SCIENTIFIC ABSTRACT SHVETSOV, I.V. - SHVINKA, N.E.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002203020001-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

USSR UDC 669.71.018.9.4
SHVETSOVA, G. B., YELAGIN, V. I., and KOLACHEV, B. A.
"Influence of Hydrogen an the Structure and Mechanical Properties of Ingots
Made, of AK8 Alloys"
Tr. Mosk. aviats. tekfinol. in-ta (Works of Moscow Aviation Technological In-
stitute), 1970, vyp. 71, pp 58-66 (from RZh-Metallurgiyai~ No 12, Dec 70,
Abstract No 12 G238 by authors)
Translation: The authors studied the formation of primary and secondary
porosity in semicontinuously cast ingots of AY,8 brand alloy. The amount of
primary porosity increases linearly with an,increase in hydrogvn content.
The tendency of the alloy to form aolid solutions, supereaLurated relative
to hydrogen, intensifies with a lessening of oxide-scale -content. A super-
saturated hydrogen solution in the solid alloy decomposes with. the formation
of secondary pores 10-3-5 microns in diameter. Hydrogen,etubrittlement de-
velops in AK8-_ brand alloy with elevated hydrogen content:at low rates of
deformation. Six illustrations,
1/1

USSR UDC 669.715j669.046-54/55
YAKOVLEV, V. I., BALAKHOUTSEV, G. A., BONDAREVo B. I., qHVET-50 V., and
CHEREPOK, G. V.
"Meet of the Refining and Casting Technology on the quality of Ingot-s and
Semifinished Goods"
ftoew, Tsvetryye Metally, No 1, jan 74, pp 64-67
Ab3tracti A comparative study of the properties of metals produced by diffeivnt
refining methods was carried out by processing statisti("-al data, on the results
of the macrocontrol of ingot templets. It is shova that traditional refining
methods provides nearly the same purity level In H contont arA other Inclusions.
The contradiction of this finding with the results of other nseaxchers is
explained. The effect of the casting technology on the.purity of the metal
was investigated on ingots of DI alloy# _540 = in diam. The results show a
linear dependence of porosity on the H content. The volume of porosity In
the Ingots determines their disposition to stratification under deformation.
To retain the fine-crystalline structure of the ingot and to eliminate strati-
fication In stamping, the use of evacuation In the mixer has to match the
modification of the melt, Five figurest one table, five biblioLa*aphic references.
4 -

USSR uDc: 658.5,oll:621-37
GEVORKYAN , M. U. , K 0ZHEVIIEKOV, I. A., SHVETSOV, K. L.
"Standardization of Power Supply Devices for Electronic Radio Equipment"
V sb. Obmen o., om -v radioD om-sti (Experience Pooling in the Radio In-
du5try--collection of works), vyp. 1, Moscow, 1971, pp 10-13 (from RZh-
-Radiotelffinih~a, No 6, Jun 71, Abstract No 6V2013)
Translation: The paper contains a brief state-of-the-art report on the
standardization and unification work being done in industry to improve the
technical ana economic indices of power supply devices for electronic radio
equipment. Res ume.

USSR
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4
L-~; 10CLtC LhC E2:.M-Lt:er at L, &;.-pth Of: H Jl ia'ati.
a of -Cie sou-nd ~-=Jission surZace 7--o zhe molte~~
1/2

USSR UDC 669.71:669.046.517
ESKIN, G. I., SIMTSOV, P. N., and IOFFE, A. I., Moscow
"On the Relationship Between Cavitation and Degassing During Ultrasonic
Treatment of Aluminum and Magnesium-Containing Aluminum Alloys"
Moscoil, Akademiya Naulk SSSR. Izvestiya. Metally, No 6, Nov-Dec 72, pp
69-74
Abstract; It is shown experimentally and theoretically that effective ultra-
sonic degassing of molten aluminum and magnesium-contiLining aluminum alloys
requires treatment in a regime of developed cav-.i.tation. A dependence of the
threshold of cavitation in molten aluminum and magnesium-containing aluminum
alloys on the concentration of solid nonmetallic impurities is shOWn, a fact
whicb leads to an assumption that propagation of cavitation in molten metal
is realized on nonwettable solid impurities of the A1203 type. The analysis
of the results of experimental and analytical investigations shows that under
the conditions of cavitational regime treatment (P3B:i> 10 atm abs.) cavitation
cavities, approximately equal in size to solid impurities, multiply rapidly
(hundred- and thousand-fold) and gas pressure in them decreases to 10-8 atm
(abs.). Thir, leads to formation of reliltively large gris blefiholes due to
rectified diffusion that leaves the melt Pras a result of collapse lead to
multiplication of cavitation nuclei in molten metal.
111

7--112 010 UNC L A S S I F LED PROCESSING DATE--04DEC70
~TITLE--REMOVAL OF UNPOLYMERIZED NONOMER:SIFROM LATEXES -U-
,
:AUTHOR-(05)-KIL, T.A.s ZAD0R5KIYp'V.m.f,LUKYAN0VA, I.P.r SHVETSOVP N.V,t
~-VOLKOVAP N,~I.
.,COUNTRY OF INFO--USSR
SiDURCE-U.S.S.R. 262,382
R,EF-ERENCE--OTKPYTlYAj LZGBRET.v PROM. OBRAZTSYr TovARNYE VIAKI 19TOo
--26JAN70
DATE PUBLISHED
SUBJECT AREAS-MATE-RIALS
TOPIC TAGS-MONOMER, LATEX, CHEMICAL PATENTi DISTILLATION
CCNTROL X A R F, 1 114 G - - N 13 Ri E s rp I CT I QNS
CLASS-UNCLASSIFIED
PROXY REEL/FRAiME-3001/0836 STEP NOf--LJR/Oit3217(41/00i)i'O,')0/0000/0000
No--AA01'36?70
ss--lf- j 1"'D

USSR UDC 669.715:66.065.51:621.9.048.6
ESKIN, G. I., DANILKIN, V. A., and BOROVIKOVA, S. I., All-
Union Institute of Light Alloys
'VInfluence of Ultrasonic Treatment on theCrystallIzation Process of Aluminum
and Its Alloysto
V sb. Modifitair. siluminov (Modification of Silumins Collection of Works),
Kiev, 1970, pp 148-157 (from RZh-Metallurgiya, No 12, Dec 70, Abstract No 12
1742 by 0. PIDIENOVA)
Translation: Results are presented of experiments involving ultrasonic treat-
ment of crystallized ingots of aluminum and alloys (Al-Ma, Al-Mg, Al-Cu-Hn-Zr,
Al-Cu-4fn-Mg-Si, etc.) during continuous casting in a viato-,r-cooled crystallizer.
The authors determined the shrinkage, hydrogen content, mtructute, chemical
composition, and "chanical properties of the ingots. With ultrasonic treat-
ment, uniform EjIze reduction of macrograimover the enti~.-a ingot cross section
can be obtained. The effectivenes3 of modifying additivos (Ti, Zr, etc.)
mid the hydrogen content of ingots declineg 2-3 times. Apart fiom a
10 to 15;10 increase in strength aifd plasticity characteristics, ultrasonic
treatment makes it possible to equalize properties over t1he cross section,
which is of the greatest practical importance. Seven illustrations. One
table. Bibliography of 13 titles.
T,

0
TTSSR UDC 619.611.9-022.64-636.1+636.2+636.44-636,521.58
ONUFRrYEEV, V. P.; I?UDNIKOV, A. I.; MURAVYEV, V. K.; Lulrg:,%~
Yu. F.; CHIPITAYEV, Yu. V.; YRAVCMNNO, V. M.', ZAIUI.A.ROV, V. M.;
I. A.; NIKITIN, -A. Y.
I'Diatelic Immunization of Cows o' Tith Foot-and-Mouth Disease and
Prospects for Obtaining Mmune Milk"
Vladimir, V sb. Yashchur. T. 1 (Foot-and-Mouth Disease, Vol 1
Collection of Works), 1970, pp 160-172 (fron., RZh.-58. Zhivotno-
vodstvo i Veterinariy , No 4, Apr 71, Abstract No ~-7. 7
-h
Translation: DiRtelic immunization of cows trith foot-and-mout
dIs-ease antibodies -provides, lactoserum and iiiuiiunolactone with a
high conaentration of foot-and-mouth disease,antibodies. The
foot-and-mouth disease innunolactone- has Dronounced Dreventive
properties in research with baby mice,, gulnen, -oicus, -bull calves,
C)
and suckling pigs. Polyvalent foot-iind-mou'uh disease irriuno-
lactone has a more nronounced virus-neutraliZing activity with
respect to heterologous strains of foot-and-mouth disease virus
112
92

USSR
OTNUFRIYEV, V. P., et al, V sb. Yashchur. T., 1, 1970, pp 160-172
than the monovalent one. The high specific activity of the
foot-and-mouth disease lactone) obtained under biolougical n-rc-
duction conditions by immunization of cows with inactivated
foot-and-mouth disease virus, indicates apr6mising use of the
diatelic, immunization method under industrial conditions.

USSR UDC 542.91: 547 It 118
REZIMP V. S.3 SIIVETSQV, )3J___S_,..and PASHKUROV, N. G., Institute
of Organic and-IP_hysical Chemistry imeni A. E. Arbuzov, Academy of
Sciences USSR
"Synthesis and Properties of Pyrimidinylalkylphosphonic Acids.
Communication 5. The Synthesis of If - (Oxopyrinlidinyl-N) -Ethyl-
phosphonic Acids"
Moscow> Izvestiya Akademii NaWt SSSR, Seriya Khimicheskaya, No 2,
19733 Pp 402-406
Abstract: Several methods were investigated for the synthesis of
(oxopyri.midinyl-N)-ethylphosphonic acids. The reaction of 3-
)(8i--chloroethyl)-6-methyluraci1 with triethyl phosphite (I) at
150-1,55', resulted in the formation. of
methylox,
,1zoloL3,2-a]-pyriniid1ne and diet by], pham pho r ic, acid. 1,3-
bis-.Li9-(di~othylpliospfiono)-etliyll-6-methylur-aci.l. wit'i synthesized
by the reaction of I with I..,3-bis-(/3-chloroetliyl)-6-netliylxlraci1
at 160='L6sO,.,8-(3,6-dir,-ethyl-2,4-di6xo-1,2,3,4-tetril)ydropyri-
midinyl-N-1)-ethyl p-toluetiesulfonate (II) was prepared by the
addition of S-5 9 of p-toluenesulfonyl chloy,ide to 5 g of 3,6-
diinethyl-l-(P-Iiydrooxyetiiyl)uraci1 in 12 of triethylaminc, with
113

USSR
REZNIK3 V. S., et al., Izvestiya Akademii
cheskaya, No 2, 1973., PP 402-406
N4uk SBR, Scriya Khimi-
the temperature not .exceeding 40'. 2.2 g of II were obtai-iffied,
with a m.p. of 153.5-155.50 (from benzene). The dibutyl estev of
B-(3,6-diinethyl-2,4-dioxo-1,2,3i4-tetrahydropyriizidi-nyl-l-N)-
ethylphosphonic acid (III) was obtained in a36% yield by the
addition of II to Na dissolved indibtttyl phospbite, and boiling.
III is a bright-yellow oily solution highly soluble in benzene and
Ccl4 (nD20 1.4895; IF spectrum (1/, cm-1); i,675, 1703 (C:--0), 1270
(P--0), 1000: 102 5 (P-O-C) ) * Tile f ormatio.:-i of III indicates that the
presence of a tautomeric Off group in 3-(,8-hyr-1roxyethyl)- or 3-(~-
chloroethyl)-6-methyluracil on the 2 position of the pyrind.dine
ring makes possible the closure of the 5-membered oxazole ring.
For the formation of 4-oxopyrimidinyl-N-c-thyl.pliosplioiiic acids,
studies were undertaken on the reaction of thc,tosylate of j-(j5-
hydroxyetliyl)-6-int--tliyluraciI (IV) and 2-anino-3-(P. -hyclroxyethyl )--
4-axo-6-metliyl,3)4-dihydrooyrimictine (V) and with tviphenyl I)jl(.)S..
phite Orl). The reaction of IV with VI proceeds at 230-240o with
t -6-methyl-30 ,rii-,iidinyl-')-
a 51% yJ.cld of/Y-(2-oXY-4-oxo -dihydropN
ethylphosphonic acid (amorphous powder., insolub'.1eir. alcohol,
highly soluble in water; IF spectrum (V ~ cm--')'. 930-12,50, 111aximun,
2/3
- 44

USSR
REZNIK, V. S.3 et al., Izvestiya Akadeinii Nauk SSR., geriya Khimi-
cheskaya, No 2, 1973, 1:)p 402-406
at 1215, 2250-3600 (diffuse, P-011 and N-11), 1660 and 171S (C=O)).
The reaction of V and VI commences at 1600 and attains 2300 and
results in a yield of 421~ of /3-(2-~-airino-4-0>--o~-6-metl'Yl-3,4-diliydr-o-
?yrimidinyl- 3 ) ethylphos phonic acid (amorphous sybstance) soluble
ectruin (-P , c1ii--L):, 10803 117S, 1230,
in water but not alcohols; IF sp
and diffuse absorption at 2300-3500), and a 36% yield of 2,3.,4,5-
tetrahydro-5-oxo-7-methylimidazolo [3,2alpyrimidine.- (VII). The
formation of VII was attributed to an attack of the amino group of
8-carbon atom, whose elec
the pyrimidine ring on the trophilic prop-
erties were enhanced by the inductive effect of- the oxyphosplioryl
group. VII is a crystalline substdnce, highly, soluble in water and
moderately in hot n-butanol) and insolipble in acetone. IF studies
of VII showed that7- appeared at 3060-3125 ent-1, and 7/ at
N-11 C=O
1670 cm-1. The reaction of VI with 1,3-bis-(P- -oxyethyl)-6-methyl-
uracil at 16o-1650, following hydrolysis, gave a 33% yield of 1,3-
bis-()G-phosphonoetli3,1)-6-metliyluraciI and a 21% yield of 1,3-bis-
(j8 -phenoxyethyl)-6-inethyluracil.
3/3

USSR tmc 542.qix661.?18.i+547.854
REZNIK, V. S., and S YU. S., Institute of Organic and Physical
Chemistry imeni A. rib. Arbuzov go emy~,of Sciencos USSR
"Synthesis and Properties of PyTimidinylalkylpbosphonic Acids. 3 Communica-
tion. Reaction of Some Hydroxypyrimidizies with Dibutyl-4-eblorobutyl-
phosphonate"
Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimichsskaya, No 10, Oct 71,
pp 2231-2237
Abstracti Reaction of 6-metbyluracyl (1) =d 2-=W-4-hydroxy-6-methyl-
pyrimidine (II) with clibutyl-i~-chlorobutylphosphonoto (111) ;fore studied, To
a solution of 2 g lia In 200 ml butanoll 10.9 g of dry (1) was added and re-
fluxed for 2 hTs. The solvent was evaporated and 200 M1 dimethy1formarnide
and 24.6 g (III) were added and refluxed for 20 hrs. Then the mixture was
~filtered, the solvent evaporated and the residue chromatographed on a silica
gel column. Blution with chloroform gave pure lp3-bls-/-I~'-(6ibutylpho&Dbono)
butYl-7-6-methyl-uracyl (IV) - an oil# d 0 1.0653, nP 1.48E0. A solutiion
0 D
of i0 8 (IV) In CHM was heate and bromine was added to it
3
dropwise until the solution became perzanerxtly colored. ~Then it was cocled,

USSR
REZNIKj V. S.j and SWMSOV, YU. S.# Izvestiya Akademii Nauk MR, Seriya
:Khtdcheskayag No 10t Oct 71, pp 2231-2237
treated with active charcoal and evaporated. The residue was redisolved
in benzene, washed -with water, treated with active charcoalp A.1203and
allica gel and evapoxated yielding 1,3-bis-f4l-(dibutylphosphono)butYl2-5-
bromo-6-metbyluracyl 01)11 d20 1 2447 20 1.4865. In a similax way reaction
of (II) and (III) gave 2-a2no-4:r4'-'(Abutylphosphono)buty1 7-hydroxy-6-
(VI), 20 1.0WI 20 1
me.thylpy-rimidien d4 .4884 and dibutyl-41-(2-amino-4-
20
keto-6-methyl-3,4-.cUhydropyrimidinyl-3)-butyl~hosphonate:.(vii)I 1-1051,
d~
20 1.5100. Reacting (VI) with CH I gave 2-amino-4-keto-1,306-trimethyl-3,
nD 3
4-dihy-dropyrimidinium iodide, im.p. 244-2450. (VI) and (VII) itere brominated
in CHC13 to give the 5-bromo derivatives# an oil and a arysta.121ne product
M.p. 105408P respectively.
2/2

USSR UDC 542.91t661-718.1
REZNIKj V. S., and S Institute of Organic and Physical
Cbemistry iraeni A. UZOV, cadeMy of,ftienCDS USSR
"Synthesis and Properties of Pyrimidinylalkylphosphonic Acids. 2- Some
Properties of 4-OxopyrJmddinyl-3-miathylphQ$Phonic Acids"
Moscow, Izvestiya Akademii. Hauk 65SHo Seriya Xhinichaskaya, 11o 9, Sep 71,
pp 2006-2009
Abstracti The authors synthesi2ed the dimethyl eater of (2-hydroxy-4-oxo-
5-bromo-6-methyl-3,4-dibydropyrimidinyl-3)-methylphosphoiLic acid and the di-
(pherxyl-amide) of (2-hydroxy-4-oxo-6-methy,1-3i4-dihydrop),rJ-midizlyl-*-")-
inethylphosphonic acid by the reaction respectively of mathanol. and aniline
with the acid chloride and studIed the methylation of (2-'amino-4-oxo-6-
ine-thyl-3,L~-dihYdropYrJ-mi-dinYl-3)-mothylphosphor4a acid.. Some properties and
the IR spectra of the resultant compounds were.studied.

p
USSR UDC c~42. 92 +547-85
REZNIK, V. S. ,an. d
SHVETS~Y~~-YU- Institute of oz ai-~ic and Physical
Chemistry lmeni A. Ye. Arbuzov, j%cademy of Sciences,
"Synthesis of Solne
Moscow, Akade-nii Nauk, Seriya Khimicheskajya, No 7, Jul 70, pp
1646-1647
0
Abstrac 1. 1. 1 k,
was- established that in 2ynthesizing, -:~-'C; --omo -(hy d
-X-LxYL)-pYri--idona-4 ty~)c of compouvids, which are- ingoluble in nonpolar
solver, i
ts, is best 4, carr"j out the reaction in zinhydrous but-yl
alcohol at. 60-1200C, the bro-mination taking place vigi -6-u-1y, so that
the reac'j-ol
are completed within 5-10. min. After cooling,, Crystal-
line, product-a st
--ocipitate in sufficiently pure state so that for no,-
purposes they Yieed no furtlier purificat
-ion, MieltI.N, points of several
representative compounds are reported.

USSR UDO 632.~5
GOLYSHINt I. H.*O MONOVA, V. 1. , XLIZOaKA, L .P., 119 -OV A3 - X., MELINIKOVI?
N. N.,KHUSh=I1?OVA9 F. 1. 0 BLVMOV=8Hj Y N. I.0 S~MYSHia ta I Ii. A. I
and BOLONINAS YE. I.
"An Antiseptic-
USSR Author's Certificate No 355008p Div B, filed 11 Jan 71, published 1.3 Nov
72 (from RZh-.Tdmiya, Ho 14, 25 Jul 73t abstract No 14H616 2 by T. A. Belyayeva)
Translationi It is Proposed that 4t5,6-trichlorobenzoxazolinoto-2 (1) be
Uged as an antiseptic for noninetaI21c materials, and at the s=o time is a
bacte-ricida, which considerably extends the, sphere of its action# Compound
I la used in a 2-2.5% concentration. to control Moldt Wood-rotUng and wood-
discoloring-fungi,

k
USSR UDC 547-794-.543.422
A, R. G., NAMMMIA V. YA.,
IAKTY,-jI. 1., IGNATOVA, N. P., BOBKOV
and WL'NIK(JV, N. N.
"Some Derivatives of Phosphadiazoles-1,2,3"
Leningrad, Zhurnal Obshchey FlAinii, Vol 42 (lo4), No 9, SeP 72, PP 1939-i941
Abstract. Continuing the study of the reaction of phosphoms trichloride
with hydrazone8, A -Cyanoethy1hyArazones of~,acetone, acetophenone and p-
bromoacetophenone were reacted vith PC! 31 yielding derivatives of phospImAi-
azole-1,2,3. Benzoyl- and carbobutoxyhy-drazones of acetome reacted with PC13
to yield 2-substituted phosphadiazoles. Adding aniline to 2-acetyl-4-
methylphosphadiazole along the -P:C bond gave 1-anilino-2-acetyl-4-methyl-
phospbaliazole-1,2,3- Analogously starting with 2-acetyl-4-methyl-l-chloro-
1,5-dihydrophosphadiazole and 8-hydroxyquinpline, 2-acetyl-4-metharl-l-(8-
hydroxyquinolinyl)phosphadiazole-lp2.3 ~ms obtained.

LTDG 543-51 1 18
IX03-TYANWSPaY, R, C. PLE-KYWN011, V. G. ICTU.TWA., N. P., POT"M?., R. G.., ani
In-stituto Of Chemical phy-A Aal~ir-;v o.-LE, Sclon-Cs
"I'lass Spectm of 1,20-Phospha.0Jazoles"
Moscow, Izvestiya Aakadeali Nawk SSSH, Se7-lya Yhi;.,dd.,cska!rZL, NO il, Nov 71j
92611
Abatract Th
1 -3 authors studica th,~ electron im-mot-induced d-=~,, of a new clazs
f co=.ounds wi-1-h a 2-cooi-d-inale pho phorus at z. '.'a~ss :sp-z~ctrnl ciata corXi=
0
the arozatic character of 1,2,)-phosphaddazolcs,

USSR
MEMNIKOV, N. N.j UaQY4BII0VSKIY,_ N. -.I,, LYALYAKINA, N. P., and RUDNEVA,
-6-methyl-1,4-
"Synthetic Met*od for -Substituted Hydrazides of 2,3-Dihydro
-oxathiyncarboxylic Acit
USSR Author's Certificate No 364-51~, filed 20 Jul 70# ublished 20 Feb 7.3
-(from BZh-Khimiya, No 191 Oct 73p Abstract 110 i9N540
Translationi Title compounds with the general formula R'NIUI(R,)C0CSCIi 2CH 2OCO(Me)
W exhibiting biological activity are obtained by reaating 2,3-dihydro-
-;ethyl-1,4-oxathiyncarboxylic acid chloride with a hydrazine or -aoylhy-
drazine in presence of an HU (gas) acceptor# for example excess of fhe starting
hydrazine (R, RI# yield of I in %, m.p. in 96 being reported)l Ht HI 99,
184; Ht Ph, 86.5 (oil)j A, Ac, 26.80 130-~91 Ph, iso-Proco, 99, 108-9;
Ph. Etco, 67.2, (oil)j Ph, Mot 44.3p -~(oil)#

USSR
POZNANSKAYA, N. L., GOLOSKOVA, A. V., IVANOVA, S. N.,.0111
IlUalEal
N. I., and Y-EL'NIKOV, N. N. 0 Q J-~V S K ~IY ,
"Method of Producing N-Carbamoylbenzoxazolin-2-thiones"
USSR Authorts Certificate No 283987, filed 12/04/69, published 5/04171.
(Translated from Referativnyy Zhurnal Khimiya, No 4, Ha5cow, 1972, Abstract
No 5N668P by L. V. Razbadovskaya)
Translation: Compounds with the general formula (1) (Xutlower alkyl, H, halide,
R-lower alkyl, alkenyl, aryl, 6ubstituted aryl) are produced by the reaction
of the corresponding benzoxazolinthione with RNCO in the presence of a base in
an organic solvent. Four drops of Et3N and 10.4 of MOICO are added to a
suspension of 18.6g 5-Cl-benzoxazolinthione in 150 ml ditholaroethane, stirred
for 20 hours at 20*, the solvent is distilled, producing 12 g I (X=5-Cl, R=Me)
(Ia), yield 50%, mp 244-6* (Isooctane). I,can be similarly produced (given
are X, R,
x
1/2

USSR
POZNANSK&YA, N. L., et al., USSR Author's Certificate No 283987, filed
12/04/69, published 5/04/71. (Transiated,from Referativnyy Zhurnal Khimiya,
No 5, Moscow, 1972, Abstract No 5N668P by L. V. Razbadovskaya)
yield in %, mp in 'C): H, 11fe (IB), 50, 97-8; 6-Cl, Me,,78.8, 216-8; 6-Cl,
M-Cl C6H4, 84, 168-9; 5C1, Ph (1c), 78, 245-6; H, allyl, 60,5, 82-3; 5-Me,
Me, 30, 135-6; 5 lie, m-CIC6H4, 74, 164. Under similar conditions but with
boiling of the reaction mixture, the produ6t is I (given are X, R, yield in
2, mp in *C): H, m-ClC61141 68, 139-40; 5-G1$ nr-ClC 11, 70, 260-2. 1 has
6 14 "
biological activity. la and Ic in concentrations of 0.005% are superior
to Phygone in their effects on Botrytis cinerea, Fusarium Moniliforme,
Venturia inaequalis, Aspergillus niger.- la-and lb~are effectivis seed
disinfectants.
212
70

USSR UDC 632.95
BLINOVA, V. C., IWOOVA, S. W., KLIMKINA, L. G., SlIVe-TSOV-SHILOVSKIY, N. I.,
and MEL'NIKOV, N. N.
"Method of Preparing 2-Oxo-3-chrysanthe'ntoylhydroxy-~.iethylbenzoxazoline or
2-Thio-3-chrysanthemoylhydroxymethylbenzoxazolire"
USSR,Authors' Certificate No 259891, filed 2 Aug 68, published 12 May 70
(from RZh-Khimiya, No 1, 10 Jan 71, Abstract No IN597P)
_'CT'20COb'C'I'Te2tII%IH
Translation: Compounds of the general fonjiula (---_-Y)O(P13(X\
-0 o S)
===CXe2 [I; C6H3(X) ==substituted o-phenylene; X~H, halogen; Y- r
are obtai7n~d by the reaction of benzoxazolinones or berizo-xazolinethiones
with acid chloride of chrysanthemumic acid (11) in the'~presence of an HC1
acceptor, e.g. COO, at temperature 0-9* in an organic solvent or without
it. Example. To a suspension of 0.01 mole 3-hyd roxyme thylb cnz oxazo line-
thione in 10 ml anhydrous PhMe are added~0.04 mole C51151~ with stirring and
then, dropwise, at temperature 5-9* a solution of 0.01 mole II in 10 ml
PhMe. Tn~ reaction mixture is stirred for 5 hr at ^,20% aftier which
C5H5N-HC1 is filtered off. The solution is extracted consecutively with
a 5% IICl acid solution, an NaHC03 solution, an NaCl solution, and dried
over Na2SO4. The solvent is distilled off in vacuum, and the residue is
1/2,

USSR
BLINOVA, V. G., et al., USSR Authors' Certificate -q-o 25989.1, filed 2 Aug 68,
published 12 May 70 (from RZh-Khimiya, No 1, 10 Jan 71, Abstract No IN1597P)
crystallized from heptane, to yield 2.9 9 .1 (X Y- S) , malting point
91-2% The following ~'s are synthesized (indicated here are X, Y, % yields,
melting point, 'C): 11, 0, 90, 85-6 (heptane); 6-Cl' 0, 93, oil; 6-Br, 0,
91, 78-9 (heptane); 6-Br, 95, S, oil.. Compounds possess high fungicidal
activity.
T-1
2/2
43

USSR UX 5117-7945113-422
V, 1'. it.)
guq,!~PaLovs 1~_TOVA, N. P. and A111-Union
Scientific Research Institute o, Chemical Plant Prot,Cct,~ants
"Reaction of Substituted Hydrazones vit,hPhosphoms Trichloride"
Leningrad, Zhurnal Obshchey K Vol 40, No 7, Jul 70, D-P 1-5,01-1505
Abstract: The reaction oC pheny1hyalra zone U of aliphatic methyl Ketores idth
phosphorus tTichloride, resu-ltiiig in the formation of 4,alkyl Pnyl
-2-p~ n -1,'
phosplaadiazzoles, is e%tended to cover otner aiyIIh.,,-dra,,oni-~.-, and. 1',cyllaydrazon-es.
The interaction of phosphorus trich-laride vith acetone ae,,.e-yI:-IyIAraZOne (gave-
1-dilo Q-4 -meth %'1-2 -ace tyl- 1, -di' ny(L-o-1, 2, t, -Vho sphimIiazole (T), ti-.-- stnx-.U_,re
of ~Vaich was confir,,.:td by tl,.e pres-:~nce Of an azmrathine ~go-.q) (1633 Cn-1) 'and
carbonyl amdde (16-.91 iiin in its DI nue,~thva. I rl~ ~ri`h alcohl-I)IS
in tbe presence of triethyL=_,ine to ;,-,ive 4- thyl-1-allikoxy.."j-
ace
J.
dihydro-1,2,"-p-osDliadiazol-3 and with aro.-ra -.Lc arhines or nitr,3-,n hetero:~ycles
taken in excess to Five
diazoles. The action of triethylamitne on Igave
phosphadiazole.

USSR UDC 632,95
LYALYAKINA, N. P., 14ELINIKOV, N. N.p SHMSOV-SIIILOVS!~KJY, 11. 1.
"Method of Obtaining 1-Allcyl-3-iirylhexa,'iydropyriiiiidiii'()nes-411
USSR Author's Certificate No 290894, cl. 12 n, 7/01, (C 07 d),
fileU 22 Ila; 6B, published 20 J= 70 .(from RZh-Kh'JLian:U,[IL0 No 19 (11),
10 Oct 70, Abstract No 19 N635) by T.. it. B)EYAYB.VIj.)
Translation: Substances of the formula ACH2N(RIJCH(R")CIIf CO (I-)
2 Z:
(R = aryl-,Rf, RII -- alk-yl), which can be employed-in the production
of herbicides and plant growth regulators, are synthesized by the
interaction of anilides of beta-IT-alkylamino acids With IICIIO in
tho presenco of KOII. To a solution of 1.5 9 3A.-dichloranilide
of beta-li-isobutylslanine in 30 nil alcohol, 6, nil 3'~% f ormalin and
0.02-0.04 g KOH are added, the mixture.is boiled 4hours and evapo-
-rated, and 1.42 g j (R a 3,4-CI2G6H3v RI . iso-But R" - 11,
0
T20) is obtained, melting p Int
C141118G21-1 65 Alao~ nyrtthDsizod tire
tho following I (shown are R, RI, R111 evipirical fqjmuln. yield in
boiling pol7nt in OC/mm or malting point in.00).:. .0,4-012C031
1/2

USSR UDC 546-165:661-:b30
SHVETSOV-SHILOVSKII. N. 1. and PITINAI M. R.
"Synthesis of Moncchloro-, Monoalkylwnido-, and llonoalkoxyp--titaamidocyclotri-
phosphazines"
Leningrad, Zhurnal Obshchey Khimii, V01,41, Xo 5., May 1971, PP 1025-1028
Abstract: In the search for new pesticides among the cyclotriphosph-azines,
monochlorope.ntaamidocyclotripbosphazine and the monoalkylamido- and moncalkoxy-
pentuamido- derivatives were fomed by successive subetit,,Ations on a base of
hexachlorocyclotriptiosphazine using. amides of dissimilar~ a-umlil-tity- One
group of these com-nounds, 2-monoalkylaniido-2,4y4l6-tet-roxy(ii-dinLthylamido)-
6-chlorocyclotriphosphazines, foria the corresponding alkoxy derivatives when
treated with various alcoholatese

USSR. UDC 547.26'118
ITALINSKAYA, T. L., KHLUDOVA,~A. I., and
MMINIKOV, N. N.
5* -Phosphathiadiazoles"
0 2-2,3
Laningrad, Zhurnal Obshchey Khimii, Sep 71, Vol 41, No 9, pp 1980-198"
Abstract: Earlier research showed that the reaction o~ 1-chloro-4-alkyl(aryl)-
2-=ph~m-.yl-1,2-dihydro-1,5,2,3-phosphaoxadiazoles (1) with phosphorus thic-
trichloride yielded 1-cliloro-l-thio-4-alkyl(aryl)-2-pheiivl.-1,2-dihydro-1,5,2,3-
pbbsphaoxadiazoles (H). Continuous hea.ting of these compounds with phosphorus
thiotrichloride leads to the replacement-of oxygen in the ring with sulfur to
f6rm.1.5,2,3-phosphathiadiazoles (III). Addition of 6ulfur and triethylamine
hydrochloride fails to affect the (II):(III) product ratio formed in the
reaction of (I) with phosphorus thiotrichloride. Distilling~the volatile
reaction products of compounds (1) with phosphorus thioLrichloride by pai;s-
ing~_throagh dry nitrogen and the additionlof ferrous tr-Achloride facili-
tates~the formation of compound (III).

USSR UDC 669.71.018.9.4
SHVETSOV, I. V., B. YELAGIN, V. I., arid. KOLACHEV, B. A.
"Influence of Hydrogen an the Structure dnd Mechanical Properties of Ingots
Made of AK8 Alloys"
Tr. Mosk. aviats. tekhnol. in-ta (Works of Moscow Aviation Technological In-
stitute), 1970, vyp. 71, pp 58-66 (from M-Hetallurgiya, No 12, Dec 70,
Abstract No 12 G238 by authors)
Translation: The authors studied the formation of primaLy and secondary
porosity in semicontinuously cast ingots of AK8 brand aUay. The amount of
primary porosity increases linearly with an increase in hydrogen content.
The tendency of the alloy to form solid solutions, supersaturated relative
to hydrogen, intensifies with. a lessening of oxide-scale content. A super-
saturated hydrogen solution in the solid al-loy decowposes,~iwith the formation
of secondary pores 10-1.5 microns in diameter. Hydrogen embrittlement de-
velops in AKS brand alloy with elevated hydroSon content ~at lov rates of
deformation. Six illustrations,

USSR uw 582~288.4,,>-,633-511:632.938
and TOLQK.. P. P., Scientifie,Research Institute of Plant
Uction, Tashkent
Content of Free SH-Groups in Protein of Cotton Seeds Depending on Resistance
to Verticillium wilt"
Uningrad.. Ydkologiya i Fitopatologiya, Ito 4, 19T1, PP 4OT408
Abstract: Shifts in the content of SH-groups in cotton seeds folloving the
use of large a unts of mineral fertilizers were studled. The protein con-
tent of seeds from healthy cotton plants (varietieo 8,196 ana Akala 4-42)
increased in the course of matu=tion, but aecreased eharply in seeds from
vilt-infected plants after they were 50.days old. When the fertilizer rates
vere stepped up, the protein content of both healthy amd cUseased plants
increaaed substantially. The content of SH-groups dec.tvased as the seeds
matured, bat the amount was much higher in seeds from diseased plants. The
increase in protein content vith decrease In.free SH-groups vas correlated vith
increased resistance to -41t in the offspring. Plants gr=i from such seeds
vere more resistant to the disease. For example, in the Akala 4-42 variety
with a disease rate of 68% among the mother plants, thelmeidence of vilt in
the offspring dropped to 52-7%,as compared with 7q in the control.

Polywrs'~. and P41ymerization
USSR UDc 678.85-03
PAYZULL:ENt 1. N. 0 arA
I'Dianyl Esters of Alkyl(ai7l)thiophosphoric Acid"
Moscovs Plasticheskiyo Massy# No 119 1971p pp 29-30
Abstracts The authors synthesized diallyl esters of alkyl-, pelluWlthiophos-
phoric-acid, The synthesis occurred in two stages. In the first stage alkyl
(aryl)thiophosphoric, acid dichlorldes were obtaiaed by the reaction of phos-
Phorus thiotrichlorlde with aliphatic alcoholso in the second stage allyl
esters of this acid were synthesized by the interaction of tho laid dichlorldes
with the alcoholate of allyl aocohol. The structure of the resultant esters
me confirmed Iq -the results, of elementary analysis and IR spectroscopy# as
vell as Haman speatra, The esters are promising monomers for making some poly-
mers incombustile.

USSR UDC 576.C-5i.--.-a.o6
I-INRAYWICH, A. S., VEYM) A. A., 9jT,,DAR., Ye. A. M-kKABOVA A. P.;I,�Tr%F
R~ I., and TiMIUMVICH, L. Ya., IrIkutsk Itntiplague Institute of Siberia and the
"Determnation of the Cholero-enic Properties of Vibrios in Newborn Rabbits"
L7
I-bscow Zhurnal Mrobiologii, Epidentiologii i Imanobiolozij., No 10, 1972,
-64
PP cg
Abstract: Study of 65 vibrio strains from different sources in ne,~iiborn rabbits
(coasi6red a suitable mcdel for testing the pathogenicity of a given chole ra
Vibrio strain for mn) showed that all tha cholera straina could produce the
typical syndrone of cholerogeaicity, vhereas,the nona,-Zlu-tinable vilbrios could
not do so except for o--casional stTains (Ileib~-rgls group 1) isolated. from humarn
nicity~are mar~-ed dill- ntio-,
beings in cholera foci. The main signs of cholerove 'a I
ar - d an
of the lum-en of larze int-stine filled irith a light ty, ,.,pzxent flui d
marked hyperemia of the small inte9tine containing a viscour, yellow fluid
thz-mjzhout. Cholero~enicity was regularly observed after imtra-intcst4-ral
b
infection of 9-to 12-da~y-old ra:bbits N.,ith doses mnging from 103 to 100 viIbrios/
100 g of weiC;hu.
"Emaller doses generally failed to elicit any reaction.

2
~;C L AS S I' 'F I Eli PRUCESSING DATE--2Gsi,.'0V7C
ACTIC,`~~' FILTEkS -U-
'AUTHOR-( 03) - rSOVA, 'v.P., TISHCHENKC, k.O.t BELUdidVAt V.V.
CCUNTRY C F I 1N F 6-- U S S R
:.:.:ISC.URCE-ELEK. STA. L970, 41(- 22-4
DATE PUBL
S u- .3 J E C TA R C H E M f S T R Y
ICP I C TAGS--ILC_N EXCHANGE PE S I IN FILTRATIONI CHEMICAL REACTION RATE
CCNTACL IRAPM I Nu',--NO f- S TR I C-T 1611 S
'WXY 'P P11 '12 iC
S I'L Q 1 (.1 , 41 'ti/003/0- 2 024
f "SICIN
C III C Act,
WNCLASSIF

2/Z G 12 U L A S S I f 1 1) 0 C E:i S 1) i~ F 0 1,110 V 7
1 !~ C A C E S S C I i 3 - - 1, P 13, 7 1
R 4k C T / E X I R A C T - - - ( ti ~*jj~ -
3 S T, T R A C T I EXCHV41GE F 1 L 7 ER S v,' I T H
E G 1- -,1 E K I I f, I (-', NLX~:,,M,Gbi RESINS AFTE:0 L[-AVPi(; 1'rfii FILI'--::R APE
F C U N G,'-1 I C i, T"At T h~~S I- ~.~ 1 T 11 1 N T Lvk,'i A L KE GCNE A T 10,"; T"i: ccoNSUMP
T I Jh GF
REAGENTS A i) L ON 0 E -N S A I t S 13 L E S S 1-0 R ~ f H ~ F ORM F k V~ .1 L. T E -,1 5 1 P; V 1 [,,4 Cj F-
6 E T I E h P, E G L- K A T.1 0 N I T 1, 1.N i I I C H JS Tf-il CAUSE' U-1: I INCRf AS ED EXCIMNGE
UPERATIM;'~ Ci--,PilClrY, lt4E AUAISSI BLE FILTRiNFION AATF (;F: FILTF~~S WITH
INI'ERNAL AEGE; ERATL-J~ 1S 5UN-tiR; FOR F ILTER i -craipitkL ;-~EGE"EkiATION
MIS kATL i'-!AY 3E- HIOHEIZ, LCSSES IN ION EXCHAi4GER 41N-1 L-X'fC-RNAL
REGENFRATICN ARE lNGF (jRb\rL-R FHAN THOSE WITH -INTLKNAL kLGL-NEkATI0iN
FILTEkS.
UNCLAS)SIFIED

....... .. .... .. . .... -_-_....... ........
.029 UNCLASSIFIED PROC:ESS, 114'
_DWrE 30UL I iU/
TLTLE-7-CORROSION PROTECTIVE PROPERTIES GO 'SILICONE LIQUIDS AND DIOCTYL
SLBACATE.-U-
AUTHOR-(05)-SMIOTANKOv E~Aot SHEKHTERI YU.N,t NIKGNOROVY YE.M.1 YEROKHIN2
G.S., SHVEj�ZA4_V.T.
CCUNTRY Or_lt4FO--USSR
SOURCE-NEFTEPERERAB. NEFTEKHIM. (MOSCOW) ~.1970, (2), 14-16~
JATG PUBLISHED------70
SUBJECT AREAS--MECH,r IND.r CIVIL AND MARINE ENGRv MATERIALS
TOPIC TAGS--CORROSION PROTECTION, SILICONEr COPPER ALLOYt LUBRICANT
PROPERTY
CONTROL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/FRAME--1996/1674 STEP NO~--UR/0316/70,rOOO/002/0014/0016
CIRG ACCESSION NO---AP0118652
UNCLASSLFIED

029 UNCLASSIkEol 0POrE$S:lNG'OATE--3 OCT7C
CIRC ACCESSION NQ--AP0118652
ABSTRACTIEXTRACT--(U) GP-0- ABSTRACT. A RELATION UAS OBTAI~iED BETwlEZ:N
THE RELATIVE ELEC. RESISTANCE (R) AND THE RELATIVE POLARIZATION
RESISTANCE (R SUSP) OF THIN LUBRICANT LAYERS ON METAL SURFACES AND THE
ELECTROCHEM. CORROSION. DIOCTYL SEBACATE (1) OR VARIOUS COM. SILICONE
OILS (POLY (METHYLSI LOXANE) t POL.Y(METHYLPHENYLSILOXANE)~,
POLY(ETHYLSILOXANE1, POLY(METIIYL,G4Mt4ApTRIFLUORDI'ROPYLSILOXANIE)) GO Nor
PROTECT CU PLATES AGAINST A RAPID WT.~ LOSS IN 0.5h! NACL SOLNe Ai"JO HAVE
LOW A AND R SUBP VALUES (1.N 0-30.0PERCENT RANG6). THE AODN. OF 2PERCLiNT
CORROSION INHIBITORI SUCH AS "UREA SUCCINIMIDE119 TO I INCREASED ITS R
FRO14 5.0 TO 9,9.SPERCENTY ITS R.SUBP F~Om 0 TO 66PERCENTi AND
CONSIDERABLY REDUCED ME ELECTROCHEM,,CCRROSION OF CU PROTECTED i4ITH IT.

USSR
UDC 612.53i~612.58
SLONIM, A. D. , and Departm ent of W'cological Physiology,
Institute of CytoloMr and Genetics, Siberian Department, Academy of Sciences
USSR , Novosibirsk
"Chemical Thermoregulation After 'Accelerated' Adaptation to the Cole
LeningTado Fiziologicheskiy Zhurnal SSSR iment I. M. Sechenov, Vol 59, No 8t
Aug 73, pp 1262-1267
1A
45
Abstracti Metabolic and electromyographic reactions durin.-, che,-.,lical thermo-
regulation are compared for rats subjected to lone-term, tminterrupted "slow"
cooling, or Lnitermittent "rapid. ada-otation" cooling of -Yaxylng, Intensities and
durations. One-time or two-time cooling which caused a lowering of Internal
temperature to 300C and intermittent cooling (15 perio&s~of 2 minutes at -200C),
which caused no decrease In internal temperature, both ylelded long-term
after-effects, These included a gxeater internal sLablli~ty -to cooling,
lowered muscle electrical activity and increase In 02 re-qvirement. The
Intermittent cooling la Gaid to cau6e a more effeetive arlaptation to cold
than lonC-teria cooling.

V ob, n. Im, aredetva zashchity rast. (Chemical Plant FrGtective Agents)
Hoscow, T 3, 1973, pp 126-127 (from BU-Khimiya, No 20.1 Oct 73, Abstract
No 20N4171
Translationt A TLC method has been proposed for qualitative determination of
the conpoaltion of technical (Me0)2PSCl The analy~ Wal; carried o-Lit
on plates witb a fixed layer of silica gelp grade KSK JJI the solvent system
hexane-06H6 (2-i1). The chromatograns were developed with bromphenol blue
followed by illumination with UV light. I contains the following impuritiess
~KOOPSCI and,(MeO) PS.
2 3

USSR UDC 632.95
MIL'SHTLYN, 1. 11., ROGATYKF N. C., SUVETS K D MVNIYOV,
N. N.
"Procedure for obtaining 0-arylsulphonyl.carbanoylocimes"
USSR Author's Certificate No 316638P filed 21 Oct 68, published 14 Dec 71 (from
RM-Khiniva, No 12, Jun 72, Abstract Vo 12N459)
Translation: Compotmds with the general fornula RR'C = NOC(O)MU302A (I) 'R and
R1 = alkyl or aryl; A = aryl) with acaricid activity are obtained with inter-
action of the correr~iponding oxime with, ai-ylsulphonylisocyanate. In the presence
of Et 11) 0.015 moles of PhSC~TICO are added to a solution of 0.015 moles of
meth;1 i,opropyl ketone oxime in 50 m-e of benzene; it.is mixed for 4-5 hours
r
at 40-500; the solvent is distilled off and I is obtained (E = Y4, R1 = iso-Pr,
A = Ph); the yield is 95%, the melting point.is 3200 (benzene). The I (R = Me,
A = Ph) is obtained analoGously (R' is recalculated, the yield in melting
point in OC): Et, 74, 126; 14e 97, 324-5; 95, EQ-

USSR Or; 61 2.95
s A P a,.71uzov, Yu. u., and
CIMRINAKU11 1.
"Dicresyl Compound"
V sb. Khin sredstva zashchity rast. (Chenical Ar!eritr- Tor Plant Protection --
collectio
n of worko), vyp 1, moscow, 1970, pp 56-60 (Trov. ji,'Ih--.ILbinAya, vo 11,
Jun 72, Abitract No 111099)
Translationt A mixtur-a of Latai- a-rid pa'ra--cTasyl VISIATS of 11-methyl=I-a.-Ac
acid, called dicresyl, is recoxxended for use aTainst ticks on allir-als ax.'d
birds. The mixture in a ratlo of I&I Is no 1a:.-3 cffec-t;Ave thitn pw-e
meta-cresyl ester. Dicresyl can ba synthesized by roacting
T.Axtuxe of
mools with phosgene in the =evence of acid-bindiii'4: Ugentc with Guhsr:~IiVjnt
nethylamine treatment of the resultant chlorofoviate esterj. Iqy amidining
absolute cresyl carbonate,. and, by ereacting a mixture of cxmsols with C17~fj
P.~ Y. Popov
64

USSR uDd 632.1)5
POL-141Kul, if. ti. D SAPMNI-17 YU Ii FUGHINA,
H. YA. , and TITUM, -.B
'!TrIcbIoromstaPIIoS-3 Cor4pound"
V sb. nba aredstya zashchity 3-a-st. (Chemical Agents fo;c Flan."L Protection
collectior, of works), vy-D I , flloscol,, 1976,- PP P-8-32 (fron R-Zb-XhIiAya, No if,
-L - 9")
Jun r-, Abstract No Mil U
Tranalationj Trichlorometapho*-3 of formula(DEO) 3-2,4t5 (1)
witIh a boAlling point of 1270/0.151 d20 1 OkU5 a 20 1) 1,5Y:-'0 iu synthesized.
by re"cting (EaO'I(Ito'P(5)C1 with Campouiw--'~ I iz us-ed
against thQ larvae of botflion, nitoo w4 Slioa. in oxi'lor to purify tho 80,f
'commercial DzIoduct, i.,iparities. am contlnubualy *tcwi--dAuti:W.e~I utilizing a
'10-100c" C aria a
glau.5 packing colu=. The purified produat is dried Pt
preLmure of 20-30 1uh for 1 hour,. A diag;am Az pnovii-WF] of thu colu:j-1 for
puzIfying I.

ussl~ UDC 632.954:547P,11,95. 1
x n
STONOV, L. D. , 1; L 71; 1 M V , N. N., All-Union Scientific J?.osoa7ch
'Institute for Chenicc. L of P*Ianl- -Protection, Roscow, S.1--a-a
Committee for Chemistry USSR
THerbicidal Activity of Some Darivatives of Carbanic Acids"
~.oscow, Xhiriiya v Selfskom M_hozyajst,:.re, Vol 8, No 0, jun 70,
pp
Ab,~, t- rae t scrio.- o- fl-diadli 'wiinoothyl t-,,sto-s (-,f (or
a- I .,Y.L 1:
2, yl) cn_zb=,,.4c acido and their cuaternary w7aronix% with
trimpth~,,-l (or triethyl) thio-phosphato was i,,..,:id investi-
gated in Oogard to horbicidal, actuivity ~aj, 1a'_,w.v,,ta,-y can-
di t ~,_ on 4; T`- w, that an increaso ii., Liu,, Lan.-
o f t h o a I -,a dl cr-~ 'I 1'rwT. 2 carbon atomg tl-w noi,"cl-
f 17! a~ C -G a V;L avylcarball-.~Ic Ov~ar's
Y.
0 ~,;7,re actlvc than the zcapoctive nonch arii 1111;,1, e, d anajo~tl:,62.
C Ili j U,
r 4 a' J_. dnoothyl aster:3 o- ..a, icij.vb,:~"rl,
Tho
of ~4.0 b.,_ar~!! cJU*b,-,,-;k1O 1-CJ.d

;H 11 Ii IHim- 1 .1
USSR
BAKLMETIKO, L. et, -al, Mnin.10ra v So I s korl K-h a a
I;v e, Vol
No 6, Jun 70, PP 57--t)2
Int.-oduction o' the thiophosphoric aci d anion inc-oeaaed the h,~~-bi
cidal activity soinowhat, keeping the: relationship of the claain
length to activity.
212
R~ WN16--i" "'i:ii imm "H
;ii4 W6 " d 6-4id

USSR UX 5)'T.j?6,i,8
M'NI]KOV
N., D.) and
"DI-splacement Of Pseudohalor'ens in Plaosphinates and -~ho,nllinc 0:~~iesll
Leningral, Zhurral Olb o lz c I I c-,, 1.2-Aitrli i, Vol 40, NO 7, Jul 70, 1) 16'
?2
Abstract: A previou5 article by the authors showed tl-,at ic~ pho-1,1 on"tc-~;
a]Jt
y1 groups "'ith sucli a's the
groun, which ca-n be risl~l.~~lo,,.,;,.!,,;.~-t-,ns-,
are displaced by a2lmxyl LroU-DS ,In-4er aCtion O-P j,,1
of alkalies. C-o-i-t'l-i-omim- work in this area, thc-
C- a
pseudo,;izao~en I--- s- -, ~11'lli
in pho phin-,ttel; E3
under analogous con.,litions. It was fowid that th~e p-,cudohalo,-,,'eIl r,ro,llp if;
mach z, re readily d.-Lsplaccul by an sUkzoxyl
I O-up -1.n
oxidea t4an in illeaker bacer, (e.g. "ria, n
ca to i.:,-ed
as Catalysts.
�

USSR
UDC 547.2kl-1615.777/779
YAGNYUKOVA, Z. I., SMTSOTrA_SH MEL! MY
N. Do, and I GV, N. N., All-
Union Scientific R666 of Chemical Plant Protectants
ster-amides of Acylated ArylthiOphosphoric Acids"
leningrad, Zhurnal Oloshchey Khinal, Vol 41, No 1, Jan 71, pp 84-88
Abstract. Twelve ester-amides of acylated aryl thio_hos];~ te of the type
L) 'Ia 13
CH_COCcH4O(S)(OR')MM", vhere RI is CH through Ch, tLad. R" ir. either It or
3 3
CH , 'were obtained from the corresponding dichloroaryl thiophobThates by treat-
3
ment with alcohol and subsequent amidation.~ Me resulting ester-amides possess
pesticidal activity comparable to the activity of the dioJ-'kyl derivatives, but
are considerably more toxic warm-blooded animals.

"Method of Preparing O,O-Dialkyl-O-acylnaphthyl Phosphates or Thiophosphates"
USSR Authors' Certificate No 257501 filed 5 Nov 67, ~ublislied 20 M-N, 70
(from.RZh-Khimiya, No 1, 10 Jan 71, Abstract No 1N56519
Translation: Compounds possessing pesticidal activity of the formula
(RO)(R'O)P(X)OY (1) (R and 10 = lower alkyl; X = 0 or S; Y - I-acetylna-ph-
thyl-2) are obtained by the reaction of (R0)(R'0)P(',X-)Cl trith acetylnaphthol
(II) or naphtholate in the presence Of K2CO3 or NaOlf at 70-110' in organic
solvent. For example, 0.62 g Na is added to a soluti6a of 5 g II in 50 ml
HePh at 90* and stirred 30 min; the unreacted Na is removed; at 100' 5.1 g
(Et0)2P(S)Cl is added and heated 8 hr at 1100. On cooling, 50 ml water is
added; the organic layer is rinsed with~saturated solution of K2CO3 and
water, and dried over MgS04; the solvent is distilled off, to yield after
distillation I (R = R' = Et; X = S), yield 63%, boiling point 159-62*/0.14 mm,
d4 20 1.2003, ;~20D 1.5740. The following'.1's are prepared analogously with
a yield of 40-45% (given here are: R = R', X, boiling point in 'C/mm,
1/2

USSR
m. 1., et &I., USSR Authors' Certificate No 25T501, filed 5 Nov 67,
published 20 May 70 (from RZh-Khimiya, No 1, 10 Jan 71, Abstract No B1565P)
4 , n Me, S, 172-5/0.2, .1.2544, 1.6050; Me, 0.156-810.18, 1.3548,
d 20 20D):
.1.5630; Et, 0, 155-60/0.1, 1.2177, 1.5465. A mixture of 3.72 g II in 50 ml
ThMe, 3.49 g (MeO)(EtO)P(S)C1 and 2,9 g Y,2C() is heated 7 hr at 90' to yield
I (R = Me, R' Bt; X S) boiling point 178-3*/0. 2 t1w, dj~ 20 1.2396,
ii2ft 1.5850.
ei,
2/2
- 21

USSR UDC 632.95
SHAPOVALOVA, G. K. ROZ-11ANOVA, V. V., M&RCIIENIKOI L. F, ,G U 1Z ,IM.1.
SHMV,'AT5,-,,kYA, T. N., MIKHALY-UTINA, YE. B.,,4S1[V4TS0VA-SKLGVSKAYA
and HELINIKOV, N. N.
"Insecticide'
USSR Authors' Certificate No 244800, filed 9 Feb 68, j)ublished 15
Jan 70, (from RZh-Khimiya, No 20 (11), 25 Oct 70, Abstract No
20 N,1547P by S. LYUB101SKAYA)
Translation: The authors suggest as insecticides compounds o,-` the
formUla (R0)(%,10)P(X)(01?!1) (1; 11'and R1 = Mer Et; 1,111 acetyl-,
halwten- or alkyl-subutituted pheny). or naphlhiyl; X 0 or 3),
whieft are obtai"ed by the interaction of diallryl rhlorol)hosphates
or thiophosphates- with t4e corru r, pond ing, phenpiG av waphtho].-- or
pnenolates in MeM 1-lith 1(2G03 at,7-5-80o ot- S11 an i n I,- rt, -, o 1 V C! r, t a t
90-11,00. The 'following ah- obtained: I (R = R1 , T' = sub;:,tiLtuted
phenyl; given are It substituents, in thi ph(~avl- rinif, X, brj,ilict-
26 0
point in 11C/mm, d,,~ , n2oD) Me, 2-Ac, S, 120-6/0.IJ4, 1.2465,
1.5372; S.t, 2-Ac, S, 110-4/0.091 1.191L, 1.5-171; Zt, 3-r-,,,c, s,
j
120-4/0-1, 1.1378, 1.5260; Me, 4-Ac-, 0, 1.24-30/0.03, 1.2539, 1,5070;
Et; 0, 130-3/0.1, 1.1846, 1.4970; 4-Ac, S, 1.1-0-3/0.08,
1.2648, 1.5445; 4-Ac, 5, 127-130/0.011., 1.18,22? 1,5230; 1,jo,,

USSR
SHAPOVALOVA, G. K., et al., USSR Authors' Certificat., 'No 244300
2-Ac-4-Cl, S, 136-43/0.1.5, 1.3519, 1.5510; Et, 2-Ac-.4-Cl, S,
126-30/0.13, 1.2531, 1.5295; Et, 2-Ac-lia-Cl, ,;, 125-7/0.1, 1.2542,
1 5325; %,"c, 2-Ac-6-k-al, 0.1-9-7-910.11, 1.3555, 1.5118; mie, 4-Ac-2C1,
0
2-3/0.15, 1.3556, 1.5218; Et, 4-Ac-2-N-L, 0, 159-61/0.12 1.2699,
H5 p
1.509Lj; Ile, 4-Ac-2-C1, S, 135-43/0.11.8, 1.3463., 1.5538; Me, 2-Ac-4-Me,
S, 133-8/0.15, 1.2340, 1.5-405; We, 2-Ac-5-111e, S, 1.32-8/0.17,
1.1864, L.5388; Me, 4-Ac-2-Me, S, 3,53-6/0.13, 1.2400, 1.5465;
Et, 4-Ac-3-111a, 0, 150-1/0.2, 1.1740, 1.5015; Me, 4-Ac-3--Iele, S,
155-61/0.22, 1.2404, 1.5442; Et, 4-Ac-3-1,10., S, L52-4/0.2, 1.1656,
1.5290; Me, 2-Ac-1i-1-fe2j S? 130-2/0.05, 1.19"17, 1.5330; Et, 2-Ac-4,
541e2, S, 135-40/0.05, 1.13L2, 1.5200; Et, 2-121:GO, 0, L30-2/0.1,
1.2565, 1.4930; Me, 4-EtCO, 0, 1.49-52/0.08, 1.2273, 1.5070; I'lle,
4-EtCO, S, 142-7/0.1, 1.2264, 1.5420;
.1 (R It' = Et, X = S;
R11 = substituted phenyl; given here ire sulbstituents- in tile phenyl
)C/mm, djj20
nucleus, boiling point in n2OD), 4--!,c, 121-4/0.1,
1.2333, 1,5368; 2-Ac, 120-4/0.13, 1.2245, 1.j318; 4-.%c-2,5-&%`
'(!21
156-8/0.05, 1.1896, 1.5375; 4-EtCO, L48-52/04L, 1.1-95, 1.5321.;
I (R11 = 2-acetylmhthyl; given here are R, It', X, boiling point
En oc/mm, d~20
n D): Me, Me, 0, 156-7/0.1B, 1.3548, 1.5630;
Et, Et, Of 55-60/0.1, 1.2177, 1.5465; Me, Kit-, S, 170-3/0.2,
mmijap, Mw

'USSR
SHNPOVALOVA., G. K., at al., U,(j-SR,,AuthorsI Certificate No 244800
L.2396, 1.5850; Et, Et, S, 159-62/0.14, 1.2003, 1.5740. I's are
approximately as active as chlorophos against 114usca dories-Eica,
Calandra orycae and Porthetria d.is2ar and have7f6 oxicity
or warm -b-f-oo-d-ed animals.

tF
USSR UDC 5147.261118-122.07
ET and M"E'LINIKOV, N. N.
TYRKINA, T. S., Sh-V,.,._nM
"A Method of Synthesizing O,O-Dialkyl-S-(I-Oxo-2-Alkylmercapto)-
-Ethyldithiophosphates"
Moecow, Otkrytiya, Izobreteniya, Promyshlennyye Obraztsy, Tovarnyye
ris Certificate No 268428, filed 17 Jul
Zhaki, No 14, 1970, Autho
68 p 25
Abstract: This Author's Certificate introduces a method of
synthesizing 0,0-dialkyl-S-(l-oxo-2-alkylmercapto)-ethyldithio-
phosohates of the general formula
(RO)2P(S) _C_ C112SX
0
where R is an alkyl, and X is an alkyl /-sic7. As a distin-uishin~,
feature of the patent, 0,0-dialkyl-S-chYor'Ecyidithiophosptiates
are interacted with mercaptans.in the presence of acid-binding
ent isolation of the~pal product by a con-
agents with subsequ
centional method.

USSR UDC 621.762.01:669.295'787'784
BOGOMOLOV, G. D., and MgM,IN, G. P.
"Conditions for Producing Compact Specimens of Titanium Hydro--cycarbide'
Tr. In-ta khimii. Ural'sk. nauch. tsentr. AN SSSR Worlcs of the Chemistry
Institute of the Ural Scientific Center of the Academy of Sciences USSR),
1971, vy . 23, pp 56-61 (from RZh-Metallurgiya, No 1, Jan 72, Abstract No
1G264 by S. Krivonosova)
Translation of Abstract: The article considers the conditions for producing
compact specimens of Ti hydroxycarbide according to composition and powder
grAin size during sintering at 1500-1600* in vacuum, aa well as during hot
pressing. Porosity of sintered specimens increases with the growth of x
in TiCx0y and particle size of the initial charge. A xeliable method for
obtaining nonporous specimens is hot pressing. One t4le. Bibliography
with three titles.

USSR UDC /-546.821'21'261 -/:536.631+536-66+536-75
CHERNYAYEV, V S 5HMLK I G.F. and GEL'D. Ural Polytech-
nic Institute
"Heat Capacity, Entropy,and Enthalpy of TitaniLtM Oxycarbides at
Reduced Temperatures"
f4oscow, Izvestiya Akademii nauk SSSR, Neorganicheskiye materialy,
Vol 8, No 3, Mar 72, pp 459-463
Abstract: Discussed here is the temperature dependence of the
'thermal capacity of Ti oxycarbides of a close composition to the
quasi-binary section TiC-TiO ( i.e. with x + y::~~ I Use was
made of a low-temperature adiabatic calorimeter to measure
55-300'K) the heat capacity of equiatonLic Ti monoxide. and mono-
carbide as well as their relative solid solutions of Ti C x 0 I-x
Jhe entropy changes in the entbalptes,and the characteristic tem-
peratures ~f Ti oxicarbides are calculated from the experimental
1/2

USSR_
au
CHERNYAYEV, V.S., et. al, Izvestiya Akademii n k SSSR, Neorgani-
cheskiye materialy, Vol 8, No 3, Mar 72, pp 459-463
data. It has been possible to approximate the experimental data
on 'the thermal capacity and entropy of Ti oxicarbides using the
simplest rule of additivity. It is suggested that the linear na-
ture of the relationships between the heat capacities and entro-
pies is related with their tendency to ordering. It is noted that
the regular drop in the characteristic temperatures of Ti oxycar-
-n
bides with the increase of oxygen in them is caused basically by d
increasing screening of M-M intera ctions. 3 illustr., 2 tables
16 biblio. ref

USSR UDG 546-831'171.1-21
MOVSKIY, S. I., SHVEYKIN -L,D, P. V.
ZAPI TU LIN YU. G., ALY4 , G. P. , GE
"Domain of Homogeneity of Zirconium Oxynitride:With NaCl Structure,
at .1,5000c"
Ve
Moscow, Zhurnal 1% onzanicheskoy, Khi-mii, Vol 16, No 2, 1971,
Prp 315-317 -
Abstract: The binary systems Zr-lor,and Zr-O have been studied in
det91l; however, there is no informa-tion on the ternary system,
and especially its cubical component (of NeCl type). Only a f e,,Y-
papers have appeared dealing with certain characteristics of
ZrNxO with low oxygen content, and those dealing with partial
ZrOPrIT systems.
Using 901.9 percent pure Zr02 and oxynitrides of composition
zr1!O.76Oo.lP and :7 rNO 8700.12, and also 99.9 p~rcen
t pure Zr
powder as startin,? mGter'als, the
authors prepared.samPles for
X-ray analysis and determination of Zr and 1.1 content.
1/2
2 6
t LlAi I
U14, IVKI ~,M~ ~t i V, -1,Y11 0.0 1 hi HE d W!

MS S R
ZAY1-.ULI7T, 1-U. et al, Zjhuirnal Neor~-,an cheskoy ~Ji ii, 'loll
No 2, 19711, -op 315-317
It was found thpt at 1,5000C and 10-5mm pressiire, the donain of
T
homogeneity of zirconium oxynitride with -NaCl ntruct-ure is IL-n-Ited
(7max*=--:z-0.3, while the lattice oeriods, within these lLmits, vary
only very slightly (from L1.574 Lo 4-575 X-). J?or ~Z:r'l,,:0y, vacant
Doln's.are a dis.
L, tinctive feature, both in the sublattice of the
metal and in tb.!:-:t of the nonmetal.~

V26
USSR !JDc. 546.821'2
BOGOMOLOV G. D., LYTJ31MOV, V. D.~ and "LY~*iOVSKIY,
S. 1, Institute of Chemistry, Ural Brancrt. oi., them Academy of
Sciences TISSR
"Physicochemical Properties of Titanium oxyezirbides"
Moscow, Neorganicheskiye Materialy, Vol 6, No 11, Nov 70, pp
1961-1963
Abstract: A study was made of the stability of' a series of TiCxO
preparations toward acids, and alkalies, and also to air oxida- Y
tion. Ti, CII~oujldl CEree, and r2 levels were determined in pre-
parat'Lons made Dy vacuum sintering of mixturt-!s of starting oxide
"'iOl.03 and carbide TiCO. 4 to form tablets 1.0 x 1 0 trim in size.
Tir,.O preparations were bound to be stable towarfl concentrated
dyiulte' H(Ill and 112S04, both at room tompexi~,turo and at
and
elevated temperaturef';. The nyycarbide proved t:(- DC
T4e ox-carbide
most acid-res4stant of' the hot-prdssed swipUts.
nhowed the rreitest resistatice jio a-' oxida-
T~ r j
1. * 10
loft '1,100, and L250 c.

USSR UDC 546.821'26'21
BOFOYOWV, G. D., ALYAMOVSKIY, S. 1" ~BVEY and 1~
KIN, G. P., H.BlljoV, V. D.,
Institute of Chemistry, Ural Bra-nch of ill",e emy 0 Scienceis USSR
"Certain Structural Characteristics of Cubic Titanium Oxycarblde"
Moscow, Neorganicheskiye Materialy, Vol 6 No 8, Aug ?0, pp 1405 1408
Abstracti This report presents information on the axea of single-phase
existence, concentration dependence of lattice periods,,and deg~ree of
filling of the elementary TiC 0 unit cell. Seventy sperimens ifere made by
x Y
pressing carefully ground nixtures of the initial compon,-~nts, followed 'crj
sintering at 1500 0C and 10-? nm H9 for 30-50 hr. Sixty of the specimens
were found to be single-phase specimens. The specimens were subjected to
X-ray and chemical analysis. A phase diagram of the Ti-TiC _TiO system
-3 1.3 1.3
at 15000C and p - 10 mm Hg is presented. Data on the fall mutual solu-
bility of cubic TiC and TiO phases accompAnied by fornation of the Tic 0
X Y Y
oxycarbide axe confirmed. It is assurx,-d that the concerst;ViLtiOr. dererdClIce of
the lattice periods of' TiCX 0Y is complex. The lineirit"Y of the :Nxiction. n
f(x) is confirmed, where no
tl~.e number of carbon rartlHen ~rj ci T.IC 0 ujnit
call, 1/1 X-Y_

1/2 ~019 UNCLASSIF16 PROCESSING DATE--IBSEPTO
',,-T-ITLE--0XIDATION OF THE OXICARBIDESt CARBONITTRIDES AND OXINITKIDES OF
TITANIUM -U-
-AUTHOR-.(02)-SHVEYKIN9 G.P., SLOBODIN, BOV.-
COUNTRY OF rNFO--USSR
~~_,SOURCE-POROSHKOVAIA METALLURGIIAv, VOL* 10, FEB. 1970, P 63-68
PUBLISHED ------- 70
I~_~SUBJECT AREAS--MATERIALS
T~OPC TAGS--OXIDATION# NITRIDE, TITANIUM CARBIDE, CHEMICAL REACTION
.~'~.-.::MECHANUSMr THERMAL STABILITY
~CGNTROLMARKING--%O RESTRICTIONS'
_-DOCUMENT CLASS--UNCLASSIFIEO
-.:.PROXY REELIFRAME--1989/0590 STEP NO--UR/02261'rO/010/000/0063/0063
CIRC ACCESSION N10--AP0107137

019 UNCLASSIFIED PROCESSING DATE-13SEP70
~CIRC ACCESSION NO-AP0107187
AMTRACTAUXTRACT-W) G11-0- A13srR6CT, STIJOY OF Tlil: nXIOATION PROCESS OF:
TIYANEWI CARBIDES, TtTANIU4 CARSONITRIDES, AND T11"ANIUM OXY-NITRIDES,
w- USING A 0ER-1VATOGRAPHIC METHOD. A DISCUSSION IS (,-!VEN OF THE CF041CAL
PROCE55ES ANO OXIOATION MECHANISM. IT IS FOUND TI-14T THE STABILITY OF
~TITANIUM COMPOUNDS STUDIED DECREASES-IN THE FOLLOWING SEQUENCE:
-CARBONITRIDE.St OXYNITRIDES, ANO OXYCARBIDrES.z

USSR
t rj -a of
3 i Eym.", G. P and SDO30DIA, 13. V., institute of Chexis oral F*fi-lia
A.
0T7Ce7l!eatRy 7ol Sciences Ussi
"O)ddation of Titanium 0;,Wcarbides, CarborL, trides, and Oxynitzidosll
Kiev, Poroshkovaya Vetallurgiya, No 2 (86), Felo 70, Lp 63-63
Abstract: The authors 5-Ludy the process of o3cidation of cxyccarof-des
The stvdies were,done on -a 4~rivato-rao'-
yn-44-rides "-L*YC L - 0 1.i
(?iC,O,,), ox- .~ ~l .
;r) 'n air.
of '/min to a te;ml orature of
*th heating at a, rate
U
tion prGd-acts ~,,ere constantly removed fro.,,i the reaction :apace thlo cour:~e
of the exncriments. The complex process of oxidation of~thc L-lit-Jal r.-.ate.-ials
may in gencral be divided into low-teirmorature and
kletallic titaniwm has the highest tc-lperature for initi-ation G.", oxidatiar.
6800C) and,the highest reaction rate on both sta-res. TitLnium c.:xbidli~ ~--s t*-e
lowest tommerature for initiation of oxidation (4001C). 1'.ne ra'~.e of o.,7iafatior.
i or t- 0 in 4"ho lov-tc-m-perature sta-e is o-er of
carbid-
magnitude gre-rter fcr metztUic titanium. As the car~boa conwIL-ration is ir-
croased in t1taniun oxycarbidat;, tho def,reo an,--'I rxte~ of.oydidal~lon in lo;,-
temperature stage increases. TitaniiLm dioyide is t-ho cUol' pr~)iuct of oxidation
1/2

USSTR
STrZYM, G. P., et a!, Poroshkovaya- Zetallv--riya, No 2 Bo" 70,
of titanium o.Vcarbides. Titanium carbonitrides are not ZLs ri:~adily an-- c:).-.1-
-oletely oXi-diZe4 to tJ anium diodde as are 'itanium. oxyCarb-'
4 t tit. 11 - iaaz.
Taniu,-.i oxq--nit -d
ti- - - ri es is initiated at a higher temperature than- is the case for
ox-jearbides and carbon-itrides. The following equat4cni d~iscribe oxidation of
these compounds:
TiC-,Oy+ (1 + x - 0-5Y) 02 Ti02 + XC02,'
Tic "I + (1 + X) Oo TiO2 + XCOz + O.V~?. (2)
--y
TiN.,cOy (1 O-5Y) 02+ TiO2 + 0.5xli2-
The stab roor4tricles o~~,ni-
ility of the compounds decreases in the series a;4
trides oxycarbides.
2/2

USSR UDC 8-94
DMMDIIW, V. D.
"Thirteenth Session of the Scientific Council of the Academy of Sciences USSR
on the Problem of "Physical-Chemical Principles of Production of New Heat-
Resistant Ma-terials'"
Moscow, Neorganicheskiye Materialy, Vol 8, No 11, Nov 72, pp 2,058-2,059.
Abstract: The ;3ession mentioned in the title was held in Pervourallsk
23 through 27 INfay, 1972, discussing the theme "Refractories, High-Meltilig
Materials iind Coatings." Two-hundred seventy persons from 76 organizations
of 31 cities from 7 union republics of the Soviet Unicui tool; part in the
session. One-hundred seventy reports were read in the; two plenary and two
sectional sessions, covering tile following topics: refractory materials;
oxygen-frec compounds; oxides and coatings, Subjects covere-d by tile reports
included; prediction of the productionof refractories; physical-chemical
principles of the use of zirconium diaxide as a refractory; new trends in
the technology of densely sintered ceramics; methods oF production of synthe-
tic mullite; the properties of refractory materials based on electrically
melted periclase and periclaso-chromite materials; problens of production of
1/2

USSR
UDC 8-94
SHVEIKIN, G. P., DYUBIMOV, V. D., Moscow, Neorganicheskiye Materialy, Vol 8,
No 11, Nov 72, pp 2,058-2,059.
oxygen-free compounds of boron nitride and aluminum nitride; the interaction
of refractories with metal slags; study of the kinetics and mechanism of solid-
phase synthesis of oxide compounds; phase equilibria in oxide systems; new
methods for synthesis of refractory materials based on zirconium and hafnimi
dioxide; the properties of individual and complex oxides. Certain shortcom-
ings in the development of work on the problem of refrictories were noted,
including: insufficient utilization of modern methods of theoretical and
experimental physics and solid state chemistry for detormination of the
general regularities of the structure, chemical bondin;~ and properties of
refractory materials; insufficient utilization of mode3-n methods of physical
and chemical investigations, methods of experimental planning and computers;
slow transition from laboratory studies to practical utilization of results;
insufficient prediction of properties of refractories considering developing
trends-in technology; and insufficient coordination of the activities of
scientific resea-rch institutes and applied research organization.
2/2
10

USSR .UX 5k-lQ?.2'546.824126,21
ALMAMMKIY, S. I., ZAYIMIN, YU. G., SMYKIN, G. P., and GELID, P. V.,
Institute of Chemistry UNTs, Academy
"Concentration Relationship of the Degree of Filling the Unit Cell in Cubic
Titanium 04rearbide"
Mscov, Neorganicheskiye ~hterialy, Vol 9, No 4, Apr 73, PP 596-599
1.
Abstract: Results are reported on a study of the effect a' composition on
the completeness of the TiC 0 lattice for x + y = 0.7 to x + y = 1.2, which
practically encompasses theXeyntire regiIon of homogeneity for titanium oxy-
carbide. The characteristics of 39 senples of TiCxoy were uBed (13 from this
work and 26 from previous works) to determine the gquotionfl for oxycarbides
with x + y equal to 0.70-1.20 using the relationship nTi = f(x) and components
A, B, and C yielding nTi = Ax2 + Bac + C. It is noted that twinning defects
exist in the lattices of oxygen-containing cubic tricomponent phases of tran-
sition metal-base oxycarbides and nitrocarbides. I figure, 3 tables, 22 bib-
liographic references.

7.
USSR
UDC 621-375.82
BORODULM, V. 1. K&LYkVKIqA, G. M PAK, G. T., PETROV, A. I., CHERNOUSOV,
N. P. , ~�JWMKI I., YASHLMOV,~ V.
"Some Properties of Degradation of Heterolasers"
V sb. Kvant. elektronika (Quantum ElectroDics-collection of works), No 3, Mos-
cow, Soviet Radio, 1972, pp 108-110 (from, RZh-Fizika, No 12, Dee 72, Abstract
No 12D977)
Translation: An experimental study was made of the catastrophic and slow
degradation of heterolasers. It was demonstrated that catastrophic degradation
occurs for aver;~ge light energy flux densities (2-4).106 watts/cm2 and local
densities of 107 watts/cm2. Depending on the light energy flux density the
service life of the heteralasers can vary from several minutes to 100 hours
and more; catastrophic degradation in this case is the limiting case of slow
degradation under the effect of radiation. ~ Heterolasers with a radiation
power in che pulse of > 10 watts, a frequency.of 6 kilohortz,and a pulse
duration of 100 nanoseconds aref capable of~operating more than 100 hours with-
out a significant reduction in pourer,

USSR uDc: 621.315.592
ANDREIM V. M., BORODULIN, V. I. ,KoNyAYEV, V. P. , PETROV, A. I
PORTNOY, Ye. L., SHVEYKIII, V. I., Physicotechnical Institut,e imeni A. F.
Ioffe, Academy of -!~'cire-ne.-ets"'~'.'O'-f"~YSI?USS.R,:Lenir-grad
"Spatial Distribultion of Heterolaser Emission"
Leningrad, Fizika i Tekhnika Poluprovodnikov, Vol 6, No 9, Sep 72, PP 1739-
Abstract, The paper presents 'he results of e"cerimental and theoretical
studies of the lum-anous field of emission from a heterolaser in the short
razige and long range zones for -various thicknesses of the active region and
outside dimensions of the cavity. The distribution of the luminous field
on the :mirror fece of the cavity crosswise of the active region which was
obaerved in the experiments can be satisfactorily described vithin the
framework of a flat triaxial waveguide model. The angular distribution of
heterolaser emission in the plane perpendicular to the heterojunction Plane
can be treated with a fair degree of accuracy as diffraction of a waveguide
vave on the oDen end of a fiat metal waveguide filled wit-h a dielectric.
The pattern of the long-range field is symmetric relative to the normal to

USSR
ANDRETEV, Y. M., et al., Fizika i Tekbnika Poluprovodnikov, Vol 6, No 9,
Sep 72, pp 1739-1748
the mirror. The directions to the principal maxima are determined by the
angle of refraction of the partial waveguide plane waves. Modes of in-
creasingly higher orders are stimulated in the active region as its Vidth
is increased, The pattern of the short-range field (order of the mode)
does not depend on either the cavity length or the Dumping. In heterolasers
with wide active regions, three-dimensional modes of t-otal internal reflec-
tion are stimulated which impair the quantum efficiency and increase the
divergence of emission. These modes can be suppressed by increasing the
ratio.L/1, TM modes being suppressed faster.

USSR UDC 621-378-55
GOR:3t~IIEV, lr.k., P;u:, G.T., FETROV, A.I.,
YAGH-ji"OV, 1.V.
4Depcndatmc~ 01' TIL--roahold CE Gcio2rutica Of Injoction Lasers On'The Duration Of
Tho
No 5, Y, Y 97-99
1121v studiod of the threehold oV vemar-
-uec~'i ind junctions in tbe oys-
ation of lac~!ra Ath diff
t= on the durution of t'oo paher, of the Vxrpinv current in tho in-
-Z) asr~c. The aro detariairin-I of tho efl.'octive lifetimo
of ILI-a c3t3cfrorio for throe of 'uoor divd~~o: vith diffused p-n
junctIcr. j,,L;nc), uith ona list-orwiunction (,--.J2.5 nccc) vid with two
mico'. Tho mnoc-ccond pulcoa or the pimping current in
the 2-10~; n,:ioc with r. buildim-, upfront loan th-an 1 nbac waro shm"ped
- h 4-11.2 011L, E: 117G11-8/1 tfi%,ratron =1 divn~-rsed pulce raps-
v"it, L- linas. The
van from NO liz, to 10 1,111z. f:eceivud by editorv, 22
j ri Y 71. 2 1" 1 tn b. roP.

USSR UDC 621.315.592
n GORBYLEf,
ALFEROV, I. I., M.DIREYEV, V. M., BELOUSOVA, T. YA., YVI POLIN V.
V. A., PAIK, G. T., PETPOV, A. I., PORVOY, YE. L., Cft-i~NOUSOV, N. P.,
YAS11cliumov, 1. V.
"Effective Injection Ileterolasers Operating in the Wavelength Band of 7,400-
9,00o
Lenin-rad, Fizj.la i Tekhnil,-a Poluprovodnikov, Vol 6, No 3, 1972, pp 56S-569
Abstract: Results arc! presented from a study of the cliaracteris tics of C-ffec-
Live heteralzirers rarliatitif in the uravelenj,,th band of ~,1100-90000 X .1c room
temperature. The ti-Al Ca As-p-Al Ca As-p'~-Al. Ga As lie terojunctions, were
x 1-x Y I-Y. x . 1-).
obtanined by epitaxial growth from GaAs-Allts solutions. All the investigated
diodes had a rabry-Perot resonator. The threshold current density, the excer-
nal differential citimitum efficiency and the radiation power per pulse et 300'1,
are tabulatcd for various modcls of die lasers. Gra.phs are proserited sho~-,incr,
the mean values of tlie t.hrcishold current donsity nnd Oe extcrnal differential
quantun efficle-I-ICY as functions of- the emission quantum -,,icr,;y and Lae temper-n-
Lure depc;,.:c,.ncc, of the e%,Lernal difforonLial. quantum flie threshold
curront VJLLII all Jrjcrcn,i(- Jn ttjq),~raLuru iccor(!--
i
, to the Jkiot.%-, Lrn., [V. i, P.L al., rTP, Na 1, 11;40, 19671. Up to
ng
1/2

USSR
AIXEROV, ZH. I., et al., Fizika I Tekbilika Poluprovodn kov, Vol 60 No 3, 1972,
pp 566-569
A temperature of 250* K, the external differential quant-um efficiency does not
vary, in practice, but then it decreases with temperature. The data demon-
strate the ppsibility of obtaining generation in the continuous mode at 300*K
up to 7;700 A.
212

USSR UDC 621.373.826
PAK, G. T. , "JJ:T4*-WV, A. I., I ~AYEBOYN, YE. G. , C HEMN 01,1S.W.T, N. P. , SHVEYKIN, V. 1. ,
YASilUMV, 1. V.
"Internal Parameters of Injection Lasers at 300" K"
V sb. lwai-*- ((~,kj~jntu-,j Ejectj:t)jjjcs-- collaction of works), 1,10sco-.1,
No 5, 1971, pp 9,~",,61 khidha, No 1, 1972, Abstract D'c ID350)
Translatic.,.: T'-c 7-ct,;-ults of c.-perimeatal. studies of the basic p~irnmetcrs of
OIC aCti-VC- 71d.-,0 C, based on diffusio~i and epita-zial yp-n-trar-
sitions ai,:1 ii
-1 the G~zAs-A!As system -ire described. It is
demonoLraLcki dwL i)1:Lt~iu1a-1-;crr, with two-sidcd IiiniLad.on have bvt:tLr character-
istics: i.c x1lidjJ!'cation codfid.c...-It is 1.0*.). cm/mmp, Lhe inversion
Current and t 26 cr-1.
dcn-,ity :~.l kilm-y.~Ilcm ~lic! losrc.,, nic. ii Yhere is I
MusLrat'Jain aml 'i 6-cutry blblioeraphy.

IJSSR ITDC 535, 37
n,I'AB, 0. D., ',%kCA'LIYAS, V. I., FROLOV, V, D. and , IIE
RUN, I. A,
ItMeasurement of the Pho'Columinescence., Pho toe lectro-1---i-tive Force and
glectroluminescence of Semiconductor Naterials and Structilres"
MOSCOW, Pribony i Telchnika Eksperiineita, No 4, Jul/Au- 71, pp 225-226
Abstract: The paper describes an installation for high-resollution mo-asurei,,,i-n-nt
of the photoluminesceiice, photoelectromotive fA:jrce and electroluraincsc,~ncc e!,
semiconductor structures and materizils. The dri-vice is bivied on Lhe princip-le
of normal reflection of a Ii,-ht beam. 'rile excitine, 0-nd optical
systems are combined to enable the use of short-froew; o)jectlvc, len~3es- This
appreciablv reduce8 the 5ize of the light spot and Lhim, incvonsc,!~ rerolotion.
The e-;--citing amd t--Xcited light are separated by a warrot,7-band intcrferencc
filter. Placement of the ourface of the specimf%, nonnal to the beam (if- inci.-
-e- force and
dant light makes it Possible to woasure the phoLoclec!~rvrioti%
eIecr-ru-'jW::d-rescence o*f dic-de structures.

iown D
~OU
S NO I I) I VIS9'd ON-ONINM loldit'lo:)
9Nl9',J0:! 310
Nn I K) 1. lH "I I I Vil 9NI 11016 S S 3'DW d-133lS--S9V.L DWI
S'lV 1891111,1 9N 93NJ'MJ Ci fq'V 'l lAl DONI *HD~W-.-Sll;)~V 103,rigns
OL ------- 03HS11EMd 31V
I L-91) '(2) '0L6T I*z n 'A 'IS-DAZI-33,enas
'8ssn-D,~N1 40 UiAno'-
It
N I W) HD I d19, /jo w ~,~InVSO)ldWI'YlN'dV9V-df~AN I 'AAM-AH S 470 -'dOHJn%,
-n- 3 1 (1 -13141t,'0 iV N1
S3i!.n,, '!:!PIS 20 9MI(ITHS 9,H'i N11 3 ~l H193 9 A I 10 V1 9-4 H 10 N 0 11 VIN, I V, ? 3 1 :~; c1 -- 3 -).L I
0tA0NET--]-lVQl 9fqlSS3).,6dd C1.3 i 3 1 S IS V.1 T." F~ seo Z/T

Z/z 025 UNCLASSIFIE01 PRPCEMING DATE-- 13NOV70
CIRC ACCESS10il 1110--AP0123889
~_ABSTRACT/EXTRACT--(U) GP-0- A3STRACT. A MATHEMATICAL A~JALYSIS OF THE
FORCES INVOLVED IN THE SHARING OF STEEL TUBES IN A: SPECIAL DIE IS
PRESENTED, WITH SPECIAL kEF. TO THE TRACTIVE FORCES PE,101q.ED AND THE
OF wHICH THESE ARE MADE UP.~ THE TOTAL iR.'%crIVE FORCE
INCLUDES THE FORCE REQUIRED TO.DEFORM THE MATERIALIPASSING INTO THE DIE,
THE FORCE REQUIKED TO OVERCOME FPLICTION IN THE LATTER, A-IJU THE FORCES
ASSOCIATED WITH THE PASSAGE OF THE TUBETHROUGH TH:E PULLIW~ R.OLLS. THE
NTAGES OF THE "PUiNNEL' CONVENTIONk T E 1-1, 1 U E S A' E
-ADVAl MiTHOD OVER
CONSIDERED.
4
':~4,i. Wil 4,11M Mill-111"M MIMI! 1,1111"Mil I IMF U.'MAIvulifilli III -diii I annnim! i mrimir-IIA-0:444 41 i~ 1.11 Mill M IMIMPT Ilvil Ii ffilk INUN 911

USSR UDC: 539.3:534.1
BRUSIMMaY, A. DP
0=0141, ~Yu_ ~14u
"on the Natural Oscillations of Cylindrical Shells Reinforced by Transverse
Stiffening Ribs"
V sb. Reschety, na Orochnost~. 'Vyp. 15 (Strength Calculations-collection
of works. No 15), ~)oscov, "Mashinostro"I'enlye", 1971, nP :--12-327 (from
RZh-Mekhanika, ITO 7, Jul 71, A~stract Ho TV201)
Translation: The paper presents some results of a !itudy of the nat--u-al
oscillations of cylindrical shells reinforced by trunsvense stiffening
ribs. Bending, 5tretching and twisting of discrete, ribs n~rranged eccen-
trically relative to the middle surface of the shen -are ~-.aken into accoimt
as well as all componenti of forces of inertia of tl-.,(! she).1 and rib:~. The
number, rigidity wid location of the ntiff~!ning rtbq wer(! vttried. It is
14ty
shown that a-,-Dlicab.--- of the theory of structurally crt~iotroric -9halls
-to the given problem is limited. It is also shown ho-w the natural fre!-
quencies of =reinforced chells are affected by the fastening of their
end faces (including elastic connections). The exact solution of equations
of oscillations of the shell in displacements is used in solving the prob-
lem- The frequency equation for the reinforced shell is d~-rived by a
special matrix method. Authors' abstract.
106

WIN 11
USSI,
I :UDC 629-7FT40141:525(47)
BAL,kYPV, N. F., GFOD,-C-VSKIY. G. L., DANILOV, Yu. I., , Z A.k-.h,A. P-0.11 V,.
KP,AVTS---V, N1. Fi. KUZ-VJN, R. N VAROV, 14. Ya. , MOROZ, OV, F, f,7~
NIKITIP, V. Ye., PEROV, S. P., PETUNIN, A. PI. , UTKIN, V. IJ., and
SHVIDK 3 G
"Scientific Data on the Flight of Automatic Ionospheric "Yantar"
Laboratories"
Uch. zP-D. Tsentr. Aprorridrodin--im. in-ta (Scientific Notes of the
Cantral Aerohvdrodvnar1i.c Institute) 1071, Vol 2. No 2, PP 5e--65
(from Refer,-t~Lvnyy Zhurnal,Raketostroyeniye, No 11, Plov 71,
Abstract IR'eswne)
Abstract: Launches of -.,utomatic ionosnheri.c "Yantar' " laboratorie~--
With frasiec-Us rni~--nes up to 100-0-10 Kin altitudr-s v.,ere
conriucted, with ai,! of ~reonl-yricnd roc!'-~ctc,, for ti-p- purpose Cf
s, t u o y I n!7 -orw;r,--,tr3 o-P controlled fli.1-ht, in LII)Tie-v of the
atr, osr;h ere. Per Ior,~i,,inc F~ of r.1 a-i ni
spheric conlitir,n~~ stud'.01, P~~,rameters ch:~,ricterisirg I-hp
%-A U
iOn C T) 1, Ir-ma ntor.-ction, ~~S W011, cl~-- T)~~-rz~lnrs c. f
neutml meqrzurfd. qcientif;-c on conducted ox-
perimen-Its IF, -r--r-ntnd. rf!~errnces,
HI MIt 11-111H ~i

PZOMSAIS Voa D-110NING HOULIZ OF TPE INTMNATIONAL STANDARD ATMkN.MjK);E
fArt'_clJby Pro!assoxn_S,._.j_ r_P~fXjLov,j:_2__"h h. ya.
Condidater of Geographic Sciences
Ye. G. Shvidkovskiv,~~-ihdittkAsz:,-ft, Central tcrologjcal
Observatory; has idroloriva, Russian. No 7. !'J172, sub-
mlttej.~ july 1971. ?p 36-44ij
A study wa--,, made a! the vertical prof'. 1e a' t4s, cs*dn annual
ta=puraturv of the hemisphere and alqo~modeja of the stnndi~
ard :t=tzphcrc for different latitudinal zones and possible
longitudinal variations. The characteristic. of the dats
used to construct the models a' the standare atmonithere is
presented.
Introjuctlon
The rx-voonr proponals with respect to erpatitilon of the intarTiarlonal
tandar,l dutuapherL are prezented in the pzacedures for "rcutiork of the
resolutions of the =oetinr of the Worklxt~ Group of the ISO jIntornationel
Siandarditation Organization) TK-10/RG-6 26-29 May l9ti-9. The uutu.Lug group
adopted the rc~olutiort to charge the USA (A. E. Cole) and the USM (Ye. G.
Shvid'-,.ovskly) with prepar-nP, t" design for models of the International
ritanda~d atmunphert! for altitudes of 20-60 km (the =an distribution and the
two reflecting the
- 4els latitudinal and seasonal variation.,;). In the resolution
there is a reconnendation regarding the ne~enslty of selecting the tempera-
ture proftle clogeit to t4c mean annual profile with re,;vect to t1ho, torthorn
Y/ Hemisphere for the mttan nadel. At the m"ting of th- -~rklng group. It wits
recoltnt:nd ar. d~.,4irablo to expand thh st4njard to 30 kei. convider-
inii the data !n the 60-60 km layer as a supplement to thr. basic profile,
0 'Tito given proposala were presented by the Soviet Union tOr MIMillAtion
by the 3I.XLh Working Croup of the wentieth Technical Commicalcto of the Inter-
national Standardi;,,atcion Organization (ISOITC/Wc - 6) - Standard Atmomphere
meeting of wbich wat) hold in France (Poeurbevoir) In FebrwAry 1970.

1/2 048 UNCLAssi rtlEo' PROCESSING DAt~--230CT70
L N. H I N 0 E UP ER A M
WITH THE AID OF RESONANCE SCATT RING EFFECTS -U-,
.,A'UTHOR-(03)"SHVIDKQVSKIYp YE.G-i KOSTKPA O.K., CHAYANOVA, E.A.
-COUNTRY OF INFO--USSR
SOURCE--KOSMICHESKIE ISSLEDOVANIIA# VOL. 8# MAR.-APR. 1970, P. 310, 311
~.:"'DATE PUBLISHED ------- 70
-SUBJECT AREAS--ATMOSPHERIC SCIENCESt PHYSICS
::.JOPIC TAGS--UPPER ATMOSPHEREv RESONANCE SCATTERING, LASER RADIATION,
ATMOSPHERE COMPOSITION
'~..CCNTROL MARKING--NO RESTRICTIONS
:.-DDC))MENT CLASS--UNCL4SSIFIEO
PROXY REEL/FRAME--1994/1761
CIRC ACCESSION NO--AP0115590
STEP ND--UR/0293/*YO/OC,31000/0310/0311

--230CT70
PRIKESSING DATE
2/2 048 UNCLASSIFIED
~CIRC ACCESSION NO--AP0115590
..ABSTRACT/EXTRACT--(Ut GP-0- ABSTRACT. CONSIDERATION OF THE POSSIBILITY
F %
-USING RESONANCE BACKSCATTERING OF LASER RADIATION PROPAGATING THROUGii
0
THE EARTH'S AT140SPHERE AS A MEANS OF STUDYING THE COMPOSITION OF THE
UPPER ATMOSPHERE. ON THE BASIS OF AN*ANALYSIS OF THE RADIATfVE
TRANSITION'S CHARACTERISTIC OF CERTAIN STATES FJP NITROGEN MOLECULES* IT
IS SHOWN THAT THIS liACKSCATtERING EFFECT, ALTHOUGH HARMFUL FOR PURPOSES
OF COM4UNICATION AND INFORMATION TPANSMfSSIONt IS,USEFIJL FOR STUDYING
THE FINE STRUCTURE OF THE COMPOSITION.OF THE ATMOSPHERE. AN ESTIMATE IS
-MADE-OF.THE EFFECT OF RESONANCE BA:KSCATTERING DUE TO ABSORBING NITROGEN
ID IONS IN THE EARTH'S ATMOSPHERE ON THE ENERGY ENTERING THE
MOLECULES AN
RECEIVER OF AN OPTICAL RADAR.

/>1/2 010 UNCLASSIFIED PROCESSING DATE--IISEP70
-T:LTLE--METEOROLOGICAL ROCKET SOUNDING -U-
~.AUTHOR--SHVIDKOV-SKlYt YE.G.
,",.COUNTRY OF INFO--USSR
I GIDROLOGIYA, 1970v NR 4t PP 28-35
--DATE PUBLISHED---70
~~'SUSJECT AREAS--ATMOSPHERIC SCIENCES
_i'TOPIC:_TAGS--MFTE0R0LOGtC ROCKETv SOUNDING ReCKET
~XONTRDL MARKING--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
REEL/FRAME--19B7/1034 STEP NO--UR/0050/70/000/004/0029/3035
CIRC ACCESSION NO--AP0104432

0123

T.
USSR UDC 669.3/6.476(088.8)
S
BUBYALIS, Yu. S., -1,VUV G. P., BYARNOTAS, A. K., and MATULIS, Yu. Yu.,
Institute of Chemistry and Chem--f-c-al Technology, Acadeny of Sciences Lithu-
anian SSR
"Method for Electrodeposition of Copper;Tin Alloy
USSR Authors' Certificate No 305206, Cl. C 23 b 5/34, filed 7 Jan 70, pub-
lished 13 Jul 71 (from RZh-Metallurgiya, No .1, Jan 72, Abstract No IG196P
by G. Svodtseva)
Translation of Abstract: In order to obtain adherent deposits of alloys, Sn
in the form of Na stannate and LN~03 are introduced into the electrolyte in
the following ratio of components (in g/liter): Cu pyrophot3phate 15-35,
Na stannate 20-35, K pyrophosphate 170-240, KN03 5-17. The process is carried
on at pH 10-11, D = 0.8-5 a/dm.2 and temperature 40-60'. The Cu content of
the alloy is 70-95%. The composition of the alloy does not.depend on current
density, but current efficiency declines approximately,froin 100 to 55% with
a rise in D. With a rise in pff of the electrolyte from 10 to 11 and of
temperature from 40 to 60* the Cu content of the alloy drops; by - 15%.

-LA-S I Fl ED P1,110CESSUNIG DAH-090C170
112 034 UNC I
.,!T`ITLE--0N THE KINETICS OF PHOTOINDUCED C~YTOCHRUME CHANGLS u,;
ELTGTHICRt-s000SPIRA SHAPOSHUNIKOV11 CELLS' -U-
~~-AUTHUR-(04)-KUFJIN, L.B., DUdRUVIN, V.,N.,~ ADAMOVA, sl-lvlNAK, Yu.I.
",COUNTRYOF INFL~--USSR
,._S0URCE--llIKRO8IOLQGIYA, 1970, VOL
39, NR 2v PP 264-266
~-DATE PUBLISHED----70
1: -SUBJECT AREAS--BIOLOGICAL AND MEDICAL SCIENCES
-TOPIC TAGS--PHOTOSYNTHESIS, BACHRIAt CULTURE METHOD, LIGHT BIOLOGIC
EFFECTt RESPIRATION
C GNTR OL ,4A.RKlNG--N0 PESTRICTIONS
.,.DOCUMENT CLASS--UNCLASSIFIED
STEP NO---' R102201'rOI03qlJO2102.-~lt-IO268
:PROXY REEL/FRAME--1933/14tl NJ
C IRC ACCESSIO.~,i NIG--AP0054274

Z12 034 UNCLASSIFIEP P1,')CESS1i',,'G 0ATE-090CT70
CIRC ACCESSION NO-AP0054274
~A(_1STRACT/LXfRACT--(U) GP-O- A3 STRACT MAX I M A 1. PH'_'TUI~NJUC~D ABS04BANCE
CHANGES OF CYTOCH.RiONES Al- -'j,2G 1*1 ARE OBS EJRV ED 1;"j FC701_HJQRHJDCSdIRA
SHAK)SHNI.K.DVII CELLS CULTIVATED UNbER, .11-LU11,111ATION GF- Lu'4 LIG"ir
INTEINSI TIES 110 PRIME3 EAC';-CA PAIME2 S E C ) A ~"l 1) T r t - i 1 : L 0" 61 F H M I C(3, 1., r
PHASE. IN THE AGL:0 CELLS TH~: AMPLI I*U[)E OF A S IG%1AL I') AND IHIS
EFFECT IS ACCUMPAINIED BY CHANIGES IN THE KIINETICS 1]F (;YTL'1c-i-if1OmE
REACT 1.0'.S: UNDER AEL,061'.C C'GNOITIUN'S N"Ll ABSOLIAINCI: CHANGES A:kE': 0~6; V i-_ L)
NHILL IN bEAIRi-TED SUSPENSIGN THE FAST PHASE OF LYrI-j'CriRblIE-~ RE-.0ucric',111 is
ABSENT. THE ADMINISTRATION OF ACETATE OR SULPH[Oe'.: RESULTS IN 1-*0,11'LETE
RESTORATION [IF BOTH ANAERe3IC AND AER061C PROTOIN-VOCED (,14ANGES OF
CYTOLHROMES. IT SHOWS DEEP CONNECTIONS BETWEEN PR.Ij4AW( PHOTosy,,,irHET IC
REACTIO14S AND PHYSIOLOGICAL STATE OF THE PURPLE BACTERIA CELLS.

USSR UDC 63p-.95
IU=N) 11. N., FIIATOV, L. N.j, SHCHERPAI-=) Yu. I. SIMQL-C"IrNKO, P I and
BVINDLERMI, G. S.
"Preparation of Technical Chloro-lsopropylphenyl Carbamate in Crystalline Form"
V sb. Khiin. sredst-va, zashchity rast. (Chemical Protection of Plants --
collection of vorks), 111o 2, Moscov, 1972, PP 31-35 (frola RZ-11-1ali-miya, NI-3 22J
25'1,ov 73, Abstract No 221,
'570 by A. F. Grapov)
Translation, In r-annin- the reaction of M7ClC6HjI:'CO with absol-ate in
the absence of solvents, it is easy to obtLill chloro-iso-orop ljtenyl
in the fona of a melt, from which it can be.processed quite efficiently in
dnm crystallizer to obtain a crystalline praduct-. Exa-UMIc. 65 rl of
iso-PrOH at 50-650 is addud a drop at a time to IQ,,) ml of* %-~
f0 111,2 ")
r 30 rzin at 60-70'P4 and the excess iso-PrOll dirAillcLl c)S'f at 9o0'
The nelt with a maltin- , "' 45 to 500 is then pla-ced in the crysta~..~z~~r.
point
Yield of chloroioopro-pylpiwnyl raft1w..!ite 93.2,,t; mclting point
laboratory rodal of the ec)nri--tn of " hollow wr1ind.-!r (150 m:.-. b ii
and 50 r!n. in dia,",atar) Cooled 'by water. Date of crystal.]Jz-ation 10 to U
Izg/irr--/hour.

M. 632f.95
and BASKAROV, YTI. A.
GCRSXAYA, T. V,
ItA Method for Preparing Esters of i4-Carboaryloxy-o-hydroxylamin