SCIENTIFIC ABSTRACT SHVEDOV, V.I. - SHVETSOV, I.K.

Document Type: 
Document Number (FOIA) /ESDN (CREST): 
CIA-RDP86-00513R002203010020-1
Release Decision: 
RIF
Original Classification: 
S
Document Page Count: 
99
Document Creation Date: 
November 2, 2016
Document Release Date: 
September 17, 2001
Sequence Number: 
20
Case Number: 
Publication Date: 
December 31, 1967
Content Type: 
SCIENTIFIC ABSTRACT
File: 
AttachmentSize
PDF icon CIA-RDP86-00513R002203010020-1.pdf4.18 MB
Body: 
.Jllti 7: Dervent, pressure iu-the-llmjt,, so,-~ ceds'gad dn be Byphoned off, (16). :- Wher,~rjllmt'r'~t~~su6ii toxic~ gases are used, lamtrai he val~Iiij (17) r Into the Jock 'and held:iot less wri ror iqual .0essuve to that in the furnace-itAOU Thip'i: co~n~j:arprtssure safely seals the furnace qontonts ftom'chj~. surrburLding 12.2.68 as 1222511122-1. MTl N, YA. I - : -677; 1 C ~ (9.9-69) Bul 14/18.4.69 468:71 2975:0454 uR o482 -~ I .. . .- I -T7!-- A .0 f1p a - ~ 17 X~,/- USSR UDC 5411.752.753.755.07:542.953 SHVEDOV. V. I., PANISHEVA, Ye. K., VLASOVA, T. F., GRINEV, A. N., USSR institute of Chemical-Pharmaceutical Scientific Research imeni S. Ordzhonikidze, Moscow "The Synthesis and Aminomethylation of 6-Hydroxyiudoles" Riga, Akademiya Nauk Larviiskoy SSR, Himiya Geterotsiklicheskikh Soedinenii, No 10, Oct 73, pp 1354-1356 Abstract: It was found that, while reaction of p-benzoquinone with 6-aminocrotonic ester or N-mel.hyl-a-aminocrotonic ester at O*C 'An acetic acid produced 5-hydroxyindoles,-the reaction of p-benzoquinone with N-aryl-0-aminocrotonic ester under the same conditions produced 6-hydroxyindoles. Thus,-the substituent on nitrogen determines whether the ester reacts at the double bond or the carbonyl group of p-benzo- quinone. Reacting the 6-hydrox-yindoles with bisdimethylaminomethane produced 6-hydroxy-7-dimethylaminomethylindoles. Bromination and nitration of 6-methoxyindoles and 6-acetoxyihdoles led to,substitution at position number 5, which is explaimed by the fact that bromination and nitration take place in acid solution, and aminomethylation In basic. Structure determination was by MIR spectroscopy. 17 Nitin~;cn CbIrpounds USSR U D 01 615-.)25.2!547.5l-~7.'~3.012.1:542.c) NT Z"I V n 0 11 c G. I -, and GPTjj 11-U j S i entific Researca Institilte of Pharmacelatical Cjjc-,7-,-Lstry i,,I-ieni S. OrdzhQnil-,':.dze, '11~oscow "Research in tne Field of XLVI II Synz.;-ie,~,is of Do- rivaLives of 2-3'enzyl-5-oxyindole. and 2-L-~etizyl-5-oxy'-Venzi-~idole"- Moscow, Khi-miko-Far:r~atsevtlichesi-.iy.Zliurnal~p 1.161 4, LIlo 9, Sep 70, pp 7-12 Abstract: T.he &rtui cle sui%r---ts a, metimdA fo~, f th 5 i .I CD deriv--i-I.Aves of are in th-, synthlesi3 of aralogs ol" ~eroi-.anin, The are obzained b7 ~f P-bolnzoqui.IMII,114~! or quinone witz.. the metji-i ester of -substituzed or urisubs V N u t ~ t ud ac! C& P Q iethy*;~;tion fIQ ~erlvaLivcs with GIrnt-thyl 3!)-71 .4,1 an solur.-ion t110-4 to derivatives of and 2- benzY1-3-carIbu ei;i~o y->-methoxybenzindole. Hy~`I-Qly:3L5 of rhe -0, USSR KV F-,) o v v et al. pp, Ihurr~aj, 4 0 latter Ei7es ca- bOXY-5-r,-,ethoxy-t, IR 2 -1, e co:"Younds. Llcctl-a tal1cf-Ill Of t. .7'It 2/2 34 USSR UDC 615.214:547.759 MASHKOVSKIY, If. 0., GRINEV, A. N., ANDREYEVA, N. 1.1 SWIEDOV, V. I., and ALTUKHOVA, L. B., Laboratory of Pharmacology and Laboritairy of-S~ntbesis, All-Union Scientific Chemical-Pharmaceutical Research Institute imeni S. Ordzhonikidze, Moscow "Investigation of the Psychotropic Activity of 1,10-Trimethylenepyrazino [1,2-alindole" Moscow, Farmakologiya i Toksikologiya, Vol 34, No 4, Jul-Aug 71, pD 387-391 Abstract: Five novel derivatives of 1,10-trimetliylenLpipera;,,inofl,2-a]indole (I) and two derived from l,"LO-trimetliylenepyrazinofl,2-aliftdole (N) were studied in respect to their psychotropic activity (reaction to the effect of phenamine and reserpine on mice and rats, cataleptic activity of these materials on rats, their effect on body temperature ,:.nd overall state of The derivatives of (1) were found to be more active, especially those without any sub.-3tituents in the ring, those vith a methoxy group in position 8 and ot-thyl group in 2 and 8 po~~sitfon of tl~ie heterocycle. 13,; rheir.activity these substances resemble the of tile tri- cyclic structural type such as imizines. DeriVativiis of (11) exhibIted it 1/2 USSR MASHKOVSKIY, M. 0., et al., Farmakologiya i Toksikologiya, Vol 34, No 4, Jul-Aug 71, pp 387-391 definitely lower activity. Ttansition,from a tertiary amine derivative of (I) to a quaternary amine lm-yered its activity. 2/2 TJSSR UDC 547.661.31752 N., All-ITnion I., ALTWHOVA, L. 3. and GTZ I N M-T Im ti tu te imenil S~Prgo gcip~t7ific !Zesearch Chemico Pharmacieutical Ordzhonikidze, Moscow, Ministry of Health USSR 'IN-Acyl and N-Alkyl Derivatives of 1, 10- Tr im e thy LP n e p ip e ra~' i no (1,2-0indole" Mos~co-, Khimiko-Farmatsevticheskiy Zhurnal, Vol 4, No 7, L97o, pp 5-7 Abstract: "Iethods were developt-'.d for synt4esiu-inf! the N-aUyl and N-acy! drrivatives of piperazino9l,2-a)ird,Af-, W11-11'.Ch exhibits antihistaminic and hypatensive action. T'hf, 1,17-acyL derivatives (7-TIJ) were obtained by acylation of piperazino(1,2-a)indole with acetic anhyd-ridle nr acid chlorides. Al~ylation of dprivatives of piperazino(3,;2-.-.)in(InLP by oi-dinal'y C~ C, -i ds . 'I-la - alkylating agents occurs with complicatIons at ,-I. le-- to I'or - tion of resinous products. N-alkyl derivativ~,s can be obtained by indirect methods. Hydrogenation of iodomethylates (VII and, VIII) over skeletal nii-.kel catalyst leads to the corresponding N-methyl derivatives UK ad X), while reduction of "it-acetyl-8-methyl-1, 10-trimethylenepipera--ino (1,2-0indole(l) with lithium aluminum h%'tjrj(je Vielda the N-ethyl derivotes (xi). US SR SHVEDO V, V. I., et al., Khimiko-Farmataevticheskiy Zhurnal, Vol 4. No 7, 1970, pp 5-7 I Z~ f.;j I X4 2/2 ANN 11-2~' all IJNCLAS,~tF PPOCESSTING 0ATE-13NOV70 :~',TITLE--OIALKYLAMINDALKYL DERIVATIVES OF INDOLE Ott TETr.AHYf)rWLAi-~bA10LE -U- AUITHOR-1 03)-iiiVE0~0VpVI GR 1 NEV, A.N., ALTUKHOVA, L.B. CGUNTRY OF INFO-OSSA :-SOURCE-USSR 265ta65 REFEAENCE-UKRYTIYA, IZOBRET., PROM. 084ALTSY, TOWAkNYE ZNAK I 1970'r DATE PUBLISHED-17iMAR70 '-:SUBJECT AREAS-CHE."111STRY .~JGPIC TAGS--AMINE DERIVATIVE, INUOLEi ORGANIC AZUCCOMPOUNDi HYDROXYL RADICAL, CHEMICAL PATENT CONTROL 14ARKING-NO RESTRICTIONS ~-DOCU:iEINT CLASS-UNCLASSIFIED PROXY REEL/FRAME-3002/let8l STEP NIO--IJR/04d2/70/000/OOU/C)~)00/0()00 CIRC ACCESSIWLi 1';G---AAG1Z3660 F I ED -77~ J- 2/2 OLI UNCL ASS I F t 8b: PKErCESSING OATE--13NOV70 CIRC ACCESSION Nil-AA01288dO ABSTRACT/EXTRACT-M GP-0- ABSTRACT. TITLE Cl)',IPDS ARE PREPO. BY OF 51HYDROXYMOULES OR IN TREATING 3 METAL DERIVS. , ,METAL DL:R[VS. OF sU6STIIIJTED INDOLES CR TETIRAHYDROCARBALGLES WITH A VlALIl'-i!,LKYLDlAlLKYL AMINE AT 120-50DEGkEES. FACtLITY,: GkDZHGPlr-'-~l0ZEr S., ALI. UNION SCIENTIFI,C RESEARCH CHE.MICAL. PHARMACEUTICAL INSTIJ~UTE. u N AS 1 F i E 012 UNCLASSIFI~D P~:OCESS[,%G DATE-13NOV70 T1, TL E- - S YN TH F S I SF P YK RU LO 1 1 2 1 A L P:iA t PYR I H I U I N E DE R I VAT I V E S - U- A UTWI 0 4) - S HV E DOV V.I., KtiARIZCMEN0VAi I.A.p A L TUK I IG-VA L.8-t GRINEIV, A.N. -'--USSR --.CCUNTRY OF I NFU S.GuRce-K1411"i. GF--TEROTSIKL. SOEDIN. 19710, 3) , 428 ~:-'DATE PUBLISHED ------- 70 j UaJ EC T AREAS-CHEMISTRY, BIOLOGICAL AND MEDICAL SCIENCES -fOPI TAGS--?YRKOLE5#.0RGAN1G NITROGEN (;~OMPGUND, PYRIMIBINEi AMINE URE DERIVATfVE, MOLECULAR STRUM C H E,,i, I CA LSYNTHESIS tCflTR0L MARKING--flq RESTPICTIONS DOCWIENT CLASS-UNCLASSIFIE0 ~PKOXY E STFP N0--UR/0(t,)9/70/0-l'% 3/0428/0428 -EL/FAA-lE---3002/0~t79 W/00' 212 012 UNCLASS IF I ED P~:CJCFSIS I f-IG L)ATL-- I 3NOV7 0 CIRC ACCESSION NO-AP0126048 6WlA(:T/EATRACT---(U' GP-0- A BS TR A C T. -OFR [VS. OF ;f I ) WERE I TH 1 , 3 , D 1 r-,', P. 6 0' YL,1:r2lVS- IN REFLUXINCA- Skk H S035 N OR J.5 A ACCH OR HEATEO itifTHOUF SULVENT AT 150,60DEGREC.S TO YIELD Tii;~ FOLLi' ING 11 (Rt R PRL;'-,F-lr k PRIME2, R PRIME3, 14.P.,, AND PFf,,CPAT, YIELJ GIVEN): S H OW Ill ON ',l I CROF I CHE FACILITY: VES. INAUCH,-ISSLEO, KHIM.-FARM. INST. IM. ORWHONIKIDZEir MOSCOW? USSR. .... . ...... ........... opi .112 .010' UNC L ASS I Fl E D~ CICES.SIN6 DATE--13NOV70 :TlTLF--lML)0LE DE;NJVATIV-::S -U- AUTHl],R-(G3#'-SHVED[)V, V.I.o KURILOt G.N.j: GRMEVp A N Ito --OSSR -COUNTRY OF INFO SOURCE--U.S.S.R. 2629906 ....REFEKENCE--GTKRYTKYA, OZOURET., PkOM. 06RAzrsy, T0'VAkNYE LNAK 1~;70, 47(71 PUBL ISHE0-04FEB 70 SUBJECT AREAS-CHEMISTkY, SiOLOGICAL AND MEDICAL SCHN'CE5 JOPIC. TAGS-- CHEMICAL PATENT, CHEMICAL SYNTHESISr MOLii-CULAR STRUCTUREr 1NOOLE 'FING--NO RESTRICTIONS C ONTROL A;.. G 0 C U.4 E i't T C LS - - jN C L A 57' S I F I E D PROXY REEL/FRAME--3004/1777 STEP N 0 - - UR 04 3 2;l 0 0 f) 00 300 00 0 0 CIRC Ac'CEISSI.C.N NU-440132043 i I Nc L i_l ol, S IF I F 0 N,3 V 7 0 010 UZNCLA~S I'F I EG: PiQICES~S[NG DATE-1- C IRC A CC ESS ION NIG-AA0132043 A6STRACT/c--XT~ACT---(U) GP-0- ABSTPACT. JiNDOLF DEklVS. (1, R E!,jUALS H, ALKYL, ARYL; R F1,11,141tl EQUALS ALKYLr H*f~R PRPME2 ElAJALS H, ALKYL) WF.RE BrAl'-%iED BY TREATING P 3ENZOQUINONE W[Tll GAMMA PHFiNYL BE-TA AMINO CROTOINIC ACID ESTER OR A DERIVP IN AN, INERT SGLvEiq-r, SUCH AS OICHLOROP-THANE. THE RESULTING PROMICT:-WAS SEP0. (.-jR IMETHYLATC-0 BY ME SU32 50 SUB4. FACILITY: OROLHONIKIDLE, S., ALL UNIGN SCIE?4TIFIC RESEARCH CHEMICAL PHA-iiACEUTICAL INSTITUTE. UNCLASS if- [ED. A/Z 022 UINCIL ASS IF I ED: PROCESSING DATE-09OCT70 JITLE----NEW ,,.ErH00 FOR SYNTHESIZING THIEN0(3,2,b)PYKRQLE: UERIVArfvEs -u- C03).-SHVEDUV V.A GR IN L A. N, s' VA$ILYEVAt -V K. -COUNTRY OF INFO-USSR SOURCE--KHIM. GETEP.OTSIKL. SUEDIN. 1970, (2), 276-7 ~AATE PUBLISHED--70 SUBJECT AREAS-CHEMISTRY, BIOLOGICAL ANDMEDICAL SCIENCES .10PIC TAGS-CHEMICAL SYWHESIS, BIJMEDICAL R AND L)v py~ukol_vs, -CTRUM, EPH SPE-0-RUM MULECULAR STRUCTURE, UV SPECTRUM, IR SPE 65;* f T R 0 t. t4APX*IhG--N0 U'.ESTRICTIGNS :.DOCUMENT CLASS-UNCLASSIFIED PROXY REEL/FRAME-L98311194 STEP NO--UR/0409/ 70100610,021,32 2 77 'GLASSI FtEG rC--0')0CT70 2/2 022 U N j3RrjCESSjt4G 0- ACCESSION NO-AP0054093 ~-,P-o- .43 STRACT. IN SEARCH F'OR NEW 310L. ACTIVE P0. [3Y i(EATU'l-C E . G SUbSTANCES, FHE TITLE COMPUS- -A,ANILllN0ACErupHENUNE WITH TO STERS C '~R ~ ; 140-601JEGRELS FOr, 10 MIN. c U~- THlEN0(3rZjb)PVi 3 b ~' XYLIC UM: OF Tf-ii: P--i:PD. ACID (3) ARE FORMEL) IN 54-7PERCF-NT YILEDS. TLIE Sf'41JCTW - - 1. .. SUBSTANc'ES WAS CHECKLD BY UN., IR., AND EPR SPECTROSCUi't. THUS PREPU.- I IR, A PKIME2, R PRDMU? AIND DECOMPIN. Ft:NP. SI'vIU0 El, PHt 11-1cl-I 81 2DEGRLES,; H, PH, MEa 25f)-80EGREE-S; It, PH, H, 27(-.30~rRU fit RHCjr.MEC SUB6 H SUB4, H, 2SG-2DEGREF-S; li#~RHO,CLC SU86 H SU~4, 2701-LDEGREI-S. USSR UDC 615.31:547-759-32-'.012.1: 542.9 -Unio ien-4 f -, 0 n Se KURILO, G. N. GRINEV, A. N. t All J. +esearch Chemloo Pharmaceutical Institute imeni'Sergo Ordzhonik-ifte, proscoler, Ministry of Health USSR "Synthesis of 2-Arylindole Derivatives" Xlescow Miimiko-Far-matsevticheskiv Zhurnal, Vol. IVt No 33, 70, pp Abstract: Use was made of the intramolecular cyclization of 2-aryi-In- dolyi-3-acetic acids to synthesize 1,2-benzoa.rbazolo derivatives. ~Introduction of an aryl chromophore into the indole heterocycle increases the absorption intensity and moves the absorption bands toward the long-wave spec-IL-Iral region. The type of substitutlent in the aryl chromophore has no effect on the Dosition of the absorlotion maxima. Only two of the eighteen derivatives exhibited &ntiviral activity in vitro against A type FR-8 strain. UDC - '.54 7. 7 5 7. 07 USSR ~V. 1. jdJJRILO, G. N. GRTIqFV, 1". N. All-UiJon Scientific Rosearch S/ 0.2 a/CM2 the rate of the formation of eas bubbles should give a -complete removal of colloids -- those present iki the. original solution and those formed by electrocoagulation Into the foamy product. 4A0052677' UR 0482 I XIR Soviet Inventions Illustrated, Section III Mechanical and Genera., Derwent 7C- -CH LLM has a working memb#-,r com- 'F241301 TREN F1 prising -i frame I joth closed scraping chain 3 placed In a vertical plane.: It-i* distinguished by mountingi in the horizontal plane idditional closed 4craping chain 2 to, This achleves preloomening of the soil. 12.2.66,-Aia J655oq7/Rq-j6,' PO-LTATELFV, I.S. et al. Kiev Binding Bul, 13/1.4-ji9 Class 84d, lot. C!;*Z 02f. 198Z1444 . 4 . F )-.-: 19S21445 - ~m -MI-I'Mil'i'llhi I 19E 19 ", MR I M F11 I RIV W.1 I fl, / .) Foltavtsev, 1. S.; Smryagin, A. G.; Protsenko., V. V.; Shve4ov V. Ye.; ZSurskaya, L. M.; Lekhovich, 1. F.; Rutbarg, Ye. I.; Borovik, N. A.~~ MzevsKII Filial Tsentral'uogo Nauch-tio-Issledovatel'skiy instituta Svyazi 1982144G . .................... ir WNIMm. W~fi aagam" _~A USSR UDc. 621-382.3 KAKOVKIrI, V. V., ZAYTSEV, B. D., and SMDOV, Ye. Ye. "Measuring Infrared Noise of MOS Transistors by the Frequ~ency Transformation Method" Kiev, Izvestiya VUZ--Radioelektronika, Vol 14, No 1, 1971, pj~ 67-71 Abstract: An important characteristic of 140S transistor amplifiers is the inher- eat noise which limits the sensitivity of the device and, most typical of the noise in the infrared spectrm, causes drift of the zero -point. Discussing the various methods of measurin~r, the noise spectral denfiity, the authors conclude that the i7,iost promising is the frequency transformation method, which involves the use of a tape re-corder. According to this method, the noiae voltages are re- corded at low speed and are p1wfed back at a speed provWng the required charge in time scale for investigating the noise spectral density with ordinary equip- ment. This article gives the results of experimenta perfor7red in the measurement of infrared noise in the 0-005-1 11z range, using the MG-1 and MAG-2 recorders. The recordings were made at speeds of 0.141 0,07, and 0.035 MM/s, and the play- backs at 381 and 762 mm/s. The distortions, iii the apectAt, computed theoretically for this process, were ex-erimentally checked. For their.~L-xpeerlrental specimens, the authors used MOS transistora with induced p-channel &ind an imulating Sill~ film 0#17 Ll thick. Curves are plotted for the noise factor an a f"twatioxi of the frequency.,'- Kiev, Izvestiya VUZ--Radioe_'ektroaika, Vo 1 13, No 11, -1970, PP 1358-1361 Abstract: it is asserted that data reCarding the drift time of 1108 (metal oxide semiconductor) transistors it; rather. exiguous EO.t~iough sitch data in ir-Port- ant since the stability requirements of linear circults, InvolvU43 Duch corrPon- ents are much stricter than present-day integrated dlgif;al c1rcuits. Mis paper gives the.results of measuxements made of 40 MOS t-ranslstorB, with induced p-channel, of either SiO, or Si3N4 films. Both,these films were 0.17 ,v thick. Me parameter cho6en Tor the drift ti= criterion -wp-s the increase in voltage applied to the gate correBpondil~g to the xutio of the measured incre- ment in the drain cur--ent, to Vie transconductance of thl) traxisistor under measurement for a given d-rain current. A block diagr= of the reasuring equip- ment is sho,.m. It was foundj in the course of t1ru. nnaauremeDta, that the drift time of the WS with SiO2 is fullj reproduced evert after the, gate is deprived of its voltage. The results of an experiment performed, on the basis of that fact indicated that the drift of the 14081tranaiator if; basiCally caused by the migration of ions and the charge of the surface fftatefl* UDe~ 53i,. '5 ZAA YITSEII, B. D., 5'.1UP~iLNn. rE D- 3 V1 YZ Noisel athods or eleasurin:r Lcw-'Frequency HosecTr, lzzeri~eilnava Te~-hrdka, 0 6. Jun 1970, n? 4)-46 T~,is arLicle contains a re%riew of the exiz7z;-Jn~,:- and :7:eans Abstract: men4, s e ertz and s-ub.Eertz Measur-LYIg low-:rcquency noise in electronic Ln., v, w ranges). The review 4-s based on an analysis of Sovitn fore-i.gn literature. Low- f ue,-,cv no-i'se -%nd null drift , irethods of measvxxing -ov--'requercy nD: Lse, frequency band filte:7s, ar-,~ low-frequency lo-w-frequercy noise ganerators, lw~t, voltmeters are considered. it is concluded that measurinjI, not.-ci :~n de,.rices in the infrasonic fro-quency range is of great Lscle--~i.f:.C: ar,i practical interest. Various methods sY4 equip~.ent have be,~~n devairwc-,4 --t T.~i-, ti,,;:e for measuring the charac,"'eristics of noise at 'Lrequenc--es up -.C, t~'r-Cz. easur- inS lonw-frequency nodse b~- tilre methoi of 'Lrequen,I-y speq-ur,,~-n magnetophorda technique) nas not -st this time L-eer, S~ f4cirentl~,,,- The Com- Parative =easurement tech.niques using analo,cr ?.C-filLe-rs arid an ir.-4-il-a-tin7 volt mater are mast pros-, e ar..-Ive. These nethods can be usod to :~ea.,;ure ro-?--,e Ln the frequency range fron a fow hertz to frequencies on the a.'r~-.er of 'LU-J' nertz. Descriptive diagrams, gra-p'is aril mathomatical doscriptions aro used -Vo illust-rate a rxt expLain t,',,e various techniques and equipment, M-NIAMM ~P- USSR UDC 681.2-621,391,822.029.33 ZOTSEV, B. D., SFIVEDOV, YE. YE. "A Device for Measueng Very Lm,- Frequea(*? x0ises" Njoscow, Izmeritel'aaya Tekhoika, No 8, Aug 70, pp 74-76 Abstract: The authors describe an instrimment which tkev have developec measuri-ng the spectral density of noises in the 0.1-101) Ilz irequency range V by cormaring the noises with these from a standard Itni -1rc-.que:ic,,, 101~~O. -~Ouvce. ~rle standard industrial U4-1 wide-band =plifier was iji;od ivizil varici-l-,le - In ga - -i`rom 0 Co 5 X 101. An 15-M oscillozraph, was used as zhe j:~~,cording iniLrumont. rzircuirrv of Zile matitor low frequency noise gezex,ator, narrow-bai~d t-,inable Y`o "n- f:ilter ara voltneter ~tsed In the imstrurwmt. ~Nii dot;(-xihou- 1. Was used rr, ricai;ire z'-!C- VLO:.se zactor of MDS-' trans;stors with ~mh)cvd effect4ve passbaud of the filti- varlx.~-, over a range of lf','- I&a, -erca:~, or ne resonance frequency6 vas derernined ~ry the sensitivity of t~,e -vi-dz-band -Aii,,h urtwt am -:i in these experiments was 0.1 AIV /I'z. The -measur-mment: itrrcr 6etemined UY: the error oi~ eazh of the modules iu: the device is no mcivgi t:han 15 1),2rcent. --230CT70 014 UNCLASSIFIED V*RUCESSING DATE jITLE--NQR NUCLEAR QUADRUPOLE RESONANCE SPECTRA OF ARSENIC 75 AND CHLORING 35 OF CHLCRINE CONTAINING ORGANUARSENIC III COMP("UNOS -U- AUTHOR-1 05)_ SVERGUNv V.j.j BABUSHKI,NAt T.A*7 KUi)RYAVTSEVAt V.j SE.MINp G.K. COUNTRY OF INFO--USSR SOURCE--IZV. AKAD. NAUK SSSRP. SER* KHIM# 1970v (Z)v 482-3 PUBLISHED ------- 70 ,,~SUBJECT AREAS--CliEMISTRY, PHYSICS, NUCLEAR SCIENCE AND TECHNOLOGY --NUCLEAR RESONANCEt SPFCTRUMv. ArkSfN[C ISOTOPE, CHLORINE ,.ToPIC TAGS :~ISOTOPE# ORGANIC ARSENIC CUMPOUNDo MOL ECULAR ORBITAL 'CONTROL MARKING--NO RESTRICTIONS DOCUMENT CLASS--UNCLASSIFIED ,~:PROXY REEL/FRAME--1997/0643 STEP MO--UR/0062170/000/002/04-112/0483 CIRC ACCESSION NO--APf-')Ll9560 2/2 014 UNCLASSI FIED PROCESSING DATE--230CT7C CIRC ACCESSION NO--AP0119560 GP-0- ABSTRACT. NOR SPECTRA IoJERE REPORTED FOR PRlJME75'AS AND PRIME35 CL IN ASCL SU63t ME SUB3 AS, ET SUB3 ASt PH SUB3 ASI PH SUB2 ASC SUB6 H SU84 CO SUB2 Fl P AND M ISUMERt PH SU32 ASCLP MEASCL SU62, ETASCL SUBlt PRASCL SUR2, AND BUASCL.SUB2. THE P CHARACTER OF THE SP HYBRIDIZED UNSHARED ELECTRONS OF AS INCREASES UNDER THE INFLUENCE OF DIVERSE SUBSTITUENTS ON AS; THIS CORRESPCNDS TO INCREASED ANGLE BETWEEN METAL ORBITALS RELATIVE TO THE VALENCE A,11GLE AND D~VIATION .,OF THE ORBITAL OCCUPIED BY THE LONE PAIR FROM THF-PSEUDOAXIS OP THE 3RD -ORDER. FACILITY: INST. ELEMENTOORG. SOEDIN., MDSCOWr USSR. LINE _~4 if USSR 7 UDC 538-113 t 543-42 -0- 547. 242 + 546. 13 SVERGUN, V. j., BABUSHKINA, T. A. vSHVEDOVA, G. N,, XUDRYAVTSEVA, L- V., and SMIN, G. K., Institute of 7OF-6-noeiiiiiiitli Compounds, Academy of Sciences USSR 75 35 "As and C1 NQR Spectra of Chlorine-containing Organoelemental Com- pounds of Trivalent Arsenic" Moscow, Izvestiya Akademii Nauk SSSR, Seriya Kbimicheskayaq No 2, Feb 70, pp 482-483 Abstract: The As75 and C135 XQR spectra for compounds of the type R;tAsR 3-x were studied. It was found that sharply different substitu- ents in these compounds produce a significant increase in the angle between the atomic hybridized orbitale of the nottalf ithich increases the p-character of the sp-hybridized pair of tho meui, resulting in a sharp increase in the As75 NQR frequency. The 4ingle becomes,much 1/2 USSR SVERGUN, V. I., et al., Izvestiya Akademii NaLik SSSRI Seriya Kbi.,ri- cheskayap No 21 Feb 70j PP 482-483 greater than the valence angle. In additionp deviation of the orbital occupied by the unshared pair from the.third-order.pseudoaxis also brings about an increase in As75 NQR frequancie s. The authors thank A. YE. BORISOV for ~ds interest in the work and G. KH. KAMAY for pro- viding samples of Ph2AsPh*o al a f USSR UDC 543.42 PANICHEV, N. A., PRUDNIKOV, Ye. D., TURKIN, Yu, I., SHVEDDVA, I. V. "Scintillation Method of Recording in the Atom Absorption Method of Spectral Analysis" Minsk, Zhurnal Frikladnoy Spektroskopii, Vol XVIII, No 5, 1973, pp 772-776 Abstract: The scintillation method of recording in the atom absorption technique for spectral analysis is based on recording the absorption pulses of the analytical line caused by evaporation in an atomizing source of individual particles the composition of which includes a defined element. In the example of analyzing Zn, Cd, Ca, Pb, He, and Au the possibility of direct analysis of these elements in pm7dered samples by blowing them into an air-acetylene flame in an oxygen stream with a relative sensitivity of 10-5 to 10-6% is demonstrated. A study was made of the effect of the number of particles containing the defined element on the efficiency of the scin- tillation recording. The method is highly promising for evaluating the form of the concentration distribution of the elements in the sample composition and analysis of an object with a nonuniform concentration