SCIENTIFIC ABSTRACT ISMAILOV, I.M. - ISTOMIN, N.P.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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ip,6t~ESSLNU uA UNC ~:O M ;,q j,:. ,:~'CIR A ESSION NO~ 4PO118947 ~.,46MACUEXTRACT--(U) GP-0- ABS-T9APT4--,-'A FOklli 'THE: lEMP. DEPODENCE DERIVED. THE -E- -AMASATIC.-VIBRATIONIAL AELAxAnbk' 0 F L b iS E ADIARATIC UA BA T-1 CV I B R-A T I.-ON AL RELAXATION 1 1) ~!tk -'CALcr,,'.~ ai Jfli i IES QU T! N, F'~ EU WELL ELA XAT.ION : T I P E A 0 0 ~,O AGRE IONAL R F-N'-- ~200: 3500AGREE K MOSKx OBL, P GO SW A ------7-7777:-77 T. USSR UM 66.028.08 LPMALIYEV, K. A... and ISMA-ELOV, I. M. "Apparatus for Microdosing Low-Boiling Liquids" Avtomatiz. i Kontrollno-lzmrit. Pribory. Rdf. St). (Automati7--d and Control- f4easuring Apparatus. Re-ference Collection), 1972, No~ 5, pp 10-11 (from Referativnyy Zhurnal, No 10, Oct 72, 32. Matrologiya i lzr'.eritel'naya Tekhnika. Single Issue. Abstract No 10.32-925 by V. S. K.) pe Translation: A microdosiN, apparatus of low-boiling liquids has been develo d in the Institute of Petrochemical Processes of the Academy of Sciences of the Azerbaydzhan Soviet Socialist Republic. The working of the microdosing appara- tus is based on the displacement of,the dosed prcduct by gases escaping during the electrolysis of water, it is characterized by absence of moving components in it. The-microdosing apparatus consists of a stabilis.ed poiter source, an . ctrolyzer, and a microburet, connected,to one another through a microsection. e le Me electrolyzer is filled with a-30% aqueous solution of potassium hydroxide, and,the dosed,liquid is flushed into the microburdt'. Tb exclude an effect of the ec"mterpressure of the system on microdosing, a copper tabe with a needle from a medical injector Is fixed on the end.of the microburet. The serrice experience of the inicrocb.)sing appamtus In aseries olf 'se ientif Ic -research one 0 - ----- -- -- --- ---, ~USSR UDC 631.542.25:632.7:633.57 -ISMAILOV M. G., and IBRAGIMOV, G., Azerbaydzha'n ScieatificlResearch Institute of Cotton Growing "The Role of Defoliation in Lowering the Quantity of Cotton Plaat Pests" Moscow, nimiya v Sel'skom Khozyaystve, Vol 11, No 8 (118) 1973, pp 39-40 Abstractt Under conditions prevailing in Azerbaydzhan, the optimal period "for'defoliatiGn of cotton plants (the first half of Septev.6er) coincides with ma sive hibernation migration of arachnoidal mites.: Treatment.of cotton plants during this period with-magnesium chlorate or withi'butyphos should Imer consideribly the potential reservoir:of.the mites!and owlet moth larvae on the cotton fields. UOG, 621.M7.7,M V. B., IILQUi"Sh. Yu. CHERNYAVSKIY, Ye. A., f2OBORD-711GINI DZE, D. D. venom "An Analog-Digital Watt Me~ter" USSR AutAorls Certificate ?lumber 290226, filed 29/07/69, published 9/04/71 (trans- lated from Referativnyy Zhurnal Avtmiatika- Telemekhanika; i VycliislitelInaya Tekhnika, No 3, 1972, Abstract No 3.A2_S6 P), Translation: An analog-digital watt meter for alternating current is suggested, containing-a.dc voltage-to-code converter with,halanced t-~acking, a prograruned distributorand switches. Ln OTder to increase operating speed, the watt InOtOT contains an analog memo-Ly unit and a digital-analog nultIplier consisting of a register and a digitally con troll ed'vol t age, divider. Tile i,nPut to the voltage- to-code - converter Is connected to th-- connon terminal of one switch, one terminal of which is connected to the source of -voltage being measwred, while the other terminal is connected to the output of the digitally controlled voltage divider. One input of th-A analog men-cry is conbected !to the source t)f cirrrent being neasured, -the other input is connected to the output of thic J, flip-florp of the voltage-to-code converter, The output of the analog nemory-i~; colinected tn,~the i.nput of the digitally controlled voltage divider; the discrato output w of the voltge-to-code converter 7777-,T -1 -6R U S ~1,011 V. B., ISMAILOV, Sh. Yu., CIPERNYAVSKIY, Ye. DOBORM"'liGINIME, D. D., ~-USSR Author"s Certificate Number,290226, filed .29/.07/69,:publi lied 9/04/71 (trajis- :Iated,,from Referativnyy Zhurnal Avtomatika Tel emcklianika. i V)#;cIiislitelInaya nika, No -3, 1972, Abstract No 3 A256 P) 'Tekh x$, connected to.the,common terminal of the second switch, one terminal of which ~is:.conne'cted to the -register of the digital-analpg:-multiplier~ while the other is nnected to,the output of.the entire devai-ce-Wo figures. 2/2 USSR UDC 547-341 AKJRfxDOV, LVAILUr.'V. M.. NO MIZCV, B. A., KRASILOV, A. M., and SH. T. rzeN~y_ n State University Imeni S. M. Kirov- "Reaction of Phosphorus Pentachloride With Isoprene Hydrochlorides" Leningrad, Zhurnal Obshchey Rhimii, vol 43 (105)., No 5, Mj~y 73, p -1197 Abstract: Studying the effect of two electron donating mid one electron accept- ing, stibstituents at the olefinic bond on the phosphor7lation the reaction of phosphorus pentachloride with primaryand tertiary isoprene hydrochlorides was studied. It has been shown that in ~both cases the reaction leads to the prod ucts of chlorination and phosphorylatIon.. In the process I-chloromethyl-2- chloro~.2-methyl-propylpho5-phonic acid dichloride was synthesized which could undergo dehydrochlorination after prolonge4 heating to yield 1-chlorometbyl-2- acid dichlorlde.. mothyl-propenyl.-l-phosphonic USSR UDC 547-341 + 546-185'131 IUA~ AWMOV, A. -1., AIMIED011, SH. T., MOSKVA, V. V., BABAYEVA, T. A., P ZYKOVA.,.T. V., and SUAMTDINOV, R.- A. 0 Fhzan~Chemical-Technological Institute Imeni S. M. Kirov,, and Azerba3dzhan State University Imeni S.. M. Kirov 111~erivatives of Substituted Vinylphosphonic Acids. XV. Reaction of Phosphorus (X -DicUoravinyl Alkyl Ethers" Pentachloride With Leningrad, Zhurnal Obshchey Mtimli, Vol 43 (105),,T0 5.- MY 73, PP 10-U-n13 Abstract; It was shown t1,Lat ~X -dichlorov-1inyll a.13qrl ethers react with phos- phorus pentachloride in an in-art solvent such as benzene or:,carbon tetrachloride at 0-50 . forming a complex which after decomposition with hydrogensulfide yields 4x,,,p -dichloro-P -alkoxyvinylphosphonic or thiophosphonic acid dicillorides. The ..reaction is sensitive to temperature; increased t0verature 1owers the phosphory- .1ation products and inareases the byprod eta. Analogous detlyatives Pay be ob- u -~*Iwd by high temperature chlorination:iof/)-alkoxyvinylphosl,~honic acid dichlorides. MEW USSR U X- 547 '1341+ 546-185'131 1%!A-UDV V. M. ZY1(-OVA T. V., MOSXTA, V. V., NOVIMOV, S. A., RAZURNOV, A. I., P T., and SAIAMITDINOV, R. A., Kazan' Cherical-Tb&molo-ical Institute Imeni S. M. Kirov, and Azerbaydzhan State University Laieeni S.1M. Kirov "Deri ratilres of Substituted Vtnylphosphonic Acids. XV1. Schematic for the Thosphorylation of Al~,,rlacetates With Phosphorus Pentachloridell PP 1247-1250 Leningrad., Zhurnal Obshchey M,-ixai i, Vol 43 (105) No 6,, Jun. 73, Abstract; Reactions of phosrhonis ventachloilde vith et yl=etate have been investigated using different reaLent ratios. It has been. e.stablished that the reaction products consis*; of ~3 -chloro- 8 -etho)qvinylphospihonic acid dichlorides and phos-phanodichloroacetic acidLtrichlorides. The first step in this reaction -is the replacement of the carbonyl oxygen ator. witli two chlorine atons yielding C)(, C( -dichlo:~oethylallWl ether, uhich: upon dehydrochl'orination vields 0( -chlorovinylalkyl ether. The. latter reacts irith Mlc- yielding the ~final nroducts. On the basta of 11M 1, data, it. has been shoim that the /3-chloro- -athowyvizkylpliosyhonic acid dichloride forms in two geometric isomers. 1/j USSR UDC 547.26.11.8+547-341 ISMAILOVot V -MOSKVA, V. V., BABAYCVA, T. A. j AKIrMEDOV, S11. T. anT-FUVZM'--IIOV, A. I., Kazan Institute of Chemical Technology imeni Kirov, and Azerbaydzhan State University imenk. Kirov I%ixed Esters and Ester Chloroanhydrides of .-Alkoxyvinylphos- phonic and -Th-4ophosplionic Acids" Baku, Azerbaydzhanskiy Khimicheskly, Zhurnal, No, 4, 1-972) Pp 47-49 B -alkoxyvinyl- Abstract: Mixed dialkyl anti alkylaryl esters of phosphonic acids were synthesized by reacting ester chloroanhy- drides with alcohols (1 mole) or phenol. at 0-50C under a current of dry CO 2 in the absence of IICI acceptor. Treatment of the mixed dialkyl esters vd-th PCI, yielded the corres'ponding chloro- anhydrides by substitution of Cl for the differeiit alkoxy groups. Conditions were determined for the substitution OC CI atoins for the alkoxy groups (2 on th:.,~ P atom and I on the C atom) by react- ing diethyl.- 16-etlioxyy,inylpito,~iphorii-ite with PCI In CCI At 40- 5 4* 50'C one of the allCoXy r.1.*oUps on the P atom is replactid by CI ing the appropriate ester chloroanhydride. Ret-ItcLion of L-11c USSR ST ydz*ians.1 iy Zhu k1AILOV, V. 1M., et al., Azerba C rnal, No 4, 1972, I pp 47-49 latter with an additional portion of PC1 at 70-800C results in 5 the corresponding ester chloroanhydride of G(-chloro- "8- ethoxyvinylphosplionic acid, in which treatment with excess alcohol ill the. cold replaces one of the C1 atoms~ on the P. atom with an a xy,group, and on further reaction svi at lleC yields lko. th PCI~ the dichloroanhydride of Ck-chlcro- acid. The above approach may be utilized to replace 2 oi- 3 of the al-koxy groups with Cl. The resultant~chloroanhydrides are readily distilled liquids with it characteristic odor, and are stable on long--~term storage in the cold. 2/2 USSR uDa 547.341 MOSM V. V.* ILOV. _V.- MOVA, T. V., and TAZM1OV`j A. I., Xar-=' gy imeni S. M. Kirov Institute of Cliemi Techhe~o "Substituted Vinylphosphonic Acid Derivatives. IX. Study of the Possibility O.f Thione-thiol Isomerization ofA1~-Alkcxyvinylthiophosphonic Acid Derivatives" UnIngrad, Zhurnal Obshchey Xhinii, Vol 41, Vo 8, AU9,71, pp 1676-1679 'Abstracti In an earlier article the authors reportwd that they found no ..thione-thiol isomerization In the synthesis.of 4Lalkoxyvinylthionophos- phonic acid esters. The present article gives additional data, on the tasis of which a thione structure is assigned tothe synthesized esters. The possibility of thione-thiol isomerization:was studiea In the esters them- selvesp as well as products of their subsequent conversions. For this pur- pose the-diethyl ester of 40-ethoxyvinylthionophosphonic acid was compared with Its thiol isomer the 0,3-diethyl ester of /~_6thoxyvinylphosphonic aoldq obtained by pamUlel syntheals,: The conversion products of these esters were also compared. The resultap as well an IR PandlihR spectral and thin- layer chrazatographydata confirin the:resistance of'Ue ritaction products to thione-thiol isomerizationp at leapt under the conditions of their synthesis and Identification. USSR uzc K. A., and -T. Ap vi n 3.'L uz; USSR LY-UWX,IYEV, K. A. nd ISMAILOV, I. M., Avtomatiz. i Kontrollno-Izmerit. illus'Un., two biblio. USSR UDC 631.542.25:632.7:633.57 ISMAILOV,__M._G., and IBRAGTMOV, G., Azerbaydzhan Scientific Research Institute ~T-Co---tt-o-n -G-row-ing 1he Role of Defoliation in Lowering the Quantity of Cotton Plant Pests" Moscow, Khimiya v Sel'skom K'hozyaystve, Vol. 11, No 8 (118), 1973, pp 39-40 Abstract: Under conditions prevailing in Azerbaydzhaa, the optimal period for defoliation of cotton plants (the first half of September) coincides with -.q-qsive hibernation migration of arachnoidal mites. Treatment of cotton plants during this period with magnesium chlorate or with butyphos should lower considerably the potential reservoir of the mites and owlet moth larvae on the cotton fields. 1/1 USSR UDC: 621.317.784 SMOLOV, V. B. , _lSiNLAILOY, Sh. Yu-., CHERN-YAXISKIY, Ye. A., DOBORDZ11GINIME, D. D. "An Analog-Digital Watt Meter" USSR Author's Certificate Number 290226, filed 29/07/169, published 9/04/71 (trans- latea i-run kvtmaxt-~ka-, Teleutekhaaika i Vychislitellnava Tekhnika, No 3, 1972, Abstract No 3 A256 P) Translation: An analog-digital watt meter for alternating current is suggested, containing a dc voltage-ta-code converter with balanced tracking, a progralmned distributor,and switches. In order to increase operating speed, the ivatt meter contains an analog memory unit and a digital-analog multiplier consisting of a register and a digitally controlled voltage divider. The input to the voltage- to-code converter is connected to the cornnon terminal of one st-.,itch, one terminal of which is connected to the source of voltage being neasured, i-dlije the other terminal is connected to the output of the digitally controlled voltage divider. One input of the analog inenory is connected to the source of current beinIg measured, the other input is connected to the output of the flip-flop of the volt'-f-c-to-c1cde converter. The output of the analog memory is connected to the input of the digitally controlled voltage divider; the discrete output of the voltage-to- code converter 112 USSR SMOLOV, V. B., ISMILOV, Sh. Yu., CI-IERNYAVSKIY, Ye. A., DOBORD-ZHIGINIDZE, 1). D., USSR Author"s Certificate NLunber 290226, filed 29/07/69 published 9/04/7/1 (trars- lated f:roin Referativnyy Zhurnal Avtomatika Telemel-hanih'a i 17% chislitel Inaya Tekhnika, No 3, 1972, Abstract No 3 A256 P) is connected to the common terminal of the second switch, one terminal of which is connected to the register of the digital-analog multiplier, while the other is connected to the output of the entire device. Wo figures. 2/2 USSR UDC 547---:541 ISMAILOV V. M. NOVRUZOV) S. A., KRASILOV, A. M., and AK15ZDOV, SH. T. . 1 - - ...) - - ~ 1) Azerbaydzhan State University Imcni S. M. Kirov "Reaction of Phosphorus Pentachloride With Isoprene Hydrochlorides" Leningrad, Zhiarnal Obshchey Khimii, Vol 43 (105), 110 5, May 73, P 1197 Abstract: Studying the effect of two electron donating and one electron accept- ing substituents at the olefinic bond on the phosphorylation the reaction of phosphorus pentachloride with primarj and tertiary isoprene hydrochlorides 'Was studied. It has been shown that in both cases the reaction leads to the prod- ucts of chlorination and nhosphorjlation. In the process 1-chlororrethyl-2- chloro-2-rrieth:/Ipropylphosphonic acid dichloride was synthesized which could undergo dehydrochlorimation after prolonged heating to yield 1-chloromethyl-2- methyl-propenyl-l-photiplionic acid dichloride. 1/1 USSR uDc 547-341 + 546-185'131 ISMAILOV, V, 1j., MOSKVA, V. V., RABAYEVA, T. A., RAZMOV, A. I., ANHMEDOV, SH. T., liikOiA'T. V., and SAIAKRUTDIDIOV, R. A., Kazan' Chemical-Technological Institute Imeni S. M. Kirov, and Azerbaydzhan State University Lmeni S. M. Kirov "Derivatives of Substituted Vinylphosphonic Acids. XV. Reaction of Phosphorus Pentachloride With(y-,/3-Dichlorovinyl Alkyl Ethers" Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 5, May 7 3, PP 1011-1113 Abstract: It was shown thatc4,)5-dichlorovinyl alkyl ethers react with phGS- phorus pentachloride in an inert solvent such as benzene or carbon tetrachloride at 0-50 formin1g, a complex which after decomposition with hyarogensulfide yields Oq -dichloro-P -alko.Winylphosphonic or thiophosphonic acid dichlorides. The reaction is sensitive to temperature; increased temperature lowers the phosphory- lation pvoducts and increases the byproducts. Analogous derivatives my be ob- taiwd by high temperatura chlorination ofO-alkoxyvinylphosplionic acid dichlorides. USSR ISMAILQV-7- T , RAMIMOV, G. R. PM�MMMMWM~ LTj)c: 621-3T2.o6l "Third-Order Subharmonic Oscillatiors in a Circuit With an Active Non- linear Element" Kiev, Izvestiya VUZov, Fadioelcktronika, Vol 15, No 1, Jar, 72, pp 93-98 Abstract: The paper is an analytical approach to the question of excitling and sustaining subliarmonic waveforms of third order in an electric circuit with a tunnel diode in cases of i)aranlel and series connection of the load impedance. An examination of the frequency characteristic shows it to be generally asyminetric relative to the average frequency. Three fiC-urcs-, bibliography of two title,;. 1/1 - 29 - USSR 0 UEC, 547-341 + 546-185'131 ISmA,-LL-OV V. M., Zy,~-C!,,,!l T. V., YOSKVA V. V. -C.OVNJZCV, S, A., FAZ13YOV A. T., clff~-E;~, ~~;f - T.J. and ',11JAKHUTDIV`0V, R. A., Irazan' instit,at-, .171,cni S. 14. Kirov, said Azerlbaydzhan Stet~a Universit,, Lmeni S. M. Kirov "Derivatives of Substituted Vtrivlphosphonic Acids. XVI- Schem.'atic for the Phosphorylation of iUl-ylacetates With Phosphorus Pentachloride" Leningra,l., Z-hurnal Obshche,,; Ydlimii, Vol. 43 (105), No 6, Jun 73, PP 12-47-1250 Abstract: Reactions of phosrlhorus nentachloride with etlilylac~3tate have been investi,ratud using. different rea[---ont ratios. It has been established that the reaction Droducts consist of IP-) -chloro - 1Y -ethox.,ptiny io sql ion. ic acid dichlorides an,-L ptiosphonodichloroacetic acid trichlorides. '"Lao- first step. in this reaction is the reDlacer-ent of the carbonyl oxy,,~en aton vith two cl-Llorire attor.s yielding a, G( -dichloroethylaLkyl ether, which upon dehydrochlorination yields 0( -chlorolrinylallky 'I U Fhe latter reat.us ~,-rith FC1.5 yielding the , I ether. final productB. On thf- basis of' TINM (L-ita, it has been sin,nwri that the /-3-(,h-Loro- rwi(t (Itchloride. fomrrin In two Lsomera. USSR UDC S47.26.113+547-341 ISHAILOV Nr iq MOSKIVA, V. V., BABAYEVA, T. A., AICHMEDOV, S11. T. affT-MUU~MOV, A. I., Kazan Institute of Chemical Technology lmen-i- Kirov, and Azerbaydzhan State University inieni Kirov "Mixed Esters and Ester Chloroanhydrides of R-Alkoxyvinylphos- phonic and -Thiophosphonic Acids" Baku, Azerbaydzhanskiy Khimicheskiy Zhurnal, No 4, 1972, pp 47-49 Abstract: Mixed dialkyl and alkylaryl esLer-:, of alkoxyvinyl- phosphonic acids were synthesizcd by reacting est`e~r-chloroanhy- drides with alcohols (I mole) or phenol at 0-.S'C under a current of dry CO2 in the absence oC- 11CI acceptor. Treatment of the mixed dialkyl esters with PC1 5 Y'e'ded tho corresPonding chloro- anhydrides by substitution of C.I. for the different alkoxy '-roups. Conditions were deterriined for the substitittion of C1 aLollis Col. the alkoxy -roups (2 on the P atom and I on the C atom) by react- in- diet 1, yl- /-3-etlioxyvinyti)[iosi)llorllte with PC1- in CC], At 40- 50oC one of Hie all