SCIENTIFIC - PHYSICS

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CIA-RDP80-00809A000600231008-7
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8
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December 22, 2016
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July 15, 2011
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1008
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July 1, 1949
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REPORT
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Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 C'_+.SSIF ?\TION - SAT CENTRAL I Y IMFORMATION FROM FOREIGN DOCUMENTS OR RADIO BROADCASTS COUNTRY USM SUBJECT Scientific - Physics HOW PUBLISHED Monthly periodical WHERE PUBLISHED Moscow DATE PUBLISHED Jun 1946 LANGUAGE DATE OF INFORMATION 1948 REPORT CD NO. DATE DIST. I ?,u;l 1949 NO. OF PAGES 8 SUPPLEMENT TO REPORT NO. THIS IS UNEVALUATED INFORMATION Zhurnal 1 ri7ees.; -I Inoi Teoraticheako Fiziki, Vol XVIII, No , 1, V. Zrd:mov and L. Tilchonova Siberian Physiec -Tech Inst Tbmak State U 25 Nov 194T ffiguree referred to are appended] .The stability of a monatomic cubic face-centered crystal lattice during unilateral compression a:yi extension is discussed. It is shown that the collapse of a lattice during compression and extension has an essentially distinct and dbfinite character and. that the lattice reefs+s compression considerable ese than it resists extension. 1. It is veil known that residual inelastic stra:as in macroscopic solids are a secondary result of the collapse of microscopic crystal. lattices in certain minute regions, which appear initially as regions of overstrain. Stepanov, for example, shoved experimentally that the phenomenon of the collapse in solids coreicte of tVo phases. (l) t-.e appearance of centers of disintegration or collapse "nuclei" and (2) the development of these minute nuclei into a macroscopic formation. In those regio a serving as collapse nuclei or centers )f disintegration in solids, stress and strain evidently can attain large values. It can be assumed that the mechanical stability of these regions and the moron inelastic deformations attain the same values as those calculated from the theory of crystal lattices Insofar as the behavior of thece regions of overstrain is determined by the development of plastic strains and fractures, it to essential to know the conditions governing stability in ideal crystal lattices for various conditions of stress. These conditions should tatormine the mazie?m stress at which thv lattice can st?,ll be elastically deforaed (defining the stabl ityy of the lattice), and its maximum elastic deformations. CLASSIFICATION DATE MW I ARIrY NR FBI - 1 - DI'S71I1l m _L I H Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 50X1-HUM They should slag ohc?,:n hsv >r, idea` c.ya: i lattice collapses when stress exceeds the mnximun permltted for olastic stress values. Of course, a theory based on the concept of 'n ideal crystal lattice can- not fully explain the dynamos of collapse in a lattice, but an idea of the initial phase of disintegration in s collapsing lattice can be completely developed. Because of the rather large elastic strains in the regions of o.Jistrain, deformations naturally cannot be described by the theory of elasticity as based on Hooke's law. Nonlinear terms can be introduced into Hooke's law to describe such strains, as was done by Mixnaghan in the case of a continuous medium and by Fuerth for cubic crystal lattices. These authors supplemented Hooke's law with second-order terms relative to components of homogenous strains. For these problems, spch a ge"e tlization yields five constants characterizing the elastic properties of material., instead of the two in Hooke' s law. , However, elastic strains in an ideal lattice can be so large, e.g., amounting to one third of the initial volume, that calculations of only the first-order and second-order tome, and the discarding of third-order terms and above will become baseless. The, calculation of still h1'_hfr-order terms will lead to nsv: constants of elaasticity in such large numbers that their physical significance and the description of elastic properties of solids will be vague. It seems more expedient to us, in cases of great stresses and strains, to use:iooke's law, i.e., "linear" relationships between stress components and strain components, taking into account the dependence of ordinary coefficients of elasticity (according to Fuerth'e first-order coefficients of elasticity) upon strain nr stress. From this point of view, the coefficients o, elasticity lose their significance as characteristics of the materitu. itself and become functions of stress; but with their help we can draw an ordinary "classical" picture of the elastic properties of a solid in a strained state without'requiring new coefficients of elasticity (second-order coefficients and higher). 2. A condition governing stability in crystal lattices is positive free energy, considered :is a quadratic function of the components of unilateral stn-t-, of the lattice, preliminarily deformed by externe.l siresses. These are represented by positive coefficients of elasticity in the determinant and its chief minors. Because the det-,)xminant is of the sixth degree, there will be a total of six conditioao governing stablity, expressed by the coefficient of elasticity. P. specifi, physical significs. ce can be attached to each of the conditions governing stability; therefc.f during the collapse of this or that condition the lattice will collapse in a specific manner. They nature of the W lapse of the lattice is evidently determined by that condition governing 3tablitiy which is the first to collapse. 3. In the present work we shall consider the stability of a monatomic c"bic crystal lattice under monoaxtal stress -- unilateral compression or extension along one of the edges of an elementary nucleus We shall set the coordinate axes along the edges of an elementary lattice cube and set the stress along the Z-axis so that Xx= Y,, = 0. zz-f ; YZ~ZX~~(y~ a. (1) Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 CO AL. Then the elementary nucleus takes on rhe form of a rectangular parallelepipedon and the la"..rice aoswaee to;,tagonal symmetry; the lattice will be characterized by A;ix r;oefficients: C11, C33, C44, Chti, C12, C23. With this we ;btain the following corditions of stability; I) `ii -C~arte'D; aJ c!+" ',a~ 0; 33(C,,+ e, z.) C,,--20,4>0. 4)c,~>O 5) ca>'? 41 c,,>0 7 rw?O? (2) We assume that the energy of interaction of two particles is expressed in the form a-g,Y ~t 1 ry t Y ) (3) where e is the energy of dissociation of the d -=tomic molecule; to is the' equilibrium distance in the molecule and d' is the distance between interacting particles. For numerical tale""latious we assume m,n ? 6,2.2. In view of the problem's symmetry, t., parameters of state can be selected as the length a of the edge perpendicular to stress and the ratio ec of the length of the edge, parallel to stress, to the length a,. In their work Zhdenov and Konueov briefly discussed a method of calculating the elasticity of a crystal lattice as a function of the staves upon it, .nd set up general formulas for the equation of state and coefficients of elasticity. The general formulas were quite unwieldy; therefore we shall state here only the s npler formulas for the case of 'temperatures near absolute zero. The equations of state then will be: Sae+2` S7r+2 ~a~~ ~(Sf31 S(S) y~l1 ~,{2 7r+2 c, 7. The consideration of the first ease should result in. an essentially different relation of p rd), from that given In Figure 1. During coa*re. lion of a face-centered lattice a stable volume-centered. lattice should occur; that Is, the tangent of the curve pfel) at the 'point o( should be positive and hence the curve should have the form as shown in Figure 3. Deformation due to compression according to the curve in Figure 3, should lead not to simple collapse in tae cubii face- centered crystal lattice, but to its polymorphous transformation into a volume-centered lattice. Thus the problem of central forces can distinguish two types of face-centered cubic 1-ttices; lattices of one type collapse during unilateral compression and lattices of the other type undergo poly- morphous transformation. Peng and Power etudied the stability of a monatomic face- centered cubic lattice (m, n, = 6, 12) relative to extension (and compression) along the major diagonal of a cube. They established that during extension, the face-centered lattice passes into a free simple lattice and that with further extension the free simple lattice passes into a volume-centered one. Considering the lattice energy as a function of the parameter of extension .Y , they fur?.her found that face-centered and volume-centered lattices are stable because they correspond to miniasom energy and that a simple lattice is unstable because it, corresponds to ^.aximim- elnergy. As a matter of fact, the energy surface at the point of the volume-centered lattice forms a saddle -- a minlimm relative to the parameter of Pang aid Power and a maximum relative to other parameters and in rerticular to our parameter cC ; therefore, such a lattice for the law of forces given above is unstable. We shall now investigate the conditions of stability (2). a. 3)Ci-'-e,,>44cu>4Q)4 Al_ these conditions have a tendency iovards disruption ituring extension. This tendency is lacking or weakly expressed during ;onpression. Figure 4 above the left parts`.of conditions 3), 5), 6), for TowO. The change in piassure was taken in the range determined by the equations of state, C I I I W I AL Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 cc The expression C11 C1~ eo?als the coefficient of shear in the plane of the "face of a rhombic dodechahedron"; Cll - C12 during extension decreases to zero at p/p,.= $.j1 am A thereupon becomes negative. Consequently, during axtensicn the lattice decreases its resistance to elaetio shear in the plane cf the face of the rhombic dodecahedron and at p/po $.5 loses stability relative to these shears. The stress at which C11 - C12 becomes zero, we shall conditionally call to "third" stability of the lattice. The coefficient C33 characterizes the resistance of the lattice to extension iarallel to the basic stress. By increasing the extension stress the coefficient decreases, but remains positive for all values of pressure, and becomes zero at p=p nmx. Thus at T = 0 the "fifth" stability agrecoa with the absolute stability of the lattice. The coefficient C44 is characterized by resistance to shear in the plane of the face of the cabs; perpenciicular.to the applied stress p. As can be seen in Figure 4, the lattice does not lose stability relative to such shear, although its resistance can be greatly weakened. b. 7) C66 >O . ^-i.e condition of stability has a tendency to disruption during compress:..: of the lattice. The left part of this condition for T+s+ 0? is represented in Figure 4. Coefficient C66 characterizes resistance to shear in the plane of the face of the cube, parallel to the basic stress p. The graph clearly shows that the lattice remains stable relative to these shears, although the resistance to such shears during the prerence of "basic" compression is weakened. c. 1) (G?+C,s)Cs3 2,19J?0. This condition has a strong tendency toward disruption in case of great compressive and extensional stresws. d. 2) C,,?C, . >0,4)G?>O. The left parts of these conditions of stability, for all values of pressure, remain quite large. Therefore their investigation is not essontial.. Thus investigations of conditions of stability yield the following conclusions: Exteneio:.- -- During extension the lattice collapses because of she4rs in the llane of the face of a rhombic dodecahedron; the oorrer eponding "third" atr.uility appears as the lowest of all the stabilities of the lattice. Compression -- In the case of compression the accuracy of calculation (accuracy of calc..l.ating see) proved to be inadequate. There- fcreuno definite conclusions can be mode concerning the character of lattice collapse during compression. Because the first condition is disrupted during rompression in the limits of abio.lute atabtlity, collapse can be asetmted to take place by the appearance of a complex eoexdinatlon of the particles. This can be contthaod by the ultimate compression -- the appearance of P. free volu.ae-centered lattice. We did not investigate the important problem of the simulteneoue influence of monobasic stress and temperature upon elastic characteristics and stability of the lattice. This problem will be investigated separately. CAL Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 We wish to thank Proioeao Ya. I. Fi?, kel' for bia valuable comments during preliminary discussio. of this work. [5 1 V. Zbd.aacv and L. Tikhonova, Theses and Annotations TV 44 BIBI.IOCBAPHT A. V. Stepanov, Zh''1'F 17, 601, 1947- F, D. )4urnc han, An. Jour. Math 59, 235, 1947. B. Puerth, Proc. Boy. Soc. 180, 285, 1942. 47 4 .] V. Zhisnov and V. Honuso?, Trans. Siberian FTI 24, 30, 1947. , Conference of Young Students of Tamale, 19 [6' J M. Born and B. luerth, Proc. Cambr. Phil. Soc. 38, 454, 1942. [7 _ V.. Born, Proc.Cambr. Phil. Soc. 37, 160, 1941. [8 ?] R. D. liera, Proc. Carabr. Phil. S- 36, 466, 1940. [9 ] B. W: Pang and S. C. Power, Proc. Cambr. Phil. Soc. 38, 67, 1942. DA peaded figures foliow_7 CO ML Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7 CO P, -7/10 io q Figure X. The relation between the Parameters of equilibriui of the lattice. Volume-centered lattice is stable. Figure 2. Formation of a volume-centered lattice from a face-centered one. Figure 3. The relation betveen the parmetere of equilibriua of the lattice. the volume-centered lattice is stable. CINMAI Figure h. Coefficient of elasticity, as a function of stress (pZI0 . 50X1-HUM W Sanitized Copy Approved for Release 2011/07/18: CIA-RDP80-00809A000600231008-7