14(5)
AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
Card 1/~
SOV/127-59-3-8/22
JermolqZUJ" 9 Bakal.eynik, YaJA.. and Vinogradov,
L.V-. Engineers.
The Semi-Automatic Control of Mechanisms in the Mine
Shaft.(Foluavtomaticheskoye upravleniye mekhanizmami
ahakhtnogo stvola..)
Gornyy zhui~nal, Nr 3. 1959, pp 31-33 (USSR)
An experimental installation for the semi-automatic
conVol of hoising mechanisms in the Kapitaltnaya
Nr 2 pit of the Degtyarka Copper Mine has BUCcess-
fully passed industrial tests. The installation was
developed by the KB TsUA (Design Office of Tsvetme-
tavtomatika) in collaboration with the Degtyarka,Mine.
The maximum utilization of already existing mechanisms
64uipped with pneumatic gear was taken into constdorat-
ion, Air distributing devices VR-350 ( figure 1)
developed,from ENIMS air distributors, are used in the
system. Two men in the hoist cage direct different
operations in the hoisting shaft. The system is des-
SOV/127-59-3-8/22
The Semi-Automatic Control of Mechanisms in the Mine Shaft.
cribed in detail (figure 2). The introduction of
this system in the Kapitallnaya Nr 1 and Nr 2 pits
will permit a reduction 30 men in the working
staff. This represents :1 yearly saving of 340,000
rubles. There are 2 diagrams.
ASSOCIATION: Tsvetmetavtomatika, Moscow,
Card 212
EPYOTAML.L.L
....Owwwp-
PhytcpleLnkton of lake Krivoye of the Warasuk River system. Trudy
TSSBS nci.802-96 164. (14IRA 130)
L 01293-66 :;.IT
AMMM MR: AP54017080- Wogqo/Wod
i 581,526-325
1AUTHOR: Yermolayev, V.,
VITLE: Primary production of lakes with lovered;wat
northern part of t1me-Kh1undisk Steppe
SOURCE: AN SSSR, 141birsko7e otdolenlyso .X06sttyas
.biologo-meditsinskII& naukv no* l# 1965P.14-99
TOPIC TAGS: lake, hvkojoW, algae, photosynthomiss
respiration# plant ecology
ABSTRACT: In 1962 phytoplankton production of Lakel
(Narasuksiy Ra-yon of Havosibir'sIcala Oblast') was!itx~~
its water level was 35 am-below normal# an
production of Lake-Kusgan.(in the sam ra
m.] gn) wai-` iii
its water level was. 1L9 em belask na . A vtonl anirt'
~0,03) 009h/0"9
10V,18 .131 61
0~iy4l
I)Ianil
when
when,
(M Iff
6m)- imdat---dt~M -dr- i.- -im --1-4-6 - a LOY -t,1666 -to
pie 9
Septembem, 'At the sime UW irstor dMploO (0015 1) liewe flite
determino ttio mmbisr or sigios ooutdalii dftd, 66116 amd tive Omouftt of
Card 1/3
Y
L 02293-t~6
ACCESsioil NR: AP5017080
Aritensity
phyto lankton biomass* The ooeffici6nt ot~ph6tosynt~vdia;'
P
and respiration intensity was detatmined and the it, of, ox;rgen
released. per hectare of Uka awfaoe at aAean da'pth 41T 101.1 M'Was (LIMC
deteinninede Findirtga.show that- both laked at':Iow9re4Gi4atm1jv 1TVals
maintained their J*LOtOsynthetie aotiviit7 des its' a S'ii-pinglani; levol
of dissolved salts in the water (1000 to 1999 ;;/1)., ~~Ihe !1sor-s-inal
oxyg;)n -production of Lake Xuagans which,. is ~more shallix( aT11 itiore
mineralized than Mike. KrIvoje# was aignif toantly ht .111 ir Moth bodiso
of watQr'are oharaoterized by intense devOlopment P algae
duritag the sumnor nonths, As: a rule, Oeai6nal ohan lit'l-ytopla&.-
ton 'production ohmr that with increased nl~mbero of in a
given unit of voluxies the intensity of its. photo~jxJ-WIJOIS ~IJJOWO&13004
Howeverg no true correlation wds established betiloon thm OaIues of
true ph-ytoplemkton photosynthesis (coefficient. oP plu"400 ,
intensity and respiration intansitjok PhyOPI'mWiOn jPOIUibei:jm# and
Ph`ytDP1ankbon biomswe Orig., art* has: 4,tOleo.
ASS011JIATIONs TAMral'tn7l Sibirskif, bbtWchesi .1i arid Siblipokogo
otdoleniya AN OSSR11 Novosibirsk (Otntodl: Siberian HotoliaA Garden 6f
the Siberftn 13ramli ff SM)
L 01293-66
11COESSION NRI AF54017080
UBM ,..
ubtrit
60
~,Goollp
RR MW sovt :,
i v! i,
Lot m
W-66-
KC NRs AP5025697 JD r,/, scums 6(563t:: UAM86~
RX
AUTHORS:
111 a oi I- - -- I
ft,4 1~ 7.77
Razava7sv. Go A., Akol '80
CI]LS/OD47/0047
Au
I,'
Ar, I A
T IWIb
;No* 174697
SOURM Byulletenl lacbretwAy i tovarny1ch anakaw, noo
TOPIC TAOSs electric. resistarp chromium.. nickel
ABSTRACTs This Author Certificate preal 'hoa'foi:Ma*d)
vit ad
electrical resistors by vac=m dopq WI%r gr-I Ii3nnto
f-JIM to th6 InAttubing, ty~ Him
da thin filis
beaO.'
rA to deargane
L. T
49 351.ai6, ixoW :1
Card 1/2
I III "T I
''Issmunw.
Winter phytoplanktm In I&M Irivoys of the laremak liver vm+4m.
-Trudy TUS wolosi*.49 165,
Pbwt%"akton In Lalm Studessys of W Luua River Systea.
-Ibid. 350-% (KDtA 18310)
S/l95/6l/o153(2?11(?03/O04/0O9
As-/ 0 2030/Z452
AUTHORS: Molin, Yu.N. and'Yormolayov, V.K.
TIM: The causes of the change in proton relaxation time
during irradiation of aqueous solutiona
PERIODICAL: Kinetika I kataliz, v.2, n0-3, 1961, 358-361
TZXT: Hitherto the decrease in relaxation times have been
attributed to the formation of free radical a, bu calculation shows
that improbably high concentrations, 1017 to 101A 9-1 would be
necessary to give the size of effect observed'* The present work
therefore resolves this question by irradiating solutions of
hydrogen peroxide and also distilled'wat*r, h*xan*,, benzene and
solutions of benzoyl peroxide in benzene, and aqueous solutions
close in concentration to those used*previously by Y.M.Ydovenko and
V.A.Shcherbakov (Ref.2: Dokl. AN SSSR, v.127, 127, 1959), and
observing simultaneously the NMR signal and also the RPR signal,
the latter indicating the formation of any parama4pietic bodies,
including free radicals. The apparatus consists of an EPR magnet,
with a hole drilled through one pole, to admit a boam of fast
(1.6 MeV) electrons. The specimen in hold in a Slass ampule,
diameter 7 mm and volume 0.25 cm3, which in located close to the
Card 1/3
313.9
S/195/61/o t/003/004/009
The causes of the change ... 9030/9452
opposite pole to minimize the field inhomogeneity dud to the hole.
The NMR field coils are wound on a former which slides over the
ampule. ++ The MIR signal in calibrated with standard CuSO4 solutions
with Cu concontrations of -OW17 cm-3; the sensitivity is rather
less than in previous work because of the Increased field
inhomogeneity. The %pecimen of 30% stabilized impurified H202 was
-irradiated at 6 x 10 rad/sec and after 2 min the amplitude of NMR
signal, which had increased rapidli within seconds reached a high
steady value. equivalent to 4 x: 10 9 ions Cu*+ cm-1. On removal of
the irradiatibai, the signal fell over some 30 min to about one thlid
thinvalue and then appeared constant. It was remarkable that all
this time thero was no observable change in the RPR signal, thus
precluding the formation of a significant concentration of frte
radicals. Similar results were not obtained with the other
solutions. The only plausible explanation of the results is tha'~
the relaxation time is decreased by supersaturation into free
oxygen, which is known to be formed on irradiation of hydrogen
peroxide; thiis is confirmed by the lack of signal in the other
solutions indicating that not more than about 1017 cm-3 free
radicals could remain undetected, and by the failure of the signal
to revert to its initial small value in H202, as should have
Card 2/3
309~-9
S/195/6l/OU2/OO3/Oo4/ooq
The causes of the change 3030/E452
accurred if formation of free radicals were the operative
mechanism. Ackmowledgmonts are expressed to Y.Y.Voyovodskiy and
N.Ya.Buben for their interest in the work. There are 2 figures
and 9 referencesi 6 Soviet and 3 non-Soviet. The references to
three English language publications read as follows.
Ref,l; V,T,Duft*y, Bull. Amer. Phys. Soc,, II, VA, 250, 1958;
Ref.8.- J.G.Marshall, P.V.Rutl*dge, Nature, v.184. 2013, 19W~
Ref.9: G.Chiaratti, L.Guilotto, Phys. Rev., v.93, .1241, 1954.
ASSOCIATIONS: Institut khimicheakoy fiziki AN SSSR
(Institute of Chemical Physics AS USSR)
Institut khimicheskoy kinetiki i goreniya SO AN SSSR
lInstitute of Chemical Kinetics and'Combustion SO
AS USSR)
SUBMITTZD: October 31, 1961
Card 3/3
35062
s/195/62/003,1001/00/Clo
E071/E136
AUTHORS; Yermolayev, V.K., Molin, Yu.N.* and Buben, X.Ya.
MW -
TITLE: Recombination of radicnis in solid organic substancea.
I. Investigation by the method of fusion ,
PERIODICAL: Kinetika i kataliz, v.3, no.1, 1962, .156-611
TEXT: The range of temperatures at which rCcombination of
radicals takes plAce on fusion of various organic substances,
irradiated with fast electrons, was studied by the 3np (EiLiz)
method. The object of this work was to determine the molecular
movements leading to the recombination of radicala in a solid.
For this reason the substances investigated had a known phase
behaviour on heating. Normal alcohols, ketones, hydrocarbons,
aromatic compounds etc. were investigated. To dotermine the
stability of radicals at various temperatures, fusion curves were
obtained. For this purpose a substance was irradiated at a
sufficiently low temperature To in a stream of fast electrons
to obtain a concentration no of radicals, The irradiation was
stopped at the beginning of the linear part of the curve of
accumulation of radicals (no PO 1019 radicals/&).
Card 1/3
Rocombination -of radicals in solid ... s/195/62/003/001/003/010
E071A.136
The tenperature To was so chosen that during 10-15 ininutes no
noticeable decrease in the concentration of radicals occurred.
The substance was then heated for 2 minutes at a temperature
Ti '.>T0, cooled to To and the concentration of radicals n1
measured etc. The dependence ni (Ti) was called the fusion
curve. It was established that for crystalline substances
(substances of type I) a rapid recombination of radicals occurs,
as a rule, before melting; for amorphous substances the process
takes place near the divitrification -temperature. For cyclo-
pentane and cyclohexene (type 11), radicals recombine near the
temperature of their polymorphic transformation. For hexamethyl-
benzene, acetone, succinic acid (type 111) several ranges of
recombination of radicalB can be separated. In the majority of
cases the recombination of radicals is, apparently, caused by
self diffusion, appearing close to the temperature of a phase
change. For substances of type III the recombination of radicals
takes place at; a temperature at which the self diffusion of
molecules is apparently absent, e.g. in hexamethylbenzene and
acetone, radicals recombine partially in the region at which
Card 2/3
Recombination of radicals in solid ... S/195/62/00/0011U63/010
E07.1/E;36
the molecules begin to rotate. The recombination of radicals in
the absence of self diffusion could be explained by the formation
of radicals cl()se to each other, e.g. on the neiglibouring
molecules in pitirs, Then initiation of any molecular movement
may lead to their recombination. However, the f6riflatiOn Of
radicals on ne:Lghbour-ing molecules should be accQr-.pan;Led by a
strong widening of components of the superfine structure of the
EPR spectra, mtch higher than was actually observed.
The authors thank V.V. Voyevodskiy and G.K. Voronova for their
assistance. Part of the material of the present r.~Lper was
presented at the Second All-Union Conference an Radiation
Chemistry. There are 5 figures.
ASSOCIATION:-Institut khimicheskoy fiziki AN SSSR
(Institute of Chemical Physics, AS USSR)
Institut khimicheskoy kinetik! i goreniya SO AN SSSR
Card 3/3 (Institute of Chemical Kinetics and Combustion
SO AS USSR)
SUBMITTED: August Ili, 1961
4~236
3/844,/62Y000/000/056/129
D204/11307
AUTHORS:,,,-Yermalla Holin, Yu. V. and Buben, N. Ya.
'IMSY
TITLE: Recombination of radicals in some frozen organic compounds
SOURCE: Trudy 11 Vsesoyuznogo aoveehohaniya po radiatsionnoy khi-
mii. Ed. by L. 8. Polak. Mose-ow,jod-vo AN SSBR., 1962,
331-334
TEXT: The pre6ent work was aimed at a study of the molecular mo-
tions occurring during the recombination of radicals formed under
the action of fast electrons at a temperature To, such that no, the
number of radicals formed, remains fairly-constant over 10 - 15
min. The compounds were then warmed up*to a series of temperatures
Ti (where T i> To ), maintained at Ti for 2 min and cooled badk to
Tor at which temperature the remaining conecitrations of xudicale,
niq were measured. In cystalline compounde,'duch as MeUH, C 6H6 or
n'oetanol, the :mdicals 4~qajjpeared at 0.9 1.0 T (where T
M m
Card 1/3
U %62/000/000/056/129
Recombination of iddicals..r... D20,4rD307
m.p.), whilst in poorly crystallizing Elubstlan~bes, such as glycerol
or n-butanol, the recombihdtion took place in~ the region of vitri-
I
fic9tion (0 , .6 - U.7 Tm). Tifts rule was confir'med on slowly frozen
(crystalline) and quenched'(amorphous) 191-di'cyclohexyldodecane;
cooling at an intermediate3rate gave rise to '(ni/no) versus' (T.
m
plots of an intermediate dhbLracter, shoving the presence of cry3-
tellites of varying temperature stability. Such intermediate type
curves were the only ones oboerved for paraffin, polyethylene and
polypropylene. The recombination is connected with partial destruc-
tion of the lattice and amorphous compounds rest)ectively. In cyclo-
pentane and cyclohexane, ia'which molecular rotation begins at T rot
(T rot 14 Tm)q it vras found that recombination of the radicals took
place at T rotv showing that'the radicalvare probably formed in
pairs and'recombine as Boorr as rotation becomes possible. The as-
sistance of V. V. Voyevodskiy and G. K. Voronova is acknowledged.
There are 4 figures.
Card 2/3
Recombination of radicals
ASSOOIATION: Institut
Chemical
kinetiki
K,inetics
LISSR)
$,/844,/62/000/000/056/129
D204/D307
khimicheakoy fisiki AN 603R-(Institute of
2hyeical AS USUH); Institut khimidheskoy
i goreniya SO ILK SSSR (Inat'Ltute of Chemical
and Combustiont Siberian Branch of the*AS
Card 3/3
YERMOLAYWs V. L.
PA 175T77
r
lye
Teiji*~reti is of
t ur
0 a P4r
9
4"stwikov,, V. L.: Yei
J~: Dok Ak Nauk. SWR" V61 LW NO 1: 4 ppy
k5tudies variation ixi
phoophorciscence,of OcLe. i63z ti
]Avin et t t -0-114 d4r*&~
n co o:
W,v ncu of-activai a, t
W ': -I
0,
he' of isiditins:
6.UtaittedL
r4tv litt, eitt, A .4.,
...... IGAIIIC M'dil,
MES AT. t xTZ MP
*!Jj~At Pri Mzkot
Temp"criturd). A.: K. Te
4w bp 0. Sol froiri Old" S.
vLvttdta lit-46( lap,,
An xtttt*Vt two f 4('thihj~ of exlItArl
99
onarjr in co erat
one WgIocMIG to ttcu~~' a( a-
tumustemenco of
t4,11wd
teduldi im
wbero thip prim"y Im f it 0 lit O"imuldi 06
tit 4 muldi im
USSR/Physics - Phosphorescence Sensiti- 21 Jta 52
zation
"Sensitization of Phosphorescence of Organic Male-
cules. at lov Temperatures: Intermolecular Trans-
fer of Energy With Excitation of the Triplet
Level," Acad A. N. Terenin, V. L. Yermolayev
"Bok Ak Nauk SSSR- Vol 85, No 3,,Pp 547-550
Ditc-asses investigations devoted to the,problea of
t*ansfer of excitation energy in soIns of mirts of
f-h-orc=11-us- 9-r-1-am-tic-mols st te*p of liquid air--,
fvr--the 7urpose of establishing the 'phenomenon of
sensitimtion of excitation by one compd. of the
A Giver, t a
Z;VU_DI_rQi7J_-i PhOSPbor&acence of wwl=a dc*4d& in
dijendlence on conen of another. Submitted 3 May 59-
235T92
phoophorescence ot ax=mtI*to*.u~Aj!
Periodical 1 Dok. AN SSSR 102/5, 9125-928, jrt~, 3a 2.4 51
Abatrtat I An experimentea otudy wapi, a .~i of th'O
Ond=t ienditin44
4
,ae- of t: in 1
all
~,Osphore nce and the. doU= atj
TEMNIN, A*N. ; ,Y=~WA~!Wj%hp.,t
Intemolomlor transfor of onera owurrim In sonaltised luminesconce.
lzv,.AN SSSR. Sorf1s, 20 no*40W Ap 156. (MU loa)
(imlawam) (I%wmaowo)
ern*-NO'tf~\JQ-NI VL
USM/Optical - Aysical Optics K-5
Abs Jour fteferat Zkur - Fizika, No 5, 1957, 12962
Author I sFM' V LW---
Inst
Title Sensitized Phosphorescence of Aromstic Compounds (Baergy
Transfer from Triplet to Triplet Level).
Orig Pub Ity. AN SON, ser. fiz.,, 1956, 20p no 5. ~1"19
Abstract A quantitative investigption was mode of the phenomenon
of sensitization of phosphoresewces comected vith radia-
ti(mless migmtion of the energy of electron excitation
between the molecules, vith the excitation ofthe triplet
l4wel. For nor details see Abotract 12961.,
Card 1/1
T:
t1ft/Physics, - Luminelpeence
Pub. 118 - 2/7
Authorm I Tereniii, A. No and' Yermolayev; V. 1 L.
S Intormolecular transfer. of onergy, :~11 ~htt phimoi 0, 1 0-r!
.Eli rill itized
lurdineseence of organic Symema I t' 11)
Usp. Fiz. nauk Jan 014
58/1,# 37-689
I The intemolecular tran-S'far of ovlem~fly ikeer-4wt "I'l III-%
, ;
an the sonAtization of
prglxdv~ I
Two types of energy transfer:am- cl4nrAA~rvdi 01 'ItAc mm" lnlluctivu~.
Varimis cases are analy?ed ~rt whicH emAtiie& 1111,110111 and thh
enerj7,,r tran-ifur vo-re obsvrvoi~. B Gum., 121 UI;A,
28 USb1t (1927-1955). Gra-phs d i a I..rv', an So.
inst.itution
i Submfitted woo.,.
m
YANOZATNT. V. L, XRMCEMOV, T.T.. SN=14N, N.M.
-- 1013
Nodorn mignallng, central control mad block mystem ovdPwat used
In underground electromotive transport. MborostrooUt no,12:2-5
D '56, (Submwo-41analing) (fttematic control) (MIRA 10:1)
AUTHORS$ Daitriyovskiyo 0. D. 0 Yeraglaxas, 2o- 114-4-20/63
Torenin, A. X., Nombor'of the Academy
TIT18i Direct Measurement of the Lifo of Excited Molecules of Chloro-
phyll and Analogous Pigments in Different Media (Pryawye iz-
moreniya vreasni shizni vosbushdonnykh malakul khlorofilla i
analogiobqft *. pignentov v razlichnykh aredakh)
PIRIODICALs Doklady Akad"ii Sauk 335R, 1957P Vol. 114t Nr 4,--Pp,. 751-753
('USSR)
ABSTRACTe In order to determine this life 't the authors measured the
duration of fluorescence by means of the phase fluorimeter
by A. M. Sonch-Bruyeviah ot &I. whose resolving power in time
is 2.lo-lisoo. Other devices used in these investigations and
the errors of seasuresent are also shortly discussed. Fluoresc-
-
ones was excited by the mercury line 436 0"-- Observation was
effected through the light filter XC-1o wii
h a thickness of 4
an. The concentration of the solutions always remained below
10-5 Rol/l. The values obtained for the solutions of ahloro-
ph7ll and related pignonto in various solvents at + 2oOC are
summarized in a table. The here measured life of the excited
singlot state of chlorophyll markedly differs from those values
Card 1/2 which were obtained by indirect methods from the polarization
Direct Measurement of the Life of Szoitod Molecules of Chlbro- 2c 114-4-20/63
pbyll and Analogous Pigments la Different Media
-of the fluorescence and from the integral of the absorption
band. The decay time of the fluorescence of the pigments de-
ponds only little on the solvent. for chlorophyll by it is ap-
proximately twice as small as for chlorophyll a, which is con-
nooted with the different quantitative yield of fluorescence.
In phtalooyanidoe life is monowhat longer than in phoophitines
of the corresponding metals. Romatoporphinin has the loMmt de-
lay time* If a Zn-atox is tntroduced into the pigment instead
of a Mg-atomj the decay tizio of the fluorescence is reduced
-to about half of its fozuor length. A *0, 1e contains the here
obtained date on the docay time of the fluorescence of ohloro-
phyll in natural media. The values thus obtained are about
3-8 times as short as in acloular solutions. In the living loaf
,t depends on the intensity of exposure to light. The reduction
of't and the reduction of fluorescence yield in the living loaf
are largely due to the high concontration of pigments under
thoso'conditions. There are 2 tables and 6 references, I of which
I a Soviet.
SUBMITTnt NOY 31 o 1957
Card 2/2
.YERMOLAYE'll V.L.; ALESHIN, V.G.j SAYENKO, Ye.A.
Determining the velocity constanta of enera trunsfer in chelate
ecmplexes of rare earth ionis. DokI. All SSSR 165 no.5:1048-1051
D 165, (IMIM 19: 1)
1. Submitted April 26, 1965,
YERWjLkYEVv V.L.qGand Phyn-]L~.th Scl-(dics)
Of Org,-UIJC COMPOUIIdS ~'Lt 10""' tOUPOr!:tUres" LL-:,,ll 1953- 10 Pi)
v
(Stato Order of Lenin Optical Inut in S.I.Vavilrw), '1450 mdzlo
(4147-5'~,', 129)
-'. TIMLATW,, V.L.; KOTLTAR, LP.; SVITASIW, K.K.
Internal conversion frou the fluorescent to the phosphorescent
1wrel In naphthalene d*rlystivem, lsv,AIW SSOR.Ber.fiz. 24
no,.5:492-495 Ff 060. (91U 130) -
(11aphthalene-Optical properties) (Umineacence)
24(4) sov/51-6-5-14/34
AUTHORs YermolAyev, V.L.
TITLBs Dependence of the Probability Of Energy Transfer in Sensitized
Phosphorescence on the 0--cillAtor Strength of a Triplet-aingist
Transition in the Molecule of an Snergy Aa,,-optor (ZMViC1M03tt
varoystnosti perenons, snorgli pri sonsibilisavannoy fosforostoant-Ai ot
oily ostaillystors. triplot-vinguletnogo perskhoda v molokule
aktaeptora energii)
PBRIODIGALs Optiks, I Spektroalcoplya, 1959p Vol 6, Wr 5, pp 642-647 (USSR)
AMTRACT: The paper vas presented at the Sixth Conference on Wminescence,
Ld,ningrad,1958. In 1952 Teronin and the author (Rats 1, 2) discovered
sensitized phosphorescence of aramtic compounds. Later kReft 3-5)
it; was found that a resonance transfer of energy -with direct excitation
of' a triplet level in the energy acceptor takas place in sensitized
ptoophorescence. The present paper describes studies of the effect of
the oscillator strength of triplet-singlat transitions in thacnergy
acceptor on the probability of energy transfer ax4 consequent quenching.
For this purpose acceptors witti similar phosphorescence spectra anrl
Yvidely differing decay constants were used. Xhey were: naphthalene.
Card 1/4 l-,chloronsphthalons, 1-bromonsphthalone and 1-iodonaphtnalons. Their
SOV/51-6-5-14/34
Dependence of the Probabilitj of NA&rgy Transfer In SenslUzed PbosphDreseence on
the Oscillator Strength of a Triplat-Singlot Transition in the Uoiscule of an
Snargy Acceptor
phosphorescent properties are listed in 'Able I,- the height of the
triplet level, in ca-1, is given in col 21 the decay constant, in see,
in given in col 3; the quantunt yield Is &1vvA in col 4. Experiments
showed vat phosphorescence of bwzophenons or bensaldehyde was quenched
to the same extent by any on* of the four aeceptors listed abovs (at
tJ20 same acceptor concentration of 0.32 solo/litre at -19,50C, see
%ble 2). This is shown clearly in Fig 1 -whore the continuous curve
represents quenching klowering of intswity of phonphorescenee)of
benzophenone by naphthalene (circles) and 1-bromona phtho. leas (crosues)
as a function of the acceptor concentratioa. Although the oscillator'
strengths of the triplet-einglet transitions in naphttAlone a-ad
1-bromonaphthalene differ by a factor of about 100 their quenching
action in represented by the same curve. ThIs is also t--ue nf the
door@&@* of the pbosphores".nas decay constant It, due to
xgLphthalezo and I -bromonaphtheL Ions in bentophenono. -ghe effect on ,e
is represented by the dachod avirve In Fig Is the effs---t of naphthalene
La shown by dots and that of l-brmonaphtbalene by trianglos. These
lacts contradict directly one variant of t1w theory of radiationless
%J
bard 2/4 i)norgy transfer (Galanin, Figrater, Dexter). This variant predicti
BOV/51-6-5-14/34
Depen4ence of the Probability of unergy Transfer in Sonsitised PhoaFhoresconce on
the Oscillator Streqtft of a Triplet4linglet vansitioa la the Molecule or *a Zaergy
Acceptor
strong dependence of the probability of energy transfer between donors
and acceptars(and the consequent quenching of the donor phosphorescence)
on the probability of radiative transitions %or-cillator strengths) In
the, acceptor. Xt was also found th,Lt the quaatum yield of sensitized
phosphorescenco (defined as the ratio Of IA, the number of quants
emitted by the acceptor, to ID, the number of quanta emitted by the
dortor) increases more slowly along the acceptor series from napnthalone
to 1-iodonsphthalone than predicted by the theory mentioned above (Fig 2).
This several predictions mentioned above stem from an assumption that
eniorgy is transferred by an inductive interaction of electromagnetic
fiolds of the molecules talcing part In the transfer process - Consequently
this mechanism must be abandoned in favour of another variant which
ascribes energy transfer to exchange -ros onance effects vrnich axplain
satisfactorily the observed facts. Ackzowledonento are made to
Mqrd 3/4
V
SOV/51-6-5-14/34
Dependence of the Probability of Energy Transfer in Sensitized Phosphorescence on
the Oscillator Strength Of A Triplet-Ginglat Transition in the Molecule of an
Energy Acceptor
Academician A.N. Teranin who suggested the work and directed It.
Tharis are 2 figures , 3 tables and 28 reforences, 16 of which are Soviet,
4 Frencb, 4 German and 4 English.
SUMffTTBDs July 20, 195P,
card 4/4
Boll
it, J~S_O 0 B006Y,31
AUTHORSs J'orwolayev, V.- 0. Serenin, Ao W.
TITLEs Intrasolecular inergy Transfer on Triplet Levels
PERIODICALs Ifspekhi fisicheskikh naukp 1960P Vol- Tip 10~ 1, pp. 137-141
TEXTs The prosent paper is a continuation of a nuab4r of previous investi-
gations (Refs- 1-7)p that had dealt withsimilar problemes. It was the aim
of the investigation under review to show that an intramolecular energy
transfer from the triplet level of a carbonyl group to a triplet level of
diphenyl- or naphthyl group is possible. For this purpose, the authors
investigated the spectra and the duration of phosphorescence in a Beries
of diphenyl ketones, naphthyl ketones, and aldehydes. The clearest results
were obtained with phenyl-4-dipbenyl ke4one (pbenyl-4;bsazophenone), the
absorption spectrum of which at -1960CI In ethanol eth r (mixture 20) is
shown in Fig. 1. The benzophenone spectrum taken under the same
conditions, is also shown for a aomparition. P~hnyl4iphonyl ketonelexhibits
two bands; a scheme of the electron lerel of in
Fig. 3. Wumerous details are giveng concerning the opectra that were
5/053 6()/071/01/05/011
Card 1/2
4W
Intramolecular Energy Transfer on Triplet 0/0~/60/071/01/05/011
Levels B006/B011
examined. Fig. 2 shows the phosphorescence spectra of~tenzophenone,
phwW1r4-dipbeny3. ketone and p-oxydiphonyl in other, taken under the same
conditions as the absorption bandl. The duration of phosphorosconott of
these three compounds was 4-7*10-2 seci 94 see, and 2.5 sta, respective-
ly. Table I contains date an phenyl diphbnyl ketone and a number of
other carbonyl derivatives of diphonyl, concerning the position of singlet-
and triplet levelt extinction periodl and phosphorescince quantum yield.
Three of the compounds investigated wert'syntbealzed by 1. Ys. Postovskiy.
Table 2 offers the same data for some o&rbonyl de'riTatiTeg-of na hthaleney
Fig. 4 shows the phosphorescence spectra of I-ebloronaphthalene, and
2-naphthyl methyl ketone. All data and all spectra reeer to mixtures with
ethanol ether Wt -1960C. Investigations show that the luminescence of
carbonyl derival6iVea of diphenyl and naphthalene can be ascribed to an
intramolecular excitation energy transfer. This sxplainm tho lack of
fluorescence in these compounds. The naphthalene derivatives were prepared
by A. I. Shatterishteyn. V. K. Watveyev anti A. T. Troakehenko.. There
are 4 Ngur 9, 2 tabies', and 10 Soviet roferenceso
Card 2/2
YER14OIAYEV, V.L.
ImEmocence, of o imple benzene derivatives. Part 1. Arozatir.
amineo. OptA opektr. 32 noe,4s492-497 0 061. WPA 14.20)
(Benzene derivative&-Spectra)
YIMMOLAUV,, T. L.
Spheres of action of quenching in the case of energy transfer between
triplet levels. Dokl. AN SSSR 1.)9 no.2:348-150 JI 161. (IMA 14:7)
1. Predstavleno, akademikom A.N. Terenih*m. .
(phosphorescence.) (Nucloit At6mic)
S/051/62/013/001/006/019
E039/E420
AUTHOR: Yormolayev, V.L.
TITLE: measurement of the quantum yields of xonsitized
phoxphorosconce as a method of studying quenching
processes at the triplet level of organic molecules;
PERIODICAL: Optika I spektrookopiya, v.13, no.1, 1962, 901-05
TEXT: The quantum yields of xonxitized and normal
phosphorescence are measured for a series of aromatic molecules
in solid solution at 770K. It is shown that the quantum yields
of sensitized phosphorescence for all the Investigated
combinations is independent of the concentration.of acceptor and
donor energies. Results obtained are explained on-the
assumption that the non-radiating tranxfor of energy up to the
triplet level in accompanled by-quenchIng and that all the
quenching inxidearomatic molecules-In solid-xolution is
concentrated in the triplet state. Measurements of quantum
yield of sonxitized phosphorescence are able t6 be used to
determine quenching in t rlpl*t levels of donor or acceptor energy.
Quantum yields are determined for valuex:of imccoptor on-orgy
Card 1/2
s/o5i/62/013/001/oo6/019
Measurement of the quantum E039/9420
concentrations"wr 6.3 x 10-2 to 4.8 x 10-IL'mole/litr*. A minimum
quaintum, yield of 0.070 is observed for carbax6le
and a maximum quiantum yield of 0.73 for phonanthron* + 1-chloro-
naphthalene, There are 1 figure and 3 tables.
SUBMITUD:
Card 2/2
May 25, 1961
.. .............
TERENIN, A. N. ; YERMOIAIU.. V. L.
Inaetl*ation of the triplet state In aromatic moleculeas
Ixv. AN SSSR. Ser. fiz. 26 no.1:21-29 Za 162. (MgM l5s2)
(Aromatic compounds)
(Kolecular dynamics)
M0401AYEVP #.L. s av Yea.; SHIGORINO D.N.
I-
Nomrsdiative onersy tr=oror betwom the triplet and singlet
station In organic so2sculowl d1ommolon of A*N*Teronla and
V.L. Iriolmm's report Ormeftmation of the triffileVotate
in aromtic moleculejP. Inv. AN SUL Ser. ris. 26 no.1:29-
31 -T& 162. (MITA 15:2)
Organic a -A-N
Nolecular ftomics" ).
i
ARISTOV, A,V.; ULA)p
I V.L.; LEVSHIN, V.L.; 140KHMA, G.A.; MEMASOV, A.S.;
SHIROKOV, V.I.
Boris IAkovlevich Sveshrdkov; obituary. Usp. fla. nauk 81 no.lt
201-210 S 163. (MIRA 16:12)
1- A. 11 1
0110,4/6.3 107/005/061'7/0~pp
mpjt~~s in vitreaus
Jbilld ~n Hlnok 10- 15
fis I ii6~.o 617-622
31 i3itald.ait ~f molgiciAea' in
ani
JURkL I r,-,nf:-t-
Card 1/2
- - - - - - - - - - - - - - --
6~~-
11 ;!
I
T .I ;
i
. I Ii
i . -
, ;.. . . , ;I ". I- I . . , '. - ~ A I.. . ~ - . . -
1
m
L 3.02~77-0
ACCUMON V; AP3002305 8 -1/153P80A 1/60 !1/06T)
AUTHOR: Yenoolayev,- V. L.
TrAt ~~f ~energ~mj
T'ITLE ~Or o M SX lzorgoAic sys,taM vl~ t~~ tLrtV11Pqti011 rit, tno
triPlet stat4l, 3- Solid solutiova'and
SMIRCE Usj*khJL fizichesklkh nauk,, v, 80j, n I$; 19,6j 3 14
;17
w
na
TOPIC TAGS: - triplet level transitio , glasslik6~ org~,L-. Yrtinw.. crys-zalli'le
organic systAms.# co
ncentratlon quenchingi:orpnic
ABSTRACT: Via articlep a th i )f
orough and &-tailed #uv ol I Tic~nt level nts in
tZe-field-oflenergy transfer in
orrsgnic 6-A6=, Is i in a sarj~es. The
first (by A. ff, Tarenirl-) and -the I second ~ty Me
195' z
published in:1951 and o, respectively4 ~ Tz with the t~tudy
of nonradioactive electron excitation en4rgy;tranm ilt,jareft-4 tbe triplet L-wels
of organic molecules in glasalike and.cz,at i1ne! all MLCeiIA4, 10W f--Ppi!Z -ttllre3.
- i -t - .Ohl' re.-
The text. Is - divided. into three Par so Cion rj: ~gj, de~, mi3. In
quenching tij~~, and the coacdntration qu~n; o. h ani ~Nita Phos.Ph,.)res,,!en--e
:e Al~
C,,d 1 /2
MM
JMW4rLV?.V.L.; SVEMIKOVAO Ye.B.
Indwtive resonance energy, transfer from aromatic molflicules in %e
triplet state. Dokl. AN SSSR 149 no.6tl295-2298 Ap 163.
(MRk 16t7)
1. Predstavleno akademikon A.N.Tereninym.
(Aromatic compounds) (Quantum theory)
ACCBSSI01f KA: U'4020978
AVnIOR: Yermolayev, VA.
TITLE: Triplet-triplet energy transfer between identical molecules in solid solu-
tions at 90ft
SOUIM. Optika I spektrookopiya, v.16, no.3, 1964, 348
TOPIC TAM: enfargy transferp energy migration# triplot-tri plot tranxforp phospho-
roscence quend4ingp benzophonons, naphthalene# triplet level
ABSTRACT: Tho phenomenon of triplet-triplet energy trans~or between different mole-
cules was discovered by the author in collaboration with 'rerenin In 1952 (A.K.Ters-
nin and V.L.Yermolayev, DAN SSSR 85,547,1952) and is known to occur in solid solu-
tions, liquid solutions and crystals. The purpose of the present study was to de-
termine whether it can occur between 111w (identical) molecules in solid solutions
at GOOK. The experiments consisted in'moasuring the quenching of the phosphoroscarm
of bonzophenona (donor) in the presence of naphthalene Caacoptor) in other-alcohol
solutions at different, concentrations (from 10-2 to 1.11 11) of the benzophonone.
The observed vixiation In quenching Is attributed to anorgy migration between the
... .......
ACCESSION XR: J"20978
triplet levels of the dowre "In conclusion, I desire to otpress my gratitude to
A.H.Torenin for his Interest JA the work and 0,5.2sossax"Yad for stinulating dis-
:cUssions.
ASSOCIATION:
SUM11ITIM MUM DAIS AM Mpr" INCL: 00
8198 COWS m Ew SM 003 OMM: 000
Card
=77-7=
YERMLAYET, V.I,.;
Wi3th of luninescence spectra aM Stokes's lDsseu :Ln tx-8nzI'~-_f'2r;z
from fluarencent and phosphorescent levels of axonall-ar corToun`:3,
Opt. i spektr. 16 no. 4:704-705 Ap 164. (MrHA 17; 5)
L 00988-(6
'P 'XESSION NR*
AUMOR: Yermolam,. V. L.
7TITLE - Triplet 4riplet energy transfer and Ltd applic.atianf;Hliri lit hescence and
~'Jeoto;hemiLal reactions 17
'S, 1965', 1266-1270
'SOURCE: AN SSSR. Izvestiya. Seriya fizichesk4a, v. 29 no*,~
PIC TAGS: IntermDlecular energy transfero tiiplat triplet!'biranarer, organic
luminescence, energy decay, photochentlcal~rewtioaj! rare4ttrth chelate,
loser
CT: Soviet al2d. Western research data, including i964 46i;a. triplet-triplet
0!a
energy transfer in organic molecules were reviewed and,dii)eusnfid, flew data ob-
talned by, the auth&r on triplet-triplet energy transfer betqekt id4ntiaal molecules
in solid (fr--zen) s6lutions vere given and discup'se&T6 rapiday goiring number of
publications on the'~ subject in the past few year6 (since''-i962) was:explained in terms
of possibilities for the application of tripletp-triplet energi, tranafer to the study
:1of the decay of eleittronic excitation energy in'organic molecules, mechanism of photo-
-data were re-
Ichemical reactionsgiand rare-earth chelate lasers. Rev experimental
ported on concentration quenching of the phlophorescence, of -a benza,phenone -donor by
1/2
LM
L 00988-66
ACCUSION MR: AP502DT80
a naphthalene-accept6r in alcohol-ether solution; at7: 90K. Recently, ~Preliiainar~y data
on this subject were,. published (Yermalayev, V. V. Optika I s"Idroatolpiya, v. 16,
no. 3A 1964, 548). 1.1he new data included.changea..ih the phosp6oresdence spectrAun,
quantum yields and~.quenching of the phosphorescence of 9. be~*'&phe~'oqe-donot at
high donor concentrations. These changeh vere**.ainad ?nain1;yj,Ps tho Wtict of the
radiationless tripleii-triplet energy transfer bet*een idantt4',%J,i dondp'moloculeb in
oolutions. This eff4ict is considered important for.bi6logicml~!Aad drolahic scintil-
lators studies. In tonclusion. the author, e ressed, the be]AO'ij'~ thst~l iriplet-trip~ei~
VP I I .
transfer must p1q1 &~'significant part in photobi6logical proc6i~ses.'! This paper was
presented at the Thikeentb conference on Lumin'e9`4 %nd Holecw
u1sal, Lumineacence r 'held june 25-JulY- 1. 1964, im* dr ov., Ori~v art,4 'has: 2 fig-
uree and 3 formulas. CJX1
MSOCI&IOIT
none
SUBMITTED: 00 ENCL:. 00
SUP CODE:NPIOP
NO REF SOV# 012, OTHM! .017i *06
ATO M.Es
p
TITLE.- Various types of nouradiative ensrj&:Ar4nsfsr fvWj inwiltUd wolecitdles In
triplet state
SOURM Simpozium pa islamentarap pratisessojo M-11. 11~qfroy. Holstow 1963.
Elementarnyye protsessy khIaLL vysokikh e*ifx
Uy of high energies); trudy simpozluma/xbsi~ov, 1965, 100.
TOPIC TAGS: particle interaction, excited isitivie. phoeph:01im,tisced4a. particle collision
molecular Interaction
ABSTRACT: Various types of nonradlative ene= transfilrAll soild solutlow involvirg
aromatic molecules in the triplet state am discussed. . his filist type occurs during
the sensibilized phosphorescence of organic compounds in'g~lxssji solution at low tem-
peraturiss. The process of deactivation oactirs here &CC61kiLag to. the triplet-triplet
schme
or, + IFA 1rt6 A
where A is acceptor and D is dmr. The pr*ab Uity of the tjAptlet-triplitt emergy
transfer is Independent of the singlet-triplat trowf0rojition !of the acceptor vsolo-
rd 1/2
c
e
L 11086-66
~C C N 5023434
cule. The triplet-triplet type energy transfiW (oonradlamotive), conforom to the Wig-
ner rule of preservation of total spins of tW~ oftimiond Ojo acq~irpitor during the
energy transfer act and the nonradioactive tr4knsfer of elmi~troni~ excitatiom en-Orgy
from organic molecules in the triplet state f4UNS the
In the case of this triplet-singlet transfer the acceptor violecUloi trw3foram into
the excited singlet state according to
3rD + IrA * Ir. + I rA
The triplet-singlet type energy t Irensfer.nee¬ conforai +o'i Wl~nmrls rule. This in-
dicates -that in the absencu of photochemical' veaction the Utemal decay of the elec-
tronic'excitation energy of armatic noleculle~* occurs via ~-Jlplmt state. Ovig. art.
i hass 2 f1gures.
SUB CODEt Guam DATEI MOM/ Opw DZIFS 1X17/ Mi REF:, 00.2
j
2JR
IV 'J"
AUTHOR: Yeratolov, V.
ORGt none
TITLE: Triplet states of organic cowpounds~in evergy tro~sfer
SOURCE, 61mW-glitm Va *1c=njjjXU= Mosc*W jqf"~4.
Elemntarnyye protsessy WaLL vyso Ikh oneigly'(Elementaty pro,4*mses of the chemis-
try of high energies) ; trudy simpoziuna. Moscow, 1965, 1~6;459
TOPIC TAGS: particle interaction, excited st-otel. excitedklect~or,t. state, particle
collision
ABSTRACT: The michanism of ener1q. transfer betsteen 0~aani~ 1%010~iules in solid solu-
tions I liquid solutions and crystals Is discussed, In term ~ c! vo;onance tfi~my - In
solid solutions. if the Wigner rule of preseivatlon of toial spUi Is satisfied, the
energy is transferred frm an orgarAc molecule in a tilplat~ ctatO to another in a
singlet state and Is in accord with the exchaitge-pasonanca ti~kidchat~'Um
,0+ FA I rD + 3FA
where D Is a doom and A Is = acceptor# This ~"*iiplai-trliliqtn~
3 t chanism is opera
tive at a donor ccucentration Intiallid. soluti of S-LO-2-StM-1 ~ioiles/l an4 for the
1/2
a
k
-L-10840-66--
ACC NRs AT502344.1
Istance of 10-15 A. An Ludu4
interwolecuIar d; "_resonz =6V Mechwui= is "rative
and the Wigner, ritle Is not followed when the intermolsculaii,. distimce (donw- acceptor)
in the solid solution in 25-60 X. In this case, the acceptov mlecule converts into
an excited singleit state according to:
3r + Ir + Irb t Ir
D A A
In the oxygen-ftee liquid solution, the enerv transfer Is' 1)~! airlplet-trlplet type
and follows tho exchange resonance methanism.l: In' liquid S~ivrtiwia the UR.-of organ-
Of, ~ b
ic molecules in tiAplet state is 10-r--10-3 sec. in ease enzeindl WPIet -trip, let
tyEe ener do at an appreciable rate ast an 1'j,_ cone-entratiat of
gy trans;Fer procee ccept~v
10 6 _10-6 moles/1 (2930K, [021 = 0, We of the dowwr triplqt Otate 2 10-3 see). The
problems of triplot-singlet type energy transt~r in liquid siolutij !ins and of the trip-
let-triplet type onergy trawfor in crystals romala wuolveC
SUB CODE: SUBM DATE: 23FebG5/ ORM Mr: 6611 !!,VI*H PEr: wo
jw
2/2
_71-6
r
SOME OMNI
AUMOR: Yermolayery, V. L.: Aleitbl% V. Q.; 9a entop Ye. A.,
ORG: none
TITIZ: Detervowbion or th7 energy transport velocity cmatents'la cbelateis of com-
plex rare-earth iims t'_"L'
SOURCE: AN 866H. I Doklady., Ve 165, no* 5, 1965
TOPIC TAGS: rexC~eartb element, nouradiativel!trailAtIon, li ines~ence quenchingj,
electron energy. i6vel
ABSTRACT: . The authors deacribe a method!. -for the d0q.ormination of,
the rate constantiof nonradiative transfer of~eledron anttd~ rare-
Vfrodi a 11gand to a
earth molecule forcomplexes of dibjnzoy2qwth4mtc(DB14) with Sr'vi' and iu3"' and for
acetylacetonate (AA) with Sm3+, Eu3 0 Tb3+ Dy-"v I The, mmstbod 1~ based an the com-
petition between the Intramolecular 11gazd-rare earth tram atitt the intermolecular
energy transfer over the triplet states of organic ~ ligind-ct~jmicbai (acceptor) com-
pounds. The quon6ers used were raphtthalene for AA and acill'iLinso !.wvthrucene, 1)2-
benzanthracene, a#1 pyrene for DEK, The rare-eartb tAmd*dnagnce van excited
outside the abn4n7blon band of the quencher (3340 A for M a)~a 4099 A for DB14). 11he
measurements. were icisde in toluol at 293L Plot +0 are present~W. of the electrorAic lev-
els in triplet-trilget quenching,, of the phosphorescence spe4tra C& the ligand and of
the rare earth amd, of the behavior of the luninexce=e quen6bing a~ant. The results
M. ~i
C,rd .1/2 535 ~73-2
1~ 13631-66
ACC NRs AP60024ft
A ~nera tjimi~tr.befteqm orgs
show that the intermlecular triplet -triplet i~ nic wolec~les
has a higher rate constant than the. lijand--2~ieisrth tii4iti"s ~ vhIch has a Ixigher
order of forbidde '' mesa. The application of ibl'a re"Its t,6 ~n attiartic detertaimtIon
of.the.content.ot.rare earthaby means of re-
e pful to Ac6deWciari
sidues is briefly'discussed. Authors ar .4. U1. Terjq_nfor
interest, and to A. V. KaEZakin, V. A Arkhangolf alwyat andifl, I.; 'Pitaksakov for sup-
plying the rare-earth elements. Ozi t. his [021
ar
a-- ~. -gures j
SUB CODE: 20/ 6UBM DATE:V 16rApr65/ ORIC Pj6..-' 003/ OTRIPEF: ~'012/ ATD rmq-.ellg~
&-Card
ACC NRt AP7004147 SOURCE CODE: UR/0051/671022/GO1/0165/0167
AUTHOR: Yermolayev, V. L._; Sveshnikova, Ye. B.; Sayenko, Yt. A.
ORG: none
TITLE., Study of the degradation of electron excitation In organic molecules in
liquid solution by the method of triplet-trIplot transfer tolraro.sarth chelates
SOURCE: Optika i spektraskoplys, v. 22, no. 11, 1967, 165-167
TOPIC TAGS: energy transfer, photolundnescence, fluor"coac*, tucited electron
state, aromatic hydrocarbon, aromiatic ketone, strosaftc other, orgonoeuropium compound,
chelate coupoundp WAj*#A"d-AWE_
ABSTPAM The controversial nechaniss of do6radation of excitation energy In organic
mAecules, such as 2-acetonaphthone, 2-sethoxymaphthaleneo or naplithalene, In liquid
solution has been istudied by the method of triplet-triplet transfer to europium
t:rie-thenoyltriflui)roacotonate-1, 10-phonanthroline. The nonradiative energy fractia
which degrades on the triple level of the organic donor moleCUle vas determined by
two procedures. Following the first procedure, the lusinesce-nee Intensity of the
evacuated binary solution of the organic donor molecule and chelate was compared
to that of an Identical but nonevacuated solution. The differenco between the lumin-
escence intensity of evoicuated and -nonevacuated solutionst lev -Anoilevo was equated
to the intensity Il.t due to the energy transfer an tritlet levels under operating
conditions excludifig the donor to chalets energy tranater on siniiat levels and the
Card 112 UDC: 535.373o2
NRs AP7004147
reabsorption of the donor fluorescence by the chaletie. The experimental values of
(lev - Inonev) X I--' which are the measure of the fractlon of donor molecules in
monev,
the triplet state, were found nearly equal to the values of CDCD(1 - qfj)qACzA1
where c and C are wolar absorption coefficients and concentrations of donor and
chelate and qfj is the quantum yield of fluorescence of the donor, In the second
procedurep the luKLnesconce Intensity of the evacuated binary solutions was compared
to that bf the solution of the chalate alone on excitation with a 313 nm source.
Under given conditions, the ratio (Iov - Inonev)(Ich - InO460-1 was equated with the
fraction of donor molocules, in the triplet state q This value was found nearly
' N'txperiments that the energy
equal to 1 - qfl. The conclusion was drawn from bot
degradation in the aromatic molecules studied in liquid solution proceeds exclusively
-A& the triplet state. Thanks are expressed to A. N. Terenta. Orig. art.' has.,
1 table and 1 figwra.
tilt)
SUB CODE: 07, 20/ SUBM DM: -16Jun66/ OILIG RUs 004/ OTH MYs 004/
GRE)ITOR, M.A., inzhk; TMOLLTW, VtM. . inzh.
J.
Automatic computer of the amocat of wood In cable netere. Wkh-
I avton prols. 14 no.6:46-" Je 160. (MI" 13:?)
illectrosic digital computer)
.';/147/61/000j'004/011/021
.2 o o E025/E120
AUTHORS: Yermolayev~ V.M:, and Talantov, A.V4
TITLE: Investigation of the effect of pressure on the speed
of propagation of flames in the turbUlerat flow of a
homogeneous mixture
PERIODICAL: Izvestiya vysshikh uchebnykh zavedenJ.y,
Xviatsionnaya tekhnika, no.4, 1961. 82-93
TEXT: The investigation of the dependence of the
fundamental characteristics of burning on pressure are of grent
practical value because this problem in connected with the known
worsening of the efficiency of the combustion chambers at great
heights, The published investigations into the effect of
pressure on burning were carried out for axially symmetrical
flown In a small range of variation of the fundamental parameters.
In most cases the speed of flow and composition of the mixture
were not varied. In the present investigation the i9peed of
propagation of the flame has been varied from 20 to 80 m/sec,
the composition of the mixture has been varied from 1 to 1.5.
CardCY4)
Investigation of ihe effect of ... S/147/61/000/004/011/021
E025/E120
the pressure from 0.35 to 1.4 kg/cm2 and the temperature was
equal to 423 OK. To obtain the best approximation to the
conditions of burning in an engine the experiment was carried
out on a flow bounded by walls in a chamber of constant section
with forced turbulence of the flow. The combustion chamber was
a tube of square section 50 X 50 mm of length 1700 mm, cooled
externally by water. A very detailed schematic diagram of the
experimental arrangements is given. The values of speed of
propagation of the flame in the turbulent flow for various
speeds of the flow, mixtures and pressures were obtained, and
from these were constructed graphs giving the re.lation between
the speed of propagation of the flame and the pressure for
various mixtures and flow speeds. A comparison of the nature of
the relation 'between the speed of propagation of the flame and
the pressure for various mixtures and flow speeds; was made by
the use of diimensionless*flame propagation velocities and
pressure rati,DS. The effects due to.longthening and shortening
the flame are discussed. The following conclusions are arrived
at:
Card 2/ 4
Investigation of the effect of 5/147/61/000/004/011/021
E025/E120
1) The values and nature of the speed of propagation of a flame
are approximately the same in a turbulent flow bounded by walls
and in open turbulent flow. 2) The speed of propagation of
the flame is proportional to the 0.8-th power of the pulsation
velocity, taking account of the dependence of the latter on the
pressure. 3) Damping of the turbulence is responsible for
varying estimates of the effect of the pressure on the speed of
the flame for different speeds of flow and mixtures. Hence it is
necessary to calculate the speed of propagation of the flame
taking account of the normal and pulsation velocities and their
dependence on pressure and damping.- 4) The speed of propagation
of the flame in a closed turbulent flow is in good agreement with
theory when the effect of damping of the turbulence is eliminated.
5) The decrease in the speed of propagation of tho flame with
fall of pressure is one of the causes of decreased efficiency of
the processes in the combustion chambors of primary ginginon in
high altitude conditions,
There are 10 figures,
Card 3/4
Investigation of the effect of ... S/147/61/ooo/oo4/oll/021
E025/E120
ASSOCIATIONI Xazanskiy aviatsionnyy instituti KaZadra teorii
aviadvigateley
(Kazan' Aviation Institute, Department of Theory
of Aircraft Engines)
SUBMITTEDt April 31 1961
Card 4/4
YERMDLAM YIM.L TALANTOV, A.V.
InvestIgating the effect of pressure on the bingth of the con-
butation zone in a closed turbulent flow of a uniform mixture.
I2-v.vya.ueheb.zav.; av.tekh. 5 no.3tl43-156 162. (MIn 15:9)
(Combustion)
41UXOV,, G.1b.,p I=h.; MMOLAMWIJ.A,
Coaferonce an inpro"ment of offloiiency in tb* pleettio
oquijpmat industry in tho lJralm# Vest# sloktr~wvmo 34
no.2:76-77 7 163o (KM 16:2)
(Blectric equiFmont industry-Congresses)
4W)~AMYO.:. V..M,.; TALANTOV, A. V.
Rate of flaw propagation in an open and lijkit*d fLow of bcsogens-ouis
mixtare, Izv.vys,,uchsb.znv,jav.tOkh. 7 no.2s134-141 164,
(lam 171())
Y,
I"Fd,X-J4 4~,
PIIASL 'I Trtntauro In.1-ind RtbUlorraphlc !1orq-t-t
BCOK 140.1 '4c.: TU',~~'71 Nol"?
Authors;- ErVIGLAFIr. y. I., and y;o,,vjz-rj,, is.. 11.
F'all Titlot F(K--4Y,IJI (F "MIUCTURAil
Transliterated Title: Manter strukturnof.-o burentia
Publishing Data
Originating Agency: None
Publishing House: State Scientific-Technical Publishing Hous.? of Cil and Viner-I
Fuel Literature. Leninarad BrZ'Lnch. (Gostoptekhizz~at)
Date: 1952 No. pp.: 318 No. copies: 7,r)00
Editorial Staff'
Editor: Gridin, V. K. T-~ch. Ed.: 'kne
Ed.-in-Chief: PerminQv, S. V. Appraisor: 'Icrie
Text Data
Coverage: The book cr..ntains elementary data on ge6logic.-il structures, conc3tructlr~n
of derricks, arrangement of equiTwient, types and quality of drilllii,~,
tools, and characteristics of varicus materials (metals, lubricants,
transmission belts and transmissirn cables, cement, luvber, etc.) uswcd
in well. drilling. The practical methods of drilling wells for !-eo1(-,fjcI-1--l
surveys (mapping), structural, and prospecting dr-iLlIflir are
Plso, method3 of computinp simple work probleirs unj rat'r!"; of tiril'iln,---
through various strata.
Purpose: A textbook for well drilling foremen and personnel eng,11,.ea in survey-I-Ir
and prospectinf-.
Fac.iliti~s: licne
No. Russian References: 11
Available: Library of Congress
TWMOIAYEV, V.M.; KARAMZIN. A.Y.; KOVAIRTA, AL.A., inzhener, vedushchly
POLOSM, A.S., tekhnichealriy redaktor.
t3truct-mral boring; practical manual for workmen] Striaturam
burents-, prakticheakoe posobie dlis rabochikh. Mosicra, ks.
nauchno--tekbu. Izd-vo neftianoi i gorno-toolivnol lit-ry, 1954.
138 P. (MM 8:1)
(Boring)
.............. ....... ....
"INO V"IIL#yevlc&,* .qvich;
r
ummirem.y., redaktor; 1motilmovWr., r;
I.M...-tekbilabseldy redaktor
[Drilling structural and mploratorywells3 Burents str*turno-
poiskarykh ekwashin. Leningrad, Goe.asuchno-tekkno lvd-vo neftia-
not L Igorno-toplLynoi lit-ry, 1955. 36) p. (KLRA 9:3)
(Boring machinery) (Oil well drilling)
I v .414- U41~1-1A
MARAVIZIN, Aleksandr Vasillyevich; MU40 - - &A-h
.LdIcjamiL, SHEVTSOVA, . .. ved,. red.
(Boring structural prospecting holes] Burenie strukturno-
poisk-OV,Ykh skvazhin. Izd.2.p isp. i dop. Leningrad Ned-
ra,, 1964. 390 P. (MIRA 17;9)
LYtJBCH=Op A.?.; )Z-FM-OJAW-t-V.Ue-
Effoot of cerium on the self-diffusicin of iron, Fix. note i
astiMoved. 3.4 no.lsl57-160 n 162. (111M 15;7)
(IroD-4%tallography)
(Cerium)
SOYA IN., A.I., insh.j IZMGLA32VO T.H., insh.
Technology of-blant furnace pa purifioation andAle design
of scrubbers. Stall 23 no.2t176-1778 F 163. (MIU 16:2)
1. MagnitogorsIdy metallurgichesidy kambinat.
01ases-Por,4-fication)
(Scrubber (Chmical technoloa))
V
jERMOLRYEV, V'P-
MOLf r1j, V. P. . and 114. P. MY(MUT.
----- ------ --
Pamiatka nomirovshchiku-strolteliu, 'Poskvii 4 M15
j 15h8o 70 )~i# s ro
At head of title: Nauchno-issledovatellskii aerodronnyi Institut
VVS Vs.
Title tr.: Instructions of wq)erts 1n setting constructlon work
standardso
TL?25.2A
SO: Aeronautical Sciences and Aviation in the Soviet Union, Library of
Congress, 1955.
- -XC - -.Te- V
F RPTA KE U,-A c 9 1 13 2 ~Urgory Fab 59
868- (316) EXPERIMENTAL PARENTERAL PROTEIN NUTRITION IN SUPGIC-
AL PATIMNTS (Russian text) - Ermotaev V. P. - KHIRURW.4 Igs-f, 9
(97-102) Graphs 3 Tables 2
Data concerning metabolism in Wlents following operations on the gaMro4nt~NtjnaI
tract and In burned patients are presented. Pronounccd neilat1ve nitrogen balatice
(7-12 g.) was revealed In the postoperative period. In burned patients aW in cu,ses
with postoperative complications nitrogen balance equittled from 30 to 35 it. In 34
hr. There was it lose of weight and reduced content of protein in the plazins. lPro-
loin was administered parenterally In 20 postoporalive cases and 1h 5 ease* with
burns, and 55 Lv. injections wore carried out. In 12 cases untoward Mde- reactions
were observed, which were severe In 5. Aminopeptide - a new prepaimUout of
heteragenic protein. fermentative hydrolynate of whole animal blood - was investig-
ated thoroughly. It was tested clinically in 174 patients (85 postoperative 4u-4.89
burn cases). Aminop*pttde was administered I.v., I.m. and s.c. in a doze 14 800-
1,500 ml. (III to 20 injections to each patient); 2 patients had fever and chilLs. In
order to determine the efficacy of parenteral ad ministration of &minopeptide in
28 postoperative and 12 burn cases, determination was made of nitrogen talance,
protein content of blood plasma, excretion of urea and amino rdtrog*n in the urine.
The results of these experiments show that sminolpeptid* has no snaphylaclogenic
Foropertles ond to rat toxic. Nitrogen, administored in this form, to Sleadily assim-
lated by thit Organism, irrespective of the method of Its introduction. It in poss-
ible to maintain nitrogen equilibrium and a positive balance If an adequate dose of
aminopeptide to given. Clinical observations and Eaborstory examinations 311ow of
the conclusion that aminopeptidt to an effective pr"ration In Parente-rol protein
nutrition In surgical patients and its recommendation for wide clinical use to
warranted
'Af
YMXOIAYNT, T.R., kandLUt meditsinsikih nauk
XoWleatlon of prot*Ln a*taboUsm; in mono surgical tients with
parenteral infusion [with suw&&V in Uglish, p. 157rirest,ktdr,
77 w.6:12-17 Je 156. (XLRA 9:8)
1. Is gospitallnor khtrurgichemkoy klialki (nach. Prof. 1.S.
11olsonikov. nauchn. rukoyod, - prof o S.SAirgoICIT) lroyenno-seditain-
skoy ordena Lenina akadexii Lm. S.R.Kirovs. IsaWrad, Botkinekaya
ul., d.19, kv. 126.
(IMUSION, FAMONUAL,
protein hydrolyeate in protein depletion in surg. (Ram))
(noings,
hydrolyeates, parentorvil infusion In protoin depletion
in surg. (Rus))
(SuRany. MUTITI. Complicatlons,
protein depletion, tho.v protein )V&olysate parenteral
infusion (fts))
YKNOLAIRV, T.R., kancl.med.muk (Ioningradt 9, Botkinstays ulal. d*19, L-v#126)
WANNION
basis and embolism of the pu2nomary arter7 folloving luxNg
surgery [with sommory in Saglish]. Teat.ihlr. 79 no.9t55-62 8 1579
(MIRA 10:11)
1. Is goopitallney k1birmVichookoy klWki (rAcho - prof.' I*$*
Calsonikov) Vaemao Itainskay ardons Ionim skademil In. S.N.
Kirovs.
(ANURM, FulAvlaff, dive
I 4albollon & thrombosis after Ina surc.)
(Pommnom, cowl.
so'bollso & throsibools of pulime artery)
YMNOIAIW. V.I.. icand.wed.neuk
arenteral orotain nutrition for surgical patients Evith sw=ry
in %glishl'. Khtrurgilm 33 no.9:97-102 5 '57o (MIRA 11:10
1. Is gospitalluoy khirurgichookey klinilki (nach. - prof. 1.S.
Ulsenlkow) Toyenno-maditainskoy ordens Imenins jiksdftil imeni
S.N.Alrova.
(PROTIMp there use
pore burns & postope core, perenteral admin.)
(BUM. there
proteins, parenterel admin.)
(POSTUMATIVX CARZ
parenterel admin* of proteins)
(IXPMIOMB, PARIWXRAL
proteins, in burns & postope cars)
TWHOLAYN, V.I.. kandeved.nauk; SRATALIDVA, N.A.0 kand.med.nauk
Chronic atelectasis of the middl lobe and lisCils, of the lunC
of varied etioloj7 [with sumaa:7 In AnglIsh]. Tsmtokhir. 82
no.1:86-93 Ja 159. (MIRA 12:2)
1. rs gospitallacy kh1rurgicheskoy kliniki (nach. -.prof. 1.S. Ealse-
nihm) Toyanw-seUtminskey ordena Lenins akadosit Ineul SoNs Kirovae
Adrom awtora: Leningrad, 1-9, BotkinsWa ule, 4-23, gosPitallwa
kh1rurcleheskeya klinika.
02SUMAS18v etlol. & pathogen.
chrente. of al"le lobe & HWIs (1hu))
YEMOIAIEVp V.R.v Wor meditainskoy oluzlibyi, kwAmed#muk
. "
HoLung Of VOWAN containing a foreign body foUxdj* tota.1,9wy
irraflation of snimalne VoenspookLesbure wel#sW Ap 060
(M& :L4:1)
(I(Oum) (RADIATION-PUM Tol, CT
--.nMLATBvs- V.R.p kandomed,nauk
Arulsion of the nain bronebw ft blmt tmm& of tbo thorax,
adrall" 37 so.103-17 Ja I&L. (Him -use)
Is lv.,Vsp#al'wy kbinrgioboolcoy kliniki ("~v, - ;rd, IJ.
Koleslik*) %y o-meditsirAkay ordma Umiza ekdadi immi
SAO Kirevazi
I(C=T-4V= AND WORM) (NO=-4WM AND MURIES)
MUMMK(ArA, A. T., kand. mod. naukj TIUMIAM, V. R , kand. mad. nauk
Aeutw gastric obstruction caused by complete Waxattan of the
left half of the diaphrup with transposition ~f the stomach,
ap3min and left lobe of the liver Into the tho"i-Ac cavity.
Mdrstrglia 37 no.7:87--90 J'l 162. WMA 15:4)
1. Is k3in4ki gospitallney kidrurgil No. I (useb. P"fe I* SO
Solemnikov) Voyenno-weditsinakay ordens Lenina &Wemil - Imeni
S. M. 11raft,
(DIAPMUW.--DISZASZS) (ROWN) (UM) (SPIM)
YMOTAYW, T.R. (Uningrad.. K-9, ul. Smirnova, d. 10-es, k7.22)
Burg-Ical treatment of late Bronchossophageal fistulas. Grudn.
khir- 4 no.59132-1.13 S-0162 (MIRA 170)
1. Iz kliniki goopitallnoy khirurgil No.1 (naalmlInIk - prof.
I.S. KC esdkov) Voyenno-medituinskoy ordena Lenin& akedemi-'A.
imeni. Kirova.
ul, Sul~smd.10-ap;kwo
nRXDIAl13Tq Y.R. (L*nlftWo
:EntrsPlvmsl b"UTW4PO fOlIAW189 r"I"l Pulxmwry mwgin7-
t,'.rod.khir. -ho.446-& JI-4 162. (MM 15: 10)
:1. IS Irl4n4lr4 gogq)JW'wy khirunil go. 1, (wwh. - prof. I.3.
Jolemnikov)V*nno 4wlltslmkoy ordena Unins aWadi.bwni S.M.
Kira".
INMAMW V.R. kand.med.nwk (Uningrado X-9v UIq Salmoval d.10AO
late results or the stirgical treatment of bronabiectasis. Mn.
Irbi vOqnsUo%U N 962, (MM 16 Q)
Io, Ufafta gospitallnoy kbIrnr#i (macho, - launat Immimakoy
pradi pror, LS. Koloodkovi voyamm-esditaimAroy Ordens,
ladna akRdoLU imeni Box. Kirov 0
(~CHIMASIS)
MMOIAU.V,q V.A. (Leningrad Y,,-3, ul. Sairnova, d. lQa,, kv.22)
Segmental and combined reaect-ons of the lungs in bronchiectuls.
Grud.khir. 4 no.6.*59-66 14-D'62. (141itA 16:10))
1. 1z klirdki gospitallnoy kNItutgii lio,l(nac'hallnik -prof.
I.S.Koleard3cov) Voyenno-meditainakoy ordena Unina akademii
iwnl S.14.Kirova.
(BRONCIII-DISMES) ( LUMS.-DUMBRY)
YERMOLAYEV, V.R., kand. mod. nauk
Priwa7 failure of the bronchial stump and the pulmonary
woUM following radical operationip on the lungs, XhIrurgiia
38'6,1204-19 D 062. (MIRA 17:6)
1. Iz gospitallnoy khirurgichookoy kliniki No.1 (nachallnik -
prof, LS, Kolesnikov) Voyenno-seditainskoy ordena Imina
akadadi imeni S.M. Kirova,
KOLESNIKOV Jq I.S.,, prof.; FUTOV, N-V., prof.1 YEPMULLM., V.R., kand.med.
nauk; SOKOLOV, kand.med.nsuk
Acute blood circulation disorders in the residuia lum part
following patrial g*sectionse Ve.9t,khir.90 no.2028-135 F163.
(MIRA 16:7)
1. 1z gospitallnoy khirurgicheekoy kliniki (n*cWd'n:Lk prof.
I.S.Kolesnikov) Voyanac-moditsibskoy ordena leaLra Pkademil.
imaid S.M.Kirovas Adres avtorovz loeningrad3 Botkinekaya u1.,,
d.23, Gospitallnaya khtrurgichealmA k2inika Yoyenno-medietisk-
skoy ordena Lanina akademii imn:L Kirova.
(LUM4-SURGERT-)
(BLOOD-GIRCUIATION., DIBORDFM CIF)
JERMIAM kand.med.nauk (Leningrad, K-9,, al. Smirnova, d.10-a,
lz:~Ik-v.2.i)
Resection of the lungs in bilateral bronchiectmis. Vest,,
khir. 90 no.3:11-19 W163. (KMA 16:10)
I* Is 1-y gospitallnoy khirurgichookoy k"nik' (naebalinik
prof* IeSoNdlesnikov) Voyenno-maditainskoy ordena lanina
akedemii imeni Kirova.
(LUW6.SUHGFM) (BENCHIETABIS)
rI.RMC:-k'rFIIT, 'I.R., dotsent (Leningrad, ul. SmIrnova,
Some chara3teris t 'Ice of tl-.-e terhm'yue of -lunit,
bronchlertazi.s. Vest. kh:Lr. 1~1 no.9s2rj-2'1 j16,1.
1. Yz gn~tpital lacy kW-urglcheakoy klintki. (rrwh:t~ jr~'-Ic
I.S'. K--IP-ozi'Ikcv) Voyenno-meditalrio?v;y rd(tn,
iment S.M. Kir:)-m.
KOLISNIKOV, I.S.; ORDZHMIKXMO G.K,; SMlWHMKIY, 14.1t.; XW V.R.
UKU-BrVSKIY, F.I.
Adenoma of the bronchij, their camplications and operative
treatment. Orud. khir. 5 noe6llM,-106 N-DO63 (MIMA 1712)
le Is kliniki goopital9noy kbiTurg:li (nachaltnik - prof. 1.S
Xclesmikor) Voyanno-meditainskoy ordena Imina akademii imeni
S.M*Kirova. Adres avtorovs LeningradiN-9. BDtkinskaym ul., d.23.
Klinika gospitallnoy khirurgii Voyenno-meditsinskoy ordena
Lenin& akademii imeni S.M. Kirow #
14(5)
AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
Card 1/~
SOV/127-59-3-8/22
JermolqZUJ" 9 Bakal.eynik, YaJA.. and Vinogradov,
L.V-. Engineers.
The Semi-Automatic Control of Mechanisms in the Mine
Shaft.(Foluavtomaticheskoye upravleniye mekhanizmami
ahakhtnogo stvola..)
Gornyy zhui~nal, Nr 3. 1959, pp 31-33 (USSR)
An experimental installation for the semi-automatic
conVol of hoising mechanisms in the Kapitaltnaya
Nr 2 pit of the Degtyarka Copper Mine has BUCcess-
fully passed industrial tests. The installation was
developed by the KB TsUA (Design Office of Tsvetme-
tavtomatika) in collaboration with the Degtyarka,Mine.
The maximum utilization of already existing mechanisms
64uipped with pneumatic gear was taken into constdorat-
ion, Air distributing devices VR-350 ( figure 1)
developed,from ENIMS air distributors, are used in the
system. Two men in the hoist cage direct different
operations in the hoisting shaft. The system is des-
SOV/127-59-3-8/22
The Semi-Automatic Control of Mechanisms in the Mine Shaft.
cribed in detail (figure 2). The introduction of
this system in the Kapitallnaya Nr 1 and Nr 2 pits
will permit a reduction 30 men in the working
staff. This represents :1 yearly saving of 340,000
rubles. There are 2 diagrams.
ASSOCIATION: Tsvetmetavtomatika, Moscow,
Card 212
EPYOTAML.L.L
....Owwwp-
PhytcpleLnkton of lake Krivoye of the Warasuk River system. Trudy
TSSBS nci.802-96 164. (14IRA 130)
L 01293-66 :;.IT
AMMM MR: AP54017080- Wogqo/Wod
i 581,526-325
1AUTHOR: Yermolayev, V.,
VITLE: Primary production of lakes with lovered;wat
northern part of t1me-Kh1undisk Steppe
SOURCE: AN SSSR, 141birsko7e otdolenlyso .X06sttyas
.biologo-meditsinskII& naukv no* l# 1965P.14-99
TOPIC TAGS: lake, hvkojoW, algae, photosynthomiss
respiration# plant ecology
ABSTRACT: In 1962 phytoplankton production of Lakel
(Narasuksiy Ra-yon of Havosibir'sIcala Oblast') was!itx~~
its water level was 35 am-below normal# an
production of Lake-Kusgan.(in the sam ra
m.] gn) wai-` iii
its water level was. 1L9 em belask na . A vtonl anirt'
~0,03) 009h/0"9
10V,18 .131 61
0~iy4l
I)Ianil
when
when,
(M Iff
6m)- imdat---dt~M -dr- i.- -im --1-4-6 - a LOY -t,1666 -to
pie 9
Septembem, 'At the sime UW irstor dMploO (0015 1) liewe flite
determino ttio mmbisr or sigios ooutdalii dftd, 66116 amd tive Omouftt of
Card 1/3
Y
L 02293-t~6
ACCESsioil NR: AP5017080
Aritensity
phyto lankton biomass* The ooeffici6nt ot~ph6tosynt~vdia;'
P
and respiration intensity was detatmined and the it, of, ox;rgen
released. per hectare of Uka awfaoe at aAean da'pth 41T 101.1 M'Was (LIMC
deteinninede Findirtga.show that- both laked at':Iow9re4Gi4atm1jv 1TVals
maintained their J*LOtOsynthetie aotiviit7 des its' a S'ii-pinglani; levol
of dissolved salts in the water (1000 to 1999 ;;/1)., ~~Ihe !1sor-s-inal
oxyg;)n -production of Lake Xuagans which,. is ~more shallix( aT11 itiore
mineralized than Mike. KrIvoje# was aignif toantly ht .111 ir Moth bodiso
of watQr'are oharaoterized by intense devOlopment P algae
duritag the sumnor nonths, As: a rule, Oeai6nal ohan lit'l-ytopla&.-
ton 'production ohmr that with increased nl~mbero of in a
given unit of voluxies the intensity of its. photo~jxJ-WIJOIS ~IJJOWO&13004
Howeverg no true correlation wds established betiloon thm OaIues of
true ph-ytoplemkton photosynthesis (coefficient. oP plu"400 ,
intensity and respiration intansitjok PhyOPI'mWiOn jPOIUibei:jm# and
Ph`ytDP1ankbon biomswe Orig., art* has: 4,tOleo.
ASS011JIATIONs TAMral'tn7l Sibirskif, bbtWchesi .1i arid Siblipokogo
otdoleniya AN OSSR11 Novosibirsk (Otntodl: Siberian HotoliaA Garden 6f
the Siberftn 13ramli ff SM)
L 01293-66
11COESSION NRI AF54017080
UBM ,..
ubtrit
60
~,Goollp
RR MW sovt :,
i v! i,
Lot m
W-66-
KC NRs AP5025697 JD r,/, scums 6(563t:: UAM86~
RX
AUTHORS:
111 a oi I- - -- I
ft,4 1~ 7.77
Razava7sv. Go A., Akol '80
CI]LS/OD47/0047
Au
I,'
Ar, I A
T IWIb
;No* 174697
SOURM Byulletenl lacbretwAy i tovarny1ch anakaw, noo
TOPIC TAOSs electric. resistarp chromium.. nickel
ABSTRACTs This Author Certificate preal 'hoa'foi:Ma*d)
vit ad
electrical resistors by vac=m dopq WI%r gr-I Ii3nnto
f-JIM to th6 InAttubing, ty~ Him
da thin filis
beaO.'
rA to deargane
L. T
49 351.ai6, ixoW :1
Card 1/2
I III "T I
''Issmunw.
Winter phytoplanktm In I&M Irivoys of the laremak liver vm+4m.
-Trudy TUS wolosi*.49 165,
Pbwt%"akton In Lalm Studessys of W Luua River Systea.
-Ibid. 350-% (KDtA 18310)
S/l95/6l/o153(2?11(?03/O04/0O9
As-/ 0 2030/Z452
AUTHORS: Molin, Yu.N. and'Yormolayov, V.K.
TIM: The causes of the change in proton relaxation time
during irradiation of aqueous solutiona
PERIODICAL: Kinetika I kataliz, v.2, n0-3, 1961, 358-361
TZXT: Hitherto the decrease in relaxation times have been
attributed to the formation of free radical a, bu calculation shows
that improbably high concentrations, 1017 to 101A 9-1 would be
necessary to give the size of effect observed'* The present work
therefore resolves this question by irradiating solutions of
hydrogen peroxide and also distilled'wat*r, h*xan*,, benzene and
solutions of benzoyl peroxide in benzene, and aqueous solutions
close in concentration to those used*previously by Y.M.Ydovenko and
V.A.Shcherbakov (Ref.2: Dokl. AN SSSR, v.127, 127, 1959), and
observing simultaneously the NMR signal and also the RPR signal,
the latter indicating the formation of any parama4pietic bodies,
including free radicals. The apparatus consists of an EPR magnet,
with a hole drilled through one pole, to admit a boam of fast
(1.6 MeV) electrons. The specimen in hold in a Slass ampule,
diameter 7 mm and volume 0.25 cm3, which in located close to the
Card 1/3
313.9
S/195/61/o t/003/004/009
The causes of the change ... 9030/9452
opposite pole to minimize the field inhomogeneity dud to the hole.
The NMR field coils are wound on a former which slides over the
ampule. ++ The MIR signal in calibrated with standard CuSO4 solutions
with Cu concontrations of -OW17 cm-3; the sensitivity is rather
less than in previous work because of the Increased field
inhomogeneity. The %pecimen of 30% stabilized impurified H202 was
-irradiated at 6 x 10 rad/sec and after 2 min the amplitude of NMR
signal, which had increased rapidli within seconds reached a high
steady value. equivalent to 4 x: 10 9 ions Cu*+ cm-1. On removal of
the irradiatibai, the signal fell over some 30 min to about one thlid
thinvalue and then appeared constant. It was remarkable that all
this time thero was no observable change in the RPR signal, thus
precluding the formation of a significant concentration of frte
radicals. Similar results were not obtained with the other
solutions. The only plausible explanation of the results is tha'~
the relaxation time is decreased by supersaturation into free
oxygen, which is known to be formed on irradiation of hydrogen
peroxide; thiis is confirmed by the lack of signal in the other
solutions indicating that not more than about 1017 cm-3 free
radicals could remain undetected, and by the failure of the signal
to revert to its initial small value in H202, as should have
Card 2/3
309~-9
S/195/6l/OU2/OO3/Oo4/ooq
The causes of the change 3030/E452
accurred if formation of free radicals were the operative
mechanism. Ackmowledgmonts are expressed to Y.Y.Voyovodskiy and
N.Ya.Buben for their interest in the work. There are 2 figures
and 9 referencesi 6 Soviet and 3 non-Soviet. The references to
three English language publications read as follows.
Ref,l; V,T,Duft*y, Bull. Amer. Phys. Soc,, II, VA, 250, 1958;
Ref.8.- J.G.Marshall, P.V.Rutl*dge, Nature, v.184. 2013, 19W~
Ref.9: G.Chiaratti, L.Guilotto, Phys. Rev., v.93, .1241, 1954.
ASSOCIATIONS: Institut khimicheakoy fiziki AN SSSR
(Institute of Chemical Physics AS USSR)
Institut khimicheskoy kinetiki i goreniya SO AN SSSR
lInstitute of Chemical Kinetics and'Combustion SO
AS USSR)
SUBMITTZD: October 31, 1961
Card 3/3
35062
s/195/62/003,1001/00/Clo
E071/E136
AUTHORS; Yermolayev, V.K., Molin, Yu.N.* and Buben, X.Ya.
MW -
TITLE: Recombination of radicnis in solid organic substancea.
I. Investigation by the method of fusion ,
PERIODICAL: Kinetika i kataliz, v.3, no.1, 1962, .156-611
TEXT: The range of temperatures at which rCcombination of
radicals takes plAce on fusion of various organic substances,
irradiated with fast electrons, was studied by the 3np (EiLiz)
method. The object of this work was to determine the molecular
movements leading to the recombination of radicala in a solid.
For this reason the substances investigated had a known phase
behaviour on heating. Normal alcohols, ketones, hydrocarbons,
aromatic compounds etc. were investigated. To dotermine the
stability of radicals at various temperatures, fusion curves were
obtained. For this purpose a substance was irradiated at a
sufficiently low temperature To in a stream of fast electrons
to obtain a concentration no of radicals, The irradiation was
stopped at the beginning of the linear part of the curve of
accumulation of radicals (no PO 1019 radicals/&).
Card 1/3
Rocombination -of radicals in solid ... s/195/62/003/001/003/010
E071A.136
The tenperature To was so chosen that during 10-15 ininutes no
noticeable decrease in the concentration of radicals occurred.
The substance was then heated for 2 minutes at a temperature
Ti '.>T0, cooled to To and the concentration of radicals n1
measured etc. The dependence ni (Ti) was called the fusion
curve. It was established that for crystalline substances
(substances of type I) a rapid recombination of radicals occurs,
as a rule, before melting; for amorphous substances the process
takes place near the divitrification -temperature. For cyclo-
pentane and cyclohexene (type 11), radicals recombine near the
temperature of their polymorphic transformation. For hexamethyl-
benzene, acetone, succinic acid (type 111) several ranges of
recombination of radicalB can be separated. In the majority of
cases the recombination of radicals is, apparently, caused by
self diffusion, appearing close to the temperature of a phase
change. For substances of type III the recombination of radicals
takes place at; a temperature at which the self diffusion of
molecules is apparently absent, e.g. in hexamethylbenzene and
acetone, radicals recombine partially in the region at which
Card 2/3
Recombination of radicals in solid ... S/195/62/00/0011U63/010
E07.1/E;36
the molecules begin to rotate. The recombination of radicals in
the absence of self diffusion could be explained by the formation
of radicals cl()se to each other, e.g. on the neiglibouring
molecules in pitirs, Then initiation of any molecular movement
may lead to their recombination. However, the f6riflatiOn Of
radicals on ne:Lghbour-ing molecules should be accQr-.pan;Led by a
strong widening of components of the superfine structure of the
EPR spectra, mtch higher than was actually observed.
The authors thank V.V. Voyevodskiy and G.K. Voronova for their
assistance. Part of the material of the present r.~Lper was
presented at the Second All-Union Conference an Radiation
Chemistry. There are 5 figures.
ASSOCIATION:-Institut khimicheskoy fiziki AN SSSR
(Institute of Chemical Physics, AS USSR)
Institut khimicheskoy kinetik! i goreniya SO AN SSSR
Card 3/3 (Institute of Chemical Kinetics and Combustion
SO AS USSR)
SUBMITTED: August Ili, 1961
4~236
3/844,/62Y000/000/056/129
D204/11307
AUTHORS:,,,-Yermalla Holin, Yu. V. and Buben, N. Ya.
'IMSY
TITLE: Recombination of radicals in some frozen organic compounds
SOURCE: Trudy 11 Vsesoyuznogo aoveehohaniya po radiatsionnoy khi-
mii. Ed. by L. 8. Polak. Mose-ow,jod-vo AN SSBR., 1962,
331-334
TEXT: The pre6ent work was aimed at a study of the molecular mo-
tions occurring during the recombination of radicals formed under
the action of fast electrons at a temperature To, such that no, the
number of radicals formed, remains fairly-constant over 10 - 15
min. The compounds were then warmed up*to a series of temperatures
Ti (where T i> To ), maintained at Ti for 2 min and cooled badk to
Tor at which temperature the remaining conecitrations of xudicale,
niq were measured. In cystalline compounde,'duch as MeUH, C 6H6 or
n'oetanol, the :mdicals 4~qajjpeared at 0.9 1.0 T (where T
M m
Card 1/3
U %62/000/000/056/129
Recombination of iddicals..r... D20,4rD307
m.p.), whilst in poorly crystallizing Elubstlan~bes, such as glycerol
or n-butanol, the recombihdtion took place in~ the region of vitri-
I
fic9tion (0 , .6 - U.7 Tm). Tifts rule was confir'med on slowly frozen
(crystalline) and quenched'(amorphous) 191-di'cyclohexyldodecane;
cooling at an intermediate3rate gave rise to '(ni/no) versus' (T.
m
plots of an intermediate dhbLracter, shoving the presence of cry3-
tellites of varying temperature stability. Such intermediate type
curves were the only ones oboerved for paraffin, polyethylene and
polypropylene. The recombination is connected with partial destruc-
tion of the lattice and amorphous compounds rest)ectively. In cyclo-
pentane and cyclohexane, ia'which molecular rotation begins at T rot
(T rot 14 Tm)q it vras found that recombination of the radicals took
place at T rotv showing that'the radicalvare probably formed in
pairs and'recombine as Boorr as rotation becomes possible. The as-
sistance of V. V. Voyevodskiy and G. K. Voronova is acknowledged.
There are 4 figures.
Card 2/3
Recombination of radicals
ASSOOIATION: Institut
Chemical
kinetiki
K,inetics
LISSR)
$,/844,/62/000/000/056/129
D204/D307
khimicheakoy fisiki AN 603R-(Institute of
2hyeical AS USUH); Institut khimidheskoy
i goreniya SO ILK SSSR (Inat'Ltute of Chemical
and Combustiont Siberian Branch of the*AS
Card 3/3
YERMOLAYWs V. L.
PA 175T77
r
lye
Teiji*~reti is of
t ur
0 a P4r
9
4"stwikov,, V. L.: Yei
J~: Dok Ak Nauk. SWR" V61 LW NO 1: 4 ppy
k5tudies variation ixi
phoophorciscence,of OcLe. i63z ti
]Avin et t t -0-114 d4r*&~
n co o:
W,v ncu of-activai a, t
W ': -I
0,
he' of isiditins:
6.UtaittedL
r4tv litt, eitt, A .4.,
...... IGAIIIC M'dil,
MES AT. t xTZ MP
*!Jj~At Pri Mzkot
Temp"criturd). A.: K. Te
4w bp 0. Sol froiri Old" S.
vLvttdta lit-46( lap,,
An xtttt*Vt two f 4('thihj~ of exlItArl
99
onarjr in co erat
one WgIocMIG to ttcu~~' a( a-
tumustemenco of
t4,11wd
teduldi im
wbero thip prim"y Im f it 0 lit O"imuldi 06
tit 4 muldi im
USSR/Physics - Phosphorescence Sensiti- 21 Jta 52
zation
"Sensitization of Phosphorescence of Organic Male-
cules. at lov Temperatures: Intermolecular Trans-
fer of Energy With Excitation of the Triplet
Level," Acad A. N. Terenin, V. L. Yermolayev
"Bok Ak Nauk SSSR- Vol 85, No 3,,Pp 547-550
Ditc-asses investigations devoted to the,problea of
t*ansfer of excitation energy in soIns of mirts of
f-h-orc=11-us- 9-r-1-am-tic-mols st te*p of liquid air--,
fvr--the 7urpose of establishing the 'phenomenon of
sensitimtion of excitation by one compd. of the
A Giver, t a
Z;VU_DI_rQi7J_-i PhOSPbor&acence of wwl=a dc*4d& in
dijendlence on conen of another. Submitted 3 May 59-
235T92
phoophorescence ot ax=mtI*to*.u~Aj!
Periodical 1 Dok. AN SSSR 102/5, 9125-928, jrt~, 3a 2.4 51
Abatrtat I An experimentea otudy wapi, a .~i of th'O
Ond=t ienditin44
4
,ae- of t: in 1
all
~,Osphore nce and the. doU= atj
TEMNIN, A*N. ; ,Y=~WA~!Wj%hp.,t
Intemolomlor transfor of onera owurrim In sonaltised luminesconce.
lzv,.AN SSSR. Sorf1s, 20 no*40W Ap 156. (MU loa)
(imlawam) (I%wmaowo)
ern*-NO'tf~\JQ-NI VL
USM/Optical - Aysical Optics K-5
Abs Jour fteferat Zkur - Fizika, No 5, 1957, 12962
Author I sFM' V LW---
Inst
Title Sensitized Phosphorescence of Aromstic Compounds (Baergy
Transfer from Triplet to Triplet Level).
Orig Pub Ity. AN SON, ser. fiz.,, 1956, 20p no 5. ~1"19
Abstract A quantitative investigption was mode of the phenomenon
of sensitization of phosphoresewces comected vith radia-
ti(mless migmtion of the energy of electron excitation
between the molecules, vith the excitation ofthe triplet
l4wel. For nor details see Abotract 12961.,
Card 1/1
T:
t1ft/Physics, - Luminelpeence
Pub. 118 - 2/7
Authorm I Tereniii, A. No and' Yermolayev; V. 1 L.
S Intormolecular transfer. of onergy, :~11 ~htt phimoi 0, 1 0-r!
.Eli rill itized
lurdineseence of organic Symema I t' 11)
Usp. Fiz. nauk Jan 014
58/1,# 37-689
I The intemolecular tran-S'far of ovlem~fly ikeer-4wt "I'l III-%
, ;
an the sonAtization of
prglxdv~ I
Two types of energy transfer:am- cl4nrAA~rvdi 01 'ItAc mm" lnlluctivu~.
Varimis cases are analy?ed ~rt whicH emAtiie& 1111,110111 and thh
enerj7,,r tran-ifur vo-re obsvrvoi~. B Gum., 121 UI;A,
28 USb1t (1927-1955). Gra-phs d i a I..rv', an So.
inst.itution
i Submfitted woo.,.
m
YANOZATNT. V. L, XRMCEMOV, T.T.. SN=14N, N.M.
-- 1013
Nodorn mignallng, central control mad block mystem ovdPwat used
In underground electromotive transport. MborostrooUt no,12:2-5
D '56, (Submwo-41analing) (fttematic control) (MIRA 10:1)
AUTHORS$ Daitriyovskiyo 0. D. 0 Yeraglaxas, 2o- 114-4-20/63
Torenin, A. X., Nombor'of the Academy
TIT18i Direct Measurement of the Lifo of Excited Molecules of Chloro-
phyll and Analogous Pigments in Different Media (Pryawye iz-
moreniya vreasni shizni vosbushdonnykh malakul khlorofilla i
analogiobqft *. pignentov v razlichnykh aredakh)
PIRIODICALs Doklady Akad"ii Sauk 335R, 1957P Vol. 114t Nr 4,--Pp,. 751-753
('USSR)
ABSTRACTe In order to determine this life 't the authors measured the
duration of fluorescence by means of the phase fluorimeter
by A. M. Sonch-Bruyeviah ot &I. whose resolving power in time
is 2.lo-lisoo. Other devices used in these investigations and
the errors of seasuresent are also shortly discussed. Fluoresc-
-
ones was excited by the mercury line 436 0"-- Observation was
effected through the light filter XC-1o wii
h a thickness of 4
an. The concentration of the solutions always remained below
10-5 Rol/l. The values obtained for the solutions of ahloro-
ph7ll and related pignonto in various solvents at + 2oOC are
summarized in a table. The here measured life of the excited
singlot state of chlorophyll markedly differs from those values
Card 1/2 which were obtained by indirect methods from the polarization
Direct Measurement of the Life of Szoitod Molecules of Chlbro- 2c 114-4-20/63
pbyll and Analogous Pigments la Different Media
-of the fluorescence and from the integral of the absorption
band. The decay time of the fluorescence of the pigments de-
ponds only little on the solvent. for chlorophyll by it is ap-
proximately twice as small as for chlorophyll a, which is con-
nooted with the different quantitative yield of fluorescence.
In phtalooyanidoe life is monowhat longer than in phoophitines
of the corresponding metals. Romatoporphinin has the loMmt de-
lay time* If a Zn-atox is tntroduced into the pigment instead
of a Mg-atomj the decay tizio of the fluorescence is reduced
-to about half of its fozuor length. A *0, 1e contains the here
obtained date on the docay time of the fluorescence of ohloro-
phyll in natural media. The values thus obtained are about
3-8 times as short as in acloular solutions. In the living loaf
,t depends on the intensity of exposure to light. The reduction
of't and the reduction of fluorescence yield in the living loaf
are largely due to the high concontration of pigments under
thoso'conditions. There are 2 tables and 6 references, I of which
I a Soviet.
SUBMITTnt NOY 31 o 1957
Card 2/2
.YERMOLAYE'll V.L.; ALESHIN, V.G.j SAYENKO, Ye.A.
Determining the velocity constanta of enera trunsfer in chelate
ecmplexes of rare earth ionis. DokI. All SSSR 165 no.5:1048-1051
D 165, (IMIM 19: 1)
1. Submitted April 26, 1965,
YERWjLkYEVv V.L.qGand Phyn-]L~.th Scl-(dics)
Of Org,-UIJC COMPOUIIdS ~'Lt 10""' tOUPOr!:tUres" LL-:,,ll 1953- 10 Pi)
v
(Stato Order of Lenin Optical Inut in S.I.Vavilrw), '1450 mdzlo
(4147-5'~,', 129)
-'. TIMLATW,, V.L.; KOTLTAR, LP.; SVITASIW, K.K.
Internal conversion frou the fluorescent to the phosphorescent
1wrel In naphthalene d*rlystivem, lsv,AIW SSOR.Ber.fiz. 24
no,.5:492-495 Ff 060. (91U 130) -
(11aphthalene-Optical properties) (Umineacence)
24(4) sov/51-6-5-14/34
AUTHORs YermolAyev, V.L.
TITLBs Dependence of the Probability Of Energy Transfer in Sensitized
Phosphorescence on the 0--cillAtor Strength of a Triplet-aingist
Transition in the Molecule of an Snergy Aa,,-optor (ZMViC1M03tt
varoystnosti perenons, snorgli pri sonsibilisavannoy fosforostoant-Ai ot
oily ostaillystors. triplot-vinguletnogo perskhoda v molokule
aktaeptora energii)
PBRIODIGALs Optiks, I Spektroalcoplya, 1959p Vol 6, Wr 5, pp 642-647 (USSR)
AMTRACT: The paper vas presented at the Sixth Conference on Wminescence,
Ld,ningrad,1958. In 1952 Teronin and the author (Rats 1, 2) discovered
sensitized phosphorescence of aramtic compounds. Later kReft 3-5)
it; was found that a resonance transfer of energy -with direct excitation
of' a triplet level in the energy acceptor takas place in sensitized
ptoophorescence. The present paper describes studies of the effect of
the oscillator strength of triplet-singlat transitions in thacnergy
acceptor on the probability of energy transfer ax4 consequent quenching.
For this purpose acceptors witti similar phosphorescence spectra anrl
Yvidely differing decay constants were used. Xhey were: naphthalene.
Card 1/4 l-,chloronsphthalons, 1-bromonsphthalone and 1-iodonaphtnalons. Their
SOV/51-6-5-14/34
Dependence of the Probabilitj of NA&rgy Transfer In SenslUzed PbosphDreseence on
the Oscillator Strength of a Triplat-Singlot Transition in the Uoiscule of an
Snargy Acceptor
phosphorescent properties are listed in 'Able I,- the height of the
triplet level, in ca-1, is given in col 21 the decay constant, in see,
in given in col 3; the quantunt yield Is &1vvA in col 4. Experiments
showed vat phosphorescence of bwzophenons or bensaldehyde was quenched
to the same extent by any on* of the four aeceptors listed abovs (at
tJ20 same acceptor concentration of 0.32 solo/litre at -19,50C, see
%ble 2). This is shown clearly in Fig 1 -whore the continuous curve
represents quenching klowering of intswity of phonphorescenee)of
benzophenone by naphthalene (circles) and 1-bromona phtho. leas (crosues)
as a function of the acceptor concentratioa. Although the oscillator'
strengths of the triplet-einglet transitions in naphttAlone a-ad
1-bromonaphthalene differ by a factor of about 100 their quenching
action in represented by the same curve. ThIs is also t--ue nf the
door@&@* of the pbosphores".nas decay constant It, due to
xgLphthalezo and I -bromonaphtheL Ions in bentophenono. -ghe effect on ,e
is represented by the dachod avirve In Fig Is the effs---t of naphthalene
La shown by dots and that of l-brmonaphtbalene by trianglos. These
lacts contradict directly one variant of t1w theory of radiationless
%J
bard 2/4 i)norgy transfer (Galanin, Figrater, Dexter). This variant predicti
BOV/51-6-5-14/34
Depen4ence of the Probability of unergy Transfer in Sonsitised PhoaFhoresconce on
the Oscillator Streqtft of a Triplet4linglet vansitioa la the Molecule or *a Zaergy
Acceptor
strong dependence of the probability of energy transfer between donors
and acceptars(and the consequent quenching of the donor phosphorescence)
on the probability of radiative transitions %or-cillator strengths) In
the, acceptor. Xt was also found th,Lt the quaatum yield of sensitized
phosphorescenco (defined as the ratio Of IA, the number of quants
emitted by the acceptor, to ID, the number of quanta emitted by the
dortor) increases more slowly along the acceptor series from napnthalone
to 1-iodonsphthalone than predicted by the theory mentioned above (Fig 2).
This several predictions mentioned above stem from an assumption that
eniorgy is transferred by an inductive interaction of electromagnetic
fiolds of the molecules talcing part In the transfer process - Consequently
this mechanism must be abandoned in favour of another variant which
ascribes energy transfer to exchange -ros onance effects vrnich axplain
satisfactorily the observed facts. Ackzowledonento are made to
Mqrd 3/4
V
SOV/51-6-5-14/34
Dependence of the Probability of Energy Transfer in Sensitized Phosphorescence on
the Oscillator Strength Of A Triplet-Ginglat Transition in the Molecule of an
Energy Acceptor
Academician A.N. Teranin who suggested the work and directed It.
Tharis are 2 figures , 3 tables and 28 reforences, 16 of which are Soviet,
4 Frencb, 4 German and 4 English.
SUMffTTBDs July 20, 195P,
card 4/4
Boll
it, J~S_O 0 B006Y,31
AUTHORSs J'orwolayev, V.- 0. Serenin, Ao W.
TITLEs Intrasolecular inergy Transfer on Triplet Levels
PERIODICALs Ifspekhi fisicheskikh naukp 1960P Vol- Tip 10~ 1, pp. 137-141
TEXTs The prosent paper is a continuation of a nuab4r of previous investi-
gations (Refs- 1-7)p that had dealt withsimilar problemes. It was the aim
of the investigation under review to show that an intramolecular energy
transfer from the triplet level of a carbonyl group to a triplet level of
diphenyl- or naphthyl group is possible. For this purpose, the authors
investigated the spectra and the duration of phosphorescence in a Beries
of diphenyl ketones, naphthyl ketones, and aldehydes. The clearest results
were obtained with phenyl-4-dipbenyl ke4one (pbenyl-4;bsazophenone), the
absorption spectrum of which at -1960CI In ethanol eth r (mixture 20) is
shown in Fig. 1. The benzophenone spectrum taken under the same
conditions, is also shown for a aomparition. P~hnyl4iphonyl ketonelexhibits
two bands; a scheme of the electron lerel of in
Fig. 3. Wumerous details are giveng concerning the opectra that were
5/053 6()/071/01/05/011
Card 1/2
4W
Intramolecular Energy Transfer on Triplet 0/0~/60/071/01/05/011
Levels B006/B011
examined. Fig. 2 shows the phosphorescence spectra of~tenzophenone,
phwW1r4-dipbeny3. ketone and p-oxydiphonyl in other, taken under the same
conditions as the absorption bandl. The duration of phosphorosconott of
these three compounds was 4-7*10-2 seci 94 see, and 2.5 sta, respective-
ly. Table I contains date an phenyl diphbnyl ketone and a number of
other carbonyl derivatives of diphonyl, concerning the position of singlet-
and triplet levelt extinction periodl and phosphorescince quantum yield.
Three of the compounds investigated wert'syntbealzed by 1. Ys. Postovskiy.
Table 2 offers the same data for some o&rbonyl de'riTatiTeg-of na hthaleney
Fig. 4 shows the phosphorescence spectra of I-ebloronaphthalene, and
2-naphthyl methyl ketone. All data and all spectra reeer to mixtures with
ethanol ether Wt -1960C. Investigations show that the luminescence of
carbonyl derival6iVea of diphenyl and naphthalene can be ascribed to an
intramolecular excitation energy transfer. This sxplainm tho lack of
fluorescence in these compounds. The naphthalene derivatives were prepared
by A. I. Shatterishteyn. V. K. Watveyev anti A. T. Troakehenko.. There
are 4 Ngur 9, 2 tabies', and 10 Soviet roferenceso
Card 2/2
YER14OIAYEV, V.L.
ImEmocence, of o imple benzene derivatives. Part 1. Arozatir.
amineo. OptA opektr. 32 noe,4s492-497 0 061. WPA 14.20)
(Benzene derivative&-Spectra)
YIMMOLAUV,, T. L.
Spheres of action of quenching in the case of energy transfer between
triplet levels. Dokl. AN SSSR 1.)9 no.2:348-150 JI 161. (IMA 14:7)
1. Predstavleno, akademikom A.N. Terenih*m. .
(phosphorescence.) (Nucloit At6mic)
S/051/62/013/001/006/019
E039/E420
AUTHOR: Yormolayev, V.L.
TITLE: measurement of the quantum yields of xonsitized
phoxphorosconce as a method of studying quenching
processes at the triplet level of organic molecules;
PERIODICAL: Optika I spektrookopiya, v.13, no.1, 1962, 901-05
TEXT: The quantum yields of xonxitized and normal
phosphorescence are measured for a series of aromatic molecules
in solid solution at 770K. It is shown that the quantum yields
of sensitized phosphorescence for all the Investigated
combinations is independent of the concentration.of acceptor and
donor energies. Results obtained are explained on-the
assumption that the non-radiating tranxfor of energy up to the
triplet level in accompanled by-quenchIng and that all the
quenching inxidearomatic molecules-In solid-xolution is
concentrated in the triplet state. Measurements of quantum
yield of sonxitized phosphorescence are able t6 be used to
determine quenching in t rlpl*t levels of donor or acceptor energy.
Quantum yields are determined for valuex:of imccoptor on-orgy
Card 1/2
s/o5i/62/013/001/oo6/019
Measurement of the quantum E039/9420
concentrations"wr 6.3 x 10-2 to 4.8 x 10-IL'mole/litr*. A minimum
quaintum, yield of 0.070 is observed for carbax6le
and a maximum quiantum yield of 0.73 for phonanthron* + 1-chloro-
naphthalene, There are 1 figure and 3 tables.
SUBMITUD:
Card 2/2
May 25, 1961
.. .............
TERENIN, A. N. ; YERMOIAIU.. V. L.
Inaetl*ation of the triplet state In aromatic moleculeas
Ixv. AN SSSR. Ser. fiz. 26 no.1:21-29 Za 162. (MgM l5s2)
(Aromatic compounds)
(Kolecular dynamics)
M0401AYEVP #.L. s av Yea.; SHIGORINO D.N.
I-
Nomrsdiative onersy tr=oror betwom the triplet and singlet
station In organic so2sculowl d1ommolon of A*N*Teronla and
V.L. Iriolmm's report Ormeftmation of the triffileVotate
in aromtic moleculejP. Inv. AN SUL Ser. ris. 26 no.1:29-
31 -T& 162. (MITA 15:2)
Organic a -A-N
Nolecular ftomics" ).
i
ARISTOV, A,V.; ULA)p
I V.L.; LEVSHIN, V.L.; 140KHMA, G.A.; MEMASOV, A.S.;
SHIROKOV, V.I.
Boris IAkovlevich Sveshrdkov; obituary. Usp. fla. nauk 81 no.lt
201-210 S 163. (MIRA 16:12)
1- A. 11 1
0110,4/6.3 107/005/061'7/0~pp
mpjt~~s in vitreaus
Jbilld ~n Hlnok 10- 15
fis I ii6~.o 617-622
31 i3itald.ait ~f molgiciAea' in
ani
JURkL I r,-,nf:-t-
Card 1/2
- - - - - - - - - - - - - - --
6~~-
11 ;!
I
T .I ;
i
. I Ii
i . -
, ;.. . . , ;I ". I- I . . , '. - ~ A I.. . ~ - . . -
1
m
L 3.02~77-0
ACCUMON V; AP3002305 8 -1/153P80A 1/60 !1/06T)
AUTHOR: Yenoolayev,- V. L.
TrAt ~~f ~energ~mj
T'ITLE ~Or o M SX lzorgoAic sys,taM vl~ t~~ tLrtV11Pqti011 rit, tno
triPlet stat4l, 3- Solid solutiova'and
SMIRCE Usj*khJL fizichesklkh nauk,, v, 80j, n I$; 19,6j 3 14
;17
w
na
TOPIC TAGS: - triplet level transitio , glasslik6~ org~,L-. Yrtinw.. crys-zalli'le
organic systAms.# co
ncentratlon quenchingi:orpnic
ABSTRACT: Via articlep a th i )f
orough and &-tailed #uv ol I Tic~nt level nts in
tZe-field-oflenergy transfer in
orrsgnic 6-A6=, Is i in a sarj~es. The
first (by A. ff, Tarenirl-) and -the I second ~ty Me
195' z
published in:1951 and o, respectively4 ~ Tz with the t~tudy
of nonradioactive electron excitation en4rgy;tranm ilt,jareft-4 tbe triplet L-wels
of organic molecules in glasalike and.cz,at i1ne! all MLCeiIA4, 10W f--Ppi!Z -ttllre3.
- i -t - .Ohl' re.-
The text. Is - divided. into three Par so Cion rj: ~gj, de~, mi3. In
quenching tij~~, and the coacdntration qu~n; o. h ani ~Nita Phos.Ph,.)res,,!en--e
:e Al~
C,,d 1 /2
MM
JMW4rLV?.V.L.; SVEMIKOVAO Ye.B.
Indwtive resonance energy, transfer from aromatic molflicules in %e
triplet state. Dokl. AN SSSR 149 no.6tl295-2298 Ap 163.
(MRk 16t7)
1. Predstavleno akademikon A.N.Tereninym.
(Aromatic compounds) (Quantum theory)
ACCBSSI01f KA: U'4020978
AVnIOR: Yermolayev, VA.
TITLE: Triplet-triplet energy transfer between identical molecules in solid solu-
tions at 90ft
SOUIM. Optika I spektrookopiya, v.16, no.3, 1964, 348
TOPIC TAM: enfargy transferp energy migration# triplot-tri plot tranxforp phospho-
roscence quend4ingp benzophonons, naphthalene# triplet level
ABSTRACT: Tho phenomenon of triplet-triplet energy trans~or between different mole-
cules was discovered by the author in collaboration with 'rerenin In 1952 (A.K.Ters-
nin and V.L.Yermolayev, DAN SSSR 85,547,1952) and is known to occur in solid solu-
tions, liquid solutions and crystals. The purpose of the present study was to de-
termine whether it can occur between 111w (identical) molecules in solid solutions
at GOOK. The experiments consisted in'moasuring the quenching of the phosphoroscarm
of bonzophenona (donor) in the presence of naphthalene Caacoptor) in other-alcohol
solutions at different, concentrations (from 10-2 to 1.11 11) of the benzophonone.
The observed vixiation In quenching Is attributed to anorgy migration between the
... .......
ACCESSION XR: J"20978
triplet levels of the dowre "In conclusion, I desire to otpress my gratitude to
A.H.Torenin for his Interest JA the work and 0,5.2sossax"Yad for stinulating dis-
:cUssions.
ASSOCIATION:
SUM11ITIM MUM DAIS AM Mpr" INCL: 00
8198 COWS m Ew SM 003 OMM: 000
Card
=77-7=
YERMLAYET, V.I,.;
Wi3th of luninescence spectra aM Stokes's lDsseu :Ln tx-8nzI'~-_f'2r;z
from fluarencent and phosphorescent levels of axonall-ar corToun`:3,
Opt. i spektr. 16 no. 4:704-705 Ap 164. (MrHA 17; 5)
L 00988-(6
'P 'XESSION NR*
AUMOR: Yermolam,. V. L.
7TITLE - Triplet 4riplet energy transfer and Ltd applic.atianf;Hliri lit hescence and
~'Jeoto;hemiLal reactions 17
'S, 1965', 1266-1270
'SOURCE: AN SSSR. Izvestiya. Seriya fizichesk4a, v. 29 no*,~
PIC TAGS: IntermDlecular energy transfero tiiplat triplet!'biranarer, organic
luminescence, energy decay, photochentlcal~rewtioaj! rare4ttrth chelate,
loser
CT: Soviet al2d. Western research data, including i964 46i;a. triplet-triplet
0!a
energy transfer in organic molecules were reviewed and,dii)eusnfid, flew data ob-
talned by, the auth&r on triplet-triplet energy transfer betqekt id4ntiaal molecules
in solid (fr--zen) s6lutions vere given and discup'se&T6 rapiday goiring number of
publications on the'~ subject in the past few year6 (since''-i962) was:explained in terms
of possibilities for the application of tripletp-triplet energi, tranafer to the study
:1of the decay of eleittronic excitation energy in'organic molecules, mechanism of photo-
-data were re-
Ichemical reactionsgiand rare-earth chelate lasers. Rev experimental
ported on concentration quenching of the phlophorescence, of -a benza,phenone -donor by
1/2
LM
L 00988-66
ACCUSION MR: AP502DT80
a naphthalene-accept6r in alcohol-ether solution; at7: 90K. Recently, ~Preliiainar~y data
on this subject were,. published (Yermalayev, V. V. Optika I s"Idroatolpiya, v. 16,
no. 3A 1964, 548). 1.1he new data included.changea..ih the phosp6oresdence spectrAun,
quantum yields and~.quenching of the phosphorescence of 9. be~*'&phe~'oqe-donot at
high donor concentrations. These changeh vere**.ainad ?nain1;yj,Ps tho Wtict of the
radiationless tripleii-triplet energy transfer bet*een idantt4',%J,i dondp'moloculeb in
oolutions. This eff4ict is considered important for.bi6logicml~!Aad drolahic scintil-
lators studies. In tonclusion. the author, e ressed, the be]AO'ij'~ thst~l iriplet-trip~ei~
VP I I .
transfer must p1q1 &~'significant part in photobi6logical proc6i~ses.'! This paper was
presented at the Thikeentb conference on Lumin'e9`4 %nd Holecw
u1sal, Lumineacence r 'held june 25-JulY- 1. 1964, im* dr ov., Ori~v art,4 'has: 2 fig-
uree and 3 formulas. CJX1
MSOCI&IOIT
none
SUBMITTED: 00 ENCL:. 00
SUP CODE:NPIOP
NO REF SOV# 012, OTHM! .017i *06
ATO M.Es
p
TITLE.- Various types of nouradiative ensrj&:Ar4nsfsr fvWj inwiltUd wolecitdles In
triplet state
SOURM Simpozium pa islamentarap pratisessojo M-11. 11~qfroy. Holstow 1963.
Elementarnyye protsessy khIaLL vysokikh e*ifx
Uy of high energies); trudy simpozluma/xbsi~ov, 1965, 100.
TOPIC TAGS: particle interaction, excited isitivie. phoeph:01im,tisced4a. particle collision
molecular Interaction
ABSTRACT: Various types of nonradlative ene= transfilrAll soild solutlow involvirg
aromatic molecules in the triplet state am discussed. . his filist type occurs during
the sensibilized phosphorescence of organic compounds in'g~lxssji solution at low tem-
peraturiss. The process of deactivation oactirs here &CC61kiLag to. the triplet-triplet
schme
or, + IFA 1rt6 A
where A is acceptor and D is dmr. The pr*ab Uity of the tjAptlet-triplitt emergy
transfer is Independent of the singlet-triplat trowf0rojition !of the acceptor vsolo-
rd 1/2
c
e
L 11086-66
~C C N 5023434
cule. The triplet-triplet type energy transfiW (oonradlamotive), conforom to the Wig-
ner rule of preservation of total spins of tW~ oftimiond Ojo acq~irpitor during the
energy transfer act and the nonradioactive tr4knsfer of elmi~troni~ excitatiom en-Orgy
from organic molecules in the triplet state f4UNS the
In the case of this triplet-singlet transfer the acceptor violecUloi trw3foram into
the excited singlet state according to
3rD + IrA * Ir. + I rA
The triplet-singlet type energy t Irensfer.nee¬ conforai +o'i Wl~nmrls rule. This in-
dicates -that in the absencu of photochemical' veaction the Utemal decay of the elec-
tronic'excitation energy of armatic noleculle~* occurs via ~-Jlplmt state. Ovig. art.
i hass 2 f1gures.
SUB CODEt Guam DATEI MOM/ Opw DZIFS 1X17/ Mi REF:, 00.2
j
2JR
IV 'J"
AUTHOR: Yeratolov, V.
ORGt none
TITLE: Triplet states of organic cowpounds~in evergy tro~sfer
SOURCE, 61mW-glitm Va *1c=njjjXU= Mosc*W jqf"~4.
Elemntarnyye protsessy WaLL vyso Ikh oneigly'(Elementaty pro,4*mses of the chemis-
try of high energies) ; trudy simpoziuna. Moscow, 1965, 1~6;459
TOPIC TAGS: particle interaction, excited st-otel. excitedklect~or,t. state, particle
collision
ABSTRACT: The michanism of ener1q. transfer betsteen 0~aani~ 1%010~iules in solid solu-
tions I liquid solutions and crystals Is discussed, In term ~ c! vo;onance tfi~my - In
solid solutions. if the Wigner rule of preseivatlon of toial spUi Is satisfied, the
energy is transferred frm an orgarAc molecule in a tilplat~ ctatO to another in a
singlet state and Is in accord with the exchaitge-pasonanca ti~kidchat~'Um
,0+ FA I rD + 3FA
where D Is a doom and A Is = acceptor# This ~"*iiplai-trliliqtn~
3 t chanism is opera
tive at a donor ccucentration Intiallid. soluti of S-LO-2-StM-1 ~ioiles/l an4 for the
1/2
a
k
-L-10840-66--
ACC NRs AT502344.1
Istance of 10-15 A. An Ludu4
interwolecuIar d; "_resonz =6V Mechwui= is "rative
and the Wigner, ritle Is not followed when the intermolsculaii,. distimce (donw- acceptor)
in the solid solution in 25-60 X. In this case, the acceptov mlecule converts into
an excited singleit state according to:
3r + Ir + Irb t Ir
D A A
In the oxygen-ftee liquid solution, the enerv transfer Is' 1)~! airlplet-trlplet type
and follows tho exchange resonance methanism.l: In' liquid S~ivrtiwia the UR.-of organ-
Of, ~ b
ic molecules in tiAplet state is 10-r--10-3 sec. in ease enzeindl WPIet -trip, let
tyEe ener do at an appreciable rate ast an 1'j,_ cone-entratiat of
gy trans;Fer procee ccept~v
10 6 _10-6 moles/1 (2930K, [021 = 0, We of the dowwr triplqt Otate 2 10-3 see). The
problems of triplot-singlet type energy transt~r in liquid siolutij !ins and of the trip-
let-triplet type onergy trawfor in crystals romala wuolveC
SUB CODE: SUBM DATE: 23FebG5/ ORM Mr: 6611 !!,VI*H PEr: wo
jw
2/2
_71-6
r
SOME OMNI
AUMOR: Yermolayery, V. L.: Aleitbl% V. Q.; 9a entop Ye. A.,
ORG: none
TITIZ: Detervowbion or th7 energy transport velocity cmatents'la cbelateis of com-
plex rare-earth iims t'_"L'
SOURCE: AN 866H. I Doklady., Ve 165, no* 5, 1965
TOPIC TAGS: rexC~eartb element, nouradiativel!trailAtIon, li ines~ence quenchingj,
electron energy. i6vel
ABSTRACT: . The authors deacribe a method!. -for the d0q.ormination of,
the rate constantiof nonradiative transfer of~eledron anttd~ rare-
Vfrodi a 11gand to a
earth molecule forcomplexes of dibjnzoy2qwth4mtc(DB14) with Sr'vi' and iu3"' and for
acetylacetonate (AA) with Sm3+, Eu3 0 Tb3+ Dy-"v I The, mmstbod 1~ based an the com-
petition between the Intramolecular 11gazd-rare earth tram atitt the intermolecular
energy transfer over the triplet states of organic ~ ligind-ct~jmicbai (acceptor) com-
pounds. The quon6ers used were raphtthalene for AA and acill'iLinso !.wvthrucene, 1)2-
benzanthracene, a#1 pyrene for DEK, The rare-eartb tAmd*dnagnce van excited
outside the abn4n7blon band of the quencher (3340 A for M a)~a 4099 A for DB14). 11he
measurements. were icisde in toluol at 293L Plot +0 are present~W. of the electrorAic lev-
els in triplet-trilget quenching,, of the phosphorescence spe4tra C& the ligand and of
the rare earth amd, of the behavior of the luninexce=e quen6bing a~ant. The results
M. ~i
C,rd .1/2 535 ~73-2
1~ 13631-66
ACC NRs AP60024ft
A ~nera tjimi~tr.befteqm orgs
show that the intermlecular triplet -triplet i~ nic wolec~les
has a higher rate constant than the. lijand--2~ieisrth tii4iti"s ~ vhIch has a Ixigher
order of forbidde '' mesa. The application of ibl'a re"Its t,6 ~n attiartic detertaimtIon
of.the.content.ot.rare earthaby means of re-
e pful to Ac6deWciari
sidues is briefly'discussed. Authors ar .4. U1. Terjq_nfor
interest, and to A. V. KaEZakin, V. A Arkhangolf alwyat andifl, I.; 'Pitaksakov for sup-
plying the rare-earth elements. Ozi t. his [021
ar
a-- ~. -gures j
SUB CODE: 20/ 6UBM DATE:V 16rApr65/ ORIC Pj6..-' 003/ OTRIPEF: ~'012/ ATD rmq-.ellg~
&-Card
ACC NRt AP7004147 SOURCE CODE: UR/0051/671022/GO1/0165/0167
AUTHOR: Yermolayev, V. L._; Sveshnikova, Ye. B.; Sayenko, Yt. A.
ORG: none
TITLE., Study of the degradation of electron excitation In organic molecules in
liquid solution by the method of triplet-trIplot transfer tolraro.sarth chelates
SOURCE: Optika i spektraskoplys, v. 22, no. 11, 1967, 165-167
TOPIC TAGS: energy transfer, photolundnescence, fluor"coac*, tucited electron
state, aromatic hydrocarbon, aromiatic ketone, strosaftc other, orgonoeuropium compound,
chelate coupoundp WAj*#A"d-AWE_
ABSTPAM The controversial nechaniss of do6radation of excitation energy In organic
mAecules, such as 2-acetonaphthone, 2-sethoxymaphthaleneo or naplithalene, In liquid
solution has been istudied by the method of triplet-triplet transfer to europium
t:rie-thenoyltriflui)roacotonate-1, 10-phonanthroline. The nonradiative energy fractia
which degrades on the triple level of the organic donor moleCUle vas determined by
two procedures. Following the first procedure, the lusinesce-nee Intensity of the
evacuated binary solution of the organic donor molecule and chelate was compared
to that of an Identical but nonevacuated solution. The differenco between the lumin-
escence intensity of evoicuated and -nonevacuated solutionst lev -Anoilevo was equated
to the intensity Il.t due to the energy transfer an tritlet levels under operating
conditions excludifig the donor to chalets energy tranater on siniiat levels and the
Card 112 UDC: 535.373o2
NRs AP7004147
reabsorption of the donor fluorescence by the chaletie. The experimental values of
(lev - Inonev) X I--' which are the measure of the fractlon of donor molecules in
monev,
the triplet state, were found nearly equal to the values of CDCD(1 - qfj)qACzA1
where c and C are wolar absorption coefficients and concentrations of donor and
chelate and qfj is the quantum yield of fluorescence of the donor, In the second
procedurep the luKLnesconce Intensity of the evacuated binary solutions was compared
to that bf the solution of the chalate alone on excitation with a 313 nm source.
Under given conditions, the ratio (Iov - Inonev)(Ich - InO460-1 was equated with the
fraction of donor molocules, in the triplet state q This value was found nearly
' N'txperiments that the energy
equal to 1 - qfl. The conclusion was drawn from bot
degradation in the aromatic molecules studied in liquid solution proceeds exclusively
-A& the triplet state. Thanks are expressed to A. N. Terenta. Orig. art.' has.,
1 table and 1 figwra.
tilt)
SUB CODE: 07, 20/ SUBM DM: -16Jun66/ OILIG RUs 004/ OTH MYs 004/
GRE)ITOR, M.A., inzhk; TMOLLTW, VtM. . inzh.
J.
Automatic computer of the amocat of wood In cable netere. Wkh-
I avton prols. 14 no.6:46-" Je 160. (MI" 13:?)
illectrosic digital computer)
.';/147/61/000j'004/011/021
.2 o o E025/E120
AUTHORS: Yermolayev~ V.M:, and Talantov, A.V4
TITLE: Investigation of the effect of pressure on the speed
of propagation of flames in the turbUlerat flow of a
homogeneous mixture
PERIODICAL: Izvestiya vysshikh uchebnykh zavedenJ.y,
Xviatsionnaya tekhnika, no.4, 1961. 82-93
TEXT: The investigation of the dependence of the
fundamental characteristics of burning on pressure are of grent
practical value because this problem in connected with the known
worsening of the efficiency of the combustion chambers at great
heights, The published investigations into the effect of
pressure on burning were carried out for axially symmetrical
flown In a small range of variation of the fundamental parameters.
In most cases the speed of flow and composition of the mixture
were not varied. In the present investigation the i9peed of
propagation of the flame has been varied from 20 to 80 m/sec,
the composition of the mixture has been varied from 1 to 1.5.
CardCY4)
Investigation of ihe effect of ... S/147/61/000/004/011/021
E025/E120
the pressure from 0.35 to 1.4 kg/cm2 and the temperature was
equal to 423 OK. To obtain the best approximation to the
conditions of burning in an engine the experiment was carried
out on a flow bounded by walls in a chamber of constant section
with forced turbulence of the flow. The combustion chamber was
a tube of square section 50 X 50 mm of length 1700 mm, cooled
externally by water. A very detailed schematic diagram of the
experimental arrangements is given. The values of speed of
propagation of the flame in the turbulent flow for various
speeds of the flow, mixtures and pressures were obtained, and
from these were constructed graphs giving the re.lation between
the speed of propagation of the flame and the pressure for
various mixtures and flow speeds. A comparison of the nature of
the relation 'between the speed of propagation of the flame and
the pressure for various mixtures and flow speeds; was made by
the use of diimensionless*flame propagation velocities and
pressure rati,DS. The effects due to.longthening and shortening
the flame are discussed. The following conclusions are arrived
at:
Card 2/ 4
Investigation of the effect of 5/147/61/000/004/011/021
E025/E120
1) The values and nature of the speed of propagation of a flame
are approximately the same in a turbulent flow bounded by walls
and in open turbulent flow. 2) The speed of propagation of
the flame is proportional to the 0.8-th power of the pulsation
velocity, taking account of the dependence of the latter on the
pressure. 3) Damping of the turbulence is responsible for
varying estimates of the effect of the pressure on the speed of
the flame for different speeds of flow and mixtures. Hence it is
necessary to calculate the speed of propagation of the flame
taking account of the normal and pulsation velocities and their
dependence on pressure and damping.- 4) The speed of propagation
of the flame in a closed turbulent flow is in good agreement with
theory when the effect of damping of the turbulence is eliminated.
5) The decrease in the speed of propagation of tho flame with
fall of pressure is one of the causes of decreased efficiency of
the processes in the combustion chambors of primary ginginon in
high altitude conditions,
There are 10 figures,
Card 3/4
Investigation of the effect of ... S/147/61/ooo/oo4/oll/021
E025/E120
ASSOCIATIONI Xazanskiy aviatsionnyy instituti KaZadra teorii
aviadvigateley
(Kazan' Aviation Institute, Department of Theory
of Aircraft Engines)
SUBMITTEDt April 31 1961
Card 4/4
YERMDLAM YIM.L TALANTOV, A.V.
InvestIgating the effect of pressure on the bingth of the con-
butation zone in a closed turbulent flow of a uniform mixture.
I2-v.vya.ueheb.zav.; av.tekh. 5 no.3tl43-156 162. (MIn 15:9)
(Combustion)
41UXOV,, G.1b.,p I=h.; MMOLAMWIJ.A,
Coaferonce an inpro"ment of offloiiency in tb* pleettio
oquijpmat industry in tho lJralm# Vest# sloktr~wvmo 34
no.2:76-77 7 163o (KM 16:2)
(Blectric equiFmont industry-Congresses)
4W)~AMYO.:. V..M,.; TALANTOV, A. V.
Rate of flaw propagation in an open and lijkit*d fLow of bcsogens-ouis
mixtare, Izv.vys,,uchsb.znv,jav.tOkh. 7 no.2s134-141 164,
(lam 171())
Y,
I"Fd,X-J4 4~,
PIIASL 'I Trtntauro In.1-ind RtbUlorraphlc !1orq-t-t
BCOK 140.1 '4c.: TU',~~'71 Nol"?
Authors;- ErVIGLAFIr. y. I., and y;o,,vjz-rj,, is.. 11.
F'all Titlot F(K--4Y,IJI (F "MIUCTURAil
Transliterated Title: Manter strukturnof.-o burentia
Publishing Data
Originating Agency: None
Publishing House: State Scientific-Technical Publishing Hous.? of Cil and Viner-I
Fuel Literature. Leninarad BrZ'Lnch. (Gostoptekhizz~at)
Date: 1952 No. pp.: 318 No. copies: 7,r)00
Editorial Staff'
Editor: Gridin, V. K. T-~ch. Ed.: 'kne
Ed.-in-Chief: PerminQv, S. V. Appraisor: 'Icrie
Text Data
Coverage: The book cr..ntains elementary data on ge6logic.-il structures, conc3tructlr~n
of derricks, arrangement of equiTwient, types and quality of drilllii,~,
tools, and characteristics of varicus materials (metals, lubricants,
transmission belts and transmissirn cables, cement, luvber, etc.) uswcd
in well. drilling. The practical methods of drilling wells for !-eo1(-,fjcI-1--l
surveys (mapping), structural, and prospecting dr-iLlIflir are
Plso, method3 of computinp simple work probleirs unj rat'r!"; of tiril'iln,---
through various strata.
Purpose: A textbook for well drilling foremen and personnel eng,11,.ea in survey-I-Ir
and prospectinf-.
Fac.iliti~s: licne
No. Russian References: 11
Available: Library of Congress
TWMOIAYEV, V.M.; KARAMZIN. A.Y.; KOVAIRTA, AL.A., inzhener, vedushchly
POLOSM, A.S., tekhnichealriy redaktor.
t3truct-mral boring; practical manual for workmen] Striaturam
burents-, prakticheakoe posobie dlis rabochikh. Mosicra, ks.
nauchno--tekbu. Izd-vo neftianoi i gorno-toolivnol lit-ry, 1954.
138 P. (MM 8:1)
(Boring)
.............. ....... ....
"INO V"IIL#yevlc&,* .qvich;
r
ummirem.y., redaktor; 1motilmovWr., r;
I.M...-tekbilabseldy redaktor
[Drilling structural and mploratorywells3 Burents str*turno-
poiskarykh ekwashin. Leningrad, Goe.asuchno-tekkno lvd-vo neftia-
not L Igorno-toplLynoi lit-ry, 1955. 36) p. (KLRA 9:3)
(Boring machinery) (Oil well drilling)
I v .414- U41~1-1A
MARAVIZIN, Aleksandr Vasillyevich; MU40 - - &A-h
.LdIcjamiL, SHEVTSOVA, . .. ved,. red.
(Boring structural prospecting holes] Burenie strukturno-
poisk-OV,Ykh skvazhin. Izd.2.p isp. i dop. Leningrad Ned-
ra,, 1964. 390 P. (MIRA 17;9)
LYtJBCH=Op A.?.; )Z-FM-OJAW-t-V.Ue-
Effoot of cerium on the self-diffusicin of iron, Fix. note i
astiMoved. 3.4 no.lsl57-160 n 162. (111M 15;7)
(IroD-4%tallography)
(Cerium)
SOYA IN., A.I., insh.j IZMGLA32VO T.H., insh.
Technology of-blant furnace pa purifioation andAle design
of scrubbers. Stall 23 no.2t176-1778 F 163. (MIU 16:2)
1. MagnitogorsIdy metallurgichesidy kambinat.
01ases-Por,4-fication)
(Scrubber (Chmical technoloa))
V
jERMOLRYEV, V'P-
MOLf r1j, V. P. . and 114. P. MY(MUT.
----- ------ --
Pamiatka nomirovshchiku-strolteliu, 'Poskvii 4 M15
j 15h8o 70 )~i# s ro
At head of title: Nauchno-issledovatellskii aerodronnyi Institut
VVS Vs.
Title tr.: Instructions of wq)erts 1n setting constructlon work
standardso
TL?25.2A
SO: Aeronautical Sciences and Aviation in the Soviet Union, Library of
Congress, 1955.
- -XC - -.Te- V
F RPTA KE U,-A c 9 1 13 2 ~Urgory Fab 59
868- (316) EXPERIMENTAL PARENTERAL PROTEIN NUTRITION IN SUPGIC-
AL PATIMNTS (Russian text) - Ermotaev V. P. - KHIRURW.4 Igs-f, 9
(97-102) Graphs 3 Tables 2
Data concerning metabolism in Wlents following operations on the gaMro4nt~NtjnaI
tract and In burned patients are presented. Pronounccd neilat1ve nitrogen balatice
(7-12 g.) was revealed In the postoperative period. In burned patients aW in cu,ses
with postoperative complications nitrogen balance equittled from 30 to 35 it. In 34
hr. There was it lose of weight and reduced content of protein in the plazins. lPro-
loin was administered parenterally In 20 postoporalive cases and 1h 5 ease* with
burns, and 55 Lv. injections wore carried out. In 12 cases untoward Mde- reactions
were observed, which were severe In 5. Aminopeptide - a new prepaimUout of
heteragenic protein. fermentative hydrolynate of whole animal blood - was investig-
ated thoroughly. It was tested clinically in 174 patients (85 postoperative 4u-4.89
burn cases). Aminop*pttde was administered I.v., I.m. and s.c. in a doze 14 800-
1,500 ml. (III to 20 injections to each patient); 2 patients had fever and chilLs. In
order to determine the efficacy of parenteral ad ministration of &minopeptide in
28 postoperative and 12 burn cases, determination was made of nitrogen talance,
protein content of blood plasma, excretion of urea and amino rdtrog*n in the urine.
The results of these experiments show that sminolpeptid* has no snaphylaclogenic
Foropertles ond to rat toxic. Nitrogen, administored in this form, to Sleadily assim-
lated by thit Organism, irrespective of the method of Its introduction. It in poss-
ible to maintain nitrogen equilibrium and a positive balance If an adequate dose of
aminopeptide to given. Clinical observations and Eaborstory examinations 311ow of
the conclusion that aminopeptidt to an effective pr"ration In Parente-rol protein
nutrition In surgical patients and its recommendation for wide clinical use to
warranted
'Af
YMXOIAYNT, T.R., kandLUt meditsinsikih nauk
XoWleatlon of prot*Ln a*taboUsm; in mono surgical tients with
parenteral infusion [with suw&&V in Uglish, p. 157rirest,ktdr,
77 w.6:12-17 Je 156. (XLRA 9:8)
1. Is gospitallnor khtrurgichemkoy klialki (nach. Prof. 1.S.
11olsonikov. nauchn. rukoyod, - prof o S.SAirgoICIT) lroyenno-seditain-
skoy ordena Lenina akadexii Lm. S.R.Kirovs. IsaWrad, Botkinekaya
ul., d.19, kv. 126.
(IMUSION, FAMONUAL,
protein hydrolyeate in protein depletion in surg. (Ram))
(noings,
hydrolyeates, parentorvil infusion In protoin depletion
in surg. (Rus))
(SuRany. MUTITI. Complicatlons,
protein depletion, tho.v protein )V&olysate parenteral
infusion (fts))
YKNOLAIRV, T.R., kancl.med.muk (Ioningradt 9, Botkinstays ulal. d*19, L-v#126)
WANNION
basis and embolism of the pu2nomary arter7 folloving luxNg
surgery [with sommory in Saglish]. Teat.ihlr. 79 no.9t55-62 8 1579
(MIRA 10:11)
1. Is goopitallney k1birmVichookoy klWki (rAcho - prof.' I*$*
Calsonikov) Vaemao Itainskay ardons Ionim skademil In. S.N.
Kirovs.
(ANURM, FulAvlaff, dive
I 4albollon & thrombosis after Ina surc.)
(Pommnom, cowl.
so'bollso & throsibools of pulime artery)
YMNOIAIW. V.I.. icand.wed.neuk
arenteral orotain nutrition for surgical patients Evith sw=ry
in %glishl'. Khtrurgilm 33 no.9:97-102 5 '57o (MIRA 11:10
1. Is gospitalluoy khirurgichookey klinilki (nach. - prof. 1.S.
Ulsenlkow) Toyenno-maditainskoy ordens Imenins jiksdftil imeni
S.N.Alrova.
(PROTIMp there use
pore burns & postope core, perenteral admin.)
(BUM. there
proteins, parenterel admin.)
(POSTUMATIVX CARZ
parenterel admin* of proteins)
(IXPMIOMB, PARIWXRAL
proteins, in burns & postope cars)
TWHOLAYN, V.I.. kandeved.nauk; SRATALIDVA, N.A.0 kand.med.nauk
Chronic atelectasis of the middl lobe and lisCils, of the lunC
of varied etioloj7 [with sumaa:7 In AnglIsh]. Tsmtokhir. 82
no.1:86-93 Ja 159. (MIRA 12:2)
1. rs gospitallacy kh1rurgicheskoy kliniki (nach. -.prof. 1.S. Ealse-
nihm) Toyanw-seUtminskey ordena Lenins akadosit Ineul SoNs Kirovae
Adrom awtora: Leningrad, 1-9, BotkinsWa ule, 4-23, gosPitallwa
kh1rurcleheskeya klinika.
02SUMAS18v etlol. & pathogen.
chrente. of al"le lobe & HWIs (1hu))
YEMOIAIEVp V.R.v Wor meditainskoy oluzlibyi, kwAmed#muk
. "
HoLung Of VOWAN containing a foreign body foUxdj* tota.1,9wy
irraflation of snimalne VoenspookLesbure wel#sW Ap 060
(M& :L4:1)
(I(Oum) (RADIATION-PUM Tol, CT
--.nMLATBvs- V.R.p kandomed,nauk
Arulsion of the nain bronebw ft blmt tmm& of tbo thorax,
adrall" 37 so.103-17 Ja I&L. (Him -use)
Is lv.,Vsp#al'wy kbinrgioboolcoy kliniki ("~v, - ;rd, IJ.
Koleslik*) %y o-meditsirAkay ordma Umiza ekdadi immi
SAO Kirevazi
I(C=T-4V= AND WORM) (NO=-4WM AND MURIES)
MUMMK(ArA, A. T., kand. mod. naukj TIUMIAM, V. R , kand. mad. nauk
Aeutw gastric obstruction caused by complete Waxattan of the
left half of the diaphrup with transposition ~f the stomach,
ap3min and left lobe of the liver Into the tho"i-Ac cavity.
Mdrstrglia 37 no.7:87--90 J'l 162. WMA 15:4)
1. Is k3in4ki gospitallney kidrurgil No. I (useb. P"fe I* SO
Solemnikov) Voyenno-weditsinakay ordens Lenina &Wemil - Imeni
S. M. 11raft,
(DIAPMUW.--DISZASZS) (ROWN) (UM) (SPIM)
YMOTAYW, T.R. (Uningrad.. K-9, ul. Smirnova, d. 10-es, k7.22)
Burg-Ical treatment of late Bronchossophageal fistulas. Grudn.
khir- 4 no.59132-1.13 S-0162 (MIRA 170)
1. Iz kliniki goopitallnoy khirurgil No.1 (naalmlInIk - prof.
I.S. KC esdkov) Voyenno-medituinskoy ordena Lenin& akedemi-'A.
imeni. Kirova.
ul, Sul~smd.10-ap;kwo
nRXDIAl13Tq Y.R. (L*nlftWo
:EntrsPlvmsl b"UTW4PO fOlIAW189 r"I"l Pulxmwry mwgin7-
t,'.rod.khir. -ho.446-& JI-4 162. (MM 15: 10)
:1. IS Irl4n4lr4 gogq)JW'wy khirunil go. 1, (wwh. - prof. I.3.
Jolemnikov)V*nno 4wlltslmkoy ordena Unins aWadi.bwni S.M.
Kira".
INMAMW V.R. kand.med.nwk (Uningrado X-9v UIq Salmoval d.10AO
late results or the stirgical treatment of bronabiectasis. Mn.
Irbi vOqnsUo%U N 962, (MM 16 Q)
Io, Ufafta gospitallnoy kbIrnr#i (macho, - launat Immimakoy
pradi pror, LS. Koloodkovi voyamm-esditaimAroy Ordens,
ladna akRdoLU imeni Box. Kirov 0
(~CHIMASIS)
MMOIAU.V,q V.A. (Leningrad Y,,-3, ul. Sairnova, d. lQa,, kv.22)
Segmental and combined reaect-ons of the lungs in bronchiectuls.
Grud.khir. 4 no.6.*59-66 14-D'62. (141itA 16:10))
1. 1z klirdki gospitallnoy kNItutgii lio,l(nac'hallnik -prof.
I.S.Koleard3cov) Voyenno-meditainakoy ordena Unina akademii
iwnl S.14.Kirova.
(BRONCIII-DISMES) ( LUMS.-DUMBRY)
YERMOLAYEV, V.R., kand. mod. nauk
Priwa7 failure of the bronchial stump and the pulmonary
woUM following radical operationip on the lungs, XhIrurgiia
38'6,1204-19 D 062. (MIRA 17:6)
1. Iz gospitallnoy khirurgichookoy kliniki No.1 (nachallnik -
prof, LS, Kolesnikov) Voyenno-seditainskoy ordena Imina
akadadi imeni S.M. Kirova,
KOLESNIKOV Jq I.S.,, prof.; FUTOV, N-V., prof.1 YEPMULLM., V.R., kand.med.
nauk; SOKOLOV, kand.med.nsuk
Acute blood circulation disorders in the residuia lum part
following patrial g*sectionse Ve.9t,khir.90 no.2028-135 F163.
(MIRA 16:7)
1. 1z gospitallnoy khirurgicheekoy kliniki (n*cWd'n:Lk prof.
I.S.Kolesnikov) Voyanac-moditsibskoy ordena leaLra Pkademil.
imaid S.M.Kirovas Adres avtorovz loeningrad3 Botkinekaya u1.,,
d.23, Gospitallnaya khtrurgichealmA k2inika Yoyenno-medietisk-
skoy ordena Lanina akademii imn:L Kirova.
(LUM4-SURGERT-)
(BLOOD-GIRCUIATION., DIBORDFM CIF)
JERMIAM kand.med.nauk (Leningrad, K-9,, al. Smirnova, d.10-a,
lz:~Ik-v.2.i)
Resection of the lungs in bilateral bronchiectmis. Vest,,
khir. 90 no.3:11-19 W163. (KMA 16:10)
I* Is 1-y gospitallnoy khirurgichookoy k"nik' (naebalinik
prof* IeSoNdlesnikov) Voyenno-maditainskoy ordena lanina
akedemii imeni Kirova.
(LUW6.SUHGFM) (BENCHIETABIS)
rI.RMC:-k'rFIIT, 'I.R., dotsent (Leningrad, ul. SmIrnova,
Some chara3teris t 'Ice of tl-.-e terhm'yue of -lunit,
bronchlertazi.s. Vest. kh:Lr. 1~1 no.9s2rj-2'1 j16,1.
1. Yz gn~tpital lacy kW-urglcheakoy klintki. (rrwh:t~ jr~'-Ic
I.S'. K--IP-ozi'Ikcv) Voyenno-meditalrio?v;y rd(tn,
iment S.M. Kir:)-m.
KOLISNIKOV, I.S.; ORDZHMIKXMO G.K,; SMlWHMKIY, 14.1t.; XW V.R.
UKU-BrVSKIY, F.I.
Adenoma of the bronchij, their camplications and operative
treatment. Orud. khir. 5 noe6llM,-106 N-DO63 (MIMA 1712)
le Is kliniki goopital9noy kbiTurg:li (nachaltnik - prof. 1.S
Xclesmikor) Voyanno-meditainskoy ordena Imina akademii imeni
S.M*Kirova. Adres avtorovs LeningradiN-9. BDtkinskaym ul., d.23.
Klinika gospitallnoy khirurgii Voyenno-meditsinskoy ordena
Lenin& akademii imeni S.M. Kirow #