SCIENTIFIC ABSTRACT TOLYBEKOV, A. S. - TOMILETS, V. A.
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December 31, 1967
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SCIENTIFIC ABSTRACT
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UWR ~UDC'~l5~-~81-875:615-385.-3-011-17
'r'KTY V. Y-7., SOROI~M'1, A. V~, YEFI-UIOV~ 0., M.
PIGATOVS I _1 MOSIMIN, S. A., and
TOLYMKGI, A.-S., Institute of
"SETE-nd-eFlOMR,- Leningimd
Antiinfluenza Antitoxic Activity of Ioeucocytic Pyrogen".
Moscow Voprosy Virasologii, No 4, Tul/Aug 7?' 439-444
Abstract: The prophylactic effect of pyrogen~ obtained from rabbit leucocytes in
peritoneal exudate was studied by injecting pyrogen intravenouslY into rabbits
suosequently irfected with AO/32 influenza virus. When inj-ected~24 hoiirs prior
to viral infection, pyro~en prevented death and the tissue 4nd vascular destrac-
tion typical of influenza intoxication-jTh.. o- n,also altered the body
-yr 0C
temperature pattern in response to influenza virus infection, causing dis, pear
ar
ance of an early hyr-o-Cliermic phase., and development of a rapid tte:qierature
---reaction.) A aimilar reaction was observed with~injection~of Jewcastle disease
-virus prior tc infection. 7
-his virus inducediformtion of irterferon and
pyrogens in rabbits. Though the mechanisms by uhich pyro.-ea ircreases resitit-
ance to virus in toxication are unkaowm.and re.ouire further otudy, Lhere is.now
~an obvious connection between leucocyte productslincludin- Ir
),rogen, released
during Intoxication or infection and the increasedn body repistance to virus
toxins, "Tie possibility of employinG leucocytic~pyrogen as aiprophylactic or
therapeutic a-ent against influenza must be stUdied.
U,
...... Z NMI
USSR UDG: 616.~-4-002-022.6-02:616-988-73-092.2792
T YURMUNA, F. A., and VISHINYAKOVA, ~L A., :Laboratory of P~To-
J V. S
gens md Nonspecific Resistance, Division,o:C Gene ral Fatholdgy, Laboratcry of
W ectious Pathology, Division of Pathological kiato4my,,, Institute of aperimental
Medicine, Acadepy of M"-dical Sciences US$R, ~~zdid Divisio In, of Eq)ecially Dangerous
Imfections Leningrad Institute imeni Pasteur.
ulkirphogenesis of Rcperimental Ornithosis~, Neiimonia"
26-20
Moscow, krlddv Patologii, Vol 32, No 11, 19703
Abstract: Within 24 hours of intranasal Jilfection of mice T..ri~h the agerftu of
ornithosis., tkie -rirus ,,ias found in the alveolar. Thagocyte's, where it multiplied
to form nacrocolonies of ek-mentarj particles* Thee.virus was 111co famd in the
epithelial cells of the bronchi.. 'I'ho vix-aal-containing calls at first --ho'..'ed no
signs of dogonor~ation, xid there ww.no reaction in, the adjacent cells. '11he PC---
j U
lymorphonuclear lcaukocytes reacted ady after the virus-filled ;macrorhageS were
destroyed. . Mey engulfed the viral particles mleased froqm t1le, )ImcroPhag(I,- and
then died them--elvez. The repeated cycles of viral grawU,, in the macrophages
and ;hagocytosis by the polyauclear leukoay~ues tiocomts. f dr the,Ixotracted course
of omithocis pneumonia.
7-7-j-
J,,. 7Z
USSR UDC 621.317.74;:621.317.742
KULESHOV, E. M., LITVINIOV, D. D. , TOMACHEVA.- N. I., YANOVSKIY,.TM. S.
"Direct Readir- Meter for the Standing Wave Coefficient in the Millimeter
Range'
Radiatekhnika, Resp. mezhved. nauchno-tekhn. sb. (Radio Engineering. Republic
Interdepartmental Scientific and Technical~Collectipn),~19,691 lryp. 11, PP 83-88
.(from RZh-Radiotekh nika, N.
o 1, Jan 70 Abstract No IA318 'Resume)
Translation: This article contains a description oi a new direct , reading meter
for the standing wave coefficient in the T=11im-eter range, t~sing an original
version of tile co-mparison. method. The instrt~ment-errors and results of testing
it are analyzed. The error in measuring the standing wave coefficient does not
grange. Means:ol' decreasing the
exceed 6-8 percent in the entire millimeter
=easu--ement.errors are pointed out. There are-tmo illustrations and two
entries in the bibliography.
77.
USSR
UDC 539-385
V. I., ABABKOY, 0. V.0 YEVSMEVS V. Vs. 0and TO
"lavestigation of the Laws Goveniing the Fatigue.Failure of AvlAtion Alloys"
Sb. Nauch, Tre Kiyev. Irx--t Insh. C=hd. Aviatsil (Collectinn of Works of the
Kiev Institute of Civil Aviation Engineers)t No 40 197is pp,57-61 (from Refdra-
tivnyy,Zhu�nal, He"=Mmv No Zj Feb 7Zj Abstract No m366 by L. 14. Shkol. vik)
Tzanslationt A study kdz made of influence of the vid
the th and longth of the
woeking part of a sample upon the rate of groutL of fatigua cracksp as uell as
of scattering of the test results with respect toithe sonent of appearance of
the first zacroscopic exackts and the, moment of total failmv of the saxple.
The toSts wam conducted on flat samples of aluminum alloys 1)16r =1 V95 ilith
a central aparture, for repeatod cyclical alongtition vith a hxtquaney of 435
cycles per minute, It was established - that - the. langth of the samples does not
affect thoir lonpvity and rate of =Ckgrovth. -With m uldth increase of the
emples and a length increase of the crack, tho'groirth xatelo~f the:cracks
inareases. Increasing the Adth of the samples iAso brings about a. decrease
of the fatigue-failure stage and of the relative crack length.at the moment of
fallura.- With an increase of sample width, the.doefficient of strOss concen-
end of a fatigue c=ck'incxeasos'o.'*-Tho.gwateBt' scattering is
tration at the
2
69
USSR UDC 621.382.5
SEIMUK, V. A., TOMASREVICH, N. M., SHALEM, E. Gi
"Use. of Semiconductor Materials in Thermopiles With New System of Commutation"
V sh. Nizkotemperaturn. termoelektrich.~Materialy (L(mol-Temperature Thermo-
electric Materials--Collection of Works)? Kishinev, 1970, pp 168-172 (from
RZh--Elektron-ika i yeye primeneniye, No~5, May 1971, Abstract No 5B188)
Translation: Problems connected with reduction of the cost of producing
semiconductor thermopiles are considered'. An equation is found for the
minimum height of the thermoelement, taking account of the rwaste of semi-
conductor materials during cutting and pdlishiag.~ A neor method is proposed
for commutation of the thermopile without soldering, by~~means of a clip with
'a preliminary galvanic covering of the surfac6s being j.-,,Lned.' 1 ill. 3
ref. Author's Abstract.
'70
'~PROCESSING VATF-11SEP70
UNCLASSIFIED
t.lKC ACCESSION NO--AP0104722
:ABSTRACT/EXTRACT--lU) GP-0- ABSTRACT IT IS SHOWN THAT ONE OF THE
oOSSlRILlfIES:Fqi INTENSiFiCA*ION~OF HEAT FXCHANGE.IS A DISPERSAL OF
THEIRMOELEMENTS WHICH CONSIDE!kABLY INtREASES,THE 4REA~.DF THE PIROING BASE
AND DECREASES HARMFUL TEMPERATURE DROPS-BE-TWEEN JUNCTIONS AND MEDIA.
~DESIGN RATIOS.ARE GIVEN FOR DENSITIES~OF~HEAT CURRENTS ON JUNCTIONS OF
THERMOBATTERIES. 'SINCE THr- OPTIMUM:DEGREE OF DISPERSAL OF
THEMELEMENTS CANNOT-36 DETERMINED THEORECTICALCY.IN A GENERAL FORM, A
METHOD OF EXPERIMENTAL DETERMINATION OF THE OPTIMUM.DENSITY OF PACKING
-FOR,THF- CAS.E-OF.NATURAL. CONVECTION~WAS US.ED. ANOPTIMUM DE.SIGN OF THE
MODULE FOR A REFRTGERATOR WITH CONVECTIVE COMNG,~IOF HOT JUNCTIONS WAS
FOUND. ONE:TABLE. THREE ILLUSTRATIONS,~~SEVEN REFERENCESi
UNCLASSulto
Rock Density at High Pressures
(Abstract; 'Study of Density of Rocks f rom Central Yazakhstan Under High
Pressures," by 14, P. Volarovich, A. K, KurskeVev, A....I. Le-a~in, I. S
I. L. Tu-ova and B. M. Uraqq. tute ur Ph sics
_ygy, Inc till.
the Eartn, ademv of '~ciances USSR, and Institute of.Geological Sci-ences,
k- SR,
dem of Sciences Kazakh SSR; Moscow, Izvestiya Mkademli Nau
Aca
Fizika Zemli, No. 1, 1970, pp. 46-51T-
The density of rocks of variousi composition1-rom Central Kazakhstan
wcs determined athigh pressures,in the laboratory. ;. Rock, tests were at
quasihydrostttic pressures up to 15 kb. The apparatus used made it possi-
ble to measure the velocities of elastic waves.,, The!sample was compressed
by hard-alloy pistons. Change in volut~e (from displacement of the pistoa)
was determined simultaneously with meastirements. of. tfig velocity of ~ongi-
tudinal.waves. Change in denaty at different pressures was computed
~usin the for=la
-1: VYV 7
Ree3j~~
-:19780902,
AF0045875
where. P 0is the initial de le in g1cm3,
rsity of the samp A V/V is the
volume-decrement. Change in density w4as determined~with an error of
about 5 percent. Samples were selected alo ng two deep seismic sounding
~profiles. Under the applied pressure density of all rocks increased.
Mensity changes were greatest in~the initial phase to 4 kb. Later the
cha nges became less and the density-pressure curves flattened out. The
greatest density changes were observed~in samples of metamorphosed
roclevs: ,schists, gneisses and porobyroids of more acidic composition for
which the density changes at 15 kb attain 3.5 percent. The density of
increases continue to 15 kb,
granit2s also changes rather sharply and
Relative density changes are dependent on, initial denrIty: ~ the lesser
the density at atmospheric pressure-, th4Lgrearer is Oe change when
pressure is applied. The maximum change~s~JnLdensity for rocks of acidic
composition are evidently cause Id by their greater inho-mogeneity than for
rocks of basic composition.. Acidiarocks are also poorly preserved.
Defects in the rock, largely miclrofis.sures,'close under pressure and deosity
at the attained pressures approach's an identical ~valtte~. for r0 eks of similar
composition. For rocks of baBie
ultrabasic compositlon the density
at.pressures up to 15 kb does not exceed 2 perceat, that is, the
compressibility of rocks of acidic COMPOStioti is greater than for basic
A
19780903
77777
AP0045878
rocks bj approximately a factor,of 1,5. Density is dependent primarily on
chemical and mineralogical composition'.~ Differentiation of rocks by densi-
ty. corresponds to their basicity. The. densiry of saims tones at high pres-
sures approaches the de-,vsity of~granodicrltes, Tuff-diorites approach the
density of diorites. The density of eclogites fromnorthern Kazakhstan
thern Kazakhstan can be-attributed-to the fact that they
to 15-20 percent). The..results of studies of rock
ressures can bemused in the geological interpretation
The author~l used such,data in constructing a density
e crust in. central Kazakhstan.~.
USSR
UDC: 6~2.001.43
VOLAROVICH, M. P.., TOIMASMSKAYA I S~
."On the Velocities of Elastic Waves When Rock Specinveins are Dedorme4 and
Dest d by Uniaxial Compression at HIydrostatic Pressures of up to 10,000-105
roye
V sb. Frobl. reologii gorn. porod'.(Problema 'of the H~e6logy of Rocks--
'collection of vorks), Kiev, 'Tduk. dumka~'j, 1970, P'p 38-41 (from R&-Mekhanikal
No. qx Sep 70, Abstract No qv63o)
Translation: The paper describes.a.high-press4re installation in which tests
the vel.=itios of ultra-
may:be conducted on compression a-nd:on measuring
sonic longitudinal waves along.an&.across~the application of a uniaxial load,
as vell as determining the axial force and. longitudinal. deformation of a
specimen in the course of an experiment,using resistance tstrain gauges.
Bibliography of six titles, Authors*,-abstiact#
USSR UM 632.1-06:612.865/.867
L
NAVAKATMPIT) A. 0.,, KUNMEV, YU. I-, LYSMA, G. G.,
4VSKAY.A Ts.-~L
DERKACH V. S. j, KAPSRUK, A. P *j, KOVALEVAj, A o I.,, STAITIST-
.1 Dy
OSD-SKAYA, L. S., and--PARLYU-K, A. F., Kiev- institute,of Industrial Hygiene and
C)C'eupational Diseases
"Effect Pf Yantal Work Accompanied by Nervous and- Emotional Stress of Varying
Degrees on the CardiotvascWsa- Syst
Mzscow, Kardiologiya, No 3, 1973, pp 50-56
Abstract: In addition to making a statistical anaaysis of 1,585 cases of
myocardial infarction among Kiev twor-kers, the authors ran physiological studies
on engineers, typesetters, mathematicians, and neurosurgeons. 'They found that
the effects of mental work on the cardiovascular system vary vith the degTee
of nervous tension and som-- other factors. Me manifeatiLtions range from incip-
ient functional disturbances of regulation to severe patholoa. Moderate ten-
sion elevates blood pressure, the increase in systolic and diastolic pressjares
being related. Great tension,-however, tends to diBrupt,.,the relationship
-probably because the centers regulating vasoular tonus become uncoordinated.
Intense nervous and emotional strain increases the heartleat as vell as the
sim~`vraves among the periodic constituentslof;the correlation function of
1/2
USSR uDc 616,153.96/61.6.1:612-825.8:616.8-
oU3.615
TOMASHEWSMAY L. I., Kiev Scientific Research Institute of Labor Hygiene and
'OFe-u-p-a-tTo-iia-l-MTa-dw~-i-a, Kiev
"Catecholamines and Their Relationship tb-~Cardiovascular Shifts in Eental Work
Involving Different Degrees of Nervous and Emotional Tepqion~'
Kiev, Vrachebnoye Delo, No 8, Aug 72, PP 135'138
Abstract: The degree of secretion-of cat~-cholamines in relation to cardiovas-
cular shifto in various types.of meatal work,differing i4ith respect to nervous
band emotional strain uss studied on. engineers,,, type sett. ~rs, and neurosilrgeons.
Under high.emotional strain (e.g*, that to~ ifhich neurosIurgeons are subjected),
the rate of excretion of adrenaline and noradrenaline, particularly that of
noradrenaline, increased significantly. Activation of the,syn-vathic-adrenal
system, accoumanied by an increased forrration of catechoLlmdnes, iray have a
harmful effect on cardiac activity, increasing the requiriirient of coronary
vessels for oyygen and producing hypoxia- A~.high incidence of 1.1ypertension,
-fienta
caronary atherosclerosis, and myocardial infarction in parpons ~diose i
work involves a high de[rree of emotiotia,l strain . (e.g. I leading, engineers of
industrial enterprises) has been establivAied.,, Observation .bv ca-rdiologists of
the state of tile cardiovanoular systent in marital workers whohe a~-tivit,;j involves
a great amount of neuro-emotional strain is advisable.
36
UDC 613-6:6-t2.766.i
ITAVMTMA11, A. O.;~ WIND=) YU. I., AYMIIC, NKO A. P.,
VASMENKO, Yu. I., &AMEMKO) N. P., BUZU011, V. A., and
DEMC11, V. S., Institute of Industrial Hygiene and OccuTational Diseases,
Kiev
',Principles for Quantitative Evaluation of th,_a Zifficulty~l and Strenuousness
_611" Work.on the Basis of Physiological Data!',
lbscow, Gigiyena Truda i Professional' nyye Zabolevaniya, No 7) 1971) PP 3-9
Abstract: A.four-leval classification of Jobs by difficu-1"Y and stress is pro-
posed on tho basis of research conducted.'by the7Tnstitute 41nd the literature
data. The criteria usted to measure the amount of effort involved as well as
the chanses therein during the course of the workday include energy consump-
tion (~mnging from under 150 kcal/hour for class 1 work., computer pro-
grar-ming, to 351 kcal/hour or nora for class w6rk,- e,.g.,, teel casting),
muscular, cardiovascular, central ;-ervous, and,endocrine functions. A table
lists'average values of n different kinds of
f several physiologicalTunctions i
v rk while another ~2v-_,Luates 'he dJfficulty and strenuousness of different
0
ficu r. chines iB classified as class I in
Ands ofjobs (e.g., oporation of of. m
-difficulty and class 2 ir. atrenuoiinness, lathcvork 2 and, 2, vicel cattint,--,
112
USSR UDC ~621-355-8
DRACHEV, G. G., HATMEVA, 14. 1. and MMOMMY
"Cobalt as a Trace Element in the Anode'~Part of Alka4 Batter-los"
Sb. rabot no khlsA. istachnikam toka. Vaes. n.-n akkumulyator. in-t (Collec-
tion of Works on the Chemical Source of Current. Alli-Vnion' Scientific Study
institute for Storage Batteries) VYp 70 1972# pp 118-iZ3 (from Referativnyy
Zhurnal Kbiziya, No B(II), 1973, Abstract No 8LZ40 by V. S. Levinson)
Translations The influence was determined of traces of cobalt in tha form of
a zetallie powder and as different cozpounds An the positive working te=ina:L
on the capacity of allmline batteries.of.the type TZHHK-300. The greatest
effect was shown by the compound COSO, in the;form of a 6.1turated solutionp
approximately %. Under these condithns#'Aha capacity of the~battaries
Increased appro.-dmately0ZVo with a concommitant improvement In its power at
higher temperatures (40 C) for conditions of a small,redu4tion In the din-
charge current. The actual specific energy I of. batterien having, cobalt addi-
tions with unlaminated negative and laminaUd,poettive alectrod6s was 73.5
)ratt hours/l,and 34 watt-hours/kg. Such batteries are rec6amended for appli-
cation for loading machines.
'N" UDC: 362.147:616-936.8
rr
.W~IHMS OF THZ EFFECTIVENIMS 01~ DISPENSARY CUE
C-4 rr%)
lArticle~-b -L.M. jj~,Firnt Polyclinic. Hel'zay Republic 116spi tal
(Chief Por5a)-,Bel tey, Moldavian SSR; ~!oacow.
okhra~,*,ni~ Russlin ;o 5, 1971, subiratted:1 Dbconber I IFIT"'plovei 4
Zdrav,,
"We concur wftU ch. AuLhot o ' the article 1~ qu"tion with regard to
the -ited for c-nifl-cation o~ the system a! keeping race.rds of and evaluating
the in~lc" of e~~ Ctive-
"t -eso of dispensary ser,,Lcea. They should be, developed '
cif data already publiahed In the pre~as as wall as of-tb6
0i d-ffercrit madtcal
Tt~v three --aps of I ndices rnbmIt ted iru the -artIcla do, in ei3ence.
cortectly coflett the work of a dizptiararv. They are-used by many medical
ii'StItutiqns firar ;rLup of indices), volume of, work (extent of
41,Ypansary shcu ,14 be cnIntpd, and Lt should be called "volume and
quality of. ilfrc,:~~Ary czia." In ad4ft'lou to,data abput qon~-Yal patiant
coverale by care, a r=bor of otlt.r ladices should be iticl.ded.
They cav~~bc f-i)m the infoyl.ntion contAined In the new form, No 271
Cixrziiary list of di~~aaes subjzct ~,, dJvpi--jivar-/ care)i.ispprevod ~n -, 1)acemloer,
1969. Such include.*. coveraL- 01, epatinits SO.
sect tv,
care by suzh. c4r-~ zs nk~ ,f p4t itnrz .it -Ai nn.a for
ate ftrec~ It. tu to ta ke Into consideration
przfypt 4#zzt-z~n C-~ --:;tleatp aub)eet to Unponsary care.
:hc- ArLXc:e lizt, th" third Lrollp of in&-Ca4z of
~La;c.-,r.ary cork.- =`-y ara well fortitulated. "Ii~ IrdAx In thLs group,
nclt~-i 'tdiz;t:~nsary -,~tl~ntz with cemporary disability" Is isaad In report-
fenz. =o -3-1 of ~,orbldiry Involving temporar), Jii;obiliry).
It In '-, th-r iiamber of for-'s pubnLtte4 1,7 Qmpl.~ed pati-Es unable
t') wort,. *,!~ --~r opi-~ion, rhJ6 Index ahould 1#e replaced by anoLlier, and
~uld ee cr4litt! ".~.&-ioe of exacerbation (recurrence) of III s ." It
C. ahL ne S
tht of discusslun.
*',(With Roforenze Ar-.Iclc by Ya. 1. Dreycrrmcn)
N') Y, pp 22-25
- 5b -
3, 1
USSR 616.282.7-073
LIHARg B, TA., Candidate of Medical Sciences, and Engineer
of the Sourdo-Acoustic Laboratory of the Kiev Bci#i~Wc'~WeseaxAcitYn'-;-4tituto
of Otolarynolo&v
"Diagnostic Significance of the Sensation of.Frequency Changes in the Modulation
of Sound,Intensity"
Kiev, Zhurnal Ushnykh, Hosovykh, i Gorlovykh Bolezney,~Ilo 50 Sep/Oat 71,
PP 30-38
Abstractt Thresholds of differentiation of sound Itensity modulation fre-
quencies were studied in five persons with normal hearing and 39 persons with
functional.auditory disorders. Tests were made with threshold tonal audio-metry,
speech audionetry, and noisc audiometry, :Apparently,~ a lowering of the
threshold of differentiation of sound inteasity with impbAred.reception,
regardless of zodulation frequency# under ~cert,ain conditions raises the
apperception of speech as a result of physiological recruitment. With pro-
gressive auditory inpairment, however,.such~roarultment disappears and
apperceptior deterioratez. Comparison of thresholdz of41fferentiation of
sound Intensity at different modulation froque'noits ew" If ound -to be of dia,-
gnostic significance, holping to.detornizo ~.tho eatLse of diaraption of speech
aDparception In certain forms of cochlear-neur#es.
717-
UDC: 529.78
LEYKIN, A. Ya, ROVINSKIY,.V. Z., Z~Q~MASK ~~.ZRTIK, N. S.
"Use of Passive Rubidium Frequency Measures as Storage Devices in the 'rimc
and Frequency Service Operated by the,Khar1kov State~Institute of Measures
and Measuring Instruments"
Tr. Metrol. In-tov SSSR. Kh~rlkov. NII Metrol. [Works" oT Metrological
Institutes of the USSR. Kharlkov.- Scientific Researcli.lastitute for Mctrology],
1972, No 7, pp 360-374 (Translated from Referativnyy Zhurnal Metrologiya i
lzmeritelInaya Tekhnika, No 4, 1973, Abstract No~,4.32 ~538, from.the Resume).
Translation: The primary ebarecteristics. of passive rubidium frequency
measures which have been developed;and the first -results of their use as
s,torage devices in the time and.-frequency. serviceiby the Khar1kov State
Institute of Measures and Measuring Instruments are reported. The long-term
frequency instability of the,rubidium storage'devices is (I.S_ 2)-1o-11. The
mean square relative random frequency deviation from its inean~value with a
time interval measurement of one~day. Nonsystematic drift of the devices
exceeding the measurement of error was discovered over the measurement time
(two months). The short-term. frequency.in'stability% of the devices is
.1/2
111M 1_~~ mm-
USSR
UDC 620.193.1:669.4%95
TOMASHOV, 11, D., ANOSHKINI 11. F., MOROZWOVA, S. V.), CGINMIYA, YE. i.,
RUSKOLI YU. S., and CHEFWOVA, G. P., Inatibite of Physical Chemistry, Academy
of Sciences USSR
Investigation of the Effect of~Palladium,on.the Fhgineerina, Mechanical and
Corrosion Properties of Titanium Alloys OT4,and VT1411,~
Moscow, Zashchita Metallov, Vol 9, No 6,1973, pp 672-675
Abstract: The possibility of.increasing the corrosion resistance of titanium
alloys OT4 and VT14 by means of alloying.with 0.2% Fd was studied. The alloys
ver0l,produced in a vacuum-are furnace. ~rlth.the palladium added in the form of
powder. Structure of OT4 and OT4+0~~% Pd'.was the alpha-solid~solution, and
VT14-and VT14+0.2% Pd--fine grains of the alpha- and alpha"-phases inside a
beta-inatrix, Strength propertieis of the titanium alloyp"were Improved somewhat
with the addition of palladium while duct!]..ity,waB lowered. The add tion of
2.0% Pd significantly lowered the oxidationtendency of the alloys at 600 and
8O(PCj and especially at 1000oci 3 figures,:4,tablesj 6 bibliographic refer-
ences.
WSR UDQ,6Z0.193.OIt669,295
TOMASHOV Nt_,P. I RUSKOLI YU. S.-I AYUYANj,G. A.$ IVP-- ION, YU. M., PIAVNIK,
d'*~ 44
and NAZARVIAt R. 1.# Academy o~-'Sciencoz USSR,,. institute of Physical
Chemistry
"The Effect of Alloying Elements, on the ~CQMsi6n Dt~havior of TitaniW'
Moscow, Zashchita metallov, vol 9 s i~o f,~j~n4eb 73t 10-15
VP
Abstracti The method of.potentiostat a polarization =Yes,, corrosion tests,
i
4nd electron diffraction investigatiors,were applied tP Investigate the
corrosion and electrochemical properties of alloys based. on titanium icdj.d(--
with criall additions of ch-ramiunj molyrtdenum, niobium, alum. Inung Mil1rWlese,
U
and tin in a 4AV, H 2S04, solution at 80 U21der natural a~xratioh, conditiors.
The structure of the anodic oxide films developing on U,V:Zse alloys. was
analyzed. The passivation and full Wsivation potontUIs wexe found to. be
practically independent of tho natuxe and con,,,entration'.of tho alloyinr
addition, whenas the critical Wsivation currentz and the currerts in the
passive zone varied sigaific=tly. Aluminum ippaizz thc- corrasior rropert-Jos
of tifaanium both in the active.and passives atates. tAnr
chronilim
increase the rate of corrosion in the active:state "d ~~.aacretxoe it in tho
passive sta-te. Niobium$ on the other hando reduce3 titanlwi eorxozion rate
In the active stato and tjjq jV,613iVO_.Stat,,i!~. One ftgurej three
tabloal,thirtoon bibliographic roferencest
-USSR UD.d 620-193-196.669-295
T N D., MIATVEYEVA, T. V. ~and.IVANOV, YU. M., Institute of
emistry, Academy of Sciences USSR
~Effect of Ruthenium. on the Corrosion Behavior'~Of Titaniud'
Moscow, Zashchita metallov, Vol 8, No 2, Mar-Apr 72, pp 174-177
Abstract: This paper deals with the' ~effect of x~uthenium on the pas-
sivation and corrosion resistance of.-titanium as compared to the
passivation effectiveness of palladium.' The marked difference be-
tween the corrosion behavior of Ti alloys with Ru and Pd is explaii-
ed by the.difference of hydrogenation and cathodic polarization.
'Added in small amounts to Ti, Ru~hydr~ogenates to a lesser degree
than Pd and is therefore a more effective cathode~.capable of con-
verting Ti to the passive state. It is 4~ssentialjhat unlike Pd,
even minimal Ru additions (0.01 0 -05t);) while insufficient to
1/2
IN
USSA
2/2
m
USSR UDC 620.193.013:669.295
D~, CHUKALOVSKAYA, T. V.91CHERNOVA, G. P., BUDBERG, P. B., and
URUE, A. =.-nStitute of Physical Chemistry, Acadeivy of Sciences USSR
~111study of the Corrosion Resistance of Alloys of the Tiltanium-Tantalum--
Niobium System!'
Moscow, ZashIchita. metallov, Vol 8, No I,I Jan;.-Feb 72, pp 3-7
Abstract: Tantalum effectively.xaises the, corrosion resistance of titanium-
base alloys; its use, however, is limited due to cost factors and scarcity.
The~stvdy of the ternary Ti-Ta-'Nb syst em is essential f r detormining the
feasibility of partial replacentent of tantalUm with the more readily avail-
able niobium. The corrosion and electrochemical behavior of tho alloys was
studied as annealed and quenched.i. In.a 5Z ITC], solution at~100*C. Analysis
of the phase transformation Wad micros tructure ~ of the alloy indicates an
isothermal section at 6000C which is charac'terized by a narycxr region of
a-aolid solution, a wide two-phase. (a+o) - re'gion',! and a wide region of
Cf-solid solution. At about the,same average.compositions3 Ti-Ta-Nb alloys
with~single-phase structures exhibit corrosion resistance values which are
one or two orders of magnitude higher than those~, shown by two-phase alloys.
The higher resistance is characteristic:of annealed Ti-Ta-10 alloys with
USSR
TOMASHOV, N. D., et al., Zashchita metallov, Vol 8, No 1, Jan-Feb 72, pp 3-7
a more stable 6-phase. Alloying of TI with Nb and, specifically, with Ta
results in a considerable increase in corrosion resistance, the total con-
_.tent.of alloying elements,.ranging from.20-40% for annealed and 10% for
quenched.-alloys. . The study demonstrates the feasibility of replacing
tantalum with niobium without reducing markedly the corrosion resistance
of the above alloys. (3 illustrations, 1 table, 9 bibliographic references).
2/2
USSR UDd 620.193.013:669.295
UZBEKOV, A. A., RISKIN, 1. V. !ADOZHINA, Z. I. and T
A,
"Study on the Corrosion of Titanium Alloyed With 0.2% Palladium in
Hydrochloric Acid Using the Radioactive Tracer Methckl"
Moscow, Zashchita metallov, Vol. 8 No 10 Jan-Feb 72.* Pp 8-1).
7V Abstract; The study of palladium dissolution rate at various stagges of
corrosion conducted on a titaniurn allot vith 0.2% palladium, in both aerated
and deacrated 20% solutions of hydrochloricacid usinir, the radioactive
tracer method indicates that the transfer,of palladiurn into the solution
takes place at room temperaturcs.~ Rotating'the,specimen increases the
transfer rate of palladium into solution and decrease6,its amount on the
surface -which is apparently related to the nechanical removal of some of
the palladium from the specimen's surface4 The study of the kinetics of
palladium transfer to both aerated and deaerat4d solutions indicates that
palladium transfer to the aerated solution ceases on p6psivation while the
transfer to a deaerated solution.continu6s for the entire period of active
dissolution of the alloy. It isauggested~ ~thp-t the ionization of palladium
1/2
ly
USSR UDG 6210-193.411;:669 ~295
RISKIN, I. V., LAPOZEINA I. an; d~ T1(4)j =0 N. ',D
-"'Crevice Corrosion of Titanium and its Alloy with 0.2% Palladium
iti Hydrochloric Solutions"
Moscow, Zashchita metallov, Vol 8, No 2, Mar-Apr 72, pp 177-181
Abstract: Described are the results of,corrosion tests on spec-
imeris of VT-l titanium and Ti alloys~with 0.2% palladium under
crevice corrosion conditions.in:both aerated and deaerated hydro-
chloric solutions using argon. The test results,indicate that Ti
alloy with 0.2% Pd -- as compa e:d m -- hot only is capa-
r pure Ti
ble of maintaining a higher corrosion.reslstancO~'Jn the crevice
than in,the bulk of the solution but wil.1 also promote the passiva-
tion of pum Ti provided the crevice is~:formed bytthe specimen pair
-.Ti-Ti alloy with 0.2% Pd in the statejof electric,contact.(l illus.
L table, 12 biblio. ref.)
1/2
Titanium
USSR UDC 20-193-01
XWHOV, N. D CURNOVAi- G~. PO j and YAMKIYI YE. G'., Institute of Physical
Chemistry, Academy of Sciences USSR
"The Electrochemical Behaviorof Metal,'Ceramic 1itanium"
Moscow, Zashchita Metallov, Vq-1'l0,'No'l Jan-F
eb 74' pp A12-27
Abstract: The electrochemicalbehavior of-specimens of titanium pro-
duced by powder metallurgy methods~in 20% HCI is: studied. The cathodic
and anodic behavior of specimens and the-.change in potential of inner
layers upon polarization of the surface.'are''.studied, The true surface
of the specimens is defined by measurement of the capacitance of the
binary layer, Cylindrical specimens 2.2 mm' in diameter and 6 mm high
were pressed 'from electrochemical titanium powdm.urith~,'partlcie sizes
of 100-180 p with microdendritic strmture, at pressu'res'of U-60 t/cm2
with subsequent sintering Li a Ivacuum. at~11000, It.is e~stablished
that the decrease in active surface, is more intensive than the decrease
in porosity, apparently related to.the decrease in depth of penetration
1/2
UDC:620.193.01
RISKIN, P. V., KOLOSOV, N1. G. and TOMASHOV, N. D.
"Corrosion gehavior of Titanium and Its Alloys with Palladium During
J_I Heat~Transfer in Moving Solutions"
-Feb 74, pp 28,32
Moscow, Zashchita Metallov, Vol 10, No 1, Jan
Abstract: The influence of heat transfer and motion of hydrochloric-
acid on the corrosion behavior of titanium and its a4loy with 0,2% Pd
is studied using a rotating heat transmitting-disc electrode designed
by the'Wrairim Scientific Research Institute for Chemistry, The
saturation of solutions of hydrochloric,acid with a!' increase
r causes an
in the temperature boundary of corrosion stability of titanium and its
alloys with 0.2% palladium. The boundaries of corrosion stability of
titanium and its palladium alloy in,solutions of hydrochloric acid de-
~pand on the wall and inedium temperaturej the temperatpre drop and the
direction of the heat flux, Upon transition of1aminar flow mode around
a,disc. to turbulent flow, the temperature boundaries~ofcorrosion stability
in aeratcd solutions of hydrochloric acidik-reas'e.
orrosion.
USSR UDO 669.o18.8+62o.3.7,
TOMIASHOV, N. D., and CHEITOVA, a. P,
Korroziya i Korrozionnostoykiye SpIAVy (Corrosion'and dorrosion-Resistant
Alloys), Plosecm, "Metallurgiya, -1973, 2 ~20 pp
04' Cor J()
Translation of Annotation: 7
mis book considers the theories ros L
processes, localized corrosion (such as pitting, intercr-,,stallite corrosion,
fractures), and corrosion during. the simAtaneous action of mechanic al loading
(corrosion cy-acking, corrosion fatigue, and cavitation). Scientific prin-
ciples are given for mking metal alloys having high passivity and corrosion
resistance. The properties of the major contemporary corrosion-ressistan't
alloys used in construction are described-~
This nonograDh is of interest to both scientific and en,-;-inLerin,.,, perwnnel,
and builders dealing -,rith probleris of corrosion, ayrti,--orl-0,3ior,~pi-otectiori, and
the application of al-loys to ini~rease corrosion resistanco- 76 Illurtrations,
12 woles, all"' 138 references.
Wole of
Contentz:
Page
Introduction
Chapter I. Current 7heories aP Corr*aion uses 9
0 proce.
ThennodmiAes and.Kinetics 'of -Coi-josion,
9
Mechanisms for the Corrosion Process~ 12
Kinetics of Biactrochemtcal Corrosion 19
USSR
T
M N
ASHOV
. D.)
and CHERITOVA, G. P., ~~tallurgiya, 197"~, 232 po
Factors Controlling Corrosion
Controlling Factors and Yjethods of Antico~rosian
Protection
Tnertness of Vlatals
Kimetics of Anodic Processes to Render Mzmt . Passive
Ir
Conditions for the StOility-of Inert Materj.p_ls Ln
Corrosion Systems
Chapter II. Localized Corm.,jon of - Alloys -
Contact Corrosion
Fracture Corrosion
Pitting Corrosion
Intercrystalline Corrosion
Chapter III . Influence of Y-echanical Factors -on Corrosiom
General Corrosion of Stressed 1,14,tals
Corrosion CrackinS
. . . Corrosion FatiCue
Corrosion Cavitation
CorAmsion Erosion,-
Chapter TV. Princi:ples. of Preparing Corrosibn-Resistant A14oys
2/3
22
27
32
38
43
47
48
59
72
97
118
119
135
138
142
j.45
USSR
TOMASH91, If. D. and CM, NOVA, G.P i1etallurgiya, 1973, 2 Y_ Pp
-ro, Resistant Alloys 145
Basic Trends in the Cmrposition of Com sion-
Forration of Surface Structures, in All
oy;u Dari-nE; the
Corrosion Process.. 156
ation of,Highl~ Inert Alloys
Study and Applic a-77
General Principles of Alloying Corrosion-Rmsistant
MaterLals 196
Chapter V. Corrosion Resintance.of Go
nstrudtion. Alloys 200
Iron-Based Corrosion-Resistant,Alloys
200
Double-Layer IMetals 220
Vickel and Its Alloysi 222
Titaniml and Its Alloys 224
Bibliography
3h
USSR uDc: 620.193.03:0'69.295
RUSKOL, Yu. S. , VLASOV, 'V~ I., Institute of Physical
TOMASHOY,,A
the USSR
AcadeDW of Sciences of
"Oscillographic Study of the Self-Passivation of Titanium After Surface
Dressing in NaCl Solutions
250-255
Moscov$ 7.~shchita Metallov, Vol 9, No 3 KaY/Jun 73, PY
Abstract: The authors studied oscillographic,curves for the potential drop
of a titanium electrode after.its surface had been cleaned under a sodium
chloride solution, The experim ens of iodide ti-
ent5 were done on specim
tanium (TsMTU 05-18-67, HB 66-5) which wash remelted in nm are furnace with
consumable electrode in a helium attrosphere,, forged and. arnealed in a
vaCUUM (10-4 mm jig) at 650'JC for 40,minutes.,:spec Iiriens 6 mni in dia-meter
vere -oressed into Teflon holders so that only-one end surface vas exposed.
Before the experiments, the specimens,were cleaned with M-28 abrasive papt~r,
degreased with acetone and rinsed vith distilled water. iThe installation
used for cleaming the surface wider sodium~chloride:was described in a
previo", paper (R. D. Tomasbov, R. M. AlItovskiy, G. P. 03ernoya., "A Device
for Electrochemical Study of Metals During Surface Cleaniing Under a Solu-
1/2
USSR
T014ASHOV, N. D. et al. Zashchita Metallov, Vol 9, No 3, may/jun 73, pp
250-253
'The rate of ro-
tion" Moscow, VINITI, theme No 13, No M,58-94/7, 1958),
tation of the Corundum disc was 1320 rpit (linear velocity of grinding wit'l.
respect to.the center of the specimen 3.11 m/s), and~the st~eed of recip-
rocating motion of the disc was 2.15 YT,/hr (600,nm/s), corunduza grain size
6 pm. After 15 minutes of surface dressingi the wheel was removed
vas 57-7
from the specimen and the.change~in potential of the rrpecimen with time
vas measured. For the first five, seconds.the measurements were made on the
SI-19A CRT oscilloscope, after which an N-39 chart-recardiniF mil-livoltmett.
'was use.d*in some cases. The LPU-01 pH meter was used ICU: a high-impedancc
amplifier. Cathode polarization curves were plotted a~ a rmte of 1,2 V/hr
using the P-5827 potentiostat, in a threeelectrode cell. A saturated
calome]. comparison electrode was used. It was found that the self-passi-
vation of titanium is slowed do,6-n consider .ably in neutral solutions by in-
creasing the concentration of chlorine anions and reduci.ng the concentra-
iJU4-
tion of dizscilved o.-jgen. In d Ue aerated sodium chloride so2utions,
titanium is covered to a considerable extent -by. a chenosloTpticn laye.- of
oxygen even with continuous mechanical surface, clea.ninE under solution.
2/2
14
USSR ~UDC: 669.017:620.193.4(02)
T2MPjaV,,. M. D., CHERNOVA, G., P.
"Corrosion and Corrosion-Resistant'Alloys"
Korroziya i Korrozionnostoykiye Splavy.,-[English version above], Moscow,
Metallurgiya Press,.1973, 232.pp (Translated from Refprativnyy Zhurnal
Metallurgiya, No 8, 1973, Abstract No 81698K, by 0. Pimenova).
-Translation: This monograph presents the most importailt statements from the
theory of,corrosion processes. Particular attention is given to the most
dangerous types of corrosion damage (pitting and intercxystalline corrosion)
an&the influence of niechanical.factors on corrosion pr9cesses, as well as
the,basic principles of creation of corro5ion-resistantialloy,,;. The principle
and possibilities of cathode modification~of alloys in oTder to increase their
corrosion resistance are descrited.in det i1 A brief.review and primary
a . 9
characteristics are presented from the most important modern corrosion-resistant
alloys, primarily those based on Fe..
WSW UDC 620.193-01
CHUXALOVSKAYA,T. V.,. WEPOVA, G. P., PLONIK, G. H.,
oft,and SMHEMA# Z, TEE., Academy of Sciences
ZAE"V,~ A. P
TSSR#:~' Institute of Flusical; Chemistry
#Structural Study of Surface Layer on Ti-Pd Alloys"
Moscow# 2ashchita Hetallov$ Vol 8f No % May-Jim 72, pp 291-294
Abstracts The article describes results~ of an electron. microscopic, elec
troa:diffractionand X-ray study of the surface layer forming on Ti-Pd alloy
Ti-08*2 percent Pd and TU-1 percent Pd) 4uring cornsioz in 4o percent H~SO4
and 20 percent HCI at 1000. The electron~,Inicroscopic r3twly of the surface of
TI-Pd alloys after their corrosion confirins the supposition aB to the accumu-
lation of palladium on the surfaco in theform of very flnel~ dispersed crys-
talline formations. After tre;atzent of the, awxface idth, hot concontrated
W103# which dissolves Pdp the electron - microphotogmpha, show to particles.
In the caze of Ti-l porcent Pd palladium mainly: forms very, fine particles
on the surface, The Pd accumulations on n-0.2 percent Pd alloy reveal a
tendency towards the branched growth of primary cryistalligation centers.
1/3
16,
TOWHOV# No Dot et al-t Zashchita Metallovo Vol 8,, No 3# YAY-Jun 72, pp 291-
2S4
7he results of the electron diffraction studyof the surface of Ti-I
-percent Pd alloy show that after cornslion in 20 percent HOI at 1000 there
are -:3trong lines cIvn-acteriatic of Pd and, very weak lines chaxacteristic of
Tiog and Ti%. After treatment of the alloy in HN03,the lines characteristic
of Fd disappearand only TiH2 and TiO2 are found on the surface, The Via-
tive intensity of the reflectionscharadtorlstle of Pd. increases with an in-
crease in the corrosion time, "I* it decroazes for TIH2 and TiO2. After
cornsion in 40 percent H2so4 at loOO reflections charac~teristie of Pd, T02,
and'=2 are observed, Houever, the intensity of the Pd-cha=cteristic lines
2-_ lit, considerably weaker than after corrosion in 20 percent 11CI, at 1000, and
they, are of a diffuse character, while the intensity of. the reflections char-
acteristic of TiH2 and T102 is stronger,
7--ray analysis of the powdered surface layer that forms-on Ti-I per-
cent. ?d alloy shows that after corrosion In 20 percent IICI at 1000 the alloy
C
USSR UM 669'14.018.8
T-- I MTOVAt G. P, 1~ Z'~LNINAI (% S., I DBERGI
BU P. B.9
arld G117-IM", -WL. Instit4te of Physical Chemistry, Academy of
Sciences USS1
"Investigation of the Structure and Corrosion Behavior of
Alloys of the System Ti Ta Cr
Moscow, Zashchita Metallov, Vol 79 go. 41 Jul-Aug 71, pp 387 -391
Abstract The structure and corrosion behavior of alloys of the
system Ti Ta - Or , containing Cr from 2.5' 20 ~-L and Ta up to
30 ~&, were investigated, using for the analysis of the phase equi--
librium the microstructure, roentg~enophase, diffferentiai-therma17
and dilatometry me-'Uhods -and characteristic diarrams of the alloys
subjected to hot plastia deformations in the temnerature interval
of ltOOO -600 deg. and subsequent~hardening (~!,kO -600 deg.
Depending on the temperature of heat.t.reatment, these alloys can
1/2
USSR
TOMASHOVP N. D., et al., Zashchita Metallov,, Vol 7, No:4, JO.-Aug 71,
'PP 387-391
have a homogeneous s1ructure of a r5-solid solution or a hetero
geneous strue ture v4 + $ + 6-. The investigation results are discus-
by reference to the shovm nicrostructurt,,and'dia.-;,-rans of po-
lythermal cuts of the alloys by different correlation of their
components and effects of the alloying comporiezritus oa the corrosi-
on rate. It was found that the stability rec;ion of the P --phase
on the state diagram increases and the bep,,inhing:eutectoid trans-
formation shifts into the region of, hi~4ier contonts of
alloying elements ,Lid lower~temperatures by increasing; the rela-
tive content of Ta to Cr relations of 1:3 , 111 and 3;1 . The
corrosion rate of alloys with homogeneous structure is lower
than that of alloys with heterogeneous structure by 2 -10 times
and more. The Ti - Ta - Cr alloys.with ~Pa:Cr=-3:1 and the Ti - Ta
alloys with a Ta-content of 20 '14: and higher are oorrosion-resis-
tant in 5 % H01 at 100 dog. The Gr-alloying~of Ti. decreases its
corrosion -oroDerties*in the H01-solution and,the corrosion rate
increases with increasing.:Or-contentg particularly for alloys
with heteroTeneous structure.:Pour illustr..~eight biblio. refs.
2/2
10
USSR UDC11669,018.8
TQWHO~MINI D., HUSKOL, YU. S., IVANOV, YU. 14.0 and PIAVINIK, G. H. ,
L e oft
fn=su e o ysical Chemistry, Academy of Sciences USSR
"The Effect of Phase Composition of Ti-15% Mo alloys on its Corrosion Behavior
In the Active State"
Moscow, Zashchita Hetallov, Vol 7, No~5, 1971, PP 507-513
strue-
Abstracti The corrosion behaviorof Ti alloys with 15-1% 1,10 with a
ture was studied. The alloy.was prepared from titanium iodide'with the addi-
tion of molybdenum, first subject-ing it to crucibleless electrorL-radlation
zone smelli .
.,- ng The smelting was ca.-LTIed out in an are furnace with non-
consumed tungsten electrodes in the holes.o.f a water cooled copper tray In an
atzosphere of speetrally pure helium. At the same time a,control with titanium
iodide was --un in one of the holes. If tbe.haxdness of t) ie titaniura as a
result of smelting was increased due to gas adsorption muoh mote than 10
units on the Vickers scale, the melt uasdiscaided. The 50 g ipgots obtained
were forged at 9000 into rods and sheets, Finally, after.:remov'ing the scale
and surfaces dafect-s, it wds rolled into strlps4.
Thermal processing of the samples was carried out 17y'heatlng evacuted
0'. -y were then
and sealed ampules in a muffle furnace for 30 min. at 950 The
USSR
TOMASHOV, D. IT., et al., Zashchita Metallov, Vol 7, No 5P 1971, PP 50?-513
transfer-red to a water bath and fast mixing the ampule ~as broken. The
samples.prepared in this fashion had a Vickers hardness Hv of 10130 - Igo.
Before the electrochemical studies, the samples were cleaned with sand-
papert degreased with acetone, washed with distilled water, and dried in a
dessicator for not more than I day over CaC12' The tests were carried out
with natural aeration In 40% sulfuric acid solutions at different temperatures.
Since &-&mples with a/!9and,&-?+ CJ structure with a svontanuous natural
air oxide film are not activated at texperaturesbelow 850' "ev+CY
0 1, and with a
structure below 70 p a preliminary.activation:(61 min, in',the same acid) of
the alloys with a gand 9+d-Jstructure at 90. and with a -,4 + 06 structure
at 750 was carried out. Without activation.the,melt reradned in 0the -Dassive
state, having a positive stationary potential (e.g., O,1,v a~ 80 for alloys /-61
and /d + 4,, and a lower velocity, of corrbsion~ (lilO.09 eh' ~ hr). After
activation the alloy was steadily dissolved in an active state with significant
velocity.
A, significant effect is shown by ~141he phase composition of Ti - iC% 1.10
a.110Y ~ on- its corrosion in the activated condition. A much higher corrosion
resistanco is observed with the single phaze'Aalloy, the leaut with the
two phase + C~ alloy, This was determined by the m uch':. higher resistance
22
M REM 005"_.-
USSR
TOVLASHOV N. D., et al., Zashchita Pletalloy Vol 7, No 5, 1971, PP 507-513
of the 9-phase containing, in comparison to the O(and Oj phases , a higher
Thus, for maximum.inerease in the resistance of titanium alloys,
alloys with a 1:5? -stabilizer (e.g.# Mot. Nb, Y) it folloWs that it is possibla
to apply a thermal processing which will pXpm.ote the corj.~ervation.of a single
phase,,& state.
It was also shown that a significant deterioration In the corrosion ro
perties of-TI-Mo alloy occurred in thq presence of the metastable 4J -phase,
In the diffusion of two phase A + (-I and '~e + 0) 4'loys- in the activated
state in the region of a potential of 0.260-0.140 v, a concenti-ated 1,11o phase
accumulates on the surface.
3/3
Orr~00ibn
U~SR
UDC~669.295.018.8
IVANOV, Yu. M., TOMASHOV, N. D.
"Influence of 'Mdllafftar t_a~tors on Carrosion Resistance of Titanium and
Titanium Alloy With 0.2' Palladiumll~
Nauchn. Tr. N-i. i Proyektn. in-t Redkomet,~ Prom-sti [Scientific Works of Scienti-
fic-Research and Planning Institute for them Rare Metals Indus-cry], 1971, Vol. 32,
C,
pp,,130-144. (Translated from Referativnyy..Zhurnal Metallurgiya, No. 5, 1971, Abs-
tract No. 5 1741 by the authors)
Translation: A review of the literature is presented and it i's (temonstrated that
interstitial impurities with contents of up.to 0.2-0.3% increase the corrosion
resistance of Ti, N increasing the resistance even with higher contents. Addi-
tions of Fe and Cu > 0.310 significintly tiamaie corros-lon resistance of Ti.
Cold rolling decreases tile rateof generall,and pitting carrosion of Ti, while
annealing of deformed sheets causes an increase;in the rate of~corrosion. Weld-
ing of non-annealed sheets causes an,incre.ase
`in the width of.corrosion of
welded scams. 5 figs; 2 tables-.22:biblio
refsi;
USSR UDC 669.295..5128'234:620.193.41
CHERNOVA, G. P., KOSHECHKIN, K. I., and.;W-YAP0YJ.U'Y,,,
'.Corrosive and Electrochemical Behavior of Ti-Mo-Pd Alloys in Solutions of
Hydrochloric Acid at 100* C"
V sb. Korroziya i zashchita met. (Metal Corrosion and Protection Collection
of Works), Moscow, "Nauka," 1970i pp,40-43 (from R7.1i-Metallurgiya, No 12, Dee
~,70, Abstract No 12 1831 by the authors)
Translation: A study was made of the.corrosion resistamce of Ti-Mo alloys
(5, 10, 27%) and of the same. alloys supplementally doped with 0.2 and 0.5%
Pd in 3-20% HU at 1000. Alloys ofTi with-5 and 10%:Mrj and-0.2% Pd in 3-10%
HCI at 100* approach Ti-27% Ho alloys with regard toreorrosion. resiotance..
On the addition of Fe3+ or Cu" Aons to 20% IICl, Ti-Ho~~nd Ti-No-Pd alloys
have a corrosion rate > 10 mm/year. -This isAu,e to the.,Aift of the corro-
sion. potentials of thes-e alloys.in the Hbtrmspaasivation region. One
illustration. One table. Bibliography of :10 titles.
25
USSR UDC .669.~295.5'28',26.018.'8-669.234
TOMASHOV N. D., IGNATOV, N. N., and CHERN6VA, 0. P.
all
"Investigation of the Corrosion Resistance of Ti-Mo-Cr-Pd Alloy
V sb. Korroziya I zashchita met. (Metal.Corrosion and Protection Collection
of Works), Moscow, "Nauka," 1970, pp 44-49 (from RZhrMetallurgiya, No 12, Dee
70, Abstract No 12 1832 by the authors)
Translation: A study was made of the corrosion resistance of Ti-Mo-Cr alloys
Ho and 1-10% Cr) and certain ternarynalloys suppleventarily doped with
0.2 and 0.5% Pd in solutions Of H2SO4 (5-40%) and HC1 (5-251) at 20, 60, and
1000. Supplementary doping of Ti-Y-o alloyawith chromium lessens the corro-
sion rate of the alloys in proportion to the increase of Cr concentration.
The doping of Ti-Mo-Cr alloys with palladium raises their corrosion resis-
tance 10-100 times. Two illustrationos :Three- tables. AO~Jiography of 11
titles'.
Him
USSR UDC 669,018.8
TO,11USF0V N. D,, RUSKOL, Yu. S., FILIPPOVI A. F., BELi24X%_1HIK0V, L. N.,
G. M., and FEDOROVA, G, M., I
ITLA nstitute of 2hys 16 Chmistry,
Academy of Sciences USSR
"Corrosion Behavior of Ti tanium-121olybdentun-Chromiun Allo~,s'
Moscow, Zashchita Netallov, Val 6, No 5, Sep-Oct 70, pp 499-504
Abstract: This paper deals with the effect of cbromium~ on the; corrosion
resistance of titanium alloys containing-51:4nd,JOX r'1o1yt)d:enum.: The
electrochemical and corrosion behavior of the~alloys was '$tudied by
-io indicators
potentiometry, both the current and weight ~1*sses beiag t~
of the corrosion rate.- It has been shown -that the fl-phas~ a of 'Llitanium
alloys containing a stable (under thevuesting
ca-aditioms)%'~compa.ient such
Posses - - - a active
as molybdenw-a ses elevated.corrosion "resistatice .7 '.
In tht
dissolucion of two-phase a+a-alloys,oi titatiitx6 vrith mo~,~bdent~ii,
predominantly the a-phase goes inm 0 W the ~.;Pllasv. remains
1; liltiorl 11ile
at the surface in the forn of a f inuly, d ispi!rae layer, lw~the active
1/2
7-7777-77-1 1,
U S 5 IDI
TOMASHOV, N. D., et al, Zashchita metallov, Vol. 6, No 5, Sep-Oct 70,
pp 499-504
dissolution in nonoxidizing,, meAia, thopcorros-ion ratC~ of TI-Mo-Cr allovs
only on'.addition of 'chromium in a n', a r. o u
markedly decreases nt; suf f icient
-phasell-alloys (Ti-51-To
for producing, sinpje -lOCr aid Ti-101lo-IOCr);
however, if the alloys havern a+,q7structUre) thea the ~corroslan rate
remains about the same (as compared to Ti-Vo alloys). , Chropium addition
reduces the tendency of alloys to over-passivation, which is.caused by
the presence of Ma, and the Ti-5111-fo-IOCr P119y exhibito,~Ithv -,,ime low
corrosion rate within 0.15 to 1.2 v as tilanim or Ti-!QCr a",Ioy. At
potentiails which are more positive than 1.2 vIthe corr,Osion',rate of
Ti-',Ilo-Cr alloys begins to increase ot~ing -to the tende)~C~-of chromium
to over-passivation,
2/2
USSR UDC 620.197(075.8)
TOMASHOV, N. D., ZHUK, N. P., TITOV, V. A., and NIEDENEYEVA, M. A.
"Laboratornyye raboty po k-orrozii i zashchite metallov" (Laboratory Studies
on Corrosion and Protection of Metals), Moscow, Izd-vo ".MetallurgLya," 1971,
280 pp
Translation of Annotation: An account is given of 34 laboratory works an the
courseof.corrosion and protection of metals. Each work contains a brief
theoretical introduction, a description o'fecuipment and work methods, and
a discussion of methods of data process' The reference data necessary for
Ing
calculations and a recommended bibliography are presented at the end.
The book is intended for students at schools of higher technical education
as a handboc-.k of laboratory studies:, and:may, 4e-used by %'corrouion laboratory,
personnel. 72 figures, 50 tables, 10 references.
TABLE OF CONTE~TTS
Foreword 5
Introduction
9
I. Processing and formulation.of measurement data
9
II., Brief information on the use:of'ceriain apparatus
21
1/4
USSR ~jj .7777=
TORMHOV, N. D., et al., "Laboratorayye rdboty po korrdzii i zashchite
metallov" (Laboratory Studies on Corrosion and Protection of Metals), Moscow,
Izd-vo "Metallurgiya," 1971, 280 pp~'
Introduction 59
Work- No. 5. Electrode.potential~df met.al~ 64
Work No. 6. Electrochemical hetor,ogereity of corroding
metal surface.;. 73
Work No. 7. Effect of alloy cathode structural:~:components
on the rate of:electrdchemic4l coriosion 82
Work No. 8. Polarization- ands, depolarization of:: the working
corrosion pair electjro6~s 86
Work No. 9. Cathode:depolarization,by oxygen 94
Work No. 10. Hydrogen:overvoltage~ 103
Work No. 11. Passivity of steel 109
Work No. 12. Contact cor:rosion ofimetalA U6
Vork No. 13. Potentios'tatic method ofatudying tile corrosion
behavior of steel.6 121
Work No. 14. Acid resistance of alloys 130
Work No. 15. Temperature.le-ffect on acid metal corrosion 139
.3/4
USSR
TOMASHOV, N. D., et al., "Laboratornyye raboty po korrozii i zashchite
metallov", (Laboratory Studies, on Corrosion and Protection of Metals', Mos cow-,
--wvo "Metallurgiya
.Izd ," 1971, 280 pp
Work
No.
16.
metals
Groundi(underground), corrosion o.f 143
Work No. 17. .
Intercrystalilne~corrosion of chrome-nickel
steel 152
Work No. 18. Point corrosion of cdrrosion-resistant steels 160
Work No. 19. Corrosion of welded-joints 164
Work No. 20. Corrosion of steel:. at coIustant tensile stress 171
Work
No.
21.
Corrosion fad
Igue. of metals
175
Work No. Comparative mdtial corrosion tests'on special
apparatus:.and.,~inE;tallations 182
4/4
'77
777 _77. -7~ -7
USSR, uDc: 66 MaM
RNOVA, G. P and VOLKOV, L. R., Institute of Physical
C
HM
C4=istry, Academy of Sciences USS13
E ff e c tof Palladiwa on the Corrosion and Faectrochemical:Behavior of
N6T Steel"
OKh25
Moscow, Zashchlta Metallov, Vol. 6, no. 4, Jul-,'1;g 70, pp 425-427
J.
Abstract: This study concerns the effect of DalladJum an the corrosion of
0&%25N6T steel in 10 and 20% sulfuric acid at 1000C and fiee access of air.
r -ate of
Mle stut.- shom. that in 20" sulf"uric acid at 100'C the col-osion -
01, z,- u
How-
OKh25V6T steel alloyed with palladium JA.; I-OWer-by one -tj7rlit ~
'LL
ever, since the corrosion potenbials'of atc.els vith pallm,"11 -a j!ail to attain
stable passivity, the steels continue to dissolve.at a co~isiderable rate.
In 10% sulfuric acid at 100'C, a steel with 0.5,:palladium,after a period of
active dissolution is in a completely passive state-and the corrosion rate
is four orders of magnitude lower.than La: passive-active state. -khe
obtained data. suFgest that the passivation of,chromium st~-els alloyed with
nickel (6%) and pallad~~;. (0.1--Oi5f) occuis, in.two stage4';, The first one
1/2
USSR
WAASHIOV, N. D., et al, Zashchita Metallov,~ Vol. 6, no. 4, Jul-Aug 70, pp 421-42?
tat a potential of -0.22 v) is controlled by,the buildup of nickel on the
surface of the alloy, while the second (-0.12 v) -- isinontrallm-i ~y ~.rle ouildup of
palladium. 71he nickel buildup stage is completed by the partial nickel
passivation to its stationary potential (-0.12.v); the prlladium buildup
I of 40.01 v which
stage results in a more thorough passivatilon to potentia,_
corresponds to the cathodic process of hydrogien liberatii~n on,palladium.
Steels with 0.5 palladium affected by oxyge depol&rizat~on (with free
n
access of air) may even exhibit a more thoroug'h passivat'57on up,to potentials
of the order of 0.5 v fonoved by a steep rise..in corrosion resistance.
2/2
0 210 UNCLASSI F I ED' -"13NOV70
2 '2 p MESSING DATE
CIRC ACCESSIG-vi NO-AP0123091
A t
A35TRACT 4ETHOD GF;CONTIMUOUS MECH.
K_CNEWAL (SCOURING) THE '.4HQLE; REACTION , SUP FAC E OF A SOLID METAL
PLECTRODE w'AS USED FOP INVESTIGA310.4 OF: THE KMETICS OF VA~IOUs
CHARACTERISTIC ELECTkODE r-POCESSES. CATHODIC. PROCESSES CiF H EVOLUTION
O'~ Pn Nf, FE, Pil, S~N, 0 ION11ZAT.10i'l ON ~.PD, ACTIVE-_~!,ANODIC DISSCJL-' . (FE,
N
till PBt SNI), ANjDfG PASSIVITY (Trj~ Cp'l AS WEL1L AS: THE EFFECT OF:
ADSOPPITION OF SURFACE ACrIVE,~AN10,111S ON
THE KINETIGS OF ELECTRODE AND
CORROSION PROCESSES ON FE AND.441vmWER.Ei SJUD I ED. 0JFFW"I0N INHP31TION Or-
AN,-ELECTRODE PROC S E LIM I -N A 5 y -G -rA U ~ TI;RRING~OF THE SOLi'-I.
I c, -- _ESS I 4IF-1 13 vp J~o S ~ . I
POT tcj"4 1'~4
A f)S- H131 TION MAY BE COPI'PLETELY: ELIAMINATED (iY SUFFICIE'ITLY
VIG-UROUS MECH. SURFACE RENEe,AL' OEPENIOMG.~:(IN THE NANRE: OF THE 10:1S BE-ING
ADSORBED, THEIR CONC~~)S.j AND ELECTRODE:P01TENITTAL.. : INHIBITION OF THE
T
T
ELECiRODE REACTION OUE Tf[) THE CHARGE TRAINSFER. RATE: IS N1.0T FLIMINATE0 BY
?4ECH. SURFACE SCOURVNG. CUMPARISON OF KINETICS OF~ELE(,TRODE PROCESSES
WITH OK WITHOUT COINIrMUOUS RENEWAL OF'THEI META'1_ ELf 'CTRO DE SUPFACE ALLOWS
A QUANT. EVALUATION OF THE DEGREE OF I N;H 1-81 TION OFi,THE 'rCJTAL ELECTRODE
PR 0 C E S 5 BY ITS IfJ0IVfDUAL STEPS~. CHEM.
FACILITY1 Vi 5 PHYS.
MOSCOW USSR,
U*_"LASS I F I ED
1/2 UNCLASSIFIEP PROCESSING DATE--230CT70
~-.:-.TJTLE--EFFr-CT OF THE VOLUME OF A SO.LUTI.QN AND THE PRESENCE OF OXYGEN AND
TITANYL IONS -IN IT ON THE CORROSION 13F TiTANI:UM PALLADIUM AND TITANIUm
"'AUTHOR-(03)-TOMASHOV N D., CHEkNQVA, GiP.-,~:MATVEYEVAl T.v.
TRY OF INFO--USSR
..~.'~SDURCE-ZASHCH. METAL 19701 6(2)v 14 5-5:6
6 A T EPUBLISHED ------- 70
_~SUBJECT AREAS--MECH*r IND.t CIVIL AND MARINE ENGRt MATERIALS
"JOPIC TA.G.S--TITANIUM ALLOY, RUTHE.NIUM ALLO'fy PALLADIUM Al-LilYr METAL
tOWQO$ ION t OXYGEN, [ON
C ONT R 0 LMARKING--NO RESTRICTIONS
~::-.00CUMENT -CLASS--UNCLASSIFIED
PROXY REEL/FRAiltE-1996/1912 STEP ',)U~--UR/0365/70/006/002/0145/0150
.,C.f.RC ACCESSIOIN NO--AP0118874
UNCLASSIFIED
'CLASSIFIED, PROCESSING DATE--23[JCT70
212 030 U N
ACCESSION !qO--AP0116874
ABSTRACTIEXTRACT--(U) GP-0- AaSTRACT. 'A STUDY WAS: MADE ON THE EFFECT OF
_E AREA RATIO,
THE SOLN. VOL. TO SURFA' souN.i ATM. COMPN.p AND
CHANG
TI PRIME4POSITIVE AUDNo ON THE cbARoSION ~OF TI-P,D~ A ND JI-RU ALLOYS* IN
H 'D
SUB2 SO SUB4 AND HCL SOLNS. AT ROOWTEMP.9 TI-0.2PERCENT PO AN
Tl*_(O.2-0.5PERCENT~ RU ALLOYS IN AN ATA OF N P. A I N T .4 1 NJHF. POTENriAL OF
JHE ACTIVE PASSIVE STATE AND CORRODE AT A HIGHEk RATE THAN IN AN AIR ATM
OR IN THE PRESENCE OF TI 1014S IN THE SOLN., THE TI IONS PROMOTING SELF
CONSEQUENTLY EVEN IN THe.PRESENCE OF CA"m(IDIG ADDirlvEs
.~~-,'THEPROCESS-OF H ION DISCHARGE CAN IN SOME CASES GE INSUFFICIENT To-
SHIFT,THE,ALLOY POTENTIAL INTO THE REG:ION-JF TI PASSIVATION. ONLY THE
INTRODUCTION OF 4DONL. OXIDIZERS110 SUB21-TIO PRIME2POSIT[VE) LEADS To
SELF PASSIVATION OF THE ALLOYS. ALTHOUGH TI IONS HAVE.4 LESS POS. REDOX
POTENTIAL THAN Ot THEY ARE MORE SOL. -AND WHEN THEY, ACCU_-MULATE IN THE
SOLN., THEY ACT AS ACCUMULATORS ANDtARRIERS OF TH_ OXIDIZING F UNC T f.ONS
OF DISSOLVED OXYGEN FROM THE 8ULK~,JJF'-THE SOLN. TO THE C,OHRODING SURFACE.
:ON INCREASING THE RATIO OF S0LN.'VOL.:jO'.THE SURFACE AREA OF THE-
SPECIMEN-OR ON PERIODICALLY CHANGING TH.C.,.S.0L.N., THE, COR0.11SION RATE OF T!
_-AND ITS ALLOYS WITH _PO CAN INCP EASE - NOTABLYt VUE NOT TO THE DECREASE IN
PO ION CONCN, IN SOLN. BUT TOJHE TJTANYL ION L:,QNCNo WHICH ARE
FACILITY;:. 'AINST. FUg KHIM.P IMOSCOW2
SUPPLEMENTARY OXIDIZERS.
USSR.
UNCLASSIFIg:O
2 / 2 0287 UNCLASSIFIED PPU(;EssrNG DATE--Z3OCT70
C* I R CACCESSION NO--AP0118910
,-',.A-BSTRACT/EXTRACT--(U) GP-0- ABSTRACT. STUDIES PERE MADE OF THLCK FrLM
ANODIZING OF 4NDUSTRIALLY IMPORTANT A L- ALLOYS IN ~i SU62 SO SUB4 20 PLUS
H SUB2 C SUB2 0 SUB4 15 G-1. AT 15-16DEGREES, 2.5 AND'5 A.-OM PRIME2
C.D., AND FOR 0.5-3.5 HR. VOLTAGE VS-TIME CURVES ARE OBTAINEO AND
THEIR CHARACTERISTICS ARE EXPLAINED. THE RATIO ETA OF THE Ia. OF t'NHY0.
AL SUB2 0 SUB3 FORMED TO THE WT OF AL REACTED DECIREASES WITH TIME FOR
MOST CASES DUE TO DISSOLN. OF THE OXIDE FILM. THF QUALITY OF THE
THE
ANODIZED FILM DETERIORATES WITH LOWER ETA. T?-'.ICKN=SS INCREASES
LINEARLY WITH TIME AT THE RATE 0.7-1 MU-MIN. FOR ALLOYS CONTGo
NEGLIGIBLE CU,, THE MICKOHARDNESS.IS -480-520 KG-MM PRIME2. CU DECREASES
THE MICROHARDNESS AND INCREASES THE PdROS11Y. AT THE HIGHER C.D. Or
5A-DM PRIME2r THE FILM QUALITY IMPROVE.Se THE CWIPOSITE ELECTROLYT[-
GIVES FILMS COMPARABLE TO THOSE OBTAINED IN COLD H, SUB2 SO SUC34 AND CAN
'olbE USED WIDELY IN PRACTICE. FACILITY-* I N ST..., FIZ. KHIM., MOSCOW,
USSR.
UNCLASSEFLED
024 UNCLASSIFIED PR068'SSING DATE--230CT70
0
,.TITLE--EFFECT OF AWMIONIUM IONS~OW THE'~~ELECTRODEPOSITION OF CHROMIUM FROM
SULFATE SOLUTIONS -U-
.-'AUTHOR-(021-TOMASHOVA, G.N.,~ VAGRAMYAN.t A v:T.
~,COVNTRY OF:INFO--USSR
..:SOURCE--.ZASHCH. METAL. 1970t 6(2)i182_5
~.DATE PUBLISHED ------- 70
,SUBJECT AREAS--_CHEMISTRY
AMMONIUM COMPOUNDt IONv CHROMIUM
STEP '40--UR/0365/701006/002/0182/0185
'ACCESSION NO--AP0118873
UNCLASSIFIED
7-7-7-
2/2 024 UNCLASSEF'.18D. PROCESSING DATE--230CT70
-C.IPC ACCESSION NO-AP0116873
.~.,ABSTRACT/EXT RACT--fU) GP-0- ABSTkACT. CR METAL WAS DEPOSITED ON A CR
PLAT'ED CATHODE FROM A 0.2M SOLN. OF K CR OXIDES (CIR PRI-lE3POS!TIljf---) AT
PH 1.9 AT 35DEGREES. THE OVERALLELECTRODE REACTION RATE WAS INCREASED
IN THE PPESENCE OF NH SU84 PRIMEPOSIT1VE (F'~lbm NH S'Jii(t) SU~52 SO SUB4)
BECAUSE NH SUB4 PRIMEPOSITIVE ACTIVATED THE CATHODE SURFACE BY FREEING
IT OF OXIDES AND HYDROXIOES. ADON . OF- 0.5 MOLES~ NH SUB4
PRIMEPOSITIVE-1. ACCELERATEO THE,METAL DEPOSITI'FiN AT, POTENTIALS 1.0-1.2
AND AT 1.3 V, IT SLOWED THE OEPOSITIQNo~ 4T ALL1,PUTENrIALS STUDIE0 5
7*MOLES NH SU84 PRIME POSIT IVE-1. DISSOLVED. THE NETAII INSTEAD OF DEPOSITING
JT. THE QUALITY OF CR DEPOSITED WAS ENHANCED~BYJHE PRESENCE OF NH SUB4
PRIMEPOSITIVE*
UNCLASSIFRO:~
USSR 621. --1,1-6.6
MONTESTROV, V. M., NOVODERE-2:1.11-UH, V. P, F. DIPBOVA,
E. S. , KISILEV, V. 1.
"A Device for Protecting the Front Surface of 01)-Ucalroystevul,,
yye Zn~ -,i,
Moscow, Otkrjtiya, Izebreteniya, Pro.Wshlemm,-ye Obra:?,L,,, ~Torarn,
No 6, Feb 72, Author's Certificate No 328411, Division,"a, ffiled 20 Avg 69,
published 2 Feb 72, p 143
Translation: Mis Author's CerLificate introduces a di-_-vice for protect.-
ind the f o. t o
opticO. systemn. f rom, -;,tmnsj~heric canti: T'.Q
j-r n cc
containu a fittinF, ihich Tmte~; vith the mount of the Opt ical s ys t f L, mid
has a Joint for feecl-ing in compressed gas As a distiiif;u-Ishing feature
of the pateut, iln order to nre,,~er-vl~ image ~(rikllty, the ~urlit for feedirl~
in ga3 is maide in the form of a gas-,collecting chwxb -with guide chan-
nels which goes iAto a blender- nozzle.
137
USSR UDC:, [537.226+537.,,-11.331..r537+r-1351
ITbrr6elec,tricity in Pine Films"
-or. kachestvon i standart4z.
te?nn sb. U
Elektron. tekhnika. 111auch.
(Electron Engineering, Scientific-Technical Collection, Quality
and Sta'ndardi--ation Control-collectlbii.of works') No. 1M, 1971,
PP,3-12 (from RZh-Fizilca, 1,10 11, 1971p Abstract. I-To - 111, 917)
Translation: A theory is propoqd for them f eii*roelectric charac-
teristics of BaT'03 films 1000.A in thicImess; the co Iravated and
xperimental data are
compared;~ the peculiariti~,41 of.the emergence
offerroelectricity in thin filos are analyzed.~ ~~Re,Oume
57
PR
U35 UNCL4SSIFitO' ' OCE'SSING DATE--11SEP70
Tl_tLE--PHASE TRANSFORMATIONS OF-GADOLINIUM. M3LYBDATF_ AND ISOSTRUCTURAL
--comp
OUNDS __U_
.-AUTHO.R. -DRnlYSHEVp L.A.9 FROLKINAi I T.:~, PoNOMAREV V.Iot T0,"lASHP0LSKlYv
VENEVTSEVv YU.N.
RY or-*INFO--USSR
U
NT
7