SCIENTIFIC ABSTRACT GRISHIN, E.P. - GRISHUKHIN, V.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002201020012-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

2/2 023 J,',;C 1.4 S S I F I E D P P, (:, C E. S S I N G DA T E - - 13 -,~i j 117 C
CIRC ACCI---SSiGN Nlu'--AT0t34797
ABSTK,XCT/EXTjR.ACT--(U) GP-0- ABSTRACT THE SYSTF,14S Tr'~l ,,i,C;CrYLA!,1lINE,H
SUB2 0,4C[0 YiFRE STUJIF(') BY USINC', THE ACIDS HCL, H SUB" NO SUB4, Hi',,'O
SUB3, AND H SU,92 SO SU34. POTENIA131,1ETRic r[TRIN. A.N;j lk METHODS WERE
USED TO ANALYZE THE PHASE-S. 1.14 THIS SYSTE-M THERE: IS A LAR,,)E 9"~~GION IN
WHICH 3 LIQ. ;JIIASES CCI,,:xIST: AN Ati. AND 2 ORG. PHASES. G;IE ORG. PHASE
CORRESP&INDS TO THE HYDkATEO SALT U~ lRicurYLAMINE ANJ) THE CljfRESPjfjoING
ACIL) ANU THE OTHER P14ASE TO THE PURE AMINE. THE [k DATA ESTABLISHED fHE
INTER PAESENCE OF INTEr-ACT.10H BET~,-,E&'i THE SALT AND WATER USING THE HCL
SALT AS EXAMPLE. FACILITY: INST. f~EORG. Klif'li.p NOVOSIoIRSK,
USSR.

Acc. N Abstracting Service: Ref. Code:
W~0049777 CHEMICAL ABST.-r-76
e" 101972k Determination of acyl groups in cellulose acetate-
butyrates. Nlironov 1) p.; -'] - - '. 'harkov. V. V.1
pozosov 2 Vu. L. (USM*. Plaies. ~Iassy ~197d, (I ), 134-5 (Russ).
Th; total VOIRCTIt of acvl groups in cellulose acetatebutyrate (I)
wa,~detd. hysapon., whereas the content of PrCO groups wat, detd.
by ir spectroscopy at '!1370 crn-'. Thus, I was placed in a conical
flask and mixed with Alv.,CO and set aside ior 20-60 min. The
mixt. wasshaken, and (1.5,Vaq. MeOll soln. of Na0H was added;
the rnixt. was refluxed at 65* for 3 br. The sapond. sample was
neutralized with 0.5N HCI and titrated with 0.5N KOH. Opti-
cal d. of I was measured at 2970 cm-' and of a std. at 1430 cm-1.
The content of PrCO groups was detd. from the ratio D2970/
D141-0 and froin the corresponding adsorption coeffs. The con-
tent of Ac groups was calcd. from a general equation. CKJR 4
REEL/FWIE

USSR UDc 621.396.6-72:621,7101
KOPYLOV, Yu. N., GRISHIN, I. S., SAT-)OV3K!Y, A. A.
"On the Problem of the Stressed State of Joints in Di--~TL-3ion 1,-1elding"
V sb. Progressivn. teklinol. i _novoye oborud. dlya T)rf)i-;-,-_Va elektron.
borov TP-rogressive Technology a-rid Dew Equipment f(--)r Making Electronic Dt?-
vices-collection of works), Saratov, 1970, pp 85-87 (from
No 12, Dee 70, Abstract No 12V310)
Translation: The authors discuss the rossibility of r-,-.~ducinz residual.
stresses caused by the di'f;~rorice in pnysicom~~chn-nical. cbaract,~-risltics of
7
materials in welded ioizitu of dif.Acctrics with meta.1z. Th,~., r-zults of a
0
study of welded joints in quartz glass show that minimv~,--i residual strt.!.,,se~-
are observed -vhen higli-ductility metals are used (Ag arid Cu) in thin
etching of the ground-glass surface 5-mediately before weldi-n,- a1so pro-
mates reduction of the stress level. N. S.

USSR LJDC ~2L
RIS,
HN L.
G
"Tomverat-ure-Rate D(.n-,ozidence of' Resistanec o," CertIJ.n
Moscow, No 4, A-c!j" 't2l p-p I'-')
Abstract: Cill-ed are the result.~ of exverim~cij4.s oil
steel, and AK6 aliupinixm and. VT3-1 ti.tan-iLun alloys to
as a .~'unction o-f del'ol-nation tC-T,1-po,-atur-,:, and rates. T;~u da4-a
on tests involving u.,i),set-L-InC th-e rae"als' --n
30 uun long) (11i, u-,e oc a (-Impc)~,'der p.*Ie di-Iver. rl~!,:- 4~i~ 1%
ref,lecti-A in r!lwvct~ :;howinl- varIaLLon'; of,
tcmj)Qraturt..,~ t.uid i-,.-
lice (in thu Cw-v~~;;
-u'J~;n f'or the 45
def'orm,,jIi-on v.,,-. dc-fo-r,
bu'ued Lo the ui'l.'ect rjIf p-la,;t:i e defon,,i~~Lti,.n whi 01 J(pud
dif f er-n t wftli iJnc ~; Ulu) undvi,
r

USSR mi)c: 681. 327
BURDONSKIY, I. N-, G KURBANOV, Sh. M. , MARKELOV, V. P. , SER-
GEYEV, V. V SIDORD BUROVA, L. MI.,
MKO, V. R., TSEREVITINOV, S. S., SHA
Moscov
"Computer Processing of Optical Interference Patterns"
Novosibirsk, A-vtometriya, No 4, Jul/Aug 71, pp 21-26
Abstract: The paper is a report of initial experiments in using a phrto-
metric scanning system in conjumction vith a gene ral-purpose computer for
analyzing halftone images (optical interference patterns). Line-scanning
of the pattern was used for computer input through an analog-digital con-
verter with 64 levels of qiwiftization. A flowchart of the processinU. pro-
gram is given. 'Me results of computer plocesging on the Mins-k-22 com-
puter are compared with manual analysis for plasma interference patterns.
Excellent agreement is observed with a time reduction of more than t,,.,o
orders of magnitude for machine processing. The authors thank V. S.
Vaynshteyn and M. I. Fergament for taking part in the initial phase of
the work. Three figures, bibliography of five titles.
1/1
- 62

USSR
LEVIN, G.E. , 1RISHIN, Y.-E. , PCTAFCV, A.M.
"Photoelectron Device"
UDO 621.,~8~1.292.8
USSR Author's Oertificute No 25'.951, riled 5 June 68, publisined 16 Tine 7C (from
RZh--Elektroni~a I ye~~-Irl--enq No 12, December 1970, iibatric;t No 12A242p)
--L- -!!lye .1
Trunels tion: A nhotoelectron device is proposed which consists of d nhcto.-Dultiplier
with a hiFh resolution time and a resonator coupled with it, which has septirute
channels for input and output of the siEnal. dith the object of in increase of the
signol-to-noiee ratio during reception of optical siEnala zodul,!tted in d narrow
band of the microwave ran7e, the anode input of the photomQ1tiplier Is introduced
into the resonator cavity through un input channel kind ht~e the form of a loop.
1/1

USSR
UDC 537-563t547-23
FRIDLYANSKIY, G. V., PAVL---IFKO, V. A., VINOGRADOV, B. A*,~ ~t. imeni
BOGOLYUBOV, G. M., and PETROV, A. A., Leningrad Technol.
Lensovet
"Organic Derivatives of Group V-VII Elements. XX. Exact Composition of Ions
in Mass Spectra of Alkylphosphine Sulfides and P-S Bond Strength"
Leningrad, Zhurnal Obshchey Khimii, Vol 41, No 8, Aug 71, PP 1707-1709
Abstract: The article describes results of the measurement of mass numbers
of ions in mass spectra for triethylphosphine sulfide and tetraethyldi-
phosphine disulfiae on a double-focusing mass spectrometer. The dissocia-
tion energy of the P-P bond in tetraethyldiphosphine disulfide was previously
found by the authors from the appearance potential of the ion (P',/2)+. Pre-
cise measurement of the mass in the present article confirms the com-position
assigned to this ion. The dissociation energy of the P--S bond was found
to be equal to 3.7 ev or 85 kcal/mole, which is in satisfactory agreement
with the value obtained from the thermal effect of the tripropylphosphine
oxidation reaction (91.6 kcal/mole). Determination of the exact composition
of ions in the mass spectra of alkylphosphine sulfides shows the resistance of
the PaS bond to the action of an electron impact. This resistance lz; chzLrac-
teristic of the chemical bonds between atoms of Group V and VI elements
possessing unshared electron pairs.

USSR
LIDC 537-563,54?.242
BOGOLYUBOV, C. M., and PETROV, A. A., Lenins=ad Technological
Institute imeni Lensovet
"Organic Derivatives of Group V-VII Elements. XXI. I-lass Spectra of Tri-
alkylarsines and Tetraalkyldiarsines. Effect of Alkyl Substitution on
Bonding Strength of Adjacent Reteroatoms"
Leningrad, Zhurnal Obshchey Khinii, Vol 41, No 8, Aug 71, Pp 1710-1714
Abstracti The authors took mass spectra of triethyl-I tripropyl-, tributyl-
arsines and tetraethyl-, tetrapropyl-, tetrabutyldiarsines and determined
appearance potentials of the basic ions. The mass spectra of tria-lklylarsines
and tet,-Laalkyldiaraines display features characteristic of alkyl derivatives
of Group V and VI elements of the thirs and higher periods, i.e. high intensity
of molecular ions and predominance of ions formed with cleavage of E-C bonds
as compared to ions formed with cleavage of E-E bonds (where E is an atom of
a Group V or VI element possessing un hazed ekctron pairs), A corriDarison of
dissociation energies of E-Ebonds in alkyl derivatives with dissociation
energies of diatoaic aolecules E2 indicates that alkylation weakens the bond
strength of adjacent heteroat-oms.
30

USSR
UDC 537.563:547-241
BOGOLYUBOV, G. M., GRISHIN, N. N., and PETROV, A. A., Leningrad Technological
Ihstitute imeni Le_n-s-6-vet-
"Organic Derivatives of Group V-VII Elements. XVIII. Conjugation Energy
of-'the P-P Bond. Mass Spectra of Phosphine Sulfidesit
Li~ningrad, Zhurnal Obshchey Khimii, Vol 41 (103), No 4, Apr 71, pp 811-815
Abstract: The conjugation energy of the P-P bond in retraethvldiphosphine
was found to be of the order of 25 kcal/mole. Phosphorus atoms in this
molecule have unsbared pairs of electrons. Studying the electron spectra,
dipole moments and the dissociation energy of the E-E tvoe of compounds,
where E= an element of the V, or VI group possessing and unshared pair of
electrons, it was found that the conjugation between eleniients led to an
increased resistance of the E-E bond to electron artaclk. Yet at the saT-..e
time these compounds are highly susceptible to the action of nucleophilic
agents. This phenomenon has been explained by an anti-ion participation
in7 their chemical reactions.
1/1

USSR
UDC 537.563:547.341
BOGOLYUBOV, T. M., ZUBTSOVA, L. I., � AZU1
;:z 4 , R 40VA, N. A., and
PETROV, A. A., Leningrad Technological Institute imeni Lensovet
"Organic Derivatives of the V-VII Group Elements. )[VII. Mass-Spectra of
Phosphine Derivatives"
Leningrad, Zhurnal Obshchey Khimii, Vol 41 (103), No 3, Mar 71, pp 527-530
Abstract: Fragmented ions formed during mass-spectroscopical anaiysis of
phosphines and phosphine oxides retain the positive charge on fragments con-
taining heteroatouLs. In this paper mass-spectra of phonphie oxideS are re-
ported, where this tendency does not exist. The spectra si-,ow high Intensity
of the molecular ion and fragmented hydrocarbon ions, in contrast to phos-
phates, phosphonates, and pliosphine oxides. The predominance of fragmented
hydrocarbon ions may be related to the presence of electron accepting sub-
stituents of the phosphorus atom. The intensity of the fragment ion m/e 54
correlates qualitatively with the activity of organophosphorus compounds in
nucleophilic substitution reactions at the tetrahedral phosphorus atom.
1/1

UNCLASSI FIED Ptz(lCt_SSING T7c
TITL',_:--A,-)SGLUTE C~!--FNSATIL jl'~ PU4P -U-
AUTHt"-_-'-(f',3)-~ljR(',VlK, YE.S. , GP.ISHI-%, S Ft,~j Gk ISHVIA, YE.YA.
COUNTRY UF INFO--USSI
SC:URrE--ZH. TEKH. FIZ. 1970, 40(3) 581-6
k-
DATE PUf3LISHED------70
SU3JECT AREAS--PHYSICS, '-IECH., IND-, CIVIL AND MARINE ENGR
TOPIC T~AC,,,--HiGli VAC01PA POMP, CRYOGEN IC LNUID COOL IN6, GAS L [QJEFACT I.)%,
CEINTR AL :~Akr~ I "IG--NIG 'RESTR ICT I UNS
DOCUMENT CLASS--UNCLASSIFIED
PROXY 2.f-LL/FkAMF--lr)8y/I929 STEP
CI-RC A~CESSI~""i NO-AP010~25i

212 015 UNCLASSIFIFI)
CIRC ACCESSION NO-AR0108258
ABST;J,ACT/EXTP,ACT--(U) GP-0- ABSTRACT. THE
C3NDENSATION PUMP IS DESCRIBED. BY USING
CONDENSING SURFACE OF 0.24DEGREESK, IT 15
10 PRINE NEGATIVE12 WITH HE. FUR ACHIEVIIG
THE SURFACE MUST BE DECREASED.
1-!%LCLASSIFIED
PRL--,CESSIN~ DATE--021j,'-T70
CONSTRUCTI[IN OF AN ABS.
SUCH PUMPS WITA 4 TF4P. -)~: T-iE
POSSIBLE TJ CISTAIN A VArLlum, OF
LOWIER VACUUINS, THE TE,1,1P. UF
89

USSR
GRISHF11 V. G. ; et al (Joint Ins'llitute of lluclear
"Irr'begral Equations of Cascade !'"Jinc-mat 40311
Mosco-u,, Yadernaya Flzilm; October, 1970; pp 757-69
A-bliT-RACT: The authors consicler t',-.e ci:-;,- In w:-.1'rh th~c Of two
groups of parLiclas from, 6ifforent brinclcs of a Ln
measured. dist:,ibutioulr of thece quartiti"7 aro
by the interml ntructure: the of ti-nir lev(.d-s arc.,
Idnerwitics of a =;cadc (lby connenatior. la-,;) and nut ")", t`v! :]r:mt,rl'n o~-
effective maos of the whole partlicle systeri. A L; i r, --' "I ar, t r, i ( - ', u -- --) i s ;i 0 o T, o 3 -
sible in tiro-rinerzio~,, ener,,7j (listributions, T*.:e concr.-it- of tha
1 u
T)otentip-l as a fu=tion of one varift)le deten'dnindr, two-r,,J.nmslon,.U
tiorz in introduced. 7nt,~,;,-al ryqunftuions th-d; allow One ."If) -,-,e'l*(-,-'J-re ill)c 1-.,'
sn'ectnm of the dp'(jctin!-- o~ tht.- f" -,-tl pro-Illict's
u
7or ~mrlanco, tlo u,, t h o
L -
c dr;rivcd.
I +
o. T,I;T 7i ar,~l n(;-, P-) ""lic'.

USSR UDC 535.243.25
RISHINN, V. G., Candidate of Technical Sciences, andl RUSIOKO'~, A., Engineer
"Automatic Series-Connected Dynamic Spectrograph"
Moscow, Pribory i Sistemy Upravleniya, No 8, Aug 70, pp 19-2i
Abstract: The described spectrograph applies tile meLhod of dynamic spectroscopy
based on the production of a three-diMensional intense conLour wi).ich is close to
the contour of the amplitude momellLary signal spectrum in tilze -- frmquency --
intensity coordinates. ln comparison with visual oscillographLc ind spectro-
graphic nethods, the described method is characterized by a more e:.-.teasivu ap-
plicability and improved quality in d4stinguishing complex acoustic sLgnals.
The resonance frequency and tile dariping of tile filter, in the capacity of which
is employed an analog model of oscillating circuit (AI-110C), cao, be varie(I,by
simDle means and according to any rule within a wide range. The selection o~_-
one of the spectrograph's seven frequency ranges 0--125; 2-250; 4-500; 8-1000;
16-2000; 32-4000; and 64-8000 hz) is realized through a chango-over switch at
the expense of variation of thf_~ XIOUILS of two capacitances. itil equal mean
density of details on ali parts of the representation is attained by equalizjzg
the filter transmission band for all frequencies. The working principle of the
1/2

USSR
GRISHIN, V. G., and RUSAKOV, L. A., Pribory i Sistemy Upravleri-i'va, X%o 8', Au;-, 70,
pp 19-21
spectrograph is illustrated in the flot,~ sheet and the AMOC and tr.111S~11-it:Ler dia-
grams. Numerical characteristics of the four AMOC amplifiers, devellojle(`~ by the
Physics Faculty at Moscow State University, and the function of their vottage_
output variations are presented. The transnitter block serves as recipLent oy
the signal modulating the beam brightness of the oscilloscope which is provilded
with a darkening system Of the beam's backward run. The amplLtude-freqLlency
characteristic of the signal analyzer, that is to say, the dependence of the
continuous voltage output on the frequency with. constant si&nal al-aplitude at, the
input of the A1,110C, represents a straight line outgoing from bit, origin of c0or-
dinates, as the quality factor of the contour increases linearly in relation to
fErequency. The dynamic amplitude characteristic of the spectrograph's through
channel is practically linear in the range of 46 db; the dynamic range of the
AMOG amounts to 70 db. The time required to get the dynamic spectrogram of a
signal is T = (ts + td)-n, where ts = signal duration, Cd = damping time of
transients when switching the contour (t,jtr, I sec), and n = 125 (number of
lines). The device can be used to analyze heart defects by sound. Phonocard-
iagrams and dynamic spectrograms of heart sounds in mitral and aortic stenosis
are shown.
212

112 022 UNCLASS11 FIED PR3CESSING DATE--23OCT70
TITLE--ON REPPESENTAT ION Ui: PHASF INFORMAT 10,') IN PtRG5LFf'lS OF V ISUAL
ANALYSIS AND ON RECOG11ITION OF COMPLEX ACOUSTIC SIGNALS BY UPERAft'j'R -IJ-
AUTHOR-(02)-AN0KHINr A.M., GRISHINt V.G.
COUNTRY OF INFO--USSR
SOURCE--AVTOMATIKA I TELEMEKHANIKAY 19701 NR 31 PP 177-182
DATE PUBLISHED ------- 70
SUBJECT AREAS--PHY.SICS, BIOLOGICAL AND MEDICAL SCIENCES
TOPIC TA(;S--AC(]U'iTIC SIGNAL, SIGiNAL ANALYSISt SVER.11 Sll-,NAI., WECTRUM
ANALYZER, PiIASE ANALYSIS
CONTROL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/FRAME--1988/1456 STEP NO--L)R/01IJ3/70/0,)~1/003/0177/0182
CIRC ACCESSIG!il "q:'j'--'*AP01062t2

2/2 022 . UNCL ASS IF I ED PROCESSING DATE--230CT70
CIRC ACCESSION NO--AP0106212
ABSTRACT/EXTqACT--(U) GP-0- ABSTRACT. THERE IS DESCRIBED A DEVICE FOR A
THREE DIMENSIONAL (BRIGHr) REPRESENTATION OF THE f-,ELIEF OF THE
DERIVATIVE OF THE PHASE INSTANTANEl"JUS SIGNAL spFcrRum. THE
PERSPECTIVENESS JIF THE APPLICATION OF SUCH DEVICES TG THE P~03LEMS OF
THE ANALYSIS AND THE CLASSIFICATION OF COMPLEX ACO!JST!C SIGNALS (SPEECHt
PHONOCARDIOGRAMS, ETC.) IS SHOWN.
t 1 % ~- 1 A ": -,~ T F 1 -- 1-1

u IS S R
UDCO 621.791.856.2.013
-0, ?(JVOD, G.
G U1777 C'
~.Sz is , 'z ins t i t LI t- e 0 fELectric Welcling imCIVL
Academy of Sciences IJI,,.rSS7.,, GRISMIN V. X., V. G.,
ESTRIM, V. N,, LEW"OVIC11, Moscow
"Equipment for Vleldin,,, Chemically-Active Refractor% 'Netals in a
Control].Cd Jji~~jj 2-Urity NeLiurn Atmosphere"
Kiev, 'Svarkri, Na 8, Awr 70, pp t;5-47
u
AbstrnctL: A dcscrip--ion is given of eqL1!'-,MCk-'C f'C)r Mj-.-,-1L1rjj ~Iljd
automatic (J.ecluric welditq~ o--"* rc;`ractory tni!i:als III a coritroLlod
altnozs-hcre of hi4~11-pu--ity helium. The octuipi-ilent:, ~,h:ick war
deveLoped alt thc Institulue of Y'Le-ctric Ye. 0. r)nj
ennul-". coti-L-11111OUS COLItrol of o-.:ygen, tvitrolrun, nnd wfiter v.-,P,,),,-
impurli Lies ind helitim ri-,"fncration. it: Coll 0~ a
-C-.-! t Lon
chnmbor with a vacuum Systcm; 2) (-(lL',ip;aCI1!: 4'01- [)Llrl
1. (-) -J r;~ F) iIld
and 3 ) a 'n r! L J` trn p ur C(-",-i I,- r0 I s 7 f; t Cul. i% pho- ~
of L',Ir ;,,)I!. or- Th42
(70i) ciiii in di;!-,u,t7er, vuhulil"!, 1.00~) J.) j"; o),
1/2

USSR
CURFVInf , S . "N'. , et al,. , j%v tortitticheskaya Svarkn, ".o 8 , Aug
70, pp 45-47
I-KhI311'9T steol. It is provided uith a VN-1 sucL-J-Or, pump, makin."
it possible to obtain a 2 x 10-53 torr vacuum in thc chwriber t.-ith
full load. A sorption method using activated ca-z-bon and zi--!olite
at liquid nitrogcn tcmperature at --n abrorber pro-,;nure 0.1
150 atm iS used for heliurki purification. A lViG-type gas claroma-
tograph is used for heliUm purity control.

USSR
FILIPPOVICH, V. I., SHUMIKHIN, S. L., Scientific Research Institute for
Physiology of Children and Adolescents, Academy of Pedagogical. Sciences USSR,
and GRISHIN--Y--N-, Moscow Institute of Energetics
"A Method for Research on Human Motor Behavior Under Changing (Stochastic)
Conditions"
Moscow, Teoriya i Praktika Fizicheskoy Kul'tury, No 2, 1972, pp 66-69
Abstract: This method permits the study of human motor behavior under
conditions which demand well-timed and precise movements of varying degrc-es
of complexity for the purpose of learning how to increase man's ability to
control his movements under various conditions. The method erriploys the
following apparatus (fig. 1): The apparatus consists of tvo identical,
independent assemblies, each containing two concentric rotating shafts, and
a tensometric platform one meter square. The two assemblies, placed 2.5-3m
apart, rotate t-ao horizontal rods which serve as obstacles. The height and
speed of the rods will depend on the parameters of the movement problem.
The height of the lower rods is variable from 5cm to 1-I, the upper, from 1-
2m. The spced of rotation is variable from 10-120 rpm. A safety device
protects the subjecL in the event of contact with any rod. The spatial
I
"0

USSR
FILIPPOVICH, V. I., et al., Teoriya i Praktika Fizicheskoy Kul'tury, No 2,
1972, pp 66-69
parameters of the subject's movements are registered by a pickup which fre-
quency modulates a signal generator according to capacitance changes between
antennas (mounted on the rods) and the subject. The signal is detected,
amplified, and recorded. The tensometric platform records reactive forces
to an accuracy of 5kg. The sequence of rotation of the rods is determined
by a program whIch may be changed during operation. An ink recorder (USCh-8)
and oscillograph (K-105) are used for recording data. Measurement devices
for collecting data to determine individual characteristics and adaptive
behavior, as well as for data on normal bodily functions, may be simul-
taneously employed. The apparaws may be used for trainIng.
2/2

.1119S 59061
31 July 1973
AUTUATIC 1711.0!, MR F 'R
ON T( BASIS CF
V. V. rr 1. M. --n' r'
~AHA-1~ t~~ D:.
2~~
0. J "ILLLxt, Runnian. pp 339-343. no further availAblel
Ili- ~,jst Linportant -r)b1cm in 'hr tivrvivetrN v* ridi3ticn is vie
cteas,tre~er'. of the tcnror~,.tire or it bcdy -t t-.- t--ri, f when the
rau'laUng cftpaclt,,t of the char4-s~c 1,.,rlng
o;,: %.mw that the. rolutl~n t~ thIr
C3
of a the2retlal roture and the only rucce~_; tftmt. -,a~ tev~ a,iL~yii thus fur
In It has i!lvv,lved have ex,.~tLt _Itf-~r -r =; -.r
ret'leci-t-m thit. obeys the 1,=bert law. In *.~!~,e oz.~cz. tl~- .Wng
urttion on nALutLng cupicity Ln .."tnInct! fr,.n -%~ f! ix -~f
radlant tnerQ, f,om 1, luter,.il source, reClezi-I ty s ~'.' the
rndla-o- 1 2 '7. P~l irizntion of the mt! is' 1 ~ i: m lrr~,, "i
tis, 7 to obta n t~ is ~ ~ng infcrm~ t
11 hn~ b~~n nh~vn ;-5_- 'hit within th- ~!~Ilty )f the
Drood, f-mul:. 'he ~alur, Tr 'lie trace te_rer:l~-e --'I t~ t!etem'.,~01 ty ~n~
t)f tht, -"-icx1n nf pyr-,mrtri on t1le barle f the ~*_,.- ~f
-i~rj*.y demity of therr.,,- rn,lintl-1. X,-wc-.-, tt'.~ can _nly
be a rclativie:;; lo. a'.-- mn r ~.n
thit heru ,re nev~~ral ri~,i postitilitler ~:f -he trzr t,~;?em%,res
with ra,Uititig, cuf~cLty, b-el un izql,llf~'~'.-,~ f ~!'itl -m' lnf~i-
=tlon t'_ntned d1recttj rr~_ the rlm ~_,f tTl~zhr-.mat;z. ,~.i 7 on
thp bn-iit; ~f it now f~rsi of dIntribution ?f t~ctr,l !,~~ ty ~f
It hn3 been rh-ti in there pnrert; that I' - % ",e, ~f t e rue
temper,tt-,re and radLattrig cnpacity cannot te :!Tte~lnt~t -ect'~ fr= tht,
mlue ~,C the fluxes of intrinsic rndinti~n, t!-,e -hih i~ held In
antics', ryrcetry concerning the Lmrossibiltty or estiza-A se",-Irstezlp rmm
tempernture the influence or the radiattng c-~ctty ~r tite results of
meusurectents of the fluit of the temperature mdlatllm Itself Is not always
valia.
11 - USSR - Ll

USSR
UZC 620-1P,'-I:C21.785-5,0
GIZKTIOV) V. TD and,,GRISHITi YA. V~) Voij:a Branch of the Al!-Union Scientific
Tn tit -e
Research 3 L 1.1 v Ive s and G r i na: in f.;
"Structure and Phr-se Content of a Diff~_ision Titaniferous
V , 11 - ter:7,-*c-i,:!s'mva obrabotka motallov, _1970, p-L 64-65
1;oscow Yetallovedenive i V D
Abstract: Tae invest-icatlioL 11_~s =_dle of the structu:-t- and p'.-ase content of a
diffusion lay-er fornned by allo,,-inT A=cj ir.3n (0.011,c Cj anti St C)
St 45 (0.44'-;j C), St Ub" (0-79~C) and St UIO (1-05%,C) carbon steels witl-.i titani~iim.
The diffusion saturation was conducted in titanium powder nic:ron) (93.4~ 'L Ti
0.721% MLI-.) obtained from titanium spon.-e. 'The -ohase layer content was dietemnined
by metallo-,raphic and X-ray analysis an,"' microhardness mea~3_,rencm-~S. A -poss-lb-le
mechanism of the forration of the diffusion layer is tenta-~ively ex-ph-.~ined rin "he
bas-_'.~ of 'he results obtained and previous data. The microstructure of tlne 14~1_
fusion layer consists of an re'-T'3-2 outer laver with FeTi fonmatirnz, usually con-
centrated arolmd carbide inclusions. The absence of FeTi su;~er3tracture lines
my be the result of either an insufficiently smull difference in the inten*itv
of titani,_-- =-d the irlon atomic scattering, or the absence of orderinf, in -.-encral.
,7,:,e FeTtL rh_-Se d--,-zs out in the zone of the solid solution at coolir.:-, as the
result of a reduction in the solubility of titanium with decrea3in~-, tem,--rature.
V references.
1 1

USSR UDC: 533.6.oll
PUDOY, B. P. , 2R~IH
"Gasdynamic Functions for One-Dimensional Isentropic Unsteady F)_ows"
Tr. Ufim. avlats. in-ta- Wor?s of the Ufa Aviation institute), 1970, %-y-t-
17, pp 23-29 (from Hh-Nfekhanika, No 7, Jul 71, Abstract No 7B222)
Translation: Cases are considered where a one-dimenslonal translation-12
flow of a perfect gas is decelerated in a simple rarefaction wave propa-
gating in the same direction or in a simle compression wave going counter
to the flow. Formulas are given which exDress the relative chan.-c- o-~'
pressure, density, temperature, and speed of sound in the corresponaing
waves in terms of the Mach number in an undisturbed flow. Gra-ohs are
plotted for y = 1. 4.
Abstractor's note: The article contains no new results. The forniulas
presented in the article are a special case of formulas (LO.101) given in
the book by Courant and Friedrichs cited by the authors. No mention is
made in the article of the fact that the computation~d fornula.,; in th--~~ case
of a simple comression wave are suitable only 7= to -,he moment of de-
generation. G. Ya. Galin.
1/1

Acc. Nr. A, - Abstracting Service: Ref. Code
~055672 - CHEMICAL ABST.5j1Q) /VC 0000
r 10569lr Nuclear magnetic resonance spectroscopy of metal-
cyclopentadienyls. IV. Carbon-13 NMR spectra of sigm.&
cyclopentadienyl compounds of silicon, germanium, and tin.
Gxishin, Yu-K.; Serzeev N 1. M.; 1~~Jvnyijk, Vu. 2,- i~\IMR
Lab-.',*' M. V. Lomonosov St.1 Smscow
-70Fg&i6inetal. LTem. 1970, -12~2), 3 NT it'
spectra of Si, Ge, and Sh cyclopentadienyl corripcis. were studied.
11C chem. shifts and JOIC-11) consts, verifv the a-structure of
the cotrij)(1s. The variation of the K NXIR spc-ctrum of CJI~Gc.
(Cl-lilli Nvith ternp. shows that a fast nietallotropic rearra.-.1.4ement
occurs In this compd. at as low a temperature as:-'O'. 11C NNIR
data are discussed with ref. to the structure of metal cyclopenta-
dienyls. RCLC J
REEL/FRAMF', t3-
1.9840981

USSR UDC 621.762.3
GRISHINA, A. I., KAN-fAROSHIN, A. P. , PASHKW, P. 0.
"Structure and Certain Properties of Alloys Produced by Meltiri,fy, Mixtures o--l,
Metal Powders with Impact Loading"
C,
Metallovedeniye i Prochnost' Materialov, T. 3 [Metal Science and the SLrelijIth
of Materials, Vol 3 -- Collection of Works], Volgograd, 1971, lip 28S-29,1,
(Translated from ReferativnyN 7hurnal, Metallurgiya, No 5, 1972, AbsLract
No 5 G470 by S. Krivonosova).
Translation: The regularities OIL' formation of solid SOILItiOlis Of SlIbStitti-
tion in systems CLI-Ni and are studied. The structure and properties
of the melted zone with impact comp-z-cssion Of Plixtures of powdei-s are de-
termined by tile shape of the state diagram of tile components ijicluded iii
tile mixtures. A high heating rate and brief ivapact loading result in the
formation of noneqUilibrium solid solutions in the 11jelled z1,11v %-.-ith Ifigh Coi)-
tents of impurities in the lattice. 6 Figures; 3 Tables; 7) Biblio. Refs.
70 -

USSR
UDC 621.762.001
GR I NOVIKOVA, L. V., RYADINSKAYA, 1. 1-4.
"Stud), of the Fine Structure of Specimens of Powder Prochiced by lmp~--,Ct
Loading"
Metallovedeniye i Prochnost' Materialov, 1'. 3 (IMetal Science and the Strcni,,th
of Materials, Vol 3 -- Collection of Works], Volgograd, 1971, pp 309-314,
(Translated from Referativnvy Zhurnal, Metallurgiya, No S, 19721, Abstract
No 5 G471 by S. Krivonosova~.
Translation: An x-ray study is presented of specimens produccd by im-pact
loading. The level of !;train hardening of various Zones decrease'; upon trallsl-
tion from the surface to the center of the specimen. Wj'th impact. tile
temperature of the central portion of the spcci-11C.11 is increased sirnificantly,
leading to melting of the powdcr and full relief of strain ha-i-deld DO (incl-e;js-
ing temperature resulting from intensity of plastic defonmation of the puwdei-).
4 Figures; 11 Biblio. Ref.

USSR
GEDBERG, M. G., GRISHINA,_A. I.
UDC 621.762.3:669.2
"Effect of Deoxidizing Additives and Preliminary Annealing During I im act Com-
pacting, of Iron Powder"
V sb. Metallovedenive i urachnost' materialov. T. 3 (Physical Metallurgy aiid
Materials Strength. Vol 3 -- collection of works) , Volgograd, 1971, pp 294-302
(from FZh--Metallurgiya, No 4, Apr 72, Abstract No 4G407)
Translation: A study was made of the effect of complete reduction of FO. pcr.~dler
on the properties of briquettes obtained by impact compacting. Complete reduc-
tion of the powder reduces the hardness and increases the plasticity of the
briquettes. Better results were obtained on complete reduction of the Fe-pow-
der containing 0.11" C wid 0.5" urea. Flive illustrationG, 1 -tjjj)le, arid a
3-entry bibliography.
1/1

us S R U, C : z:i.
GRISHENA, G. A
"Formal i zation of Problers of Probabilistic-Autoriaton Modeling Eased on
a Si)ecialized Alleorithr-ic Language"
V sb. Veroyatnostn. avtomaty i ikh Dritneneniye (Probabilistic Automata
and 7h ir Use--col--- ection of works) , Riga, "Zin-atne", 1971, pp 157-161
T
(from RZh-Kibernetika, No 9, Sep 71, Xbstract No 9V417';
Clio abstract2
25 -

IJSSR
CRISHIIIA, G. S.
UI)C 1581-132.08
"The Use of the Amperometric Method for Determining Chxygen Exch3w=e in Al,--e
and Chloroplast Suspensions"
Poscow, Biofizicheskiye Metody v Fiziologil. Rasteniy, 11'auka, J.G,?I, DD 34-43
Translation of Russian Abstractt A modified polarographic deternination of
the concentration of oxyxen dissolved in a IlIqtLid is doncr3bcd in detail,
The suggested nethod na~e-s it possible to investigate photosynthesis
respiration of aleae according, to oxy6en exchange &nd to study some rezctions
a--sociated vith or.~gen exchange in isolated chloroplants. A covorej,
pointed platinum electr-we of the Clark 'hype was used in the irivestization.
The basic features of the equip.-ent setup are descrlb3di tho volt-ami:ere
curve, sensitivity, reproducibility, inertia, calibration off the electl~~--de,
and so on. The range of the applicability of the aziperometric method for
deter-mining oxygen ccncentration in a closed Eystez is specified.
1/1

112 012 UNCLASSIFIED PKOC ES S *UNG' DA7 E-- I b0c r
.TITLE--INHIBITION OF PHOTOSYNTHESIS BY OXYGEN IN PLANTS CULTIVATED UNDER
VARIOUS CONDITIONS OF NITROGEN SUPPLY -U-
AUTHOR-(03)-SLJ6QDSKAYAt G.A., GRISHINA, G.S., NICHIPOROVICH, A.A.
u
COUNTRY OF INFO--USSR
-SOURCE-FIZIOLGGIYA RASTENIY, 1970, VOL 17, NR 2, PP 244-252
DATE PUBLISHED ------- 70
.SUBJECT-AREAS--BIOLOGICAL AND MEDICAL SCIENCES
TOPIC TAGS--PHOTOSYNTHESIS, NITROGEN, OXYGENt CARBON DIOXIDE, INITRATE
CONTROL MARKING-NG _-lESTRIrTI0NS
DOCUMENT CLf'SS--UNCLASSI~l_r'l_'
PROXY STEP
CIPC ACCESSICNI Nf6--AR0052734
UNCLASSIFIFD

2/2 012 UNCLASSIFIED PROCESSING DATE--163CT7C
CIRC ACCESSION NG--AP0052734
ABSTRACT/EXTI~ACT--(U) GP-0- ABSTRACT. THE LIGHT CL);*"VES OF PHOTOSYNTHESIS
AT OXYGEIN' TENSIONiS OF 21 AND 3PERCENT WERE MEASURED IN PTISOM SAT!VU-%ij
VICIA FAB4, HEL14NTHUS ANNUS AND NjCnTIANA RUSTICA PLANTS CULTIVAI'EL)
UNOER VARIOUS CONDITIONS OF NITROGEN SUPPLY. THE DEGREE OF INtillbITICIN,
DUE TO OXYGEN 44S APPIZOXIMATELY THE SAvE AT VARIOUS LIGHT INTENSITIES
BUT GREATLY DIFFERED BETWEEN THE SPECIES (13PERCENT IN H. ANNUS L. A:'40
UP TO 44.5PERCENT IN No RUSTICA Lo). THE DEGREE OF INHIBI110N WAS
APPRECIAELY SMALLER IF THE PLANTS WERE ADEQUATELY SUPPLIED WITH NITRUGEN
OR IF THE CO SUB2 CONCENTRATION INCREASEDY PRGVIDiN~; THESE FACTOks
ENHANCED THE ACTIVITY OF THE PHOTOSYNTHETIC APPARATUS AND THE RATE OF
PHOTOSYNTHESIS. AN 0 SU32 CON-CEINTRATION OF 21PERCE%T NOT ONLY
SUPPRESSES PRIMARY FIXATION OF CO SUB2 BUT ALSO REDUCTIGiN OF NITRATES.
FACILITY: Ko A. TIMIRIAIEV INSTITUTE OF PLANT PHYSIOLCGY, USSR
ACADEMY OF SCIENCES, MOSCOW.
WNGLAS~IFIH)

Acc N Abstrac ting Service:
;&iW47(;47_ CHEMICAL ABST.,5ho
Ref. Code:
40 aa F 0
11-1-61
ko
0' I"U7& Hy&*lyz1z of potssWum meftphospbutte. Vol'f-
h S. L., Chere, &nova A. S.; Grishina- I A. (U,49R).
1 z7-(Rtk317-,-Th
N
IMPrOl. Khim. (Lessinwrad)*1970, 43(1j ~-j e acid
hy&olysis of the polymeric (KP03). was a Ist order reaction and
proceeded from the end of the chain. The primary intermediates
were orthophosphate and trimetaphosphate. The rate of hy-
&-olysis increased with increasing temp. and decreasing pK; at
pH 2.75, the rate consts. were: KzOO 9.82 X 10-3 min-',
Ksso 0.25 X 10-1 min-, and K-a* 0.59 X 10-2 min-.
The half life of (KP03). in acidic media at 50, 65, and 75* was
'14.1, 4.6, and 1.9 hr, resp. and the activation energy for the acid
hydrolysis was 18,000 cal. The results of this investigation
could be correlated to the ngtochern. data, for the rate of conver-
sion of K metaphosphate into orthophosphate on various SO%
G. melame J
HEL/FRAME rt
19791ZZ1

USSR
UDC 542.91:547.1'118
GRECF-~O, N. P., and GRISHINA, L. N., Institute of Organic and Physical
Chemistry imeni A. Ye. Arbuzov, Academy of Sciences USSR
"Reaction of Ethyleniminocarbinols With Some Derivatives of Phosphorus
Acids"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No 8, Aug 73,
pp 1883-1884
Abstract: The reaction of a-ethyle-iiminocarbinols with some phosphorus
derivatives was investigated. Reacting 0-tricbloro-a-eLhvleiiiminoethanoI
with dialkylphosphorous and glycolphosphorous acid chlorides yielded
~-trichloro-a-ethvlenir,inoethy1 esters of the respective acids.
1/1

USSR
tIDC 539-27
NAUMOVi V. A., MMMO, V. N., ZAV'---ALOVj A. P-t EZ=914 R. A.t and
'GRISnN& L. N., institute of organic and Physical Chemistry Imeni A. Ye.
Arbuzov, Academy of Sciences USSR, Kazan
"An Electron Diffraction Study of the Structure of the hollecules of Ethylene
Chlorophosphate and Ethylene Chlorotrithiophosphate*
Moscow, Zhurnal Strukturnoy Khimii, Vol 14, No 5, Sep-Oct 73, PP 787-?90
Abstractt On the basis of data obtained by an electron diffraction study
carried out on ethylene chlorophosphate and its 6tructural analog ethylene
chlorotrithiophosphate (II; 2-thiono-2-chloro-lt3p2-dithiaphospholane) in
the vapor statep the molecular structure of these compounds was determined.
The five-membered heterocycle had a conformation of tho semi-chair type in
both cases. The molecular parameters for I were r(C-C) - 1.547 + 0.020,
r(C-O) - 1.468 + 0.020, r(r-O) - 1.438 + 0.015, r (F-O) - 1.61C+ 0.010,
r(P-Cl) - 2.057 ; 0.010 R~ Z-0-P-0 - 10~-.7 + 1.50, /- C-P-Cl - Ij-3.9 � 2.0',
e- 0-P-C1 - 1 CI .3 + I - 0 , t- C-C-0 - 108.,i + 1. 00; those for II r(C-C)
1-525 (assumed)# r(CF-S) - 1.879 + 0 01o - 1-8`5 + 0 020, r(P-S)
2.123 + 0.010, r(,P-Cl) - 2.006 -t7-0-6;5 2; 4 S-P-S - ~8.4 1*16 56, 4 SWP-C M
113.2 :; 2-0'j, 4 S-F-C - 104.2 - 1.0 j Z. C-C-S 112.9 � 2.5
4) -

Tj SSR
UDC 542 .91: 547 -1 Ill 8
GRECHKIN, N. P., and GPISIIINA-.---L.N-., Tnstitut.c, of Organic mid
Physical Chenistry 1:ni-dn-3. Ye. Arbuzov, Academy of Scionces USSR
Ka. zan I
"Pyrrolidides of Phosphorus Acids"
Moscow, Izvestiya Akademii Nlauk SSSIII, Seriya Xhimicheska-va, No 7,
Jul 73, pp 1670-1671
Abstract: Research on organophosphorus derivatives of pyrrolidine
with the purpose of syntliesizin- physiologically active compounds
was continued. By reacting 2-chloro-1,3,2-dio-~z,-il)liosi)~liolan(--s and
-phosphorinanes with pyrrolidine in the presence of Et 3N, 2-pyrro-
lidido-1,3,2-cli.ox,il)iiosl),)iolai-)es and-phosphorinanes were obtained.
The reaction of these compounds with chloralhydrate was accompailied
by opening of the 11-contaiTling rin,,Ir and a Perkov rearrimrement.
As a result, formation of chloroalkyl di-beta, beta-chlorovinyl
N-pyrrolididophosphates took place. The pyrrolididophosphates
had antifungal. activity towards deri-iiatophytes. The physical.
properties of the cor.-ipounds prepared are listed i.n t-lab1cs.
13

USSR UDC 542.91+661-718.1
GRECHIKIN, 14. P., and GRISHINA L,,. N., Institute of Organic and
Chemistry Imeni A. Ye~. Arbuzov, Academy of Sciences, USSR
"Phosphonaminoethylation of Spirophosphoranes"
rv"Oscow, Izvestiya Akademii Nauk, Seriyaj,"himicheskaya 1";o 7, 'jul 70,
pp 1644-71-64t)
Abstracti A mixture of 3 is of 1,4,6,9-tetraoxa-5-!)'rio~:,plia,;I)iro-(L~,L~)-
nonane, 4.6 1- ethyleneaminde of diisobutylphosphoric acid ind about
0.1 g of ammonium chloride was heated in a sealed tube at 120-170') for
18 hrs to yield after distillation 5-'%','4-~-dilsobu'iylpliosl)lion~Lnirio)-
e~8yl-1,4,6,9-teti,aoxa-5-phosphaspiro-(4,1~)-nonane, b.p. 143-1460/0.1mm
d4 1.1508, n6O 1-4580, Following alkyl analsgues were obtained simil-
arlyt alkyl derivative, b.p.or,/mm Jig, d"0,-n iven, n-propyl,
125-126/0.3. 1.2015, 1.456o, i-propyl, K 1~WOG.3, 1.17)1, 1.4625;
n-butyl, 133-135/0.4, 1-1564, 1.45721 and i-pentyl, 182-184/0.6.
1.1322, 1.4620.
1/L

USSR
UDC 669.14.018.23
KOZHIN, V. M., Y-&-RPOV, A. G., OPANASENKO, T. V., aLS~INA 11. A., and
YEROFEYEV, V. 1.
"EP378 High-Strength Automatic Stainless Steel"
I
oscow, Metallovedeniye i Termicheskaya Obrabotka Metallov, No 10, 1970,
M
pp 25-27
Abstract: A new high-strength automatic stainless steel, type EP378 (0.35-
0.45% C; 0.6-1.0% Mn; 1.7-2.2% Ni; 0.6-0.9% Mo; 16.5-18.5% Cr; 0.15-0.25% S;
0.08-0.15% P), is desribed. The new steel has superior physical and mechan-
ical properties to types Khl4, 1Khl8NIOYe, and E1474. The bteel is designed
for parts of instruments working in friction which must have hardness HRC >
48. The critical points for EP378 steel, detemined dilatometrically, are,
Acl - 7500C; Ac = 820*C- M, - 220*C. The steel has maximum hardness when
hardened from 1840-1060-C'. The influence of tempering on mechanical prop-
erties is studied. The mechanical properties of the steel are: tensile
strength 168-175 kg/MM2'UO.i- 140-145 kg/imn2, 6 - 8-10%, ,p - 15-17%,
an- 1.0-1.8 kgm/cm2, HRC - B-52. Heat treatment modes are discussed.
1/1

USSR UDC: 548.4
1
BELYATSKAYA, N. S., LOPATIN, Ye. P-, MIL'
VIDSKIY, M. G., OSVENS'KTYT-V. B., FOMIN, V. G., State Scien-
tific Research and Design Institute for the Rare Metals
C,
Industry
"Structural Singularities of Gallium Arsenide Single Crystals
Heavily Doped With Donor Impurities"
Moscow, Kristallop pp 158-16S
grafiya Vol 17, No 1, Jan/Feb 72,
Abstract: A study is made of the cffect.which tCl.lUriwii,
selenium,-and sulfur doping has on the degree of perfectness
of GaAs single crystals. Metallographic and radiographic
studies show that doping to high concentrations witi, donor
impurities (n. >101~'/cc) may lead to an appreciable reduction
in the dislocation density and to a specific distribution in
the volume of the GaAs single crystals due to strenatfening
of the material and intensification of the process of dislo-
cation creep during doping. Nonhomogeneous dopant distribu-
tion in heavily doped sinEle crystals is an additional source
1/2

USSR
BELYATS*KAYA, N. S. et al., Kristallografiya Jan/Feb 72, pp
158-165
of dislocations. Structural investigations show that in the
process of growing gallium arsenide single crystals heavil-'-
doped i-. !ith donor impurities, partial decomposition of sLiper'-
saturated solid solutions takes place, accompanied by the de-
velopment of additional internal stresses and a lumped struc-
ture within the crystal. Five figures, one table, bibliog-
raphy of eleven titles.
2/2
33

USSR
IODC 547.241
G91M11U_O__1L_ KOSOVA, L. M., and KLYUCHANSKAYA, S. M., Institute of
organic and Physical Chemistry imeni A. Ye. Arbuzov, Acad. of Sci. USSR
j
"Alkylthionophosphine Sulfides. Part XII. Reactions of Alkylthionophosphine
Sulfides With Organomagnesium Compounds"
Leningrad, Zhurnal Obshchey Khimii, Sep 71, Vol 41, No 9, pp 1995-1999
Abstract: The principal reaction products of alkylthionophosphino sulfides
with organomagnesium compounds are dialkyldithiophosphinic acids. The
reaction in addition the principal product also yields ivercaptans, tri-
alkylphosphine sulfides and oxygen-containing phosphorus acids. The yield
of these byproducts is 40-602. The reaction losses are considerable (20-
30%) and are assumed to be due to the oxygen-containing phosphoru~i acids
which are lost during the hydrolysis of the complex. The formation of
trialkylphosphine sulfide is related to the mobility of zinc sulfur in the
sulfide which, as sho,,,n in an earlier study, splits from phosphorus Lo form
a 11CW SUMir-containing rimvourid, in Lbis cmse, possibly a micrcaptan.
Distillation of (11,iilky.tdi-tiiioplic).qi)iiiiiic acids under vacuum, FoHowf.--d by
the elimination of hydrogen sulfide, results in the formation of
1/2

USSR
GRISRINA, 0. N., et al., Zhurnal Obshchey Khimii, Sep 71, Vol 41, No 9,
pp 1995-1999
thioanhydrides of these acids. Identification of the new compounds was
based on elemental analysis, physicochemical constants and IR spectra.
2/2
- 40 -

USSR UDC: 547.241+661.725
KOSOVA, L. M., LIPATOVA, I. P., and SHNGIDULLL~,', R. R.,
~'Ihstitute of Organic and Physical Chemistry imeni A. ie. Arbuzov, Kazan',
Academy of Sciences USSR
"Alkylthiophosphine Sulfides. 9. Synthesis of Pentaerythrityl 0,0,0,0-Tetra-
kis (Alky1dithiophosphonates) and Their Derivatives"
Leningrad, Zhurnal Obshchey Khimii, Vol 40, No 1, Jan 70, pp 66-69
Abstract: A series of dithiophoSDhonate derivatives, previously unknoiM, were
synthesized in the pursuit of investigation of alkylthiophosph,ine sulfides
(I). Four partial esters, pentaorythrityl 0,0,0,0-tetrakis(alkyidithiophospho-
nates) (II), were Drepared in 100;!D yields by mixing I with pentaorythriLoi in
anhydrous dioxane at 900. 11 were clear viscous products. Dropping triethy-
lamine slowly into a mixture of I and pentaerythritol in dio.,:ane at roon
termerature, then heating the mix-ture to '700 gave corresponding quat-arnary
triethyla. ni= salts o'~ IT (IIII) (yields 92_9'~,~',), clea'
.1 - r viscouz substances
uhich crystallized on st-nnding. Adding slowly ethyl iodide or ethyl chloro-
acetate to M 1r, d_-'oyane at 70-`V) -Fave after t.,lxee hours 66-60'
yields of-
pentaerythrityl 0AM-te'Lrakis ex-tremel",
viscous substances which crystallized on standing. Sinilarly III in dioxane
1/2

USSR
GRISHLNA, 0. N., et a!, Zhurnal Obshchey H'hi-mii. Vol 4C), No 1, Jan 70, P~l 66-69
solution reacted with aoueous iodine at room temperature to give 78-6-94.8;'b:
yields of disulfides
C[ (CH?OP (3)RI -11-~ 912
where R is butyl, cycloheql, or CO'H13. The disulfidas !'I were crystaliL-Ie
products, indentified by their melting points. Shaidng 11, where al-IiWl is
butyl or cyclohexyl, with aqueous nickel sulfate in equinmolar amounts give
100~ yields of correspording nickel saits, gray-greenish powders meltin- at
145-1470 and 2-40-33 respective1j.
2/2
CO

Ussi
UDC 535-113 54!.L~g + 6)61-71-5-1 + 546
and G.RjSjr.., -i le of C::er-
SOLO Z:-- Z-
!:O-T S-f.,', ~1,.
A
istry, Academy of Sciences Tad--.SSR
"EPR of the Divallert Copper O-Alkyl Alkyldithiophospnonate Solutions"
Moscow, Zhurnal 3tr,-,'zturnoy Vol 12, No 1, Jan-Feb 71, z 167-170
-P -
Abstract; Cozrzlexes between di-vale-rit. copper ani O-al:cyl alky-Idithioi~'.,.os~'-.-
nates (1) were obtained by treating copper sulfate in aqueous sclution WiL~-I
the appropriate phosphonic acid in organic solvents. `~Jncn the co:--~Piex-:'s we-'re
studied in different solvents at room temperature, no effect was noted or, the
EPR spectra. Thu superfbic :structure and compiimentary suparfine Structure
from the interaction of copper and phosphorus aLov-.s v-;ts anaiy,,,u'I coatrasze-'
with the structures of dithiophospi-aLes and ditniop~os-phinaLcS. Coll --i'd erao ie
dislocation of the-unpaired electron is observed in (I) which results in the
interaction wi~ r--I
'n ~-he bonding to copper is of a cxialenL charac,-er.
47 -

112 022 UNCL ASS I Ff ED PROCESSING OATE--13NOV70
TITLE-IfIFLUENCE, OF METAL OtALKYLALKYLUITHLOPHOSPli0tiArk:S OIN THE P.4JPERTIES
OF LUB81CA, -U-
NTS
AUTHOR-(02)-GRISHINAt O.N., POTEKHItNAv M.16
wwmwp~---
CCUNTRY OF lNFO--USSR
SCURCE--NEFTEKHf-!IYA 1970, 19)2), 297-302
DATE PUBLISHED ------- 70
SU6JECT ARF-i,,S--:-lATERIALS
TOPIC TA(;S--Ai%;l i-AXIDAt',lT A~.,)IJIT IVE, LUBRICANT A(.)DITIVFt PK)SPHATE ESTER$
ZINC BAPIUM Ulf',11CUND, THIULt NICKEL COMPLUNUIN)IMS20
LUBRfCANTING OIL
CONTROL MAKKING-NO kESTklCfIONS
OCCUMENT CLASS-UNCLASSIFIED
PROXY REEL/FRAME--3005/1964 STEP ~)0--Uk/0201~./70/01,)/C()2/0297/0302
CIRC ACCESSION N(,l--AP0l33303

212 022 UNCLASSIFIEU PROCESSING DATE--13NOV70
CIRC ACCESSION 'NO-AP0133608
ABSTRACT/EXTRACT--(U) GP-0- A3srPAGT. Z%, 84, AND N1 GOALKYL
ALKYL---IlTi-i[GPIIC,,*S[;HO~IATES ARE 0XIbNl. INH16ITURS FOR OILS. LN AND 3A SALTS
DECREASED THE C0RkJSIV[TY OF MS-20 OIL. ,METAL DITHIOPHOSPHATE5 ~~ERE
LESS EFFECTIVE THAN THE DITHIOPHOSPHONATES. NI SALTS WERE MORE ACTIVE
ANTIOXIDANTS THAN ZN SALTS AT 150DEGREES, BUT LESS ACTIVE AT
170-200DEGREES. BRANCHING IN THE ZLKYL CHAIN INCI'-IEASED EFFECT IVEMESSt
BUT THE CHAIN I-EiNIGTH HAD NO EFFECT ON THE ANTICORROSION ACTIVITY. AT
LARGEA THAN 140DEGREES, THE ANTICU~,ROSIGN ACTIVITY CF THE SALTS
DECREASED. FACILITY: INST. ORG. FIZ. KHIM. IM. AR60ZOVA, KAZAN,
USSR.
1-C LAS.41 I F I- E 0- ---- - ----

1/2 024 UNCLASSIFIED PROCESSING DATrl--300".T70
TITLE--StiLFIDES OF ALKYLTHIONOPHOSPHINES. IX. SYNTHESIS OF
PE,,-,iTAE,~YTH-~,ITOL,0,0,0,0,TETRAKIS,ALKYLOITHlji)HCJSPFiONATES, AND THEIR
AUTHaR-(04)-GRISHINAP O.N.t Kt3SOV-4f L.M., LIPATOVA, I.P., SjiA6IDULLlNi
R.R*
COUNTRY OF INFO--USSR
SOURCE-ZH. OBSHCH. KHIM. 1970, 40(l), 66-9
DATE PUBLISHED ------- 70
SUBJECT AREAS--CHEMISTRY
TOPIC TAGS-- CHEM I CAL SYNTHESIS, HETEROCYCLIC OXYGEN CO,'~POUND, IR Si-_CT~jm,
OkGANONICKEL COMPOUND, PHOSPHATE ESTER, HETi-ROCYCLIC SjLFJII~ COMP-JU,""D,
HETEROCYCLIC ?HOSPHOURS COMPOUNDy THIOL
CONTROL MAkKING--Nnj RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/FRAME-1992/1.739 SILP P4()---Ul~/0071)/*Io/ozfO/t-)()I/Oo~,f)/.,)Ot~1)
L.IRC ACCESSIG~,, r4,o- -A P~q
~A 112-727
UNC L A'j- S I f~ I

2/2 024 UNCLASSIFIED
CIRC ACCESSION NG--AP0112727
ABSTRACT/EXT~IACT--(U) GP-0- ABSTRACT. HEATING 5
WITH 2.24 G C(CH SUB2 OH) SUB4 IN DRY 0IOXANE I
IGOPERCENT VISCOUS C(CH SU62 UP(S)-(SH)k') SU34
PRIMEZO SUBD 1.5630. SIMILARLY WERE PREPI), THE
MICROFICHE. IR SPECTRA ARE REPORTED.
FIZ. KHIM. IM. ARBUZOVAI KAZAN, U~5.SR.
PROCESSV-~G DATE--303CT70
G (MEETCHPS SUB2) SUB2
HR AT 90DEGREES GAVE
(1) (R EQUALS MEETCH), N
ANALOGS ~iITH: SHOWN ON
FACILITY: INST. ORG.
W I% -r I A ~i I- I F I p 0

zmeni A. Arbuzov Acnd~-.--y r)" Sci-nce~s U-Si-
"Ef-fects Of !"Lc~t','~l .nc~

1.1oscow, Nofl'el~d-'_ImLya' V(.1' if), :7, '(G

A stud-Y w-L.L; carried owo of "~Le ar.41i ..-it-lit %~-'l
Mos trac L V -, o:
of .._;L_. rc-
nom.,.--l ~nd 1-I Ur
al'zlyi ffrol;pj il~ the ulp 7~0 ':%.16

petrointum. the pr,'. i3once '~'n z i. i..:,
.qui d
V I , - ...'
11-',.(-Lx_- comnr)i.ind.; 1[n :11 N

T-
creasinig lenflrth of ;1,1, bctii 1i ~tn-
d": -
creased wit~i increasini:, 11,~.-.pt_-raturus in Ul,e 150-20C)o
were more active -."Lan Zn wiAie _'70-2!,;D() re].'-~ 1 u.,.
cause o' ~he i r-he r stabi o 7 Zn .1-i
C. ~.J
S/QZ~-, ( !
JT7
(III) shmwed that tiae _ntiLc-.,'.'RJaw6
In anticorrosion !bests carried out "Fiti CA-

-arate, Zri
s
.t
./ to

UIS S R
URISE E "'i t 'L -)1 10
7.,rotective eftfecz. '--."-,)e --.c-,~fivity of compounds
effect was on --iie sania leve'L as LL-az of DF-11 and ~Le ij-oc-t:-tdecYl-
ocUY1diDhcsi)hoi:a-.,es o-f :._i am. Zn. wt--& did noL con-.ai- S, 7.*.,-e corrosive
effect produced by t-be oil in tLe Les-,,s. Tiie anticorrosion Of tLe
coukpounds tes,-ed decreased -47--.h incre',.sing- tempe ra Lures in .6Le -356-1~fOO
-/2
IMIMT-9-m-M --- ~W

USSR UDC 548-4
MILIVID.Si=, E. G., CSIJENSKII, V. B., NOVECOV, A. G., MM-T, V. G.,
G R I S11 INA I _q~~ernment Scientific-Research and P1=11-n-g-11-EH-tute for t~
S. P., C. C
Rare YRtals Industry
"Effect of Thernal Processing on the Ideall Structure of Monocrystals of
Gallium Arsenide Alloyed. with Tellurium
pp 826-829
Meow, Krist-allografiya, vol 18, No 4, Jully-August 1973
The effect of thennal processing (11000C, 7000C, uD to 50 hr) on the rhysical
-oromerties of gallium arsenide containing 1019 tel-lurium atoms per cubic
centimeter was studied by celective che,-ucal etching, measurement of the
Hall effect, two-cvystal spectrometry, diffraction topor.7ranhy, and precision
measurements of "he lattice. The electrical properties and zmanocrystall Strruc-
tural data indicate a de3truction of the sLpersaturated solld solutions with
formation of a second phase.
1/1

111-2 T air THE ErrECT OF THE DEVIATIO14 ()Y TRE COMPISITION FRO4 THC
TRY h: r)
I rj I c ~ I L" TI1 CRYSTALLOGRAPHIC DIRLCTiON OF GROWTH LS VIL Ulf-WCATIOS
STWXTURE W SINGLE GA.LLI',M kRSULIDE CAMALS
[Altill~ bY '. P. llri.hiaua. M. C. 4il',idskly. V. B. Oaveikiy. V. F. pa~lov'
V. ';. F-In, 4oscov; Nri*oolbir.k, III 11~ ajr I '. i - L,
__ __ F_ - - - _ A!,I_S~Aa= R~tj"t __ -
_LZL*T'!_k- P11-1- 13-17 1-112, P -61
it vat I can2tratiad that durinx the travth from a milt. the devL.tion of
the craiDaialtion from the stoichicametry can have an effect on the d'slocaticn
sLrjctura of xallium aragailds single crystals both through the crystallixati,an
proceed smi by creatinq additional dislocation source* in the suireri4l which
has alresly bwpn crystalliated. In the first came the deviation of the cocapo~
.Ition of the ."It fro,s atotchtom*try can Idol to destruction of the atal,flity
of tNe -)th crjotallitattnn front und~.r t%- canditions of concentration super-
coollno ulilch I@ expressed In the formation of the low-analle boundaries said
the cellular structure. This effect to exhibited met clearly when growing a
tr7stal In the 11UG) direction and with a sunall magnitude of the axial tmperA-
turd gradient at the corystallitation front. In the second case the deviation
of the composition from aLoictitainstry has an affect on tht formation of the
dtqlDtation* in the cr7iatal under the effect of thermal stres3es. I t was
saitat,limbed that the deviation from toichlonstry In the diraction of excess
pmlliuda in the surface layers of the crystal leads to more Intense generation
of the dislocation& where the deviation in the direction of the excess arsenic
had the opposite .(fact by comparison with the atolchlosetric conaposition. For
growth umlor condltto"4 of Identical scoichionatry of the welt. 4 nottcoiable
effect of the itrowth direction on the dislocation density In the crystal use
saot observed. This to confirmed by the results of calculating the thermal
-tree. field. Using the x-ray 417raction topography, a study was adds of the
type* of dislocations in the single crystals axpressed In various crystallographic
directions.
- 23 -

1/2 031
TITLE--HEAT TREATMENT
WITH TELLURIUM -U-
AUTHOR-104)-GRISHINA9
V.I.
COUNTRY OF INFO--USSR
UNCLASSIFIED PROCESSING DATE--160CT70
TRANSFORMATIONS IN GALLIUM ARSENIDE STRONGLY DOPED
S.P.r
SOURCE-FIZ. TEKH. POLUPROV.
DATE PUBLISHED ------- 70
MILVIQSKIYv M.G*t OSVENSKIY, V.3.t FISTULt
1970, 4(2), 294-8
-SUBJECT AREAS-IMATERIALS, PHYSICS
TOPIC TAGS--.'-IETAL HEAT TREATMENT, GALLIUM ARSENIDE, DOPED AL(jY,
TELLURIUM, HALL CONSTANT, CRYSTAL UISLOCATION
CONTROL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/FRAME--1995/0940 STEP NO--UR/0449/70/C)Ott./002/029ft/0298
CIRC ACCESSIUN NC--AP0116448
U N A ~ S I F.9

212 031 UNCLASSIFIED Pk(JCESSI.,'4G UATE-160C17C
CIRC ACCESSION NO--AP0116448
ABSrRACT/EXTkACT--(U) GP-0- ABSTRACT. TE DOPEO GAAS SINGLZ': GAYSTALS
DOPED WITH SUFFICIENT TE TO GIVE A CHARGE CAkkIEk CUNCN. Of- (7-10) I-IMES
10 PRIME18-CM PkIME3 AND DISLOCATIUN D. SIMILAk TJ 10 Pki,XIE3-Cli Pki~AE2
WERE GRO-dN bY THE CZGCHPALSKI METHUL). THE HEAT fk-E.'%TMENT AAS
OUT IN EVACJATED QUARTZ AMPULS. THE CARRIER 0. ANO ~'10611_111 Oti-ij.
FROM HALL COEFF. ANO CON0. MEASUREMENTS OF CROSS SHAPED SAMPLES.
ANNEALING WAS PERF0kAEO AT 700-10OU0EGREES 4FTEk 1t_::vPEklNfJ' AT
11000EGREi.-S. FULLUvlING TH~ TEMPEkING PROCEOURE ALL SAMPLeS SHLIkED AN
40-60PERCENT iNCkEASt OF ELECTRON CUNCN. A GENERAL OECAY it- N SUc3E IS
OBSERVED THROUGHOUT THE ENTIRE ANNEALING PROCESS TG loo-15L)
HRS.) AT EACH ANi',lEALING TEMP. THE INITIAL N SUB" VALUt P~IUK To
TEMPERING IS REACHED 'rqlFHIN 20 -MIN DURING THE ANNEALING PROCESS
REGARDLESS OF TEMP. Ar HIGHER COOLING RATES AS THOSE MET UNDER USUAL
CRYSTN. CONDITIONS THE IMPURITIES REDISTRIBUTION CANNOT P~UC-EEJ,'ANJ THE
CRYSTAL REMAINS IN A METASTABLE STATE. THE DECAY OF N SU6E DURING
ANNEALING IS ATTRIBUTED TO A TRANSITION OF PART OF THE TE ATOMS INTO
INTERSTITIAL POSITIONS GK TO AN INCLUSION INTO A SECGNO P-lASE. A
DECREASE IN ELECTRON MOBILITY IS CAUSED BY THE ANNE4LING dROCESS. IT
IS ASSUMED THAT TE AT014S IN THE SECOND PHASE FOP".1 "!ULTrCH(ikGE COMPLEXES.
U,',IDER ISOTH~::RMAL C3NDITIONS AT GREATER THAN boODE(;~;,EESC 7HE
TRANSFUR-MATION PRiCEFDS IN 2 STAGES. DURING THE FIdST 20 MIN A
METASTABLE rE CCMPLEX IS FORMED, WHICH IS THEN DISS'~'LVED '.-ND A SECONO
COMPLEX APPEARS, EVENTUALLY WITH THE FORM4TIGN OF A FINELY DISPER'St'l-D
SECOND PHASE. FACILITY: GOS, NAUCH.-I.SSLED. PR6E-,T. INST.
RE L) K (j?-, E T A L -!'OSCOW, USS4.
INOM HMO

1/3 017 UNCLASSIFIED PROCESSING DATE--lb:DCTTQ
TITLE--STRUCTUR4L FEATURES OF SILICON SINGLE CRYSTALS STPONGLY DOPEL) .4.*rH
ARSENIC -U-
AUTHOR-(04)-GRISHIN4, S.P., KLIMOV-At N.M., OSYENSKIY, V.B., MILVIDSe,116
M.G.
COUNTRY OF INFO--USSR
SOURCE--IZV. AKAD. NAUK SSSR, NEORG. MATER. 1970, 6(2) 1.93-5
DATE PUBLISHFO ------- 70
SUBJECT AREAS--PHYSICSI MATERIALS
TOPIC TAGS--SILICON SINGLE CRYSTAL, OOPED ALLOY9 ARSENIC CONTAINING ALLOY,
SOLID SOLUTION
CC;%TK-C-L MAPKING-NO RESTKICrfONS
00CUMENT CLASS--UtiCLASSIFILD
PROXY REEL/f-_-kAMC--199u/082I STEP NO--UR/0363/?0/00~)/Oo2/01")3/~-)11)5
GIRC ACCESSION' NG--AP0118002
UNrLASSIFIED

2/3 017 UNCLASSIFIED PROCESSING DATE--lbOCT70
CIRC ACCESSION NO--AP0118002
ABSTRACT/EXTRACT--(U) GP-U- ABSTRACT. AN ELECTRONMICROSCCPE STUDY V;AS
MADE OF THE STRUCTURE OF SI SINGLE CRYSTALS DOPED WITH AS TO A CONCN. OF
5 TIMES 10 PRIME20-CM PRIME3. THE CRYSTALS WERE GROWN BY THE
CZOCHRALSKI Tt-CHINIQUE IN THE MEAN VALUE Of: 111 DIRECTION. THE SAMPLES
WERE SECTIONED BOTH IN TRANSVERSE AND IN LONGITUDINAL CROSS SECTION,
COINCIDIN6 41TH THE (110) PLANE. ELECTRON REPLICATION AND THIN FILM
ELECTRON TRANSMISSION TECHNIQUES !JERE USED. FOUR SYSTEMS OF PARALLEL
GROWTH BANDS WITH PERIODS OF SIMILAR TO 100, SIMILAR TO 40, SlimILAR TO
lot AND SIMILAR TO 2 MU WERE OBSERVED ON LONGITUDINAL SECTIONS. FINER
BANDS, WITH PERIODS OF SMALLER THAN OR EQUAL TO 0.1 MU, WERE OBSO.
INSIDE THE SIMILAR TO 2 MU BANDS* THE PRESENCE OF PE8~1001C
HE TEPOGENE IT Y 1IN CAYSTALS IS GNERALLY ASSOC D. w IT H r'E,~ I (J 0 1 C CH A %GE JF
GROWTH RATE. THE PRESENCE IN THE CRYSTALS OF A 4HOLE SPECTRUM GF FINE
GROWTH BANDS ATTESTS TO THE COMPLEX ITY OF THE PkOCESSL-S TAKING Pt.Af' E AT
THE CRYSTN. I'RONI . IN THE MIDDLE PART OF THE Ci