SING DATE--30OCT70
2/2 027 UNCLASSIFIED" PkOC(54-
!CIRC ACCESSICN NO-AP0125258
,~A.BSTRACTIEXTRACT--(U) GP-0- ABsrkACT.. THE REACTIGN OF GE(IV) WITH
~:3,5v[)INITRUPYPOCATECHOL (L)..WAS STUDIED:SPEUROPJ~
IOTU.METRICALLY AND
POTENTLOMETFICALLY. AT A GE:L CCN(;N.'.RATI0 OF 1.*13, A COMPLEX FORMED
-WHIHC H IAD Pi~OPERTIES OF A STRONG DIBASIC ACID w[T.4 A V,.,0 IONIZATION
CUNST. OF,(.1.24 PLUS OR MINUS 0.10) T LMES:10 PRIM E INEGATIVE2. THE
INSTABILITY CONST. OF THE COMPLEX 15 (1.42 PLUS OR MINUS 0.29) TIMES 10
PRINE NEGATIVE48. AT IONIC STRENGTH 0*1: AND 25PERCENT, THE IONIZATION
CONSTS., OF L ARE: K SUBI, EQUALS-4.4 T I MES 10 PRIME NEGATIVE4 AND K SU,32
'EQUALS 9.3 TIMES 10 PRIME NEGAT IVE 11. FACtLITY: INST. 08SHCH.
NEORG, KHIM., KIEVt USSR*
UNCLASSIFIEO
USSR UDC 1537-22(")-1-537-311-331 -01
Y V. L. I-
,L'o-KOVSKIYA M. A., and.KUKUSHK-W, ~L. S.,
"Interaction of Conduction Electron With. Transverse and lonzitudinal 0011-ical
Vibrations in Ionic Crystals"
Vzairnodeystviye.elektrona provodinosti,s poperechnymi i prodollnymi opticheski-Mi
kolebani,-,-axii. v kristallakh- (cf.' English above'~ Physies Institute,
AcadenV of Sciences Ukrainian:,SSR, No 2):~, Kiev., ~1971,:. 16 k., rotaprint.
to 1, Jan J~bstract No
(from RZh-Fizik-a, N 72
Translation: The article considers the interaction of conduction elee'rons with
vibrations in ionic er
ystals. w1lich have an isolated. typta of transverse optical
vibrations (c. g "soft" node,in perovskAte ferroelectrics, do-ably degenerate
rnde of transverse cjptica~ vibrations in diatomic allmii-halide ci-jstalr,). At
the sar-- tir-re, for purposes of corx"crison.the swrie method is used to study the
interaction with loncitudinal optical vibrations, a precision study being made
of the cirystal latt-ice (co-called lattice model in Vaich interaction wi-Lh the
internal field created by longitudinal and transverse vibrat can br-- taken
into account, in contrast to the conlUnuummodel where, rinly interaction with
the macroscopic field of longitudinal vibra-tions is taken into consideration).
Op. the basis, of the model of polarizable ions, the authors cohs-ider the
1/2
USSR
VIMMIKIY, V. L., et al., _Iye ,-roy( rljr~,
V?'aimodeyz'_~V clektront-.~._-.L_ osti s -poocrechn.- A
i prodo"wa,,ii opttehoskimi kolebaniyami, j ionrjXkhIYiGtVI2LhLI' KiCTt 191.i-.
Hamiltonian of the interaction of the'"superfluous"*~electron vith both longi-
tudinal and tran5verse optical vibrations. From the forin of the "trans-,rerze"
Razil-tonian it follows that tr2ere is no interaction:.vith transverse vibrations
y at the center of the Brillouin zone. An
for crystals wi-Cn minimum energ-
analysis is niade of limitinG, cases where interactionirith optical vibrations
can be regarded as perturbation (case of a~wedk bond) and where it is Creat
(case of a strong bond).
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58
USSR
UIPC: 537 .2-222
and I,9MIDIFr-,V,, N. T.
"Solvin-- the Poisson Equation for a Periodic Distribution of a Static Charge"
Kiev, Ukrainskiy Fizicheskiy Zhurna-1. Vol 17, Ho 2, 1972, I)P 334-338
Abstract: The POisson equation that must usually be solved in
handling actual problems in the physics of seLiiconductors is of
the form
XI);Y P(Y) e
where e9/kT,,g is the electrostatic potential in a crystal
-having a static charge, eN, JI(x) is -theunidimensiohai impurity
distribution with a T)eriod.d,:y = x/d. A periodic.0olution foi-
this eauation is found, although the.solution in not exact but
ed in
approximate, being based on the condition? usva,liy realiz.
ation is a
practice, that M