SCIENTIFIC ABSTRACT KRYUKOV, P.G. - KRYUKOV, V.B.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000826920002-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: April 3, 2001
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KRYUKOV, P.G., Jcand.med.nauk
late complications in operations for the elimination of transyeroe
flatfoot by the M.I.KusUk method. Ortop., travm. i protez. 21 no.8t
67-68 Ag 160. (MIR& 13: 11)
1. In Cherepavetakogo (Vologodskoy oblasti) ?orodakogo meditoinskogo
ob"yedineniya (glaynyy vrach - N.A.BelyaLkova).
(FOOr"ZURGEM)

KRYUKOV, !~~G-I-,.Aand.med.nauk
Mild form of idiopathio fragilitas ossium. Veot. rent. i rad. 30 no.6s
56-60 11-D 161, (HIRA 1512)
1. Iz Cherepovetakogo gorodakogo meditainakogo ob*yedineaiya (g3.avny7
vrach II.A.Delyakova) Vologorodskoy obDwti.
(OSTEOPSAT M OSIS)

KRYUKOVP P.G., kand.med.nauk
Stamping (marking) roentgenograms. Med.sestru 21 no.7:50-51 Jl 162.
(KIRA 15:8)
1. Iz Cherepovetakogo gorodakogo moditsinakogo ob"yedineniya
Vologodakoy oblasti. (X PAYS)

ELASOV, 11,G.1 ZUYEV, V.S.j KRYUKOV, P.G.
Increasing the power of a ruby-type quantum pulse optical maser
by resonator Q-faotor modulation* Zhur. ekep. i teor. fiz, 43
nool:353-355 J1 162. (HIRA 15:9)
1. Fizicheakiy Inctitut im, P.N. Lebedwva All SSSR.
(Masers)

L 10272.-h)
=-31?-W.,1AM,--~11JF( 0)
ACCEMIM NRs AP3002751 0/018D/63/060/003/0188/0189
AMCLR: D-Wev's Ve P... 00 74
0. 71-
TITU: 0agrifte4r fo;~~~rsd4tlm.endm of an optical qu=tun
oscillator 0
BOME: Fribory I tekhniks akeperlmata, w, 1 1961, 18&189
TOPIC TAM optical tors; Me"urments Of radiatim evera
AWMM: Fig. I of Enclosure shows tAs schemt1c diagram of a calorlmetar-tM
melver used for asasuring this =41stlon anera of In crPtIcal qpantum
oscillator. copper-foil hallw sphere I vith aperture 2 is pl=ed in a vma=.
The ray is directed through-the aperture lnt~o the sphere aM Is abaotbed by the
walls; temperature is measured by t2ormocouple 4,- the sphere is blackened Inalde
and its outer surface is coated with aL thin layer of silver. The sphere in
susperAed by glass hooks I f&ich Insure therml Insulation. it is placed In
glass flank 6, iftse vacuum Is maintalned. by Suter 5, 'Aw emf of the
thermocouple Is measured with a galvanonster vhose aensitivity is 10 suP -7
v/mm/za and Internal resistance in approximateay 10 ohms. For a sphere of a
Card
...........

L 10270-63
ACCEWION M AP3002751
mis of 0*6 S* a aw*i4r of 90' mm* am overture diameter of.7'=, a fodthlcknasa
e. 0.,05 =, and a thermocouple awmitIvIty 6r 5 z 10 m* -4 imile, the
meavirement range van 5.x 10 amp -4 to I joule.. For a sphare of a mass of 8.7 9,1
a d1mmeter of 30 =, an aperture Alm of 3 mm, a foil thIckness of 0,5 =, I--!
anti -~,hermoccruple aens=Aty Aof 34,x -10 wA-, -rj2- II the r"surtment re Vw
uqalaj ~I 11
5 x 10 sUP -3 Joule- In both'emesp the tharmoiwuples consisted of copper
~;-05 m) and constantan (0.08 =) vireo, and mea=xment accuracy was 2DA. *In
nf-lusion, the authom thank N. 0. Bwovp M, D. 011~, A. M, I& VIO'b"
and 1~, :~.t. Maly4shey for their useM dinewalma." Orig. apt. hast I flo=e and
table.
ASSOCIATIONt. rizichaskly Inatitut AN SM (WIcq InstItute, AN SSM)
WIMTrM: 24"169 DM AMt 1274163. MiCL:' 01
am CCME2 00 NO MW SOVI 001 01m: 02
Card

ACCES*SION NR: AP4019968 S/0020/64/154/006/1303/1305
!koy P909*
AUTHORS: Grasyukj A Z,; Zuyev, VeSo; Kokurino Yu.L.;-.Krlx
Kurbasov, ~.V.; Lobanov IV.P. ; Mozhzherin, V.M.-;
A.N.; Cherny*kho NeSe; Chuvayev, K.K&
TITLE: Optical moon ranging
.SOURCE: AN SSSR. Doklady*j V. 154, no. 6, 1964t 1303-1305
I
TOPIC TAGS: laaerg ruby laaerl moon ranfnft moon
.light reflectiont celestial ranging.opt ca ranging
ABSTRACT: The paper de'scribee the preliminary results~of moon
[ranging with a ruby laser* For the transmission and reception of
the light pulses, a telescope was used with a mirror diameter of 2*6
M. (see Fig. I of the: Endosure)' Ta amused wai developed by V. S. Zuyev nd
P.M. Kryukov and had th; following parameters: wavelength 69431, -
Ipulse energy 50 to 70 joules, pulse dufttion 2*vsec. diameter
of the beam 3.1 mm., and divergence 31, By taXing into consideration
-the light"scattering in the atmosphere, the diameter of the spot on
the moon is estimated to be 14 km. For the detection of the signall
.quC.113.

ACCESSION NR: AP4019968
a photomultiplier cooled with dry ice was used. The signal to noise 1
ratio was 0.16. Therefore, statistical treatment was necessary..
The authors believe that the results prove the reality of the re-
Plected signal. "The authors are grateful to corresp. members A. G.
Ba3ov and A. B."Severny*yl and to B. 1. Belov, F. Kh. Nigmatullin
of the Lebedev Phys. Institute# and to V. B. Nikonov, Ve-Ko Prokorwv
P, Pe Dobronravin, N. V. Stesheuko, and B. P. Abrashevskiy of the
Cr~mean Astrophysics Obsez*atory." Origs art. hast 1 figure..
ASSOCIATION: Fizicheskiy institut im. P.No Lebedeva AkMemLi nauk i
SSSR (Institute of Phyeicap AN SSSR) Kry*mskaya astrofizicheskaya
I
1 observatoriya akademii nauk 8SR (CrLean -Astrophysics Observatory,
:AN SSSR)
ENCL: 01
SUBMITTED: O5Nov63 iTD PRE96i '30477'*
SUB CODE: =I AA NO RZY SOV i -'fool OTHSRs 001
2/3

ACCZSSION NRI AP4019968 EXCLOSURZI 01
Pigs lo Diagram of unit for optical moon
ranging
T - Teloscopel OKC - optical 4uantized gen-
aratorl L, matching lansl Z - throwovar
uLrrorj D dL&phragml ZIP - interference fLI-I
tort FZY slectrou.photomultLplLer; OK dry'
ice container,
low,
3/.3

AMBARTSMAN, R.V.; BASOV, N.G.; YELISEM, P.G.; ZUY?V, V.S.; KRYUKOV,
P.G,,.;_STOYLOV, YuJu.
Measurement of the time parameters of a large laser using a
photodiode. Radiotekh. i elektron. 10 no.91l729-1?30 S 165.
(MBA IS: 9)

r, rev

VIA

-L 59527-65 EWA (k)/FBD/EOG (r)IEWT(l )/tEC(k)-2/E IF (n)-2/94G(m)/E PA(,v)-2/T/EEC(b)-2/
ENF'(k)1EWA(M)-2AJA(h) , Pm-4/Psi.-4/Pz-6/Po-4/Pi-4/Peb/pi-4/pl-4 SCTB/IJP(C) AG/W/A
ACCEUION Of AM16~~ UP/0056/65/00/006/1563/lieT ri,
AUTHOR R. V41 so #i VAUD.
Amabartsumq J- V
An. -LASJ ttavy, 10 611 $610y, No,
ZAO
0. 1. 1 SEMka, P. 0. t Genstaklyj Tit Y. I Otc7lovii Y140 Tn.
i
i-T-ITLIt Keating of matter by :focused laver radiation
SOUMIt Zhurul eksperivientallom I teorstleheakcy fisiki, Y. 48p no. 6, 1965,
TOPIC TAM high tMsratmuaw~p laser a2dicatio xamer radiatioup 11thUmej, I
air
ABSTRACTs In discussing the main factors that limit the beating of matter to high 1
temperatures by laser radiation, the authors point out that to solids the UnIte-
tions are Inposed by the sharp focus that obtains under most experimental condi-
tionsp and that In games the limitation Is 4vosed by the poesibillty of gas break-
dom. in view of theme limitation, they ewoludsp after snLl7zing the motion of
the breakdown toondary In a gas qualitativelyp that focusing of laser radiation w
the surface of a condensed- vWum located In vsou= to the wet promising wthod at i
*t�424go kJ& f4q%"r&tVM pUMIS IS JUS 4"S tM UNA C=Vod=t Note of

L 59527-65
ACCESOZON NRi AJPP16549
operation to one In which one-dimensional motion of plasmim. occurs, mince thres-
dimensional motion leads to rapid reduction In density and a decrease to the re-
lative fraction of the laser radiation absorbed in the plama. Under these tonal-
tions the uaxlxm achievable temperature to determined by the anorgy lose due to
radiation and thermal conductivity. The authors then report the results of a
optatral analysis of the emission from a plasm produced b7 focusing %he radiation
from a noodymium glass q-twitched laser an the surfaao of a solid sample of lithium
In vacuum. Ili* laser radiation consisted of tvg pulses, each with energy approx-
imately 3J w4 oseh approximately 40 save In length. The motivated obtained tow
peraturs in this case Is of the order of 20 my (2.3 x 105 dog). In the case of
breakdevn produced In air of normal density by a ruby laser pulse of approximately
31 the earresponding temperature eannot exceed 10.3 *To Orig. &A- beat 3 figures
and 3 formulas. (021 j.
?Isichoskil Institst ixo~ ?a No Wbedm Akiduli sauk MR (rastes
_17vWI~U;, Led of $classes, $881t)
louna=s x6jazO WLI M SUD CM1, CC# $41
Ito nr say 1 009 MMI 003 M PIMI .40"

v-,~1-13/IJP(c SOUIR'ci(F NE': UA/ 16'~A 1 01,
Wo (T6
WIMOR: Basov ~ (~o r io' L. rA;; 53SR) ; km~~a~pumiZ;~n,.V Zuy!q, V. 5
I N. opondiL6 momb
V. Kryukov P. G,-, 1,6tokhov, V. S.
ORG: physics Institute im. P. (Fizicheakiy 70
institu~*,_'Akadeaiya nauk SSSH)
TITLE: Velocity of propagation of a powerful light pulse in a medium vith population
inversion
SOURCE: JVI SSSR. Doklady, Y. 165, no. 1, 1965, 58-6o
je, 19
TOPIC TAGS: laser, rly laser, laser pumping, optic'pumping
ABSTRACT: The article is a brief advance report of a comprehensive work to be pub-
lished separately. It was shown that the leading edge of such a pulse does not change
naterially while propagating within a medium with inverse population. In the case
of a. ruby medium with usual parameters the velocity of the pulse maximum on reaching
its stationary value van shown to be Ii x 1010 cm/sec, which greatly exceeds the
velocity of light. This fact, however, does not contradict the causality principle,
since such a propagation taken place as the result of the deformation of the initiall)
weak leading edge, and can continue only to the point of zero intensity vhich always
propagates with the velocity of light in the medium. An amplifier composed of two
ruby yods 24 cm long wan used for experimental study of the problem. The end faces

L 4065~6_
ACC NRs AP5027834
of the rods were cut at the Brewster angle. The total gain for a weak signal was
about 50. Both Input and output pulses were recorded by the same coaxial photocell
arrangements, but the output pulse was made to travel an additional distance so that
it reached the photocell 56 X 10-9 sec after the input pulse. The parameters of the
input pulse were as follows: energy 1.3 J. pulse width 16 x 10-9 *sec. A comparison
of oscillograms of weak and strong pulses revealed that no appreciable shortening of
the pulse occurred, and that only the time interval betueen the input and output
pulse shortened us the pulse strength Increased. The shift in the time interval in
this case was 9 x. 10-9 sec, which agrees with the theoretical considerations pre-
sented above. It follows that amplification ef the exponentially growing leading
edge of the pulse results not in a shorter pulse, but in an additional shift of the
pulse peak. To shorten the pulse, it is necessary to increase the steepness of the
leading edge by, say, cutting it off by a shutter, by nonlinear absorption, etc, It
is noted further that the shift of the pulse peak with velocity exceeding the veloc-
ity of light is accompanied by the shi:rt of the boundary of Inverse population and
can lead to the emergence of a number of new effects such 83 that of Cherenkov radia-
tion. Orig. art. has., I figure and 2 formulas. [ ,-T I I
SUB CODE: EC, OP/ SUBM DATE:- 3ljul65/ ORIG REF: 002/ OTH REF: 002/ ATD PRESS:

L 1379-t,61 -2/~EWAW 3CTB/lJP(c),
ACCESSION NR; AP5022443 WO UR/0109/65/010/009/1729/1730
621-318-325-001-5:621.383-52
AUTHOR: Ambartaumy&n, R. V.; B&NOV N. 9 Y
Kr ZHXev.
.,Yukov, P, G.; Sto
_ylov, YU,
qq
TITIX- The measurement Ofthe time parameters of & giant pulse laser by nesna of
a photodiode
SOURCE: Radiotekhnika I alektronika, v. 10, nd. 9, 1965, 1729-1730
TOPIC TAGS: giant pulse laser, gallium &rsenide,,photodiode, resolving time, Kerr
cell, photomultiplier
ABSTRACT: The time-dependent characteristics of a giant pulse lasqr switched by
a Kerr cell were measured by, means of a gallium arsenide photodiode. The photodi-
ode was obtained by diffuolon'of cadmium into n-type GaAs with a 2 x 101a cM73 con-
centration of tellurium during a period of 60 hr. The depth, thickness, and area
I of the p-n junction were 80 u, 0.9 p, and 2.5 x 10-3 CM2, respectively. The photoj'
diode was pumped at right angles by & nonfocused lr-aer beam and the pulse width I
frcm the photodiode (connected across a T5-ohm load) was 40 nanosec at room temperL---
ture, and 20 nanosec at 77K. The results Indicate that the resolving time of the

L 1379-66
ACCESSION NH: Ap5o22443
photodiode is not greater than 5nanosec, a quality which-awkes it competitive with
photomultipliers. Mike photomultipliersi which introduce a signal time log,
photodiodes are capable of accurately determining the time lag of a laser pulse
released by the Kerr cell. The experimental value of the lag was 80 nanooec. Orig'.
art. has: 2 figures. (YK1 I
ABSOCIATIONt none
SUBKITTED: 09Dec64 EXCL: 00 SUB CODE: EC
NO REF SOV: 001 OTMM: 001 ATD PRESS:
i Card
-2/2_

.L 4'-'a4-0-f,6 EEC (k)-2/i7wA(h)/W(k)/LWT(1)/rBD/T IJPW
ACC NT AP6004913 SOURCE CODE: UR/0056/661050/001/0023/0034-
"I'l 1011: Basov, N. G, Ambartaumyaq R. ZpySyLy !ayu G. Le okhov V !i
p.
ORG: Physics Institute Im. P, N. Lebedev, Academy of Sciences SSSR
(Fizic skiy institut Akademli nauk SSSR)
TITLE: Nonlinear amplificatioh of a li ht pulse
SOURCE: Zhurnal eksperimentallnoy I teoreticheskoy Mild, v. 50, no. 1, 1966,
23-34
TOPIC TAGS: laser, nonlinear optics, stimulated einission, quantum amplifier
ABSTRACT: A theoretical and experimental analysis is made of the passage of
a powerful light pulse from a laser through a laser amplifier consisting of two
ruby rods operating in a saturation regime. The preliminary experimental results
have already been reported (Akademiya nauk SSSR. Doklady, v, 165, no. 1, 1965,
P. 58-60 (see ATD Press, v. 4, no. 138, p. 7-8)). In the experiments performed,
1 it was shown that as the result of nonlinear amplification the velocity of the pulse
is 6-9 times greater than the velocity of light In vacuum. To decrease the pulse
duration during nonlinear amplification, the olope of the incident pulse should be
Card 1/2

L 2184o.66
ACC NR, AP6004913
increased by chopping off the exponential leading edge of the pulse. By using a
second Kerr cell, the duration of the pulse was shortened from 8.7 * 0.5 nsec
to 4.7 -k 0.5 ndec and the time from 3.7 -t 0.5 nsec to 1.9 * 0.5 nsec. The theo-
retical analysis of nonlinear amplification predicts both of the observed effects
Orig. art. has: 19 formulas and 8 figures. ICS)
SUB CODE: 20/ SUBM DATE: 31Jul651 ORIG REF: 011/ OTH REF: 008
Card 2/2 not

L ~17)1i.;_66 1 1 113 1 r I_T
ACC NR. AN=67 COE t uR/o3%/66/oo3/oo6/026l/M&
54 SOURCE
AUTHOR: Amb suwan. JR. YJ fts- L_N,._Qt0*,,KrYukoY. P. G.; P~okhoy S.
ORG: Physics Institute im. P,-N. Debedev, of Sciences SSSR (Fiziche Lo
uk Y skiy_
atitut Akademii na SSSR
TITIZ: JAser vi h
,21~!jonrescnant feedback
SOURCE: Zhurml"e%perlmentaltwyiteoretlcheskoyfizikl. PielmayrodaMsiyu.
Prilozhenlysp Vo 3P no* 6, X9a,, 261-264
TOPIC TAGS,* laser r and ds ruby laserp laser beamp light scatteringp laser QVtIcs
ABSTRACT: The authors report achievement of laser action with nonresonant feedbackp
produced by back-scattering from a volume or a surface# which behaves like a "sto-
chastic" resonator with a continuous natural-frequency spectrum. The luing frequen
does not depend on the--length of the resonator,, but Is determined by the resonant fr
quency of the active medium. In this laser (Fig. 1) the active medium comprised two
Fig. 1. Diagram of experiment, I - Beat-
tererp 2,,3 - ruby crrstalp 4 - Mirrori, 5
filter,, 6 phortocellp 7 osciUoscoPeo
4 a I
k

ACC NR: AP6008754
ruby crystals in seriest each 24 cm long and 1.8 cm. in diameter. The feedback was
produced with the aid of a mirror (reflection 99%) and a volume scatterer (suspension
of chalk particles In water) or mwface scatterer (plate with a Wer of sputtered
MgO). The light was recorded with a photocell and oscilloscope, and its spectrum -was
measured with a Fabry-Perat interferometer. 7be gain of a weak signal In one passage
through the tro crystals reached 900. The condition of self "citation of the laser
Is described. The lasing -threshold is found to be practically independent of the
angle of inclination of the scattererp over a wide range, but increases with increaain
distance between the acatterer and Us crystalt The radiation line width was smaller
than 0.015 crr3- and was determinedby the resolution of the interferometer (the spon-
-taneous emission line width of ruby Is 15 cm7l). An investigation of the beat'radi&.~-,
tion.Aspectrum has shown that there are no frequencies characteristic of lagers with '-'
resonant feedback. The angle spread of the beam was proportional to the ratio of the
crystal diameter to the average distance between the mirror and the scatterer. The
distribution of the radiation field in the far zone was quite homogeneous. A pulse
with duration 200-nsec was obtained in the case of Q-switching of the stochastic res-
onator. The average frequency of the generated radiation in the laser with nonreso-
nant feedback was detexmined by the position of the center of the atomic transtRon"
and not by the resonance of the feedback. It is consequently possible to produce an
optical frequency standard on the basis of a laser with nonreeonant feedbac~jp using
high-gain atomic transitions in a gas discharge (Nep Xe, etc.) operating. in the con-
-tinuous model and also acatterers with narrow back-scattering directivity pattern.

C tilt'
AP6008754
It is noted thet generation with feedback due to scattering by inhomngeneities of tho
cryatal and by the matte side surface of the crystal can limit the maxima gain.
Orig. art* hast 2 f1gures, [021
SUB CODIt 2o/ sm Dais ogr"6/ OM RU: OW OTH PXF3 003/ ATD PRZSS:
Card

L 44793-66 1JP(C) W011WH
ACC NR. AP6031433 SOURCE CODE: UR/0056/66/051/002/0406/0411
AUT11OR: Ambartsumyan. R. V.; Basov, N. G.: Zuyev,_V. S.; Kryukov, P. G.; S_
Letokhov. V. .; 41!ptberas viii, 0. B.
ORG: Physics Ingtitute Im. P. N.-Lebodev. Academy of Sciences SSSR (Fizicheskiy
institut Akademii nauk SSSR)
TITLE: The structure of a giant pulse of a Q-switched laser
SOURCE: Zh eksper I teor fiz, v. 51, no. 2, 1966, 406-411
TOPIC TAGS: solid state laser, ruby laser, giant pulse laser, Q switched laser,
laser output
ABSTRACT: The spatial and temporal development of a giant pulse of a Q-switched rubyl'
laser in a transverse direction and the effects of the cavity on it were Investigated
experimentally by means of the setup shown in Fig. 1. A ruby rod 9 mm In diameter
and 120 mm long with dull lateral surfaces was placed in a reflector with a helical
IFK-15000 flashlamp. For an 8-kj pump the gain per pass was approximately 12. A
1.5-j single laser pulse was generated with a duration of 10-15 nanosec. Q-switchigg
was done by means of a Kerr cell or a vanadium phthalocyanin solution. The exponen-
tial results indicate that generation commences in the center of the crystal and
spreads transversely over the entire crystal in 3-10 nanosec, i.e., in a tir%e com-
parable to the duration of the integral pulse. The spat-.al development of generation
Card 1/2

ACC NR, AP6031433
~41
r
Fig. 1. The experimental setup
1 - Mirror 99% reflective; 2 - polar-
izer; 3 - Kerr cell; 4 - ruby cryst+
5 - lens; 6 - semitransparent plate;,-~
7 - screen with diaphragms; 8 - int4r-
ference filter; 9 - dull glass; %A'.
10-12 - coaxial photocells;
13 - multibeam oscillograph.
depends essentially on the density distribution of population inversion in the
crystal and on its refractive index. The experimental data agree fully with theore-
tical data presented elsewhere (V. S. Letokhov and A. F. Suchkov, ZhETP, 50, 1966,
1148). The authors propose further experiments on the measurement of nonuniformity
of the complex permittivity at the Instant of Q-switching and generalization of the
theory "or the case of a nonuniform refractive index. Orig. art. has: 7 figures'. IYK)i
SUB CODE: 20/ SUBM DATE: 06Har66/ ORIC REP: 007/ OTH REF: 006/ ATD PRESS: 5080
2/2 b1g

SOURCE: Zhurnal eksperimentallnoy i teoreticheakoy fizikis v. 51, no. 3, 1966,
724-729
1 and di
TOPIC TAGS: solid state laser, ruby laser, nonresonant feedback,,=---=.=-iL- laser r
ABS7RACT: A description is given of a pulsed laser with a no.,resonant feedback
achieved by back scattering of radiation (See also FSB, v. 2, no. 5, 1966, 1-6).
The arrangement used In the experiments Is shown In F1g. 1. The active medium
2
4 6 7
Fig. 1. Experime-ntal arrangement
ord 112
a r i
A
APL)U321W
ACC NP SOURCE CODE. 56/"6/051/00-3/0724/07
2y-
AMMOR; AmbartswVfin, H. Vo; Basov, N. 0.1 Kryukov, P. G.; Letokhov, V. 3.
ORG: Physics InrL'A*tute im. P. N. Lebedevi AcadcuV--of SelenceafSSSR (Fizicheskiy
instit-W-ARa-emli. nauk 605P)
s e r
TITLE: Laser th a nonresonwit feedback

L
ACC NRt AP6032h(;'(
conalats or two 'Mt)~~roda, 2 and 3, each 24 cm long and 1.8 cm In difureter with the
ends cut at the Brewster angle. 7be reedback in achieved by mervis of -mirror 4 (70%
reflective) and a volume or surface ocAtterer 1. The volume scatterer consists of
sulfur hydrosol particles with diameters not less than the laser wavelength which
are placed in a 15-cm-long cell with Brewater angle windows. The surface scatterer
is a layer of magnesium oxide sputtered onto an nluminum plate. The rest of the
experimental setup consists of a filter 5, a photocell 6, and an oscillograph or
Fabry-Perot interferometer 7. Experiments indicate that varying the inclination
angle of the actitterer between 0 and 600 has virtually no effect on the oscillation
threshold, which was observed to Increase with distance between the scatterer and thq
crystal. The sl,itial coherence length of the nonresonant feedback laser does not
exceed 0.25 mm. The laser emission is highly monochromatic and the frequency of
radiation is independent of the cavity dimensions. 7he line narrowing (to 0.005 cm-11
above the threshold for laser action depends on the resonant properties of the activ
medium. This pr\iperty makes such a laser a reliable optical frequency standard.
For this purpose it is preferable to use mixtures of gases ouch as Xe, Me-He, etc.,
as active media +,o provide a high gain per pass and a cw operation. Orig. art.
has; 1 figure w.il 4 formulas. [YKI
SUB CODE: 201 StmM DAM 21mar66/ ORIG REF; 003/ 07H REF: 005/ ATD PRESS: 5093
ea 'rd 2/2

lir , I - ;' i - -uc- -
u f
-L.1) --- TJF((,
C'NRF--,-A,P6o 35 SOMICE COM VP/0386/66/004/001/0019/0022
AUTHOR* Ambartawqun) R. V1; BaBoy) 0. 04; Z!MM-V. S. !~x ev P. G.., AjekhovL.:2~
n!t_j L
V. S.
ORIG: .119sics Institute 1FA, no Lybedey, Acq4cmy p-f-AqjSq~en Ma_L.Fizichealdy in-
atitut Akademii nauk SSSR)
TITLE: PrqMatlon of a 11 pulse in a-nonlinearly. arpiltying and absorbing medium
SOURCE: Zhurnal. eksperimentallnoy i teoraticheakay fiziki. Pialma v redaktaiyu.
Prilozheniye, v. 4, no. 1# 1966, 19-22
TOPIC TAGS: coherent Light, light pulse, laser beam, laser r and d, pulse ahal)e, ruby
optic material
ABSTMCT: This is a continuation of earlier work by the autbors (ZhETF v. 50, 23,P
1966), where propagation of coherent light in a medium with nonlinear gain was in-vesti-
gated and the possible shortening of light pilvea in such a medium predicted. 'The
present letter reports on successful experiments in this direction, showl%r that to
obtain coripresnion of a propagating light 1ALIze it in necessai-j to elildnate the trans-
verse structure that is produced in the light pulse when the latter is produced) for
example, by a q-awitchq laser. In the test setup (Fig. 1) the amplifying component
consisted of three rvbyj;-~crystals and the a~sorblng component was two cuvet-tes filled
with a solution of vanftdlum Phthal e n tolurne. In the initial experiments the
pulse compression cc-ula-in-o-f-R-r-eilIze bee use of the transverse structure resulting
Card

ACC NRl AP6023635
Fig. 1. Diagram of experi-I'
ment. 1 - TAcer, 2 - Kerr
shutter, 3 - cuvettej, 4
ruby crystal
from the fact that the dcrrelopment of pulse generation in the peripheral P&AG of the
crystal is delayed by a timo'Qf the order of the pulse duration. Success was attained
when tM3 structure was eliminated by means of a second Kerr shutter that cut a" the
leading front of the generator pulse. The pulse width was redu,:ed from about U nsec
(at o.5 T energy) past the Kerr shutter and the first absorbing cuVette to 5.7 nsec
(R) J) past the second amplifying crystal) and 2 nsee (15 J) patt the third. A light
oultPut of 7 - 8 GW 0 GW/cp?) van attained. The pulse power is much higher than the
power causing dama4ge in ruby cryot&la at 10-0 sec duration (1 GW/cM2). Although
dar,age to thq crystal is hindered by the short duration of the pulse, it does not pre-
vent generation of powerful light pulses shorter than 10-9 see. It is concluded that
e-,tr(.-nc3j short light pulses are obtainable with two-component media In which the ab-
norbing component has a saturation energy much lover and a homogeneous line width much
larger than the amplifying =di". Orig, art. hast 2 floves. [02)
BUD CODE- 30/ MM DM: 03YAYa/ ORIG MW 0031 OTH PXF: 001/ ATD PRMS
L & 2/g

ACC NR: AP7003209 SOURCE COON; UR/0056 66/05 1/006 /1 w_/1~7-5__
AUTHOR: Arbartsunyftn, B.V.;j~,ryukov,.P.G.; Letokbov, V.S.
ORG: Phyaics Inatitute im. Poll. Lebedevt Academy of Sciences 535E
(Fizicheskiy inatitut Akademii nauk SSSH)
TITLE: Dynamics of spectral line narrowing in a nonresonant feedback
laser
SOURCE: Zh eksper i teor fiz, v. 51, no. 6, 1966, 1669-1675
TOPIC TAG9: solid state laser. ruby laser, fee
laser lml"~
ABSTRACT4-The authors proceed from rate equations for the spectral density of th
.photons and for the density of the active particles. The time-depende:t
line width Av, is expressed in terms of exact solutions through numericall
integration, and also in terms of a simplified formula which shows that
Av; after an initial transient-state period, growe roughly as k/vf-h
(k--threshold gain per pass), toes) much more slowly than in lasers wit
resonant feedback. The experimental part of the paper deals with the
1/2
none

ACC NRs AP7003209
,spectral analysis of the emission'-Of a nonreionant feedback ruby laser by
the method of the Fabry-Perot interferometer and the rotating-mirror
spectrograph. The parameters of this laser were described earlier
'(Ambartsumyan, R. V., N. G. Basov, P. G. Kryukov, V. S. Letokhov. ZhETF,
.PvR, 3, 1966, 262; ZhETF, v. 51, no. 2, 1966, 724). The observed values
of the spectral width are shown to confirm the theory. White paper and
magnesium oxide were used as surface scatterers, and smoke and sulfur
,hydroaols were used as volume scatterers. With smoke the threshold gain
:pass k was naturally very high, and narrowing (to 0.03 cm-1) occurred
quite rapidly (in 100-300 psec).
SUB,CODE: 20/ SUBM DATE: l9jul66/ ORIG REP: 005/ OTH REP: 005
ATD PRESS: 5113
2/2

T1. 1. 1 "r- 6A / I I - '_ I _i__1 -- - 1~ - r I - ~''
-Ay~j _FiFt
ACC NRj
AP6011277 SOURCE coDE.' UR/04-13/66/000/006/0137/0137
INVENTOR: Kryukov, P. 1. ; Chugunkov, V. 1.
ORG: none
TITLE: Method of grinding and polishi_qg of curvilinear sections. Class 67,
No. 180108
SOURCE: Izobreteniya, promyshlennyyeobraztsy, tovarnyyeznaki, no. 6, 1966,
137
TOPIC TAGS: grinding, metal polishing, jet vane
ABSTRACT: This Author Certificate introduces a method for grinding and polishing!
jet vane sections using a grinding belt and the short -hue contact method.-To eliminate
profile unevenness caused by moving of bases, residual and elastic deformations
occuring during the treatment process, the part being worked on is given an
additional degree of freedom. It rests on a supporting roll with a premachined
surface. LD)
SUB CODE: 13/ SUBM DATE: 0lJul631
wd 1 / 1 0 (1- Ot/ mc: 621.923.1:621.924.24

SCHTJLZo X.I., prof essoro doktor; TUXOT I inshoner [trans2ator];
-JUL v rl
XIUXXO, 8.79, rodaktor; AgIX;.uaV"I'.LZrlr.",&':rodaktor; TAROT, I.X.,
takhnichookly rodaktor
[Xllk that keeps weU. fteas2stod from the Oormau] Stolkoe moloko.
Forevod 9 noustakogo F.I.KrIulcival, ftd red. B.FoXivoukoe Xoskvag
Mehobspromisdati, 1956o 106 p, (NLPA 10:1)
(Xilk)

AZBELI., S.M.1 ZAIKIN, N.I.j_APgOVj_Pj.j SAVINt I.M.; NOVIXOV9
V.F., insh., reteenzent; KHARLAMOV, P.G., insh., red.;
VORDTNIKOVA, LA,-takkn. red.
(Repair of failures of the CbME2 diesel locomotive] Ustrananis
asispraynostai toplovosa ChH92, Moskyap Tranesholdorisdat,
1963. 53 p. (MIRA 160)
(Diesel locomotives--Maintenance and repair)

_'XRTUKOV, Petr Sergeyevich; VADEM, 0., redo; DANILINA. A., tokhn.red.
(This must not happens against Imperialist plans for an ato2io
wail Xto no dolshno proisoiti; ptotiv imperialistichoskikh
planov podgotovki atomnoi voiny. Moskva, Gos.izd-va polit lit-
1959. 46 y. (Mlil 12:51
(Atomic weapons--International control)

,I _r-
- KRYUKOV, R :j_J n2h.
N
Ipartment bouse built of prefabricated
Ifosk. I no,9:11-14 5 138*
(14oscow--Apartment houses) (Precast
room-blocks. Na stroi.
(MRA 11:12)
concrete construction)

-IRIgKOVI_~. ~., Cand Tech Sci -- (diss) "Basic problems in the tech-
nology of manufacturing in an upright position thin-walled safety
frameworks for apartment houses." Moscow, 1960. 18 pp; (Moscow Higher
and Secondary Specialist Education RSFSR, Moscow Order of Labor Red
Banner Construction Engineering Inst im V. V. Kuybyshev); 160 copies;
price not given; (KL, 29-60, 125)

SARAPIN, Iosif Godelevich, kand. tekhn. nauk; Kg;grKgv- " , kAnd.
tekhn. nauk, nauchnyy red.; YEMOI(AMUL, M.D., red.lzd-
va; GOLIBERG, T.M., tekhn, red.
(Manufacturing keramsit-conerete wall panels for completely
prefabricated apartment houses] Proizwodotvo keramsitobeton-
nykh atenovykh panelei d1la polnosbomogo domostroeniia.
Moskva, Goostroiizdat, 1963. 134 p. (MIRA 16:8)
(Walla)

M.N.., kand. tekhn. nauk; YRT;K011, R.V... kard. tokhn. nauk;
PEYSIKGVP V.A., inzh,
Mobile shield method for molding large panelB. Stroi. i dor.
mash. 9 no.1:24-28 Ja 164. (MIRA 18:7)

"I
KRYUxOV, B. 1. Cand Tech Sci -- (dies) "Selective dimerization of propylenes
and syntheses based %ipon It." Yaroslavl', 107. 12 pp incl cover (Ma of Higher
3duo&tIon USSR. Yaroslavl# Toohnolocia4l Inst), 125 ooplas (Mu. S,53. 0?)
-24-

vil
Os Oil

A~THORS# Farberoy, M. I., Machtina, K. A., Xryukov, S.I., 20-1U-4-35/63
TITLEt Two bethods for a Commercial Scale 1'roduotion of Ilethyl-
pentadiene (DVS metods tekhnicheekogo sinteza matilpentadi-
yona)
PIRIODICALo Doklady Akademii Nauk SSSR, 19571 Vol- 114, Nr 4,PP- 807-81o
(USSR)
ABSTRACTs Hitherto mothylpentadione is a commercially little aoasssible
diene. The only method of some technical value was proposed by
American authors and produces nethylpentadiene from acetone.Be-
cause of the properties of its polymers and oo-polymers methyl-
pentadieno is of a certain interest. The present paper describes
two methods of its technical synthesis. 1.) The authors thorough-
ly inyeatigated the interaction reactions of olefines with al-
dehydes, Thus the chief reaction product from the interaction
of isobutylene and acetaldehyde in the presence of 1-2%p sulphur-
io acid in 294P4,6-tetramethy1dioxans-i93 (denoted TXD/I/ in the
followingo 9o% yield of the aldehyde reacted through). Publish-
ed works report that the alkyldioxanes-1,3 may be serve as ini-
tial substances for the dion6synthesis. The authors' experi-
Card 1/3 ments proved that by the passage of TO with vapor over a o&.

Two Vethods for a Coamercial Scale Production of Uthyl- Z."
ptntadieno
"alyst, ustapenta.419ne witb & 75% nol. yield ,f
04 TXD/I/ in obtained. On this occasion two isonio-y-ic dienes
d:vsloys 2-m*tbYlV#ntadI*nQ-193/II/ and 4-methyly*ntadiens-
I 3/Ill/, Their pbjsiaal p"pertiot art very siallar. Their
quantitative determination in the mixture is based upon their
different behaviour towards maleic anhydridei 11 given an ad-
duct, III a co-polymer. In the presence of Inhibitors the po-
lymerization inclination of III may be suppressed, so that it
can be separated from 11411 and III were obtained in the pro-
portion 45155, Beside methylpentadiens a small amount ( ) of
a mixture of two isomeric methylens pentanoles (IT &am T re-
sults from contaot cracking. There oocurs also a cracking r4-
action of 1. giving the original substancess &oetald*Wo and
isobutylens. A diWaa of contact cracking of TXD/l/ in dJme in
given in the paper, The water apparently participates in the re-
action and favours the hydrolysis.of I into an Interm*diat* di-
ol on the surface of the catalyst. In the moment4of its forms. -
tLon tr dehydration under liberation of one or two water mole
cules and under according formation of a aixture of two isom;ric
methylpontanolon IV,V or diense 11,111. 2) The second technical
Card 2/3 method of methylpentadions synthesis is the dehydration of the

Two Nothodsfbr a Commercial Scale Production of Xethyl- 2o4lk-4-35/63
pentadione
propylen*-dimero 2-methylpenteno-1/VII/. The expe-iments with
catalytic dehydration of VII show that zeth.Tlpontadiene can be
produced in this manner, Here# too a mixture of the isomers
II and III is obtained in about the same amounts and with a
yield of 35o38% of the VII sent through and 70-75% of the VII
decomposed. There are 2 figures, 2 tables, and 11 references,
4 of which are Soviet..
ASSOCIATIO11i YAM1ATI'Toohnologioal Institute (Yaroolavokiy tokhnologiohookly
inatitut)
PRESERTIDo January 15, 1957 by I. N. fiazarov, Member, Academy of
Sciencest USSR
SUBXITTZDj November 14v 1956
Card 3/3

AUTHORBs XgZ_qkgX,. S. I., Kut' in, A. M., Levskaya, G. S., 153 -58-1-13/29
Tepenitayna, Te. P., Ustavahchikova, Z. F., Farb,~rov, M~ I.
TITLE: An Improved Method of the Synthesis of Triethyl-Aluminum
(Uluchahennyy sposob sinteza. trietilalyuminiya)
PERIODICAL: Izvestiya vysshikh uohebnykh zavedeniy,
Xhimiya i khimichookaya takhnologiya, 1958, Nr 1,
pp. e6-93 (ussn)
kBSTRACTs The authors give a survey on the publications of trialkyl-
aluminum as specific catalysto both alone, as well as with
cooatalysts for olefinio polymerization (references I to 3),
and they compare with each other the known methods of
production of aluminum-grganio compounds (references 4 to 6).
The authors selected the method by Grosse and Meviti
(MavitYt ref- 5) as the moot convenient one. A)- Production
of ethylaluminum seaquiohloride (mixture of ethylaluminum-
-diohloride and diethyl-aluml-num-cbloride). The first stage
of the process according to reference 5 proved to be rather
incomplete. It is difficult to be controlled, has a long
period of induction and often lead@ to the complete
Card 1A destruction of the products, sometimes with explosion. The

An Improved Method of the Synthesis of Triethyl-Aluninum 153 -58-1-13/29
authors tried various initiators at atmospheric pressure
(crystalline iodine, othylaluminum-gesquichloride, ethyl-
bromide and a mixture of these substances). Table 1 shows
the influence of individual initiators on the period of
reaction. Ethylbromide acted most efficiently. Table 2
shows the influence of the initial temperature with the
supply of ethylohloride on the reaction-period. Optimum
conditions for the carrying out of the process were selected
from the obtained test results. Further tests were carried
out on an enlarged plant (figure 1). The laboratory.results
were confl rmeds It was possible to reduce the reaction-
-period to from 2 to 3 hours. B)- Reaction of symmetrization
of ethylaluminum-sesquichloride. In order to obtain tri-
ethylaluminump the above reaction must be carried out
with the participation of metallin sodium. According to
reference 51 various insufficiencies exercised a disturbing
effect in this connection. The authors found the conditions
for removing themo I)- Sodium ought to be used in fine
dispersion, the surplus of Na must not exceed 5 to 10% of
the theoretically required quantity. 2) - sesquichloride
must.be introduced in portions as a 20 to 30% solution in
Card 2/4 hvdrocarbons. 3) - The temperature of reaction must not

An Improved Method of the Synthesis of Triethyl-Aluminum t,153-58-1--13/29
exceed 1300 and an intense agitation should be guaranteed.
The gasolinetraotion "galosha" (boiling above 1000) proved
most effective among soveral tested solvents. The yield of
triethylaluminum, amounted to 70 to 76% of the charged
sesquichloride under the selected optimal conditions. A
certain quantity of partly oxidized triethylaluminum was
proved in the produced triethylaluminum. The inactive part
of the catalyst formed a mixture of all 3 possible ethoxy-
-compounds. An experimental part follows. C) - Production
of aluminum se9quichlorides According to the method described
here, a 99% yield of that theoretically possible was
obtained. The two (paragraph A) components were present in
the mixture in approximately squimolar quantities. D) -
The reaction of symmetrizatioA was carried out in a device
shown in figure 3- A filter required for this purpose is
shown in figure 4-
There are 4 figures, 2 tables, and 12 references, 3 of
which are Soviet,
ASSOCIATIONt Yaroslavskly tekhnologiohoskiy institut I opytnyy zavod
Card 3/4 Ministerstva khimicheskoy promyshlonnosti. Kafedra

An improved Method of the Synthesis of Triethyl-Aluminum 153-56-1-13/29
tekhriologii ounovnogo orgadahuakogo Gintoza i Ljr
(Yaroulavil . - - - -''. ~ .,I I - I., Technological litatitute and
the Experimental Plant of the Ministry for Chemical Industry.
Chair for the Technology of General Organic Syntheeia
and SK)
SUBMITTEDi September 23, 1957
Card 4/4

S/O81/60/0oo/oo-(/oo5/o12
A0061AOOI
Translation fromit Referativnyy zhurnal, Kh1miya, 1960, No. 7, p. 189, # 26523
AUTHORS: Kr"jukov. S. I., Farberov, M. I.
TITLE., Methylpentadienlynthesis on Propylene Base
PERIODICAL: Uch. zap. Yaroslavsk. tAekhnol, in-ta, 1959, No. 3, Pp. 21-33
TEXTt 2-methylpentene-I (1) -is easily obtained by d1meriznion of
propylene according to Talgler; It is dehydrated into methylpentadiene (11) In
the presence of a K-16 catalyzer (preparad on the base of metal -oxides and 0
additionally heated for 1.5 hours at 830 C). Under optimum conditions (500, C
volumetric rate 0.6 1 per 1 1 of the catalyzer per I hour; molar dilution by
vapor I : 12) the following substances and the yield peroentage pt%r decomposed
I, were obtained; 11, 71.8; Isoprens, 3.4; Isobutylene, 6.4; propylene, 2.3;
higher hydrocarbons, 2.6. Changes In the temperature conditions of the reaction
reduced sharply the yield of 11. Kl~ and K18 eatalyzers yielded less satlsfac-
tory results; changes in the volume ric ra e had only a slight ef"fect on the
Card 1/2

Methylpentadione Syntheato on Propylene BAso
s-r/081/60/000/007/005/012
A006/001
yield of II; a greater effect was exerted by changes in the amount of diluent
vapor. Thermodynamical calculations of the reaction are given.
L. Shchukina
Translator's note: This is the full translation of th,!, originad Ruseian
abstract.
Card 2/2

-S/081/160,fto/o 17/013/10 16
A006/AO01
fr-.T,, Referativnyy zhurnal, Ehimiya, 1960, No. 17, P, 372, 170452
Yrvuh,;V- S.I..,Kut 1y1n *L A.M., Loevskaya, O.S., Tepenitsyna, Ye.P,,
Uslavehchi a, Z.F.., Farberov, M.I.
?SyntheS45
.iz 7e.,hnical Mcde of Trlathylalumint=
FE~:OICAL- U:h. zap,, larosllavak.,tekhnol. In-ta 1959, Vol. 3, PP. 5-17
TEXT." rhe devels;ed a technical mode of prepmring ethylaluminum-
10 wi-h a yield :f about 100% cn the tas1s cf a method dezeribed
A.U,, Majity, J.M., Organ. Ch,~-n,, 1940, N,-. .5, p. 196) 'which consists
in !---era:*.1:n .:,f C2H Cl (1:) and Al ir. the presence of 5-10% C2H Br (III)
1 5 "?ators yield-
wl-*h r~.O'a!.!:n -: Al. 12, (1) and their mixtures were tested as Init,
i.na ~neatisfa:t~ry resjl*,z. ~-t is assumed that the prc-ess 1B initiated by inter-
X~Aia-~:y f-rm!ng el~tylaiurrinirnsesq,,iltr~,mide, in 'he case that III Is 1;sed. I is
~.ran;f-r:ro~l n- 12F5 )3A! (ZV) by pr,,ce3sIng with dlsper~ed Na metal in organic
~7~,'*~-:~- (tznzin-r~-ittsr, reflne,l kerosene, xylene, iv-cctane). Na is taken in
lln-,- the rea~,~!;,n by p~,rtlcnz In the fcrn cf

3/108 1/160/tw/t 17AIL3140 16
Y:J~ *f :'rvi-ty!.a;.imin,.im Synthezis A006/AO01
the yield of V1 is 70-76% in relation to I, and
Al. All *.he experiments are carried cut in dry N2
s ;nere fr4? -!A of Arr-:,.ints of 40 g Al and 24 g 1:1 are heated, while stir-
jC g (11C%' I' Is al-isd by portions of 10 ml., the react,
5C'C vi 16 cn
a_t 8 1 iG5 -~:._Ialned in t-he form of a colorleEs or slightly colored
trr- yt,7.3 i-i 99%, bciling temp*rature 117-122'0C/,50 mm, - in ICO g of '~he
~?q g Va 1. ~ej,94 ar 1(>OOC, 4nt-) the hot dispersion 91,4 g Is added
d~rlna 2C T,:r in -he f::rm cf a 30% solution in benzi-ne-rubber (boiling temperature
rr~_-red `:r 30 minl;tes at 105-110oC and filtrated, the precipitate is
wa,' hed wl,h 2.50 T.: cf .3:1vent; IV is obtained In the form of a colorless liquid,
_'n alr rhe yield In 12 the boiling temrerat-jre 100-107cC/
ee 1~ .5 9 o
10 mir, d 0.872. The ailhcrs present two tables and schematic diagrams cf metallic
appars,us -Ln4. eqil;ment lnclAdlng descriptions.
S. Davydova
11"ransla-:-1 6 nz!-e '7h!5 is the full translation of the original Russian abstract.
Card 2/2

0
/62/035/010/000/012
"/080
D204/U307
ixyukov, ;.I. and Farberov, I.I.I.
.,otic syathcrea based on 2-methylpentene-1 (I)
'1UiJ1(;"L: '"'liurnal )ril:ladnoy ItWiii, v. 35, no, 10, 1962,
22;19-2-*;;!4
a" 1'. T 11ropylene dimerized staooilily at 200 - 2200C, under
100 120 atm, , uith Al--.'t3 (*,isnolved in iso-octance as the catalyst,
over a period of 1.5 hotirs, in nVarly qUaRntitative yields. The pro-
duct, 1, was dincrized at 500(;V 70';! 112304 48 the catalyst in 30 min
(O.ninun conditioiis), in up to , 80,~ yields w.r.t. the wcl~ht of the
startin,r ..iatcrial. The dincrization of -I may also be carried out
ci I/
-7itll 113;.'(J3 on hicaelguhr as the catalyst, at 120 - 1600C, under'20
U
atm pressure, the hi~',hnst yield of the tatramer being - 50cla. In
looth cases the conversions -jere practically quantitative, calculated
on reacted 1. Ihcn 401; 11-2,;04 was used as the catalyst, I did not
dimcriza', Init und(,ruent a *highly selective isomerization to 2-methyl-
vcnteiie-2 at 25 - 300j, over a period of 2 hours. This reaction
Card 1/2

S/080/62/035/010/008/012
Some syntheses, based or. D204/1)307
also proceeded rca-dily in the presence Of 113P(J3 on 1,,icsclguhr, at
120 - 1400ki, under a pres-sure of 10 - 30 atm; the conversions being
nearly quantitative in both cases. At 10 - 200C, in the presence of
1',',)SC)4 and water, I was hydrated to 2-methylpentanol-2 over 30 min,
w1th a nc~-.rly 100,~ cotiv,--!rsion. lith C1120t I condenseA at 5000, in
the presence Of 112:;01~, to give (in 30'1" yield) 3-methyl-3-n-propyl-
dio::an,-1,3, over j hours. I was also used0to alkylate beiizene,
toluene a-Lid phenol, ovcr 112904, at '10 - 15 0 in ;Ood to excellent
yields. The alkylation of'tolucnc with 1, over `11C13, was less
effective. Thcrc arc 3 figures and 1 table.
ASJACUNON: Yaroslavshiy telchnologicheakiy institut i nauchno-
issledovatellskiy institut monomerov dlya Sk (Yaro-
slav Technological Institute and Scientific Research
Institute of Nonomers for Gynthetic Rubber)
~X31:ITT:,D: July 13, 1961
Card 2/2

s/2o4/63/003/001/003/013
E075/r.436
AUTHORS: Folldblyum, V.Sh., Komissarova, G.P., blyasnikova, L.D.,
Farberov, H.I.
TITLE: The synthesis of isoprone from propylene. 1. Analysis
of aluminium alkyls in the process of dimerization of
propyleno
PERIODICAL: Neftakhimiyat V-3, no.1, 1963, 13-19
TEXT: The aim of the work was to investigate the methods for tho
analysis of activity and composition of aluminium alkylx. The
analysis consists of determining the ratio of the "active"
alumirMm in AlR3, where R - an organic radical, to total Al~
The methods used to determine the "active" Al were: 1) the indicator
method of Razuvayev and Grayevskiy, 2) the Ziegler anunoniacal
method, 3) the Tepenitayna-Farberova oxidation-reduction method,
4) decomposition of AIR3 with H20 with the subsequent measurement
of the evolved gas volume. . The first two methods gave correct
values of the activity but are tedious in operation. The authors
improved the Ziegler method by using di- or trimethylamine iA place
of N113, which greatly decreased the analysis time. Examination of
Card 1/2

The synthesis of isoprene
5/204/63/003/001/003/013
E075/E436
AlR3 used several times for the catalysis of the dimerization of
propylene showed that the first portion of the higher hydrocarbons
(byproducts) forming during the reaction attach themselves to Al,
or displace a part of' the lower alkyl groups in A1113. Thus AlR3
uscd aoveral times as catalyst is a complox mixtura of aluminium
alkyls, the molecules of which contain propyl And inobutyl groups
and at least one C9- C12 group. There are 2 figures and 2 tables.
ASSOCIATION; Nauchno-issladovatellskiy institut itionomerov dlya SK
Yaroslavskiy tokhnologicheakiy instiWt
(Scientific Redearch Institute of Monomers for
Synthetic Rubber, Yaroolav,Technological Institute)
SUBMITTED: June 9, 1962
Card 2/2

S/2o4/63/003/001/004/013
E075/6436
AUTHORS:, Folldblyurd, V.Sh., Kryukov, S.I.-, Farberov, M.I..
Golovko, A.V., Tyurja_YiW-'_1..Ya., Pankov, A,G,
TITLE: The synthesis of isoprene from propylene
2. Isomerization of 2-mothylpentene-I in the liquid
phase in the presence of solid acidic catalysts
PERIODICAL: Neftekhimiya, v-3, no.1, 1963, 20-27
TEXT: The object of the work was to isomerize 91.4% wt. pure
2-methylpentene-l in the liquid-phase using silica-alumina,
cation exchange romin KY-1 (KU-1), pho~4phoric acid-kieseiguhr,
alumina and silica Sol as catalysts. All experimonts were carried
out at 100 and 1500C and at 75 to 125*C with KU-1 as catalyst.
The isomarization is complicated by three secondary reactions, the
main of which is the formation of dodecene (dimerization of
isohexenes). A small amount of cracking gives amylencs
(especially at the higher temperatures). Thore is also formation
of small amounts of various isohexones. Silica gel and alumina
were the least active catalysts. *1ith the rentaining more active
catalysts the velocity of the main and secondary reactions was much
Card 1/3

S/2o4/63/003/001/004/013
The synthesis of ... E075/E436
higher, the increased temperatures favoring the formation of
do-decene and--decrea sing_ the -yiel-d-of --2-methylpentc ic-2.
Isomeriza fi onof 9---me-thylpentene-1 W-to-2-methylpentene-2 (D)-
with the formation of dodecenes (A24 AD and B2) proceeds as follows'
K Kl K2 K3
A ___4 BI 2A ---) A29 A + B ---I A B 2B --) B2
The relativo values of K and KI, K2, K3 depend on the proton
acidity of the catalysts. Thus their effectiveness may be
obtaine4 from all these values. The catalysts were rated in the
order of increasing activity:
A1203 ~~ S102 < silica-alumina < 113PO4 - kieselguhr ~~KU-l.
The effectiveness of acidic sites increases in the order
KU-1