"SCIENTIFIC ABSTRACT LYALIKOV, YU.S. - LYALIN, G.N."

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• Collection: Scientific Abstracts
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• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

5(2),5(4)
AUTHORS: Novik, R. M., Lyalikov, Yl.. S. SO V/7 5 -1 15 /21
TITLE: Polarographic Determination of Iodides in Melts
(Polyarograficheskoye opredeloniye yodidov v rasplavakh)
PERIODICAL: Zhurnal analiticheskoy khimii4, 1958, Vol 13, Nr 6, pp 691-694
(USSR)
ABSTRACT: Earlier papers (Ref 1) reported on the possibility of
determining various anions in a mixture of molten nitrates
acting as medium and an electrode couple Ptmicro - Ptmacro
The behavior of chromates and PJtrites in molten nitrates had
already been accurately investilgated (Refs 2, 3). In the present
paper ion J- is investigated, 1!,hicq causes two u-nmista-k-able
waves in the anode range. The first ccrresponds to the anodic
oxidation of the iodide; its magnitude depending on the
concentration of the iodide. The second wave occurs only at the
moment of introducing iodide into the melt and corresponds to
tqe nitrite anion wave. Acidifying of the melt by KHS04 ca--ses
the second wave to disappear) wahilst the first wave rerains
unchanged. An addition of sodium nitrite to the melt causes the
Card 1/3 second wave to increase in macnitude. The formation of nitrf-te

Polarographic Determination of Iodides in Melts SOV/75-13-6-15/21
in the melt after addition of iodide is explained by the
reaction: 2 KJ + KNO 3 J2 + K1102 + K20 .
Without considering this reaction, the determination of J- in
the melt can be effected in a polarographic way, basine on the
occurrence of a condition of equilibrium. The magnitude of the
first wave of the iodide dies not change during the 30-120
minutes following the addition of the weighed iodide portion
and is well reproducible. The polarographic curves are different,
depending.f rom which side they are taken. This is due to a
modification of the electrode surface while polarographing,
especially at high temperatures. in order to obtain
reproducibility, the anode must be cleaned by annealing.
At 340 1 50 the half-wave potential is 0.32 � 0.02 V and is
almost independent of the iodide concentration. W'hen the
polarographic wave begins to appear, the anode potential changes
only to a slight extentl while the cathode potential change is
considerable. When the limit current is reached, the anode
potential changes to a high degree, while the cathode potential
remains almost unchanged. The temperature coefficient of the
diffusion current was determined 'by two methods (Ref 3). it
Card 2/3 amounts to 1.5'~~( per degree. It was established that the

Polarographic Determination of Iodidas in Malts SQV/7r-1"_6-15/21
.j .11
quantity of the diffusion current linearly depends on the
concentration of J- in the melt. The determination of various
quantities of potassium iodide on the basis of the calibration
line offers satisfying results.-The mean error amounts to-� 11~-.
Investigations showed that polarographic determination of
iodides in molten nitrates at temperatures of 270-3900 and in
molten chlorides at temperatures of 700-7500 is possible.
Also the possibility of amperometric titration of the iodide
with weighed micro-portions of silver nitrate and potassium-
bichromate is shown. It was also established that a complex
formation occurs between the ions J-, Cd2-~' and Pb2+ in molten
nitrates. StiAdents of the University of Kishinev N. Zotova
and Ye. Levinzon participated in carrying out the present paper.
There are 5 figures, 4 tables, and 4 Soviet references.
ASSOCIATIONi Kishinevskiy gosudarstvennyy universitet (Kishinev State
University)
SUBMITTED: May 30, 1957
Card 3/3

5(2,4) SOV/153-2-1-7/32
ALrLHORS. Temyanko, V. S., Bardin, bl. B.,.Lyal.ikov, Yu. S.
z- -
TITLE: Polarographic Determination of Flatinum on a Rotating Platinum
Microdisk Electrode
PERIODICAL; Izvestiya vysshikh uchebnykh zavedeniy. Xhimiya i khimicheskaya
tekhnologiya, 1959, Vol 2, Nr 4, PP 503 - 508 (USSR)
ABSTRACTt The authors criticize the use of the dropping electrode for
the investigation of the polarographic behavior of platinum
(Refs 1-14). The use of a solid electrode instead of the dropping
electrode is more favorable for overcoming the difficulties
occurring (Ref 15). There are, however, also some shortcomings.
They can be eliminated if a rotating electrode is used. The
composition of the paper under discussion was caused by these
facts. Figure 1 shows the hermetic cell with a shutter and a
rotating electrode. Figure 2 shows the volt-ampere curves of
platinum. Figure 3 shows the examination of the reversibility
of the reduction of the ion
LF tCla '-. Table 1 shows the reduction potentials of platinum.
Card 1/3 Table 2 shows the computation of the number of electrons parti-

Polarographic Determination of Platinum on a Retatirg SOV1153-2-4-7132
Platinum Microdisk Electrode
.;ipating in the reduction reaction of the ion mentioned. Figure
4 shows the dependence of the diffusion current of platinum on
the rotation rate of the microdisk electrode. As can be seer.,
the dependence found here agrees with the theoretical one found
by means of the equation of V. Levich (Ref 22). The authors in-
vestigated the possibility of polarographing platinum on the
background of various electrolytes. They investigated the effect
of the nature and concentration of the salts: NaNO 31 NaCl, NaBr,
NaJ, NaClO 4' etc,further of the buffer solutions: of the
acetate- and phosphate-citrate buffer, of E11031 H2SO 49 HC1, of
ammonia, and other substances. The platinum wave increases to
a certain extent (Ref 16) with the increa3e in the NaNO 3 or HNO 3
concentration. The acidity increase of 10-5 to 2 n by a concen.-
tration increase of HNO did not influence this wave but,
naturally, increased tha second wave. The use of NaCl or HC1,
instead of nitrate, changes the character of the platinum polaro-
gram. NaBr and NaJ (Fig 5) are still more effective. This in-
dicates the formation of sufficiently solid complexes which
Card 2/3 practically cannot be reduced on a platinum electrode. The second

Polarographic Determination of Platinum on a Rotating SOV/153-2-4-7/32
Platinum Microdisk Electrode
wave corresponding to the hydrogen reduction is preserved in
this case. The reduction potential, however, is somewhat shifted
towards the more posItive range. The authors try to explain this
phenomenon. The determination of platinum may be disturbed by
oxygen since the reduction potentials of these two elements lie
close to each other. Therefore, oxygen has previously to be re-
moved. This is achieved by letting through nitrogen for 30-40
minutes. Further disturbances are caused by the surface condition
of the electrodes formation of an oxide film. Various methods
for their elimination are suggested in references 24-26. Figure
6 and table 3 show the dependence of the diffusion current on
the platinum concentration in the solution. Hence it appears that
the average determination accuracy is +5r,"o in the case of large
platinum amounts, and about 10cllo in the-case of small amounts.-
There*are 6 figures, 3 tables, and 26 references, 11 of which are
So-let.
ASSOCIATION: Kisainevskiy gosudarstvennyy universitet) Kafedra analiticheskoy
khimii (Kishinev State University) Chair of Analytical Chemistry)
SUBMITTED% January 2, 1958
Card 3/3

(4)
Dardin, M. B. , j!yalikov, Yu. ~S. , SOV/75-14-1-4/3,'
Temyanko, V. S.
Rotating Platinum 1.-icro-Disc
On the Cluestion of Usina
1!',loctrodoo in Polarogra-phic Analysis (K voprosu o primenenii
vrachchayushchagosya platirovoCo mikrodiskovogo elektroda v
polyaroCrafichoskom analizc)
-27
4,1 Zhurnal analiticheskoy khimii, 1959, Vol 14, ',r 1, pp 24
(USSR)
C -'evich (Rof 2) worked out a general quantitative theory of the
disc olcctrode. In the nresenco of an indifferent electrolyte
the diffusion current id9 caused by the re 'duction of an
unchs-r~;ed particle or byan ion, obeys to the following equation-
id ~ o.62n P D2/3 0) 1/2 V -1/6 es
..7r,cre nis the number o.~ electrons participating in the
reaction, -,. is the Faraday constant, D is the diffusion
cr~f~:icient in cm2see, w is the angular velocity of the
01-octrodo rotation (- 21rin, ri boing the number of rotation
s:'Cond),

(.,~:tion of !~,:J

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'r -
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-
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-I

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,u /75
Annlyiis
tl- at olcctrij~vc ~-lay also ba, orriplo,.-od fo:,.,
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corpared, .At*.,i roll cloctrodo.,,, bc~in!;
(:-,Ic*i to c1can, .xid. thero-fore, havinf~ Ion-Or lifo.
(1-*, rt~ront t--Pc-, Y,:-;cro-di--c clectrodec aro
al-o 5 Z'icu-1-a ~'nlble~;, ziiid 15 rof orenc., l.; of -.;I.ic:,t
-ciy tvc~7z-.yy uni,.r. - i t . t
-Arhinow;, c C,
September 27,
Gard 5/3

AUT11011. Dili ... Loh. a. 3: 3OV/75-14-4-30/30
TITU* Sootlass of Analytical Chemistry of the rill x*nI*l-Ywv
CO'Wross an Coneral and Applied Chemistry
?ZRZODICA.Li Zhurn4l analiti.ho.kay Wisil, 1959. Vol 14. or 4. pp 511-512
(van)
APPrOxIsest-ly 300 Per--" Parti-iv-t-d in the wark or
Department at Analytical Chemistry. Among then My"samte,
of vq~ioam gotenWic ragerah inatioute~, higher schools and
"Is. 'let. true, Chi".
DMICGJ!184 - 313 ft hd UWWU7. zA Italy. Lppmxi-t.17 10
"port .." board. In his opening speech 1. P,_Ajl,~~rvprt.l
am thl.:hlo,od ".ulto and on -d.M problems of .0424tl4.1
Ghoul *try. 4. 1. Ta--z!v reported an the &rplloatl*a of physica-0
chemical foualTain In W*-tera"wous systems for th* solution of 4
"rise . problems Of analstloal. aba=l:tr7.P1T. 1. Zus-tanT
"Dort-4 -4 w44= 8.148 In the us. of
_A.J~~bk Moved at the Axampl. of halide .A tl~iccyaosl.
mon ::., the co~latlon between the stability of coapI
the pualtia. of the corresponding co,atral mines in the ;:ri*dLe
IL lectured an the stability
27*06. T-X..EMAbkaTjL
Of 6XI"t.6 of Cu. Co. and MU an d..pszdL=C an th. structure of
the oxIat molecule. _TZ~Jmxuau lectured an the double
character of reaction of same compounds in the formation of
eampl. nos. the p-tl.a of the apyt1catL*v. or bAturopolyazids in
anayUGLIL chemistry was dealt vIt3h In the lectures at
4.4 31. A.
.X-Z-XuiL.khoTa and co-scrrkars, &rAA.1 To
ID221&knau. A large -wab.r of X..tuxv .1:,k the'... .
are, organic reagent. In _AZ_A~A Y_Z._Z!Rgyutlz
"Ported an the application of dia.1kyl And dlaryl dlthlo-
phosphoric -14 far th4 w.p.-t1a. of elements. A I
&r.yl ~mlc maLd and U71. ph.sphlale "Id. 1. P l4stovokLy ad
him ool-awkeft treated a.- proportion of ..; ompl".us. ?h.
lactu,res of I_A__XAXa=ZL9, C_g. Im"t-1,3L and . I - A
tic& or a *:t
dealt with the photometric date-mir"' .3-66 ~~!: =.t$
"1n& fluorine drIvat... A. 1. Charts.., I.at-I .4 1" .- of
bal-brazati.a. 1. analyti-I hAoi &.4 T. U,
lta:umd an the determination of tantalum u.slAd
Patroybot...tr7. tR_r_Xj-.h-kiZ had "
Lto part4a on now highly awnsIll- analy.ia ~thcdm
1.2ot 5.worml lectnres dealt with
methodical sad theoretical pmbl..* of spectrum
Q_._tL_takbpzLy and Y- T.Traht. -A
am~rkarw~ ;CU. 3. Poluokta, And X. I. Ilk.nowe tra.z.1 th.
port r1 4 pb4toottr7. S."ral loct."m d.&Z* with the
*at
do It. raL n& of element. by polaxacrphy (S. T, Al -k-
1. Iq-hd--tx,n,k 1. A. Ya___1 I To. P. Gokh; n.D-.e' U..
erm And-
"Oultg in usire ri.od I.NANG1. ~-.. rij~rited-bx- T. D.
es.nahj&q Lad ju. S. Lyalikov And oo-woessra. Mh* locturv of
1. 1. vdau!n- Iros.-ad the -4 of -;wrvz.trtc
titratl.n t n the chemistry of uradlun t44
thorj%ag. U. M. S.vy%win h ... d p .. ibiliti.. of p-dl.tIuj the
oditl." of ch-astag-pbl. ..gazatio. of ol.a..to based
their pool lan I. ~. periodic my.%... T. A. 3.1y.w. ralort.1
t
oa the us. of %on exckarge In the Isw94tIS&tL0M 4' the $14%. of
wabstana In walutlo.4 &,j_j!rL.Adb And
bra" gr%;hlc up.- in.
,.v t= th to t .1
reported an adapting the g.-Pr As
is,
be . ra end rol,.,t.,
1-1d. preps~-tl- In
on the hraantog-phi
Card 314 liquid& of the orgs-nila. G. I- Staroblrots and &860CIAtO8 trva-et
the application of high polynors in chromatographic analy.te.
The J.ctrv of r4 G..S*L
dealt with gas chro"toraphy. Several lectures t-eatod tt~e use r
re.dloentIrs Isotopes for the chr-t~rraph4c Invootifat4on of
co.~Jsx f.-.tio. end ss..J.tos). far %h.
Iavestigation of the co-procipit&tIon machari.. of t.- of to r.
metals with vulfide& (D- I. R-ijoar) and for do . ral. mi ~g -re
.laments bj Aa- of I topz dllutioL
ad VA~=Isars with
th A I.. __ ... Z,-:.l
annoclataw twTo to be uentinmd, vho t-tod Me al-~tlon -If
rapid micromethods for the sizujtu~ous d.tomi-ti.. r ..,-z
f-..." brc.. fl~rl- -4
I ~y

PHASE I BOOK EXPLOITATION SOV/4278
Lyalikov, Yuriy Sergeyevich
Fiziko-khimicheskiye metody analiza (Physicochemical Methods
of Analysis) 3rd ed. Moscow, GoskhImizdat, 1960,. 438 P.
Errata slip inserted. 15,000 copies printed.
Ed.: K. D. Leontlyeva; Tech. Ed.: Ye. G. Shpak.
PURPOSE: This textbook is intended for students of chemistry.
It may also be used by workers In research and plant lab-
oratories.
COVERAGE: The book deals with the theory and practical appli-
cation of physicochemical methods of analysis. Laboratory
apparatus and instruments are described. In this edition
special attention is given to des-riptions of new apparatus
used for physicochemical methods ~f analysis. Problems
and practical exercises are given at the end of each chapter.
The author thanks the following persons for their assistance:
Doctor of Chemistry A. I. Kokorin and Candidates of Chemistry
N. A. Polotebnova and M. B. Bardin, all members of the
Card~

Physicochemical Methods of Analysis SOV/4278
Department of Analytic Chemistry, KishinalrRviv go5udarstvennyy
universitet (Kishinev State University); , V.,P.Sychev,
Docent, Optics Department, and Candidate oi iriijalcs and
Mathematics; and L. V. Nazarova, Docent, Inoraanic Chemistry
Department, and Candidate of Chemistry, both of the same
university. References accompany several of the chapters.
TABLE OF CONTENTS:
Foreword to the Third Edition
5
Ch. I. General Information 7
1. Methods of analysis 7
2. Processing of observation data 10
3. Graphical presentation of observation data 20
Problems and questions 22
Bibliography 26
Ch. II. Colorimetric Method 27
1. Theory of colorimetric method 27
2. Equipment 42
C&rd447.

IYALIKOV, Tu.S.
First All-Union Conference on Polarographic Analysis. Zav.lab.
26 no.5:648-649 160. (MMA 13:7)
(Polarograph-Congresses)

$8278
S/032/61/027/001/003/037
~'v3oo 3 1/3) BO17/B054
AUTHORS: Safronkova, N. N. and Lyalikov. Yu. S.
TITLE: Chemical Analysis of Semiconductor Allopin the System
In - Sb - Te
PERIODICAL: Zavodskaya. laboratoriya, 1961, Vol. 27, No- 1, pp. 21-22
TEXT: A complexometric method of determining indium in the presence of
antimony and tellurium by redox reactions has been developed. Tellurium
is reduced in acid medium by iodine, and antimony (III) is determined by
titration with bromate using methyl red as indicator. Preliminary tests
were made with synthetic mixtures of spectroscopically pure indium,
antimony, and tellurium. The sensitiveness of tellurium determination in
the presence of antimony was found to be t 0-5%- Indium determination in
the presence of antimony and tellurium was possible with an accuracy of
t 0.5%. Indium was determined at pH 8-10 by titration with 0.01 M Trilon B
solution and with the use of eriochrome black ao indicator until the color
changed from violet to blue. Compounds and alloys in the system In - Sb- Ta
were studied. There are 4 figures.
Card 1/2

Chemical Analysis of Semiconductor Alloys
in the System In - Sb - Te
f . - !
88278
S/032Z61/027/CC1/003/037
B017/3054
ASSOCIATION: Institut khimii Moldavskogo filiala Akademii nauk SSSR
(Institute of Chemistry, Moldavian Branch of the Academy of
Sciences USSR)
Card 2/2

LYALIDOV, Yu.S., prof., doktor
"Electrode processes and research methods in polarography" by
W.K.Delimarskii, A.V.Gorodyskil. Reviewed by IU.S.Lialidov.
Zav.lab. 27 n0-7:918 161. (MIRA 14:7)
(Polarography) (Delimarskii, IUA.) (Gorodyskii, A.V.)

8/137/62/boo/612A85/685
A0061AI01
AUTHORS: Iyalikov,~Yu. S., Kopanskaya, L. S., Safrokova, N. N,
TITLE': Chemical and physico-chemical methods for determining Indium,
antimony, ,and tellurium in semiconddetor alloys
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 12, 1962, 19
abstract 12K118 (In collection: "Fizika", Leningrad, 1962.'
26 - 30).
TEiT: The authors developed m&cro- and microchemical methods of determin-
ing'In, Sb and Te, without separating same, in semtoonductor *alloys. The mean V
errpr does not exceed + 0.5%. For In determination,.5 mllO%-solution of Seig- -..
nettels salt, 10 - 15 ;l buffer mixture (pH 8 -% 10). and eriochroire black tracer..
are added to the solution under investigation. The mixture is heated to the boil-
ing point and titrated with trilon B until it turns blue. To determine Sb,
5 - 10 ml HCL (It4) and one drop of methyl red tracer are added to the aliquot
portion of the solution, which is t1trated in 0 1 n KBrO solution until it
turns yellow. To determine Te, 1 2 g KI is added io th~ aliquot portion of the
Card 1/2

S/137/62/00()/012/085/085
Chemical and physico-chemical methods for. Aoo6/Aioi
solution which Is then titrated with Na thlosulfate in the presence of starch.
To determine the aforementioned s6b3tances, physico-chemical methods were also
developed (potentiometrical, polai*ographical and colorimetrical methods).
L. Voroblyeva
[Abstracter's note: Complete translation)
Card 2/2

PODRAZHANSKAYA, Ye.Lj-.~Y K-QY,-Yu,$,.,..-,doktor khim.nauk, prof.,
A~L
nauchnyy red.; MATKOVSKAYA, N.A., red.; M&NDELIBAUM, M.F.,
takhn. red.
[Polarography; index of literature on polarographic study
methods, 1950-1957]Poliarografiia; ukazatell literatury po
poliarograficheskim meto4am issledovaniia, 1950-1957 gg.
Kishinev, 1960. 72 p. (MIRA 16:2)
1. Akademiya nauk SSSR. Moldavskiy filial. Nauchnaya bibliotaka.
(Bibliography-Polarography)

ACCESSION NR: AR.3000205,
of the sam acid to a 10,m1 flask and brought up to-the mark. To dater-
mine Ta: to 1ml sample solation, added equal volume of 10 K-Na-tartrate
Ml a=oniUm chloride buffer of pH 8-10; heaM at 75" and
solution,, 40-5
titrated with 0.01 M solution of Comnlexon III to Eriochrome Black T. -To
determine Sb: to 1, ml of solution be ing analyzed -is added I ml HC I ( I I
heated at.60* andtitrated with 0.*05 N solution of bromide-bromate to
Yethyl,Red (the indicator Is added at the end of titration).- To determine
Te: to I ml of solution being analyzed is added I ml 11C1 (1-0), an excess
a-
of dry HI, andthe liberatediodine is titrated with.0.1 N solution of N
thiosulfate, in the preience of starch, Titers of the solutions are deter-
mined under the same conditions against solutions of salts prepared from
elemenU OfLhighest degree of purity. In-titrations it is mandatory to
take into account indic4t,or error. Reproducibility of determinations is-
entire13~ satis&ctory. Average relatIve error less than 3%. On analysis
of a sam 'L
,ple'of less than 'I'mg, 8b, and Te are titrated potentimetrical. y.
determine Sb,' to-$OlUtion of the sapple are added 3 ml 11C1 (1: 1), di-
TO
luted with vater~ to about 20. ml.. ~ an4' titrated, with. bromide-bromate solu-
tion, with Pt Indicator electrode and saturated calomal electrode,, using
LP-58 potentimatear, ln~ determining To. to the solutionLof the sample are
Card 2/3

ACCEW1011 ?;R:. MOOM05
added 3. ral IICI01), excess of KI, diluted with water to 20 ml and tit-
rated with SolUtiOn of Na-thiosulfate. Ablank.titration is carried out
concurrently., Error of determination.of Sb less than 4.7%; of Te, less
than 6.4. ~ The methodAs suitable for analysis of film of semiconductor
ass it is treated with molten
materials (to remove the film fromthe g3
K-bisulfate and veight of samle is determined from.decrease in welght
of glasB)., and ofmie'rosamples obtained-by drilling from different phases
of,semiconductor materials, N. Chudinova

KOPANSKAYAI. L.S. ; LYALIKOV, YU.S.
Photocolorimetric analysis of the system indium - anti-Mort.7 -
Izv. AN Mold. SSR no.10:31-37 162, (MIFA 17:12)

BODrtl,, V.I.f KOZ14VA, I.V.1 IZA=OV, U.S.
Palm polaregrapbie-nothod of analysis (survey). Zav. lab. 28
no.911042-1047 162. (MMA 16W
(Pblaroxmpby)

BODYU, V.I.; KOZLOVA,.I.V.; SISTER, Yu.D.; LYALIKOV, Yu.S.
Determination of the end voint in acid-baBe titr-ation by
means of tensammetric pea6. Zhur. anal. khim. 18 no.5:
659-661 My'63. (WRA 17:2)
1. Institut khimii AN Moldavskoy SSR, Kishinev.

BODYU, V.I.; LYALIKOV, Yu..S.
Pulse polarographic determination of some alklehydes. 7nur.anal.khim.
18 nc,.8-.1007-1011 Ag 163. (MIM 16:12)
1. Institute of Chemistry, Academy of Sciences, Moldavian S.S.R.,
Kishinev.

LYALIKOV, Yu.S.; MADAN, L.G.; BODYU, V.I.
Pulse polarography on solid electrodes. Zav.lab. 29 no.11:
1289-1291 163. (MIRA 16:12)
1. Institut khimii AN Moldavskoy SSR.

LYALIKOV, Yu. S.; BODYU, V. I.; MADAN, L. G.
"Alternating current polarography at the stationary electrodes."
report submitted for 3rd Intl Polarography Cong, Southampton, 19-25 Jul 64.
Univ of Kiev.

LYALIKOV, Yu.S.; SISTER, Yu.D.
Pulsopolarograph-4c detemination of calcium and magnesiizn.
Zav. lab. 30 no.9:1073-1074 164. (MIPA 19:3)
1. Institut khimii AN Moldavskoy SSR.

LYALIKOV,ju.S.; RADAUTSAN, S.I.; KOPANSKAYA, L.S.; MOLODYAN, I.P.
Synthesis of complex semiranductor phanes and th-(jir
analysis, Vest. All SSSR 34 no.9:75-78 3 164.
(MTRA 17:10)
1. Institut fiziki i matematiki AN MoldavBkoy SSR i institut
khimii AN Moldavskoy SSR. 2. Chlen-korrespondent AN Mol-davskoy
SSR,

SOLONAR', A.S.
Polarographic determination of hexachlorobutadiene. Zhur. anal.
khim. 20 no. 11:1228-1230 165 (MIRA 19:1)
1. Kishinevskiy gosudarstvennyy universitet. Submitted llovember 17,
1964.

PCDOIEIJKO, A.A.; CHIKRYZCVA, Ye.G.;,,WgKgV, Yu.S.
Coulometric determination of nitroso compoundB. Ukr. khim. zhur.
31 no.8:844-846 16~. (MRA 18:9)
'-. Institut khimii AN Moldavskoy SSR.

MADPJI, L.G.; LYALIKOV, Yu.S.; BCjDY(f, V.I.
Puli3e polarographic dot-ormAriation of motala on rolid
Zav.lab. 31 no.10:1182-1183 165. (mi'u :L9: I)
1. Institut khimii AN MolCavskoy SSR.

LYALIKOV, Yu.S.; BODYU, V.I.; KOZLOVA, I.V.
Ise polarographic r,,--t'-rad of deLe-Jr-ing Z-neb. 7a-,-.Iab. 32
U .1 -
P
no.10:1190 t65.
1. Institut khi-mii AN Moldavskoy SSR.

LYALIKOV, Yurly Sergeyevich.- VASKEVICH, D.N., red.
1~
[Rqsicochemical methods of analysis] Fiziko-khimiche-
skie metody analiza. Moskva, Khir-iia, 1964. 557 P.
(MIRA 18; 10)

W
ACC NRt AF6036390 SOURCE CODE: Uq/0032/66/032/01AL/13'i9/1.120
AUZHM: Lyalikov, Yu. S.; Kolchina, X. Ye.
O'RG: Institute of Chemistry, MoldSSR (Institut khinii L\I I-LoldSSR)
'TITIE: Datermination of the main component's in semiconductor compounds of indium with
and phosphorus
.SOTjRCE. Zavodskaya laboratoriya, v- 32, no. 11, 1966, 1319-1320
~TOPIC TAGS: indium containing alloy, arsenic o-o phosphorus cc;;;~
quantitative analysis
;.ABS'LaACT: Zae article describes a method and the results of an analysis o' fhe binary
!alloys InP and 1nAs and the ternary alloy InP-InAs. To bring arsenic and Phosphorus
;'into the pentavalent state, weighed portions were dissolved in a flask with nitric acidi
i
!or with a mixture of nitric and hydrochloric acids. Determination of indiiza was done
by thp direct volumetric: complexometric method using xyxyl orange as the indicator. Ini
the analysis of the alloys InP and InAs the results were on the low side; this is
it~aought to be connected with the formation, at a certain p1i, of indium. arsenate and
Adding ammonium citrate salts to the solution before titration promotes
,rhos,phate.
;solution of the precipitate which falls out and aids the normal titration ol' indiun.
!In addition, the addition of this reagent helps to establish the required pH of the,
Card 1 /2 UDC: 543.7

ALL;
-AP6036390
solution, 3.5. In analysis of the BP alloy, phosphorus was determined i=ediately
after the determination of indium in the same solution, by the magnesia weight method.
in Vne analysis oil the InAs alloy, after determination of indium, AsO4,- was determinedp:
in the sam solution by the io ometric method. In the analysis of the !nP-!nAs
system, As was reduced according to the reaction:
Aso3-+2j- + 2H+ ~- AsO3'- -JrIi,O-N,.
4
'thus paving the way for the subsequent determination of in the presence of As03-
. t> Pq 3
hosp. orus content was determined after determinati n of the arsenic, by
The V 0 the
magnesia method. All experimental results are shown in tabular form. Orig. art. has:
Itable.
SUB CODE. 07, 11/ SUM DATE; none/ ORIG REF.- 002/ OTH REF. 003

I L 12155-66 EW(d) rJP(c)
,ACC NRt AP6000012_ SOURCE CODEs UR/0208/6570-05/006/0979/09901
,CMHORS s Birger, (Moscow); joralikoval N.B. (Moscow)
ORG: none
TITLEs Pinding solutions satisfying a given condition at,infinity for systems of
.ordinary differential equations. I
SGURCEt Zhurnal vychislitelluoy matematiki i matematicheakoy fizikig V- 5t no. 6,
19659 979-990
TOPIC TAGSt differential equation, boundary value problem nonlinear equation,
first order differential equation, Cauchy problem
ABSTRACTi The authors consider the system
:t'AX+v1(t,X) +, 19 01'-
0)
to < I
of nonlinear first order'equationsi,where r is a nwmegative integerp A is a constant
matrix allof whose .eigenvalues have positive real,partat f(t#X) is defined and
,continuous for IXI small and t t'g(t) is defined and continuous for
to
Z too lim g(t) - 0. Considering the Cauckq problem at oo# they show on the basis
t -P 00
of their results that one can solve the bmmdu7 value problem for linear aystems with
Card 1/2 UBCS 518!.-

L 12155-66
.ACC NRs Ap6o()0012
t7 49 t -P oD with a condition of boundedness of solutions at the
right end of 110 ICO)j and some condition at to. A version of this problem on the
finite interval ZTO,T7 is also considered. The authors express their gratitude to
A. A. MIA kor stating the problem and for mch valuable advice. Orig. art, hast
25 formlas-
SUB CODEs. 12/ SUM DATE i 04-TaU65/- ORIG RM 003/ OM Mwt 002
Card. 2L2

EU t(d) ljp~c)
ACC NR, A1'6018627 CODE: UR/0208/66/006/003/0446/045.3
,':AUTHOR: Birger, Ye. S.; Lyalikova, N. B.
ORG: none
TITLE. On finding solutions with a given condition on infinity for several-syste
ordinary differential equations, IT
SOURCE: Zhurnal vychislitellnoy matematiki i matematicheskoy fiziki, v. 6, no. 3,
1966, 446-453
TOPIC TAGS: ordinary differential equation, Cauchy problem, boundary value problem,
perturbation theory, approximation method
ABSTRACT: On the basis of Part 1, 1965, 5, No. 6, 979-990), which treated the Cauchy
problem in infinity for several nonlinear systems of form
X; = tA (t) X + V/ (t),
under the assumption that matrix A0 does not have purely imaginary eigenvalues, an ex-
tension is made to the case where A0 does have simple eigenvalues on the imaginary
axis. In (1) the functions AM and f(t) are continuous on [to, oo) and for t-+.oo have
the following asymptotic representation:
0* A
A (9) - 2 _".
th.

M
iACC NR- AP6018627 0
JA practical solution of this problem is offered by the method of projection from infin-
jity to a finite point T, thus reducing it to an equivalent boundar-j value problem on
ithe interval [to,T]. The extension is made practicable by the possibility of using
perturbation theory to determine corrections in the non-multiple eigenvalues of AO
which lie on the imaginary axis. This means that one can find a linear manifold of
bounded solutions of system (1) by considering only a finite number of matrices Ak in
the asymptotic representation of AM for large t. Orig. art. has: 36 formulas.
SUB CODE: 12/ SUBM DATE: 22Jul65/ ORITREF: 001/ OTH MF: 000
Card 2/2

LYALIKOVA, N. N.
Some properties of microflora of silt and their role in
balneologic properties In silt. Trudy Inst.mlkrobiol.
no.4:202-206 155. (MLRA 9:1)
(90 THZRAPT,
bacteriol. factor in ther. value of silt)
(BACTMIA, '
in silt, balneol.aspects)

USSR/Microbiology - General Microbiology. F-1
Abs Jour : Ref Zhur - Biolso No 12, 1958, 52741
Author : Lyalikova., 17.N,
inst
Title : A Study of the Assimi0tion Process of Free-.Xarbonic
by Purple Sulfobactoria in Lake Beloved,
Orig Pub : Mikrobiologlyn, 1957, 26, No 1, 92-98.
Abstract : In 1954 a study was conducted on the ecology of purple
sulfobacteria (PS) in 1.0ce Beloved (Vladimir region),.
which.is characterized by PS mass production frora the genus
chromatium (up to 170-000 cells per ml) at a depth of 12-
13 M, where the border of o-4gen and hydrosulfite zones is
located. By exposing light cuid dark flasks with cultuxes
of Sconedesmus it vas established that photosynthesi 's in
the lake is possible up to a depth of 17 m. At a depth of
13-14 m the PS have a sufficient amount of light and H2S.
Laboratory experiments with a ctrm-lative culture of PS
Card 1/2

IVANOV, M.V.; LYALIKOVA X.N.- k=NETSOV, S.I.
-------
Role of Thiobneillus in the weathering of rocks and sulfide ores
[with summary in Engli8h]. Izv.AN SSSR Ser.biol. 23 no.2:183-191
Mr-Ap 158. (MIRA 11:4)
1. Institut mikrobiologii AN SSSR.
(THIOBACILLUS) (WEATHERING)

ITALIKOVA. N.H.
"
Studies on chemosynthetic processes in Thiobacillus ferroxidans
[with summary In English]e' Mikrobiologiia 27 no-5:556-559 S-0 158
(MIRA 11:12)
I# Institut mikrobiologii AN SSSR'
(TRIOBACILWS. metab *
chemosynthesis in Thlobacillus ferrooxidans (Riis))

SOV/18()~59-1-25/29
N-11
AUTHORS: Zarubinaq Z.M.,.Lyalikov~. N. and Shmuk, Ye.I. (Moscow)
TITLE: Investigation of the Microbiological Oxidation of the
Pyrite of Coal (Issledovaniye mikrobiologicheskogo
okisleniya pirita uglya)
PERIODICAL; Izvestiya Akademii nauk SSSR, Otdeleniye tekhnicheskikh
nauk, Metallurgiya, i toplivo, 1959,Nr l,pp 117-119 (USSR)
ABSTRACT: This is a preliminary communication on work carried out
ointly by the Laboratoriya Obogashcheniya IGI AN SSSR
Enrichment Laboratory of the IGI AS USSR) and the
~
Institut Mikrobiologii AN SSSR (Institute of Microbiology
of the AS USSR) on the oxidation of coal pyrites by
microbiological methods. The work was started in 1957
as part of the general study by the former organization
of methods of oxidizing -zoal pyrites for desulphurization.
A culture of Thiobacillus ferro-oxidans was prepared and
added to coal samples. In one of each pair of samples
the bacteria were killed. Analysis for sulphur after 10,
20 and 30 days showed that in these no desulphurization
Card 1/2 occurred In contrast to the samples with live bacteria
(table). The fineness of the coal and the age of the

SOV,/180-59-1-25/29
Investigation of the Microbiological Oxidation of the Pyrite of
Coal
culture had some effect on the oxidation.
A.Z. Yurovskiy and S.I. Kuznetsov advised on the work.
There are 1 tabl"a and 7 English references.
SUBMITTEDs July 12, 191~8
Card 2/2

LYALIKOVA, N. N.: Master Biol Sci (diss) -- "The physiology and ecology of
Thiobacillus ferrooxidans in connection with its role in the oxidation of
sulfide ores". Moscow, 1959. 16 pp (Inst of Microbiology of the Acad Sci
USSR), 200 copies (IG., No 11, 1959, 117)

LYLLIKOVA N. N.
IMNA of Thiobacillus ferrooxidans in the oxidation of sulfide
ores in pyrite deposits of the Central Urals. Mikrobiologiia 29 no,3.
V2-387 Mv-Je '60. (MIRA 13:7)
I
1. Institut mikrobiologii AN SSSR.
(URkL MOUITTAINS-PYRITES) (THIOBACILLUS)

LYALIKOVAt N.H.
PhYsiology and ecology of Thiobacillus ferTooxidanB with reference
to its role in the oxidation of sulfide ores. Mikrobiolool'Aa 29
no.5s773-779 S,-O 160. 13:13.)
(IR(~ff BACTERIA) (SULFIDES)

WIN
LYALIKOVAO N.N.
Role of bacteria in.the oxidation of sulfide ores. Trudy
Inst.mikrobiol. na.9:134~1-/1,3 161. (MMU 15:5)
1. Institut mikrobiologii AV SSSR Moskva.
(Sulfides i
(Him Wter-MicroblolbW) -

LYALIKOVA, U.N.
Role of bacteria in the oxidation of sulfide ores in the copper-
nickel,beds of the Kola.Feninsula. Mikrobiologiia 30 no.1:135-139
Ja-F 161. (MIRA 14:5)
1. Instituta mikrobiologii AN SSSR.'
(KOLA PENINSULA--SULFIDES-~IICROBIOLOGY)

KUZNETS0V S-L; IVANOVx H.V.; LYALIKOVA, Iq N.- IMSHMTSKIY, A.A.,
BEV FM
;tv. red.; SHCIMRBAKb~,. ,*,e -va; S C NO, G.N.,
tekhn. red.
[Introduction to geological microbioloq] Vvedenie v geologi-
cheskUiu mikrobiologiiu. Voskva, Izd-vo Akad. nauk SSSR
1962. 238 p. (MIRA 15:31
1. Chlen-korrespondent Akademii nauk SSSR (for Imshenetskiy).
(Geology) (Microbiology)

IVANOV, V.I.,-.LYALlKOVAs N.N.
TaxonoTq of iron-oxidizing Thiobacilli. Mikrobiolo iia 31
no-3:468-469'My-Je 162. %L 15:12)
1. Inatitut mikrobiologii AN SSSR i Urallskoye otdeleniye
Vsesoyuznogo nauchno-isaledovatellskogo geologo-razvedochnogo
instituta.
(BACTERIA$ SULFUR)

LYALIKOVA9 N.N.; KU--IKOVI%, M.~.
Leaching of rare elem---nts from sulfide ores -,uider the influence
.3-674
of bacteria. Dokl. AN SSSR 164 no -6,~6 S 165.
(MJRA 18:9)
1. Institut miki-obiologii AN SSSR i Institut mineralogii i
geokbimii redkikh elementov. Submitted November 28, 1,964.

LYALIKOVA2,14.1l.; jSOKOLOVAP GOA.
Microbiological characteristics of Some ore deposits of central
Kazakhstan. ldkrobiologila 34 no.2:335-343 Mr-Ap r69'.
(MIERA 18: 6)
1. Institut mikrobiologii AN SSSR.

LIPIS, B.V,, Rani.takhn.nauk; LYAI,IKCJVA, 1,,.Yu.; L.L~
I
SLeci-r3plictuiretri-2 M3thod for detqrm3n-rg +,arln-ng and
- - - - , -f 1 4.
Substancea in grzape must and w,ne. Trad~i MITT-l"T 4ilG9--,-L,,. 0
(MIRAI 18,,~)

LT PTS 9
B.V., kand.takhn.riauk; LY.AlIKOVA, R.Yu.~ DUGAYVIA, L..,~
HLgl--froqur-.n,,y Utration of vfne a-ad Trudy ri-11.11PIP, 4--l'.15-123
164. (MIRA 18".1',

POL0TFjBVOVAq N.A.; ~YALIKOVAq R.Yuo
Photocolorimetric determination of dionine. Apt* delo 10
no. 1:5&-59 Ja-F 161. (MIRA 14:2)
(COLORIMETRY) (MORPHINE)

LIPIS, B.V,j MOIAKOV, A.A.; YEPIFANOV, P.V.; Prinimali uchastiye: SPEUOR, L.A.;
LYALIKOVA, R.Yu.
Naeration of grape juice. Trudy NNIIPF 2:81-86 162. (MIRA 16.4)
(Grape juice)

LIPIS, B.V.; DUGAYFXA, L.J.; LYALIKOVA, R.Yu.
Spectrophotometric method of determinIng the quall%i a-f
i-IM
anticorrWive epoxy resin coatings on aluminum. T , 112111 -11PP
5379-86 164. 0~1-~IfIA 19,~J)

30417
0/-? .5) S/058/61/000/009/b39/050
A001/AlOl
AUTHORS: Simashkeviah, A.V., L7alikova, T.
TITIE1 Temperature dependence of zinc selenids photoconductivity
PMUODICALs Referati.vnyy zhurnal. Fizika, no. 9, 1961, 225, abstract 9E38O
I'Uch. zap. Kishinevsk. un-t!', 196o, v. 55, 21 - 23)
TEXTt 3:n order to-alarify the processes taking place In ZnSe being sub-
jected to illumination, the temperature dependence of photo.conductiVity of ZnSe
layers obtaine*d by atomiXed cdating in vacuum and annealed in air was investi-
gated. Thu temperature dependence of photoconductivity was-Dbtained in both
the aimosphere from room temperature to +3000C and in vacuum from the liquid 02
temperatmeto+1500C. In both cases, with rising temperature photocurrent in-
.creases, attains a maximum and +,hen drops (in the atmosphere the maximum is
displaced toward higher temperatures). The magnitude-of photo -currOnt-and dark
current at measurements in vacuum is higher than.In the atmosphere; this is
apparently explained by disappearance of traps, created by adsorbed air, in the
ZnSe layer in vacuum. The gr6wth of photo-conductivity in ZnSe occurs in the
Card 1/2

3e417
S/058/61/000/009/0.39/050
Temperature dependence of zinc selenide ... A001/A101
temperature range corresponding to transition from extr1iD#ic to intrinsic con-
ductivity; it is probably connected-with an increase in the life time of
carriers. P. Nad' Z
[Abstracter's note: Complete translation]
Card 2/2

LYALIKOVA, V. S.: Master Med Sci (diss) -- "rhe state of the organ of vision
in syphilis patients with protracted observation". Tomsk, 1958. 18 pp
(Tomsk Med Inst), 200 copies (KL, No 6-, 1959, 145)

IZAL1KOVAv V.S.
State of the eye in patients with syphilis during prolonged
oboervation. lbst.demA ren. 33 noo6t4&31 N-D 159.
(SUM S) (M) (MMA 13:12)

BERCH, P.F. [Birch, P.F.l ; -~Y ~A.A. ~ranslatorl
Use of the regression method in compounding'rabber mixtures.
Kauch. i rez. 19 no. 11:58-63 9 160. (?4I:U 13:11)
(Rubber)

ACCESSION NR: -AP4038905 S/0138/64/000/005/0001/0004
AUTHORS: Lyalins A. Ao; Shvarts,* ke G.; Buyko, 0. N,
TITLE: Applia-Go-n-oT -calculated characteristic properties of rubber mixtures
SOURCE: Kauchulc i rezina, no. 5, 1964, 1-4
TOPIC TAGS: internal friction, rubber plasticity, impregnated mixture, activation
.energyj*polymerj viscous flow, intermolecular interaction, vitrification temperature..
'ABSTRACT: The temperature dependence of tihe hardness index and modulus of internal-
:,friction in rubber, determined on a Cornfeld instrument, were investigated experi-
mentally. Hardness measurements permit the determination of original rubber
:plasticity for a specific mixture, and friction measurements shed some light on tho~
:heat-generating characteristics of rWober. Both impregnated and nonimpregnated
:mixtures-of various rubber bases: NK, SKI, butyl-300, SKS-30MIN and SKN-26 were
'investigated (properties of each specimen are given in tabular form). Xeasurements
'were made in the temperature range 20-100C, and the results are presented graphical-
~ly as lgk versus 1/T (r~- viscosity). The results agree closely with the
'Arrhenius formula
Card 1/2
!16 -

!ACCESSION NR.- AP4o389o5
ulqr
4where ~T - viscosity at absolute temperature T, U nominal activation energy of
jpolymer in viscous flow, R - gas constant,),-O-'eonstant. The magnitude of U was
I
!was calculated for the hardness index of raw mixture specimens and for internal
ifriction modulus, U is found to depend on the nature of the polymer,, increasing
'Un general) with an increase in intermolecular interactions and increase in
Ivitrification temperature. The initial plasticity of the rubber does'not affect
!the temperature dependence of the mixture hardness. Orig. art. hass 5 figures,
12 tables, and 1 formula. ./
!ASSOCIATION: Nauchno-issledovatellsldy institut shinnoy promy*shlennosti
i(Scientific Research Institute of the Tire Industry)
!smrrm: oo DATE ACQ: O5Jun64 EDICL; 00
SUB CODE,-. Mr NO REF SOVz 009 OTHIM% 002
Card 2/2

LYALIN, D.
I
Improving the deoign of ta4cabs. Avt.tranap. 40 no.12:32-33
D 162. (MIU 15.12)
(Ndcabs)

RZADKOWSKI, Jan (translator]
Soviet-made passenger cars. Horzy techn 18 n0-4:12-13 Ap 1641.
1. Chief Specialist of the State Committee for the Construction of
Automobiles and Machinery for Farming Purposes at the Stato Planning
Commission of the U.S.S.R.

KAGAKOVICH, Z. I.; SK
_jPl,IT D. V.- ; 1,TSHM' 1y, 1- 1,1-
j_,_
EnUs -
The Lubrication of the Stamping Hammers
'lest Mash p. 30, Sep 51

LYALIN, D.Y.; ATOYAN, X.M.; YUSHMP.HOV, A.H.
Passenger care and motorbuses at the Geneva Automobile
SxUbition in 1960. Avt.p:rom. no.8:36-43 Ag 160.
(MIRA .13:8)
(Geneva-Exhibitions) (Automobiles) (Hotorbuses)

UAL IN. Z,
inzh.
O:i~arilzation of' tIns traasportat~on of mineral bu-41ding =.aterlalz
5hou"A meet current de4plinds. Rech, transp. 24 no.7:15-16 165.
(MMA l8s8)
I, T3entrai~riyy naachno-donledovatellskiy instultut ekonomiki i
!..Tar..,.porta.

LYATAIN, F.
Separation of a gravel and sand mixture in hydraulically
mechanized unloading. Rech. transp, 21 no.10:15-18 0 062.
(MMA 15: 10)
1. Nachallnik mookovskogo Zapadnogo porta.
(Hydraulic conveying) (Separators (Machines))

- -L-Y"~j-ulvr- -
-
LTALIN, iao
-
Operation of crevless barges. Rech.transp, 16 no.12:35-36 D 157.
(mm 11:1)
l.Glavnyy inzhener Zapadnogo porta Moskovskogo parokhodstva.
(Barges) __,

Ai-
LYALIN, F.I.
Hydromechanical unloading of sand from barges. Recb.transp. 17
no.9:13-16 S 158. (faRA 11:11)
1. Glavnyy inshener Mosknvskogo ZapadmgIO-Porta.
(Sand--Transportation) (Loading and unloading)

BUKHMN, Yevgeniy 14ikhay'lovieb; LYALIN, Foliks Isayevich; SANDLER,
Polina Yev'seyevne, SHLYAPIN fg--o ri I -A nidre"y--ev I a-h--;--R'-OK'-&YAN,
S.S., red.; DWKOV, Te.D., red.; BOWHOT, H.I., takhn. red.
[Survey and comparison of foreign standards for designing
the structural section' of electric ppwer transmission systems]
Chor i sravnenis zarubezhnykh norm na proektirovanie konetruk-
tivnoi chasti linii elektroperedochi. *Pod obahchei red. S.S.
Rokotisna. Moskva, Goa. energ. izd-vo, 1960. 143 P.
(MIRA 14:5)
(Electric power distribution)

ARTEMIYEV, Aleksey Vasillyevich; VOSEMENSKIY, Aleksandr Alekseyevich.-
ITTENBERG, I.A.9 kand. tekhn. naukv retsenzent; LYALIRNU-F'I9f inzh.p
red.; MAKRUSHIM9 AJI.p red. izd-va; BODROVAp V;-r.9 teklm. red.
[Loading and unloading machines and mechanisms] Pogruzochno-
razgruzocbrye mashirq i mekhan' =y. Moskvaf Izd-vo "Rechnoi
transporty" 1961. 409 0 (MIU 34:7)
(conveying machinery~ (Cranes, derricks, etc.)
(Loading and unloading)

LYALIN, F.I... inzh.; I%IOVGO,;IODTSP-,V, B.P.p inzh.; SIERENUSIS,
red.
[Designs of the supports and wires of a.c. superhigh
voltage power transmission lines, 1961-19631 Konstruk-
tsii opor i provodov linii elektroperedachi peremermoga,
toka sverkhvysokogo napriazhaniia, 1961-1963. Moskva,
1964. 68 p. (MIRA 18:2)
1. Akademiya nauk SSSR. Institut nauchnoy informatsii.

---AP6025684- souRcz-coDE-.---M/0411/66/000-/013/0150/0150
Nk,
EhTOR: L~alin, F. I.
ORG; None
TITLE': A steering unit for guiding docking vessels. Class 65, No. 183617
1 SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarny-ye znaki, no. 13, 1966, 150
TOPIC TAGS: marine equipment, auxiliary ship, remote control
ABSTMCT: This Author's Certificate introduces a steering unit for guiding docking
vessels. The unit consists of a motor-propeller assembly set in the bov of the
vessel and remotely controlled from a tug. Vessel control efficiency is improved
under conditions of rotary motion, and coupling reliability is increased between the
vessel and the motor-propeller unit by mounting a plate which can turn horizontally
on the deck of the motor-propeller unit with a bar connecting the bov of the vessel
being towed by hinge-and link couplings.
Card 1/2 uDc; 629.12-42

4
7-
1-~rmotor-propeller assembly; 2-bov of docking ve&sel; 3-attacbment, for turning the
motor-propeller assembly; 4-turning plate; 5-rods
SUB CODE: 13/ SUBM DATE: 20Apr64

BUKHARB, Yevgeniy Mikhaylovich; KOLYAKOV, Ayzik Mordkovich;
KUROSOV, Aleksey Ivanovich; LYALIN, Feliks Isayevich-
tom'-f-.E., ine.-- -
TROFD40V
Viktor Ivanovich; L
[Designing structures for electric transmission lines
using the method of limiting states] Proektirovanie
stroitel'TWkh konstruktsii linii elektroperedachi po
predel'rWm aostoianiiam. Pod red.B.M.Bukharina. Moskva,
Energiia, 1965. 111 p. (MIRA 16:11)

LYALIM, G.M.
11 .... ~ 7
Attachment to the TaPA irachine for sawing veneer. Der. prom. 12
no.lOs2O 0 163. (MIRA 16:10)

MALIN, G*M*
Working of parts with nemiuval profiles on the FK-l
carrouBel-type milling machine. Der. pram. 12 no.8:23
Ag 163- (MIRA 16:11)
1. Sarapul'skiy Issokombinat.

.j
-7
~.-ACCESSIOI NR: ~AP300. 0 0'
6/0051/63/015/002/0253/026
fA
OA:,, Koby* shev 0,
U
M
,TITLE.- Luminesoefice of
and iniracomplax energy transfer In uranyl phthalocyanIne..
opti4a'I ~spoktroskopiyai: .15. no.2.~ 1-963 253-261
V,
:TOPIC TAGS: lunitnescence,energy transfer' uranyl ion phthalocyanlne~
AbSTRACT; The purposes of tlie work, were to Investigatti the luminescence of the cam.
~Pl6x com I witir, phthalooyanine in the expectation,that there would be:
pound of:urany
ob rum c ar t'
served'the spect 4 h eristic'ofietal-containing hthalo-eyanines nd MSI.~;
bly~the luminescence of th ran I cation itselg, and-to obtain evidence or intralf
complex. en r transfer; The uranyl-phthalocyanino complex was synthesized. _byV.F'.,:
gy_
-BorNkin In tlie.lvitnov,-Ch6mical,Enginearing Institute by a procedure analogous to
-that empl yed,b X.M.Kogan (Khimiya krasiteley PYye chemistr p.657, H. 1956) 'Tot
.0 Y/
..synthesizint metallo-phthalocyanines. That the complex actually was formed was
'chacked by.Infraired.spectroscopy. T4e luminescence.spedtra.in the red and near
-kinfrared (500 to 1000,mll) regions were recorded photoelectrically by means of-a
set --up. assembled- about. an ISP-51 glass optics spectrograph (dispersion at 700,04L

L-17782-63
-?M: :AP30058W~:
ACPESSION
-6p66tra-wi~r6 'obtained for the- 02Phc (Phc the phthalo ya-~
b~ouiv,5!m~vmm), The ,U
nin*o-s'holeto*n)-!s~s6ended~iu:va~aline:oiI and in. solutioncr in dioxano and nonane i-!
~Thes were compared,*ith:.the spectra-of-metal-free J12PhQ and MetPhc, The re
sdltm;-~
6n. nqs-i ~
0. DOMI 96imAti Study of the fine structure of the I J~
umi
plearly in
solution) method Indicates that the urany.L,
,cance spectra by the- Shp6l,tski (frozen
.,i' -scarce -4Z
1y perturbs th ener y,leveU of:tho.conjugated bond a
on 0 g Ystem of the'
O'rp6irin~rincOf U020hc.Jhe:,'coordinat1nC uranylAon participates in the 6-11
P
process, The excitation wavelength dependence of the luminescence spectrum Jndj.a~
the' existence of at leant two.types of luminescence centers: one active:ifi
cates
~tr nsitions from an excited singlet state to the ground state of the:; 1;
--6lectronic a
..complex; the other,~ig responsible for luminescence incident to transfer of cnergy~
fi- th ranyl cation to the~~systcm of it-conjugated bonds of :the azaporphyrin
rom e it
bring. A number of the absorption and luminescence
spectra are reproduced in~' thq:."
figures. The waVenumbers of.the luminescence lines are listed in tables.
take this 4portunity.to thank Academician A,N.Teranin for suggesting th t I
OP
and*,guidanco in the work. We. are also grateful to Docent V.F.Borodkin of vfic
'Chemical Engineering Institute for synthesis of tho-c
nov amplen and to labortitc
techniciarl,P.S.B *strov for i~ecordlnd the Infrared absorption spectra. a
10: f igures and 4 tablesb
.,Card

8/020/63/148/005/012/029
B'102JB186
AUTHORS: Lyalin, G. N., Kobyehev, G. I.
TITLEt Luminescence of the uranyl-phthalocyanin complex
PERIODICALt Akademiya nauk SSSR. Doklady, v. 146, no. 5, 1963, 1053 - 1056
TEXT: The uranyl-phthalocyanin complex investigated was synthesized by V. F.
Borodkin in the Ivanovskiy khimiko-tekhnologicheskiy institut (Ivanovo Insti-
tute of Chemical Technology). The IR absorption spectrum of the complex was
characterized by the 1055, 1068, and 1530 cm-1 bands which are observed in
phthalocyanins containing metal atoms, and the 1310, 1325, and 1006 cm-1
bands similar to those observed in free phthalocyanin. The 920 cm fre-
quency observed is attributed to stretching vibrations of the'UO++ ion. All
2
bands differ in intensity from those-observed in metal-free phthalocyanin.
The electron absorption and luminescence spectra also differ for uranyl
phthalocyanin and metal-free phthalocyanin, both dissolved in dioxane. The
solvent has little effect on the position of the peaks. The presence of the
uranyl complex is characterized by the 661, 632, and 598 (2900K) absorp-,
Card -1 /2. --- ----

S10201631148100510121029
Luminescence of the ... 3102/B186
tion and 676, 710, and 748 m (77 K) ltLminescence bands. The integral in-
0
tensity of the luminescence spectrum decreases at 77 K and increased with
T. The vibrational structure of the spectrum was studied by Shpollskiy's
method (UFN, 77, 321, 1962) at 770K on UO 2-phthalocyanin samples dissolved
in honane, and compared with the results obtained for metal-free H 2-phthalo-
cyanin in equal concentration 00-5 M). The fact that the luminescence in
UO 2-phthalocyanin proved to depend partly on the exciting frequency indicates
the presence of at least two different luminescence centers. The series of
peaks with 676, 709, and 747 MPL is a result of the luminescence of electronic
excitation on the complex as a whole. The series with the green peak
(692 m~L at 2900K) arises on energy transfer from the UO++ to the system of
Tr-conjugate bonds of the azaporphyrin ring of the UO 2-pgthalocyanin molecule.
There are 3 figures and 3 tables.
ASSOCIATION: Leningradskiy gosudarstvennyy universitet im. A. A. Zhdanova
(Leningrad State University imeni A. A. Zhdanov)
PRESENTED; July 21 1?g2, by A. N. Terenin, Academician
AUBMITTED; July 10: 2
Card- -272 -

L 134lo-63- BDS.
ACCESSION NRt AP3000526 1662 /04ib
"~AUTHOR:-- Lyalin,,'~G. No'; Koby*sbav, G.'I,;-Teren1n,4..H._
~TITLE: Qwnching of luminescence of carotenoid adsorbanto
MUM-. AN SSSR. Doklady jr.~ 150# no. 2,0 1963, 407-410,-
-;;TOPIC TAGS t luminescence-quenching,, carotenoid adsorbants',.klabilityj Beta-
~!carotine, lutein
a rue
;ABSTnCT-.- The adsorbants and solutions of Beta-carotin and the st turally
related lutain which enter into the composition of the pigments of a photo-
synthesizing plant were studied. The lability degree of addition of 0 sub 2 to
themolecules of~tbese pigments was explained in detail by the luminesuence
lquenabing,method. "'We wish'.to express our thanks to Professor D. I. Sapozhnikov
foraubi6itting Data-carotine and luteiii specimens and to V. I. Shirokov for
carrying outAh6 fluorometric measurements." Oiig. art. has: 3 figures and
formula.
~:ASSOCIATION:- Nauchno-isoledovateltskiy fizicheskiy institut Leningradskogo
I.gosudarstvennogo uhivtraiteta Im. A. A. Zhdanova (Scientific Research Institute
z ;of P48ics, Leningrad State University)
Card,,

KOBYSHEV, G.I.; LYALIN, G.N.; TERENIN, A.N., akademik
Photoreaction of Mg-phthalocyanin with a coordinated
uranyl cation, Dokl. AN SSSR 153 no-4:865-868 D 163.
(MIRA 17:1)
1. Leningradskiy gosudarstvennyy universitet im. A.A. Zhdanava.

ACCESSION NR: AP4009478 S/0051163/015AO6/0837/0838
AUTHOR: Koby*shev, G.I.; Lyalin, G.N.; Terenin, A.N.
TITLE: Manifestation ol a hydrogen bond in the luminescence spectrum of magnesium
phthalocyanine with uranyl nitrate hexahydrate
SOURCE: Optika I spektrookopiya, v.15, no.6, 1963, 837-838
TOPIC TAGS: hydrogen bond, protonization, magnesium phthalocyanine, uranyl nitrate,
magnesium phthalocyanine luminescence
ABSTRACT: In an earlier investigation (G.I.Koby*shev, G.N.Lyalin and A,'N.Terenin,
DAN SSSR,148,1294,1963) in which photoluminescence was employed to study excitation
energy transfer from the coordinated Uor, ion to magnesium phthalocyanine in ethyl
alcohol solutions there was established the following unique effect., at 2900K there
.is present in the luminescence spectrum of Mg phthalocyanine the usual narrow peak
of this compound at 673 aft together with a number of secondary longer wavelength
peaks, but upon freezingof the solution (cooling to 7M this peak virtually dis-
appears and a now peak at 703 up appears in the sensitized luminescence spectrum.
It was Interred that the now band was due to a protanized fozu of the pigment. Ac-
Card 1/2

AP4009478
cordingly, in the present study there'were recorded the fluorescence spectra of mag-
nesium phthalocyanine molecules adsorbed on silica gel and aluminosilica gel under
.conditions of higher resolution (DFS-4 diffraction grating spectrometer with photo-
.electric recording). In the case of both adsorbants there was observed the same
strong peak at 702 mg. In view of.the fact that these different adsorbants have in
common the presence of proton donor centers, it is logical to attribute the now
peak to a protonized form of.Mg phthalocyanins, ioe., to a formation of a hydrogen
bond. The probable mechanism of protonization is discussed and other features of
the luminescence spectrum of protonized Mg phthalocyanine are described. Orig.art.
.has: 2 figures.
ASSOCIATION: none
SUBMI 23May63 DATE AOQ: 03Jan64 ENCL: 00
SUB CODE: PROCH NR REF SOV: 006 OTHER: DOO
Card 2/2

LYAL111, G.N., ibzh.
..........
Efficiency of electronic systems vith unit-type or panel structure.
Priborostroenie no.12:23-24 D 165.
ORIF A 19: 1)

L 26061-66 9a(i) sarp DD
ACC NRi AP6015085 SOURCE CODE: UR/0020/66/168/001/0068/0071
AUTHORI Kobyahev, G. I.; Lya-lin, G, N.; Terenin A. M. (Academician)
Leningrad State University im..A. A. Zhdanov (Leningradakiy gosudarstvennyy
universitet)
kzr~.' TITLEz Luminekencei.of chlorophyll-excited by a'ruby laser-
17,
.~SOURCE: AN SSM Doklady, v. 168,1no. 1, 1966, 68-71
'_~TOPIC TAGS: luminescence, lumineacence*spectrum, luminescent material, laser
laser effect, chlorophyll
ABSTRACT., Experiments were performed. to detect radiation emission.during transition
of a molecule from the second excited sirgkt level to.the:ground level (S* so).
.':4'h1gh-power ruby laser (J. L. Hall et al., Phys. Rev. Lett., 11, 364.(1913); W. L'.
Peticolas, et al.-, Phys. Rev. Lett., 10, 43, (1963);' J. R. Birks et al,, Ph a. Lett.,
y
18, 127 (1965) was used to excite solutior of chlorophyll "a" (5 x 10- M), methyl-
chlorophyllide (5 x 10-3 M), magnesium phthalocyanine (10-4_M) in ethyl alcoholp
chlorophylline (5 x 10-3 M) in methyl alcohol, and phthalocyanine without metal
(10-4 M)..in dioxaneo The emission from a "Razdan" K-4-2 laser (pulse energy of 1
joule, with a pulse repetition frequency of 2 cps) was focused on the object by a
lens thra*h AKS-17 light filter. The luminescence of the object was separated by
means of a'ZMR-3 monochromator (linear dispersion in the investigated range was
Ccird 1/2 1JDC: 535,373.2