SCIENTIFIC ABSTRACT NOVIKOV, S.S. - NOVIKOV, S.S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001137430012-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 19, 2001
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

V,264
5/020/6 1/139/00--/'018,/021
Interaction of the weak ... Bl(P/B208
the pressure in the products of t ion : 5u
- -('
)(~P
1p
)'
1f
. 6p /c2
6Q2 2 2 2
2
; the (:ntropy r,tve ~ n the pi c F of combust ion : 2
2
2
bw
. -
1 ( r - 1
(2) . T!, , a ut h o r9 t (, t h j t c h ri niz e of the
1
2 2
propat.-ition velocity of thr- fla;,,e is relritf.-d to the of the thermo-
dynamic para meters of the combustible mixture as folio-owsi 5U - A8p + B6Q e

3 where A )p 1 ) T+ I IrlT1/pl) (JU/)TI)

-c 1
2 ~Qjc

s c
. Th- funct ion T1
')U/)Tl)
(kj
1j

ns i d e re d
~YS
pj
p1

to be dt-t~ ri.,i ined exp-i-.rimentally or theoreticr~lly. Us i ng ',l'), (2) and
the hurs obtaint for the pres.,iure viivf- in the coml.,i- ~:blv -,,ztjre
(Pi - PS) CIB + UCI - t)
I 8p;

6PI C1
(4)
+ - (p, - p%) cjA -
C (11 2 (Ts
"
r
I
PI I
l
for the prf.-osure wnve in the proda(.-.,i of
(,nrd 5/

Interaction of the weak . . . B%
,~, B2uB
(PI - PI) CIB + Uc, - T- -U - 2 B 1 4- L, ) !~~ 6P
6P2 ~ I - 't, - C, --Cl ~ Cl (5)
(P, - P a) c3 A -(T. -c-' 4-- 3) '-' -
PICI Cl C11 U
Cl
,ind for t~j, - ntropy wave in thc, T-roducts (A'
pc2rturbation of ti~- heat supply 'I, occurs in th(.. i Y. 1 the
valueg for 6p p Find 5Qe may be determin,-d. U - A"P, +
1 2 2
J/ T 11-ice 7 s e x p r es 7, ~ol I o -,,; E-,
(PI - PI) CID + (71 '1 U I ~Q
hPI = - - -C, (7)
+ (p, - pt) cj.4 (To - + 2 - (TI - C, U
PICI Cl I Cl
Th~t of pcrturbqt ions e an~i ~., in th- t ibl" 7!.i) turf,
1
r t s ull i n kv a v c~ s vi ho s (1 i n t (- r.,; i t1 ii t h f- 'N tAV e i n tn s t i tL
T
r, by erich of thes,-. pc~rturb,itiono . h-, of thf; i i~t n-
re waves -,%hl~;h ~jr(, iliven ir. lo f . r:i,,j y ti iv

27t64
S/UC/c 1/15 9/0~5,/C 18/02 1
Interaction (~I' tiie oieaK B IQ 5,1D208
and (7) if the variation of the propagation velocity of the flame is
zero. There are 1 figure and 5 Soviet-bloc references.
ASSOCIATIONs Institut khimicheakby fiziki Akademii nauk SSSR (Inotituto of'
Physical Chemistry of the Academy of Sciences USSR)
PRES~NTLL: March 11, 1961 by V. 11. Kondratlyov, Academician
SUB14ITTEL j March 8, 1961
Legend to fig. It (1) Flame front, (2) c-i,tropj 'wFve.
VOO JXNAX0 VAINOO
7 F
C,ird

J (,-,I
3/02c/6 1 /' 4 C,'~C 2,!,2 71
A' uv
und 1(~
r. El * F, ie f) t I
7E IL, naak 9 S SR ~CAI&dy , v.
-ko 1. for a uouBlIbIl'.1ty nf avoid,%6
T E X T
d I f f I t the accuo tic Impedance ~,f a b rr :.,z
They probe- i .1:,.car (tub-ular,' model in whict.
aipear direction only. 'in !inear a;)-,rcxI:..iA,-:
r -.' b I () M lt~-,- of combuotion of a condensed 8~-Stom l.-, it
rogar-l", I ki Li i:. t , ~ p r c, b I em o f na t u ra I c a c I I 11 a t I or. 9 n t
o Z and Z, - Assuming a low
loneth to noglocted. h a f o w r. 6
r-luenclea: (z I
0
oqo .,!A, the wave vector, Z the I m e d ar. P t
0
11 r Ll- t n Impedance of t, e nd . f
..o open t "; r, e
Car I

8 t 1. On
J e n for the se:f-ex.-Iltatlor, of the 3,,, s e:n
r
R_ r " Is t~,.e reflncti:,n
C
RI R, - r, ~ xp 2 'l C , 8 t e
~Len Vibo erld. If Z a r-, d 7, ar-i '.t in
r I t i c a.1 0 c r cr f o r the li:!~lt j a t
nf 'lnqta~ility, '- t 1, s u 'I
to t~-,.
a., i - e r I
Reference i a Made t c) 3 -j n Zh-l 7
c r
r the calcul
t Z,
L.-. tl '. o) r a I a t f r oq%i e n c y 7.
0 1 1'. A t~.on a a t n
ani r c.
,,j a 9 1 np, c --m bu a c r, o *,I e 7, 1 iA ~n an E t ~l
j f q j and f ina. ly reache C
1~, c nme a ~na tab I e an,
8 s
1 r ra -r- ;~r- I f.46ure and 13 reference

-567r
sloe, I/,
d c 1 ~) finstable ccmbU3ti~,n 3 1 C
Soviet . 'L,.e 1-c f,? r~2.,. c j sZnt,' ,3
11011 ow a H. I,rai, Co=-.. on Pure anrl Al~-'.
c u r P N. F. 31 rd A i 5
!!art F. T
Bird , L. Haar, R. W.
- 3 -, 1 - r.
'w';. ~':axwell , Fourt~' s'. a t
ASSOC'.AT',C,.'-. k- -':n' chaskoy f-- i n U~- e~ n s i t -.i t e
of 1,hysics of of Scl ,-- .,e5 'SSR.
PRESENTED: A~ri. 1,3, 1 )61, , by V. N . K,~ni--rtt '.,,9v ,Acaaem.'cian
K B'.:IT-4 ED; A;ril
C a rd 3 /1

SOSNOVAP G.S.; VOSKOBOYNIKOV, I.M.; BRUSNIKINA, V.M.; IX)VIKOV, S.S.;
APIN, A.Ya. ; LAPSHINA, Z. Ta.
Comparative data on the physicochemical properties of some
liquid explosives. Izv. AN SSSR Otd.khim.nauk no.2:351-
352 F 162. (MIRA 15:2)
1. Institut kbimichaskoy fiziki AN SSSR I Institut organicheskoy
khimii im. H.D.Zelinskogo AN SSSR.
(Explosives)

IJ:
T 17 E,
Novixov, Lin
Or, the -efiecti:-~.n
en,l of a c1rcul-r
D2 9 9/:)-'
-,Lzantoev, Yu.~. ~:-:o',co',
of' plane sc)ur,,l vi:ives from the open
tube
0 D ICA!,: Prikladnaya :-atcmatika i -.ekhan'-',~a, ~. 26, no. 2, ',~,-,62
576
-Qc
is ler`ve~ 'or t',-.e l-,- n c L f I C i e t 0 f
nu s3un~-,aave the open end of a circu-,-.r, -~-c.-.i-fnf
,, L -~Lc t d i c on ~` n,,-~ -~y a- t.,,.e C)un-
~rolu'ely ri;;id vialls; t,,.e con I
a
"GUnuInj ~% iu:.'' into L~Cc-)Iu
ry co,,..big T. 1~017 - L, -. I n'..
.i.o reflectlin coefficient is roi irucl, 1".-. the of vibratic'nal
co:.-i"bu--tion. T-e --x--;s of the unfiar.-:-ed tub, , of r --~--'us a, colnciceo
Cy14
wIth "',,.e z-ayis o f aa nd ri cal sy s t o f c, ~, r : in at e s ( r, z axi-
al. symmetry is as--u:,-ied. S-.c--:Iy oocill-la-ions ore -onsidered; the
t-'me-dependence of the acoustic field is iescr'-'td by a function o~
t*!pe exp(- i,ot). The equatiors of the acoustic f4-eld ar,~:
L
2,~ 2 0
+ k , 0 1, 2; k 7; ~P+
j c r 0 C) 2
Card 1/4"

02/322/025
On the reflection of plane sound ... D2~ )01
vil% e r e ciis the velocity of sound, and 1^ i is -.he velocity po-~entiai'
T 4 4C
he bol.nd-ry conditions are set up. '.,',,,e sour-ht-for coeffc- -t cf
U
ruflection is expreszed as t'-.e ratio R = B'A (of ti-.e amplitude 33 of
t'-e reflected viave, to the amplitude A of the incident viave). After
transformations, one obtains
L
-- polaziJo (azlj 11, (a z l)
w`,ere H is hankel's function an-' J - Dessel's func-.-3n. '13r conven-
i4ence, it is assumed that t,-.e constants k j are coz;plex numbers. it
is s-.ovin that
res Ilk
'q = ._ _ k1 1 -) (17)
res k ii 7-7 1'~'
the asymptotic values of the function f3r z co , follows
t 'n a t
Card 2/4

of -..C:

o,~: u

L 6Wa.-6- LEU-C,
-F,7 (k)
6~(f JTI~iA(b)/DIA/EED-21 r-4/Ps-4/Pt-10/Paa-4 RFL/~BW(a)/SSD(&)/
kFdL/B5D/SSD/kFETP~/AFTC (b) JWD/Z WJWIWW M
IEDC
ACCESSION NRi AP4043842 S/0020/64/157/00511188/1191
~AUTHOR: Hqvikovq '~. S.; ~yazantsvv, Yus So
~TITLE: Analysis of mathematical models of combust on in the condensed
'Phase
JSOURCEtk AN SSSR. Doklady*, v. 1~-Y, no. 5, 1964, 1188-1191
'TOPIC TAGS: explosiviL, propellant, combustiont solid proppllant,
nitroglycerine
~ABSTRACTs The combustion of condeased systems is characterized by the
multistage conversion of the combustible in the combustion front.
Thereforep :the study of the individual stages and their interaction and
-determination of the controlling stage are of importance. It"was pro-
viously shown that ur to 70% of the heat required for heating the burn-
jng surface is liberited by chemical reactions 4n the condensed phasei
ss~combustion of nitregi F11-a ~ 1-p o w
11n flamele _y ce r combustion is sus-
tained exclusively by h-e-a-FT dense d phase# It us#
n
also previously found that with increasing prossureo the heat liber-
Card

IL 8443-65
i:ACCEMON NRt AP4043842
fated in the condensed phase lacreaces. In the present article the
!existence and uniqueness was proved of the solution of Clio equations
;describing the combustion process in the condensed phase. Ys. B0 Zal"-
,do'vich'.s thermal.theory of combustion in gases was generalized for the
!
'case.of'combuotion in the condensed phase. Two models were considered#
1) the T -model, where T is fixed temparature analogous to the boil--~
ing point in the Zel'dovith-Belysyev jodel, and 2) the Qk model, Ln
which the condensed phase is gpmifte6 when a fixed amount of heat
100 is evolved byi;hasical rriaction in the condensed phase. This
-of- both solutio ~-vas proved. It was also shown that,both
uniqueness a#.
Itiodals. are ~4oi-iutvally. aidlustirit and can'be toed staultaideoully",
I this case:
-pressure isdiscussed,' 0 ig, art. bass 2 graphs and 9
ifunction of r
:formulas*
KSSOCIATIONs Institut khimichaskoy fisiki Akadenti nauk SSSR (1nstL-i---
~tuta of Chemical Physics$ Academy ok.' 'Iciences SS-SR)
IlUBMITTEN 02Mar6A ATD PRESSs 3098 ENCLI 00
VU3 CODES TP No REP SOVI 009, OTHERI 000
d

NOVIKOIJ, .1. '. ; 7 "; "J:." ? "pv ,I -,.
Ana'p~is of mathemiAtIcit', n~rl (- ~ s , '. '--de7, i~ "0 - h fL q ~-.. -1 : I il .
" I ~. .-
D-) kL . A N 3S"'R I')" :-, . ~ ; 11 ' ~', ~v "i.. II
1. 1.,iil*,itu*. "; , ;-N f "I ~ , !~ ".,! v . - 1.
R~,tciemikom II.N.

L 143~8-65 EPA/EPA (a) -2/EY,r (w.)/EPF(c )/9PR/F.VP (j Pc-4/Paa-4/Pr-4/Pa-4-/_
Pt-io/pi-4 RPL/AYvVL/A.EDC(b)/AED--(a)/SSD(a)/SSD/BSD/AFr-,TR/AFTi,(p)/RAEM(i)
ACCESSION NR: AP4044889 71W1J'M1JWD1R1i S/0020/64/157/006/144p,/1450
AUTHOR: Nov~kov,__S. S.; Ryazantsev, Yu', S.
TITLE: Combustion theory of condensed systems
SOURCE: AN SSSR.-.Doklady*, v. 157, no. 6, 1964, 1448-1450
TOPIC TAGSt combustion, combustion theory, explosive, solid fuel,
propellant condensed phase
ABSTRAM An analysis of the condensed phase process in the.combus-
tion of explosives was made on the assumption that the reaction
is monomole cular and - that - heat- f lows f rom the gas phase to - the cor--
donsed-phaae. The equatiohs describing the condensed phase prpcess
were reduced to the following formi
dp (n M (T. - T)
P
pto r - r.;
P - q3' at. T - 73:,
Card 1/2
-4- -:571 7 E:.:T.

L 143?8-65
ACCESSION NR: AP4044889
where p m Adt/dx (A to them.,al conductivity), O(T) cAO(T) (0(-1L)
is the dependence of the chemical reaction rate on temperature),
W = me (m is mass burning rate, c is heat capacity) and q. is beat
flux through the hot surface. The equation was sollid f .r he cases
> T T T T v 0 t
T
* " * S, s, ano T*,( T , where T* - To + ha./c (h in heat
aii'i a t c tio&), T.
of re ct ofi and 8 oncentra is a parameter introduced
previously by Zel'dovich, and T 9 is temperature of the hot surface.
It was shown that when q. < q. n lution exists, but tha: when
q Iq there is a unique s.lutoion'o. The function w io.shown for
> er'
diff.ren t cases in a graph of p va6 T. Orig. art. has: I figure and
12 formulas.
ASSOCIATION: Institut khimicheakoy fiziki AN SSSR (Insritute of
Chemical Physics, AN SSSR)
SUBMITTED: 17Apr64 ENCL: 00
SUB CODEt WAI FP NO REF SOV: 010 OTHER: 000
Card 212:

VVIT (1)/FPF W -2/LED (b)
3 Pu-4 jjp,c) MI
-
JVXESSION M.- AP5008501 S/0207/64/000/006/OM/0080
AMOR: Novikov, S.S. (Moscow); RyLzan~sev Ya.S. (moscov)
TULE: Acoustic admittance of the hot surface or condensed systems
SOURCM Zhurnal prikladnoy meUhanild i tekhnicheakoy fiziki, no. 6, 1964, TT-80
VIPIC MCZ: acoustic wave (condensed cystem, hot rurface, wave front, acoustic
-aIdmittance, sound field
ABGTRt%CT: On the basic of the theory of Ya.B. Zelldovich, an expression is de-
r!vQd for the acoustic admittance of the hot surface of a condpmed system which
Ia dependenton three parametersY and it is shown that, depending on these param-
etcrs., acoustic waves reflectedfrom thebot surface mny be intensified or etenu-
eted. Acoustic waves having a wavelength considerably greater than the vidth of
the burning zone in the gas are considered, so that in the given case the front
cj'. the chemical reaction in the gas coincides vith the surface of the condensed.
phase, and to determine the acoustic admittance of the hot surface it is necessary
to determine the ratio of the magnitudes 6u and Sp (the velocity and pressure,
Zespectively, of the sound field on this surface), Orig-.art- has: 13 forMUl"
4n&. igure.

WhNi
c Ai~bb 543 S/020'(/65/00-3/001/005T/r,06.1
WXESSION NR:- 9
1AWHOR: Novik'Ov, S. S. (Moscow); ByazantBev, Ye. S. (Moacov)
TITLE - Theory of combustion st-abIljty%f solid propellants
OURCE: Prikladnoy r-ekhaniki i tekbnicheskoy fiziki, no-, 1. 1965, 57-61
~(_)PIC TAGS: combustion stabilit-7 theory, solid propellant, combustion stability
,4ter on, combustion tability- combustion---.
--AIISTRAC,T: Mathematical criteria-of-the~combustion stability of solid propellants veic,
d(Tived for the zero- and let-order reactions in Q-model combustion (vhen the gas-
:iVication of the condensed phase (k-phase) qccurs as a result of the exothermic
ircaction in the k-phase) and for Ithe zero- and lst-order reactions in Tg-m6del com-
btistion (vhen the gasification of the k-phase occurs as a result of the surface, j
Igeseous-phase temperature, TO). The proposed combustion stability theory takes into,
t~ccount the beat generated In the k-phase. The effect of the heat generated in the
ofAhe.k-phas--and the -tm-perELture--flu6tuations-in-',he-gitseous -phase
an
..iear the charge surface on the combustion stability of solid propell ts is discussed
..:61g. art., has .1 figure and 21 formulas. [PSI
4

14 JWD
L 27554-65 -EPA/EPA(a)-2/EWT(m)/EPF(c)/EPR/EWA(c) Paa-4/Pr-V~t-7
-'-----di626f/651600/003/0043/0-046 I
i1CCESSION NR: AP5018193
.1i ALITHOR: 429WA-L-S-U.Woscov); Itrazantsev, Yu. S. (Moscow) 0
eattion
1`17M The theory of the steady propagation velocity of an exothermic r
I!ront in the condensed phase
43-48
1- it.OURCE. Zhurnal prikladnoy mekhaniki i tekhnicheskoy fiziki, no. 3, 1965
IDPIC TAGS: iolid propellant, combustio.-k, combustion instabilit burning velocity
condensed phase reaction
14STRACT: The exothermic reaction in the condensed phase may in some cases Uberat~
%p to 80% of the total- heat release in the combustion~of a solid propellant.11 Hav-
ever, even,in cases vhen the heat release in the condensed phase is much smaller,
Ibis process is fully or partly responsible for the gasification and thus has a
Controlling effect on the overall combustion process. Formulas for the velocity. of;
The reaction front propagating in the condensed phase are also of'importance for
unalyzing non-steady state phenomena associated vith combustion instability. In the
preseni. study.the Zelldovieh.-Frank-Kamenetakiy method for thermal 'flame propagation'!
irms applied, and formulas vere derived for calculating the velocity of the reaction~-
i:wd. 1/Z-

ACCESSION NR:. P25018193
'
front propagating due to a first or zero order reaction in the condensed ph&se._ For-

mulaa for the maximum and,minimum velocities were &lso obtained. Arb got
Orig, b
27 formulas. IPVI
(ASSOCIATION:- none
SUMTTEM.- W665-.i ENCL: 00- StM CODR: P?

NO 1W SOV: 012 OMERI 001 ATD PrM 4039,

4

lcardl_&12

SLCVETSKI'~, T.I.; OKHLOBYSTINA, L.T.; FAYWILIBETZ, A.A.;
IVANCV, A.I.; BIRYUKOVA, L.I.; "OVlKCVA.-&~t--.-
S pe ctrophotome trio determination of the Ionization constant
of fluorodinitromethans. Izv. AN SSSR. Ser. khin. no.11:2063-
2065 065. (MIRA 18:11)
lo Institut organichaskoy kblmll Im. N.D. Zelinskogo Ali' S,SSR.

77 '01

. i , i"FE , -" ) . i . -, T A 1) - A K. ( VS K ' Y v 0.. .
V.A.; f , - I
S;3'e c' -, Ive red,,(-!.icn of aliphatic func'.Ionri~ nitro comFoundo.
I
I'vi- kitim. 35 no.1:43-6c) J'a 161 . ( 'm :?lk I (I : !~ I
I . I n.~, ti t!; * orran 1 rhpskcy khi'mi 1 AN ",-~'SR i men ~ 11. i . -e' inskovc.

-LI4708-66-
MCC NRI AP600-1102 SOURCE COLZI U.Ii/GC-62/)5/'M/Oil/20~,3/~'C,65
Ar khlobystina
'llms: siovetolciy, V. 1.; 0 L. V.; Faj!p~bor~ A. A. 1 ivanov, 1,;
NovikoV, S. 5,
ORG: Institute of -Organic Chemistry im. 11. D. Zolinski, AcadozZr of ScioncosSSSR
(Institut orga
Akadoaii nauk S65R)
TITLE: Spectrophotomotric determination of the ionization com,ant of fluoro-
dJnitromo thano
SOURCE: All SSSR. Izvestiya. Seriya khimichookaya, no. 11, 1965, 2063-2065
i021C TAGSt ionization, fluorine compound, nitromethano / ~'F-4 spectrophotonoter
'X MACT: Ionization constant of fluorodinitrumothnno (I) in water and absolute
ethanol was determined spectrophotometrically according to the mothod described by
V. I. Slovotskiy, S. A. Shovelov, A. A. Faynzillborg and S. S. Novikov (Zh. Vaes.
khim. ob-va im. D. 1. Mondoloyova, 6, 599, 7017, 1961~. The measurezonts woro taken
on a SF-4 epoctrophotomoter fittod with a ther-mostatic attachment. Concentration
of I waj kept within 2.2 x lo-5 to 5 x 10-5 molo/'10 . The measuro=onts were taken
1 in the region 365-395 mA. Spectra of the species present in solution are shown in
Fig. 1. Acidity of I was found to be 10-4 loss than that of the parent dWtro-
mothano. E 0 onthalpy, and free energy were calculated.
ard 1/2 UDCs 543.422+541.132+547.232
1Z_

L 1),70&66
ACC NR, AP6=102
400
Ip
J40 ma vp
Fig. 1. UV spectra of fluorodinitromethane
in aqueous solution:
1 - anion; 2 nondissociated
molecule.
Orig. art. has3 2 tables and 2 fignmes.
i ;UB CODEs 07/ SUBM DATEs 24YAr65/ ORIG REFj 004
lv/~
/
;':ard 2/2

W)VIKOV If S. S.
of ,tisawraTed Ilvdirocath9w; oil the dchOto
C, -~Tntlii7 ~-- 7. L
v.rifing Ilt pciftes 4 rWi jjtjb-qts N
iwle
'T, Jill' Rw,Uf7t---`,TM , 'A
K,ls"Imr (;.ItfIvtl 0) O's 101
"'(11 ot
i-.1, Mm, I"
vid tl'~ 1, 1% l, y lilt-
'hkT!-.ff, wil aft. I flic I till q "a.; le-Of !~N I
'l,1111ITI 'If 1 11" 11 "1 1" 0 ,
L y 1,&I If.- 4,,, , 11, , 11
I ffe, t Ow m tIN ltv .11, "t O"ll t N.
l, [ff, I hf pt"lle, xt! I .
NfIrl,:,ol ;II-fl, I I . lz
(V
al"ll'' lit I
the 'Ictivity nf 111C ca'alyst unrl'I'liz, I'
h ;I rc.i tit of lit nr tif Cf-f, ( ~vvxs otilv I sltvtit
1~, M , ill 11 e II
I'll -0, if, 01,~ ;, ....
-I- flIN-1I IS ,) r . Ill a ;tliaol If
II N r. it, t ""'at cd lilt " b", ill;
I i: ) 5 7l ( 4 5 g I , rc i I,ic
I 1--d .'ipi ff (-T,. tr~ "?, .1 " fill d
f. .. ......
IN
-I'll" fl'-Wf
lm~-11%
V
10""'t"I it!
I,q-ll(blig cy
.. . ..... 1., 17, C-T
If,, :~: 'd,, I -.,,I f
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a
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AIL T
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00

4
awyqo revocutto and at tho su'aw.

*
63 11dodittmto-41. S. S. Novikov,
0" of
1. Stiumit, N*4W, 4 b,,d _
A. atid N
1=mwxZ:z
v1
,
1
mduk S-55.9. 4j, 2C.1-ail "46 1 4,
'W"W"T .4 '1"
e
r,

d
-4,
14 "61.111.4 'm 4,11%, 1
r-114(1410 -C(q01 ef's Si
j
owal wiwww
vmIquity of Clod; ["Cittl
w" asmtstucd by 1cbFi1r,KmAt..,t, .4
mial"i hr
Ole
Oost 4"d the Co"tito Sift 01 dic P1 (-W A.)
utwhamard. Itegiettec
041
MW $Los.. do mm* r'. 1W hr. 11
or"(01'M th* GriCiVA! 4cttvtty 4mj 1,1t th, -I t.1
"M"Ced- I-e- 60 fft"'Stn IMJA PL~~ c-i , -1
[vAq-utKb u ItiChly dismse pt wilhm--t r,am,r r-~,t.,l
lir, iftsilyeven *I itIc"s. trmp-, it Wkiiorii thAv m it,,
14 tanifrwinly. No the cr--
40.

u a to -0 it 05-

*"
dittoolt $fact
0. .0,000 0 0 0 0 0 SO of 0 0 of of 0 0 a Ole e 0 00 0 0 0 0 41 411 4110 0 0 0 46 0 0 0 0 a
A
.
0 0 0 0 0 04 0 0 0 0 0 0 0 a 0 * 0 0 0 0 a of 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 '

00000000004 **Goo** a Ole a ago

j .1 m is ;a r .v m
v A t L M 10 ~A ct

I'll-,
Ago

00

0
is
4
's0000 00 0 00 Ole000 00000 **so 0 0 41 0 0 000a00 00.0"'o
a,
.T
:
~2
.
0*0*000*00000000000000000000 904e660040006:

Eff"I of h)dtocarbons of vasloui cless- -i sw-prits
(Wri o( live membeird tycl4net ;n thr pi-n- m at.
fillnum duacide N I , , . , I I I -
. ~ 14 Mll- - I , .
A.,mb All,- %-1 1950 1 ~
A 1,.two .4 IlAti .,,a -I
1 11- at
l" ... ...... ...
0, Alk
nu. 111- .-k
J flka
It '411) ..........
. . . . . . . . . . .
hv k1k i.

NOVIKOV, ~' S I
" Investigation of Boundm7 Film of Liquids by Blowing Off the Liquid,"
Vest. Ak. Nauk SSSRO 20, No.3, 1950
Digest W-12652, 1 Aug 50

'.-dxW"d%ft ad bitatiltme "A d461*644"Itiam ad cydo-
kaounto. 'a "to catalm 46 facthrukad "Cloatims. A. %I
kuhtushtv~~ 3, tj Novikarr Z vill Upskina. W N I
shumn (I..t. 0io-I'harm" ". SH. ITAS.R.. M(M~W)
Akad. Nqmb S.S.S.R. 14, 77-OMAW).-Hydro.-
- " 11. At a 21VAV TT6.%rttv "af a) I" I I CSIGIV.1
1141- itao$ J arrvIsihotan.
wm "'I h "At al"'t, t hy
tion of "firt, (L' with a local". (it 47 g. 1 .4(0 it,
compan. At tvatilait. Il-ra "-Id' tit tMa*. .jaly,j, 0
%P "'. W, too I-ited aht? fri. -m
CV "N' 41 .19)
vvkviticia cit"hir m.,
h al. istaly.11. hichi-.1 sut'-ity vta.f..iltif tit, 'MISIV.t.
:"It a ,, iiallit '. if the Of, 4 - oil A In
:
Its,fir, 'IW otatisily J.1 .4. it, I.,
"Cratir with the No "Viltalitife 0" it, a,, MP A 'k- to-
mus". We attakiefatis tit it"aite oittiriveil with %'a cataliartat.
,an AIO,. it f,,ffiammas that the aftitnition grain Om 4 that, "ts-
Ittrins 111viiij dmit n"t driat-tut on the nature "I the ca"",
"W Iiii-thilit all it hiChr,at atilh catislir-c-
-fecov"l-t. al 00"; icher dematimpt; fromp. Inter" the mar.
tivily. wh~ffrots ointoristj in twan at Win' int-ratatic, it ,m-
-Wirfattir triaritait 1" a 1.5-fattil tracreatar tif the Ni Eta" tattor
The d4thydrograotfing milvity lcwrftwq with Incrimciaing
"W"Itrr-ims Cal that Ni 14411tv kettaretral
f-41 tat it, 614-11% .4 OW 0-11.161 No claittat. ruvil i" filtlit't
.4 alartir IL ractiort taffistr-c' ...a-
11W,111Y. the st-ti'lly im-rva-it vaith "
;.4far,I I Itar 141,01ar Ittaf.1 %I catailiv.1.
,"I &"I., C art q1ttable ('W I"Ah ain't
I-atiatiauldfly. at I%-II$rmIwfv4 thicia I'm
their 44-tivitv 1. 111firs'at it, that '4' Afalvial. nf the P? Crimp
%! ,ts. ,

SHUY"KIN. N.I.; WVIMV, S.S.; ILkRYSHKIIIA. T.1.
Nature of sexavalent Wrocarbons of hit-,her fractions in Mailcopsk
benzene. Izv.Akad.-iauk SSSR; Xhim.otd. no.2:11'-llg R:w-Apr 51"
(C;u4L n: !)
1. Instituto of Organic Chomiatry of the Acadomy of Sciences USSR.

USSR/Cheyristry - Alomatlc Hydrocarbons Ai4~ 52
A kylation
"Catalytic Transformation of Etlivl-Sut)stituted
Five-and Stx-Membered Hydrocartunri," S 1. Khromov,
S. S. Norikov, R. A. Radzhabli, and Acad N. 1,
Zelinakiy, :nst of Org Chem Acad Sci IBSR
"DA- SgSR'Vol 85, No 5, PP 1053-105r,
A study wao made of the stability of the C - C bood
in the ethyl group of ethy'-substituted cyclopen-
tane, cy-lohexane, and benzene. It was found by
means of catalytic transformation over a special
N1 catalyst that ethyl .-yclohexane dealkylates
mor: ea3ily than ethyl benzene, deaLkyLs"s
mor easily than eth7yl cyclopentane. 239T18

KHRMOV, B.I.; MOVIKOT9 S.B.; PJSULOVik. 1.L.; ZALIUSKIY, U.D.
Catalytic reactions of butyl-eubstituta4 benzene and cyclohexane. DoIclady
Akad. Uauk S.S.S.R. 67, 613-16 152. (KLRA 5: 11)
(CA 47 no.20:10489 153)
1. N.V. Lomonosov State Univ.. Koscow.

;.The de rl.:. 0 by a contin-
, ui~,*
u I lj~l w an,] S. S.
VN,,vikm Aknd. Nnsik S.S.S.P.. 0,.114. KX7QF-.
I Y4ffVTvM. 112 -13-The ronfonious depolyinermation of
dirv(41i,votadicne in pure ninnorticr was effected by ftefling
the (1111af hous a dropping funnel Into a heated tolumn
parked %with pieces of class tubinK 5 mnl~ in lianit. ind .5
otin. long. Thecolumacrjusisted ofa 7Mnim. length fif3O
rom. tubing. The lower NIO rom. was electrically licated
anit the dimer W-ts fed in at the top of this portion. The
oplicr poftion acted as a fractionating column to return any
divncr entrained in (he monomer vapor. 'rile ctit at the
ovprr end ol the colunin led to a water-cooled cmidi-owr and
thence to an icr-CM11(d fircriver. The lower end of t lie
( ol n in n Ivil t o a flask heat rd t o fivrom p. an y (I mi cr xct t i it c liv
the i,lutim. The capacity of the app. was IMI g.,/[. of rear-
tion voi. After about 100-150 ht;. of continuous operation
it was rjec"&-try to stop and clean out the high polynier cars
th;Lt had collected. A sample run with the cnlumn at 19r-
20W lasting 12 hrs. converted 582.6 C. of dimer to 57.5.6 g.
,if monomer. The ditntr had the follawinK characteristics:
b.p. 5X430" at 14 mm.; m" - I-5JZ5; d,'* - O.Q-MI Th
v 114 ve
juanomer characteristics were: b.p. 40-42'; Pi 1~ - 1; -
%11.* - 0.9010, Joseph R. Levy

.. .-- -.I,-"-- - - "' , i. 1, 4 ~, ~j I-l'i" 1* , I
L- L-

ra

Chemical Ab3t
Vol- 48 No- 8
Apr. 25, 1954
Organio ChemdstrY
C-wl 'Celloirlic frimirforr". flop of I'd cormal
It
d' TIxt M 111 10:
Ind
A I f 'va."115. M75 M;
':I I'M 27 1 of "-
I"'I las.
u,rwn a 'J' I ns ivith i, ;,~riyjoinn A
ai L, I I,, t h, i I I,,,, a nd h ~ ll I, ,,, 0, , A th,
"f C.1 1. hid, I, , - ;' ~
I h., I, I,!, 10
11.. hiii is rn-Ov int.) and 03-rnrihvIpen-
t.i p- -c tr-1 ~ ',Iu;;rthN1but,mr alnng
thr -igi' w, ~ufl,rs tacking
'Ind -r,,,!1 'n't, if w"I'lics are fi-ruvd i-
11'.1 1,-- -S I
" ~ r" .'Ad 1081"
a 1, v, , I, ( it 11 '1 if an,] Mu, h ~- and .4 lilt f!l%.I-
I- , 2~3 th,ILitartel, anA 2.2. and 2.3-
J~"e l1lized -;rollufic 11"!r"
2-mrth~ m-hexane.
and 1-t-nethyl-
lh,t; ;~~
0;'. '-M- "f. t~, alka%e,
~f CH, '."I-h it liw:f "'!l C It.q.,
ig i ' %I, h urid, r
0 rT,r 2 -1 '1 The

7
USSR/Chemistry - retroleum, Kdr/Apr 53
Ar~)znatizatior,
"Cataly-tir loomerllzat Ion of Ethylcyclopentane
In th#-? Vap~,r Mml-e," Shuykin, Novikov,
Jn5t Org Chem, Am] 3~-i USSR
1: Ai( Nauk SiSR, No 2, pp 27,5-26,'
The poscibility cf i-merzinj~ -'thy".CYCIOI-;~-
ta.m~ Witil F1 yield of 9~4 in-,o methy1cyclohexane.
ovF,r C Was shown. At R voliLie ve'locity
of 0 3 , tyle optli;zI tcmr., for this rcaction is
natvr,-, o: the oth-~,r ingrpdients
?c;~127
,-,f thf- ila3,~Cllm, fraction (~-ntp, -'.tv',-yc-)pen-
1.~tr%P JOPL not make-, any diffAr-n-coo. r)ry il,"~
loimerizini; AIC'. If-
po.-tte,! mi activated

U981
You= atom iwf"dmacr
K. V. Tomickv-1. Rftd4vtkayg
EL
j,8.Nov&M,&rAS.t.Khmaov.
T
At"I". Usk. 1, No. 12, MAIO. i ldtA-. Ks-k N4. 9.
97-100(imil.-C (11. meth*7dopt"tam
th kl"i 5
tatoe (IV)6
At-saim walystff ) tit No A: V. E &M n
lWak thasm. yW& ff. tatutne. kopeuts-.
t
unkwwa hydromtbom IV pvc detive. of crdehetam,
od
I-(- th.
`,d 1_
or
75

Chomicnl Abmtructm
May 25, 1954
Organic Chemlfitr7
8,14
J
zx~,f r -,ni .:fwn A flip rnf~;,V-
411AIL .0-

TIKOYETZY&, Tc.A.-, MOVIKOV. S.S.; SiRMLY. M.I.; WaZili KIT, B.A.. akademik.
7--!~ - - 5.. - -
Dehydrogenation of A -pentans. Dokl.AH SSSH 92 no.2:345-3448 S 153.
(KIRA 6:9)
1. Akademiya nank SSSR (for razanakiy). (Dehydrogenation) (Pentaaa)

10 1
XTherma tritatf ~70Z or i "It
iff, S. S f",'= .1.11 A,
IPK-. C41M, 341. 05*1

SHMIN, N.I.: NOVIKOV.,;L,15r;~, IURTSMYA. T.I.
Thermal converelons of 1,)-pentadiene. Izv. AN SME Otd.Yhim.
muk no.5:898-903 S-0 154. (nn 8: 3 )
1. Institut organicheakoy khiAit im.N.D.Zalinskogo Akademil
nauk SSM.
(Piperyiene)

LSO/CheMistry'
Card 1 1/1
Authors i Khre-tov, S. I., Novikov, S. S., Petrov&, G. B. and Zelinskil, N. D. Acad.
Title Contact conversions or propyl substitutes of benzene and cyclohexane
Periodical Dokl. AU 332, 96, Ed. 6, 1175 - 1178, June 1954
Abstract t Contact conversion of vrolkyl. substitutes of benzene and cyclahexane was
investigated. A study of the catalysate showed that complete or partial
cleavar,e of the side chain carbon atoms takes place in the investigated
hydrocarbons. This process is much =.oother for proyleyclohexanes than
in propyl benzenes whereas lsopropylbenzene is more stable against contact
conversions than n-propylbenzene which corrost)onds with the facts observ-
ed during catalytic conversions of ethyl- and butyl benzenes and ethyl-
and buty1cyclahexanes. Five references. Table, graph.
Institution The M. V. Lomonosov State University, The N. D. Zelinskiy lAb. of Org.
Chem., Voscow.
Submitted April 5, 1954

QW/ Chemistry - Catalysts
Card
Authors Movikov, S..S., Khromov,, S. L and 3evostyanova, V. V.
Title t Contact conversions of ethyl- and butyloyclopentane in conditions of in-
creased temperature and hydrogen preamwe
Periodical Dokl. KN SSSR, 97P Ed. 3, 463 - 466, July 21, 1954
Abstract The effect of oxide-metallic catalysts, increased temperatures and hydro-
gen pressure on the contact conversions of ethyl- and butyleyelopentanes,
was investigated. The effect of catalyst composition and magnitude of
the hydrocarbon side-chain on the contact conversion, is explained. The
hydro- and dehydrz;gsnation activity of the Pt and Ni catalysts was deter-
mined by the hydrogenation reaction of benzene and the dehydrogenation
reaction of cyclohexane. The results obtained are shown in tables. Five
references: 4-USSR an-A 1-German.
Institution : Acad. of Se. USSR, The N. D. Zelinskiy Institute of Organ. Chemistr7
Fresented by t Academician, B. A. Kazanskly, Harch 24, 1954

AID P - 28rj9
Subject USSR/Chemistry
Card 1/1 Pub. 119 - 5/7
Authors Novikov, S. S. and Ye. A. Timofeyeva (Moscow)
Title fSomerization of alkanes and cyclanes
Periodical Usp. khim. 24, 4, 471-507, 1955
Abstract A review Is given of the literature on the Isomeriza-
tion of normal alkanes and of cyclanes in the presence
of various catalysts. The effect of hydrogen and
organic additives on the suppression of secondary
reactions Is discusGed. Four diagrams 16 tables,
186 references, 81 Russian: (1897-1954~.
Institution None
Oubmitted No date

MIMI

and
pgntzimll' coav"Ied lia Cite 0111~~O'L- Yslii.~h with

dp 0'7"~ cill'CHCHICI W1
C,
NI
VY-T 1*1 t--
t-R; 143 9" I.Ul
A;Ut I

(1yrr PI-C t" f1mrf

"20' in A:i H atul Iro-

Pr[h.
dolifittvit bz,w;;-~,, (~r-, m 1~
1-11f, 'oul 1.1")
give 1111"'Crie, I j
i~-wo r,. o,-' Is

d antfUtonadmprnerdels of Sura"Amy
"Uasl~ NAL A iA.
n~ MCI-
_Chrm
mi. Naiii
Kk;-
tow). ysizT IT I
------ Tte c-.)unpa. (A Sarakhan~ rvoliut Tras,
hyJrm-wbons 2-1, tmr-iffins (J.0in-eb-
-Ar u"I cr,-I-
dtfivs. 17
in th. f-,~'11fxwjr)j Milli -lwc LAI lo-%L 15
ra''ni.

S

Distj
Us tr t )X3d/lM4IU2c(j)

1), A. OW12,
DO =I D. I L_,K". i TAUA.
-rio
40MA"04 IV37-
octane
.
.
. I
neg. Were found lot the "othetic hydro, t3, ed dur
Vt
~
Ma. of 20%
.
.
maphtht6ft: ryclopentane 104.8 an4 !04.9; ethykydo-
tane 104.8and-, isopaop kyckopeiitane 104.8and 102k;
t
1044
m 104
"
1
Od
-
.
s
.
a
m
inp of the lonowing nopuynthetk-5 are gtveu 6s, CZC!Qbtx.
one 03; aWbyk-yclohrx&m 89, etbykrdobe=ue-,3- iso-
D
82
b
k
..
Clane
Ydo
Py
p

NOVIZOV, S.S- oskva); KHMEL'NITSKIY. L.I. (Moskva)
Synthesis and propmrties of aryInitrometUnes. Usp.khim. 26 no.4:
459-493 Ap 15". WLRA 10:5)
Nothane) (Paraffins)

NOVIKOV, S.S.; KORSAKOVA, I.S.; BABITEVSKIT, K.K. (Moskva),
Addition reaction of nitroalkanea with compounds hAving nctivated
double bonds. Usp.khim. 26 no.10:1109-1124 0 15?. (MIRA 10:10)
(Vitro compounds) (Paraffins)

fro:,-,
t h
r. V
w19

D Z I

z3o vu
t J.')n
-vin 1 :( a
1 11 1 1 QII Ll
i n w;
-a f f . n 3
Ir ~ul.
A c r t u, r e j r
,XL iple on the c,'I-
a,.:
(
Q r e n t
(2 c:, lo r i r,% t . on o
C, )F' i r, i
n
L; t
r

ri n~it i in of Five- ai,,~ Si x -M.,
nol,,_-j . The I-,al ide torl v t
,; i ie I i ~;tri but ion a-,
a r~ J pho t 0 ?,L 1 r!, r
.umid c!~Icr;.ne in t~:,?
t o d. Cc nJ i ti~ no r o i' i i
::iona - or c i, r r.
i o n perff-,rmol ir.
t!ier ci-.Ic rin-iti~,no, I
r-, ') ta ~) I f, -i LvI ' r(, fo r~,
A 5 1 A I C rlmean A!-ri A'- tu,-i 1 1,,. ~3
, i j t ry All LI3.3R
on
Krymio ~ iy oe I ' 3i-. lr,.,
~~o -i i i A'11;~ i- i
I': ~'E 1) n Li; i r~;
Lj !,rtiry
Ir 'Yolic aomnoun(ts 2 Cy,,Ioj)arFff,..,) Chlorination
3. chemistry

T H )R Z N ovi~ov, S. S. , Khma I 'ril tak I y, '- I., zz-';
TIT,',--: Dec-)mposition Reactions of .14 20 With
(V-_A1MDdeyqtViYe 11 0 a orp,'an~ieskimi ~,,oyo~iineniyami~ I,
2 4 1
:nvestif,,ation of tne Conditicna for the Reaction of N 20A
With B nzaldoximei Combinatior. of the PrDd,icts and tne
Reaction Eq'iation (I.Izlichenive u3loviy rfakt!~-.i 0 a
Ler--ii'doksimom, nostriv prod,;k-tov i r',i t 4, 1 i
~EPTO'_',CAL: Zn,;rT.!i1 obshchey khimii, 1958, Vol.28, ',or 6,
p;. 296, - 25o2 (USSR)
A~3ST.",ACT Invest ioated were the influence of the no'.;-.r r~itio,
tne concentr.tion, the method oil mixinr the reao~ents, arid
t~,e nature of thi! solvent upon the course of the reaction
between 11 20 and benzaldoxime under cooling with ie.
~Jll
In conolle. theoe fiactors the hign~st pher..71dinitro-
metnane yiell obtT,ined was 43c") of the theoretical yield.
All the combinations of the products of the reaction between
I 1 0 '.tn(l tenzal3oximp which form under v~iriou3 con1itions
2 4
ws~r- determined jual.,tutively anii quantit~it~.vely. It was

Reri-tior..,; of 11 2 0 With Orj~,anic Conprj,~,ndo. 307j"79-2f~-8-64/66
of tti#~ Con'lltions f',r tho hoaction of 0 With Berzi,'-
doxi-.im; Co,7t.J?.~ttion of the Prodiict.,3 anti the Reaction E ,i--i~jtion
f )ur'.1 tl.,.t nitr.,t~on. i~~ ,~~r.)J,~ced in th;r reartion. Equations
which indic,ite the formation of phenyldi-
and benzaldehyde ~,; the reacton of N 0
,m 2tj
with the salt of benz-al',14oxime. The ;xper "e ti , I
rejulto ar,-~ giver. in 1, ind t~~(, fol lo-ring conclisions
can be ~ir-iwn from them: with ibc-,it a ' : ' r-itio of N 2 0 4
to tei;z~ildehyd(- In tne so , vort only phe,.yllinitror-nethane
InA benzaldehyde are for7ne,J; a 0,5:1 r-.*Iio of these
re,'1,7ents in the solvent the main prol%ct is ~,..-diph~,nyl
I I , fj , Q r **
o x% n ( , ~ 7' ~ , - r, i I ~ amounts of llir.itromethane
an~ ber~zrildeny'le alao form. By c~-,rrying out the
rea-ticr witnoat novent t,%p :ildehyde is r--10d almost
i,,i n t i t a t ivol y Fi tru rc, o ' nd 2 t,.,2 dep-ndence
o' d o f I ~ n i t romo t h~.,n e u pon t ne f,,. -- r s i r~ 1 : c,~i t e,1
f~ r e T,, -o~ a r f r,~ s , 2 t 3 rA ro -, 7 e "l f
S(,V:et.

/19
Decomposition Reactions of N 0 With Organic Compounds. SOV
I. Investigation of the Conditions for the Reaction of N 0 With Berzal-
H 2
doximel Ccibination of the Products and the eaction Equ:,tion
ASSOCIATION: Institut organicheckoy khimii Akademil nauk 353R (Instit,;te
of Organic Chemistry)AS USSR)
SUBMITTED; December 51, 1957
Card 5/5

A7TTIORS: Khmellnitakiy, L. I., Novikov. a. S.,
Lebedev, 0. V.
TITLED The Decompoadion Reactions of Nitroi~en Dioxide Wt- Or.-anic
Compounds (Vzaimodeystviye N 204 a orranir-eskimi
11. T-e Reaction of IN 204With Aci-Phenylnitromet%a.~.e and Its
Salts (11. Reaktsiya N 204 a atsi-feniln,.trometanom i yego sol'yu)'
PERIODICAL: Zhurnal obshchey khimii, 19~8, Vol. 26, Nr 8,
pp. 23o3 - 23o4 (USSR)
ABSTRACT: In the course of investigations on the decomposition reaction
between nitrogen dioxide and benzaldoxime and its salts,
which leads to the for-nation of phenyldinitromethane, the
authors found it necessary to study more closely the reaction
between N 204 and aci-phenylnitromethane and its salts. In the
literature the otatement is made without further data that
"the aci form of pheny1nitromethane enters into rcaction
especially easily with nitrogen dioxide" (Ref 1). The ex-
periments of the authors showed that, analogous to other
Card aliphatic-aromatic compounds (Ref 1). the'reaction of N 2 04

The Decomposition Reactions of Nitrogen Dioxide With SOY/79-26-8-65/66
Organic Compour,da. 11. The Reaction of 11204 With Aci-Phenylnitromethane
and Its Salts
with aci-phenylnitromet-ane and its salt produces the expected
~henyldinitromethane;
N2 04 C '1 204
C H6H5CH - NO011a - 6H 5CH (NO 2)2< C6H 5CH - NOOH
The maximum yield of phenyldinitromet'nane was 41,551 based
on the aci-phenylnitromethar,.e, and 28%. based on the salt.
The rea,~tion went in solution, and although it resembl,~d
externally the reaction between nitrogen dioxide and uerizal-
doxime and its salts, it required much less heating tnan
thic reaction. The results and the conditions of the ex-
periment with aci-phenylnitromethane are indicated in table 1,
while those for the sodium salt of phenylnitrometnane are
given in table 2. There are 2 tables and 2 references,
which are Soviet.
ASSOCIATION: Inst4tut organicheskoy khimii Akademii nauk SSSR 'Institute
Card 213 of Orl-,anic Chemistry)As USS11)

The Decomposition Reactions of Nitrogen Dioxide With SOV/79-28-8-65,'66
Organic Compounds. II. The deaction of N 204 With Aci-Fhenylnltrozetlane
and Its Saltu
SUBMITTED: December 31, 1957
Card 3/3

NOVIKOV, S.S.;LZBZDEV, 0.V.;KfDGWL11;ITSKIY, L.I.;TEGOROV. Tu.P.
InterFtctiono if V204 with organic compoundR. Part ): Interaction
Of N202 with salts of aliphatic nitro compounds. Zhur. ob.khm 28
no. 6:2)05-2)07 Ag 158. (1412A 11-10)
1. Institut ordanictieskoy khImii Ab SSSR.
(Sitro compounds)
(bitrogen oxides)

SHUTK121, IT.I.; KrFACHY.V, Xh.M.; ummov, s.s.; KOPoNcv, r.F.; GvWim, r.L.
Reforming straight-run gasollneo by low-tompernture dehydrogenAtion
on plAtinized chnrconl. Zhur.priklAhim. 31 no.11:1732-1738 H 158.
(MITLA 12:2)
(GRsoline)

SHUTM, F.I.; MIRI.ACHEV. Di.14.-, GARANTN, I.L.; NOVIKOV, S.S.; MITONOV, H-F-
Production of toluenn concentratoB from petroleum fractions by low-
temperature dehydrogenation on plntinnted chnrcoal. Zhur.prikl.khim.
31 no.11:1765-1?67 N '58. (MIRA 12:2)
(Toluene) (Petroleum products)
(Dehydrogennt i on)

AUTHORS: Novikov, S. S., Korsakova, I. S., 20-118-5-29/59
Taiskovskaya, 2. A.
TITLE: On the Reaction of the Addition of Nitroalkanes to
Benzalacetone (0 reaktaii prisoyedirieniya nitroalkanov k
benz&llatsetonu)
PERIODICAL: Doklady Akademii Nauk SSSR, 1958, Vol. 11-~, 11r 5, pp. 954-956
(USSR)
ABSTRACT: The authors give a bibliography Foint~ back to 1916 and state
that nitroulkanes are ndded to a, 0-unsat,trated ketones in
presence of basic catalysts and natriumethylate preferences
1-3). Yet this reaction was not investigated in dependence
on the number and on the position of the nitro 1~7roups in
the nitroalkanes, which in done in the present paper. By
interaction of nitroethane and benzalacetone (catalyst:
alcoholic solution of ethoxy trim-ethylphenyl-ammonium) a
small yield of 2-nitro-5-phenylpentanone-rl was obtained.
1,1-dinitroethane reacts much more eaoily and shows better
yields of 2,2-dinitro-3-phenylhexanone-,. A much more acid
Card 1,2 nitroalkane-trinitromethane adds still more actively to

On the Reaction of the Addition of Nitroalkanes to 20-U8-5-29/59
Benzalacetone
benzalacetone and forms without catalysts 1,1,1-trinitro-2-
-phenylpentanone-4 with a good yield (Do%). Dinitromethane
is easily added to benzalacetone in presence of catalysts
and forms 1,1-dinitro-2-phenylpentanone-4 without yielding
an addition product of dinitromethane to 2 molecules of
benzalacetone, as is the case as a consequence of several
other reactions of dinitromethane (reference 4). This is
followed by an experimetnal part with the usual data. There
are 7 references, 2 of which are Soviet.
PRESENTED: October 26, 1957, by B. A. Kazanskiy, 'Ilember of the Academy
SUBMITTED: October 11, 1957
Card 2/2

5(3)
A U T H OR 3 Bel I chev, F. V. , Snuy~in,
Novil,ov, S. 113.
TITIE. Catalytic Synthesis of A]
Catalysts Under 1-n,!-reased
alifatichoskikh tr,-i_,nc)v nA
pri povyshenno,,n davlenii)
i ph,it .'c ~minoi- Cv-- '.fixed Oxi
i-q-tiuro ("'Italiticheskiy _4nte-
,nnshn,:ny~-Ii ol'.ianvkh kataliz-, :.,~!,h
XER107'ICAL: Izvestiya Akademii nau~~ ',~'SR. tdeloniye khimichoski'-h na,~ik,
1959, Nr 4, PP 710-714 (U3SR)
A13"TRACT The experimental results found in the :--rez;ent work --how that
a considerable yield of amires Cain I e 31 tained by u sci ?-It if -
ically founded selection q,-' catqlysto conditions of
aminating alcohols. Thc rel~ttiva ictivity of the fill.)-~vin,;
catalysts was investi-itel. p-ar- alu-iinum oxide (65 + for-
rous oxide (15 10'), aluminum r~xide (9~ + titaniu,-,l oxile (5
aluminum oxide (90 "') + maEnenium, oxidp (10 ,) and industrially
produced aluminum silicate. The %lcoholc were twice distilled
before the investigation uis carried out. Their properties
were in good a~-rcement wiA described in technical pub-
lications (Refs 4-6). The expe-.imerts carried out in a
Card 1/3 continuous flow an-paratus ~'FiC). The ~,xperimental results

I - I ~ - . I 'ier WI xed Z - -4 -2 3/4, 2
n, C-i t 1 2 I'ndoi Incremsed P re s su re
nhown in t%1-1(-:- 1 , -- , --. n J Thf, o t i 7 u-i conditior~:
t he cat-il--tir. aminition of r-but ir,,-)l Jetcr!~ined or. n
alumirnm-titanium cat -il y,-t v.-hi -.. th,7 hi,-hent -kct, v 1 t v
-tmmoni~~ , rennu-rc G.~, re-ct. )n rate , .3, ".- -inli
3700. .1 further 1)r- - 0 the amille L, i Ol ! ,
i.r,)bibly b,~c ~usc of t~- c -,r. !,,? n:-.;,. tn - f a.1-1 On i,--. lln I C r t lie
con,litionn asnu-net.. Ath c:it,l-,,t-i- -minqti,-~n of alcohol~-
~as formLtion is obocrv,~('. , pr-'-.il~ly r" th~- clover
)f alc~ol decwn, :f t::,- exec-els
t',~,, opti-Tium vilue the f r-at~-,n i. Ind 1-mino
r !uce,'. 't :stops u,)on
1,!V-;,lti,,,n from, the o,)Limum j -i n d
, e t~i,., -,Icc)hol
IM17ori,'! V,I)or:,, ovor thf, c,t 'y,t. c-m,-rol t,~ purp
nltmirw-m oxido, almoot ,Il -:xf,! c~t 1.,~: ., .1
(Triblen , -!-,! 3 ' - ~'.' ; - r t !,,, c --, ~ i o n um ed 0 ma 11
t i t i e a o f un s a t u r- hy I r- : F :-~ors, paraffin
-itrille.- f~--r-iet', in addition
.-dnPr, ~r .-.11 c- ~nv rti ~rc,,ertio3
or tl~c oc,.-II-A:~'! Ut -f ~ir-: -howr in
a r,

at -1 .-ti c n t .,~ :-
o i !-, t ir. ve r M i xed
Under Increased Pressure
tablc ;. 7~irro ----r -, I fi-rz-2, ' r-'crer.?eO,
-)f --;hick,. -re Sovi,~t.
A ~j C I T T
-usska,,a sel ya aka
cultural Tr:7titiit or-mic~ierl-oy 1,11i'mii i-7.
~ I - U
Zclinsko-o le -ii niu~,. 0,= (I,1--t itutc of
(I - % I
'hemistry i-meni N. D. -.i,1ins'-iy of th,: --f
- .3'1 )
J,tl,, 12, 1957
Car,i 313

SCV,'6, - - 9- 5 /40
A U ~'R S Y~rshova, L. V., Gogitidze, V. N., Belikov, V. M., Novikov, S.S*
E: -'reparation -~f Gem-dinit roLaraff ins '0 poluchenii gem-
..nitroparailf.ov,
'ER10:):CAL: 1--ves-viya "-idemii naulk SSS%. Ctdeleniyp khimicheskikh nauk,
/U3W
Nr 5, PP 94,
A3STRACT: For the invostiCation of the inf 1~,ience exercised by the carbon
f-
.hair. in the gem-dinitro-comiDcrinis uFor, their physical proper-
t,es tre i-,omclogous series of gem-dinitrc-oompounds was
,gyrth etized. Fcr this purFose the a.Ky! acetoacetic eaters were
nitrated. This method was applied f7)r the fir3t time by G. Chan-
cel (Ref 1). It reniers it Toss`ble to extend the carbon chain
in stages, _J.e. t~.e initia' pro-iuct is extended each time by
one carbon atom. in the course ~~` tno~ -.-,,~sent investigation,
series of gem-dinitro~ araff.%.9 frDm I,'-dinitropropane to
I-Jini trodpcane -.,,,as in this chtained. Of the synthetized
compounds, the molar rf~fracti~n 3f tn.? d4-4
-itromethyl group
wa s ~i P
termined (Table 1~. Moreover, the ph'~sical constants
M'.1 hoiling points determir-.-_~ 'TRIt'lo 2). There are
C a 2 tables and 6) refc~rene~,~,s, ' -z" is Scviet.

C
Prepaxa,ti on G em - ii n 4 t ropara, f f i rs
A3SOC:.~ ~l ON :1!3titut orCllnich,,13~,-Y im- N. D. Zrlinsko6o Akad~lmii nuuk
SSSR (In5t i I'll to Of Cr#,!in4c
Acal,am.-,- of USSR' N Z? - 3k f
r
C

5 (3)
AUTHORS: Novikov, S. S.~ bVlikt'V V
TITLE: InvestiCation in tl,e Fiell Df NitrDrpyii~,Ics
v oblasti nitropirroiov). Communication 1. New SynthesiE;
Methods of the Pyrro"a Rine \SonbshchHniye I . lovyy met-1
sinteza pirrollnogo tsiklq~
PERIODICAL: Izveatiya Akademii nank SSSR. Otdc-leniye khimickieakik~ nauk,
9 -,), i
Nr 6, pp 1098 - 110
ABSTRACT Tr continuation uf a previ(~us pap(-r (RPf Jr, which the ~n-
den3ation of nitroacetic arid f-ster witl~ ald,~hydes was invest,.
6ated, this paper deals with the reaction of a,Pj-trinitr-,,-r-
plone aldehyde with formalin and nothylamine. Tot,~ether wit',
Ylannich's oase a couipauna with the meltine point of 170- was
found, to which accordinr, tc) its ultimate analysis and
chemical properties the chemical structure of 1 -1,1ethYl
dinitropyrrole was aacribed. The roaction acheme is given. For
the parpuse cf provinC it, the splittinC-cff ,f tLe mpthyl-
amino group in the cyclization was iriv~-sti~~ate(i in ~Jrder t,~
st! rve whi ct~ hy,! r~)g~,-n at om r(!Mll i TI B i 'I tL(' T- I '~,- . V 1 th '~ t I k- 111 IT-
I T1 - 3 t I I C' I. o Is s " as ~" i Ii; I ~e t itl ". It!*, wo(- ri t?. e t ;q 0 r
lard 1
I

Investigation if. tho Fi~,ld of 4itr(ipjrrul(-,3. 'I
Communication 1 New gyrithesis Mathcds of tho
llyrrole Hing
C Il "'q C 11
iE P E3 " (01);')' \\
Ej / CH
IIII IIN- H
R
I was ab8 e rved tha t1 rol t~ ~ t-,-A un t' yti-i am i i, j; rs c.,n,
me tty 1 d i n i t ropyr :- ~- 1 ~~ was ~ilway a ob t ai ii e i. in 6ono r~i I i t c oil ~ d
be determined that it is alwuys the m~)re basic methylamine tf,'At-
remains in the rin6- Th.~- methylamno (,croup may also
with the methylaimin.?. The i ~actJor. .f methylimide with -Ahyl-
amino and CH20 yiuld~-,d covup,irativc., ju-intiti4.,3 of mvthj;- an~'
etl,yld.initrcpjrrole. In t'%E! c3urse :,f firther at Was
possible ro ayr.Lhu-ize qiJ.-'i*r)pyr,-.l-l,~ fro7i d;&lka~,i
aalts of the trinitr,,p.-Dpiorie aldahyi(-~ by ~aesinj, over tlh;~
methylimide stage. Bj :,reans of t!.ls new mpt!,,)-! cf synthotiaa:-t;
dir.itropy-rcil-r-a alsc, '~.- pr-j~ -siy
Card 2/~ll Gild bu producpd. J.-i t~~ ex- f

Investigation in the Fir,,ll of N."tr,)pyrroluB. S -,V
Communication 1. New Syntheeis Methods uf thu
Pyrrole Ring
the different substances is descril-ed 4n detail. Ther-j a.-
refcrenc,~s, I uf which iq
ASSOCIATION: Institut oreanicheskoy klAi!iiii ii:,. N. D. 2A.Iinq~~)C;o
nauk SSSIO(Instl tute of' Cr(,ariic, Chomistry ir-~iori N. D.
Zelinakiy of the Academy of Sciences, ~TSSR'
3UBMITTED: Septem~er 30, 1 ),r'.
Card 3/3

50)
EMORSr Safonova, E. F., Belilkci, V. U., 14ovikov, S. S. 307/62-59-6-30/36
TITLE: Some Reactions of the Nitropyrrolles WiLh tl7e
Mobility of tile 14-H Bond (Nekc,-tDryye renktsii nitropirrolov,
s,rjazannyye s pedvizzlmost'yu svyazi 11~-H)
PERIODICJLL: Izvestiya Akademii nauk 333R. 0-tdelerdye khiml-heskikh nauk.,
1959, Nr 6, PP 1130 - 1132 CU3311'
110TRICT t In a previous paper by V.e nuthors (Ref 1) it wa.,3 found th?-.t the
ni-Lropyrroleg, which do not have Pi 3ubstituent cn the hydroten,
are acids, ard that their acadity del-ends -:~n the nitro groups bound
to the pyrrole ring. (2-rd'tropyrrole weakly aoid, 2,4-nitropyrrole
stronger ac;.d, ~!jid 2,5-i~-.tropyrrolctacid). if, as is ftsc=-ed, the
chemical a-,t4Vity Cf the rdtrupyrrole3 Is connected with the
mobility of the hydrobc%, atorrs ii. ttds c;cmpr,,jhd, the change in
ch;-mical activi'V ~,mst depend 0,,the 1433o,-intion constarts of the
nitropyrrole3. In oider *o prDve tid.3, the formation of sAlts, tho~
cyano- ethyl ati or., nnd the methjlatior. :1 the pyrroles menticned
was investigated, It nas sl,)Arn thoit ail three nitropyrroles form
stable sodium salts, while the &~U,Ord= SPtlt3 are Un3table. The
hydracine salt of 2-nitro,-yrrol,~ nct ba produced, "he other
Card 1/3 t--vo PYrroles formed n)r-7-k1 hylr~,,,!Iiae rt!~s. Yhen put into clilutc3d

SO-1162- 5ri- ~-30i36
Some Reactions of the Nitropyrroloo '-. :!,! W, ". ";!~,
Robility of the N-11 Bond
sulphuric actid &11 salts sere again decomposed ii-to the initial
products. Tith the cy&noethylaVor -it shcwed that the more acid the
nitropy,prole, the muro tcid & ~Atslyst had tc be ,used for the
retotion, (Cathly3t.,3 IL thi, cxler of tLe rdtropyrroles mentioned;
CE3CN a, CH 3cay., cli 3GCOH)~ Lothylatior; of the 2,5-din-itropyrrole
by diTnethylsulphate o-,--urred iei3 rea4lily trpu. with the -.-Wo other
pyrroles. The N-H b~;nd in dej,,~,ridr-x.ce on its molility, is
m-ble to r--&~,t in the PLfornmerti.--ued i's also resporsible
for the motioyi of the hydr(-,gc.-,, atcms of t-a metlyl gr(rup, of the
t1cohols, or of t'-,e ca.--bcxyl,'L-- acid. Me -.ha.-tc cr of the atom to
which the hydroger, 4.9 lo-and is of m-injr iriport,*Aice. In the
exTerimental part the synt.-,eses of tl-e differei.L end of the
cyanoethylated and metilylatlel 1-~miour-13 of t:~e nitrcpyrroles
mentioned are described !.% detail. For some of the ccmpcunds
syrithetized, the bftcteric-stati-, sctivi,.y was deteimined in theVI&WI
(Vsesoyuzuyy nauchno-~' ssledovatel 'ski y k-iiirail~-o-farl-.atsev-tiche-.3kiy
institut imeni OrdzLonikilze (Ul-Union
Scientific Research Distitute imerA Ordzhoi-i~-idzeD by Professor
Card 2./3 N. G, Persbi-n to whorn the, aiither-3 therefore exTress their Cratitude.

Some Reactiow of the Vitropyrroler Assof,'-cV-;r--d Wit', --o SOV/62-59-6-30/36
Mobility of the N-11 Bond
There are 2 Soviet references.
ASSOCIATICN: Institut organicheskoy khimii ini. N. D. Zelinskop Akpdemii nauk
33SR (Institute of Organic Chemistry imeni N. D. Zelinskiy of
the Academy of Sciences, USSR)
SUBMITTED: December 89 1958
Cexd 3/3

AMuRS S a fono,ia BF~ I i~-.ov, 'I. V v
T IT I,z,: An Investi.-ition ef ,:v,%ije v ob',-t.,;fi nitro-
=olov) . Co-r,~~unic~it ion - - ~C~
shch,-ni e 2 5ir~t-z t~,rjk!, nitr-, 1,
y
P LR I I C.L 1, 1 z V'- 3 t i., a dt- i i 2 e 1~
I ) 5~) N r 7, 1 5 c)
A BST -',A C T I n a 1) r c c t! c: nC :1. r a f, r i t f t h o f I -, u 1, 3 11
N - 2 L t hj 1 - 3 , - (I i n i t r a - r r o :i j, the i~thors hy a
new ~.iothod of synthesis. Tl~,, t~Jl!~
vas not -)ossible. T~.-refore, su.,, cl.,,cr i,.d
vy i t h o r Y., i t h o u t N - s a ~~ s t i t a t !i T# i- 9 , i. f. n r C
cal 4aalitirs arid !-,,;)uct:u T :iQ thse
f the sub8tarcut3 '... trio abovc ni:,c.! --i or. In t1., t i')Iv t~"e
uata of all nitropyrrols tre d 'J.1ich i!-(, describ,,d in
other publications (Refs 1-4) - '.o--.e :., th,-'s of "i, snthesio of
nitro-pjrrols, ithich nre ~escr~.b, d in pa')1 :c,itions ar, inu'icatcd
(Hefs 3,5,2). Li'r-e the schei,c-
Ca:d '2

An Inv~~-.i ~ti
Cci
jo...e ~JitjI8-:yrr(-1s
2 ard (Tic,
H
0
-l.'.
P t
zrl t
c
'1q t i on, r,:, i
i e:. t
CH
e~'l c r i "I let I
1 -2 S t
ASSC~IATI07;: If,;tit It 'j,
t
2 J M. IT. Se. + r 107,7
'Urd 2, /2

50), 5(4) sov, 0-5)-,- 16/42
AUTHORS Novikov., S. 5.. ,Belikov, V. M., Yegorov, Yu. F., Safonova, E.H.,
Semenov, L. V.
TI'~LE: Investigations in the Field of Nitropyrroles. Communication 3.
Ultra-violet Absorption Spectra and Tautomeric Transformations
of Some Nitropyrroles
PEPIODICAL: Izvestiya Akader-,ii nauk SSSR. ,)tde.eniye khimicheskikh nauk,
1959, rTr 8, pp 1438-1444 (USSR)
ABSTRACT: In the present paper the ultra-violet 9,,ectra of 8 nitro-
pyrroles are investigated. Th6 banis of the various compoind8
are given in table 1 and shown in the figures. The spectra
were interpreted as inJicatizi, that the pooition of the
NO2 group in the pyrrole nucleus can be determined by means
of the ultra-violet spectrum. The already supposed structure
of 1-methyl-3,4-dinitropyrrole ~Ref 1) could be proved. The
tautoneric phenomena were investigated in a series of deri-
vatives not substitutod at the nitrogen of nitropyrrole and
it could be shown that tho acidity of these compounds increases
with the increasing number of nitro groups. The eame effect
could be observed by reirouping the nitro t,-roup from position
Card 0 into a. This phenomenon was conoidared an inductive effect

SOV/
Investigations in the Field of Nitropyrroles. Communication 5. Ultra-violet
Absc:~ption Spectra and Tautomeric Transformations of So7:ie NitroparrrolC3
Df the nitro grokip on the polarization of the N-11 bond.
There are 0 figure3, ; table, and " references, 6 of which
are Soviet.
ASSOC IAT 1011 Institut organicheskoy khimii im. N. D 17elin3kzgo Akademil
nauk SSSR
(Institute of Organic Chemistry imeni 1. D. Zelinakiy of
the Academy of Sciences, USSR)
SUBMITTED: Novembor .30, 1957
bard 212

5~3) SOV/62-59-8-23142
AUTHORS: Novikov, S. S., Korsakova, 1. S., Babiyevskiy, K. K.
TITLE: Addition of 1,1-Dinitroothane to 1-Nitroalkene-l
PEhIODICAL: Izvestiya Akademii nauk SSSR. OtdelQniye khimicheskikn nauk,
1959, Nr 8, pp 1480-1-181 (UL'SFI)
kB")'TRACTi Here the addition of dinitroalkane with a mobile If-atom to
nitroalkenes io investigated. An addition of sinilar kind has not
yet been described. The initial materials were 1-nitropropene-1,
-butene-1 , and -pentene-1 . The addition was carried out in methyl
alcohol + 10% 1120. The re%otion took place quickly at 600 in the
presence of small quantities of sodium acetate. The following
mechanism is given: 11C2 R
\ I
R-CH=CHIM + CH C If ( lio 'H I
X-1-CH-CH 110
2 3- 2)2 1 2 2
N02
R - 11, CHY C 11 51 n.-C 5H7
Card 1/2

Addition of' 1 1-Dinitroethane to 1-Nitroalkene-1 3~. v/62-5 9-[J-2 11/1f2
In the addition of 1 , 1-dinitroethane to ri-itroe tl,ylene
ramifications may form which are caused by the polymers of the
latter forming during the reaction. The addition reactions are
described in detail in the experimental part. There are
7 references, 1. of w~icvi is Soviot.
AS.i(, C I AT 10 11: Institut organicheskoy khimii im. N. D. -,(!1insko,;~o Akaderiii nauk
SSSR (Institute of Organic Chemistry imen-, 11. D. Zelinskiy,
Academy of Sciences, U~-'SR)'
SUBMITTED: ~9, 1918
Card 2/2

5( 5)
AUTHORii !3hvekhgeymer, ~. A. , Pyatakov, :". 1'. 3CV/74-25-,,-o-/6
,'Liovikov, S. :3. (~IUSCOW)
TITLL: 6jnthesia and lleacti(,ns of Ali~hatic :,Ltroalcl~hcls
I
~Sintez i ruaktsii alif ati,:~ieskikh fItrc,,;iirtov)
PEalUDICALs Ujpok,,I khiL,li, Vul "', ;Ir 114, 1', 404-)1u kU;;jA)
A-BSTRAM I., this paper an attempt iu made to jumr.arizo tne data on the
chemiatry of' nitroalcohola published in the technical
literature. To begin with tf,L autlior rej~,rts on the
preparatlLn i:c:tL,Ab of nitroallcoi,cls. ~ne ~.ethod iTost
.h-ruughly invest-leated and %iost fre-,uentl~- used is the
,,.,iJLiiaatiur, of c--iuuridu with rAtroparaffins
(Aefa 1 - ~~q 41, 4~, 50). Loruover, nitrualck,*-Ij can be
u'jtained by the rcactio:, ~f silver aiL.L,ite .,ith !halide
hydri,ies (Refs 24, 45 - 45), !~y the effect of ritroE;en
oxides (Refa 46 - 60) and ENO 3 (Refs 45t 44) on olefins,
and frum C)(-oxides Olufs 61 - 65). ~;itrualcLI- *cla could be
obtiii,oc it, t-,v,, casL-fj in the -.itration Qf P-,LCLh(;1S
~Refs 66, 67), ctherwise, nitroalKanes are icr~;ied as ;Cain
Card 1/4 roaLL-un i.roducta. A ji'amloor of were ijyzit)4(.siz~i

Synthesis and Reactions of Aliphatic Nitrualcohols SOV/74-28-4-6/6
by the selective redution of the nitroc&rbonyl compounds
and the eaters of nitric acids (Refs 66, 69). Halide-
-nitroalcohols containing the halide at the carbon atom
connected with the nitro group can be reduced up to
nitroalcohols in the presence of palladium and pyridine
attached to barium sulphate (Refs 70, 71, 73). A great
number of 2-nitropropanedioles-1,3 sutatituted by the
p-nitrophenyl (Ref 75) or arylazo group (Ref 74) were
s,ynthenized in an acid medium by the decomposition of the
dioxant.s obtained from aldehydes or ketones and
corresponding 2-nitropropanedioles-1.3. The effect of
alkaline agents on trioles and dioles is also worth
mentioning (Refs 70, 75). In the second part of this survey
the author deals with the reactions of nitroalcohols.
Numerous papers are devoted to the methods of esterification
of nitroalcohols (Hefs 39, 40, 68, 76 - 116). lJoreover,
the preparation of acetals and ketals (Refs 83, 117 - 121),
the reaction with ammonia and &mines (Refs 122 - 133), the
reaction with aminea and formaldehydes (Refs 134 - 136),
the oxidation of the hydroxyl group into the carbonyl group
Card 2/4 (Refs 137 - 140), and the substitution of tvdroxyl by a

Sjnthesia an(' Reactions of Aiij,hatic I'litroalcohola 301' /74-28-4-6/6
chlorine atom (Refs 18, 22 - 24, 102, 108, 141, 142) are
described. Duden and Ponndurf discovered a spontaneous
dehydration of nitroalcohols (Ref 37) which wap later on
confirmed and investigated by other authors (Refs 15, 138,
143 - 163). So far ether cuuld not directly be obtained
from nitroalcohola. But there are some indirect methods which
were described in the papers 159 and 164 - 169. K- and
Na-salts of nitroalcohols are formed already during the
synthesis of nitroalcohols (Ref 41), moreover, with the
decomposition of glucoles by the effect of alkali
metal-alcoholates (Refs 70, 75, 130). Finally, they can be
obtained by the effect of alcoholates of alkali metals or
caustic lye on nitroalcohols (Refs 71, 172 - 17j). There
are no data in publicationa on the preparation of
C-halogen derivatives of nitroalcohols by a direct
substitution of the hydrogen atoms at the carbon atoms
by halogen. In all cases the effect of the corresponding
halogen on the sodium or jotassium salt of nitroalcohol is
used instead (Ref8 70, 75, 139, 171, 173, 176, 177).
Loreover, the reactions with aromatic aldehydes (Rei 178),
Card 3/4 the decomposition of 2-nitro-2-methylolpropanediol-1,3,

Jynthesio and Reactions of Ali~hntic Nitruaicuhols 50-1/74 -26 -4 -6/6
nitroglycols and nitroalcohols (Refs 37, 40, 70, 72, 759
130, 171, 177, 179), the effect of phenyl diazonium
chloride (Refs 175, 176)' and the reduction of nitroalcohols
(Refs 51, 58, 70, 123, 166, 180 - '90) are described. In
conclusion, 3 reactiuns are mentionedi 1) The synthesis
of 3,5-dinitrooctane by the interaction of nitrobutane
mith 2-nitrcbutanul-1 in the presence of (C2 115)2 NH in
CHCI and after removal of water (Ref 191). 2) Only one
case is known of C-alkylatiun of nitrottcohols. In 1924.,
2-nitro-"I-chloropropanol was synthesized by *%,he reaction
C113J -iith the Na-salt of 2-nitro-2-zhloroethanol in
boiling methanol (Ref 148). 3)' It was shown in reference
192 that the K-salt of dinitroothanol combines with
acrylate and eaters of the r, r -dinitro-i-oxyvalerieLnio
acid are formed. The enclosed table shows the properties
of some aliphatic nitroalcohols. There are I table and 309
references, 7 of which are Soviet.
Card 4/4

AMORS: Novikovq S. S., Lebedev, 0. V.,
Khmellnftakly-, L. I., Yegorov, Yu. F.
TITLE: Decomposition Reactions of Nitrogen Dioxide and Organic
Compounds (Vzaimodeystviye N 204 3 organicheskimi soyedineniyami)
III. Decomposition Reaction Of N20 Witt Sa-ts of t~-'E'
Aliphatic Nitro Compounds (III. 7zaimodiystviye N 0, s
solyami alifaticheskikh nitronoyedineniy) 2
PERIODICAL; Zhurnal obghchey khimii, 1958, Vol. 28, Nr 8,
pp. 23o5 - 23o7 (USSR)
A.BSTRACT: In contrast to the reactions of the aromatic oximes and
the arylnitromethane salts with N 20 producing dinitro
compounds, the reaction of the alipiatic oximes with nitrogen
dioxide produces nitrosonitro compounds. Thus, for example,
acetoxin and N 204 react to form propylpseudonitrole (Ref 3)
(CH3)2 C(90)(1102). Analogous to the course of the reaction
between the oximeo and the nitro compounds of tho aromatic
series, it is to be expected that the aliphatic series would
react in the same way, i.e. tbat t*,e salts of the aliphatic
Card 1/3 nitro compounda must react with 11 204 to give nitrosonitro

Decomposition Reactions of Nitrogen Dioxile and Organic S()V/"t9-2a-a-66/66
Compounds. III. Decomposition Reaction of N 204 Vith Salts of the Aliphatic
Nitro Compounds
compounds. In the work reported in this paper this hypothesis
wan tested uDing the alkali salta of the following compounds:
2-nitroprop,ane; ethylnitroacetate; and 1,1-dinitroethane.
T!-'us propylpseudonitrile was obtained by the reaction between
the sodium salt of -nitropropine and 11 0 (reaction diagram 4).
In the reaction of the sodium salt of nitioacetate with
11 0 the ethyl ester of nitroozimeacetic acid was formed
(~ijgram 2). In the reaction between the potassium salt of
1,1-dinitroethane and 11 04 ethylnitrolic acid was produced;
in this reaction a labiie intermediate product, a nitroso
compound, formed (Diagram 3). Contrary to expectation, only
the nitromalonic acid ester separated out quantitatively
in the reaction be*ween 11 0 and the POtaSSiUM Salt 3f
-lysis -showed that t~,is
nitromalonic acid ester ~pictral an,
anomaly resulted from the fact that the potassiui formed the
salt not at the nitro group, but at the carbonyl group. There
Card 213 are 4 references, ~ of which is Soviet.

Decomposition Reactions of Nitrogen Dioxide and Or~-anic 507/79-28-6-',,~, 66
Compounds. III. Decomponition Rea.ction of 1420 1With Salts of the Aliphatic
Nitro Compounds
ASSOCIATION: Institut organicheskoj khimii Akalemll nauk SSSR (In3titute
of Organic Chemistry,AS USSR)
SUBMITTED: December 51, 1957
C ar d 3, 3

5 ( 3
AT'. -I I C) V
K, v
o
TIT L Z iri
:,q!: n oil F, I k: 7:. !~~e
:;e r i,,:a t- v r,7,i
e 1 r,
P~~ R I C,D I L Dolm I;i Iy
r j e
s,, e t rar. i tr c-
n e 'IeFilCO,
un o i r
1-f- da-~, I !itr iz.~er r 11 r ii ii LL.9 P s n c) 9:,,-
r r. c 'ne I r.-,,, ane i
rqif~,] 1~e f arl-vi L i On o l'it-, e t i un I 11A iu efl,(I(~t-
1) t ,i i i t t n,- - f o f ti i ro r t a t i n of L h
c C) a
E; e 0 n Le r e s , n or. t ~e L o: er i zat i ~)n
I' .etrnn r D Ellie
f
,C el
Carl 1 n t ic r,! w,icf, :3 r ;,i a j e

On an Inter e!- t im: -ii::e of za t ~ or, in S-ri j ~3 J t r E: t 7, - t C
Ni tro-,ompoun Is
in an aqueous alcohol solu t ion i t can no t be o f f ec t ed in non-
1 ol a r so lven tg) . Tn e ~,ield o t ~,.e ,vm--,et-ic I iammonium s a I t
w a a 4' O~. -'h i a 9a 1 t i:i t r an s f o rme I , 1,y c~,loride,
into t rx ,Otasjium salt, t~~e la *ter 1,ein,- event,ial I.,,- convert-
,7d into I, 5-dibromo- I, I, ~, 3-totrari t r,,: a n e t 1, e ; :j j or
under review, these comI:o1inJj :-ivo e,~n leocri ~o I f or t~,e
f irs t t ime . -he transf ormat ion of' I , I . I, tra:- i oi 1-0 ime
i ,
to t~,(~ OYMMO tri - j flol:~er is t rst -~o f,.r bserved case
wt an isomerizLit~ c r-.h in,-e of ~)l a 2itro
b in
s !tiirated aliphatic 'he i~t:,er cjnt~tins a
let:,iled rec_~T-,e for t;;e of
for the -re;,aration of the 9 -mmetric :,)tass4i::, oalt,
aa well as of' the 1,5-dij1r0r.:4,J(- )r the re ara t 4. on of
I tri n i *,ropi oi ane i- the rtise.,4,e of ii-lethylarine. 7here
jj I reference.
ASSOCIATION: InFititut :-ii im. D.
:~~3uk SSSR (.:;otitute of
Card 2,'1 the '%CLi'Jen
,'/ of Sciences, 7'S71C

2
A'JT "-:OR S i 1107ikov, 3. S., ',cdovikova, T. e--'24-4-29/67
TarrnmvnTy-, V. A.
TITLEi Synthesis of Orgpuicinarcu-7ir Cczl;~---ds 3:ntez
rtutlorganicheskiicr, n1l"ros:111,01-n-ar-
f~EKODICAL; Doklady Akademii riauk 35SR Vc. '-' N r 8 3.1-8 37
'U ~; SR
A-B STRACT i As is kncwn, many c, a.,.d inerganic ar:iis
FAre used for *-e ad : i t-, 0 n t o d c 111b e
and trlpie bo,,-,ds, etc.. The a-it,.or3 fc-r.j t,,at the ~rinitro-
methane mercury salt r,,4aui -./ zr -r;z-2~ 7i~- st- --crn~o,.;nds cf trie
aliphatic series whic- :7c7'a-i a atcm, as wr--'-.'
as those of the aromatic a-.d sltrie2. In *,.-.Is Process
I NO
substances with a c,mmor. -e4
-.91 2 3 ELre ~r- d,;- .
The authors studied this re:,ct-, ma1c:.:C, P-Cetoacetir- and
n1troacetic esters, with. a -~~ *, yF- 7 -1 A-,, L r. E , cy c '. o p 9 n ~ anc,,
b e nz ene , t o-' ue ne, ar. I 1~ I i i _7 n - I f,-iran and
Tat.e 1 contains ths,, .,--e-'di ana
4 analyses 64. 'he fira.' 7.,:
rv a:,,,

c s - E3 of Organcriercur~c Ili troGea
C ;L.- 1 ,
or. ',,,e actior o. r'. :E.,- r -m- 'ic~
and bromc- trini -. rc t r.a. - r. j M El T C
chlorides by cc e- a-q".-ed -:-e
mercur`zat'~cn `--ane me~- _ry 3 a- -
can exist as two interc~nvt~, fcrms, leperd~, ng
on the r, a t,,;r e of * J,. e j t L, r. 7 r. t ~~ -a a,,. t n c, 9
joint to the fact t h P. t r c.-?, j,,.? are fory
different in polar ana a .3.; 31- LJ RO f 2 ry a t a E
state, these -:UbStanCee are L a-
,;o ,-,e rea2 f
R - HgC, C.Irv 3e.-
,
2
voith nitro-berzene, r.-,-di - r & r.,~ a
o-nitro-ani3ole takea~ L r e r 71
subst~,nces synthes; zr-a z x a i T
z)-F a mercury salt molec I t~ of ~e res"q"~~
aromatic co=pcund. -K a-, 'n, ~-MT-~x '_9

destroyed ,;nder of i al'
compound, mErcur~- ox,.da a:-,' tri r me an
s a 1 t - T ~.,- t -. i n i t rc --m e a%t,
any
5 7. e t 5 r
v i th re s i e c t ', o th 7 1~ ~ f X

24
-y Organamercuric Ni ~rog-!r ~7 Xi.- ),-ci

or a
--ad

3,3.M 13
75 -C -7-- me7c-:-j
u m z r . e r -3 f r

-3,- n n e 31 z e'

r L r c - T. e a r, m,

a ~,3 c)

i r
r i n

vi 7- j

r a, i

j s t

f i - ~. r. , ; I r1 c:: , , , ~m;,
7
asymmetrical cnes er.ter -1- ac ording
the scheme menticned. T':q mer~,.ury salt cann-,-.
be added to clel in6 N, In i j cb, , t~, I ~ T-~,) ,
3-c-th,71 jenten,~-3,N e1h3t One 1~-iaterr
h,,drc -, c r. at om at t hc- 19 ~)-.d. T~.e:-e E~-.:-e ' ta"le-1 bind
re 1,1 i. rer ce s of wn- --h a:-& e
A SOC A T 10N s :nstitut crganic s 7, 1 e s,,. c !E Ax P-
na~~k SSSR ~, :ngtl ate -f
N. 1 e S
i H E SE:, T ED -q ,
21'! 1 ED