SCIENTIFIC ABSTRACT TOLSTONOGOVA, V.I. - TOLSTOPYATOVA, A.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001756120010-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 16, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

TOLSTONOGOVA, V.I. (Khabarovsk)
Cooling off with chlorethyl in the treatment of neuralgic
syndromes* Klintmed. 34 no.8:76-77 Ag '56. (MIRA 12:8)
1. Im kliniki nervn:rkh bolezney (zav. - prof. B.H.Serebryanik)
Mmbarovelcogo meditainskogo instituta.
LGIA, ther.
ethyl chloride spray)
(ETHYL CHLORIDE, ther. use
neuralgia)

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V 900
N. F. City 15A Assmir. Vol. 4
7-&)(1939)(fn
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Rnglish)~A review. C. S. Ship"

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SHCHEPOTIYEV, F.L.; TOLSTOPLET, A.Ya.; NAVALIKHINA, N.K.
Growth and frost resistance of oak (Quercus robur L.) treated vith
gibberellin. Dokl,AN SSSR 138 no-4:966-969 Te 161. (MRL 14:5)
1. Ukrain kiy nauchno-isaledovateltakiy inatitut lesnogo khozyaystva
i agrolesomelioratsii, Khartkov. Predstavleno akademikom V.N.
Sukachevym.
(Gibberellins) (Plants-Frost resistance) (oak)

------------- --------------- -----------------------------------------------------
It /I /d P/ e 7~, 11.1X
USSRI/Forestry - J-4
Abs Jour : Referat Zhur Biologiya, No 16, 25 Aug 1957, 69122
Author : Tolstoplet, A.Ya.
Inst
Title : Agrotechnical Means of Increasing the Productivity of
Spindle tree on Open Plantings.
Orig Pub : Nauch. tr. Ukr. n.-i. in-ta les. kh-va i agrolesnometior.,
1956, No 18, 81-94
Abstract : An experiment is described in initiating planting of
European spindletrees in the district of Kharkov. The
data of soil preparation, addition of organic and mine-
ral fertilizers, density and manner of planting :in crea-
tion of plantations of European spincIletree are given.
It is noted that a deep planting under plougbing leads
to a high productivity due to additional roots, which de-
velop from stems. The spindletree productivity is also
increased by wrapping the stem from 15-20 cm from the
Card 1/2 - 42 -

OSSR/Forestry J-4
Abs Jour Referat Zhur Biologiya, No 16, 2-5 Aug 1957, 69129
ground. Also effective is the use of annual feeding of
the soil and above-root growth., Stump planting is con-
ditioned by intensity of root growth and increased syn-
thesis of gutta in the root bark. This operation is per-
formed in the third year after planting the seedlings.
There are stated the norms, proper periods and the tech-
nique of conducting root and above-root supplementary
feeding of NPK on loamy, exhausted soils.
Card 2/2 - 43 -

WDVEDEV, I.A.; BELIGOLI,9KIY, B.P.; GLIKMAN, E~S.; SPASOV, A.A.;
_T%STOFYAT,_ A-A,-
Methods-of dividing production expenditures into constant and
fluctuating ones. Stall. 2.3 no.8-74$-752 Ag t63. (IERA 16:9)
1. Dnepropetrovskiy metallurgicheskiy institut-i Pridneprovskiy
sovet narodnogo khozyaystv
_A!
Netallursy-09ats)

MEDVEDEV, I.A., kand.tekhn.nauk; SPASOV, A.A., inzh.; TOL,9MPYAT., Akk inzh.
Using correlation analysis for determining the specific consumption
of coke. Stall 24 no.7:647-650 J'l 164-
1)
1. Dnepropetrovakiy metallurgicheskly institut
sovet narodnogo khozyaystva.
(MIRA. 18:
Pridneprovskiy

TOLSTIOPYAT, A.I.; KAYUROV, V.S., red.; SAYTANIDI, L.D.. tekhred.
[Loading cartridges with buckshot] Snariazhouie patronov
k drobovomu ruzhliu. Moskva, Goe.izd-vo "Yizkalltura i sport,w
1953 P. 130 P. (MIRA 13:7)
(Cartridges)

TOLSTOMAT, A, 1.
Agriculture
Hunting runs and their amunition. ('Ioskva), Fizhulltura i sport, 19.51.
Monthly List of Russian Accessions, Libi-ary of Conptess, November 1952. UNCLASSIMM

LITVINEUKO, A.D., dot'.~jant; ANTONYUK, I.G.; KABARDIN, N.Yo.; -TOLSTOPYA,rov,
-B
Methodology of internal compressing metallo-osteosynthesis with
osteoplasty. Ortop., travm. i protez. 25 no.1:34-38 Ja 164.
(MIRA 17:9)
1. Iz Ukrainskogo instituta ortopedii i travmatologii (dir. - dotsent
I.P.Aldkseyenko, nauchnTj rukovaditell - chlen-korrespondent AM14 SSSR
prof.IF.R.Bogdanov). Adres.avtorov: Kiyev, u1. Vorovskogo, 27,
Institut ortopedii i travmatologii.

FAVORSKAYA, T.A.; TOLSTOPYATOV, G.M.; GALIDING, M.R.
- -
Synthesis and study of the transformations of acetylenic
c4-glycols. Part 9: Molecular rearrangements observed in -
the reactions of 3,4-dimethyl-l-hexyne-3,4-diol with
hydrochloric acid. Zhur. ob. khim. 35 no.4:593-597 Ap 165.
OMIRA 18: 5)
1. Leningradskiy gosudarstvennyy universitet.

PLETAKO' Borrs-i-a-t-Veyevich. Prinimal uchastiye TgPTQEUTff-. -K-S.-
KAGANOT, T.Tu.. red.; TAGIN, A.A., red.izd-va; DOBUZHINSKATA,
L.T., tekhn.red.
(Temperature control and the introduction of automatic control
of thermal processes in heating furnaces] Kontroll temperatury
i avtomatizataiia teplovoi raboty nagrevatelInykh pechei.
Moskva, Gos.nauchno-tekhn.izd-vo lit-ry po chernoi i tavetnoi
metallurgii, 1959. 165 P. (MIRA 13:2)
(Purnacee, Heating) (Thermocouples) (Automatic control)

TOKAREV, V.V.; TOLSTOPYATOV, K.S.; OKUNEV, L.R.
Voltige regulator for supplying measuring circuits of electronic
potentiometers. Sbor.rats.predl.vnedr.v proizv. no-1-37-38 '61.
(MIRA 14:7)
1. Zavod "Elektrostall.11
(Voltage regulators)

TOLSTOPTATOV. N.I.
Fastening of line insulators having annular threads. Avtom.
telem. i eviazi 3 no.1:23 Ja 159. (MIRL 1-2:1)
Is Machallnik Rmbinskoy ~istanteii signalizatsH i avyazi
Nazakhakoy doro I
f3l'iectric insulators and insulation)

TOLSTOPUTPOV. N.I.; MAKAWV, G.T.. inshenqr distanteii
Direct-current converter for automatic block systemo. Aytom., telem.
i eviaz' 2 no.11:22 N. 158.
l.Nachallnik Imbinskey diotantaii signalizataii i avyazi Xazakhokay
doregi. (Ilectric current copverters)
L

T01STOPYATOV. P.I., gorn77 inzh.
Mining steep seams without a haulageway along the coal bed.
U9011 34 no.10:6-7 0 159. (MIRA 13:2)
l.Nachallnik shakhty "Krasny7 Profintern".
(Coal mines and mining)

SHL.'Gk, A.O., prof.; TOLSTOVI-TURO-
Otogenic abscesses of the brain. Vest.otorin. 21 no.3:48-53
my"Je '59. (MIRL 12:9)
1. Iz kliniki bolezney ukha, gorla i nose (zav. - prof.A.0.
Shullga) Orenbi=gskogo meditsinskogo instituta.
(BRAIN, abscess
otogenic, progn. (Rue))
(OTITIS, compl.
brain abscess, progn. (RUB))

TC-1,07GITA, A . G. , C a-,-. d Bio Sci--l ss~ "I t-L.-n I ru, tz
'aacarid.
4 r r,
sici,ificn,not- in 4opC#4- -:I:
rfcctio- L ' v,,v
y n.
16 i,, T) A '- 'J f A "S. L'V-:~v Zoo-V!" Inst) , 15C~ c,:)--i

_IQ,L,5toEYATOLV,-Iv.an--Va-sillyevirl'i; ROMANENKO, V.P.., red, - TSYURKO, M.I.,
tekhn. red.
[Mass-political-vork in sowing] Massovo-politichaskaia rabota na seve;
iz opyta raboty partiinoi organizatsii kolkhoza im. Michm-ina, Ak-
Bulakskogo raiona, Orenburgskoi oblasti. Orenburg, Orenburgskoe knizh-
noe izd-vo. 1960. 23 p. (MIRA 14:12)
(Akbulak District-Sowing)

Y
TOLSTOPATOT, Ve M.
Planirovanie transporta., ZT-he planning of transportationT (In Egorov, K. D.
Proizvoditeltnye sily r-entrallno-pronushiennoi oblasti. lafoskva., 1925, p. 263).
rT,C: HC355-E4
Transport i khoziaistvo. ZTransportation and the econor-,~,7. g. 1- 1926- moswa.
v.(l) fold,map.diagrs.
NN DLG: HE7.T68
Transport i narodnoe khoziaistvo. ffransportation and the national economY7-
ITeperiodicheskie sborniki. ),Toskva, 1923-24. 5 v. in 1. "Collection of a7ticles
and analysis by Mernstein-Kogan and others." Contents- v.l. Transportation and
finances.-v.-2. Transportation as an industry m-aWe =-- v- 3. Transportation problems
In international treaties.-v.4. Poplavskii, 1. A. Estimate of national income from
transportation.-v.50. Railroad rates.-
DLIC: HE255.T7
Transport in the Soviet Union: 1. Reconstruction and development. 2. Expansion and
reform-clektrification of railways. 3. Railways and waterways compared - linking the
great rivers. 4. Road development. 5. Road expandion and airlines. (Modern transportV
Sept 27, v-46, p.9; Oct. 4, P. 111 Oct. 18) P. 11; Nov- 1, P. 13-14; Nov. 15) P. 7,
190.
DLC-. HElJ16
(cont.)

TOLSTOPYATOV, V. if.
Transport in the Soviet Union the five-year plan. (I;oder-n transpost, April 1,
1933, v.29, P. 4).
DBRE DLC: HD,1.'M6
Transport Severnogo Kavkaza. ffransportation in North Caucasus7. Transportnyi,
nauchno-tekhnicheskii i ekenonicheskii zhurnal. Rostov-na-Donu, 192- (monthly).
v. illus., tables. /-Published by~ Direk-tsiia Lljevero-Kavkazskoi zhcleznoi
NN
Transportation and com-mnication. (In Economic review of the Soviet Union, 1934,
monthly-).
LU: HC331-E3
Transportnoe stroitel'stvo. LTransport construction7. TUl', 1931- Moskva, 1931-
v. (1). illus.., maps, diagrs. (monthly).
DLC: HE7.T7
SO: Soviet TransDortation and Communications, A. Bibliography) Library of Conp_,rezsj
Referenee-.Department, Y.ashington.1952.. fn-cla-ssified.-

FAVORSKAYA, T.A.; TOISTOFIATGVj, G.14*
Synthesis and study of transformAttqns of acetylenic6t-gly-
cols. Part 8: 3,4,5.,5-Tatramethyl~.1-he-qne-3,4-dioI and 3--methyl-
1-hexyne-3,4-diol and their trank1prinations under the effect of
concentrated su-Ifuric acid. Zh~r.ob.khim. 33 no-10:316o-3166 o
163e (MIRA 16:11)
1. Leningradskiy gosudarstvennyy universitet.

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P-1 (list 1 .-0 Filloo(SMS
The Ptefliaratlon of pentawthylethanof and the ketol rearrangement of *&wIL&
K
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EA
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RI). .-III thle a
V. M. TivLsiuPvAt,,v. J. Russ. Phys.-Owas. S~w. 62, 1913 tX R
putk-*rIes thearignard sy"thirsisof carbilkits from aldchytks and ketinses L4 Invariably
;I anird fix side rt-actiuns,e. g.,coodew-4tion. Siam (1) can Its
t nn In 141
6 yield from pitiatcolix (11) and MeMsfir or McMgi. this reaction has
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days with Nub -I rry'tn'
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00 a uniattl krtg"ir (IV) which call The removed only fly inany diOrm In k a colorltS =9 0

490 a b,, t(Xl'. d" 0.8971. mol- refraction AN.71. It i,, ttuggewd that tile tip-itt
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for tile rrartungrusent tif It is .1frit'ClIetoMil M. ()lie niol It witli ',~, III-J V "C I s
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to its.). J4St).Vg8' Kove LW% 111. The low Vivid I' 'I'M 110 011 1110111- 11131117111"1 chain -lift
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;
ti.14:12. mol. retract ion M.M. Oxidation id IV with -lf~ K'%1110' gave It and %It-,CCO,
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fissi- O Mr.. N-11licarl -At. tile ill IV Ill.
but no WWI. IV theintflire Is I1r3CCAfe:C11(
117 M' frorn aq. EMU. N11,011.11CI and NaOlf its aq. FtOlf give 2 oxinics: VI. in
734M* (not purified), obtaintd by pouring the reaction mixt. Into HgO. and VIL us.

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Mlled AlcolinlAt" Of 0411111PRIUM and their molecular compounds. 1. Moleculitt
compounds formed by iodomajoeslum alcoholateg with benjaphgnon, &ad Gtbqr
ketones. V, M. ToLs70PYA10V AND B. N. NVIINDLOVA. J. (,eX, Chrm. (11. 8 8, R.) 2,
I04-27(tIMI). --The jenrrally,ifetrilted 1jjtvrpgvjetj,,O 4.1 tile Origilartl
l(It'01 + R"MVX explAill. us-itlict wily fj~'r ll.lw all twg %1s
"mqQ. NvOild to a C0 gloup t, dvounipl. Into --%IgX ami -- W. imr tile hweiialimi ,I
tvttaitt t.v-I1-ttkvt% %if the svnthv~4' C. g'. tile ft-ductunt of tile initial krimic or altithWe
1. tile COSr"j-11,1111K ulc~ Lilpts. ar &.4ktilk-d to show that hAmilgAllenium alcull"lAtri
tonit with PNCO and piaacolune. ntol. compils. of the type RR'C0...%fg(0R'
')X
As the inixcd alcoliolatrs of Mg. Afg(OR)X, are the riul prOduct% 4 tile Crigiiard slyis
thesk, these "14A. Compds- t1sw4t always be (onticil with alilv1sydei and keintwo as ill,
starting 11 y
iialerijbi, vafficularl when the letter arc used ill excess, Thi'k explains th,
lonslaii'll ill %Ome CUWq t4 al'umillid Products Of tile (StissiAld Ivactimis Awl C1,411fi-
Z)mcwl;at tile mcclumis'll (if nannally proxtrashig GrignArd rvactiont. AlLvIiijag-
-%iUln halides Illust also fortil analogous itatil. comtk1s. [it tilLs work tile milrd all-.
were lirvilil. Ily tile action (if the Correquiuding ate. on tile
111"th'"I it i. ilvtv~%try W kll"W C%activ (N. oltlt'.M4~ ill
&ITALLUMICAL LITEIRATLRt CLAWfICIMM
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oll Ill& lulls halide was Ildd. by the luctluxi (it titration with ll,~Alj ((lidituses. ed al.,
00 L. AA, &14)) and I by thr Voils4rd surth.Ad. 1-.101141 was obtaini:41 ill Oil'; yield fly
adding the calc& anti of VtOll to a clarified solu. of litNill in M.U. The -wpn. ,f
00 crystals from the lower layei begins in 2 days anti is complettil its 1; days. Ill
0 some cases inoculation with RtOMXI was rvquilrd to start cryitn. 7rhe ul,prr
layer of HUO contained hlgls in propurtiort to the amt. -A MOMKI crystd. out
00 HWMXl wait also obtained by the action of FtOH oil AfrNIXI in 1-1 SLAYS of cryst".
so EOOMII ... OCPAs was prepd. (a) in I%% ykM by stiMng a mixt_ of F IoNigl ... OlAt
with an ciaw of MCO in W40 wid filtering; (b) in 81% yiOd by adding Ph,&o
00 directly to the reaction mist. obtained by the interaction of Nfe.Nfgf and Etoll. Aft-
All* OMC1, obtaitted as MeUMg1...ORt,, in 75% yield, gave import: AbrO.Ifir ... 0(*Pht
Tite interaction of stormai ituou 4nd MeMKI 111.1 not give 2 IQvCrq or %-I'll of HiS0.11cl.
of bils. oil alldn. %,( 1,111CO 11140AW ... O(Tha brild. Ill 11.7.1*~ Yield. Aftit,t).11(l ,it addil
00 of urt-1111011 to Alchisl is , ropidly depwittA 8, 1;0
a it, 'of,%frjCO.%ljl...0Htj which
gm vt 75% of Ve&CO.Vfl ... OCAPAl Thus the structure of the compoijunt a1c. affecti thv
00 soly~ of the mixed alcoholates of Kig formed. A(rjCQ.Ve,)O.kff1. prvSxi. as the inow,
00 ether %alt in theoretical yield from ahyd. It its rtjO and Nic.Nfgl in Ft.0 quantitativr1%
00 gave Mec(I'VetwAltz., ()(:Ph. CIIAS. BLANC
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linc-tion (nnn 6(ollars. *1114hydex are VAIMIldr, "illiving with
00 a .411*4 alcoholaige of rup"Siuln and their "ftwo
compeatods. 11. molft'Alarcol0powlieformodbylodil. I allnetlum skabagaitta 2 tYpar,a A itiol. vninjuh.:
so 6; Jalchydals and dlkotmts. ROAIAI ... ArCII0 final R0htjrI...2ArCII0. INOM&I
;;1 magiwaium akoholates with Avrrtilova. J-G- in varium privIftartlanis gave only "U01151_111 in -00
06 AriI V. M. Towuptrat- -111. N. -VI ef. (7. A. 27, irM.-The nearly 100% yirld, In. Xquillbrium systartman In the -00
00 Ztw w. S. s. R-1 3, 73 A!I(IfxlA). all. cintim- elhorM edutims of inixed mpealum alcoholat" (io&- 800
I nm,inn 0( 6xlumagfw~ium alanahatal" with B y the
04P alkbr-k (1) arml bell") -nied out h mapeallum skabackles). , V. hl, Totmopyaloy and A. T.
111) in F
Inrilitul pfrTiANNY &~fil". gave with I incal. RuiskaPebuk. Md. It was -bown =00
W1,16-Aid wll%.h was not inv"li- that Meolifill find RIONIxt err kw4 in final that 4411110
11jill a Cal they remet with PhmC0 with thar (mm*f6mi tat life anti.
j SAI"(1, %flat wills aft r4tv-0 -4 HM Ilid. -.Calif.
I nd 1". t hon 2 111411q. 1$1 conlixh. fit McOhfgl ... QCM, anti 0101'hi, &Z 0 0
l1w, 111"Ir thAll
~jr : Willi SitltU*r tests with PO)II, IlmOil. tvtyl. heptyl and octyll
i. Ftill .1 With I 1111itf. 'Aillil 11101, i too
litoNlItI.-J. and with sk-s. prothiced loclonnigneglunt ak-olualatet conipletely sall.
name than I mail. I was flyinnd than
nicAc off acm"pd. with n1tvr than I rm"CAA. aw~mw - in EW, which an the &data. nf Ph,400 gave large ykialf; td .700
Fj,C0NlItl With little 11"w" lbun Incil. of the saine I*tgll ... 3 Ilh.Co. with tire conrslxanaling free
n,,A-. ail I. S**
full save F'-c,()?.fffj ... 1111r. .",I wills :1 nuall. n( HM &W. In 1-.*t.0. Thus, rtintfrary to the mmito e4 the pftvi.
so id %X) fill% study. oil kxtmagtw&Wm slenholat", obtaincil by the ::0 0
I(j,C0xj,lI ... 20,11. the heinit7ohlitim4l in %
1 ~; HuOlilgl
yteki. Duohtsl With I final, ail I live interactioct of magueslunj alkylA with nimmial, primary
#s. in EtA beginning with laiOll file sial. in liftO anti
ttvr with PhsC0 not the 6tol. cmrxk. id the malln"itatu
itkvitolairs.litit the Ph,-
CO. A.
-6 was shown br(otv, the smax ictimnagnmunt sk-t. no 0
hillorc-A rrwt Wif If U Cal ift if itlffrrrnf ly, giving 00% yields "Oo
Doo
:tfllo
1111111
,a 0tt it it ri Q it It M 1114 luo 0 000000*4000 0 4
~00'11661 " Ta, -1-00 -
0 0 0 * 0 * 1 0 6 0 : : : 0
* 0 0 00 a 0 0 0 0 Ole 11111~9 0 0 Ill 0 0 * 0 0 0 0 a a sea,

0
0
0
1
410
00
00
of
0
00
400
It 0
0*60,06
00
00
IS 0
410
41 *
00
410
00
00
00
00
00
00
00
*0
00
00
*0
(if the tjlol~ n1lop(lit" stwh at TIU10141 ... I'hC(WOM aruf
l"Afal ... I'lic0collb. 14XIMISSTIV,4ull) tvtylaic fivivirit
nol1q.wittill,
madoctiurn mkoh'ilafri with J'h,C0 anti with It and
"Whyth,% can only be explained fly the r1tistener In thr
Witt stshm of labite rijuil. qmmc an indmaity"U"I
ak~-holwitr, lisistir.1 hy t W arthwit c-4 sit 6%k-. on imlismse-
tirsium atkyl its RIP twists its a %lair oif valud. wilts a %)mi
kk~hotxte and &lg1,:2lt0%fgI " MCIOR)l + Mcf..
rhe joil(stragnesturn ale,,holates of NtrOll, Ht0ll, Mr,-
C(Af milif perstasnolitylefhanol ve im-wil. In Ft*O; thew -in
,rpn. still# the equil. to the right, givin; tromi yields of the
In the vam AA lW)ll' Run" anti tb~ir
hoitmilitIq with sumnial mitim-lim., the niiiril ;skN)NAA1rv as
wrIl nv N111011), still Mills arr -K11. It' V10, and. little-
fmv. cm Hir 441.1n, is( uldrhydr* Willies, difirfoltr4, vl-%,
ihrlr nor t'WISIM the'roir"Isowliag til4st. colitt"N' with Ihi,
jjj%t-4 almlitilsilev 4rRt with JfXt.. Witen the 2 mA.
s;'ott"I" 41, 04, Its 1011), there 14 fortned no pvt a4 was
1 - raw Its thir Av%lrln 4 orlylafiland a,
't lu, exissirtsm if och equil. mysitcull o( litlited Orolicilderx
in MA) was demonstrated when fnv IWNISI, 1wem. sluil
Imitated by the mctbW of Chelinkrev (C. A. 1F.M111. 30.
"SH4. 19, 1244); BUM. W. (him. 141, 33, 74 1 ( IM I' a?,
..'"llpleltiv WA. 11) F(Sto. save with Pb*CO
Pli'M and with II PrONIKI ... 11. C. Plang
00
*0
00
00
00
to
00
00
41040
0 4p
so
so
0
of
00
so
0 e
00
00
::1
*0
00
09
00000*000000000000000*600000000000000000000 0
"*0000000*000000900900000*eoootooois 00690*40:9~

-
91)
4 1 4 1 1 1 11 11 It 13 M 11 is IF I; it n 33 R A 14 V le , 11 !]a It 3: U )a Is k )I U F. 4 41 41 41 43 f'
ooA A C A l! F is I I- a a 1 -9 x- -"-AA N A
rX -09 At i-A-- 1 t --A
4 010C.1 - -.1- 1.
00
t ~ -.00
a

0 Mixed Zlhplil., of 6=slum and their molettilar
00
0m ds. IV. The a of tertala ketones on
C -
of buty a spesium Iodide In other solution, V. NI. -00
Tolu atov and A. T. Ryskal'chuk. J. Gen. Chem.

0411 -:( - _ ,~-Q. 1148-50(19.79); cf. C. A. 20, 47481.-
00 Th reactio of HuOMgl (1) will: p-MvC.H,COPh (11),
it none (M) and dibentalacetone (IV) in ether was
rried out by the method previously deticribed. Of the
o ketones only 11 gave a mol. compd. Willi Mgt,. III anti
IV
d i
h

0: reacte
n t
e same manner aq aldchyd" anti henzil
to give mol. conipdq. Willi 1. 1 (0.1 mole) Willi 11 (0.15
04a"t mair) gave 24% yield of 31LMItl'. III and IV Willi I
Zell 0
under the same conditinn% gave U1.11, orange-brown (W1%
00 yield) and IV.1, yellow-bfown (88% yield), resp. The
0'31
latter, decompil. with dd. HWSO., gave BuOll and 91 1. WO
TV. John Livak
04

00
00
O
f .00

:3 too
k A S A. S I. A 4111ALLunrICAL 1.11111001 CLASSIFICATICIN It P, a fjo 0

Willi, CWC C'. Is,
--
- "
U is IV No It,
I
o T An 1 s I (W 0 9 - I * 04
~
ii
koft ;fx
lost
!* 0 1111110 0061 all WR
tolli it
(
0 0 0 0 0 0 0 0 6 0 4 6 4 0 1 ^3
0 0 Co 0 a 0 0 0 0 0 0 4 0 4 0 0 0 0 * 0
:
0 0 0 0 !0 0 0 a 0 & 0 0 0 0 0 0 0 4 4 0 0 0 04 0 0 0 0 4 4 0 0 0 4 0 0 0 0 0 0 0 0

goes wool
is
y a 9 In 11 t2 13 u
go
T1 FI-,
000
got
O~e4V~~"" L fewooseemove
e
Y tar -W. fe
IFIF-1 _T:
IS 16 it M 13 U A 16 9 A M C &I Q A) a 4
-1 29 00
A, 0 Ut- A k-, ~ _s
FOCC(Sill AND racorkVil mDfl

Action of ptnalMe on urt-buty1magnesitint crd,,ridc
, :-GO
a. %
.
__Mn Opyalsov and I. V,
Mtvad State rITIM11. J. Gm, Ukemi. fUS ~;.W) 15,
E1.0 -1n. (615
jv,)0-M g.1er1-IJu%fxCl wa4 Irrtmil.with ,lirriug anclive
NM*i.~ 3 hre., with 37.5 11. phsart-how (1) lit 110 cc.
RiO: after,afirfing ItIr I hr. the utiAt. IAa% livated with
10% 1119(h to give Is K. 'Wighlal I R11.1 30P" 2.ZT.f;,N-
-3-kepon-3-ople, tj,, W J11YA'. if: O.-Old. if.",
pentaROdhe
' 'go
(ftom aq. MtOll). When the upt. was -e-
pe",with equimolar anits. of rriiVvits, there was of.-
taiDed.43% of unlrelllCtM 1, 411.1 4 1"', $4 the 81MV 44-111111-
aml. "I
1wPM11-14-d-Ow" If 1 14 li-wil ill 13 Y,, V%1 cii, 20''i Zoe
I Is recovinvd, with Immailt,is #if q a mill.
of the above kittaue slid keto ale., with ev,dutiun 0
W which was ri,clivrrof after jm-~Ige thrWIll fir milia. cc 0 o
the rcactimi gives 30.5~ t1firractcd 1, 19.5';; lylak..
'
'
b. 110-11.)*. zind 50'~*O
abi've tjn~ld. unw. '111'.
( the
~
zoo
reaction tims procceds ill 3 if rectimis; citulizaliton, rcalut -
i
tion, and condensation; aij addil. rcartiiin faiI3 (u mam. go
fc-t itself altogether. G. M. Koof1LjXM
A S a I L A a[TALL%IltGKAL LITFRAIURE CLAS11FKAUCH
u 1 0 3 11
11 It 99 99 It a tt It cc fl
too
12-
-~Tl;t _20~
Vim,
.11111 CO all Ail
n An
I ?m 0 4 2 1 N

TOMTOPYATOY, V.M., professor.
"Organizing the transportation of large masses of earth." N.D. Averin.
Reviewed by Tolstopyatov. Mekh.stroi. 10 no.5:31 M,,f '53.
I (MLRA 6:6)
(Earthwork) (Averin, Nikolai Dmitrievich)

TOLSTOPYATOV, P.I., gorMy Inzhener.
I - ~ --~ -a . -
Automatic Milng-loading car. U901' 31 no.11:35 N '56.
(MLRA 10:2)
1. Shakhta "Krasnyy Profintern."
(Coal-handling machinery)

jj~
U
*0 4 f, A*kJm-"t"L---
76,
~pf 010000
R&
AN!
Yom
ww, DmAA FFjww5wj by 4fkit"
go*
Uwe
A% At.! L.~ UIALLU"ICAL LIVINATURt CILALISFICATICIN WOO
glow 61 IN %DORI w"InT
sajawo MAP O"T avc NIALS1 OW 0-1 All
to's
u 1jilLf TIZAAni %a ado W #jWIWqaQ 319 V
a AT 00 9, ;lot; 0141;4 ;- I A 'n A
it 1 14 94,9 0
0 0 0 0 0 0 * 6 0 0 a 0 0 0 el

-0 0 a a a a a 0 0
0 a 0 0 0
0 a * * a 0 0 6 9 4 0 0 0 0
IY I a 1 6 a I Ia it u U u Is 14 11 m 11 x j it a 23 'U a 93 Jd 0Is V A 0 4 4- 41 &1 a dt 0
A&-~L- A-Z W- L-L-J A -P -j---j--rAjq 0
AP I- .. --- -- ..P ". - I -
.-so
00
90
0 00
-00
00 of
of t The effect of various smotilits of Moisture of the son an -00
the -Auses"m Of Rk*t1n* 16 tobacco i"Yea. A, Va.
"roistapw- rabackmayu prum. 193j, No.
0 a c!. C. A - SO, 14W."-The effect of irrigation on the'TnkQ- =at
tine content of various types of tob
.3 accul grown in Russil\ roe
is presented in curves. Ninety % Sam. of the "I
Irnds to lowff the nicotine content or all types of lotmtw.
MAXiMS and mbilins of irrigatim are given. A. A. It.
coo
00 -a ago
00 X1
009 coo
i ISO@
as
No*
as
i-.j Aj..SLA .1TALLUPOCAL LIVIIIATOP. CLASSIFICATIC14
-3~ Vi~.-' I I I .--.. - I -- - - -- .. - I ~ -- - - - - - --- - --.- - - -.1- 1
00 8~
0111JI01C,
Iti TI I lee
-A
Z- X r 0 1 If 64 5A 0 3 4 V
U. ap K K x n it it a
0 0 0:0 a 0 a 0 0 : a 0 0 0 0 0 go 0 0 0 oic 0 0 0 0 0 0
0 0 0 0 *;a 0 * 0 0 0 to 0000 go* 0 0 *is 0 C 0 0 0 00000 0 Oi/
I/

0 0_0 of a 0 0 0 0 0 0 0 0 0 a 0 4
4 w vi 1: U 14 It Is I? Is It 11fi4maholog m P uu 6"s lip Uplo" 040 ms~~O*
A, 8--", 4 - A _L_ V. .. . -1 W icc cc A-A.. ii & 0
I-so
0* J, A! 1. Mw raqwnwaft in won died hrof"m fw dw do- 4
gunwatlas *(&wefts boom " d Nkcd~ , Is
so 'A www"m (a dw kr4pbd G" fm dw Wa4w Vve togtoa
009 -40
rop t 00
toodlikes are cthe
N"idws tsakds neatly.
A A Rnrhtfiack
43
VAIALLUSINICAt LITINAIWI CLAHIMATICIN
.00
A500
off
coo
Joe 0
xOO
No*
=be
tto 0
-#T'ir
Iff
0 6 4
0 0 0 0 0 Ole 0 0,0.0. 0 1'0 60- 0-

6060906000069 00 0 40 0Ole O's
00*40090660960 09 0 0.0 4 0 0 a 0 0 6 0 i--46-0-g W
it a 24 v 'S ".): Jill Ifis lip ooob& v 2
�.t tab"
A I v P. AA
I I I

*XrlMVntS 00 WS 4411110toVe Phoorloolena
LAbors4T
so .4, ,
occurring d tutorials with bitumen., H. V, Tol.

n.
LIMN, bess and.%everal kinds of clays Ire treated
0 with bilutitest dissolvcd in toluene and the adsorinion was
detil. by washing the snateriAl with t(Iturne. The ad-
sortord hilumen couk! isot be F"mvvd two by peolooligrd
w"filusivilk4oluew.
00 Itti-41% rglunictated dcptuds Qn the %:IAy fmcii,ml. of The

so jr! corillitumls of bituorwrl adsorbed the asphaltenes tollic
`
6
1
11t; tbev are followed by worlaill quaijillics of jar, but to

so zi toil h adstirbed. With a decreAst in the hygraw"icity a
t Uk material the quantity of bitumen adsorbed Increases

00 jz~ .

/The adsorption aho depends on the tyW of arAvent, The
00 0: q1tartlity of bitumm adsorbed by the fractiort ins than
0-00i min. is aboul 3%. although in some cam It might be
so j as high as ".5%. S. loge

PO

0.11
U n !70
-00
-00
-00
.-so
-0*
go
P.0 0
=40 0
zoo
zoo
AD 0
so
.,so
-4
At*
Leo
t
-64 -a
to to It 9p 0M11, It% Ytttrt Itot'Ll3n Ila
00000000000toooooooo*0*0000000000000000
XL 00- 61.0."001"0" 0 000 0 0 0 0 0 *0 0 0 0 0 0 0 0 0 0,0 0 00 of 0 0 * 0 0 0 0 0 0g0

-Aj -#;A 0 0 0 9 0 0 0 0 * 0 0 C 0
0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 a
0 0 0 0 0 6 09
41 1
11,10 Is 1. 0 It It0 ISO loll Boost vil"IMP'O
I I, to if of if Is III
A It-4 11--it -1111 'k I ~ 0 ,
**A I, a.0 -rdos. I. -Dill.
go :-so
go,
sea
The blem of electrochemical treatment of the tround.
IV Pedvidu (F. S S. H-) 1940. No
v , -a'
1?-%A~d through quartz, Clit-rilotrill. moraine I-killi and Zoe
I'lle Illj- ", Iliad,- III, It, the Z
crivot it, a 12 ~ I.., X-N cm. I he so
CIV I X 8 rill. ,I AI and Co. I [it- , ottvill wa, roe
tintil the ru~"tallvw- inerca-l to a high PAIlt. 'Uhr Pil.
Fe, Ca all.] Mg, A,i WvII it., vxvIIAnKeahIC ions, Wt-ft.
d0d. art valiou, Itoilits ill the 'rhr rffc,,. .,I III,.
ditin. chang" on the btructurt: anti otlt,,r phy~. I)rOlk-Ft it,
were noted.
iviv
1:196
~-LA &ETALLURGICAL LITERATURE CLAISPICATION uz -zv..='
W
'lee
-vi W.
"a.. Ill 400
An j, s a rw 0 9 9 1 W 14 5 JCI a 3 0
a, ZIP t*r CIO 419 KI
u 5 AT 10 It 11 -C Ct uit
* : g . so
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 9 Ole * 0 0 0 0 0 0 0 o 0 0 0 o 0 0 * * *19 0 0 0 0 0 0 4 a o 4 0 0 0 0 off

Is if M Jul sin Us: will IOU 004 so
A
I as A-- a I A 9 4 &$a$,"
s
4"Q IN ONO!*1 .00 ..n r.
"
1
4 z-1
;-so
-00
if

00 a Water pornairability of b1tumfiaous materials. 11, V.

'
'
-99
t' ~
sINY Poror No. 1. 15 111(lik
yatov, .9ruatel
V t3iOii: show that water Prn4trvitrs tilack bindull
materials by diffuslion said forms microscopic drops. The
content of water in thin layers of oil bitumen lncrra,&,

l*
withtime. Addn. to the bituanta of selts or fine day
c
'S tkin stimulates The difftWon of (be wafer. The c
r
irnd-
henomenon Is
arter of the diffusion
racticWl
inde no*
p
p
y
p
ent of the chem. nature of the mineral components in
!1111011111
00 the asphalt tuixt. H. Z. Kamich
COO
90
00

400
451111411

ji
t:4 0

if-SLA
SETLLLUNGKAL LITERATUNI CLASSO'KATICIN too 0
Naomi NINON,

s4noss -0 1 0.9
-
fill" -Gm- &I1
U 1A AT NO al,,
at of If K tr ; It 0 0
9 1 Is 0 9 AS 4 31 1
F
IN

o,
48 **go**
OT

:
:
0-00- 4111011111041111-1110 0-0 IS 0*0 *** O
, Ole 0
0 00 4 4 0 0 000 0 ISS o4

goo 0 0 0 0 0 0 a 0-0
Sol j L a 0 r Q it I I v I I L AA Irt rt; it
Soil stabilitation and its efectrokinstic polontial. F V
I N'~ A M,Ak-im-hl,
11W41.
o -.1 Nml 0 ..1
ck-ctromAtiv ctiniflimm. The v1e,-trAmvttc 1-fetimal i% -1 .00
I ~n%vtsvr and cuqily determatiable ind"tur. By lowermt
the clertrokinctic lm)tentW #4 the w)tl (he hydratims c4-
d parity dccrraws. B. Z. Kaillicls =0 0
A 0
00
oil
oil
A 0 - S L ANETALLURGICAL LITIOAT01 CLASSIFICATION f I
A
IT-
u IV -1-0 111
.' ", ; ' s, 11 ", *19 it It at It 1.14 -11
0 0:0 0 0 0 0 0 0 0 0 0 0 0 0 0 *10 0 0 ; 0 0 0 * a a ~ * 0 ; 0 0 * 0 0 0
40 4 0 0 0 ois 0 0 0 0 0 0 0 4 0 41 9 0 0 0 0 0 9 *~* 0 0 41 a 0 a 0 0 4 0 0 4 0 4 0 0

a c 9 IF G If X L A 0 F T w 30 It 2 V 31 A 36 1? V 30 4 A a a 4m
IS itA a k
43
100 ~Lf t I it Ito &%D 4t" 040129 V. Olt I
~61
IV3004411tive VIIINIV
00R
IA
DO 'AOGVAII V
*d'
:0. 0 #plow Aqw
2411 141 I'll, i I a
pp-,Zww; ofi~ ,que. 00
IMAIN apy"
impaw
JO Poo
numpow. 9 Ropq 00,
040
am
Do-
*WA r 00
so-
so. 00
Do-
'so
00
It
eggs It a 61" #1 if 't TT
000
00000000000 1 0 0 0 0 0 0.0 0.4) a
-000000009099

0.0
It UO
at a a
-_2 1 - U a
0* A
"060CMIS &AID 1,440911111S tMols
00 v .00
040 000
Cokbd
--a -ft -,-do V_ mi"AdAll .00
00 11~7 TL -
00 01 Vwl "Wive Isus"Ad on ~ad
00 dw Akahal . do*
w"m , , %Owlrlpww4l, ".
BORK. _M~l I- w _414"I 1*0
00 1 ale" - OIL ~'vm_ -adeld- .00
00
SINU1016LUM
400
At
t zoo
0o
Wd .800
0 a A BOUX
a both PeOH and POOR 900
0
-Vai for Pr"OH and 100
00 u W, 8, 671 40 -416; POOH,fekkft*dj that f0i'MOR uA tbum, Cos
cf. A.; IW7,-1,673);-Vl. The tompAndn
so X swdeaft of
Ou MPOI'l~'ium`aM;Y, 'the Mentation ~ol'lhe~ worg. of the
0 the rebtfive sUy of the 140 moL, -*M Ufa wtim -Omt alwhoh; on the smrfim'of the catab* is z see
surfim at temp. m-2w-W, h" bumampaimeaWly d&W. qO a
dommittuted. ~ ~. I - :, -~,' .: i - . Ix 7be Wfluetwe of He Substituefits*On the wti, 1111149
VU. -The dehydratim of EtOH by 0 the
equsuci:t rviouly obtahted for At' I" Stjon -kohol. ;10 0
ohydro- hae bein
genstion a EtOH (A., 1936, 1. 1472). The ratio W.- R. A.
I too
%/a of the adwtption coeffs. of B~O to that of RtOR NO 0
st is O.M.
too
coo
I L 1.17911AILORE CLASUPICATION
too., 410.14V 0
%.n0 5 A talcaj -it 0.1 04C 49ASSI anc a- 1" 0
U AV -0 V_A_~ a An L SO two MINIMIllead I's q
0 as a IC 49 No A I Iral
0 0 0 * It 0 0 * 0 0 0 0 0 0 0 0 0 0 411 0 0 0 0 0
0 00 : IV* 00 *0 106 so 0 0 0 6 0 - 0 : 6 ,, 0 0 0-0 0 o 4 0 0 0 0 0 0 a 0 0 00

bases 060000410OW's
0606f RMS sees 9
ooo*#0 #**see 000909606 ;

t
is NACLXRIAII Uzi big
a u 0
Al v *so 41 a a

114 f
A- L-k ~ I'
o

e, 0A
it bb 040# at

-0 0

so
so
of a@ qft"ty .00
of "Dim. vu. Kww" of the 41tAydividan 0(
66
IN 41101hIM IlMe. A
Xh
Dock and A
A

d

l -
-
.
.
Ads phyak"". '. S. 8. 677-W
T= V. R. S
I
m
T

l
00 a T
0
he I of RtUH ZAIA atte" the
f
or
(C. A. Al OW) The m

of
6 IS #h~j Oi &O the of
tk,
R 11, adw
VIW-

885 is o
m
VI .00

e
g
e .
.
L
agabAtk ak*Ws n

0001 and isco-PtOff do IW

PrOH and kw4PoMj IMO dw ftwe cl
01/0, for
wWmtj
j
i
h
06 m
w
t
t t for lijoll &n1l
PregINNOW'0111 Otitated.0 of the m4i
of III,
00, .
diff- t a- --the VAdWe of the Cat&l
a i
q
il S
M
af.
y
041 Oway "balft"fis ft tb* Activation '00
me Suphatic doelbala CJRI. I to
an ohm"Imm 6Q. (Ml~-113--,nie innurmv t)i roe
hit
0 ir,91 Suhnt"Auts 02 tbG WSIVRtion factu of the dchydra.
I im a( 6 Aulthatic SkAuls w" elp"Imentally Int,"glauted. 000
C. P. A.
'00
av 81 Qj, it,
T r .. . . . ., i v
ado
u a AT to it
00 41 cr 00
V 00 000 0 0 00
o a 0 a 0 0 4b 0 9

%1~1121
TOLSTOPJATOV, V,. M.
w5ur lee alcoolates mixtes do magnesiim at
i. at II&Ak2MLA leurB COMPOses moleculaires. Memoire IV.9
Tai~ tv~ (.1p. 1.14,S)
SO: Journal of General Ch I t
go ry
mii) 1939, Volume 9, #12

TO
I-S-1,31'~r-TOVA, A. .1"
A. A. G. 1% A. A. Toisto-zly-ptava
"The F~-rolysis of Lth.-lbenzene and Styrene." Jour-nal of Applied C- --4str-
..e - " -, ,
19, 1079-92, Iloverber 1946, Mloscow, Ldborator-T for OrEr"Mic Catalysins, of ll-he
University wid Institute for Organic Chem-str, ~ . L --
y of the Acade-,V of Sci ences.
D-5005"

A.
Kinetics of the catalytic formation and decomposition of styrene.
A. A. Balandin and A A Tole nova (Acad. Sci. U.S.S.R. and
-a -77 -9-2 (1947)
Moscow 8tM--Univ.). J. Gen. Chem. kU.S.S.R.) 17, 2 2
(in Russian); cf. C.A. 41, 5117i.-In order to det. quantitativqy
the yields of PhCH:CH2 from PhEt as a function of temp., space velocity,
and time of contact) 30-min. runs were made under rigorously controlled
conditions with catalyst off medium activity, regenerated at frequent
intervals for just the time necessary (15-25 min.) to keep the activity
unchanged; this was checked by standard runs, before and after each
expt., with 273 ml. liquid PhEt/l. catalyst/hr..,
PhEt:CO2 '- at the given temp. With frequent short regen-
erations, one portion of the catalyst kept a const. activity during
78-80 runs The contents x of PhCH-.CH2 in the condensate were corrected
in each ca;e for the slight difference between the actual activity
of the catalyst in the main run and'.that shown in the 2 control runs,
and refer consequently to the same activity. In a special 7-hr.
expt. at 6500, it was ascertained that the condensate contains only
PhCH:CH2 and unreacted PhEt. At 55oO and 5750., with 20ml., 7 am-of
catalyst,, diln. PhEt:C02 = 1:2 mols., increase of the space velocity
resulted in rapid decrease f xV. g., at 5500, 100 and 5oo mi./i./h4.,
x n 70 and 30% resp.; at 540) and 34.5%, resp.; the 2 curves
(550 and 5750) intersect at about 150ml./l./hr., x - 48.5%. At 65oO.
x first increases with increasing space velocity, passes through a
"Ou
very flat =m. (x about 46% t b t 380 ml./l./br.., then slowly
decreases, to 33% at 2293 2-N-7hre- Correspondingly, plots of x

Bee.; this evidently is due to rapid consumption of the 0. through
reaction with the H2 formed. IT. Thon

1 LL6 ilu f Y :1- - I ~- V -t4 , A . A .
Vorbatim: - "Model structures and catalysis. The comparative catalytic activity
of fluorine5 of alkA!i and alkaline earth metalsol' Vestrdk MoF7k. un-ta, 1948
No. 12, p. 75-83, - Bibliog; p. 83
SO: U-4355, 14 August 53, (Letopis 'Zhurnal Inykh Statey, No. 15, 1949.)

70LSTCHAWTVA, A. A.
USSR/Chemistry - ;3enzene, Ethyl May 48
Chemistry - Dehydrogenation, Speed of
"Studies of the Speed of Dehydrogenation of Ethylbenzene in Its Binarv rixture -dit~-,
Styrene, Toluene and 3en%enepll A. A. Balandin, Inst Org Chem Acad Sbi Us'sR, A. A.
7blstopyatova, Lab Org Catalysts, Chem Faculty, P'loscow State U, % pp
"Zhur Obshch Khin" Vol XVIII (LXXX), No 5
'A uring
Method used was to investigate adsorption on active surface of catalyst by meas
the speed of reaction. It was found that, during the dehydrogenation process,
ethylbenzene is absorbed more than toluene and benzene but less than the'product, styrene.
Models of the reaction complexes were constructed, r7,iving the orientation of the
absorbed hydrocarbons relative to the surf-ice of the crystalline catalyst.
Submitted 1 Nov 1946.
PA 8/49T59

CA
mf~r* 9 d dence of the retv of dthydroornstilm of
,Ioh= A, A~ T-44topii-mova. L A~ kiti,litt..
th~7
V. 'Sta*- tniv.s. 1. ell"fk
lf,,Ifer. Vivir. 6. No. 2, Ser. Fjj..Ildl. i 1,,ifejtiyx. Nauk
No 1. a 28~70 I't caul"t, the tate of
l-vi,lutimi of 11, froin methyleyclubexane pa%,iftl 4t floi
mi./fisin. dg" not %-ary with file prri,iiiw 1w1wrint, 27 mill.
lix "Ifil I atilt. With 0,05 s. rmaly,f. the ratri %%rrr, m
ZVI' in-I 31W. temp., 9.5 atul VIA ce. (.,;.T.1', M, I lmo.
'Fili, 111.1riwil.11,11cr vf file pir,me indii-mc-t 0.111-
f4ete stirfAce roventge. The actiwAtkwi energy. between
L'10 and 275", was detd. (on 0.6 r~ cutalyst) to be 19.2
kmj./Mole. N. Thou

JvL
u S S
cinponents of the activation eneiij wn~a tlWproblem of
1cho6oslng catalysts A. A. Unlanditi und-A, Tol,ton
7
(ova CW. V. Lc
k-Y.S.-S
;iRM4w7V4fj -.R. N1;AN4;'.TiPT ~41..;27
-The activation energy for a cutalytic reaction can he --cpd.
Into component parts consisting of the bindlull energy of the
reRcting atoms with the catalyst 'rhese values Lan be
deld. by the kinetic method des;Ibcd eaTlk-r by B. T'he
Pplibility of this ruethod is proved by the following reac-
tions: (a) dehydrogenation of hydrocarbons, (b) dehydro-
genation of ales., and (c) dehydration of ales. 7lic caudyst Af","
was (N-.0j. 1. Rovtar LeacIL_

mmv

BAIANDI14 A.A.; TOIASTOPYATOVA
Kinetic determination of bond energies as an approach to the
theory of the selection of catalysts. Part 2. Comparison of re-
sults with chromia [with Znglish summary in insert]. Zhur.'fiz.
khim. 30 no-7:1636-1646 J1 '56. (MLRA 9:11)
1. Akademiya nauk SSSR, Institut organicheskoy khImii imeni N.D.
Zelinskogo, Moskovskiy gosudarstvennyy universitet Imeni M.V.
Lomonosova, Moskva.
(Chromium oxides) (Catalysts)

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AUTHORS. Tolstopyatova, A. A., Balandin, A. A., SOV/62-58-10-4/25
TITLE: Kinetic Determination of the Binding Energies With the
Chromium Oxide Catalyst.(Kineticheakoye opredeleniye
energiy svyazi s katalizatorom okis' khroma)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdaleniyo khimicheakikh nauk,
1958, Nr 100 PP 1184-1191 (US.9R)
ABSTRACT: In the present paper the authors investigated the
dehydrogenation and dehydration kinetics of isopropyl alcohol
as well as the dehydrogenation of cyclohexane on chromium
oxide (obtained by annealing ammonium bichromate). The authors
found the relative adsorption coefficient of acetone and
hydrogen. They also determined the activation energy of the
reactions of the dehydrogenation and dehydration of isopropyl
alcohol, as well as of the dehydrogenation of cyclohexane.
The binding energies of the atoms reacting in the molecule
with the catalyst were determined. The authors also compared
the catalytic properties of chromium oxide produced by other
Card 1/2 methods with those described already. There are 6 figures,

Kinetic Determination of the Binding Energies With SOV/62-58-10-4/25
the Chromium Oxide Catalyst
9 tables, and 12 references, 11 of which are Soviet.
ASSOCIATIONt Moskovskiy gosudaretvennyy universitet im. M.V. LomonoGova
i Institut organicheakoy khimii im. N.D. Zolinskogo Akademii
nauk SSSR. (Mosoow State University imeni M. V. Lomonosov.
and Institute of Organic Chemistry imeni N. D. Zelinskiy
of the Academy of Sciences USSR)
SUBMITTED: April 2, 1957
Card 2/2

1; ~. ~'. R _; .1.1 /_ 72_~4 17157
Toistopyatova, A. 73slandin, A. A., "Y '7~-
TITL~".- The Catalytic Properties of Cerium Dioxide in the Dehydra-
tion and Dehydrogenation of Alcohols and in the Dehydro-
genation of Cyclohexane (Kataliticheskiye svoystva dvuokisi
tseriya v otnoshenii reaktsiy legidrogenizatsii i
degidratat3ii 3pirtov i degidrop,,enizataii tsi.klogeksana)
PERIODICAL: Zhurnal fizicheskoy khimii, 1958, Vol, 32, Nr 8,
PP. 1831-1841 (USSR)
ABSTRACT: In the introduction publications in the field mentioned in
the title are mentioned, among them are those by Cremer
(Kremer) (Ref 8). In the present paper methanol, ethanol,
n-propanol and isopropanol, and cyclohcxane were investigated-
The authors described the apparatus used, the initial 3ubstan-
ces as well as the preparation of the catalyst, ani the ex-
perimental technioue. 'the dehydrogenation of cyclohexane was
carried out at 496-5480C, that of methanol at 299--;cdaOC, t,hat
of ethanol at 311-36630C, that of n-prODanol at 315-3600C, an!
the simultaneous dehydrogenatien and dehydration of isopro-
pariol wns carried out at 307-1690C. Individual datlt (~a.3, for
Card 1/3

The Catalytic Properties of Cerium Dioxide in the SEC'! If 7 6 -z 2 - 8 - 17.
Den,ydration and Duhydrogenation of Alcohols and in the Dehydrogenation of
C,ycloh,-_,xanQ
Card 2/3
example, tho activation energies) and the results obtained
are given separately for each single investigation, as well
as tables containing the experimental results. Determinations
of the binding energy of C, H and 0 with CeO 2 were carried out,
with data by Cottrell (Kotrall) (Ref 16) being used. A com-
parison of the values obtain3d of the activation energy
(except for methanol) shows that it is smaller in the case of
secondary alcohols than with primary alcohols, and that it in-
creases with a lengthening of the chain. The assumption by
Palmer and Constable (Pal:mer and Konstebl) rRef 17) arp:u3d
upon by A.Kh. Bork (Ref 18) was disproved by the observations
made by G.F. 3ogdanova, A.A. Balandin and A.P. Shcheglova
(Ref 19) as well as by those mentioned above. "he adsorption
potential of the catalyst decreases according to the increasz?
of the activation energy; this causes the rcaction to take
place with greater difficulty. Sone oxplAnations on the
binding energies are given. L.S. Aevenkc, Laboratory Jorker,
participated in the experiments.

The Catalytic Properties of Cerium Dioxide in the SOV/76-32-8-17/37
Dehydration and Dehydrogenation ef Alcohols and in the L-chydrogenation of
Cycloh~2xane
5 figures, 7 tables, and 23 references, 11 of
wl-~'X'fi ar:~ Soviet.
nauk jS3R)Institut organicheskoy I-.himii im. N.D.
v;1 (AO '~.S_-:H)inotitute of Or,-L-nic Chemistry
i-n-2ni ..Ioscovv~
Card 3/3

AUTHORS: Balandin, A. A. , lie-111-ler, Acadeny of 3z OV/ 2 2 2 - 2 - 17 // 2
;1-
rpeyskaya, Ye. I., Tolstopyalova, A. A.
Sciences, USSR, Ka-
TITLE: Investigation of the Catalytic Dehydrogenation of
Hydrocarbons and Alcohols Over Metallic Rhenium (Issiedovaniye
kataliticheskoy degidrogenizatsii uglevodorodov i spirtov
nad metallicheskim reniyem)
PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol 122, Ur 2,
pp 227-230 (USSR)
ABSTRACT: In recentyears more attention has been given to the
investi,~;ation and the use of rhenium above all to
the determination of its catalytic properties. The
authors extended their investigations beyond the ~.ubject
mentioned in the title ( a review Ref 1). Accordini., to
the multiplet-theory of catallysis a lattice of the
catalyst of the Al or A3-type and an atomic radius
r within a rant--e of from 1,22 to 1,39 A in nocennitry
for the dehydroC;enation of the sextet-type (Ref 2).
Later it was known that metallic rhenium has an A3-lattice
and an atomic radius of 1,368 R. Thus, it corresponds
Cai,d 1/3 to the above require-,.-,ents and must theoretically be able

Investil-ation of the Catalytic Deh.-ydroCenation of H1,,;-dr-,- SOV,"2o-1122-2--1.7/42
a I
carbons and Alcohols Over Metallic Rhenium
to dehydrogenate catalytically 6-membered hydro-
carbons. The structure and the atomic radius of rhenium
sazisfy the principle of the maintenance of the valent
an-le of the multiplet-theory (Rei's 3,4); for this
reason rhenium may also serve as catalyst for the
dehydroGenation of hydrocarbons and alcohols according
Uo the doublet-mechanism. The mentioned catalytic
properties were experimentally only insufficiently in-
vesti,r,rated (Refs 5,7,B). Above all, the experiment-al
details as well as the method of production of the
catalyst are unknown. For this reason the luthors made
tile present investi.--Itions. It was proved by the authors
that rhenium applic~d on coal yields an active clutalyst of
dchydroL;enat ion of cyclohexane and its homolo,,-s, cumene,
as well as of the debydrocyclization of n-heptane. On
the rhenium catalysts produced by the authorc also 0
alcohol-dehydro,---enation takes place between 120 and 300
as well as the converoion of butane-diol-1,4 into d-
butyrolactone..There are 4 tables and 13 references,
Card 2/3 9 of which are Soviet.

Investi,,-ation of the Catalytic Dehydrogenation of Hy~lro- S07/2o-122-2-17/42
carbons ~---,nd Alcohols Over L~etallic Rhenium
ATION: Institut organicheskoy 1:himii im. N.D.ZelinskoE;o Ak!~demi
nauk SSSR (Institute of Oroanic Chemistry imeni IT.D.
Z(-lin.,.il:iy, AS USSR)
SUBI.,IITTED: July 16, 1958
Card 3/3

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5 (3) :,07/55~59-31-20/32
AUTHOR: Jolatopyatora,_A, A.
TITLEs The Work Performed by A. A. Ba lar 01in in the Field of
Heterogeneous Catalysjs'~
PERIODICALs ve
ewnik Moak-avskogo univeraiteta. Seriya matematiki, mekhaniki,
astronomii, fiziki, khimii, 1959, Nr 3, PP 159 - 169 (USSR)
ABSTRACT: This article was published on the occasion of the 60th birth-
day of A. A. Balandin (December 20p '1958)- It gives a survey
of the more than 500 papers by this scientistg and mentions
the following v!i>rke whi,.,:h are -based on the iniltiplet theory
of catalysis developed by hims De'~ijEARogei!LLtionlof six-mem-
bered ~ycli-, hydro