SCIENTIFIC ABSTRACT YUNUSOV, S.YU. - YURCHENKO, O.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002203710018-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

USSR UDC 547.944/945
MIRZOYEV, Kh. M., ABDUS&MATOV, A.) Yu., Azerbaydzhan Medical
Institute imeni N. Narimanov; "Order of the Red Eanne'r of Labor".Institute of
the.Ghemistry of Plant Materialsi Academy of:'Scieaces,of the. Uzbek SSR
"Alkaloids of Taxus Baccata",
Tashkent, Khimiya Priroduylth Soyedineniy, No 6, 1970, pp. 777-778
Abstract: The authors investigate the alkaloid make-up of the leaves of Taxus
baccata (the English yew). An etber extract~of the plan.t material yielded an
alkaloid sum which was chromatographically separated into two bases -- A and B.
Base B is identified as taxine. IR-spectroscopic data are given for base A.

USSR UDC 547.944:945
UMAROV, Kh. S., ISMAILOV, Z. F., and S Institute of Plant
YUM.S.0
Chemistry, UzbekSSR Academy of Sciences.-
"Thalictrum Flavum Alkaloids. The Structure of-Thalfl.avin"
Tashkent, Khimiya Prirodnykh Soyedineniy No 4, 1970, pp 444-446
Abstractz Two alkaloids were isolated from Th. flavum L. roots. The new
alkaloid thalflavin was obtained in the form of prismatic crystals melting
at 132-1330. Its structure, as derived from spectral analysis is most prob-
ably 1-oxy-N-mathyl-5-methoxy-6,7-methylenedioxy-tetrahydroisoquinoline.
The other alkaloid was obtained in the form.of a yell6w, amorphous powder,
melting at 105-106*C. It was found to be thalicarpihil.

".112 '020 UNCLAS'stfitD WCES;SING DATE--04DEC70
J'ITLE--STRUCTURE OF ERVINCEINEP.CPVAMYCINE'l~~ANi), ERVINCINE -U-
AUTHOR-(04)-RAKHlMOVr D.A., MALIKOVr~~V.Mov YAGUDAYEV, MvR., YUNUSOVj S.YU*
.'.C,OUNTRY 0 INFO--USSR
--SOURCE--KHIM. PRER. SOEDIN..1970w. 4-A 21 226 31
J
:Q.ATE.PUBLISHED ------- 70
s UJU E C TAREAS--BIOLOGICAL AND MEDic.AL sc 11ENCIE S
-TOPIC TAGS_-PROCESSED PLANT PRODUCT`f~ I.R SPECTRUM, MAtS SPECTRUM, NUCLEAR
~`,,',_AAGNETJC RESONANCE, MOLECULAR STRUCTUREi
J~COUTROL MARKING--NO RESTRICTIONS
!-,!DOCUMENT CLASS--UNCLASSIFIEO
P R., OXY REELIFRAME--3005/0466 STEP NO--UR/039-3/70 1006/1)02/0226/0231
1,CIRC- ACCESSION NG--AP0132681
UNC LA SS~ I F, It 0~
.411"m
~m ~_Tlls ol i'l) mll,

0 12 -AS VROCESSING DAT&-~-1-3NOV70
UNCL SIFIEU~
-.iTLE--STkUCTURE OF TALATISAMINE :-U-
T
'AUTHOP-( -2)-YJNUS OV, M.S.,, YUNUSOV, S.yu
:c
TRY ~OF FO--USSR
SOURCE-.WIM. PRIQ- 19701 6(l), 110-4: f
i)ATE,PUBLISHED ------- 70
SUBJECT AREAS-CHEMISTRY
TGPIC~ TA GS--;-tqC LFC ULAiw-- S Tk UC T Uk ENUCL EAR MAGtj L-T I CRESONAN~E, AMINE
~'--()EitIVATIVE? 3FjllZEi*ljE 0ERIVATIVE, HYDROXYL RADICAL
:CONTROL MARKING-NO RESTRICTIONS
D 0 C 1131 E;--.'T CLASS-UNCLASSIFIED
'PROXY REEL/f'RAME-3004/0173 STEP HO--tjR /0393/70 /Q0b)'lJQ1/0090/009(t
C[RC ACC~~SSInj%4, IN10-AP0130932
L ~SI
RUM,
fl, ~14 Rml

UNCLASSI Fl ED PRUtUSSlWG DArr=--300-CT70
E STEAEOCHEMISTRY. GALANTHAMINE TYPE
TUDY OF TH W
.-TITLE-NMR. SPECTROSCOPIC Sa
:ALKALOIDS. I -U-
A-UTHOR-103)-YAGUDAYEV, M.R.t ABDUSAMATOV,: A.v YUNUSOV4 S.VU,
COUNTRY OF INF0---USSR
2*SOURCE-KHIM. PRIR. 19701 6(2) 235-9
_~-DATE: PUBL ISHE C--7 0
UBJECr AREAS--BIOLOGICAL AND MEDICAL SCIENCES
-S.
.'"'TOPIC TAGS-NMK SPECTRUM, ALKALOID, STEREOCHEVIIISTRY it'. __j L G U L 14 R S T R U C, I UAI E
~4'_CGNTROL MARKING-NO RESTRICTIONS
.-1)OCUMENT CLASS-UNCLASSIFIEO
._,PRaXY~REELIFRAME--1999/1890 5 TE PNO-UR/ 03 9 370:1 WO& 0042 o 23 50,-! 3 1
ACCE5SICU NO-AP0123678
'I Asc IFIFID - -

UNCLASSIFIED' PROCESSING DATE DIT
2/Z 010
CIRC ACCESSION NO-AP0123678
ABSTRACT/EXTRACT-CU) GP-0-- ABSTRACT. PAR SPECTRA OF GA 1. A ~'i T11i A M I N,'l 11"'i
-ERIGALANTHAMINE AND ITS ACETYL DERIV. ~TED THE: OH 6,L.R ilki
.,.QUASIAXIAL i3UT IN EPIGALANTHAMINE: IS QUA51EQUAJORIIAL APT'll I E1 Z
.,,,,POSSESS:. HALF CHAIR CONFORMATION IN CIS LJNKAGEq WITH MING C.
-T
ME OH IN I IS INTERMOLo H BONDED. FAC -4 L I TYt. INST. R AS T~
--..VESH
CHESTV,.TASHKENT, USSR.
il~arl 'Act 1"Gli:

-112 020 UNICLASSI FIEG: PROCESSVIG UATE--04DEC70
-lTJTt&--_ALTEA AMINEANEW ALKALOID FROM THER14OPSIS ALTERNIFLORA -U-
R.A.r.1SKANDAROVs sot YuNusov, S.yu.
~_CQU,ITRY OF INFO--USSR
~'SOURGE-KHIM4 MR, 5 Of: 0 1 N. 19701 6(?,11 276-T
a-A PUBL.ISHED ------- 70
SUBJECTAREAS--SIOLOGICAL AND MEDICAL SCIENCES
-tCPf" TAlGS--PRGCES5E::D PLAINT PR('-tGU(;Tt 'ALKALOID, S 0 L VNT EV..'RACTEONt
'04LOROFORMo VV SPECTRWtt IR SPECTRUM
tONTROL MARKING--NO RESTRICTIONS
~.DOCUMENT CLASS--UNCLASSIFIED
!'PROXY REEL/FRAME--3005/0454 STEP. NO--UR/03q3/70~t0i)6/03."/0276/0:-?7T
_C_r Rr kf~r E~ ,),kl N10-AP0111-52-669
SS

UNCL ASS I FIED JATE::--Olt~ EC70
020
-:C-jRC ACCESSMU %-0- -.A Pul -132 669
'ABSTRACT/ lcX TR AC T-- W ) GP- 0- A5STRACT, EXTN. OF THF OVER EARTH PARI'S OF
5 'T
T aALTERNIFLORA WITH CHCL SU53 GAVE 3.35PERCEN OF Al-'Xlil 01-05; ET SU-
-HYCARPINE, ISOLATED AS T ME . H C L PSU84 S.ALr, M,. 17LIDE'o"REES"
0% IS SOL VED RA L
' r I 5HE 'ILN. GWE N-ACETYLCTTlS!f.',l'E AND CYTISINE;
C~ii?,QiHATj Y. OF - CHU SU3-3
L T ER AM I lk4Ef C S U 3 15 i i S U-20
-:FROM THE JM 0 T HER L 1 Q U U R% S f A N E wALKALOI D: A
-G;~ES, (ALPHAS 1UNUS 43191::GREES flict(l Su--,)~ SALT A.
ON S U- -3 2 D
234-50EGREES; HI SALT A. 212-13DEGREESp , PICRATE M.: .1 :5 - L 6 --~ E GIR E E S , -4 i: L
SALT M. 185-60EGREESr MEI SALT M. 225-6DEG-.REES% WAS', OBTAINE~0.
NYIDROGEMATIT! 141TH RA~4EY IN11 GAVE A DIHYORG IDERIV. ;41.TH iALPHA) SU30
14INUS 100DEGREES; HCLO SUB4 SALT M. 21J17-DEGREES. UV AND IR SPECTRA, AS
AELL AS CRO SUB3 OXILDN. SUPPORT A TRrCYCLIC ALKALOIJ) OF THE CYTISINE
-STRUCTURE WITH A PROPYL SIDE CHAIN FOR It FAC I L IT Y: INST. KHIM.
VESHCHE-STVs TASHKENTt USSR.-.

T N 0 V -10
-,-T I T L E --M.A S SSPECTROMETRIC STUDY OF TiiE STRUCTME or-.!,FETIj)1NE -U-
~-.AUTHOq-102)-ISMAILOV, Z.F.s YUNUSOVIts Yu .
COUNTRY OF INFO--USSR
'~-_~',SCURCE-011?4. PRIq. SO E D IN. 1970t 6(l), 1142,r
_:_,D AT EPdBL I SHED ------- 70
SU3Jz,CT AR FAS--CHEM IST RY
TAGS--~,IASS SPECTMUI-Mt MOLECULAR STRUCTURE, 4ETEMICYCLIC NITROGEN
C0,14POUNI)v TERTIARY AMINE
IG
CONTROL MAPAIN --W) RESTRICTIONS
WCUIMENT CLASS--UNI'LASSIF IED
.~PROXY, REELIFRAME-3004/0187 STEP i'-110--UR/039347of 006/00 1/0142/0142
C-1 R CA CC E 5 1D NMfj--AP0 1. 30946
TL
FIREA,

012 UNCLASSIFIED, P.R11CMING DATE-271NOV70
T,I.TLE__DIFFEPE.'JCE IN IN-H PROTON 511,GNALS: IN NMR SPECTRA Of'- INDOLE,
u~
INDOLINEY -ANID HYDROXYINDOLE ALKALOIDS
.,AbTfi0R,-(03)-YAGU0AYEV, M.R., MALIKOV, V.Woe ~YUNUSOV,I:i S.YL).
.COUNTRY OF INFO--USSR
,.S43ljRCE--KHVkl- PRIR. SC)'
!~:D I N1 1970, 6tl)l 89-90
PU3L ISHED ------- 70
SUBJECT AREAS--- [CAL A,"10 MEDICAL SCLENCES
r- P I C TA',S--PP'.j!_.E5:;UD PLANT PRODUCT, ALKAL010i I N f 0 L r, U100LE DERIVATIVE?
-:4UCL EAR MA G~ I C 9 S C'N A N C U
:'~:C'GNTROL MARKING--NO RESTRICTIONS
CLASS--UNCLASSIFIED
PROXY REEL/FRAIME--3004/0174 STEP 110--Ur.103C)3/7OtfOO6YO01/00~l)/,)090
ACCESSInN Nn- 0 110 9 33
UNCLASSIFIF,

U',It'C'%_.A 5 S I F I ED P RM C E S SING WJE-2VIDV70
CTRC ACC ESS101k.' N0--AP0 30933
_TR'CT/EXTRj%C'~*--(U) GP-0- ABSTRACT. .1 E
ABS A CONS IDSME-ILE D' PFERCNCE AS
FOUNU IN THE 1-i-H PR9'1;3fl SIGNALS, IN THE NjMRI SPFCITRA OF VINCANINE7 2t
HYDROVINCANINEt VINERVININEy AKU011"11GINFp
16il9#20,TETRAl
-Z?16,,QIHY0R0AKUAMMICINE , ERVAMINEi ERV,MIDININIE, Otl H Y 0,4', 0 F A V liN f D I i'kl G
COPS Ir. INE , PSEUDOCCOPS IM IIINE , P I CR t iNt NE VNICAMGINEi RESERP(bi(Ncl, ERVINE.
'TYLTCiiA0SlNEt O?ACETYLI-~ili"~'(~~Uti'-1131iiEt lylINLAWIME.* MMOINEP
OtACE
0SITION OF 'THE: N-H PRDTO-,,4~ G AL VAluEs FRO-M
AIND CARAPA~'iAIJIBIINE. THE Pt S I N~
TAU 6.50 WITH PICPIDINr- UP TO TA-U.1,11NUS 0.69 WITH 'VINCANINE.
FACILf TY: INST. KHI"-,. RAST. VESHCHESTily JASHKEtqr u s sfi
UNCLASS[F-JE4

Z----~ 010 CLAS,S.LFIEDi%
UN PROCESSING DATE--04DEC70
..-j1TLE--STRUCTURE OF THALPHINE AND-THALPHININE -U-
~-AU,THOR-(03,)-,-~ABDIZHABBAROVAt S.t ISMAILOVs Z-Fs~v YUNUSOY? S. YU.
~-Z:OUNTRY OF INFO--USSR
~SOURCE-KHIM. PRIR6 SOEOiN. 1970p 6(2)? 279-80,
AT E PUBLISHED ------- 70
'~344JF_CT AREAS- BIOLOGICAL AND MEDICAL SCIENCES
-T 0-PIC TA,GS--PROCESSED PLANT PRODUCTv ALKALDION' CH8MICAL STRU"TURE, Ulf
-ECTRUM
P
S
~,CONTROL MA.RKING--NO RESTRICTIONS
.0or-UMENT CLASS--UNCLASSIFIED
PROXY REEL/FRAME--3005/0439 STEP NO--UR/039,-3/70/0i)e~,rC,02,,',,)27q/023,.3
CIRC ACCESSIO-N NO--AP01_3)2661
_11i 11, %C LA ----- - -
WIM hil 6"'M I NRM I 11! 1 -4 k & II 11. 11 iMIN U RE M W10A L KIM

010 PROCESSING UAT&--~140EC70
2/2 UNC L A SSI F I E 0:
~:CERC ACCESSION NLI--001737-661
'Aa J
STRACT/EXTRACT-WI, GP-0- ABSTRACT. THE STRUCTUIRE; OF THE TH;'(-'CrR01!
FOETIOW4 (MEADOW RUE) ALKAL010S TALPINE ~(1) ANO THALPHINTNE (N) 'AAS
o~--,EST'ABLISHED BY UV SPECTRA AND THE HOPMANN, DEGRADAT11,0N. MING -SU34
OF. I YIELDED THE ZKETHGXYjLtl PRIME.; 01PHl:?4YIjj3XH~p 5-j4 Pil., I i'l E
-DICARBOXYLIC ACID (SICIV M. 2900EGREES;.~ME .FESTER, Ilk -111L--20EGREES.
A
-CLEAVAGE~OF I WITH NA LIQ. NH SUB-3: AFFOROF0 LALWANIOINE A ii, Z 0
FACILITY: INST. KHIM. A(kST. YESHCHE-SrVt
JASHKENT* USSR
.wow
Ham

~PROdESSfl4d OATE--04or=c7o
UNCLASSIFIEO'
TtITLE-STRUCTURE AND STEROCHEMISTRY-OF UNGERNIA ALKALOIDS STUDIED BY NMR
.,AUTHOR-(03)-YAGUDAYEVi M.R.r ABDUAZIMOVI KH.Al.:t YUNUSOV, S.YU*
'C OUNT RY OF INFO--USSR
~~ORCE-KHIM..-PRIR. SOEDIN. 19701 6(1)t 94-7
~QATE PUBLISHED ------- 70
:.SQajE_CT AREAS--BIOLOGICAL AND MEDICAL SCIENCES
TOPIC TAGS--PROCESSED PLANT PRODUCTs ALKALOEDI~MOLECUL0~R '.-j'ERUCTURE
CONTROL MARKING--NO RESTRICTIONS

04
s
USSR UDC: 547-944/945
MASIMOV, A. III., SHAKIR6V, R., and )a9flKOVj S. YU., Order of Labor Red Banner
Institute of Chemistry of Plant Substances, Tashkent, Academy of Sciences,Uzbek
SSR
"Alkaloids of Veratrum Lobelianum"
Tashkent, Khimiya Prirodnykh Soyedinenly, N1 o3, 1970, PP 339-310
Abstract: Alkaloids in the epigeal part of,Veratruir, Iobclian-a-ii grown in the
valley of the Kar-Kara River are reported on for the first time. Upon separation
~of the total ethereal -fraction isolated from the epigeal part of the plant (coi-
lection madde on 13 M'wY 19668), new alkaloids weie differentiated as to "'OlUMILLY
and basicity: veralosin C Bifc 0 N 'veralosJjiin and -%reralo;tddin 027 11 43 0 N. It was
found that at the out.5ot 01 t~&'vegetlative period, total Calkaloids in ihe epigeal
nart o.'L Veratnm lobelianum is 2.5% of dry matter weight,, and at the end of this
vir
period -- 0.036%. Based on study of chemical properties, infrared, ultray let,
nuclear magnetic resonance, and mass spectra, and also con7ersion to tetrahydro-
solasodin, the most probable structure and configuration.is established for
veralosidin.
I RMHEMN MR. MORM-1. I

Alkaloids
USSR UDC: 547.944/945
UMUDAYEEV, M.R., MALIKOV, V., Order of Labor Reii Banner Institute
M.,
.~of Chemistry of Plant Substances, 71ashkeat, Academy of Sciences Uz"bek SSR
"Difference of N-H Prot-on Signals in the MR Spectra of Indole, Indolene and
Oxyindole.Alkaloids"
Tashkent, nimiya Prirodnykh Soyedineniy, No 1; 1970) pp 89-90
Abstract: Data are given on the chemical shift of theV-H proton signal in the
VER spectra of vinca alkaloids. Twenty-three alkaloids vere,,studied using the-
Jum-4H-100/100 instrument a" room temperature with concentrations of 5-10% in a
CD solution with hexamethyldisiloxane ws an intornal stan(lard. Dilution of a
C13
reserpinine nolution by a factor of more than 3 (from 15 to iW shifts the 21-H
~,d tl)rL4- tit. char4,i~ Jn c1 0
once., tr
signal by only 0,15-0.20 rfi,d. Thus it may be
tion in the 5-10'p'~ ralige hau lit LIC effect on the cht~ndcfll Will't of' till, N-11 protC)II.
It war, found that the chemical shift of the N-H proton signal in -me thylenindolines
differs appreciably from that in the indole altaloids. As a nile, the N-H chemical
shift in - methylenindoline alkaloids is observed in a wea.102-r fia!ld (-0.69 -
.1.20 m.d.) than is the case for indoles (1,75-2-15 M-C-)) -while the DT-H chemical
shift for.oxyindole alkaloids occupies an intermediate Place (0.56-2.18 m. d.).
In the 2-16-dihydro derivatives of the -me-thylenindoline alls.&Ioids and in
copsinine, pseudo-copsinine, picrinine and vincaricine,, the,N-H proton signal
-1/2
- - - --- ------- ---

-ry - - - I - --- - - - - - - -- -

USSR UDC: 547.94:543-51
RASMES, YA.V., FAYWIDMOVA, Z Order of Labor Red 'Oanner
SH. TJM
-Institute of the Chemistry of Natural Cpmpoujad~, Academy of Sciences Uzbek SSR
"Mar
s Spectrometry of Haplofoline and Folifine'.'
-Tashkent, Khimiya Prirodnykh Soyedineniy, No 10 1970) PP 107-110
Abstract: Data are given from an investigation of the mass*spectra of alkaloids
isolated from Haplophyllum tuberculatum: haplofoline, N-methylaplofoline, folifine
and acety1folifine. The principal paths of decay of these four compounds may be
studiedon the basis of localization of a positiye.~charge-on~the nitrogen atom.
e.
-Two decay schemes are described on the basis of t4 mass-c-pectroscopic data.
i0

USSSR UDC: 547.944/945
YAGUDAYZV R.R., ABDUAZDTOV, KH.A. Order of IAID-or Red Banner
-Institute of Chemistry of Plant Substan a
c4, T sbkent;,, Academy of Sciences Uzbek SSR
'Investigation of the Structure and Stereochemistry of Ungernia Alkaloids by the
ectrosco-py,
'Method of NMR Sp
Tashkent, Kbimiya Prirodnykh Soyedinen1y, No 1) 1970~, PP 941-97
Abstract: NMR spectroscopic data are given on ungerine, dihydroungerine, hippeastrine
trine and unsevine to expl-in the stereo-
:~dihydrohippeastrine, acetyldihydrohippear
chemical singularities and structure of their molecules. The,spectra of all com-
pounds were taken on the JM4-4H-100 inatrumentwith a working:frequency of 100 bMz
in a CDCl solution The internal standard vas hexamethy1disiloxatie. It was found
that the i/~ rin"gs in these compounds have the cis-arrangement. In contrast to
'the alkaloid clivonine, in dihydrohippeastrine the B/C rings have t-ae cis-configura-
tion and the N-CR3 group is situated above the plane of the benzene ring. The
-orientation of the H51 H5a and #Uc pro'tons and.of.the OR substituent associated
:_with C5 in the C-ring is established.

USSR
YUNUSSOV, M.S., RASHKES, YA.V., OV S_ SAMATOV, A.S..1 Order of Labor Red
Banner Institute of Chemistry,of Plan Substances., Tashkent,,Academy of Sciences
~Uzbek SSR
I'Mass Spectra of Alkaloids of the Songgorine Type. Structure of Songoramine"
Tashkent, Khimiya Prirodnykh Soyedineniy, No 1, 1970, PP 101-1107
Abstract: Analysis of alkaloid mixtures extracted from the tuberfs of Aconitum
karakolicum. which grow in the upper regions of the Tyup River (Terskey Altau
Range) showed aconitine, songorine and an alkaloid with a melting point of 211-2120C.
This base is identified as songoramine. Astudy was made of the maas spectra of
songorine, dihydrosongorine, their diacetates,; N-desethylsongorine, deutero analogs
of songarine and dihydrosongorine. Analysis of chemical and~sipectral data shows
that songoramine has the following structure: 0
C14,
R,
OR,
'N
X
X
RI.A2=H
Diagrams are given showing the fragmentation of songorine and its derivatives.

~547.944/945,
T Order of the Labor
RAZZAKOVA, D. M., BESSONOVA, 1. A., and YUN -SOY, S. YU.f
Red Banner institute of the Chenistry Acade,-w of Sciences
Uz-SSR
"Folinin.- a Novel Alkaloid from Haplophyllum FoUosujn'~'
Tashkent, Khmiya Pr1rodnykh Soyadinenly', No 11, 1972,~ p 133
Abstracts A neu alkaloid was isolated from HN: foliozun Vved after alw-_4 na
chromatography of the non-Phenolic fraction. This:compound had ap 139-140',
was optically inactive and-formed a hydrochloride,'MD 1~11 '-1720 and a picrate
mp 193-1940, It -gas named and on the basis of.UV, IR, NMR, and
mass-spectroscopic data it ~ms s~,oim. to be 41 E~-dimeihoxy".Ii-jpetliyl-2-quinolore.
'A
4 -
11 t - Ur j; jj j.kI I. . ...... .

USSR UDC .547 9144/945
-i Labor
VINOGRADOU, V. ISKAIDAROV, Sal and Onier of the
Rod Danner Institut-e of tj~a chemistry of Natural Academy of Sciences
UzSSR
"Ditermaminei a new Bimoleculax Alkalbid~From Thermapsis Laaceolata"
Tashkent, Khimiya Prirodnykh Uoyedinenlys No it 1974t PP b7-92
Abstracti From t~e Plant poi-tion of Thermopsis Lanceolata, a. new bimolecular
alkaloid of the quinalizidi-ne series was isolated, in a/je-ition to -L~exnnopsardne,
theimomine, citizinc~, N-ifte-thy1citizine, pa-chycarpine amd rhombifoline. On
the basis of NPM and mv~s-spactroacopic studies of thisiallcaloid ani its
hydrogenated derivatives, T)Ius the fact that on vacuum disilillation it
6' -dehydro- c~ -
yields themopsina, this product wds identified as
isolupanyl-51-therzopsin-14

-777
USSR tWC 547.944/945 + 543.5,L
YUNWOV, H. S., RASHKES, YA. V., Oyder of the Labor
Red Banner Institue of the Chemistry of Natu~~l Product~'sij Acwidemy of
Sciences UzSSR
"Frapentation Features of FIng A Sub.stituents o:t Lycoatonin Alkaloids Cn
Electron.Impact"
Tashkent, Xhimiya Prirodnykh Soyedinanly, No It 1972, PP 85-87
Abstract!j By studying mass-sy~ctroscopic entation of ly4!ootonin alkaloids
it was established that the ease with which a substituent at C-1 is eliminated
depends on its config=tion# inarcasing Atli tho siA-je of the atilb-stituent.
Changing the orientation of a C-1substituent frati C--(to stabilises
the molecular Ion and as a result th-a peak at E-17 is dadreasel-1, while the
one at.H-15 Is increased. 'zeriperature changes have little or -,G effect om
the intensity of vstuious -puaks. I..'ass spectvai (tata of c-=blnolamine catej:4
of three aiterpone alkalolas w9eful In obaractorizing the' substituent at 0-4
are reported.
rawlir

USSR WC 547.94~j945
YUN SOV S. YU., Order
YAGUDAYEVp M. R. t IUMAMOVA, S. F., AIMIKOV, V. 14:0 4 W
of the Red Banner of labor Institute of:the:Chexistry~of PlaA'M--' tances
UM
of the Uzbek SSR Academy of Sciences
"Study of the Stereochenistry of the Alkaloids of Codortopsin and Codono_wJ-nin
by,the Method of Nuclear Magnetic Resonance:Spectrosco~yll
Tashkent# Xhiaiya Prirodnykh Soyedineniy, No.4, 1972, pp 495-108
Abstracti A structure was proposed previously for the:neif alkaloids
codonapain (I) and. codonopsinin (III) isolated from Codonopsis clematidea,
on the basis of chemical transformationsand.spectral data (G. F. Eatkhalikov%,
et al.j KhPS, 30# 1969; S. F. Matkhalikovat et. al., KhPS, 210, 1971). A study
has now been -made of the nuclear magnetle resonance spoetra of the bases ard
their acetyl derivatives in order to establir;h the spatial structure of these
alkaloids. The R-methylpyrrolidine ring A has a semier,uciformation with
relative reciprocal arrangement and orientation o f the protons and H I and H 3-
(t groups paeudoequatorial, H. and F~,,8equatorla, 'and C-C pseudoaxial,
OR Cr pseudoaxial, OR.- le p3eudoaxial and Hir IT' pseti.loaxia.
1/1

USSR UJDC 547-91 945
NAMULIAYEV I A* Sol YMMOVt H* 36, YUN~VAQXj$,.S1,,jM. rOxder'~of the Red Banner
of Labor, Institute of the Chemistry ~af Plant Substances of the Uzbek SSH
Academy of Sciences
"Delphinium Dictyocarpum Alkaloids"
'4v 1972, 498-502
Tashkent, Xhimiya Pr1rodnykh Soyedlneniyj No PP
Abstracti A study was made of Delphinium dictyacarpmu ktlkaloids. From 44,,he
roots of the D. dietyocarpum gathered iathe-viciri-ty. of Topolevka,
Dzhungarskiy Alatau (flowering stare), methyllicaconitine, licoctonine and
the bases II and. III were isolated; by chloroform extraotion of the above-
ground part of the D. dictyocarpum gathered In the Kok-tal Highlands, Kuyazdysay
ancl Dzhungar,31iiy Alatau (budding stage) 0,58% of the tatal alkaloids were
obtaired from which mothyllicaconitin, eldeling eldelidine azA a new alkaloid
0 N width a melting polntl~of 210-4^120, H 493
called dictyocarpine W C2039 8
(mass spectrometrically were obtained. By comparing the nuclear rutgnetic
resonance and mass spectra of dietyocarpinev its amino alcohol and diacetate
with eldelinet eldelidine and eldeline acetate# tho licoctorane skeleton
was established for tho I with a mathoxyl group on the Oil thsi c-methyl group
1/2

IISSR

Mc 547.944
JURZAHATOY, R. T., MALIKOV, V. M. 0LUTFULLINj K. L. vOrder
ofthe Red Banner of Labor, Institute of the Chemistry""'W-P-lant Substances of
the Uzbek SSR Academy of Sciences, Andizhan State Medical Institute imeni M. I.
Winin
"Study of Physochlaiha Dubla Alkaloids"
Tashkent~ Kbimiya Frirodnykh Soyedineniyp No 4v 1972,1pp 493-495
Abstracti Chloroform extraction was used to Isolate 1.25% of the total
alkaloids from the roots of Physochlaina dubia Pasch. (Ph. alalca E. Korot.)
gathered In the flowering phase in.the Fergan Oblast. By sepamting the
Aixture of bases by solubility in organic solyents, hyoscyamine and a new
base I were obtained. The new base, had a melting point:,of 61-620 (benzene),
20
f4-7 13-5' (with 1.9 methanol)# the bromohydrate with a melting point
D
of 156-1570 (acetone)* The infrared$ ultr~Lviolet, nucleavir magnetic resonance
and mAss spectral data and chemical properties of the baste I indicate it has
the structure of 6-oxyhyoscyamine~

2/2
i .
. - 7 -

USSR
uDo ;1:621-391
ARIPOV, M. N., and IUNILTSOV, SR. Z.
'I'mass, Probability Distribution of Coded Transmission Distortionsif
V sb. Vopr. kibernetiki (Questions in Cybernetics -- Collection of Works),
VYP- 51, Tashkent, 1972, pp 162-166 (from RZh-Materratika, No 3, Mar 73,
Abstract No 3V465 by YU., PYATOSHINO)
Translation- The article -oresents an experimental hi&to6ram for variations in
the len~;th of a pulse transmitted over a certain -commmication channel and
presents a formula for its approximation. pend t4; an evaluation of the
probability of erroneous recepLion.-

USsR
ARIPOV,. M. N., YUNUSOV, Sh. Z.
"Distribution of Probabilities of the I'Mass," of Distortions of Code Samples"
Vopr. Kibernetiki lProblems of Cybernetics.--- Collection of Works], No 51,
Tashkent, 1972, pp 162-166 (Translated from Referativilyy Zhurnal, Kiberne-
tika, No 3, Moscow, 1973, Abstract No 3,V465 by Yu. Pyatoshin).
Translation: An experimental histogram is presented foT the change ir.
duration of a pulse transmitted through a certain communications channel,
and a formula is suggested for its approximation., This allows the pro-
bability of false reception to be estimated.,.

.4'
USSR
VDC 6 2 1 .3 9 54.4
ARIPOV, M. N., and
Z.
"On J!.0-,j_E;qU4Prob- 04:' (1
of Di3tortion;s Caabinations in
graph Communicationso
'b
V
s 4-va Kon-i-e:7ents-,ya po teorii p-r';'_daChi i ill'orm. SckUv 5
4th Conference On The Theory of. -vranslnissioa and. Encoding of Infovma-
-tion. Section 5 - %Iollectioa of, Works), 1:1 1969, pp 30-
:.13 (from _P_7h-EIeIktrosvyazI !4o 4, ~.pr: 701: AW,
- -t:c4ct No 4.64.257)
Code ccmbinations with an anwUal pz~robability of dstor-
+-ion in tele-apbic ccaclunications were inv'
Cot:- ~'Cvtlad, by which it- is
Possible ar, a Afirst approxirtxudoR to jud'ge ti-le rstatistical Stzructuze'e Ot
pulse no-A'Xe in the chavRcls of voice-friaqucnoy te'LL-3fraphy. The
sults of two series of m asurements were. subjeci pro-
Md
Te tO StaL
ceasing. During
m-easurements of the f:Lr.-;.t serial on chanaeLG of a T2-
12/16 system with frequency modulation, test textD wh-ich were
the two directions of communication we st-Lin- acc~-arit of
in re co,'Opoi;ed, , t
the identical fre-juency for all codes of 5-elemeat combinations. Dur-
im" measurements olf' the second Ceries on ~chcaqvels, of a CWT (c.-'-coar-ision
unknowrt)* system, separate code combinati-ons were, transtaitted, iile
1/2:,

USIS a
ARIPOV, M. N., at a!., V sb. 4-ya 111to ferentalya po teorii peradacl-d i
n
lrodir. inlCorm . , ',",elcts , Moscow-Tashkent , - 1969~, pp ;30-33 f rom RIZh-
ElektrosvyazI, No 4, Apr 70, Abstract No 4.64.257)
distortions oif which were revealed by an znalysis o the accepted
text. Data an the extent of measurement ands the distance of the
routes; tested are presented in tables. B. B.
Lble gyarbleA for VChT (high- A
POSS.: freque ey telephqL
~2/2
75

r
USSR UM 539.194.536-27
Y-W, V. B. pXA14AYEVI F. G.j ASLANOV, KH. A., SADYKOV,
anner of-labor State Un Yersity.imeni
A. S.,.-Tashkent Order of the Red B
V.J. Lenin
"Conformational Conversions of Lupinin and Tropin Alkaloids During the
Formation of X-Oxides"
Tashkent, Khimiya Prirodnyl,-h Soyedineniy, No 4j 1972, pp 477-483
~bstractt Experiments were performed in which N-oxides of lupinin and tropin
were obtained under light conditions by mixing the initial bases with 5%
H 0 at room temperature. Lupinin forms two isomeric N-oxides the separation
0j 2h,
w ch is realized by solubilityf* and the.individuality is checked by
chrozatography on a thin layer of Al 0 (the benzene-ether-methanol system,
2 3
5t2il).
The infrared, mass and paramagnetic resonance spectral data indicate
that the first isomer N ->- 0 of lupinin has-trans-confQrnation with ala N--~- 0,
the axia)--CHOH group with an intramolecular hydrogen bond between > N ---~r 0
CH OHt and the second isomer, cis-coinformation with a, e N---It- Of axial CH20H
2
1/2

1/2 017 p!IOCESSING DA-T_c---2?%T/70
E
Tj TL CCH4kq i DE lHY0POSE NAt f 014 C. A TPA LYST
-AUTHOR-(04)_$n_-0LSK,IY, 0.11., YUkjUSLjV, U. I LillW-14016
A *M
-.r-OWNITRY OF. INFO--USSR
~:SOURCE-U.S.S.R 266,733
_~tff EREI __-OTKRY1 -1 ZU BRET. , PROM. 01341AITa
NC E. _IYA, SY, TOVARNYE: ZNAKI L970,
-.0 A T EP Ui3t SH ED ------- 70
AREA-S--CHEMISTRY
~.TGPIC TAGS--SACCIIARIDE, PATENTI CATALYTfC HYDROGENATION, CATALYST, MICKEL,
I NUIll IRON
~C'ONTROL 14ARKING--NO RESTRICTIONS
-OOC(Jt4F?4T CLASS--U14CLASS[FILD
-PROXY REEL/FRAM"-3004/1792
E S T E P 140-
IRC ACCESSION MO-AA0132058
EMIR I M

L A VRQ~ES51NG OATE--?7.%OV70
C-IR.C ACCESSION NO-AA01321,158
ABSTRACT/EXTRACT
--(U) GP-0- ABSTRACT. A HYDROGENAT[ON CATALYST FOP,
VIONOSACCHAR IDES. CONSISTED OF NI , AL , AND FIE , WI TH 2 -WT. PERCENT NIN
ADDED* FACILITY: KAZAKH CHEMICAL TE-Cl"NOLOG f CAL INSTITUTE.

USSR
Candidate of Medical Sciences', BRUSILOV, G. I. and YAKOVENKO,
V. I., Chair of 'Normal Physiologyii and Blectrophysiolqgy Division, Central
Scientific Research Laboratory-, Tashkent,Medical.Institute
'_'Venous Tone of the Lower Extremities and~Methods of Wtermining It"
Thshkent, Meditsinskiy Zhurnal Uzbekistana, No 8, Aug 10, pp, -18-20
Abstract: A method is described for determining venous tone frorn orthostatic
distensibility of-the veins. The results obtained using this method are very
close of those obtained on the basis of changes in the 1,rx and Mh indices of
arterial pressure in Hellong's orthostatic test. A special cuff is applied
to the thigh of the recumbent subject. The cuff is coxinected through a tee
to a ranometer and tank with compressed air.- When the,cock is opened, air is
quickly forced into the cuff, creating a pressure of 300 to 350 = Hg- The
aubject then assumes a vertical position and:10wers one leg into a special
vessel filled with water.. up to the topthird of the leg. 1he initial volww
f water flowing out
of the leg to the top third is determined from the amount o4
into a measuring cylinder. 7he pressure In the cuff is thet reduced to zero.
The increase in the hydrostatic pressure of:the colu=.of blood causes the
1/2
48

USSR
YUMJSOV) Z. R., et al., lv4ditsinskiy Zhurnal Uzbekistana,, Ito Aug 70, pp 18-
rTT

112 025 UNCLASSIF lecy"~ ~oRoCE,SSING DATE--160CT70.
JITLE--T0XIC EFFECTS OF ISOPROPYL.NI.TRirE AND ISOPROPYL, NITRATE -U-
.-,,.AUTHOR- 102 1-YUNUSOVA, K ARKHIPOVAv. 04e.
.`.Z OUN T R Y0 FINFO--USSR
,,~SOURCE~--FARMAKOLo TOKSIKOL. 4M SCOW 1970,.33(l), 110-12
-DATE PUBLISHED ------- 70
'-_.SUBJECT~AREAS--8IOLOGICAL AND MEDICAL SCIENCES
b P I CTAGS--ISOPROPYL NITRATE, NITRITE TOXICITY, L IE R
CONTROL MARKING--NO RESTRICTIONS
~-JDDCUMENT CLASS--UNCLASSIFTED
.'.PROXY REEL/FPAME--1987/0047 STEP Ni3--Ult/0390/70/033/001/011(Y/0112
--AP0103727
;,.C IRC ACCESSION NO
UNCLASSIFIED

212 025 UNCLASS I FEb -PROCESSING DATE--160CT70
ACCESSION NO--AP01037Z7
CIRC
ABSTRACT/EX TRACT-- (U) GP-0- ABSTRACT. EXPTS. ON HICE AND RATS SHU'WED
THAT INHALED ISOPROPYL NITRITE WAS MORE TOXIC THAN ISOPROPYL NITRATE,
WITH MEDIAN LETHAL CONCNS. Of 2700 AND 29000 MG-M VRIME3i RESP.
ISOPROPYL NITRATE DID NUT INDUCE mkrHEmbGLOBIN FORMATION IN THE BLOOD.
THEM BULK OF INHALED ISOPROPYL NITRATE WAS RESORBED IN THE LUNGSt aUT A
-FRACTION WAS REDUCED TO ISOPROPYL,N11RITEIIN THE C.IVER.
FACILITY:~ INST. GIG. TR.. PROFIABOL.It MOSCOW USSR.
UNCLASSIFIED

USSR UDC 547.944/945
NUSOV 0 S.: YU. Order of the Red Banner
. IYUT
RAMULUMV, A. S. , =Q9
;118 Plant:Substance' ::of the Uzbek SSR
of laborg1nstitute of the Chej try of S:
Academy of Sciences
"Delphinium DictyocaxpuM Alkaloids!',
Tashkent, Kbimiya Prirodnykh Soyedizeniyp No 4, 1972p PP 498-502-
Abstracti A study was made of Delphinium dietyocarpum alkaloids. From the
roots of the D. dictyocarpum gathered in the:vicinity of Topolevka,
flowering stage, thyllicaconitine, licoctonine and
Dzhungarskly Alatau 1, me
adl by chloroform extraction of the above-
the bases II and III were isolatt
ground part of the D. dictyocarpum gathered In the Koktail Highlandsj Huyandysay
and.Dzhungarskiy Alatau (budding stage) Oo58% of the total alkaloids were
obtained from which mothyllicaconitint eldelin, eldelidinee and a new alkaloid
called dictyacarpine (I) CZ6P ~N with a. melting point of 210-2120, 14 493
3
(mass spectrometrically were obtained, , By coxp3xing the nuclear magnetic
resonance and mass spectra of dictyocarpines, Its amino alcohol and d1acetate
with eldelinot eldelidine and eldeline, acetate, the licoctonine skeleton
was established for the I with a metho)Wl: gmp on the Olt the c-methyl group

UNCL A-5S I: F I ED PAOCE~`,ING OATE-, ~93C-73
RfARRANGtP!EiNT,oF DI-ALKYLAMINIJ. 1,HLQP.IJ qUINIONES ITNTO
BENL 12, 1 0),21 3, OXAZOLINE DERIVATIVES; -U-
A.M., FOXAN, YC-.P'o
::tClUNTRY OF lNFG_-UJSR
:-Su-URi;E--lLVESTIYA SlBiRSKOGO GTOELENIYA AKAOU411 'AALIK SSSA, NO 4, SEfRIYA
...~KHIMICHESKIKH .164AUKi 1970, NR Z, PIP, 124-128
'DATE PUBLISHED-70
--CHEMISTRY
UBJECT.AREAS
.fOlPIC JAG S--PH310EFFECT, AMINO, CHLORINATED ORGANIC
-CHEMICAL DEGL;MP051110h, FORMALDEHYDEs DEALKYLATIOW
:CCUTROL MARK I RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIE0
40RUM RF-:--L/FRA","E--199e"/I~o"76 STEP
t IAC ACCESSION NO--AP 0 112. 856
UNCLASSIFIED

UNE'L A S Sl F I ED PA3CESSING DATE--'09z)[.T70
_CIRC ACCESSIOV4 NO-AP011285ta
~A6STRACTli-i-XI R AC T-- ( U) G; P - 0- A0 S TRACT 1 N, it AD I AT I GN OF
~3,5 t 6JR lCliLQk0,2 i) I MET HYL40-1 I NO, 1 1,4 j. BENZOQU INONE i
114rbENZOQUlNQNl: AND
LIMETHYLAi~INUill4lbEN*479QUlf~ONE IN
'S OF
SOLUT11INS '~iITP VISIbLE LIGTH GIVES TH& UNSTABLE DER!VATIVE
6
-E.NZGXAZk,,Lij'4E# THAT 0ECGi4P()cE INTO., THE DEAL~KYI.A.TION,~CO.%IPOUi,iUS UF THE
-f-PAREN'T CHLORG, Di-t4ET,iYLAMli",'Cit;~UINONf:S AjVD:FQRMA-LoEHY[)E.
JLI TY:
FAC NUVOSIBIRSK INSTITUT URGANICHESKOY K"Hlhl A SU AN SSSR.
U114C LA s s I HE 1)

Lasers 6; Masers,
USSR UDC 621.375.82
A-
J0, ATAVICHUS, M., KaIELYA, V., PMURSKAS, A., atid,~,VqW
"Use of Thin Phototropic Films for the Synchronization, of a Neodymium Laser"
V sb. Nelineyn. protsessy v optike (Nonlinear Processes in Optics Collec-
tioa of W`orks) No 2, Novosibirsk, 19721 pp-61-66 (from RZh-Fizika, No 11,
Nov 72, Abstract No IlD891)
Translation: The oscillatica of a Nd glass laser with a synch roniz ation of
modes produced by a thin phototropic film of polystyrene with polymethenyl
dye introduced into it was invastigated.~ With an initial film transmission
of 60% the pulses generated with a total energy of uO.J. joule consisted of
12-15 subpulses, the duration of which as determined:&om two-photon lumines-
cence was q-4 psec. Total radiation modulation was obsnved in 7-5 out of 10
oscillation pulses. The smoothness of the spectrum (the spectral width of the
radiation close to threshold was ,,6 X), the stability of the average wave-
length of the radiation, and the ease of achieving oscillation in single-
mode-operation were noted; this.is expla-ined by the high degree of homo,-
geneity of the polystyrene films. 3refl. S.; F-Sharlay.
m n ;Iniai, 411r.,"11 41i"Ta F

i:. M i.
USSR UDC 536.46:533.6
KALABUKROV, G. V., RYZHIK, A. B., YURAMNOV, Yu. A.,,SIDOROV$ V. M., OSIPOV,
B. R. FAYERMAN, S. N.
mm.
"On the Effect of Reaction-Kinetic Properties of an Infla able Flow in the
Combustion of Aluminum Powders"
V sbl Gorc-niye i vzryv (Combustion and Explosion Collection of Works),
Moscow,."Nauka", 1972, pp 204-206 (f rom. Hfi-.Mekbanika, No' 3, Mar 73, Abstract
No 3B969)
Translation: Shock tube studies were made of the combustion of aluminum powder
when detonation waves act on it. These waves differ in intensity and chemical
composition. It was established that the increase in the. detonation rate of the
gas mixtures impedes combustion to a:greater degree than~the detonation tem-
perature is lowered. The positive-effect of ovygen, carbon dioxide, and small
quantities of nitrogen and argon on the combustion of disperse-aluminum is
noted. Rarefaction of the stoichiometric. mixture of hydrogen and oxygen with
Light gases (hydrogen and helium) leads.to:a decrease inthe degree of combus
t1on of the powder. 5 ref. Authors.' abstract..
55

USSR UDC 538.245
KORNEV, Yu. V., 'URASOV I., and BYKOV, G. P., Moscow, Higher Technical School
imeni N. E. Bauman
"on the Role of Magnetic Microstructure for Ferromagnetic Resonance in a Conduct-
ing Fer,romagnetic Layer. I. Character of the,Skin Effect in Ferromagnetic
Resonance Without Allowance for Magnetic S tructurelF
Tomsk, Izvestiya Vysshikh Uchebnykh Zavedeniy Fizika, No 9, 1970, pp 7-12
Abstract: A study of the properties of a ferromagnetic metal layer in an electro-
magnetic field yielded the simultaneous solution of Maxwell's equations and the
equation of magnetic moment density variation. The latter was chosen in the
Landau-Lifshits form, with the relaxation term suggested by Ifilbext. The usual
local relation with homogeneous and isotropic static conduction was used for tile
conduction current density. The results indicatle the ano-malous character of the
skin effect for the first mode and the presence of anomhlous skin-effect features
for the second and third modes in the range-of fields used in practice. No al-
lowance was-made for the influence of the microstrueture.~on the. character of the
skin effect. An evaluation of the'influence of this factor will. be given in the
st--cond part of. the article. A "Minsk?-22" digital comput.,~r was used for some of
tile calculations. S. A. Temirbulatov took part in the work.
1/1
26

Ref. Code
u i~ 04 8.t
r- 135549t Steti. Oze-.sk;i A- D SoIntsev, Yu. P.; OR
11,in
MyaKkov. A~ ov'--N~ I~tlras
M. F.; ftir
0 -F Parfel
Nikan '~--V. _Z~K ffiv.9xil. ~~ 11 70
-un:t~a, :5. :5. U.b.51xl 2150,899 (Cl. C 220l 06 Jan
E pp . TDR 968; From OlkryUya, lwbrel., -Pidut. Obrarlsy,
Tomt-nye Zlta*i 1970i 4Z(4), 81., SteA with improved-inech,
properties consisted of., ~ C 0.40-A45, Si 0.5-0.7; Ain 0.".8,
Cr V 0,3-O.'S, Mo 0.9-1.2. impurities of,