SCIENTIFIC ABSTRACT SHNEYERSON, YA.N. - SHOKOL, V.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002203010002-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

P. W. et al. TEKIMIKA BOL'SIII M IVPUL SANYKH TOKOY I
DASHLIK
,
POLEY, Moscow, "Atomizdat", 1970
C h a p t e r 1. Schemat ic Ci-rcuits of Iligh-Current Pulse Generators 12
I.I. SchemaLkic Circuits . . . . . . . . . . . . . . 12
1-2. Circuits With Load-Shorting (Crowbar) . . . . . . . . . . . 23
Refere nces (12 titles) . . . . . . . ; . . . . . . .. ... . . . . 27
Chapte r 2. High-Volt-age Pulse Capacitots . . . . . . . . . . . .. 28
2.1. S ecial Recuirements f0or the High-Voltvge Pulse Capacitors
P
Used in Current Pulse Generators . . . . . . . . . . . . . 28
2.2. Characteristics of Basic Insulating lVaterials t-.-.t
of --LO4-10, 11Z . . . . . . . . . . . . . . . . . . . . 29
2.3. 0 Conditlo,is oil Cnpacitol, jni~ulation Cv-bjectuod to Re -
P
peated Oscillatonj Discharger . . . . .. . . . . . . 311
24h. Inductance of Ca-pacitors . . . . . . . . . . . . . . . . . 4't

2.5.
VnerMr Lozse~, in Pulre Capacitors . . . . . . . 65
2.6. Fz&perimenta-l DeterLdnation of Capacitor Characteristics 73
2,7. !!~.,pes o'L Fuji;e Cupacitors and Their Strut,-tural Elements 76
R e f e r ~~ n c c s 7 t i_ . . . . . . . . . . . . . . . . . . . . 101,
C
a P t C
h

07
3.1. . . . . . . . a07
3.2. of Vaeutzxn Dit;cIiari7crt; . . . . . . . In- ol
3 3 . . . . . . . . . . . .

T 'NITTYKH
11. et al., TEKIMIKA BOL'SU1101 UVULISINY1,11 TCKOV I MAG
POIZI, 140scov. "Atonizdat", 1970

3-h.
Delay in Breakdow-n of Vacu= Dischargers . . . . . . . . . 120
3.5. Distribution of Current in a Vacuum Dischzn~rger . . . . . . 146
3.6. Durability of a Vacuum Discharger . . . . . . . . . . . . . 153
3.7. Construction of Vacumq Dischargers . . . . . . . . . . . . 156
References Oil titles) . . . . . . . . . . . . . . . . . 173
Ch ap t e r It. Dischargers at Atmospheric Pressure . . . . . . . . . 175
4.1. Basi2 JA-%sturipticns . . . . . . . . . . . . . . . . . . . . . 175
4.2. Frincip"es of Controlling Spark Dischaxgers . . . . . . . . 178

4.3.
Triga-trons . . . . . ... 194
14 Cascade Dischrrreers . . . . . . . . . . . . . . 216
4.5. Electrode Erasian Accompanyin~, Cotmmutation of HiGh-Current
Pulses 222
Refere n c e s (Oh tltleL) . . . . . . . . . . . 228
C h a p t e r 5. ffigh-N-Oss-ure Dischargors . . ... . . . . . . . . . .
5.1. 71~,Tlcal Peculiaritics of the Dischargers wid I'leld of Appli-
c a, i On . . . . . . . . . . . . . . . . . . . . . . . 232
. . . . . . . . . . . . I . . . . . . . . 233
'5-3- of and Delay in Flrin,,, of 23)6
V6

J14
ASHUYL, P. It. et al THMIKA BOLISHIMI IMULITIM.1 TOKOV I MAG111TUIXF
POIEY, 11.1osecru, "Atopliz&LIL", 1970
5.4. Max-acteristics of a Spark Channel and Fnerf3y PZelease 241
5.5. Structural Elements and Some Peculiarities of Operational Use
of Compressed-Gas Dischargers . . . . . . . . . . . . . 2117
Refere nces (37 titles) . . . . . . . . . . . . . . . . . . . . 254
C b a p t e r 6. Sol id -Dielectric Discharg
gers . . . . . . . . . . . . .
256
Re f:~-re ne es (8 titles) . . . . . . . . . . . . . . . . . . . . . 267
C h a p t e r 7. .1ii-sulation of CUrrent Pulse Geno-rators. lxw- 111dUCtance
Cables . . . . . . . . . . . . . . . . 268
7.1. Design i.,'odi fi cat ions of Connecting Elemr!nts in Current Pulse
Generators, and Requirements for Insulating, tham . . . . . 268
7.2. Some General Characteristics of Insulation of Ccnne~ting Ele-
Ments of All ','~Tes . . . . . . . . . . . . . . . . . . . . 269
'7.3. Discharree lroltares Over the Surface of Insulation 278
7.11. Cons t nict, ion of Individual Sections of the Ins-ala-ticn of Cor-
necting Elernentz, mid 'their Discharge Characteristics . . . 281
7.5. Lou-Inductance Cabl(,s . . . . . . . . . . . . . . . . . . . 286
7.6, Cable 'Zt-n-m-drial.: . . . . . . . . . . . . . . . . . . 296
. . . . . . . . . . . . . . . . . . . . Ki

DASHUK, P. 11. et al., TEIKETNIKA BOL'SHIKH IIA-PULISNYK-111 TOKOV I MhO lIUM17
POLEY, M'oscow, "Atemizdat", 1970
C h a p t e r 8. Calculations of Current Pulse Generators . . . . . . . 30h
8.1. Computational Schene . . . . . . . . . . . . . . 3o4
8.2. 1'undamentals of an Approxinate 1,%thod of Calc-ulating the In-
ductamce of Flat Busbars . . . . . . . . . . . . . . . . . 307
8.3. Cale-,daating the Inductance of Busbars When Current is Supplied

. . . . . . . . . . . . . . . .
Along the Periphery . . . . 319
8.4. Calculating the Inductance of Current Pulse Gererators With
Cable Connect,ion Between the Capacitors and the Central Buses 328
8.5. More Frecine Colculation of the'Dischaa-ge Modc of a Current
Pulse Generator Ulith Flat Busbars . . . . . . . . . . . . . 330
8.6. Calcidation of t1le Resistance of Flat Lu;5b-nr::; and the Electra-
dynai,.:ic Forces Acting on the Busbars . . . . . . . . 33"
8.7. Conditions of Parallel Operation of Dischargers . . . . . . 336
R e f e r e r C c s (21 titles) . . . . . . . . . . . . . . . . . . . . 3118
C h a p t e r 9. Types of N1 se airnnt Gen,erators . . . . . . . . . . 3L9
9.1. Currimt `ulse Generators . . . . . . . . . . 3L'9
9.2.
j Currf~mt "u1se G,-, er tors . . . . . . . . . . . .
n a
377
5 16

FM
ASIIIJK, P. N. et al., TrXIMIKA- BOWSHIP-9 DIPUL'SNYMI TOKOV I MAGNI11"YKE
POLEY, Moscow, "Atordzdat", 1970
9.3. Auxiliary Devices Used in Current Pulse Generators 381
Refere rces (29 titles) . . . . . . . . . . . . . . . . . . . . j9h
Chapte r 10. Produciil,' Strong 1,11agnetic Pulse Fielcls . . . . . . . -396
10.1. Field of Application of a Strong Magnetic Pulse Field. Basic
Types of Solenoids and Tlieir Peculiarities . . . . . . . . .
39'
10.2. Requirements for the FnerU Sourci. . . . . . . . . . . 04
10-3. Calculations of the M-agnetic Fields Of Solenoids hog
10.4. wid Cawiitruc Lion of Solenoids for Producing
Strong Magnetic Pulse Fields . . . . . . . . o . . . . . . L4 32
10-5. Ifeat Characteviz;tdics of Coils for Obtainbig StmnC~, Ful5e Mag-
netic Fieldz . . . . . . . .. . . . . . . . . . . . . . . . 4.45
10.6. Singular-itics in the Operation o- Single-Turn bolem-Ads in
Superstrong I'llagnp-tie Fiel&p . . . . . . . . . . . . . . . . h,16
R e f e r e n c e s UK-, titles) . . . . ... . . . . . . . . . . . . . . 466
616
CSO: 10 n. END
P't 9
71 7~7

Acc. Nra. Abstracting Service: Ket. Uode:
INTERNAT. AEROSPACE A6ts-'r o
AVO
rA70-25120 P Investigation of the rapid exprision of thin-
walled metal cylinders in & itrong magnetic field (Issledpwanie
bystrogo rasdiirenii3. tonkostannykh metallicheskikh tsiliodroy v
sil'nom magnitnom pole). V.~P. Knia?e and G.,A Shnee n
(iepingradskii PalitekhnicheO-,ii Iristitut, Leningrad, fffln"iblr~~`al
Tekhnicheskoi Fix.~ki, vol. 40, Feb. 1970, p. 360-371. 18 refs. In
Russian.
Experimental investigation. of the high-speed fl-:formaiion of
thin-walled alurnimim-alloy cylinders under, the aclion of pulsed
magnetic premre- High-speeti streak camera oscillooraphy of (he
magnetic field is used to determine the instantaneotir. values of the
prepure and the behavior of the deformalion. It is 3hown that
Maxwell's model of an elasteplastic body with an eliplicit rtlation
bet"?p, relaxation time, sqrVse ;s. and, temperaiure picrjides the best
approximation to the experimertif data obWned. V.P.
MEL/FRME

1/2, 014 P7 OCESSING DAT; -13NOV70
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FRACTI&NAL PKECiPITATIDN -U-
AUTliu-R-(o4)-KRASK0VSKlY, G-1-v LESHCH p YU., FRUMINA, L.M., SHNEYERSONP
COUNTRY OP INFO-USSR
-SOURCE-TSVET. METAL. L970, 43(3), 32-3,
DATE PUBLfSHE'o----- -70
S U Bi E C TA4EAS- CHEMSTRY
TOPIC TA%'JS--CHE,*A-.ICAL SEPERATIONt AMMGNTAv AQUEOUS SOLUTION, COBALT,
NICKELt 'CHEMICAL PkECIPITATIGN
CONTaGL MARKING-!N0 RESTRICTIONc
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UNCLASSIFIED, PROCESSING DATE-20NOV70
r12 018
-ITLE ON
--w-MULECULAR KINETIC THEURY OF THE PROPAGATION OF ULTRAS IC WAVES IN
-U-
I Q U LIC S,
~:AUTHOR-~ SH.
,CCUNTRY: CF INFE;--USSR
.,:.SOURCE--DGKLo AKAC. NAUX TADZH. SSR. 1970f :13 -1) 119-f2 1
"CATE zPUBL I SftED-----70
S U B J E C-T AREAS-PHYSICS
-PIC --MOLECULAR KINETICS#: ULf,RASUNIC WAVE PROPAGATION, 14ATHEMATIC
TAGS
C
-ABSORPTION
ANALYSIS,
CENTRGL MARXlhG--NQ RESTRICTIONS
DGCUMENT CLi4SS-UNCLASSIf- LED
:?KOXY REEL/FR~,ME-199611633 STEP NU--UR/0425170/013/001/0019/0021
-AT0118612
CCE
sim

.2/2 018 UNCLASSIFIED n6CESSMG OATE--20NOV70
CIRC ACCESSICN NO--AT0118612
-.A6STRACTlEXTRACr--(U) GP-0- ABSTRACT. THE QUANT-. INVESTIGATION OF
PROPAGATIGN AND AUSORPrIGN OF ULTRASCNIC WAVES IN t,IQS. WAS CARRIED OUT
ON THE 6"l-SIS OF EQUATIONS OF MASS, PULSE, AND ENEAGY CCNSERVATION. THE
VELOCITY AIND ABSORPTION COEFF. OF ULTRASONIC WAVE-S,:IN L.IQS. DEPEND
STRCNGLY CN FREQUENCY AS A RESULT OF THE FACT 'rHA'I*'YHE PROCESS !S THE
IMPOPTANT ONE ONLY IN A CERTAIN FREQUENCY RANGE. THE DERIVED
EQUATIONS ARE GENERAL FORMS OF WELL KNOWN EQUATIONS OF CLASS[CAL AND
RELAXATIUN THEORIES CF PROPAGATION ANOiAUSD~IITIONICIF ULTRASONIC WAVES.
FACILITY: TADZH. GUSUNIV. IM. LENINA, DUSHANBE, USSR.
I A -L k: I I-

Pesticides
USSR UDc 632. 9 51: 542 .432
REZb-N,ENXO, 0. A., TIZETIYAK, M. ..L SHOKOL3
G V. A., InsLitute of
Organic Ch-=istry, Academy or Sciences or the b!'cFS3R
ItIdentification and Ouantitative Determination of Domuphos in
Water"
Moscow, Khimiya v Sel'skom Khozyaystve, Vol 10, No 5, 1973, pp 44-
45
Abstract: A method is given for determining Demuphos (dimethyl-N-
methylisopropyl urethane phosphate) in the water of reservoirs and
effluents. The Dciiiuphos was extracted with carbon tetrachloride.
A 3:1 hexatic-acetone mixture (Rf=().53) 'tira,-I USC(I to identify WIC
chemical in water. The sensitivity of the chromatn graphic method
is 7.5.10 2/1g. Quantitative determination of Denuphos in water
is done by the method of ivet combustion analysis with potassium
persulfate followed by colorimetric determination of the phosphorus-
molybdenum complex.

USSR UDC 541.67
)MG0ROV YU. F., KISILENICO, A. A., and SHOKOL, V. A Institteve of Organic
Chemistry, Acad. Sc. UkrSSR, Kiyev
"IR-Spectra and Structure Of Phosphorus IsocyanatesIl
Moscow, Zhurnal Strukturnoy Khimii
V01 14, No 2, Mar-Apr 73, PP 210-245
Abstract: Continuing the studies of the Characteristics of chemical structul-e.
of phosphorus isocyanates, calculations have been carried out of the frequencies
and forms of normal vibrations and the.force field has been analyzed of a model
molecule C12P(0)NTC0, the results being correlated with the IR spectral shifts
of the assyretric valence vibration frequency of the NCO group. An increase in
the force constant of the P-N bond and the-characteriBtics of,the changes in the
IR spectra of phosphorus isocyanates can be interpreted on the basis of the
participation of higher orbitals of the phosphorus atom in bond formations.
Vi

USSR UDC 632.95
PROTOPOPOVA, G. V., REYDALOVA, L. I., DZYUBtO. A. D., MQLXA~~q, L. I., DOROSH-
UKO, V. V., NIIUIAYLYUCHENKO, X. K., SHOKOL, V. A.., DEPRACH, G.
"Insecticidal Activity of Esters of bis-0-ary1carbami,do) phosphoric and
thlophosphoric Acids"
Fiziol. aktivn. veshchestva. Resp. mezhved. sb. (Physiologically Active
Materials. Republic Interdepartmental Collection) , 1972, vyp. 4, pp 9-11
(from RZH-Khimiya, No 5 (11), 1973, Abstract No 5N579)
Translation: A study was made of the insecticidal activity of esters with
the formula ROP-(X)(NHCO,1T11R')2 M (X = 0 or S; R = alkyl, aryl; RT = Ph,
C014SCr1-Tr, ct-pyridyl) for rice weevils, housefly larvao, and.iiiiago and
greenbugs. Thc I containing the SCU-Sroup have the hij,,hest insecticidal
activity, and awag them the activity rises on going frow the meLhyl to
the propyl and isopropyl radicals.
WJ4 "A", WAR WIP.-MME MW

USSR UDC 632.95
PROTOPOPOTIA, G. V., DZYUBAN, A. D., REYDALOVA, L. I., GQ~JK
C. ~A. ,and
SHOKOL, V. A.
"Insecticidal and Acariasicidal Properties of the Es ters of Ph,:,svhazo-
methylphosphonic Acid"
Fiziol. aktivn. veshchestva. Resp. mezhved. sb. (Physiological Effects of
Compounds, Republic Interscience Symposium), Vyp 4,. 1972, pp, 11-13 (from
Referativnyy Zhurnal -- Khimiya, No 4(11) ,1973, Abstract No, 4X603 by
T. A. Belyayeva)
Translation: The esters F of phosphazomethylphosphonic acid under laboratory
conditions demonstrate insecticidal- and acariasicidal propertics of a contact
and systemic nature. Of the wilpounds studied, MeP(O)(OEt)N=P(OisoPr)3
compound 1) showed the stronget:t contact effect -- SK50 1.78 in 3 days
for rice weevils and 0.39 for grain aphids, Contact insecticidal activity
was increased by uring iso-Pr in tae trialkoxyphosphazo group. Comp. I in
a 0.05% concentration results in 96% mortality of the mite Tetranychus
urtical on the second day,

IJSSR UW 547-26,118
GONMKAYA, YE. S., GAMMA, V. F., and SHOKOL V. A., institute of Organic
Chemistry, Academy of Sciences Ukrainian"aw
Ito
S-P -isocyanatoethyl dithiophosphates"
Leningrad,, Zhurnal. Obshchey nimii, Vol ~2 (1,04), 116 9, E;e'3 72, p 2112
Abstract: The title compound can be obtained by intranolecills thermal isoineri-
zatiOU 04-6 0)0-dialkyl IS-(K-ethylenecarbomoyl) dithiophosphates or by the Curtius
reaction from 0,0-dialkyl 8- azidocarbonylethyl) dithiophosphates.

-M
USSR UDC 547.264118
SHOKOL, V. A., and,KOZHLGHKO, B. N., institute of Orgwdc Chemistry of the
.Acmmb~y-o?'Sciences Ukrainian SSR
"Ethoxyfluorophosphonylchlormothyl- and Bis(ethoxyfluoiophogohonyl)methyl
Isocyanates"
Leningrad, Zhurnal Obshchey Xhimli, Vol 42 (104)~ Vyp ID, 1972j pp 2y;6-2347
Abstracti The reaction of diethyl fluorophosphite with dichlormathyl iso-
cyamate without a catalyst yielded either othoxyfluoropboso-olionylchloro-
methyl ittocyanate (I) or bis(othoxyfluorophcephonyl)methy1 isocyanate (II)
depending of tI-j ratio of reagentas
+ F(C21140)1)(OpICI \ c0
C1,CIIVeo-
2(Cjf,O),PF jF(C2"TP)')(O)I2C I IN C
20 20
The yield of (I) was 27,4t btPI- 46-400C (0-05 mm)t d~ 1,39551 "D 1043280
20 20
~The yield of (II) was 30%, b.p. Bi-8)C (0,05 mm), d~ 1.3813, '~D 1.4250.
ZmpJxical fornulas for (I) aM (11) arei C4H6CIFNO P and F P,
respectively. 3 C6HII 2N05
IA

USSR UDC 547.241
SHOKOL, V. A., GOLIK, G. A., LEVCHUK, Yu. N., YEGOROV, Yu. P., and
(Deceased), Institute of Organic Chemistry, Academy of
Sciences, UkrSSR
"8tructure of the Reaction Products of Amidoesters of Alkylphosphonic
Acids.Wita Phosphorus Pentachloride"
Leningrad, Zhurnal Obshchey Khimii, Vol 43(105), No 2, Feb 73, pp 267-274
Abstract: Reactions of phosphorus pentachloride with the amides of ethyL
and aryl esters of methyl-, chloromethyl-, dichlorow-,thyl-, and trichloro-
methyl-phosphoric acid were studied in'an attempt to determtne under what
conditions isometic products could be obtaini-d. Analyzing the products
by the IR, NMR31p, and NMR 1H spectroscapical methoda, it was shown that
depending on the alkyl radical attached to the phosphorus atom, the
reaction products could either be trichlorophosphazoalkylchloro- and
alkylaroxyphosphonyls, or their isomers,-- alkyldichloro- and alkyl-
aroxychlorophosphazodichloraphosplionyl$ or their mixture.
30
WIII

USSR UDC 546.185
SHOKOL V A., MOLYAVKO, L. I., MATYUSHA, A. G., MUGLANLYUCHENKO, N. K.,
M, G. I. (deceased)
and UhAKA
"Diisocyanates of Phosphorus Thioacids"
Leningrad, Zhurnal Obshchey Xhimii, Vol 41, No 11, Nov 1971, pp 2,380-2,383
Abstract.- Twenty-four derivi~tives of alkyl- and aril diisocyanothiophosphates
ROP(S)(NHCOR')2, and the diisocyanate of pheny lthiophos phonic acid, were
synthesized by reacting alkyl- a-ad aryl diisocyanophosphites and diisocyanate
of pher., -( ~lphosphonic acid with lihosphorus. thiochloride. The isocyanate groups
of' these compounds were fcund to react with substances containing active
hydrogen atoms. Details oi experimental procedures and tables of physical
constants are given.
1/1
i:-.. I i -A
55 UK--
21 '1 ".TIL'
ROMMUMMen ME IM ~ '- -., I I, I I I I M; b I UP: M I H NI
EM '" Iffitt

USSR UDC 546.185
SLYUSARENKO, Ye. I., MLMIAYLIK, S. K.,, GMIALETA, V. F., and QSLQ&_V _A.
Institute of Organic Chemistry, Ukrainian Academy of Sciences
"Derivatives of Isocyanatcphosphoryl Dichloride and Diisocyanatophosphoryl
Chloride"
Leningrad, Zhurnal Obshchey lUiimii, Vol 41, No 11, Nov 1971, pp 2,383-2,386
Abstract: The dialkyl esters of alkoxycarbonylamido- and ureidophosphoric
acids have contributed a number of substances with insecticidal and complex-
ing properties; this suggested the synthesis the monoalkyl esters of these
acids. Alcohols a-ad aniline, and also alcohols in chi, presence of triethy-
lamine ard water, end triethylamine alone, react with IsocyanatophosPhoryl
dichloride; this produced the monoalkyl esters of alkoxycarbonylamide- and
3-phenyluretdophosphoric acids. Alcohols, mercaptans, thivphenols, and
aniline react with diisocyanatophosphoryl chloride to form the acid chlorides
of bis(alkoxycarbonylamido)-, bis[(alkylt-hio)carbonyl,!Irr-ido)-, bis[(phenyl-
thio) carbonylamidoj- and bis(3-phenylu-reido)phos-phorie- ac-ids. n. e hydrolysis
of these substances yields free acids. Sixteen compo;.inds were synthesized.
Prc~cedures: of synthesis ara giveno alonk:with some physical data on the
esters.

USSR UDC 547.26'118
MOLYAYEKO, L. I., and DERKAM, G. I., 1xistitute of Organic
-Chemistry, Ukrainian Ac3demy of Sciences
"Alkyl Esters of Alkoxy-B is (dime thy lard.do) - and Dialkoxy (dine thy lamido) car-
bonic Acids"
Leningrad, Zhurnal Obshchey Khimii, Val 41, No 11, Nov 1971, pp 2,379-2,380
Abstract: As part of their work on synthesizing and studying the insecticidal
activity of the N-phosphorylated derivative amides of carbonic acid, the
authors synthesized the alkyl esters of alkoxy-bis(dimethvlanido)- and
dia:Lkoxy(dimethylamido)plioEipliazocarboni.c arids frora thrt azides of the alkyl
esters of carbonic acid and the alkyl b4p (dime thylamido) - ind dialkyl (di-
methylamido)ptiosphites. The previously- unknown isopropy b is (clime thyiamido) -
phosphite was also obtained. Physical constants and yields of these sub-
stances are given.

USSR
DOROSHENKO, V. V., KOZHUSHKO, B. N., SIUKALO, Ye. A., and
"SSR
Institute of Organic Chemistry, Academy df Scien ces of thAR
"Dihalophosphonylchloromethylisocyanates"
Leningrad., Zhurnal Obshchey Khimii, Vol 42(103), No 2, Feb 72, pp 484-485
Abstract: Dichloromathyl isocyanate reacts with alk-yl difluora- and
dichlorophosphites to form dJ.fluorophosphonylchlorometliyl isocyanate (I)
and dichloraphosphonylchloromethyl isocyanate (II).
2X
C
(HCOAc)n + P(oc2H5)3 + (H5C20)JOC-Z-02
CH2OAc JoAc)n
2uac
III'Iv
(I) X==Cl, n==4, D-galacto; (11) X-Br, tL-=3, -L-arabino.
1/2
---- - 56

USSR
DOROSHFMO, V. V., et al., Zhurnal Obshchey Khimii, Vol 42(103), No 2, Feb 72,
pp'484-485
Isocyanate (II) is synthesized by chlorination of dichlorophoSDhO-.Iylmethyl
isocyanate (III) in the presence of UV-radiation.
Cj.P(O)C11,NCO C" I COCI 1C7TT')JN. if
--* C12NOPIPW I
The structure of compounds (1, 11, IV) was confirmed by IR-spectroscopy.

USSR UDC 547-26 n8
SHOKOL V. A*j DOROSHENK0, V. V., DERKACII, Go I. (DECEASED),
ffitute f Organic Chomistry, Kiev,' Academy of Sciences
0
Ukrainian SSR
ITR tion of Ghloromothylisocyanate With the Salts of,Thlo-
GAO
horia and Thioearbonic Acidall
h
P cap.
Leningrad, Zhurnal ObahShRy IC41mii, Vol 40, No Aug 70,
pp 1692-169V-
Abstract: Reaction of chloromethylisocyanato with potassi un salts
of I-diallcylthlo- and dll;hiophosphorle acid3 yiolds 0,0-dialkyl
S-isocyanatomet"'iy11"hio- and -dithiophosphates, avd. witb L-bo
potassium salt of 0-athyldithiocarbonic acid, 0-athyl-S-isocyanato_
methyldithio carbonate. Chloromethylisocyanate in arflxydrous bon-
zone is added dropwise to a 3olixtion of the potassiinn salt of
0,0-diethyldithiophosphorio acid in anhydrous bow%ene at 200 and
refluxed for _5-10 hours. The precipitate is aeparated, the filtrate
evaporated, and the residuftl 0.0-dial*kyl-B-isceyEinatothio- or
dithiophosphates are radistilled. p-Chloromotliylplion,,rlisocyanate
in benzene is added to the potassimi nalt of 0, 0.,, dime Lhyldithio-

USSR
SHOKOLI V. A., et al. Zhurnal Obshchey Ehimil, Vol 40, No 8,
Aug 70, pp 1692-1696
Pho3phoric acid in benzene and refluxed for 11 hours, the precipi-
tate is contrifuged and +he filtrate evaporated Co give a product
with b.p. 75-760/1=a, ng6 1.5668. Th 0 tk 1-S- Booyanatomethyl-
- 70-71/0 1 io ~'2'162v. 1-5536 is
dithiocarbonate, b.P .2
obtained analogously to 0,0-dialkyl-$IisocyapatoLieth5-IthioDhGsnhate.
To obtain 0,0-dialkyl-S-(carbalkoxyam nomethyl)-dithiophosphates, a
solution of anh7drous alcohol in absoluto other Is added dropwise
to a solution of 0,0-dialkyl-S-isocyanatoinethyldithic,pbosphate in
absolute other, stirred, and after 16-20 hours Cllie solvent is re-
moved at 10-15 mm, and the residue is kopt at 0.2 rrm (40-500) until
constant weight. The 0,0-d.ieth-yl-S-(oarbalkoxyaimincmiethyl)-
thiophoaphaton and 0-othyl-S.(oarbalkoxyaminomatkql)-dithioearbonates
are obtained analogously.

VSSR 547.26illB
S52601A. V,.A., GOLIK, G. A., TSYBA, V. T., YEGOROV, YLT
:DERKAGH, G, 1. (DECEASED), Institute of, Organic, Chemistry, Kiev,
'Ukrainian SSR
Academy- of Sciences
"Phosphoazoalkylphosphonic Acid Esters"
Lefiingradq Zhurnal Obsh2bgy Rhilrii, Vol 40, No 8, Aug 70.
p 1680-1691
P
stract: Reaction of trialkylphosphites, triamidopho.,3phitos,
Ab
diallcyl- and diamidophosphonites, and triphenylp).-ioxphine with the
azides of alkylphosphonic acid osters yiold3 esters of phoaphazo-
alky1pbosphonic acids -- compounds with pest;-icida-l aetivity. The
reaction is exothermic and occurs easily at room temperature either
n:ether or in benzene. Af tar evaporation of the solvent, licraid
phosphazophoapb-4r-rla aite obtained. Dopending on heating conditions,
the esters of trialkyl- and nothyld:Lall.-ylpho&pYLa.'zoalic7lpliosphonic
acids rearrange into diesters of the allry1dialkokyphosphazo-
osphoric aold or into eaters.of N-alkyl-N-dial.kylpliosphononmido-
ph
alkylphosphonio aoid. In all oasesUe side.prOucta consist of the
112

USS11
SHOICOLO V. A.,, et al, Zhurnal Obsht~hey~ltizli, Yol 40.? No 8, Aug 70#
pp 1630-1691
diethyl ester of methylphosphonic acid and a yellow, viscouz3 fluid,
probably polypho3phorene formed by condensation, Detailed analysis
of the IR and ITMR spectra of tho above compoundaq is reported and
characteristic bands and shifts are listed.: Pblysical properties
of~the products obtained are tabulated, but no biological data a-ve
reported.
2/2
50

USSR UDC 547.241
V- GOLIK, G. A. and DERKACH.,.G. L, (deceaned), Institute of
Organic Chemistry, Academy of Sciences Ukrainian SSR
"Azidoisocyanate of the Methylphosphonic Aidid and Its Derivatives"
Leningrad, Zhurnal Obahchey Khimii, Vol 41 (103), No 3, Mar 71, pp 545-550
Abstract: Reaction of chloroanhydride of metbylphosphonic acid azide wit') a
suspension of sodium cyanate in chloroform yields the amido-socyanate of
methylphosphonic acid W -- a colorless liquid with a sharp odor. Reacting
(I) with alcohols, phenol, and aniline yields the azideB of caTbalkoxy- and
carbophenoxyamides and phanylearbwaide of merhylphosphopic acid which, when
reacted wit1i phosphites mid phosphine give corresponding carbalkoxy- and
carbophenoxy.-=ides, and phenylcarbamide of (P-phospbazo)-methylphosphoaic
acid. IR spectra of these azides exhibited.an intensi" band at 2158-2179
~-CM7-1, characteristic of the azido group.
45

USSR
UDC 547.261118.07
SHOKOL. V. A., MIK-HAYLYUCHENWO, N. K., DERKACH, 13. 1., KY~S.' ','~OV,
A-".7V.,"rr1's-tTtute of Organic Chemistry, Kiev, Academy of Sciences
Ukrainian SSR
11A Method of Producing trichlorophosphazo Compounds"
Moscow, Otkrytiya, Izobreteniya, Promyshlennyye obraztsy, Tovarnyye
Znaki No 18, Author's Certificate No 271520, filed IS Mar 69,
p 24
Abstract: This Author's CertiCicate introduces: 1. A method of
producing trichlorophosphazo compounds by interacting an amine or
amide with a phosphorus-containing reagent and chlorine in an
organic solvent in the presence of heat with subsequent
of the goal pro4uct by conventional methods. Az a distinguLshing
feature of the patent, the process is simplified by using red or
white phosphorus as the phosphorus-containing component. 2. The
method described in (1) is distinguished by the fact-that the pro-
cess is carried out at 50-800C.

USSR
UDC 547.26,118
SHOKOL, V. A., MOLYA-MCO, L. I., NaKHAYLYUCHENKO, N. K., and.DERKACH, G. I.
Institute of Organic Chemistry, Academy of.Sciences Ukr. 33H
"Alkyl Esters of tris-Dimethylamido-, Methyl-bis-dimethylamido- ard DiaDWl-
dialkylamidophosphazocarbonic Acid"
Leningrad, Zhurnal Obshchey Khimii, Vol 41 (103), No 2. Feb 71, PP 318-~19
Abstract: The reaction of tris-limethylaniidopho--Phil-.0, methyl bis-dime-
thylamidophosphonite, and dialkyldialkylamidophosphinit,;j with the azides Of
carbonic acid esters yields corresponding~al~yl esters of phospnazoearbonic
acids.. To a solution of 0.1 g-mole of the azi-.A;,e of carbonate ester in ZO M11
of absolute other, 0.1 g-re--1e of the respective phosphate, pVoTPhonjta i-n 20
Ml of solvent is added dropwise. The reaotinn is exotbermic. After the
addition is completed, the mixturais heated for 30 min, tho solvent is re-
moved and the product is distilled underivacu um.

Oil UNCLASSIF! ED, PROCE'SSING DATE--30OCT70
,.--.1rITLE"-ACID DIHALIDES ANU MONQHALIDES Of ISOCYANATOKETHYLOHOSPHONIC ACID
-.ALKYL -ESTERS -U-
~,~.~AUTHOR-(03)-SHOKGL,s V.A.# DOROSHENKO, V.V.t DERKACfft G.I.
OF INFO--USSR
_,UURCEZH. UBSHCh. KHIM.
1970t 40(3)v 535-42 f
000,
""."'_DATE PUBL ISHED----70
___'.~-_SUBJECT AREAS-CHEMISTRY
.,..TOPIC TAGS-ISOCYANATE, PHOSPHONIC ACID* ESTERt ORGANIC PHOSPHORUS
COMPOUNDo CATALYTIC ORGANIC SYNTHESIS# CHLORINE, FLUORINEt A1410E
j_2.CCNTROL_MA9KING-NO RESTRICTIONS
-..DOCUMENT CLASS-UNCLASSIFIEO
.-PROXY REEL/FRAME--ZOOO/0896 STEP NO--UR/0079/70/040/003/0535/0542
ACCESSION NO--AP0124559
UNCLASSIFIED

W5 017 PROCESSING DATE--30OCT70
UNCLASSIFXEO
CIRC ACCESSION NO-AP0124559
ABSTRACT/EXTRACT-(U) GP-0- ABSTRACT. MIXING EQUIMOLAR AMTSe OF ROPCL
SUB2P ROPF SUB2# OR (RO) SUB2 PCL AND CLCH SUBZ NCQ IN THE PRESENCE OF
MOLE DRY FECL SUB3 CATALYST RESULTED IN A MILDLY EXOTHERMIC
REACTION, COMPLETED BY HEATING TO 45-50DEGREES TO,ELIMINATE THE EVOLVING
ALXYL HALIDE TO GIVE THE FOLLOWIING RP(O)(CH SUB2 flCOJX CX AND R SHOWN):
CLrCL 56-75PERCENT (FROM MEt ETv OR ISOPPR ESTERSIP 5 SUBOTIMES15
:59-60DEGKEESi 0 PRIME20 195744v N PRIME.20 SUBD 1.4t980; CL, ETU (1)f
37-53PERCENT,,, B SUBOTIMES3.5 82-30EGREESP 1.3334t 1-4625; CLt ISOtPROI
16PERCENT, B SUBOTIMESO.4 75-6DEGREESt 1.2664t 1.4690; Er F (FROM BUOPF
SU82)9.57PERCENT, B SUB15 68-9DEGREES, 1.5490v 1.4085; AND F, ETO (II)v
17PERCENT, B SUBOTIMES2 68-70DEGREES, 1.3002, 1.4180. ALTERNATIVELY9
HEATING EQUIMOLAR AMTS. CLCH SUB2 NCO AND EITHER ETOPCL SUB2 OF (ETO)
SUB2 PCL TO 65-75DEGREES ALSO GAVE ETCL9 BUT IN THE 1ST INSTANCE THE
PRODUCT FORAEG A TAR# WHILE IN THE 2ND CASE I WAS ISOLATED. EQUIMOLAR
AMTS4 (ETD) SUB2 PF AND CLCH SUB2 NCU WITH kCL SLli33 CATALYST REACTED AT
50DEGREES TO GIVE ETCLv 17PERCENT ETP(O)(OET)Ft 8 SUB12 50-10EGREESt
1'.1130s 1.3884; ANU 17PERCENT 11. SIMILAR REACTION WITH IC SU68 H SUB17
01 SU82 PCL 6 HR AT IIOUEGREES GAVE 75KRGENT C SQ68 11 SU1317 CLP ~*1111LE
JHF_.~AEST OF THE MATERIAL PULYMIJ. ON BEING HEATED* EQUJMOLAR AMIS.
MEDPCL SU82 AND CLCH SUB2 CH SUB2 NCO:WITH FECL S683 CATALYST REFLUXED
12 HR GAVE NO MECLt AND THER REACTANTS, WERE RECOVERED*
-UNCLASSIFIED

'1/5 OLT UNCLASSIFIED PROCESSING DATE--30OCT?O
-:CIRC ACCESSICN NO-AP0124559
..:AB~TRACT/EXTRACT-EQUIMOLAR AMTS. CL SUB2 PIO)CH SU82 NCO AND ROH IN ER
SU82 0 GAVE OVERNIGHT UNDISTILLABLE AR PRIMEI P(OJCH SUbZ NHCOR PR[ME2
(111) (R EQUALS R PRIME1 EQUALS CL* R PRIME2 EQUALS ETO)w 0 PRIMEZO
L.4560,t N PRIMEZO SUBD 1.4945; ATTEMPTEO OISTN. GAVE ETOH ANU AN
ISOCYANATE AS CONFIRMED BY THE IR SPECTRUM. REACTION OF THE CRUDE
1) ET SU83-7; ii.4 ET
~DICHLORIDES* PREPD. AS ABOVEr WITH 2 MOLES DRY ROH AN
~SU82 0 AT 50EGREES AND FINALLY All TOON TEMP. GAVE!THE FOLLOWING fill
ALSO PREP04 GROM 3 MOLES ROH, 2 MOLESIT SUB3 N AhU 1 MOLE CL SU82
O(OICH SUBZ NCO (OR.SIMILARLY FROM OCNCH SUB2 P40(011)CL) (Ro R PRIMEly
AND R PRINE2 GIVEN): F, ETOP ETOP IIIA)v 8 SUBOTIMES05 100-12DEGREESt
1.2497, 1.4368; MEO, MEG, MEOr 8 SUBOTIMES03 122-5DEGREES# 1-3250v
1.457.8; MEOv MEOt ISOrPROv 8 5UBOTIMES06 11-12DEGREESt A.1929t 1.4495;
MEOr ETO, MEO, 8 SUBOTIMES03 115-18DEGREES.. 1.2~*Gfi, 1.4525; MEOV
ISO,PRO, MEC. B SUBOTIMES05 114-16DEGREESt 1.1765, 1.4503; ETOP ETOY
ETOi B SUBOTIMES2 L31-30EGREES# 1.1516, 1.4465; AND ISO,PROP ISOPPRO*
ETG* 8 SUBOTIMES05 137-400EGREES, 1.1149t 1.4486.. EQUIMULAR ANTS. OCNCH
SUB2 P(OJ(OET IF AND ETCH IN ET SUB2 0 3 DAYS'GAvE UNDISTILLABLE IIAv.
ALSC FORMED FROM 2 MOLES ETOH IN ET SUB2 0 AND L MOLE OCNCH SUB2 P(O)F
SUB2 IN 3 DAYS.
UNCLASS IF LED

131
4/5 017 UNCLASSIFIED PROCESSING DATE--30OCT70
C-19C ACCESSION NO-AP0124559
.ABSTRACT/EXTRACT-REACTION OF I MOLE ETOH WITH THE LATTER DIFLUORIDE
.(FULLGWED BY IR SPECTRA) PROCEEDED WITH DECLINE OF NCO DANC INTENSITY
OVER 10 HR* AFTER WHICH THIS NO LONGER.TOOK PLACE~OVER 3 DAYSv BUT NO
PRODUCTS COULD BE ISOLATED inbiviDUALLY, OCHCH SU112 P10)(OCHME SU82)CL
AND 1 MOLE MEGH IN ET SU6Z 0 AT NEGATIVE IOUEGREES, THEN AT ROOM TEMP9
OVERNIGHT, GAVE AN UNDISTILLABLE MIXT. OF THE STARTING MATERIAL AND
EVIDENTLY (1509PRC)CIP(O)CH SUaZ NHCO~SUBZ ME; SIMILAR REACTIGN OF ETOH
WITH (ETOJP(O)CLCH SU82NCO GAVE ONLY CRUDE (ETO)P(UKL~H SUB2 NqCO SU82
ET AND STARTING MATERIAL, WHICH WERE 40T SEPARABLE. OCNCH SU82 P (0)F
SUB2, OR OCNCH SUB2 P(O)(OET)F, TREATED WITH I KLE PHNH SU82 IN ET SUB2
0 AT NEGATIVE 15DEGREES, THEN WARMED TO ROOM TEMP. GAVE III (R EQUALS R
PRIMEI EQUALS Rt R PRIME2 EQUALS PHNH)*,DELOMPD. 128-31DEGREES; OR III
(R EQUALS F5 R PRIMEI EQUALS ETO* R PRIME2 EQUALS NHPH), M. 93-5UEGREESf
RESP. SIMILARLYt REACTIONS WITH ET SUS2 NH-AND OCNCH SU82 P10)CL SUB2
OR OSNCH SUB2 P(OllOEr)CL, GAVE III (ft.EQUALS K PRCHEL EQUALS R PRLMEZ
-5DEGREESp 1.0711,p 9
EQUALSET SUSZ N), 8 SUBOTIMES05 152 1.4740; OP III (R
.,EQUALS R PRIMEL EQUALS R PRIMEZ EQUALS ET SUBZ N) b SUBJTIMES05
140-3LEGRtESt 1.0470, 1.4850. REACTION CF OCHCH SUB2 POCL SUB2 WITH 0.9
MOLE PHNH SUB2 IN ET SUI3Z 0 AT NEGATIVE 1OUEGREES* COMPLETED AT ROOM
TEMP., GAVE CL SUB2 PIOICH SUB2 NhCONHPHv CONTAMINATED WITH MUCH
STARTING MATERIAL AND M. 142-50EGREES; THIS CONTAINED ALSO SOMEPlAMIDE
MATERIAL# SN OCTOATE AS A CATALYST GAVE A SIMILAR RESULT. REACTION OF
FAMINES OR ALCS. WITH OCHCH SU82 P(O)(OR-)CL RESULTED IN INVOLVEMENT Of
BOTH CL-AND NCO GROUPS SO THAT PURE PRODUCTS COULD 140T BE ATTAINED.
UNC LAS S I F I E 0

........... . ...... . . ..... ......... ...
112 cy 1'~ UNCLASSIFIED PAOCES~SING DAT*E--13.NOV70
TITLE--CHLOROMETHYL AND D ICHLORGAE THY LU I.CHLOR(jPfl0.Sfh-A Z 0 '11CYLS -U-
AUTH0.R-(03)-SH0K0Lt V.A.1 GAMALEYAv V.F. t KUKHAP, P
'-7
COUNTRY OF INFO--USSR
OBSHCH. KHIM. 1970p 40(3)t 55'4-7
DATE PUBLISHED ------- 70
SUBJECT AREAS--CHEMISTRY
:_-,TOPIC TAGS--CHLORINATED ORGANIC COMPOUNOt ORGANIC PH"I)SPHORUS COMPOUNDi AZO
0,
'WOUND, CHLORIDE, NirtkILE, PYROLYSIS
C
~-CONTRGL MA rRK I NG--NO RESTRICTIONS
DOCUMENT CLASS--U.NCLASSIFIEO
PROXY REEL/FRAME--3002/1380 STEP NO--UR/0079/70/040/003/0554/0557
CIRC ACCESSION ',40--AP0128780
Ji qi~ LAS 'A Ik")

USSR UDC- 546.185
GOLIK, G.A., TSYBA, V.T., and DERKACH, G. I., (Deceased), Institute
of Organic Chemistry, Kiev, Academy of Sciences Ukrainian SISR
structure ~~f Reaction Products of Amidoesters of Alkylphosphonic
:Acids With Phosphorus Pentachloride"
Leningradq Zhurnal Obshchey Khimii, Vol 40, No 40 Apr 70, PP 931-932
Abstract: A detailed study of the reaction product of amide of ethyl
ester of methylphosphonic acid with phosphorus pentachloride showed
~that in its physicochemice.1 constants it is identical to the isomeric
product obtained by the authors from amide of diethyl ester of phos-
phoric acid and methyltetrachlorophosphorus. A comparisoa of IR spec--
31 35
tra, P NPIR ard especially Cl KWIR spectra shows that the compounds
obtained in both cases have the structure of methy1dichlorophosphazo-
'phosphoric acid dichloride CH rather than isomeric
3(C12) PCX ='KFA OG12
~trichlorophosphazomethylphosphonic acid CH PO(CI)N=PCI
3 3'