SCIENTIFIC ABSTRACT MALINOVSKIY, M.S. - MALINOVSKIY, N.N.

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• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

J S S R
and U
SbCfgi4fL Sk-'Ct 'P6 ObSlkkei KUM. 4S;,
,
1674~l
r( 19591
D
f
h
f
at~
w
p
)
j
ecoux
c
l o
et
e= ax
.~~
. quir
y
ff
3,40 at 400* and it rot. rate.66* of ra't vut.4-0ox Itr, to traL
X of c2talyit) of AcIr an
, ~Of its ethylene jfyc6tuetaf (Uytc - 0 cot
%aher With S-1ale C

ar
0 . Fr. c1 Lf, CHI% Cift c H Mee Er. 0 H, "ID .

F= 55% ffta~and;177* qkq!~,- arcmitki.a-nd 5aid

ke to Imercues yr. of,AcH ttad IE:and al-d'jpib~

and ECOM, Th-
ducts cipto=Idehyde, diount,
of I
------------
Mw~

ka I') I ter

vqj Oleft gxid-- IX Cnadensatlen.of oleffn oxide.-, with
-
Nf,dv
K
d N
M
it
li
t

-
-
ru
.
, i
, 0
.
n
r
rosy
al 1. m,. of").*'.'1;';rN;.7"'
V. 1-1. t
6
q jo.-I.1): ef i~~. A. 4.5 t,573i; 46, 0282g.-NOCl (frourt
nitrmy1sulturic aciff mid lNoCH wal p:med into W

-thylene oxide (1) in I wit. Ft-() truitil red colot 11 allaillf-f
c
the ructiort is run with lrt rijolijIg itit] itr(t-r ljr7. ;It f)*
the mixt. wits di,ld. (immediate dl~tn. )-tchiq ortiv vinreactc(l
trt.turbtls). There %~a5 obtainni IR ~. colorle-'s procilict.
dm 1.2179, a, C1C11,CH!0,-'--'O: with
hot NaOll it regcrrnte~ I mri Si,rrij,-jr reactrun
Ivith propylene oxide 117 g.1 Lw.-v I t i I: M'-C[[(O'V01cH'-
Cl, bro 101-2*. (it* 1.1214; ,:ih aq. KJCO' it gave "'fecfl-
(GH)CHjCl. Cyclohem!nO. oid,- (7 &.) gave 8 g. 1-chlor-
2-cyclohexyl nitrile, bT, 81 -3 '' Ik' 1 H68; with act KICOI it
gives cyclohexene chlaroln-drin, while lint NaOll gives
cyclohexene oxidr. Ppichh,mlivdi-in (7 g.) gas-C 9 F.
CICHICIA01VO)CHIC11 h,, '72 1', do J.;J-1.14; dit ' V '
KCO, yields CIC11,CH(OHIC11'ri. while NaMi ViOds
d
aches
epichhortihydrin, All the above products muluce hea
a er ation.

Chemical Abst.
Vol. 48 No. 5
i4ar. 10, 1-954
OrFanic Chemistry
ii=i.ov kil ~a.,IV.-R.
I glycVel. M. S. Ma inovskif anti M.
~Avftlr.'-~Ikv-v Forestr III-st. . . ur.. 3 chef Kht"t.
ca ing g ycitiol with ROlf in tile
presence of I % by wt. of IIIS04 gave exclusively ROCH,CII-
(OH) C11,01I (1), usually primary n-ales. gave best yields
(60-80%); primary iso-aics. gave 29-34%, secondary ales.
30-15%, anti tertiary al". only 3-4% yielfli after very long
reactions (np to 20 hrs.). PhCll,Ofl reacted poorly and
gave but 16-18% yields. The structure,.; of the I were
confirmed by synthesis from epichlorohydrin and RONa;
the yields were poor. For best results a 5-fold excess of
ROTI is used: decrease of the amount of flSO. lowers the
vield. I -b.P. fiTISI-AM--holyul;
Me MEWWR. 1.06-17; Pr. 2'-)1-4*,
LOA20; iso-Pr, 187-90-, 1.0063; Bit, 226-7*, I.OU5;
i,a-Ru, 216-1R', 1.06.56; HeX, 209-11', 1.076-1; Ant,
257-60*, 1.0(16.,3; iso-lin. 24P-50*, 1-0047; allyl, 209--10',
1 0,969; PhOl., 271-6*. 1.02013. G. AL Kosolannif /

(Haft oxides. gandett"llo" A
dA. Z. M. Milinovskill and Yomiseva
zMar. UOS""S rfism. zj,
-L-309M).-The caled. amt. of s. chilled alefin oxide was
to COCh In EtBr with cooling and- the mixt.
nd r, 0' dvernight; usually a small excess of
dAw C-O, Cf. It dealrable. The products of the reaction are caters
of CICO&H. Ethytette oxide and COCts gave 50% CICH3-
CHtOCOa. b. 153% (6 1,3760, propylene oxkfe 55% Cl-
CH*CHA(eOCVa. bm 08-70% du 1.1610. x W 1.44619; cy-
CIO';
too
his

pri~~!q
'
-tiw 1:J to I:Zr o nr a cawyst 7
oxide and lphl,1111
irt in of.
mixed Al,%-COs at 400* and 450' pvc a wide-bollinz
-ea, yzatew nor-
W hich on qulnafd!T~l I
~ W'T-A,
line
3- and 2;pheriApyrrole
,
,
HCIIjCHzOff, Ordy L-aces of inJoie wem fonned
'
-
Thw, Crz% favors - them fornuition: of. the qui:iqline-ring
-structure.- The beat ~icfds of the OR fraction. f-the cata-:
obtained at- 1:5 or 1.110
Cr,
0,/.Uo.;
zt mtios and 40V or 450', resp. - G, ml,-Xv-olapoff
h
i
e8 - V
e actid!,ne ser
Chg-iotherapoutic derivatives of t
'
Singli~ .......
2-W&0~6aciifte. Surjit Singh Ia4cV-11ahan
'
'(Council Sci. -Ind. Research, Punjab). J, S,-i. [nd Ft.
298-9(1051); d. ~ C.A_ 44-

--30* (from HOA
live $,2 ~PkNH) W1, COff (1), in - 22q c
L
Ct
75
f
i
n
_gavc
n6 (
j
7o o
)
- T
' C
1664^, (f
H
1r
a
EtOID
c-
m n
es M.
Gjrr.
.
6
o
iXQ cc: abs. ate. vras Vded 6.3 k. of O-CIC~ILCO~H
,
-inin, at U
the mitt. heated 15 '0*, 30 ce. lzo-;AmO~I (I
anct-0.1 c-powd. Cu wemwWa, thel%
teinp-was increased to 130-5',-tvaintalned 4 hrs., and the;
c"Ied mixt. dild, with water nnd stearn-distd, to removrl
III,- hot filtrattort of the residLIC 4rd Oddn. of dL-SICI
CH..Ci?ltr (IV), M. 200-39 (front 1J
RMg cloture o IV with POCf, gavc~ 11
0
4 gJ rt: uxe
.
.
4 bm -with 20 -ave 240
cc, 10% UCI g tc d p~ crearn-
1
.-colared- mIcranmd1ci frum. ILOAc, m. ~i
ve S_
of
9-4mitwacridine (V) gd. b,~vthe
ledliul(C.A 39 49M 'ell
G ~stlc plates
Cjc,- m W1 VIZ , in. 35L,3'~ (dc=rapn.)-
SWICS'Low that 11 Inhibits the growth of StaphylowaW.
*
'B
-
i
h
um b,
ader
v=#n, B and Profew X-19 t
aureas, It
,m1yp
coacps.-of 1:20
SWPt4ccaus hamolyticus and B. colf'w
0W
,
,
lat 1,40,0W, and Vibria a"Irroe at -1-.1.30,000. c
hibition of the gr6wth-of

B. shiga, Zf~
flemer, B lyp4osum, D, A, and
P;.-Oolmanai py"mcp. C ark3 A. burk4ard

r '-; dV
N f !SS7'~, fP.'t`.fs ko it.
zlizir,
Tor.-Crac3dnz RPh in the
presence of eth yleme oxide (I , 2-2: 1 ratios) at SW-5w, VMS
examd. accoriing to previously described ech i u
t '"I
PrPh, ho - BuPh, Iso-AmPh under these conditloo. YcId
Nteph and C.114, 'Arith evolution of 0'. CO, coj~ and olefins.
[so-PrPh yields only CjHs. The greatest extent of cracking
occurs with higher proportion of ethylene oxide (1: 1 or
0.8:1). The reaction o( cracking is considerably facilitated
'lit the prescrice of e1hytene oxide. G. M. Kosolaaaff-.,,,

KALINOVBKIY, H.S.; BAWOV. S.N.
%---
Thermal degradation of propylene oxide and its condensation with
&-onia over aluaiwim oxide. Ukr.khI=.zhur. 20 n0-1:37-63 '34.
(HLRA 7:3)
1. Llvovskiy gosudaretvannyy univergitat im. I.Iranko, kafedra
organichookoy khimii, L'vovskiy msdit9inekiy Institut.
(Propylene oxide) (Condensation produots (Chemistry))

jqaq

the ptesp-
4D
mer
.7:
a
jLdd ally:- ~bi
6~1~s th-
tau
VA

hcc
doll
emC 1 0 .
OX 6F IM L GUt
5-br"f ut
E 00
0
h
.
o
t O
wit
jt&,
the C&-a
UULM
sh9"
The
77
_z
7::

J,
b
-ofB- wom 71,
a
RM
8. Liallgovrkif and A
t
IM,
7-7 --is ggu&tW thak 'he reaction Mg with RX in pr me.
2U of
:-,of traviole
while the r0
ttAdiationlaamdical reaction,
milkals on frmd[a - of eofns. 15 catzb-
Me
e belnir -
RX was adde
red
Z4:2"
tedyvithultmviolet. e tion usually, cominen,
Ultraviolet illumination during the for mtion
-,j-bfRMgX red yields (Improvement c d
mp in 7a)
fgllr(lic/
C v, and phN
AUA the following vp lower idds- [so-PrMSBr
(6%~. PLOUCH29,Rr (0.47a); In
C.Hi as the:
FAvent With catalyLaisof the reaction by a little PhNUXe, the
~tbffowlng- ~fiowed decreased yields of Rfrcx when filufri-
'tlt uluuviolet.,
i~-o-Prlfgr- (ILI%). iza..s vcr
IL
10.1%), and Iso-AinNIZI (14,4%,), PftCHjN1gRr jmve,tht
iame~mufts [a both instance. The6c rrsults Indlc4te-the.
read
WtW !orrrmf-fon Ot R f9dicals whi i h MiX rad L--ah
~tjor the Primary halkles, and R radicals rtactinj with VgX,
V
ifor accomdarv R radicals. ' Tim reactions vim In gave
not only R, ~roducu but also RPh. which indicates the radi-
~:~cal nature of thd reiction. (isci-PrPh, ha-Buph, and
J~
L
AmPhware. scialted). 11fuminat, of.p~repd. R-%fg-X re-
r d. mbd. of sad. and L=&W- rascous hydrocarbo
ntl C It (I r494. for7ne-1 front Et md[cals, -pp.
on
-Ar ircaction also yielde& a ppt;, which: 6n treatment with IrtO
~gvertC,".,; the,quant.. results irdicatt- that illumination.
A O'wc d th t, concn. of EtMg- in thexIn. and mised tbat of
-EatzEr; 'the mictforr'of EttNfg: is'ofradLaA type involvin
A: decompLi. Into 1UNfr and , R ridicals, z then yield
RAfzX'am1 X mdicals~ the fatter reacting with R-2-Ug
yidd. R?4gX. BuMgBr did not yield gases under ulft7m-
tror
vialet Murruna Wheu,mbfts~ of RN1g)C and RX were
hem ~Was it slight
irradiated C 5-7%) apparent roductlamcf:
avallabl lc XWzX,: possibly thiougli formtIon of R,. M
it art amd Heck, C.A. 24, Mi. G, M. ~C
I m
G

d
,&n. properues of 2,3-digh% Xa&e!hymut=*.
:

nivq

Kfiinss. -Zk-4r., 2 240(10ZS).~Thm li~dfo=bous.
6MOI' W.
0. IV!
d Rlhii!i [Ber. 2)) -:xs havin'g flie formula,
aclt';btl jw6j,
Irml c ter ift TLe
"
r
- 9l
r
b
6
t~l
t, in. 119-20
hYdrWV2r[N)a
icVoz
.g
.
y
5 iodine itt arfainfAil 8
wit firs.at 235-40 rave2p
'
mrturi -P '
E,~mlertc st. s:~~
onc ofllu~, - bus, 151~2* the othix, rn~
'
Oxid;ttioa -',X 3. imb4tanms
wkft- K%fnO. -
indic;' ree;."X--
&ve yffl g M4 &uqc -itni~tum f,-r itt th
dilrj~Lctioj diog~attmulf the 3 substances shIIW -si"Ltr~
~_hmt differr
rerctlowa -
C :iltl C'etlit, Ir-
Ph BEM fAilikin and 1,yuhl&
,
Is ~CII s, "I is, tfi~jsc t,rdle
faid -War(
ill'-f. 'tive, Ow jarc,(!txt~ 111 19% and gr6ater,
of thsi ii(pild
(4 Iff-t et, 1-1. 521 31.

fi? X) Z
USSR/Organic Chemistry Synthetic Organic Chemistry, E-2
Abst Journal: Referat Zhur - Khimiya, No 11 19571 907
Author: Morgun, G. Ye., and Maiinovski~_, 111 3
Institution: Lvov University
Title: Condensation of the Oxides of Ethylene with Aniline over Lead Oxide
Original
Periodical: Nauk. zap. Llvivsk un-tu, 1955, Vol 34, No 41 llo-n4
Abstract; The condensation of ethylene oxide (I) with aniline (II) over PbO at
420-4400 yields quinolinic bases, the chief product being quinaldine,
bp 2470 (picrate, mp 191-1920; condensation product with C13 CCHO, mp
630; with C6H5CHO, mp 990), with small amounts of,4-methylqatnoline
(picrate, mp 186-1870); the formation of the latter compound the au-
thor explains by the isomerization of crotonaldehyde (formed from I
and CH CHO) to methacryllic aldehyde and condensation of the latter
with Il. The condensation of I with II over FeO does not yield 6-
membered heterocyclic compounds. FeO favors the formation of pyrrole
rings: phenylpyrrole is formed (III) (bp 271-2720, mp 1290 from
Card 1/2

USSR/Organic Chemistry - Synthetic Organic Chemistry, E-2
Abst Journal: Referat Zhur - Khimiya, No 1, 1957, 907
Abstract. alcohol)l its formation
I +ITFe 6H5N-(C2H4011)2
-~vc
N-phenylpyrrole--~III.
apparently proceeds by the mechanism:
-j~C6H5N(C2H4)20---,%C6H5N(CH = CH2)C2H5-
Card 2/2

ly -)n o e
"Investig; ti, h. il asibilil.y o' 'h-
-lu~rdnm F'luoridc--.il,,im'n,-Ci~l,:iuin Flouride System." ',!in Higher -du-
c-~tion USSR. Lenin-.,r-id Inst imeni 'I. I. KAlinin.
(Dissertition for th- D-avre- of ',ndid~L'c- in Te,~hni:!,l
SO: Knizhn;iLya Leto-As', No 1956

USSR/Organic Chemistry - Synthetic Organic Chemistry.. E-2
Abst Journal: Referat Zhur - Khimiya, No 19, 1956, 616c)6
Authort Malinovskiy,, M. S., Olifirenko, S. P.
Institution: None
Title; Cleavage of Diphenyl Antimony Chl de and Phenyl Ant:Lmony Diiodide
by Acid Chlorides and Alkyl Halidek-in the Presence of Aluminum
Chloride
Original
Periodical-: Zh. obshch. kh4mii, 1956, 26, No 1: 118-120
Abstract: It is shown that (C6H5)2SbCl (I) and C6H5 SbJ2 (11) form by the ac-
tion of acid chloride in the presence of AlCl 31 fatty-aromatic
ketones,, while by the action of alkyl halides under the same con-
ditions they form fatty-aromatic hydrozarbons. Increase in tem-
perature-lowers the yield of the reacti= products. Tbao have
been synthesized from I (listing the yield in %): C6H COCH31 52.3;
C6 COCH(CH3)2, (111), 63.7; C6H5COCH2CH(CH3)2, (TV), ~6-3;
CZH2CH2CH2CH31 44.7 and 68.5; C6H5C(CH3)31 (v), 46.1,.
Card 1/2

USSR/Organic Chemistry - Synthetic Organic Chemistry,, E~22
Abst Journalt Referat Zhur - f0himiya, No 19, 1956, 61606
Abstract: C6H5CH2CH2cH(CH3)2, (VI), 62.0. There have been synthesized from M
C05COC05, 75.5; ITI, 80.0; IV, 84.3; C6R5GH(CH3)2, 84.2; V, 77.8;
vi, 6o-3.
Card 2/2

- IIALINOVSKIY, H.S.; OLIFIMIKO, S.P.
Cleavage of tri-e-tolyl antimony and tri-te.-naphthyl antimony by
acid chlorides and alkyl halides in presence of aluminum chloride.
Zhur.ob.khim.26 no.q:1402-1405 HZ IJ6. (K[aA 9:9)
1.LIvovskiy gosudarstvannyy universitet.
(Antimony organic compounds) (Halides)

USSR/ Organic Chemistry - Synthetic organic chemistry
Abs Jour Referat Zhur - Khimiya, No 4, 1957, U794
Author Zemlyanskiy N.I., Malinovskiy M.S.
Synthesis of Acyl----I '-
Title Der vatives of OO-Dialkyl Thiophosphates
Orig Pub Zh. obshch. khimii, 1956, 26, No 6, 1677-1678
E-2
Abstract (C2H5 0)2 P(S)OCOR M are prepared by reacting (C2H50)2PSCl (II) with
Na-salts of carboxylic acids in alcohol (method.A) or with the free
acids in the presence of C H N. For I are listed R. yield in %, NP
in OC, method of synthesise 5 -
CH3, 29, 2, 64, A; Cl, 12, 0, 200
(decomposes), A; CC1 , 16.o, 200 (decomposes), A: XcH2, 14.6, 115,
A; C6H5 , 55.5, 11-114, dropwise addition of II to triple excess
C6H5 COONa in C6H6; p-N02C6H4I 13.1, 234-235, heating II with 50%
excess of acid and C5 H5N in C6H6; P-NH2C6H41 14.0, 148-150, an 10-
gously to the preceding; furyl, 4.0, decomposes intehlorobenzene vith
Card 1/2

USSR/ Organic Chemistry - Synthetic organic chemistry
Abs Jour : Referat Zhur - Kftimiya, No 4, 1957) U794
several drops of C5H5N. Mixture of 0.03 mole II and 0.03 mole
CH3COONa in 30 ml alcohol boiled 1 hour, I (R = CH3 ) recrystal-
lized from alcohol.
E-2
Card 2/2

K&LIKOVSXIY, K.S.: VVIVENSKIY, V.K.
Obtaining 01,~ -diethere of glycerin. Ulu. khim. zhur. 23 no-5:626-
628 '57. (MLRA 10:11)
1. LIvovekiy lesotekhnicheskiy institut.
(Ether) (Glycerol)

low-
L -j
of with ax-nonia, aminez. %!j:, ; other uitrogen
'leactions (1-1'.:A~ 10-8)
'Dijunds. Uop.kh-ii-. 26 -oo.,:RC,1-P23 Jl '57.
(ON-Ides'i ~ iii t?c 7en couipcUMS,

CZECHOSLOVAKIA / Physical Chemistryl Thermodynamics. B-8
Equilibrium. Phase Transftlons~ Physicochemical
Analysis.
Abs Jour- Ref Zhur-Xhimiya, No 8, 1959, 26420.
Author
Inst :Not given.
Title :Contributions to the Theory of Multicomponent
Condensed Systems. 11. Systems With Congruently
Melting Chemical Compounds (Part 1).
Orig Pub: Chem Zvesti, 12, 'No Z, 83-94 (19581 (in Slovak
with German a-n7 Russian summaries),
Abstract: Differences between the characteristics of simple
eutectic systems and ol' bystems containing congruent
melting chemical compounds are pointed out. The
following terms are Introduced: 'stable sectionst
(the geometric loci of the figurative points
Card 1/3

CZECHCSLOVAKIA / Physical Chemistry. Thermodynamics. 8_8
Equilibrium. Phase Transitions. Physicochemfcal
Analysis.
Abs Jour- Ref Zhur-Khtmiya, No 8, 1959, 26420.
Abstract: [Ifigurtavnyy tochkif] of the inteenal phases in
the phase diagrams of n-component systems with
congruent melting chemical compounds, the number
of solid phases in each section being less than k)
and 'characteristic trianglet (constructed from
th,., individual structural comoonents of the various
orders of the above-characterized systems). The
complex of solid phases present in the melt at any
given stage of crystallization of the given system
Is characterized as a combination (without recurring
elemants) of order k consisting of k+a elements,
where a Is the number of congruent melting compounds
present In the system. Formulas are given for the
following: the number of structural components of
Card 2/3
ZO

CZECHOSLOVAKIA / Physical Chemistr Thormodynamics 3-~8
Equilibrium. Phase Trans~t-ionsf: Physicochemical
Analysis.
Abs Jour: Ref Zhur-KhImiya, No 8, 1959, 26420.
Abstract: the i-th order of the system of k components with
one congruent melting compound, Z'; the total num-
k
ber of structural components In all k orders,
L7 k Zi; and the number of elementary crystalliza-
1=1 k
tion fields in the phase diagram of systems of the
type described above E: (sicl Zk = Ci + Ci-1
k I k It- I
k Zi = 3 .2k-l_,; = 2(kt.), where Cn is the
i=1 k (k) m
symbol for a combination of m elements taken n at
a time. For Communication I see RZhKhim, 1958,
700Z3. -- V. Anosov.
Card 3/3

1UTHOR: Malinovskiy, 11. S. (Dnepropetrovsk) 74-27-5-4/6
TITLEt On he Production of a-Oxide Compounds
(Polucheniye a-,okisnykh soyedineniy)
PERIODICAL: Uspekhi Khimii, 1958, Vol. 27, Nr 5. pp 622-642 (USSR)
,LBSTRACT. Various compounds which a-e later used in different
fields of national economy are today produced on the
basis of simplest a--oxides as well as ethylene and pro-
pylene oxides. No generally valid method was hitherto
found for the production of such compounds. In the in-
troduction an enumeration of possibilities for the for-
mation of an a-oxide ring is given. In section I the
author of the present report deals with the production
of a-oxide compounds by the oxidation of unsaturated
compounds. Section 2 deals vith the production of u-com.-
pounds by means of a condensation reaction., above all
by means of condensation of the aldehydes or ketones with
ethyl.-.chloride-acetate or aromatic aldehydes with a eto-
phenone halide. The synthesis of glycidic ester and the
Card 1/2 mechanism of glycidic synthesis are discussed. In this

On the Production of a-Oxide Compounda 74-27-5-4/6
connection the works by Rutovskiy and Dayev (Reference
111) and Scheibler (Ref erence 112)?Oui-jeau and BiUeter
(Reference 1,13) as well as by Muncn-Petersen (Reference
114) and others are mentioned. Section 3 is devoted to
the production of a-oxide compounds from halohydrines.
Among others the author also reports on the synthesis
of cis- and trans-halohydrines. In section 4 the aurhor
deals with the production of oxides of olefines by the
dehydrogenation of a-glucols. in section 5 tith the pro-
duction of a-.oxide olefines by means of the dry distilla-
tion of cholines of high molecular weight. The investiga-
tions by Braun (References 162-183) are discussed. In sec
tion 6 the author discusses the production of a-oxides by
the influence of diazomethane upon aldehydes and ketones.
It is pointed out that it was already found in 1928 that
a-oxides form after the interaction of diazomethane with
aldehydes and ketones., The mechanism of the formation of
a-oxide compounds after the interaction of diazomethane
with aldehydes and ketones is described in detail, Finally
it is mentioned that not all possibilities with regard to
the production of a-oxide compounds have been exhausted.
Card 2/?_ There are 203 references, 67 of which are Soviet.
1. Organic oxides--Synthesis

SOV/79-28-8-55/66
AUTHORS: Gitis, S. S., Malinovskiy, M. S., Glaz, A. I.
TITLE: Reactions of the Aromatic Nitro Compounds (Reaktsii aromati-
cheskikh nitrosoyedineniy) IV. The Re-Alkylation Reaction of
the 2,4-Dinitrophenol Ethers (IV. 0 reaktsii perealkilirovaniya
efirov 2,4-dinitrofenola)
PERIODICAL: Zhurnal obshchey khimii, 1958, Vol. 28, Nr 8, pp. 2262-2264
(USSR)
ABSTRACT: In this paper the re-alkylation of not only 2,4-dinitroanisole
is reported, as was the case with an earlier paper by the
authors (Ref 1), but also that of other alkyl ethers of 2,4-
dinitrophenol. In the substitution of one alkoxy group for
another the authors found it to be a regular occurrence that
the alkoxy group was displaced with a greater negative induction
effect. It was found that by re-alkylation the following com-
pounds can be obtained in good yield, 2,4-dinitroanisole from
the 3-oxyethylether of 2,4-dinitrophenoll 2,4-dinitrophenotol
from the n-propyl ether of 2,4-dinitro-
phenol from 2,4-dinitrophenetol; the n-butyl ether of 2,4-di-
Card 1/3 nitropheno'. fr= the n-propyl ether of 2,4-dinitrophenol; the

SOV/79-28-8-55/66
Reactions ~0 the Aromatic Nitro Compounds. IV. The Re-Alkylation Reaction
of the 2,4-Dinitrophenol Ethers
primary isobutyl ether of 2,4-dinitrophenol from the a-butyl
ether of 2,4-dinitrophenol; the primary isoamyl ether of 294-
dinitrophenol from the primary isobutyl ether of 2,4-dinitro-
phenol. From 2,4-dinitrophenetol, however, 2,4-dinitroanisole
could not be obtained, and so forth. The alkoxy groups can be
arranged in the following order according to the strength of
their substitution effect: primary iso-C 5 H11 O> primary iso-
C4H90) n-C4H9O> n-C 3"70>C2H5O> CH 30 >HOCH2CH20. The series Js
in complete agreement with the data on the strengths of alkoxy-
acetic acids (Ref 4). The reaction occurs at room temperature
over the period of one hour. Upon warming the solution a ccm-
plete saponification takes place with the formation of dinitr~;-
phenylate (Table 1). The constants of the solid and liquid
ethers obtained are given in table 2.
There are 2 tables and 6 references, 2 of which are Soviet.
ASSOCIATION: Dnepropetrovskiy gosudarstvennyy universitet (Dnepropetrovsk
Card 2/3 State University)

SOV/79 --28-8 -5 5/66
-Alkyl-ation lif~acc,-' cr
Reactionq of the Aromatic Nitre Compounds. IV. The Re
of the 2.4-Dinitrophenoll Ethers
SUBMITTED: June 25y 1957
Card 3/3

5(3)t 101(81
AUTHOR; Malinovskiy, M. S. SOV64-59-2-8/23
TITLEt Application of Alpha-Oxides for the Synthesis of Glycol Esters
(Primeneniye allfa-okisey dlya sinteza efirov glikoley)
PFMODICAL: Khimicheskaya promyshleniiost', 1959, Nr 2, pp 127-134 (TJSSR)
ABSTRACT: In connection with the forthcoming &velopment of the industry of
synthetic materials provided by the new Seven-year Flan also new
solvents, wetting- and plastifying agents must be developed.
Ethylene oxide and some other alpha-oxides are suitable initial
materials for their production. Their reactions with alcohols and
phenols are investigated in the present paper. Many of these reaction
products are already used in induZtry. Thus, monoalkyl esters of
ethylene glycol are good solvents for nitro- and acetyl-cellulose
and some synthetic resins. Their properties (boiling point, density,
and refractive index) are mentioned (Table 1). Higb-molecular
condensation products of propylene oxide with alcohols (Table 2)
are used as solvents for nitro-varnishes, lubricants, hydraulic
liquids, etc. Some esters which may also be recommended as solvents
may be produced (Table 3) by condensation of allyl alcohol with
asymmetric alpha-oxides of olefins. In synthesizing the esters of
Card 1/2 isobutyl alcohol it was found that primary esters are better solvents

Application of Alpha-Oxides for the Synthesis of Glycol SOV/64-59-2-8/23
Esters
than the tertiary ones, since the latter exclusively form viscous
solutions (Table 4, esters obtained). Tn analogy to univalent
alcohols condensations may be carried out also with multivalent
alcohols, such as glycerin, erythrite, hexose, cellulose, etc/and
various esters may be obtained. Syntheses of this kind and respective
investigations may be found in publications. The author of the
present paper, for example, produced -yt-diester of glycerin (Table 5
esters obtained) and obtained monoesters of glycerlm-(Table 6Y. by
a similar method (Ref 69). In the series of the afore-said syntheses
the author makes mention of the influence exercised by various
factors on the course of reaction and on the product (from
publications). There are 6 tables and 116 references, 33 of which
are Soviet.
Card 2/2

ALUSNM, V.V.; IVIINDVSKIT4,
Phosphorus organic compounds and their use. Khin.v shkole 14
no-3:&20 My-Je '59. (HIRL 12:9)
1. Dnepropetrovskiy goandarstvennyy universitet.
(Phosphoms organic compounds)

YAVOROVSKAYA, V.P.
--AAL-IKO-V-4K
Zffect of salfur7l chloride on d--pinene. Ukr.khim.zhar. 25 no.l:
107-3.10 959. (MIRA 12:4)
1. Duepropetrovskiy gosudarst7ennyy universitet.
(Sulfuryl chloride)' (Pinens)

5 (3)
LUTHOIIS: .11alinovskiy, 14. S., Romanta-evich, W. K, SOV179-29-3-29161
TITLE: On the Reaction of Propylene Oxide With Organochloronilanes
(0 vzaimodeystvii okisi propilena s organokhlorsilanami)
PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29, Nr 3, PP 888-891 (USSR)
ABSTRACT: In the present paper the synthesis of eight P-chloropropoxy-
6rganosilanes hitherto not published is described and the way
of cleavage of the oxide ring in the propylane oxide on the
reaction with organochlorosilanea is investigated. This re-
action (1) may proceed in two directions:
CH _CH__CH + R Sicl R nSi(OCH2CHClCH 3)4-n (a) N
3 \ / 4 1
2 n -