SCIENTIFIC ABSTRACT GRANAT, I.YA. - GRAPOV, A.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002201010018-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

44 M40721
UR 0482
Soviet Inventions Illustrated, Section I Chemical, Derwent,
242214 METAL VACUUMING .~211TINE utilises variable
raref:Udation in''the feed funnel and high
residual pressure in the treatment chamber itself.
Varying the residual pressure above the meniscus
in the funnel and maintaining the residual pressure
inside the chamber ensures smooth control of metal
feed and at the same time keeps a constant metal level.
Electron ring or vortex pumps are suitable, sealed
to the upper lip of the funnel. This allows metal
to be poured into the funnel without disturbing the
residual pressure control.,
13.5.66 as 1078001/22-2. GRANAT.I.YA et a1(11.9.69)
Bul 15/25.4.69. Class 18b, 3lb2.' Int.Cl.C 21c,
B 22d.
19750364

AA0040721
AUTHORS: Granat, I Ya.; Gorskiy, V. B.; Zhuravlev, P. Ya.;
slEu-T-S-vl-y-:-'T':"T.; and Morozenskl~, L. 1.
197503G5
lyre-

UCSR
UDC 534.232.14.6-8
GPXIAT, Ye. G., RUBkNOV, L. A., VLASOV, S. 1.
"Device For Irmregnation of Piezoceramic Transducer"
USSR Author's Certificate No 27000], filed 13 June 68, published 31 Aug 70
(from RZh--Elelftronika i yeye Drineneniye, No 3, March 1971, 'Abstract No 3A41-(P)
Translation: An Lriproved procedure is proposed for i1mrognation of a piezo-
C;
ceramic transducer, Which differs in the fact that a piazoceramic transducer
subject to izpregnation is used as an ultrasonic vibrator which produces ultra-
sonic vibrations in a bath with impregnating material. 1 ill. N.B.

USSR 1A)C' 577.4
A. C., C:iI-IMt,'S11--,,,V, A. A.
7
"Experimental Calculations of the ',)est-East Problem"
V sb. lfetodj i modeli territorial'a. plmiir. Olu.thwls and '.Ioduh; of
Planning -- collection of works) vlvp. 2, Novosibirsk, 1)71, pp ICUO-1-37 (frm-,
RZii-KiberneLika, No 7, Jul. 72, Abstract No 7V5-'].)
No abstracL

USSR
GRMBERG, A. G.
UDC: 5-1
"Modifications of an Interterritcriai Midtisectoral Opti!uizatiori 1~106.ev,
V sb. Metoc'~- i modeli territorialln. Dlnnir. (I'lethods and Kodels of Terri-
torial Planning-collection of works), vyp. 2, Novosibirsk, F.P 5-28
(from RM-Kilverrctiha, !~Io 6, iLm -(2, Abstract Ilo 6V41ig)
Ello abstract]
1/1 - 30 -

USSR
GRIVIBERG, A. G., GUR-YEV, V. P.
aw
"Problems of Modeling of Interregional Communications"
Metody i Modeli Territor. Planir. [Methods and 'Models of Territorial Planning
-- Collection of Works], No 1, Novosibirsk, 1971, pp 222-265 (Translated from
Referativnyy Zhurnal, Kibernetika, No 2, 1972, Abstract No 2 V497).
NO ABSTRACT.
17 -

USSR 62-531.6
BARYA121, B. 1-1. and jlggen-Ag, /"Tyazhpromavtomatika" Ukraind.-
an State DeuiGn IndICITUM/
"Device for Re-ersible Control of a Single-Phase Condenser .7otorl,
UISSR kuthor I s Certif icate_ No 294217, f iled 13 J,-:,,ii 691, juI,?_J_shed
_.A_ - j chi-L-IJ -L-.e'- I na%-a
21 hay 71 (from, te2 emehhanika, i
tekhnilka, No 12, 1971, Abstract 1.~o l,2T1_T4_P)
Translation: A known device for reversible cont--rol of a sin-le-
phase condenser motor with ti,-o unconnected vi-ndings contains a
flip-flop with two oppositelly connected thyristors. 'J"Ine invention
can be used as an automatic control element amd ;a remnte tran_-jait-
ter. The proposed device provides a reduction in the distortion
of the sha-De of the voltl~~Ee applied to the control wii-Iding of the
-motor and,,- cons e quently, ro-sult s in an increaze in efficiency. Y1, J ss
is achieved by ecu_ippin,~:, the secondary i-:inding of the flir)-flol)
with a center tap, -,,ith one of the motor windin-,rs connected be-
tween, the tap -nd the th'-y-ristor cathodes. of the thyristor_
in connected ill "r) a an-~ Ot,'liar 47 r.:,Q
winditi- of' tliu if,u C 0", 1111-1c lk.(--d to
urdt U11,01.1T.."11

USS r.
UDG: 658.562.012.7
BARYAM, B. M. , _g ~NBERVG_, -G. Ya. LEMNER, 1. U., SLOTSMY, Ya. Yu., B. MI.,
CHERINKOV, V. V.
"Device for Centralized Testing of Parameters of -in Object"
USSR Author's Certificate Nltviiber 30843i, filed 16/03/70, publi.siied 12103171 (traas-
lated from Referativny), Zhurnal Avtomatila, Telemckhanik-a i Vychislitel 'naya
Tekhnika, No 3, 19721, Abstract No 3 A371 P)
Translation: A device Is suggested for centralized testing of the parameters of
an object, containing a unit for selection of parameters, an autocompensator I.;J11i
a servo system, a rotation-digital converter, a unit for checking the accul-acy
of the servo systern of the autocompensator, a defect indi.cator, a counter unit,
and a recorder. In order to increase the speed and reliability of testin.-, the
device contains a threshold unit connected to the input of the xotation-di.-ital
converter and a self-testing unit in the servo _ system, and the output 0f 1.110
threshold unit is connected to one input of the self-testing unit of the -1:(~-_-,-:_~
system, the second inr~ut of" which is connected to wi additional output of thc
unit for selection of par-mmete,_rs, t-he outntlit of the counting COTItT01 iS C011111CCtCd
112

USSR
BARYAM, B. M., GRANBERG, G. Ya., LERNER, 1. U., SLOTSNIK, Ya. Yu., TSIVIYkN, B. Kh
GIE-RNKOIT, V. V., USSR Author's Certificate Nuiiber 308433, filed 10/03/70,
published 12/08/71 (translated from Referativnyy Zhurnal Avl:ojnatik-a, TelemckhalliLa
i VychislitelInaya Tekhnika, No 3, 1972, Abstract No 3 A371 P)
to the input of the counting unit, the output of tile false balance checkin- unit -is
connected to the controlling input of the servo system balancing element, while
the output of tile signalling unit is connected to tile addiLi-ollal illplItS Of tile
defect indicator and recorder. 2 figures.
2/2

trogen
USSR
UDC 547.754:543.M.4.541.67
,_QgWq]~ERG, I. I., BELYAYEVA, L. D., and DMITRIYEV, L. B., 'Mcscow Agricultural
Academy Imeni K. A. Timiryazev
"Indoles. MXV. Preparation of 4-Nitro- and 6-Nitroindoles Forming During
Cyclization of m-Nitrophenylhydrazones in Fischer Reaction"
Riga, Khimiya Geterotsiklicheskikh Soyedineniy, No 1, Jan 73, pp 37-39
Abstract: Cyclization of diethyl ketone m-nitrophenylhydrazona was studied
under various conditions, always leading to a mixture of 4-nitro-3-methyl-2-
ethylindole and 6-nitro-3-nethyl-2-ethylindole, the first compound forming
in slight excess. The ratio of the isomers depends on the catalyst used.
In general, the results support the mechanism of intramolecular electro-
philic substitution, The nitrogroup exhibits a strong I- and M-effects.
The I-effect deactivates the ortho position, but the mesomeric polarization
specifically deactivates the para-position. During the cyclization of the
m-substituted pheny1hydrazones, steric factors will always favor the
formation of 6-isomer, regardless of the electronic nature of the sub-
stituent. For example, cyclization of the m-nitropheny1hydrazone of
methylisopropyl ketone yields 6-nitro-2,3,3-trinietliyl.:Lndolenine exclusively.
1/I

USSR
UDC 547-75-071543-51
ZFJGLTL-rV, K. K., KF1-:EL'NITSX1Y, H. A., G.HAW=,.Jt, I. , and VYSOTSXIY,,
V. I., Moscow Agricultural Academy Imeni. K. A. Tia*azey
"Indoles. XXVII. Mass-spectrometry of Compounds with Eserine and Homoe-
serine Skeletons"
Riga, Xhimiya GeterotsMicheskikh Soyedineniyo No 8, Aug 72, pp 1065-1069
Abstracti Mass-spectroscopical data on 12 derivatives of dinordesoxy-g-
-methyleseroline (I) and dinordesoxy-10-methylhomoeseroline (H) have been
reported. The derivatives of (1) are somewhat more stable toward electronic
bombardment than (II). introduction of a methyl. or methoxy &roup onto the
benzyl ring or N(.) -poaition Increased the stability of the molecular ion.
The pyrolidine or piperidine rings are the first to undorgo fragmentation,
so that the stability of molecular ions must be connected with the localiza-
tion of the charge on the N(b) nitrogen atom. Most probably the principal
dissociation involves the breakdown of the ring, splitting off the methyl
ro p forming ions with a mass of 30. The most intensive Deaks obtained
f
r=om dissoci~tive ionization correspond to the formation of pseudomolecular
ions of 2,3-dimethylindole derivatives. A mechanism of the formation of
regrouped pseudomolecular ions RC6Hj~i*H2 has been proposed.
1/1

U 10~ S R UDC 510-51:547-71L'
~7 --IT3`~_IY, R. A., i T I B
A.
"Ma s sSpectra and StrL-,c-U-or_-_ of Some
LeninF3rad, Z_hul-nal Cr~:anichasi-oy -K-hInii, Vol 7, 1110 10, Oct 71,
pp 2038-20,10
Abstract: ',he article describea results of a mass snectromet-ric
study of t-he beh7-vior of compo-.-.nds of the 3)yr--!-olin-- class 'Linder
the action of electro-n imnact. The follo-,,,in:-,-, -oyrrolines ,rere
_S at-IVI-.61 -'7-yrzoline, 2-isonro-
studied: 2-ne-t-h- 11- 2,
pyl- A' --oyrrolinc, 2-nh_e'nY1- L\~ -nyr.-oline and 1,2-dimothy!-A:
P7rroline. The mass r,-)ectra were obtainod at a tcrq-.)erat1_,rc of
2500, acceleratuin7 volta~:-e of _2 'rv, cathode --niss-Lon currenIC. of
1.5 and 1.0 mr and ionizin7 electron ener:77ies of 50, 30, 20 and
4_7
15 e--- "Relative sensi`ivi coefficients and relative ionintion
cross-sections were deterrsi-ned. I-t -..,as found th',.t- tahere is a
lincar relation bet-...re,,_~n the nvnber of carbon ~,twin in all,:-il
subs t i tuent rnd the r-clative ionization cross,soct;~;on, dccrrilb(.-
112

USSR
KLYL;'Yz-,-,T, N. A. , e-'6-1 al, -.hurnal Organicheskoy ---.-himii,.eIol 7, N-0 10,
Oct 71, DD 2038-20113 -
by a reCressive equation. It Js sug-r-ested that in the e-%~citued
state the studied conmounds hrve an enanine structure and their
decomposition path is the result of this form.
1 2/2
- 33 -

USSR
uDc 615-21+612-178
PARIN, V. V., Academician (Deceased), FEDOROV, B. M.,
BATULIN., Yu. M., and PODMOVA, N. A., Institutc of Medical-Biological
Problems, Moscow
"Myorelaxation of Animals by the Injection of 3,5-Dimethyl-4-bromopyrazole and
the Effect of Extracardial Nerve Stimulation Under These Conditions"
Moscow, Doklady Akademii Nauk SSSR, Vol 200, No 5, 1971, pp 1,252-1,253
Abstract: Intraperitoneal administration of 3,5-dimethyl-4-bromopyrazole in
a dose of 200-400 mg/kg to rabbits or in a dose of 300-500 mr,/kg to dogs pro-
duced a state of profound myorelaxation, from which the animals recovered
within a time that increased with increasing doses of the drug. A dose of
450-500 og/kg ands> 500 mg/kg was lethal for rabbits and dogs, respectively.
Study of the effects of direct stimLlation of the vag-us or of sympathetic
nerves effecting adrenergic innervation of the heart, which was carried out In
experiments on dogs to which 350-500 mg/kg of the drug had been injected,
showed that the state of myorelaxation did not affect the action produced by
direct stivralation of the extracardial nerves.
1/1

USSR UDC 5417-551.4 -t- 5k1 .49
GARNOVSKrZ, A. D. KOLODYAZRNYY, YU. V., ALIYEVA, S. A., _=M-0ZIZ "Tk
_I, GRAN
N. F I'DBERG, I. I., OSIPOV, 0. A., and PRESINYAKOVA, T. PI.,
and All-Union Agricultural Acadenrr
imeni K. A. Timiryazev
"Complex Co~mpounds of Metals With Nitrogen-Containing Ligands. XLX.
Complexes of Tin Tetrachloride With 1-Pyridylpyrazoles and Their
.5-Hydroxy(amino) Derivatives"
Leningrad, Zhurnal Obshchey Khimii, Vol 40, No 5, MaY 70, pp 1114-
1120
Abstract: Continuing their study of complexing in systems with
sevaral donor centers, the authors studied the interaction af tin
Uetrachloride with 1-(o!,, 6 or r-pyridyl)pyrazoles and their
5-hydroxy and amino derivatives. The dipole moments of the rezul-
Uant complexes were determined and their IR spectra studied for
purposes of solving the question of the configuration and 4v
-automer-
ism of the ligands. A comparative study was made of the IR spect-ra
of ligand and complex -molecules in order to establish the localiza-
tion site of tile coordination bond.
1/1

Acc. Nir Abstraftin Serwice: Ref. Code:
14
S
_00370_ QiEM1d4,%9 T. .~7,7 0 0/0 y
110432b Nitrogen-containing bilieterocyclic systems. 1.
r
Dipole moments and structure of I-pyridylpyrazoics. Vicv~~
S. A., Kol d azh I Vu. V.; Garnp~lskii, A. Q~
.U.-Grandber
. Krokhma, X. F. (Rosto
Uni Don, USSa). Khi"s- Gelcrws iki. S,7rdlin.
19M, -M. 45--9 (Russ). The dipole moments of I-pyridyl-
"'razoles and their amino derivs. %vere detd. in C.111, at 25*
wilh 5 X IO-L~2 X 10-1 mole fraction. Cam,-urison of ex-ml.
and vectorially calcd. dipole moments shows that I-pyridyi
p razoles, and 1-(3- or 4,pyridylp~aonnopyrazoles have non-
Pranar Configuration; the planar angle tlvl%vet~l Aile Pyrazole alld
pyridine rings was calvd. For
the planar trans configuration ts assurned due to intra-aws. If
-L/FRIUME
-1UA41rj3

AP0100370
bonding. The following data were obtained (R, IV, R', posi-
tion attachment of pyridine ring, and planar angle betwct:n two
rings given): Me, H. Me, 2. 58'; 34c, H, Me, 3, 8-l'; IMC, H,
Me, 4. 0': Pr, Et, Nil,. 3. W; I'llclis. I'll, J%:l I" 'i "; I-
Xlec'u'. H, NH., 3, 80*; Et, h1e, Nil,, 4. 0*: Me, 1. Cl, 1,
0*; Me, H. NHs, 2. 0% PhCIfi. Ph. NM, 2, 00; Et. Me, ANH,,
2, 0'; Pr, Et, NHI, 2, 0*; p-H:z%,CjH,, H, NI-6. 2. 0*-
S. K. Bancrice J
1984179G

112 027 UNCLASSIFIED PROCESSING DATE--18SEP70
TITLE--PYRAZOLES. LXIV. PROTONATION OF ANTIPYR[NE ANALOGS -U-
AUTHOR-(05)-GRAN
OBI~JKGj_j . I .VINOKUROV,
-
T. A. , MOSKAt-eTWO, V.A.
COUNTRY OF INFO--USSR (.0'
A)
lak__
SOURCE--KHIM. GETEROTSIKL. SOEDIN. 1970,
V.G. , TROYSKAYA, V. S. I I VANOVA,
(2), 202-8
DATE PUBLISHED ------- 70
SUBJECT AREAS--CliEMISTRY
TOPIC TAGS--13YRAZOL.E, IR SPECTRUM, UV SPECTRUM, IONIZATION, PROTON,
HETEROCYCLIC NIT70GEN COMPOUND
CC~ji-~fll_ MARKING-N'l) RfEsrRICTIONS
DOCUIENT CLASS--UNrLASSIFIED
PRU'"XY REEL/FRArIE--1987/1110 STEP NO--UfZ/0409/701000/002/02t)2/0208
CfRr ACCESSION NC-AP0104501
L
UN(._LW)IFIf_-D

212 027 UNCLASSIFIED PROCESSING DATE--18SEP70
CIRC ACCESSIl?N NO-AP0104508
ABSTRACTIEXTRACT--(U) GP-0- ABSTRACT. IR SPeCTaA IN CHCL SU33 OR IN
C4YST. STATE, UV SPECTkA IN H SUB2 L-1, MEOH, OR CONCD. liCL, AND EPR
SPECTRA IN ME SU52 SO OR IN a:l D SUB2 O-D SU32 SO SUBZ, WFRE RECORDEO OF
ANTIPYRINE ANALOGS (1, 11). IONIIATION CONSTS. (PK SUBA) IN WATER WERE
MEASURED FOR (1, It, R PRIMEI EQUALS PH, R PRLIME2 EQUALS ME) (R PRfME 3,
R PRIME5, X AND PK SUIBA GIVEN): Hy -p Ot 2942; -1 H, 01 2-ItO; ME, -, Op
2.85; MEv -9 St 2.49; ME, -, SE,-2.64; ME, -, Wit 10.4; -p MEt NH, 10.6;
ME, S. 2.29; -, ME, SE. 2.42, -, ME,.0, 2.49.
UNIC LASS TF- TFf)

1/2 016 UNCLASSIFIED PROCESSING DATE--04DEC70
TITLE--NITROGEN CONTINNING BIS HETEROCYCLIC SYSTEMS. IV. SYNTHESIS AND
ST4UCTURE OF 5,HYO,-'OXY,A?4[NO,I,BENZALOLYLPYkAZOLES -U-
AUTH3R-(05)-GARNOVSKlYt A.Dol KOLODYAZHNYYq YU.V., GR ANDBERG, I.I.t
ALIYEVA, S.A., KROKHINAr N.Fo
C~OUNTPY OF INFO--USSR
SOURCE--KH[M. GETEROTS[KL. SOEDIN. 1970, (5), 660-3
DATE PUBLISHED ------- 70
SUBJECT AREAS--CHEMISTRY
TOPIC TAGS--IAETEROCYCLIC OXYGEN COMPOUND, PYRAZOLE, THIAZOLE, DIPOLE
MOMENT, ORGANIC SYNTHESIS, MOLECULAR STRUCTURE, IiYOiIA/-INL- ORGANIC
COMPOUND, HYDROXYL RADICAL, AMINE DERIVATIVE
CONTPOL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASS(FIC-0
PROXY FICHE NO----FD70/605012/EO2 STEP NO--UR/0401)/10/0()i),"(,)()')/0660/0()k')I
CIRC ACCESSION NO-AP0140304
U ~, ~C L 1-' 5 5 1 " I 1] 0

212 016 UNCLASSIFIED PROCESSING DATE--04DEC7O
CIRC ACCFSSION NO--AP0140304
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT.
5,HYDROXY, 1 v (BENZAZOL 12 YL)PYRAZOLES (I) WERE PREPI). 1-37 REFLUXING A
MIXT. OF 0.05 MOLE APPk[jPRIATE HYDRAZINE AND 0.05 MOLE RCOCHR PRINEI CO
SUBZ R PRIMEZ OR PHCH SUB2 C(:NH)CHPHCN (11) IN 50 ML URT BUOH9 ` 14L H
SUB2 0, AND 5 ML ACOF1 12 HR. THUS PREPO. WERE THE FOLLOWINC3 1 (R, R
PRIME1, R PRIME2, Y, PERCENT YIELD, AND M.P. GIVEN): P-Hr q# Otit So 73t
201DEGREES; PHt CH SUB2 PHt OH, S, 76, 165DEGREFS; CH SU82 PH, PH, OHY
NH, 63, 2240EGREES; AND CH SUB2 P119 PH, OH, NCH SUB2 PH,-7-. R-EFLUXING
EQUIMOLAR AMTS. 2,11YDRAZINOBENZOTHIAZOLEt Ili AND 30PEXCENT 11C1. IN ISO
PROH GAVE 60PERCENT
5,AMINO,4,PHENYL,3,BENZYL,I,(BEiNZTHfAZOL,2,YL)PYRALOLE (1) IR EQUALS CH
SUB2 PH, R PRIME1 EQUALS PH, R PRIME2 EQUALS NH SUB2, Y EQUALS S), M.
1630EGREES. DIPOLE MOMENT AND IR STUDIES SHOW THAT I EXIST BOTH INT HE
CRYST. FORM AND IN SOLN.'MAINLY IN HYOROXY AND AMINO FORMS, WHICH ARE
STABILIZED BY INTRAMOL. H BONDING, FACILITY: ROSTOV.-NA-DONU
GOS. UNIV.y ROSTOV-ON-DON, USSR.

USSR
UDC 542.957:547.355.9:547.558.1
GRANTBERG, K. i., S!-r!SLO%~A, Ye. I., and KOSINA, A. N., institute of Metal
Organic Compounds, Academy of Sciences USSR
"Reactions of Vinyl(triphenylphosphine) Gold"
I
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, N'o 12, Dec 73,
pp 2787-2789
Abstract: When vinyl(triphenylphosphine) gold (1) is reacted with electro-
philic reagents -- acids, halides, mercury salts -- the gold-carbon bond is
broken. Borohydrofluoric acid converts (1) into the borofluoride of gold
organic complex cation containing two atoms of gold. With potassium per-
manganate in acetone (1) yields one of the first representatives of
a-aurylated ketones -- triphenylphosphine-gold keton,
1/1

Organophosphorous Compounds
USSR UDC 541.1..9:547-559-1:541-1113
NESMEYANOV, A. N., NDIEWALOVA, E. G., BAUKOVA, T. V., GRANDBF-RG K. I
"Triphenylphosphine Complex of Cyclopentadienyl (Manganesedicarbonyltri.phenyl-
phosphine) Gold"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimichoskaya, No 11, 19,73,
pp 2641-2642
Abstract: The triphenylphosphine complex of cyclopentadienyl (manganesedicar-
bonyltriphenylphosphine) gold (H) was obtained:

it hou'rs
"ILI Ma

C0 c0

The structure of the (H) complex was established on the basis of spectral data
and confirned by the chemical behavior of the comnound. in the infrared
spectrum of (11) a shift of the two intense absorption bands of the GO groups
toward the long-wave range is observed by comparison with the spectrum of
1/2

USSR
NESMEYANOV A. N., et al., Izvestlya Ak-ademii Nauk SSSR, Seriya Khin`cheskaya,
1 4
No 11, 1973, pp 2641-2642
cyclopentadienyltricarbonylm,anganese (I). This usually occurs on replacement
of one of the GO groups in the cynantrene by a stronger electron-don~r ligand
b~ursanov, D. N., et al., Izv. AN SSSR, Ser. Khim., 2242, 196V. In the Para-
magnetic resonance spectrum of (II) signals are revealed from the protons of
the phosphine groups along with two multipleths of the protons of the substi-
tuted cyclopentadienyl ring shifted to the stronger field by comparison with
of (II)
the sipmals in (I). In the nuclear magnptic resonance spectrum of
two signals of the pho5phorus nuclei from nonequivalent triphenylpho5phine
groupings are observed.
When (II) reacts with concentrated hydroahloric acicl, (1.11) arjr! t)lo' tri-
phenylphosphine complex of gold chloride are formed:
F, /I
Co ("o C() CO 111,;13
The complex (II) is less stable than (I) especially in so'utions, and It decor-
poses during chromatographic studies ~n a column vith alwminum oxide in contrast
~~2(1)'
- 21 -

USSR
UDC 542-957:51rl.559-59'118.'51~7.2,~94-3
I,F,S]Ck'fAlIr;Vjp A. N.) GRANDIET-U, 'K. I., S?~YSLOVA, Y~',. I,
Moscow State University Imeni !". V. TA)monosov
"Tri-olien,,r~n'aosl-hin,a~-old.acet-,)ne"
Moscow, Izvestiya l0rademii NT-w.01 SSSE, Seri,,-a KlAricheskaya, No 10, Oct
p 2375
Abstract: Reaction of v-Lyi,,,,I-oldtriph-~n,,~irhosnlii.iie with an P-,--~tone solu,tion of
potassium pen!-,inganate at- OP ,,ields tri-,hon,,tiplios,?Iiine6olc"tcf.,torf-, (11. lic-1,
HgC12 apd Br2 arld to (I) in the 1,2-po:Ation, while acetyl eliloride reacts via
1,4-addition yieldin.-I -isopropenylacetate and
1/1

Organometallic Compounds
USSR
UDC 547.13
GRAI~Br-.RGX --;., BAUKOVA, T. V., PEREVALOVAt E. G., N'ESMANOV, A. N.,
, __K.
xc"Zelll~c Z-, I-loscow State University Imeni M. V. Lomonosoy
"fq-Tolyl-(triphenylphosphine)-golg-triphanylphosphinegold Borofluoride"
N'oscowl Doklady Akademii Nauk SSR, Vol 206, No 6, 1972, PP 1355-1358
errocenyl-(triphenylphosphine)-go triphenyl-
Abstracti The synthesis of ED ig
phosphinegold borofluoride (I) -- a new type of organogold compound containing
two gold atoms per molecule -- was reported earlier CE. G. Perevalova, et al.,
W., Vol 202, 97, 19727. The formation of this type of complex is not a
specific property of fe-rrocenyl-(triphenylDhosphine)-sold. Organogold
compounds of the benzene series -- P -tolyl-(triphenylphosphine)-gold (II)
and nhen3r'--(triDhenylphosphine)-gold (III) -- also react with HBF4 yielding
similar complexes; P -tolyl-(triphenylphosphine)-gold was obtained from
Q -tolyllithium and the triphenylphosphine complex of gold chloride. The
reaction of II and III with an ether solution of HBF 4 leads to the forma-
tion of borofluorides of fe -tolyl-(triphenylphouphine)-gol -triphenyl-
47
phosphinegold (IV) and CDhenyl-tripenylphosphine)-gol 7-triphonylphosphine-
8old (V), respectively. The auriferous ligand CH 4*Au-P(C6H ) in
3C04 5 3
1/2

USSR
MOBERG, K. I., et al., Doklady Akademii Nauk BSSR, Vol 206, uo 6, 19?2,
pp 055-1358
combination with IV is easily replaced by other electron donor ligands --
triDhenylphosphine, morpholine, ferrocenyl-(triphenylphosphine)-gold. In
the presence of an aqueous solution of sodium chloride, II and the tri-
phenylphosphine complex of gold fluoride are formed. The paramagentic
resonance spectra . and ultraviolet spectroscopic data of some of the above
organogold compounds were analyzed. jhe experimental procedures and results
for the reaction 1OF4 and Ill HBF4 and phenyl-(triDhenylphos-ohine)-goldI
an aqueous solution of sodium chloride and IV, IV and triphenylphosphine,
IV and ferror.,enyl-(triphenylphosphine)-gold, IV and morpholine, and IV and
fe=ocenyl-(triphenylphosphine)-gold are described.
2/2
- 115

LTS S C, -51 L7 -13
PUT?, -;
G. T" r 'U":
s t
GPJJ K. 1 -,d
Ils"."'v"' T.
Relact-on of n d 1 1, y P!, y I, C. z P
L-L o.
philic
Cl
(I Dc !-3, 51'1',*~-R, Vol, 2"%~
Ab3trac
oc-, -op~
clectro,
Y, 1 LLor,.,. t1 1 T).-, C:",I;- :1 r.J
_1. 4 .... ...
0i
acotic C) II.L C:
the X Cl or GCOC"', 0
occur ,il-~'Lh i,:: ~l
fe=oc:,,i-- was. iz!J11, Ily fl,
phosph o 1 c'- n o c c. c L c. on
ol - ........ lic!r l:clc"-,7--~,,
I
th
rc'.. - t.; 1, C!" t~~ 11
b -1 i t

Compounds
USSR UDC 247.13
PEOVALOVA, E. G., LErzNOVSXIYo D A.9 and OSIeYANOV, A. K.,
Moscow State University imeni X. ~. Lomonosov
"Ferrocenylgoldtriphenylphosphine Complexes With Monovalent Cold Salts"
Moscow, Doklady Akademii Nauk SSSR, Vol 202, No 1, Jan-Feb 72, pp 93-96
Abstracti Reacting hydroborofluoric acid with ferxocenylgoldtriphenylphosDhine
(I) yields the borofluoride of (triphenylphosphineferrocenylgold)-tri-Dhenyl-
phosphinegold (11). Excess of HBF4 shows no particular effect on the reaction
course or on the yield. P14R spectrum of (H) resembles the spectra of ferro-
cenylcarbcations. The data of 11MR and UV spectroscopy Indicate that a con--ider-
able positive charge Is located on the gold atom next to the cyclopentadienyl
ring in the compound (II), Compound (II) is believed to be monovalent gold
borefluoride bound with two stabilizing ligands - triphenylphosphine and ferro-
canylgold triphenylphosphine; the positive charge is evidently delocalized
between the gold atoms. Compaund (H) is also obtained by reacting (1) with
(C6H5)2Fe+BF4-, HO2+BF 4- , CH3C&BF4-, except that with these reagents their
ex,cess lowers the yield of (H). Reacting (I) with concentrated H2SO4 produces
A

USSR
PBMAWVA , E. G. , et al. f Doklady kkademii Nauk SSSR, Vol 202, No 1, jan-
Fab 72 # Pp 93-96
Um sulfate analogue of the compound (II), somewhat less stable than the boro-
fluoride complex. The UV and PMH spectra of the sulfates are identical with
those of the borofluorides.
2/2
- 65 -

112 ols UNCLASSIFIED PROCESSING 0ATE--t9SEP70
TITLE--ANALYSIS OF HETEIROORGYANIC COMPOUNDS- V11- ;')fr_-FERENTlAL
SPECTROPK,)TOMETRIC OETER,"IMATION OF SILICON AS MOLVIDUSILICIC ACID
AUTHOR-(03)-TERENTYEV, A.P., GRANDSKOVA, N.A., BONO)APEVSKAY"', YE.A.
CCUNTRY OF INFO--USSR
1970, 196-8
SOURCE--ZH. ANAL. KHIM. 25(1)t
DATE PUBLISHED ------- 70
SUBJECT APr_AS--CHFkilSTRY, 9ATERIALS
TOPIC TAGS--r-ABRIC, HETFROCYCLIC BASE C0mP-',]UN0t SILICON,
SPECTROPHDTOMEIPIC ANALYSIS, UENZENE DEI-111VATIVE,
CCNTROL
DOCUMENT CLASr)--[J*;CLA:;'~,fi:frr_'F,'
PROM REEUFFAME-I'M4/132,~ STEP
CIPC

212 0111 UNICL ASS IF I ED PP0CESSV4k; DATF--18SEP70
CIRC ACCEESS10f'i N"-D--AP0055991~
ABSTRACT/i:XTRACT--(U) GP-0- ABSTRACT. A VARIANT Ff)*--~, ft-11- Olf.pzi~ENTIAL
SPEC TROOHOTU'AtETP I C METHOD F 0 R S I DE T'14. AS 14jLY(!G0S I LI C I C AC I D IS
SUGGESTFO WITH K SU62-CRO SU'14t fM(TATU4G THE COL(IR CF- THf-: ACID AS --~EF.
SOHN . THE r'FF. SUN. IS PREPO. BY DISSOLVING 3 G K M.B2 CRO SJ04 ITN I
1.0.051N KOH. THE ABSORBANCS OF THIS SOLN. H NIL IN 50 IML 11 SUB2 11)
CORRESPONDS AT 400 MMU T!) THAr OF THE 'AOLYBP-rjSILI(.-.IC ACID Ct-jbjfG. 365 "Mc,
ST . THE METHOD CAN BE USED FOR, THE OETN. UF St IN ORGAiNUSILICOIN,
COMPDS., SUCH AS PH SUB3 SIAH1, PH SUB3 S[USIPH SUH3 AND F41MCS
UMPREGNATED BY VARIOUS HYDkOPHOBIC ORGANOSILICO14 L[4:S. WITH STD.
DEVIATIONS OF 0.08-0.14.
U " 1 C L A S S I '-- I E D

USSR
MALAKHOVA, M. M. , PLYASHKEVICII, Yu. N. ,,,,G
,EjNE,V'A, V., LOZE)ERNIK, i. M.,
BATUASIIVILI, Sh. A., FdIEYFETS, V. 1.
"Modernization of the Minsk-22 Computer"
Tr. N.-i. i Prockt. In-ta Mekhaniz. i. Avtomatiz. upr Proiz-vom %, Avto,-Tlob.
Prom-sti. fWorks of Scientific Research and Planning Institute flor Meclizini-
zation. and Automation of Production Control in tile Motor Vehicle Industry],
No 1, 1971, pp 132-1,11, (Translated from Referativiivy Zhurnal, Kibernetika,
No 3, 1972, Mstract No 3 %1482 by the author's).
Translation: A llLIiIIIWl' Of modern i zati ons of tile Millsk-22 compla.el. ;11,e des-
cribed. Diagrams and descriptions are presented of changes concc-1-11ing th~;
punch card input device, magnetic tape reader, inPut start stop mcchanism
card puncher and matching of magnetic drum to computer.
11/7

USSR
uDc 681-32
MALAIMOVA; M. PLYASHIEVICH, Yu. N. LMDEMIKY i. III.,
BATUASHVILI, SH. A.., and MEYFLTS) V.
"UpdatinG the IIinsk-22 Cori.-Outer"
Tr. N.-i. i nrovekt. in-ta rrekhaniz. i avtorati,_,. uDr. rvoiz--voi!~ v avto!.-o-6.
prom-sti (UTor-k-s of ScientifIc-iiesearch and PlarninZ I_nstit-ute for t'Zic
zation and Autuo.,,Mtion of Production Control in the hutozobile Industi-Z),
1971, vyi). 1, pip lQ2-141 (_-Prori i-2h-A-,rtu,!a-tika, Tel-sume'z-11anika i Vychislitcll-
naye. Tekhnika, -"SO 5, May 72, Abstract lio 5B75 by V. F,)
Tranr,latiori: 'rite artiele describe6 it number of i-nodernizittions ill tne
computer and givcs eircuito and (ILocriptions of charijeo nffectilji_~ t1w, C~vr,.,. lind
magnetic tame input units, the st-art-stop input =.chanism, eLc. Eig~ht
illustrations. Bibliography with two titles.

Photography
USSR UDC 778.37
DUBOIIIK, A. S. , and ."R.LZIG-G, A. B.
"Driven-Sweep Type Mirror Scanning in Ifigh-Speed Cameras"
Moscow, Zhurnal Nauchnoy i Prikladnoy Fotografii i Kineplatogral-ii, Vol 16,
C,
No 2, March-April 1971, pp 81-86
Abstract: Some driven-sweep type mirror scanning systerns used in cnnnieras
operating both in the frame mode and the slit scanning mode are investigated
ia this paper. The general principles of driven-sweep mirror scanning used
in high-speed cameras are investigated. Special atteialon is given to mirror
scanning systems which permit maximum shooting _,speeds.
The following. mirror scanning svstei,.is are described: systells constructed on
the basis of plane-parallel mirrors and on the basis of mirror polyhedrons,
systems located in one plane and in two and more planes, systems having twc
optical inlets and two, four and more working sections in which the investi-
gated processes are recorZ'ed. Mathematical relations permitting calculation
cf the basic parameters of mirror scanning systems are presented, and the
structural features, advantages and deficiencies of the described syster.-is
b
are discussed.

USSIR UD C 5 ',`~ G4
GRAY IKIA
"Interaction of Fast; 11"',".cne to sonic and Shocjk- Waves"
Ri--a, Gidrodinamil:a, J.1o 2, 10,72, pp 20-24
A
Abstract: This PaDer considers a situation in which a shocl-
propa4gat-cd in an ideal, clec,~ric-~11,y a
MagjC_--oSC),,j4 C
f ast U _L wave head on.. This, Situtt.-I.C11 i0 Consicit2red -in
a rectill-ricar cuor(linat(3 oystem, with -the J.11
yz plane (x = 0), and the gas moving through it. in the j;0,--,`Aj_%,(!
x directlon. The Incident magnetosonic wave j_Ttoves _Ji) thr-, oaii!e 6j__
rection. In the imnertarbed =--cnetic field co t*.!,t
field is practically parallel to the interface. 1"IM111ti-, witl, the
laws of conseinmtion, the author obtaLjo L., ~e~y,~t-uju W fivC,
.4-4
U.Lo--s -.-IT-ith five xilaic-.-ns andi arrives at a sin'!:-ie. fo*r
I - - t,~.
rat-io of the pressures of the Inbident and trans-mitted u mir ~ Z -
netosonic waves. The behavior of this solution is investiL-,ated
for the case of degeneration.

UDG 536.46;538.6
USSR
GRIVN IK, A. T.
'-~nc~-bimensional Stability of Normal Gas Burning in a
Constant Magnetic Field"
Minsk, inzhenerno-Fizicheskiy Zhurnal, Vol. 20, No. 5,
May, 1971, pp 841-845
Abstracts In the paper the results of studying the stabi-
lity of normal gas burning in a uniform magnetic field
are presented. The solutions of linearized system of M.,IF!ne-
tohydrodynamics are joined at discontinuity surfaces
by the continuity laws and reverse equations. A charac-
teristic equation is obtained relative to the frequency bi
The solution of this equation within 0 '/2 2 is
( 1 + H )
presented in an explicit form. The analysis n he equal:ion
shows that the magnetic field exerts intense stabilizing
effect which leads to the expansion of the burning stability
region as compared to nonmagnetic case studied previously.

t/2 021 UNCLASSIFIED PROCESSING OATE--020CT70
TITLE--PHASE COMPOSITION OF A BINDER FOR A DIAMOND TOOL -U-
AUTHOR- (03)-POGODI NALEKSEYEV9 G.T., GRANIK9 G.I.# NAL104OVA, M.M.
COUNTRY OF INFO--USSR
SOURCE--METALLOVEO. TERM. OBRAB, METAL. 1970, (2), 53-4
DATE PUBLISHED ------- 70
SUBJECT AREAS-MECH., IND., CIVIL AND MARINE ENGR
TOPIC I`AG~--DIAMLIND, CUTriNG TOOL, ALLOY DESIGNATION, ALUN[W-M ALLOY,
COPV0 BASI: ALLOY, SOLID SOLUTION, INTERMETALLIC cnimpout.,i) TIN ALLOY,
L114C ALL(;Yt MAGNESIUM ALL()Y/(U)M5 DIAMONO TOOD BIND[R
L --, I I ; I CT I i %S
T CL,.1 ~ S-WiC LAS I F I LD
..P'JXY iFtLlPRAML--1W'8/1290 STEP Nr)--(JR/0I29f70/-
Cl:~C ACC~SSION %---APO 10[),17 1
U ~ - ~,_ L "' '3S 11- 11

212 021 UNCLASSIFIED P4t'.JCESS 1',,G DArE--02rlCT70
CIRC ACCESSIoN NO-APOtO6071
ABSTRACT/GXTRACT-W) GP-0- ABSTRACT. THE PHASE C014PN. OF THE '4EW N1.5
BUIDER CONTG. AL 50, AN 241 CU 15, SN 5.51 MG 3.4t St 1.5, V10 Cl
0.6PEPCENT WAS STUDIE0-4Y--X RAY STRUCTURAL AND MICROPROBE ANAL. MET14"IDS.
THE X RAY PATTERNS WERE OBTAINED BY USING CU K SU13ALPHA RAD14rION AND
POWD. AS WELL AS SOLID SPECIMENS. THE BINDER COMPN. CONSISTS OF 5
PHASES: THE AL BASE SOLID SOLN, CONTG. CU AND ZN (FCC.); THE ZKI BASE
SOLID SOLN. (HEXAGONAL); THE CUAL SUB2 BASE SOLID SOLN. (TETRAGONAL);
THE MGZN SUB2 BASE SOLID SOLN. (HEXAGONAL); AND THE CU SJB3 SN BASE
~IJLID SULN. (HEXAGONAL). ALSO A CU BASE SOLID SOLN. (FCC.) Aqf) THE l-U
SU66 SN SUB5 COMPD. (THE SUPERSTRUCTURE OF THE NIAS TYPE LATTICE) A~E
ASSUMED TO BE PRESENT.
1- A 51 51 1 F 1 f C'
I

USSR UDC 616.2-057-02:613.632.4
SMIRNOVA, N. A., and _GEAN1K_.L_L
"Remote Aftereffects of Acute Occupational Lesions of the Respiraton, Tract
Caused by the Action of Irritating Gases"
Moscow, Gigiyena Truda i Prof essional'nyye Zabolevaniya, Vol 15, No 11,
Nov 71, pp 16-19
Abstract: Remote aftereffects were investigated after acute occupational
lesion of the respiratory tract in 88 workers at chemical enterprises as a
result of exposure to chlorine (46 cases), hydrogen chloride (2 cases),
phosgene (9 cases), nitrogen oxides (11 cases), nickel tetracarbonyl (14
cases), formaldehyde (4 cases), and ammonia (2 cases). The remote after-
effects, which were exhibited by 35 persons, comprised pneumosclerosis,
bronchitis of various degrees of severity, bronchiectasis, pulmoaary em-
physema, and respiratory insufficiency. Subatrophic pharyngo-laryngitis
was also encountered, but rarely. The most severe remote aftereffects
followed renewed acute intoxication with irritating gases. Persons who have
sustained acute poisoning with such irritants should reinain tinder medical
observation and work for a certain period of time under conditions in which
renewed contact With irritating Bubqtances cannot occur.
1/1

USSR
GRANIN, S. S. and RAVICH, A. V.
UDC 629.7-036.3-CO2.3
"Wear of GraDhitized Carbon and Chrome Plated Friction Pair Surfaces of Hich-speed
End-Contact ~ealsll
Tr. Kuyby~shev. aviats. in-t (Works of the Kuybyshev Aviation Institute) , 1972, v~p.
51, pp 129-140 from FZh-341. Aviatsionnyye i Raketr~qe Dvi , teli No 4, Apr 73,
Abstract No 4-34.99)
Translation: Results are g~iven from tests on the experiw-ntal lapping of the fric-
tion pairs of end-contact seals which are designated for sealing off' shafts from
air leaks at a sliding speed up to 100in/sec. Graphitized carbon r,-nr,,.- and d1scs
made from the 40KUBIA material were used for the friction paix!3. Origin(LI article:
8 illus. and 16 bibl.

Hydrau-7ic & Preumatic
USSR
BELOUSOV, A. I., INLiVUSHIN, A. B., GRANIN, S._S., RAVICH, A. V
"Experimental Study of Flow Characteristics of Dual Radial Hydrostatic Bearing
with Self Choking"
Tr. KLI)-bySlIeV. Aviats. fn-t [IVOl-kS Of 1,UYI)YSIICV IllStitLItC of Aviation], ]972.
No Sl, pp 99-115 (Translated from Reforativiiyy Zhurnal No 5, 1973,
Abstract No 5B709, by A. 1. Snopov).
Translation: A description and experimental results are produced of a study
for determination of tht~ flOW 2',ItC in a dual hydrostatic be;irinv with s(,If
chok, i ng. The bearhig Ila-; I)OLkOtS oil tile Shaft, with oil fed into tllQ J)oCkcL~-
thl'01Jj),)l ;II)VIAM-1--i in ',110 hIV;hjhg ['YOP) ;I COMMOD circul;ir chai;h(-r. lhe jp(--i'turt-
are covere (I Witil .11 CYjjljkjj-jC:ll j7,lC(!V(I, 1-ij "idly Conlicch 11 to III('- shaft. so thi:t
the oil, before entering the feed hole", flows throu"'ll a 61-ctIkIl. 4~lit oi,
variable thickness, depending on the displacement of th(2 Shaft. Th L! Ca o f
symmetrical two-row feed with four chainbers pcr row (dual is studied.
The lengthcf each working portion of tile bearinzg jr, S-55 v!vj, the shaft. di;imC-Lcr
is 50 mm. Assumi"I'r* t1i
1'at tile flow rate depends little on occentricity, tcsts
were performed for the case when the shaft touchcs the, bushing
1/2

USS R
Belousov, A. 1. , Makushin, A. B. , Granin, S. S. , Rjvich, A. V. , Tr. xuvbv~~hev.
Aviats. In-t, 1972, No 51, pp 99-115.
2. oil are not indi-
pressure was varied from 0 to 2 ko/cm Ilic properties of the
cated.
I'welve graphs are presented of the dependence. of oil flow rate through
each end and the summary flow rate as functi-ons of the distance from tile
pockets to the end, as well as 8 graphs of the dependence of those flow r:~.tes
on feed pressure for various snaft position,,. A significant divergence is notc~i
between theoretical and experimental data on flow rate for each end, and good
(within 101) agreement is noted for summary flow.
Also, certain results of static testing of an individual bearing with seli:'
Chokilig With shaft diameter ISO jim are presented, including S graphs of loading
and flow i-ate characteristic:;, the dependences of pressure in the end gnp at
the exit from the hearing on flUid feed IM!"SUIT at Oil! illf)(It, WhIch rf:aul.t-d
100 kg/cIfI2.
2/2

USSR
UDC: 629.78.018.3
13ELOUSOV, A. I., MAKUSHIN, A. B., GRANIN, S. S. and RAVICH, A. V.
-4-:- ~ . . ~ I
"Experimental Investigation of Flow Rate Characteristic of C-Oupled Radizil
Selfthrottling Hydrostatic Bearing"
Kuybyshev, Tr. Kuybysliev. Aviatb. In-ta (Transactiolls (-)f Kiiiby-illev
Aviation Institute), 1972, vyp 51, p1--) 99-115 (from Referativnyy Zhurnal-
Rake tos troye niye, 1973, Abstract No 4. 41. 264 by T. A. E. ).
Translation: Hydrostatic bearings Can SUPPOI-t IICZ--IVy J0;id.--, With')Llt r(A-1t;on
the shalt, However, this involves a relatively liigh rl--tte of flow throi.qgh 01C
bearing, increases operating cost of high-pow(-r units bind reduceF; flicir
efficiency. Witli sonic designs Mgh losses of liquid cl-iiiinot b(.- tolf!i-atod. Iii
sucb cases t1w hydrostatic SUP1101-t functions its t I)CM-ing ;And -,ts a Seal. ~,t
this time, designs of low-flow hydros till. ic- be;triligs liavc ))ocn d'-Vcjop(.-d. 0!11'
of such designs is the selfthrottling radial hydrostatic "waring. Investig,'tion
results are prcsented of flo%v-rate cliaracteristic of a cotilfli,(.1 Mirott
bearing consisting of a block of bearings wiLb ~, corntn(,n stij)pl-y ofliquid.
J5 ilhistrabon:;. I i-eft. i,ence.
K)

USSR UDC: 532-516.2
BELOUSOV, A. T. I GRPJ~,TIN, S. S
"Effect of the Forces of Inertia of the Fluid on the Characteristics of a
Hydrostatic Thrust Bearing"
Tr. Kuybyshev. aviats. in-t (Works of the Kuybyshev Aviation Institute),
1971, vyp- 35, pp 48-52 from Hh-Mekhanika, No 9, Sep 72, Abstract No
9B788)
Translation: The authlors investigate the effect of shaft rotation on the
distribution of rressures in axi-sp.=-etric flow of an inc=rressible lubr4--
cant in an annular ga-D of fixed thickness in a hydrostatic thrust ",earin'-L
fed throuCh a central rocket. The thin-layer equations
dv III Op olt,
PL, -r ~ +
&J
VO
r III,
1/2

USSR
BELOUSOV, A. I., GRAININ, S. S., Tr. Kuyhyshe--.r. aviats.i-t, I Q- ~Tr.
pp 48-52
are taken as "lie init-lal equat--~ons, where p is density, r IS T.ressure, Z,
V and w are the radial, tangential end transverse compon~~-ts of velocil-
ty respectively, p is the coefficient of viscosity, and r and v are c,.-
lindrical coordinates. TI is assumed that the temperature a lirE:a-
function of radius, and that the viscosity is inversely proporticna2 to
temperature. When the equations are integrated under sticking conditi-C-Cl
~ e term pv'vl~r 4 1
th 0 is averaged over the thick'ness of the la,.er P-id exzresse4-
in terms of flo-~,rate. Formulas are found for the distribution c~-f rres-
sures and for lifting capacity. Two numerical exanple~~ are giver. .rhi--h
show the appreciable influence of inertial forces of the lubriezurit. rill th(-
lifting capacities of the bearing; under certain conditions the bearinE
may lose lifting carac-itly. A. 1. Snopov.

USSR
UDC 632.95
BLIZNYUK, N. K., KOLO-,IIIYETS, A. F., GOLUBEVA, R. N., GRAN-IN,__Ye--._ F.,
FADEYEV, Yu. N., VRUBLEVSKAYA, L. S., VARSHAVSKIY., S. L., KOnLON, L. P.,
VIICEWSKTY, K. N.
"A Method of Making Derivatives of Aryl Esters of S-Isothiuronium
Ethanesulfanic Acid"
USSR Author's Certificate No 337381, filed 1 Aug 63, published I Jun 72
(from RZh-Khimiya, No 9, May 73, abstract No 9N522P by T. G. Chekareva)
N
Translation: Compounds of the general formula R03SC2114SC0110 =NIHIA (1)
(R - aryl unsubstituted or substituted by Cl, N02, Me; A = C! or an Organic
acid radical) are syntliesized by reacting C]19-(;"031~ 00 -wILII s"Its of
thiourea or a mixture of thiourea with inorganic or organic acids. [`,xample.
Solutions of equimolar quantities of 11 and thiourea hydrochloride in
butanol which are saturated at 60-90*C are heated at 80-90% for 111 our,
cooled, and filtered, giving I with a yield of 85-961'. Evaporation of
the mother liquor gives an additional quantity of I. The overall yield of
I is 95-100%. The following compounds of type I (A = Cl) are synthesized
(given are R and the melting point in 'C): Ph, 165-6; 4-ClC04 (Ia),
1/2

USSR
BLIZNYUK, N. K., at al., USSR Author's Certificate No 337381, filed 1 Aug 63,
published 1 Jun 72
144-6; 3-ClC~% 168-70; 2,4-ClI)C 6H3, 157-9; 224,5-Cl3C6H 178-80; 2,4,6-
2. Saturated
-Cl decomp.); 4-N0 C-H 155-8; 3-MeC HA, 16M,
3C6H2I 18 6 41 6
aqueous solutions of equimolaf quantities of Ia an 2,4-Cl,C6H
t- 30CF'2COO'a
are mixed at 90-100%, cooled, and filtered, giving compound I (A =
2,4-Cl2C6H3OCH2COO-2 R = 4-ClC6H4), melting point 134-5'C, yield 99.5%.
in concentrations of 3.1-25 mg per liter compound I suppresses the growth
of the mycelium Botritis cinerea and Piricularia orysae by 50-10W%; in
concentrations of 0.25-1 mg per liter, compound I suppresses the growth
of spores of Botritis cinerea and Piricularia orysae by 8-100Y., and in a
concentration of 0.1% the chemical suppresses rust of the wheat strain
Puccinia graminis f. trictci by 42-58%.
2 12

112 016 UNCLASSIFIED PROCESSING DATE--30OCT70
TITLE-METHOD CF CCNSTRUCTING TRANSIENT PROCESSES IN ELEC f RODR I VE S wl I'li
NONLINEAR STATIC CHARACTERISTICS OF IRANSDUCERS -U-
AUTHOR-GRANIT 'P.I. llo~.
CGUNTRY OF INFO-USSR ( r
SOURCE-AVTGMATIKA I TELEMEKHANIKAs 19709 NR 69 PP 164-167
DATE PUBLISHEC---70
SUBJECT AREAS--MECH., I'NO., CIVIL AND MARINE ENGR, ELECTRONICS AND
ELECTRICAL ENGR.
TOPIC TAG S-NGi%-!- I.N EAR SYSTLM, ELECTRIC ANALOGo URIVE TRZAIN,
AMPLIFIER, THYRIST-OR
CONTROL MARKING-NO RESTRICTIONS
DOCUMENT CLASS-UNCLASSIFIED
PROXY REEL/FRAME--2000/102i STEP NO--UR/0103170/000/306/016/i/0167
CIRC ACCESSICN NO-AP01224680
UINCLASSJ IFTH-0

2/2 016 UNCLASSIFIED PROCESSING DATE--30OCT70
CIRC ACCESSICN NO--AP0IZ468O
ABSTRACT/EXTRACT-(U) GP-0- ABSTRACT. THERE IS PKESENTED AN ENGI.-NEE""ING
METHOD OF UNSTRUCTING A TRANSIENT PROCESS IN NGINILINEAR SYSTEMS OF AN
AUTOMATED ELECTRODRIVE, THE SYSTEMS CONTAINING STATIC TRANSDUCERS
(MAGNETIC AND THYRISTUR AMPLIFIERS) WITH A NONLINEAR INPUT OUTPUT
CHARACTERISTIC. AN EXAMPLE OF BUILDING A TRANSIENT PROCESS IN A SERIAL
DRIVE IS GIVEN,
1) 1,! r ! ~ ~ S ~ f F ~-' E C.,

USSR
uDc: 621.791.'(2:621-373.8
L MMEV, V. K., GkMTSA, V. T., and GRACUCIIUK, V. P. , Institute of Electric Welding
Sll I
imeni Ye. 0. Paton, Academy of Sciences, Ukrainian 55R
"The Effect of Radiation Pulse Shape on the Depth of the Zone of Fusion During
Laser Vielding"
Kiev, Avtomaticheskaya Svarka, No 10, Oct 73p pp 10-12
Abstract: The authors present the results from studying the nature of the rela-ion
between depth in the fusion zone and radiation enerLy during the effect of various
pulses. The results show that the shape of a radiation pulse with eyponentially
varying power with respect to time is most rational, since it ensures maxinial
depth of fusion and minimal enerp U
y loss. Copper plate -v.,as used as the material
to be welded by the optical laser.
1/1 - 55

USSR
UDC 621.791.72:535.14:621.315.3
LEBEDEV, V. K.,and GRANITSA, V. T.
"Laser Welding of Insulated Winding Wires"
Kiev, Avtomaticheskaya svarka, No 3, Mar 72, pp 70-71
Abstract: Described are experiments conducted at the Electric 1~,Telding
Institute imeni Ye. 0. Paton involving laser welding of cylindrical and
flat terminals of insulated winding wires. The welding was done with
a modernized UL-2 ruby-crystal unit by overlapping. A curve shows the
dependence of the weld strength on radiation energy W. Ulith increasing
energy, the wold strength increases, attains its maximum,and then smoothly
decreases. Based on botb visual and metallographic examinations, the
decrease in strength is attributed to vaporization caused by Ole increase
in energy. Under optimum conditions the strength of welded joints
comes to 70-90% of tliat of the wire. The study in(]LcaLes Lhe ftasibilfty
of laser-radiation weld'NF, for Viniflex-insulated winding, w1re. The new
technique eliminaLCS Lile time-consuming operations such as stripping,
degreasing, fluxing,and tinning. (2 illustrations)

USSR
UDC g~Bt - t 1 .033 .1
GRANKIN, V. K., MAYAROV, YU. S., RONZHIN, 0. V., KOZYREV, L. S., and Y3,'CROV, A.
"An Information -Jisplay Device,,
USSR Author's Cer-tificate No 37256'~ kl C 0(, k 15/1R, filed I? Sep 70,
published 27 Apr 73 (from RZh Aytonatika lelemek-hanika i Vychislitel,nava
Tekhni , No 11, Nov 73, abstract No 11 A406-0)
Translation: An apnaratus is proposed for information display, containin!.r
indicators and current conductors. To improve the reliability and visibility
of the apparatus, its indicators are in the form of li--hted ed-,es located alo'-L-
the outline of t~eometric figures, with the cur-rent conductors at the vertices.
One illustration.
1/1

Ion Exchakille
USSR mm
1AP01,111iLOV) if. p ..7 M- MER) A . S V. I., PORMIINA , 1. A.
"Ion-Exchange Properties of Sodium Hydroaliuriocarbonate"
Novosibirsk, Izvestiya Sibirsko,,.,o Otdeleniva Akade!'.Iii Nauk SSIR -- S(~riya
1,Chimicheski1kh Natfk., 11o 1; 19713., '-LIP 88-92
1
A
bstract: The results are preser,ted from a study oC the 3quill.tvii~ui diz ibu-
tion of cations (Na+ and A~1~ 4- ) end tile kinetics of the exe -ntmL,,e -process
between sodium. iiydroalm-.ocarbonatc and Aj,'10 solutions. The cotion-t~xclan~-,ta
a Or 1.1~~ . L
isotherm was detlermdnedl f ~,O AL-0 *2CO 2-31[?Q ~.nd a nixtj', -4~- of
3
sodium nit-nute wid ollver riltnil o, solutions. 'Nith the ion fract-lon oe siUrer
in the eouilibrium, liquid Divist.,m oquiil to or greater tho-n 0-1, tAu., ot'
sl-cbstituLon of AG, for Na Ln Lae ecuilibriuri solid is
Phases vith UaF and Pj,+ content are m-n-fluers of a continuous series
of so'-, 4~,d sol, utions 'bet..".3en, tho so~!i w.-I and silver f ormm of
,zhe li=itir--, Stai-e 01, exci,--4tLe is difi-Alsior, of the :.-',i+ and+ir)--is in tile
solid ohase. -fie mutual diffusion coefficient of the it-d-ieate~-?, ions d,~!terTAn-ld
on the basis of t~.qe kin,---tic uieasamv:ents D- 5.7-!'J-') or~-/fsc-~C
2/
Satisfactorily vith the calculated value of -5.1,10-0 cl-~i /see.
1-/l

USSR
UDC 546.791-'27'11
VOLKOV, V. V., GRk%1KTiNA_Z_. A., and MYAKISHEV, K. G.
"The Nature of Uranium (Tetravalent) Borohydride"
Leningrad, Radiokhimiya, Vol XIII, No 3, 1971, pp 401-405
Abstract: Tetravalent uranium borohydride, U(B114)4 is of interest as a
member of a comparatively new class of compounds, namely the metal hydro-
borates noted for the presence of boron hydride ions or radicals. ilv.%Tever,
the structure of U(B114)4, and its appropriate classification in the salt-
forming or the non-salt-forming categories of metal hydroborates, are in
doubt, thanks to contradictory published data.
The authors made a complete infrared analysis Of U01104 san?les syntile-
sized by the Braan-Schlesinger method; also, a thermographic sLudy of tl~e
samples.
It was concluded that the U(""4)4 molecule is of "bridge" structure, wEch
involves the presence of a substantially covalent U - B bond with partici-
pation of the "bridge" atoms of hydrogen. Further, it was shown that
1/2

USSR
VOLKOV, V. V., et al.,, Radiokhimiya, Vol XIII, No 3, 1971, pp 401-405
U(BH4) does not undergo any phase transformations in the temperature
intervil from -180 to 55'C. The interplanar distances which may char-
acterize U(BH4)4 were also determined.
2/2

f~P9053082_
UR 0289
PRIMARY SOURCE: Izvestiya Sibirskogo Otdelen:Lya, AN SSSR,
Seriya Khimicheskikh Nauk, Nr 12(162), Nr 5,
PP ?6--9;1, 11)3
A. A. Va s i 1'ey a, L. M. G i n d i n, - 7, _.A. G_r.~ ij k ill-i4,
G. 1. Sniirnov,a, I. R. Shelpakova, 1. G. judelevich
ANALYSIS OF PI:ATINUM METALS BY THE EXTRACTION-SPECTRAL
AND PHOTOAIETPIC METHODS . 1/
1. Extraction of Platinum and Palladium froin Iriditint ' Rhodium
and Ruthenium for the Analytic Purposes
In the extractioa of Pt (M), Pd (11), Ir (111), Rh (111) and RLI (111) with tetraocty-
lammonium bromide from toluenecaprylic acid (HR) and from foluene-2-ethylbeh-ano!
(R"OH) decrease of the acid (alcohol) concentration results in a decrease of the distri.
butior coefficients with all the metals studied.
Caprylic acid f,_-r1T11S a product of the composition (C81-117) 4NB,-)~ (HR2). With
J/
1839

AP9053082
Octylammoniurn bromide as revealed bv 'the JRS method.
This interaction is the cause of the "decreasing" effect of HR'(R"OlI) or, t1he abili-
ty of Br-ion to the exchange reactions with the extractable anions.
The chemical and spectral method have been elaborated for deteril'i nation ol
the platinum metals In HG-media.
1- 0

Acc. Nr: S, Ref . Code: vq 0,,zooll
410100219-
PRIIIARY- SOURCE: Izvestiya Sibirskogo Otdeleniya Akadendi Nauk-
SSSR, No 2 , Seriya Khimiclieskikh Nauk, 1970,
Nr j , p p 3 ?-,q V
L. K. C h u c h a I i n, Z., A. G r a xdiJu.a-j--
S. P 101ratie n k o, B. 1. "s"T. 6-~e v i t s k i y
INFRA-RED STUDY OF THE COMPOSITION AND STRUCTURE
OF HYDROXONIUM ION COMPOUNDS FORMED BY THE EXTRACTION
OF STRONG MINERAL ACIDS WITH TRI-n-BUTYL PHOSPHATE
Infra-red irv'7estigation o ft? solvates of tv.-droxonium ina founed by th,,,
of 111104 311d I ICIU, With tri-n-butyl PlID-Sphlite (TV) has been t-nade. S(,lvate~
I] l.,0 ilj~,01 11-1,C)
a'! $0 V,
tlli~,O -2J'120 - TBI)]-; havc becn found in uxtracts of IITIC~, anti solvale-,
IH,0-3ff2O]+,,olv-fli-0,211~0.*I'Bl)]',,, ll[30.11,0-2TB,')I~,fil:l()*'-142(J-'I'tl)' i0li
a q, so C --
acts of perCilloriC -pid. -ic:d concentration in orlanic
extra Wifli increase of
pFecce-aing- loTm lurrl,~ into substQuent one.
�r1 REEL/FMIE
19841609 Alc~

1/2 023 UNCLASS1 FIED PRUCESSING
TlTLL--FXTff'.ACTlf~-') OF MCIDS 6Y T~li"JFOCTYLAMINF- -IJ-
AUTH(,9-(04)-,'41K:.-4-LAYEV, A.V., KOLESNIKUV, A.A., GRIS11174, GRAiNAUNAt
C,efbrJ-M-JF INFI~,--USSR
SIJUPC~--UJKL. AKAL). fl[VUK SSW( L970f 191(5it 1074-6 CHEM
DATE PU3L ISHEID - - - - - - -70
SUBJECT AREAS-CHEMI IS TRY
TOPIC TAGS--AMII~ILE, ACIO, P0TENTIf3#'4ET.--,IC TlTtlATION., Im SPECTRUM, CHEMICAL
ANALYSIS
CGiNTMI'L Rir-ST-; [CTIONS
DOCUMFNT CLASS-UNCLASSHIED
PROXY
Sic[)
CIRC ACCLESSIO'l "i-5-AT0134797
L A ~! S 1 f1 E

2/2 023 UNCLASS I F I ED Pk,~)CESSIN,-, DATE-13NOV7C
CIRC ACCESSION NO-AT01.34791
ABSfKACT/EXTR%ACT--(Ul GP-0- A-6STRACT THE SYSTEMS Fr~l j.'Iti-iCTYLAMINE PH
SU8Z OPACID WERE STUJIFJ BY USIING THE ACIDS VICL, H SU63 PO Sti;14, HiNa
I., 'j
SU63, Aillf) H SU132 SO SU64. POTC-1-4110"ETRIC rfrRIN. ANJ IR METHOOS WERE
USED TO ANALYZE THE PHASES. IN THIS SYSTEM THERE 15 A LARI~-r-: REGION IN
WHICH 3 LIQ- PHASES CO'~7:XIST: AN AND 2 ORG. PHASE-S. (14F 0:~G. PHASF
CORRESPOINUS TO THE HYDkATED SALT OF TRIOCTYLAMINE AND TH-': CuPRESKINDING
ACID AiAL) THE OTHER PHASF TO TH~ PURE AMINEE. THE lk OATt, EST;%BLISH-;:D THE
INTER dAFSENCE OF INTEMACT,IGN BETWEEN THE SALT AND 14ATER USING THE HCL
SALT AS EXAMPLE. FACILITY: lt,4ST, '~EORG. KHl'-4.,
USSR.
LA SS 1 tJ

USSR
AGEYEV, N. V. , Acader,,2.-; ci an, PETROVA, L. A. , GRANKOVA, L P -1 V A 11;1()V, 1..
Institute of Metallurgy imeni A. A. BayRov, -7 ~-- I ~Of-C-fences of the USIS-~:"
Moscow
"A Titanium-Based Composite 14aterial"
Moscow, Doklady Ak-ademii Nauk SSSR, Vol 210, No )', I Jur. 73, Pp
Abstract: The Daper describes a composite laminar materia-1 hatsed on
titanium made by hot-rol ling in a- vacuinn. Fi-~e-layer and three-layer
composites are studied to determine the force and tenp(-i,atur~---
and the feasibil-ity of malking a strong
joint butween Jnyc-r~. T1,e plastic
component for the five-la-ered composit-e- was VT1 u-titLnium, foll 0.1 Mm,
j
thick. It wa-s assumed that a sheet built up fron, n Lkycrc of such foil
would have greall-er resistance to brittle fractiire thar, a nonolit-.1ic Shc-C--'-.
of titaniiza of -,he same thickness. The 'f'oil was etched irl dilitc- !~Y(J----
fluoric ae4d and washed in hot wf-Lter with hydrogen percyiJc- aocc-(] befr-'re
rolli-tir the sheet. A sheet 0.6 = thick vas t11'en rolled 1'rom nir-- layc-T~
of foil, Etnd t-.;c such s .reets were rclied together to r-ak- a ~elcut
1 mm thick, which was used in the canposite, The stren~,*I.'.-, mmaterial fc-.
112

USSR
AGFEYEV, N. V. et a!. , Doklady Akademi i Nauk SSSR, Vol 21.0, NIo I Jun '13,
PP 811-814
the comDosite was IVT1 alloy (Ti-7MG-5.5Cr-3Fe-3Al) in 0.6.1 rm cold-rolled
sheets. The two outside vlates and the central plate were IM allcy with
alternating 1E~vers of titanium foil. After assembly of the stt;~-k, the
edges were welded and rolling was done to 351% reduction at 12000C. T'lie
resultant 2.7 mr. -Diate was then cold-rolled to 2.'3 =-Tn. 'Fhe L'late cu-
in the direction of rolling into specimens which were het'-t treated an~
studied for structure, vicrohardress of the layers and diffusion redistri-
bution of the a-Iloying elements betveen layers. The three-layer sandwich
plates were made with a-titanium in the ouLer layers an(i at, allcy s-imilar
to IM in the center. The results of tests show that :1-vr_-cimens ma(i(, ur
of n layers of the stme inaterial tire stronger thazi a nionolithic plate of
the same thickness. Greater strength can also be achiev(i.,d by i_TICI*CI".I_IiriC
the number of layc-rf! in- & COEMOB-itr:
2/2

USSR
UDC 669.295:620.186.5
PETROVA, L. A., BABAREKO, A. A., GRANKOVA, L. P., KOZLOVSKAYA, T. M., and
SAZONOVA, T. N., Institute of Metillurgy ima"n-i''A. A. Baykov
"Recrystallization of 5-Alloy of IVT-1 Titanium"
IMoscar.4, Metallovedenive i Termicheskaya Obrabotka Metallov, No 11, 1972,
pp 30-34
Abstract: The ionization method of taking texturograms was used for plotting
polar figures. The changing character in annealing of polar figures describes
the process of recrystallization. Specimens were cut fro-m a bar forged by
broaching in two perpendicular directions at 950%. The specimens were an-
nealed in air at 400-1200'C with 30 min aging at each temnerature. The
textures of specimens of different grain size and boundary character in
continuous heating up to 700% are discussed by reference to microstructures
and polar figures. Specimens annealed at 600% showed a considerably changed
texture in comparison with the initial texture. This is connected with tile
begivInina, recrystallization, which is practically completed at 650*C. Ex-
trusion or forging by a more complex method is recommended for obtaining
stable properties of normal forging an two mutually perpendicular surfaces.
'No figures, one bibliographic reference.
1/1

USSVI
UDC 669.295.5:539.376
-AGEYMI , N. V., P ETIROVA, L. A. , GRF-KOV I N. A. 1 9",
kOZLOVS.K--kY,k, T. M. , and AI~LXOVEITKO, G. I, Moscow
"Creep of IVT-1, a S-Alloy of Titanium"
Moscow, IAIN SSSR, Mletally, No 12, ttar-Apr 71, pp 163-167
Abstract: The creep of M-1, a ~~-alloy of titanium (7'a Mo, S.S' Cr, 3% Fc, 3' Al,
remainder Ti) was determined at temperatures of 100, 200, 2-50.and 350cC at stresses
of 120, 115, 110, 90, 801and 71S kg/mn2 over 1,000 hours, and in some ca5cs uD to
2,SOO hours. Me 11imiting stress causing 0.0210- residual deformation of the allcy
after 1,000 hours. is 103 at 200C arid 79 kg/rmi' at 'M'C. Th,,~ rate of
stable creep -qt these stresses arid temneratures is 2-10-1%,11ir. The creep trsts
showed that if ti-M snccimens ttsted under identical conditions shot.., different
Initial deformation, the specimen wi-ch greater initial defcriaa-tion gc-ncrallv h=
lower creep than the specimen with less initial deformation. Total dc-for-.Iation
increases little -.1---*, th increasir,7, load Limne at 100-2~50cC and 120-75 2 /1171 1,T, Fol-
lowing creep tests. sc:ne oZE ~ phase grains is observed; :nigrotion o~ 3rLin
boundaries and displacement aiong grain axes (5lipping) were noted.
7 2

USSR UDC: 539.385
AGEYEV, N.V., PETROVA, L.A.$ TERENT'YEV, V.F., GRANKOVA
demo IM~6;4~
and KOZLOVSKAYA, T.M., lnstitute of hletalrurg_y imeni
A. A. Baykov, Academy of Sciences USSR
"Effect of Structure on the Cyclic Strength of IVTl Titanium
Beta-Alloy"
Moscow, Sb. "Ustalost' metallov i splavov". "NRUka" Press, 1971,
pp 70-73
Translation: The cyclic strength of IVTI titanitim alloy (6,7't~
Mo, 4.99% Cr, 2.87, Fe, 3.1% Al) has been. investigaLed under
alternating loads fOllOWiD9 heaL treatments unde.r variOLIS COn-
ditions. The structure of the alloy was examined a.,~ a JAII]CLiOn
of these condiLions under both lighL and electron microscopcs.
The highest fatigue limit of 5.3 kg/ijim2 was exhibited by an
alloy heat treated under the following specifications: harclen-
ing at SOOC for I hr. , water quenching, aging for 1.5 hrs. it
550C,,and coolin- in open air. The alloy treated undev these
conditions is Characterized by homogeneous decay of the/13-solid
solution. (3 illustrations, 6 bibliographic references:
summary) .

USSR
UDC 669.295.r):539.376
AGEYEV, N. V., PETROVA, L. A., GREKOV, N. A., GRA,"TKOVA, L. P.,
KOZLOVSKAYA, T. M., and ARKOVENKO, G. I.) M06cow"
"Creep of IVT-1, a B-Alloy of Titanium"
Moscow, IAN' SSSR, Metally, No 2, Mar-Apr 71, pp 163-167
Abstract: The creep of Wr-i, a 5-alloy of titanium (7' Mo, S.1546 Cr, 3' Fe,
remainder Ti) was determined at temperatures of 100, 200, 250, and 35OcC at stresse5
of 120, 115, 110, 90, 80,and 7S kg/mm2 over 1,000 hours and in some cases ur) to
~2,500 hours. Ilie limiting stress causing 0.02*0 residual deformation of the a I lo%
after 1,000 hours is 105 kg/mm2 at 2000C and 79 kglynm~ at 250"C. 1-he rate of
stable creep at rliese stresses and temperatures is 2-10-,`Q/hr. The creep tests
showed that if two specimens tested under identical conditions show differc-nt
initial deformation, the specimen with greater initial deformation generally has
lower creep than the specimen with less initial deformation. Total deformation
increases little with increasing load time at 100-250*C and 120-7S kg/M1712. [--O1_
lowing creep tests, some breakup of a phase grains is observed; migration of orain
boundaries and di5placerrient along grain axes (slipping) were noted.
72 -

Acc. Nr-. V0047353 Ref . Code: dhdy
PRMay SOURCE: Vest-,Ak Khirurgii imeni I. I. Grekova, 1970,
Vol 104, Nr t , pp q-T-Y-5
THE DIAGNOSTIC OPPORTUNITIES OF PORTO H EPATOGRA P HY WITH AN OILY/
CONTRAST SUBSTANCE
By i1. M. Ganichkfn, A.,4_. ~Grr and V. A. Mikhaylov
Based on the experimental and clinical studies it is felt tha t the use of contrast
substances on oil base widen the opportunities of portahepitogriphy, providing a distinct
Image of intrahepatic vessels.
REEL/FRAM
1979087.9

USSR UDC 621.396.677022)
ARDAB'YEVSKIY, A. I., VOLKOV, 0. A., VOSKRESENSKIY, D. I., COSVOIKIIIN, V. L. ,
f' YA. F I I OV,
GRANOVSKAYA, R. A., GRINEVA, K. I., KRITSYNT, V. A., WIAKISI a,,, PP
V -,CiitjmHEV4~ V. V.
"Microwave Antennas and Devices. Calculation and Design of Antenna Arrays
and their Radiating Elements. Textbook for Students at the Radiotechnical
Specialized Institions of Higher Learning"
Antenny i ustroystva SVCh. Raschet i proyektirovaniye antenny"'11i reshetok i ikh
izIuchayushchikh elem entov. Uchebri. posobiye dlya stud. radiotekhn. spetS. vyzO',7
(cf. English above), I'loscow, Soviet Radio, 1972, 320 pp, ill., 75 k. (from RZh-
Radioteldinika, No 6, Jun 72, Abstract No 5B32K)
Translation: 'Methods of calculating the basic parameters of nnLenna arrays
with electric rocking of the radiation pattern and . frequency and co-umutation
methods of controlling the radiation pattern are discussed. A study is made
of the structure of the optimal arrays with Dolf-Chebyshev distri .butLoll: t~-Ie
design of irised-wave guide and horn arrays and also methods of calculat-Ing
the array elements; dielectric, rod, spiral, horn and director antennas.

USSP UDC:
GRANOVSKAYA R. M. VOROB'YF~, 0. Yu.
AIWOWNSWROMWAM 2 ;4.~
"Synthesis of a iMathematical t4odel of a Reurcn"
V sb. Vychisi. tekhn. i vour. ki-bernet. (Ccriputer Technc-1cr-N, and Elrob_'~_::iS
of Cybernetics --collection of works), vj,-_o. 6, Leningrad, LeningraO Unl_
versity, 1971, D_P~ 139-156 (from M-Eibernetika, 11a 1, Jar, 72, AbF-Iract
No lV1107)
Translat--ion: An alc-critnm ic rrorosed for constructlor, _--f a net c~ si-ric
threshold elem=,s, enabling sirm-lation of the operation of any pre(7~,ivcr.
neuron of the su=mation neuron type, or the innova~_jcn and cu_rvature
neuron type. This algoriti,"m i~; made up of two independent zalr~crithr-..,,.
Important requirement"s are rade on the minizzium number of crjmpon(,n1. t,:1_1.e-
ments of the ne", high level of reliability in onc-ralior. cf, the nct, ar.,_`
these recuirements make the prob-ler: of narticular interev,. brth f'rom. tht,
standpoint of th(-, theory of neuron syntlic-sis, and from tht, !;tayit~roinz. of
technical real i tfon f'rr-- *,?~: threrhcJd elementz. A
of a representa ion of -.. neuron ne-twork in the form of' a r-,raih, oTr,-11-
tions an graphs, are Ot-fined. The ocheme of' an cori,,Ar~wt.jr,~j
1.12
- Olt -

USSR 8.,7):
GR~A I I-OVS'~-~%YA
vjp. 6, Lenin~, n:-1-a
rp
of a minimun. Craph is given well as an elgorithm. Cor synthesis of' an
n-input threshcld element. A. DorosN.,nknc.
2/2

USSR
UDC: 51:1551-001-57:6122.82
GR.A_NDV,S._ YA 'P. M. I 'ICROB'YEV, 0. Yu.
- il~~
"Associative Neuron Memory and Complexity of Neurons"
V sb. Lvchisl. teklin. in vorr. kibernet. (Computer Tec-hrolalry ard PrC..b.I(,!Is
of Cybernetics--collection of works), vyp. 8, Leningrad, Leningrad Uni-
versity, 1971, PP 1-07-120 (from RZh-Kibernetika, No 11, 11ov 71, Abstract
No 11V890)
Translation: The authors consider the Drobler, of constructinE a memory
model from homogeneous structural groups, where this mcdel has a cert;~.in
type of generalizaticn of input codes, i. e. it has certain prcre--ties
associative rremory. Consideration is also given to formulation of criteria
of complexity for neuron riodeln. The number of differert states of a neuron
which may show up with a change in its threshold is used as the basic cri-
terion of complexity. In this connection, the throshol.-d of' a i~;
defined as the minimu.7, anoun'.. of excitation necessary ror the neuron still
to be able to generate a pulse. it is noted that the trorcsed criteria
can be used to evaluate and compare the complexity not only of individual
112

USSR
GRANOVSK-AYA., R. M. , VO'.qOB'YFV, 0. Yu. , Vychisl. teklu-1. i -voir. kibernet. ,
vyp. 8, 1971, Pp 107-120
neurons with various sets of varameters, but also circuits of neurons of
different types and made up of several layers with different kinds of con-
nections. Tllustrative examples are given. V. Mikhc-ye-,7-.
2/2
- 64 -

USSR
UDC 0--11.9.(1-12F).O[):I.(-~:~7i.~.01
G. 1. , D-ctor of Technical Sciences, Professor,
A., Lngineer
"The Nature of 11.car of Teeth of High Speed, Dispursi on- Stcell,
Vestnil, .Mashinostroyeniya, No 11, Nov 71, pp 65-1-0.
ABSTPACT: The tv-car products of cutting tOOIS I-,,,IdC Of
steels 'from the Sharpening of various steels and ti tanium a.! loys werc, fculld
to be particles of the tool material, from I te JoO 11 ~111c,
0.1 to I p and more in thicknuss. They were spre;id UJIC\~L-n]` CA'Cl' 1:11i.-
of the material bein,,, v.-~)~,-Iwd froll! :1 few, p to I mm and mol-(~ iloal"t III arp-, (,f,
hig"W'St J)IaStiC Oll 010 C-011taCt St.irfaccs, stwroul)(iled ))v Oxldc~,-,
indicating increased loc;ll The di~;,ribul:ion of' Lh(.- 1),Irtic
structure, clic-riical ca-iqposi ti Oil and total mass indicatc, that
mcna are most significant in the ucar of 11jph SP-Ilud,
steel cutcting tw)l Mt-Chall i ~Ajl Of' ;H111C.Sioll Cotind 1 1", i fv-~
Th
d ult of-- f", tcol li;j- c I It t ing rate , c I It I. i jitf, I f,~- ~j I i]
cuttin,! dcoth t,-ithin L;ic StLIdi(!d.
only the illtulv~ily of' Ow lv:car, not il,~ nat.111'e.

USSR
UDC 621-357.7-035-52(088.8)
GRANOVSKLKL_;,L_jB. , LIFTMAN, 1. B., and SKOBLIKOV# R. I.
"Auto-operator for Galvanic Lines"
Author's Certificate No 316755, filed 28 Nov 69, published 24 May ?2 (from
Referativnyy Zhuzmal - Khimiya, Wo 8(11), 1973, Abstract Ito BL339P)
Translationt An auto-operator is patented for the galvanic lines i(hich con-
tains a mechanism for transfer, a mechanisa for lifting having a flexible
traction device, and a clamp for the hangers. It is iaproved in that in
order to increase the reliability, it is provided with an apparatus for
accidental disconnections accomplished by a double arm lever, one end of
which is connected to a sensor for the accidental shut off and the other with
assemblies for the deflection of the flexible traction device.
12 -

USSR
BASS, F. G. , A!;D GPN!r)VSYTX M, d Electronics,
- I Institute of Radiophynics an
Academy of Sciences rSSR, Kbar1kov
"Effect of Phonon Heating on the Propagation of Strong Electromagnetic Waves in
Semiconductors"
Leningrad, Fizika Tverdogo Tela, Vol. 12, No. 6, Aug 70, pp 2437-2441
Abstract: The nonlinear propagation oil electromagnetic waves assccia~Led with the
heating of electrons and phonons is considered. In earlier studies of" the propaga-
tion of strong electromagnetic waves in semiconductors it was assumed that long-
wave phonons with which conductivity electrons basically interact remain in equili-
brium; this is possible if the interaction of long-wave phonons with short-wave pho-
nons is more considerable than the interaction of long-wave phonons with conductIvity
electrons. it was shown in several theoretical studies that this situation does not
always occur and in a certain range of temperatures and external electric fields
dragging and hearing of long-wave phonons can play an ,important role and short-wave
phoncris carry out heating transfer. It is shown that in the case of strong electron-
phonon interaction the relationship between electron temperature and field amplitude
112

USSR
BASS, F. G. , and GRANTOVSKIY, M. YA. , Flzika tverdogo tela, Vol. 12, No. 8,
Aug 70, pp 2437-2441
changes along with the nature of field attenuation. It is shown -,hat the Maxwell
equations become nonlinear in the case of degenerate semiconductors and semimetals
due to Dhonon heating. The authors note that the results indicate the considerable
effect of phonon heating on the propagation of electromagnetic waves in a semicon-
ductor plasma; under phonon heating parameters of the phonon system enter into the
coefficients of reflection and other characteristics of the electromagnetic field
so that high-frequency methods can be used to study not only the electron but also
the phonon system.
411
2/2

Ahb047054 UR 0482
Soviet Inventions illustrated, Section Il Electrical, Derwent,
241555 EIXCTRI~LL CONDUCTIVITY OF GAS in magneto-
hydrody'hamic generac6is is increased. Gas
heated to IOGOOK is admitted to an ionisation cham-
ber where voltage signals are applied to the ion-
ised particles to accelerate the electrons which
result in further ionisation. The voltage is rem-
oved when ne reaches 1012 - 1013 /cm3. This is
achieved by 1.0-7 - 10-8 sec. long pulses. A pinch
developed then passes through a magnetic field by
which an emf that is proportional to the magnetic
field and speed of gas Is induced in the plasma.
The inEerval between ionising pulses is determined
by the development time to pinch. 15.7.64. as
-25. V. . ':.NOVICHKOV.
912030/26 L GRANG11SO, D.,
Lenin Electrotechnical Institute (28.8.69.)
Bul.14!18.4.69. Class 21g. Int.Cl. H05h.
Vsesoyuznyy_0rdena Lenina Elektrotekhrlicheskiy institut
iin. V. I. LenipY
Y,

USSR
uDc: 621.396.6.o19.3
PIR010HOROV, E. I. , ZHOFZH0LT_,1~,jj, B. L. , GRANOVSKIY, Yu. V.
"Investigation o--:' the Reasens for Failure of Modules in Conpley Radio Ecluip-
ment"
V sb. Nadezhnost' i kontroll kachestva (Prilozli. k, zh. "St-widartNr i 1-achest-
va!') [Reliability and Quality Control--collection of works (SuP.Plement to the
197.1, h'-9 '~ + .1
Magazine Standards and Quality)], No 1, Moscov, -1 from R,:,-
-Radiotekhnika, No 5, May 71, Abstract No 5V222)
Translation: Statistical data on the failure of modules during f1he manufac-
turing process collected over a period of a year and systematized accordiric
to special characteristics (construction defects, defects in assembiy and
adjustment, failures due to the quality of elements) are used as the basis
for analysis of the reasons for failures by the llox-Wilsori inc-thad of planning,
experiments. As a result of the analysis it is established that the quali.~;y
of elements has the greatest effect on failure of module!-, followed by circuit
quality and construction defects. Three tables. N. S.
-i /I

USSR LrDC: 519.24
GRANOVSKIY, Yu. V.
"Some Methodological Problems of Planning an Experiment"
V sb. Metodol. probl. kiber7iet. T. 1 (Methodological Problems of Cybernetics
--collection of vorks. vol. 1), Moscow, 19TO, pp 128-132 (from RZh-Kiber-
netika, No 1, Jan Tl, Abstract No 1VlT5)
[No abstract]
1/1

112 031 U N C L A S S I " I PROCESSING DATF--21NOVYO
TIT Lf:- -m OSS 3A UFR. STU D Y OF THE rHElU1QlM A GNE I It' TRE AT ME IIT OF T I CO N 11L 'tLLJYS
_u_
'UTH0R-(05)-P0V[rSKYj V.A., GRANOVSKY, YE.B., FRIDMAN, A.A., AAKAROV,
YE.F., PASHKOV, P.P.
&COUNTRY OF INFO--USSR
SOURCE-FIZ (KA METALLOV I METALLOVEDENIE, FEB. L970. 29, ( 2) , 247-25L
34TE PUBL 1SHED----FE370
SUBJECT AREAS--MATERIALS, PHYSICS
TOPIC TAGS--ALLOY, MOSSBAUER EFFECT, MOSSBAUER SPECTRUM, SPECTROSCOPIC
ANALYSISt MAGNETIC PROPERTY, METAL HEAT TREATMENT, X RAY
ANALYSIS/(U)TICONAL ALLOY
C0WqrjL MARKING--N0 RESTRICTIONS
DOCUMENT CLASS--UNCLASSIF[Ef)
PROXY REEL/FRAME--"003/0212 STEP ~10--UR/0126/70/029/002/0247/0?51
CIRC ACCFS')ION PIO--AP0129463
UNCLASSIFIEU

212 031 UiNCL ASS IF I EO PROCESSING DATE--27,14OV70
CIRC ACCESSION NO--AP0129468
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. TliE EFFECTS OF THERMOMAGNETIC
TREATMENT (ISOTHERMAL QUENCHING IN A MAGNETIC FIELD) ON THE STRUCTURE
AND PROPERTIES OF TWO TfCONAL ALLOYS WERE STUDIED BY A TECH-NIQUE BASED
ON THE MOSSBAUER EFFECT, MOSSBAUER SPECTROSCOPY WAS EMPLOYED IN
CONJUNCTION WITH X RAY DIFFRACTION TO TRACE THE BEHAVIOUR OF THE ALLOYS
AT VARIOUS STAGES OF HFAr TREATMENT. IN THE FIRST STAGE OF AGSING AFTER
QUENCHI.NG IN A MAGNETIC PHASES OF THE ALLOY TOOK PLACE; IN THE
SUBSEQUENT STAGE THE DEGREE OF ORDER OF THE WEAKLY MAGNETIC PHASE
STARTED INCREASING.

1/2 014 UNCLASSIFIED PROCESSINIG "'AFE--04GE77~-,
T ITLE--VIBRAT IONS OF THE NITRO GRCUP IN NITROPHENOLS WITit lNfRANOLECULAR
HYDROGEN BONDING IN PROTON ACCEPTOR SOLVENTS -U-
AUTHOR-(03)-GRANZHAN, V.A., SEMENENKO, S.Vol ZAITSEV, P.M.
COUNTRY OF INFO--USSR
SOURCE-ZH. PRIKL. SPEKTROSK. 1970, L2(5)v 922-5
DATE PUBLISHED ------- 70
SUBJECT AREAS--CHEMISTRY
TOPIC TAGS--AROMATIC NITRO COMPOUND9 PHENOLt HYDROGEN GONOING,
INTRAMOLECULAR MECHANICSt SOLVENT ACTION
CONTROL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY FICHE NO ---- FD70/605018/Bll STEP
CIRC ACCES5f!_.-'l" NO-AP0140i~)00

2/2 014 UNCLASSIFIED PR 0 C. E ~ S 1 "11C, 1,,l T L- C) 4
CIRC ACCESSION NO--AP0140800
ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE EFFECT OF INTRAMOL.
ON FREQUENCIES (NU) OF SYM. AND ASYM. VALENCE V15RATIOINS fjii~ -V) '-,!J111~
GROUPS OF SUBSTITUTED NITROPHENOLS, IN DIFFERENT SOL'YENT.S), AN:') THEIR
MIXTS. WAS STUDIED. IN BASIC SOLVENTSt NU SUBSYM INCREASE.0 OUL TO
DISRUPTION OF THE INTRAMOL. H BOND (NO SUB2-OH) AND rr~ORMATION OF
INTERMOL. H BOND BETWEEN OH GROUP OF THE PHENOLS AND MOLS., OF THE
SOLVENT. IN MIXED SOLVENTS, THE INTENSITY OF NU SU6SYM OF THF FREE AND
BONDED NO SUB2 GROUPS DEPENDED ON THE CONCN.-OF NONPULAR AND PROTON
ACCEPTOR SOLVENTS.

112 018 UNCLASSIFIED PROCESSING DATE--20NOV70
TITLE--A GIGITAL MEASURI.iG SYSTEM FOR AUTOMATIC INTERI-EkOMETRES -U-
AUTHGR-(05)- UA ~!ll IM.YA., LORIN, D.I., KAYEKIN, V.V., SVEKOLICHENKO,
V.D.t SFESTGPALOV, YU.N.
CCUNTRY CF INF'U--USSR
SOURCE--b!USCCa, IZMERITEL'NAYA TEKHN ~KA, NG 2, 1910,PP 35-37
DATE PL8LI5HED------70
SUBJECT AREAS--PHYSICS
TOPIC TAGS-016ITAL SYSTEM, INTERFEROMETER
CC,"4TPCL RF-')T!(fCTIC,qS
DOCUMENT CLASS--UNCLASSIFLED
PROXY REEL/FkAML--L994/1463 STEP
CIRC hCCFSl',C:,J N111--AP-0115393

212 0181 UNCLASSIF[Et) PRIXESSI.NG
CIRC ACCESSICN NO-AP01,153933
1BSTRACI/Ex1RA,'T--(U) GP-0- S T4,- T T P.G D II TAL '61- ASI,;~.,' ffl~' ISYS I L.0
IS iNTENLE-0 f7fk CHFCKP'iG ~-AICHEU MEASURES OF LEN`---"fH UNLER DY','iAMIC
CC,%D I T I C% EThE ESSEM-E 6F THE METH(210 CF MEW'JREMENTS THE LP-16f;-i
THE SubUIVISIGNS 1JF Ht~,TCHI'E,) MEASURES CONI'S[SrS M, THE f--.ACr THAT
REGISTRAT[CN Gf- THE CROER GF INTERFERE.NCE ANG FIXATION OF rHE
MEASUkEMENT k-ESULTS CAT THP~'.0,4ENT THAT THE C,':-;v[FK OF FHE HArCH PASS'LS
UNDER TFL AxIS OF THE SLIT LF I PHUTCELECI-kIC CRUS,,-,'oPf: ) r4,ixES PLAd'E
OURING 1, CGINSTAN'T CHAN.-GE OF THE U;)TICAL DIFFF-r,~ENC~E OF ]"HE: CuUkSE 1,DF
V -i E ", A L
IN TFE 1NTEFFE-,,CMETEK. 11-4 ACCORDANCE WITH THIS, F~-FUNCTV"i LAY
OF THE DNA CGNSISIS GF A PiAuTGE'LLCTRIC DL-VICE FOR UPOE;,:
INTERFEkIl-i%CL -A.,NC A DEVILE c~.E~A-STERING THE mA:,1,E~,r fi-4-T [HE CENfl-:~
THE HATCH PASSES UNDER THE AXIS OF File SLIT UF IHE PHU-] '-,'ELECT IC
MIC&USCLPE FUR OUTPUT "JIF rHc- SIGN.AL CF RECCIROING, L-F THF 11" E ASUR EM ENT
RESULT. THE ---ASiC METRULO(ACAL AND Tt-~~-HNICAL Pt~RAMETLIRS OF ME DMIS
PRESENTED.
i f I L

USSR
UDC 547.241
gE&W F., KOZLOV, V. A., BABKINA, E. I., and IMELNIKOV, N. N. , All
X,. ~.
Union Scientific Research Institute of Chemical Plant Protective Agents,
and the Branch of the Scientific Physical-Chemical Research Institute
imeni L. Ya. Karpov
"Chlorocyclohexylthiophosphonic Acid and Cyclohexenylthiophosphonic Acid
Chlorides and Araides"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 9, Sep 73, pp 1919-1921
Abstract: Heating phoiphorus trichloride with
phosphine at 125' for 3 lirs yields 2-clilorocyc.LotiL,-..cvltiii,:)I)hosplionic acid
dichloride, which reacted with triethylamine in betizene solution converts
to cyclahe.-Ken-1-ylthiopliosplionic acid dichloride. a-Cliloroc,~elolie-,:vldichloro-
phosphine reacted with triethylamine yields cyclohexen-1-yldicliloropliosphine
-w can be converted to a derivative of tetracoordinated phosphorus by an
exchange reaction with phosphorusthiotrichloride.

USSR
UDC 547.451
GRAPOV. A, Fe, and MELINIKOV, N. N., All-Union Scientific Studies Institute
of the Chemical Compounds for the Protection of Plants
"Organophosphorus Fungicides"
Moscow, Uspekhi Khimii, No 9, Vol 42, 1973, pp 1681-1698
Abstracti The current literature on particular organophosphorus compounds
used as fungicides is reviewed together with such Information as synthesis,
doses, types of organisms against which each is effective. etc. Classes
of compounds discussed include derivatives of phosphorus and phosphonous
acids, phosphine, phoopnone salts, the acids of tetracoordinated phosphorus,
its salts and its esters, and the amidas of the various phosphorus acids.
The latter two sections were considered in much greater detail than the forrar
sections. The fungicidal activity of F(III) is apparently due to its being
a reducing agent. The phosphone salts are significantly more effoctive than
phosphine,
1/1

USSR UDC 547.26'118
GRAPOV, A. F., KOZLOVA, T. F., MEL'NIKOV, N. N.
"Alkoxy- and Alkylthiomethylthiopbosphonic Acid Dichlorides"
Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 3, Mar 73, p 676
Abstract: The best method for the synthesis of thiopbosphonic acid dich-
lorides is by heating the corresponding phosphonic acid dicilloride with
phosphorus pentasulfide to 120-160*. Following acid dichlorides have
been synthesized, parent acid, b.p. n25 and d25 being reported:
methoxymetliyltliioptiosphoiiic, 34-35*~02'mm, I.i5l,8, 1.4262; ethozy-
methylthiophosphonic, 34-35*/0.12 mm, 1.5358, 1.3512; ethylthlomcthyl-
thiophosphonic, 66-67.5'/0.12 mm, 1.5852, 1.3797, isopropylthiomethyl-
thiophosphonic, 82-82.5*/0.17 mm, 1.5702, 1.3392; and butylthiomethyl-
thiophosphonic acid, 85-86'/0.17 mm, 1.5622, 1.2975.
1/1

USSR
UDC 632-95'
qAMAJ~-- I-EL-NIKOV, N. N., ANDREYEVA, YE. I., RASVODOVSKAYA, L. V.,
PROXCHENKO, T. S., USMANOV, M. T., kaUAYLOVA, 0. B., SPalTiOVA, X. F. , and
ZBARSKIY, F. SH.
USSR AUthors' Cer'Uficate No 276572, Cl. Aol n 9/36, filed 13 J&n 69,
published 11 Feb 72 (from Wh-Khlmiya, No 20, 25 Oct 72, Abstract No 201N582
by T. A. Belyayeva)
Translationt In order to widen the assortment of effective fungicides for
controlling cotton wilt, it is suggested that use as systemic fungicides
be made of asymmetric diamides and amidohydrazides of alkylphosphor-ic and
alkylthlophosphonic acids of the formula R'R"N(R)P(X)(NH)nR"(I) (R and R'
- alkyll R" - H or alkyl; R"' - unsubstituted or substitut.ed phenyll n - 1
or 2; X - 0 or S). I is obtained from amines or hydrazidea and alkylphos-
phonic or alkylthiophosphonic acid chlorides. The preparations were tested
under field conditions on naturally infected plants. Experimental results
showed that, as compared with control, I possesses definite systemic activity,
suppressing the development of cotton wilt. Data are presented on tests of
I in comparison with phosbutyl.
1/1

USSR UEY': 5)i-(.'D'l
4
KOZLOVA, T. F., GRAPG11- A '., NELIHIKOV) N. N.) All-Union Scientific Research
Institute of Af~ents for Plant Protection
"The Reaction of 04',--thyl Dichlorophosphite With Alkyl Chl orone thy]. Et'ners,
Catalyzed by Boron Trifluoride Etherate"
Leningrad, Zhurnal Obshchey Khirnii, Vol 42(10h), No 6, Jur, 72, pp
Abstract: The authors studied the reaction of alkyl chloromethyl with
methyl dichlorophosphitc, cataly-zed by the etherate of boron trirluoridc.
When the reaction mixture is heated for several hours at 8o-loo0c, alkoxy-
methylphosplionic acid dichlorider, are formed in 25-55-~,i Yl-uld- Tne reaction -J~3
apparently analol-;ou.-i to the Arbuzov reartion. The eluctrophilic boron
fluoride facilitates forr-ttion of an intermedinte
C)fj"0 CL 10
CH,QPCL-~4 k0C11,CL+8F, --- v\-~ CUF ROCH 1"rl, 1 ("!Vt 4 BF3
POCH CL
Aniline in an ether sol,~,tion readil- converts the alkoxvilleth, I -rffiosl-" an4 c acid
dichlorides to the correGpondin!7 dianilides.
q
The authors thank V. V. Uefrebetshiy for studying the nmr s-c-r-tre. of the com-
P,91,.nds.
11-1. i

USSR
UDC: 547.26,li8
MIKHAYLOVA, 0. B., MELINIKOV, N. N., All-Union Scientific
Research Institute of Chemical Agents for Plant Protection
"Methylthiophos-phonic Acid Dihydrazide"
Leningrad, Zhurnal Obshchey Miiriii, vol 42(lo4), 1~o 6, jun 72, pp 1420-1421
Abstract: Experirental work was done which showed that h'ydrazine hydrate
acts on 0-2,4-d-ichlororhenyl rethylthiopliosphonic acid chloride with h'ydrazin-
olysis of both the acid chloride and lcbile ester bonds to give nethyltlhio-
phosphonic acid dihydrivide. Treatment o' the reaction mixture with excess
potasslum carbonate isol,-tt.,s the end product.
S
+ if
".I&thylthi-o-nhos-z;',i,)r,i-c acid dibydrazide with benzaldehyde _and substituted
benzaldehydes Vi-ves the corresponding bydrazones.
1/1

USSR
uDc 632.95
VLAD=ROVA,? i. L., MANDEL'BAUIM, YA. A., and KEL'NIKOV, N. N.
"Fungicidal Mixed Ester-amides and Diamides of Thio- and Dithiophosphoric
and Phosphonic Acids"
V sb. Khimiya i prineneniye fosforor~.an. soyedin. (Chemistry and Application
of Organo-phosphorus Compounds -- Collection of Works.), 'Moscow, "Nauka," 1972,
pp;449-476 (from RM-Khimiya, No 14, 25 Jul 72, Abstract No 11111485 by
T. A. Belyayeva)
Trans.lation: qlie authors synthesized ester-amides of thi.ophosphoric acid
amides and hydrazides, of 0-all~.,~l-S-aryldithiopliorrlioric acid, estc- 1--urlij des of
methyl-, chlorometh.-Y-1- and trichloromethylphosphonic acids, O-all,,yl 14, IP-
diaryldiamidothiopliosi)',Iates, O-alkyl N-alkyl-li'-arylclieiiiidothiol)iit)ST)hl',es,
amides of thiophosp .rionic acids, dithiocyclodiphosphazpnes, and diamides of
methylphosphonic acid, in order to study their fun,ricidal activity. Ester-
amides of meth,vlpohosphonic acid, although containin;r Cro-j-ps clipable of pnrtici-
sjppreE,3 tI
pating in reUox procennes, he growth of fun!-,al or:~ani..-,rns weakly.
Derivritives of thtopho.,;phoric and thiOT)h0aphonLc acid.~; i-nowed irnif'icant
cidal activIty. S-Ar ,v! wddo4ithiophosnhates porsesr; ti;,:! h-jOlk."fft D!Ywici,!~11
activity. 'Fqe funrjej.0-al activity of the preparations IjMlalj~l eW4~jj -11
increase of the radical at the nitrotfen from Cl to C)~.

I
USSR
UDC: 547.26,118
RAZVODOVSKAYAJI L. V,, QjjQ11 A. F., MELFNIKOV, N. N.. All-Union Scientific
Chen,=,I,rm awm
'ic -ant Protection
Research Institute of Chenica gents for PJ
.a )rten
"The Reaction of Phosphonic and Thiophosphonic Acid Chlorides With
0(-Pyrrolidone"
Leningrad, Zhurnal Obshchey Xhimii, Vol 4?(lo4), rib 6, J-,In 72, pp 1277-1282
Abstract: The authors investigated the reaction of phosphonic and thiqnlios-
phonic acid ch1crides with substituted amides of carboxylic acids and lacLams,
and also studied the reaction of secondary amides of phos-phonic acids with
acetyl. chloride. It war, found that when p.~iTrolidon-2-yliN,-t'~lylplio.-,V)',Ionic acid
chloride reacts with primary and secondary amines and ariiiines, aS,,!rM:ff4triC
diamides of methylpha3phonic and thiophosphonic acids are formed. The same
products were formed by reacting 3),,~rrolidori-2-ylrf.,ethylpho3piionic acid with
prirrzry aminer, and anilineu. The products of the reaction of pyrrolidon-2-
ylmth,ylphosphonic acid with secondnry amines, alcohol and phenol underf-,o
thermal decorrmosition leadinG to the formation of a -thiov rrolidone an, ts
conversion prodl~cts. ~tlien methylphosphonic acid dichlori-_;e naacts with
U
pyrrolidone, a nixture of I)yrrolidon-~l-jl,ir,~,,,'tilYlTi~10-~, honic ar-id c' lorfd,~-, I -

w
USSR
RkZVODOVSKA-fA, L. V., et al., Zhurnal Obshchey Klairdi, Vol 42(104), No a,
Jun 72, pp 1277-1P82
(pyrrolinyl-2) pyrrolidone-2 phosphonate and di(pyrrolidon-2-yl) dimethyl
pyrrophosphonete is produc--d. 'Fhe authors thank T. F. Tulyakova, M. Sh.
Shifman and M. K. Vasilenko for doing the spectral studies.
2/2

Compounds
USSR
UDC 632.954
LEBED
1,RAPQY EVA, 14. V., MEL'NIKOV, N. N., SERGEYEVA, T. A., STONTOV,
!.--D.-s--TfT-OVA, L. M., and VOLKOTRUB, E. N., All Union Scientific Research
Institute of Chemical Means of Plant Protection
"A New Herbicide Called Isophos"
Moscow, Agrok-himiya, No 1, 1972, pp 96-103 N11C H sec.
4 9-
Abstract: Herbicidal properties of isophos-1, ClC11915 1~11 H Cl and
OC6 3 2-2,4
ZN1'C3"7-"-
isopho.q-2, C1012 1) 11~1 OC0113C12-2,4' were tested on many plants, includIng
cockspur grass (Echinochloa crus-galli), and rice grass (Echinochloa orvzicola),
the weeds which commonly grow with rice. Application of 2-6 kg isophos-1 or
isophos-2/ha killed 100% of the above weeds. The best time for application of
the herbicides was before sowing of rice, or prior to its sprouting. A surface
application produced the best results. Both types of isophos in 4-8 kg/ha
doses were toxic to garden orache, amaranth, and white bent. Field Dennycress,
spring wild oat, and knotweed were of average sensitivity toward isophos.
1/2

TJSSR
GRAPOV, A. F., et al., Agrokhimiya, No 1, 1972, pp 96-103
Among the cultivated plants, rice was most resistant toward this herbicide,
followed by wheat, oats, and barley (most sensitive). Cotton, beans, radishes,
and sunflowers are resistant to isophos, but sugar beets and flax are sensi-
tive. Carrots were most resistant to isophos in doses of 1-4 kg1ha and
tomatoes and cucumbers showed medium resistance. Isophos was 100% effective
against rice grass in meadow-marshy, soddy-podzolic, and sierozem soils. It
was only 83-97% effective in soils with high humus content. Effectiveness
of isophos lasted for 30-100 days after application. Analysis of the Soil
horizons indicated that it remained mainly in the top 0-10 cm of soil. The-
structure of theJaryl radical determines the phytotoxic properties of amides
of thio- and dithiophosphonic acids. Presence of two C1 atoms In the phellyl
group increaser, the herbicidal effects of these compounds.

U;Ssr.
IJDC 547.341.26'118,D7
MIKRAYLOVA, 0. B., ',IIEL'NIKOV, N. N., and GRAPOV, A. F.
"A Method of Making a-Phosphorylated Semicarbazides"
Moscow, Otkryt4-ya, izobreteniva, promnyshlennyye obraztsv, tovarnvve ~nakj_
No 9, Mar 71, Author's Certificate No 296774, Division C, filed 26 Feb 70,
Published 2 Mar 71, p 83
Translation: This Aur%or's Certificate introduces: 1. A method of producing
B-phosphorylated semicarbazides of the general formula
Clia-, < 0 0
ArO / NIINH -JIMMIR
where R is an alkyl or aryl., and Ar is an aryl. As a distinguishing, fe;lture
of the patent, an unsui)stituted hydrazide of 0-ary1riethylphoschanic acid is
interacted with alkyl- or arylisocyanate in an organic solvent such a.,; ben-
zene with the application of heat and subsequent isolation of the goa-I product
by conventional methods. 2. A modification of this irethod distinguished by
the fact that heating is done to SO'C.
1/1
- 16 -

USSR
GRAPIOV A F. MIEL'NIKOV, N. N. and R_AZV0D0VSKAY..%, L. V. ~'6
fffrc8-'_R'e"se arch inst4tUte for Chemical Means oC Plant
State Committee for Chemistry USSR
"Cyclodiphosphazanes"
Mosco-w, Uspekhi Kliimii, Vol 39, No i, Jan 70, pp 39-61
Abstract: Recent foreign and Soviet literature on
i - :-I. i a~i cs
membered NN-P ring compounds which might be uscicl in
or biologically active preparations is reviewcd. The.
contain alternating P and N atoms in the ring urith Lri.
coordinate P atoms. The reviewed data pertain -ko
structure of cyclodiphosph az zinc ring and studies oL'_
conversions, and physical and chemical properties o.C
Relative )(-)~.4tjonS Of ;,ktL,M.-
in the mol(!cules worsl!
of the N-IjI bond was conclusLvely in compoulli~~, k_.'LC"k- L-(;
penta-coordinate P atoms only. Thuse conclusions
tained by X-ray diffraction study, analysis of the Tj?, f'V,
spectra, and measurements Of dipole Moments.
.1 /1

UIOSR UDC 547.241
MIKHAYLOVA, 0. B., GRAPO HEL'NIKOV, N. N.
Y_ A. P., and .
"Phosphorylated Semicarbazides and Thiosemicarbazides"
Leningrad, Zhurnal Obstichey Khimii, Vol 43 (105), No 7, Jul 73, pp 1449-1451
Abstract: Reaction of the hydrazides of 0-arylmethylphosphonic and tliio-
phosphonic acids as well as that of the lt,N-diethylamictometLivltliiopliosplionic
acid with alkyl- and arylisocyanates, alkyl- and arylisocyanates was in-
vestigated. The products of these reactions are ~-phosphorvlated semicarba-
zides and thiose-,nicarbazides. The Dhosphonic acid hydrazides react faster
with isocyanates than corresponding thiophosphonic acid hydrazides. 'Elie
structurqs of all products were confirmed by IR and PMR spectral data.
I /I