SCIENTIFIC ABSTRACT SHVEDOV, V.I. - SHVETSOV, I.K.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002203010020-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 99
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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pressure iu-the-llmjt,, so,-~ ceds'gad dn be
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USSR UDC 5411.752.753.755.07:542.953
SHVEDOV. V. I., PANISHEVA, Ye. K., VLASOVA, T. F., GRINEV, A. N., USSR
institute of Chemical-Pharmaceutical Scientific Research imeni S.
Ordzhonikidze, Moscow
"The Synthesis and Aminomethylation of 6-Hydroxyiudoles"
Riga, Akademiya Nauk Larviiskoy SSR, Himiya Geterotsiklicheskikh Soedinenii,
No 10, Oct 73, pp 1354-1356
Abstract: It was found that, while reaction of p-benzoquinone with
6-aminocrotonic ester or N-mel.hyl-a-aminocrotonic ester at O*C 'An acetic
acid produced 5-hydroxyindoles,-the reaction of p-benzoquinone with
N-aryl-0-aminocrotonic ester under the same conditions produced
6-hydroxyindoles. Thus,-the substituent on nitrogen determines whether
the ester reacts at the double bond or the carbonyl group of p-benzo-
quinone. Reacting the 6-hydrox-yindoles with bisdimethylaminomethane
produced 6-hydroxy-7-dimethylaminomethylindoles. Bromination and
nitration of 6-methoxyindoles and 6-acetoxyihdoles led to,substitution
at position number 5, which is explaimed by the fact that bromination
and nitration take place in acid solution, and aminomethylation In basic.
Structure determination was by MIR spectroscopy.
17

Nitin~;cn CbIrpounds
USSR U D 01 615-.)25.2!547.5l-~7.'~3.012.1:542.c)
NT Z"I V n 0 11 c
G.
I -, and GPTjj 11-U j S i
entific Researca Institilte of Pharmacelatical Cjjc-,7-,-Lstry i,,I-ieni S.
OrdzhQnil-,':.dze, '11~oscow
"Research in tne Field of XLVI II Synz.;-ie,~,is of Do-
rivaLives of 2-3'enzyl-5-oxyindole. and 2-L-~etizyl-5-oxy'-Venzi-~idole"-
Moscow, Khi-miko-Far:r~atsevtlichesi-.iy.Zliurnal~p 1.161 4, LIlo 9, Sep 70,
pp 7-12
Abstract: T.he &rtui cle sui%r---ts a, metimdA fo~, f
th 5 i
.I CD
deriv--i-I.Aves of
are in th-,
synthlesi3 of aralogs ol" ~eroi-.anin, The
are obzained b7 ~f P-bolnzoqui.IMII,114~! or
quinone witz.. the metji-i ester of -substituzed or urisubs
V N u t ~ t ud
ac! C&
P Q iethy*;~;tion fIQ ~erlvaLivcs
with GIrnt-thyl 3!)-71 .4,1 an solur.-ion t110-4 to
derivatives of and 2-
benzY1-3-carIbu ei;i~o y->-methoxybenzindole. Hy~`I-Qly:3L5 of rhe

-0,
USSR
KV F-,) o v v
et al.
pp,
Ihurr~aj, 4
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ca- bOXY-5-r,-,ethoxy-t,
IR
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2/2
34

USSR UDC 615.214:547.759
MASHKOVSKIY, If. 0., GRINEV, A. N., ANDREYEVA, N. 1.1 SWIEDOV, V. I., and
ALTUKHOVA, L. B., Laboratory of Pharmacology and Laboritairy of-S~ntbesis,
All-Union Scientific Chemical-Pharmaceutical Research Institute imeni S.
Ordzhonikidze, Moscow
"Investigation of the Psychotropic Activity of 1,10-Trimethylenepyrazino
[1,2-alindole"
Moscow, Farmakologiya i Toksikologiya, Vol 34, No 4, Jul-Aug 71, pD 387-391
Abstract: Five novel derivatives of 1,10-trimetliylenLpipera;,,inofl,2-a]indole
(I) and two derived from l,"LO-trimetliylenepyrazinofl,2-aliftdole (N) were
studied in respect to their psychotropic activity (reaction to the effect
of phenamine and reserpine on mice and rats, cataleptic activity of these
materials on rats, their effect on body temperature ,:.nd overall state of
The derivatives of (1) were found to be more active, especially
those without any sub.-3tituents in the ring, those vith a methoxy group in
position 8 and ot-thyl group in 2 and 8 po~~sitfon of tl~ie heterocycle. 13,;
rheir.activity these substances resemble the of tile tri-
cyclic structural type such as imizines. DeriVativiis of (11) exhibIted it
1/2

USSR
MASHKOVSKIY, M. 0., et al., Farmakologiya i Toksikologiya, Vol 34, No 4,
Jul-Aug 71, pp 387-391
definitely lower activity. Ttansition,from a tertiary amine derivative of
(I) to a quaternary amine lm-yered its activity.
2/2

TJSSR UDC 547.661.31752
N., All-ITnion
I., ALTWHOVA, L. 3. and GTZ I N M-T
Im ti tu te imenil S~Prgo
gcip~t7ific !Zesearch Chemico Pharmacieutical
Ordzhonikidze, Moscow, Ministry of Health USSR
'IN-Acyl and N-Alkyl Derivatives of 1, 10- Tr im e thy LP n e p ip e ra~' i no
(1,2-0indole"
Mos~co-, Khimiko-Farmatsevticheskiy Zhurnal, Vol 4, No 7, L97o,
pp 5-7
Abstract: "Iethods were developt-'.d for synt4esiu-inf! the N-aUyl and
N-acy! drrivatives of piperazino9l,2-a)ird,Af-, W11-11'.Ch exhibits
antihistaminic and hypatensive action. T'hf, 1,17-acyL derivatives
(7-TIJ) were obtained by acylation of
piperazino(1,2-a)indole with acetic anhyd-ridle nr acid chlorides.
Al~ylation of dprivatives of piperazino(3,;2-.-.)in(InLP by oi-dinal'y
C~ C, -i ds . 'I-la -
alkylating agents occurs with complicatIons at ,-I. le-- to I'or -
tion of resinous products. N-alkyl derivativ~,s can be obtained
by indirect methods. Hydrogenation of iodomethylates (VII and, VIII)
over skeletal nii-.kel catalyst leads to the corresponding N-methyl
derivatives UK ad X), while reduction of "it-acetyl-8-methyl-1,
10-trimethylenepipera--ino (1,2-0indole(l) with lithium aluminum
h%'tjrj(je Vielda the N-ethyl derivotes (xi).

US SR
SHVEDO V, V. I., et al., Khimiko-Farmataevticheskiy Zhurnal, Vol 4.
No 7, 1970, pp 5-7

I Z~ f.;j I X4

2/2

ANN
11-2~' all IJNCLAS,~tF PPOCESSTING 0ATE-13NOV70
:~',TITLE--OIALKYLAMINDALKYL DERIVATIVES OF INDOLE Ott TETr.AHYf)rWLAi-~bA10LE -U-
AUITHOR-1 03)-iiiVE0~0VpVI GR 1 NEV, A.N., ALTUKHOVA, L.B.
CGUNTRY OF INFO-OSSA
:-SOURCE-USSR 265ta65
REFEAENCE-UKRYTIYA, IZOBRET., PROM. 084ALTSY, TOWAkNYE ZNAK I 1970'r
DATE PUBLISHED-17iMAR70
'-:SUBJECT AREAS-CHE."111STRY
.~JGPIC TAGS--AMINE DERIVATIVE, INUOLEi ORGANIC AZUCCOMPOUNDi HYDROXYL
RADICAL, CHEMICAL PATENT
CONTROL 14ARKING-NO RESTRICTIONS
~-DOCU:iEINT CLASS-UNCLASSIFIED
PROXY REEL/FRAME-3002/let8l STEP NIO--IJR/04d2/70/000/OOU/C)~)00/0()00
CIRC ACCESSIWLi 1';G---AAG1Z3660
F I ED

-77~
J- 2/2 OLI UNCL ASS I F t 8b: PKErCESSING OATE--13NOV70
CIRC ACCESSION Nil-AA01288dO
ABSTRACT/EXTRACT-M GP-0- ABSTRACT. TITLE Cl)',IPDS ARE PREPO. BY
OF 51HYDROXYMOULES OR IN
TREATING 3 METAL DERIVS. , ,METAL DL:R[VS. OF
sU6STIIIJTED INDOLES CR TETIRAHYDROCARBALGLES WITH A VlALIl'-i!,LKYLDlAlLKYL
AMINE AT 120-50DEGkEES. FACtLITY,: GkDZHGPlr-'-~l0ZEr S., ALI. UNION
SCIENTIFI,C RESEARCH CHE.MICAL. PHARMACEUTICAL INSTIJ~UTE.
u N AS 1 F i E

012 UNCLASSIFI~D P~:OCESS[,%G DATE-13NOV70
T1, TL E- - S YN TH F S I SF P YK RU LO 1 1 2 1 A L P:iA t PYR I H I U I N E DE R I VAT I V E S - U-
A UTWI 0 4) - S HV E DOV V.I., KtiARIZCMEN0VAi I.A.p A L TUK I IG-VA L.8-t GRINEIV,
A.N.
-'--USSR
--.CCUNTRY OF I NFU
S.GuRce-K1411"i. GF--TEROTSIKL. SOEDIN. 19710, 3) , 428
~:-'DATE PUBLISHED ------- 70
j UaJ EC T AREAS-CHEMISTRY, BIOLOGICAL AND MEDICAL SCIENCES
-fOPI TAGS--?YRKOLE5#.0RGAN1G NITROGEN (;~OMPGUND, PYRIMIBINEi AMINE
URE
DERIVATfVE, MOLECULAR STRUM C H E,,i, I CA LSYNTHESIS
tCflTR0L MARKING--flq RESTPICTIONS
DOCWIENT CLASS-UNCLASSIFIE0
~PKOXY E STFP N0--UR/0(t,)9/70/0-l'% 3/0428/0428
-EL/FAA-lE---3002/0~t79 W/00'

212 012 UNCLASS IF I ED P~:CJCFSIS I f-IG L)ATL-- I 3NOV7 0
CIRC ACCESSION NO-AP0126048
6WlA(:T/EATRACT---(U' GP-0- A BS TR A C T. -OFR [VS. OF ;f I ) WERE
I TH 1 , 3 , D 1 r-,', P. 6 0' YL,1:r2lVS- IN REFLUXINCA- Skk H S035 N OR
J.5
A
ACCH OR HEATEO itifTHOUF SULVENT AT 150,60DEGREC.S TO YIELD Tii;~ FOLLi' ING
11 (Rt R PRL;'-,F-lr k PRIME2, R PRIME3, 14.P.,, AND PFf,,CPAT, YIELJ GIVEN):
S H OW Ill ON ',l I CROF I CHE FACILITY: VES. INAUCH,-ISSLEO, KHIM.-FARM.
INST. IM. ORWHONIKIDZEir MOSCOW? USSR.

.... . ...... ...........
opi
.112 .010' UNC L ASS I Fl E D~ CICES.SIN6 DATE--13NOV70
:TlTLF--lML)0LE DE;NJVATIV-::S -U-
AUTHl],R-(G3#'-SHVED[)V, V.I.o KURILOt G.N.j: GRMEVp A N
Ito
--OSSR
-COUNTRY OF INFO
SOURCE--U.S.S.R. 2629906
....REFEKENCE--GTKRYTKYA, OZOURET., PkOM. 06RAzrsy, T0'VAkNYE LNAK 1~;70, 47(71
PUBL ISHE0-04FEB 70
SUBJECT AREAS-CHEMISTkY, SiOLOGICAL AND MEDICAL SCHN'CE5
JOPIC. TAGS-- CHEMICAL PATENT, CHEMICAL SYNTHESISr MOLii-CULAR STRUCTUREr
1NOOLE
'FING--NO RESTRICTIONS
C ONTROL A;..
G 0 C U.4 E i't T C LS - - jN C L A 57' S I F I E D
PROXY REEL/FRAME--3004/1777 STEP N 0 - - UR 04 3 2;l 0 0 f) 00 300 00 0 0
CIRC Ac'CEISSI.C.N NU-440132043
i I Nc L i_l ol, S IF I F 0

N,3 V 7 0
010 UZNCLA~S I'F I EG: PiQICES~S[NG DATE-1-
C IRC A CC ESS ION NIG-AA0132043
A6STRACT/c--XT~ACT---(U) GP-0- ABSTPACT. JiNDOLF DEklVS. (1, R E!,jUALS H,
ALKYL, ARYL; R F1,11,141tl EQUALS ALKYLr H*f~R PRPME2 ElAJALS H, ALKYL) WF.RE
BrAl'-%iED BY TREATING P 3ENZOQUINONE W[Tll GAMMA PHFiNYL BE-TA AMINO
CROTOINIC ACID ESTER OR A DERIVP IN AN, INERT SGLvEiq-r, SUCH AS
OICHLOROP-THANE. THE RESULTING PROMICT:-WAS SEP0. (.-jR IMETHYLATC-0 BY ME
SU32 50 SUB4. FACILITY: OROLHONIKIDLE, S., ALL UNIGN SCIE?4TIFIC
RESEARCH CHEMICAL PHA-iiACEUTICAL INSTITUTE.
UNCLASS if- [ED.

A/Z 022 UINCIL ASS IF I ED: PROCESSING DATE-09OCT70
JITLE----NEW ,,.ErH00 FOR SYNTHESIZING THIEN0(3,2,b)PYKRQLE: UERIVArfvEs -u-
C03).-SHVEDUV V.A GR IN L A. N, s' VA$ILYEVAt -V K.
-COUNTRY OF INFO-USSR
SOURCE--KHIM. GETEP.OTSIKL. SUEDIN. 1970, (2), 276-7
~AATE PUBLISHED--70
SUBJECT AREAS-CHEMISTRY, BIOLOGICAL ANDMEDICAL SCIENCES
.10PIC TAGS-CHEMICAL SYWHESIS, BIJMEDICAL R AND L)v py~ukol_vs,
-CTRUM, EPH SPE-0-RUM
MULECULAR STRUCTURE, UV SPECTRUM, IR SPE
65;* f T R 0 t. t4APX*IhG--N0 U'.ESTRICTIGNS
:.DOCUMENT CLASS-UNCLASSIFIED
PROXY REEL/FRAME-L98311194 STEP NO--UR/0409/ 70100610,021,32 2 77

'GLASSI FtEG rC--0')0CT70
2/2 022 U N j3RrjCESSjt4G 0-
ACCESSION NO-AP0054093
~-,P-o- .43 STRACT. IN SEARCH F'OR NEW 310L. ACTIVE
P0. [3Y i(EATU'l-C E . G
SUbSTANCES, FHE TITLE COMPUS-
-A,ANILllN0ACErupHENUNE WITH TO
STERS C '~R ~ ;
140-601JEGRELS FOr, 10 MIN. c U~- THlEN0(3rZjb)PVi 3 b ~' XYLIC
UM: OF Tf-ii: P--i:PD.
ACID (3) ARE FORMEL) IN 54-7PERCF-NT YILEDS. TLIE Sf'41JCTW - - 1. ..
SUBSTANc'ES WAS CHECKLD BY UN., IR., AND EPR SPECTROSCUi't. THUS
PREPU.- I IR, A PKIME2, R PRDMU? AIND DECOMPIN. Ft:NP. SI'vIU0 El, PHt 11-1cl-I
81 2DEGRLES,; H, PH, MEa 25f)-80EGREE-S; It, PH, H, 27(-.30~rRU fit RHCjr.MEC
SUB6 H SUB4, H, 2SG-2DEGREF-S; li#~RHO,CLC SU86 H SU~4, 2701-LDEGREI-S.

USSR UDC 615.31:547-759-32-'.012.1:
542.9
-Unio ien-4 f -, 0
n Se
KURILO, G. N. GRINEV, A. N. t All J.
+esearch Chemloo Pharmaceutical Institute imeni'Sergo Ordzhonik-ifte,
proscoler, Ministry of Health USSR
"Synthesis of 2-Arylindole Derivatives"
Xlescow Miimiko-Far-matsevticheskiv Zhurnal, Vol. IVt No 33, 70, pp
Abstract: Use was made of the intramolecular cyclization of 2-aryi-In-
dolyi-3-acetic acids to synthesize 1,2-benzoa.rbazolo derivatives.
~Introduction of an aryl chromophore into the indole heterocycle
increases the absorption intensity and moves the absorption bands
toward the long-wave spec-IL-Iral region. The type of substitutlent in
the aryl chromophore has no effect on the Dosition of the absorlotion
maxima. Only two of the eighteen derivatives exhibited &ntiviral
activity in vitro against A type FR-8 strain.

UDC - '.54 7. 7 5 7. 07
USSR
~V. 1. jdJJRILO, G. N. GRTIqFV, 1". N. All-UiJon Scientific Rosearch
S/ 0.2 a/CM2 the rate of the formation of eas bubbles should give a
-complete removal of colloids -- those present iki the. original solution
and those formed by electrocoagulation Into the foamy product.

4A0052677' UR 0482
I XIR
Soviet Inventions Illustrated, Section III Mechanical and Genera.,
Derwent 7C-
-CH LLM has a working memb#-,r com-
'F241301 TREN F1
prising -i frame I joth closed scraping
chain 3 placed In a vertical plane.: It-i*
distinguished by mountingi in the horizontal plane
idditional closed 4craping chain 2 to, This
achleves preloomening of the soil.
12.2.66,-Aia J655oq7/Rq-j6,' PO-LTATELFV, I.S. et al.
Kiev Binding Bul, 13/1.4-ji9
Class 84d, lot. C!;*Z 02f.
198Z1444

. 4 .
F )-.-:
19S21445
- ~m -MI-I'Mil'i'llhi I 19E 19 ", MR I M F11 I RIV W.1 I
fl, / .)

Foltavtsev, 1. S.; Smryagin, A. G.; Protsenko., V. V.; Shve4ov V. Ye.;
ZSurskaya, L. M.; Lekhovich, 1. F.; Rutbarg, Ye. I.; Borovik, N. A.~~
MzevsKII Filial Tsentral'uogo Nauch-tio-Issledovatel'skiy instituta
Svyazi
1982144G

. .................... ir
WNIMm. W~fi aagam"
_~A
USSR UDc. 621-382.3
KAKOVKIrI, V. V., ZAYTSEV, B. D., and SMDOV, Ye. Ye.
"Measuring Infrared Noise of MOS Transistors by the Frequ~ency Transformation
Method"
Kiev, Izvestiya VUZ--Radioelektronika, Vol 14, No 1, 1971, pj~ 67-71
Abstract: An important characteristic of 140S transistor amplifiers is the inher-
eat noise which limits the sensitivity of the device and, most typical of the
noise in the infrared spectrm, causes drift of the zero -point. Discussing the
various methods of measurin~r, the noise spectral denfiity, the authors conclude
that the i7,iost promising is the frequency transformation method, which involves
the use of a tape re-corder. According to this method, the noiae voltages are re-
corded at low speed and are p1wfed back at a speed provWng the required charge
in time scale for investigating the noise spectral density with ordinary equip-
ment. This article gives the results of experimenta perfor7red in the measurement
of infrared noise in the 0-005-1 11z range, using the MG-1 and MAG-2 recorders.
The recordings were made at speeds of 0.141 0,07, and 0.035 MM/s, and the play-
backs at 381 and 762 mm/s. The distortions, iii the apectAt, computed theoretically
for this process, were ex-erimentally checked. For their.~L-xpeerlrental specimens,
the authors used MOS transistora with induced p-channel &ind an imulating Sill~
film 0#17 Ll thick. Curves are plotted for the noise factor an a f"twatioxi of the
frequency.,'-

Kiev, Izvestiya VUZ--Radioe_'ektroaika, Vo 1 13, No 11, -1970, PP 1358-1361
Abstract: it is asserted that data reCarding the drift time of 1108 (metal
oxide semiconductor) transistors it; rather. exiguous EO.t~iough sitch data in ir-Port-
ant since the stability requirements of linear circults, InvolvU43 Duch corrPon-
ents are much stricter than present-day integrated dlgif;al c1rcuits. Mis
paper gives the.results of measuxements made of 40 MOS t-ranslstorB, with
induced p-channel, of either SiO, or Si3N4 films. Both,these films were 0.17
,v thick. Me parameter cho6en Tor the drift ti= criterion -wp-s the increase
in voltage applied to the gate correBpondil~g to the xutio of the measured incre-
ment in the drain cur--ent, to Vie transconductance of thl) traxisistor under
measurement for a given d-rain current. A block diagr= of the reasuring equip-
ment is sho,.m. It was foundj in the course of t1ru. nnaauremeDta, that the drift
time of the WS with SiO2 is fullj reproduced evert after the, gate is deprived
of its voltage. The results of an experiment performed, on the basis of that
fact indicated that the drift of the 14081tranaiator if; basiCally caused by the
migration of ions and the charge of the surface fftatefl*

UDe~ 53i,.
'5
ZAA YITSEII, B. D., 5'.1UP~iLNn. rE D- 3 V1 YZ
Noisel
athods or eleasurin:r Lcw-'Frequency
HosecTr, lzzeri~eilnava Te~-hrdka, 0 6. Jun 1970, n? 4)-46
T~,is arLicle contains a re%riew of the exiz7z;-Jn~,:- and :7:eans
Abstract:
men4, s e ertz and s-ub.Eertz
Measur-LYIg low-:rcquency noise in electronic Ln., v, w
ranges). The review 4-s based on an analysis of Sovitn fore-i.gn literature.
Low- f ue,-,cv no-i'se -%nd null drift , irethods of measvxxing -ov--'requercy nD: Lse,
frequency band filte:7s, ar-,~ low-frequency
lo-w-frequercy noise ganerators, lw~t,
voltmeters are considered. it is concluded that measurinjI, not.-ci :~n
de,.rices in the infrasonic fro-quency range is of great Lscle--~i.f:.C: ar,i practical
interest. Various methods sY4 equip~.ent have be,~~n devairwc-,4 --t T.~i-, ti,,;:e for
measuring the charac,"'eristics of noise at 'Lrequenc--es up -.C, t~'r-Cz. easur-
inS lonw-frequency nodse b~- tilre methoi of 'Lrequen,I-y speq-ur,,~-n
magnetophorda technique) nas not -st this time L-eer, S~ f4cirentl~,,,- The Com-
Parative =easurement tech.niques using analo,cr ?.C-filLe-rs arid an ir.-4-il-a-tin7 volt
mater are mast pros-, e ar..-Ive. These nethods can be usod to :~ea.,;ure ro-?--,e Ln the
frequency range fron a fow hertz to frequencies on the a.'r~-.er of 'LU-J' nertz.
Descriptive diagrams, gra-p'is aril mathomatical doscriptions aro used -Vo illust-rate
a rxt expLain t,',,e various techniques and equipment,
M-NIAMM ~P-

USSR UDC 681.2-621,391,822.029.33
ZOTSEV, B. D., SFIVEDOV, YE. YE.
"A Device for Measueng Very Lm,- Frequea(*? x0ises"
Njoscow, Izmeritel'aaya Tekhoika, No 8, Aug 70, pp 74-76
Abstract: The authors describe an instrimment which tkev have developec
measuri-ng the spectral density of noises in the 0.1-101) Ilz irequency range
V
by cormaring the noises with these from a standard Itni -1rc-.que:ic,,, 101~~O. -~Ouvce.
~rle standard industrial U4-1 wide-band =plifier was iji;od ivizil varici-l-,le - In
ga -
-i`rom 0 Co 5 X 101. An 15-M oscillozraph, was used as zhe j:~~,cording iniLrumont.
rzircuirrv of Zile matitor low frequency noise gezex,ator, narrow-bai~d t-,inable
Y`o "n-
f:ilter ara voltneter ~tsed In the imstrurwmt. ~Nii dot;(-xihou- 1.
Was used rr, ricai;ire z'-!C- VLO:.se zactor of MDS-' trans;stors with ~mh)cvd
effect4ve passbaud of the filti- varlx.~-, over a range of lf','-
I&a, -erca:~, or ne resonance frequency6
vas derernined ~ry the sensitivity of t~,e -vi-dz-band -Aii,,h urtwt
am -:i in these experiments was 0.1 AIV /I'z. The -measur-mment: itrrcr 6etemined
UY: the error oi~ eazh of the modules iu: the device is no mcivgi t:han 15 1),2rcent.

--230CT70
014 UNCLASSIFIED V*RUCESSING DATE
jITLE--NQR NUCLEAR QUADRUPOLE RESONANCE SPECTRA OF ARSENIC 75 AND CHLORING
35 OF CHLCRINE CONTAINING ORGANUARSENIC III COMP("UNOS -U-
AUTHOR-1 05)_ SVERGUNv V.j.j BABUSHKI,NAt T.A*7 KUi)RYAVTSEVAt
V.j SE.MINp G.K.
COUNTRY OF INFO--USSR
SOURCE--IZV. AKAD. NAUK SSSRP. SER* KHIM# 1970v (Z)v 482-3
PUBLISHED ------- 70
,,~SUBJECT AREAS--CliEMISTRY, PHYSICS, NUCLEAR SCIENCE AND TECHNOLOGY
--NUCLEAR RESONANCEt SPFCTRUMv. ArkSfN[C ISOTOPE, CHLORINE
,.ToPIC TAGS
:~ISOTOPE# ORGANIC ARSENIC CUMPOUNDo MOL ECULAR ORBITAL
'CONTROL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
,~:PROXY REEL/FRAME--1997/0643 STEP MO--UR/0062170/000/002/04-112/0483
CIRC ACCESSION NO--APf-')Ll9560

2/2 014 UNCLASSI FIED PROCESSING DATE--230CT7C
CIRC ACCESSION NO--AP0119560
GP-0- ABSTRACT. NOR SPECTRA IoJERE REPORTED FOR
PRlJME75'AS AND PRIME35 CL IN ASCL SU63t ME SUB3 AS, ET SUB3 ASt PH SUB3
ASI PH SUB2 ASC SUB6 H SU84 CO SUB2 Fl P AND M ISUMERt PH SU32 ASCLP
MEASCL SU62, ETASCL SUBlt PRASCL SUR2, AND BUASCL.SUB2. THE P CHARACTER
OF THE SP HYBRIDIZED UNSHARED ELECTRONS OF AS INCREASES UNDER THE
INFLUENCE OF DIVERSE SUBSTITUENTS ON AS; THIS CORRESPCNDS TO INCREASED
ANGLE BETWEEN METAL ORBITALS RELATIVE TO THE VALENCE A,11GLE AND D~VIATION
.,OF THE ORBITAL OCCUPIED BY THE LONE PAIR FROM THF-PSEUDOAXIS OP THE 3RD
-ORDER. FACILITY: INST. ELEMENTOORG. SOEDIN., MDSCOWr USSR.
LINE _~4

if
USSR 7 UDC 538-113 t 543-42 -0- 547. 242 + 546. 13
SVERGUN, V. j., BABUSHKINA, T. A. vSHVEDOVA, G. N,, XUDRYAVTSEVA, L-
V., and SMIN, G. K., Institute of 7OF-6-noeiiiiiiitli Compounds, Academy
of Sciences USSR
75 35
"As and C1 NQR Spectra of Chlorine-containing Organoelemental Com-
pounds of Trivalent Arsenic"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Kbimicheskayaq No 2, Feb
70, pp 482-483
Abstract: The As75 and C135 XQR spectra for compounds of the type
R;tAsR 3-x were studied. It was found that sharply different substitu-
ents in these compounds produce a significant increase in the angle
between the atomic hybridized orbitale of the nottalf ithich increases
the p-character of the sp-hybridized pair of tho meui, resulting in a
sharp increase in the As75 NQR frequency. The 4ingle becomes,much
1/2

USSR
SVERGUN, V. I., et al., Izvestiya Akademii NaLik SSSRI Seriya Kbi.,ri-
cheskayap No 21 Feb 70j PP 482-483
greater than the valence angle. In additionp deviation of the orbital
occupied by the unshared pair from the.third-order.pseudoaxis also
brings about an increase in As75 NQR frequancie s. The authors thank
A. YE. BORISOV for ~ds interest in the work and G. KH. KAMAY for pro-
viding samples of Ph2AsPh*o
al a

f
USSR UDC 543.42
PANICHEV, N. A., PRUDNIKOV, Ye. D., TURKIN, Yu, I., SHVEDDVA, I. V.
"Scintillation Method of Recording in the Atom Absorption Method of Spectral
Analysis"
Minsk, Zhurnal Frikladnoy Spektroskopii, Vol XVIII, No 5, 1973, pp 772-776
Abstract: The scintillation method of recording in the atom absorption
technique for spectral analysis is based on recording the absorption pulses
of the analytical line caused by evaporation in an atomizing source of
individual particles the composition of which includes a defined element.
In the example of analyzing Zn, Cd, Ca, Pb, He, and Au the possibility of
direct analysis of these elements in pm7dered samples by blowing them into
an air-acetylene flame in an oxygen stream with a relative sensitivity of
10-5 to 10-6% is demonstrated. A study was made of the effect of the number
of particles containing the defined element on the efficiency of the scin-
tillation recording. The method is highly promising for evaluating the form
of the concentration distribution of the elements in the sample composition
and analysis of an object with a nonuniform concentration