SCIENTIFIC ABSTRACT FREYDIN, YA.V. - FRIDLAND, S.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002200820010-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

2/2 019 UNCLASSIFIED PROCESSING DATE--230CY7(
CIRC ACCESSION NO--AP0119493
~ABSTRACWEXTRACT--(U) GP-0- ABSTRACT. ME CYCLOHEXANECARBOXYLATE (1) (60
GVWAS OXIDIZED WITHOUT CATALYST 34 HR AT 130DEGREES IN A GLASS COLUMN
BY Ov INTRODUCED THROUGH A POROUS BOTTOM AT 8 L.-HR.' BY CHKOHATOGRAPHIC
ANAL. THE COMPN. OF THE REACTION MIXT.,WAS: I50,2PERCENT; 14E
1-HYDROXYCYCLO14EXANECAR30XYLATE 16.9PERCENT; 2-OXOHEPTANEDIOIC ACIDP lr~
EINOLIC.FORM (2-HYDROXY-2-HEPTENEDIOIC ACID) AND,'THE~LACTONE OF THE
-ME
LATTER.6.3PERCENT; oklONO 1,2,,41BUTANETRICARBOXYLATE 7.8PE CENT;
HELANEDIOIC AICD 4.5PERCENT; AND OTHER COMPDS. iCONTG. SOME
14.3PERCENT. THE NATURE OF THE PROOOCrS SHOWS THAr THE
~TERTIARY C-H BOND IS MOST VULNERABLE TO 0 ATTACK, TO FORM A
HYDROPERIOXIOE. SINCE THE TERTIARY. C OF I IS IN THE ALPHA POSITION, THf
ALPHA FREE RADICALSt WHICH FORM ON DECOMPN. OF THE PERIOXIDE, ARE
STABILIZED THROUGH CONJUGATION WITH:THE PI ELECTRONS OF THE CARBOXYL
-.GROUP. FACILITY: VSESd NAUCH.-ILLSED.: INST. NEFTEKHIM.
PROTSESSOV, LENINGRAD.

.. . .... . .. . . .
USSR UDC 612.8220-06:612.621.33/014
GOFTUN, S. S. and J..,.Xhair of Eidustrial Pl~ysiology md Psycholog-T.
Institute of the National Economy, and Laboratory of Medical Radioclectrollics,
Scientific Research Institute of Labor Ifjgiene aid G~.Icupationad Discases,
Sverdlovsk
"Multichannel Radioelectroencephalogi-aphic Stud~lr of Man During Nei-vous md
Raotional Stress"
Moscow,, BrtMetent EksTerimentallnoy Mologii i IiBdit6iny, Vol 70, No 11 , Nov 70,
PP,19-22
Abotract: A Re-diotelernstric study vao conducted to ddta-i-mine the bioclecturica-1
'a 'Aie s t rerve d
activity of the brain in 10 students taking an eximInation. re u! s ale
an increase in slow activIty instead of the expected, clapreasion. Slou, MC.,~-
amplitude, oscillations predaananted, especially in the occipital mgdons of cria
or -both hemispheres, occa--icnally alternating with lGw'~-Mnljlude CscillAtions.
~ktile the students were thinking -r-hat to irrite, and vith th~3 eyes temporarily
closed, more or less pronounced alpha activity was rec rded in all of the 1fa1s.
1/2

USSR
GORMN and FRMEI., Yk. V., PyulleLen' Eksperimentallnoy Biologii i M2dit-
Sa so>
siny, Vol 70, No 11, Nov 70, pp 19-22
The importance of stress is sh(Mla by the fact that thwe EIM shifts did not tzdke
place iihile the students weare attonding class peLor td, the ocwnination period.
The appearance of the slow rh~rthm is regarded as an indication of increased act-
ivity of the cortical md aubcortical. elements, rather'~than of predominance of
the inhibitory processes.
2/2

112 026 UNCLASSI FlIE0 OROCtSSING DATIE--18SEP70
,TITLE--SOLUBILITY OF ACETYLENIC HYDROCARBONS IN THE N.tq,N-,Nl TETRAFTHYL
.-GLUTARAMIDE -U-
~'~AUTHOR-(02)-FREYDLIN9 G.N.s BUSHINSK[Yi Val.
.--COUNTRY:OF INFO--USSR
PRIKL. KHIM. (LENINGRAD) 1970v,43(21 3~5-91
-'~DATE PUBLISHED ------- 70
SUBJECT AREAS--CHEMISTRY
TAGS--ACETYLENE HYDROCARBON# AMIDE, SOLUBILITY, PRESSURE EFFECTI
ENTHALPY, ENTROPY
..'CCINTROL MARKING-NO RESTRICTIONS
..-,.DOCUMENT CLASS--UNCLASSIFIED
REEL/FRAME--1987/0336 STEP '4!J---UR/0080/'10/0431002/0,3n5/0391
CIRC ACCESSION NO--AP0103991
UNCLASS I F IE 0

il t
UNCLASSIFIED ~:PRCCESSING DATE--18SEP70
212 026
-~CIRC ACCESSION NO--AP0103991
'ABSTRACTIEXTRACT--(Ul GP-0- ABSTRACT. T14E SOLY. ;~OF C~ SUB2 H SUB2 (1),
METHYLACETYLENE (11), CH SU82: CHC:CH (111), !qC:CC.,CH (IV), ANO CO SU32
IN DRY AND WET NtN#N#rN' TETRAETHYL GLU~ARAMIOE ~(V) WAS STUDIED AT 2, TO
50DEGREES AND VARIOUS PRESSURES. THE SOLY. OF THESE HYoRnCARBONS
INCREASES WITH THEIR MOL. WT. DEVIATIONS FROM THE HENRY LAW WERE
OBSERVED AT LOW PRESSURESe THE SOLY. DECREASES ~WITH 114CREASING WATER
CONTENT. THE DATA FOLLOW THE KRICHEVSKI EQUATION LN(P SU62-N SUB21
EQUALS LN K MINUS BETA(1-N SUBI PRTMEZ)s WHERE IP SUBZ IS THE EQUIL.
PRESSUREt N SUB2 THE MOLE FRACTION OF GAS IN SOLN.,,N SUB1 THE~MOLE
,FRACTION OF SOLVENT IN THE LIQ. PHASE, K THE HENRY COEFF.9 AND'BETA A
CONST. CONSTS. K AND BETA AND THE ENTHALPY AND THE ENTROPY OF MIXING
ARE T4BULA-TED., THE, SOLY, OF, THESE COMPO.S., IN, V 1.5 BETTER, THAN THAT IN
LPVINYLiPYRROLIDONEP SO THAT V IS RECOMMENDED A&~A SOLVENT FORITHE SEPN.
OF THE PRODUCTS IN C SUB2 H SUBZ PRODUCTJON.
UNCLASSIFIED

USSR UDC 542 -97:547-263,546-11.547-5911-3
SHARF V. Z. FRE SYM
4~tjKff-) MUTII) V. ff., LYS K, T. V., Institute of
Organic Chemis ry Imeni H. D. Zelinskii, Acad. Be. USSR
"Investigation of the Homogeneous Hydrogen Transfer From 2-Pen-Canol to
Cyclohexanone in the Presence of Tris(triThenylphosphiiie)-dielilororuthenium. and
a~Base"
Moscow, Izvestiya, Akademii NaLik. SSSR., Seriya MityrAche-Anya, Wo 10, Oct 72,
PP 2195-2198
Abstract: Base accelerates the redaction of cyclohexan,one throijgh hydroFen
transfer from 2-pentanol as well as its hydrogenation;.a~nd cond-u'nsation in pres-
Crice of the tri~.(triphenylrhorniiiziL-)dicliloronithetziv-m 06LIDILIX. Uie hydrog
,an
transfer reaches a raxinim at a bace concentration of I',64-10-31,1/1 ander, zirCon
atmosphere and at 4.oB_lo-3m 1 under hydrogren. The degree ot hydroger-qtion of
the ketone by hydrogen and its condensation increase with increasing concentra-
tion of thQ base. Raisin" the te-merat'iire from 50 to 811-00 results in a bi,,Iier
rate of hjdroggen transfer; the rate of hyd-roVe-nation rea~-.Ihin(- a Too.
This evidently is due to the fo-r-ration oC mrious intar;neliatr~ coq)lexes
catalyzing these processes. Ilia duration of the process has practic,,illy no
effect on all or the processes discussed.

'USSR
UDC 547-971.2
VPPV'nT-TM T...Q6,
SHARFY V. Z.Y KROMIYY V, N., and t`:X1C11SR1MK0VA) S. I.
'Institute of Organic Chemistry imeni N. D. Zelinskir, Academy of Sciences USSR
"An Investigation of the Reduction of Cyclohexanone~with an Alcohol in the
Presence of Tris(triplienylphosph-ine)dichloro thenit Im"
ru I
Leningrad, Zhurnal Organicheskiy Ehimii, vol 8, vyp,'5, "wr 72, PP 979-931
Abstract: The authors investigated the homogeneous catalysis by tria(triphenyl-
phosphine)dichlororhitthenium of the reduction of cyclohexanone with aeveral
five- to seven-carbon aliphatic alcohols. Reactions were:conducted under
reflux condenser under an atmosphere of argon or hydror-,en, and analysed by gas-
liquid chromatography. Me low yield of cyclohexamc~l shows that condensation
is a side reaction. The reaction rates for various degrees of substitution
on the alpha carbon were studied. They showed,a correlation between increased
steric hindrance and slower rate of reaction. The i~termdiate fomation of
a hydride of tris(triphenylphosl)hin,e)dichlororliutlieniixrr, was st4rgested as a
irechamism. Hydrogenation by the ambient medium cont~-ibutes to the reduction
of cyclohexanone.
1/1

USSR UDC 547.315.2
LITVIN, Ye. F. , and TOPURIKE, L, V,,, Institute of Organic
Chemistry imeni IN. D. Zelinskiy, Acad. Sc. USSR
"Study of the Direction and Mechanism of Homogeneous ilvdro enation of Dienes
9
in Presence of Tris-(triphenylptiosphine)rhodium Chloride"
Leningrad, Zhurnal Organicheskoy Khimii, Vol 8, No 4,:Apr 72, pp 669-674
Abstract: Hydrogenation in presence of RhCI(PPI13)3 was studied using
cis-1,3-pentadiene (I), trans-1,3-pentadiene (II), 2,3-dimethyl-1,3-
butadiene (III), 2-metliyl-1,3-butadiene (IV), 1,3-buta~diene (V) and
1,4-pentadiene (VI); for comparison, monoo lefines were also hydrogenated.
The hydrogenation rate depends on the strudture of the dienes, decreasing
in the following order: (VI) (1) (11) . (III) , (IV) The conjugated
diene C=C bonds are hydrogenated much more selectively over RhCl(FPh3)3
than over rhodium black. (IV) adds hydrogen preferentiallyat the 1,2-
posit-iont while (III) does it exclusively so. During~the 1,4-addition~
4 of hydrogen, M reacts Predominantly in the cis-conf6rmati :on, while
(VI) does it in the trans-conformation.

~,PROtESSING DATE-30OCT70
-.1/2 010 UNCLASSI IE01
CCNVERSION MECHANISM IN THE PRESE~CE.OF ACID CATALYSTS. 1.
CONVERSION OF 1,39PRGPANEUlGLv;I,3o8UTANEDIOL At4D BETA OXIDES ON CALCIUM
~~,',AUTHOR-(04)-FREYDLINP L.KH.vSHARF, V.Z.f~BARTOKii!M., o4tZARYAN, A.A.
::~tOUNTRY OF INFO--USSR
,~,~_SGURCE-IZV. AKAD. NAUK SSSR. IER.~K~Hl'm. 1970t (2) 3LO-14
~:,`DATE PUBLISHED-70
..SUBJECT,AREAS-CHEMISTRY
TOPIC,TAGS--PRQPANEv--BUTANE# HYDROXYL RADICALS ORGANIC OXIDE, ACID
CAT A LY S I SFURAN# EPOXIDE, KETONE
_.CCJ4TR0L MARKING-NO RESTRICTIONS
~-DGCUMENT CLASS-UNCLASSIFIED
'PROXY REELIFRAME-200010749 STEP NG--UR/0062/70/OiO(1/002/031010314
~CIRC ACCESSION NG--AP0124419
UNCLASS-1 FIED

Olt) UNCLASS.IFIED" 1.)ROCESSING DATE-30OCT70
CIRC ACCESSION NO-AP0124419
AESTRACT/EXTRACT--(U) GP-O- ABSTRACT. THE PRODUCTS FORMED BY PASSAGE AT
Z75-350DEGREES OVER CA SUB3 (POLSUB43 SUB2 OF Ho(cH SU82) SU83 OHr
.-TETRAHYOROFURAN, AND ALLYL ALC. WERE TABULATED FOR EACH TEMP. IN
25DEGREES STEPS. SIMILAR DATA ARE REPORTED FOR HO(CH SUB21 SU82 CHMEOH
AND 2,METHYLTETTRAHYDROFURAN, BOTH RUN OVER.230-I-OODEGREES. THE
1,3901OLS ARE CONVERTED INTO A MIXT.'QF SATO. AND UNSAT6. ALCS.,
ALDEHYDESv KETONES, EPOXIDESt AND OTHER COMPOS. iDEHYDRATION OCCURS BY 2
PATHS TO AN UNSATO. ALC. AND TO A CYCLIC OXIDE, WITH INTRAMOL.
CYCLIZATION BEING PREDOMINANT. OXIDES ARE THEN~~IICONVERTED BY
ISOMERIZATION TO UNSATD. ALCS. AND CARBONYL COMPDS. MUCH OF THE SATO.
ALCS. AND UNSATO. ALOEHYUES IS FORMED BY THE H TRANSFER REACTIONS.
2,2,DIETHYL,1,3,PROPANEDIOL GAVE ILPERCENT 3.0,01ETHYLTRIMETHYLENE
OXIDE, 18PERCENT ISOMERIC HEPTENOLSt.AND 71PERCE14T MIXED PRODUCTS AT
300DEGREES; 2,BUTYLe.193tPROPANEOICL GAVE NO.TRIMtTHYLENE OXIDE DERIVS.
BUT,20PERCENT ISOMERIC HEPTENOLS AND 80PERCENT Ml XED PRODUCTS4
2,BUTYLTRIMETHYLENE OXIDE WAS 96PERCENT CONVERTED TO ALCS. AND OTHER
PRODUCTS AT-30ODEGREES. FACi LLTY: INST*.,IORG*: KHIM. IM.
ZELINSKOGOv MOSCOWfp USSR.

'OROCESSING DATE-30OCT70
0 14 UNCLASSIFIED
OF 1,3 DIOL CONVERSIONS IN THE PRESENCE OF ACIDIC
CATALYSTS. 2. CCNVERSION OF: 2,4;,PENTANEDIOL AND'~ METHYL 2t4 PENTANEDIOL
.:~AUTHOR-(03J-SHARF# V.Z.o FREYOLIN' L.KH.or ANt A.A;
NAZARY
-USSR
,CCUNTRY-OF INFO t
,'~SOURCE-IZV. AKAD. NAUK SSSR, SER. KHIM. 1970,,Mi~ 597"6027
zDATE PUBL ISHED---70
T;SUBJECT AREAS-~HEMISTRY
-_JOPIG TAGS-CHEMICAL--REACTION MECHANISM, PENTANE, AiLCOHOL, CATALYST,
DEHYDRATION, STEREOCHEMISTRYt CARBONYL COMPOUNDr JSOMER DIENE
CCNTROL MAAKING-NO RESTRICTIONS
.~DOCUMENT CLASS-UNCLASSIFIED
TROXY REEL/FRAME-2000/0839 STEP ND--UR/0062/'10/0(30/003/0597/C6O2
CIRC ACCESSION NO--AP0124506
U IN C L AS S 11: 1110

_213 0 14 UNCLAS IFIEO~~. AOCE~_~ING DATE--30OCT70
P
C I RC, ACCESSION NO-APO124506
i~:*ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE CONVERSIONS OF 2,4 PENTANE01OL
AND ITS 2 ME ANALOG OVER CA-SUB3.(PO*SU134)SUB2 OR AL SUB2 0 SUa3
CATALYSTS-IN THE TEMP. INTERVAL 140-360DEGREES WERE 5110kN GRAPHICALLY.
THE DEHYDRATION OF THESE ALCS. OCCURS~SPECIFJCALLY IN RESPECT UT THEIR
STERECCHEMISTRY AND RESULTS IN TRANS 1,3 PENTADIENE FRGM THE LST ALC.
ALSOP APPRECIABLE DECOMPN. TAKES PLACE: THE PHOSPHATE CATALYSTS LEADS
TO ME SUB2 CO AND ISO PROH, WHILE AL SUB2 0 SUB3'iGJVE!)' ALSO OSME ACH.
THE CARBONYL COMPDS. ARE FORMED BY EITHER ISOMERI ZATION OF DEHYDRATION
PRODUCTS SUCH AS THE EPOXIDE OR UNSATD. ALC. OR BY DEALOOLIZATION OF THE
KETOL FORMED AS AN INTERMEDIATE. IN THE CASE CJF~iHE 'HUSPHATE CATALYST
THE CLEAVAGE IS CAUSED BY H TRANSFER FORM THE HO PROUPS.OF THE 0101- TO
THE CARBONYL GROUP TO FORM THIS KETOLv WHICH THEN CLEAVES BY
DEALDCLIZATION. THE REACTIONS OCCUR IN THE 100-50DEGREES INTERVALt AT
WHICH DEHYDRATIGN CANNOT TAKE PLACE. OVER-AL SU132 () SUL13 THE DECOMPN.
OF THE DIOL IS LESS PRONUUNCED AND CLEAVAGE*VIAJHE; Kl.JUL IS INHIBITED
BY H SUB2 0 GENERATED IN THE REACTIONIOWLNG TO POISONING OF THE
CATALYSTS IN RESPECT OT THE H TRANSFER REACTION. lUEHVDRATION OF THE IST
DIOL OVER CA SUB31PO SUB4)SUB2 AT 290DEGREES YIELDS MIXED UNSATD. ALCS.
CONTG. 68PERCENT 4 PENTEN ZOL AND 32PERCENT TRAN&I,3 PENrEN 2 OL, WHILE
GREATER THAN 325DEGREES THE PRODUCT IS~ONLY 4 PENTEN 2 UL; AS THE TEMP.
JS RAISED ThE YIELDS CF THESE ALCS. DECLINE AND TlfAT (IF oIENE RISES, AND
THE FINAL PRODUCT CONTAINS 75-LOOPERCENT TRANS PIPERYLENE AND
-0-20PERCENT CIS ISOMER; THE YIELD OF t94 PENTADIE19E 15 LESS THAN
5PERCENT*
UNCLASSIFIED

USSR UDC 519.2+519.9
VEMEL', A. D. and FREYDLIN, M- I
S all Random Perturbations of Dynamic Systems
Moscow, Uspekhi Matematicheskik Nauk, Vol 25, No 1, Jad/Feb 70, pp 3-55
Abstract; The effect of small random perturbations of the white noise type
:kC E
bc(xt) + za (xi) t
t
b(xt) is studied, where t is:'an r-dimensional Wiener
onadynamic system At
process and bE (x) b W as E 0., The ef f ect of thest~ perturbations over large
time intervals which increase with decreasing a is emphisized. Two problems are
discussed: the behavior of the invariant measureM of the process xt as 0
and the distribution of the position of the trajectory' Of xt immediatelyTafter
leaving the compact region. The probability that the trajectory of the process
xZ in time [0, T] does not deviate from a certain smooth function +t by more than
t
is calculated. It was found that~ for small S and S the major term in this
1/2

2/2, 025 UNCLASSIFIED PROCESSING OATE--20NOV70
ACCESSIGN NG--AP0132758
iA13.STRAU'T/EXTRAcr--(u) GP-0- ABSTRACT. THE.NEW E0 I f LON OF A TEXT1500K FOR
MEDICAL SCHULILS IS ATTRACTING ATTENTION BECAUSE I NAUDITION TO THE
,~._QUESTLCNS-OF PUBLIC HEALTH GRGANIZATfO41 IT EXAM 'S T(lE FUNDAMENTALS OF
SOCIAL HYGIENE FOR Tf-~E FIRST ]-[ME. THE 114PO.R,rANCE ~ OF 510CIAL HYGIENE TO
HEALTH IN GENEkAL AND LAS SUBJECT MATTER FOP, TEACHING IN
~PARTICULAR IS DEmCNSTRATED IN THE FIRST CHAPTER. THIS CHAPTER GIVES 4
~:~'--,CORRECT AND CCMPLETE IDEA OF THE ESSENCE OF THE QUESTIrOll IT IS WRITTEN
A VERY I-NTFLLIGf6LF_ SlYLEP BUT AT THE SAME IT .15 ON A
:...,.,SUFFICIENTLY FIGH SCIENTIFIC LEVEL.. THE OTHER UJUJAPTERS TREAT
la.SPECIFIC ARLAS OF SUCIAL HYGIENE -AND PuaLlci HEALI-ii ORGANIZATIUN:To TfiE
~EXTENT NEEDED BY ALL MIDDLE LEVEL MEDfCM - WoRir-'IERSi~i~
L [Fik plui'~4clp(.Es 01=
THE STRUCTURE OF.bTS 80OIE5' rH&~ SIROCTUKE OF THE
SfjV[ET PU6LIC HEALTH,
_,,WORLL) HEALTh ORGANIZATION, HISTORICAL :INFORPIA'rijN~,:m PUikLIC HEALTH IN
RUSSIA A~ND 'OW THE STAGES,~OF JT S OE VEOPMEN f I N rHE
f:4KLY THE SECOND AND
SOVI ET PER I CC ARE PRLSENTED BR I EFLY BUT. VERY, Ct
CHAPTERS.

026 UX L AS S II ED ;lPRt3Gr-SSI?4G 0AtF--20'lq0V70
TITLE--SLi-,L ~.,WESTI06 At!, JU TTtiE URGANIZATiuN 01-~ Ac~~,ULATURY TRAUIMAT~I~tu6ICAL
AID IN CITIES. -U- 10101"
.0k~-hcYULIN, S.YA.
AUTH
-USSR
CLN T R Y: CF INFU
SWRC&-VLYtNNC-M1C ITS Ii',.SKIY 1HURNALt- NO 3t 1970,1 PP ii 0-6 L
0 A T EPUBL IShEG------70
UBJECT: AREAS-ijIGL'u~GICAL ANO MEDICAL SCIENCES
JGP I C AGS-FIRST AID, VILITARY MEDICINE
CCNTRCL kFSTRICTILNIS
I) G C U M E k TcL,,,ss--u,hl,ct_AssiFiED
~PRG XY K E C L lF -IM L- 3 OG 6 1 C,~ 02' STEP NO--UK/ 0 L 77/1,0/0~,01`103/0(td O/C-081
C If_ AL C E 5 S I Cl'. L P 0 1. J. 4 1 7,U
um, M~
puma
i.
m

UNC LAS S'I F ID R ~oSS[NG DATE-20NOV70
c
ACLESSICi NO-AP0 13 170
AbSTRACT. I N' OUR COU 1~1'1 P Ytj" 1: FF EC IIVI: SYSTL-'.!4
A--;F C C V 6 A T T IGT k A W-11 A IIS~'i AND RENDER lt~G F IRST A I p') I TO T~iE STRICKE,"; HAS
E 0 IN OUR CIPINIGINt Ab"ki ITHII 0AGANIZATION,
~bErct% CREAT" CERTA ;N QIUEST I ums
TRAW-1ATOLUGICAL All) TL-j AN URBAN POPULATICN, ,STIATEU TI-I E P Rr
INTEREST TUt AIL I )''FtY PHYSIC I A,,\l S
ARTICLEt A R ETO A CERTAIN GE-GREE GF
IASSfF1 01

;IRC~ACCESSICN NO--AT0124370
UNCLASSIFIED
I

-~NCLA~STFIED PROCESSING DATE--30OCT70
.IRC,%-L,ss,*
iCN NO-AT0124370
iDSTRACT/EXTRACT-(U) GP-G-- ABSTRACT. CHEATING MIXTS. OF UNSATD. SULFIDES
,'AND PHSH WITH FEICO SUB5 (1) (0.5 MOLE.PERCENT) IN SEALED AMPULS AT
..80DEGREES OR 150DEGREES 10 HR WAS USED ASITHE TECHNIQUE FOR STUDYING THE
..EFFECT OF THE CARBONYL ADDITIVE ON THE REACTION INHIBITED THE
RADICAL ADDN. OF PHSH TO THE OLEFINSo : THE FOL~OW:ING PRUDUCTS WERE
.OBTAINED FROM THE INDICATED OLEFINS~IN THE PRESENCE- LABSLNCE) OF 1;
-~PHSCH:CH SUB2 100PERCENT MECH (SPH) SUB2 (100PERCENT (PH-jCH SUB23 SUB2);
PHSCPH:CH SUBZ 1000PERCENT,MEC(SPH) SU82 PH (56PERCENT PHSCHPHCH SU02
SPH AND.27PERCENT MEC(SPH) SUEIZ PH); AND MEC(SPHJ:~SUB2 Ph 100PERCENT
MECH(SPH)PH; NU REACTION TOOK PLACE WITH OR WITHOUT-FE(Cn) SUB5 WITH
AND MECH(SPH) SUB2. FORMATION OF IPHSCHPHM&AbOVE kcSULrED.FROM
OF PHSH IN ACCORD WITH THE.MARKCVNIKOV-RULE,:~I'AND,CONVERSION OF THE
..KERCAPTAL INTO THE FINAL PRODUCT OCCURRED BY LOSS OF PHS RADICALt WITH
.,,,FE(CO) SU135 INHIBITING THE RADICAL AD0N* 0 -PHSH OT ~ THE: CJRIGGINAL~
.OLEFINIC-SULFIDE. FACILITY INST*~ELEMENTO,URG.~SOEDIN.m.MOSCOli,
UNCLASSIFIED

REPROCESSING DATE--30OCT70
zfz 020 UNCLASSIFIED
CIRC ACCESSION No--AP0124406
iABSTRACT/EXTRACT-(U) GP-0- ABSTRACT. A MIXT. OF 2 G:3,4 CL SUB2 C SU86
H SUB3-N SUB2 BF SUB4 AND 1.8 G POWD- SCINH SU82~)SUBZ HEATED-IN H SUB2 0
TO 50-60DEGREES UNTIL GAS EVOLUTION HAD CEASEDGAVE,-AFTER EXTN. WITH C
SUB6 H SUB6 AND ADDN. OF PICRIC ACID IN ETOHP 1.5 G 3,4 CL(H SL182~
NC(:NH)S)C SUB6 H SUB3 SC(:NH) NH SUB2 2C SUB6 H~SUBZ(NO SUB21SUB3 OHR
M. 2360EGREES; SIMILARLY 2,P6 CL,SUBZ.C SUB6,H SU6 N SUB2 BF SUB4 GAVE
Zt6 DICHLOROPHENYLISOTHIURONLUM PICRATEj M. 223-40EGREES. THE
REACTION. MIXT PREPD. SIMILARLY FROM,O CLC SU86~ 14 SU8,4 N SUB.2 Or- SU84
-GAVE AFTER EX~N. WITH C SUB6 H SU86 AND NEUTRALIhATION'WITH NANCO SUB3v
O-CHLORO,PHENYLISOTHIURONIUM BICARBONATE# WHICH HEATED WITH AQ* H SUB2
SO SUB4 1-2 HR UNDER N GAVE Z2PERCENT 0 CLC, SUB6I~H SU04 SH, B.
204-60EGREES; SIMILARLY WERE PREPO. 0 CHLOROPHENY,LENEOITHIOLI 22PERCENTO
8 SURIO 1200EGREES; 2s6 DICHLOROTHIOPHENOL, 50PERCENT* Me 44-60EGREES;
ANU P PHENYLENEDITHIOLv 20PERCENT#.M-~98DEGKEES.:~.SPONIANEOUS OECOMPN*
OF P NITROPHENYLENEDITHIOL DICARSONAMGAVE P 0 SUB2 OC:SUB6 H SUB+ SHo
CIRECTLY OXIDIZED IN AIR TO THE DISULFIDEP. Me 178-9DEGREES. A REACTION
MIXT. OF 11.3 G 0 CLC SUB6 H SUB4 N SU62 8F SUBf*,AND 7.6 G SC(NH SU82)
:SUB2 IN H SUB2 0 WAS EXTO. WITH C SUB6 H SU86.AND,:,THE"AQ. LAYER$ AFTER
AODN. OF CQNCO. KOK UNTIL ALK.9,WAS REFLUXED UNOE9:N 2~HR TO YIELD AFTE
ACIDIFICATION WITH HCL' 25PERCENT 0, CLC SU06 H, 504 5H.' FACILITY:
ELEMENTOORG. SOEDIN-or MOSCOW$ USSR*'~
UNCLASSIFIED

UNCLASSIFIED P~OCESStNG DATE--23OCT70
~T
-I,T,LE--O.ADICAL ADDITION OF METHYL DIBROMOACETATE TO ~ETHYLENE AND I HEXENE
R.KH.1, KAMYSHOVA, A.A
:COUNTRY OF INFO--USSR
_.~.SOURCE--lZV. AKAD. NAUK SSSR, SER..KHIM, 1970, (3)p;721-13
DATE PUBLISHED ------- 70
SUBJECT.AREAS--CHEMISTRY
"TOPIC TAGS-BROMINATED ORGANIC COMPOUND, ETHYLENE, ACETATE, HEXENE,
POLYMER, LACTONE# NMR SPECTRUMP IR SPECTRUM
CONTROL MARKING--NO RESTRICTIONS
.,~_.DOCUMENT CLASS--UNCLASSIFIED
-PROXY REEL/FRAME--1999/1907 STEP NQ--UR/0062/'701000/003/0721/0723
CIRC ACCESSION NO--AP0123691
UNCLASSIFIE0

212 032 UNCLASSIFIED PROCE.~SING DATE-Z30CT70
CIRC ACCESSION NO--AP0123691
*A8STRACT/EXTRACT--(U) GP-0- ABSTRACT. TELOMERIZATION OF C SIJF32 H SU34
WITH CHBR SUB2 CO SUB2 ME (1) WITH PEROXIDIC INITIATION WAS UESCR[BED.
IN AN AUTOCLAVE 42.5 G I AND 2 G 8Z SUB2 0 SLJ82 FLUSHED WITH Nr
PRESSURIZED WITH 100 ATM C SU82 H SUB4t AND THE WHOLE HEATED 7 HR AT
100DEGREES (MAX. PRESSURE 320 ATMI, GAVE 66PeRCeNT CONVERSION PROOUCTS
WHICH YIELDED 35PERCENT OF THIS MATERIAL-AS 14E0 SU82 CCH13R(CH SU82 CH
SU82) SUBX BR (11) (X EQUALS I)* B SUB5 71DEGREES, N PRIME20 SUBD
1.5084, 0 PRIME20 1.8446, AND 42PERCENT It (X EQUALS 2)v B SUB2
113DEGREES, 1.50569 1.6555 ALONG WITH TELOMER ICIX EQUALS 3) 23PERCENT,
WHICH WAS NOT DESCRIBED FURTHER. 11 (X EQUALS 1), HEATED 8 HR WITH FE
(CO) SUB5 AT 135DEGREES GAVE 83PERCENT 29BORMOBUTYROLACTONEt B,SUB5
96-7DEGREESt 1.50839 1.7640. 1 AND I-HEXENE INITHE PRESENCE OF
DICYCLOHEXYLPEKOXY DICARBONATE INITIATOR GAVE ItTj HR AT 55DEGREES
80PERCENT CONVERSION PRODUCTS WHIC4 YIELDED ON DtSTN* 70e6PERCENT
1,3tOlBROM0919CARBOMETHOXYHEPTANE#:B SUB4 10-180EGREES, 1.4926t 1.5002,
B SUB3
AND THIS AFTER REPEATED FRACTIONATION GAVE THE Z:!RACEMIC FORMSt
113DEGREES,.AND B SUB3 117DEGREES, RESP.-~ WHICH WERE CHARACTERIZE[) BY NMR
'AND IR.SPECTRA. FACILITY: INST, ELEMENTOORG.iSUEDIN.t MOSCOOt
USSR.,
UVICLASSIFIED
m

y--1112 010 UNCLA~S I FtED p DATE
RIOCESSINS --11SEPTO
..-T..ITLE--HOMOLYTIC ADDITION OF THIOPHENOL TO TRIVINYLMETHANE AND RELATED'
COMPOUNDS
-AUTHOR--VASILYEVA, T.T.t FEDIN, E.I*t FREOLLI Re 0
-I,z-, ~. ~ . , , ~ I _V.
-WOW
.7COUNTRY OF INFO--USSR
:.,SOURCE--IZV..AKAD. NAUK SSSRv SER. KHIM, 19701, (I)t 100-6
PUBLISHED ------- 70
"SUBJECT AREAS--CHEMtSTRY
i.:TCPIC TAGS--THERMAL DEGRADATION9 THIOLi PHENOLt NUCLEAR ~OAGNETIC
RESONANCE, VINYLBE4ZENEt CHLORINATED ORGANIC COMPOUND, CYCLopRnPAFIIF,
'CONTROL MARK ING--NO RESTRICTIONS
.DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/FRA4E--lq87/1071 STEP 40--UR/0052/70/000/001~010010106
CIRC ACCESSION NO--AP0104469
UNCLASSIFIED

-2/2 010 UNCLASSIFIED PRO.CESStNS DATE--IIS'EP70
CIRC ACCESSIONzNO--AP0104469
-ABSTRACT/EXTRACT--(U) GP-O- ABSTRACT. HEATING 0.94 ~G HC4CH.CH SUB?) SUB3
WITH 1.1 G~PHSH AND 5 MOLE PERCENT BZ SUB2 0 SUB2 1.0 HWAT 80DEGREF.~ IN
A SEAL.ED TUBE GAVE 73PERCENT.5tPHENYLTHIO,3tVINYLiltPENTENE My B SIJB2
104DEGRElaSi N PAIME2 SURODEGREES 1.5541, 0 PRIMF20'0.q864, PH SUt32 S
SUB2,-AND STARTING MATERIALS; NMR, EXAMN. SHOWED TH5 PRESENCE OF SOME
CYCLOPROPANE-iDERIVS. I AND PHSH UNDER THESE CONDITIONS IN 10 HR GAVE
~-30PERCENT~CWSUB2*.C(CH SUB2 CH SUB2 SPHI SUBZ B SU%j ISBUEGREFS-t 1.6030,
1&0928* 51'CHLORO,3,VI'4YL,IPENTENE ANQ PHSH SIMILARLY TREATED GAVE
..6rOPF-RCENT CH4;SUBZ*-.-C(GH. SUB2 CH SUB2 CUCH SU13Z CH SUBZ SPH.s B SUB2.
J30DEGREESt 1.5653; 1.0944. lvCHLORO,3,VINYL; 50HENYLTHIOPENTANE AND
PHSNA IN ETOH 1 HR AT 70DEGREES GAVE 82PERICENT 39VINYL,10iBIS
~~(PHENYLTHINPTNTANE, 8 SUB2 207DEGREES, 1-6037t 1.0917, ALSO REPORTED
~:WERE (CH SUB21-CH) SUB2 CHCH SUB2 CH SU82 CLv B SUB60 66DEGREES, L.45251
CH4SUB2:CHCH SU82 CH(CH SU82 OHI CH:CH SUB2 B S.U;311 59DEGREr.
4560,- 0.8655; -CH SU82:CHCH SUB2 CHICH SUB2 CLICHOCH SU82 B SUB74
-.-76DEGREES* ft *-4549, 0.9223; CH SUB2:CHCH,SUB2 CH(CHI-C4- SU52)CH SUB2 SP4t
:8 SUBI. .,900EGREESt 1.5570, 0.9916.
UNCLASSIFIED

FE Ald?
it P~6-
Acc. 'N 9- Absturacting Serviceo
'
3 Code
Y
O1002
I
- CHEMICAL ~ABST.. 6- LLmd 66
11856q ftedlation-chemical lelomdrizallop of atbvlene by
methyl formatc. Bryantsey
-L-
T!trenq- v B-,,-Freidr,5.
-
p,
_
, &
~
N-
;Z t,%.
I
", P, A - ffi;minn N.
_
-
, I, Irv, A kd
t I
&Z. mL
A ~ NQ S
S UIM.1910:
(1). 169~71 (Russ). The telornarizatinn of HA
r CH.- with
d
~
OjN,1c (1) (n - I
HCO,Me gives %1e(C11j). , an
5).
HCO01-1d.Me (11) In - 2. 4. nr 6). a compd, 0~ mk rnrMula
CpA.0i. and C,-,H,,CHEtCO..,Nte, whether initiated %ith-firr-
Bujo I -r-irradn. The incres" in the reaction teni p. incrtams
I + 11 (at MV and 190'. the yields W prv 0.2,5 and
7.0% and the G-values 0.71 and 20.0, mp.) and th ~ proportOon
of 11 in the ;nlxl. increased, The percentoges of I hip pro&cts
listed above of 125'. were 20,11, 27.0.'21,2. 2,5 4 2 3 ~
110'
'
1
l2 4 P 0 had
,
7'ld was 24,0%
j%
h
l!h
6 at 140* in 4
2-
20.0, 10.8. 19.4. 9.7. 3.2.
hr ii~d
.
6.2, Stid 4.3 Mp. cPJR I
REEL/Fpl~m
19841629

USSR
MALMOV, M. B. and FREYKINA, V. L~.
"Application of Information Theory to One.Problem of SCP~aration of
Significant Factors"
Teoriya Veroyatnostev i yeye,Primeneniya [The Theory of Probabilities
and Its Applications], 1973, Vol 18,,No 2, pp 438-4,40 (Translated from
Referativnyy Zhurnal Kibernetika, No 10, 1973, Abstract No IOV168)
Translation: There are t variables (factors)'x a~= 1, t.
taking on values of 0 or 1. It is knoim.that some $