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SCIENTIFIC ABSTRACT YERMOLAYEV, V.I. - YERMOLAYEV, V.R.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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14(5) AUTHORS: TITLE: PERIODICAL: ABSTRACT: Card 1/~ SOV/127-59-3-8/22 JermolqZUJ" 9 Bakal.eynik, YaJA.. and Vinogradov, L.V-. Engineers. The Semi-Automatic Control of Mechanisms in the Mine Shaft.(Foluavtomaticheskoye upravleniye mekhanizmami ahakhtnogo stvola..) Gornyy zhui~nal, Nr 3. 1959, pp 31-33 (USSR) An experimental installation for the semi-automatic conVol of hoising mechanisms in the Kapitaltnaya Nr 2 pit of the Degtyarka Copper Mine has BUCcess- fully passed industrial tests. The installation was developed by the KB TsUA (Design Office of Tsvetme- tavtomatika) in collaboration with the Degtyarka,Mine. The maximum utilization of already existing mechanisms 64uipped with pneumatic gear was taken into constdorat- ion, Air distributing devices VR-350 ( figure 1) developed,from ENIMS air distributors, are used in the system. Two men in the hoist cage direct different operations in the hoisting shaft. The system is des- SOV/127-59-3-8/22 The Semi-Automatic Control of Mechanisms in the Mine Shaft. cribed in detail (figure 2). The introduction of this system in the Kapitallnaya Nr 1 and Nr 2 pits will permit a reduction 30 men in the working staff. This represents :1 yearly saving of 340,000 rubles. There are 2 diagrams. ASSOCIATION: Tsvetmetavtomatika, Moscow, Card 212 EPYOTAML.L.L ....Owwwp- PhytcpleLnkton of lake Krivoye of the Warasuk River system. Trudy TSSBS nci.802-96 164. (14IRA 130) L 01293-66 :;.IT AMMM MR: AP54017080- Wogqo/Wod i 581,526-325 1AUTHOR: Yermolayev, V., VITLE: Primary production of lakes with lovered;wat northern part of t1me-Kh1undisk Steppe SOURCE: AN SSSR, 141birsko7e otdolenlyso .X06sttyas .biologo-meditsinskII& naukv no* l# 1965P.14-99 TOPIC TAGS: lake, hvkojoW, algae, photosynthomiss respiration# plant ecology ABSTRACT: In 1962 phytoplankton production of Lakel (Narasuksiy Ra-yon of Havosibir'sIcala Oblast') was!itx~~ its water level was 35 am-below normal# an production of Lake-Kusgan.(in the sam ra m.] gn) wai-` iii its water level was. 1L9 em belask na . A vtonl anirt' ~0,03) 009h/0"9 10V,18 .131 61 0~iy4l I)Ianil when when, (M Iff 6m)- imdat---dt~M -dr- i.- -im --1-4-6 - a LOY -t,1666 -to pie 9 Septembem, 'At the sime UW irstor dMploO (0015 1) liewe flite determino ttio mmbisr or sigios ooutdalii dftd, 66116 amd tive Omouftt of Card 1/3 Y L 02293-t~6 ACCESsioil NR: AP5017080 Aritensity phyto lankton biomass* The ooeffici6nt ot~ph6tosynt~vdia;' P and respiration intensity was detatmined and the it, of, ox;rgen released. per hectare of Uka awfaoe at aAean da'pth 41T 101.1 M'Was (LIMC deteinninede Findirtga.show that- both laked at':Iow9re4Gi4atm1jv 1TVals maintained their J*LOtOsynthetie aotiviit7 des its' a S'ii-pinglani; levol of dissolved salts in the water (1000 to 1999 ;;/1)., ~~Ihe !1sor-s-inal oxyg;)n -production of Lake Xuagans which,. is ~more shallix( aT11 itiore mineralized than Mike. KrIvoje# was aignif toantly ht .111 ir Moth bodiso of watQr'are oharaoterized by intense devOlopment P algae duritag the sumnor nonths, As: a rule, Oeai6nal ohan lit'l-ytopla&.- ton 'production ohmr that with increased nl~mbero of in a given unit of voluxies the intensity of its. photo~jxJ-WIJOIS ~IJJOWO&13004 Howeverg no true correlation wds established betiloon thm OaIues of true ph-ytoplemkton photosynthesis (coefficient. oP plu"400 , intensity and respiration intansitjok PhyOPI'mWiOn jPOIUibei:jm# and Ph`ytDP1ankbon biomswe Orig., art* has: 4,tOleo. ASS011JIATIONs TAMral'tn7l Sibirskif, bbtWchesi .1i arid Siblipokogo otdoleniya AN OSSR11 Novosibirsk (Otntodl: Siberian HotoliaA Garden 6f the Siberftn 13ramli ff SM) L 01293-66 11COESSION NRI AF54017080 UBM ,.. ubtrit 60 ~,Goollp RR MW sovt :, i v! i, Lot m W-66- KC NRs AP5025697 JD r,/, scums 6(563t:: UAM86~ RX AUTHORS: 111 a oi I- - -- I ft,4 1~ 7.77 Razava7sv. Go A., Akol '80 CI]LS/OD47/0047 Au I,' Ar, I A T IWIb ;No* 174697 SOURM Byulletenl lacbretwAy i tovarny1ch anakaw, noo TOPIC TAOSs electric. resistarp chromium.. nickel ABSTRACTs This Author Certificate preal 'hoa'foi:Ma*d) vit ad electrical resistors by vac=m dopq WI%r gr-I Ii3nnto f-JIM to th6 InAttubing, ty~ Him da thin filis beaO.' rA to deargane L. T 49 351.ai6, ixoW :1 Card 1/2 I III "T I ''Issmunw. Winter phytoplanktm In I&M Irivoys of the laremak liver vm+4m. -Trudy TUS wolosi*.49 165, Pbwt%"akton In Lalm Studessys of W Luua River Systea. -Ibid. 350-% (KDtA 18310) S/l95/6l/o153(2?11(?03/O04/0O9 As-/ 0 2030/Z452 AUTHORS: Molin, Yu.N. and'Yormolayov, V.K. TIM: The causes of the change in proton relaxation time during irradiation of aqueous solutiona PERIODICAL: Kinetika I kataliz, v.2, n0-3, 1961, 358-361 TZXT: Hitherto the decrease in relaxation times have been attributed to the formation of free radical a, bu calculation shows that improbably high concentrations, 1017 to 101A 9-1 would be necessary to give the size of effect observed'* The present work therefore resolves this question by irradiating solutions of hydrogen peroxide and also distilled'wat*r, h*xan*,, benzene and solutions of benzoyl peroxide in benzene, and aqueous solutions close in concentration to those used*previously by Y.M.Ydovenko and V.A.Shcherbakov (Ref.2: Dokl. AN SSSR, v.127, 127, 1959), and observing simultaneously the NMR signal and also the RPR signal, the latter indicating the formation of any parama4pietic bodies, including free radicals. The apparatus consists of an EPR magnet, with a hole drilled through one pole, to admit a boam of fast (1.6 MeV) electrons. The specimen in hold in a Slass ampule, diameter 7 mm and volume 0.25 cm3, which in located close to the Card 1/3 313.9 S/195/61/o t/003/004/009 The causes of the change ... 9030/9452 opposite pole to minimize the field inhomogeneity dud to the hole. The NMR field coils are wound on a former which slides over the ampule. ++ The MIR signal in calibrated with standard CuSO4 solutions with Cu concontrations of -OW17 cm-3; the sensitivity is rather less than in previous work because of the Increased field inhomogeneity. The %pecimen of 30% stabilized impurified H202 was -irradiated at 6 x 10 rad/sec and after 2 min the amplitude of NMR signal, which had increased rapidli within seconds reached a high steady value. equivalent to 4 x: 10 9 ions Cu*+ cm-1. On removal of the irradiatibai, the signal fell over some 30 min to about one thlid thinvalue and then appeared constant. It was remarkable that all this time thero was no observable change in the RPR signal, thus precluding the formation of a significant concentration of frte radicals. Similar results were not obtained with the other solutions. The only plausible explanation of the results is tha'~ the relaxation time is decreased by supersaturation into free oxygen, which is known to be formed on irradiation of hydrogen peroxide; thiis is confirmed by the lack of signal in the other solutions indicating that not more than about 1017 cm-3 free radicals could remain undetected, and by the failure of the signal to revert to its initial small value in H202, as should have Card 2/3 309~-9 S/195/6l/OU2/OO3/Oo4/ooq The causes of the change 3030/E452 accurred if formation of free radicals were the operative mechanism. Ackmowledgmonts are expressed to Y.Y.Voyovodskiy and N.Ya.Buben for their interest in the work. There are 2 figures and 9 referencesi 6 Soviet and 3 non-Soviet. The references to three English language publications read as follows. Ref,l; V,T,Duft*y, Bull. Amer. Phys. Soc,, II, VA, 250, 1958; Ref.8.- J.G.Marshall, P.V.Rutl*dge, Nature, v.184. 2013, 19W~ Ref.9: G.Chiaratti, L.Guilotto, Phys. Rev., v.93, .1241, 1954. ASSOCIATIONS: Institut khimicheakoy fiziki AN SSSR (Institute of Chemical Physics AS USSR) Institut khimicheskoy kinetiki i goreniya SO AN SSSR lInstitute of Chemical Kinetics and'Combustion SO AS USSR) SUBMITTZD: October 31, 1961 Card 3/3 35062 s/195/62/003,1001/00/Clo E071/E136 AUTHORS; Yermolayev, V.K., Molin, Yu.N.* and Buben, X.Ya. MW - TITLE: Recombination of radicnis in solid organic substancea. I. Investigation by the method of fusion , PERIODICAL: Kinetika i kataliz, v.3, no.1, 1962, .156-611 TEXT: The range of temperatures at which rCcombination of radicals takes plAce on fusion of various organic substances, irradiated with fast electrons, was studied by the 3np (EiLiz) method. The object of this work was to determine the molecular movements leading to the recombination of radicala in a solid. For this reason the substances investigated had a known phase behaviour on heating. Normal alcohols, ketones, hydrocarbons, aromatic compounds etc. were investigated. To dotermine the stability of radicals at various temperatures, fusion curves were obtained. For this purpose a substance was irradiated at a sufficiently low temperature To in a stream of fast electrons to obtain a concentration no of radicals, The irradiation was stopped at the beginning of the linear part of the curve of accumulation of radicals (no PO 1019 radicals/&). Card 1/3 Rocombination -of radicals in solid ... s/195/62/003/001/003/010 E071A.136 The tenperature To was so chosen that during 10-15 ininutes no noticeable decrease in the concentration of radicals occurred. The substance was then heated for 2 minutes at a temperature Ti '.>T0, cooled to To and the concentration of radicals n1 measured etc. The dependence ni (Ti) was called the fusion curve. It was established that for crystalline substances (substances of type I) a rapid recombination of radicals occurs, as a rule, before melting; for amorphous substances the process takes place near the divitrification -temperature. For cyclo- pentane and cyclohexene (type 11), radicals recombine near the temperature of their polymorphic transformation. For hexamethyl- benzene, acetone, succinic acid (type 111) several ranges of recombination of radicalB can be separated. In the majority of cases the recombination of radicals is, apparently, caused by self diffusion, appearing close to the temperature of a phase change. For substances of type III the recombination of radicals takes place at; a temperature at which the self diffusion of molecules is apparently absent, e.g. in hexamethylbenzene and acetone, radicals recombine partially in the region at which Card 2/3 Recombination of radicals in solid ... S/195/62/00/0011U63/010 E07.1/E;36 the molecules begin to rotate. The recombination of radicals in the absence of self diffusion could be explained by the formation of radicals cl()se to each other, e.g. on the neiglibouring molecules in pitirs, Then initiation of any molecular movement may lead to their recombination. However, the f6riflatiOn Of radicals on ne:Lghbour-ing molecules should be accQr-.pan;Led by a strong widening of components of the superfine structure of the EPR spectra, mtch higher than was actually observed. The authors thank V.V. Voyevodskiy and G.K. Voronova for their assistance. Part of the material of the present r.~Lper was presented at the Second All-Union Conference an Radiation Chemistry. There are 5 figures. ASSOCIATION:-Institut khimicheskoy fiziki AN SSSR (Institute of Chemical Physics, AS USSR) Institut khimicheskoy kinetik! i goreniya SO AN SSSR Card 3/3 (Institute of Chemical Kinetics and Combustion SO AS USSR) SUBMITTED: August Ili, 1961 4~236 3/844,/62Y000/000/056/129 D204/11307 AUTHORS:,,,-Yermalla Holin, Yu. V. and Buben, N. Ya. 'IMSY TITLE: Recombination of radicals in some frozen organic compounds SOURCE: Trudy 11 Vsesoyuznogo aoveehohaniya po radiatsionnoy khi- mii. Ed. by L. 8. Polak. Mose-ow,jod-vo AN SSBR., 1962, 331-334 TEXT: The pre6ent work was aimed at a study of the molecular mo- tions occurring during the recombination of radicals formed under the action of fast electrons at a temperature To, such that no, the number of radicals formed, remains fairly-constant over 10 - 15 min. The compounds were then warmed up*to a series of temperatures Ti (where T i> To ), maintained at Ti for 2 min and cooled badk to Tor at which temperature the remaining conecitrations of xudicale, niq were measured. In cystalline compounde,'duch as MeUH, C 6H6 or n'oetanol, the :mdicals 4~qajjpeared at 0.9 1.0 T (where T M m Card 1/3 U %62/000/000/056/129 Recombination of iddicals..r... D20,4rD307 m.p.), whilst in poorly crystallizing Elubstlan~bes, such as glycerol or n-butanol, the recombihdtion took place in~ the region of vitri- I fic9tion (0 , .6 - U.7 Tm). Tifts rule was confir'med on slowly frozen (crystalline) and quenched'(amorphous) 191-di'cyclohexyldodecane; cooling at an intermediate3rate gave rise to '(ni/no) versus' (T. m plots of an intermediate dhbLracter, shoving the presence of cry3- tellites of varying temperature stability. Such intermediate type curves were the only ones oboerved for paraffin, polyethylene and polypropylene. The recombination is connected with partial destruc- tion of the lattice and amorphous compounds rest)ectively. In cyclo- pentane and cyclohexane, ia'which molecular rotation begins at T rot (T rot 14 Tm)q it vras found that recombination of the radicals took place at T rotv showing that'the radicalvare probably formed in pairs and'recombine as Boorr as rotation becomes possible. The as- sistance of V. V. Voyevodskiy and G. K. Voronova is acknowledged. There are 4 figures. Card 2/3 Recombination of radicals ASSOOIATION: Institut Chemical kinetiki K,inetics LISSR) $,/844,/62/000/000/056/129 D204/D307 khimicheakoy fisiki AN 603R-(Institute of 2hyeical AS USUH); Institut khimidheskoy i goreniya SO ILK SSSR (Inat'Ltute of Chemical and Combustiont Siberian Branch of the*AS Card 3/3 YERMOLAYWs V. L. PA 175T77 r lye Teiji*~reti is of t ur 0 a P4r 9 4"stwikov,, V. L.: Yei J~: Dok Ak Nauk. SWR" V61 LW NO 1: 4 ppy k5tudies variation ixi phoophorciscence,of OcLe. i63z ti ]Avin et t t -0-114 d4r*&~ n co o: W,v ncu of-activai a, t W ': -I 0, he' of isiditins: 6.UtaittedL r4tv litt, eitt, A .4., ...... IGAIIIC M'dil, MES AT. t xTZ MP *!Jj~At Pri Mzkot Temp"criturd). A.: K. Te 4w bp 0. Sol froiri Old" S. vLvttdta lit-46( lap,, An xtttt*Vt two f 4('thihj~ of exlItArl 99 onarjr in co erat one WgIocMIG to ttcu~~' a( a- tumustemenco of t4,11wd teduldi im wbero thip prim"y Im f it 0 lit O"imuldi 06 tit 4 muldi im USSR/Physics - Phosphorescence Sensiti- 21 Jta 52 zation "Sensitization of Phosphorescence of Organic Male- cules. at lov Temperatures: Intermolecular Trans- fer of Energy With Excitation of the Triplet Level," Acad A. N. Terenin, V. L. Yermolayev "Bok Ak Nauk SSSR- Vol 85, No 3,,Pp 547-550 Ditc-asses investigations devoted to the,problea of t*ansfer of excitation energy in soIns of mirts of f-h-orc=11-us- 9-r-1-am-tic-mols st te*p of liquid air--, fvr--the 7urpose of establishing the 'phenomenon of sensitimtion of excitation by one compd. of the A Giver, t a Z;VU_DI_rQi7J_-i PhOSPbor&acence of wwl=a dc*4d& in dijendlence on conen of another. Submitted 3 May 59- 235T92 phoophorescence ot ax=mtI*to*.u~Aj! Periodical 1 Dok. AN SSSR 102/5, 9125-928, jrt~, 3a 2.4 51 Abatrtat I An experimentea otudy wapi, a .~i of th'O Ond=t ienditin44 4 ,ae- of t: in 1 all ~,Osphore nce and the. doU= atj TEMNIN, A*N. ; ,Y=~WA~!Wj%hp.,t Intemolomlor transfor of onera owurrim In sonaltised luminesconce. lzv,.AN SSSR. Sorf1s, 20 no*40W Ap 156. (MU loa) (imlawam) (I%wmaowo) ern*-NO'tf~\JQ-NI VL USM/Optical - Aysical Optics K-5 Abs Jour fteferat Zkur - Fizika, No 5, 1957, 12962 Author I sFM' V LW--- Inst Title Sensitized Phosphorescence of Aromstic Compounds (Baergy Transfer from Triplet to Triplet Level). Orig Pub Ity. AN SON, ser. fiz.,, 1956, 20p no 5. ~1"19 Abstract A quantitative investigption was mode of the phenomenon of sensitization of phosphoresewces comected vith radia- ti(mless migmtion of the energy of electron excitation between the molecules, vith the excitation ofthe triplet l4wel. For nor details see Abotract 12961., Card 1/1 T: t1ft/Physics, - Luminelpeence Pub. 118 - 2/7 Authorm I Tereniii, A. No and' Yermolayev; V. 1 L. S Intormolecular transfer. of onergy, :~11 ~htt phimoi 0, 1 0-r! .Eli rill itized lurdineseence of organic Symema I t' 11) Usp. Fiz. nauk Jan 014 58/1,# 37-689 I The intemolecular tran-S'far of ovlem~fly ikeer-4wt "I'l III-% , ; an the sonAtization of prglxdv~ I Two types of energy transfer:am- cl4nrAA~rvdi 01 'ItAc mm" lnlluctivu~. Varimis cases are analy?ed ~rt whicH emAtiie& 1111,110111 and thh enerj7,,r tran-ifur vo-re obsvrvoi~. B Gum., 121 UI;A, 28 USb1t (1927-1955). Gra-phs d i a I..rv', an So. inst.itution i Submfitted woo.,. m YANOZATNT. V. L, XRMCEMOV, T.T.. SN=14N, N.M. -- 1013 Nodorn mignallng, central control mad block mystem ovdPwat used In underground electromotive transport. MborostrooUt no,12:2-5 D '56, (Submwo-41analing) (fttematic control) (MIRA 10:1) AUTHORS$ Daitriyovskiyo 0. D. 0 Yeraglaxas, 2o- 114-4-20/63 Torenin, A. X., Nombor'of the Academy TIT18i Direct Measurement of the Lifo of Excited Molecules of Chloro- phyll and Analogous Pigments in Different Media (Pryawye iz- moreniya vreasni shizni vosbushdonnykh malakul khlorofilla i analogiobqft *. pignentov v razlichnykh aredakh) PIRIODICALs Doklady Akad"ii Sauk 335R, 1957P Vol. 114t Nr 4,--Pp,. 751-753 ('USSR) ABSTRACTe In order to determine this life 't the authors measured the duration of fluorescence by means of the phase fluorimeter by A. M. Sonch-Bruyeviah ot &I. whose resolving power in time is 2.lo-lisoo. Other devices used in these investigations and the errors of seasuresent are also shortly discussed. Fluoresc- - ones was excited by the mercury line 436 0"-- Observation was effected through the light filter XC-1o wii h a thickness of 4 an. The concentration of the solutions always remained below 10-5 Rol/l. The values obtained for the solutions of ahloro- ph7ll and related pignonto in various solvents at + 2oOC are summarized in a table. The here measured life of the excited singlot state of chlorophyll markedly differs from those values Card 1/2 which were obtained by indirect methods from the polarization Direct Measurement of the Life of Szoitod Molecules of Chlbro- 2c 114-4-20/63 pbyll and Analogous Pigments la Different Media -of the fluorescence and from the integral of the absorption band. The decay time of the fluorescence of the pigments de- ponds only little on the solvent. for chlorophyll by it is ap- proximately twice as small as for chlorophyll a, which is con- nooted with the different quantitative yield of fluorescence. In phtalooyanidoe life is monowhat longer than in phoophitines of the corresponding metals. Romatoporphinin has the loMmt de- lay time* If a Zn-atox is tntroduced into the pigment instead of a Mg-atomj the decay tizio of the fluorescence is reduced -to about half of its fozuor length. A *0, 1e contains the here obtained date on the docay time of the fluorescence of ohloro- phyll in natural media. The values thus obtained are about 3-8 times as short as in acloular solutions. In the living loaf ,t depends on the intensity of exposure to light. The reduction of't and the reduction of fluorescence yield in the living loaf are largely due to the high concontration of pigments under thoso'conditions. There are 2 tables and 6 references, I of which I a Soviet. SUBMITTnt NOY 31 o 1957 Card 2/2 .YERMOLAYE'll V.L.; ALESHIN, V.G.j SAYENKO, Ye.A. Determining the velocity constanta of enera trunsfer in chelate ecmplexes of rare earth ionis. DokI. All SSSR 165 no.5:1048-1051 D 165, (IMIM 19: 1) 1. Submitted April 26, 1965, YERWjLkYEVv V.L.qGand Phyn-]L~.th Scl-(dics) Of Org,-UIJC COMPOUIIdS ~'Lt 10""' tOUPOr!:tUres" LL-:,,ll 1953- 10 Pi) v (Stato Order of Lenin Optical Inut in S.I.Vavilrw), '1450 mdzlo (4147-5'~,', 129) -'. TIMLATW,, V.L.; KOTLTAR, LP.; SVITASIW, K.K. Internal conversion frou the fluorescent to the phosphorescent 1wrel In naphthalene d*rlystivem, lsv,AIW SSOR.Ber.fiz. 24 no,.5:492-495 Ff 060. (91U 130) - (11aphthalene-Optical properties) (Umineacence) 24(4) sov/51-6-5-14/34 AUTHORs YermolAyev, V.L. TITLBs Dependence of the Probability Of Energy Transfer in Sensitized Phosphorescence on the 0--cillAtor Strength of a Triplet-aingist Transition in the Molecule of an Snergy Aa,,-optor (ZMViC1M03tt varoystnosti perenons, snorgli pri sonsibilisavannoy fosforostoant-Ai ot oily ostaillystors. triplot-vinguletnogo perskhoda v molokule aktaeptora energii) PBRIODIGALs Optiks, I Spektroalcoplya, 1959p Vol 6, Wr 5, pp 642-647 (USSR) AMTRACT: The paper vas presented at the Sixth Conference on Wminescence, Ld,ningrad,1958. In 1952 Teronin and the author (Rats 1, 2) discovered sensitized phosphorescence of aramtic compounds. Later kReft 3-5) it; was found that a resonance transfer of energy -with direct excitation of' a triplet level in the energy acceptor takas place in sensitized ptoophorescence. The present paper describes studies of the effect of the oscillator strength of triplet-singlat transitions in thacnergy acceptor on the probability of energy transfer ax4 consequent quenching. For this purpose acceptors witti similar phosphorescence spectra anrl Yvidely differing decay constants were used. Xhey were: naphthalene. Card 1/4 l-,chloronsphthalons, 1-bromonsphthalone and 1-iodonaphtnalons. Their SOV/51-6-5-14/34 Dependence of the Probabilitj of NA&rgy Transfer In SenslUzed PbosphDreseence on the Oscillator Strength of a Triplat-Singlot Transition in the Uoiscule of an Snargy Acceptor phosphorescent properties are listed in 'Able I,- the height of the triplet level, in ca-1, is given in col 21 the decay constant, in see, in given in col 3; the quantunt yield Is &1vvA in col 4. Experiments showed vat phosphorescence of bwzophenons or bensaldehyde was quenched to the same extent by any on* of the four aeceptors listed abovs (at tJ20 same acceptor concentration of 0.32 solo/litre at -19,50C, see %ble 2). This is shown clearly in Fig 1 -whore the continuous curve represents quenching klowering of intswity of phonphorescenee)of benzophenone by naphthalene (circles) and 1-bromona phtho. leas (crosues) as a function of the acceptor concentratioa. Although the oscillator' strengths of the triplet-einglet transitions in naphttAlone a-ad 1-bromonaphthalene differ by a factor of about 100 their quenching action in represented by the same curve. ThIs is also t--ue nf the door@&@* of the pbosphores".nas decay constant It, due to xgLphthalezo and I -bromonaphtheL Ions in bentophenono. -ghe effect on ,e is represented by the dachod avirve In Fig Is the effs---t of naphthalene La shown by dots and that of l-brmonaphtbalene by trianglos. These lacts contradict directly one variant of t1w theory of radiationless %J bard 2/4 i)norgy transfer (Galanin, Figrater, Dexter). This variant predicti BOV/51-6-5-14/34 Depen4ence of the Probability of unergy Transfer in Sonsitised PhoaFhoresconce on the Oscillator Streqtft of a Triplet4linglet vansitioa la the Molecule or *a Zaergy Acceptor strong dependence of the probability of energy transfer between donors and acceptars(and the consequent quenching of the donor phosphorescence) on the probability of radiative transitions %or-cillator strengths) In the, acceptor. Xt was also found th,Lt the quaatum yield of sensitized phosphorescenco (defined as the ratio Of IA, the number of quants emitted by the acceptor, to ID, the number of quanta emitted by the dortor) increases more slowly along the acceptor series from napnthalone to 1-iodonsphthalone than predicted by the theory mentioned above (Fig 2). This several predictions mentioned above stem from an assumption that eniorgy is transferred by an inductive interaction of electromagnetic fiolds of the molecules talcing part In the transfer process - Consequently this mechanism must be abandoned in favour of another variant which ascribes energy transfer to exchange -ros onance effects vrnich axplain satisfactorily the observed facts. Ackzowledonento are made to Mqrd 3/4 V SOV/51-6-5-14/34 Dependence of the Probability of Energy Transfer in Sensitized Phosphorescence on the Oscillator Strength Of A Triplet-Ginglat Transition in the Molecule of an Energy Acceptor Academician A.N. Teranin who suggested the work and directed It. Tharis are 2 figures , 3 tables and 28 reforences, 16 of which are Soviet, 4 Frencb, 4 German and 4 English. SUMffTTBDs July 20, 195P, card 4/4 Boll it, J~S_O 0 B006Y,31 AUTHORSs J'orwolayev, V.- 0. Serenin, Ao W. TITLEs Intrasolecular inergy Transfer on Triplet Levels PERIODICALs Ifspekhi fisicheskikh naukp 1960P Vol- Tip 10~ 1, pp. 137-141 TEXTs The prosent paper is a continuation of a nuab4r of previous investi- gations (Refs- 1-7)p that had dealt withsimilar problemes. It was the aim of the investigation under review to show that an intramolecular energy transfer from the triplet level of a carbonyl group to a triplet level of diphenyl- or naphthyl group is possible. For this purpose, the authors investigated the spectra and the duration of phosphorescence in a Beries of diphenyl ketones, naphthyl ketones, and aldehydes. The clearest results were obtained with phenyl-4-dipbenyl ke4one (pbenyl-4;bsazophenone), the absorption spectrum of which at -1960CI In ethanol eth r (mixture 20) is shown in Fig. 1. The benzophenone spectrum taken under the same conditions, is also shown for a aomparition. P~hnyl4iphonyl ketonelexhibits two bands; a scheme of the electron lerel of in Fig. 3. Wumerous details are giveng concerning the opectra that were 5/053 6()/071/01/05/011 Card 1/2 4W Intramolecular Energy Transfer on Triplet 0/0~/60/071/01/05/011 Levels B006/B011 examined. Fig. 2 shows the phosphorescence spectra of~tenzophenone, phwW1r4-dipbeny3. ketone and p-oxydiphonyl in other, taken under the same conditions as the absorption bandl. The duration of phosphorosconott of these three compounds was 4-7*10-2 seci 94 see, and 2.5 sta, respective- ly. Table I contains date an phenyl diphbnyl ketone and a number of other carbonyl derivatives of diphonyl, concerning the position of singlet- and triplet levelt extinction periodl and phosphorescince quantum yield. Three of the compounds investigated wert'syntbealzed by 1. Ys. Postovskiy. Table 2 offers the same data for some o&rbonyl de'riTatiTeg-of na hthaleney Fig. 4 shows the phosphorescence spectra of I-ebloronaphthalene, and 2-naphthyl methyl ketone. All data and all spectra reeer to mixtures with ethanol ether Wt -1960C. Investigations show that the luminescence of carbonyl derival6iVea of diphenyl and naphthalene can be ascribed to an intramolecular excitation energy transfer. This sxplainm tho lack of fluorescence in these compounds. The naphthalene derivatives were prepared by A. I. Shatterishteyn. V. K. Watveyev anti A. T. Troakehenko.. There are 4 Ngur 9, 2 tabies', and 10 Soviet roferenceso Card 2/2 YER14OIAYEV, V.L. ImEmocence, of o imple benzene derivatives. Part 1. Arozatir. amineo. OptA opektr. 32 noe,4s492-497 0 061. WPA 14.20) (Benzene derivative&-Spectra) YIMMOLAUV,, T. L. Spheres of action of quenching in the case of energy transfer between triplet levels. Dokl. AN SSSR 1.)9 no.2:348-150 JI 161. (IMA 14:7) 1. Predstavleno, akademikom A.N. Terenih*m. . (phosphorescence.) (Nucloit At6mic) S/051/62/013/001/006/019 E039/E420 AUTHOR: Yormolayev, V.L. TITLE: measurement of the quantum yields of xonsitized phoxphorosconce as a method of studying quenching processes at the triplet level of organic molecules; PERIODICAL: Optika I spektrookopiya, v.13, no.1, 1962, 901-05 TEXT: The quantum yields of xonxitized and normal phosphorescence are measured for a series of aromatic molecules in solid solution at 770K. It is shown that the quantum yields of sensitized phosphorescence for all the Investigated combinations is independent of the concentration.of acceptor and donor energies. Results obtained are explained on-the assumption that the non-radiating tranxfor of energy up to the triplet level in accompanled by-quenchIng and that all the quenching inxidearomatic molecules-In solid-xolution is concentrated in the triplet state. Measurements of quantum yield of sonxitized phosphorescence are able t6 be used to determine quenching in t rlpl*t levels of donor or acceptor energy. Quantum yields are determined for valuex:of imccoptor on-orgy Card 1/2 s/o5i/62/013/001/oo6/019 Measurement of the quantum E039/9420 concentrations"wr 6.3 x 10-2 to 4.8 x 10-IL'mole/litr*. A minimum quaintum, yield of 0.070 is observed for carbax6le and a maximum quiantum yield of 0.73 for phonanthron* + 1-chloro- naphthalene, There are 1 figure and 3 tables. SUBMITUD: Card 2/2 May 25, 1961 .. ............. TERENIN, A. N. ; YERMOIAIU.. V. L. Inaetl*ation of the triplet state In aromatic moleculeas Ixv. AN SSSR. Ser. fiz. 26 no.1:21-29 Za 162. (MgM l5s2) (Aromatic compounds) (Kolecular dynamics) M0401AYEVP #.L. s av Yea.; SHIGORINO D.N. I- Nomrsdiative onersy tr=oror betwom the triplet and singlet station In organic so2sculowl d1ommolon of A*N*Teronla and V.L. Iriolmm's report Ormeftmation of the triffileVotate in aromtic moleculejP. Inv. AN SUL Ser. ris. 26 no.1:29- 31 -T& 162. (MITA 15:2) Organic a -A-N Nolecular ftomics" ). i ARISTOV, A,V.; ULA)p I V.L.; LEVSHIN, V.L.; 140KHMA, G.A.; MEMASOV, A.S.; SHIROKOV, V.I. Boris IAkovlevich Sveshrdkov; obituary. Usp. fla. nauk 81 no.lt 201-210 S 163. (MIRA 16:12) 1- A. 11 1 0110,4/6.3 107/005/061'7/0~pp mpjt~~s in vitreaus Jbilld ~n Hlnok 10- 15 fis I ii6~.o 617-622 31 i3itald.ait ~f molgiciAea' in ani JURkL I r,-,nf:-t- Card 1/2 - - - - - - - - - - - - - - -- 6~~- 11 ;! I T .I ; i . I Ii i . - , ;.. . . , ;I ". I- I . . , '. - ~ A I.. . ~ - . . - 1 m L 3.02~77-0 ACCUMON V; AP3002305 8 -1/153P80A 1/60 !1/06T) AUTHOR: Yenoolayev,- V. L. TrAt ~~f ~energ~mj T'ITLE ~Or o M SX lzorgoAic sys,taM vl~ t~~ tLrtV11Pqti011 rit, tno triPlet stat4l, 3- Solid solutiova'and SMIRCE Usj*khJL fizichesklkh nauk,, v, 80j, n I$; 19,6j 3 14 ;17 w na TOPIC TAGS: - triplet level transitio , glasslik6~ org~,L-. Yrtinw.. crys-zalli'le organic systAms.# co ncentratlon quenchingi:orpnic ABSTRACT: Via articlep a th i )f orough and &-tailed #uv ol I Tic~nt level nts in tZe-field-oflenergy transfer in orrsgnic 6-A6=, Is i in a sarj~es. The first (by A. ff, Tarenirl-) and -the I second ~ty Me 195' z published in:1951 and o, respectively4 ~ Tz with the t~tudy of nonradioactive electron excitation en4rgy;tranm ilt,jareft-4 tbe triplet L-wels of organic molecules in glasalike and.cz,at i1ne! all MLCeiIA4, 10W f--Ppi!Z -ttllre3. - i -t - .Ohl' re.- The text. Is - divided. into three Par so Cion rj: ~gj, de~, mi3. In quenching tij~~, and the coacdntration qu~n; o. h ani ~Nita Phos.Ph,.)res,,!en--e :e Al~ C,,d 1 /2 MM JMW4rLV?.V.L.; SVEMIKOVAO Ye.B. Indwtive resonance energy, transfer from aromatic molflicules in %e triplet state. Dokl. AN SSSR 149 no.6tl295-2298 Ap 163. (MRk 16t7) 1. Predstavleno akademikon A.N.Tereninym. (Aromatic compounds) (Quantum theory) ACCBSSI01f KA: U'4020978 AVnIOR: Yermolayev, VA. TITLE: Triplet-triplet energy transfer between identical molecules in solid solu- tions at 90ft SOUIM. Optika I spektrookopiya, v.16, no.3, 1964, 348 TOPIC TAM: enfargy transferp energy migration# triplot-tri plot tranxforp phospho- roscence quend4ingp benzophonons, naphthalene# triplet level ABSTRACT: Tho phenomenon of triplet-triplet energy trans~or between different mole- cules was discovered by the author in collaboration with 'rerenin In 1952 (A.K.Ters- nin and V.L.Yermolayev, DAN SSSR 85,547,1952) and is known to occur in solid solu- tions, liquid solutions and crystals. The purpose of the present study was to de- termine whether it can occur between 111w (identical) molecules in solid solutions at GOOK. The experiments consisted in'moasuring the quenching of the phosphoroscarm of bonzophenona (donor) in the presence of naphthalene Caacoptor) in other-alcohol solutions at different, concentrations (from 10-2 to 1.11 11) of the benzophonone. The observed vixiation In quenching Is attributed to anorgy migration between the ... ....... ACCESSION XR: J"20978 triplet levels of the dowre "In conclusion, I desire to otpress my gratitude to A.H.Torenin for his Interest JA the work and 0,5.2sossax"Yad for stinulating dis- :cUssions. ASSOCIATION: SUM11ITIM MUM DAIS AM Mpr" INCL: 00 8198 COWS m Ew SM 003 OMM: 000 Card =77-7= YERMLAYET, V.I,.; Wi3th of luninescence spectra aM Stokes's lDsseu :Ln tx-8nzI'~-_f'2r;z from fluarencent and phosphorescent levels of axonall-ar corToun`:3, Opt. i spektr. 16 no. 4:704-705 Ap 164. (MrHA 17; 5) L 00988-(6 'P 'XESSION NR* AUMOR: Yermolam,. V. L. 7TITLE - Triplet 4riplet energy transfer and Ltd applic.atianf;Hliri lit hescence and ~'Jeoto;hemiLal reactions 17 'S, 1965', 1266-1270 'SOURCE: AN SSSR. Izvestiya. Seriya fizichesk4a, v. 29 no*,~ PIC TAGS: IntermDlecular energy transfero tiiplat triplet!'biranarer, organic luminescence, energy decay, photochentlcal~rewtioaj! rare4ttrth chelate, loser CT: Soviet al2d. Western research data, including i964 46i;a. triplet-triplet 0!a energy transfer in organic molecules were reviewed and,dii)eusnfid, flew data ob- talned by, the auth&r on triplet-triplet energy transfer betqekt id4ntiaal molecules in solid (fr--zen) s6lutions vere given and discup'se&T6 rapiday goiring number of publications on the'~ subject in the past few year6 (since''-i962) was:explained in terms of possibilities for the application of tripletp-triplet energi, tranafer to the study :1of the decay of eleittronic excitation energy in'organic molecules, mechanism of photo- -data were re- Ichemical reactionsgiand rare-earth chelate lasers. Rev experimental ported on concentration quenching of the phlophorescence, of -a benza,phenone -donor by 1/2 LM L 00988-66 ACCUSION MR: AP502DT80 a naphthalene-accept6r in alcohol-ether solution; at7: 90K. Recently, ~Preliiainar~y data on this subject were,. published (Yermalayev, V. V. Optika I s"Idroatolpiya, v. 16, no. 3A 1964, 548). 1.1he new data included.changea..ih the phosp6oresdence spectrAun, quantum yields and~.quenching of the phosphorescence of 9. be~*'&phe~'oqe-donot at high donor concentrations. These changeh vere**.ainad ?nain1;yj,Ps tho Wtict of the radiationless tripleii-triplet energy transfer bet*een idantt4',%J,i dondp'moloculeb in oolutions. This eff4ict is considered important for.bi6logicml~!Aad drolahic scintil- lators studies. In tonclusion. the author, e ressed, the be]AO'ij'~ thst~l iriplet-trip~ei~ VP I I . transfer must p1q1 &~'significant part in photobi6logical proc6i~ses.'! This paper was presented at the Thikeentb conference on Lumin'e9`4 %nd Holecw u1sal, Lumineacence r 'held june 25-JulY- 1. 1964, im* dr ov., Ori~v art,4 'has: 2 fig- uree and 3 formulas. CJX1 MSOCI&IOIT none SUBMITTED: 00 ENCL:. 00 SUP CODE:NPIOP NO REF SOV# 012, OTHM! .017i *06 ATO M.Es p TITLE.- Various types of nouradiative ensrj&:Ar4nsfsr fvWj inwiltUd wolecitdles In triplet state SOURM Simpozium pa islamentarap pratisessojo M-11. 11~qfroy. Holstow 1963. Elementarnyye protsessy khIaLL vysokikh e*ifx Uy of high energies); trudy simpozluma/xbsi~ov, 1965, 100. TOPIC TAGS: particle interaction, excited isitivie. phoeph:01im,tisced4a. particle collision molecular Interaction ABSTRACT: Various types of nonradlative ene= transfilrAll soild solutlow involvirg aromatic molecules in the triplet state am discussed. . his filist type occurs during the sensibilized phosphorescence of organic compounds in'g~lxssji solution at low tem- peraturiss. The process of deactivation oactirs here &CC61kiLag to. the triplet-triplet schme or, + IFA 1rt6 A where A is acceptor and D is dmr. The pr*ab Uity of the tjAptlet-triplitt emergy transfer is Independent of the singlet-triplat trowf0rojition !of the acceptor vsolo- rd 1/2 c e L 11086-66 ~C C N 5023434 cule. The triplet-triplet type energy transfiW (oonradlamotive), conforom to the Wig- ner rule of preservation of total spins of tW~ oftimiond Ojo acq~irpitor during the energy transfer act and the nonradioactive tr4knsfer of elmi~troni~ excitatiom en-Orgy from organic molecules in the triplet state f4UNS the In the case of this triplet-singlet transfer the acceptor violecUloi trw3foram into the excited singlet state according to 3rD + IrA * Ir. + I rA The triplet-singlet type energy t Irensfer.nee¬ conforai +o'i Wl~nmrls rule. This in- dicates -that in the absencu of photochemical' veaction the Utemal decay of the elec- tronic'excitation energy of armatic noleculle~* occurs via ~-Jlplmt state. Ovig. art. i hass 2 f1gures. SUB CODEt Guam DATEI MOM/ Opw DZIFS 1X17/ Mi REF:, 00.2 j 2JR IV 'J" AUTHOR: Yeratolov, V. ORGt none TITLE: Triplet states of organic cowpounds~in evergy tro~sfer SOURCE, 61mW-glitm Va *1c=njjjXU= Mosc*W jqf"~4. Elemntarnyye protsessy WaLL vyso Ikh oneigly'(Elementaty pro,4*mses of the chemis- try of high energies) ; trudy simpoziuna. Moscow, 1965, 1~6;459 TOPIC TAGS: particle interaction, excited st-otel. excitedklect~or,t. state, particle collision ABSTRACT: The michanism of ener1q. transfer betsteen 0~aani~ 1%010~iules in solid solu- tions I liquid solutions and crystals Is discussed, In term ~ c! vo;onance tfi~my - In solid solutions. if the Wigner rule of preseivatlon of toial spUi Is satisfied, the energy is transferred frm an orgarAc molecule in a tilplat~ ctatO to another in a singlet state and Is in accord with the exchaitge-pasonanca ti~kidchat~'Um ,0+ FA I rD + 3FA where D Is a doom and A Is = acceptor# This ~"*iiplai-trliliqtn~ 3 t chanism is opera tive at a donor ccucentration Intiallid. soluti of S-LO-2-StM-1 ~ioiles/l an4 for the 1/2 a k -L-10840-66-- ACC NRs AT502344.1 Istance of 10-15 A. An Ludu4 interwolecuIar d; "_resonz =6V Mechwui= is "rative and the Wigner, ritle Is not followed when the intermolsculaii,. distimce (donw- acceptor) in the solid solution in 25-60 X. In this case, the acceptov mlecule converts into an excited singleit state according to: 3r + Ir + Irb t Ir D A A In the oxygen-ftee liquid solution, the enerv transfer Is' 1)~! airlplet-trlplet type and follows tho exchange resonance methanism.l: In' liquid S~ivrtiwia the UR.-of organ- Of, ~ b ic molecules in tiAplet state is 10-r--10-3 sec. in ease enzeindl WPIet -trip, let tyEe ener do at an appreciable rate ast an 1'j,_ cone-entratiat of gy trans;Fer procee ccept~v 10 6 _10-6 moles/1 (2930K, [021 = 0, We of the dowwr triplqt Otate 2 10-3 see). The problems of triplot-singlet type energy transt~r in liquid siolutij !ins and of the trip- let-triplet type onergy trawfor in crystals romala wuolveC SUB CODE: SUBM DATE: 23FebG5/ ORM Mr: 6611 !!,VI*H PEr: wo jw 2/2 _71-6 r SOME OMNI AUMOR: Yermolayery, V. L.: Aleitbl% V. Q.; 9a entop Ye. A., ORG: none TITIZ: Detervowbion or th7 energy transport velocity cmatents'la cbelateis of com- plex rare-earth iims t'_"L' SOURCE: AN 866H. I Doklady., Ve 165, no* 5, 1965 TOPIC TAGS: rexC~eartb element, nouradiativel!trailAtIon, li ines~ence quenchingj, electron energy. i6vel ABSTRACT: . The authors deacribe a method!. -for the d0q.ormination of, the rate constantiof nonradiative transfer of~eledron anttd~ rare- Vfrodi a 11gand to a earth molecule forcomplexes of dibjnzoy2qwth4mtc(DB14) with Sr'vi' and iu3"' and for acetylacetonate (AA) with Sm3+, Eu3 0 Tb3+ Dy-"v I The, mmstbod 1~ based an the com- petition between the Intramolecular 11gazd-rare earth tram atitt the intermolecular energy transfer over the triplet states of organic ~ ligind-ct~jmicbai (acceptor) com- pounds. The quon6ers used were raphtthalene for AA and acill'iLinso !.wvthrucene, 1)2- benzanthracene, a#1 pyrene for DEK, The rare-eartb tAmd*dnagnce van excited outside the abn4n7blon band of the quencher (3340 A for M a)~a 4099 A for DB14). 11he measurements. were icisde in toluol at 293L Plot +0 are present~W. of the electrorAic lev- els in triplet-trilget quenching,, of the phosphorescence spe4tra C& the ligand and of the rare earth amd, of the behavior of the luninexce=e quen6bing a~ant. The results M. ~i C,rd .1/2 535 ~73-2 1~ 13631-66 ACC NRs AP60024ft A ~nera tjimi~tr.befteqm orgs show that the intermlecular triplet -triplet i~ nic wolec~les has a higher rate constant than the. lijand--2~ieisrth tii4iti"s ~ vhIch has a Ixigher order of forbidde '' mesa. The application of ibl'a re"Its t,6 ~n attiartic detertaimtIon of.the.content.ot.rare earthaby means of re- e pful to Ac6deWciari sidues is briefly'discussed. Authors ar .4. U1. Terjq_nfor interest, and to A. V. KaEZakin, V. A Arkhangolf alwyat andifl, I.; 'Pitaksakov for sup- plying the rare-earth elements. Ozi t. his [021 ar a-- ~. -gures j SUB CODE: 20/ 6UBM DATE:V 16rApr65/ ORIC Pj6..-' 003/ OTRIPEF: ~'012/ ATD rmq-.ellg~ &-Card ACC NRt AP7004147 SOURCE CODE: UR/0051/671022/GO1/0165/0167 AUTHOR: Yermolayev, V. L._; Sveshnikova, Ye. B.; Sayenko, Yt. A. ORG: none TITLE., Study of the degradation of electron excitation In organic molecules in liquid solution by the method of triplet-trIplot transfer tolraro.sarth chelates SOURCE: Optika i spektraskoplys, v. 22, no. 11, 1967, 165-167 TOPIC TAGS: energy transfer, photolundnescence, fluor"coac*, tucited electron state, aromatic hydrocarbon, aromiatic ketone, strosaftc other, orgonoeuropium compound, chelate coupoundp WAj*#A"d-AWE_ ABSTPAM The controversial nechaniss of do6radation of excitation energy In organic mAecules, such as 2-acetonaphthone, 2-sethoxymaphthaleneo or naplithalene, In liquid solution has been istudied by the method of triplet-triplet transfer to europium t:rie-thenoyltriflui)roacotonate-1, 10-phonanthroline. The nonradiative energy fractia which degrades on the triple level of the organic donor moleCUle vas determined by two procedures. Following the first procedure, the lusinesce-nee Intensity of the evacuated binary solution of the organic donor molecule and chelate was compared to that of an Identical but nonevacuated solution. The differenco between the lumin- escence intensity of evoicuated and -nonevacuated solutionst lev -Anoilevo was equated to the intensity Il.t due to the energy transfer an tritlet levels under operating conditions excludifig the donor to chalets energy tranater on siniiat levels and the Card 112 UDC: 535.373o2 NRs AP7004147 reabsorption of the donor fluorescence by the chaletie. The experimental values of (lev - Inonev) X I--' which are the measure of the fractlon of donor molecules in monev, the triplet state, were found nearly equal to the values of CDCD(1 - qfj)qACzA1 where c and C are wolar absorption coefficients and concentrations of donor and chelate and qfj is the quantum yield of fluorescence of the donor, In the second procedurep the luKLnesconce Intensity of the evacuated binary solutions was compared to that bf the solution of the chalate alone on excitation with a 313 nm source. Under given conditions, the ratio (Iov - Inonev)(Ich - InO460-1 was equated with the fraction of donor molocules, in the triplet state q This value was found nearly ' N'txperiments that the energy equal to 1 - qfl. The conclusion was drawn from bot degradation in the aromatic molecules studied in liquid solution proceeds exclusively -A& the triplet state. Thanks are expressed to A. N. Terenta. Orig. art.' has., 1 table and 1 figwra. tilt) SUB CODE: 07, 20/ SUBM DM: -16Jun66/ OILIG RUs 004/ OTH MYs 004/ GRE)ITOR, M.A., inzhk; TMOLLTW, VtM. . inzh. J. Automatic computer of the amocat of wood In cable netere. Wkh- I avton prols. 14 no.6:46-" Je 160. (MI" 13:?) illectrosic digital computer) .';/147/61/000j'004/011/021 .2 o o E025/E120 AUTHORS: Yermolayev~ V.M:, and Talantov, A.V4 TITLE: Investigation of the effect of pressure on the speed of propagation of flames in the turbUlerat flow of a homogeneous mixture PERIODICAL: Izvestiya vysshikh uchebnykh zavedenJ.y, Xviatsionnaya tekhnika, no.4, 1961. 82-93 TEXT: The investigation of the dependence of the fundamental characteristics of burning on pressure are of grent practical value because this problem in connected with the known worsening of the efficiency of the combustion chambers at great heights, The published investigations into the effect of pressure on burning were carried out for axially symmetrical flown In a small range of variation of the fundamental parameters. In most cases the speed of flow and composition of the mixture were not varied. In the present investigation the i9peed of propagation of the flame has been varied from 20 to 80 m/sec, the composition of the mixture has been varied from 1 to 1.5. CardCY4) Investigation of ihe effect of ... S/147/61/000/004/011/021 E025/E120 the pressure from 0.35 to 1.4 kg/cm2 and the temperature was equal to 423 OK. To obtain the best approximation to the conditions of burning in an engine the experiment was carried out on a flow bounded by walls in a chamber of constant section with forced turbulence of the flow. The combustion chamber was a tube of square section 50 X 50 mm of length 1700 mm, cooled externally by water. A very detailed schematic diagram of the experimental arrangements is given. The values of speed of propagation of the flame in the turbulent flow for various speeds of the flow, mixtures and pressures were obtained, and from these were constructed graphs giving the re.lation between the speed of propagation of the flame and the pressure for various mixtures and flow speeds. A comparison of the nature of the relation 'between the speed of propagation of the flame and the pressure for various mixtures and flow speeds; was made by the use of diimensionless*flame propagation velocities and pressure rati,DS. The effects due to.longthening and shortening the flame are discussed. The following conclusions are arrived at: Card 2/ 4 Investigation of the effect of 5/147/61/000/004/011/021 E025/E120 1) The values and nature of the speed of propagation of a flame are approximately the same in a turbulent flow bounded by walls and in open turbulent flow. 2) The speed of propagation of the flame is proportional to the 0.8-th power of the pulsation velocity, taking account of the dependence of the latter on the pressure. 3) Damping of the turbulence is responsible for varying estimates of the effect of the pressure on the speed of the flame for different speeds of flow and mixtures. Hence it is necessary to calculate the speed of propagation of the flame taking account of the normal and pulsation velocities and their dependence on pressure and damping.- 4) The speed of propagation of the flame in a closed turbulent flow is in good agreement with theory when the effect of damping of the turbulence is eliminated. 5) The decrease in the speed of propagation of tho flame with fall of pressure is one of the causes of decreased efficiency of the processes in the combustion chambors of primary ginginon in high altitude conditions, There are 10 figures, Card 3/4 Investigation of the effect of ... S/147/61/ooo/oo4/oll/021 E025/E120 ASSOCIATIONI Xazanskiy aviatsionnyy instituti KaZadra teorii aviadvigateley (Kazan' Aviation Institute, Department of Theory of Aircraft Engines) SUBMITTEDt April 31 1961 Card 4/4 YERMDLAM YIM.L TALANTOV, A.V. InvestIgating the effect of pressure on the bingth of the con- butation zone in a closed turbulent flow of a uniform mixture. I2-v.vya.ueheb.zav.; av.tekh. 5 no.3tl43-156 162. (MIn 15:9) (Combustion) 41UXOV,, G.1b.,p I=h.; MMOLAMWIJ.A, Coaferonce an inpro"ment of offloiiency in tb* pleettio oquijpmat industry in tho lJralm# Vest# sloktr~wvmo 34 no.2:76-77 7 163o (KM 16:2) (Blectric equiFmont industry-Congresses) 4W)~AMYO.:. V..M,.; TALANTOV, A. V. Rate of flaw propagation in an open and lijkit*d fLow of bcsogens-ouis mixtare, Izv.vys,,uchsb.znv,jav.tOkh. 7 no.2s134-141 164, (lam 171()) Y, I"Fd,X-J4 4~, PIIASL 'I Trtntauro In.1-ind RtbUlorraphlc !1orq-t-t BCOK 140.1 '4c.: TU',~~'71 Nol"? Authors;- ErVIGLAFIr. y. I., and y;o,,vjz-rj,, is.. 11. F'all Titlot F(K--4Y,IJI (F "MIUCTURAil Transliterated Title: Manter strukturnof.-o burentia Publishing Data Originating Agency: None Publishing House: State Scientific-Technical Publishing Hous.? of Cil and Viner-I Fuel Literature. Leninarad BrZ'Lnch. (Gostoptekhizz~at) Date: 1952 No. pp.: 318 No. copies: 7,r)00 Editorial Staff' Editor: Gridin, V. K. T-~ch. Ed.: 'kne Ed.-in-Chief: PerminQv, S. V. Appraisor: 'Icrie Text Data Coverage: The book cr..ntains elementary data on ge6logic.-il structures, conc3tructlr~n of derricks, arrangement of equiTwient, types and quality of drilllii,~, tools, and characteristics of varicus materials (metals, lubricants, transmission belts and transmissirn cables, cement, luvber, etc.) uswcd in well. drilling. The practical methods of drilling wells for !-eo1(-,fjcI-1--l surveys (mapping), structural, and prospecting dr-iLlIflir are Plso, method3 of computinp simple work probleirs unj rat'r!"; of tiril'iln,--- through various strata. Purpose: A textbook for well drilling foremen and personnel eng,11,.ea in survey-I-Ir and prospectinf-. Fac.iliti~s: licne No. Russian References: 11 Available: Library of Congress TWMOIAYEV, V.M.; KARAMZIN. A.Y.; KOVAIRTA, AL.A., inzhener, vedushchly POLOSM, A.S., tekhnichealriy redaktor. t3truct-mral boring; practical manual for workmen] Striaturam burents-, prakticheakoe posobie dlis rabochikh. Mosicra, ks. nauchno--tekbu. Izd-vo neftianoi i gorno-toolivnol lit-ry, 1954. 138 P. (MM 8:1) (Boring) .............. ....... .... "INO V"IIL#yevlc&,* .qvich; r ummirem.y., redaktor; 1motilmovWr., r; I.M...-tekbilabseldy redaktor [Drilling structural and mploratorywells3 Burents str*turno- poiskarykh ekwashin. Leningrad, Goe.asuchno-tekkno lvd-vo neftia- not L Igorno-toplLynoi lit-ry, 1955. 36) p. (KLRA 9:3) (Boring machinery) (Oil well drilling) I v .414- U41~1-1A MARAVIZIN, Aleksandr Vasillyevich; MU40 - - &A-h .LdIcjamiL, SHEVTSOVA, . .. ved,. red. (Boring structural prospecting holes] Burenie strukturno- poisk-OV,Ykh skvazhin. Izd.2.p isp. i dop. Leningrad Ned- ra,, 1964. 390 P. (MIRA 17;9) LYtJBCH=Op A.?.; )Z-FM-OJAW-t-V.Ue- Effoot of cerium on the self-diffusicin of iron, Fix. note i astiMoved. 3.4 no.lsl57-160 n 162. (111M 15;7) (IroD-4%tallography) (Cerium) SOYA IN., A.I., insh.j IZMGLA32VO T.H., insh. Technology of-blant furnace pa purifioation andAle design of scrubbers. Stall 23 no.2t176-1778 F 163. (MIU 16:2) 1. MagnitogorsIdy metallurgichesidy kambinat. 01ases-Por,4-fication) (Scrubber (Chmical technoloa)) V jERMOLRYEV, V'P- MOLf r1j, V. P. . and 114. P. MY(MUT. ----- ------ -- Pamiatka nomirovshchiku-strolteliu, 'Poskvii 4 M15 j 15h8o 70 )~i# s ro At head of title: Nauchno-issledovatellskii aerodronnyi Institut VVS Vs. Title tr.: Instructions of wq)erts 1n setting constructlon work standardso TL?25.2A SO: Aeronautical Sciences and Aviation in the Soviet Union, Library of Congress, 1955. - -XC - -.Te- V F RPTA KE U,-A c 9 1 13 2 ~Urgory Fab 59 868- (316) EXPERIMENTAL PARENTERAL PROTEIN NUTRITION IN SUPGIC- AL PATIMNTS (Russian text) - Ermotaev V. P. - KHIRURW.4 Igs-f, 9 (97-102) Graphs 3 Tables 2 Data concerning metabolism in Wlents following operations on the gaMro4nt~NtjnaI tract and In burned patients are presented. Pronounccd neilat1ve nitrogen balatice (7-12 g.) was revealed In the postoperative period. In burned patients aW in cu,ses with postoperative complications nitrogen balance equittled from 30 to 35 it. In 34 hr. There was it lose of weight and reduced content of protein in the plazins. lPro- loin was administered parenterally In 20 postoporalive cases and 1h 5 ease* with burns, and 55 Lv. injections wore carried out. In 12 cases untoward Mde- reactions were observed, which were severe In 5. Aminopeptide - a new prepaimUout of heteragenic protein. fermentative hydrolynate of whole animal blood - was investig- ated thoroughly. It was tested clinically in 174 patients (85 postoperative 4u-4.89 burn cases). Aminop*pttde was administered I.v., I.m. and s.c. in a doze 14 800- 1,500 ml. (III to 20 injections to each patient); 2 patients had fever and chilLs. In order to determine the efficacy of parenteral ad ministration of &minopeptide in 28 postoperative and 12 burn cases, determination was made of nitrogen talance, protein content of blood plasma, excretion of urea and amino rdtrog*n in the urine. The results of these experiments show that sminolpeptid* has no snaphylaclogenic Foropertles ond to rat toxic. Nitrogen, administored in this form, to Sleadily assim- lated by thit Organism, irrespective of the method of Its introduction. It in poss- ible to maintain nitrogen equilibrium and a positive balance If an adequate dose of aminopeptide to given. Clinical observations and Eaborstory examinations 311ow of the conclusion that aminopeptidt to an effective pr"ration In Parente-rol protein nutrition In surgical patients and its recommendation for wide clinical use to warranted 'Af YMXOIAYNT, T.R., kandLUt meditsinsikih nauk XoWleatlon of prot*Ln a*taboUsm; in mono surgical tients with parenteral infusion [with suw&&V in Uglish, p. 157rirest,ktdr, 77 w.6:12-17 Je 156. (XLRA 9:8) 1. Is gospitallnor khtrurgichemkoy klialki (nach. Prof. 1.S. 11olsonikov. nauchn. rukoyod, - prof o S.SAirgoICIT) lroyenno-seditain- skoy ordena Lenina akadexii Lm. S.R.Kirovs. IsaWrad, Botkinekaya ul., d.19, kv. 126. (IMUSION, FAMONUAL, protein hydrolyeate in protein depletion in surg. (Ram)) (noings, hydrolyeates, parentorvil infusion In protoin depletion in surg. (Rus)) (SuRany. MUTITI. Complicatlons, protein depletion, tho.v protein )V&olysate parenteral infusion (fts)) YKNOLAIRV, T.R., kancl.med.muk (Ioningradt 9, Botkinstays ulal. d*19, L-v#126) WANNION basis and embolism of the pu2nomary arter7 folloving luxNg surgery [with sommory in Saglish]. Teat.ihlr. 79 no.9t55-62 8 1579 (MIRA 10:11) 1. Is goopitallney k1birmVichookoy klWki (rAcho - prof.' I*$* Calsonikov) Vaemao Itainskay ardons Ionim skademil In. S.N. Kirovs. (ANURM, FulAvlaff, dive I 4albollon & thrombosis after Ina surc.) (Pommnom, cowl. so'bollso & throsibools of pulime artery) YMNOIAIW. V.I.. icand.wed.neuk arenteral orotain nutrition for surgical patients Evith sw=ry in %glishl'. Khtrurgilm 33 no.9:97-102 5 '57o (MIRA 11:10 1. Is gospitalluoy khirurgichookey klinilki (nach. - prof. 1.S. Ulsenlkow) Toyenno-maditainskoy ordens Imenins jiksdftil imeni S.N.Alrova. (PROTIMp there use pore burns & postope core, perenteral admin.) (BUM. there proteins, parenterel admin.) (POSTUMATIVX CARZ parenterel admin* of proteins) (IXPMIOMB, PARIWXRAL proteins, in burns & postope cars) TWHOLAYN, V.I.. kandeved.nauk; SRATALIDVA, N.A.0 kand.med.nauk Chronic atelectasis of the middl lobe and lisCils, of the lunC of varied etioloj7 [with sumaa:7 In AnglIsh]. Tsmtokhir. 82 no.1:86-93 Ja 159. (MIRA 12:2) 1. rs gospitallacy kh1rurgicheskoy kliniki (nach. -.prof. 1.S. Ealse- nihm) Toyanw-seUtminskey ordena Lenins akadosit Ineul SoNs Kirovae Adrom awtora: Leningrad, 1-9, BotkinsWa ule, 4-23, gosPitallwa kh1rurcleheskeya klinika. 02SUMAS18v etlol. & pathogen. chrente. of al"le lobe & HWIs (1hu)) YEMOIAIEVp V.R.v Wor meditainskoy oluzlibyi, kwAmed#muk . " HoLung Of VOWAN containing a foreign body foUxdj* tota.1,9wy irraflation of snimalne VoenspookLesbure wel#sW Ap 060 (M& :L4:1) (I(Oum) (RADIATION-PUM Tol, CT --.nMLATBvs- V.R.p kandomed,nauk Arulsion of the nain bronebw ft blmt tmm& of tbo thorax, adrall" 37 so.103-17 Ja I&L. (Him -use) Is lv.,Vsp#al'wy kbinrgioboolcoy kliniki ("~v, - ;rd, IJ. Koleslik*) %y o-meditsirAkay ordma Umiza ekdadi immi SAO Kirevazi I(C=T-4V= AND WORM) (NO=-4WM AND MURIES) MUMMK(ArA, A. T., kand. mod. naukj TIUMIAM, V. R , kand. mad. nauk Aeutw gastric obstruction caused by complete Waxattan of the left half of the diaphrup with transposition ~f the stomach, ap3min and left lobe of the liver Into the tho"i-Ac cavity. Mdrstrglia 37 no.7:87--90 J'l 162. WMA 15:4) 1. Is k3in4ki gospitallney kidrurgil No. I (useb. P"fe I* SO Solemnikov) Voyenno-weditsinakay ordens Lenina &Wemil - Imeni S. M. 11raft, (DIAPMUW.--DISZASZS) (ROWN) (UM) (SPIM) YMOTAYW, T.R. (Uningrad.. K-9, ul. Smirnova, d. 10-es, k7.22) Burg-Ical treatment of late Bronchossophageal fistulas. Grudn. khir- 4 no.59132-1.13 S-0162 (MIRA 170) 1. Iz kliniki goopitallnoy khirurgil No.1 (naalmlInIk - prof. I.S. KC esdkov) Voyenno-medituinskoy ordena Lenin& akedemi-'A. imeni. Kirova. ul, Sul~smd.10-ap;kwo nRXDIAl13Tq Y.R. (L*nlftWo :EntrsPlvmsl b"UTW4PO fOlIAW189 r"I"l Pulxmwry mwgin7- t,'.rod.khir. -ho.446-& JI-4 162. (MM 15: 10) :1. IS Irl4n4lr4 gogq)JW'wy khirunil go. 1, (wwh. - prof. I.3. Jolemnikov)V*nno 4wlltslmkoy ordena Unins aWadi.bwni S.M. Kira". INMAMW V.R. kand.med.nwk (Uningrado X-9v UIq Salmoval d.10AO late results or the stirgical treatment of bronabiectasis. Mn. Irbi vOqnsUo%U N 962, (MM 16 Q) Io, Ufafta gospitallnoy kbIrnr#i (macho, - launat Immimakoy pradi pror, LS. Koloodkovi voyamm-esditaimAroy Ordens, ladna akRdoLU imeni Box. Kirov 0 (~CHIMASIS) MMOIAU.V,q V.A. (Leningrad Y,,-3, ul. Sairnova, d. lQa,, kv.22) Segmental and combined reaect-ons of the lungs in bronchiectuls. Grud.khir. 4 no.6.*59-66 14-D'62. (141itA 16:10)) 1. 1z klirdki gospitallnoy kNItutgii lio,l(nac'hallnik -prof. I.S.Koleard3cov) Voyenno-meditainakoy ordena Unina akademii iwnl S.14.Kirova. (BRONCIII-DISMES) ( LUMS.-DUMBRY) YERMOLAYEV, V.R., kand. mod. nauk Priwa7 failure of the bronchial stump and the pulmonary woUM following radical operationip on the lungs, XhIrurgiia 38'6,1204-19 D 062. (MIRA 17:6) 1. Iz gospitallnoy khirurgichookoy kliniki No.1 (nachallnik - prof, LS, Kolesnikov) Voyenno-seditainskoy ordena Imina akadadi imeni S.M. Kirova, KOLESNIKOV Jq I.S.,, prof.; FUTOV, N-V., prof.1 YEPMULLM., V.R., kand.med. nauk; SOKOLOV, kand.med.nsuk Acute blood circulation disorders in the residuia lum part following patrial g*sectionse Ve.9t,khir.90 no.2028-135 F163. (MIRA 16:7) 1. 1z gospitallnoy khirurgicheekoy kliniki (n*cWd'n:Lk prof. I.S.Kolesnikov) Voyanac-moditsibskoy ordena leaLra Pkademil. imaid S.M.Kirovas Adres avtorovz loeningrad3 Botkinekaya u1.,, d.23, Gospitallnaya khtrurgichealmA k2inika Yoyenno-medietisk- skoy ordena Lanina akademii imn:L Kirova. (LUM4-SURGERT-) (BLOOD-GIRCUIATION., DIBORDFM CIF) JERMIAM kand.med.nauk (Leningrad, K-9,, al. Smirnova, d.10-a, lz:~Ik-v.2.i) Resection of the lungs in bilateral bronchiectmis. Vest,, khir. 90 no.3:11-19 W163. (KMA 16:10) I* Is 1-y gospitallnoy khirurgichookoy k"nik' (naebalinik prof* IeSoNdlesnikov) Voyenno-maditainskoy ordena lanina akedemii imeni Kirova. (LUW6.SUHGFM) (BENCHIETABIS) rI.RMC:-k'rFIIT, 'I.R., dotsent (Leningrad, ul. SmIrnova, Some chara3teris t 'Ice of tl-.-e terhm'yue of -lunit, bronchlertazi.s. Vest. kh:Lr. 1~1 no.9s2rj-2'1 j16,1. 1. Yz gn~tpital lacy kW-urglcheakoy klintki. (rrwh:t~ jr~'-Ic I.S'. K--IP-ozi'Ikcv) Voyenno-meditalrio?v;y rd(tn, iment S.M. Kir:)-m. KOLISNIKOV, I.S.; ORDZHMIKXMO G.K,; SMlWHMKIY, 14.1t.; XW V.R. UKU-BrVSKIY, F.I. Adenoma of the bronchij, their camplications and operative treatment. Orud. khir. 5 noe6llM,-106 N-DO63 (MIMA 1712) le Is kliniki goopital9noy kbiTurg:li (nachaltnik - prof. 1.S Xclesmikor) Voyanno-meditainskoy ordena Imina akademii imeni S.M*Kirova. Adres avtorovs LeningradiN-9. BDtkinskaym ul., d.23. Klinika gospitallnoy khirurgii Voyenno-meditsinskoy ordena Lenin& akademii imeni S.M. Kirow # 14(5) AUTHORS: TITLE: PERIODICAL: ABSTRACT: Card 1/~ SOV/127-59-3-8/22 JermolqZUJ" 9 Bakal.eynik, YaJA.. and Vinogradov, L.V-. Engineers. The Semi-Automatic Control of Mechanisms in the Mine Shaft.(Foluavtomaticheskoye upravleniye mekhanizmami ahakhtnogo stvola..) Gornyy zhui~nal, Nr 3. 1959, pp 31-33 (USSR) An experimental installation for the semi-automatic conVol of hoising mechanisms in the Kapitaltnaya Nr 2 pit of the Degtyarka Copper Mine has BUCcess- fully passed industrial tests. The installation was developed by the KB TsUA (Design Office of Tsvetme- tavtomatika) in collaboration with the Degtyarka,Mine. The maximum utilization of already existing mechanisms 64uipped with pneumatic gear was taken into constdorat- ion, Air distributing devices VR-350 ( figure 1) developed,from ENIMS air distributors, are used in the system. Two men in the hoist cage direct different operations in the hoisting shaft. The system is des- SOV/127-59-3-8/22 The Semi-Automatic Control of Mechanisms in the Mine Shaft. cribed in detail (figure 2). The introduction of this system in the Kapitallnaya Nr 1 and Nr 2 pits will permit a reduction 30 men in the working staff. This represents :1 yearly saving of 340,000 rubles. There are 2 diagrams. ASSOCIATION: Tsvetmetavtomatika, Moscow, Card 212 EPYOTAML.L.L ....Owwwp- PhytcpleLnkton of lake Krivoye of the Warasuk River system. Trudy TSSBS nci.802-96 164. (14IRA 130) L 01293-66 :;.IT AMMM MR: AP54017080- Wogqo/Wod i 581,526-325 1AUTHOR: Yermolayev, V., VITLE: Primary production of lakes with lovered;wat northern part of t1me-Kh1undisk Steppe SOURCE: AN SSSR, 141birsko7e otdolenlyso .X06sttyas .biologo-meditsinskII& naukv no* l# 1965P.14-99 TOPIC TAGS: lake, hvkojoW, algae, photosynthomiss respiration# plant ecology ABSTRACT: In 1962 phytoplankton production of Lakel (Narasuksiy Ra-yon of Havosibir'sIcala Oblast') was!itx~~ its water level was 35 am-below normal# an production of Lake-Kusgan.(in the sam ra m.] gn) wai-` iii its water level was. 1L9 em belask na . A vtonl anirt' ~0,03) 009h/0"9 10V,18 .131 61 0~iy4l I)Ianil when when, (M Iff 6m)- imdat---dt~M -dr- i.- -im --1-4-6 - a LOY -t,1666 -to pie 9 Septembem, 'At the sime UW irstor dMploO (0015 1) liewe flite determino ttio mmbisr or sigios ooutdalii dftd, 66116 amd tive Omouftt of Card 1/3 Y L 02293-t~6 ACCESsioil NR: AP5017080 Aritensity phyto lankton biomass* The ooeffici6nt ot~ph6tosynt~vdia;' P and respiration intensity was detatmined and the it, of, ox;rgen released. per hectare of Uka awfaoe at aAean da'pth 41T 101.1 M'Was (LIMC deteinninede Findirtga.show that- both laked at':Iow9re4Gi4atm1jv 1TVals maintained their J*LOtOsynthetie aotiviit7 des its' a S'ii-pinglani; levol of dissolved salts in the water (1000 to 1999 ;;/1)., ~~Ihe !1sor-s-inal oxyg;)n -production of Lake Xuagans which,. is ~more shallix( aT11 itiore mineralized than Mike. KrIvoje# was aignif toantly ht .111 ir Moth bodiso of watQr'are oharaoterized by intense devOlopment P algae duritag the sumnor nonths, As: a rule, Oeai6nal ohan lit'l-ytopla&.- ton 'production ohmr that with increased nl~mbero of in a given unit of voluxies the intensity of its. photo~jxJ-WIJOIS ~IJJOWO&13004 Howeverg no true correlation wds established betiloon thm OaIues of true ph-ytoplemkton photosynthesis (coefficient. oP plu"400 , intensity and respiration intansitjok PhyOPI'mWiOn jPOIUibei:jm# and Ph`ytDP1ankbon biomswe Orig., art* has: 4,tOleo. ASS011JIATIONs TAMral'tn7l Sibirskif, bbtWchesi .1i arid Siblipokogo otdoleniya AN OSSR11 Novosibirsk (Otntodl: Siberian HotoliaA Garden 6f the Siberftn 13ramli ff SM) L 01293-66 11COESSION NRI AF54017080 UBM ,.. ubtrit 60 ~,Goollp RR MW sovt :, i v! i, Lot m W-66- KC NRs AP5025697 JD r,/, scums 6(563t:: UAM86~ RX AUTHORS: 111 a oi I- - -- I ft,4 1~ 7.77 Razava7sv. Go A., Akol '80 CI]LS/OD47/0047 Au I,' Ar, I A T IWIb ;No* 174697 SOURM Byulletenl lacbretwAy i tovarny1ch anakaw, noo TOPIC TAOSs electric. resistarp chromium.. nickel ABSTRACTs This Author Certificate preal 'hoa'foi:Ma*d) vit ad electrical resistors by vac=m dopq WI%r gr-I Ii3nnto f-JIM to th6 InAttubing, ty~ Him da thin filis beaO.' rA to deargane L. T 49 351.ai6, ixoW :1 Card 1/2 I III "T I ''Issmunw. Winter phytoplanktm In I&M Irivoys of the laremak liver vm+4m. -Trudy TUS wolosi*.49 165, Pbwt%"akton In Lalm Studessys of W Luua River Systea. -Ibid. 350-% (KDtA 18310) S/l95/6l/o153(2?11(?03/O04/0O9 As-/ 0 2030/Z452 AUTHORS: Molin, Yu.N. and'Yormolayov, V.K. TIM: The causes of the change in proton relaxation time during irradiation of aqueous solutiona PERIODICAL: Kinetika I kataliz, v.2, n0-3, 1961, 358-361 TZXT: Hitherto the decrease in relaxation times have been attributed to the formation of free radical a, bu calculation shows that improbably high concentrations, 1017 to 101A 9-1 would be necessary to give the size of effect observed'* The present work therefore resolves this question by irradiating solutions of hydrogen peroxide and also distilled'wat*r, h*xan*,, benzene and solutions of benzoyl peroxide in benzene, and aqueous solutions close in concentration to those used*previously by Y.M.Ydovenko and V.A.Shcherbakov (Ref.2: Dokl. AN SSSR, v.127, 127, 1959), and observing simultaneously the NMR signal and also the RPR signal, the latter indicating the formation of any parama4pietic bodies, including free radicals. The apparatus consists of an EPR magnet, with a hole drilled through one pole, to admit a boam of fast (1.6 MeV) electrons. The specimen in hold in a Slass ampule, diameter 7 mm and volume 0.25 cm3, which in located close to the Card 1/3 313.9 S/195/61/o t/003/004/009 The causes of the change ... 9030/9452 opposite pole to minimize the field inhomogeneity dud to the hole. The NMR field coils are wound on a former which slides over the ampule. ++ The MIR signal in calibrated with standard CuSO4 solutions with Cu concontrations of -OW17 cm-3; the sensitivity is rather less than in previous work because of the Increased field inhomogeneity. The %pecimen of 30% stabilized impurified H202 was -irradiated at 6 x 10 rad/sec and after 2 min the amplitude of NMR signal, which had increased rapidli within seconds reached a high steady value. equivalent to 4 x: 10 9 ions Cu*+ cm-1. On removal of the irradiatibai, the signal fell over some 30 min to about one thlid thinvalue and then appeared constant. It was remarkable that all this time thero was no observable change in the RPR signal, thus precluding the formation of a significant concentration of frte radicals. Similar results were not obtained with the other solutions. The only plausible explanation of the results is tha'~ the relaxation time is decreased by supersaturation into free oxygen, which is known to be formed on irradiation of hydrogen peroxide; thiis is confirmed by the lack of signal in the other solutions indicating that not more than about 1017 cm-3 free radicals could remain undetected, and by the failure of the signal to revert to its initial small value in H202, as should have Card 2/3 309~-9 S/195/6l/OU2/OO3/Oo4/ooq The causes of the change 3030/E452 accurred if formation of free radicals were the operative mechanism. Ackmowledgmonts are expressed to Y.Y.Voyovodskiy and N.Ya.Buben for their interest in the work. There are 2 figures and 9 referencesi 6 Soviet and 3 non-Soviet. The references to three English language publications read as follows. Ref,l; V,T,Duft*y, Bull. Amer. Phys. Soc,, II, VA, 250, 1958; Ref.8.- J.G.Marshall, P.V.Rutl*dge, Nature, v.184. 2013, 19W~ Ref.9: G.Chiaratti, L.Guilotto, Phys. Rev., v.93, .1241, 1954. ASSOCIATIONS: Institut khimicheakoy fiziki AN SSSR (Institute of Chemical Physics AS USSR) Institut khimicheskoy kinetiki i goreniya SO AN SSSR lInstitute of Chemical Kinetics and'Combustion SO AS USSR) SUBMITTZD: October 31, 1961 Card 3/3 35062 s/195/62/003,1001/00/Clo E071/E136 AUTHORS; Yermolayev, V.K., Molin, Yu.N.* and Buben, X.Ya. MW - TITLE: Recombination of radicnis in solid organic substancea. I. Investigation by the method of fusion , PERIODICAL: Kinetika i kataliz, v.3, no.1, 1962, .156-611 TEXT: The range of temperatures at which rCcombination of radicals takes plAce on fusion of various organic substances, irradiated with fast electrons, was studied by the 3np (EiLiz) method. The object of this work was to determine the molecular movements leading to the recombination of radicala in a solid. For this reason the substances investigated had a known phase behaviour on heating. Normal alcohols, ketones, hydrocarbons, aromatic compounds etc. were investigated. To dotermine the stability of radicals at various temperatures, fusion curves were obtained. For this purpose a substance was irradiated at a sufficiently low temperature To in a stream of fast electrons to obtain a concentration no of radicals, The irradiation was stopped at the beginning of the linear part of the curve of accumulation of radicals (no PO 1019 radicals/&). Card 1/3 Rocombination -of radicals in solid ... s/195/62/003/001/003/010 E071A.136 The tenperature To was so chosen that during 10-15 ininutes no noticeable decrease in the concentration of radicals occurred. The substance was then heated for 2 minutes at a temperature Ti '.>T0, cooled to To and the concentration of radicals n1 measured etc. The dependence ni (Ti) was called the fusion curve. It was established that for crystalline substances (substances of type I) a rapid recombination of radicals occurs, as a rule, before melting; for amorphous substances the process takes place near the divitrification -temperature. For cyclo- pentane and cyclohexene (type 11), radicals recombine near the temperature of their polymorphic transformation. For hexamethyl- benzene, acetone, succinic acid (type 111) several ranges of recombination of radicalB can be separated. In the majority of cases the recombination of radicals is, apparently, caused by self diffusion, appearing close to the temperature of a phase change. For substances of type III the recombination of radicals takes place at; a temperature at which the self diffusion of molecules is apparently absent, e.g. in hexamethylbenzene and acetone, radicals recombine partially in the region at which Card 2/3 Recombination of radicals in solid ... S/195/62/00/0011U63/010 E07.1/E;36 the molecules begin to rotate. The recombination of radicals in the absence of self diffusion could be explained by the formation of radicals cl()se to each other, e.g. on the neiglibouring molecules in pitirs, Then initiation of any molecular movement may lead to their recombination. However, the f6riflatiOn Of radicals on ne:Lghbour-ing molecules should be accQr-.pan;Led by a strong widening of components of the superfine structure of the EPR spectra, mtch higher than was actually observed. The authors thank V.V. Voyevodskiy and G.K. Voronova for their assistance. Part of the material of the present r.~Lper was presented at the Second All-Union Conference an Radiation Chemistry. There are 5 figures. ASSOCIATION:-Institut khimicheskoy fiziki AN SSSR (Institute of Chemical Physics, AS USSR) Institut khimicheskoy kinetik! i goreniya SO AN SSSR Card 3/3 (Institute of Chemical Kinetics and Combustion SO AS USSR) SUBMITTED: August Ili, 1961 4~236 3/844,/62Y000/000/056/129 D204/11307 AUTHORS:,,,-Yermalla Holin, Yu. V. and Buben, N. Ya. 'IMSY TITLE: Recombination of radicals in some frozen organic compounds SOURCE: Trudy 11 Vsesoyuznogo aoveehohaniya po radiatsionnoy khi- mii. Ed. by L. 8. Polak. Mose-ow,jod-vo AN SSBR., 1962, 331-334 TEXT: The pre6ent work was aimed at a study of the molecular mo- tions occurring during the recombination of radicals formed under the action of fast electrons at a temperature To, such that no, the number of radicals formed, remains fairly-constant over 10 - 15 min. The compounds were then warmed up*to a series of temperatures Ti (where T i> To ), maintained at Ti for 2 min and cooled badk to Tor at which temperature the remaining conecitrations of xudicale, niq were measured. In cystalline compounde,'duch as MeUH, C 6H6 or n'oetanol, the :mdicals 4~qajjpeared at 0.9 1.0 T (where T M m Card 1/3 U %62/000/000/056/129 Recombination of iddicals..r... D20,4rD307 m.p.), whilst in poorly crystallizing Elubstlan~bes, such as glycerol or n-butanol, the recombihdtion took place in~ the region of vitri- I fic9tion (0 , .6 - U.7 Tm). Tifts rule was confir'med on slowly frozen (crystalline) and quenched'(amorphous) 191-di'cyclohexyldodecane; cooling at an intermediate3rate gave rise to '(ni/no) versus' (T. m plots of an intermediate dhbLracter, shoving the presence of cry3- tellites of varying temperature stability. Such intermediate type curves were the only ones oboerved for paraffin, polyethylene and polypropylene. The recombination is connected with partial destruc- tion of the lattice and amorphous compounds rest)ectively. In cyclo- pentane and cyclohexane, ia'which molecular rotation begins at T rot (T rot 14 Tm)q it vras found that recombination of the radicals took place at T rotv showing that'the radicalvare probably formed in pairs and'recombine as Boorr as rotation becomes possible. The as- sistance of V. V. Voyevodskiy and G. K. Voronova is acknowledged. There are 4 figures. Card 2/3 Recombination of radicals ASSOOIATION: Institut Chemical kinetiki K,inetics LISSR) $,/844,/62/000/000/056/129 D204/D307 khimicheakoy fisiki AN 603R-(Institute of 2hyeical AS USUH); Institut khimidheskoy i goreniya SO ILK SSSR (Inat'Ltute of Chemical and Combustiont Siberian Branch of the*AS Card 3/3 YERMOLAYWs V. L. PA 175T77 r lye Teiji*~reti is of t ur 0 a P4r 9 4"stwikov,, V. L.: Yei J~: Dok Ak Nauk. SWR" V61 LW NO 1: 4 ppy k5tudies variation ixi phoophorciscence,of OcLe. i63z ti ]Avin et t t -0-114 d4r*&~ n co o: W,v ncu of-activai a, t W ': -I 0, he' of isiditins: 6.UtaittedL r4tv litt, eitt, A .4., ...... IGAIIIC M'dil, MES AT. t xTZ MP *!Jj~At Pri Mzkot Temp"criturd). A.: K. Te 4w bp 0. Sol froiri Old" S. vLvttdta lit-46( lap,, An xtttt*Vt two f 4('thihj~ of exlItArl 99 onarjr in co erat one WgIocMIG to ttcu~~' a( a- tumustemenco of t4,11wd teduldi im wbero thip prim"y Im f it 0 lit O"imuldi 06 tit 4 muldi im USSR/Physics - Phosphorescence Sensiti- 21 Jta 52 zation "Sensitization of Phosphorescence of Organic Male- cules. at lov Temperatures: Intermolecular Trans- fer of Energy With Excitation of the Triplet Level," Acad A. N. Terenin, V. L. Yermolayev "Bok Ak Nauk SSSR- Vol 85, No 3,,Pp 547-550 Ditc-asses investigations devoted to the,problea of t*ansfer of excitation energy in soIns of mirts of f-h-orc=11-us- 9-r-1-am-tic-mols st te*p of liquid air--, fvr--the 7urpose of establishing the 'phenomenon of sensitimtion of excitation by one compd. of the A Giver, t a Z;VU_DI_rQi7J_-i PhOSPbor&acence of wwl=a dc*4d& in dijendlence on conen of another. Submitted 3 May 59- 235T92 phoophorescence ot ax=mtI*to*.u~Aj! Periodical 1 Dok. AN SSSR 102/5, 9125-928, jrt~, 3a 2.4 51 Abatrtat I An experimentea otudy wapi, a .~i of th'O Ond=t ienditin44 4 ,ae- of t: in 1 all ~,Osphore nce and the. doU= atj TEMNIN, A*N. ; ,Y=~WA~!Wj%hp.,t Intemolomlor transfor of onera owurrim In sonaltised luminesconce. lzv,.AN SSSR. Sorf1s, 20 no*40W Ap 156. (MU loa) (imlawam) (I%wmaowo) ern*-NO'tf~\JQ-NI VL USM/Optical - Aysical Optics K-5 Abs Jour fteferat Zkur - Fizika, No 5, 1957, 12962 Author I sFM' V LW--- Inst Title Sensitized Phosphorescence of Aromstic Compounds (Baergy Transfer from Triplet to Triplet Level). Orig Pub Ity. AN SON, ser. fiz.,, 1956, 20p no 5. ~1"19 Abstract A quantitative investigption was mode of the phenomenon of sensitization of phosphoresewces comected vith radia- ti(mless migmtion of the energy of electron excitation between the molecules, vith the excitation ofthe triplet l4wel. For nor details see Abotract 12961., Card 1/1 T: t1ft/Physics, - Luminelpeence Pub. 118 - 2/7 Authorm I Tereniii, A. No and' Yermolayev; V. 1 L. S Intormolecular transfer. of onergy, :~11 ~htt phimoi 0, 1 0-r! .Eli rill itized lurdineseence of organic Symema I t' 11) Usp. Fiz. nauk Jan 014 58/1,# 37-689 I The intemolecular tran-S'far of ovlem~fly ikeer-4wt "I'l III-% , ; an the sonAtization of prglxdv~ I Two types of energy transfer:am- cl4nrAA~rvdi 01 'ItAc mm" lnlluctivu~. Varimis cases are analy?ed ~rt whicH emAtiie& 1111,110111 and thh enerj7,,r tran-ifur vo-re obsvrvoi~. B Gum., 121 UI;A, 28 USb1t (1927-1955). Gra-phs d i a I..rv', an So. inst.itution i Submfitted woo.,. m YANOZATNT. V. L, XRMCEMOV, T.T.. SN=14N, N.M. -- 1013 Nodorn mignallng, central control mad block mystem ovdPwat used In underground electromotive transport. MborostrooUt no,12:2-5 D '56, (Submwo-41analing) (fttematic control) (MIRA 10:1) AUTHORS$ Daitriyovskiyo 0. D. 0 Yeraglaxas, 2o- 114-4-20/63 Torenin, A. X., Nombor'of the Academy TIT18i Direct Measurement of the Lifo of Excited Molecules of Chloro- phyll and Analogous Pigments in Different Media (Pryawye iz- moreniya vreasni shizni vosbushdonnykh malakul khlorofilla i analogiobqft *. pignentov v razlichnykh aredakh) PIRIODICALs Doklady Akad"ii Sauk 335R, 1957P Vol. 114t Nr 4,--Pp,. 751-753 ('USSR) ABSTRACTe In order to determine this life 't the authors measured the duration of fluorescence by means of the phase fluorimeter by A. M. Sonch-Bruyeviah ot &I. whose resolving power in time is 2.lo-lisoo. Other devices used in these investigations and the errors of seasuresent are also shortly discussed. Fluoresc- - ones was excited by the mercury line 436 0"-- Observation was effected through the light filter XC-1o wii h a thickness of 4 an. The concentration of the solutions always remained below 10-5 Rol/l. The values obtained for the solutions of ahloro- ph7ll and related pignonto in various solvents at + 2oOC are summarized in a table. The here measured life of the excited singlot state of chlorophyll markedly differs from those values Card 1/2 which were obtained by indirect methods from the polarization Direct Measurement of the Life of Szoitod Molecules of Chlbro- 2c 114-4-20/63 pbyll and Analogous Pigments la Different Media -of the fluorescence and from the integral of the absorption band. The decay time of the fluorescence of the pigments de- ponds only little on the solvent. for chlorophyll by it is ap- proximately twice as small as for chlorophyll a, which is con- nooted with the different quantitative yield of fluorescence. In phtalooyanidoe life is monowhat longer than in phoophitines of the corresponding metals. Romatoporphinin has the loMmt de- lay time* If a Zn-atox is tntroduced into the pigment instead of a Mg-atomj the decay tizio of the fluorescence is reduced -to about half of its fozuor length. A *0, 1e contains the here obtained date on the docay time of the fluorescence of ohloro- phyll in natural media. The values thus obtained are about 3-8 times as short as in acloular solutions. In the living loaf ,t depends on the intensity of exposure to light. The reduction of't and the reduction of fluorescence yield in the living loaf are largely due to the high concontration of pigments under thoso'conditions. There are 2 tables and 6 references, I of which I a Soviet. SUBMITTnt NOY 31 o 1957 Card 2/2 .YERMOLAYE'll V.L.; ALESHIN, V.G.j SAYENKO, Ye.A. Determining the velocity constanta of enera trunsfer in chelate ecmplexes of rare earth ionis. DokI. All SSSR 165 no.5:1048-1051 D 165, (IMIM 19: 1) 1. Submitted April 26, 1965, YERWjLkYEVv V.L.qGand Phyn-]L~.th Scl-(dics) Of Org,-UIJC COMPOUIIdS ~'Lt 10""' tOUPOr!:tUres" LL-:,,ll 1953- 10 Pi) v (Stato Order of Lenin Optical Inut in S.I.Vavilrw), '1450 mdzlo (4147-5'~,', 129) -'. TIMLATW,, V.L.; KOTLTAR, LP.; SVITASIW, K.K. Internal conversion frou the fluorescent to the phosphorescent 1wrel In naphthalene d*rlystivem, lsv,AIW SSOR.Ber.fiz. 24 no,.5:492-495 Ff 060. (91U 130) - (11aphthalene-Optical properties) (Umineacence) 24(4) sov/51-6-5-14/34 AUTHORs YermolAyev, V.L. TITLBs Dependence of the Probability Of Energy Transfer in Sensitized Phosphorescence on the 0--cillAtor Strength of a Triplet-aingist Transition in the Molecule of an Snergy Aa,,-optor (ZMViC1M03tt varoystnosti perenons, snorgli pri sonsibilisavannoy fosforostoant-Ai ot oily ostaillystors. triplot-vinguletnogo perskhoda v molokule aktaeptora energii) PBRIODIGALs Optiks, I Spektroalcoplya, 1959p Vol 6, Wr 5, pp 642-647 (USSR) AMTRACT: The paper vas presented at the Sixth Conference on Wminescence, Ld,ningrad,1958. In 1952 Teronin and the author (Rats 1, 2) discovered sensitized phosphorescence of aramtic compounds. Later kReft 3-5) it; was found that a resonance transfer of energy -with direct excitation of' a triplet level in the energy acceptor takas place in sensitized ptoophorescence. The present paper describes studies of the effect of the oscillator strength of triplet-singlat transitions in thacnergy acceptor on the probability of energy transfer ax4 consequent quenching. For this purpose acceptors witti similar phosphorescence spectra anrl Yvidely differing decay constants were used. Xhey were: naphthalene. Card 1/4 l-,chloronsphthalons, 1-bromonsphthalone and 1-iodonaphtnalons. Their SOV/51-6-5-14/34 Dependence of the Probabilitj of NA&rgy Transfer In SenslUzed PbosphDreseence on the Oscillator Strength of a Triplat-Singlot Transition in the Uoiscule of an Snargy Acceptor phosphorescent properties are listed in 'Able I,- the height of the triplet level, in ca-1, is given in col 21 the decay constant, in see, in given in col 3; the quantunt yield Is &1vvA in col 4. Experiments showed vat phosphorescence of bwzophenons or bensaldehyde was quenched to the same extent by any on* of the four aeceptors listed abovs (at tJ20 same acceptor concentration of 0.32 solo/litre at -19,50C, see %ble 2). This is shown clearly in Fig 1 -whore the continuous curve represents quenching klowering of intswity of phonphorescenee)of benzophenone by naphthalene (circles) and 1-bromona phtho. leas (crosues) as a function of the acceptor concentratioa. Although the oscillator' strengths of the triplet-einglet transitions in naphttAlone a-ad 1-bromonaphthalene differ by a factor of about 100 their quenching action in represented by the same curve. ThIs is also t--ue nf the door@&@* of the pbosphores".nas decay constant It, due to xgLphthalezo and I -bromonaphtheL Ions in bentophenono. -ghe effect on ,e is represented by the dachod avirve In Fig Is the effs---t of naphthalene La shown by dots and that of l-brmonaphtbalene by trianglos. These lacts contradict directly one variant of t1w theory of radiationless %J bard 2/4 i)norgy transfer (Galanin, Figrater, Dexter). This variant predicti BOV/51-6-5-14/34 Depen4ence of the Probability of unergy Transfer in Sonsitised PhoaFhoresconce on the Oscillator Streqtft of a Triplet4linglet vansitioa la the Molecule or *a Zaergy Acceptor strong dependence of the probability of energy transfer between donors and acceptars(and the consequent quenching of the donor phosphorescence) on the probability of radiative transitions %or-cillator strengths) In the, acceptor. Xt was also found th,Lt the quaatum yield of sensitized phosphorescenco (defined as the ratio Of IA, the number of quants emitted by the acceptor, to ID, the number of quanta emitted by the dortor) increases more slowly along the acceptor series from napnthalone to 1-iodonsphthalone than predicted by the theory mentioned above (Fig 2). This several predictions mentioned above stem from an assumption that eniorgy is transferred by an inductive interaction of electromagnetic fiolds of the molecules talcing part In the transfer process - Consequently this mechanism must be abandoned in favour of another variant which ascribes energy transfer to exchange -ros onance effects vrnich axplain satisfactorily the observed facts. Ackzowledonento are made to Mqrd 3/4 V SOV/51-6-5-14/34 Dependence of the Probability of Energy Transfer in Sensitized Phosphorescence on the Oscillator Strength Of A Triplet-Ginglat Transition in the Molecule of an Energy Acceptor Academician A.N. Teranin who suggested the work and directed It. Tharis are 2 figures , 3 tables and 28 reforences, 16 of which are Soviet, 4 Frencb, 4 German and 4 English. SUMffTTBDs July 20, 195P, card 4/4 Boll it, J~S_O 0 B006Y,31 AUTHORSs J'orwolayev, V.- 0. Serenin, Ao W. TITLEs Intrasolecular inergy Transfer on Triplet Levels PERIODICALs Ifspekhi fisicheskikh naukp 1960P Vol- Tip 10~ 1, pp. 137-141 TEXTs The prosent paper is a continuation of a nuab4r of previous investi- gations (Refs- 1-7)p that had dealt withsimilar problemes. It was the aim of the investigation under review to show that an intramolecular energy transfer from the triplet level of a carbonyl group to a triplet level of diphenyl- or naphthyl group is possible. For this purpose, the authors investigated the spectra and the duration of phosphorescence in a Beries of diphenyl ketones, naphthyl ketones, and aldehydes. The clearest results were obtained with phenyl-4-dipbenyl ke4one (pbenyl-4;bsazophenone), the absorption spectrum of which at -1960CI In ethanol eth r (mixture 20) is shown in Fig. 1. The benzophenone spectrum taken under the same conditions, is also shown for a aomparition. P~hnyl4iphonyl ketonelexhibits two bands; a scheme of the electron lerel of in Fig. 3. Wumerous details are giveng concerning the opectra that were 5/053 6()/071/01/05/011 Card 1/2 4W Intramolecular Energy Transfer on Triplet 0/0~/60/071/01/05/011 Levels B006/B011 examined. Fig. 2 shows the phosphorescence spectra of~tenzophenone, phwW1r4-dipbeny3. ketone and p-oxydiphonyl in other, taken under the same conditions as the absorption bandl. The duration of phosphorosconott of these three compounds was 4-7*10-2 seci 94 see, and 2.5 sta, respective- ly. Table I contains date an phenyl diphbnyl ketone and a number of other carbonyl derivatives of diphonyl, concerning the position of singlet- and triplet levelt extinction periodl and phosphorescince quantum yield. Three of the compounds investigated wert'syntbealzed by 1. Ys. Postovskiy. Table 2 offers the same data for some o&rbonyl de'riTatiTeg-of na hthaleney Fig. 4 shows the phosphorescence spectra of I-ebloronaphthalene, and 2-naphthyl methyl ketone. All data and all spectra reeer to mixtures with ethanol ether Wt -1960C. Investigations show that the luminescence of carbonyl derival6iVea of diphenyl and naphthalene can be ascribed to an intramolecular excitation energy transfer. This sxplainm tho lack of fluorescence in these compounds. The naphthalene derivatives were prepared by A. I. Shatterishteyn. V. K. Watveyev anti A. T. Troakehenko.. There are 4 Ngur 9, 2 tabies', and 10 Soviet roferenceso Card 2/2 YER14OIAYEV, V.L. ImEmocence, of o imple benzene derivatives. Part 1. Arozatir. amineo. OptA opektr. 32 noe,4s492-497 0 061. WPA 14.20) (Benzene derivative&-Spectra) YIMMOLAUV,, T. L. Spheres of action of quenching in the case of energy transfer between triplet levels. Dokl. AN SSSR 1.)9 no.2:348-150 JI 161. (IMA 14:7) 1. Predstavleno, akademikom A.N. Terenih*m. . (phosphorescence.) (Nucloit At6mic) S/051/62/013/001/006/019 E039/E420 AUTHOR: Yormolayev, V.L. TITLE: measurement of the quantum yields of xonsitized phoxphorosconce as a method of studying quenching processes at the triplet level of organic molecules; PERIODICAL: Optika I spektrookopiya, v.13, no.1, 1962, 901-05 TEXT: The quantum yields of xonxitized and normal phosphorescence are measured for a series of aromatic molecules in solid solution at 770K. It is shown that the quantum yields of sensitized phosphorescence for all the Investigated combinations is independent of the concentration.of acceptor and donor energies. Results obtained are explained on-the assumption that the non-radiating tranxfor of energy up to the triplet level in accompanled by-quenchIng and that all the quenching inxidearomatic molecules-In solid-xolution is concentrated in the triplet state. Measurements of quantum yield of sonxitized phosphorescence are able t6 be used to determine quenching in t rlpl*t levels of donor or acceptor energy. Quantum yields are determined for valuex:of imccoptor on-orgy Card 1/2 s/o5i/62/013/001/oo6/019 Measurement of the quantum E039/9420 concentrations"wr 6.3 x 10-2 to 4.8 x 10-IL'mole/litr*. A minimum quaintum, yield of 0.070 is observed for carbax6le and a maximum quiantum yield of 0.73 for phonanthron* + 1-chloro- naphthalene, There are 1 figure and 3 tables. SUBMITUD: Card 2/2 May 25, 1961 .. ............. TERENIN, A. N. ; YERMOIAIU.. V. L. Inaetl*ation of the triplet state In aromatic moleculeas Ixv. AN SSSR. Ser. fiz. 26 no.1:21-29 Za 162. (MgM l5s2) (Aromatic compounds) (Kolecular dynamics) M0401AYEVP #.L. s av Yea.; SHIGORINO D.N. I- Nomrsdiative onersy tr=oror betwom the triplet and singlet station In organic so2sculowl d1ommolon of A*N*Teronla and V.L. Iriolmm's report Ormeftmation of the triffileVotate in aromtic moleculejP. Inv. AN SUL Ser. ris. 26 no.1:29- 31 -T& 162. (MITA 15:2) Organic a -A-N Nolecular ftomics" ). i ARISTOV, A,V.; ULA)p I V.L.; LEVSHIN, V.L.; 140KHMA, G.A.; MEMASOV, A.S.; SHIROKOV, V.I. Boris IAkovlevich Sveshrdkov; obituary. Usp. fla. nauk 81 no.lt 201-210 S 163. (MIRA 16:12) 1- A. 11 1 0110,4/6.3 107/005/061'7/0~pp mpjt~~s in vitreaus Jbilld ~n Hlnok 10- 15 fis I ii6~.o 617-622 31 i3itald.ait ~f molgiciAea' in ani JURkL I r,-,nf:-t- Card 1/2 - - - - - - - - - - - - - - -- 6~~- 11 ;! I T .I ; i . I Ii i . - , ;.. . . , ;I ". I- I . . , '. - ~ A I.. . ~ - . . - 1 m L 3.02~77-0 ACCUMON V; AP3002305 8 -1/153P80A 1/60 !1/06T) AUTHOR: Yenoolayev,- V. L. TrAt ~~f ~energ~mj T'ITLE ~Or o M SX lzorgoAic sys,taM vl~ t~~ tLrtV11Pqti011 rit, tno triPlet stat4l, 3- Solid solutiova'and SMIRCE Usj*khJL fizichesklkh nauk,, v, 80j, n I$; 19,6j 3 14 ;17 w na TOPIC TAGS: - triplet level transitio , glasslik6~ org~,L-. Yrtinw.. crys-zalli'le organic systAms.# co ncentratlon quenchingi:orpnic ABSTRACT: Via articlep a th i )f orough and &-tailed #uv ol I Tic~nt level nts in tZe-field-oflenergy transfer in orrsgnic 6-A6=, Is i in a sarj~es. The first (by A. ff, Tarenirl-) and -the I second ~ty Me 195' z published in:1951 and o, respectively4 ~ Tz with the t~tudy of nonradioactive electron excitation en4rgy;tranm ilt,jareft-4 tbe triplet L-wels of organic molecules in glasalike and.cz,at i1ne! all MLCeiIA4, 10W f--Ppi!Z -ttllre3. - i -t - .Ohl' re.- The text. Is - divided. into three Par so Cion rj: ~gj, de~, mi3. In quenching tij~~, and the coacdntration qu~n; o. h ani ~Nita Phos.Ph,.)res,,!en--e :e Al~ C,,d 1 /2 MM JMW4rLV?.V.L.; SVEMIKOVAO Ye.B. Indwtive resonance energy, transfer from aromatic molflicules in %e triplet state. Dokl. AN SSSR 149 no.6tl295-2298 Ap 163. (MRk 16t7) 1. Predstavleno akademikon A.N.Tereninym. (Aromatic compounds) (Quantum theory) ACCBSSI01f KA: U'4020978 AVnIOR: Yermolayev, VA. TITLE: Triplet-triplet energy transfer between identical molecules in solid solu- tions at 90ft SOUIM. Optika I spektrookopiya, v.16, no.3, 1964, 348 TOPIC TAM: enfargy transferp energy migration# triplot-tri plot tranxforp phospho- roscence quend4ingp benzophonons, naphthalene# triplet level ABSTRACT: Tho phenomenon of triplet-triplet energy trans~or between different mole- cules was discovered by the author in collaboration with 'rerenin In 1952 (A.K.Ters- nin and V.L.Yermolayev, DAN SSSR 85,547,1952) and is known to occur in solid solu- tions, liquid solutions and crystals. The purpose of the present study was to de- termine whether it can occur between 111w (identical) molecules in solid solutions at GOOK. The experiments consisted in'moasuring the quenching of the phosphoroscarm of bonzophenona (donor) in the presence of naphthalene Caacoptor) in other-alcohol solutions at different, concentrations (from 10-2 to 1.11 11) of the benzophonone. The observed vixiation In quenching Is attributed to anorgy migration between the ... ....... ACCESSION XR: J"20978 triplet levels of the dowre "In conclusion, I desire to otpress my gratitude to A.H.Torenin for his Interest JA the work and 0,5.2sossax"Yad for stinulating dis- :cUssions. ASSOCIATION: SUM11ITIM MUM DAIS AM Mpr" INCL: 00 8198 COWS m Ew SM 003 OMM: 000 Card =77-7= YERMLAYET, V.I,.; Wi3th of luninescence spectra aM Stokes's lDsseu :Ln tx-8nzI'~-_f'2r;z from fluarencent and phosphorescent levels of axonall-ar corToun`:3, Opt. i spektr. 16 no. 4:704-705 Ap 164. (MrHA 17; 5) L 00988-(6 'P 'XESSION NR* AUMOR: Yermolam,. V. L. 7TITLE - Triplet 4riplet energy transfer and Ltd applic.atianf;Hliri lit hescence and ~'Jeoto;hemiLal reactions 17 'S, 1965', 1266-1270 'SOURCE: AN SSSR. Izvestiya. Seriya fizichesk4a, v. 29 no*,~ PIC TAGS: IntermDlecular energy transfero tiiplat triplet!'biranarer, organic luminescence, energy decay, photochentlcal~rewtioaj! rare4ttrth chelate, loser CT: Soviet al2d. Western research data, including i964 46i;a. triplet-triplet 0!a energy transfer in organic molecules were reviewed and,dii)eusnfid, flew data ob- talned by, the auth&r on triplet-triplet energy transfer betqekt id4ntiaal molecules in solid (fr--zen) s6lutions vere given and discup'se&T6 rapiday goiring number of publications on the'~ subject in the past few year6 (since''-i962) was:explained in terms of possibilities for the application of tripletp-triplet energi, tranafer to the study :1of the decay of eleittronic excitation energy in'organic molecules, mechanism of photo- -data were re- Ichemical reactionsgiand rare-earth chelate lasers. Rev experimental ported on concentration quenching of the phlophorescence, of -a benza,phenone -donor by 1/2 LM L 00988-66 ACCUSION MR: AP502DT80 a naphthalene-accept6r in alcohol-ether solution; at7: 90K. Recently, ~Preliiainar~y data on this subject were,. published (Yermalayev, V. V. Optika I s"Idroatolpiya, v. 16, no. 3A 1964, 548). 1.1he new data included.changea..ih the phosp6oresdence spectrAun, quantum yields and~.quenching of the phosphorescence of 9. be~*'&phe~'oqe-donot at high donor concentrations. These changeh vere**.ainad ?nain1;yj,Ps tho Wtict of the radiationless tripleii-triplet energy transfer bet*een idantt4',%J,i dondp'moloculeb in oolutions. This eff4ict is considered important for.bi6logicml~!Aad drolahic scintil- lators studies. In tonclusion. the author, e ressed, the be]AO'ij'~ thst~l iriplet-trip~ei~ VP I I . transfer must p1q1 &~'significant part in photobi6logical proc6i~ses.'! This paper was presented at the Thikeentb conference on Lumin'e9`4 %nd Holecw u1sal, Lumineacence r 'held june 25-JulY- 1. 1964, im* dr ov., Ori~v art,4 'has: 2 fig- uree and 3 formulas. CJX1 MSOCI&IOIT none SUBMITTED: 00 ENCL:. 00 SUP CODE:NPIOP NO REF SOV# 012, OTHM! .017i *06 ATO M.Es p TITLE.- Various types of nouradiative ensrj&:Ar4nsfsr fvWj inwiltUd wolecitdles In triplet state SOURM Simpozium pa islamentarap pratisessojo M-11. 11~qfroy. Holstow 1963. Elementarnyye protsessy khIaLL vysokikh e*ifx Uy of high energies); trudy simpozluma/xbsi~ov, 1965, 100. TOPIC TAGS: particle interaction, excited isitivie. phoeph:01im,tisced4a. particle collision molecular Interaction ABSTRACT: Various types of nonradlative ene= transfilrAll soild solutlow involvirg aromatic molecules in the triplet state am discussed. . his filist type occurs during the sensibilized phosphorescence of organic compounds in'g~lxssji solution at low tem- peraturiss. The process of deactivation oactirs here &CC61kiLag to. the triplet-triplet schme or, + IFA 1rt6 A where A is acceptor and D is dmr. The pr*ab Uity of the tjAptlet-triplitt emergy transfer is Independent of the singlet-triplat trowf0rojition !of the acceptor vsolo- rd 1/2 c e L 11086-66 ~C C N 5023434 cule. The triplet-triplet type energy transfiW (oonradlamotive), conforom to the Wig- ner rule of preservation of total spins of tW~ oftimiond Ojo acq~irpitor during the energy transfer act and the nonradioactive tr4knsfer of elmi~troni~ excitatiom en-Orgy from organic molecules in the triplet state f4UNS the In the case of this triplet-singlet transfer the acceptor violecUloi trw3foram into the excited singlet state according to 3rD + IrA * Ir. + I rA The triplet-singlet type energy t Irensfer.nee¬ conforai +o'i Wl~nmrls rule. This in- dicates -that in the absencu of photochemical' veaction the Utemal decay of the elec- tronic'excitation energy of armatic noleculle~* occurs via ~-Jlplmt state. Ovig. art. i hass 2 f1gures. SUB CODEt Guam DATEI MOM/ Opw DZIFS 1X17/ Mi REF:, 00.2 j 2JR IV 'J" AUTHOR: Yeratolov, V. ORGt none TITLE: Triplet states of organic cowpounds~in evergy tro~sfer SOURCE, 61mW-glitm Va *1c=njjjXU= Mosc*W jqf"~4. Elemntarnyye protsessy WaLL vyso Ikh oneigly'(Elementaty pro,4*mses of the chemis- try of high energies) ; trudy simpoziuna. Moscow, 1965, 1~6;459 TOPIC TAGS: particle interaction, excited st-otel. excitedklect~or,t. state, particle collision ABSTRACT: The michanism of ener1q. transfer betsteen 0~aani~ 1%010~iules in solid solu- tions I liquid solutions and crystals Is discussed, In term ~ c! vo;onance tfi~my - In solid solutions. if the Wigner rule of preseivatlon of toial spUi Is satisfied, the energy is transferred frm an orgarAc molecule in a tilplat~ ctatO to another in a singlet state and Is in accord with the exchaitge-pasonanca ti~kidchat~'Um ,0+ FA I rD + 3FA where D Is a doom and A Is = acceptor# This ~"*iiplai-trliliqtn~ 3 t chanism is opera tive at a donor ccucentration Intiallid. soluti of S-LO-2-StM-1 ~ioiles/l an4 for the 1/2 a k -L-10840-66-- ACC NRs AT502344.1 Istance of 10-15 A. An Ludu4 interwolecuIar d; "_resonz =6V Mechwui= is "rative and the Wigner, ritle Is not followed when the intermolsculaii,. distimce (donw- acceptor) in the solid solution in 25-60 X. In this case, the acceptov mlecule converts into an excited singleit state according to: 3r + Ir + Irb t Ir D A A In the oxygen-ftee liquid solution, the enerv transfer Is' 1)~! airlplet-trlplet type and follows tho exchange resonance methanism.l: In' liquid S~ivrtiwia the UR.-of organ- Of, ~ b ic molecules in tiAplet state is 10-r--10-3 sec. in ease enzeindl WPIet -trip, let tyEe ener do at an appreciable rate ast an 1'j,_ cone-entratiat of gy trans;Fer procee ccept~v 10 6 _10-6 moles/1 (2930K, [021 = 0, We of the dowwr triplqt Otate 2 10-3 see). The problems of triplot-singlet type energy transt~r in liquid siolutij !ins and of the trip- let-triplet type onergy trawfor in crystals romala wuolveC SUB CODE: SUBM DATE: 23FebG5/ ORM Mr: 6611 !!,VI*H PEr: wo jw 2/2 _71-6 r SOME OMNI AUMOR: Yermolayery, V. L.: Aleitbl% V. Q.; 9a entop Ye. A., ORG: none TITIZ: Detervowbion or th7 energy transport velocity cmatents'la cbelateis of com- plex rare-earth iims t'_"L' SOURCE: AN 866H. I Doklady., Ve 165, no* 5, 1965 TOPIC TAGS: rexC~eartb element, nouradiativel!trailAtIon, li ines~ence quenchingj, electron energy. i6vel ABSTRACT: . The authors deacribe a method!. -for the d0q.ormination of, the rate constantiof nonradiative transfer of~eledron anttd~ rare- Vfrodi a 11gand to a earth molecule forcomplexes of dibjnzoy2qwth4mtc(DB14) with Sr'vi' and iu3"' and for acetylacetonate (AA) with Sm3+, Eu3 0 Tb3+ Dy-"v I The, mmstbod 1~ based an the com- petition between the Intramolecular 11gazd-rare earth tram atitt the intermolecular energy transfer over the triplet states of organic ~ ligind-ct~jmicbai (acceptor) com- pounds. The quon6ers used were raphtthalene for AA and acill'iLinso !.wvthrucene, 1)2- benzanthracene, a#1 pyrene for DEK, The rare-eartb tAmd*dnagnce van excited outside the abn4n7blon band of the quencher (3340 A for M a)~a 4099 A for DB14). 11he measurements. were icisde in toluol at 293L Plot +0 are present~W. of the electrorAic lev- els in triplet-trilget quenching,, of the phosphorescence spe4tra C& the ligand and of the rare earth amd, of the behavior of the luninexce=e quen6bing a~ant. The results M. ~i C,rd .1/2 535 ~73-2 1~ 13631-66 ACC NRs AP60024ft A ~nera tjimi~tr.befteqm orgs show that the intermlecular triplet -triplet i~ nic wolec~les has a higher rate constant than the. lijand--2~ieisrth tii4iti"s ~ vhIch has a Ixigher order of forbidde '' mesa. The application of ibl'a re"Its t,6 ~n attiartic detertaimtIon of.the.content.ot.rare earthaby means of re- e pful to Ac6deWciari sidues is briefly'discussed. Authors ar .4. U1. Terjq_nfor interest, and to A. V. KaEZakin, V. A Arkhangolf alwyat andifl, I.; 'Pitaksakov for sup- plying the rare-earth elements. Ozi t. his [021 ar a-- ~. -gures j SUB CODE: 20/ 6UBM DATE:V 16rApr65/ ORIC Pj6..-' 003/ OTRIPEF: ~'012/ ATD rmq-.ellg~ &-Card ACC NRt AP7004147 SOURCE CODE: UR/0051/671022/GO1/0165/0167 AUTHOR: Yermolayev, V. L._; Sveshnikova, Ye. B.; Sayenko, Yt. A. ORG: none TITLE., Study of the degradation of electron excitation In organic molecules in liquid solution by the method of triplet-trIplot transfer tolraro.sarth chelates SOURCE: Optika i spektraskoplys, v. 22, no. 11, 1967, 165-167 TOPIC TAGS: energy transfer, photolundnescence, fluor"coac*, tucited electron state, aromatic hydrocarbon, aromiatic ketone, strosaftc other, orgonoeuropium compound, chelate coupoundp WAj*#A"d-AWE_ ABSTPAM The controversial nechaniss of do6radation of excitation energy In organic mAecules, such as 2-acetonaphthone, 2-sethoxymaphthaleneo or naplithalene, In liquid solution has been istudied by the method of triplet-triplet transfer to europium t:rie-thenoyltriflui)roacotonate-1, 10-phonanthroline. The nonradiative energy fractia which degrades on the triple level of the organic donor moleCUle vas determined by two procedures. Following the first procedure, the lusinesce-nee Intensity of the evacuated binary solution of the organic donor molecule and chelate was compared to that of an Identical but nonevacuated solution. The differenco between the lumin- escence intensity of evoicuated and -nonevacuated solutionst lev -Anoilevo was equated to the intensity Il.t due to the energy transfer an tritlet levels under operating conditions excludifig the donor to chalets energy tranater on siniiat levels and the Card 112 UDC: 535.373o2 NRs AP7004147 reabsorption of the donor fluorescence by the chaletie. The experimental values of (lev - Inonev) X I--' which are the measure of the fractlon of donor molecules in monev, the triplet state, were found nearly equal to the values of CDCD(1 - qfj)qACzA1 where c and C are wolar absorption coefficients and concentrations of donor and chelate and qfj is the quantum yield of fluorescence of the donor, In the second procedurep the luKLnesconce Intensity of the evacuated binary solutions was compared to that bf the solution of the chalate alone on excitation with a 313 nm source. Under given conditions, the ratio (Iov - Inonev)(Ich - InO460-1 was equated with the fraction of donor molocules, in the triplet state q This value was found nearly ' N'txperiments that the energy equal to 1 - qfl. The conclusion was drawn from bot degradation in the aromatic molecules studied in liquid solution proceeds exclusively -A& the triplet state. Thanks are expressed to A. N. Terenta. Orig. art.' has., 1 table and 1 figwra. tilt) SUB CODE: 07, 20/ SUBM DM: -16Jun66/ OILIG RUs 004/ OTH MYs 004/ GRE)ITOR, M.A., inzhk; TMOLLTW, VtM. . inzh. J. Automatic computer of the amocat of wood In cable netere. Wkh- I avton prols. 14 no.6:46-" Je 160. (MI" 13:?) illectrosic digital computer) .';/147/61/000j'004/011/021 .2 o o E025/E120 AUTHORS: Yermolayev~ V.M:, and Talantov, A.V4 TITLE: Investigation of the effect of pressure on the speed of propagation of flames in the turbUlerat flow of a homogeneous mixture PERIODICAL: Izvestiya vysshikh uchebnykh zavedenJ.y, Xviatsionnaya tekhnika, no.4, 1961. 82-93 TEXT: The investigation of the dependence of the fundamental characteristics of burning on pressure are of grent practical value because this problem in connected with the known worsening of the efficiency of the combustion chambers at great heights, The published investigations into the effect of pressure on burning were carried out for axially symmetrical flown In a small range of variation of the fundamental parameters. In most cases the speed of flow and composition of the mixture were not varied. In the present investigation the i9peed of propagation of the flame has been varied from 20 to 80 m/sec, the composition of the mixture has been varied from 1 to 1.5. CardCY4) Investigation of ihe effect of ... S/147/61/000/004/011/021 E025/E120 the pressure from 0.35 to 1.4 kg/cm2 and the temperature was equal to 423 OK. To obtain the best approximation to the conditions of burning in an engine the experiment was carried out on a flow bounded by walls in a chamber of constant section with forced turbulence of the flow. The combustion chamber was a tube of square section 50 X 50 mm of length 1700 mm, cooled externally by water. A very detailed schematic diagram of the experimental arrangements is given. The values of speed of propagation of the flame in the turbulent flow for various speeds of the flow, mixtures and pressures were obtained, and from these were constructed graphs giving the re.lation between the speed of propagation of the flame and the pressure for various mixtures and flow speeds. A comparison of the nature of the relation 'between the speed of propagation of the flame and the pressure for various mixtures and flow speeds; was made by the use of diimensionless*flame propagation velocities and pressure rati,DS. The effects due to.longthening and shortening the flame are discussed. The following conclusions are arrived at: Card 2/ 4 Investigation of the effect of 5/147/61/000/004/011/021 E025/E120 1) The values and nature of the speed of propagation of a flame are approximately the same in a turbulent flow bounded by walls and in open turbulent flow. 2) The speed of propagation of the flame is proportional to the 0.8-th power of the pulsation velocity, taking account of the dependence of the latter on the pressure. 3) Damping of the turbulence is responsible for varying estimates of the effect of the pressure on the speed of the flame for different speeds of flow and mixtures. Hence it is necessary to calculate the speed of propagation of the flame taking account of the normal and pulsation velocities and their dependence on pressure and damping.- 4) The speed of propagation of the flame in a closed turbulent flow is in good agreement with theory when the effect of damping of the turbulence is eliminated. 5) The decrease in the speed of propagation of tho flame with fall of pressure is one of the causes of decreased efficiency of the processes in the combustion chambors of primary ginginon in high altitude conditions, There are 10 figures, Card 3/4 Investigation of the effect of ... S/147/61/ooo/oo4/oll/021 E025/E120 ASSOCIATIONI Xazanskiy aviatsionnyy instituti KaZadra teorii aviadvigateley (Kazan' Aviation Institute, Department of Theory of Aircraft Engines) SUBMITTEDt April 31 1961 Card 4/4 YERMDLAM YIM.L TALANTOV, A.V. InvestIgating the effect of pressure on the bingth of the con- butation zone in a closed turbulent flow of a uniform mixture. I2-v.vya.ueheb.zav.; av.tekh. 5 no.3tl43-156 162. (MIn 15:9) (Combustion) 41UXOV,, G.1b.,p I=h.; MMOLAMWIJ.A, Coaferonce an inpro"ment of offloiiency in tb* pleettio oquijpmat industry in tho lJralm# Vest# sloktr~wvmo 34 no.2:76-77 7 163o (KM 16:2) (Blectric equiFmont industry-Congresses) 4W)~AMYO.:. V..M,.; TALANTOV, A. V. Rate of flaw propagation in an open and lijkit*d fLow of bcsogens-ouis mixtare, Izv.vys,,uchsb.znv,jav.tOkh. 7 no.2s134-141 164, (lam 171()) Y, I"Fd,X-J4 4~, PIIASL 'I Trtntauro In.1-ind RtbUlorraphlc !1orq-t-t BCOK 140.1 '4c.: TU',~~'71 Nol"? Authors;- ErVIGLAFIr. y. I., and y;o,,vjz-rj,, is.. 11. F'all Titlot F(K--4Y,IJI (F "MIUCTURAil Transliterated Title: Manter strukturnof.-o burentia Publishing Data Originating Agency: None Publishing House: State Scientific-Technical Publishing Hous.? of Cil and Viner-I Fuel Literature. Leninarad BrZ'Lnch. (Gostoptekhizz~at) Date: 1952 No. pp.: 318 No. copies: 7,r)00 Editorial Staff' Editor: Gridin, V. K. T-~ch. Ed.: 'kne Ed.-in-Chief: PerminQv, S. V. Appraisor: 'Icrie Text Data Coverage: The book cr..ntains elementary data on ge6logic.-il structures, conc3tructlr~n of derricks, arrangement of equiTwient, types and quality of drilllii,~, tools, and characteristics of varicus materials (metals, lubricants, transmission belts and transmissirn cables, cement, luvber, etc.) uswcd in well. drilling. The practical methods of drilling wells for !-eo1(-,fjcI-1--l surveys (mapping), structural, and prospecting dr-iLlIflir are Plso, method3 of computinp simple work probleirs unj rat'r!"; of tiril'iln,--- through various strata. Purpose: A textbook for well drilling foremen and personnel eng,11,.ea in survey-I-Ir and prospectinf-. Fac.iliti~s: licne No. Russian References: 11 Available: Library of Congress TWMOIAYEV, V.M.; KARAMZIN. A.Y.; KOVAIRTA, AL.A., inzhener, vedushchly POLOSM, A.S., tekhnichealriy redaktor. t3truct-mral boring; practical manual for workmen] Striaturam burents-, prakticheakoe posobie dlis rabochikh. Mosicra, ks. nauchno--tekbu. Izd-vo neftianoi i gorno-toolivnol lit-ry, 1954. 138 P. (MM 8:1) (Boring) .............. ....... .... "INO V"IIL#yevlc&,* .qvich; r ummirem.y., redaktor; 1motilmovWr., r; I.M...-tekbilabseldy redaktor [Drilling structural and mploratorywells3 Burents str*turno- poiskarykh ekwashin. Leningrad, Goe.asuchno-tekkno lvd-vo neftia- not L Igorno-toplLynoi lit-ry, 1955. 36) p. (KLRA 9:3) (Boring machinery) (Oil well drilling) I v .414- U41~1-1A MARAVIZIN, Aleksandr Vasillyevich; MU40 - - &A-h .LdIcjamiL, SHEVTSOVA, . .. ved,. red. (Boring structural prospecting holes] Burenie strukturno- poisk-OV,Ykh skvazhin. Izd.2.p isp. i dop. Leningrad Ned- ra,, 1964. 390 P. (MIRA 17;9) LYtJBCH=Op A.?.; )Z-FM-OJAW-t-V.Ue- Effoot of cerium on the self-diffusicin of iron, Fix. note i astiMoved. 3.4 no.lsl57-160 n 162. (111M 15;7) (IroD-4%tallography) (Cerium) SOYA IN., A.I., insh.j IZMGLA32VO T.H., insh. Technology of-blant furnace pa purifioation andAle design of scrubbers. Stall 23 no.2t176-1778 F 163. (MIU 16:2) 1. MagnitogorsIdy metallurgichesidy kambinat. 01ases-Por,4-fication) (Scrubber (Chmical technoloa)) V jERMOLRYEV, V'P- MOLf r1j, V. P. . and 114. P. MY(MUT. ----- ------ -- Pamiatka nomirovshchiku-strolteliu, 'Poskvii 4 M15 j 15h8o 70 )~i# s ro At head of title: Nauchno-issledovatellskii aerodronnyi Institut VVS Vs. Title tr.: Instructions of wq)erts 1n setting constructlon work standardso TL?25.2A SO: Aeronautical Sciences and Aviation in the Soviet Union, Library of Congress, 1955. - -XC - -.Te- V F RPTA KE U,-A c 9 1 13 2 ~Urgory Fab 59 868- (316) EXPERIMENTAL PARENTERAL PROTEIN NUTRITION IN SUPGIC- AL PATIMNTS (Russian text) - Ermotaev V. P. - KHIRURW.4 Igs-f, 9 (97-102) Graphs 3 Tables 2 Data concerning metabolism in Wlents following operations on the gaMro4nt~NtjnaI tract and In burned patients are presented. Pronounccd neilat1ve nitrogen balatice (7-12 g.) was revealed In the postoperative period. In burned patients aW in cu,ses with postoperative complications nitrogen balance equittled from 30 to 35 it. In 34 hr. There was it lose of weight and reduced content of protein in the plazins. lPro- loin was administered parenterally In 20 postoporalive cases and 1h 5 ease* with burns, and 55 Lv. injections wore carried out. In 12 cases untoward Mde- reactions were observed, which were severe In 5. Aminopeptide - a new prepaimUout of heteragenic protein. fermentative hydrolynate of whole animal blood - was investig- ated thoroughly. It was tested clinically in 174 patients (85 postoperative 4u-4.89 burn cases). Aminop*pttde was administered I.v., I.m. and s.c. in a doze 14 800- 1,500 ml. (III to 20 injections to each patient); 2 patients had fever and chilLs. In order to determine the efficacy of parenteral ad ministration of &minopeptide in 28 postoperative and 12 burn cases, determination was made of nitrogen talance, protein content of blood plasma, excretion of urea and amino rdtrog*n in the urine. The results of these experiments show that sminolpeptid* has no snaphylaclogenic Foropertles ond to rat toxic. Nitrogen, administored in this form, to Sleadily assim- lated by thit Organism, irrespective of the method of Its introduction. It in poss- ible to maintain nitrogen equilibrium and a positive balance If an adequate dose of aminopeptide to given. Clinical observations and Eaborstory examinations 311ow of the conclusion that aminopeptidt to an effective pr"ration In Parente-rol protein nutrition In surgical patients and its recommendation for wide clinical use to warranted 'Af YMXOIAYNT, T.R., kandLUt meditsinsikih nauk XoWleatlon of prot*Ln a*taboUsm; in mono surgical tients with parenteral infusion [with suw&&V in Uglish, p. 157rirest,ktdr, 77 w.6:12-17 Je 156. (XLRA 9:8) 1. Is gospitallnor khtrurgichemkoy klialki (nach. Prof. 1.S. 11olsonikov. nauchn. rukoyod, - prof o S.SAirgoICIT) lroyenno-seditain- skoy ordena Lenina akadexii Lm. S.R.Kirovs. IsaWrad, Botkinekaya ul., d.19, kv. 126. (IMUSION, FAMONUAL, protein hydrolyeate in protein depletion in surg. (Ram)) (noings, hydrolyeates, parentorvil infusion In protoin depletion in surg. (Rus)) (SuRany. MUTITI. Complicatlons, protein depletion, tho.v protein )V&olysate parenteral infusion (fts)) YKNOLAIRV, T.R., kancl.med.muk (Ioningradt 9, Botkinstays ulal. d*19, L-v#126) WANNION basis and embolism of the pu2nomary arter7 folloving luxNg surgery [with sommory in Saglish]. Teat.ihlr. 79 no.9t55-62 8 1579 (MIRA 10:11) 1. Is goopitallney k1birmVichookoy klWki (rAcho - prof.' I*$* Calsonikov) Vaemao Itainskay ardons Ionim skademil In. S.N. Kirovs. (ANURM, FulAvlaff, dive I 4albollon & thrombosis after Ina surc.) (Pommnom, cowl. so'bollso & throsibools of pulime artery) YMNOIAIW. V.I.. icand.wed.neuk arenteral orotain nutrition for surgical patients Evith sw=ry in %glishl'. Khtrurgilm 33 no.9:97-102 5 '57o (MIRA 11:10 1. Is gospitalluoy khirurgichookey klinilki (nach. - prof. 1.S. Ulsenlkow) Toyenno-maditainskoy ordens Imenins jiksdftil imeni S.N.Alrova. (PROTIMp there use pore burns & postope core, perenteral admin.) (BUM. there proteins, parenterel admin.) (POSTUMATIVX CARZ parenterel admin* of proteins) (IXPMIOMB, PARIWXRAL proteins, in burns & postope cars) TWHOLAYN, V.I.. kandeved.nauk; SRATALIDVA, N.A.0 kand.med.nauk Chronic atelectasis of the middl lobe and lisCils, of the lunC of varied etioloj7 [with sumaa:7 In AnglIsh]. Tsmtokhir. 82 no.1:86-93 Ja 159. (MIRA 12:2) 1. rs gospitallacy kh1rurgicheskoy kliniki (nach. -.prof. 1.S. Ealse- nihm) Toyanw-seUtminskey ordena Lenins akadosit Ineul SoNs Kirovae Adrom awtora: Leningrad, 1-9, BotkinsWa ule, 4-23, gosPitallwa kh1rurcleheskeya klinika. 02SUMAS18v etlol. & pathogen. chrente. of al"le lobe & HWIs (1hu)) YEMOIAIEVp V.R.v Wor meditainskoy oluzlibyi, kwAmed#muk . " HoLung Of VOWAN containing a foreign body foUxdj* tota.1,9wy irraflation of snimalne VoenspookLesbure wel#sW Ap 060 (M& :L4:1) (I(Oum) (RADIATION-PUM Tol, CT --.nMLATBvs- V.R.p kandomed,nauk Arulsion of the nain bronebw ft blmt tmm& of tbo thorax, adrall" 37 so.103-17 Ja I&L. (Him -use) Is lv.,Vsp#al'wy kbinrgioboolcoy kliniki ("~v, - ;rd, IJ. Koleslik*) %y o-meditsirAkay ordma Umiza ekdadi immi SAO Kirevazi I(C=T-4V= AND WORM) (NO=-4WM AND MURIES) MUMMK(ArA, A. T., kand. mod. naukj TIUMIAM, V. R , kand. mad. nauk Aeutw gastric obstruction caused by complete Waxattan of the left half of the diaphrup with transposition ~f the stomach, ap3min and left lobe of the liver Into the tho"i-Ac cavity. Mdrstrglia 37 no.7:87--90 J'l 162. WMA 15:4) 1. Is k3in4ki gospitallney kidrurgil No. I (useb. P"fe I* SO Solemnikov) Voyenno-weditsinakay ordens Lenina &Wemil - Imeni S. M. 11raft, (DIAPMUW.--DISZASZS) (ROWN) (UM) (SPIM) YMOTAYW, T.R. (Uningrad.. K-9, ul. Smirnova, d. 10-es, k7.22) Burg-Ical treatment of late Bronchossophageal fistulas. Grudn. khir- 4 no.59132-1.13 S-0162 (MIRA 170) 1. Iz kliniki goopitallnoy khirurgil No.1 (naalmlInIk - prof. I.S. KC esdkov) Voyenno-medituinskoy ordena Lenin& akedemi-'A. imeni. Kirova. ul, Sul~smd.10-ap;kwo nRXDIAl13Tq Y.R. (L*nlftWo :EntrsPlvmsl b"UTW4PO fOlIAW189 r"I"l Pulxmwry mwgin7- t,'.rod.khir. -ho.446-& JI-4 162. (MM 15: 10) :1. IS Irl4n4lr4 gogq)JW'wy khirunil go. 1, (wwh. - prof. I.3. Jolemnikov)V*nno 4wlltslmkoy ordena Unins aWadi.bwni S.M. Kira". INMAMW V.R. kand.med.nwk (Uningrado X-9v UIq Salmoval d.10AO late results or the stirgical treatment of bronabiectasis. Mn. Irbi vOqnsUo%U N 962, (MM 16 Q) Io, Ufafta gospitallnoy kbIrnr#i (macho, - launat Immimakoy pradi pror, LS. Koloodkovi voyamm-esditaimAroy Ordens, ladna akRdoLU imeni Box. Kirov 0 (~CHIMASIS) MMOIAU.V,q V.A. (Leningrad Y,,-3, ul. Sairnova, d. lQa,, kv.22) Segmental and combined reaect-ons of the lungs in bronchiectuls. Grud.khir. 4 no.6.*59-66 14-D'62. (141itA 16:10)) 1. 1z klirdki gospitallnoy kNItutgii lio,l(nac'hallnik -prof. I.S.Koleard3cov) Voyenno-meditainakoy ordena Unina akademii iwnl S.14.Kirova. (BRONCIII-DISMES) ( LUMS.-DUMBRY) YERMOLAYEV, V.R., kand. mod. nauk Priwa7 failure of the bronchial stump and the pulmonary woUM following radical operationip on the lungs, XhIrurgiia 38'6,1204-19 D 062. (MIRA 17:6) 1. Iz gospitallnoy khirurgichookoy kliniki No.1 (nachallnik - prof, LS, Kolesnikov) Voyenno-seditainskoy ordena Imina akadadi imeni S.M. Kirova, KOLESNIKOV Jq I.S.,, prof.; FUTOV, N-V., prof.1 YEPMULLM., V.R., kand.med. nauk; SOKOLOV, kand.med.nsuk Acute blood circulation disorders in the residuia lum part following patrial g*sectionse Ve.9t,khir.90 no.2028-135 F163. (MIRA 16:7) 1. 1z gospitallnoy khirurgicheekoy kliniki (n*cWd'n:Lk prof. I.S.Kolesnikov) Voyanac-moditsibskoy ordena leaLra Pkademil. imaid S.M.Kirovas Adres avtorovz loeningrad3 Botkinekaya u1.,, d.23, Gospitallnaya khtrurgichealmA k2inika Yoyenno-medietisk- skoy ordena Lanina akademii imn:L Kirova. (LUM4-SURGERT-) (BLOOD-GIRCUIATION., DIBORDFM CIF) JERMIAM kand.med.nauk (Leningrad, K-9,, al. Smirnova, d.10-a, lz:~Ik-v.2.i) Resection of the lungs in bilateral bronchiectmis. Vest,, khir. 90 no.3:11-19 W163. (KMA 16:10) I* Is 1-y gospitallnoy khirurgichookoy k"nik' (naebalinik prof* IeSoNdlesnikov) Voyenno-maditainskoy ordena lanina akedemii imeni Kirova. (LUW6.SUHGFM) (BENCHIETABIS) rI.RMC:-k'rFIIT, 'I.R., dotsent (Leningrad, ul. SmIrnova, Some chara3teris t 'Ice of tl-.-e terhm'yue of -lunit, bronchlertazi.s. Vest. kh:Lr. 1~1 no.9s2rj-2'1 j16,1. 1. Yz gn~tpital lacy kW-urglcheakoy klintki. (rrwh:t~ jr~'-Ic I.S'. K--IP-ozi'Ikcv) Voyenno-meditalrio?v;y rd(tn, iment S.M. Kir:)-m. KOLISNIKOV, I.S.; ORDZHMIKXMO G.K,; SMlWHMKIY, 14.1t.; XW V.R. UKU-BrVSKIY, F.I. Adenoma of the bronchij, their camplications and operative treatment. Orud. khir. 5 noe6llM,-106 N-DO63 (MIMA 1712) le Is kliniki goopital9noy kbiTurg:li (nachaltnik - prof. 1.S Xclesmikor) Voyanno-meditainskoy ordena Imina akademii imeni S.M*Kirova. Adres avtorovs LeningradiN-9. BDtkinskaym ul., d.23. Klinika gospitallnoy khirurgii Voyenno-meditsinskoy ordena Lenin& akademii imeni S.M. Kirow #

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