SCIENTIFIC ABSTRACT CHERNOGRYAZSKAYA, N. P. - CHERNOV, A. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002200530006-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 99
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

212 016 UNCL.ASSIFIED PROCESSING DATE--090CT70
CIRC ACCESSIuN NO-AP0116823
ABS-fs~ACT/EXTRACT--(U) GP-0- A65TRALT. EXPTS. HAVE bEEN CARRIED OUT iiITH
STEEL CASTINGS (0.3PERCENTC) OF DIFFERENT SHAPES AND CROSS SECT104N
AAEAS, TO DET. THE EFFECT OF SHRINKAGE ON THE SURFACE PROCESSES
GCCURkING DURING THE COCLIAG PERIOD (1200-800DEGREES) IN A SA;,jD MOLD.
AMONG OTHER FACTORS, SCAB FORMATION IS INFLUENCED BY THE TIME OF CONTACT
BETWEEN THE HOT METAL AND THE MOLD SURFACE; HERE THE DIRECTION AND AMT.
OF SHRINKAGE ARE IMPORTANT. THE CHARACTER OF THE 5CAo FORMS AND
DIFFICULTIES INVOLVED IN THEIR REMOVAL ARE DISCUSSED 43N THE BASIS OF THE
POSITION OF THE CASTING SURFACE UND'ER CONSIDERATLON, WITH RESPECT TO THE
MOLD, THE CHARACTERISTICS OF THE MOLOING SAND, THE INTENSITY OF OXIDN.v
AND OF SILICATE FORMING PROCESSES AT THE SURFACE.

112 020 UNCLASSIFIED PROCESSING DATE--160CT70
IN NONSPECIFIC ULCEROUS COLITIS -U-
AUTHOR--CHERNOGRYAZSKAYAt N.P.
COUNTRY OF INFO--USSR
SOURCE--TERAPEVTICHESKLY ARKHIVt 1970, VOL 42v NR 51 PP 42-44
DATE PU13L ISHED------70
~.SUBJECT -A.REAS--BIOLOGI-CAL AND MEDICAL SCIENCES
TOPIC TAGS--HEMATOPOESIS, LARGE INTESTINE, LESIONt DIGESTIVE SYSTEM
DISEASE, ANEMIA, DIAGNOSTIC MEDICINE
CONTROL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/FRAME--1998/0015 STEP NO--UR/0504/70/042/005/0042/()044
CIRC ACCESSION to'0-0012071.5
UNCLASSIFIED

212 020 UNCLASSIFIED PROCESSING OATE--16OCT70
CIRC ACCESSION NO--4POI20715
ABSTR ACT/EX TRACT-- (U) GP-0- ABSTRACT. THE AUTHOR STUOIED HEMOPOIESIS IN
PATIENTS WITH NON SPECIFIC ULCEROUS COLITIS. THE PAIPHERAL BLOOD vl,*,i
STUDIEU IN 180 PATIENTSP MYELOGRAMv IN 25. IT WAS ESTABLISHED THAT JON
SPECIFIC ULCEROUS COLITIS WAS OFTEN COMPLICATED BY OEVELOPMENT OF
HYPOCHROMIC, HYPOGENERATIVE, HYPOFERRIC ANEMIA. Di:LAY OF
HEMOGLOBINIZATION OF NORMOBLASTS AT THE STAGE OF BASOPHIL AND
POLYCHRUMATOPHIL NORMUSLASTS WAS DETECTED IN THE MAJCRITY OF PATIENTS.
THE INCREASE IN THE ERYTHROCYTE COUNT AND A SHIFT IN THE LEUCOCYFARY
FORMULA TO THE LEFT IS DIRECTLY DEPENDABLE UPON'THE M.ARKEDNESS OF THE
DESTRUCTIVE PROCESS IN THE INTESTINE. THE INCREASE IN THE PLASMOCYTE
COUNT, THE PRESENCE OF PLASMOCYTIC ILANUS AND EGISINOPhILIA TESTIFY TO
THE PRESENCE OF ALLERGY IN NONSPECIFIC ULCEROUS COLIT15. THE
PATHOLOGICAL CHANGES OF THE PERIPHERAL BLOOD AND BONE MARRO4 IN
NONSPECIFIC ULCEROUS COLITIS DEPEND UPON THE CLINICAL FORM, SEVERITY OF
THE COURSE, STAGE OF THE DISEASE ACTIVITY AND ARE NOT ASSOCIATED WITH
THE DURATION OF THE DISEASE. FACILITY: LABORATORIYA
PISCHEVARENIYA I OBMENA VESHCHESTV INSTITUTA AKUSHERSTVA I GINEKOLOGII
AHN SSSR, LENINGRAD.
UNCLA-s-SIFIED

USSR
VIDC 591.1,15
A. T. ZMNIUKOVICH, N. V. KIIR 111 C 13
and V Nf
"On the Mochani-lism of the Action of lcuizin Radiation on Acti-vitv of
Amipotransferase i-n the Brlain of TWIlite Rats"
Nauch- do!-11. -- .,ssh. M-01. r1. (Scicntific of rlie tv.
Biolcljival Scfonccs) 5 191-1, ~Io '91, pp 43-248 (from
Khi,.~,.iya, No 21, 25 JLn 7-2, Abstract INo 2--F272)
Trpmir;] ation: 11-ic of transamatnation -,)rocess,-!s catalyzec! 1,)~, tho
-inA I !
4-,; 1-n
tile effect O-L, )II Z, Of 700 roull:. U-) a
th-c!
al"d -Jusc, Lo in tlt-
i.s
especialiv Oil uhe ftrsc and scv~:-,Ith d.,iys allter exprisure v0
tion. I s u
I/I

Radiobiology
USSR UDC 577-15
CHWOGUZOV~ V. Lt. and PIKULEV, A. T., Belorussian State University
"The Effect of X-Ray Irradiation on Aspartate Aminotransferase Activity in Brain
Mitochondriall
Minsk, Doklady Akademii Nauk BSSR, No 4. 1970, pp 367-369
Abstract: Whole-body, single X-ray irradiation of rats with 40 r increased the
activity of soluble aspartate aminotransferase in brain mitochondria within 24
hours by 21~ compared with the control. This increase was at the expense of the
bound form of the enzyme, because total aspartate aminotransferase activity in the
mitochondria. remained unchanged. The observed phenomenon is ascrfbed to partial
liberation of the bound farm of aspartate aminotransferase, due to physicochemical
changes in the properties of the mitochondria brought about by ionizing radiation.
ill

USSR
UDC 547.26.119 + 543.422
GARAYUROVA, V. S., KUZ'MIN, V. K., qffga~~ and SHAGIDULLIN,
R. R., Kazan' Chemical Technological Institute Imeni S. 1-1. Kirov
"Spirocyclic Esters of Arsonic Acids"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 9, Sep 73, pp 1937-1939
Abstract: New esters of arsonic acids and dihydric aliphatic glycols have
been synthesized. The reaction consisted of refluxing a mixture of the
appropriate substituted arsonic acid, ethylene glycol and benzene in a
system equipped with a Dean-Stark trap. The cyclic structure of these
esters has been confirmed by IR spectral data.

USSR
UDC 541.127.547.242
CHERNOKAL'SKIY, B. D., and VOROB'Y-EVA, L. A., Kazan' Chemical-Technological
Institute Imeni S. M. Kirov
"Basicity of Tertiary Arsine Oxides and the Kinetics of Their Reactions With
Alkyl Halides"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 9, Sep 73, pp 1939-1943
,Abstract: Thermodynamic basicity constants of five tri-n-alkylarsine oxides
in water were determined. It was shown that in this case the size of the
hydrocarbon radical has no effect on pKT. It was found that the reaction
of tri-n-alkylarsine oxides with butyl iodide is of a general second degree
order, but first degree order in respect to the trialkylarsine oxide. The
relationship of the reaction rates of trialkylarsine oxide!) and 01c itruc-
tures of alkyl halide is analogous to that of the SN2 reactions.
1/1

USSR
UX 54-7-2112
GELT011D, A. S -, GALYA",~T-;TDTjjOV, YU. G., 141-1,01,10VA, V. G.) CATAUIX,ima.~ R. 101r..1
a
nd IIUBNOKWSIUY,.-B- D., Kazan I Chc,,idcal-Technojo,ricaj - InL;t t-, n
c j Lte Tr
S. M. Kirov
"Synthesis .3f Some Tertiary Arsines and rEncir StLIfides"
LeninU,Yad, Zhuirnal Olushche,7 Khinui, Vol 42 (1010, Iqo 9, Sep 72, pp 1962-1c,-163
Abstract: A w.-jc-; of p- Itricl In-rmbul- 'Ifutc-d oxider, and. rulfidcs- of aryl(IIaL-hyl-
and ary1diphenylarsiries has been syntlicsized by known methods. Yicld~; and
meltinG paintG are, tabulatcd.
1/1

USSR
UDC 547.242
GAIMILOVY V. I.J, KHLEBITIKOV., V. N., GAVRILOVA, G. R., and CHERNOKAVSKIYP B. D.;
Kazan' Chemical-Technological Institute Imeni S. 14. Kirov
"Synthesis of 10-Alkylphenoxyaraines"
Teningrad, Zhurnal Obshchey Xhimii, Vol 42 (1o4), No 9, Sep 72, pp 1963-1966
Abstract: A series of new 10-alkylphenoxyarsines was synthesized by reacting
appropriate alkylmagnesium halides with 10-chlorophenoxjarsine in benzene or
toluene solution. Following compounds were obtained and chai-acterized: 10-
propyl-, isopropyl-, n-butyl-, 2-methylpropyl-, tert-butyl-, n-amYl-, 3-methyl-
butyl-, n-hexyl-, n-heptyl-, n-octyl-, cyclohexyl-, allvl-, benzyl-, and
phenylacetylenylphenoxyarsines.
1/1

XWR UDC 541.13:541-515:543-422.27
ILIYASOV) A. V.) YJIRGIN, YU. M., MOR(-0-VA, I. D., CIU3RT,-TOKhJ,'SKIY,, B.:D.)
'U MV~,' A.'SH., and
VIVIIIA A. A.) IVU
.4 1,SL'ITMV B. V., GLL'FOZTD, A. S.,
GALYM~ETDITTOV YU. G., Institute of Organic and Physical Chemistr~j, Imeni A. Ye.
Arbuzov., Acad. Sc. USSR, and 11,izaal Chemical-Technolozical Institute Imeni S.
Kirov
"Electrockiemically Generated Free Radicals. 9 Cornamication. Reduction of Some
Hitrophenylarsine Derivatives and EPR S-oectra of Their Anion Radicals"
Moscov, Izvestiya Akademii Hauk SSSR, Serlya Vltimiche!:ka~-a, NO 10, Oct 72,
pp 2174-217EI
Abstract: The mecbanisr, of polarographic reduction of nit rophe nyldiethyl rsiness
and their oxides and sulfides in an aprotic medilun ~,.ras, stu_,'iedl. These eomnounls
exhibit two red~uct-ion uaves, the firot one co2,responding to a cne-el-.~ctron wave,
the procesn being reversible. The second ~hm,,.rc i,- typical of a ')"-procesm A
dia._--ram ?or the sequentiall chemical processes of these Com--po-ands after the
capture of second electron- has been proposed. Both -.iavas rz!present a stelnise
oxidation of the unotable dianion of the substib-ited nitrob-2r,-crc; the phc!jiyl
ring -- arsenic systun. remains untouched in thio p-rocess. Ncriel orlr_,anoarsine
anion radical-s have I-,een obtained by electrochemical reduction and ztudicd by
t~,e EPR method. 'Bilocalization of the unpalred electron in theoe rinion
1 2

USSR
ILIYASMIJ A. V., et al., Izvestiya Akademii Nauk SSSB, Seriya KhiT-Acheskaya, 11o
10, Oct 72, pp 2174-21-18
radicals has been imrest-i.,7ated analyzing possible reasons for a considerable
decrease of the spin density on the arsenic atom during the transition from
tetracoordinarted Prsenic atom of the anion radicals to a ".1ri-coordinated- one.
2/2

USSR
UDC 546.19 + 541.124.7
TSENNTOVSKIY, V. M., G-%-NtkYUROVA, V. S. , ZAGIDULLINA, D. Sh., and
CHERNOKAL'SKIY. B. D., Kazan' Chemical Technological Institute Imeni
Kirov
"Ionization Constants of Arylarsonic Acids in Nonaqueous Media"
Leningrad, Zhurnal Obshchey Khimii, Vol 42 (104), No 12, Dec 72, pp 2702-
N05
Abstract: The pK of eight arylarsonic acids were determined in nonaqueous
media -- dimethy1formamide [DMFA] and dimethylsulfoxide [DITS01 by means of
potentiometric titration. In both the DMFA and DMSO arylarsonic acids
titrate as monobasic acids with the exception of nitrohydroxyphenylarsonic
acid which acts as a dibasic acid in DMSO. Depending on the substituent
in the phenyl ring, the acid strength diminishes in the following order:
N02 + OH>N0,),> H> CH3 >CH30 N112- Ortho substituted nitro- and amino-
phenvlarsoni~ acids are weaker than their para substituted analogs.
Analyzing the DK values in different media shows that the arylarsonic
acids increase in strength going from DHFA to DMSO to water, In comparison
to water, DMFA and DMSO exert a differentiating action on arylarsonic acids.
1/1

USSR
uDc 547-26.119
QTFRUNWA T.
GAMNYUROVA, V. S., KRALICHKIM, M. G., Kazan' Chemical
Technolo7ical Institute imeni S. M. Kirov
"Synthesis of Aromatic Esters of Arsonic Acids"
Ivanovo, Izvestiya vysshikh uchebnykh zavedeniy, 19iimiya i It-himichesk--ya
tekhnologiya, Vol TV, No 7, 1972, PP 1023-1o26
Abstract: A study was made of the possibility of sn,4hesizinr., aromatic esters
of arsonic acids. Direct esterification of these acids by phenols did not
lead to the exTected products, but transesterification of the dialkyl esters
of arylarsonic acids by phenolo -in the presence of catalysts was cuccessful:
RAs(O)(OA1)0 +PhOjj.~%A.,q(O) (ffl'll) +Alkoii.
2 2
The alkyl esters of the arsonic acids were obtained by the Kolditz-flac-P, method
[Z. aviorffan. und allr1em._ Chem., No 307, 304, 1961]. Transef~-,tcrification of
the dialkyl esters of' the arylarsonic acids was performed in xylenes, which
make the reaction possible at a comraratively hi~:;h temperature ard form
azeotroDes with the aliphatic alcohols. Sodi,-un rl-,enoxidc and also perchloric
acid, sulfuric acid and glacial acetic acid were used as catalysts. Glacial
acetic acid was the best catalyst. The ~;ynthesizcd aror.:ttlc erterE; arld sarile
of their properties are tabulated the lowest representatii,i!.,; of' the ,;curies of
1/2 17

USSR
GAIA&YUROVA, V. S., et al., Izvestiya vysshikh uchebnykh zwiedeniy, Khimiya i
khimicheskaya tek-hnologiya, Vol XV, No 7, 1972, PP 1023-1026
compounds are high-boiling, viscous and very hygroscopic
crystalline esters were isolated with abnost quanbitative
highly hygroscopic. The infrared specti-um taken for the
n-tolylarsonic acid confirms its proposed structure.
liquids. The
yield and are
diphenyl ester of
2/2

USSR
UDC 542.945+542 .957-2-1-547.852.7
KAMAY1 G. Kh. [decd.), QWWQW'AT1c;TCTY. Gmnuv, V. I., TSENMISKIY,
V. M.., and TSENTOVSFAYA., V. S.; Kazan' Chernico-t--chnological Institute imeni
S. M. Kirov
"Quantitative Separation of the Combined Effect of the Substituent in Para-
Substituted 10-Aryl-5,10-DihydroDhenarsazine Oxides"
Kiev, Teore-I.-icheslmya i EksperimentalInaya Khimiya, Vol 8, No 3. 1972,
pp 4oo-W2
Abstract: Quantitative evaluation was carried out of the transmission of the
effect of the substituentl through the induction and polar conjui,-atior. effects,
in para-substituted 10-phenyl-5,10-dihydrol)henarsazii,e oxides (I), on the
protonation. of oxygen at the arsenic atom. By solvin,- the equation correlaV _nrl
the basicity of I with (TO and