SCIENTIFIC ABSTRACT SPASSKIY, N.YA. - SPASSKIY, S.S.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001652630011-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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s Luden t's for ra s Two th~i qualifications of Por'~wxlyl and
kcrally SS~O'H,; ucliebitue
"!'a -,aorhrz,,Ich frz-upp pmyohmnlia kvai-,kri,n-,qtz;j-l
siwhikh I im., hene,,, --io- Le;~ ~m i -,-he sk i kh rabouilili,,
4,~ I I)

SPJV3SKIY"O.V.;l

SPAESKIYI.-G.V. I ~ I ~ 1 7
2

--p 7~= T' T7 T
USSR/Mathematics Automatic regulation systems
Card 1/1 Pub. 85 - 611P
Author Spasskiy, R. A. (Leningrad)
Title A class of regulated systems
Periodical n ikl. mat. i mekh., 18, 329-344, may/Jun 1954
Abstract Treats one of the critical cases of stability:of motion that are
encountered in certain systems, ofautomatic~r.egul~tion. In.,ordei
to construct the Lyapunov function the author starts vith the:re--.
zadachi,
sults in A. I. Lurlyels'book Nekotoryye neli~neynyye:
teorii avtomaticheskogo regulirovaniya [Ceriatin nonlinear.
problems of the theory of automatic regulation], GTTI, 1951
utilizes the -orks of I. G. Malkin, N. P. Yekugini and A. M. Letov,
all in PMM, 1950-1953.
Institution
Submitted January 25, 1954

SOV/124/58- 8- 8408
Translation from: Referativnyy zhurnal., Mekhanika, 11958, N r, 8, p 10 (USSR)
AUTHOR: Spasskiy
RA-:-
TITLE: A Special Type of Control Systems (Osobyy vid~reguliruyemykh
sistem)
PERIODICAL: Uch. zap. Vyborgsk. gos. ped. in-t, 1957, 2, pp 3- 14
ABSTRACT: A generalized examination is made of ainonlinear control sy:stem
in which the characteristic equation of the :"linear. portion" contains
an arbitrary multiple of the. zero root. The system is reduced:to the
canonical form. The conditions of the uniqueness', of the position of
equilibrium are determined. To investigate the- system's stability,
the author sets up a Lyapunov function. 'A~hat is distinctive about the
investigation is the fact that a finite region' of the, phase space is
divided into two portions, in one of which the derivative of the
Lyapunov function equals zero, while in the other part it is: positive
A general method is given.forIdetermining the conditions sufficient
for asymptotic stability in the case of a control 'system of this
special type.
Card 1/1 Ye. P. Popov

AUTHOR:
TITLE:
FEITLIODICAL:
TEXT:
19020
S/140/62/00 0100410091009
C111/C333
Spassk~y
On a control.system with auxiliary energy~
Vysshiye uchebnyye zavedeniya. I zvestiya.:! VatesgaAika,
no. 4, 1962t 146-151
Considered is the syatem
M
,K7
Uf 6'
p- r
b n
s
ij,j 5i s s
where fs(~

SFASSKIY, S.A.

ISPASSKlY, S.S.

Sn~SKIY~ S-~,. (btsk-Ta)

AUTHORSs Nodolov) V, I.P.:

S S

aides 4j' diphettic, arid, -5j.
tructwo DU I ar
01 4711,
~;ITGM, Chem,. MS-5.1 j- sg;,
,
111.
u c J 43 331
-71

v

I ly&-i

68949
's-ayj 0 SOV/8l-~59-24-88951
Translation from: Referativnyy zhurnal. Khimiya, 1959, Nr 24 p 643,.t(USSR)
AUTHORS: Tokarey, A.V., Spasskiy, S.S.
TITLE: An Investigation of -the C olymerslof Poly-1,3-B~utylene'glycolfuma.rate .
and Styrene~
PERIODICAL: Tr. In-ta metallurgii, Ural'skiy fil. :AS USS 1958,. 'Ni 4, pp 12T- 132
ABSTRACT: Diagrams plotted of the integral.and~differentiAl c6mpbsition of,tfii~ co-~
polymers show that in the case of'the initial the monpmeri, whicli
differ from azeotropio ratios, the reaction miiture,liehriched1nityrene.
The dependence between the structure of copolymers and their me6hanical
properties was studied by means of Kargin Is T'e~hod bk~ed on the; plotting: of
thermomechanical curves on which the polystyr%ne r4
ions can be detected-
The samples for the test were prepared by bloqkpolim~rization inlah~.N
atmosphere in the presence of b6nzoyl, peroxidii At 709C various :iniiial..
ratios of the comDonents. Together with theltrimera.lso1inear.poly-
styrene chains are. contained in the copolymer'.~ . at~ the same time also co-
Card 1/2 polymers are formed which are relatively homogeneous :!'in their composition

:-~i V':-
. I I I .. . . I I ; i: . ; i i
- - 1. . : I I . : - ,- . , . z - t i . 5 '. , , 4 ~ ~

66910
~
S Suvorov, A. L.? Spasskiy, S. S. !30V/74-28-11-1/5

TITLE: um~(
Organic Titani Compounds

PERIODICAL: Uspekhi khimii, 1959, Vol 2 8 Nr 11, pp 1267-1~99.~ (USSR)
ABSTRACT: The chemistry of organic titanium,compounds hasibeen
"
the presents
considerably developed in the last 10-15 years.~~In
paper, an attempt was made to summarize and systematize the.
data available in this field. Substances containing titanium
with at least 1 organic radical are dealt with more-thoroughlyi.

ps.
All organic titanium compounds may be divided into" 3 grou'
1) Compounds containing titardum-carbon bonds (real organo-
titanium compounds), including the bis-cyclopen~'adienyl
compounds of titanium; 2)-compounds in which theiorganic radical
is combined with the titanium atom byelem~nts such as oxygen,:
nitrogen et al (esters and amides of titanic acidal,mixed:
anhydrides of titanic and carbox-jlic acids~'!etc); and 3)coorAineitim
compounds of inorganic titanium compounds T~ith,organic
molecules. In the present Daper) mainly con~pounds,of the
largest, the second group, are dealt with,,aaa the Ist group is
mentioned briefly. Coordination compounds:axe not,discussed.
'Card 1/5 Methods of Preparation, Dhysical and chemical properties of

66910
Organic Titanium Compounds- Sov/7 _~8_11_1/5.
4
acid esters or dialkoxy-titanium-oxides i0) Ti6 are substance's
2
little known (Refs 113, 1239 154! 187)- Es ters of the
titanous acid or trialkoxy-titanium. compounds Ti(6R) are
7 3
obtained.on reduction of alkyl-ortho-titanium compounds with
metallic sodium (Ref 79) or Potassium (Rek-154YIn alcohoL
m-Dound , 'the pol
From-among polymeric organic titanium co [ s ~Y_
titanium oxane compounds are best known *ilch cbntain-an~:
inorganic chain of titanium and oxygen atoms surrounded by
organic groups. So far, only a few hezaalkoxy-dititanium.
oxanes (Refs 187,- 186) and ocitaalkoxy~trit,itanium oxanes
(Refs 62i 187) have been isolated- Farther* poly6rganosiloxane-,
titanium oxanes are known wh'lch.~;& polytit'anium,loxanes (I),~
and the chains of which are -Mirround-ed by,i trialkyl(aryl) 4
siloxy groups; and also polyorganotitaniulp~sil6xanes (II):
containing an inorganic chain of titaniumpisilicon and
oxygenatoms surroundedby organic groups* Fewidata:are
available on polymers obtained by polymerizatio'n,or
copolymerization of some unsaturated organic titanium-compour0s
(Refs 62, 76, 7T, ~88, 94, 95, 92, 1,18-120' 1231-.;113, 136? 13T,
Card 3/5 141-143, 151, 169, 171, 167-214). Organic.- titanium compounds

66910
Organic Titanium Compounds SOV/74~~2 B-11 -1/5
are not yet as widely used as e.g. organosi-licoil compounds'.
But the investigation.of their applicability which is mainly
described in patents-indicates a considerable.practica6~
importance of these compounds. Ortho-titainic acid"esters may.
thus be used for the production of heat-resisting.coatingsi:
(Refs 83, 88, 89, 94, 118, 119, 121, 129, -136, 1:37, 200,
215-222) as cross-linking agents (Refs 141~7-143, ~212, 223-2414
as hydrophobic agents (Refs,779 181-,-201-2~4, 2682 242-249Y
and as catalysts in the polymerization,and. interchange of
ester radicals (Refs 250-263)- Various other-possibilitieslof
application have been described in*-references 77, 193, 203,
229, 236, 264-274. The following Soviet scientists are
mentioned in this-survey: G.Y. Luchinskiy';V. k. Pletsq A~. _N.
Nesmeyanov, R. Kh. Freyd1ina 0. V. Nogina,~ G. A.; Ravuvay
L. M. Bobinova, V. S. Etlis, A. B. Brukeri:,R. 1~ Frenkellp
L, Z. Soborovskiy, E. It. Braynina, B. A. Arbuzov,. To G. Shavsha,
N. F. Orloy Voronkov,I.K. A. Andrianov,
B. N. Dolgov, M. G
V. G. Dulova, T. N. Ganina, Yu. N. Andreyev V.~A. Nik kiyo
There are 1 figure, 10 tables, and 274 references'. 46 of
which are Soviet.
Card 4/5

5W
AUTHORS: S k S S., Tarasov, A.I, To SOV'76-33-2-2/45
karev"A.V.
_
_
TITLE: -copolyr:,,
eri
za`E-1on of Unsaturated Polyesters and, Vinyl Monomers
(Sopolimerizatsiya nonasyshchennykh poliefirov s vini Ilovymi
monomerami). I. Determination of the Ndmber~of.Double Bonds
in Copolymers of UnsatUrated Polyesters anUVinyl Monomers
(I. Opredeleniye chisla dvoynykh svyaz6y v sopolimerakh no --
nasyshchennykh poliefirov i vinilovykhl~monomiierov)
PERIODICAL: Zhurnal fizicheorkoy khiziii, 195,03, Vol, 3 3, Nr; 2,
pp 249 254 (USS-71)
ABSTROCT: Although there copoly-mers represent nei, theT'mally reactive-
synthctic materials the principles involved;.in their copol'y-
merization have not been sufficiently. investigated. The
po3sibilities of applying tyto metho.ds,,T;based on the a,dditivit:T
of the specific volumes and of the sDe6ific:r6fraction-s'
were investi--ated. The following, sy tems rere used in checkin,.'r
the methods: polydiethylene glycol fumarate;- acrylonitrile-
polydiethylenc glycol fumarate M - styrene;,~ (I),-methyl
mothacrylatc; (I)-vinyl acetate. Lrtbor~toryjvTorlcers M_A.
llikhaylova, T. V. Liolchanov
a, TM. K. participated

13
C
ar d

n t he c xr iti en t r, . T1h c c o p o 1 y m c r i z at o nwas carried out

Copolymer4zation of Unoa-turated Polyesters and Vinyl SOV/76-33-2-2/45-
Monomers. I. Determination of the Nu:rbcr of Double 3onds :in Copolyners of
Unsaturated Polyesters and Vinyl Mononers
in glass ampulc in the presence of 0 11'~ by I-, e. 4 e:, -t bezizoy~
peroxide in a nitrogen atmosphere an~ at 60+0150C. The
index of refraction was determined using an~Abbe refracto-
meter. The ziao-nitude of the specific shrinking of the poly-
ester chain was determined by proceeding upon.the as~ump~ti=.
(Ref 7) that the shrinkar,-e of the mohomer6.in the polyme.ri-
zation (contraction) is dependent upon their structures.! The
styrene-methyl methacrylate system was tested using the
rule of the additivity of the specifi IC volumes (Table 2).
The contraction was determined from the specific volumes, of
the diethyl fumarate (IT) and polydi6thyl~fumarate (Iii)~
using the equation P SP ) (P-- contraction, 1-5-- MO
F
lecular weight Of (I SF &PF specific volumes of. (.IT)
and (!IT)); the value found was 16-7.1 The ispecific shrin.kage'..
for the chain of (I) was found to be;iO.08971~ The deter-
mination of the increments of the monomer~~d'ouble bond wa's
C' a Value
carried out using the specific refra tion:Oabie
Ca.rd 2/3 of 0.0144 was found for (I). The results obtained by:both

Copolymerizat ion of Unroaturatod Polyesters and Vinyl SOV/76-33-2-2/45
Mlonomers. I. Determination of the Number of Double .Bonds in Copolymersi~of
Unsaturated Polyesters and Vinyl Monomers
methods described above (Table 5) ar ;e in goodagreement,
and it may be concluded from thesedeterm.inations that
both methods are equally valid in determining the copoly-
merization constants of unsaturated~polye'sters.and vinyl
derivatives. There are 5 tables and 8 ref'erences, of which
are Soviet.
ASSOCIATION: Urallskiy filial Akademii nauk SSS4~;Sverdllpvsk (Ural Branch
of the Academy of Sciences, USS4 Sverdlovsk)
SUBMITTED: March 1957
Card 3/3

5M, 15(8) SOV/76-3373-8/41
AUTHORS: Tokarev, A. V., Spasskiyi S. S.
TITLE: Co-polymerization of Unsaturated Polyesters With Vinyl Mo~no-
mere (Sopolimerizatsiy& nenasyshchennikh po'liefirov x'vi'n:ilo-.
vymi monomerami).,II. Determination of the:Co-polYmerization
C,onstants (II. Opredeleniye konstant sopolim4rizatsii
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol~33P lir.'3t
PP 554 558 (USSR)
ABSTRACT: The example of the system polY-1,3-butyleneglyco lfumaratei-
styrene W serves.as.proof of the pos'sibillty~of applying .
the integral equation according to Mayo and Lewis tolthe
determination of the constants of co-polymerization of un-
saturated polyesters together with vinyl, derivativesCo-:
polymerization was carried out in glass ampoules in a.nitro-
gen atmosphere in the ultrathermostat,at,60,+0.10C and'
0.01% by Vreight of benzoyl peroxide.A.comparison between.
the polystyrenes obtained and a produqt'-,.(Ref:,f) described in
publications is given (Table 1). With'incre'7a'sing reaction'
Card 1/3 intensity in polymerization the atyrene-con'tent in-the co-

Co-polymerization of Unsaturated Polyesters With Vinyl SOV/76-33-3-8/41
Monomers. II. Determination of the Co-polymerization~Const~ants
polymer increases somewhat up to a ceitain bitent il'-12%_
by weight). Two different experiments4ere~carried out
(Tables 3,4) in order to investigate the reactivity OfAhe"
co-polymer; it was found that no soluble intermediate
ducts form in this reaction Only parVof the double:bonds
of the polyester takes part in co-polymerizati6n,(Tabie 2)
whereas the other part passes over into the';,co-polymer with-.;
out any change, which fact has to be takenjnto account in
connection with the calculation of the !Co_p6lYMeriZati on
constants (CPC) by a corresponding correction, The calcula-
tion results of the ON) according to~the,equation by
IfLayo-Lewi-sq with the above correction,,lare.in Good agree-.
- ment and are for Mr 3.0.� 0-4 and;~r 0-03 � 0.03.
2
The values show that the radicals M, 6fithe;polyester,do
more rapidly react.with its monomers than with styrene~iand
that the styrene radical Al- reacts predomindatly with the
unsaturated ester chains oi the polyesie'r,.which is con~si-'
Card 2/3 dered to be due to additional steric hindrances. In con-

-, ~, W9 girvallm 11 1 3 1
~ I i
Co-polymerization of Unsaturated Polyesters With Vi 1 76-3373-8/41
nyll : SOV ,

5 (4) i 15 (8)
AUTHORS: SOV/76-33-7-1/40
. Mikhaylovaj K. A. j
~paa!kiy. S. S.
.
_
Tarasov, Ao I., h1olchanova, T. V.j
Mat1kova, 11. Ye.
TITLE: Copolymerization of Unsaturated Polyesters With Vinyl Monomers,
IV. Copolymerization of Polydiethylene.Glyd.ol Fumarate With
Styrene, Acrylonitrileg Methyl Methaci-jlatei:,and Vinyl Lcetate:-:
PERIODICAL: Zhurnal fizicheskoy khimii, 19591 Vol .33v Kr779 pp 1449 -:~1454-
(USSR)
ABSTRACT: In a previous paper (Ref 1) it was found anioAg 045-her,things,
that acrylonitrile during copolymeriia"tion '(C) with tirisat-drated-
polyesters (PE) shows decreasing activity compared with that in'
!
ic acid. It W
as asiumed that these
(C) with diesters of fumar
l
c factors. In order to:~oonfirm this
phenomena are due to steri
.
assumption, the authors investigated the (C) of polydi:eth~lene.~
glycol fumarat e (I) with styrene (II),'~acrylonitrile~(III)5
'
. 'The.properties of-
methyl methacrylate (IV) ! and vinyl acetate
the vinyl monomers are listed (Table ~1). The (C) constants (cc)
were determined according to the Mayo-Lewis~6quation (Refi4).,

1~
Card 1 The experimental results obtained are listed,(Table 2):: from
/

Copolymerization of Unsaturated Polyesters With Vinyl S 'OV/76-33-7-1/40
Glycol
Monomers. IV. Copolymerization of Polydiethylene
F%imarate With Styrene, AcrylonitrileE Methyl Methacrylates, and Vinyl Acetate
which the (CC) as well as the reaction rate of the chain~xadi-~:7-1
cals of the (FE) and of the vinyl moxiolmers1were calculated.
(Table 3)~The activity of the Yinyl d4rivAtiv'es incrlea~se~ (with*.
respect to the chain radical.of the ~(PE) fi r 0m (II) ~`.,o
while during the (0) of ~inyi monomets an'6pposite Phenoienor.1..--
may be observed (Ref 5)9 i.e. (II) go'b'sess's:the stro*ngest and',
(V) the weakest activity. The expe-rimental :results obtained
confirm the above effe~-t of steric faqtors It is assumed that
the latter'increases with increasing size ofithe radi;aal;at the,:
double bond and with decreasing elas.ticity,,of the monomer mole-
aule. The authors plotted diagrams of~the integral compos'ition
of the systems under investigation (.Fi.ga 1-,-6:4-); furthermore,,.-,
they pointed out among other things that no azeotropic mixtuxes.~
are formed by the systems (1) + (II). 'and (1).~ +. (IV)., The Ab,,--Te.
diagrams permit determination of the 6ondit .ions~for IprepArin Ig.
homogeneous copolymers. Ther'e are 4 fieures,~3 tables, and
9 references, 7 of which are Soviet..
Card 2/3
q

0
-AUTHORS- Suvorov, A. L., Spasskiy, S.,S. SOV/20-127-4-21/60
TITLE. Copolymerization of Unsaturated Acyl Derivatives of Butyl
Polytitanate 'With Styrene
PERIODICAL: Doklady Akademii nauk SSSP., 1959, Vol 127, Nr,~ 4PP 80,51-807
(USSR)
ABSTRACT: Titanium-containing polymers, resultind'from ~po lyme ri i.ati 0; nof'.
unsaturated titanium-containing compounds oTi'from copqlymer:Lza
~
Act yet been:
tion of the latter with vinyl monomers have
thoroughly investigated. As may be seen fr6m.'a short'survey of

ilable on
publications (Refs 1-4), there are.no~4ata a~a the
zation of titanium7.,containin& polymers,,
synthesis and copolymeri
,
type (I)(Scheme) - of which a portioniof-oyg4nic groups is
unuaturated -.with vinyl monomers. The authorslattempte-d1to
explain the possibility'of such a syii-thesi,s" For this pu7posev
they made use of the case with vihich:~Ahe alkoxy.groups in acyl
polytitanates can be replaced by acy, rem4indera. They,obtaine4L
., By.
an unsaturated polycondensation product of. type (I)
,
an alkyl polytitanate with a fatty acid, preferably one:having:A:
Card 1/2 long chain, the acyl groups rfere substituted for the, alkyl gro-ap,s

Copolymerization of Unsaturatcd Acyl Derivatives of SOV 20-127
Bulyl Folyti tanate With Styrene
in vacuum, accompanied:by the'separatioh-of a :'correspondink.,
alcohol (II). A similar reaotion between butyl polytitanate and:~_~.
cinnamic or furyl- acrylic' acid in various ratios resultedlin
"V-he formation of unsaturated acyl deriv~Ltives of type ~('Ii).
Accordi.-LiG to-the quantity of the acid 4 he waxy or
ntroduced, tu
colophony-like substances rere obtained~'~Vlhen heating with,
styrene, these compounds entered c6bolymerizat ion at 100-150 0
in the presence of 1-2~pfiof benzoyl.peroxide so as to form
transparent brown-red polymers. The latter ate unsoluble in
acGtone, benzene, and toluene, but in tlie two last-mentioned
solvents a swelling occurs. Contrary to.b.utyl poly.titanlate and-
its acyl derivatives the above polymers-are not affected by:
storing theri in Yrater fe'r three months; They a~e furthd~ boil-
fast and --resist hoating with aqueous acetone.',There are 6
references.
ASSOCIATION: Inctitut khim-ii Urallskogo filiala Akadaiiuii n 'a uk' SSSR
(Institute of Chemisbry o If th,e Ural Drandh of tIhe Academi- of
Sciences, USSR)
ERESENTED: =arch 5, 1959, by B. A. Kazanski-,)-, Academician
SU-BK'ITTED; April 16, 1959
Card 2/2

83813:
S/190/66/002/005/003/0.15:
05
B004/Bo67
AUTHORS: Bulatov, M. A., Spasskiy,:S. S.
TITLE: Synthesis of P 1 dimethylsiloky lkylen_e_JFumarates and Thei~
Copoly erizat th StEenelLAbstracter's -Note: In the
original title kyl is used Astead of~alkylehe. This
is obviously a printing error as appear's from.the text.]
PERIODICAL: Vysokomolekulyarnyye soyedineniya, 19 60 ~9' Vol~. ~2, No. 59,
pp. 658-661
TEXT, The authors obtained polydimethylsiloxyalkylene'!fumarates by al-
coholysis of dimethyidiethoxysilane,with low-moleculAr,i glycol polyesters
of fumaric acid containing free hydroxyl groups. The reaction proceeded
smoothly at 100 - 180 0C if the alcohol formed in the r ;eacti'Dn' was dist illed
off. The following reaction equation is given for poly6thyl ene fumarate:
n,HO ICH2 CH 2OC10CH=CHCO0)] m CH2CH 2OR + n(CH 3)2 Si (01C 2H5)2
C 2H5fO Si(CH 3)2 O[CH2CH 20CO CH=CHCOOJ M CH 2CH2j nOR + (2.n -1 C 2H5 OH.
Polyesters of diethylene glycol and propylene glycol were obtained in the
Card 1/3

83813
Synthesis of Polydimethylsiloxyalkylene S/190/6b/002/605/003/'015
Fumarates and Their Copolymerization With: B004/Bo67.
Styrene
eanle manner. If dimethyl-di-n-butoxysilane is used instead o;f:i dime thyl4-.
diethoxysilane, the reaction proceeds vory slowly. atid~ Incom'Pletely. The
compounds obtained are viscous liquids insoluble in wat6r ahld:~allphatlo
hydrocarbons, but soluble in alcohol, acetone, estersq~aromatic hydro-
carbons, dichloroethane, and chloroform. On contact with vaie;r or on
storing in humid air, hydrolysis.slowly sets in. The m6lecuiar weight
fluctuated between 1,600 and 2,500. The physical data of the compounds:
obtained are given in Table 1 . In the presence of peroxides'! these poly.-
esters are capable of copolymerizing with many unsaturated compounds.
Ethylene glycol polyester. absorbed 30 - 70% styrene. the solubility of
the latter increased when the polyester contained an incteaOing amount,
of siloxane groups. Table 2 gives the data used for calculating the co-
polymerization constants according to F. R. Mayo and,F-,M.~-Lewis'(Ref.~ 8).
r1 = 0.6 + 0.3; r 2 = 0.03 + 0.03;index 1 refers tothe~ ,poly~,edter~ index.
2 to styrene. The introduction of organ.osiloxane gro'jP*5 int;o the eh a ir).
of the unsaturated polyester does not influence the character of. copoly~~'
merization with vinyl polymers. There are 2 tables and 8 references:
Card 2/3

83813
Synthesis of Polydimethylsiloxyalkylene S/190/60/002/665/003/015 J
Fumarates and Their Copolymerization With BOO4/BO6,7
Styrene
Soviet and I US.
ASSOCIATION: Institut khimii Urallskogo filials. AN SSSR
(TnRtitiifP nf Cht-mistrv n-F thp Ural Rrnn:nh nf, thp

83760
2
~6~0/60VP06/005/01
22-D3 B015 64
AUTHORS; Matlkova, It. Ye., Spas ki3r-lci.~
TITLE: Copolymerization of Polyethylene Glycol,Fumarate.
es
Phosphinate With
PERIODICAL: Vysokomol-okulyarnyye soyedi-neniya. 1960, volo .21, No. 6,.,:
pp. 879-883
TEM This is the VIII. information of the series on the copolymerization
OA, unsaturated polyesters with vinyl- and.allyl monome~rs.-Yh-;:copoly erizar,
tion of the allyl. derivatives of phosphoric acid with m"ixed,,ethylene
glycol polyesters of fumaric- and phosphinic aGid was investigated. To'
determine the relative activity of these compounds in the copolymerization
the copolymerization constants were determined of the folloswing Bystems!
polyethylene glycol fumarate phenyl phosphinate allyl didthyl-
~hosphlneacetate and polyethylene glycol fumarate phenyl plios'phinate
diethylallyl phosphinic acid and the values r + r
1 1-7YO-3 and 2
O,~045tO.06, and r 2 .12 and r 0.09i sp ively were
.07t! 0.05 re ect
2
Card 1/2
r jc ;7

0700
Copolymerization of Polyethylene Glycol Fumarate S/19%60/00~/00'6/005/012
Phosphinate WIth Allyl Derivatives of Phosphoric B015 64
Acids
obtained (Table). A comparison of the copolymerization c6nstan:ta' ahows
hat t-he activity of the allyl derivates increases with Tespe Vto the
polyester radicals if the first are copolymerized with mixod polyesters..
The increase in the activity of the allyl derivatives of!!phosp'hbric a.,!id;s
in the copolymerization with polyfumarate phosphinates is apparently due
to the presence of the P=O group in themixed polyesbers~,_The~~:m-Othoil cf
producing the mixed ester and the determination~of the copolymarizat-ion
constwits is described. Phosphorus,is determined in copolymers by tho
method of Neyman (Ref. 4), while the diagrams (Rig,, 3)~of the: iLitegral
COMI)osition of the copolymers were determined by the equationlo'f
M. Gindin, A. D~ Abkin, and S. S. bledvedev (Ref. 7). There~are 3
figureaq I table, and 8 references: 7 Soviet and US_
ASSOCIATION3 Institut khimii Ural Iskogo filiala AN SSSRI Insti tute of
Chemistry of the Ural Branch of the Academy of Sciencss
USSR)
SUBMITTEDs February 18, 1960
Card. 212

83471
S/190/60/062/009/0041/019
3 0C B004/
~i 0 0 0 "21- ~11 3, Bo6o
AUTHORS-,., Spasskiy.; S. S., MatIkova, hT. Ye., Tokarev,1A. V.
TETLEt Copolymerization\\of Unsaturated Poly4s'~ers4ith vinyl
a ical Analys is~of the copolymeTS7
Monomers. V1. Thermome ch
of Unsaturated Polyester7and Vinyl Monomers
PERIODICAL, Vysokomolekulyarnyye soyedineniya, '196 io, Vol. 2, No~ 9,
pp. 1297-1300
TEXT:,. In previous-art-icies (Refs, 1,2), the authors 6~tudield. the 00-
polymerization of the polyesters (hy polydiethyiene.glycol fumarate
and poly-1.3-butylene glycol fumarate with the vinyl monomer6 (M
2)
Styr--,ne, vinyl acetate,-acrylonitrile9l and methyl metfia2jyl,~
~e and
determined the copolymerizaz an constants given in a Tab-le ~of the present
paper, On the basis of these constants, theauthors determined the polymer,
;:,tvi-~tuz-e by calculating the fraction of, M -M or M M,
2 2' Ml-M2~'YM2;'~ 1- 1~
bop(16~ In the present artic~le, the authors describe the thbrmomechazioal
1/31

834n:
Copolymerization of Unsaturated Polyesters S/190/60/002/009/001/019
With Vinyl Monomers. VI. Thermomechanical B004/Bo6o
Analysis of the Copolymers of Unsaturated
Polyp:eters and V_Jnyl Monnmers
behavior of the copolymers.. A method developed by V. A*':Kargin et al.,
5A) was used for their investigation. Deformation as a function
.--%f ~.,t.;atperature was measured by means of an apparatus designed by
7,, L, Tsetlin, V, I. Gavrilov, N. A,, Velikovsk a, and,V. V.' Kochk-in
7'j~~-
% Re _t_J
~,F' -spar ve curves are shown in Fig. 1 . The curves observed were
of two types,. In the first type (copolymers of the two polyesters with
,74-'nyl acetate and of P01Y-'133-butylene glycol fumarate'with~sityrene in an
a,,,,s,.troP_ic raltio)~ deformation starts only at the,decompositi,on tempera-
'-ure (between 270 and 290OC; at 240 - 245'C, bnly.in the case. of:
aclryll:~nitrile copolymers). In the second type (copolympirs w.ith nonazeo-
t*_-ep:'_-, rat-_o off somponents, copolymers with styrene ex'Oess,:. copolymers. of
mf~*r'hyl me-,hai:~rylate), deformation already takes placel4t, a1. 10~ Wer tempera-
ture, but w1th further rising temperature the curve f6 ;rms S(plateau
(defr:,rmation remains constant), until a further deformatiov.6ccurs at.the'
Oharacteristil.,
decompcsitioza -temperature. The curves of the first t ;e are-
YR
of Y"'MAI"-M' and ld~-hl -M M bonds, while the curves.cf::the se cond
2 1- 2 type are
Card 2/3

83471
Copolymerization of Unsaturated Polyesters S/19,OJ60/002/009/001/019.
With Vinyl Monomers. VI. Thermomechanical B0041P06o
Analysis of the Copolymers of Unsaturated
Polyosters and Vinyl Monomers
characteristic of linear structures with M -M -M bonds. These results'
2 2 2
confirm the structures calculated from-the copolymerization~constants.'
The authors thank G. L. Slonimskiy for his introduction int6.the method
of thermomechanical analysis. There are 1,figure,.1 table, sina6 Soviet
references.
ASSOCIATION: Institut khimii Urallskogb, filiala AN~SSSR (Institute:of
Chemistry of the Ural Branch AS USSR)
SUBMITTED: November 25, 1959~
Card 3/3

83473,
S/190/06/002/009/004/019
13004/2060
AUTHORS- Spasskiy, S. S., Molchanovd, T. V.
TITLE: Copoly erization of Unsaturated Polyesters With Vinyl 1~
Monomers. X. Thermomechanical Study of,Gopolymer of
Three-component Systems
PERIODICALt Vysokomolakulyarnyye soyedinaniya, 196oi.Vol.i 2, No. 9,1
pp. 1320-1323
TEXT: The authors utilized the apparatus designed by,'V. L. Tsetlin,
V. I. Gavrilov, et al. (Ref. 12) (method by V. A. Karkin et al. Ref.11)
to study the thermomechanical behavior of copolymers '6f polydiethylone 4
glycol fumarate + styrene + vinyl acetate (I) and poijdiet~yhene IglypI o1
fumarate + methyl methacrylate + e (II) under'a~*stre-ss of
2 styron
40 kg/cm . The copolymerization constants are given in.Tabli 1, andlihe
physical data regarding vinyl monomers in Table 2. Inia previous paper
(Ref. 5) on two-component systems, the authors estabiished. two types~of
thermomechanical curves. In the first type,.corresponding:'to cross-:
linked copolymers, deformation starts only at deconipq'sition t*mperaturs.
Card 1/3

.83471.
Copolymerization of Unsaturated Polyesters S/igy6b/oO2/009/004/019
With Vinyl Monomers. X. Thermomechanical B004 060
B
Study of Copolymers of Three-component Systems
The second type characterizes linear structures, and deformation occurs'
already at a low temperature, remains constant on a temperature rise, and
further increases at decomposition temperature. Fig. 1-~shoNs:~the diagrams
of the composition of I and II. In spite of different ~,rimary,lratio of~
the three components, the composition of the forming odpolyniek tends
toward the azeotropic composition. The thirmomechanicai.properties of I
and II are graphically represented in Fig' 2. In azeotropic.1:,,the deforma-.1
tion curve forms no plateau, while plateaux appear in nonazi.otropic I''
since linear structures are formed after saturation of',,;the active bonL
of the polyester. In II, the deformation curve features a plateau. These.
results fit those obtained on the str Iength of the copolymerization con-
stants. In opposition to other researchers (Refs. 9,10), th6:authors
found that the constants of copolymerization of low-molecula:r:~die.sters'of
fumario acid with vinyl monomers are not applicable to",the calculations
of the copolymer composition (Fig- 3). There are 3 figures, ~2;,tables,~and
12 referencesg 8 Soviet, 2 US, and 2 British.
Card 2/3

B7338
S/1 6o/o 102/010/021/02 6/'
V9 1300
115.%11.10 VZOS ZI 0% 9.8 4 B064
AM'HORS-. S a.) Moichanova T. V.
TITLE: Copolymerization of Unsaturated Polyesters With Vinyl-,and
Allyl Monomers. XI. Copolymerization of Polydiethylene
Glycol Fumarate Adipinate,and of Low-molecular Polydiethylene
Glycol Fumarate With Styrene
PERIODICAL: Vysokomolekulyarnyye soyedineniya, 19609: Vol.~2, No. 10,
PP. 1481-1485
TEXT: In previous papers (Refs. 1-6) the authors reportedlon the copoly"
merization of polyglycol fumarates.Copolymers of this'.kind- are used.for
glass reinforced plastics. Since, however, no pure compounds are used in~]
the practice, this paper discusses the effect of an Addition of saturated
acids to the unsaturated polyester upon the molecular,weight and the'.co"'
polymerization constants. The copol merization with styrene of polydi-
ethylene glycol fumarate-adipinate M, molecular weight 1610,' and of. two
samples of polydiethylene glycol fumarate (II), molecular weight 510 ands
1970 was investigated. The reaction took place in sealed glass ampouls
Card 1/2

87338
Copolymerization of Unsaturated Polyesters S/190/60/oog/.010/021/026/17-
With Vinyl- and Allyl Monomers. XI. Copoly_m B004/B664
of Low-
12erization of Polydiethylene Glycol Fumarate Adipinate and
molecular Polydiethylene Glycol Fumarate With Styrene
in nitrogen atmosphere at 600C. Benzoyl peroxide served as-initiator. After
the non-polymerized products had been removed by washing with.acetone
(5 - 6 days), the composition was determined on -the balsis of the oxygen
content in the copolymer. The number of polyesteX links entered~inta're-
action was determined on the basis of the additivity:,Of the '~specific:
Volumes and the known shrinkage in polymerization. The following results:
ifere obtaineds 1 The copolymerization constants for.:I and.II with styrene
differ little. 2~ The styrene activity increases with'decreasing molecular
weight of the polyester. It reaches its maximum in the rea'ct'ion- with~di-~
ethyl fumarate. 3) Since due to the changed styrene~dctivity also it6con-
-tent in the copolymer changes, this fact must be taken infoaccount in the
Droduction of binding agents for glass reinforced plastics.:There are:
figure, 2 tables, and 9 references: 6 Soviet, 2 US,!:and I German*
ASSOCIATION: Ural'skiy filial AN SSSR, Institut khimii (Ural.Branch.of
the AS USSR, Institute of Chemistry
SUBMITTED: April 18, 1960
Card 2/2

A Study o f ul-a-, -n- s- .... f-o--r*--t,-h",e~,-"Co-m'poeit ion o '6110*61~6166zt 611 66T7dif-','_-_
B004/ B
Ternary Copolymers. 1 660
+ 22-) + I'll. M. One ti~known. tqtm tity;
r3jr2i r2jr32 rairn +
ris ased;
(3a)! BuPP37~ by i trod~cing
M. MI and M M'I/Mv.
1 il/M
+ + r3i 4-
r2:,rjs rjar, + 2 12
rn
-Moreover, -in! order to avoid:
.the
-fractions, eciprocal
Ni IN hIL
t 2 -3 va ues;of the: elative rated
+ + r2l
rL2r31 rj2ra! rnrn rts Or
const4nts are Introduced.
r
+ + A 1/r
12' 2
ri)rv r23r L2 riaris r3l + r3i 12
C.e, and the s~stem-of
,m, + m + M!, 1.
'F equat" ons
(7) i~ obtained: J!
2 2 2 211. .2
AM +2BM M +CM +2DM +2EM +F 0; A M +2B M M +C M +2D M +2E'M 0. Th
1 1 2 2 1 2 2 1 2 11. 1 2 1
coefficients of these equations are defined as::A A A
21 PlI
2B A A 1 +A A I 1 0 A A 2D A A 1 A
.2
21 32 1 12 31 2 .12 321 23 31 IIA~ 21 113. 3
it
2E A A 1+A A 1 F A A 1 A A A 2B A
12 23 3 13 32 2 13 23 3 1 21 31 1 211 32 1
+ A A C A A 2D A A31111+A A i 2E =A:A 'l I +A ~A 1 1
12 3112.; 1 12 3212; 1 23 21 131i 1 ~1 22 3 13 32~:
Card 2/4

65410
A Study of Equations for the Composition of S/196/60/do2/611/00-1/027'
Ternary Copolymers,. I B004/BO60;
F A i -AA I I I - A. A - A I V. A 1;:11 A A
12
23 3. 17; 12 21 23 3 311, 71
I. A ; J A - 1. The authors derived the'criteria under which
23 3 32
only poaitive values are obtained for equations,(7)~',~ It i~s confirmed that
only one single azeotropic point can bepresent in the ternary.system. The
following eystems with azeotropic composition are tabulateds
System Copolymerization constant zeotrop~o.,compcsitior
r
r12 jr,, Ir r,~, jr 23 Ir 32 in molar fracti6ne
13
styre e with 2.0 0.3 Q-529
vinylidene dichloride 0,,14 12.2 Q,093
~2
and dimethyl filmnrate 0.07 0,046 '0~378
44 4,,3,r :0 139
methyl mezhacrylat
with 2,5-dichloro styrene 2.25 M107 0.367
and acrylonitrile 0.18 0,22 0'.474
styrene with O~21 0.41 0467
2,5~-dichloro styrene 2.2 M1 0.153
0.380
and acrylonit-rile 0.041 0,,22

Card 3/4

S/I 0/ 0 ~/O A 0
0 0274
BOO';OB'0'6o'
4
AUTHORS: Alekseyeva, I. A Spasskiy, B~ Sl~
TITLE- Copoly erizationlof Unsaturated Polyest-ar"SrWith Vinyl-
Allyl Monomers. XII. Study of Copoly ers of'.' iethylene
M 'Poly
Glycol ~Jand St renel
Pumarate y by Infrared-.Spedtroscopy and the
Chemical Me o
PERIODICAL: Vysokomolekulyarnyye soyedineniya, !960 Vol.: 2, No,, 11,
pp. 1645 1654
TEXTs The authors --report on a new method of determining, double bands. in
c
,)polymers of unsaturated polyesters~ The method is'l;based"on the det
, ermi
nation of the ratio between the optical density of the bainds of tb~e~*
groups whose content has changed due to copolymerizationo vn the cne.hand,
and the optical density of the bands of the.groups'4hose'content ha',q
remained unchanged, on the other... The method is thus'-'inde~pendent of' the
p m iioni
'-hiokness of the irradiated sample. The co oly eriza, :'of poiydie~thy~ene
glycol fumarate (PDEGF) with styrene was studied. The infra~r ed spectrum
(Fig-la,, `b.) revealed that in the copolymerr the optical density of the*
Card !/6

Copolymerization of Unsaturated Polyesters 3/190 60/0-02/011/009/027:
With V-Inyl- and Allyl Monomers. XII. Study B000660'~
of C.~)polymers of Polydiethylene Glycol Pumarate and Styr enL% by Infrared
Spec-troscopy and the Chemical Method
!654 cm-1 absorption.band of the -CH-CH group has changeld:~asagains't them
spectrum of PDEGF~ The 705 cm band of the ben-.eri4,' ring: was also
i4ent'ified. The calculation of nonreacting double 'bonds by various -metho
yielxd,-~d the following values!,
Table 2
Method Number of nonreacting

6uble ~bonds of 'the'
d
polye~ter:conv,-rted
Anto copolymer,,%
Change in the optical density of the band for
doi,~ble bond 45�2
Cont-nt of unsaturated acids in the sulfuric
hydrolyzate
4 7:t2
Yteld of polymer separated from the sulfuric
hydrolyzate. 59�5
Change in the specific volume
5 8�5

Card 2/6

Copolymerization of Unsaturated Polyesters S/190/60/0'N/011/009/027'1
With Vinyl- and Allyl Monomers. XII. Study, B004/~060
of Copolymers of Polydiethylene Glycol Fumarate anct Styi.ene by Infrared
Spectro9copy and the Chemical Method
The last ~wo data are said to be little probable,~as their determination
error is too large.. The styrene content in the copolymer~.was foundAo be
14115% by means of infrared spectroscopy (an MAC-12 ';(IKS-~Ii) recordin
9
spectrophotometer was used). Elempntary microanalys~ip,yi.elded 13%,' tand; the.'
oxygen content determination 12%. The number of double bonds was
determined by the chemical method of I. I~ Ioffe (Reef. 12 hydr-olysia1by
means of concentrated H so aftertwo days additio~n of.0.1 N KMnO~ and
2 4
KI, and titration of free fumaric acid with 0.1 N thiosulfate. Ioffefs~
calculations had to be corrected, however, because 4iethylene~glyc6l also
11ses up some. KMnO (0,0! g diethylene glycol = O~39~~ ml thiosulfate). On
4
dilution of 'the hydrolyzed copolymer s.ome polymer -was pr.'e6ipitated~: ~th~
infrared spectrum of which wa t ke Fig-ilc),,and which'was.
6 likewise. a n
compared with a standard mixture of )6% dimethyl malonat6l'and:44%:
10thyl
banzene (Fig. 1d). Based on the spectroscopic~analysis,, the styrene con-
chem'6' 1 ' naly
tent of this polymer was 35~91 in agreement with ther :L a a sis,:In
this product., !-.7 fumaric acid molecules fall to one styrene moleauile.~
Card 316

Copolym-:~riza+ion of Unsaturated Polyesters -096/60/010/0-11/099/027,
With Vinyl- and Allyl Monomers. XII. St Iudy of BOOVB060~
Cupolymers of Polydiethylene Glycol Fumarate and Styrene by Infrared
Spectroscopy and the Chemical Method
LI/
A-cording to this, the fumaric groups of PDEGF react with.
styrene bi:~t also among one another. The suggested~s , pectIroseopic m6thod
gave mo:7e accurate results than methods us ed b ef ore,, The authors thank:
TI. V. Molchanova and G, A. Semerneva for their asssistande!:in 'he analyses.
There are 2 figures, 4 tables, and referenceses 7 Soviet., 2 US,
British, and 2 German.
t:! .Ins titut4~ of
ASSOCIATION: Institut khimii Urallskogo filiala AN13SSRiu
Chemistry of the Ural Branoh of AS USSR)
SUBMITTEDi May 3, 1960
Card 4/6

--;b 30
AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
Card 1/4
77395
SOY/79 - 30 -1 -56/78
Spasskiy, S. S., Tokarev, A. V., Mikhaylova, M. A.,
'-~oc a~Wo~a-, ~T-. Mat 11cova, M. Ye.~~
Copolymerization of Unsaturated Polyeste'rs,With Vinyl
Monomers. III Concerning the Nature ofiCopolymeriza-
tion of Unsaturated Polyesters With~Vinyl"Monomers
Zhurnal obshchey khimii 196o, vol.~O, N:r~l, pp 250-257
(USSR)
with
Copolymers of poly(1,3-butylene glycol fLunarate).
vinylcarbazole, acrylonitrile, vinyi;acetate, methyl:
methacrylate, and poly(ethylene glycol fumarate),with
vinyl acetate were prepared in,order to~s'tudy the4.
nature of this copolymerization. Literature data~
concerning the copolymerization constants~bf different
copolymers are reviewed. Copolymerization of polyesters.,
with acrylonitrile, vinyl acetate, and mlethyl meth-
acrylate was conducted in sealed glass ampo ules in a;

Copolymerization of Unsaturated Polyesters
~Iith Vinyl Monomers. III. SOV/79-30-1-56/718
nitrogen atmosphere. The ampoules,were.placed ina
,~ 1-;,~ rr,-, + 0.10. Benzoyl Peroxide was used
-1 oz;tat at 60
as an initiator. After completion of the~reaction
L
(to the given extent), the ampoulesiwere 'removed from
the thermostat and frozen with liquid nitrogen. The'
trimeric copolymer was separated from other, products.
of reaction and the initial products byltreatment'with
acetone containing traces of hydroa i
C) _uinone, and washing
with acetone. Co olymerization of poly4l-,3-but-ylene,
p %
glycol fumarate) with vinylcarbazole was conducted
in toluene solution (in nitrogen atmosphe're).in the
ture
presence of benzoyl peroxide kup to~l%).~ ::The mix
0
was heated for 65 hr at 100 , but no copolymers were~
obtained. From the data obtained, the following
conclusions were made: activity of,a,crylonitrile in
the reactions with polyesters is low in~comparison
with its acti.-ity in the reactions~with'diesters of
fumaric acid, Copolymerization of yiny~c 'arbazolp~with,
polyesters does not take place at all, Apparently,
Card 2/4 the bulky substituents cause steric~'hindran ce affectin
9

Copolymerization of Unsaturated Polyesters 77395
Wit;h,Vinyl Monomers. III SOV/79-30-1-56/78
the copolymerization process. The activity of vinyl,
acetate in the copolymerization remains'~unchanged.
Copolymerization constants of the'followzihg copolymers
were determined:
r r
1 2
Poly(1,3-butylene glycol fumarate) 1.12 + m4o 1.03 + 0-2
acrylonitrile
Poly(1,3-butylene glycol fumarate) 0.5 + 0.15 2.1 +0.30
methyl methacrylate
Poly(1,3-butylene glycol fumarate) 0.2 + 0.2 0.1 + 0';. 07;
viny-2, acetate
POly(ethylene glycol fumarate) 0.2 + 0.1 0.020 + 0.02
vinyl acetate
Card 3/4

Copol,jr.,ierization of Unsaturated Polyesters 7739-D
With *Vinyl Monomers. III SOV/79-3.0-1-56/78
There are 4 tables; 2 figures; and-16 references,.2
U.S., 5 U.K., 9 Soviet. The 5 most recent U.S. and
U.K. references are: B. Hayes, R-Hunter-_,~Chem. and
Ind., 1957, 559; V. Wychbrly, Chem.":and~Ind,, 1957,
491; W. Robertson, D. Shepherd, Chem. and. Ind., 1958Y
126; B. Hayes, W. Read, L. Vaygan, Chem~ and Ind.~
1162 (1957); F. Leavitt, V. Stannett., M., Szwarc, Chem.
and Ind., 28, 985 (1957)-
ASSOCIATION: Ural Branch of the Institute of Che~istvj*, Academy of
m
Sciences, USSR (Uralskiy filial ANZSSR~ Institut
Ichimii)
SUBMITTED: July 29, 1958
Card 4/4
i Z

.3830
AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
Card 1/7
'77396,
SOV/79-30-1-57/78~
Tarasov, A. I.
Copolymerization of Unsaturated P61yesters,With~Vin'yl
Monomers. V. Co olymerization of P.oly(1*3-Butylene
Glycol Fumarate5 With Vinyl Alkyl'Ethers
Zhurnal obshchey kh:Lmii'J$ ig6o, voi 30,"'Nr 1, pp.25T-263
(USSR)
Effect of the structure of vinyl~6thers"on*their.
activity in the copoly'merization:,~ith'~u'n'saturatod poly-
esters was studied. Copolymerization of poly(l
butylene glycol fumarate) with vin* 1 is'6amyl, vinyli
"Y
n-amyl, vinyl isobutyl, vinyl n butyl' ;'and vinyl
n-propyl ethers was c6nducted~according~~to the p'roce-
dure described in the previous work (Spdaskiy and
j
others, ZhOKh, 960), Copolymerization
_10, 250, 1
:the composition,
constants (see Fig 1), data conc6rnint
and mechanical properties of the:6opolymers'obtained
are given.* The following conclusions are made: about
60% of the double bonds of the polyester remain

Card 2/7

Copolymerization of Unsaturated Polyesters 77396
With Vinyl Monomers. V. Copolymerization of SOV/M-130-1-57/T18-
P01Y(1,3-Butylene Glycol Fumarate) With Vinyl
Alkyl Ethers
Fig. 1. Graphical determinatiom,of copolymerization
constants of P01Y(1,3-butylene glycol-fumarate) and
vinyl alkyl ethers.. (1) Vinyl isoamyl ether:(.r
-amyl ethe
3.8 + 0.7; r 2 - 0); (2) vinyl n 11V (ri 2
+ 0.7; r 0); (3) vinyl isobutyl earn ,
2 'he (r 2.0
0);(4) vinyl n-butyl, +
+ 0.7; r ether. (r, .8
2
0.5; r 0); (5).v:LnYl n-propyl.ether (r .5;
2
r 0
2
Caption for Fig. 1.
unchanged at 15-20% conversion,-~'~the al'ctivity of the
vinyl ethers (in respect to the:Tumar-6te unit)~does
not depend on their structure; d Inifor~m' (in re.spect to
Card 3/7 is formed whe-' the ratio
composition) copolymer n

Copolymerization of Unsaturated Polyesters 7739b"
With Vinyl Monomers. V. Copolymerization of SOV/79-30-1-57/~8
Poly(1,3-Butylene Glycol Fumarate) With Vinyl
Alkyl Ethers
polymer: vinyl ether is not lessithan 9:1; the~the'rmo-
mechanical investigations of the'~~copolymers obtained
show that the quoted copolymerization constants are:
correct (see Figs. 4, 5, and 6).~': Thdre are 4.tabl'es,
6 figures; and 16 references, 5 U.S...,'ll Soviet. The
U.S. references are: F. M. Lewisj C. Walling, W.
Cummings, E. R Briggs, F. R. Maio, J.;~Am.: Chem. Soc.,
70, 1519 (1948j; F. M. Lewis, C.,'W~dlng, W. Cummings,
E. R. Bri W. J. Wenisch J. Ain. Chem. Soc.' 70,
1527
Soc., 70, 1533 (1948)j~F. R. MaJ6, C~~.Walling;,F. M.
Lewis, J. Am. Chem. Soc-# 70, 1523 (1948);.-E. C.
Chapin, E. G. Hain, C. K. Mills#~~J. Polymer Scio, ~40
597 (1949).
ASSOCIATIONt Ural Branch of the Institute of Chemistry, Academy
of Sciences, USSR (Uralskiy filial AN,SSSRp-In13tiWt
khimii)
SUBMITTED1 July 30i 1958
Card 4/7

Copolymerization of Unsaturated Polyesters 773961.
With.Vinyl Monomers. V. Copolymerization of SOV/79-30-1-57/78
Poly(1,3-Butylene Glycol Fumarate) With Vinyl
Alk~yl Ethers
Card 5/7

Tn"Vvemal," nLLt rallgillm Lr-L'R-4mzwLLF

Copolymerization of Unsaturated Polyesters
With Vinyl Monomers. V. Copolymerization of
P01Y(1,3-Butylene Glycol Fumarate) With Vinyl
Alkyl Ethers

88730
3/igo/61/003/001/014/020
Bi 1 9/B2,1 6
114
AUTHORSs MatIkova, M. Ye., Spasskiy. S.
TITLEs Copolymerization of poly-1,3-butylene-g~~col fumarate and
diethyl allyl phosphinic acid
PERIODICALt Vysokomolekulyarnyye soyedineniyat v. 3,:~110-,I,:19611 93.-98'
TEXT: The present work studies the activity of each;lreaction component in
Copolymerization of the compounds mention*d in the ti tle. Poly -1,3-butylene-'~,
glycol fumarate (A) was prepared by polycondeneationj6f eq!u*imolar am'6uint's~of:
maleic anhydride and 1,3-butylene glycol Allyl phosphonid acid diet
hy,
ester (B) was obtained by A. Ye. Arbuzo,v;s rearrangement reaction (R Ief.~16)
from equimolar amounts of triethyl phosphite and allyA bromide. A and B
mixed in various proportions were copolymerized:in nitrogen'-filled,sealed
ampoules at 800C. The copolymers obtained were analyze&las,followst
Pycnometric density determination on powdered produ6t, analysis folr!:F,
hydrolysis of copolymer by concentrated H SO ;.The specifi contraction' of
2
the monomeric unit of A was found at 0.0971 by comp,dringithe specific
Card 1/3

--t8730
S11 90J61/003/661/014/020
Copolymerization of poly-1,3-butylene... B119/B21
volume of the bopolymerizate obtained from A and B vtith~ths,Vof the copoly-~
merizate of'diethYl fumarate and styrene (in accordanceiwith~~'the rulel,of.
additivity of specific volumes (Ref. 6)). 'The specific,~volum'e':~of the pplyiw
B *as determined graphically at m700~basing on the additivi ty of the'
specific volumes of the copolymer of B with vinyl acetate. Thermomeohanical
tests of the copolymer from A and B were carried out in7~'equip~ment designed'.
by'V. L. Tseytlin, V. I. Gavrilov, I. A. Velikovskaya and V.,V. Kochkin.
Copolymerization constants were calculated by means of the integral
equation by R. Mayo and M. Lewis (Ref. 2). Corrections*are made for unreacted
double bonds of the polyester. Results; The polymerization:~cbnstants of
the system A - B are r 9.25 t 3.00; r 0.12 0.008. B~exhibits a
1 2
lower activity in copolymerization with unsaturated pollesters~than the,
Y,
fumaric double bonds of the polyester. The three-dimensional sitructure~of'
the copolymer is formed not only as a result of interaction ofr~polyester
double bonds with the monomer, but also by the mutual i~nterac'tion of these
double bonds. (Approximately 80% of the existing doublejbondsi:r;eac't during
copolymerization, but only 40% of this amount reacts with B)'.~;Copolymers of.
close to azeotropic ratio of components exhibited the best mechanical and
Card 2/3

S 19 J1,170,6 0 0 2
/005/612
B1 30/B202
AUTHORS: Bulatov, M. A., Spasskiy, S. S.
TITLE: Thermomechanical study of tii~ co~01-'YW"'s of'po'ly'diphenyl
siloxyethylene fumarate With styrene
PERIODICAL: Vysokomolekiiyarnyye soyedineniya, v. 31_no.i'2, 1961, Z06-212
TEXT: Two new organosilicon, unsaturated.polyesters Were 6y~etized,by the
methodfbr the production of unsaturated silicon containing_polyesteis~from
dimethyl diethoxysilane with low-molecular glycol es-t.er ofjumaric acid
which the authors described in Vysokomolek.soyed.2,.6
58, 1960. These.polym.
esters contain twoethyl or phenyl radicals at each Bi:7atom.:. Polydiethyl:
siloxyethylene fumarate (I) was produced from low-mofecular7polyethylene,
glycol fumarate (II) (12~6 OR groups) and diethyl diet.hoxys'ilane (III):by:la
22-hr heating in nitrogen current at temperatures rising from 165 to,2250C.
The ethyl alcohol with silane additions volatilized.:~The~~siibstances"whi'ch
did not enter the reaction were distilled off at atmospheric pressure and
subsequently in the vacuum. The residue was a transbareni,product of
red-orange color. The following structural formula can be calculated from
Card 1/2

89587
S1190161100310021005/012~
Thermomechanical study of. 231 30/B2 02 -q
the C, H, Si content: I(C2H4 OCOCH CHCOO)6*1C H.OSi(c H~:) 01 Poly~-
2 4 2- 5 2 x
diphenyl siloxyethylene fumarate was produced like (I) from~~(II) and'idii-~
phenyl diethoxysilane under heating to 200OC:for foui~hr. opolymeis; from
(III) and styrene were studied thermomechanically according:.to the 'method by
V. A. Kargin, Zh. fiz. khimii,.?J-, 530, 1949, and Khim. prom-st,
1955p no.1
64. Cylindrical specimens with a diameter of 9 mm and a thicknessof:
3.2-3.5 mm. were formed from the copolymers. They ivere studied underispecif-
ic load of 8 and 40 kg/cm2.' The deformation curves are similar to:those"of
-the highly elastic substances. The introduction of b.ifun&tional di6rganO;sJl-
oxane chains into the chain of the unsaturated polyeqtersica'uses a highly
elastic deformation in the copolymers. With a composition similar to the
azeotropic one, minimum deformation occurs. The const,ants~of copolymeriza-
tion of the unsaturated polyesters containing diorganosiloxane chains only
slightly depend on the character of the hydrocarbon radicals at the.Si-atom.
There are 3 figures, 1 table, and 7 Soviet-bloc,referenced..
ASSOCIATION: Institut Khimii Urallskogo Filiala AN~iSSSR'(Institute: of
Chemistry of the Ural Branch, AS USSR)
SUBMITTED: June 15, 1960
Card 2/2

M29~
22-0q, 1-672) S/190J61/903/OQ4/002/014
B101/B207
AUTHORS: Spasskiy, S. S., Karas9j, L. Ya.
TITLE: Problem of a quantitative characteristic of-theiactivity of
unsaturated compounds in copolymerization~reactio"
PERIODICAL: Vysokomolekulyarnyye soyedineniY49 v-3, n9- 4 1:'l 961 ,505-514
1C. Piice (Ref. 1
TEXT: The authors proceed from.the papers of T. Alfreyp'.,
see below) in which the copolymerization of~unsaturate&~ompounas was
characterized by two constants, the activity.factor,Q and;polirity fact Ior e;
e denotes the electron density of the double bond. Accoraingitio these
"Miriiation constaits
researchers, the followinr e uations hold for the copoly,
r1, r2: r, ~ (Q1/Q )exp _e1te, - e2)] (1) and r 1)ex' e (e e
2 : (Q2/Q p 2
2 2 ill
(2). The correction made by L. Wall (Ref. 2, see elow)!~~is mentioned, ~by
which the polarity factors e-* and e* were added thus considering charge;of~
2
radicals with unpaired electrons. It was the aim of the!presirit study1o
te
express the activity factors by a con tant which may be de riiihed indep'ond-
ently of the equations (1) and (2). As such the n bond sl~are'!~o;f the
Card 1/ 11

21129
:8/1~; 61/903/0(4:/002/014.
Problem of ... B1 Ot-Yfib2OT1
molecular refraction was chosen, since reactivity increases with increasing,
polarizability of the n bonds. is replaced by the pro*ductap. -a expres-
ses the polarizability of the n bonds characterized by refraction, the
effectsof the monomer structure not considered by a For,the:polar factor
of the monomer Zis introduced, for that of.the radical,' the authors use
and write down the following equations:
r (alpl/a exp[-'Z*(Zl -Z,)] (5) and
2P2) 1
r exp Z'?N (2:2 _71 )1 (6). In consid r' t' nof :..th-e factoir
e a io
2 (Y2/Y1
AZ41 of the excess radical charge due to the unpaired electroi~,*: and the
number n,, and n of the conjugate double bonds the foli6wing'ia,obtaine
2
(9) and
exp (21
1 (Yl/CV2 2
r 2 (a2P2 /a1P1 (10). Table 2; lists the
exp[- (-72 +AZ*/n2)(2:2 .1fl
results of the calculation of these factors. It was possible, to.differeati-'
ate between three groups of monomers. 1) P,1 holds for.the mbnosubstituted'
ethylene derivatives the double bond of which is conjugated with aromatic
or carbonyl bond; P>1 holds.for monosubstituted ethylisne iierivatives~the~
Card 2/ 11

S/1 90161 A03/004/602/01 4~
Problem of ... B1O1/B2b!
double bond of which is conjugated with ethyl ene double bond;~~3) P