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SCIENTIFIC ABSTRACT YEROFEYEV, B.N. - YEROFEYEV, B.V.

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CIA-RDP86-00513R001962820015-7
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December 31, 1967
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SCIENTIFIC ABSTRACT
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UTZXHTIN, k.G.j VOLIFSONj F.I.1 GEWHO A.D*j DUBRWSIaY, V,N.; YAHM:W, KONSTAHTINOV,, f4M.j XiTMKOVy M.P.; BOIUWV# G.A.; STPAMIOV, N.R.; TATARINOV# P.M.j TONSON, I.N.1 SHADWNO T.H.; SHATALOYS Yn.T.; SHIPULINt F.K. Oleg Dmitrievich L4Vitskiij obituary. Geol. md. nestorozh. no.2: 3-6 1*4p 161. . (MIRA Ut 5) (Levitakii, Mog Dmitrieviclap 1909-1961) xjmrmM7, B.N* (Chita, lhabaroveltaym ul., d.2-A, kv.24) Towagraphic examination In the diagnosis of catemWelitim, Test,,rent. I red. 34 to.4:37-39 il-ft 959. (MM 12:12) 1. Is Imfedry radiologli I rentgenologli (sav. - prof. P.D. Talltsev [deceased] I Imfedry obabehey I goopital lwiy ktilrurgil sanitarno-gigi- yetichentogo, fa)mllteta (nauchiWy rukovoditell .. prof. P.1. Sapozhkov) I Moskovsko o ordena Imenlum meditaluskogo Instituta iment I.M. Sechenora. 10=13MMITIS radiography) rZUWXM,,, B. N. Orgmdsatlon of the teac" of rowntgenoloff~ and rwUology. 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Saps, OMWIL at no mmdm bm bm www"A mid himiwor a a* apL OW 4" CLAW"Aft two O"T 00 ~04& *1 so*@ Ow low, r I omasw* 4ww . a. I awims abbopt =4 war". -00 not 4*4 " 0t .00 . "WON ' notind ho Its bw omot 0=11mmin limit 1w wr- moo 400 X. Mw A. * am, see WA4 AAM 41m ly. goo at dw "10,01 XFO #u 0*0 Poo 41300 Also goo not goo so* 0 00 010 0 0 0 E 00, . 0 0 L YEROFZWO B. V. *On the Kinetic and Catalytic Reduction of Carbon Monoxide to a Carbohydrate by the use of Hydrogen wer a Cobalt-Thorium Catalyst.* Acta, Pbqs Vol. ITIT No. 1. 1940,9 Chm inst. White Russian Acad. of Sci. Minsk. TBMIM, B.V. USSR "Some Problem of Topokinetice-s zhuf. Yas. Ahim., 'Fol. 14, No. 9-10-, 19W. 0c t 22 1952 I XT T 'V T V T T T ~f T V T V V! V T T If' TI w F i I ~ L fir 8.0 lop ~*qq 00 00 00 00 00 0 0o 00 0o 00 00 IF u if UP 0 la a a a a It a 0 o 0000-8006000000060006 00000100019000000*000o'legoo TV a 17 111 IF Ill 9 OF 111: 11 11 IF 1614 4'. 'k 06 00 !-Oo :"Oe -00 00 *0 go ld i;7*o 100 so Igo an4 000000000000 00 '09 00 0 0 . 0: 0 0 ; 0 0 0 0 0 0 (9 ~40, "Topoclaemical faotorv In the formation of the lWdridto of aickail..* Balandin, A. A., and Ergtagj. B. V. (p, SO: igumal-of Generia ChemiLt_a (Zhurnal Obahchei, Xhimil) 3.94~t Vol 12, No 3~-4. A I -AAJ *0 A so so :Jig; IIII of 41'z 00 so so 00 ISO 00 AM F a- I . 1, V.. of 91.. fIolRI 14 jApit 04 a At son on I a 04, 0 0.0 0 in 0 0 0 0 4, 0 0 0 0 0 0 00 0-0 0 0.4 *is 00 00040004000 ALV- -ef - i A mmwm~~~ T-00 VID doe 9#0 4001 me Mo lb 00 so Al ego so d so j w 004 **a 00 es -17 -;VU-t ,L -4-1~ fit lift itip4ro T 041 0460 - md U A S. 1114 6 NOW W A Itimill 0 lu Mal, mille owl hm" ww NOW. am owl, $0108m was env is coo $Dome is M~W M .... ... 7 -, 7 T 7 1 -c 7, 7. - --- - - - ig. - I, - - N R ~. I. - , Y a Aj v It L-A. S. 0 woo IN woo rw-w od. makwitht om4A S W If Or S 00 . . - . , A. H, 16. of ."Cat is :93 ImpP a It 14 All00 9 0 0:0 0 is 111000 0 0 410 0 0 r!060 is0 6 W.O., Is .00 vi"lp';14 oo~ 't, 004 6 0 0 0 0 a a 0 *0 io0 6 0 0 0 0 0 woo got #00 f C410 lose it dkw si". -40 #40' too Olga at 00 it U $I* for 60A (ompelfts"41 see Ono 64 Iwo U. I dA foe !*t 00 16 M. see In. set- ''Dow. fbi W-1 see :3. 8 tL OVA" WWA& uls"OW Wr m"Agnt Z-7 17 ZZ O*A Ogg *0 00: logo 004 000 00.0 001, wee. 11"000" ....... "It ov 4#A .0 .0 1 W,,p a so a a, ; Ipt ;t1i 0 *0000004000000*40000 0 0 .00 .06 00 use see so sh"I 4UAAW Vol 0 2 Us I s4 - All L 11aON 0 v 9 A 0 T n 3 7 0 0 4 0 0 0 0 6;0~ 41 0 ': 1 aj 0 1,10 1 . 0 0 EROMN't B. V. 25383. ZBM, B..VA 0 Reaktaij E. 1. Orlava. (Reaktsiy* sintoMPOWh qrjmjodorodmr iz okisl. uglarorla i voloroda). Usmkhi khimii, 1948s -Vyp. 3. fl. $70-71, - MUNr: 3,, 371 SO: latopial Zhurnal Statay, No. 30, V400ow, 1948 Z. 4 , , I .f I BelliCavivit, P, I., Volkova, A. A., ,vid Yeroforw. B.- V., "Tito kinotims of tho taoroal disintegratlu~] of Of silvqr und it>iiuw o~u0i-.te", In-Is-Ii-,% Alavi. nauk BSSR, 1,448, 1110. 6, ). 145-59. 1 I SO: U-3261, 10 April 53, CL3tcj. 13 'Zhurzv~l I ny~h Sv-tte.~r, No. 11, lqi;,~). ' - YST V. L3. YEROFEYEV, B. V. "Successes in investigations of cherical I:inetics and catillysis durin.0 30 yearo of Soviet power", In the collection: Vaterl.aly noytabrla7krT Akad. nauk BSSR, 1947, Minsk, 1949, p. 107-15. SO: U-4393, 19 kup-ust 53, (Letopis lZhurnal Inykb Statryl, No. 22, 1949). Y!~IIOPEYEV, norin vanil'yevicIl "Successes in -the Field of Topokinetics," Izvestiy2 Akadi~nii '51pak Belorusalrov 2SR, 1950, No'., It SO: Bollshaya Sovetskaya Entsiklopedin,, 2nd edition, Vol XV, Moscow, 1949 ex. 1 0 I I,---II.--- .. . - A i. - - ~ - . -- LA j I EROFEEV9 B. V. Kinetics of tranel'OrTAtions of polymorphous modifications of umonium nitrate. I. General character of the kinetics of transformation of tbs modification IV., into the modification HIs B. Vs trofeev and No Is Mitshavicho Page 1235, Academy of Sci. Dolor. SSR Insto of Chadetry Minsk March 60 1950. SOt Journal of Rjoical Chendstryp Vol. 74,9 Noo, lOg OctoWr 1950 - -, '. /7-, / Z. ~ r-, . - ~- "I - (- A fj k- - ULIMICH,P.I.; VOIZOVA,A*A.; YXRQMM.B*V*-, LAZARIVON.Ya. Nffect of concentration on the velocity of thermal decompolitiom of silver oxalate In a vehicle. 1xv. AN BM no.lt163-175 J&-F 151. (Thermochemistry) (Silver oxalate) (NLRA 8:10) YEROFEYEV, B. V. FA 192T43 or lbactlow Taklm Pilkle; Valor 1:1-,! Osti of ~Oud ~be AWI Fvziilir Fig IbIS) 10 Owki ---71- 711- now, elk V j - A int dr tiew WPQK ,I 44,Afivm, # ttio I'slo, f P TT. T j Ammonium Nitrate "~-7-- T- Kinetics of transformitions of polymorphous modifications of amcnium nitrate. Part 2. Effect of conditions of preliminary treatment on the rate of transformations of N,1003 (,V)- NV03 ('I,)' zt=. fiz. khim. 16 No. 6, 1952. Month List of Russian Accepsionso Library of Congress Novembwl 1952. Unclassified. Am 52 okpi title YMPEM, B. V. USSR/Chemistry - POIMB�Saftt* Potassime - sop 52 "Kinetics of Thermal, Decomposition of potasglug permanganatq," B. V, Terofeyev and 1. 1. Smirnovs, Inst of Chen, Aucad Set Belorussian $51, Kinsk Zbur Piz Rhin, Vol 126, No. 9. pp 1233-1243 Studied the kineticis of the thgrmal docgmpa of crashed and uncrashed recrystallized K"4 in a temp range of 211.5 - 227.6 C. Discovered that the decompa of KKn04 has a typical autocatal:rtic character mad that practically the entire rarige of the reaction can be,quwxtitatively described by the Kolmogorov-Yerofpyev sq. The values of fln*, in most cases, were close to four or five, thus indicating single-stage and double-stage processes in the formation of the starting centers of the reaction, which arise at sepa:rate points on the surface of the crystals, The crushing of the M04 crystals did act change the general character of the kimetics of the reaction and left the valuA t3f On" without substantial change. This led the authors to dis- count the theory of A. G. ?rout and 7. 0. Tompkins (Trans. lared Soo, Vol 40, 488, 1944). 263 T 15 USEM/Chemistr7 - Ammmium Nitrate Nov 52 "Kinetics of Conversions of Pol:ymorphous Modifica- tiots of Ammonium Nitrate: 111. Kinetics of the CQr=vt',rGi= Of RH41'03(II1)__*NH00 (IV) f B* V. Tero- feyev and H. 1. Hitakevich, Inst Rem,'Acad Sci Bel- OrAws SSR, Minsk -Zhur Fiz Miin' Vol 26, No 11, pp 1631-1641 M;e--authors eta-te 'Umt tale ratee'of '66aversi6a of-- NH003 modif icatioas III --w IV, similar to the rate edf =,.;;Iv -rsion at i! do" expt- Mie :mto of.--conver-is-io-i-ef- _4*tUjon, of the C11 242TU M-0-iv in expts Couducted unddr ideutica~ condl- time (of. temp and time elapsed after the ccuver- _- -slvn of IV --oo- In) is - the same-j* vilhiii -thei- na~ - at wayta error. Protracted keeping of,111,at the eca- Ion temp of IV --*li (35-0-36-00) iewls to a do- cx*ase in the rate of the subsequent- ccaversica Pf M --*IV. The preliminary initial heating of IU:at 55,-~O also decreases the rate of the conversim- MM--v- IV. The kinetics of the couveralon of -the: UPWicationsIM4M.I., (m) --*xH4x0-, (IV) can ,be e .X- pressed by the Ainetic eq 11 exp (-- MA), Unvughout.-the vhole x~mzge of th; expts conducted :v4-,tb tested yr s. Cirushing the comMd leaas to.a. decrease in the rate of conversirm of NH41qo (III)--* woA(M.,;t- thi aithbre &M: tbi-t Ahe~,-ti~ip a;~W~;9;cve of the rate cc MR NO g xx~.4!f Is.: SOJ"t to ~Ahe ArA~us e tenp coeff of the rate of conversion z III --OIV is neg. 'YeRor- ~ t-,, 6, Ej / BU'MICH. F.I.: mmmf Bayo Nockwalco of the decompealtim of *me solid walmstawas IF be", 1sw.Jm BW.so.I,.65-7* To-& 153. (NM q: I) (Therwboulstry) 131, 3. T., and NNSIMUCH, 1. 1. 00463cople Determination of Phenol sad Ortho.-Crooolil In Peat Petroleum.* lay. AN Beloran. SSRO No pp 203-11) 0 1953 A tenvi=etric method (Yerofeyevj B.T.9 udh- agLe. ZAA,A-UQhU- In-tat 1943, Wo 7,, 65) was used for the'dotermination of a composition of 'the phenol fraction In peat petrolatui (1$0-225 degrees). The obanol content was 14.3 11.4%; the ortho-cresol content was 6.2 o*5%-. Naphthalene was not detected. (RZMim, No 200 1954) YMOFEYEV~ Boris Vusillyevivh "Progressive Poisoning of Hydrogen Sorption in the Pro(,4:rs of Formation of Nickel Hydrides," Dolady Akademii Nauk #494, iTo. 6, voi xvu., I'M aql- JO T 40 SZT!Z;)UT3( ata -9;oqTxbv*p- T-mc b.,'UOT4vnb8-~ "TWOU49- UT .'Pau ~sd4 6t~AtnvoozTm VR14 -so, 41itib, -xo NUO I-VOW =T ~Q-gaft,UOTSJQ~~Oz_ nJOA01- *q; 30 BOT40UTA QtM ell UoT,4voTJ:TPCM:O4-~,co1[,U SO in voTiMUTPOW Gq,4. j0 aorojaAuoo gnoqdxouLqod aq,4. jo ooTf4mTx ou. 13T-M-dd IT 09 'LF, TOA laqqX zTd mqZ I tt1T-G8WRTQEL 'TOS PUDY 'm8q? JO 49U], ~,Fr*T-AOXfq~Tj( wTs,i4iuO0 'Al 'Toa JO 9uOTgJQAaO3 vq!~ jo sa-r4a ,UTI. -TVaK ortoqdzomA BOAT80"Eftl &,pTwmW/jgM., i RWOMMON ... ..... ... ............. ... tu flown I'm~'Imill 1 1 ( I py., T~ I !I F 11(u:11; Iti 1.1111 tj 111 -,1,. 11 1111;111 ]IJ11 I 1111i I F 11~1 1111 1,- 111 qu 11, 11 1 1, 11 ,.11 ." I F1 I I I I - I USCIVOrganic Chemistry - Naturally Occurring Substances and Their Synthetic Analogs.. AbE,t Journal: Referat. Zhur - Kbimlyaj, No 1t 195T, 1034 Author: Yero, feyevj, B. V., Kitskevichp No I., and Soroko., T. 1. Imstitution: Academy of Sciences Belorussian SSR Tltlez Conjugated Decarboxylation During the Autoxidatitm of Debydroabietla Acid Original Periodicals Izv.,AN BSSR., 1955t No 2, 131-135 (publisbed In ltuselan)j Vestsi AN BSSR., 1955t No 2, 124-128 (published in BelommislAn) Abstractt It has been established that the autoxidation of dehydroebietic acid (I) is accompanied by decarboxylation. Heating colophony (3 hours at 3400) yields the "pyroacid.," which is sulfonatedj. acid hydrolysis of the sulfodebydroabietic acid yields It mp 172-17.J.50 (frcm alcohol) Ox-71D t 63.770. Autoxidation of I is carried out in naphthalene at U5 aDi 950 in the presence of Co-acetate (II) (one percent.by veight based on 1). The apparatus deqcribed previously (Referat Zhur - Khimiya, Card 1/2 U38R/Orgenic Chemistry - Naturally Occurring Substances and Their Synthetic A- E-1 nalogs. Abst Journal: 1955, 51500) -was used in studying the kinetics of the autoxidation. The quantity of O~2 absorbed (ard the rate of attox1dation) were de- ternined by measuring the increase in weight of tubes packed with askaxit through which the gas from the reactimL vessel is paused; the gas is displaced by a stream of 02. With tin initial flow rate of 0.7 ml_Vmin/gm I the autoxidation of I practically stops when 0.21 moles 02/mole I have been absorbed. Upon &ii3placemant of the gas fraz the reaction vaccal with a atream of 02 the rtwtion rate increa- ses tD 0.56 mi o2/min/gm. When an additional 90 al of gaLi have been absorbed the reaction rate drops off sharply. Pjwlysis of the gas e- volved during the reaction shoved the pweeence of 35-4% C02. The ra- tio COp:02 depends on the quantity of 11 used =d varios little du- ring a particular experiment. The decarboxylAtion of I toes not pro- ceed in an atmosphere of N2. The authors are of the opinion that 4 processes are involved'in the autoxidation and decarboxylation of I: (1) formation of the hydroperoxide radical from the I radical by C(9): (2) formation of the I radical by the carboV1 group (111); (3) de- carboxylation of III; and (4) splitting-off of one 11-atom from C(9) of the new molecule of I by interaction with III. Card 2/2 TERAnM, B.,V.; MBOVIK, V.I. Activation energy In the process of thermal Inactivation of Metall1sed catalmse extracted from the liver of exam, Testol AN 156* (KUU 10.0 1) (Catalase) (Liver extract) (Activity coefficients) vuwrj~vvioal choolstry.UvOics, Con'bustiou, Stplosims) Topo- dwelstryp Catalysis. Abs Jour: ileferat. Murml Mdai7a., No 2,, 1958j, 38%. AuWw z 3 -T - liEgoomm.. L.T. YAndzelem. lut : -le-adag' of Sciences or lddtO MESIM OR- Titu : MjWtlcM of,polymorghous emVersion Of ~k-ves*rciu into (I -Ifisorcla. ftlg AM Testai M I=. Bar, M.-tekba. z.,v Isy. M 3ML- Sero fiz.- tdft. ROP 19*1 No 40 99-110. Abstraft: Me kUetlcs or the mwersian of ths.lov taqwvatire modirica- Mon cdl reso 'in into its high temperature madIflcatim vas stu- dled M; 72 to IW . It is shown Us* the wbudied reaction fol- lam Via topokinatic eqmMah 1/(l - a) - 1 - kA. The deter- simied activation enerU is 33,900 cal per sole. card 1/1 -14- WOO= - J1181" NITS-ZVI=, N. 1. Selalklonship between the rate and depth of conversion In topo- abooLeal reactions " exemplified br polymorphic conversion of i 1- -.j~ --I . - ~ amoicilumn1trate. Sbor. 1-uch. robe, lam t.khin.All RSSR no.5: 3-12 03~0 (KLaA 10:5) (Chmmical reaction, We of) (Ammoulum nitrate) IN namm"WWO"I"Asgalar. V.A. Turud decomposition kinetics of 0000100 c&r%)A&SO *sd Ourf"O area of the solid Product (N90), ftrt 1: rwroal decomposition kinetice of gg=30E~O WA MgCO .4R2 0. Sbor.vAudh.r*b.Inst,Wm. AN, MSSR no.5:58-74 156. 3 (XIMA 10: 5) (Magmselus carlboustes) (Mosiml reaction, Rate of) 1~rzw, B.T.; PWUN',Cnxlz. V.A. '--~-~=rdecovpooiltloz klastice of mpselum ow-bonate and surface arfs of the solid product (NO), ftrt 2s Inven't1gation of surface anm of mgmeltm oxide In deaceposition produote of KgCO 3-3H 20 'L4 apit ".4#20 by adsorption of C, 02, Sbor,.mlxchr&b.lnmt.Wm. AN BSSR no-5:75--91 156. (KLUA 10: 5 (V4W*slw carbonate*) (Chemical reactlos, late of) (C-rbe-.1gote"s) TMNTN, B,.T.l CHIPAO, I.I. - Initiators ond peroxide lyroftate of )-carens **tooxidstion, Uch.sap. SOU no.29sl5-22 156. (win 11111) (Oxidation) (Carens) 1ARMINg B.T.; CHIRICO. A.Z. lommoww"m 40 Autamtion kinetics of 3-carens, Uch,sapo BOU mo*29:3-14 156. (Kim 11:11) (Oxidation) (Carom) USM/Physical Cheiststry - Therzodynamicso 7hermochenistry, B-8 Equilibria, Physical-Chemical Analysis, Phase Transitioas. Abe Jour : Refemt Zhur - Rhimiya, No 1, 1958, 389 Author : B.V. YerofeyevL.T. Mendeleyev. List : Acmdeqj of Scionees of Mite-Russian BE. Title : NImitics of Phase Transformti~n IM4]kr (X)4-.0- JWD4,Br (11) Orij& Pub : Vestei AX BM. Her. fit.-tekhn. n.0 1957; No'l, 57-63 Abstract : The kinetics of the phase transformation M4~Br (1)- ]Mjt]3r (11) was investigated. It is described*by the equition 1 / (1 - a~ ) - 1 - Kt, where cK is the share or Us now Oaqop K Is oomUmt and t is time,- It Is explained afj a process procosdi~g through Thai formtlon and growth of kernels of the solid product,, Card 1/1 2~-~o Y. tfa ~ Z- /-, C". Status of Chemistry In the AdndwW of Sciences of the White Russian 5.502. on the Oth wmlvorsary of the 4rest,October Revolution. Vestal M MOR Ser. f Is.-tokh. bev. no.j~:31-42 '57- (White Aussla-Chomistry) m(a By-q_v 21 ,.mmwmmww"pm~- X.H.Payluchenko's re-oly to the critialse of hio coacepto of tne mochani8c of Yeactious of solids. Zhur.fiz,khIv- 31 MO-2:505-508 F '57. (KLRA 10: 7) 1. AN BSSR, Inatitiit k121mij. Minsk. (Choutcal react ton-Nechemism) (Ulids) %4%- fama"I T. flnislation md ~b Of WPI"100 In li"Ids.4ind oallUm tr S.F.Bouden wA A.D.1offe. TrOW14*04 frd" IfffliNh W A.I.Gol'blvAort Xvieved by I.T.BrotOW. Qmr^v#*l9- 31 910-4:932-931 AP Is?. (Sxmlogtong) (BoUdM, S&P.) (loffo. A.D.',l (MLRA 10:7) YF-kv F F-7YE; J~) AUTHCR Uttske-vich, N. I., Soroko, T. X., Yerofc.'1Ov.,J3'# , Academician, Belorussian SM'Academy of Sciences TITLE ecarbo;-,lation on the autoo: lIction of in a Ilixture with Fatty Acids. (soi)ryazhennoyedekttrbpkeiliro4itniya pri avtookislonit henzola v smesi a zhlrny~mi kislotami -.Russian) PLaIODICAL Doklady Akad.11auk 5SUt1957tVO1 115#11r 1pp. P 1o3-1o6 ABSTRACT It was shown by the authors,'in earlier.paper.3 that tho lo7-'Uenparat.:- re autooxydation,of res 'inoud icids is'acco~upaniiqd by a decarbr-,xilation of these gicids.In.this. connection it was interestin,~- to find oat whe- ther a conjugate dedarbovIlation. of carbonic acids in a zaixtare with a hydrocarbon which are subject to autooxydation was possible.The tests made for this purpose show that an autooxydation of .benzene in a,mixture with aceti~,butyrio,isobutyric ane ste--ric -,zf"-- is actually a6companied by a conj ugate. de carboxylation.Thur; t%e o: iqli of the hydrocarbon induces the connected decarboXylation -irocc.-ts o~ the acid '(terminology,by 5hiiov).Since the autooxydatioa of o*arbons, especially at~higher temyeratu~ees,,ntay lead to the formatici-i of 4cids capable,in-the course of eurther iLutooxydation,of a cordL.-atc decarbo'x' dis' overy of this phenomenon is of carta-in ylation,the, 0 ~'k. est for the-und6ratanding of theoxydation. chealsm of hydrocarlborrj -In gener~l.The self-acting decarboxylation of fatty acids only takcs ce at considerably hiaher temperatures than the'conjugate deca-x'U-o-,.a- Card 1/3 lation diaco'vered'by the authors.Ill.'1 shawn that the autooxidation Conjugate Deoar4oxyl4tjon- ,of 'the 41utooxidatton of Iso- 20-1-28/54 piqpyDensene in a Mixtar6 with Yatty Auida ..speed of isoprop-lbonsone is about four tiiaas hl~,rher in t!-~~, ,rp- 40 u was ce.of an!acid than witho't.an.acid.The initial apeed it decreased .Tab.1 shovis the influence of tLie maid concentration. this speed.Addition of 1,o4 % of Isobutyric acid increases the s-.ccc- more than f our-f old. Further additions of said virtually do nct ge the amount of oxygen absorbed at all.11oweverpthey brir,~ abo'ut. a:-.~ increase in the developing C02 more than qiz-fold,at a pr:Lctica'-,l.-,- changed amount of absorbed e- gen.The' test results of the oxidatio~i . I V of isopropylbenzene,.in-a mixture with radioactive acetic acid(labelcc-. on the carboxyl)confirms-that the escaping CO at lea t partly,deve- lo:ps. at the expense of' the carb~Oxyl. kroup of Ge addead acid.The test-~ wi-th'oxydation of acetic,bixtyriopisobutyric and stearic acid3 unA-0-- axialogous conditions but withpiA i8OPVOPY113enzene showed that neit-1-'er. an absorption of oxygen noi'a foruation~of C02 takes pluce. The, zrzall amount Of C02 escaping on. this' 'occasion probably represents a procci, which is connected Nith the autooxydation of these acids.A ziche--e- i,., proposed for the 'conjugate decarboxylation process of organic aciex with a simultaneous autooxydation of hydr'ocarbons.It conz-ists of: I'.'formation of the radical of isopropylbenzene peroxide, 2. int eract -4:n ..o1'' this radical with the organic acid under foTmation of a acid ra- I dical, - 3. the decarboxylation. as such, 4.aeparation of a li:~(Iro.--en a- Card 2/3 tom from isop'ropylben.zene in'the tertiary group due to interaction Co.-&3ate Docarbox.vlation of the Autoo"i I-Itioll of TSO- propylbanzene in a Kixture -aith ~'atty -cids. with the produced radical 11. VIAs reaction leads to the re,;-2nera~i*:. of the initial radical. Thus the reactions 2 - 4 mrc Sion reactiona.It was denonstrated, an induction of the kind ed abovelreally takes place. (3 illustrations, 1 table and 7 61,tvic references) ASISOCIATION cf the. Academy of ScLercesof (Institut khimii Akademii Nauk BSSR) PU4;S L11TIO B Z 0 L111'.7ITTM 12.1-1957 An'. I LA:,' L E Librax"y of Congreos. Card 3/3 ....... ... 50) PEW I UK Akedludys, nu* Volorasokoy Mi, Institat Wadi sbornik nmcbwkh rooto v". 6 (conoction or s*0"Airta Wafts of the Institute of~hmdstryj, Delormstea SSR Aea4W of Belofteliip or.. 6) minsk,, xxd-vo m DaUrusskoy SO., 1958. M I* 1j,100 mplos printed,, 3d.: Acadedelmp I= Ac~ or Salome*; To&, U.: PURPM: Ow Ix)ok is intended for chw4ste empgod in rogooro in opwalIzed ~ fiel", COMUM., Me book Is a collection of sclwt~fto wtWAwi do%Ung with veried subjecte,p such as problems in electron tboory of som1madmeurs, catalysis, antoxidation of abiotic aC14j, as of Ofte:01setters of sulfur orgenic compounds and reactions of s.1ky1,,wy1,p Wyl-#y rMicals in the 4quid rham.o. PersomUties We Mentioned in the 1bft1w1ftWL articlaso Then are 331 references., of thich 215 we Soviet., 75 UgUshv 30 Cormwo 10 Fremahs and 1 Finnish. card 1/5 collection Of Scientific worm (Cmte) TAMX W 0~2 : vallkewhteyal, rje Sam prdw~ is tjw 21setrap meari #e CiLwyete on Smicoaftetorm 3 BVfs =A V.A, Pftt"hddk. Study of Ontut CadMom 2 =~ 11 1 of ggUlt lanwt* ml YAt&Ule Ombalt With the Aid of the Isatopo Oou-. 39 Mwke"ah; S.Y. Attachwaft fbr the MI-M No" Spectrometer for Studying Gamna Pham Dmt*ftm gxebmp Reaction an 50344 surfaces 47 Ooinavlk., 76#5, Stu4y of the Formation of XMtIvI Fleastim Centers in the Inaftetlau Period of ranual of Marlim A" 59 Mitskoviahj, I.I.j, T.I. Sorokop wad t.T. Ttmftmv. Con4vast" DeawbmW- 2AIan In the AntaxidatIon of Abletle Mid 66 and S.F,* Namovae Tbes"Oftnowles of Sawrissatiam of GramIc SWfa CanpuMs 83 Cezd 2/5 Collection of Scientific Works (Cont.) $07/1265 Filowy, B.O. and X.x. Pw71*dmWw. Determination of "mer, Lithim and Rubidiva in Ma6ral, Salts by Spectrm Analr;js 92 131"IYUchs'llwo MoNo, VeNe AlcuLlAmichp KeVo V4b0v1k# MA 1,N. DMIM. 'Tram 214monts (3, Nn,, Or, Zn) In Salts,of Stmobinshc~* i-' mestorozhdauLye (Deposit) a0 Mmdr Qawtitative Spectrw Am"Is 102 AlAwand"vich, Kh. X. Separation of Sylvinite Ores In &~ Ny4~mcyclcne 115 Krivehik, Z.A. imd N.Y. Yermolenko. Structure and Adsorbability of Peat Charcoals, Part 11 125 Novikova,, U.N. end N.Y. Termleako, 1~he FalationAlp of Sorption and Deterioration Prevention by Inhibitors In the Oxidation of )Rubber 133 Ievinav S.A. and N.V. Yermlenko. AdmorU612ity =A Strutur* Of Sesqdoxlde Gels in Relation to tbelr rmnml 145 Stambinets,v GA. and V.S. Kamerov, TM Modeling of Systems: Rubber-like Efieft Polwaer -- Binary Nixture of Components of lov Molecular Weight 154 Card 3/ 5 Collection of Scientific Works (Cont,) SM/1285 Komarov, V.S. Study of Mquillbrium Curves of a Binary Mymer-Solutlon mixture 163 Kbrotkov.. K.N. (deceased) mA Yu.P. Klywjpev. Conversion& of cA -Pimene Under the Action of Gaseous Boron nuoride 170 KlyuM, Yu6P. Investigation of Conversion Products of d% -Pinene in the Presenco of Ortho-phosphoric Acid I Yerofeywr, BA, and S.F. Nammova. Inhibitory Meet of Hydroquinow, on Fe 1WEMAtioi Of VAthyl M0thWry1Mte 190 Terofeyev, B&V.! A.N. Bakhts Peroxide !~beory in the Light of WAsm 'Studies 228 Shlyk, V.G. KInetics 6f Photopol7wrization of Vinyl Acetate in the Presence of Benzoyl Peroxide 234 011dekop., Yu&A* Reactions of saw Alkyl-,, Aryl-, sad Acyloxy lReftemIs in. Liquid Phase 243 (lard 4/5 Collection of Scientific Works (Cont.) 1307/1285 Cherches, M.A. Nature of Sepinic Acid Isolated from the Resin of Norway Spruce AVAILADIB; Library of Con6ress Card 5/5 -T fvA TMPEM._ Bj . [Brafeau, B.V.]; PRATkSWKM. V.A. Determinstion of surface area of noWnesluxi oxido In &: mixture with vagnesium carbonate by cbemsorption of radioactive carbon diozl6e. Voistal AN BSSR. Ser. fig.-tekbn.nav. jlo.2s6l-66 '58. (KRK ID10) (Sorption) (HWeslum oxides) (Ykenoslum carbonatoe) MCnM1V. B,1. (Brafesu. 3.T.3. oWealk Physical chanistry In the Aamdemy ~ of ~ $clause, at the to Russian S,S-Ro on the fortieth anniversary of the Vhite Ituestan S.S.R. Vestal All 3M.Ser.f Is.-tskh.nav. no.4:16-V. '58. 1 (KIM 12:4) 1. AN D&M. (White Russiaw-themistry, Phralcal &a& theoretical) ...... ........... ... "YEV, B.V.; PROTASHMIX, V.A, Use cf Co6O In the stwW of contact conditions betwoon metallic cobalt and its formats, Sbor., naucho robe Instill Min, AN BSSR no.6:39-46 158. (MMA 11:11) (Clobalt-Zootapes) (Cobalt formate) XMIMVICK, Nol.; SOROVD. YEROFNM, B*V, no lwftmk. Conjugated docarboz7lation Z -&-u-to-ox4dation of Abletic seld. Sbor. naadh, rab, ~nst. khlm. AN Bsn no-6:"-82 158- (NINA 11:21) (Cgldatlon) (Abletle acid) IMMOV, 39791 IAUMOVAp 5~7* - - WOMOMM thermodynamics of some reactions of on2ft- organio compounds. Sbore usiuche rab. last, ]&In* AN 138SH noi,6:83-91. 1180 (Sulfur organic compounds) (Chemical reactlims (xmu ilin) SOV/81-59-10-37459 '-Translation from: Reiferativnyy zhurnal. Khimiya,,1959, Ur-10, p 577 (USSR) AUTHON4 Yerofeyov, B. V , Maumova,-S.F. / TITLE: of.Methylmetha- On the lphibiting Effect of Hydroquinone on Polymi~ ization crylate' PERIODICAL: Sb. - riauahn. rabot In-ta khimii AS BSSRp 1958, Ur 69 pp 190-227 ABSIMCT: ~The kinetict of the polymerization of methy1methaorylato in the presence of hydroquinone at 65 - 800C has boen Investigated, The polymerization rate obeys the equation (v0 - v21ro)/Vlnh . (kol/~,)) ke,' (v, and vj,jh are ' ence of an Inhibitor, the rates of polymerization In the absence and the pro kol, kc, and kg are the constants of the rates of tfte nipture reactions on an inhibitor, at the interaction of two polymer radicals and the reaction of chain growth, M and C are the concentrations of the monomer and the in- hibitor, respectively. A diagram of inhibition hAs been.proposed, accord- ing to which hydroquinone breaks the reaction chain as a result of the Card 1/2 direct interaction with the growing polymer radical witl.,. formation of ben- Sat/'81-59-10-37459 On the, Inhibiting Effect of Hydroquinone on Polymerization of Mpthy'loothaorylate zoquinone and probably semiquinone.,- as an intermediate product, which also break fhe chain. A. Pravednikov Card 2/2 I , I . . I 1~ I I 1 '[11,1 '11tiIIIIIIJI ,, , " , . " . ., . , , I . . ~I Peroxide theory of Ael., 346 In the II&t of m0dern Ingsearch. Sbor., nauch. rab. Insto kh1m, AN BSSR no,61n&.233 158. (MIRA n 111) (OxIdAtIon) (Obemical reaotiorr-Oonditians and laws) 79-20-5-38/6~ LUTHORS: gA-~Mm A.&, Yemel Iyanovt it. P 11aumovap ISQ Fe YeS TITLE: On the Absorption Spectrum of Cyclohexadlone-10 Within the Range of From 220 - 300 wil (0 spektre pogloshcheniya tsiklo- gekaadiyena-1,3 v oblasti-220 - 300 mV) PERIODICAL: Zhurnal ObBhchey Xhimii, 1958, Volp 28, Dir 5, pP'Q 1284 - 1286 (USSR) ABSTRACT: The absorption spectrum of oyclohexadiene-Oplin the UltTa- violet range has been investigated in a great number of papers (References 1-3), however, the results of different alathors do not coincide. In table I the magnitudes found by different authors for the maximu.m positions amd the absorption coefficients are mentioned, The given data (table 1) show that the results of different authors who investigated the absorption spectrum of oyclohexadiene-lt3 in the ultraviolet range do first of all not coincide with respect to the number of maxima on the absorption curve. It is possible that this deviation of the data of come scientists is based on the insufficient purity Card 1/2 of the investigated product. In connection with this the authors 79-28-5-38/69 On the Absorption Spectra of Cyolohexadiene-lj3 Within t he Range of From 220 - 300 mg too:k the absorption spectrum of cyclohexadiene-10 in the ultraviolet range. The product was synthetized in the Labora- tor,y for Technical Analysis of the Institute for Chemistry of the AS USSR and therefore can be looked Upon as a purer com- pound than that of the other scientists. Thus the absorption spectrum of oyelohexadiene-lf3 has, contrary to earlier data, only one maximum within the ultraviolet range (220 - 300 mg) which,as regards it vapors comes to lie on 250.5 mt, (LE& 3.,73) :olution~ in hexane and alcohol and,tas regards its ,on % 258 mji (Lif_ 4ooo), There are 2 figures, 2 tables and 3 references, ncee of which are Soviet. ASSOCIATION: Ingtitut khimii Akademii nauk Belorueskoy SSR (Institute for Chemistry, AS Belorussian SSR) SUBMITTED: April 29, 1957 Card 2/2 - ... ... ~~ n.11-111.11";".~,.".""...".,.....-.""..~ ............................. - 11.1 -1. 1......I TIMOMI '. B,T.; MITSISTICHt Me w -V -,- ~ ~ m ~- F., r5 M liffect of the phase conversion 19 NO (rV)*:;;MO03 (III) on the caking of ammonium nitrate* Shur 44rl,kh Is, 31 no,.22:1805-IL809 1) '58, (MM 12:2) 1, Institut Wall, AN BM9 (Amenlum nitrate) YMMMEV, B.1'. ContnMorary idnas an the cheminm of autooxidation. reactions. Uch.2ap. BGU no-42-03-64 1 58. (MIRA 12:1) (Oxidation) YERDIMT, SJ*; CRINKO. A.I.-, TMEITIVA, YuA, I InwestlgatlW the products of the outoozidation of cyclahaxylbanzene. Uch.zap.'BGU no.42.,12?-13? 1 58. Oalk 1291) (Cyclobsiane) I a. Nikhall Semnovich JMWS". ., J!p4A-JU4Jxd uYlAb#-, TTIMTO ; -W _ A,Ao. red.; ASTACMA, lele, tekhn.red. [Imml utilization in cities, workingmen's settlementep summer and health resorts] lemlepolOsovenis v gorodakh, raboahikh, dachnfth i karortnykh poselkakh. Moskva, Oos,lsd-vo IurJd,lIt-ry# 1939. 285 :P. (KnA 13:5) (Zend) (city punnin ) lull A It 0 fig A -4~ TEMPIM, ]1.V.[Br&foeu, B#V.1; HWTKIN, T.P. Products of the reaction of W and % In th-m prourince of NICI sn4 N13r a Vestol AN B531. Sere fit * -takh anave no.2,.49-55 150a2 2 (MIRA 12:11) (Wpesluu) (Nickel covTounds) Mill HIMINIMUIERVIE MOILIMI.-.1 Classifi(stion of ccoplex roactionso, including tkiat, of catalytic jimeasev. Sbor. nauci. rab. Inst, fizo-org. khlw,,~ AN BSM no. 7:3-32,159. 041RA 14.4) (Memical reaetions) (Catalysis) 3/08 1/60/000/023/002/b21 tog A005/AO01 Translation from Referativnyy zhurnal, XhImiya, 1960, No. 23, P. 65, # 91636 AUTHOR: iterofeyev, B.V. ft, P I TITLEt On the Nature of Autocatalysis In Reactions of Solid Substances PERIODICAL: Sb. nauchn. rabot. In-t fiz.-organ. khImIi )11 BSSR, 1959, No. 7, pp. 1~1 - 22 7M.. The possible reasons are considered of self-acceleration In topo- chemical reaction processest self-fleating, self-disintegration of crystals during the reaction, chain mechanism and catalytic action of the reaction product. On the basis of experimental materials (Yerofeyev, B.V., et al., Izv. AN B38R, 1950, No. 5, P. 145) and the works of other Investigators, the author concludes that the catalytic action of the solid product is the main reasoh of nelf-acceleratlon, The mechanism of the catalytic action of the solid product consists, in the autholls opinion, in the formation, In the course of the reaction, of a boundary layer with an altered electron concentration in the interface between the initial substance and the reaction product. V. Boldyrev Translator's notet This is the full translation of the original Russian abstract. Card 1/1 IWFEYEV, B.S.; PAVLYUCHENKO, X.V- linsticis of the thermiLl destruction of OWl"es. 'Report No.2. abor, juluch. rab. lzwto fts.--org. khIm. AN WSR jao. W03-3JD9 159. (KCRA 104) -(AaWla") TAROMMi BipVe: NILUN*A, 8.7.; TffKAIlDo L.G.1 ZHAVOM, K,A. of 1,3-(Welaboxadlens. DotLAN ISSR 3 W,3:95-99 159. (ml" 12 s 8) YRROFJW, B.T,.; CHIRK0, A.I.; MM]rf,TSVAI Tu.1, limitics of liquid-pha" autoxIdation of ph*iWlcycUhszam. Vokl. AN BM 3 no.6s244-248 Jo 159. .~ (MIRA 1293.0) (Kozww) (Oxidation) YEROFEM, B. V. avd NIXIFMVA~ ff. V. "The CettalytIc Chmp of Chlolohexine on Co"or and Mit~11)10t'20027.-' report submitted for the Second Internatio&a Conaess on cdtiaysis, I)Oria, 4-9 Jul 60. IYEWFEMP B* V# "Reaction Rate of Processes Involving Solids With Different Specific Surfaces." :report mxbmitted for 4th Intl. 8MOBIUM on the ReMativity of SOLL40, Ameterdam, 30 Kay - 4 ~' j,=e 196o. AIMMS It--V*p PROTASuallut To A#) 60 OTM effect of the Co A&&Wwe an the Tarsal Docompolation Rate of Cobalt paper p"mated, at thessymposim an Uw Ommical Kfects of Trawfumationso Wagvw,, Omoeh., 24-27 October 19602 sponsored by the XAM, LA PHASZ I BOOK EXPLOITATION Sov/5410 Tashkentsks:fs. konrerentaiya po mirnomu ispollzovanlyu atoamoy energii, Tanhkent, 1959. Trudy (Transactions of the Tashkent Conference on the Poaaeful t:3es or Atomic Energy) v. 2. Tachkent, Izd-~vo All IM13a, 2540. 449 p. Errata slip inserted. 1,500 copies printed.' Spon5oring Agency: Akademiya nauk Uzbekskov SSR. Responstble Ed.: S. V. Starodubtsev, Academician, Acarlony ot Sciencsj3 Uzbek SSR. Editorinl Board: A. A. Abdulliiy*v, Can- didate of Phy.3ics and Matbpmatioaj' D. M. Abdurrasulov, Doctor of Aliecttcal Sciences; U. A. Arifov, Kcadcmician, Aca4emy or Sciences Uzbek SSR; A. A. Borodulina, Candidate of'Vlolog~Lcal Sciences; V. H. Ivashev; 0. S. 11cramova, A. Te. Ye. M. Lobanov, Candidate of Physics and Mathematics; A. 1. Milcolziev, Cand-idato of bkdioal Sciences; D. Ifichanov, Candidate of Chczdcal Scienoes; A. S. Sadykov, Corresponding Ywmber~ Acadtmy-of Sciences USSR, Adademioian, Academy of Sciences Uzbek 5811; Tu, N. Talanin, .,Tran7acticnis of the Tazhkent (cont.) SOV/5420 Candidate of Phyeios and Mathematics; Ya. Kh. Turakul*v, Doaf;~Dr of Biological 3--lenoes. Ed.: R. 1. Khamidov; Tec4. Ed,; A. 0. Babakhanova. ?M0.33 : The publl,.'~ation Is intended for scientific workers and n,-;eojal!Lata enploy-~d in enterpr1aca whmre radioactive laotopes ani nuclear radiation are u2ed for re3oarch in chemie'al, Soo- lcgloal,.and technological fields. COVERAGE: Thiz collection of 133 articles reprezents the second ve)lume of the ^-ransa-.tions of the TaLthkent Confereni,*e on the FeaTeNl Uses of Atomic Energy. The Individual articles deal with a wide range of problema in the field cf nucle&r radiation, ine,luding: production and chemical analysim or ralloa~%tiva isotcpes; invputigation of the kinatica of chemical rqactlons by meana'o: Isotopes, application of spectral analyt.11.1 for the manufacturing of radioactive preparations; radicact,11te muthods for determining the content of elements in the.rocks; and an analpsis of methods for obtaining pure substances. UertUn Card P/20 176 .Transactions of the Tashkent (Cont.) sov/541o instruments used, such as automatic regulator3s flowmotorn, lovel gauees, and high-sansitivity ga=a-reltWo are doacribed. Ho Vera;inalities are mentioneds References folioir Individual artiolea. TABLE OF CbWMTS: RADIOACTIVE ISOTOPES AND IMOLZAR RADIATION Xj; EUGj3MERnjCj AjrD (JEOLOGY Lobanov, Ye.. H. (Institut yadornoy fiziki UzSSR - Institute of Ilualear Physics AS UzSSR]. Application of Radioaotivk% Isotopes and flucloar Radiation in Uzbekistan Taksar, :E.:'fM., and V. A. Itanuohkovskiy (Institut fizi)d. AN L3tv SSR - Institute of Physics AS Latvian SSR). Problems of the Typificatlon of Automatic-Control Apparatus Based on tile Vac of Radloactivo Isotopes Card 31,0 7 9 T'Iransactiors of the Tashkent (Cont.) SOV/5410 Fal-I m Iiiatitute imeni V.G. Xhlopin AS US51Q. State of the Micro- panUtioa of Radioactive glemonts In Solutions c 353 7'rof.1mov, A. M., and L. 11. Stapanova Inadium Inatitut4t Imehi V.G. Xhlopin AS USSR]. Determ1nation or the MaMitudis of a p (of Complex Ions of Radioactive Elements by Me lon-lix- Charp change 117-3thod 360 Yeroreyev, B V and V. A. Protuahchik [Institute of Phy- fmr-5a"Ir-trg n-9 i-W~-~Omlntry AS B,ISSRI. Appllo*tion of Vadioaotive tA'*(,,, for the Invc~tlgation of the Surface Size in Wit Ronalujons of SoVA Substanoca 46q Z-ve-n, V. I., and V. V. Bochkarev (Imnlatry of Health USOR]. Obtaln:Lng RadloactIvo Xnotopan in tho Rostatoris by Mans 0t rnizmeah:t~old, Consecutive,and Secdndar7 Nuclear Reactions 368 Bukharov,*X. N. [Ministry at Health U,33R). Peculiw-ities In Identification and Analysis of the Tagged Or&anio Cmipounds 372 Card .17/20 S/OS1J61/O00/01V0O4/O28 3105/B201 AUMORs Yerofeyev B. V. TITLIs -temperature oxidation of terpenes and King tics of low rell,ted hydrocarbons P2110DICALs Beforativnyy zhurnalo Khimiya, no. 13, 1961o 70o abstract 13FI513 (Vopr. khimii torpenoy i tory*noidov. VIlInyus, 19610, 103 - 111) TEXTv On the basis of a study of the chain mechanism ofauto-oxidation of' undaturated hydrocarbons (RH), which includes the initiation of the chains during the interaotion of RE with a metal salt (MX according -to the 2) reactions RE + MX2-+R* + UX + RX (1) and RE + NX-OU + Rol 4- EX (2), and from the reaction of chain growth and rupture, the author concludes that the oxidation rate V is proportional to [RRj2 and l/V to Ahe quantity 11CUX2 The latter function was observed during the oxidation of A3 _Oenthene. _p phanyl cyclohexans V is proportional to [RRj5. In order to explain this Card 1/2 S/0ei/o/m/613/064/028 Kinetics of low-temijerature... S105)B201 act the author considers the initiation of the formation of the complex "WX2 (I) to be the first stage and assumes that, soo'oi6ing to the ( structure of RE, the nature of the initiator, and the experimental conditions, the initiation proceeds either according to reactious (1) and (2), or to the reactions zRH + MX2-PI and I-*2R' + M + (I". 2)RH + 2HX, r. -L which leads to different dependences of V on[RE]. LjLvstra6ter~g notet Complete translation Card 2/2 Twonmo -30T."Es"ffeu, B.T.1; CRUM A.I. Eftnte, A. 1.1 Diver Vroducts of the autoxidation of us"tuated b7drooorbous. Testsi AN so.lt5l-56 160. (XnU 13:6) (4drocarbouip) (Polysers) (Oxldatl*a) MMMUV9 B.V, (Brafaeut s.V.], nyjrMV, ju.p. (Knuou 1U.P.) AtudyiAg the mechanim of tv'sWirmUca of"Imne under the inf2vance,of orthophoophorAc acid Applied to ac~ivat,4d birch charcoal. vestai JK Em. Per. Fis. tem. mlvq~ zw- 4149-41 (Itosphoric aced) S/081/61/000/021/093/094 31061S203 ;AUTHORSt Terofeyevv B. V.# Naumovaq S. F., Kulevokayao I, Ve TITLEs Enitiation of ethylene polymerization b~ a complex of otherates of Grignard compounds and titanium tetrachloride PERIODICALt Refii-ativnyy zhurnal. Xhimiyaq no. 21, 1961, 507P abstract 21H55- (Sb. nauchn. rabot. In-t Piz.-organ. khimii AN VSSR, -no. so 1960, 80 - 82) TEXT t It was shown that etherates of butyl magnesium bromide and phenyl 1magnesium bromide synthesized in anisole at 100 - 1200C form&& an active loatalyst with TIM for the polymerization of ethylene. The polymer yield 4 e was doubled when increasing the ratio RVgX t TiCl from 1.4 to 1-7- 4 Etherates containing~(c2R5)2 0 did not,.form an active catalyst with T1014' ~bstracterfs no-tot Complete translation Card 1/1 6,119SO 31738 i/00IJ61/000/021/094/094 3106/B203 AUTHOR'S i Ahlykv V. G.p Yerof*yvv,9, DO ve TITLZ,,t Initiation of polymorivation Uy systems of salts of transi- tion matals and peroxide compounds PERIODICALs Referativnyy zhurnal. Xhimiyag no. 21, 1961p 507P abstraot 21R57 (Sb. nauohn. rabot. In-t Fiu-organ# kbixii AN BSIM9 no,, 89 1960, 83 - 67) TEM; The initiation of polymerization of *ethyl mothfiory~late and styrone by systems of cumene hydroporoxid* (1) &Ad manganese stearato (II) was loxamined. The kinetics of this process van gravisistrically studied. The -rate of polymerization in vacuum at 6000 in the proseno* of I in directly proportiomal to the square root of the concentration of I. AAdi tions of II at first inoreass the rat* of polynorixation of both monomers. That, a limiting concentration of II'is reached, and furthev addition@ of Il d.o not affect the rate of polyaorization any longer, It van conaludei that initiation did not proceed aocording to a redox mechanism. 1:1 probably does not react with I but with a certain intermediate,, ~he con- Card 1/2 32-736 a/08IJ61/000/021/094/094 Initiction of polymerization by systamssoot 3106/2203 - centration of which is considerably lower than that of:II. Soplacoviont of the radicals forming in thermal decomposition of I by radicals of st*arate 11 in possible. An to the rat* of polymerization, these radicals are more activit than the radLoals initially forming in decomposition of 1. ILIbetraater's notiat Complete tranvlatioul Card 2/2 P.I.; MkYDROVAg N.V. IfnitlAtion of - d"arbb)ql&ti6 :,';*tbr,"e". - qxr. nauch. rab. :rnot.'fiso-org. kbim. AN M ig j 00 1, (KIRA 14 3) J. liastitut fisiko-or' dahookoy-khWI (AnthracenoT- (04;6~ PMV) S/08 61/000/022/019/076 BI02YBIOS AUTHORS: Ycrofeyevp B. V.p Ushakhina, N. A. TIME: Inhibited self-oxidation of cyclohexanone PERIODICAL: Rafe-rativnyy zhurnal. Khim'lya, no. 22, 19610 146, atstract 22Zh53 (Bb. nauchn. rabot. In-t Pis.-organ, khimii A-N BBSR, no. 8, ig6o, 161-167) TEXT: I t i askjown that, owing to its effect on the initiation process, hyd:roquinone dece%erates the oxidation of cyclohexanonet (85-9500 as inibiated by cobalt acetate. Activation energy with respect to reaction rate is 21,600 cal, with respect to the induction period 23,900 cal, which values are almost equal. Consequently, the activation energy of the process coincides with the activation energy of the initiation period. [Abstracter's note: Complete translation.] __Ccrd 1/1 8/170/60/003/012/1014/015 B0191B056 AWHORS: Academfoian of the AS BSSII, Tr;- .-yer, V# II.; Correspondinr-Wember of the AS BBS, VallyukI V. A09 Candidate of Physical and Mathematical $cienoes TITLE: Nikolay Sergeyevich Akulov (On the Occasion of His 60th Birthday) PIMIODICAL: Igzhenerno-fizicheekiy zhurnal, 1960, Vol. 3, No. 12, Pp. 119-122 TEXT: On Septetaber 12, 1960, Acsdemio4an of the AS BSSR, Professor N. S. Akulov waa 60. He looks back upon a 35 years' activity as head of the Laboratory of Problems of Phyaiov of the FTI AS BSSA. Akulov finish,- high school in 1919, 1920 he joined the led Armyo and, jJ'ter having been demobilized in 1921, he began to study at the khimi0heskJ.y fakulltot Kubanskogo -politekhnicheakogo institut (Chemical Dayartment of the Kuban Polytechnic Institute). From 1922 onward he stuaied at the fiziko- matematicheskiy fakulltat (Department of Physics and Mathematics) at Moscow. Under the guidance of Profeew U. 1. Ixg*ryuhQv he studied the Card 1/2

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