1 1: 1 lclq 1:1 11 ;11111 ~411 11. '11 tl 4 11; 1 11 N I
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9 14 11IT"'1~7
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so oopoloollooll Nolan on,,I,l sorstoolloo vt it'. -00
do III J 41,41141[t 4"'llips
tool
kwl ml
'
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. .1. $3. 4*0
9. fit,- d. J
nljf.4~"#jI .4 111111W'
loom. If In
It 4rAnCong fri-on vril.sw m,14sk
I ran.fitortnat bin intii quilumd ac v nil m two Iv, I,N 11.18;141.01
a ..III it, Nihon I,, N If$,-
Ia. I,V 1111-1114o1, it 14101.1111,11"1 III'l 111. -6-1 i-lm
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00 v-mit,l- 4 tvl~ I
vita the anou)-funclivot III the N attim no
O
ff t*,,ittlialiwvli,,fitwi~'l.~l%,,(I"IllI J..ndifill
,
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p4ralf.1 Sul. On." *$*#*qsS 1, 1 he j"fl.edg.
Uf the second gulls grump on the C44ar j)l nII1vbq"jyj4rjI
entlaws V. A. Isinad'Ad a..1 V 1 00
00 J. Cre. CG~. , it'. S. "'. R 1 0. I'll: 111 a
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00 MIAt Itill-fis.11-1 of 4 %,-1
11 %1.. %IC41 fit its, p~I-Owti 1'. NII I.-Itins
' .00
00 4
. It -4ku%lt ils~ it rill, -NIK"If. kAulill. *1111 4-1114141.
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NI I Ac a tut M e gmi I-% int fwfaw-l its t h~ a tid I.- t -00
j I% --p6at"I bv the lihrll,Mlvl%A of
hr fAlowilI4 2,4 dffi%. Ali- Ili, 1.1 I's fh, -io so
if .0 '.4 SO, h- AtO k"lyf ( tie,
dinititAwnstl4whor (11). nshh-h
diftisitte IUD and MIN11f; .00
foluidine defiv. (IV). Inight oranSr, sit. %W hors, fit strul
00 a tiv~"iIiii,fine; p-tolukhror ql~iv. IV). ruti, nt. 1111~. 3-
0
,
tic,t.iiiiin-undsw dirtiv. IVIW. daik r-1, sit 1.1s, , .1
"'M11111"r dettv (VIII. fl~l in hitito -sl~Av, 111 00
00
-
00
W V 1.11-h-111MI,
IilAn villict 11 lyrll.)* Is"1111
w I IV .010
o t 40
0 0 1 rff-~ I t4p-NIIAr Ir V11 itiftingir-yriftest, I ii tutrilw% Ivilk
r wrok. V1 e%ill, as a "How, extrvrnrty tin%tal-Ir 1-ni and
as a dAck r.1 stable fiwits. The markrd is,~,rvittilstion (if 0
00 "whir oblaltint fly inirtwhirtkien ota'.*M atisto gromils NIIAt I
fit the
00 &too.
00
it
*
it a It a
a
4n1
It 0 It
1
0 411 0 so 0 0 It
0 t a 4 0 0 GO 0
9
0 0 0 0 0 0 a 0 0 49P w 9
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t 8 it it 11 is n 1) 4 11 a, it U v W 1. 14 11 -0 of 41
to 4
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.__A -
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I
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to 0 111CCIMS .-M ..' 1,
At T_
Alloyisdoo. V11. keparation of diethylinetAndic si:4
'
l -gig
and o
iethyl-m-ansiolophirtioll. N . A. Iiinail
,lid and It- Is
-
l .011111
P,4.yv. J. Applied Chew. (T7, S. S. R.) 12.
,~il K
i.111
pro 114-h.7XI)IMM); 4-1. C. .1. 33, NK;l Out. fil'.1 0
-00
iii,taivilic acid was alkylatord osidi 4mm moll HCI tool .00
skiriiii too" the I(trinalkni tof iii,modfroo, I tit 101%x ,I
00 Sio(M t4z"',~ soul _9411,
1.57 mols. of cislclurtl Q)Lt& at a uttili. ut)t iijur, thkn
' .00
in the auloulavor, with is yovId cof to,
, 5% ithtsay). Vnikt
00 if the game conditions Not losing 35~~ aq. N.11111, the vichl -00
60 Was lkll, The No ull it( ollotthYliFitiallibi! aVid is -I. O1
see
ale. which is stAlvantagraus for the ptirifical ~,n nol the
00
iprt;luct (d reacticin froon mmetal -1t%. tr%;~,%-ially irme ill-
go -41y. of mincrall soils in No% alt . r,mmdtfably chun-AvA
' '00
in the poicarsocit of No
the fusittil ,I
A 6
00 the aq. paste of No diethylint,fasid-olor (I jojc4. i with
,isills, of NaOlf at '70 M' yoovkhd 711.7 v 10""tY) '4
;T
dirt hyl -W -ambsoplienol (74% when K(j
was used,
ove a Two mcoillificalklas of dirthyl-m-iLminitphrolol titer ob-
iatned. m. M and 74'. rest), Vill. AtIlsyloatiou with
-
ethyl chloride in the Prounce of calcitan oxide and a
--W7
to n
toosiuroo oxide, Itivid. 780-O.-Fthylaitun of metautlo,
2
eid was carried out in ale. mediurn Inot Iris than Not-
" &k.) in the Presence of C&O RMI Mll) at 125
ibis case the unit yield was obtained with ricily.914" r%ct
j
1 of EACI. The liberation of the product without dimll. jfl
1 if:cak. was not po"Ible becouse metathetic deciouipti. with
so" or NovSO. ptucretted in sit,. %An. emrcrnorly r4cowIv
timn on prolonged licating. It is extAtiouled by the coin-
'00
PkIL I"wass i(M of CAU, with EtOlt. A. A, Pollitinny
A11111.11L 611TALLUNGNIC&L LITIOiTt*g CLASSWICITIC11111 K IF-
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11 11511-1 Pf ~i diff-1- L I-
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L"I it m a a lot, bud..
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A 00
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rmd. Amd. kki.
ISMAUAILI (COMJ?!-
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300
000 W. I t
W. R. A.
=00
See
sale
ILA
to _49TAL&MMAL LITERA1641 CLASIMPICATOW
0 u a AV go is
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0 0 0 9 0 9 0 0 0 0 9 0 0 0 0 0 at 01,1~
! E ; 1; ; I I, 1 .11 If 1
Aoir 2r!
Ausismid! ask=& SL OWedfiesilim of ampoland ebma
phob adeiiiii seeftkim dodpaMW diversOwss od suip-
M. Aftbik of siv"Ouss "N"Oss W" hbruiom
4011141W 01 1,111 somAshmbm
V. A. IssoMADMI; 7,77-4,
M, 014. six sloi-AL naithmi W UA-1 4-4
the stlarmtwo between tbv auxmcftf ealt ilj~team
11 "KAte"Amt The hwtW re"luses 1,111 COMIN-111ldh -Ith tlln,
1.11ated auxenow system; (b) chrlynbaphorK sylitrius with lillwatit
AlAll,tillilill SVSIL-M% 112 the $&nW "UA.; (t) *101
an Auie"'.id h"onviphoirk syslent Sir
7111tr4l In the
irks 41"pliklk system. fill tonjil, tt. ovettins "Ith it" .. 41,4s-
Kil-ul. In n-lil 111"'Al 1XItito to Ill.
14W P491 of the tM*l S)r*ttM It -MMUR&I W IRW Millik-'1144-1 AD-1
ovallals, kirsoannit, anti firt-tt-Ink lb.114,61.1111WOLk
all.) thrit influencra 4m c,dsvur stv Llfik us#A%l
X11. At* colamr.1 will only h,n 1..
an.) isisualininwo Arr In ohr sam C.11, nui less., 1-ut abill, o%
aviltrills 'who" Knups ritist ill t..) nultirl 6quirat"I by laval'ill
Sroups which intrnupt flie The intensity of Ih,
colour driltnilts cm the " power - of Ow interarting s"temi; (whk h
to a funirviin .1 the - pow~,- no.. and poWls.,ii, .4 the linneq.]
F~Iar group.1 mul on the st"artuto of tho conjulAti,il v%tirm t. lbri.1
th# ftl4lklft-
ati, and.11s. alilioil ),%1 11
.#-*Goo *Do Goo* 00 00-00 0 Fi -0 4t, 4 4 it -
0
4
0 ,
11 a Is of " Q
"
W-1 )1 11 if a lilt 64)4 04 444,111
A- -11~ a -1
0 F~L,
C-OM
09
The tbwy a cotior of orpnic compounds V. A.
1r AWA Vollf,4041,
4, No V. 1*1 .1(194, M. Not %Nt~4 .1 .141,
;to AtWIMUhl 10 Attalysem cd Ow
'-wt state In a Sydolu U.1kstot that ilia Invisum
'AO 6 u-Jet a mwOrtAlect ad 2 Cmups tit Wrositi-als
it%, moulting at u"isn"mm ammornpoww'i b)- #
bltmttic tdtvt. 4m-h a system, k
=
11'"m fru"I %be P-C atoms's lf'"Is the a
1wing Cni4liacd Wits, quint"Ir. 1hum, 11W ifttrmlwlk.~X~
4anstsitnigrmp hitoilir lk-Imnitimo(the Phowbris.tif
go litirtiphritylAunim 101tulurm she hathmismanar eftws an
the rwasill of th~- im-traw in the activity of tinks"I firt-trimmi
n( the N atom in the NHl pmp sumd a# the itwirrese in Lbot
effmi of this stictra tat the state of the system. The %taiv
00 is fit I he individual Sysirms of whk-h the civets mid. Is wits.
j.-A insist he r.mi.Merftl Amr (he analytis 4 balbiwkiumv.,
hytwwhr,. .law climts. W. It. Ifirritt
I'- 4411.1LIA..., 1,1196AStAlf CLAS%VKAVICN
-1
0 tp 11 a a 11
0 ; 0 0 *
0 0 ; 0 41P 0 0 0 0
0 00 0 *1* 09
0"1 4,0.0*
Ir I dvi WO 41
21
UO it I to a
0
-00
00
.00
Soo
900
sib 0
SH
age
ago
ii "so
SIX
OWPO
~A-M-A Ix- AUI-h.. A.Al.
A
A
t"'d -Al AW
IA Q
wilh rtlwr to tal. mvi-sirmil I
'V' Goft. (u t Wilted With 4 NUIV. 40. 4 It. KOH 44011 tb*,C. w0 oltU40" "60
10. VA) 7(lilltj).- 1. wid.4, Mate ills, pio' Uty and dried In a v4vtswu 4slim4slow. 11 -00
3-1 flawx frimi x1c. iind once Is= mt
i
ProprFlirs nt irwils. we InulistAy foe to the -Cu "T kmt'~ =1 pill, *11*4~ it in. Ito-4-61 A)
'if indvkjj .141"1s or groups In jll~ niol. CmIlmig an "'.
-1 tht. 1114A." analyie% CIK-tk~ ~k,11114. of the 160110-Hr")-im 3 am
so Whiih govV111% dikirilititiou itn't quite stable, am wishir &cW alsf,ov bittet. 3 to-4.
a m~~ tmvtl%,Am of the insirri4i in obe wpaixill. I'licy btlitvv
of trats fill- . bj
that the WWI- of Many thctalirulk-ally ac!ivv r WANUCill.ONle ol. 111imial Al 11.
S 1114y lie greatly ailupfified and embark upon if. .= seduced with Ism Alitilli in 10. AwOltlitt 0.11 11 "so
00 4d Anthum's ials cunt&. neither quinulim Pol Widior of a litoduit, tu. n. 6- 1 isee
nuciti. 3-Nitro-1-1ictuAnikkazisole vu Pm m. 311millov. 1W. I =00
k1d by dimaolviiig 25.2 g. ol 3-Wtro-4-eln:.'.h= pds, ol ILt- il'-Arril fol'Iflills 11toCOJU14-24",
cc. wet", swinq W It 20.7 S. .4 Koff po..'def L--.j .
in .400
so (Wtc4) and. while stiniog vul, ouling, =6 I. Ilia. ClfCHCJI tL syntlims4d. TIWO 4k. moo
0 The stirTing was continued 2-3 hts.. Then The mixt. erm ~~Vbllmnr
when Wed Wimmed an linivity to No
brought to a buil 14W a few min. 08 Cooling a JmLlow riditim. 4-(J%-TdYIlv1Iu4ax%kl04*1luk iWv g 31) 0
umngt ffm. product, in. LW-9.3', s*d. The oltro, 4111, Of Slacial l4ortic 4vR Initiled 14 111' Use,
cou;Pd. was reAuctif to the 4mina, comild. (1) with Fit . 40 111111. to 8.7 Imth m. 1-3(1) In 7 cc. :'
filings in AcOll. The yield was 02" W *Mtw nmUn at hilliq at 10- 11; Wits "altitiatmil Jar 2 ir 1W
Ax)-3WA'. Tlw aminc vrmA bitatwwlth Milli for a 294;~ 3-Wtto pd. VMS
I
iWit, *Wine the bertaylidtac drdv.. mi. W71 Oman- 077 Ibis
al. 103. 1 'nil, Ililm 040 1. 1 U
f"DOW avxflu)- rc~ wAx fillusled to Island Virtormlat. Mo.%
Irutd into 100 re, 11#0 wid talitigh NIL011 W" ad6d to 1114101
I wo trmted with %aN(.),. A W% JkW of C.' ummido. smiled, A 98A% Yield al
'I-(3-dkiky6MhWupylamiao)anijok was obtained by in. 1221-3' (from dc.), vitm; rAtistutd. J3,Nk:P"-(P- 111010,
V heating 4.91 g. I mW 3.3 g. Rt.NClfjCHjCff,CI (10% t1ii)-lautfuriamido)AN11" (N 1.) its Iml (cc, 40 sk W t 12*0
Will; 2 cc. aw. &k. 2 his. al 110
C;r -16". a It". at Itd%kxrij for I" hm. VIA R. a. mlv clti)~Ei Z;d :1
I and 10 his, at The product was a thkil g. ignited p;;,,It. The itti,wal Nita ism fibered 11`41111
TALLWKiCAL LITC44TUItt CLA"KA"O's .........
ass 11" %(WOW ------
,low
T"
W* ~AWQ 3
U 49 Wall* Itaft It x 04 10 0 0
is 40o o
41 0 0 0-* 0 1
So
* o 0 : : : : .0 e 4 0 - Llmltl-oo
a 9 ~ 0 IF 9 T f 0
* 0 0 0 0 0 t * a
;ad tbt sk. *44 *Too. lhi.44dw was &VA01vtj In
#[her and the ether MAD. was wasw with NOW. 6. -, It
ond dtkd over NspSO#. The etbrr was tvispd. wod te
Iraklion was rvoysid. frutu ak. Aturv (han 144% 4 3-
W104. luillauMmisatilklo).
=1it'd'
so. 77.6-78', was . 1 (13 g.) all"
istandiq ownigk in 23 cc, 90% HjSOq wiss jKluotird otk V
cc. Jw and was watrallsed with N14011. The W
p0
krostd w" ". Willi CA. dried over N**50. and
'00 filtered. The Cjh was tillers off and the resiclue (9 v I
00
00 vu Iyacliawed in memo. An 10% I-ld ul 0 fvd Oil
f11), bv4 was obtaisord. , 'M not "7
046 at -15% ftspicratth"VOMI. M. 114-15'sad IW7 .
A a *1d of 3-amiso4-(3-dWtbylasninoPrMYkminO)-
IM), ho tO P ("w.). was obtalard by reducin
a with finch in I I fict. III (T.7 $3 VMS gradually MIM
with il C. Acts) and heated on a water both fnr 15 onto.
The reaction milt. Was diwelived in 3D vc. 4 X 11C3 sold
490 .4used I ~3 lies. The traction product wpd. as an oU
when a 4Q% NZOH gain. ims added. The oil Visa slid,
with ether. dried VIM Potash am filtered. The ether
was eV. and the residue Was distd. in twoo. A 98%
00 rield 2-methYI41-methozY-I-(3-dietbYlaminoroPYl)-
br%dMWjoook (IV). bs Im-P (dil;Afttr, sn. 231) .). vim
00 btailwd, X-Nittv4-&ftIamMftftiwk (013 9.) was added
40 during I kr. to a well-asitalrd mill. of No I. Iron Rump,
rM or. 11.0 and 13.5 g. NsCl. The istitatittill Vim Coll-
so joined tar l.fi,_j be,. at 9v. The hot reactions miss. was
filtriv,41 and Vim "t& were twkv waawd With 300 cv. W
boiling IIto. A 00-217v yield of
of
00
0 11
00
00
0 0 0
Ltv so *0 a 0 0 0 0 0 0 0 0 6-0 -0 0-
6 0 4 a 4 4 C 4 e q ft v 4 V_ 4.,
a 0 0 a 6 0 0 0 0 * 0 41 a a 0
0
Uni*4v M. at 1401 41.1, (fee. 1. tlim lh~t_flwd, V I
10.6 0. Ift.NiC1l,)Xl 11114131 m. sita. air. tit ~Pft.F.P.
004"d
Had 1~.teifi 3 Ism at I 10-1&I wild 13 lists, at ljrr_wl~
[tit cxxAed traction tnim. was ditookird im 40 m. 1wit Ifol
land thri. to d. With qthet. and trititod with IM U 4
Potash. The dash list -no's 0111, Wilk 4w 0 pi,
Cv. la.
art tit the (At did Put Ili"KATT 10 C4114- It
In i:~. 'M ak. iolo. *its fiffived med dried. Ilie ok.
was driven off and sw ody p"oajcl# ad. In HO, vins ob-
MaMed. It WAX M PHILI. (A qMLIJVM" alts. Tilt
rit. was washed with 101MILIT Slid. Ci FIgOt dried Met
powh and filtered. '1!6.- C4H, 4r4fi dri"M off slid fill
"due tow tractinamtM in "woo " t1wes, A 1
'!:! of 2-methyl 4-sim 1 holy- I-(' .1,44ki byla-fiml op~~
=IMM&SfAr IVI); It, W40 obtalwd. 41.
pictste. tit. 914, 111 . A mi'toto tot VI (2 4 g.) a
1% 2,3
Poll was heated at 2111' 11.1 41"fal It"'. tbm
NA) and enouall III'$ for a wroiltr ad&- rvwtwa Was,
d. The extras Mill was 411mid. Swith Steams, lbr
hot win. was filttred laid evagid. to &Yftn. The I"WW
was 4U"Wvvd in a stuall amt. of 4k. and Wd.
A yield of 2.5 g. of
andropeopyt)btatinukh1salt-2HO ifibrilroste I ) was
almained.
V (27 .13M. "Al and 111) ;it. 4 N IICI witni re.
fluled 1`10 "It ppid. III thor a" was itherref
aff &ad wu-htd with A Y HO Ijul ditarl"d In "1-15d1
ce. 1110. It Was tottAtiaLsed Willi NII.Oll khtle 711%
of 9-atelhY1,101 -awl hirtybenalno Idulok JYkittm. 141
2.h' JIMI" 1*11. Offlivi. piflute, to. Mh
mist. of 0.1 g. VIU mial T. J:t.N(CHkl C
(T. ale. was it r"I. 5 1%,
bit. at l3is-AttatA I at 11 Ism. $it I Iiii! I *~# 4.
. It Willi ff"fiql vilth 31) ev. 611144%.
rild. with ether and tha aq. LilTr woo Untied with floo
N. n( ffir' 1XI114i The %!pd. 41 inas tvid. with 11101 ev
Coll+ A; C4jlf*WllJM, still t)(111. 'fjib N*Off *1111. slid
dried ow" poinds. Alliet, evalin. tit thet C48o Ow ad w&.i
"d. at 2h mus. fm yield woo 43 6 t. Ill. Info-gril;
Pimple, to. M-M*. Invid A46NIV
0 0 41 * 0 8-41 0 0 0 9 0 0
00
00
00
00
0111111
00
00
00
00
01111
00
00
to
90
*0
00
90
00
00
to
OW
i IN.
0 0 0 0 0 0 0 a 0 0 0 0 a 0 0 to fo 0 4f 4& 0 0 6 6
Igo 41
A -tk-t P
00
1 t!i 7-
MGM* slid IhO 41114ts ol tht W
antammine dirrivirliv". V, A. Itinall'skil -11141 A. N
Kimin, C&OMP6. r"d, Arad Sri, V R. T.*.S, 28 tj -4
'
0
009 (IW) Om(kfam)- d C A.J4,7?4I1A-t-C1jJjZlI
Z'.
nitrated In AcvO with WN'Ch (it. I Ml 41 S 1-:0, giving a
"
thick yellow Oil fnao wbkb the
tm atil't. on". on
9 -tandingI. The tom pd. ran be r"trtd. fKa 41 a1r. is
0: fiensim or Irm efficiently out ad tmenment. At 16'. it m
l
diff"It
y sol. In brtuhm. roin. hitittit in sk. %ml wj,
"I
w4. In limsent, and effirr.
t m. 10M. Its toculnut,if.
is established by oal4atio" with 18,30% 11144[h.
arybanine and its drdint, fimm a "I" tif hinlily mh~a
tornpils. Iwoviding low n1tru group% are In an umym,
".ftion retative to the C111 group and a quinoid coll-
f1curstloo Ir the adi-alito lorm Is wt putaiNt. 'Ili.
,.Uw wurles is clammified an the I"i of the IntrAluiJ. splu
.
1
0
0
I;.; ausirmAdt-,min:
Id
i
thi
h
f
d
6
:0
0
~1 cou
r"em,
s raw T
t14.
n
arL trim o
e conjugate
aruntsiic z uckvs; (Auto) Is the *'d(mor ogrour.. or suxv-
N
e
-"*; Mph) the ekirtrwhilic f1mip NOii and 0 IN
comijutiotion4ioruptims U04P -C IF-- fltq turn dLAIIAt
bonds. The sales (auxa, p. color of crywmit. color a
in
IWI
powder
res
) Is: rf
or
ll
. P.,
p.
~
anoge-yu
ow.
, Mnv.
:
p-Me, red, bright red, 74% m-Me. orange, uturigl, JUS".
-0.14t, red, orange, I&P, m-OMFI
p oraoSr, own n8v, M. V,
p-011. dark red. dark red, 1.10 ; w-011, ftruisn-fr4l.
I"wn4v4, 133.3'. Them are prosluced by brating III#
chloride I hr. at 001 with the cxmitrACkinding atylamint,
Pie prudiartion of color is connecttd with the action 44
%omplex-ImIlding
J
force ancl the apimarstim -it "minIgos
ILA 1111TALLUMORAL U7194U1011
A, tolaw lilt OPIT oil
P 'M
we 7 -_1 4 0 oil it it a a q I
1 0 1 1t, it
U A, '0 is is J a
not
so*
4*0
9o0
140*
Igoe
U
Wool
0
0 4 a 0 111 0 0 0 0
go A
00
00
00 c
** :
4141
60 A
004
god
094
gow
- - V ~l I I I I I ~ : 1 -1 '..
a 010 a Ike,
044-f
a 4110 40 *Is
IN 4 a a
. nit
" mom
vote
. W41$
UOT
PON!" see
goo
5104
We*
a 6 a 6 a MIALLOONSCAL UMATM CLASSIFICATOON
14114010 NO SPOT an
U. IN If 1 10 As 01 14 40 ;41 wrl;j Va.'s a a
0 a 0 0 0 0 Z 0 0 41 0 0 41
6 a a 64066066 0 -A"" All
goo
9 1
ko a
;;4n& Sasso 0 911realdla-44 T
a 0 0 0 0 a a 0 0 0 0 0 0 a 0 0 41 0 0
All-OAll-OLO 0 6 & 0 41 6 & & 0 & 6 41 0 46
. !: .I h: 1. hr. -i t I i. I i! A ! it I A , I I I i
; M ~'- IM", . a 'j, 41
-h a (1 41 a s 4, a It, 4, fi. tA
AM
is 17 1 [a 1 11a
74.)- ri P, RA k Fri
io~
1 0 L N-J-2 _.'i -,I- U_ VII X-1-1-A.-Ak
004 J11 14.
dip mxllk"I #00 "04"N - ------ '-00
if Swisarateddolaor-cuoidrytriense, XVLI. Cakrotalim-
l; bmzoyi and altrobtaxyl derivatives of 5 -00
0 4& ii these and 2-andoaftworeas. V. A. luna-Wakil. J. coo. *0
Ckew. (u S. R.) 13, #A5, Wfl" ~j Iftwisple summary);
4366-To desiVate the mmpki of cltctron lee
-kxwr W clur bxv 1. p"Towt this tam "(14mor-
enuo,-system.' Ztend of the pftvioudy u.sed "auzo.-
00 ." The culocatkm of Vfi=tftv;a coo*d*. (C. A.
V. 41 10S) is due PWy to the direct in uUtiou of 2 indl-
004 'idal yt." d..-.,ow And mitro-enow, *1 the
0091 compils. in "don. ZYM.
amiHne &ad Ift derintives. V. A. lmng'&kff &W Z. M.
Balramov. Ibid. cAlffi& (ftom 200
00 -stwi-. .1 Pbc M. 49'. was reacted with
00 1 molq. of PhNIII, at M40* for 6-10hm; tim mist. was no*
trtated with 570 IfCl, wasibed wkb NagM wk. and coo
*loa water anif cryst4. from EtOH to yitM COMIC16- I g
V ClIeNtIPA, in. 69" (from 910111), a yelcom in. 91' Ordill Fill lell'irtJ 'did
#0 40K The goit
R(Off-inwA. reslilue Yielded (P-0,.0cicZfJ*Npk' BlAing ou lotroylatul" itnit r'(1:1),lation. denp red WIWI&. 000
so m. 171 fr ow ticrimm), a yellow solid. W empd. which do not give s"WIcte"T *Ila-
d
4r ritki, the carre-i xuhng: N-formy( COMPAj, Sl ' tpi.
11' (from ACCIII). a =lb-mAtiludg; fr_~Tw!:n), n,t
withme, lico,1111, M. ", It,
J: N-A, 11.n A~A), m. 01' ifn~ F:jjjh&oce osedtk4l bIRWIMU
Eta"). fultitly in. 177' ( . I
yrlkm*4HJ p-*SIWqAMl" d4wids all-I NI,,, -M the cormponlin
P-aniddiisc a( 135 40' for 10 It". rive N-(#4dro 's&ptWl,,t. ru. fir" (ftain 111611). M-V
04" wad
not
tribe
I a - I L A IWT"L~AL LITVXAT%dl CtAlUPICAT" IM
8 slow 11"VIAM
"at C.T 44
oil
so all or, a*& tendill 11911
u x AT PC S11;
0 * to* 0 0 * a 0 * 9 0 0 0
14. 11
alla 066060066 seelolblit 00 0 41 P a 0000 as 4160 a 0 1111 a AL III
~ 11 , : ! : A 1 1 'of 1 !1' , 1
j~ d' 0 '6. 41'. K
I
U 0 4 41 a 4, " -o", 0 t T I -s' - Tv
0 0
0
#
it u TV if
it if ii m if a .1 1? m 1P 0
u t
i'4 oal;(04
00
0 f d donor v"d SYW-8- XXI- Color adectis
Sristili
thislinkidOPTOPYI) Kild
in %-i3-jsb
.00
: 01 livolissitit smints. A. jklol~vrtov as,.
derivaliv" ",l. J. (,,efs. t,Awm. S S.R.) 14. 210-ja TH"ll Uvtf It Al'Allp. XXII, C014r,ello", in 3
LS-4
V
A .00
0 ,
,
lighth surninayl; Cl. C., 39. 701'.-Whern I~ phthallmidopropyl Othe's Of litellola A. Y
j'1944)(F -00
00 if -
phthaliblikic and CK110113c in 1 4 "Pa. ratioam I'V1111410il /bid- =01-4 --%%~ seats.
* is heated with
his. at 1.10) 'W", 051-Y irivr.tsup'- S, ('s-chlotopeopyll. WIN
'
t Ose t
t
%II
C
Il
1w
i .00
A i vi
i
ype
'
'
1 g
"\ 1,1131"'W411.11
111., esher v,
philsalimide (1). tit. bU'll.." Ph
Inn" k;toki meps. which R - If tie. ipl.j 2, s,,,l ~, %Vh
h ffActkxw cerstm
hi
k .00
.
-
-
c
milt. (gain W
all" ("le' the volifflem tlhr ql~ tit
I't-, 4i~
ellow M
iline
I
t
D
'000
.
,
.
an
.
. y
vi-Imiclusit v!
V.j;I-phth&linv~If)prvpy
j" YCW)W, tn. Ok formation '4 1 1. .%'.[,1 -
(3 -Phthgilinfithilt(OPY 1) aft !lnse.
k
me*
l"mi( ii,id, in.
-AmiLar reiixtions give V.(j.pjj*aIimrid4w+ f
MA-g"31
and by losto thilo" * ill, Me , I~tfjlj. -1 he C-Ax I'-
M
6i
llow
th
490i
.
,
'
e
er m
.
YE
0,
a"'I whish A .
4
8
1
71
27
lm 4
.3 S -
.
.
1
.
in.
Ke. ul. 1
;
.8 4.1 111. still ON by-ttrothi~ I
range. M. 116
roe
so.
pok IW-0-6' (dexximpts.), is 4.1u, f4irsiscif tl,l give,
and N.N-W, 3- ?1 a Wills
E
11 .00
10
. Hydroly,is of n Kivi's lilt ether it) which R
its. ljoi.8 7_5 rail fit. P,. ci4,1. Ali IICI Wit of
yvM.w 09
Is
*0 ,
jhe,,ecornpd..Vurc-,Imk-- '~ililvt he vo;or cannot be fill,- Nits (M), offinge. It,. %I".. j 4 p. W6:11 j, .
'
h
(IV
h
i
), t
e orangt-rdby" ether tn
. IrAct, ji,F.1io. Tho:j jh~
to u,teraclion of the electron dLqtk group A and t
sev
log eptor It "in, a valur'4ted Chain. It instill bw Pbmljl etherrif hire It!" fimir tlinn thf cjjlTv4.wauIijj,[
&V T: 0
IrnAl firld.. giving a form 14 tkfi"- of aromatic iumijmc~. 3111, t-timt a
due to ij1tcraCti,,,gL 4 the cat, (the diphtW- the Slit &M X3.1c
,
rou
o1
r
A
o
pi 1
c
, g
4 lij
IV
rotisplea resonance. The 11cc-
ilij, either to btanching of the chain- a derlser color than tiu~ if 111
f,in. the reverie j, ly
i
&
,
n, v 2
s
s.
inside conlis
Of to sleltk- J"' w"I state-
tmall fitlils
l
h
0
e vi
,
n ti
t
with smaller intrractio
ersion 44 their
di
t
d
0
o
in,
v
tned 40tinnalitit, 14 the A groups
kA 1 40. - L A _MJ__T_A L _U9 GiCA L Us I 10 A I &A-[- C-1. -A I
1110.
0
'00
wee
moo
AM 91_~_ 1-061 1 t1fC43 It Ov 04V lib am .0 111
- - 10 7
U S AV 10 IS `F__-F_-TTLA aj A 1 0 fW 4 n-____.-
ol 00 11 11 11 4 9 st 000o 00 0
0 00 0
0 0 0 0 * -0 _& 0 0 0 * 0 a 0 0 0 eve 0 0 0 0 0 0 0 9 q * a 4 0 0 0 * is
41 IF 0 a 0 oqi ; q .g q, 00!#
10 * 41
a
VLr~ OR a 1.0 IT - 91 IV v v 11 is Ir a OF a 4" 11 a is 41jr*
A A I U_ I;
F I., APIA
00 .1 Poi inarthaw am"U"S. 1. 04,
00 elk_ of ill of'safteo lawr. Ft-d cvvi'lall-havi 140111,
A tuty* plianytizathavat andPWT!vdGg4=
00 a %d,
Itad the clamar gri ki. V. A. I'll -t
ina. 'J-*&
Irmail'Ail 11 K Rukov and M. A. %'vhW . - (IN) jullogio CII.IIII Cc lespil.l. M. IXI*,
00 (he". (1, 3. AL P411. vAlivir lKIOlI
14-471104:1) 1 English muninutry) W.Wwo -MI.Ifyltal. Willi-It 11tt-11 POPS 4 .7
*0 111 iyalef.jq Iflill K I K PAN (Fillot is ilmintig arlup.soill)
t1ph - 'Ift-Invul,hilt groul" K - comijugated lead vionvLame, oil, IN16 (flown 10010 Otall Illoo 4mastak*4
I
00 'wOrill. blvale"t group kiii,,alikild the tiorquev"I toAl.trity'le). ItA 11"dirt "hiell do-posit hasil 14do WWI a j.00
Q - Moll &%I
.Y.Acm) = loferatitmi of smular nitro-ortiold and t~,lltvwr.
go lin' (from 1""(4, 0
ilommi -mmlil oy0eves III* cullors, are jjA%ULr. Tile appew. tn 94
go sruv 4 oolot dn" w-C dpewl on pr.f,m Inirallon with n cow 41 &a illaiwatlir"I .1
I-41tialinti of a quilloarlid at#-IlItTo struclurv an shown by hAVISS lit* flit" 11114 two 441014 410L.: Is
0 e the intense inks cil innisix. if the tvtw different modill. V. A 14-stal 'Ail aftl D. K 11artow .00
thew t-outtmill. al.. heim all MU-j'able thool 14011 Mi. The volon 11-wiontioll in Itilhialse Oftle oleo
colurls~% form. The color in aplarrully prt%hKvd by lilmnylulethallf) drflvs, I. ~1111.31&ooml on 4 1,4161a stulumor 1.
Interaction of the external Wile of the complex chrovio. that cit dl- and ttiplienyinn-Onaiie conall4s. (we above. noto
so Owner groups. as oho" by compartiman vil' com III. otints. Part 1). 11h.-
00 a NOT and Nit, cor NRo groups In the Lame of chircrent finito COII and I'bNM*&.IICI lit Ak)110. on. III)* (f
in uAteunjugsictill priLitions: the kudeprindoit iuletaelkvl ortir,H0111. morIntim IrIlril WfOll, II-Al
froon 111WOll and IliN11011:11 is go 40
00, 1 1 A.W.
;11 the external firkh; may havv a greater effert than bass PAO'NIFIX101honlif ' : glo
00 4 orels I h the r vonamv theories. in. L'if; ',I?* front lblir). piti-IkA
djoin='d prepil. by coodensialion of mirdlicomr, m, INA' (Itons fortimstne-EtOH) UIKN" M111110tiS41- 6*0
P-(hNC4Jl.CI1i11_-Itb FbNMep in AcUlf, yellow anial. ttion and treatment With KI; losk yvllow rietAlen. P- 41
in 110' (from FtOlf). 189' Uttart Pytidine). Mel. It-Ro,"st Innowt)1"Isi al. 1247-til". In"
NCJI.CII.NIICJIAMt-P. bested with ft"Isindtliv.. llussotiomil P41, C.1011h. irtilid With tInincese In tiom,
pgoomme ~) NaUA.; light lmonwio cryfloak. w-NoIrfer'. 141411111
almoot rolorlesm; posle yellow cry-tab. The "vv pliallyfam"Bow. from sm-C)INU :110 mi liffstawits Is Ow
yArkled on treatment with p-ONC&I1jCCW1 in benzene, presence tie 1110h, collarless ef 1144jaw fn. $QP (fritats, stso a**
I P - (P - - Is' - dniarl** winadipAwayfareek- or HtUlf) .ida w4owmeriP4 be- '1- (9) an
wel"A. [I I. C& I. I. as a
mar. in. 177" itrom RtOll). deep-red crystab. jl.(w_ tsimetuslatt r
Nufabelud was) domerlhida (no ad. Ol-Nitr
gives%) "am sl&AUWujv and isolatell in bilsome to the premen of 1" 14). M. ill, P-00ma
I a I L mAtAktuitiorAl. kItIImAILA1 ktAtIOICAMS was
too
31~1 '11 dowt cow I.I.
:L I L~z
0 U n AT No st st I TV I *Al 1440141 lie to Al a AA
is IT to to It K it or Is TV
0 0 0 ~ g 0 0 Wo o o 0 0 0 o 0 0 0 Ill 0 la 0 0o to i
0 0 O_W_t qL9_AiS_"_q 41 0 0 10. 0 0 0 0
V 01
b a
42
0
0
It
0
6
0 3
l
9
t
e
C
q!
4~
41
6 ,
00 taidaw
n&9 bed-
cut (0) an bramissatlaft 44 41"t. a4ew -
go -1 0 404mmum). p-Novkmao
w
lth
of
99 0040. Tt
-"A-
h l
l r1
W ,
a
wmitmi"I
&
t AK:A
w
t
m~ Phanibm a
s madw Pad "mili.
00 tims. adtbw a tri- hat t*U*pk4"yl dwiv. Could in 66,
Istacl. I bmftd with I%NMtd la AcM IPTS 110118c.-
so
*
ywi?Aw crymak of0
IWO* (=O'ALU) M4'0"
A-
MNJNO*
M
r
:
90 .
r
). -
.
1;
, of
PbUl I ia the pnmwv W AcOH and 11-k. ga"~ shmug
cmimak" Store. M. lm .01,
h
=
=:
um
wt
(
. w h lums yeNpw In the prvwmv at
&IWI. . heated wfth PhNils.11CI in A4
VH
.
a. 117-211, 11=1.
lituli). as yvww-gfm gmku; "smif, M. IvWW.
00
so
00 0
0
00 00
60 6
00 0:
00 00
* 0 00
so 00
09
so
00 00
00
0014110404,4111 91 OP (1, 0 0 1 .11 a to It
0 Ls 0 @aft a 0 41 11 4 0 (1, it v a (b
4 # 6 4 ~ - - b 1. 4 . -
s JE A L_A_ a r Alk A,Mt_m_fP. _11- C-1-01; 4
00 A
90 Camoct V1. V. A.
ksis* S,S S R 42 2 It
compl. ft". aced. J6. 412
iti-15 1944)
~
0
lingl6b)-stahk sq. disperwous of rampbw (1). ajl~.
Wj
00 bw edministrol" is call1swali 141WI. Want
6
06 g mabinations of sk. and Na salicylut
prrpd. =um
-
lu) to in 1. St" s4. dipm
slow of I wnv not
00 n b= Itt sk. at U alone. by iwreasing
rlal
g
, -
l
be .
6.I or 10; 1 to 90., 1, the Ir. I mW,
goal' frqubvd for itably dbipaiiing I wu
00 i
t
O
f b
w ng ac
to
w o
ut
the Na ORA of
....5c
00
4 .
.
plalisubma
d"?
f t
ll
k
A A o
-eamphortai
, iAn
on
campbmwboxylic st-id and with 14MWOM (It"its. of 04
A W tyPe CollmORCOOll and CoHisOCOKC0014, lwtpd.
front phthalk and saminke "is. W. Pmv
ILA &914LLU 44KAL tITFPA IWC CL AlUTK 4TPCW
L L"i q..444
14
as Run IINWO I,"
10 0 9000000 00 0 111 0 0 0 00 0 0 0 0 0 111 0 0 0 10 0 0 0 041 0 a
0 0,0 0 0-0, 9 0 * 0 0 0 111 St 0.
0 0 0 00 0 0 06 0
-00
'Ve
-00
_*G
400
40& 0
*60
at*
$00
too
T -, V
"-op. ronar '-n -,--ate-d
I, -.cf- and Colou-it, of thc- 011:
S-.,~teT-~s hounCi by the 1,cnor by V. A T~~Njn j.1 ~,J-jf r
El c,ticv
SC : J( ixrnl of 'if nernil C*,iu- (,',hurriol Cb: ':- l.f i Lhir iJ i1~146, 1~:, 1,;'c. 10
1?7'lr,rc).,.::. cc r:ri(. ("O'! ol' r~n- I, n: lie r-
I Cl rJ t.,/ ot~ tho- '1%, 1
n i r: the Pos.J ~J.- n and ence cf a rcr Sys', cm.
Sil--cm~v r. r. e, V A.
SO J i rnd of Gr-rc-r 1 Ij r r
N
4
Y1
1)
12
-A-rl C 0 1 p c A
A
A
I- Coto,.,
00
f [l
t b
t
Ab
I
d
li
c
t
t
.4u.
AS
on o
sorist
y mo
ow a
CY&C
y".
o
00
-
I" WUWMdG bd- 111111LOW" Of Pyri4im galls And 10,0101); the lause in HtOll, ".1.11town, 4M. .j~ I
00 and P. A. colodkov. P4.
M7-MI%8).4M the
60 o"A26): MiNif + III (ruby-rtif after rrtryvm. him
1)
Pb
)) of
.
00
ifW
the color is# a
iven C111
115ifiCAtions
I
f th
Wi ,-
&=y[ sk.), HtOll. red-brown. foNl. I.tla (o.
0
;
Nil + 11 (twown-red), v,j)Ij. brogn.glA
4M.
00
UI
,
1l O
e PtrV
.
00
Y g
00 ),1 '-dialkylp-ru,14 wyan Ing salt is detd. by tllc jottswion (0.0751); Ph,N.%It + I (light yttlow), ICjICj,,, orstip-
'M
+ I i dark
IrJ Mflai
440
O
It
0
between the quincilmic clecttophilic constionent (the Imon-
` avi
.
.
o ,
;
,
deep reii-In-own
- 41*)~ broad band
Mwn-red)
ClICI. -0
0 lum chlorophor C:N9 and the clectrodisnor (sanine
0
1 ,
,
.
illow-hrovin
Af
INIM
N
%f
+ 1
CHCh
CJI
m
I I By anal-ia. u". corujids. invol
9 sitn;-
v t
.
.
e,
,
,
, r
M
: p
44d
7vilow
30 MOM; Fb%*Me, + 1
CHO,
435
1
1
(x WIN .
jj~ lar lertMbilic and rk"rationor rwps, but ,
.
.
,
,
,
(1
h
If
00 by C111 or a Umilar linstip Q. should abotaits III very much
j 14
e
t
1.15 (O.MM), At irmens, 00-0,
a ii U same way as the Cyanines. 71$e following ate ex'
Re compkars dissoc., obsotptlon NIN rapidly,and h- enov"
-
-
l
4
l
h
1h
o0
1-
"MC coulpills. with I-InethylIquir"ine 0-
-
-
1
h o. at
s.
r
sir mt
. oximp
towards shorter wavi
trilt
t
I-ethylquinciline Wide IIJ), and
e (1)
=,,
.
.
,W
0 i I s. dre
Ift(J. Ansfolpius colutrif mmipi
ly
dz -
vi
L
,
1 bensylifulnoline chloride (111); the comIxIs. with I ere
' .1
pyricline "Its. e.g.. II.Motblipyridint ps.
o
l
iIttit yellow; IV +
toluenesullonate (IV) + PhMolpv
gidig the dry substances, comptis. with It
lf~ on ,
intensely yellow; IV +
Pbo:.H
and III only an wetting with the solvent. The data refer
,
to OtAns about 4) W-0.08 M. and give, in that 01 kr:
11 .
brown-yelloria: IV + p-34vC.11. N 111, lemon - yellow. With
h
idi
d
f
h
l
o 0
00
of
V"t
colix
gid
t
te)
A
d
l
I
l:
( t
o
rse an
11-oap
phriinim (hydroquinont. I - asti
1. pyr
n si
s
v
Co
or
a
.
. W
the mo
com;s
,
). 191.-
ad"., A in Inp. toc I.// (cown. in mole/liter It"llsir Wts give yellow 1W.Aticts of valkwo shades.
1 colnes of the nail. Comptit. caniso# be intop ted
I
l lb
KH + I iyelim-brings). CUCIA, rrd-brown, 612" ajxi :r
~j e defarinstiom or vstn der WLLtIo (crm but am
by d 0*
Instant" of a particular type III compirt rtnorussacT (I.,
C.A. 34. 714,411; 1. and PLcI-4tvtt-. C.A. 36, 43'P--).
71se coW phratimeass of the smil. campilt. dromixtil am
Ito doubt related to the cislot of mic-rocittfistainirl c"nisits.
N
Th
i
h
d :t*0
retie.
n
.
m
and qu
y
t A 611ALLUJISKAL LFINJAIL41 CLAIJOKATON
o
low SU.411T.
U 10 111
DIRIPS Ka PIK man _711"Ir-An -A,
to o
r" 1) If 1 Ar as 0
0 0 0 0 o 0 o o 0 0 0 0 0 .014
I
USSR/Chemistry - Benzene, KLeotrm
Forw2as of
Chemistry - Naphtbaline,
Apr IJ*5
Me Principle of Alternation of Spin and7r -~Xlectrcn
Formulas; Benzene, Napbthaline, Oxyg9n and Otliar ne-
amples," V. A. Itmillskiy, Y"cov State Podagogical
Inst imeni V. P. Potemkin, 4 pp
wDok Ak Kauk SSSR- Vol LX, No 3
Discusses principles of alternation of ispin and
applies theories to molecules of vaxious chemical
compounds. Submitted by Aced A. Ye. 'Poray-Ka4bits
26 Feb 1948.
F 7, 7 Fri I i VI F! I II I I I I1111 PI
lialtmoletulm Intstsittkas and coltm. Abdorlitlos sw.
tm of molocut" 400POW& W Ightwimilum nadto with
arwutw mints. V. A. Isnusil'skil and P. A. Sik%lli-
tv. 11, Potmukut Pedstil. Inst.. Alkwiml, P-Alj.
'411~04'.Vdo 2%.S'S.R. 73, "1-* 19,10J.-Substa"Mi with i-
lated chruniopborris may dcvtk)p color under suilAllif mdl-
tions(C-4.0.4070); this MAY OCVW even in imtMial. Mn-
plexes. Spectm of 24p-diawtbykminost"TI*inW4m (1)
and 1-toyl-2-styrylquinotinium lodide (H) weve itianid,
At 10-1 M the substances show absorption max. at MI aml
3M miga. map with s 3T RX) and 24,TW. rrw. An qtti-
niolar mist, 4 1 and 11 it 10- M JIM MAN. at M! mm
(39,300). and at 10-0 M max. at 3W ins J24A)tb. A 4:1
MiXt. At 10-S M gifts 9 011114, it WS mp (33.M)) wbile :&
1.4 mitt. at 10-4 M gives a mal. at W6 ins N1,00,
I tthlOdidl, in MfOll gives at 10 -4 M & MAN. At IUS MO
(64.0tx)). in HgO it IN 491 in$ (V SIM wbal M rquilliam
Mitt. witit I in U0011 gives lit 15-4 11 a istax. at =1 mo
(73.8W). The curves Rm reptoduced. It Is ;xAmed rm,
that a comlapted C-boad brWgc is not an itiminsiml mndi-
tion for colur dowelopment. The Ability to (am rdoml
complexes is groutelt in 1. md immaller to fillipic-r moll
such Am PbNM% and Pb.%*Il. Tht saint genetal latremi
mWily talor lit such syments as aft operative In uniAl dec.
iroplidii4lectmodonor syst"m to cmjupted chrotnWhcum,
I- td tb&t a new ty
t &I Kj"tf ~" of tlectronic liml. namt,4
ezo-boad, may exist. which diffets, from the r-tkwid ter ob.
genct of psFring r-bon . G. M. KP*4.ls~~
.scv?m it
goxgtion jg~&Jjp nf molecular comp',exem of aromatic
-- win quinolinium salli. Absnptlon npectra of
m 1.1lar C'Itnp(ex of 4-(p~djmcthylgimlno-;tvty ~quinolinu
a)... V-Y f with I-ethyl-2-styrylquinolinfura Iodide. V. 'A.
'k-d I- o
and 11. A. Mtodkg W. 1'. Potemkin 11 jjr2- jq~t'. %jW;.
Crarl. Vokiddy .4kad.-Xiii'k N.S.S.R. 01.
cf. C.A.43,407i;
P1-14~ dimethylarninostyryl)quinollne with 2-styryl-l-ethylquino.
linfunt Iodide has abs. max. 505 inis (e 43,300). Milk (lie
corresponding inju styryl compti. of firmicyanine t)Tc (2-(t~
dimethylaminostyryl)-l-ethylflijlntilitiiiisti ifolitle, m. .240 )
the compl" has an nhi. triax. 525 in,, (64.000). Thit ctmi-
firms the carlicr suggestion that an exotiml. c,vmplex can
form,! chrnmoplinfe systein who%o opile.al rff"t.4 orr rime
to 1h c of a corresponding coiijugafcd mA. system. -The
mol. omplex of 4.tp-dinitthyliiiniiiontyryi)quinoline (111)
with 9 -c thy I-2-st yryltlitinol inium inififle at 1! 1 corilm. han
at". #Iax. 4M. trip, whirh a Ttvi Nvith that of III, %vith er*n-
plete dissocn. of the compf, %, at ronen. lit NlrOlj of 10-41
mole/I.; at t0-1 conen. abs. max. Is WO mis (o WOO
showing the complex formation and a hathachromic shift.
Further increase of catien. does not affect the abi. max.
P ition but increases the intensity to 30.8W at 10-0 conen.
-1 bus the shift of the dimethylambio-dytyl group (rant ortho
to para position gave a bathoclitomic effect of 25 rup, with a
drop In #_ from 43,31Y) to 30,~M. Thi.i r, tv.4pandi, to the
phenomena found lit hrrifleyaninvi with it yr I 11roups. The
corn lex of III with I-ethylquinnfliflurn indije I oes lint 101111,
lit 19-1 conen.. anti even at 10-0 concit. only a mimite mint.
of complexing occurl. G. M. Koqol.1g1r~-jt`
Zadania 1 Cw~lczenia Z Chemii Organimne, (Assignments and Exorcises of Organic
Chemistry., by) (V. A. %maillskiy) (A. Simonov) (and) (Ye. Smirnov) Warszawa, Parmtwowe
Wydawnictwo Naukowe, 1954.
460 P. Illus., Tables.
Bibliography: P. (463)
Translated From The Russian: Uprazhneniya Po Kursu Organicbeskoy Khimii.
SO: N/5
614-12
.19
r 1
F
MUILISKIT, V.A., professor, saslushannyy dayatel' nrwki.
Basic manual for chemical technology (*General chtmical tochnology.1
S.I.VollfkOTiCh, A.P.Igorov, D.A. Zpaht*in. Revieved by V.A. Iz-
mail'skii.) Khim.v shkole 9 n0-5:69-70 S-0 154. (HIM 7:9)
(Chemistry, Technical) (Vollfkovich, Semen louakovLch)
(Zgoroy, A.P.) (1pahtsin. David Arkadlevich)
IZKAILISKIY.Y.A.; SMIRNOV,Ye.A.
Isolated chromophoric systems. Part 29. Compnrnt:tve spectroscopic
studies of 4-nitrobenzylidene and 4-nitrobansyl dorivntives of
Aromatic amines. Zhur.ob.khlm.25 no.7:1400-1412 Jl'55- '
O(W 8: 12)
1. Mosko-rakiy gorodskoy pedagogicheBkiy institut imeM V.P.Potemkins.
i Moskovskiy neftyannoy institut imeni I.M.Gubk-ina.
(Amines-Spect,m)
ILPSHTBYN, D.A., prof.; IZRAILISEITp V.A., prof.; RUAIINIT, YoP.., dote.;
BAIMSVITOV, A:,-V,, dote.; 8MMOVA, M#Io, tekhn, red.
[Programs of pedagogical institutes; olemouto or chomical tech-
nology for natural aoienoo-faculties of pedagogd(w.l imotituteel
Programmy podagogicheakikh Inotitutov- ounovy khtsdohnoltol takh-
nologii dlia fakulltetov estestvosmniia pedagogicheuldkh inoti-
totov. Moskva, Goo. uchebno-podagog. izd-To X-va proo;7. RSFSR,
1956. 12 p. (Mink litq)
1. Russia (1917- R.S.F.S.R.) Glavnoye upravlenlye vysshikh I
arednikh podagogicheakikh uchebnykh zavedeniyo
(Chemistry, Tochnieal-Study and teaching)
Y
CatcgOrY: USSB Phydical Chemistry - ~~)lecj.LLC. Cheirdea.1 1X*Ld. 13-11
Abs Jour: Referat Zhur-Khimiya, No 9, 1957, 29585
Author : izm&iltskiy V. A., Guseva A. N., Soloviyeva Ye. S.
Inst : lot- _g i v e -n-
Title : Exomolecular Interaction and Coloration. VI. Inveotigatjon of Ab-
sorPtiOn Spectra Of Molecular Complexes of 1)3-DimLtro-banzene and
2,4-Dinitro-Stilbene with Dimethylwaino-Stilbene
Orig Pub: Zh. obshch. khimii, 1956, 26, No 6, 1766-1778
Abstract: The following were studied: reflextion spectrum of' 2,4-(nmjtrD_4,_
dimethylamino-stilbene (I)p its absorption spectra (AS) in CH OH,
alcohol, benzene and Pyridine, and the AS of the followl-ng mixturus:
1) 2,4-dinitrostilbene (II) and 4-dimethylamino-stilbene (III),
2) m-dinitro -benzene (IV) and 111, 3) IV and at diffe-
rent concentrations in pyridine, in the visible region. 17he
' 19 -~:_ and AS curves are given. It was fo,,md tbiLt tho., region of
absorption of II + III is Very close to that of I due tO exomole.
cular interaction (W) of electronophilic and e _"
lectron--donor chromo-
Card 1/2 _12-
MIT
ROT
vivv! ev"77ampA
CV
V.A., Vi3hn(.,vjLiy, L.:'.
1 jk iy,
Ab'o 0 rt I. T! I"!-
Ila-rious structur;~a with ci,.romophoric ny t; t e ins hiLve b,-~(.nI
vcoti~;ated. The anilido of the 9-acridi,nic-propionic
tlie n-anisidide of the same acid are Only slt:,htly difl.'cr-
cntiated in the spectrum. With the tr5'roition to
L;~Ilts t'oe colorinE; becomes more intensive. e ethylioli:'--,
oil thc~ CMilide is intensively yellow, but thil ~th, ~iol`ir-
n--.;ii:;ididu is dark rod. The color may becoma violet or b-I.;e
jr, :jLn,!o if the clectron supply is incroasod,
There are 2 graphs and 6 references, 5 of which are "'oviLt
n
'JOV-5-58-9-7/36
AUTHOR: Suvorov, N. 11. , Docent, Candidate of llhysico-Mathematical
ociences, 110MR Academy of 70dagogic&I aciaboagi
TITLEt The Teacher Must Rocoivo a Diplu.,a Corresponding to Ilia Know-
ledge (Uchitell dolzhen poluchat' diplom sootvctstvuyuahchiy
yego znaniyam) I
PERIODICAL: Vestnik vysshey shkoly, 1958, Nr 9, pp 29-32 (USSR)
ABSTRACT: Secondary school teachers of chemistry are trained either by
the chemical faculties of universities, by -the faculties of
biology, chemistry and fundamentals of agriculture of peda-
gogical institutes or by the biology and soil faculties of
universities. The majority of teachers come from the facul-
ties of natural sciences of pedagogical institutes and the
biological-soil faculties of universities. Graduates of these
faculties are, by their basic speciality, biologists, and the
duties of chemistry teachers are imposed on them additionally.
The majority of specialist-chemistc# who have graduated from
the chemical faculties of univeraities) enter the employ of
scientific institutions or the chemical industry, and only a
few become teachers. The author points out that often chemis-
Card 1/3 try teachers of senior classes have only little knowledge of
1)OV_3_q,1-9-7/5j6
.in 7
to v
iploma Correnponding nowledgo
The Teacher Must Receive a D
chemistry and physics. 11o refers to Profossor-Y.A. IZ12ail'-
skiy's report ItOn the Training of Teachers of C~_e,1_11MT3T__at
p-ed-agogical Institutes" which was discussed on March 1953
by a large conference of the Institut teorij i istorii peda-
gogiki Akademij pedagodicheakikh nauk RSFSR (,Institute Of
Theory and History of Pedagogics, jjr;FSR %cademy of PedagogiC-
ved the inadequacy of the train-
al Sciences). The report pro
ing of teachers of chemistry at pedagogical institutes. Yet
it was only now, after 5 years anti subsequent to the Way
plenum of the TsK KPSS, that the Board of the RSFSR Vinistry
of Education adopted a resolution whic'.1i realized both Pro-
SU -res
fessor V.A. lzmaillskiy's ,, tion and that of the Men-
deleyev ' .3ociety. The author quotes the resolution, and
states that the Vinistry should discontinue qualifying per-
sons as teachers of chemistryl who have graduated from the
Card 2/3 biological-soil faculties of universities and faculties of
SOV-3-58-9-7/36
The Teacher Must Receive a Diploma Corresponding to Hie Knowledge
natural sciences of pedagogical institutes.
There is 1 table.
ASSOCIATION; Akademiya pedagogicheskikh nauk RSFSR (RSFSR Academy Of Peda-
gogical Sciences)
Card 3/3
AUTHORS: Izmaillskiy, V. A., Vishnevski-,, L. D. S G 7/2 0 - 12 1 - 1 - 3
TITLE: Absorption Spectra of Molecular k~o.iplexs For:.ied by
meth-.,rla2iinostyryl)-kcridi-ie and 10-Ethyl-9(P-Carbometoxy-
ethyl)-Acridine Iodide (Spektry Doclushcheni~ia :dolellculyarny:~.h
..Ompleksov 9-/P-diLit.-tila.iiinostirily-at~i-idiiirt s 10-eti1-?/P-
karbometoksi-etil/-akridiniyiodiduai)
PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol 121, Nr 1, pp. 111-114
(USSR)
A35TRACT: it is a generally known theorem that for the bathochromic shift
of the coloration an uninterrupted conjugated K-systein has to
exist bet-ween the interactinl; chromophOrOL1411 co:.,.~on~:nto, i.c-
between the electro,,hile (B) and the -_-lectron ei.iittiuj,~ (A)
combonents (an endomolecular conju-ition of the chroiaophorcz,
floptic conjugation", Hef 1). B and A 4or.-n to.gother a i-ener-aliz-
ed n-clectronic system, - the Ko-chrom(-yhore (Ref 3), Compounds
with isolated chromophorous systen"s AK'and BI: may also h,~ve ~.n
intensive coloration; the systens -ire separated by a 1-rour,
-nhich interrupts the conja0ation 2, 14) J.:' stron!; (.~,Iectron
e:'licting AK- :.~nd electronophilic BK r,.,)ute~mq ~!xist. In tie Inat
Car6 1/4 caue the intc-nsive coloration dop,:ndii i)n the con-
AbsorPtion Sp.--ctra of Molecular Formed by
-Acridine -ind 10-Ztliyl-9(P-Carbo-,ietoxyethyl)-Acridiiie Iodide
sibility of a re-etherification (pereellerifikatsiya) 2ust be re-
jected -as well, since 1) t~ie component solutions AK and. 3K were
prep.tred ieparately and were not hQatud before the spectrorcopic
investigation, 2) because both componc-nts are acridine coiallounds
The authors su,-,gest in connection with the aheve ,.,ientioned
facts a fi,:pothesis: accordinc- to it-hich the bathochrci2o,;~s effect
in the case of the concentration increase of 1 'tcridine
(T alb I e 1 :r 1 is connected nit:: the form 0 f a mc'
- 3) at io z . Inc-
.11--r CoLlijlex of the t"-.De (AV + BIC), abovc al.1 for a c-1,.lorc-
form solution. BIC is the 3cridine salt, AKI a , se'do-alt ci the
latter. There are 1 figure, 1 table, anid 13 references, 10 of
which are Soviet.
ASSOCIATION: L:oskovs'ziy gorodskoy pedagogicheskiy inatitut i:;i. V. P.
Potem'cina (moacow Municipal Pedaeogical Inst-ftute imeni V P
Potemkin)
PRhSENTED: March 15, 1938, by B. A. Kazanskiy, 'Aember, Academy of Sciencezi,
Card 3/4 USSR
50)
'/35
AUMORS: Izmaillskiy, V.A., Malygina, A.V.
T ITIE Spectra of the Derivatives of' 1-(Benzene-Azo-)-2-Naoithol Containing
Counter-Polarized Electron-Donor Systems
PERIODICAL: Kilimicheskaya. nauka i promyshlennost', 19159, Vol 4, Ili, 2,
pp 279-280 (USSR)
ABSTRACT: The conclusion was drawn from fhef 1-3_7 thaL thc-. presence of two donor
chromophors in n-position produces a system wlth inoreased electron-
donor properties due 1-n count er-polari zing efrects. 11ilse conclusion
has been verified by studying the effect of' introducl.r4g, CH - and
OCH -groups into several derivatives of 1-(benzene-aio)-2-Lphthol.
it ?s assumed that tile introduction of two O1_H-.,- or 00Fr2H5_9_-0uP* 1"l1
have a still stronger effect.
There is 1 table, 1 graph and 3 Soviet referencea,
4,
5 (3)
AUTHORS: Izinailt iyp_V. A., Limanov, V. Ye. SO7/62--59-8-34/42
TITLE: Synthesis and Reflection Spectra of the Deriva:tivss of
1111trophenyl) -ethyl) -aniline wid N-[(~-(2,4-DJ.n,i-trophonyl)-.otliyll-
aniline
PERIODICj'LL: Izvestiya Akademii naak SSSR. Otdeleniye khimichezdcikh naukv
1959, Nr 81 PP 1500-1504 (USSR)
ABSTRACT: Compounds of the following kind (built according to the pattera
B-K-Q-A-K) were synthesized;
BK Q
-A (1) and
CH.-PH .-NR-C6H
2 CD2 , 2 4
BK Q ZK
0 .6"H~-CH--NR-C H A (II),
2 2 %_2 6 4-
N02 AK
where BK denotes the combined electronophilic chromophoxic
system, B the electronophilic chromophoric component,. K the
conjugated benzene system (A - the chromophoric component acting
a8 an electron donor In the m or p position In relation to the
5(3)
Izmaillskly, V.A., Limanov, V.Ye.
AUT11ORSz
TITLE: Absorption Spectra of Derivatives of
-aniline and N-[P-(2,4-Dinitrophenyl)-eth5,l]..,!inii.iiie
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khi!,,.dchxddkh nauk'
1959t Nr 9p pp 1684-1688 (ussR)
ANTRACT: The absorption spectra of compounds haring: tb,..~ otructure E;iven
below are investigated. The bohavior oT th(,,~;e compounIn and their
chromophoreB in solution is then discu,;svd :)n thlo basis of these
spectra.
BK AK
B-K-Q-A-K (1) 02 N-substituents
on absorDtion sj~ctTa and photost4bility of substituted
2-benzylidene-3-keto-2,3-dihydroiythionaplithokie. Zhur.ob.khim.
33 fio.3039-744 Mr 163. (MIFU 16:3)
1. Laboratoriya krasiteley i problemy tovetnosti pr:k
Moskovskom pedagogicheskom institute imoid V.I. Lendpa i
Rubezhanskiy filial nauchno-issledovatellskogo instituta
poluproduktay I kraoitelay.
(Benzothiophene-Aboorption spectra)
(Substitution (Chemistry))
GLUSHENKOV, V.A.; IZMAILISKIY, V.A.; MCGHKOVSKrf, Yu..,)'Il.
Spectra of the electron donor-acceptor complexes of 4-nitro-
diphenyl alkanes containing a donor group in the other
nucleus. Electron paramagnetic resonance effe,::t. Dold. AN
SSSR 153 no.6:1363-1366 D 163. (MIRA 17:1)
1. Gosudarstvennyy nauchno--issledovatellsk'.y LnsUtut
organicheskikh poluproduktov i krasiteley, Institut khlm-4-
cheskoy fiziki AN SSSR i Mookovskly gosudur:r-tvenniry pect'go-
gichesk:Ly institut im. V.1. Lenina. PrestavIeno aka-demikom
A.N. Tereninym.
IZMAILISKIYP V.A.; FEDOROV, Yu.A.
Effect of substitution of the benzene ring vith a naphthalene ring
in compounds having Individual qhromophoric sysimms. Zhur. VKHO 9
no. 3059-360 164. (MIRA 17:9)
1. Laboratorlya krasitelay i problemy tsvetnosti pri Moskovskom
gosudarstvannom pedagogicheskom institute imeni Lenina.
IZMAILISKIY, V.A.; FEDWM, Yu.A.
Spectrum genetics of the derivatives of benzylidenearilline and
benylidene-l-naphth.vlamine containing 1102- and II'Me2 groups.
Dokl. AN SSSR 158 no.4:900-903 0 164.
ON I I FU, I
1. Laboratoriya khimii krasiteley i problemy ri
Moskovskom gosudarstvennom pedagogichoskom inst, Ute 'I V.1-
Lenina.
lZMAILISKIY, V.A.; MALYGIVA, A.Ir.
Contraplarized systems and spectrum. Part 7., Ef'fecL cf'
additional oloctron-donor group6 In a snc(.xtd ring
., on 0"
spectrum rf p--d-imetiiylaminaa-~oben3tirie. Zhur. ob. ~hllja- 3'
no.31.,3554-3r/61 11 '64 (1111o~ 1'8~1,)
1. Laboratorlya krasiteley I problemy tsvetnostA pri. vs:)Okov-
skom pedagogichoskom ln,;Cttutf~., Imer.1 V.7. Lenl-na i M--gkovakiy
tekstiltnyy institut.
TZMAI-LI-nTT, 7.A.1 FKPOROV, Yu.A.
Spectra of I'tnzy1ideneanilim, jt~,j nnM theIr
khia. 39 no.3:768-7'11 Mr 165.
(salts. Zbwr. rtz.
(MIRA 1817)
1. Moskovskiy pedagogicheskly InAltut. Lment Lenilln.
"ALNC-7
4
I
A.
of
-e du
, c,n
T
-,
,
6 5
26
9
Lt
r o t s of' tllq soactra of k-riz, w~
Dcll~ I .AN 166 no.1.31,'.-I
I. briborriforIya ~,hlmll krwl t,-) 1-y
-ltrac-Auz~ of 4-*,cpht~ne and
lc:9 no.5zinS3-'-,,D8;~ D 16,
I. -1,Lcraturlya k'rlr:li kragit"tiluy i pr,~blc!my
poda go g! in.-, t 1t-,n J :i
stavieno alade-m-1korl M.J. Kaba~.~u,-lkom.
I H 11
HOSTOSBVSKlY, M.A.- IZMAILISKJY, V.A.
v
Absorption spectra of 3-keto-2 '-dihydrothiontphthene and
its substitution d,riva 3. Part 71 Ben?ylldene derivatives
of 5 nitro-3-keto-2,3--dihydrothionaphthene. Zhur. ob.
khim. 35 no.3:520-524 Mr 165. (MIRA 18:4)
MILLIARE31, Ye.Ye.; !~P ~
_ ~.Jll KIY, V~A,
Theory of the orJgJn of the absorption spnctra of 2,4--Tl,'n.4troan-"-InP
and 2.,4-dini trod iphenylamine. Fxperlmontal conflTMIltion of the
presence of quasi aut-onomoun chromphore nysteng. 2hur. ob. khim.
35 no.5;776-.785 Py 165. (MT-RA 18.6)
1. Taboratoriya khImil kraritelsy 4 prn~,Iemv ltsvetrniti pr"
Moskovskom pedagogicheskom institute imeni Lenina.
IIN., N:I H ill
,',I If Ai It I ~ d I - 11 ~ P 11 : I I I !; I !! !::I
25(7) S) V/1 17 - ::19 - --"- 18/ 2 7
A UT 11 OR: Izmalkov, A.A., EnL-,ineer
TITLE: The Punching of Fastening Holes (Problvka krepezh-
nykh otverstiy)
PERIODICAL: Mashinostroitell, 1959, Nr 2
pi) 30-31 M~SR)
,
ABSTRACT: The author describes and praise,, 4is irivvntion; a
special die for punching holes a-.,~cng the rims of
the crown of carbon steel discs of segment steel
saws. Previously, such holes were drilled by dril-
ling machines. The discs were 1.5-1.8 rLri thick,
the holeshad 4-5 mm in diameter. The Arilling of
holes done by the Kirzhach and Minsk 'tool plants
produced irregular holes with burrs. The new die
made of steel 1118, ahen properly thernio-treated,
made up to 30,000 punchin,~s%vith:)ut rej~,;rinding. it
has been in operation for mare 11-Inin one year. The
holes punched by the die were muoli more exact aiid
cleaner than the holes made by drilling.
The rate
Card 112 of production was increased two i;imes. The nex die
17
__I3MAIIWJ- A. Yu.
"On the Oil-Less Binder "P" used at the Plant "Serp i Molot"
report pressented at Scientific-Thchnical Session on ProiTessive Technolo67 of
Casting Molds, organized by the NTOMASUROM of the Kahrikov Crbletet J, In hliarlkov,
14-16 Nov 195-1.
Liteynoye Proizvodstvo, 1958, No 4, pp. 28-30
~ A 11 !11 F I,I I I i : I Z ;
Gublil) Gcorgl:7 Viktorovicb; KUMER, Al.eksan(li, I-likh-iylovich; EY)MV,
Gennadiy Vasillyovich; NZALM ..Alql::;,,!nf, -. Z-;~jyroy
)-V '- -'-7-z'---q---I
~, Ye.ll... otv. red.; Xd LF, NA "' .1
YARKHO IIA Il , Z .1 red, izd-ra;
SABITOV, A.v tekhn. red.
(Roas-ter of oreslObzhigallahchik rud. 1.',oskva, (yongortekh-
izdat, 1962. 68 p. (RIlLk 15 - 10)
(ore dressing)
I'll.1 J T:
I!N~ ~, It! .! li[411311- i 111 1111 ..II I. .;
PTSIN. S.L.; KISMV, BARARKNOV, PUS.
Automatic device for simultaneous drilling of four nall holes In
windovy sashes. Suggested by S.L.F~sin, A.I.Xisiplev, I.O.Ismalkov,
14.TS.Earabanov. Fats.1 isobr.predl.v strol. no.16:45-46 '60.
(MIRA 13:9)
1. Rabotniki derevoobrabatyvayushchago kombinatot 16.3
Glavmospromstroymaterial,v Mo8gorispolkoms., Mosk-i,a, Karacharov-
skaya ul., d,8,
(Windows) (Drilling and borirg machinery)
Problem of the optimum nurface smothneas cif parta of acrow
presses. Izv.vys.uchob.zav.; pishch.tokh. n0-3:120-12.5
'59. (MIRA 12:12)
1. Krasmdarskiy institut pisbchavoy prorVublannnati. Kafedra
takhnologii metallov.
(Power presses) (Surfaces(Tocbnolo&7))
IZMALKOV, I.I.; HAVRIYENKO, F.K.
Efficient goometr7 of the screw press platat.. Izir. v7s.
ucheb. zav.; pishch. takh. no.6193-95 163.
OIIRA 17:3)
1. Krasnodarokly politekhnicheakiy institut, Wadra tekhno-
logii metal-lov.
IZMAIKOV, lrasiliy Vpkgillyevich, shofer; GRECHKO, V.11., red..". DWISKAYA,
G.D., tekh!l.red,
[Roducing the coBt of automotive transportation] Snizhenie
Bebestoimosti avtomobillnykh parevozok. Lit.zapisl M.S.Blantsra.
Hoiikva, Nauchno-tekhn.lzd-vo Va-va avtomobillnogo branaporta I
shosseinykh dorog RSISR, 1960. 39 P. (MIU 13:6)
1. Podol'Bkaya, avtokolon- NO*28 HinisterstvIL avtowbillnogo transpor-
ta i shosoeynykh dorog RSISR (for Izmalkov).
(Transportation, Automotive-4ost of operation)