SCIENTIFIC ABSTRACT NIKOLAYEV, A.S. - NIKOLAYEV, K.G.

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SCIENTIFIC ABSTRACT
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H~dro 1:8iogy~ USSR UDC 62-506.2:534.618.3 KEPROSHIN, A. Yu. , and ILIKOLAYOV, A. S. NWMWW Its ing Sounds of the Red Salmon" pmin Moscow, Rybnoye Khozyaystvo, No 6, 19713- ~pp 14-16 Translation: As is known, the sound activity of fish depends on their bio- lo gical state, behavioral peculiarities, season of.theyear, time of day, and other causes, and attains its maximum during the spawning period. Inas- much as salmon during its.lifetime inhabits different media -- fresh water and salt water it has become necessary to investigate-both these periods of its life. Studies in fresh water were performed in Kuril'skoye Lake in southern Kamchat-. ka.. The largest run of red salmon in the Far East passes~annually into the lake for spawning up the Ozernaya River from the Sea of Okhotsk. Kuril'skoye Lake is one of the most important spavning grounds in Kamchatka. Furthermore, only red salmon (and an insignificant:number of loach (char) spawn in the lake, which greatly simplifies the deciphering of sounds of biological origin. 1/9 USSR NEPROSILIN, A. Yu., and NIKOLAYEV, A. S., Rybnoye Khozyaystvo, No 6, 1971, pp 14-16 ALccarding to T. V. Yegorova (1968),,the spawning of red salmon lasts from the-end of July to the middle of February.I True, in recent years, according to M. M. Selifonov, spawning has begun in early September. The red salmon arrive at the spawning grounds with insufficiently mature sexual products (roe and milt in the third and fourth stage-of.development). Appearing in the lake, the fish for some time stay in large accumulations in the vicinity of pits and near the river mouth where water temperature is higher than at greater depths. From the 7th to the 15th of August, 1969, we tested the intensity of bio- acoustical fields of different sector.9 of the lake in place:,~n of nectimtilation of the-red salmon. The number of specimens' in the shoal by visual observa- tion-varied between 20 and 200. In all sectors various sounds of the types of "tsok," "chok," "klak," "krou," squeaks, and so forth, were recorded. ~In the spawning ground at the source of Ozernaya.River and in the estuary a spawn in a steady atream, of Gavryushka, where red salmon were coming t -ive sounds of the It :intens type of- "tuk," "ta-ta~taj and %kh" were noted. ~2/9, USSR NEPROSHIN, A. Yu., and NIKOLAYEV, A. S.,' Rybnoye Khozyaystvo, No 6, 1971, pp 14-16 A-barium titanate hydrophone with a sensitivity of 30 microvolts/microbar was used as sound pickup. Electrical signals were transmifted from it to an am- plifier over a coaxial cable 110 meters long. The amplifier, of a semicon- had an inherent noise level of.5-7 microvolt at the input and diietor type an.amplification factor of 750. The signals were recorded by a Soviet porta- ble, "Romantik" tape recorder. here a shoal of the fish was found the hydrophone was lowered from At- a site w the launch to a depth of 1.5-2 meters and connected.by cable to equipment on shore. Recordings were made every hour for a period of 24 hours, each record- ing lasting 10 to fifteen minutes. The 24-hour station made it possible to establish the first appearance of the spawning sounds, the time of their maximal intensity and decrease, the nature of the sounds, and the values of the sound pressure at the point of reception. 'The spawning sound signals begin appearing at'-about 10 or 11 o'clock, in- creasing in intensity toward noon and then decreasing and 6topping alto- "gkh" gether by 23 o'clock. Occasionally,duriug th6'night sounds'of thL type are noted, accompanying, as a rule, the ".tuk" and ~"ta-ta-ta~' sounds. 319, USSR NEPROSHIN, A. Yu.., and NIKOLAYEV, A. S., Rybnoye Khozyaystvo, No 6, 1971, pp :14-16 The presence of a shoal in,dayLine-was recorded visually, and at night by spl-Wshes',and noise.'.'Control was carried'out by means of the dynamic loud- speaker of the tape recorder. The tW' type sounds are observed both singly and in series, with 10 to 15 pulses to a series. The level of the signals exceeded that of the noise bandwidth by 25-30 decibels. The value of the sound pressure, computed taking into account the hydrophone's sensitivity and the.transmission factor of the receiving channel, was 7 dynes per square centimeter. Signals of the "ta-ta-ta~' type represent a continuous shot noise and always precede the appearance of the "tuk" sound. Then an exchange of messages takes place at times assuming the form of a chiracteristic, communication ~by tapping of two, and-more seldom three, specimens (Figure 1). The number of pulstes in such a signal varies from units to hundreds. This.type of signal exceeds the noise level by as much as 15 decibels. The sound pressure is 2 dynes per square centimeter. 4/9 4 USSR NEPROSHIN, A. Yu., and NIKOLAYEV, A. S., Rybnoye Khozyaystvo, No 6, 1971, pp-14-16 jj -the red salmon Figure 1. Recording of spawning sounds of Key,--- 24 and 27 are.signals of the "krr" type accompanying the iipiwning sipals; 29 and 32 are the Piales' "ta-ta-ta" signals; 25,~30, 31, and 33 are the "tuk" signals of the females; 26 and 28 are the combined sounding of~ this "tuW' and "ta-ta-ta" signals. Spectral analysis of the signals demonstrated that the "tuk" sounds possess a nariow spectral distribution. This signal attains its maximum value at f requencies of 100 to 150 Hz, after which its level. diminishe bruptly to _519 USSR NEPROSHIN, A. Yu., and NIKOLAYEV A. S., Rybuoye Khozyaystvo, No 6, 1971, pp 14-16 zero at a frequency of 500 to 700 Hz (Figure 2,a) The "ta-ta-ta" signals differ strongly in amplitude-and possess a complrx spectrum, extending to frequi-rcies of 3,000 to 40,000 Hz (Figure'2,b):. The third type of signals is heard as gkVwith an aspiration. Their rela reaches 10 to 15 decibels (Figure 2,c). The main characteristics of the signals listed above are given in the table. 'It is vell known that the main sound-producing,organ in most fish is the swim bladder. In red sal mon the swim bladder is quite large, resembles a bag in shape, and is located under the kidneys and spinal column. When compared to the biological sounds which bad regularly been observed over a period of many years in the Black Sea by Ye. V. ShiMikova (1956, 1967), -salmon is it may be assumed that the source of the spawning sounds of red also the swim bladder. 6/9~ 5 USSR NEPROSHIN, A. Yu., and NIKOLAYEV, A .S., Rybnoye Khozyaystvo, No 6, 1971, pp 144-16 d"If rot !EP01-11" I Mot a) a "n b C) Figure 2. Spectral distribution of signals;:a - tuk" b) -"ta-ta-ta"; 'gkh. K ey: 1. Hz; 2. decibels For.many fish, including red salmon, spa%min'g is preceded by a lengthy period during which spawning pairs are formed and convenient sites for.spawning found. 7 Mal USSR NEPROSHIN, A. Yu., and NIKOLAYEV, A. S., Rybnoye Khozyaystvo, No 6, 1971, pp 14-16 As to intraspecies relationships connected with the functLon of propagation, r.ed-salmon may be classified in the biological category of "pair fish" (N. Tinbergen, 1969). As is well known, for:these fish signals of sex recognition and attraction of specimens of the,opposite sex are very im portant. As may be concluded from the data obtained,~the sounds of "ta-ta-ta," being of a nature of invitation, belong to the males, ulLich is confirmed by the high frequency distribution of the.spectrum:of these sigqa'ls. Such a shift, of the spectrum in the direction of high frequencies is explained by the smaller dimensions of the swim bladder in males. However, as demonstrated by studies made during the life of the red salmon in the sea, the female fish are also acoustically active. It may be assumed that signals of the "tuk," type belong to the females of th~_ red salilon, which is confirmed by the low-frequency nature of the spectrum of the signals peculiar to a large volume of the swim bladder. 8/9 USSR ITEPROSHIN, A. Yu., and NIKOLAYEV, A. S., Rybnoye Mozyaystvo, No 6, 1971, pp 14-16 Another important significance of the prespa-ining sounds is not excluded. They, may indicate for the fish the location of.the spawnihg grounds and thereby promote an even distribution of the spawning pairs, decreasing the possibility of loss of tile roe from tile digging over of the nests. Analysis of the studies completed permits the conclusion that tile red salmon are acoustically active. In order to establish a connectioa between the sound signals and behavior of individual specimens during spawning, it is necessary to carry out thorough observations:with the uselof multichannel acceptance recording equipment combined with underwater moving-picture photography. 9/9 jPM USSR uDe 639.2-081-7 7SHISMVA, Ye. V., and B=M 1. 1. "Noises Produced by Kamchatka Crabs" Moscow, Rybneye Khozyaystvo, No 3; Mar 71, pp 22-25 Abstract: Since sonic devices are not very useful for locating crabs at the bottom of the sea, the feasibility of detecting the pmsence of crabs by recording ocean sounds was investigated. The study was performed off the west coast of Kamchatka. Ocean sounds were recorded by =Aams of hydrophones lowered into water in areas knawn to be inhabited by sr,"thools of crabs, while similar sound records were taken from an.squarium kept:onboard a ship and filled with crabs caught in the same area. hualysia ot the recorda revealed that crabs produce specific high-frequency noises which tend to form brief "explosion waves" an a result of many crobe joining in.brief choir-type. voMlizationop Due to the specific pattem and an intAinsity 8-20 decibols above the ocean background noise, the matbod appears to be useful for practi- cal, application. 'PLAUA-A= ;1BATI4G [Article by A. V. Nikol u MOSCOW, PlazMenn a rets -18Y v ;t&!Iurgi~ I Tekhnoloji I W____M1eV - - . pp pan tkF~ I arov, R 41- vT statori va ous iechno heating, are presently being"developeO and industrially adopted, Such processes include themelting of metals, reduction of oxides, welding and cutting. hosting of powder for the purpose of imparting specia.L,properzies to it,and for t~atings rrom *Wetc. In these processes the a-ateriat is heated by the energy released in an arc discharge. Two characteristic cases should be distinguished: hesting,by plasma produced by discharge. i.e. outside the electric field, and heating.in the~discharjc itsolf. under the conditions, of electric fitid. In the former casm~tmalttn& is' the result* of thermal can ctivlty~. do Zonvoction and radiation. In the -lattdr casef the- biik.-i ii-ponent -of heat *a exchange is transmission of onergy.to the material by charged particles traveling in an electric field. Typical examples of Material processing In the absence of a,fleld heating,of powder ina plaima stream. cutting of nonconducting uater- are I*Is and other processes. Cood IllUs tration3 of the heating of material in the field of disa charge pre the heating Of hydrogen,43 a chemical reagent in a plasmatran and plasma-arc cutting and Melting Of ZLtBI. In the.former case the powder is used chiefly as a result of thermal conductivity and convection. and.this heating may be expressed through the Nusselt, Reynolds, Prandtl, Lewis and other criteria. when an electric field is applied On the heat exchange zone the'rate of transfer of energy to the material will depend, In addition to these pardpwters. am such properties as the Intensity of the electric and magnetic fields, charge of the particles, total current. work function, ionization potential etc. The energy indices of ploma-arc heating in gaseous and condensed ph"*$ are discussed in this article. USSR NIKOLA r-RI11111011A, 1. N., MIOLIXUTAII D. INOBTE VA) A. A.; IVIATYUK, T. V. "Phosphorus and Sulfur-Containing Sorbents. V. Organothiophosphorus 53orberits" a Akademii Nauk Seriya Novosibirsk, Izvestiya Sibirskogo Otdelaniy, Khimicheskikh DIduk, Ho 1, 1973, PP (9-83 Abstract: Data are presented on the syntlieris,.physical-cheL-iical evaluation and-sorptive power of organothiophosphorus sorbents -- cation-exobange resins and "mixed" complexites. Two types of phosphorus and Bulfur-containing sorbents were, synthesized. The first type imre cations wi th the functional group. -P (S) (OH), - The sor- bents of the second type were "mixed" camplexites containiv,;; the. cation- exchange functional groups and -P(S)(OR) 2 where R are alkyls - 111le physical- chemical characte-ristics and sorptive powers of the syntheslized 13orbents are giv-en vith special attention to the selectivity of the sorbents and their sorptire power with respect to extracting gold from acid soltations. The "mixed" complexites were distinguished by a someidtat reduced sorption rate apparently as a result of an increane In,steric factors. For the cation- exchange resins a small reduction in the degree.of sorption of gold was 1/2 - 1. - -7,7:77:~T-~~777 USSR UDC 547.241 MIRDNOVA, Z. N., TSVETKOV, Ye. N.~ PETROVSKAYA, L. 1. Ngp. 8ET�;KIY., V.. J. NIKOLAYEV,-A. V., and KABACIWIK, M. I., Institute of Inorganic Chemistry, Mdiiiiiii-ffVfs-ion, Academy of Sciences USSR,:and Institute of Mteroorganic ~-,::dompounds,-Academy of Sciences USSR "Synthesis Starting With Tetrauxymethylphosphine Chloride; Aminomethyl- hosphinesand Their Oxides" p Leningrad, Zhurnal Obshchey Khimii, Vol 42(164), Vyp 10, 1972, p 2152-2158 P Abstract- Eleven aminomethylphosphines, general formula P( 2NR Rn CH '2)3-n1 were synthesized from tri(acetoxymethyl)pliosphine, whose synthesis the authors have previously reported, and 'Secondary amines in aqueous methanol :in the presence of potassium hydroxide. This synthatia pathway is said to have fewer difficulties than those described' previously, a-hd to proceed via asaponification mechanism. The yield, b,oi-ling point,:~ ref ractive index, deastty, observed and calculated molar.1 ref. raction, percentages of C, H, and P, and formula are reported. Using, hydrogen peroxide in acetone 0 Several the phosphines were oxidized to their correso ading oxides previous synthetic pathways are listed and some:~bf. the constants are reported for ten of these. Proton magnetic resonance and double resonance 1/2 USSR UDC 547.241 MIRONOVA, Z. N., TSVETKOV, Ye. N., NIKOLAYEV A. V., and KABACEMIK, M. I., Institute of Inorganic Chemistry, Siberian Zia~W'of the Academy of Sciences, USSR and Institute of Metalorga4~ic Compounds, AcadeTay of Sciences, USSR "Syntheses Based on Tetra(hydroxymethyl)phGsphanium Chloride" Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 3, Mar 73, pp 534-538 Abstract: Reaction of Lri(chloromethyl)phosphine with a1koxides of higher alcohols yields the oxides of metliyldi(alkoxyinethyl)phospiiine which are effective extracting agents for uranium and thorium salts from sulfate solutions. It has been shown that the oxide of methyldJ,(metboxymethyl)- phosphine reacts with potassium hyd.roxide,at about.150% splitting along the phosplorus-carbon bond to,yield methylmethoxymethylphosphinic acid. Higher homologues split at 200-250*:forming.the respective me.thylalkyl ether and a salt of methylalkoxymethylphosphinic acid. The acids were isolated in form of benzhydrylammonium salts. USSR we 54.49 NIKOIAYEV A. V. YAKOLEVA N. I.s GAL TS OVAI S. A., and MhZALOV; L. N. "Correlation of the Extraction Properties of Organophasphorus Compounds with A, -Charge At the Phosphorus Atoe Novosibirskp IzY. Sibirskogo Otdeleniya Akademil Nauk SSSRp Ser, Xhimicheskikh Nauko No 6, 1972t 118-119 PP Abstracti Organophosphorus compounds are used extensively for extraction of uranyl nitra+e, plutonium and americium. The~erperiaiental inveatIgation Was conducted on the efficiency of extraction and distributimcoefficIents of organophosphorus compounds as a function of,*charge on the phosphorus atom. Pitting the newly obtained ata, as well aa sorae+ of the dattL reported in literature by the method of least squaxes a-linear relatioiishipAs found between the logarithm of the effectiye extraction constants and the charge on-the phosphorus atora.- A test~of the equation shows that;for all cases the correlation coefficient is 0.99. IA I]Dc 632-95 USSR ARDATOVA, A. N. and IqKOLAX~;V A. V. "Detoriaination of Granosan in GraWl Tr. 2-go Vses. soveshch. po issled. ostatkov pestitsidev I prof ilcAt. zaffx7azneniya ini produktov pitaniya, kormov I vnesh. arelcIy (Ta=sactlorls the-,Second A32-Uriibn Confe3mrnce on the Study of Pesticide Residues and P.-a- Vention of Their Contaminationof Food Productsp Fodder and tbr- Xxternal Envixonefatn)p Tallinn, 1971, pp 265-266 (:tr.om,RZh-Xhi.U-,ya, 140:13, 10 Jul 72, Abstract No ON505 by T. A. Relyayeva) Translationt Some 20-40 g of grain are treated tiice ~ftth 40-60 n1 2-5 N HC1 (acid), 15 min. each time with shaking,. vid filtered, EM-1gC1 Is extracted from solution with 3 x 10 ml MIC1 The OXtracts are filtered and the total 3' -filtrate volume is brought to -40 ml. Ton a3lilitsirs of ace'ate buffer (pH4,5) and 5 ml of distilled water are. addsd to 5 vil of exttact and titrated with an 0.001 percent solution of dithizone. USSR UDC 669.778.053.4.09/1 NIKOLAYEV. A. V., GINDIN, L. M.1 SOKOLOV,'A. P., ZAKHAROV, V. F., I. A. .."Leaching Antimony out of the Khovu-Aksinsk- Arsenates of Cobalt-Nickel Concen- trates.by Canstic Soda Solutionsot V sb. Sintez. ochistka i analiz neorgan. materialov (Synthesis, Purification and Analysis of Inorganic Materials -- collection of works) , Novosibirsk, Nauka Press, 1971, pp, 171-174 (from P_'1h--14etallurgjXa, No 4, Apr 72, Abstract No 4G309) Translation: The technological scheme for refining arsenate concentrates was daveloped using the irmthod of two-stage leaching out in NaO11 solutions under optimal conditions: 1) the first leaching.out stage: Initial IM01-1 concentrn- tion 250 g/l, S:L - 1:11, teirq)eraturc 80*,. durntion I hour; 2), second leaciling out stage: initial 11aOll concentration 250 SO, 1-14, traperaturn 80', duration 2 hours. Aqueous repulping of the bydroiide cake took place under these conditions: S:L = 1:7, temperature 60', duration 2 hours. The separation of the trisodium arsenate or regeneration of the alkali , from trisodium phosphate by lime was carried out under the following conditions: S:L - 1.4-5 (with re- spect to lime) , temperature 90% duration* 1.5 hours. The extraction of lis in -99%. Nonfe the solution was 98.5 rrous metals convert in practice wiiolly to the hydroxide concentrates, extraction of the metal in whicli is: 99.97. Co, 99.9'k' 1/2 ! I ~ .1 .1 ;i I - --- _-_ - - :- USSR UDC 541-183.24 BOGATYREV, V. L., ZIMRYO, F. V., VULIK-PI, A. P., P.-S. LYIJBINTAN, N . YA . . Institute of Inorganic Chemistry, Siberian Department, Academy.of Sciences of the ~USSR- "Ion Exchange Eauilibrium Between Ionite Grains'! Moscow, Doklady Akademii Nauk SSSR, Vol 198, 1971, 110 1, Pp 138- --n formulas to determine the equilibrium state in Abstract: Knoi U the case of inter-grain affinity can be applied only if the inter- bond exchange by counterions takes place by the predominantly sirmle mechanism involved in direct contact between grain surfaces. If other factors besides contact play any considerable role (such as ionite hydrolysis), these must be:considered as well, and be broupht into the formula for equilibrium state. TheLauthors de- rive-em-oirically several formulas forion exchan ge between ionite rains. 9 2 USSR UDO 541-127 j..V Academician, BOGATYREVI V. L.0 and ZHMO, F. V., Institute of-MnUrEganic chemistry, Siberian Department of the AcaderW of Sciences USSR, -Novosibirsk "Mechanism and Kinetics of Ion.Exchange Between Iw~W Gxalnslt Moscow, Doklady Akademii Nauk, SSSR, Vol 200, No 4,1971, pp M-889 Abstracti This study examines intergranular counterion exchange occu=ing only on direct contact of the swollen grains of ion.exchangers in completely deionized water. An example is intergranular counterion exchange in ihe con- tact of monofunctional strongly Ionized realnz An such ionic forns where hydrolysis is practically ruled out., An electrochemical r,,Ddel,of-the exchange Interaction of two Ionite grains wlth:the participation of electric double~layers is given, and the principal 4otors influencing the exchange process rate are considered* Extraction' ibd`R6~~f'69 USSR UDG 546+541.121.536.7 NIKOLAYEV, A. V. , et al. "Ekstraktsiya Neorganichoskikh Veshches "Nauka, Novosibirsk, 1970 tv Abstract. This book is devoted to the description of extraction equilibria of 'simple and polycomponent systems,. covering the.problenm of thermochtzmistry, thermodynamics, phase equilibria and extractive.capability during isolation of.:Lnorganic substances. The study is of interest to a wide circle of specialists chemists, scien- -technical workers, and students of chemical specialties. tific:and engineering ion: Table of Contents 3 T ranslat Yoreviord nd salting out Diagrams of distribution, separation a ~1. Types of distribution diagrams 6 1-4. General,concepts 6 1-2. Tri-component extraction systems 11 1-3. Quaternary components extraction systems 14 14 1-3-1. Salting out coefficient 1-3-2. Distribution diagrams for cases when ona substance -goes intothe extract 15 7-" USSR NIKOLAYEV, A. V. , et al., "Ek-straktsiya Negrganicheskikh Veshchestv, "Nauka, Novosibirsk, 1970 1-3-2a. Distribution diagrams with an Mactive second component (D -1), S l 17 I-3-2b. a Distribution iagrams in case. of salting out ing to linear equati' ' v a+b c > accord on (D 1) a I ' 19 I-3-2v. of D with Real salting out rules (contlectio n $al the concentration of the.fourth component 21 1-3-3. Distribution diagrams wheh-two substances go into the extract, 25 I-3-3a. Distribution diagrams of the first (dominant component 26 2- 1-3-3b. Distribution diagrams of the second component (being salted out from the extract) 27 1-3-3v. Distribution diagram for two components going into the extract similar:in their~inteiaction strength 35 1-3-3g. Distribution diagroms when a complex compound goes over Into the extract from components 39 MIT M;JT1 USSR, ~NIKOLAYEV, A. V., et al,, "Ekstraktsiya Neorganicheskikh Veshches tv, "Nauka,.- Novosibirsk, 1970 JI. Salting out curves, coefficients and diagrams 42 II-I. icients and curves of salting out. from aqueous Coeff phase (Dv sal O 42 11-2 D and corresponding salting out curves fi 44 11-3. Sa ting out digrams 45 11-4. Diagram types for salting'out from'aqueous pha-se 45 11-5. Diagrams for salting out from organic phase DO or I/Do, 51 11-6. Mial sa xed t Pes of salting out diagrams y 54 III. - Separation coefficients, curves and diagrams 55 Introduction 55 111-2. Theoretical separation.curves 0j, al 1) 56 ni-3. Separation diagrams 61 111-3-1. ' Separation diagram for,the system Ce(N03)4- O-TBP U02(N03)2-112 62 111-3-2. Separation diagram for the system UO (N03)2- 2 HN03-(C4H9)2po(OC4H9)-H20 63 3/12 USSR 7.7 -NIKOLAYEV, A. V., et al., "Ekstraktsiya Neorganicheskikh Veshches tv, :."Natika,." Novosibirsk, 1970 111-3-3. Separation diagram for the system FeC' -H01- ~3 H20-(C2H5)20 63 111-3-4. Separation diagram for. the system U02(03)2~- HN037H20-TBP 64 111-3-5. SeparationAiagram for the s stem Th(N03)4- y 003-H20-TBP~ 65 111-3-6. Separation diagram for the system:Ce(N094- IIN03-1120-TBP 67 111-,3-7. :Separation diagram for the system U02(NO3)2 O-TBP~ Th(N03)4-H2 67 111-3-8. Separation diagram for the system HN03- La(NO ) -H20-TDP 68 111-3-9. 3 r tion diagram for the Sepa a ystem Ce(IN03)4- Th(N03)4-1120-TBP 69 111-4. Combination of the separation:diagram~with the distribution diagraml(types of neparation diagrams) 71 111-5. Actual separation curves an d-isoconcentrational crossections of some separation diagrams 74 ~2_ USSR Nikoum, A. V., et al., "Ekstraktsiya 'Neorganicheskikh Veshchestv," Nauka,"' Novosibirsk, 1970 IV. Extraction rays and lines 81 IV-1. General determinations and concepts 81 IV-2. Actual extraction rays andextraction processes, characterized by them 85 IV-2a. . Extraction of.one component 85 IV-2b. -Systems with a domineering- component (two components are extracted) 88 e Extraction rays in the system,C. (N03)4-HN03- H20-TBP 91 The system TH(N03)4-M4O37H20-TBP 93 The system Zr(NO O-TBP: 3)4-HNO3_H2 95 mponents IV Extraction rays and separation of to 95 1.77-3-4. Extraction rays converging!atthe pole 95 IV-3-2. Separating extraction rays'(no,poles) 96 IV-3-3. Extraction.ray shows:a'pole in the composition field (not on the~coordinate axis) 97 IV-3-A. Extraction rays in separation diagrams of different types 97 5/1-2 USSR MXOLAYEV, A. V., et al., "Ekstraktsiya Neorganicheskikh Veshchestv, !'Nauka," Nwmzlbirsk, 1970 IV-4. Mctraction rays and distributionAia grams 98 IV-4-1- One component extracted 98 IV-4-2. Rays on diagrams -with two components being extracted. 98 IV-4-2a. Diagram rays of the dominating component 98 IV-4-2b. Diagram rays for extraction of a ternaty,complex compound 99 M Fxtraction rays and separation 41ngrams 99 IV-6. So= notes an the composition, and. properties, of orgunic phases 100 IV-7. Calculation of repeated extraction 103 action V. Separation orders during extr 108 . V-1. Separation orders 108 ~V-2. Vie effect of the radius and the charge of an :Ion on the extraction (position of the:alements'in scparatlan owderrsi 113 VI. Grapkic methods for the calculation of extraction processes 115 Literature 124 I.-.Thermal effects during extractiow 126 Ir..,Thermochemistry of binary systems 129 III.--Thermochemistry of thernary systems 139 IV. Connection of the thermochemical data with, extractabi li ty d extraction capability an 145 Literature 150 Phase equilibria and thermodynamics of binary, ternary and polycomporiefit systems during,extraction. 151 1. Conditions for stratification and stability 151 I-1. ,Stability conditions for binary phases, 151 1-2. Stability conditions for ternary and polycomponent systems 155 1"3. Stratification conditions-and solubility curve 156 Piutual solubility -4. The effect of the ternary component of 1 of two liquids 160 7/12- -1-5. Derivation of stratification diagrams from thermodynamic potential isotherms 161 II. Types of.binary diagrams with stratification 161 11-1. Binary systems with.upper critical solution temperature 161 11-2. Binary systems solubility diagrams with a stratification curve showing a lowercritical solubility temperature 164 11-3. Systems with a closed stratification curve 166 11-4. Systems with a tendencyto form*6 lower critical temperature of solution 167 11-5. Effect of the pressure on the t pe of stratifLcation y field 169 Ua-5-1. Transition through a simple eutectics 169 11-5-2. Transition through quaternary phase composition 170 11-5-3. Transition through-formation of a compound 170 111. Mutual solubility in the systems water-phosphorus-organic extractor 171 8/12 USSR NIKOLAYEV, A. V., et al., "Ekstraktsiya Ne6rganicheskikh Veshchestv, " ~"Nauka," Novosibirskj 1970 III-1. The effect of the ether radical on the mutual solubility of liquids 176 111-2. On the nature of the hydrates of organophosphorus extractors and their effect on the formation of lower critical temperature of'solution 180 IV. Phase equilibria in extraction systems 186 IV-4. Extraction equilibria exceptional case of r"ha'se e quilibria 186 IV-2. ases wttliout Distribution of the component between ph chemical linteraction 186 IV-3. Distribution of the component between phases in systems with chemical interaction:.of the components 189 IV-4. System uranyl nitrate water BEDBP 203 V. Quaternary extraction systems 209 V-1. Metrics of quaternary diagrams with stratification 209 V-2. Some characteristics.of the quaternary systems U0-9("3)2 HN03-11,)O-TBP and U02(NO3)7-IIN03-11 0-BEDBP 211 .. . .. ..... USSR NIKOL&YEV, A. V., et al., "Ekstraktsiya Neorganicheskikh Veshchestv ," !'Nauka, Novosibirsk, 1970 .-Literature 219 Extraction of uranyl salts with neutral oxygen-~containing. ..:extracting agents 222 ~1. -Extraction of uranyl nitrate with ethers, esters, mid Vith ketones 222 II. Extraction of uranyl salts with neutral organophosphorus extracting Agents 225 III. Extraction of uranyl salts with organic'N-oxides 229 IV. Extraction of uranyl salts with dialkylsulfoxides 240 A,iterature 241 'd.the dependence on correlation of the extracting capability an the structure on extracting agent 244 I. Correlation of the extracting capability with Hamet-Taft- Kabachnik constants 244 II. Correlation of the extracting capability of organopliosphorus compounds and their physico-chemical! properties 249 III. Correlation between physico-chemical constants and the structure of extracting agents 251 --~Literature Description of some extraction systems 257 -1. Extraction system HNO -NH4NO3-H20-TBP 3 257 II. Extraction system La(N03)j-NH4NO3-H20-TBP 261 III., Extraction system La(N03)3-HN03-H 0-(C4H9O)PO 272 IV. Distribution in the system La(NOT-N11 -N03-8N HN03-112 O-TBP 1 # 282 287 -H20-TB . V. Extraction system Ce(N03)4:-HN03 V71. Extraction system Th(NO ) W30 11 o-np 3 4" ? -TBP VIT- Extraction system U02(NO3) iil~;O ) ~(I 5H)UN03-1120 2-, 3 47 295 302 Literature 309 Distribution, separation and swelling diagrams for ion exchange processes 311 introduction 311 1. Investigation of the ion exchan ge processes by the ray method 312 I-1. Method for the construction and analysis of the distribution diagram 312 1-2. Ion exchange system NH4CI-111CI-cation exchanger (dry)-H20 313 11/12 USSR NIKOLANEV, A. V., et al. , "Ekstraktsiya Neorganicheskikh, Veshchestv "Nauka Novosibirsk, 1970 1-3. Ion exchange system NH4cl-HCI-cation exchanger (swollen) -H20 316 1-4. Ion exchange system CaCl,-;-HCI-cation exchanger (KU-2)-H20 319 A. -Distribution diagram for the calcium ion 322 B. Distribution diagram for the hydrogen ion 323 -5. Ion exchange system MgSO4-H2SOA4cat1on exchanger-H20 325 for tri : agn A Distribution diagram, e ;m esimn ion 325 B. Distribution diagram.for the *drogen ion . 328 1-6. Method for the construction and analysis-of the separation diagram 329 Separation diagram for the system H+,Mg2+ 111t 'SO4__H20 11. Investigation of the m-ielling of ion exchangers in electrolites soluttan by the ray method 331 II-1. Method of construction and analysis.of Erwelling disigrain 331 11-2. Swelling diagram of the cation exchanger.KU-2;in the System ft+, Mg2+ R SP~4 - "20 332 Conclusion 333 334 U SSR C 546an NLKOLk)MV,~LV-~,-,-S()KOLOI,'A, V. K., and. VOLKOV, V. V. 'Calculation of Isotope Accumulation of Transplutonium Elements under Neutron Irradiation of Different 13tarting' Materials" :481 Leningrad, Radiokhimiya No 3, 1970, pp -486 Abstract: The accumulation of,transplutonium elements can be achieved by pro- longed irradiation of targets in high-density.neutron beAms, which is expen- sive. Consequently, the processes taking place in the irradiated targets must first be theoretically studipd. Nost important are: accumulation and trans- formation of transplutonium isotopes and "contamination" of the target with fission products. Calculation of the accumulation allows one to evaiuate the 24-Opu has not oeen yields and to optimize the irradiation conditions. So far, studied as possible "starting" material. The acc=ulation oj transpiutonium elements from the most probable isotopes, Z39put 240pup and 4-L.4n, ~y neutron irradiation was studied. The calculated results obtained from,evaluations of beat evolution in the targets and target c ntamination by fission products were also.studied. I f ;m USSR U U 541.1831.24 GRIBANOVA, I. N., KHOWKINA, I. D,, POLOVINKIN, YU. N., and N.1KOLATEV, A. V., Institute of Taorganic Chemistry, Siberian Branch, Academy of Sciences USSR "'The Radiation-Chemical, Chemical, and MechanicaL Stability of Porous Organophosphorus Cation Exchangers" Mo.scow Zhurnal Fizicheskoy Khimii, Vol 44, No 7, Jul 70, pp 1752- .1755 Abstract: The stability of organophosphorus cation-exchange resins derived from styrene-divinylbenzene ciopolymers (11phosphone" resins) under the action of gamma-rays during,irradiation in H20, 2N HN03, nd air was studied. Changes in the adsorption apaciEy for Na' a land UO ++ upon irrndiation and in other properties were determined. The rahation stability of the-porous resins was:higher than that of the non-porus. It increased with increasing degrees of cross- linking. The higher stability of porous resins, which had a higher content of divinylbenzene, was due to greater possibilities of structurization counteracting decomposition during irradiation. The po,-.-:-.-! resins alao ha4 a higher re-aintance to the action of acids ('~N IIN03 and !N 112SOO in tests. contiriued Por 1.5-3 mos. 1/2 USSR GRIBANOVA, 1. N., et al., Zhurnal Fizicheskoy Khimii, Vol 44, No 7, Jul 70, pp 1752-1755 The detachment of active groups took place mainly by cleavage of C-,C, not C-P bonds. The mechanical strength of the resins, which was determined by grinding tests., depended on the,density of cross- linkina and the thickness of walls between pores. The data obtained c' on the resins are tabulated in relation to the content of divinyl--- 'benzene in the resins and the amount of iso-octane used in'their is. The authors.thank N.~ YR. allYANOVA for her,assistance synthen. in the exper.Lments. Radiation.Cheuds'try USSR UDC 541.123.6:546.741 NIKOLAYEV. RYABININ, A. I., and AFANAS'YEV, Yu. A.~ ."Extraction of. Nitrates of Rare Earths, Th cirium. and: Uranium, Using Undiluted Tributyl Phosphate". Moscow, Radiokhimiya, Vol 12, No 2, 1970, pp 326-335 Abstract: Securing full information an quantitative functions of distribu- tion coefficients (D) from concentrations of the extract, coextracts, and salting-out components requires platting of ~the complete distribution diagram when studying an extraction system.. , Otherwise, a: brand interval' ~between experimental points can leave peculiarities of system behavior undetected. A table listing distribution coefficients of:rare'earth nitrates in the systems Ln(N03)3-R2o-(C4H9O )'3p' 0 at 25' showed that D as a function of concentration for.all elements.studied (Fr,~Sm, Gd, and Lu), passes through a maximum in the 0.8-1.5 H concentration Interval. Another, table listed distribution coefficients of nitrates in the system's He(N03) amma _HNO O-(C H 0) PO at 25' for the elements La, Pr, Sr., Gd, Ho, Lu, Ce(IC 3-H2 4 9 3 and Th. Tabled data showed that nonmonotonicity with the maximum of D for samarlum is observed at nitrate concentrations 4, 0.5 It. Wtith an increase 1/2 E ~j - j I - P R'0 C, E S Sl IN G L) A T E - - 13 N10V 7 023 UNCLASSIFIED ~T-ITLE--;~XT8ACTION Cl: ACIDS 13Y 1.!l,N,OCTYL.4"4[?"jE,-'lJ- 14 AUTHCR-( 04)-tJ I K-"LAYC-V IA.V., KOLE SN IKOVt A.A. , GRISHINP GRANKINAt Z.A . COUNTRY OF lNFrj--USSR S()URCE--DJKL . AKAO. NAUK SSSR f970, 191(5), 1074-6 HE M (YA T EPUBL ISHED ------- 70 -SUBJECT AREAS--CHEMISTRY p7. TOPIC TA'G5--AMfNFo AC lUi P 0 T E N T 10 M f--'T'r'%' I CTITRATION, Ik SPECTRUM, CHEMICAL ANAL Y s i s C Un I kL IV]o - - fDi~ S TIT t J 1-4 S UDCUMFNT CLA55--UNCLASSIFIED PROXY RF:EL/FRA,4E--300b/1111 51[p W-01002 0/70/191 /005/ 1074-1 10V.) CIRC ACCESSION NO--AT0134797 UNC L A 5 S. If I E 0 --13NOV7C 2/2 023 UNCLASSIFIED PROCE S S I NG DATC -CIRC ACC E S S I ON NO--ATOL34797 B S, TR A C T/ E XTRAC T-- U) GP-0- ABSTRACT. THE SYSTEMS T Ft INOC T Y L AMI N EH -:SUBZ OvAC[D ~4ERE STUOIED GY USING THE ACIOS-Vl(.Lt 11 SUB3 PO SUB41 HNO SUB3,-AN0 H SU32 SO SU34. POTENTIOMETREC TITRLIN. A,NJ 114 M.;:"THOOS WERE USED TO AP'IALYZE THE PHASES. IN THIS SYSTEM THERE.IS.A LAR',;E REGION IN c PHASES -4. ANO,2 ORG. PHASES. C.'IE ORG. PHASE WHICH 3 LIQ- i COEXIST: A N At LAMINE ANU THE CURRESP'INDING -CORRESPONDS TO THE HYDkATEO SALT f)r,.TRIOCTY ACID A14U THE.0THER P14ASE TO THE PURE AMINEi THE IK OAT4 ESTABLISHED THE INTER PRESENCE OF INTERACT.1014 BETWEEN THC SALT;AND14ATER U~ING THE HCL ~SALT AS EXAJMPLE. FACILITY: I N ST. IqE()RG. KH17l.r~1NOV05116IRSK, USSR . UNC L,*A s S I F I Eo -PROGF5SING OAT;:--I3?40V70 ou-! UNCLAS.S.IP E.0 '~TITLE-CALCLULATIGN OF THE AdS3LUTE,ENERGY OF X RAY E"ISS10,11 i'RVISITIONS OF o~~.A_IIHYC~WGEN CHLORWE MOLECULE IN AW!APPROXIIIIAT ION OF: THE Y.WFLE-D ATOM I ~.MUAAKHTANDVt V.:V- r SADOVSKIYY AUT HQR.-(05)-NIK0LAYEV., 4.V., MALALO V,. L.N.~ G U Z H 'MV ~lvl, -.13UNTRY OF :INFO- USSR ~,,-,-~:SGURCE- DOKLt AKAV. NAUK SSSR 1970, 191111 4-7.: DATE: PUBLISHED ------- 70 AREAS"CHEM ISTRY IC TAGS--HYDROGEN CHLOR[OF X: RAY EMISSIUN, ELECTRON 51-IELL 1-CONTROL MARKING--NJ RESTRICTIONS ~,.D.OCURENT CLASS--UNCLASSIFIEO ::::-PROXY REEL/FRAr'lE--2000/05q5 STEP NC)--UA/0020/70/191/001/0144/0147 CIRC ACCESSION N(J--AT0I?42$j2 LAS _[Ej -ACCESSION, NO-AP01"6926 IRC I 1~71 -2/2 022 UNCL ASS IF I ED PROCESSING DATE-27NOVU C I RC ACCESSION NO--AP0136926 -ABSTRACTIEXTRACT--(U) GP-0- ABSTRACT. THE RESULTS OF AN EXP~RIMENTAL STUDY OF THE ENERGY CHARACTEPis-rics OF A DC A'C AT 5--!10 T01-,R, STAR[Ll'.F0 T -,~_~BY -AN ARGON, PLASIMA JEt, ARE STUDIED. THE 'ARC WAS EK(',ITED RETWEEN A 0 -EC I ELY). IT vlAS COPPER CATHODE, AND ANODE f50 AND 100 14M DIAMFTER, R E S F T.v WITH A F.GUND' THAT THE REGION OF STABLE ARCING UNOER LOW PRF~TURC ' -RITICAL RANGE -FUSIVE CATHODE SPOT DEPENDS 0.4 THE AMPERAGE IJSED:t THE WHICH IS 180-200 A. FACILITY*. INSTITUTE: OF METALLURGY, USSR ADEMY.OF SCIENCES. tjNCLASS-lF.IED_ 6SR UDC 542.91+669.21/8 Aca e racian. and FOKIN, A. V~. CorrespondIng Xomber of the 111KOLATEV, A. V, IMMY WE Sultshces USSR Virection of the Synthesis of Extractants for Nonferrous Metallurgyfl MOSCOW, Zhur-nal Vsesoyuznogo Khimichaskogo Obshchestva imeni D. 1. iiendeleyev, Vol 15. No 4. 19?0, PP 364-369 Abstract: An analyz5is is made of the advantages of e-xtraction processes ani tile properties of organic substances used as extractants. The POS3ibility of mQdi- ICying oxtractants by changing their chemical structure is shown and qualities (selectivity, low solubility, chemical stability, low cost, easy regeneratiQn, etc.) are determined which the extractant should possess for effective coriunercial use. A dependence is shown between the extracting ability of a substance uid its solubility and stability, on the one hand,. and the pri,::e of the recoverod metal, and the prospects of reprocess;big low-concentration solutijrts by producing inexpensive extractants with low solubility on the other h4ind. An analysis is made of the loss of extractants, consideration Is given to:the economic feasibil- Measures ity of their use for the recovery of metalslof Wferent coxicentration. I are presented for the reductionof the costlof extraotants.through use of raw materials from wastes of the chemical, petroleumo and wood:chemical industries. 1/2 : I , I I i .. I :: 4 1 : ! : 7 .'UNCLASSIFIMI.!~'":' ~:PROCESSING OATE--30OCT70 01 9 RAY EMISSION K SUBBETA SPECTRA OF. :SUENR IN SOME SULFUR CONT A I N I NG COMPOUNDS AND THEIR RELATION.TU:.THE STRUCTURE'OF THESE EV, A9V.j MAZALOVt L~ SADOVSKIYs,~ A.P.t GALTSOYAP muRAWMANAN' V.V. A NTRY OVINFO-T-USSR ~~SWRCE-DOKL. AKAD. NAUK SSSR L970, 190(5);, 113-16,~CHEM. DATE PUBLISHED ------- 70 :,T-G-PIC TAGS--X RAY EMISSION, SPECTRUMr SULFURi CARBON QISULFIDEt MGLECULAR ~A OMPOUNDt COO _lRBITALp MOLECULAR STRUCTURE, PALLADIUM RDINAT ION '~__'_JCHEMISTRY? :CHEMICAL BONDINGo SULFIDE ,~CONTROL: MARKING--NO RESTRICTIONS ASS--UNCLASSIFIED '~DOCUMENT CL ~,.PROXY REEL/ FRAME-- 199 5/ 15 88 STE P NO-IUR/0020/701190/005/1113/1116 CIRC ACCESSION NO--AT0116996' UNCLASS IFIED PAOCESSING' DATE-10OCT70 :-019 UNCLA 0 -,C-IRC ACCESSION NO--AT0116996 .'.'ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE X RAY EMISSION SPECTRA WeRE REPORTED FOR CS SUB2 AND K SUD2 S WHERE R WAS SELECTED FROM MEt ET, 81J, --_C SU86 H SUB13, AND C SU88 H SUB17. TKE ELECTRO14 CIS. WERE CALCLI* AT HE S AT014S IN THESE SUBSTANCES BY USING THE HUECKEL: APP110AN. OF THE LCAOMO IMETHOD. FROM THE TABULATED,DATA,THE'CHAkGE ON THE 5 ATOM ~,DECREASES IN COMPOS. IN WHICH IT IS POSSIBLE TO HAVE A PI BOND BETWEEN S ---AND THE ATTENDANT RADICAL.- THE S CHARGE VALUES WERE AS FOLLOWS FOR R :_~SU82 S MOLS.: BU 1.975, eT 1.974, ME 1. 974v PH 1.913; THE INDICES OF :.-FREE- VALENCE OF THE S ATOM WEREt RESP., 1.045, 1.045, 1.043t AND 0.344. SPECTRA WERE ALSO REPORTED FOR THE PRODUCTS OF EXTN. OF PDCL SU82 BY R IN THESE C45ES THE PD-S .-SU32 S;WHERE R EQUALS PH OR CSU86 H SUB13. ~~BOND FORMATION CHANGES THE NATUR.E.AlF THE EMISSION SPECTRUM DRASTICALLY TO R SUB2 S OWING TO ELECTRON REDIS-TRIDUTION AND THEIR -JCOORDINATION WITH PD. FACILITY: JNST. NEORG. KHIM., ::'_N0VOSl8IRSK, USSR. ___UNCLAS,5-IF UNCLASSIFIED PROCESSING DATE--230CT70 --THERMOGRAPHIC. STUDY OF UORIOES OF XENON -U- tj TL E THE~ LOWER, FL :_.!~~AUTHDR-(03)-NIKOLAYEV, A.V., OPALOVSKIY, A.A., NALAROVt A.S. pl, COUNTRY OF INFO--USSR ~S OU RC E-- 17- V. ~'S I Ei OTOi AKAD. NAUK SSSRt SER* KHEM, NAUK 1970, (1)v 171 -DATE PUBLISHED-. ------ 70 AREAS--CHEMISTRY XENON COMPOUND, TOPIC-TAGS-.-THERMOGRAPHIC ANALYSIS, FLUORIDE, INEKY GAS, ";:.-'--ENDOTHERMl.C eFFECT '0 RESTRICTIONS ::CGNTPOL MARKING--ti DOCUMW CLASS-UNCLASSIFIED PROXY RE9-L/FRAME--1997/1517 STEP NOI--UR/04~89/10/000/0()1/017.,/OllI -NO -AP-01"0298 W2 015 UNCLASSTFIE6 PkOCE DATE CIRC ACCESSION NO--AP0120298 ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. I'll ET H LRM 0 GRA PH I CMETTHOD FOR C44RACTERIZATION Of- THE - LOWER FLUORIDE$ XEN0,N ()~;_:F S(162r Xl'l: !;lJf34-) OF WAS USED. THERE ARE TWO MIN. ON THE DIFFERENITIAL CiJkVES :TQ,THE ENDOTHERMIC EFFECTS. THE IST MIN- L36 PLUS OR MINUS 30EGREES Rk FOR XEF,SUB2 AND 117 PLUS OR MINUS 3DEGREES FOR XEF SU34 CC ESPOND To JHE M.PS. OF THE COMPOS. THL 2ND MIN. OF THE CURVE 155 PLUS OR INUS JS'30EGREES FOR XEF SUB4 CORRESPONl 3DEGREES XEF SUR2 ANO 146 PLUS OR MIN' TO THE QUICK PROCESS OF EVAPN* OF,THE MELTEO FLUORIOES ACCOMPANYING BY HIGH. HEAT:,ABSORPTION. THE LARGE HEATS;QF EVAPN, OF FLU13qIDES ARE IN GOOD :AGREEMEN tHEIR!:ENDOTHERM[C EFFEcrs. T:W(TH THE TEMP. OF -INST. NEORG. KHIM.,'NQV -FACILITY: 0SI8'IRSKt USSR. UNCLASSIFIED 008 UNCLAS IFIED PROr.ESSING DATE--230CT70 NMR SPECTKA OF SOLUTIONS OF XENON TETRAFLUOKIDE IN "10DINE.~PENTAFLUORIOE -U- -:--'AUTHOR- (04.) -N I KOLA Y EV rA.V.,.OPALOVSK[Yr A.A.p NAZARCJV,) A.S.r TRETYAKOVY G'41 V UNTRY OF INFO-- USSR --DOKL. AKAO. NAUK SSSR 1970, 191(3)r 629-31 ,,.,SOURCE PUBLISHED ------- 70 ,.,,SUBJECT AREAS--CHEMISTRY OPIC TAGS--XENON COMPOUND, FLUORIDE ISOTOPEr IODINE COMPOUND, NMR. OINTROL MARKING--NO RESTRICTIONS C _'DOCUMENIT CLASS--UNCLASSIFIED _-PROXY PEEL/FRAME--199711071 STEP NO--UR/0020170/L9L/(303/0629/0631 CARC ACCESSION NO--AT0119930 cf Ui LIL_A~_~_ll _f I- ---- NG oArc_'--230CT. 2/2 008 WNCLA$SIF,IE0, PikacEss r' ACCESSION NO-AT0119930 :A;8STRACTlEXTRACT--(UJGP-0- ABSTRACT. PRIMElq F CH"Ekt. stqtFrS A( C LINE41DTHS OF Ni'4R SIGNALS OF S 0 L.' jS .OF XEF SU64 114 ~[F SU65 AT 3EDEGREES ARE 61VEN. ABSFNCE OF LOW FIELD. MUL,TIPL:ETS OF rF SUB 5 WAS PRO-3ABLY DUE TO-RAPID EXCHANGE OF THE AXIAL F~ATOMS INIF SU05 wirH r4E EQUATORIAL F ATOMS -IN THE.PRESENCE OF XEF SU84. TH Ei RESULTS POINT TO A MOL. t44TURE OF THE SOLN. OF XEF SUB4 IN IF SU65 ANO~ TO. STRONGEK INTFkACTIWJ BETWEEN COMPONENTS. OF -THE XEF SUB4 IF SUB5 SYSTEM COMPARED SUiA4 HF. FACILITY: INST. NEORG. KHIM..t NOVOSIBIRSK, US,Sk k-c r_ -UN Ind NQ 7 - i ~ H. li.:~ ~ R . ! Ilw - m 1 .. .1 11 1 1 im~~ 73 - 7 AIP9 053079 UR 0289 PRIMY SOURCE: Izvestiya Sibirskogg Otdelenfya; AN SSSR, Seriya Khimicheskikh Nauk, Nr 12(162', Nr 5, PP -X bi 1 k v n v al A.~ 1. ky a hinin. V.. Karase EXTRACTION IN THE: SYSTEM Nd(N03)3-HN03 - Hj0-(CA0bPO at 25-C. The extraction of neodymiurn and nitric acid, Ni~jjlj tribatyl phosphate in tile lime tem at 2P*C was studied. Distribution coefficients of neodymium, p~aseodyi~iiufn oc n1s, fium 4swell as the extraction of IjN0a in,the correspondina syste ,were compare sama Extraction has been compared of neodymium. pra~eodvmium and iamarjum nitrates fro-n queous sofvents. without acid. P 1835. --i Uli c~ 053085 UR PR7LMARY SOURCE: Izvestiya Sibirskogo'Otdelenfya, AN SSSR, Seriya Mi6ichaskikh'Nauk, hT-r 12(162), Nr 5, 19. PP V. G. To r g9 v, V. N~ A n dj~i e v. s k y.,, E. N. Gil'bert, s k-y-. , V. A. M H(h a i I o v, 1 k 0 1 a e v V. A. P r on i n, D, D. T r o z e n THE EXTRACTION OF Pd AND Pt (IV) FROM ~NITRIC, HYDROCHLORIC AND SULPHURIC ACID SOLUTIONS BY ORGANIC suLriDES The extraction of trccer amounts of Pd and Pt (IV) from nitrlc,~ hydrochloric and w1phuric acid solutions by 0,51YI solution of organlci sulfides (R25 where R=CjIi3-CaHjY, C4Hs and thiophane) in benzene has been studied. The dialkylsulfide "~Iractidn can be used in separation Pd from Pt (IV) from nitric and hydrochloric acid solutions and for simultaneo extraction Pd and Pt from sulphpric acid- solutions. YJ 1847: USSR no 621.791-75-001:537-523.5 GAGANOV, YU. I., NIKOIAYEV$ -A. Vqi~j. RYKALIN, IT. N.1 Moscow; _Uadomy of' Sciences: Institute of Hetd lurgy$ "Low-Pressure Are Discharge,Sta:bilized by a Plasma Jet" Moscow, Fizilca i KhimiZa Obrabot~i Materialov, No 1, Jan-Feb 70, pp, 23-26- Abatract: The results of an experinental stv.dy ox' the energy 1i characteristics of a do arc at 5-10 torr, stabi zed by an argon plasma jet, are studied. The are was excitad betwi,~en a copper cathode and anode (50 and 100 mm diameter, rospeot:1.valy). It -T was found that the region of stablo~arcing under low pressure with a diffusivo cathodo.spot: da~en4a on tba; amparage used, the T__ critical rango ot which is 180-200 A6 006 UNCLASSIFIED : PROCESSING DATE--13NOV70 C I Rl.- ACCESSION iNO--AP0109476 ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE BACTERIAL CULTURE WITH 'ASPARTASE ANO GLUTAMINASE AcrIVITY WAS IDENTIFIED AS PSEUDOMONAS FLUCRESCENS AG. PROoUCTION OF BOTH ENZYMES WAS INDUCEO BY ASPARAGINE JN MEGIA WITH GLYCEROL, GLUCOSEv ACETATE, PYRUVATE, CITRATE, SUCCINATE, MALATE AND IMALONATEAS SOLE CARBON AND :EAERGY SOURCES AS WELL IN MEDIA WITH PEPTONEv UREA AND, AMMO~IUM AS...SOLE.: 141TROGEN SOURCES WAS NOT.INDUCED IN MEDIA WITH NITRATE AND ACID CASEENE HYDROLYSATE. 1OPTUMAL: PH FGR~-ASPARTASE PRODUCTION WAS:34 AND FOR, GLUTAMINASE PRODUCT ION v BOTH.ENZ-YMES:WERE INDVCED AT ~PLUS: 20DEGREESV PLUS AND PLUS 30DEGREES* 16 UNCLASSIFIED ------- Nt -USSR UDO 5~ NIRCLAYENtA, A.Z. ,*2,1_;7.R;,SHEVI14*H, I.G. ""ffect Cf Gallium Arsenide Structure On Surface, Photoelectric Effect In The X-ray Region CE The Spectrum" V sb. Yaterialy Vees. soveshchuniya po defektam atruktury v poluDrovodn. 1569, Ch.2 (Materials Cf An All-Union Conference On Structural Defects In Semiccndu~t6r . 1TF9. 'ollection Cf Vorks),:Novosiblrek, 1970, p -Part 2. p 20'"2C8 (from RZh--Elektranika Y.-ye.prizeneniye, No 12l December 1970, AbOtiract No 12A,24) Translation% Photoemission was investiEated in the soft x-ruy ragion of the spectrum of thT aur C~acea 11113A and [111]13 of GaAs, processed by machiAnical frindine, and chemical polishing in an etchant,of *he cOmPosltiOn F11)02: H,#_JSOJ41H20(2t6c5). The dependence is shown of the quantum yield on the.angleaof incidence of the x-rays with a potential at the collector-of plue 100 and minue 100 v (in the second case, slow 6econdery electrons are excluded from the meavurement's). It is obvious.from a comparison of the curven presented that the quantum yield f,rom flurface (111j, in the presence of all values of the angle of elip of the x-rayn, excecds the 01.1antum The authore-explain this by t;i* atructure of tho surfaco yield from surface [1111A on the4hotoolectric inter- layer and the dependence of the affeution,croa.vaecti, so 1 2 Ill. 2 ref. N.S. tion on the atomic number of the element (04,0106 1/1 . i 1 11 ': i 1 11 il 1 11 it I. .! t I : USSR UDC 621.039.3 -TSOV, N. A., MINENKO, V. P., NIKOLkYPV, A. I., SUI EPXD2v-, G. A., KOLOKOL AR and-TRET'YAK, S. A. 11constructing Cascades for Separating Multicomponent Isotope Mixtures" Moscow, Atomnaya energiya, Vol 29, No 6, Dec 70, pp 425-429 Abstract: At present, there is a great deal of interest in separation of isotope mixtures and consequently in the theory of buildi-a$ separating multicomponent cascades, with the requirement that isotapts of intermediate mass as well as those of extreme masu be separated. Nothing that the dif- ficulty in designing these cascades Is that the concenttaLlon of inter- mediate-mass isotopes tends to be a maximum.inside the cascade, the authors discuss systems of continuous profile cascades for separating Isotopes of intermediate mass, and the simulation of these cascades b~ actual flows consisting of constant-flow sections. The five steps required for this simulation process are outlined, and the modeling of a cafttinuous profile .Cascade for the separation of-tungsten isotopes, in the form of the gaseous compound WF6, is given as an example. 2/2 013 UNCLASSIFIED PROC:ESSIPIG DATE--04DEC70 CIPC'ACCESSION NO-AP0140340 _-~ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. LIQ. ORG. MIXTS. WERE SEPO. IN THE --Z DIFFERENT THERMAL DIFFUSION COLUMNS EACH 14 (0t SISTl(ijG OF 2 COAXIAL TUBULAR CYLINDERS OF DIFFERENT DIAMS. AND LENGTHS: ;PFICLVN~PHEXANEr M N 1 CCL PHCLtN#HEPTANEt PHCLvN,0CTANEt P liCl fNvl)G,DECANE (COLQ; )v .,SU84tt'4vHEXANEt CYCLO.4EXANEtNi HEXAN.Ev C :SUB6 H SUB6010EXANE1 HM t[41HEXANEI OPXYLENE,NtHEXANE (COLUMN 2J.. THE EFFICIENCY OF SEPN. IS .,P ~E ~DETD.; BY THE DIFFERENCE IN STRUCTURES OF -iMOLS. OF MEXT. COMPONENTS. IF THER~E JS NO DIFFERENCri, THE EFF ICIENCY OF'- SEPN.,. DEPENDS ON THE ~:.DLFFERENCES OF MOL. WTS.r B.P&:f AND OTHER.PHYS. PRQFJERTIE~ OF MIXT. FACILITY:, NAUCH.o-ISSLED. FIZ.,~-KHIM.' INST. IM. --KARPOVA, MOSCOW, USSR* L-A Tr !/a ot8 UNCLASSIFIEO PROCESSIN6 DATE-18SEP70 11"I'ME-IONIC COMPONENT OF THE CATHODIC SPUTTERING OF A COPPER SINGLE tRYSTAL -U- .;--AUTHOR-(05)-8UKHANOVr V*Mv YURASOVAt VoYEt SYSOYEVP A-.A.r SANSONOV, qLK'DLAYEVY B, I V., COUNTRY _oF7rRM--ussR i~-SOURCE-Flts TVERD. TELA 19709 12(2)9 394-7 k.DATE PUBLISHED - ----- 70 SUBJ ECT AREAS-~-MATER[AtS, PHYSICS TAGS-COPPER CRYSTALP NEON# ION, CATHODE SPUTTERINGT METAL SINGLE CRYSTAL CONTROL MARKING-NO RESTRICTIONS '.--.-DOCUMENT CLASS-UNCLASSIFIED --"'PROXY REEL/FRAME--1984/0144 STEP NO--UR/0181/70/012/002/0394/0397 CIRC ACCESSION ND--AP0054940 UNCLASSIFIED f I N 1 AA0038341 uR o482 -Soviet Inventions Illustrated..Section.1 Chemicol, Der-went, 238739 SPI!EW e.&. for thi-pirroduetion,of fibres frcaV vficods liquids, a6siett of a b4 dy (1) with channelw (2). for. Aupply~nki air, a nozi Le (3).which are made, in the;.fdrm:of-~6tatatle~c~linderi, o4 th; 6ctlonl! head with- slot-like.,opeft pr*o ' and a tube (5) for. supplyfng't4e fused matert al, one end of this tube: co1pnects, Oith--an -extruder: ~(not shown in diagram) while the other:end t6r4jinate~ in the slit aperture A toothe,d Vheel is 11 provided for rotating the cylinders,. ~ Molten,pblymer t _(5) and'flows from the extruder comes:,down he,tube out of the slit (6)'. At 'the same lima compresaed !t aii, usually preheiated..is fed4hrough the conitectica 13) into the circu lAr channel" ( 151. and. t hen of air at through (2) into (3).' The flat jat . sub-sonic speed comeo from the; opening (4) and.' strikes the f lot jets of :the Mlt : at .4n U~gle~ Rotation of tha =vable sectloh~ of, the head akmvreu T~ that a stream ofthe;desired degred:of fineaea~q,Ls obtdined, A 1.6.67 as.1161774/ZB;-12. D.N.NIKOULEV & A.T.STEPANET! TE=MF,-MAMIDMY 'LNST~, (19-8-691 Hul 101,10-3.69. Class 32a.,,,lilt-.Cl.c 013b -K 1 97314illIS4 Y3 "?'ll 2 017 UNCLASSIFIED: PROCESSING OATE ~~`CIAC'ACCESSION NO--AN0138648 .~~:AAS~TRACT/EXMACT--(U) GP-0- ABSTRACT. THE ARTICLE COWMEMORA- T ES THE 70TH THE SOVILi BIRTHDAY OF S. A. LAVOCHKIN, DIED IN 1960*:ONC- OF T PICINE'Ells 'S WE P 7WING, 45 SUPERSONIC AIRCRAFT CONSTRUCTION. LAVOCHKIN DESIGNED -b 'SOVIET: wiLl. Alli. RAFT T - -GREES, AIRPLANE, 'ILA-17611, WAS THE FIRST c' o AK THE.SOUNO BARRIER IN DECEMBER 26, 194~8.., IT WAS THE PROTOTYPE FCR, ORE -14 ;l T WINGt 55 DEGREESt INTERCEPTORS W11 :THIN lil~JGS rJ'S[(;?IED AS FUEL A*S.,.~THE LAST TEN YEARS OF HIS: IL [f E ~A VOCHKIN WONKED ON THF T -:-DEVELOPMENT OF NEW HARDWARE EMPLOYING LARCE ELECTRONK SYS'l EMS. SOME DF IDEAS ARE STILL VALID AND ARE VINDING W I BE USES.~ UNC L A S S I F I E 0 eery, TISO:R UDC 577.44 POLMOV, V. A., Professor, NT-KOLAIT!.V, G. A.., Corresponding Menber, Academy of Sciences USSR, and VOLKOV AcadenW of Medical Sciences USSR Biological Welding and Tissue Cutting" Moscow, Priroda, No 12, 1972, pp 40-45 Abstract: Present methods of cutting tissues, both soft amd hard (bones) involve a great deal of physiological trauma to the tissues and the entire orE;anism,, and in many instances delay healing. in 1964 studies were coatmienced at the Moscow Higher Technical College on the application of ultrasound waves to the cutting of biological tissues, as well as their "welding" (fusion). Li essence, the approach consisted of transforming ultrasound ener6y intomechanical oscillations by means of wave guides, -which may be variously shaped for different tasks. In the cutting of biological tissues such wave:guide "scalpels" mve with an ampli- tude of about 80/1, and the temperature in the irm~,_4Uate zone varies fro",' 50- 1700.~ AnDroximation (welding, fusion) of tissues may be accomplished with the appropriate wave guide in the case. of Iyunes by, r-.,olifcilizing the collagen matrix it to fuse. In the latter procedure an adlies ve, cyacrin is em- and permitting ployed which was developed in 1963 by A. M. Polyakova and,O. V..Smirdova. 1/2 POLYMKOV, V. A., et al Priroda, No 32 1972., PP 40-45 -sorbed in 'he Cyacrin is a sterile and nontoxic substance and is gradually ri living organism. Ultrasound enhances the polymerization of cyacrin and its penetration into the body tissue to a depth Sf 40-200 A. The stren,-th of such fused bony tissues varies from 320-580 kg/cra ~ Histologic studies conducted on animals have shown that tissues sectioned In this manner heal normally, going Ph through all of the characteristic cellular stages. T e a:pplication of these procedures to man began 5 years ago, and.up to the present time over 800 patients have been treated in such ma=er in surgery of soft:and bony tissues. Although attention rrast be given to unforeseen side,effects or disadvantages that may be- come apparent, it seems that the application of the.ultrasound:p-rocedures should open up new-therapeutic vistas in surgex7* USSR uDc 546.1654 547.412 PRONS V. N... GRINBIATj M. P. KLEBA113KIY, A .L. , NIKOLAYEV, G. A. !'Bear angement of Flnoroalkoxyhalocyclophospllimzeiies" r Leningrad, Zhurnal Obshchey Rhinii, Vol 40, No 9$ SeP 70, p 2128 Abstract: Heating a mixture of hexalcis- (p entaf luaropropoxy) - Zyclotriphosphazene (1) and tris-(pent~afluoropropo -trichloro- cyclotriphosphazene (TI) taken at a 1: 1ratio to 25760, for 40 hzs in a sealed tube leads to the formation of 12% tatrakis-(pentafluoro- propoxy)-dichloroeyolotriphosphazene (111) and a trace of pentakis- (pentaf luoropropoxy) monoohlorocyclotrrphqsphELzone~~ Increasing the reaction time brings up the ratio 0 (111) andjh-V) to about the level of M and (jI). A similar dispr6portlcnat~on reaction occurs with hexakfs-(hoptafluorobu:~OXY)-.o7olotriphoup)aazeno and,trls- (haptafluoroblitox7)-triohloracyolotriphosphazenob. iS IM'P, DAT E--64DEC70 i.-SOURCE-MOSCOWt VESTNIK MASHINOSTROYENIYAY NO 3* 1970v~PP 19-23 PUSL [SHED-----70 REC-L/FRAME--3063/1979 STEP NO-~-UR~0122/70~/1000/aO3/0019/0023 CIRC ACCESSfON NO--AP0130754 UNCLAMPLEO I ~ USSR ux - 6a .791 69`03) .8 Nr KOIAYEV, G.A.. Mloscow Higber Technical School imeai N. E. Biwman "Scientific Research of the Moscow Higher Technical School in the Field of Weldment- 'Design Strength" Kiev, Avtomaticheskaya Svarka, No 5, --Y 70, pp 9-32 Abstract: A survey is made of the scientific research perfor-med at the Noscow -nt-d i n Higher Technical School during the last decade in the field of weldmc es g strength. As a result of the study of residual strains and s-~resaes in welding, a method was developed for detenaimation of elaGtic-plastic strains i-:nd inherent stressen In thin Plateb of iimited and iullimiterl ;izeu xith shift,.; o1' the linear hange of phy~Uco,,,x!chanical Properties heat source, takinig, into tecount ito r, 14,V, C of the metal in heating and cooling, and 6tructural) and phaza tracsfan-",tions. The method 15 based on the use of hydrostatic stres2es, and body aud :;urface forces applied to volinpe elementz, with ouboequent solution of boi.~jjdary-condition e school has conductedxei5earch problems Iry computer. TL oil t.,, larj3e varie-ty of - Jects, Inclurding investigations on resi&ual stresses and strainr, in the welding of thick aluminum alloys, the effect of structural changes in -weld 'joints of steels on residual strains, determination of welding strains in thin-walled constructions, the effect of low temperature during operation on tile strength of weldment designs, strengthening of weld joints by rolling, the effe-ct of various defects on the mechanical properties of weld joints, the stranL-,th of -weld joints USSR UDC 533.6.07+536.24+536.33 KONIKOV, A. A., N40LVEV, and POLYAKOV, Yu. A. (Moscow) "Heat Exchange Behind a Reflected Shock Wave in a Two-Phase Gas-Dynamic Stream" Moscow, Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No 2, 1973, 127-136 Abstract: Measurements were made of the heat fluxes into a wall that reflected a shock wave that propagated in air containing a suspension of aluminum oxide particles having a size on the order of 1 micron. A shock tube was used, provided with a special pneumatic system for creating a gas-dust medium. The equipment used for measuring the heat fluxes was based upon the employment of thin-film resistance thermometers, and satisfied the requirements that were rocess. dictated by the short duration of the working p The range of shock-wave velocities in the two-phase medium embraced values of V. from 3 to 6 km/see. Radiant and conductive heat fluxes to the reflecting wall were measured. The measurement resuIts were coaipared with the data of control experiments with pure air and with calculated values of heat fluxes from nondusty air at equal shock-wave velocities. It was 1/2 USSR UDC 615.916:546 MRKOV, G. I., NIKOLAYEV G. M& "Variation in Content of Ascorbic Acid in the Adrenal~Glands of White Rats Under the Effect of Aluminuri-Chromiwit CatlystIf V sb..Tolcsikol. 1 -iliyena produktov neftekhimll 1 neftekhim. prolz-wv (Toxicology and Hygiene :of thel Products of Petrochemistry and Petrochemical Pro duction-Co lle ction of Works), Yaroslavl 1, 1 1972, pp 148-150 (from RZh-Farmakologiya. Khimioterapeyticheskiye Sredstva. Toksikologiya, No 3, Mar 73'. Abstract NTo 3.54.636) Translation: In rats subjected to alu'minum-chromium catlyst in a concentration of 0.00044 m.'r/liter (recalculated for cbronWim anhydride) foi' 30-90 daynt a raduction in tho vitamin C conteiii; in the cellular elements pf-.the adrenal glands wai; detected. USSRj Yaroslavl', Medical Institute, USSR UDC 577.3 XMIAYEVp G. M.# Department of Biophysics ~A Study of the State of Water in Partially Dried Yeast byi the Nuclear 11agnatic Resonance Method" Hoscow, Vestnik Moskovskogo Universitetal Vol 6# Roy-Dee 70, pp 124-126 Abstracti A large portion of intracellular4ater is so-called free water, which is simlLar to regular liquid ~mter,..Only a small Doxittion is bound by biopolymers =d differs from xegular water. This study was pexformed on commercial samples of Saccharomyces cexevislAe yeast.uhJch were'dried to con- tain 13% and 3% water. This residual irater:content was determined by drying the siamples, at 050C to a constant.weight# and it iras investigated by means of spin echo amplitude and the resonance absorption of protons, using the nuclear magnetic resonuce method. The lipid traction In yeast cells was hod. =t a determined *&.f the Folch met The results obtained on yc amples with 13%vater yielded a curve composed of thxce cUsitinat components itith cham- cetristic tine intervals for the spin relaxation of protons. This Indicated that uater molecules were present in the yeast in seyeral,physica states d -ffering considerably from each other in Internal motion The Tzoportion of i molecules in each of the three fractions wasl8sitl. 'After further drying of I1 2/2 --- :.- - -.- -_ -- - - - -- - -- -- - - - -- -- , -- ~ ASSIFIED - --l- - -- I R' .64.~o7 6i6.74-W.861 bo8.93 - .151.9-074 uDc: W-oo8.02~.r -577 3awlAYE.V7 G.M., Chair of Pathological Physiology,, Yaroslavl': Medical Institute and Toxicology Laboratory, NIIW3K 11change in Acetyleholinesterase Activity in the Motor Endings of Striated muscle During Hypoxic Hypoxia" 14oscow.? Arkhiv Patologii, No 3, 1970, pp 61-65 Abstract: Study of muscle preparations from white rats, kept in a chamber- at a simulated altitude of 8,000-10,000 m for 30-60 min sh'owed shifts in the localization and degree of acetylcholinesterase activity in the moTor endings. The region of the end-plates, vas stained with varying degrees of intensity, reflecting differences in acetylcholine activity. The.motor endings were abnormally small and compact, and,without their familiar loop- like-shape. They seemed to be in a state of "spasm," Moderate em'ymatic a ivity of the sarcolemma or sareoplasm, was noted in the muscle fibers et near the motor endings which made the striations less distinct. On the sur- face of the motor endings and immediately adjacent to them, granu.11es of different shapes (apparently neurosecretions of the my6neural synapse) could be seen. Another change noted after hypoxia was the absence of a clear-cut boundary of enzymatic activity in the structure of the motor ending, creating the impression that the ending had disappeared, and that enzymatic activity was localized in the muscle fiber or its sheath. '72 I ~ , -.9 - V ~.. - ~ ml --PROXY REEL/FRAME--1997/1037 STEP CIRC ACCESSION NO--AT0119904 I I------- U14CL ASS IF I ED I . - __ -11 . 1 11 11 .. .1 1. 11 11, . d 11, 11 1 1 j I. I t ..., . ~.;j 1, EMCTRIGAJ. EnrIlVEERDIG Cryogenics and SupercondiLctivity SR UDC: 537-312-62 GRUZIN, P. L., BYCHKOV, Yu. F, , YEVSWUMNA, I. A., KRUGLOV, V. NMI&M, -1. N. The M6ssbauer Effect in Nb3Sn as a Function Of Beat Treatment" M Sverkhprovodyashchiye splavy i soyedin,sbornik (Superconductive OSCOV -A. "Nauka", 1972, pp 42-47 (fror, Uoys and Compou:nds--collectionL of Worl-,S) RZh-Radiotekhnika, No 12, Dee 72, abstract.No 12D549 (r6sumdj) Translation: The superconductive compound lrb3Sn displays the so-called "degradation effect" -- an appreciable reduction in Tc when the annealing "OOOOC. L tion was made of to ature is raised An investigat or sintering temper, theInfluence of heat treatment in a ita cuum on: the paramet ers Of nliclear gama resonance. With a rise in annealizig temperature a considerable re- 'GR line and isome3' shift, together 7 ductionvas observed in the width of the V with a reduction in absorLA'on probability. The narrviing of the NGIR line -iicti f the is clue to an iperes-se in th ~vgxee of orearing of the sti are a und F1b ISn. . It is ehowln that the deCree of cxder-ng cat 'be d-te-ined compo J. ~from states if tbe degroe of order- absorption probability for difforentL ing end absorption probabilities are known for. two other states., With an 1/2 USSR tTDc 669-1:539.166 NIKOUYEV. 1. N.. MAKAROV V. A. PU2EY, 1. M., and PAVLYUKOV L. S. Moscow Engineering,Physies Institute, Institute of Precision Alloys, and Central Scientific Research Institute of Ferrous Metallurgy imeni,!- P. Bard-In "Mossbauer Effect in Fe-M-1--in Invar Alloys" Svexxilovsk, Fi-.ik-a Metallov i Metallovedeni-ye, Vol 35, No 6, Jime 73, pp 1305-1307 Abstract: The Mossbauer effect was studied for nuclei of Fe57 in five samples Fe the interval 0.2.< x~< O.B. After ineltin~;, 6 5-5 1-x x 3+-5 the, samples were annealed for five 11OLWS at 10000C and hardened. The resitlt- ing alloys were rolled into foil and annealed again for 0.5 hoiirs at 700oC. Geometry of transmission was used in two modes of spectra. meastirements: constant -a interpretation velocities and constant accelerations. Me method of spi~ctx y of I' sam~ples at was done by deterr.,iining the positions of centers of gravit,, a 27 temperatures above 1000K with an accuracy of +0.006 rmni/svc. A C.2 (Cr) Was sed at room ' -eratu_-e -,.rhile sample temperature was varied f2-om 4.2 to u terip 37100K. A diagram of the -,a7_net4Lc,, states of the P-1loys, 1was produced from the temperature relationship of the Mosab-nuer apectra, which reveaed alloys USSR NMOLA)EVY I. N., et al., Fizika Mletallov i Mletal I ovedeniye, Vol 35, No 6, Jua 73,, pp 1305-1307 Fe 05-5 Ni 5.5'929' Fe 65-5 N261-193 - 5' and Fe65-5 Ni.28Mn6 -5- The first alloy above was antiferromagnetic and is a doubl6t with a relatively small aavdra~e and super-thin magnetic field. An anomaly -was noted in the behra-v, ior of 'S (T) which was explained by the fact that the relative shift in the spectrum, is com- pensated by a chemical shift that decreEses the total shift with reduced tei,.rper- ature. In this case the decrease in isomeric cherdcal shift sirnifies an increase in the density of s-electrons in Fe57 nuclei 1?.Ilj:l t1lat there is F, chanc-e in the Plectron configuration of the-iron atoms during the transition fro-.,i the -oY -rid G paramagnetic to the feri i-agnetic state. YE. G. POMT07SIM T. DUI30M rendered assistance in this work., 2 figures, 5 bibliographic refer- 2/2 USSR UDC 621-376-33+5-~j',;.S--!-)15."41.i3 NIKOJAYMN, I. V. KO---'L-VVA- "Modulation of Ortical Radiation on a Wavelength of 10.6 ti" Mosco"r, Kvantovava Elektronika. No 2, 1971, PP 57-64 Abstract: The authors investigated the optical and electro-optical proper- ties o-r' crystals ol' -a'liur. aa-senide (Garks) and of cadn!~wm sulf"I'de, selenide and telluride (CdS, CdSe and CHO wbich are trans-paxent on ~L 1.7a,;e1ength of 10.6 v. The c-rystals -,ere sti.~,die,' to see if they could be u*gd -to mod%livate emission frcm lasers operatf'.ng on a nixture of C02, lie and, Tile effec- tiveness of the crystals is conpared with.re_,pect to tbe re!,nilt~ of measlare- ments. Computatione.1 formulas are presented and nodulatcnr arc- de- scribed. It was fou,~d that emission from a C02 lasx~r can be that cadmitm telluride is a pronising material for this Flirther research is needed to find more effective materials tind to develop circuits which enable a reduction ir the. controlling voltage using, t.he stine electro- -optical mapteria-'s. Six illustrations, tlilo tables, bibi ioj~raphy of ten titles. a 3; e Kulty.v, T. A., Electron-team Light Mpdulator .................. 234 HUS te 1 ' , 70. R. Faryrin, V. N. Huxtel'. Ye. R., Pary- Internal HadUlaLion of a Gas 'Laaer ............. 239 gin, V. N., Solomatin, BaBlikov, V.-R. Paj*rAtov. V. M. , Pet- Visible and Infrared LightModulator nased an a rovs, T. V. . Ponamv- Lithium IletaniGbato Cry9ts! with V Orientation 248 Ponkratov, V. H., Idide Band Light Hodulator Saxed on a LltSium Putrava, T. V., Ketaniabatt Cr7stal with 9f~* Orientation ....... V13 Ponmarevs, 1. P., Famichav, N, K. N. 11h& Relations or chai synthronous, %odo of Laser Emission Wth Modulated Dielectric Constant of the Resonator ............ 258 Deryugin, 1. A., Nonlinear. Die car tiono in Microwave Modulators Soloatka. A. A. of Laser UINOAon ......... - .................. 262 ''KOVIOV&, M. K... Utilization of Gallium Arscmidu CrystaIR to, ,-:~-.ftkolayav, 1. V, HaduJAticn:6f Radiation Vith a U*Veleasth of 10.6 micront; ........ ...................... 268 Tron'ka, V. D. Some Types of Faraday Modulators and Their Nonlindar Distortions .......................... 273 Z oka. V. D. Method of Simultaneous DetarwAnatLon of Ow Frequency Characteck, ties of the Phateraceiver and Faraday Modullktor .......................... 278 lHishitanka. )3. P., Applicatimi c: a Rofraction Acoustic Cell for Obasnenko, Yu. L. Synchronigation of the Pulse Laser Emission .... 260 Tamosodov, Yu. V., Wideband Light Detector ........................ 283 Ye. A. S.. %akin. H. P. ?~VkQNVA'CS 1. Asnottivity'ond Aertia or a Photodloda Light Receiver with Parametric AnpUfier .~ ............ 2Y3 Hillh-Fr*quenty and Low Trt~r da, Photarssis tor Light Detector with SupecUeh-Prequency Bins ... 299 .. ........ 7 Ni, I C A L 7 RA MS LA 7 10 N i~ (IIFSTC-I-IT-23-2015-72 ,2,1 0"af 7z TITLE% PROBLIM 07 LASER ISRAM DVFA THAMMSSION PROCEEDINGS Of THE FIVST ALL-UH ION, CONFMIXE, K;zv~ SrIPTEHHR 1966 I OR FIGN TITLE: PROBLUV PEPZDACHI lNFb*lKjSjj LAZE?-h'M JZLUCjIjI;-,yMj AUTHORt I. A. DZRY CIM, ST AL. XlZV ORDIA OF LZAIN STATZ VNI XVlMj TV IKUL T.G, SCHEVCHMo Tiallslatrd in# FSTC bY ACSI NOTICE Thv c,.nit-mi 4 this pttbficAtion have becr% translated as Prmilted in the ortRinal Att(;fllp( Il'is bectl "'Allc 10 ycfir)' the Jccurscy of any stafentent contained herrin, Thit trAmI.164111 is Publmlicil with a 11111111nulia of copy editing and graphics prcilarition in order dunuriobiritisition, Ilubliv 01%tributhm onlinvited. 411 USSR UDC: 51 N.MLAYEV, K. G. PUMMIKOV, L. N. pplication of the Method of 'Branches and Boundaries' to the Problem of Locating the Enterprises of a Production Unit". Moscov, Irnzh. mat. metody.v fiz. i kibernet.--sbornik (Engineering Mathe- matics Methods of Physics -and Cybernetics-co'llection of works),,vyp. 2, Atomizdat, 1973, pp 107-118 (from RZh--Matema-6ika,,No 8, Aug T3, abstract NO Yu. Finkel'Ishteyn) Translation: The paper examines the problem of selecting the optimum vari- ant of,locating a given set of enterpriseB on:a delineated section. The ~section may have any shape; the enterprises are rectangular. The presence ''an the section of sites where construction is'forbidden is not excluded. The goal function is a sum of terms representingAhe naturel~of the terrain (situation), cost of communications (connections), effectiveness of inte- .:grationiand blocking, compactness in locating.; th-i objects. For solution of the problem, the authors'. ~propose an algorithm of branches and boundpxies which accounts~for the specifies of the problem, F 1/2 USSR NIKOIAYEV, K. G., and FLUSHNIKOV, Li N., Inzhf# Hats met~dy vfiz. I kibernet, vyp 2, Atomizdat, 1973, pp 107-118 and two approximating modifications of this algorithm. To reduce the number of branches# the authors introduce two simplifying assamptionst 1. The optimum solution is reached if the objects are located in one or more com- pact groups situated in the vicinity of one or more specially selected points of the territory. 2. As a step of the solution,-we take only the optimum ,position of each object relative to those already located on preceding steps rather thah-any position, The authors present:a detailed analysis and geometric Mustration-of*an example with four objects for the'exact and two approxi- mating,methoda. Remarks are presented.on. storage sconogy In.'the computation 2/2 USSR NIKOIAYEV K. G., PLUZIINIKOV, L. N. "Application of the Method of Branches and Bounds to the Placement of Enterprises in an Industrial Center" Inzh. mat. metody fiz. i kibernet. [Engineering and Mathematical Methods in Physics and Cybernetics -- Collection of Works], No 2, Moscow, Atomizdat Press, 1973, pp 107-118 (Translated from Referativnyy Zhurnal - Kibernetika, No 8, 1973, Abstract No 8 V569 by Yu. Finkellshteyn) Translation: The problem is studied of selecting the optimal version of placement of a fixed set of enterprises in a given area. The area may have arbitrary shape, the entMrises are shaped as rectangles, It is not excluded that there may be areas where construction cannot be Undertaken. The goal function is the sum of the components representing the nature of the,terrain,(situation), cost of connecting~lines (connections) effective- ness of cooperation and blocing and compactness of placement of the objects. An algorithm in branches and bounds considering the specifics of the problem and two approximate modifications of the algorithm are suggested for solu- tion of the problem. In order to reduce the number of branches, the authors USSR NIKOLAYEV, K. G., PLUZHNIKOV, L. N,, Inzh. mat. metody fiz. i kibernet., No 2, Moscow, Atmoizdat Fress, 1973, pp-107-118 utilize two simplifying assumptions. .1. The optimal solution is achieved if the objects are place in one or a few compact groups around one or a few specially points in the territory. 2. Each step in the solution using the method of branches and bounds consists not of arbitrary placement of some object, but rather of its optimal', placement relative to the objects already placed in earlier steps. An example with four objects is discussed -in detail and geometrically illustrated.for the precise and to approximate methods. Certain considerations are p.resented concerning savings of.machine 'Memory require d for calculation. 2/2 -ill t Wo I I