SCIENTIFIC ABSTRACT VAVILOV, V.S. - VAVILOV, V.S.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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;octri, A SSGCl ATION SU N.'. TTTF.P: Card i 'i 273W I ':'~/0091/cJ32,1034 I I/n 102 1,11 S3SR, !,'oqkvF, Lebvdc~v AS USSR, Moscow) mwVa LC -'0769 5/181/61/003/oll,'001/056 3102/B1 38 AUTHORS; Plotnikov, A. F.,,Vavilov, V. S., ana Smirnov, L. S. TITLEs Kinetics of photoconductivity in p-type neutron-irradiated silicon PERIODICALs Fizika tverdogo tela, v. 3, no. 11, 1961, 3253 - 3259 TEXT: The defeat formation due to fast-neutron irradiation was investi- gated in single crystals of p.~type silicon. The specimens used had been described by the authors in an earlier paper (FTT, 8, ig6i).. The defect level system arising due to the fa8t-neutron irradiation in the forbidden band is shown in Fig. 1. The photoconductivity investigated was that connected with the electron transitions to the levelq E.,+0-30 ev, EV + 0.38 ey and Ev + 0.45 ev. Temperature was around IOOOK. Tho olec- tron was excited by steep-sided light pulses with rise and 'decay times of 5 gaec each. Photoconduction rolaxation was studied separately for each level by two independent methods. Ev + 0.30 .:vt (I)Um build-up time 4p,, of photoconductivity was found at 4p-po on an 3HO-1(ENO-I) oscillcecope. Card 1/4 3y~~9 3/ 1 1/0 5 6 Kinetics of photoconductivity in ... B102/B138 m , the initial electron concentration at level ,!, .,:as found t-s 'ne 0 12 -14 2 kf8e 10 cm and cr p4U3 -10 cm was determined for the hole trap)ing cross section. (2) The build-up curves 6pM -f(t) were investi&-.'.-i.,! for Po),&p. It was confirmed that the building is govornnd br i.,.a expo- nential law. The parameters of the centers were found to m Pil 13, -3 -14 2 0 - 0 cm 2 clp*;* 3 ' 10 cm (first illumination) and mf~41013cm-3 P aP%""-5 ' 10 14cm (second illur,',.ation). E. + 0-38 ev, (i) Recording of the relaxation ,~3 8 - 10 3CM-3 08CM-3 pulses without constant illumination for Pole and 6PP43- I yieldedt m qIev1O9cm_3. sec- 1 and a N5 '10-17em2. (2) Recording of Apbn 0 P1 -3 8 -3) yieldeds with constant illumination (POI~46* 1c, cm and 6P-*13 -10 cm MoqIrj1O9cM_3 . sec-1 and a PIR-17 * 10-17CM2. (q - capture cross section of a photon by an electron at the level MI I - intensity of exciting light.) EV + 0.45 ev: 4Pbn was studied as a function of time. It was found that for t < 0.2 sec carriers localized at centers with Ev+ 0-30 ev Card 2/4 31~81761/oO3/011/001/o=/6 Kinetico of photoconductivity in B102/B138 and for 0.2 ~t( 0.6 aec carriers localized at E + 0-38 ev participqted v in relaxation. Por t> 0.6 see the carriers taking part in ;7elaxation j were localized in centers with the following parameterss f410-17 2 9 -3 cm an~ m qI - 10 am see they belong to the (E + 0,45 ev) P 0 v level. Finally the relaxotion of photoconductivity was studied which was connected.with electron transitions from the valence band to the (BV - 0.16 ev) level. This level was found tobe an effective electron 'i a cross section of (I tv1O -13-10-15 2. trap, witl 1 -19 ' 2 cm For holes the trapping cross section was only " 10 cm . Resulti Exposure of high-purity p-type siligon specimens (resistivity ~ -110 ohm-cm; oxygen contenti ~V5'1015cm-3; hole concentration in the darks 8*108CM-31 Fermi leveli 0.2 0.) ev distant from the edge of the valence band) to a fast-neutron flux 13 2) 14 3 r410 n/cm with Pyl Mev led to the appearance qfrvIO defects /Cm in the forbidden band. The authors thank B. M. Vul, S. M. Ryvkin, L. D. Paritskiy, I. D. Yaroshetskiy, G. N. Galkin and B. S. Kopylovskiy Card 3/4 30769 S/161/61/003/011/)01/056 Kinetics of photoconductivity in ... B102/B138 for remarks, critics and help. There are 10 figures and 5 referencess 4 Soviet and I non-Soviet. ASSOCIATIONt Fizicheskiy institut im. P. N. Lebodeva AN SSSR Moskva (Physics Institute imoni 11. 11. Labodov AS USSR, Moscow) SUBMITTED: April 29, 1961 Fig. 1 Ica-if E Card 4/4 V, 20 0 29301 S/053/61/075/002/004/007 B125/B102 A LIT HOR s Vavilov, Y, S. TITLE: Processes of radiation ionization in germanium and silicon crystals Pk;itIODICAL: Uspekhi fizicheskikh nauk, v. 75, no. 2, 1961, 263 - 276 TEXTt The author restricted his investigation to photoionization and ionization under the action of charged particles, when valence electrons are liberated in semiconductor crystals. Ionization of impurity atoms as well as thermal and impact ionization in a strong electric field were left Unconsidered. The experimental arrangement is illustrated in Fig. 1. Measurements made on silicon single crystals confirmed theoretical predictions concerning the effect of an external electric field upon photoionization. In the spectral region corresponding to valence band - conduction band transitions, the edge of the absorption band is shifted considerably. In case of 0.8 - 0.911 wavelengths, the field applied raises the absorption coefficient strongly I- This phenomenon is a true "field effect", and is not associated with carrier absorption. B. M. Vul, L. V. Keldysh (ZhETF 1j, 1138 (1958)), F. F. Vollken::hteyn (Trudy FIAN 1, 123 (1937)), and K. I. Britsyn are mentioned in thia connection. '"he Card 1/3 293UI S/05 61/075/002/UO4/GO7 Processes of radiation ... B125YB102 quantum yield of photoionization in crystals with p-n Junctions is deter- mined along with the spectral dependence of the quantum yield of p'.'Icto- ionization in germanium crystals. This investigation of photoionization inside the main optical absorption band of germanium and silicon showed that the quantum yield exceeds unity by far if the photon energies are sufficiently high. M. N. Alentsev, S. I. Vavilov (Sobr. soch., t. 2, M., Izd-vo AN SSSR, 1952, str. 293), F. A *Butayeva, V. A. Fabrikant (Izv. All SSSR, ser. fiz. 21, 541 (1957)f S. Koc, 6eskoslov. 6asopis pro fiziku,.~, 668 (1956)), F_ Tn-ioncbik, 6eskoslov. 6asopis pro f,iziku, 7, 651 (1957) are mentioned in this connection. If the photon energies are a multiple of the forbidden band width (as with X-radiation and t-rays), the quantum yield will be proportional to the photon energy: q - Wl/t. ld. V. Chukichev, and V. S. Vavilov (Fiz. tv. tela, 3, 935 (1961)) found 1-.- 2.3 t 0.3 ev in their study of onization in germanium single crystals that were gamma- irradiated by a Co~O source. The same had been found by the Czechoslovakian physicists Dragokupil, Malkovskaya, and Tauts (Ca. J. Phys. 1, 521 (1957)). In case of ionization in germanium and silicon crystals under the action of fast charged particles, the energy per electron-hole pair does not depend upon the particle energy. V. S. Vavilov, L. S.Smirnov, V. M. Patskevich X Card 2/3 Processes of radiation... 2930i S/05 61/075/002/004/007 B125YB102 (DAN SSSR 112, 1020 (1957)) are mentioned. There are 11 figures and 30 references'T__~3 Soviet-bloc and 7 non-Soviet -bloc. The three most recent references '.o English-language publications read as followit 6. Plann, W. Van Roosbroeck, J. Appl. Phy6. ZI, 1422 (1954); K- MacKay, 11hys. Rev. 108, 29 (1957); P. Wolfe, Phys. Rev. 21, 1415 (1954). Fig. 1. Experimental arrangement. 0 0 Fig. 1 41thpld COON11YIP Legend: (1) Monochromator slit, (2) silicon, (3) copper rod, (4) PbS photoresistor, 5) shield, (6) evacuation, light, (8) strong-field M region. Card 3/3 pbs O'godola 141 N ~y ill -V*' VAVILOV, V. S ~; SFWVAj~ Ii ---V CHAPNIN, V. A. "On Defects Introduced by Fast Electrons into S"licon DOped Irl Lithi"" Paper was submitted at the International Conference on Crystal Lattice Defects at Kyoto, 7-12 Sep 162 (for Vavilov, v. s.) P. N. Lebedev Inst. of PWsica Leninsky,Prospect 53, Moscow 39)(19 S/120/62/000/003/042/048 '2V, 33co E032/E114 A.UTHORS: Plotnilkov, A.F., Vavilov, V.S-_, and Kopylovskiy, B.D. TITLE: An apparatus for studying the spectra and kinetics of photoconductivity in semiconducting crystals PERIODICAL: Pribory i tekhnika eksperimenta, no.1, 1962, 183-187 TZXT: The apparatus was designed for studyi-1--g photo- conductivity in single crystals in the infrared part of the spectrum at low temperatures. A block diagrn-a of the apparatus is shown in F-Jg.l. The infrare6 radiation is taken from an '!*~C-12 (IKS-12) monochromator and is focused on the specimen 0 by a system of mirrors. The radiation reaching the specimen is par'tly raflected on to,a bolot:iotor 5 whose output is fed into an aiiiplifier tunod to 9 c.p.s. This is used to control the LIV, incident intensity. The specimen is placed in a convantional metal cryostat and maintained at -100 OK. Thick germanium and silicon filters -r. are used to reduce scattered radiation. ' The specimen is connected by short leads to the input stage of an ai,xiplifier, which is in the forin of a cathode follower with double screening and negligible grid current. The double screening Card 1/1--. Z S/120/62/000/003/042/048 An apparatus for studying the spectra... E032/E114 ensures low input capacitance. The input stage is connected to a narrow-band amplifier tuned to 0, c.p.s. which is followed by a sync1ironous detector coupled to the modulator. The sensitivity is 0-5 x 10-8 V/division with an input resistor of 5 x 1o13 ohm. The photoconductivity-spectrum and the incident spectrum are recorded on a pen recorder chart. Both a.c. and d.c. operation is possible. Amplifier circuit diagrams are reproduced. The appara- tus has been used to measure p%otoconductivilty spectra of fast neutron-irradiated silicon crystals. An account of the results is given else;..here (V.S. Vavilov, A.F. Plotnikov, J.Phys.Chem. Pergamon Press, 22, 1961, 31). Studies of the kinetics Solids of , impurity photoconductivity carried out with this apparatus have led to a determination of the cross-section for carrier capture by levels associated -.-rith structural defects which are produced-in p-silicon after irradiation by fast neutrons# There are 6 figures. ASSOCIATION: Fizicheskiy instit 'ut AN SSSR Card 2/p (Physics Institute AS USSR) SUBLMITTED~- October 6, 1961 S/181/62/004/005/009/055 B102/B138 AUT".,0'J'6: Vavilov, V. S., Smirnova, 1. V., Chapnin, V. A. TTTL:': The interaction of lithium atoms introduced into silicon with the radiation defects of the structure ,ZIGDICA7: rizika tverdogo tela, v. 4, no. 5, 1962, 1126-1131 .?z A - TEXT: A-he authors studied the interaction of Li impurity atoms in Si sin '-1e crystals ,-.ith 'the structural defects that were produced by fast- electron bombardment. The Li impurity was introduced by diffusion from a Sn-Li melt containing 0.2 - 1;f) Li. Li equilibrium concentration in Si was reached at 550-0650 0C. The Li samples were p-type 0-150 ohm-cm) and cut out of sinEle crystals. After introduction of Li the p-type samples uere transformed to n-type with carrier concentrations of 14 16 -3 + a shallow 3-10 _10 cm Since Li formed oxide ions LiO , which have . donor levels and are relatively stable at room temperature, the carrier concentration (n) equals the sum of the ions Li+.+ LiO+. 4lectron boribardment (0.9 mev) took place at room temperature. At Li concentrations Card 1/1 5/lal/62/004/005/009/055 The interaction of lithium atoms ... B102/B138 Of 3-1014 _ 5-1015CL-3 two level groups were found in the upper half of the forbidden band: E -0-17 and 0.4 ev. For the level E which is filled c b ' . I with electrons 1, b=0.17 ev is found. When the irradiated samples are '4 I k. 0K t6 carrier concentration was found to be greatly I'leated to 330-350 reduced. The results, presented by a curve, which has thice sections, can b,o described by Ae Be Ce no TI < -r2 < _T3- The effective diffusion coefficient Deff ~ 0.111o Do, Do is the diffusion coefficient of Li when O'is absent. There are 2 figures. A~JGCIATIOLT: I'lloskovskiy gosudarstvennyy universitet im. M. V. Lomonosova (moscow State University imeni M. V. Lomonosov) SUBI~.,.'ITTED December 8, 1961 Card -2/1 S/181/62/004/305/G'50/055 B 16 3 / B 1 _5 13 AUTHORS: Malovetskaya, V. M., Galkin, G. IN., and Vavilov, V. S. TITLE: The spectrum of radiation defects in silicon PERIODICAL: Fizika tverdogo tela, v. 4, no. 5, 1962, 1372~1374 T EX 1 2 :Aftei~ electron irradiaticn of silicon local energy levels are found 4 , .1 the forbidden band at 0.17 ev and 0.4 ev below the conduction band (acceptor levels) and 0.27 ev above the valence band (donor level). 'V'Ihile the two acceptor levels have been shown to correspond to an association of a vacancy with oxygen and phcsr~orus respectively, the nature of the donor level remained unknown. p-ty2e silicon crystals wizh varyine oxygen content were drawn from auartz crucibles and irrad 4ated -Ni'h 1 Mev elect-,Dns from an electrostat4c zenerator at 17 + 10C. The oxyCen concentra-.-Jon determined from the intensity of the infrared absorption b_and at 9.1 =dcrons. The position of "he energy levels and the defect concentration were deter- minea from the temperature dependence of the charge carrier concentrat-Loa measured by The Hall effect. This is better than measurine res1stivity or life-time at constant temperature, as the latter Give less precise Card 1/~ s/1 a I /62/rC,4/G'v V The spectrum of radiation ... B163/B136 info-z-ation on the respect-ive influence of different aimultanei)usly exi.3ting defects. In silicon specimons drawn from quartz cruciblet; wi th an oxygen concentra-tJ on of (2-3) -1017 cm-3, a donor level' was fi~und k, -Y 0.27 ev above the vaience ban,'. I' was rather stable and could cn! above 3000C. p-type silicon produced by zone multing in vacuum withou-- a cruc4ble with an oxycer, concentration af about 5-101~~ crr-3 s`rwed =airlY other defects at levels of 0.21, + 0.01 ev above the valc~ce bank.. Thi3 wa3 determined from the position of the For;;;i level when half of t-e defect levels were occuDied. T'he 0.21 ev defects were much less stable t-ar, t,-,e 0.27 ev ones, and annealin.f, waa noticeable at room tem;;eralure. e temperature dependence of the hole concentration was nea5ured be-.ween 125 and 4GOOC for specimenA annealed bet-ueen 17 and 1200C, and from t*,4-s the a-nealinig activation energy was found to be 0.72 + 0.04 ev. The 0.27 ev defects Pay be due to interaction between oxygen 7ith interatitial atozs. The much slower rate of form--tion of the +0.27 ev defects as compared with the -0.17 ev defects is attributed to the fact that interatitial a;oms have CL I 'M than vacancies. 0.21 ev defects -~,,2re alco foun' 4n ~ - F. Plotnikoils investigations on the spectra of stationary photoconductivity. There is I figure. Car"' 213 .., C) / G 5 S/lb 02/004/005/0:~ Bi 38 5-ation ... %',03 COIl Of rad, ;,I! C'SSRI The tu Vos cow F.izichosidj inst- T ebedev kS USSR' ASSOCIAnnON: (physical -,~,,,titute 'February 57 1962 3/3 ,)q, ~ 700 37949 S/161J62/004/005/c,51/055 B163/B138 ;U'AHORS: Nolle, E. L., M-alovetskaya, V. M., and Vavilov, V. S. TITLE: The effect. of oxygen on the life-time of minority carriers in p-type silicon C,.L; Fizika tverdogo tela, V. 4, no- 5P 1962, 1374-1376 TLEXT: Sindle crystals of p-type sJilicon were obtained by zone melting without a crucible. Very low oxygen content was achieved by zone refinement in a hydro.Nen atmosphere or in vacuum. In the top part of the a;ngle crystal the oxygen concentration was increased by making part of the last passaCe in an atmosphere of moist hydrogen. The oxygen concentration was determined from the intensity of the infrared absorption band at 9.1 microns. The life-time was measured by B. D. Ropylovskiy's phaze method at a low injection level. 'With oxygen content increasing from 5-10 16 cm-3 to 1-5'10 17 cm-3 the carrier life-time.increases from 4.6 to 32 microseconds. Its temperature dependence was measured between ;20 and 4300K and was found to diminish with temperature. The decrease is less for specimens with higher oxygen concentrations, and below 000, it increased Caral 1/2 S/1 al-/62/004/005/C-51 /05z 5 The effect of oxygen on the ... B163/B138 &&rain, indicatin_- the existence of trap levels. Below 00C the life-time was reduced by biaslighting, and increased above. The temperature deDendence of life-time In specimens with low oxygen content followed th~ dependence calculated for a recombination level with an activation energy of 0.27 ev. The temperature de endence of life-time for a specimen with an oxy6en concentration of 1-5.lof7 cm-3 cannot be de6cribed by the statistical theory of Shockley and Read for one recombination level. The tremendous increase with rising oxygen concentration must be due to the interaction of oxygen with impurity atoms, dislocations and defects of the vacancy - interstitial type, to form recombination centers in silicon. It appears that the resulting recombination centers- have small cross sections for the capture of minority carriers. There are 2 figures. i'MCCIATION: Fizicheskiy institut im. P. N. Lebedeva AN SSSR, Moscow (Physical Institute imeni P. N. Lebedev, AS USSR,Moscow) SUB'.,..-ITTED; February 5, 1962 Abt Card 2/2 S/~81i)62/004/007/033/037 B111/B104 c, AUTHORS: Vavilov, V. S., Calkin, G. N., Malovet8kaya, V. M., and Tlo-tnikov, A. F. TITLE: Photo and thermoionization energies of deep level radiation defooto in Si PERIODICAL: Pizika tverdogo tela, v. 4, no, 7, 1962, 1969-1970 TEXT: Zzoerimental results of thermal and photoionization are compared by utilizing a fact recently discovered in the annealing of p-type Si, namely that the difference in stability of two olosely.adjacent levels of the centers reBijlting from 1 Ylev electron bombardment amounts to E + 0.21 ev. Pig. I shows thatIthe raising of the level balances the v disappearance of charge carriers (holes) on the donor level (3 + 0.19 ev). This defect is stable even at 2000C. There are 2 figures and T table. ASSOCIATION: Fizicheskiy institut im. P. N. Lebedeva AN SSSR Moskva ONlysics Institute imeni P. N. LebedeY AS USSR Moscow) S/181/62/004/003/015/045 B108/B186 AUTHORSt GippiuB, A. A., and Vavilov, V. S. TITLEt Radiative recombination on dislocations in germanium PERIODICAL: Fizika tverdogo tela,, v. 4, no. 9, 11062, 2426 - 2433 TEXTt A mirror monochromator and a lead sulfide phot.oresistor were used to investigate the radiative recombination in Ge crystals whose dislocation density ranged from 5-10 3 to 1-104 cm-2 and whose electron equilibrium 13 16 -3 concentrations varied between 5.10 and about 10 cm . At nitrogen temperatures, an intrinsic band was establish6d at 1.71p, due to indirect band-to-band transitions. Another band, established at 2 - 2.5p occars only in crystals which have dislocations and are the result of carrier transitions between local levels. It is better resolved in the case of high electron concentrations and it shows recombination levels at a distanae of 0.22 and 0.14 ev from the conduction band. Probably another level or level group exists at a distance of about 0.18 ev from the conduction band. The half-width of the emission line related to the Card 112 5/181/62/004/009/015/045 Radiative recombination... B106/B166 transition of holes to one of the levels equals 0.016 ev. The intensity of the intrinsic band is proportional to Im (I is the injection current, m----,2). contrary to expectation, the intensity of the dislocation band is not linearly dependent on I, because the reconbination uenters are saturated. The shape and intensity of the dislocation band-are strongly affected by the surface-treatment, this beihg'due to different filling of the levels. There are 7 figures. I ASSOCIATION: Fizicheskiy institut im. P. N. Lebedeva. AN SSSR, Moskva (Physics Institute imeni P. N. Lebedev AS US.-JR, Moscow) SUBMITTEDt April 14P 1962 Card 2/2 L0904 S/1 81/62/004/009/044/045 6, 2), B100166 AUTHORS: Smirnov, L. S., Vavilovp V. S., and Gerasirienko, N. 11. TITLE: Kinetics of silicon recombination radiation PERIODICAL: Fizika tverdogo tela, v. 4, no. 9, 1962, 2628-2629 TEXT: The oossibility o." studyinIg the kinetics of silicon recombination radiation --s examined. RectanEular current'pulsas ;,ere fed into Si crystals .-.-ith .-n junctions. The recombination radiation fror, the crystal waslta~en by a Fhotomultiplier, amplified.with a broad-band amplifier and observed with an oscilloscope. The~crystals hadbeen produced by diffusion of phosphorus and by fusing alum1num on to the surface. The injection coefficient was assumed to remain constant up to current densities of 10 a/cM2. Results: The attenuati'on of recombinAtion luminescence can be well described by an exponential law. The time constants of att'enuation arie approximately 2.7 microseconds for crystals with diffused junctions, 1.5 microseconds for crystals --vith fused junctiorfs. 7,"hen the crystal is cooled to liquid nitrogen temperaturr- the pu~lse amplitude does not decrease in proportion to the change in the Card 1/2 AUTHORS: Smirnova, TITLE: Radi4tion PERIODICAL; Fizika tverdogo h4163 3/181/62/004/012/003/052 B104/B102 1. V., Chapnin, V. A., and Vavilov, V. S. defects in lithium-doped silicon tela, v. 4, no. 12, 1962, 3373-3380 TEXT: The effect of' lithium on the formation of stable radiation defects in silicon and on the annealing of*these defects is studied by .determining the temperature dependence of the carrier concentration from the Hall effect. The lithium was introduced into Si sin-le crystals by diffusion annealjng (~50-65000 from a tin-lithium alloy. The single crystals had a resistivity of 100 ohm-cm; af -ter doping they had n-type conductivity. The carrier concentration Jay between 3-104 and 17 -3. 2-10 cm The specimens were irradiated by 0.9-14ev electrons at roor~ temperature. Results; In n-type silicon with lithium up to concentrati6po 17 of (1-2)-10 cm-7, shallow energy-levels arise in the range from 0.06 to 0.14 ev below the bottom of the conduction band, which are related to primary radiation defects, e.g., to pairs of interstitial atoms and Card 1/2 5/161/62/004/012/003/052 Radiation defects in ... B104/B102 vacancies which are separated by different distances. The lithium in the Si crystal interacts hith these defects. Such interaction is similar to the processes that occur during the annealing of genetically unrelated vacancies and interstitial atoms. The trapping radius has the same order as the lattice constant, (r min ' 5.4-10-8 cm). In crystals that, after part of the lithium has been deposited in the defects, are again of p-type conductivity, the levels 0.45 ev, 0.28 ev and 0.21 ev were observed above the top of the valency band. The centers corresponding to the level Ev + 0.26 ev did not disappear completely even during annealing for several hours at 4500 C and above; those corresponding to the level EV + 0.21 ev disappeared completely during annealing at 450 0C. There are 4 figures. ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M.V. Lomonosova (Moscow State University imeni M.V. Lomonosov) SUBMITTED: June 16, 1962 Card 2/2 S/1 81/62/004/009/040',45 Kin,w~tic3 r-C silicon recombination ... B100186 lifetime. Tlnis is explained by a shift of the recombination radiation band, cc rrt!v, pond in6 to band-to-band transitions, into a region of higher sensitivity of the photomultiplier. There are 2 fij,-ureB. I/'- ASSOCIATION: 'Fizicheskiy institut im. P. N. Lebedeva AN SSSR, Moskva (Phyaics In,-titute imeni P. N.. Lebedev AS USSR-, Moscow) SUBMITTED: June 4, 1962 1 - Card 2/2 44168 S/181J62/004/012/015/052 B104/B102 AUTHORS: Vavilov,.,,X..S.,, Plotnikov,'A.F., and Tkachev, V.D. TITLE: Invebtigating structural defects in silicon single cryatals by reference to the photoconductivity PERIODICAL: Fizika tverdogo tela, v. 4, no. 12, 19629 3446-5454 TEXT: The photoconductivity spectra of p-.and n-type Si single crystals- with different oxygen, boron, and phosphorus concentrations, irradiated by electrons (-1 Mev) from the electrostatic generator of the Laboratorts tfiziki poluprovodnikov (Laboratory of ,1 the Physics of Semiconductors) of the FIAN at 100 and 3000K, were investigated with a recording spectrometer designed on the basis of the OKC-12 (IKS-12) monocbromator. The specimens were plates (15-2.5-0-8 mm)''Nith palladium contacts (p-type specimens) or witb zinc contacts (n-type specimens). Results: Trradiation leads to the appearance of a large number of discrete levels in the forbidden band. The dependence of the shape of the photo- conductivity spectrum on the position of the Fermi level, which is related to the excitation of electrons on the different levels, shows Card 1/3 S/181/62/004/012/015/052 Investigating atructuval defects B104/B1O2 that all levels (Fig. 11) can be related to defects. The higher sensitivity of photoelectric measurements as compared with electric measurements made it possible to prove the existence of a series of centers with different ionization energies. In Si single crystals, irradiation by neutrons produces the same defects as*by electrons. The radiation defects which determine the photoconductivity spectrum of Si in the range of 2 to 6 p, are not Frenkell defects. Irradiation3 at 1000K showed that at room temperature not only simple Frenkell defects exist, but also associations of these with other types of defects. This makes it possible to study how such associations are formed and to determine the characteristics of defect diffusion. Electrically active impurities (Cu, Au) with concentrations of 1011 to 1012 cm-3 could be identified by studying photoconductivity spectra. There are 12 figures. ASSOCIATION: Fizicheskiy institut im. P.N. Lebedeva All SSSR Moskva, (Physics Institute imeni P.N. Lebedev AS USSR, Voscow) SUBMITTED: July 6, 1962 Card 2/3 U177 S/181/62/004/012/031/052 B125/BIO2 AUTHORS: Plotnikov, A. F., Tkachiv, V, D-j and Vavilov, V. S. TITLE: The photoconductivity spectra of monocrystals related with residual impurities PERIODICAL: Fizika tverdogo telat v. 4, no- 12, 1962t 3575-~577 TEXT: The photoconductivity spectra of siIicon monocrystals (~,1000 ohm-cm) were examined at 1000K at constant and alternating excitation (modulating frequency of the light 9 cps). The crystals were either produced by zone melting in vacuo or were grown in quartz-crucibles. The measuring apparatus, described by A. F. Plotnikov et al (PTE P3, 1962) recorded variations in the dark conductivity up to-10-6. The A-dependences of the relative change A d/dI in the photoconductivity of p-type sillcon monocrystals of 500 and 75 ohm-cm, have the same step-like form. I is the intensity of the exciting light. The photoconductivity beyond 3.2 p may be related with the known donor level of gold which lies 0-35 ev above the v-band. This level is due to centers whose concentrations vary between 10 11 3 10 and 10 cm- . This concentration of monocrystale produced in quartz Card 113 (D, S1ao14z1w,1eo_3/54Z10,9,e S11 a 1 /62/004/012/031/052 The photoconductivity spectra ... B125/B102 dishes is higher by one order of magnitude than that of silicon produced by vertical zone melting in vacuo. The level at 1.8 g corresponds to bipolar excitation, the level at 2.2 4 corresponds to the acceptor level lying 0-54 ev below the bottom of the c-band and the level 2.8 g arises from bipolar excitation by the copper level E v + 0-49 ev. In the latter case, minority carriers (electrons) are excited by double optical transitions to the conduction band. The level in the region 2.3 p of the 4-dependence of 8 a/61 is evidently due to electron excitation from the gold level E a - 0-54 ev to tha conduction band. The broader level below 2 g might be due to bipolar electron excitation through 2 levels. ""he shape of the spectral curves of the photoconductivity of p-type silicon monocrystals (doped with gold up to 5*1015 cm-3) confirms the above assumption that the impurity photoconductivity in unalloyed Si crystals is cauced by gold atoms. In Si monocrystals produced by zone melting in vacuo without any crucible the gold concentration is found to be 10 10 - 10 11 cm-3 and the copper concentration 10 11 - 10 12 cm-3. In Si monocrystals grown in quartz crucibles or by vertical zone melting the Card 2/3 The photoconductivity spectra ... S/181 62/004/012/031/052 B125YB102 ,residual impurities, copper and gold, produce local centers with deep levels.in the forbidden bands. There are 3 figures. .. ASSOCIATION: Fizicheskiy institut im. P., N.-Lebedeva, AN SSSR, Moskva (Physics Institute imeni P. N. Lebedev AS USSR, Moscow) SUBMITTED: July 10, 1962 Card 3/3 il I PLOTNIKOV, A.F.; XOPYLOVSKIY, MP~ w Apparatus for studying the spectra and kinetics of photoconductivity in semiconductor crystals. Prib. i tekh. eksp. 7 no.3:183-187 My-je 162. (MIRA 16:7) 1. Fizicheakiy institut AN SSSR. (Photoconductivity) (Semiconductors) LOTKOVAY E.N.; V~'JILOV,_~ OBOIZVj N.N. Infrared absorption spectrum of silicon irradiated by fast neutrons. Opt.i apektr. 13 no.2:216-221 Ag 162. (MIRA 15:11) (Silicon-Spectra) (Neutrons) VAVIIA)V, VOSO Procesiseo of radiation ionization in the geramnim and silicon crystaloo Analels mat 16 no.3:181-196 JI-S 162, VAVILOV, V.S.; YJJASHNIKOV, S.G. Photoelectric phenomena in semiconductors (Second International Conference on Photoconductivity). Usp.fiz.nauk 76 noo4:749-758 Av 162. (NIRA 15-7) (Semiconductors) (Photoconductivity-Congreases) VAVI,pV, Vjktor.Sergeye-vi.ch; DUBINOVA, V.Ya.y red.; SIIKLYA-'Iv S.Ya.) tekhn. red. Semiconductors] Deistvie izluchenii ,ffect of radiation on + [F 3. 264 P. iloskvay Fizma~gjz~ 3!)6 (mjRA 17:2) na poluprovodniki. -, _L_1555_6,,wQ EWT(1)/E7or,(k)/E~(m)/BLIS/EFC(b)-2 'AFFTCY~SD/EW-3 rz-4 AT/ UP (C),_ ~ACCESSION NR: AP3003876 3/018-1/63/X5/007/1826/1,829 ~IAUTHORSj Tkach~vp V* D.; Flotqik~vj A, F.; Vavilov, V. S. TITLEt, Spectra of photoconductivitoin n-type silica bombarded with high-speed electrons SOURCEf Fizika tverdogo tela~ v. no. 7, 1963, 1826-1829 TOPIC TAGSt photoconductivity, bilica, n-type, electron, high-speed electron, conduction bond, valence band, forbidden band, center , defect ABSTRACTi The photoconductivity of n-type silica was studied by means of the -setup described by A. F. Plotnikov, V. S. Val4vov, and B. D. Kopy*lovskiy (PTE, No. 3, 183, 1962). The spectra were investigated with oscillating (aodulation frequency of 9 cycles) and steady excitation. The samples were plates cut from single crystals and had contacts attached at the ends. The contacts were Pd and ZnJ, deposited electrolytically. The bombardmeat was effected with electrons of 1 Mev. The temperature of the samples during bombardment did not exceed.25-30C, and measurements were made at a temperature near 1004. From the measurements of photoconductivity the authors diagrammed the positions of energy levels in the -Card 1/1 L 15556-63 "ION NRt AP3003876 ACCESS iforbidden band. This diagram is shown in Fig* 1 (see Enclosure 1)o The results, Iliko data on bombardment of p-typo silica with electrons and neutrons, attest to, !a llset" of several centers, the nature of moet being sks yet unbxplained. The :"radiation" origin of centers with levels at Fr -oa6, EC -0-40, +0.54, and Fv i+0-45 Ov io not quentioned. These levels are starred in Fig. 1. Elt is possible ~that some of the levels are initially present in the material, not developing anevi but merfj).y aj)penring bocauso of tho capturri of equilibrium carriers by defects am becautic of favorable conditions for "naGurinq photoconductivity in bombarded silica~l iat low temoeraLures. "The authors exprost; thpir sincere thanks to G. N. QAlkjn, V-OK-.Malovetskjya.-and ~4 1-I,*ovkina.Vp-for;valuab1e advIce and critical remarks !and to lye,, Mo U1v"4(ovs-XAYa1 deceased)' for aid 6 f igdroc. A39)CIATJOH: Fizicheskiy institut im. P. N. Le6edeva AN mg, Moscow (Physical ?Institute, Academy of Sciences, SSSR) SU M ITTED t 30Jan63 DATE ACQs l5Aug63 ENCLs 01 tSUB CODEi PH NO REF SOVI 005 OTHERi 002 !.Card, 2/1.&-- TKACHEV, V.D.; PLOTNIKOV, A.F.; VAVILCV, V.S. Nature of local centers with deep-seated levels in slli~:on Irradiated by fast electrons. Fiz. tver. tela 5 no.11:3188-3191. N 63. (141RA 16:12) 1. Fizicheskiy institut imeni Lebedeva AN SSSR, Moskva. L 1303o--63 -- EWT(I)/EWG(k)/EWP(q)/EWT(m)/BDS/EEC(b)-2 AFFTC/' -3. Pz-4 JDAT ACCESSION M: AP300b524 S/0181/63/005/005/i4l7/?422 AUMCR: Akimchenko, 1. p., VaVildy., V. S,; PlotnikMA. F. . .................. TIME: Spectra and kinetics of pW;oconductivity )associated vith simple structural defectVin single crystals of germanium SOURCE: Fizika tverdogo tela, v. OP no. 5. 1963P 1411-1422 TOPIC TAGS: photoconductivity, capture cross section, vacancy, Interstitial, Cre, Au ABSTRACT: The authors have investigated the photoconductivity associated with deep levels of radiation effects arising during bombardment by electrons (1 mev) of very pure single crystals of Ge and of single crystals alloyed with Au. They conclude that a detected level of E sub V + 0.42 ev., belongs to an interstitial atom. 'The caoture cross section corresponding to relaxation at the latter level vu-- computed to be 3 times 10 Gup -17 Sq/cm- From this value the effectiveness of ins6rting centers and the results fell within the limits of expartmntal error. "In conclusion tine autJiora consIder It, their pleasant duty to express thanks to M. I. Iglitsy*n for discussing the resUts., and to M. L Ginzburg and Ga Fs !-- --Orig. art. has: 10 Proshko for supplying the single crystals of german um.'T figures Association: ITLqta of Pllysics, Academy of Sciences, SSSF. Card VAVILOVP V. S. International C-onference on Defecto in September 7-12, 1962, Usp, f12. nauk 79 (crystals-Congre see it) CryBtals held at Tioto, no.ltl53-159 Ja 163. (MIRA 16: 1) It L 24498-~-c F.wl~(i ) /E,~G(k )IZ~aFtm) II:; pc )/ E F Fn2 /T/EWA (h) Pz-6/Pr-4/Peb/ Pu-4~ IJ c f r' r) /A FIqD ~ t A `t)/4 F--TR G G/ A T AGGEWION MR AW4040591 BOOK SIMITA79N v vilov, Viktor gergey2vich -.- - --- -- ~I 1~ The effect of radiation on semiconductors (Deystriye ftlucheniy na poluprovodniki)g MOSCOwt Ulns., biblio4 15pooo copies primted. Fizmatgit 1963, 264 P, Series notet Fiziki poIuprcrodr,.I*,-cv I poI-upmvodnikov-y-*kh priborov. TOPTC TAGSt electronics, physics, radiation effect, semiconductor P'RPI'-5F AIM C('V-MA(,'Izt The bo~ok presents the physical concepts of the effect of ra~,Ialli-n on semiconductors. The processes of ab- and tonizatIon tn pagz-:Ing --r, 71, T- 7-2 10T fur ap'Ictalties. Ov , '' ~ I I L ACCEWICH mR Am4040591 TABtE OF-CO14TENTS fabridged]$ Foreword - 7 Ch. 1. Light absorption of sz-videanductors -- 9 r'r., 1T, PII-.otoianizaticn ar-d p-h,~rt.oconductivlt:r in semiconductors 57 Ir, tY,.e ~,-%-usapa of hiph energy charged particles -- 115 C'h. TV, RadiafAon recembinatIon in se-rdeonduatore; posalbiiit,L" -,r amrIffyinw ;nd by ra~pjd electrons, A 1-11Q 7 OTHOt 184 Corti 2/2 VAVILOV, V.. S.; MCHEV, V. D. ; SMICHENKO, A. N. "On the nature of local --enters w1t.r; deep em-rggy ie*ze,,.,,~ in IAJ bY fast' electrons." report submittQd f'or S~mp on Radiation Dwmge in Seml-ondu,--tors, -ho,7al-Imont, 16-18 jui 64 - AUTHOR: Vavilovp V. S.; Kolmanskaya# 12o/64/000/00510079/0090 Vn t:o*.IA 0 - 1 0 1 - QMkicbe V, A. V TITLE- Generation of minority carriers in silicon by fast electron* SOURCE- Pribory* i tekhnika ekspcrivicnta, rio. 5, 1964, 79-80 TOPIC TAGS: semiconductor reseazch, silicon counter ABSTRACT. The theoretical spatial diatribution of the ionization energy loss in Si given by B. Ya. Yui-kov (Zh. tekhn. fiz. , 1958. 28, 1159) hiis been expeiimen- tally verified. A p-n junction was prepared by diffusion P in p-Si having a resists-- ty of I ohm-cm. Experimental curves of the average ionization loss vs. the depth of penetration, for electron bearns with initial energies of 250, 500, 700, and 900 kev are presente(J With,,-i th(-- i5,ual experimental errors, the ,Card ACCESSION NR; AP4047462 curves show satisfactory agreement with the theoretical curve. Orig. art. has. 2 figures. ASSOCLATION: Woskovskiy gosudarstvenny*y universitet im. M. V. Lomonosova (Moscow State University) SUBMITTED: 13Nov63 ENGL: 00 SUB CODE: EC NO REF SOV: 002 orHER: 003 C-Crd 2/2 7 -9-M, N-1 mom =Essiw HRs Ai,4011786 3/0181/64/006/001/0329/0331 AUTHORS: Kryukova,, I. V.j V"apys V. S. TITLE; Orientation dependence of the formation of radiation defects in n-type I silicon SOURCS: Fizika tvi.,rdogo tela., v. 6, no. 1., 1964s 329-331 .'TO?IC TAGS: radiation defecto n type silicofi, electron bombardment, combination cvnter, minority carrier, p-n junction, mitiority carrier lifetime, electron flux, capture cross section,, thermal velocity, carr.ier velocity ABSTRACT: Determination of orientation dependence is difficult because of the necessity of working with very thin samples (10-20 microns) and avoiding loss-of initial direction of incident particles by scattering on atoms of the test materiaL The authors used a different mothod,proposed by V. S. Vavilov., V. M. Patskevich, B. Ya. Yurkov,, and P. L. Glazunov (Frr, 2., 1431, 1960), which yields data on orientation dependence by measuring dependence of resistivity changes on depth of electron penetration. A single crystal of n-type Si was used. Defects. introduced by radiation were recorded by measuring the lifetime (t) of minority carriers dur- Card -1/4 Accmim NRs AP4=786 ing bombardment. To record changes in this lifetimej the authors measured the short-circuited current (Isc) in the circuit of a crystal with a p-n junction daring botabardment by a stream of electrons. The number of combination centers introduced by radiation in small doses is equal to the product of electron flux (0) ard the rate of defeat production (8) (by ~ is meant the ratio of number of defects per cu cm to the electron flux per sq, am). The relationship among these values is then y0ovf (El Ef). 4here cr is the capture cross section of carriers by the given center,, V is the thermal velocity of the carriers, and f(Et-Er) is the function of level filling. Bombardment by electrons of 1 Mev was carried out at room temperature. The rela- tionship between electron flux and change in short-circuited current (proportional to lifetime of carriers) for various directions of bombardment is shwn in Fig. 1 of the Enclosure. The observed orientation dependence is associated with the presence or inter.,;titial positions in a loose lattice of the diamond type. "The authorn thank S. 1, Vintovkin for his aid in bombarding the samples.0 Orig. art, has 1 1 figure. Coed 2/4 =&%SION KRt A?4011786 ASSOCIATION: Mookovakly gaaud&retvenmy*y.unjv0rsit6b. la. X. V. Lomonosova (Moscow State University) SUBDa-MM: o%ep63 DATE ArQt Web64 ENGLt 01 SUB -CODFt PH NO RKF SOVt 002 OTHERt 003 Card ACCESSION NRI AP4034920 S/0181/64/006/005/1406/1412 AUTHORs Vavilov, V. S.; Nollso' E. L.; Yagorov, V, D.; Vintovkin, S, TITLEt Radiative recombination in caAdmium telluride as a result of excitation by fast electron pulses SOURCE: Fizika tvardogo tela, v. 6, no. 5, 1964, 1406-1412 TOPIC TAGS: radiative recombination. cadmium telluride, CdTe, laser material, stimulated emission, semiconductor ABSTRACT: The recombination radiation spectrum of CdTe excited by fast electrons was investigated in th photon energy interval from 0.7 to 1.6 ev and at temperatures betteen 10 and 300K. The p-type samples with resistivity of % 10 ohmscm were e-zeited by 1 Hev elec- tron pulses of 2.5 psec duration from an elvetrostatic generator. The repetition f;equency was 10 cps, and ~the current density per electron pulse varied betweeen 0o3 and 0.5 mA/cm. Since a 30 hr exposure to this type of ir-radistLon did not affect the r4combLn&tLm Icara 1/3 ACCESSION NRt AP4034920 Poo radiation spectrum, it was assumed that the effect of the formation of radiation defects could be neglected. It was found that at 10K the recombination radiation spectrum concists of three intense bands %ith maxima at photon energies of 1.05 + 01, 1.47 + 0.01, and 1.59 + 0.01 ev. The short-wave emissiZ band is l;cated in the regio7n of the fundamental absorption band. Analysis of the data shows that vertical transitions with emission of optical phonons with zero momentum.occur in CdTe and that the probability of such processes is high. According to criteria developed in: Basov, N. G., 0. N. Krokhin, Yu. M. Popov. ZhETF, v. 4, 1961, p. 1203, it may, therefore, be possible to obtain laser action in CdTe at low temperatures when the nonequilibrium charge carrier concentration is considerably smaller than that corresponding to the degenerate states Orige art. hast 6 figures* ASSOCIATIONt Fizicheskiy institut imeni P. No Lebedev&AN SSSR (Physics Inst'LtutelAN SSSR) 'Ccird 2/-3 ACCESSION NRI AP4034920 SUBMITTEDt 20Nov63 DATE ACQs 20May64 SUB CODEs PN NO REP SOVs 004 ENCLs 00 OTHERt 006 icwd ACCESSION NR; AP4041733 S/0181/64/006/007/2192/2194 AUTHORSt Tyapkina, N. D.; Krivopolenova, M. M.; Vavilov, V. S. TITLE: Electric properties of beryllium doped p-type germanium SOURCE: Fizika tverdogo tela, v. 6, no. 7, 1964, 2192-2194 TOPIC TAGSi german-Jum, beryllium, electric conductivity, carrier density, temperature dependence !ABSTRACT: In order to determine the upper acceptor energy level of ~beryllium in compensated and higher-resistivity-germanium specil~ensl !the authors measured the temperature dependence'of the carrier den- :sity-and of the electric conductivity of doped,germanium plates 2 x, ~x 3 x 15 mm in the temperature range 300--55K. The compensating im- ipurity was phosphorus. The plates were cut from the ingot perpen- -dicular to the [111] crystal growth axis. The measurements were pomade in a double metallic cryostat. A null method was used with a Card" 1ACCESSION NR: "4041733 'high-resistance potentiometer. The magnetic field reached 4600 Oe. Height samples from four ingots were tested. The results show that in all samples the carrier density is exponential in the reciprocal .temperature. The ionization energy was determined from the slope of i 3/2 3 'Plots of ln(pT) against 10 /T, and its value (0.064 + 0,003 eV) .is close to that obtained by others and also close to that calcula- ~tion by the "helium" model, which is thus shown to be applicable to beryllium in germanium. Orig. art. has: 1 figure and 1 table. ASSOCIATION: Moskovskiy gosudarstvenny*y universitet im. M. V. Lomonosova (Moscow State,University) 1,SUBMITTEDt- l3Feb64 isUB CODES sq, EC NR REP SOVj 002 2/4- ~27_ - -------------- ENCL: 02 OTHERs 004 ACCESSION NRs AP4041733 Dependence of carrier density on the tempemture for different samples Sam tard 3/4 to 01 1-7 dd~ fo k0 0.0 AD i'av I'D Tto- NO fig- rx AWSWICN NRs A4041733 ID2 Values of ionization enerpy in the Investigated samples 2 3 4-: V IS7(2) 0.8 1.4 1.75 0.064 169(l) 0.83 1.5 1.81 0.064 169(5) 0.7S 0.9 120 0.063 184(5) 1.2 -1.4 1.17 0.064 181(6) 6.8 &4 1.24 &064 1 1 - sample no. 2.,,- berylLim density in -Sc,~-3 10 8 phoWoris demity :4 - ionization energy, eV C~4 ---------- ---------- ,ACCESSION NR: AP4039659 S/0181/64/006/006/1718/1723 ,AUT11OR: Akimchanko, I. P.; Vavilov, V. S.; Plotnikov, A. F. ;TITLE: Some data on radiation defects obtained through investigations ;of photoconductivity spectra of germanium irradiated with fast elec- i itrons ISOURCE: FiAika tvardogo tela, v. 6, no. 6, 1964, 1718-1723 ~TOPIC TAGS: radiation defects, fast electron irradiation, p type igarmanium, n type germanium, germanium, fast electron irradiated ~germanium, germanium photoconductivity spectrum, irradiated germaniual lphotocnnfluctivity spectrum. forbidden zone ~ABSTRACT: The following types of Ge single crystals have been irra- idiated by fast electrons with energies ~I Hav at room temperature: ja) n-type with initial resistivities P of 3 and 56 ohm-cm; (b) dis- Jocationless n-type I P ^-1 3 ohm-cm; (c) P-type with a residual im- ~purity concentration of loll to 1013 at/cm3. The ohmic contacts were realized by the deposition of colloidal graphite. Photoconductivity ,spectra were measured at --I 100K in the 1.7 to 10 U wavelength range. ;Card 1/3 fACCESSION NRt AP4039 659 ,In the irradiated specimens the Fermi level was located 0.10 to 0.17 ev below the bottom of the conduction band. Some of the conclu- sions drawn from the results of the investigation are: 1) following irradiation with a flux of 6 x 1015 el/cmz, the photoconductivity spectra of n-type specimens showed the occurrence of a structure which can be connected with electron transitions from local levels E,-0.33, .Ec-0.37 and Ec-0.43 ev to the conduction band. When the to' ; elec- tron flux is increased to 3 x 1016 el/cM2 the specimen acquirc~; char- acteristics of P-type Ge; 2) spectra of type (b) specimens show that vacancy concentration increases almost proportionally with increased flux and chat at a certain value of the electron flux there is an increase (by almost one order of magnitude) in the concentration of centers which yield a constant distribution of photoconductivity sig- nals in the 2.5-1.9 u wavelength range; 3) a new maximum was detected in the spectra of type (c) specimens which occurred in the presence and disappeared in the absence of bias lighting from the region of natural absorption; 4) at wavelengths up to 5 U, the spectra of type (c) specimens showed a build-up of signals connected with electron transition to level Ev --4- 0.33 ev in the presence of a Ge filter; when no filter vas used a-.maximum appeared at a wavelength of 3,15 V; Card 2/3 'ACCLSSION Nil: AP4039659 '5)in nonirradiated type (c) specimens the disturbance which introduces level Ev-t-- 0.33 ev is due to copper atoms, whila in the irradiated ,type (c) specimens it is due to the joint action of copper acoras and .vacancies; 6) for the irradiated (c) specimens the hole-capture cross-section of level Ev -~- 0.33 ev is at 100*K 5 x 10-19 CM2. i-Orig. art. has: 9 figures. 1ASSOCIATION; Fizichaskiy institut im. P. N. Labodeva AN SSSR, 'Moscow (Physics Institute, AN SSSR) SUBMITTED: 28Dec63 DATE ACQ: 19Jun64 ENCLs 00 ISUB CODE: NO REF SOV9 007 OTHER: 000 ICard 3/3 L 18851-65 EwT(1)/Dr--(k)/9wV-ra1 f1r-1:KC-( QMM b )I UWA( n) A-31r-(a)/ESr,(g9) JDAT ACCESSION NR: AP4043355 S/0181/64/006/008/2361/2368 AUTHORS: Gippius, A. A.; Vavilov, V. S. TITLE: On the mechanism of radiative recombinatings at dislocationA in rmanium-- too SOURCE: Fizika tverdogo tela, v. 6, no. 8, 1964, 2361-2368 TOPIC TAGS: germanium, dislocation net, radiative recombination, forbidden band, temperature dependence, hole conduction, level transition ABSTRACT: The paper is a continuation of the authors! earlier work on Ge crystals with 103-104 d-islocations/cm2 (FTT, v. 4, 2426, 1962) which established; (1) the orpsence cf several components in the re- g that combination radiation spectrum of diS10CatL0n6 ind'CatLn - I several levels were active simultaneouslyl (2) a dependence of the T-ddlation-- band.- pra" le on tjj,~- Fermi level position, indicating hole Card 1/3 L 188.q-65 ACCESSION NR: AP4043355 transitions to levels in the upper half of the forbidden band; (3) a sublinear dependence of the dislocation band intensity on the injection current at high -_,jrrent densi-~es, sucligestinq internal processes in radiation centers giving rise to saturatio.-.. prescnt gaper 2extends thia work to higher dislocation oe-)sltles (105--lo cm ) and therefore s,ronger recombination radiation. which was easier to study and _-esolve. It Was fO'Un,~ t'-iat 17-: crease of the eqi.;ilitrium or inlectod eleCtro, :~ensitv prcid--t~- new long- (2.6--2.7 an.~ short -wave ienqt4;,, or intens-ified intermediate wavelengths (2 4 this indicated that hole transitions did not start tram tane valence band. The half-widths 'E anH the positions of the maxima of the dislocatLon bands were measured as a fuiictlion of tem,-e-ral.urp (RO--200K). Up to ;~170K the value of '.E was independent of temperatur(.--. the observations referred t,o 4bove, indicated that hoieE. were (-ap- tured by excited states and that radiative transitions occurreci within centers. The observed rLse of 'F with temperature ahovr. Card 2/3 TMMMM~M_ L 18851-65 ACCESSION NR: AP4043355 c other-band-which was very weak at --presen 6 of an lowex temper-Aures-i saturation in--the-de endence of the dislocation P band intensity on the injection current showed that radiation cen-,------- ters were not whole dislocations but jogs, nodes or other irregu- larities in dislocations. The actual positions of the levels of radiation centers could not be established from the available data. "The authors thank U. M. Vul, A. V. Spitsin, and V-.--D. Yegorov." Orig. art. has: 7 Egures. ASSOCIATION: Fizicheskiy institut im. P. N. Lebedeva AN SSSR, Moscow _LxPhysics institute AN SSSR) SUBMITTED: 24,Feb64 ENCL: 00 SUB CODE: SS NR REF SOV: 005 OTHER: 002 Card -3/3 ACCESSION NR: AP4041737 6/0181/64/006/007/2200/2202 AUTHORS: Gippius, A. A.; Vavilov, V. S.; Konoplev, V. S. TITLE: Determination of the yield of recombination radiation con- nected with dislocations in gormanium SOURCE: Fizika tverdogo tela, v. 6, no, 7, 1964, 2200-2202 TOPIC TAGSs recombination emission, quantum yield, dislocation effect, lead sulfide, photoconductive device ABSTRACT: The yield is defined here as the ratio,of the numberof quanta of recombination radiation to the total-dumber of acts of re- combination on the given type of centers. Since this yield must be, measured when the dislocations play a predominant role in the recom- bination of the non-equilibrium carriers, the tested sample was bom- barded with a beam of -1 MeV electrons from a Van de Graaff accelera- tor. The receiver was a-.lead-oulfide photoresistance calibrated with Card 1/3 ACCESSION NR: AP4041737 Ithe aid of a black body. n-type germanium with electron density no 5 X 1014 ce,3 and dislocation density N - 105 cm-2 was used. The ~dislocations were introduced by an abrupt change in the thermal con- 'iditions during the growth of the crystal. The tests were made at ipproximately BOX. The qu~rjtum yield was found to be quite sinall, indicating that most recombinations on the dislocations are.nonra- diative. Some explanations for this phenomenon are discussed. The ,results obtained for the quantum yield and for some related quanti- ties are compared with data by others. "The authors thank A.' V Spitsy*n for determining the carrier density in the sample and 1. ;Vintovkin and V. V. Mikhaylov for help with the measurements." jorig. art. has: 1 table. ASSOCIATION: Fizicheskiy institut im. P. N. Lebedeva AN SSSR .(Physics Institute, AN,SSSR) -SUBMITTED: 24?eb64 ENCL: 01 ISUB CGDEt SS NR REP SOVt 005 OTHER: 001 ;AC=ION NR: AP4041737 ENCLOSM: 01 Results of detemination of quantum yield A 06 UIL TI gw~ I N-10~' am-, I 1, .7AMS 1 1 4. 4 6.5 5 0.5 0.75 1.1 2.5 62 7.7 3.7 3.1 5 5.2 4 0-5 ' 1.0 1.7 3A U 1 6.4 2.2 1.9 7 3.8 Io 1.25 2.25 4.2 7.4 8.2 Iza 1.9 1.7 sample no. 2 (fast-electron density) Miaoamp/cm 3 3 g.10-19 Cm73SeC 1, 4 quantum yield, 104 Coed 3/3 ACCESSION NR: AP4044951 AUTHOR: Vavilov V. S.; Kryukova, I. V.; Chukichey.,_,11. V. TITLE: Effect of lithium on recombination in n-type silicon bom- barded by fast eleFE-rons SOURCE: Fizika tverdogo tela, v. 6, no. 9, 1964, 2634-2637 TOPIC TAGS: silicon, 1.1thium, p n junction, recombination, carrier mobility, radlation defect ABSTRACT: This research is tfle result of earlier studies by the authors (FTT v. 12, 337~, 1962) in wh 4ch it was shown that an In- crease of '-1h;_- lithium conlent- In sillcc~n containing oxygen reduces the rate of A-center formation, bind 1_3 ~if ascertaining the -xtert ~,a whi_h lithium reduces the concentratLnn -,a t i -~~n I!_5 of the recomtlr have high mobility and shouid :-,a Ila, ' -~r. !,-f ~-_'s a' I relatively low temperatures. The effect of the lithLum wat3 ed by measuring the lifetimes of the minority carriers in the silicon Card 1/2 L 140,"4-6 NR: AP4044931 by electrons in the presence ~i I I hium--Lmpuri t-tes. - W,thLum was int -656d- and - its --r-oduced into the silicon by diffusion at 550 :771 Z.-conten-t- -ranged.- ---from- 0. 1 --to __I-per cent. The Influence of the radia- 6- '' __ ects-, - Aer--lifetime--was determined i n'-induced-def 7-om-the--, minor y-,aari t by measuring the short circuit-current produced-in --- the `~'circuit___of- __a crystal with a p-n junction exposed to bard radiation. The tests. confirmed the earlier results obtained by measuring the Hall effect., that silicon doped with lithium has a much lower minority carrier recombination rate and a much loi-ier recombination center content. The authors are grateful to 17h, R. Panosyan, S. I. Vintovkin, and T. Granina for help with '_hf~ w~D_-;