SCIENTIFIC ABSTRACT NESMEYANOV, A.N. - NESMEYANOV, S.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001136630002-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

111casurement of thalliuia ...
a-/02U/61/140/001/020/024
B127/B101
is atomic-.. The mean evaporation heat of thallium between 519 and 9240K
1.� 40-72 Ikeal/mole. The uuthors used L. V. Gurvich's equqtion
R 1n P - t%"'~' - LIHOIT (Zhr-Kh, J4, 917 (1960)) to calculate AH
'4, r
9 0
There are 1 figure, 1 table, and 12 rc-ferences: 7 Soviet and 5 non-Soviet.
The reference to Ln-lish-language pl.Ablicatior reads as followo:
0 0
F. F-Gollemann, A. Egerton, PhiJ1. Trans., A 234, 177 (1934).
ASSOCIATIONt Moskovskiyr goou&1ratvennyy univursitet ifit. M. V. Louionosova
(mosco-w st;jte Univemity ijmcni M. V. Louionosov), Sofiya
Institute of(,hemical Technolor,y, 30,riria
PRESERTED: April 6, 1961, by V. 1. Spit3jji,
SUBIKITTIO: It-arch 2.0, 1961
Table I.. Vapor pressure of thall1wa
Legend (1).numbeir of exjjeri(ixnt, (2) sec, (3) ('0 c'Icla'-sec, (.'3) m1p
Hgt (6) kcai/inqle.
Card 3/14

NL%WMOV, Andrey Nikol ch--Drof., doktor khir. nauk;
.9 . .. red.; A&,CNA, A.S., tekbn. red.
[RacUoactive isotopes in naturelHadioaktiviWe izctopy
rode. bloskva, Izd-vo 07manie," 1962. 35 P. (1-lovoe, v
nauke,, teklmike. IX Seriia: Fizika i khimiia,, no.16)
(MIRA
v pri-
zhizni,
15:9)
(Radioisotopes)

NEMYANOV, A.N. -' PRIMKOV, Yu. A.; KARIMIN, V. V.
7
"The Vapor Pressure of Yttrium"
Report presented at the International Atomic Energy Agency
Symposium on Thermodynamics of Nuclear Haterialsp 21-25 May 62
Visma, Austria.

S/195/62/003/004/002/002
E075/E436
AUTHORS: Pozdeyev, V.V., Dzantiyev, B.G., Nesmeyanov, An.N.
TITLE: Utilization of*hot atom reactions for the investigation
of the intermolecular energy transfer processes
during radiolysis of organic materials
PERIODICAL: Kinetika i kataliz, v.3, no.4, 1962, 613-614
TEXT: The cyclohexene-tolan system was investigated to assess the
possibility of using hot radioactive atoms to produce labelled
cyclohexene excited molecules. Study of the stabilization of such
molecules in different media was expected to give information on
the energy transfer from the excited to solvent dolecules.
Excitation and labelling of cyclohexene molecules was carried out
by exchanging H atoms with a hot tritium atom, It was found that
the resistance of cyclohexene to decompooLtion increased with the
concentration of tolan in the mixture. However the increasing
tolan concentration had almost no effect on the specific activity
of cycldhexene. Thus for the system investigated, changes in the
concentration of the aromatic component did not influence the
Card 1/2

S/195/62/003/004/002/00'2
Utilization of hot atom ... E075/E436
stabilization process of the excited molecules of cyclohexene but
decreased effectively its radiolysis. Other i;ystems must be
studied to test the general applicability of the method.
There are 2 figures and 1 table.
ASSOCIATION: Moskovskiy gosudarstvennyy untversitat
im. N.V. Lomonosova. Khimicheskiy fakulltet
(Moscow State University imeni M.V.Lomono3ov
Chemical Division)
SUBMITTED: March 26, 1962
Card 2/2

NESHEYANOV, An.N.; MANTIM, B.G.1 POZDEYKV, V.V.; SIKOKOVt ra.F.
Reaction of recoil atoms of tritium with benzene, Hadioichials. 4
no.lin6-222 162. (MIRA 15W
(Tritium) (Benzene)

AMAR NAT; NESMETAMOV
I- --.
Recoil effect in inner complexes of cobalt during the reaction
Co59 (a, 2n) Co5g. Radiokhimia 4 no.1:122-124 162. (MM 15:41
(Cobalt-Isotopes) (Cobalt compounds) I

I ISCRIM" DZMIMV,, B.G.
Effect of halogen-containing additives on the reaction
of tritium recoil atoms with benzene. Radlokbimia
4 no./+0984+04 162. (HIM i5:11)
(Tritium) (Benzene) (Iodine)

EVS V.V.; W=YANOVg An.j.; DZAMMV, B.G.
Wfact of the aggregate state on the reactions of
tritium recoil atawo with hydroawbons,, MWickbimia
4 no,4:404,-410 1629 (M* 15:U)
(Tritium)
(Hydrocarbons)

S /I 80/62/COO/005/00 5 /011
E073/9535
A UTHU RS V.11. . N ri se Ikov, Yu. A. Ojo scow)
TITLE: More accurate data on the vapour pressure of metallic
y t triula,
P6R.OjOICAL Alkade;.J.ya nakik SF~SR. lzvestiya-, Otdoleniye teidini-
d
cheskilAi naulk. ~-rctallurgiya i toplivo, no.5, 1.902,
117-118
In an aarlier published paper, the authors studied
the vnpour pre85urc of rnet~,Ilic yttrium of a purity of 99.9,01
(without taking.into consiCeration, gaseous admixtures). According
to those results, the vapour pressure can be expressed by
lg Pinin 11,q =7.8130 5T803
This agreed with resiilts obtained for yttrium of 99.5% purity
(0.10,la Ta, o.4%, o New investigations were carried out with
2
high-pitrity yttrium containing only traces of metallic admixtures
and less than 0.10~ gaseous admixtures. The obtained data are
tabulated for the temperoture range 1132 to 1460"C. According
Card 1/2

AWM
More accurate data on the vapour ... s/18o/62/000/005/005/011
E073/1;535
to these data, applying the method of least squares, the vapour
pressure of high-purity metallic yttrium obeys the following
relation: 1g Pnim H 9= V,.C'7,11,6 -- 18T515 (2)
From this, tho siiblimatiori hoat was determined at 84.71 kcal/g-atrXII.
The divergence between the here obtained and the earlier rosults
is explained by the evaporation of volatile sub-oxides of yttrium,
the existenep of which was confirmed by means of a resonance niass
spectrometer. A simi.I.-,r phenomenon wari observed by GoIdstein,
Walsh and White (On the use of tantalum Knudsen cells in high
temperature thermodynamic studies of oxides, J.Phys.Chem., 1960,
64, No.40), 1).1087) who proved by means of a mass spectrometer that
the increased rate of evaporation of La oxide from tantalum
crucibles is caused by the reaction
3Ta + 4(L)La 203 ' 2TaO + TaO2 + 8(L)LaO.
The relative limit error in iaea.-3uring the vapour pressure was
+201,, for the radioactive an(] +24% for the non-radioactivo apechlIfTLs.
There is I table.
SUW,,11TZD: Jun,-I 5. 1962
Card 2/2

S/199/62/000/002/003/004
D228/D302
AUTHORL-): Karelin, V.V.p Nesmayanny AN Priselkovt Yu.Aot and
Chou Klun-Ying
TITLE: Measuring the pressure of metallic yttrium vapor
PERIODICAL: Vloscow. Universitet, Vestnik. Seriya Up khimiyav-!~ '11
no. 2, 19629 40 - 41
TEXT: The authorn measured the pressure of metallic yttrium vapor
by the integral version of Knudsen's effusion method# The amte of
evapd. matter was detd. either photometrically or radiometrically
at different temps.; the results are given in a table. The value
of the heat of evapn. which equals 72a31 kg-cal/molet was found
for the temp. range 1j61-17610K from the equation; log P(in mm Hg)
= 7.8130-15803/T. The heat of sublimation of yttrium at 2980K was
caled. at 85#71 kg-cal/mole the value for the coefficient of eva-
poration being v0.05& The coincidence of data, obtained with diffe-
rent equipment and samplesp is considered to illustrate the reliabi-
lity of the results# as is their general agreement with those of
Card 1/2

3/169/62/000/002/003/004
Measuring the pressure of metallic D228/D302
K.A* Gshneyders There are I table and 5.references: 4 Soviet-bloc
and 1 non-Soviet-bloce The reference to the English-language pub-
lication reads as follows: D.R. Stull at alt Advances in Chem6, no*
18v 1956*
ASSOCIATION: Kafedra radiokhimii (Department of Hadioohemistry)
SUBMITTED: June 21P 1961
Card 2/2

5/032/62/028/003/008/017
B101/B138
AUTHORSs Nesmeyanov, An. N~, Pozdeyev, V. V., and Klass., Ya,
.N.~
TITLEt Measurement of the activity of organic compounds containing
tritium
PERIODICALs Zavodskaya laboratoriya, v. 28, no. 3, 1962, 305 - 307
TEXT: A variant of K. E. Wilzbach's method (Ref. 3, see below) is
described. The tagged organic substances are heated with zinc dust
nickel oxide, and water in an ampoule at 6400C for 3 hr. The temperature
is measured with a Chromel-Alumel thermocouple connected to an AVM-47
(ERR-47) apparatus. The resulting methane and hydrogen (pressure 20 mm
Hg) are pumped into an C6M-8 (SBM-8) counter, and cyclohexane is added
up to a total pressure of 40 mm Hg. The activity is measured with a ~
(B) radiometer. By using cyclohexane instead of butane as quenching gas,
the CH + H 2 concentration can be increased and the size of the apparatus
reduced. The method was used to measure the activity of tagged cyclo-
hexene, cyclohexadiene-1,3, and adipic, succinic and glutaric acids The
error of measurement was not more than 1%. The accuracy of measurement
Card 1/2

S/032/62/028/003/008/017
Measurement of the activity ... B101/B136
does not depend on the amount of H20 added. Therefore it is possible to
convert tagged organic compounds without H20 addition, which is important
for measuring only slightly radioactive preparations. There are 3 figurekk
1 table, and 4 references: 1 Soviet and 3 non-Soviet. The three refer.-
ences to English-language publications read as follows; Nucleonics, ',6,
no. 3, 62 (1958); R. L. Wolfgang, C. F. Mackay. Nucleonics, 16, no, 10.
69 (1958); K~ E. Wilzbach, L. Kaplan, W. G. Browns Science, 118, 522
(1953).
ASSOCIATION. Moskovskiy gosudarstvennyy universitet im, M, V. Lomonosova
(Moscow State University imeni M. V- Lomonosov)
Card 2/2

NESNEYANOV# ln.X,; YM9TAp L.P.
got synthesis of coqpovr& togged wM rulioactive carbon&
ITap.Hda. 31 no.12t2453-U77 0 162. (?WA -16s2)
1, Niaskovskly.gamdarstrem*7 universitet, Tchfuld eal-dy
fakulltet,, kafedra, radiokbimilio
(Chemistr7,j - Organic-mSynthesis) Carbon-Isotopes)

/0,5~v- /V**.
.17519
3/02Y62/144/001/017/024
BI 19 B1 44
A., Xomissarova, L. N., Karolin, V. V.,
P-icelkoy Yu. A. Neszoyanov, An. U., an& Spitayn, Vikt. I.0
Investigation of high-purity metallic scandium
2:210DICALs Akadeaiya, naulc SSSR. Doklady, v. 144, no- 1, 1962, 122 - 125
T-LT: 99.5F,; pure So was produced by high-vacuum distillation of 97 - 97.%1-
'o
So. The pure metal was studied metallographically and tested I r its
".)Ohavior to 021 N2 (in a device desioned by R. D. Shapovalova, and
A, Vasillyeva), and differently concentrated solutions of ZCIO H2 4#
M.0 and raOIC at 25, 50, and 100100. 'rhe results were compared with those
obtained for 97,". Sc. The polished, non-atchod surface of 97,.~ So reveals
the z;Tain boundaries in polarized and nonpolarized licht. No second phano
appears in spite of 0.9~O' oxyaen content. With hiGh-purity Sc, the grain
:)cundaries are only visible in polarized light. 99.5F,; So starts reacting
at 2000C with 020 at more than 60GOG with (formation of ScX). DisGolvirZ
112
Card 1/2-

5/020
/62/144/CG1/017/024
InvestiCation of hiZ~h-yurity... B119/B144
tests rith t*r..^ ac;enta mentioned vere made under condition3 effectinc a
reaction of zero order. The dissolution rate constant for So of 'both de-
crees of Purity was 0-75 mg-1.02-2-min-g-eq at 2500 for H. so4 and HCI, and
0.015 for M10,. According to calculations, the activation enerMr of the
diasolvine process was 9.0 t 0.2 kcal/g-aq.' So reacts vary slowly with
I,r_011 solutions of more than 10~4. From 97 - 99-Z, the purity of "he se;%ple
hac; a =uch stronger effect on the physical than on the azemical properties
of So. There are 4 fidurea and 2 tables. The most important
IruiCaago reference'is: P. 11. Speddinp, A. H. Daane, G. Warkefield, D. H.
Dennison, Trans. Netallurg. Boo. IM, 218, no- 4, 608 (1960)-
ASSOCIATIONs I-oskovskiy voijudarstvannyy univarsitat im. U. V. Lomonosova
.(Loacow State University imeni U. V. Lciaonosov)
S ED a Januarr 12, 1962
Card 2/2

38107
5/020 62/144/002/619/028
3, BI 01 %144
AUTHORS: Karelin, V. V., Neemeyanov, An* Not and Priselkov, Yu. A.
TITLE: Vapor pressure of metallic scandius
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 144, no. 2, 1962, 352-354
TEXT: Data of F. H. Spedding, A. H. Daane, Go Wakefield, and Do H.
Dennison (Trans. of the Metallurg. Soc. AIME, 218, no- 4, 608. (1960)) on the
vapor pressure of So were verified by Knudsen's integral effusion method.
So was evaporated out of a tantalum crucible, and the vapor was condensed
in a quartz receiver. Th~ amount of condensate was determined
radiometrically usinff Sc4o# and, in some cases, photocolorimetrically
using arsenazo. so4rwas obtained by bombarding So with slow neutrons from
a nuclear reactorg and its purity was checked with a gamma spectrometer
or by liquid chromatography. Results: (1) At a oonstant teaperature of
1430'OKP saturation was reached at an SAd ratio of 600-60#000 (3 to gree of
vaporizing surfacel X to Klausingla coefficientl and 6 a area of effusion
port). (2) In the range 1301-16440K it is found that log P (MM ft)
so
to 8.6553-17576/T. (3) The heat of sublimation of So in given by
Card 1/2

3/020/62/144/002/011/028
Vapor pressure of metallic ... BIOI/B144
&HT - 80-42 kcal/g-atom; I&H29.0 . 82.26 kcal/g-atom. (4) The present
are a little higher than those given by Spedding et al. (errors: +15~.
Wi;h the use of radioactive samples, and + 20% with inactive samples)whioh
are believed to be too low by reason of ~_Gystsmatic error. (5) The
results are significant for the vacuum metallurgy of rare-earth elements.
There are 2 figures and 1 table.
ASSOCIATION: Hoskovskiy gosudarstvennyy universitat im. M. Ve Losonosova.
(Moscow state University imeni M. V. Lomonosov)
PRESENTED: January 22, 1962g by Vikt. 1. Spitsyng Academician
SUB-3-11TTED: January 12, 1962
Card 2/2

POZDEMP VA.; MMMOV, An.11.; DUSTMV, B.G.
Tritium recoil atoms and intramolecular migration of
energy. Kin.i kat. 4 no.2-318-319 1-t--Ap 163. (bCMA 16:5)
1, 14ookovskiy gosi4arstvennyy universitet imeni Lotmonosova,
khimiche4kiy fakulttet.
(Benzene derivatives) (Tritiun)

.#t
NOMM".
103.
(JURA 16.-2)
(Cobalt cmpounds) (Cobalt isotopes)
(Nuclear reactions)

MESMEMOV, An.N.; FILAMVp E.S.
Role of high energy reaclUons in the procesgres of stabilization
of byamine 82 hot atoms, in alkyl bromides. Radiokhillia 5
no.3:378-389 163. (MIRA 16 t 10)
(Bromine Isotopes) (Alkyl bromides)

DAKAR, G.M.; IOFA, B.Z.; NESMYANOV, An.N.
Extraction of complex acids with oxygen-containing solvents.
Part 1: Extraction of micro- and macroquantities of antimony
(T) with alcohols, ethers, and asters. Radiokhimlia 5 no.4:
428-436 163. (MIRA 16tlO)
(Antimony isotopes) (fttraction (Chemistry))
(Hydrolysis)

AVDONINA, Ye.IL; NMWYAIIOV, An.N.
Reactions of tritium recoil atoms in mixtures of cyclopentane
with cyclohexane. Radiokhimiia. 5 no.4:514 163. (KM 16:10)
(Tritium) (Cyclopentane) (cyclohexane)

. IESMEYANOV, An.N.; TSZYAN TAY-VAN [Chiang T'al-wang]; FILATOV, E.S.
Interaction of hot atoms of tritium with allphatic alcohols
in the liquid phase. Radiokhimiia 5 no.4,:515-516 063.
(KMA 16:10)
(Tritium) (Alcohols)

NESHEYANOV, An.R.; HUDROIIA-YABIDNITSKA V.
I
Effect df.cc 58 recoil after (y,'n)-reaction In complex compounds
of cobalt'. Co(Ill) triglycinatefand vitamin B~2. RadiokhJmJia
5 no.4016-519 163. (MIRA 16:10)
(Cobalt compounds) (Nuclear reactions) (Cyanocobalamin)

AVDONINA., Ye.N.; KJDRA, K.; NESWYAMOV, An.N.
Behavior of recoil atom of carbon~14 in mixtures of pyr4dine with
benzene and cyclohexane. Radio4dmlia 5 no.5-.633-635 163.
(MIRA 170)

VAN LTM-SHENI (Wang Liang-sh4a]; HMM, I.; YM CHZHI-CHZHE:Nt [Yang Chil&-clAit];
AnA.-
Separation of terpones by gas-liquid chromatography. IZv.vys.ttL*Iieb.
zav.;khim.i khim.tekh. 6 no.4:597-600 163. (MIRA 17:2)
1. Moskovskly gowidarstvennyy univeraitat im. M.V.Lomonosova. Kafedra
radiokhimii.

HMMEYANOV9 Av.N.
f, ~r "
- " - - 1 -V!~ - - - S 1L, I.. NIRA 17.1)
If .13 -
.k n, . - w"'01. 18 no~:~ ,
-~ - A.

NESMEYANOV, An.N.; POZDEM, V.V.
Hot synthesis of compounds labeled with tritium. Usp. khim.
32 no.7-.773-779 J1 163. (MIRA 16:8)
1. Khimiahookiy fakul'tet Moskovskogo gosudarstvennogo
universiteta.

BERDOLOSOV, Se,~rgey Serafirov--ch;
KLYMENIKOV) N.G.:
I
,,TTELI,SIUJA, G.S.,,
VLAXV, Lev Grigc~rlyevich-,
doktor khlr;. na-iik, pro-f., retEenzeent;
kar-,J. kLin. nauk-, dr-ts., rs-t~enzi;rit;
red.
[Appl.i~~ation of radioisotopes; a textbook for teachers]
PrImene-nie radicaktivnykh izotop,,~~; posobi-e- d1la uchite-
lei. Mcskva, Prosveshchenie, 1964. 117 p.
(111E-tA 18.9)

NESWYANOV An U.- VAN LYAN-SHEN' [WLng Llang-sfi~-nj; UNKER, A.
I I
Interaction of tritium recoil ~tcms with terpene5.
6 164. (MIRA 18;3)

AVT)ONINA , Ye ~ N, ; NFZWEYANOV, An.N. -, "IN Klikl ,'.TN
Uphavior of tritt.jjr. rc-coul atoir,5 ir. ss-ne lmir:-sr-i syvler!q.
Fadfokhimi'~n () ro.3,323-329 '64 ~ (14Ifq, 18, 3)

FILATOV, E.S.; NESMETANOV, An.N.; CHSPYZHEVO Yu.B.
Reactions of hot bromine atoms In liquid binary systems. Radickhlmlia
6 no.5:595-604 164. (W RA !13 --.1)

BARAKAT, M.F,9*, FIRSOVA, L.P.; NESMEYANOV, An.N.
Reaction of carbon-24 recoil atoms with pyridine and its hCM01cge.
Radiokhiniia 6 no.5*.605-610 064. (HIPA 1811)
Reaction of carbon-l,/ recoil atoms with pyrrole, 2-methylpyrrole, and
piperidine. Ibid.:626-630

Efle. I-T
J'arifez. cr, tl:~:. at
CM
:!oo4t13-19,
Ag
ZEE (MIRA -,q: 8
edra

LUPYANOV, V.H.; NE4kq~:fANQV, An.N.; YEREMI-*,YEV, A.P.
Products oil reaction of labeled carbon oxi,~,~s -dft.-. ~
of acetylene and hydrogen Jn an e1ectr.cal discharge'. Vest.
Monk. un. Ser. 2t Khim. 19 no.6ill-13 N-T) 164. (t1jRA 1913)
1. Kafedra radlakhImil Moskovskogo universiteta.

NFSMLYANOV~ An.N.; TSZYAN TAY-YAN tChlang Tlai-wang]; MATO, E.S.
."Ir~actions of trltlum hot atoms and the process of exclitation
c-nergy transfer. Vest. Posk. un. Ser. 2x Khim. 19 no.6;
-,7-28 N-D 164. (MlW 18:3)
1. Karedra radiokhimil Moskovakogo universiteta.

LUKIYANOVt V.B.1 NESMAKOV, An.N.1 YEREMFYEV, A.P.
Selecting optimum conditions for the syntbasis
pounds In an elactric discharge. Zav. lab. 30
1. Moskovskiy gosudarstvann)ry universitat imeni Lamonosova,
of carboiql cm.-
no.10.-1248-1251 164.
(MIRA 1824)

AVDOHINA, Ye.N.j.fflWPqVO kn.N.
laflusam of the phase on the character of the reactions
of tritiew recoil atcm in mixtures of cyclohexane vith
benzene. Dokl. AN SSSR 154 no.4:851-853 F 164.
(MIM 170)
l..Moskovskiy gosudarstvannyy universitet im. M.V* Lemonoaova.
Predstavleno akademikom V.I. Spitsynym,

All t" , ~
ZjP*ZflLlK0W,-., S.T.; REUT01", O.A.
NJk,A.
Interaction of phosphoryl.-Ides with diphenyl iodoniiim, salts.
Izv. AN SSIM Ser. khim. no.1:194-196 1650
18:2)
1. Moskovskiy gouudarstvennpj

,., I, . ~ T " . . , 1 i . f . , !.',, .,; :.
t1 '. Dt, . , 1 . ; iAl; ~J, 1. 'if I 1 7 , : ~ i ) ~- i, N ;,~;.
- IL :~ 1 ~,, , N, ., 6 1 , . .!" , " ! 1. * , :.. I , ~... . - " ~ t , 1'. " I
ReaCtiOfIS Of 1%~ CO ILI 11 C-f tri t i w, ar,.,-! C-14 i-t-, . ~ -
amines. Radiokiardia '! no.2:~:20-o--'27 165.
( "F ! ~ - , ~

BARAKATV M.F.; FIRSOVA, L.P.; -MgWyAln
!". in.H.
Reaction of C14 recoil atoms in-mixtures containing 0,1-picolire. Radio-
khimila 7 no.3061-363 165. (MIRA 19:7)

*'S~EYANOV, An.N.; TRAPP, G.
C,
.tudy of the thermodynamic properties of sorme J-ron alloys in
the closed r-region. Zhur. fiz. khim. 39 no.2:-356-359 F 165.
(MIRA 1824)
1. Moskovskly gosudarstvennyy universitat imeni. Lamonosova.

Sly,011CV, re.F.t.~~rjv ~An. &
RadimMon cowermtIon of mino acids in the course of their
interaction with tritlun recoil atomsq, Test* Kosk. Un. Sere
2:Milzei 20 no, 5:28-30 S-0 165e (MIRA 18:12)
1. Kafedra radiokbimii Moskovskago gosudarst4ermcgo universitata-
SuWdt+4ed July 21, 1965.

I.Y.; MSM&YANCV. An. ff.
Vacum vapwization of tungsten, molytden- and tantalum- Test.
&Bk. un. Sor. 2tKbdx. 20 no, 501-33 S-0 c65w OM 28t22)
I..Kafedra radiokbim i Moskovskago gasudarstwennogo universitata.
Submitted April 23v 1965o

IES~MNGV, An.N.
Reactions of hot atom in condensed systems. Vest. Mosk. un.
Ser. 2: Khim. 20 no.6:3-16 M-D 165. (mm 19: 1 1
1. Kafedra radiokhimii Foskovskogo universiteta. Submitted
June 24, 1965.

2&5-�6-
WT(M) D14~
SOUR
51'00010051=9100
9/6
..'AuTHM e S
im MiA 11,
ORG., Department of Radiochemistry~ Mosco
W
Mo.sk0v3r0g0 goeuTararvennogo uni"reit6t-aT State Unk Vs-it-k- (Kaf edra radioj
TITLE: Radiation preservatioAf aminoacids during the interaction with tritium-
recoil AE-Oms
SOURCE: KOscow. Universitet. Vestnik. Seriya II* Khimiyas no- 5, 1965, 28-30
TOPIC TAGS.-
amino acid, neutron irradiation, radioactive decay, lithium compound,
tritium, alpha Particle
ABSTRACT: The.offect, of the relativ Ie content of lithium salt in irradiated
specimens on the radiation survival of a mother compound and on the yield
of the basic decomposition products and their specific activities at.low
irradiation times was studied. Specimens.of 1-glutamic acid, dl-methionine
and 1-cysteine with the relative contents of lithium carbonate of.91, 80,
67, A 33,20 and 9% were irradiated. The total weight of the irradiated
specimens was 20-22 mg. Since the radiation compooltion during neutron
irradiation of mixtures of organic substances with lithium salts is somewhat
~higher than in the absence of the latter, the lithium salt of glutamic acid
was also irradiated for comparison. Quartz ampules containing the specimens.
were evacuated to a pressure of 10-2 mm Hg, sealed,, placed in aluminum casest!
and ixTadiated for 15 minutes, by a stream of slow neutrons of 0.87-1013 czzr2-.-
Card 1/2
UDC. 541.15+539.163

L ?-3225-66
ACC NR: AP6013601
see-1. It was shownthat the activity of HT for all aminoacids studied reaches
..a maximam at the relative contents of 50% lithium salt and that the share of
.
-activity attributable to CHJT of the total activity-of the gaseous phase for
glutamic acid is linearly varied from 10% for a specimen with WA1" lithium '
salt to 63% for a specimen with 9% lithium salt. Thus, the significant con..'
tribution of alpha-particles to the radiation decomposition of the mother
..compound becomes apparent at low relative contents of the lithium salt even
C_ small irradiation times. Tabulated~data. indicates that the- maximum
radiation preservation of the morther Ompound for the acids studied is ob-
servable at 33% relative contents of lithium salt in the irradiated speci-
:mena vhich corresponde.~o the equimolar ratio of the irradiated components.,
Origeart, has: 2 tables. [JPRS]
~SUB CODP._107 SUHK DAM. 21JuJ65 ORIG REF: 003 OTH REF:, 001

4

SOMRODE: 'UR/0189/65/0001005/0031/0033
AUTHOR: Golubtsov, 1. V. 'Neswmayt- An. N.
ORG, Vartment of ra(uo IMoskovskogo
.ffapecrir dej___ I-- __ I t
universiteta, karedra raxn0jux
uni,
TITLE. Investigation of evaporation of tungsten molybdenum. and tantalum in
vacuum.
SOURCEt- Moscbw-., Universitet. Vestnik. Seriya It. Khimiya, no. 5, 1965, 31-33
TOPICTAGS: tungsten, molybdenum, tantalum, metal evaporation, tungsten evaporation,
molybdenum evaporation, tantalum evaporation, vacuum evaporation
ABSTRACT: -The evaporation rate of W,.Mo, and Ta in a vacuum of 8-10-9 10-4 mm
Hg has been investigated. Stecimens of zone-melted, high-purity metalXa,ed
with radiactive isotopes M09 , W185, and Ta18Z were heated to 2063-3203K by
~passing an electric current or by electron bombardment. Ift was found that as
the pressure.dropped .to 10-4--lo-16 mm Hg, tIhe evaporation rate of all tested
metals increased.. A further pressure drop below 10-6_1.0-7 mm Hg brought about
'considerably weaker editional effect. The composition of residual gases also
-7
ffects-the evaporation rate. At a pressure of IG :,mm Hg and lower the evapora-
tion proceeds inthe form-of molecules,;,at higher pressures, such as 10-4 mm lfg,.
it proceeds in the form of.axides. Orig. art. has: 1 table.. [WW1
Mdal ev=oration
SUB CM-EF-11T rUBM DATE: 23Apr651 ORIG REF: 0061 ATD PRESS:
Cc UDC: 541 5+S19.163

L W(M)/EWP(J)/EWA(h)L~?JA(1_Y RM
ACC NR: -A 010715 SOURCE 11006070-0647-~,
CODE: UR/0189T6-6766-M-o
f
AUTHORt Kuklin. Yu. S. Firsova, L. P. N~~meanov ~~A" ~11_
ORG: Department-of Radjoche te Uniyersity (Kafedra radiokhimii
mistry, Moscov Sta
1toskovAogo,gosudarstvennogo universiteta)
TITLE: the-reaction of accelerated tritons with benzene in the solid phase
S'c
SOURCE, Ho ow. Universit t. Vestnik. eriya 11.. Khimiya, no..!, 1966, 60-64
TOPIC TAGS: radiolysis, iuantum yields, ion beam, radiochemica-I reaction
ABSTRACT: , This.pa'per deals with the action of ~2.5 kv tritons on frIozen benzenel The
nature.of chemical and radiological effects.produced by accelerated ions.is similar to
that of "hot" atoms from nuclear reactions, e. g., Li(n,a)T. The advantage of using
accelerated ions, aside from.simpler experimental conditions, itr that the need to
Icompensate for radiolysis by ga-ma rays' neutrons and alpha particles is obviated.
The 2,5 kv tritons e4loyed in this study have much lower energies than the recoil
tritium atom's from nuclear reactions. ~'The following equipment wag used:
Card .1/3 UDC: 541.15+539.163
IL

2060"66
ACC _kk:
6010715
j The target, covered with gubUmed.benzene from trap 4, was irradiated for 30 minutes;
the irradiated,sample, after transfer to the cold trap, was subiIected to vapor-phase
chromatography. 'The progress of elution was registered with a -gcintillatioa counter.
i The results showed that 2.5.kV tritons producS considerable es Uctio of the benzene':,
Molecule, forming in the process cXRj2hex6e'!l,3-q clohexad en 1,4-cyclohexadiene,
and a number of unidentified rraducts., The unidentified fra ti is, with one exceptior~
had longer retention times than the cyclohexenes or benzene(the stationary phase was,.
di(2-cyanoethyl) ether/fLre brick).. Aconsiderably larger amount of label is incor-
porated than in experiments with recoil atoms from U(n,a)T. Similarly the radiolytic.
Yields are larger than those obtained with recoil atoms. Orig. art. has: 2 figures
and 2 tables. [VS]
SUB CODE: 07/ SUB:M PAT E 06Jan65/, ORIG-REF. 0031 OTH REF: 008/ XTD PREP3.
Card..
Ord
L

(3, , Yi~.fl.; DIFF-3MEYANCV, D.D.
.; j
B
Mothods and primary re~ultt, of' the -,cmplex regional fleO:~LyPi~7al
st,idtes ir. en.:3tern 'TrL:riy NlLneftc~gazs
14.5, ls-~)

NESMEYANOV, D. V., Cand Geol-Min Sci -- (diss) "Structural
peculiarities of the anterior antialinal zA, !.Jes of Dagestan
kk oi u5i
in connection with petroleum-gas k of Mesozoic
deposits." Mos, 1957. 16 pp (Mos order of Lenin and Order
of Labor Red Banner State Univ im. M. V. Lom nosoy, Geol Faculty,
Chair of Geology and Geochemistry of PWWW), 100 copies.
Bibliography: P 16 (KL, 2-58, 112)

Z' "T
BROD. 1.0.; TUTMT. A.1.; RISKSMOT RsT.
Pmqmto for oil aM gas bearIM of Mesozoic carbonate deposits
In western ClocavAsta. aeol. neftl I no.3:1-11 W 157.
(Caucasus, I.Fortherm-FIstroleum geology) (HLRA lots)
(Camseus, Mortherm-Gas, Utural-Geology)

MUMMY
Structural characteristics azd oil- and gas-bearing potentials of
the western anticlinal zone In Daghestan. Creol. neftl I no.22:
16-24 D 157. (KIRA 11:1)
1. Kookovskly goeudarstvannyy universitst.
(Daghestan-64ology, petroleum)
(Daghestan-A", uatuml-Geology)

TMESIZIANW, D.V.; KOCHAWYA11TS, S.B.; L.A*
Reflection of the structure of the Meso:oic aediments in the
noithwestern Caspian Sea .region on the paleogeologic map of a
Pre-Pliocene surface. Neftegaz. geol. i geofiz. no.6:30-35 163.
(IMA 17: 10)
1. Nauchno-isaledovatellsle-aya laboratoriya geologic hesUkh kriteriy(--)v
otsenki perapektiv neftegazonoonosti,

SRDD, 1.0.; POL'STO, L.A.; NNSWANOV. D.V.
Genstructural division and oil and gas potgntlalg of CjscaUcagj&.
0601- neftl SUPPlement to no.8:11-63, 158. (MIRA 11:9)
1. Hoskovskly gosudaretvanny7 univarettat I Komplekmnaya yuzhuaya,
geologtchaskeya, ekspeditstya AN SSSR.
(Caucasus. Yortbern-Petroleum.geology)
(Caucasus, Morthern-fte. Fatural--Geolog7)

KU.PRIM. P.M.; Y3SHXMQV.~;Pj.; SMGIN. A.M.; BROD, 1.0., prof.. doictor
geologo-mineral.nauk. red.; KISMnU. Z.A., nauchnyy red.;
SIMM. Z.G., vedushchiy red.; GEBMIYZVA. I.N.. takhn.red.
[Transactions of the General Southern Geological lxpeditioul. Trudy
KompleYconoi lushnol geologichaskoi ekspeditsli. Pad red. I.O.Brods.
Leningrad, Gos.nsuchno-tekhnAzd-vo naft. i gorno-topllvnoi lit-ry.
Leningr.otd-nle, MoA [Geology and oil and gas potentials of the
southern U.S.S.R.; Daghastan] Geologlis I neftegazononnout' IVga
SM; Dacestan. 1959. 431 p. (KIRA 130)
1. Komplakenaya yushnaya geologIchaskaya ekspeditslya, 1956-.
2. Wookovskly gosudarstvannyy universitat imeni K.V.Lomonosova
(for Kuprin. Masmayanov. Seregin). 3. Komplakanaya yushnaya geo-
logichaskays akspeditsiya (LTM) AN SM (for Masmayanov).
(Daghestan-Petrolaum &eology)
(Daghestan-Gas. Katural-Geology)

BA OVSKAYA, K.S.; RZZBORODOT. R.S.; BROD. 1.0., prof.. doktor gool.-mineral.
nauk; BMIKOT, M.5,; (MIUMID. K.I.; ZHIUGO, M.P,; IBRAGIKOT# DA;
KMYAVTSST, M.P.; LXWOV. G.P.; KOSEMv M.M~; NAZAROT. R.I.;
,91 NIKOLUKO. V.A.; VYWZSKIY, I.T.. nauchnyy red.;
401
RUSMVA. L.7a.. veduahchly red.; TASHCHUMINSKAYA, A.B., takha.red.
[Geology of the eastern part of the northern slope of the Caucasus]
Geologiebaskee stroanie vostochnol chasti eevernogo sklona Kavkaza.
Pod red. I.O.Brods. Leningrad. Goo.nauchno-tekha.lad-vo neft. i gorno-
toplivnoi lit-ry, Zeningr.otd-nie 11 1960. 319 P. (Trudy Kompletanol
IUzhnoI Geologichaskol Ikspeditsil. no.2). (MIRA 13:11)
1. A SM. Komplakenaya Tushnaye Geologichaskays Skspeditslya 1956-.
2. Tsesoyusnyy nauchgo-issled.institut gazovoy promyshlamunsti Ifor
Zhivago. Kudryavtsevl. 3. Kafedra istorichaskoy i regional noy &Oologii
Uot Loonov, Moskvin). (Caucasus, Northarn--Geology)

BRODI, 1.0.; BELOV, K.A.; BURSHTAR.. H.S.; KOROTKOV, S.T.; NESMEMKOV,
D.V.pa TSATUROVp M. ------
Oil and gas potentials of Ciscaucasia in VieW of the distribution
characteristics of accumulations in the piedmont basins. Trudy
VNIGNI no.32:76-99 160. (MIRA .14:7)
,Caucasus,, Northern--Petroleum geology)
(Caucasus, Northern-Gao, Hatural--Goology)

BROD, 1.0.; ALEKSIN, A.G.;. BELOV., K.A.,- I~UPRINV P.N.-
FOLISTEHO L.A.; TSATUROV, A.I. . 'T.0MF.YAN.OVD..V.-
Middle Caspian oil- and ga&-bearing basin; appearance of regularities
in the spread of oil and gas accumulations in central and eastern
C.iscl(ucasia and In the Kara-Bog* region. Zakonom. rgt= polezn.
iskop, 5:483-535 162. 41 WRA 15:12)
1. Kompleksnaya neftegazovpya geol4gtcheskaya ekspeditsiya, AN MR..
HoAlwvakiy gosudarstvanW universitet, Komitet po koordinataii.nauchno-
issledovatel'skik-h rabot lbri Sovete 16mis+xov SSR I Stavropoltakiy I
Checheno-Ingushakiy sovety-nardonago khozyzystva.
(Caspian Sea.'region-Petroleum geology)
(Caspian Sea region-Gas.,-Natural--Geology)

We she Geoftseg Abe* NO
DarAmakayse, Too Not Broytisaft~ A* Rol
Present status of study of the Nastern Caucasus Irdreland by g1physical
Lou nothods In relationship to the direction of further geophysical work in
GITSD SOURCSt Sbe Goole I neftetaxonasnast' Tugs 89SRe KavUse Lop
1963, go-us
TAGGs geophysics# geophysical exploration. geology. geological struaturet
ted viaven method# reflected waves method, seLmology, electric exploration,
atria surveye magmfto survey
PANSUTTOIlt The status of geophysical study of the lastem Caucasus Foreland and
Ats geological structure are discuseado It is concluded that the possibilities of
11 geophysical methods of exploration are far from exhausted with respect to the
Astern Caucasus Foreloide It Is proposed that such work be continued In aaaordaaoe---
F
th a uniform plan -but a considerably bro4der scale* In this wwk primary

I-

NES11EYANOVS, D.V,; BAGIN.13KAYA, Ye.N.; Kf-llAKIi,iCN, M.Yu.
flew data on the subaurface structure of the area adjacent to
lUzlyar Bay. Neftegaz. teol. i geofiz. no.3:3-6 165. 19:?)
1. Nauchno--issledovatellskaya- laboratoripa geologiclieskikh
kriteriyev otsenki perspekti-i neftegazonosnosti, Moskva.

lls-~F,Yialov, D.V.
Tectonic anu :3 tm,, -.!~-ra i --' -.- Ic -- i . I ~ . , ~ I ~ - ~! ., - _: , :- ~.~ - " -,
arul ab~acelll- soklLhern fJ : ~; :~-- 11 . 4, 1
j
(11-1:1 , 0- 1

ACC NRiAP7004548
M_qfff -d-obt5i
AUTHOR: &-i&ipsKaZ!! .-Ye. -~N.; Nesmeyanoy,_P. V. ulgak(?Y~a --A.;
Khakimov. M.-Yu. MON. .,*W.
OIRG: WILNEFTEGAZO Moscow
.TITLE: New data an the structure of the eastern part of Cis-Caucasia on the basis
of regional geophysical work
SOURCE: AN SSSR. Izvestiya. Seriya geologichoskaya, no. 6, 1966, 63-71
TOPIC TAGS: telluric current, geophysics
.ABSTMCT:. The deev 8tructurel'bif Cis-Caucasia was studied in 1962-1964 by
igeophysical invostigiti6nis Aong three regional profiles which cut'
across the principal structural clemento of that region. The groatori
I
,part of the article is a detailed description of work-along each of
:these profiles. The objectives were tracing the surface of the base-
!ment and the underlying sedimentary deposits of the Mesozoic; wherover
1possible discontinuities in the sedimentar-y strata also were traced.
1A wide variety of methods were combinod: the refracted waves method,
!electrical exploration methods (magnetotelluric profiling and sounding
and telluric currents m6thods), as wall as gravimatric and magnetomater
work. The results are incorporated in FiGe 1, a~map of relief of the
,basement and distribution of local uplifts in the sedimentary strata#
iand in Figures 2 and 3* which are detailed geophysical cross sections
Ialong different profiles. The work was effectivq.,in detecting areas
,most prcmising for furt prosp2atind,
ihor geological 'work,, especially
for'-patideltiii a.nd-gas.-_ -Orig._-a'r't. has: 38,4603
SUJ CODE t 08 SUBM DATE: 13Apr65 3 figures,. LJFRS.-
rd -1/1 UDC: 550-81+530-3(471.6)

HISRUAROV, G.S., lnzh.; rl=aTAM, 14-ra.
Transportation of resin to tank trucks. Visal,-zhir. pros. 25 no.7:
46 59. (MIRA 12:12)
I.Gosellskiy shirovoy kombinat.
(Gums and resins-4ransportation)

MRSHWANOT, G. S.
U%Ivg pnemptic-tube transportation. Kael.-zhir.prom. 26
no.4:45 Ap 160. (IUU 13:6)
I* Gomellskly zhirovoy kombinat.
(Gomel'-Soap industry-Squipment and supplies)
(Pneumatic-tube transportation)

- NESMTANOV, N.V. " Inxh.
:7-,
Automatic unit for bright nickel plating of parts. Vest.xashinostr.
42 no.9:52-53 -9 162. - (KRA 15:9)
(Nickel plating-Equipment and supplies)

20-3-27/59
AUTHORS Neameyanoy,Nik.A., ReutovO.A.
TITLE ' -5-eInfluehce of Substituents on the Strength of Ferrocene-Carbo-
xylic Acids.
(Vliyaniye zamestiteley na silu ferrotsenkarbonovykh kielot -R..-
PERIODICAL Doklady AkadeLaii Nauk SSSR,1957,Vol 115,fir 3,PP 518-521 (U.S.5, :!
ABSTRACT It is known that ferrocene whos the properties of an aromatic c..,
pound in the substituent reactions.In the present paper the aut,
throw a light upon the similar queption of the mutual exchange
the influence of the substituents through the ferrocene core.Ti.,,-
produced the ferrocenecarboxylic acids with a common formula T',

-C2H5 -C4H -H,COOCH 31-CO387,-COCK ) and measured their dissoci&-
'
;
?
l
ether of the ferrocenedicarbo-
stan
s.furthermore monmethy
ion con
xylic acid was produced by an uncompleted hydrolysis of the dime-
thyl-ether of this acid.Furthermore,in addition to the aforemen-
tioned,the constants of ferrocenecarboxylic-,butyric-,and benzoic
acid are given in table I.The comparison between the dissociati-
constants shows that the introduction of alkyl into the unsubst4i,,-
ted cycle of the ferrocenecarboxylic acid reduces this constant -,4i1,
reas the introduction of a negative substituent, increases it.Th,,~F
the acetyl-is 2,4 timesstronger than the ferroceneaarboxylic acid.
In the benzol series the p-acetyl benzoic acid is 4,2 times sti-lri-
ger than the benzoic acid an the p-carbomethgxylic benzoic acid
3.6 times stronger than the benzoic acid.Thus the influence of
Card 1/2 substituenta on the dissociation constant of the ferrocenecarbo-

The Influence of Substituents on the Strength of 20-3-27/1:'g
Ferrocene-Carboxylic Acids.
xylic acid is well comparable to the influence of the same substi-
tuents on this constant of the benzoic acid in the p-position.The
influence of the substituents is transmitted from one ferrocene cy-
cle to the other.This is confirmed by the ferroome salphidation
carried out by the authors in the presence of an equimolar quanti-
ty of ferrocenecarboxylic acid(competing sulphidation).On this oc-
casion the acid remains unchanged whereas ferrocene is sulphuriza-
tion almost entirely.Under harder conditions also the acid was sul-
phurization by the authors.Thus the carboxyl group exercises a pas-
sive influence on the unsubstituted cycle of the molecale.It must
be emphasized that all up to now well studied systems which effecti-
vely transmit the mutual influence have an uninterrupted carbon
chain-In principle the ferrocenemolecule differs from the latter in
that here a member of the conductive system is produced by an iron
atom.The usual data on the individual above mentioned substances
and reactions are given in the experimental part. There is 1 table
and 5 Slavic references.
PRESENTED By Nesmeyanov,A. 11. -Anad ml claap bUrch 1, X957
SUBMITTED February 26,1957
AVAILABLE Library of Congress.
Card 2/2

NIF-MMAKOV, N.A.: Master Chem Sci (dies) -- "A study of the interaction of
-
substituents In the ferrocene nucleus". Moscow, 1958. 11 p-p (Moscov State
order of Lenin and order of Labor Red Banner State U im Lomonosov), 110 coDies
(KL, No 1, 1959, 114)

'AUTHORS: Ifesmeyanov, Nik. A., Reutov, 0. A. 2o-12o-6-28/59
TITLE: Functional Derivatives of Ferrocene-1,1LDicarboxylic Acid
(Funkto:bnallnyye proizvodnyye ferrotsen-1,11-dikarbonovoy kisloty
PERIODICAL: Doklady 1kademii nauk SSSR, 1958, Vol 12o, Nr 6,
pp. 1267 - 1270 (USSR)
ABSTRACT: Although the acid mentioned in the title was produced already in
1952 (Ref 1) its derivat~ives remained unknown with two exceptions
(Refs 1,2). In the present paper the authors obtained a number
of these derivatives. Thjy are: a) the chlorine anhydride b)
from the latter an amidel(V) was produced ':a) methyl ether of
the carbamido-ferrocene-1 t-carboxylic acid (VII); d) the above
amides (V), and (ni) as well as the amide of ferrocene carboxy.-
lie acid can be converted'into the corresponding nitriles by 0
heating in acetic anhydride. By heating the acid (VII) at,140
for 2o minutes e) I-cyano ferrocene-11-carboxylic acid (VIII)
formed in a yield of 55106; f) the nitrile of ferrocene-1,10-di-
carboxylic acid (IX) was obtained in a yield of 3o% by heating
the amide of this acid in acetic anhydride at 1000 during 6
hours; g) by heating the amide of ferrocene carboxylic acid in
Card 1/3 acetic anhydride at 1400 durinc 40 minutes the nitrile of this

Functional Derivatives of Ferrocene-1,10-Dicarboxylic ~' 2o-12o-6-28/59
Acid
acid formed (X); h) a cleavage of the HC1 elements from the 2
chlorine dnhydride molecules as well as from 2 water molecules
takes place under the formation of the anhydride of the ferro-
oene-1,1Ldicarboxylic acid (XI) due to the action of pyridine
on chlorine anhydride (IV) in the presence of water. ConstEaits
are given of all substances mentioned and their structure is
discussed. According to the aromatic character of ferrocene it
was found that the radical --CCl 3 may replace one of the ferro-
cene hydrogens. In spite of the variation of the decomposition
conditions of trichloroncetic acid in the mixture with ferroce.ne
no products of a double trichloromethylation of ferrocene could
be observed. There are I table and 7 references, 3 of which
are Soviet.
ASSOCIATION; gookovokiy goeudaretvennyy universitet im. M,,V.Lomonosova
(Moscow State University irieni Id.V.Lomonosov)
PRESENTED: February 11, 1958, by A.N.Neameyanov, Member, Academy of
Sciences, USSR
Card 2/3

Functional Derivatives of Perrocene-1,10-Dicarboxylic
Acid
SUBUITTED: February 11, 1958
"2o-12o-6-28/59
1. CarboVIle acids-Chemical reactions 2. Ferrocenes-ChemicP-1,
reactions
Card 3/3

5(3) SOY,/62-59-5-27/40
AUTHORS: Nesmeyanov, Nik. A., Reutov, 0, A.
- ----------------------------
TITLE: The Derivatives of 1-Carboxyferrocene-11-Sulfonic Acid
(Proizvodnyye 1-karboksiferrotsen-ii-sulifonovoy kisloty)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 5, pp 926-929 (USSR)
ABSTRACT- In an earlier paper (Refs 1,2) the authors synthetized a number
of ferrocene carboxylic acids of the general formula
Y-A H Fe-C A COOH, and an this basis they investigated the
%, 5 4- 5 4-
influence exercised by the substituent Y upon the acetic
character of ferrocene carboxylic acid. The same influence was
investigated also in the present paperp but stronger electro-
negative substituents were used. For this purpose, the ferro-
cene carboxylic acid and its methyl ester were sulfonated and
the derivatives of the acid already mentioned in the title
were investigated. The following 10 derivatives were obtained:
F'-CCOH M; F'--COC' (II)i F-"CONH2 F zC00H
(IV);
\SO 3 so C12 NSO 201 "so2F
Card 1/2

I SOV/62-59-5-27/40
-The Derivatives of I-Carboxyferrocene-11-Sulfonic Acid
ASSOCIATION:
SUBMITTED:
Card 2/2
F ~SO3H (V)1 F " COOCH 3 (VI)i F"OCOOCH3 (VII), F,,eCOOCH 3 (VIII);
\ICOOCH3 '-soci2 \302F -302 NH2
F.-ICOOR (IX); F"S02CH3 W F = -C H Fe-C H
\SO2NH 2 1111C00CH3 5 4- 5 4-*
The disso6iation constants of several acids (IV, IX) were
determined and compared with those of reference 2. This showed
that by the presence of a sulfamide substituent the acidity
of ferrocene carboxylic acid is increased 5-5-fold and by that
of a sulfofluoride substituent even 9-fold (Table 2). This is
indicative of the considerable influence exercised by the
substituent upon the carboxyl group, which is on the other ring
of the ferrocene molecule. There are 1 table and 2 Soviet
references.
Moskovskiy gosudarstvennyy universitet im. X. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
September 10, 1958

5 (3)
AUTHORS: Kazitsyna, L. A., Lokshin, B. V., 30V/20-127-2-27ti-O
Nesmeyanov, Rik. A.
TIME: The Infrared Spectra of Ferrocenes. On the Reciprocal Influence
of Substit-aents in the Ferracene Molecule
PERIODICAL: Doklady Akademii nauk SSSRO 1959P V01 127P Hr 2P PP 333-336 (USSR)
ABSTRACT: Recently it was proved that the reciprocal influence of the
substituents is passed on through the entire ferroceas system
from ring to ring (Refs 1-3)- The authors drew this conclusion
on the strength of the comparison of the dissaoiatiam constants
of the forrocone-oarboxylio acids of the Vpa Y-C 5H4-Fe-C53 4-CCOH.
The substituents form with respect to their effect the following
series$ a4H 94 02Y H< C00C:H3e* COOH3< 0