw n found all a 1. -, 1), - ro I it rv 0Si,-VC .... 1,-r,vot
a 0( phasse tran4forniation (o*rr,K--GPU). while Ilw othor ji,irl WAA
in the 0( -phabe ;it I the tirne.
X-r~&y photographs of the sectiont, of the xpertmen corrvisprindin, to
v;triouq i,aturation temperatures were taken Ili a Debyr chamber with a
diameter of 114 millimeters In CuK,( -radiation, For precision ineassure-
ment of the parameters of the latticen. the zirconi=l wam *ubjected to x-ray
photography according to the reverme photography torthod. and reflections
from planes (211). (1 14) and (Z13) uf the GPU lattice were fixed In the
CuK Cg -radiation,
On photographs of zirconium itatoraied .-ilh nitrogen to a
concentration of 0. 07% with reApvct to inari.. only at .7,t, lines oere
ob"rved; ;it a high content of nitrogen an the x-ray photographs of speci.
mens cooled from a temperature higher,thmi 90(loG, a-pittliort ef certain
diffraction lines occurred. The nature of the splitting of the ho-gonal
reflexes indicates the fact that in these conditions. Inmtrad of art ordinary
fl -- C( transformation (OTi%K--CPU) a tranisforinatinn (OT%K--
Rhomboid) occura.
r.1 Figure 1. PAriurneters of the crystal
lAttice of zirconium
saturated -;th nitroren
at a pressure of 6 x 10-4
A. torr as a function of the
a- annealing temperature.
Ails
Alit
jou foe loolo floo
106

USSR ~UDC 621.79.027
AMONENKO, V. M., AMAMA, V. M., WYUGOV, P. N., GUMENYUK, V. S., and
SIVOKON', V. V.--~~~
"The Possibilitv of Purification'of Chemically Actilr'',
e tretals by Zone Melting
Monokristally Tugoplavkikh i Redkikh Metallov_[Single Crystals of Refractory
and Rare Metals ---'Collection of 1-lorks], Nauka Press, 1971, pp 5-12
-ty melting of
Translation: An installation is described for zone cathode r.
zirconium with a residual pressure of -5-10-8 torr. The heating chamber,
sealed with metal, is evacuated with two oil-vapor pumps, with sorption traps.
Data are presented on the partial pressures of residual gases and their
changes as functions of the duration of operation of the installations with
the sorption traps. It is demonstrated that the use.of the new 5F-4E vacuum
oil as a working fluid in thd oil-vapor pumps is promising for the production
of vacuums of -4-10-6 in metallurgical pipe installations. Data are pre-
sented.on zone Durification of zirconium in a vacuum of 7-10-8-1-10-7 torr.
5 Tables; 6 Figures; 2 Bibliographic refereaces.

USSR 02-
U
I ILL
o: _-rm, V. KCITMN, G. P.,
NE D
"Effect of Titaniwnl Coat-in.-,-r, on the Plasticity of- Eolybdcniw"
k No
Moscow,, F-iziTla i r irrd~,a Crorabo' i 1-hteria-l-Ov.1 7~:ay, Jun 70, Dl) 59-1j2
Abs trac -111: Titantiu7- coadoidr.,-s cause a chan~;e in tae plasticity ol' -olylodenum. The
navare and dej~ree of the effect of the coati4~,s depend o---i z.ie.-~hicl`ness o,, t,.-ie
coatin- the ann, calin~; conditions, and other factors. Titanri~,,::~ un to 1 mdcron
L>
thick cause an increase in the elonj~ation Per -,mit len rth of denwn, af-'er
-1 0 U, . .
annealina in 'he temperature ranG
U U -c of `50-1100 C. Fiilms~110 :-.JLcr.-_)ns thickz anCL MiOre
increase the plasticil;y of molybdetram if -the annealin,-, aft-- co-.tintr
does not, exceed 7rA'C, and they cause emibrjittlevnnt af't*.t2,.- arnealin~; above 89) C.
The mechanism of the effect of titaniwm coatin-s o-- the plastic i)ropertiez of
molyidenwn is discu,,ced. Additional data are given on the effect oil, titanium
coatinZPs on "he -plastic piroperties of iriolybdenum and on the cw,-r~,cs of the pla!;,tici-
zing and enibrittlim,~ effect Of titanium coutinlgs.
Micro-photographs of them o=rPles after various 1wat ti-cat-,rentc ar,~ -prese. t,
it is noi--Led ~What dalrirn_~; the -2,rocess of an:;-_a]d_-_r~, &I.-ffurion of titiani,imm in
the surface layers of molybdenum 'Uakes p3,ace primarily with respect to the lattice
defects, in pArticular, aloiv
-.Ie Srain houndaries. in tiol-'-denw-. the s-ra-rn bound-
aries are the most p-robable centers of fracture. Fracture of polycrystalline
1/2

U.S8R
AM MA V. IM. et al, Fizika i IQIirdL5-a Gbra7ootki 1,1aterialov, 17.10 Dun
PP 59-62
~--.iples of almost always be6ins on the j;rain boundary,
s
U
Zation of ttLe fracture ca-, have a transcrystalline nature. SZ,,c diff sion of
n alon5 the grain boundaries neutralizes t',,t- effect of tlhle
aami--X-M-Tres which usu---I-ly are isolated along tine grain boundaries and harden -k-,*-e
boun-dr---ies. This cecrea-ses the probability of occurrence of centers of frac-Lure
alon~3 -;.he Z.-rain boundaries and leads to a mora- unifoi-m defornmtioa of
This explains the fact that the maxi =,n elongation of the molyludenum, samples is
-; u Lhick after a
reached with a titan.- m film 1 micron nnealing in the temperature
range of IOGO-1110000.
2/2

-112 C40 U NC L'A'S S I F I t D ROCESSING DATE--20NOV70
OF THE blETH00 GF, S EC CNDAkY I ON "ION EMISSION 170 THE
OF, P40CESSES OCCURRING DURING.THL INITIAL STAGES OF TITANIUW
:,".'AUTHCR~.ti'J'4~)-APRAMENKUV, A.D.,~AZHAZHA, V.Plof FOGEL:j YA.14. iSHVAGHKO
V.I.
#all
-C.
C UN T R YF- N FC-- U 5 SR
METALLOV METALLOVEDENIEP VOL. 29, AAR. 1970s P- 5197523
ATE r-LbLI5HEC------70,
-U-BJECT AREAS--MATERIALSo MECH.v IND., CIVIL AND MARINE ENGR
TAGS--TITANIUM, MOLYBDENUM ALLOY,'METAL VAPOR ;DEPOSITION,
315LIGGRAPHY, ~METAL CC-ATINC~,.ItJTERMETALLIC,COMPOUtil)r REFRACTORY METAL,
.-,METAL f;IFFLSIONI SP EC T R OGRA PH I C ~'A NA L Y S I S
kAki~ING--NO RESTRICTIONS
~;.DGCUMENT CLASS--UNCLASSIFIED
STEP NO--UR/0126/70/02~9/000/051