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SCIENTIFIC ABSTRACT ZAKUMBAYEVA, G. D. - ZAKUSILO, P. S.

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SCIENTIFIC ABSTRACT
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ZAKUMBATBVA, G.D.; SOKOLISKIT, D.V. Iffect of potassim iodide on the catalytic hydrogenation of some organic compounds. Izv.vys.ucheb.2aV.; khimA khtm.tekh. 2 no.3:340-344 159. (MIRA 13:8) 1. Inatitut khimicheakikh nauk AN XazSSR i Kazakhekiy gosudaretvannyy universitet imeni 6.M.Kirova. (Potassium Iodide) (Hydrogenation) SOrDLISKIY, D.V., akademik; ZAM.IMYEVA, G.D. Iffect of alkali wetal halides on the mechanism of catal7tic hydrogenation of cyclohexane. Dokl. AN SSSR 124 no.4: M-M 1 159. (MIIIA 12:1) l.AN IAzSSR (for Sokollakly). 2. Institut khimichaskikh nauk Akademli nauk UzSSR. (Alkali metal halides) (Cyclohemins) (Hydrogen& tion) IZAKUMBAYEVAN G.D.; SOKOLISKlYp D.V. I--- Effect of sillogli metal halides on the hydrogenation rate of cyclohexens and mesityl oxide over palladi= black. Tru4y Inst.khim.nauk AN Kazakb.SSR 7:3-12 161. (MIRA 15:8) (Alkall metal halides) (Hydrogenation) (Cyclobexene) (plenetenow) SOKOLISKIY) D.V., akedemik, glav. red.; POFOVA9 N.M., kand. khim. neuk., red.;IZAKUMBAYEVA, G.D., kard. khim. nauk, red. ; BUIAVKIIIA, L7A-.,--tc-hJTaMMiC.' nauk, red. ; GREMIKBIA) G.F., kand. khim. nauk) red.; DUARDMIAMPA, K.K., kand. khim. nauk, red.; GIAZYRINA, D.1.1op red.; ROROKIVA, Z.P., tekbn.red. [Catalytic reactions in the liquid phase] Kataliticheskie reaktsii v zhidkoi faze; trudy Vsesoiuznoi konferentsii. Alma-Ata, Izd-vo All Kaz.SSR, 1963. 459 P. (MIRA 16:12) 1. Vse.-oyuznaya konferentsiya po kataliticheskir. reaktsiyam v zhidkoy faze, Alma-Ata, 1962. 2. Kazakhskiy tekbnologiche- skiy institut *iInstitut 1,,himicheskikh nauk All KazSSR (for Sokollski,y). (Catalysis) ZAKUMBAYEVAt G.D.; SOKOLISKIY, D.V., akademik ZAKARINA, N.A.; - Effect of zinc ions on the sorption of hydrogen and the catalytic activity of palladium. Dokl. AN SSSR 153 no.l: 133-135 N 163. (MIRA 17:1) 1. Institut khimicheskikh nauk AN KazSSR. 2. AN KazSSR (for Sokollskiy). ION NR: AP4041403 S/0020/64/156/006/1386/1388 ACCESS AUTHOR: Zakumbaye4a, G. D.; Nookova, N. F.; Konayev, E. N. Sokollskiy, D. C e fnr~ MA ~ AM KazSSSR) TITLE; Liquid:phase oxidation of carbon monoxide SOURCE: AN SSSR. Doklady*, V- 156, no. 6, 1964, 1386-1388 TOPIC TAGS: carbon monoxide, liquid phase oxidation, palladous chlo- ride catalyst, cupric chloride catalyst.*, bromide ion, iodide cata- lyst, acetate ion, catalynt activity, catalyst regeneration, catalyst life ABSTRACT: The liquid phas idation of low concentrations (0.3-2%) 8 ox of carbon monoxide in a circulating system at 20, 40 and 60C was investigated. The CO-containing gas was bubbled at 150-300 liters/ hour through the catalyst solution at-the bottom of the reactor. At 20C only 12% oxidation was attained using PdC12 or Cucl in 0.02- 11~0.1N HC1; this yield was lowered to 6% at 40C. With thd addition of bromide or iodide ion oxidation was increased to 20% and was independent of tem rature, A maximum oxidation of 35%.was'attained with [Pd2+1 : [CuZr j 0.22, (Cl-) [Br-] 0.2 and 0.02N HCl. Card 1/2 5(2)~ 5(4), 50) SOV/153-2-3-6/29 AUMORdi Zakumbayeval G. D., Sokol'skly, D. V. TITLE: The Effect of Potassium Iodide on the Catalytic Hydrogenation of Some Organic Compounds PERIODICAL: Izvestiya vyashikh uchebnykh zavedeniy. Xhimiya i khimichaskaya tekhnologiya, 1959, Vol 2, Nr 3,, PP 340-344 (USSR) ABSTRACT: At the beginning various results on investigations of the effect mentioned in the title are quoted (Refs 1-7). The following Soviet authors are mentioneds Aykazyan and Fedorova (Ref 4) and Pleskov (Ref 5). The hydrogenation process of various organic compounds was investigated on a-skeleton nickel catalyst (0.3 g) with 20t 30, and 400 in 50 ~ ethyl alcohol. The solutions were 130,5ff, 0.14 and 0.01 N of potassium iodide. The kinetic and potential curves of the hydrogenation were recorded, namely for the following substances: cyclohexene (Fig 1), allyl alcohol (Fig 2 and Table)p mesit-yl oxide (Fig 3), and n-nitrophenol (Fig 4). The following was founds The iodide ion reduces the rate of hydrogenation of unsaturated compounds and displaces the potential of the catalyst to the negative Card 1/2 values. The inhibiting effect of the iodide is stronger than The Effect of Potassium Iodide on the Catalytic SOV/153-2-3-6/29 Ilydrogenation of Some Organic Compounds that of the bromide; it still increases with the increasing dipole moment of the hydrogenated substance-The rate of hydrogenation depends on the fact to what degree the substance to be hydrogenated may reach the surface of the catalyst. There are 4 figures, 1 table, and 11 references, 10 of which are Soviet. ASSOCIATION: Institut khimicheskikh nauk AN KazSSR i Kazakhskiy gosudarst- vannyy universitet imeni S. M. Kirova - Kafedra kataliza i tekhnicheskoy khimii (Institute of Chemical Sciences AS KazSSR and Kazakh State University imeni:S. M.:Kirov-- Chair of Cataly6i:s.and Technical Chemistry) SUBMITTED: March 14, 1958 Card 2/2 ZAKUMBAYEVA, G.D.; NIOSKOVA, N.F.; KONAYEV, E.N.; SOKOLISKIY, D.V., akademik Liquid phase oxidation of carbon monoxide. Dokl. AN SSSR 156 no.6: 1386-1388 Je 164. (MIRA 17:8) ." ~.' Akademiya nauk Kazakhskoy SSR (for Sokollskiy). .0 J) A KC, I- I BP YEVA G-.!) -1~ 1 ii.A 11. A .30KOL i Y -IT I` ad em i Ef fe c t or mi-kel na!tz, A !1.'4 hla:~k, Dok,' (1,1rilU, 18:2) A,* FAZSSR (for 50- SOKOLISKIT, D.V.; ZAKUMBA M A, G.D. Reduction of p-nitrophenol on a nickel skeliptal catalyst in the presence of potassium chloride. bromide, and iodide. Trud7 Inst- khim.nauk AN lasakh.SSR. 5:3-8 -159. * (MIRA 13:6) (Phenol) (ReductioO - ZAXUMTZVA, G.D.,- SOKOLISKIT, D.V. Iffect of alkali wtal halides on the rate of h7drogenation of allyl alcohol. Trudy Inst.khim.nauk AN Irazakh,SSR 5!9-14 159. , (MIRA 13W (Allyl Alcohol) (Alkali metal halides) (Hydrogenation) SOKOVSKIY, D.Vi; ZAKUKBAYZVA, G.D. Zffect of alkali metal halides onthe mechanism of hydrogenation of cyclohexene on platinum black. Izv.A?T Kazakh.SSR.Ser.khim. no.l: 62-64 159. (MIRA 13:6) (Alkali metal halides) (Hydrogenation) (Cyclohexons) ZAK U)."PAY L'iA, G. D., Chem -"-c:i -- "Th,~- eff~;C'.A ~f basic on the au!sorbt.--jn anu propertL~i3 of 'd) Pt aru Pu," AL,m-Atz,, 1960, 19 pp, 250 cop (Kazakh 'St-tte U i., S. 1. Kirov) (KL, 43--~,O, 117) PHASE I BOOK EXPLOITATION SOV/3537 .Akademiya nauk Kazakhskoy SSR. Institut';khLt"heskikh nauk Trudy, t. 5 (Transactions of the Institute of Chemical Sciences, Kazakh SSR, Academy of Sciences, Vol 5) Alma-Ata, Izd-vo Akademii nauk Kazakhakoy SSRj 1959. 154 p. 1,000 copies printed. Ed.: N.D. Zhukova; Tech. Ed.: Z.P. Rorokina; Editorial Board of Series: D.V. Sokollskiy (Reap. Ed.), V.G. Gutsalyuk, and B.V. Suvorov (Reap. Secretary). PURPOSE: This collection of articles is intended ftrpersonnel of scientific research laboratories, laboratories of industriil enterprises, and faculty members of schools of higher education. COVERAGE: The collection reviews problems of liquid-phase catalytic .hydrogenation to.upgrade and reactivate various products. Hydro- genation of unsaturated bonds of various types, adsorption of hydrogen on different catalysts, chrona,tographic separation of mixtures, and the effect of halogen saics of alkali metals on the rate of hydrogenation reactions promoted by'various skeleton catalysts are described., Conditions of catalytic hydrogenation Card 1/5 Transactions of the Institt;te (Cont.) SOV/3537 of natural fat, sunflower oil, and such synthetic products as esters of high-molecular fatty acids are set out. Dehydration of the butane fraction-carried out in combination with Isomeri- zation is analyzed. Principles of selecting catalysts and re- generating them are reviewed and the formation of adsorption potentials on metal catalysts is explained. Each article presents conclusions drawn on the basis of experimental findings,, References accompany most of the articles. TART OF CONTENTS: Sokol'skiy, D.V., and G.D. Zak!tinmb4ayev4. Reduction of n-Nitrophenol Carried out Over the SR-e-l-el-d-n-Ni Catalyst in Presence of Obtassium Chloride, Potassium Bromide, and Potassium Iodide 3 7,Akumhgyeva_,_~., and D.V Sokol'skly. Effect of Alkali Metal lia-lides on the Rate of Hydrogenation of Allyl-Alcohol 9 Sokollskiy, D.V., and N.M. Popova. Adsorption of Hydrogen on Ni/ZnG Catalysts 15 Card 2/5 Transactions of the Institute (Cont.) SOV/3537 Popova, N.M., and D.V. Sokol'skly. Hydrogenation of,Allyl Alcohol Over NI/ZnO Catalysts 20 .Shmonina, V.P., R.N. Khasanova, and D.V. Sokol'sXiy. Chroqiato- graphic7 Separation of Mixtures of Nitrobenzene-Aniline Products 28 Golodova, L.S., and D.V. Sokollskiy. Study of Hydrogenation Reac- tions of Natural Fats and Their Simplest Synthetic Analogues, the Esters of-High-Molecular-Fatty Acids 36 Golodova, L.S., D.V. Sokollskiy, and Ye.A. Podlyacheva. Kinetics and Mechanism of Hydrogenation of Sunflower Oil in Solut:Ibns 44 Luklyanov, A.T. Problem of Formatian.of Adsorption Potentials' on Metal Catalysts 50 Yerzhanov, A.I., and D.V. Sokollskly. Potentiometric Study of Hydrogenation of-Benzalacetune Over Skeleton,Pd/Ni Catalysts, 56 Buvalkina, L.A., G.V. Pavlova, Z.F. Prussakova, and D V. Sokoll- skiy. Dehydroisomerization of the Commercial Fraction of n-Butane Over Oxide-Catalysts 64 Card 3/5 Transactions of.the Institute (Cont.) SOV/3537 .Shmonina, V.P., K.M. Vlasova, and D.V. Sokollskiy. Catalytic Re- duction of Aromatic Nitro'Compounds. Part IX 72 Ylil- R.M. (Moskovskiy institut tonkoy khimicheskoy tekhtiologii Inewi M.V. Lomonosova- -Moscow Institute of Fine: Chemical Tech- nology imeni M.V.--Lomonosov). Some Principles of Selecting Cata- lyst3 fo7i Liquid-Phase Hydration of Acetylene to Acetaldehyde 81 Shcheglovi N.I., and D.V..Sokollskiy. Some Methods of Reactivating the Skeleton Nickel Ca:t:alyat 92 Shcheglov, N.I., and D.V. Sokollskiy. HydrolKenation of Acetylene in the Liquid Phase 97 Sokollskiy., D.V.,, and L.P. Dunina. Hydrogenation of a Sodium Salt of Propiolic Acid-Over Platinum Sokollskaya, A M and.D.V. Sokollskiy. Hydrogenation of Cinnamic Alcohol (Styro~ej 110 Card 4/5 Transactions of the Institute (Cont.) SOV/3537 . Fasman, A.B., 4pd D.V. Sokol'skiy. Effect of the Amount of Cata- lyst on the Rate of Catalytic Hydrogenation 114 .-Sokollskiy, D.V. Hydrogenation In Solutions 146 AVAILABLE: Library of Congress TM/jb Card 5/5 5-25-6o Z&KTTMWr-VA, G.D. &ND SOKOLSFI, D.V. "Hydrogen adsorption and catalytic activity of platinum, nickal and palladium in the Dresence of anio#s and cationg." Report submitted to the Intl. Committee for Electrochmical thermodynamics and kinetics, L~ome, Italy 24-29 Sep 1962 ZAMEAMA, G.D.; NOSKOVA, N.F.; KOVAYEV, R.F.; SOrOLISKIY, D.V., akademik Low-temperature oxidation of carbon monoxide by aqueous solutions of palludium salts. Dokl. M SSSR 159 no,6:1323-1325 D 164 (Y,IRA 18ti) 1. Institut khimichoskikh nauk 91 Ka3M 2. AN KazWR (for Sokollskiy). MARINA, N.A.; ZAK U 1-19.,l YEVA , C . SCK~ I--, 3'rl' 1D. in thp prPoence of endmi-in ions. Dokl. AN SSSR 11~2 no./ - ~"4-~116 Je 165. (MI71A 18:51) l.Thstitut Rhimicheskikh nalik AN KwS.311. 2. AN Kaz;*,:~' (flolr Sokollikiy). 5W SOV/20-124-4-42/67 AUTHORS: Sokol'skiy, D. V., Academician; AS Kazak-liskaya SSR, Zakumbayeva; G. D. TITLE: The influence of the Halides of Alkali Metals Upon the Mechanism of the Catalytic Hydrogenation of Cyclohexene (Vliyaniye galoidov shchelochnykh metallov na mekhanizm kataliticheskogo gidrirovaniya taiklo-eksena) 0 PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 124, Nr 4, pp 180-882 (USSR) ABSTRACT: The influence exercised by salts on the catalytic hyirogena- tion of solutions has hitherto been only very little inves- tigated. The authors investigated the hydrogenation of cyblohexene on a skeleton-nickel-catalyst (0-3 g) in solu-- tions of 0.01; 0-1; 0-5 and 1 n KC1, KBr and Kj in 50% o ethyl alcohol at the temperatures of 20, 30, 40 - For com- parison, experiments were also carried out with 5VIL-ethyl alcohol without any additions, The authors investigated the kinetics of hydrogen absorption and determined the potential of the pulverulent catalyst. A diagram shows the kinetic curves and tho potential curves for the hydrogenation of Card 1/3 0 cyclohexene in the presence of KCI at 20 .The rate of hydro-- SOV/20-124-4-42/67 The Influence of the Halides of Alkali Metals Upon the Mechanism of the Catalytic Hydrogenation of Cyclohexene genation decreases with increasing concentration of the KC1. Additions of KC1 shift the~potential of the catalyst towards the negative side. With increasing concentration, the rate of hydrogenation of the KC1 decreases. The second diagram shows the kinetic curves and the potential curves for~the hydrogenation of cyclohexene in the presence of Dr. The influence exercised by KCI and KBr is nearly the same in both cases, a certain difference becoming noticeable only in the case of the potential curves. The hydrogenation of cyclohexene in the presence of additions of KC1 and KBr takes place at more negative potentials, and the rate of hydrogenation decreases accordingly. This is apparently due to the decreases of the adsorption of cyclohexene on the catalytic surface in the presence of additions. The activation energy of the hydrogenation of cyclohexene grows with increas-, ing concentration of the admixtures from 2 to 6 kcal/mol. Additions of KJ reduce the rate of hydrogenation of cyclo. hexene still more. For the potential of the catalyst it holds that Cl < Br- /, J". The pff-value of the substances in- Card 2/3 vestigated was somewhat modified after the experiments. A 30'f/20-124-4-42/67 The Influence of the Halides of Alkali Metals Upon the 11"echanism of the Catalytic Hydrogenation of Cyclohexene potassium-cation is adsorbed in a KC1 solution on the surface of the nickel ca-talyst, but in solutions of XBr and KJ an anion is adsorbed. For the binding energy of the adsorbed hydrogen it holds that Cl 4_' Br- -'-' J_. There are 3 figures, 1 table, and 6 references, 3 of which are Soviet. ASSOCIATION: Institut khimicheskikh nauk Akademii nauk KazSSR (Institute of Chemical Sciences of the Academy of 3cionces, Kazakhakaya SSR) SUBMITTED: August 25, 1958 Card 3/3 'T. 00 66673 SOV/76-33-11-36/47 AUTHORSt Sokol'skiy, Do V t Zakumbayevaq G. Do TITLEa The Influence of Potassium Bromide Additions on the Mechanism of the Catalytic Hydrogenation of Some Organic Compounds PERIODICAL: Zhurnal fizicheskoy khimiip. 1959t Vol 33, Nr 11, pp 2579-2585 (USSR) ABSTRACTt The influence of neutral electrolytes on the mechanism of catalytic hydrogenation has hitherto scarcely been investigated. Only recently Erdey-Gruz and Tuimmer (Ref I)p and Xhosino and ' such investigations. The potentio- Miyata (Ref 2) carried out metric method developed by Do V. Sokollskiy and V. A. Druz, (Ref 3) makes possible to investigate the influence of the above-mentioned additions on the structure of the double-layer and on the concentration relation of the reacting substances on the surface of the pulverized catalysts. Additions of potassium bromide were investigated in the present case, since studies of A, N. Frumkin (Ref 4) showed that the bromine anion influences the reduction on the Pt - H 2 electrodes. The ex- Card 1/3 perimentz were made on a skeleton nickel catalyst (0-3 9), 66873 SOV/76-33-11-36/47 The Influence of Potassium Bromide Additions on the Mechanism of the Catalytic Hydrogenation of Some Organic Compounds cyclohexene., allyl alcoholp mosityl oxidep and p-nitroplionol being hydrogenated. 50%-ethanol and 0.01, 0-19 0-5, and In- solutions of KBr in 50% ethanol at 20P 30, and 400 were used. The kinetic and potential curves obtained (Fig 1) show that with an increase in the concentration of the potassium bromide the adsorption of the cyclohexan on the surface of the catalyst decreases as well as the rate of 4drogenation. It is assumed that the bromine anion forms a film on the surface of the catalyst by which an additional potential barrier is formed which pre-vents the cyclohexene from entering into the reaction. Calculations of the activation energy (Table 1) show that the limiting stage of the cyclohexene hydrogenation on the skeleton nickel represents the activation of the cyclohexane, and that this activation is increased by the addition of KBr. The in- fluence of additions of potassium bromide on the hydrogenation of allyl alcohol (Figs 2,3) is weaker than at cyclohexene, while with p-nitrophenoll(Fig 5) the effect observed is similar to that with cyclohexone. The hydrogenation of mesityl oxide Card 2/3 is accelerated by small additions of potassium bromide (0.01 b6813 SOV/76-33-11-36/47 The Influence of Potassium Bromide Additions on the Mechanism of the Catalytic Hydrogenation of Some Organic Compounds and Oeln) (Fig 4)p but inhibited by higher concentrations (0-5 and 1n), which fact is explained by an orientation of the dipoles. It is assumed that the more negative the dipole momentum of the substance is the worse is the hydrogenation in the presence of bromine ions. The hydrogenation of the mesityl oxide is also limited by the activation of the mesityl oxide (Table 2, activation energies). With respect to the amount of the adsorption the compounds investigated can be listed in the following orders cyclohexone < allyl alcohol < mesityl oxide p-nitrophenol. There are 5 figures, 2 tables, and 8 Soviet references. ASSOCIATIONt Akademiya nauk KazSSR (Academy of Sciences of the KazSSR) Card 3/3 ZAKUMBAYEVAs G.D. Effect of the structure of a double layer on the adsorptive and catalystic properties of nickel and platinum. Trudy Inst.khim. naikk AN lazakh.SSR 8t73-W' 162. WMA 15s12) (Nickel catalysts) (Platinum catalysts) (Adsorption) Ell, EV(r(,M)/EWP (J)/EVP WAILIPW Tio(c) M/J(;/Rit /1325 ACCESSION NR: AP5001991 AUTFOR- Zakumbayeva, G. 0. Uoskova, N. Sokollakiy. D. V.; Konayev, E. N. .(Acad 4~c-ian*A~NK&zS~SR TITLE: Low temperature oxidation of carbon monoxide with aqueous solutions of alladium salts -P SOURCE: SSSR. Daklady, v. 159, no. 6, 1964, 1323-1325 TOPIC TAGS: carbon- monoxide oxidation, palladium containing catalyst palladium copper iron catalyst, catalyst stability -ABSTRACT--Small-amounts -of CO_(0._ 2-416) -can -be essentially-completely -oxidiz- edi no ne pass at low-tem ature swit h aque-o- system- r containing Pd2 .-Cu- -- Fe 'The oxidation procee&-via--the formation and do _c0 sition of the- ?r complexEPdK491.w; It6e- ~tduce&Pd _xinstt-,be regenerated to Ffr H202, CrC13, K2Cr2O7, - Cu"' and Fe were investigated as oxidizing I agenits in the aqueous Pd salt solutions; t~a most stable and active system car.- 2+jj(Cu2+j= 0. 22; 0.5-1 gl Fe + increased the activity, but 1. 5- 2. 5 tained ( Fd 112 L 25137-65 ACCESSION NR: AP5001991 gfl of F63-l' retarded the CO oxidation process, Anion concentration also affected the process; optimum catalyst activity was attained with 3. 5 g/ I Cl-, 2o. G gi I Br- and 13-15 9/1 CH3CC0_, Increasing temperature from 20 to 40 C had little effect, and the gas feed rate had no effect on the catalyst activity. Complete re- versibility of the Cu2+ -*,-' Cu+ Jr e redox system is necessary to maintain high catalytic activity. Several methods for possibly increasing catalyst stability were investigated, K2Cr2O7 and CrC13 did not give desired results; high concen- 3+ tratio-s of oxidizing agents with high redox potentials We ) interfered with re- duction of the Pd complex. Catalyst stability was prolonged by the canstant addition of 0. 456 H202, but after several hours the activity fell due to the dilution of the catalyst solution. The stability of the catalyst was increased by a new me- thod of regeneration (Abstractor's note: the method was not described) so the process could be operated continuously as long as desired. Orig. art. has: 3f ig- ures. ASSOCIATION- Inotitut L-himicheakik-h nauk Akademit nauk Kaz.SSR Urlstitute'of Chemical Sciences, Academy of Sclences;KazSSRL SUBMITTED: 17Aug64 ENCL- 00 SUB CODE: GC NR REF SOV: 005 OTHER: 005 Car& ZAKMIN, S.M. Statistical generalized nownt of VA. Somenchenko. and the surface activity of metals. Zhur. neorg. khim. 5 no.8:1892-1893 Ag 16o. (KIRA 13:9) 1. Kabardino-BalMrskly goandarstvenzWy universitet. (Ketals) (Ions) I =-'UPRA, V.A. , C.-ind Sci lio:;) ,stuay of tl.-c- -::ide igin lll~-Utrtll lz-.ction cf eml-collrbro-~i con! of the Ale'-s-ndri A A7 d,~!pc-sito of the l-TXSSR r--d products of its c-italytic Di~oprop.--tvovnl-, 11)1-)`!. Ll pp-, I rnh(zet of -t-,blo-- ("in of hi,rhor Educ,ttion 11,11, S 311, 1Dn-proprlrovsl: Chnn-jechWM Inot j.:,-, F.-. Dzor- 150 GOIAL-0 (,'Ly 38-53) 116) L 19665~-65'.: ar, Vffi' (0/34T(J) Pc'MPr-'4 FZD(t)' 1VIM ACGESSIOIT UR AM5001004 BOOK EXPLOITATION nemical Scienc 6); Lebedert -1yar, Vladimir T khonovich (Candidate-of C a j)rat Vadim -fEvgraf Venediktovich (Candidate of Chemical Sciencoa); Z _gku Aleksandrovich (Candidate of Technical Sciences) -Higher monoo1eM;s,(VY,,S8hiye lefiny")o Kievj I d-vo ItTekhimikalls 1964, -monoo 281 p. illus., biblio. .1,800 copies printed. TOPIC TAGS: higher monoolefin, chromotography-f-infrared.spectra.scopyg mass- sp0c troscopy PURPOSE AND COVERAGE: This book covers the problems of obtaining monoolefins with five and more carbon atoms ang their usefor alcohol synthesis, washing substances, plastics placticizersl9synthetic resins, oil additives, high quality special lubricants, etc. The methods. of studying olefin-coataining: -carbon~mixtures,e_specially the methods of gais-liquid and liquid.chromo- tolgraphy, inrared- spectroscopy,- mass spectroscopy ---etc* -are. examined-in -de-, tail. The book is intended for researchers, engineers, and technicians in the petrochemical and oil refining industries and can also be useful for -atudente.and.graduate students specializing in petrochemical s3uthesis. -TABLE -OF.-. CONTENTS Cabridge~j I_:__ ctd 1/2. EMOMM ZA~,ILF~Vt~-; 1Z-;BED---V, Ye.V.; MAMA, I.A. Chromatographic analysis of the cracking and dehydroge-riat-ion products of paraffin hydrocarbons. Khimo i tekh. topl. i masel 10 no.2.-28-34 F 165, (MIRA 18:8) 1, UkrNlIGIPROITEFTI. DALI, V.I.; ZAKUPRA, V.A.; RURAN, I.N. Determining sulfur in coal products by the method of double combustion. Zav. lab. 24 no.12-.1445-1446 158. (MIRA 12:1) I.Dnepropetrovskiy khimiko-tokhnologichookly Institut. (Sulfur--Analysis) 11 (4j AUTHORS; Dal V. I. , Zakupra, -T. A. T I'-,'L E: The Chrcnato -rarhic Invo~Ail'-ation of the Benzine Fr~~.m 4-11io Catalytic Crackdnf- of Lh.,., "cutral Tar Sl,aro of t1,0. S-.-i of the Aleksandriya Li-snd',c of the Ul-,rSSrL 'Ie '~%ta-lit'c'esk-C krel-in-a koye issledovani,. noy chasti smclLy l-'r-1u'~ohsovaniya ale1-sanr1riysk1J1-.- b-urykh -,:k-- 1 c y us:;:,) PERIODICAL: Nauchiiyye deklady vys:,7'j0,r sh':cly. Idlimiya i 1:11 irm J. c;'-e,;'~: tekhriologiya, 1959, 7-ir 1, PI) 173 - 176 (US2",) AB',;T!-'4AC T: The complete chruma-togra--hic so,aration of hydrocarbons tho 1100 of I'atl!or (~cinjjl.icatod hich coluviu;. A neceasitat(ml L' U-Uj1rLj'0d column is rorjoved, in zthfoh the -Milrot.anco to be chromatographed moveo downward in the firut half, and upward in the second Tito cvackirif; product obtailied on C-.13 metal reactor at 450 0 yiolded 310.51-~' benzeric (boilinc- 1,:;int - ,0), "nd 3 '8.2" gac oil ( boilin- point ab(,vu 2\)1W bolbri 20C0) L , I 10.5,5' gao. The rcnainiji~; ?0.8*,*'j Au made tip of culko, moi~Jvv(ll and losses. Bcri7~)r--c was d on -;ilica AS'-'. P1.'Y-,-;cal Card 1112 data a;-,d iodine in rc~licct of the The Chromatographic investi~atior, r,~f the Ben:1-ine FroZ '.Lhe ICA C, ~ 1w --j.1 . Catalytic CrackinG of the Neutral Tar Share of the Sami-cokin~ of t1ne Aleksandriya Lignite of the UkrSSR individual fractions (Table). The chrumato.-rams presserited chow the separation Into iwaffin- and n!.,.phtl,,o.~e-li,,clrocarbo-,is, cle- fines and aromatic hydrcearbona, The phy,,A.cal con3t.-~nto chance accordingly. One table shwws the compositiuna of tho Individual fractions from these hydrocarbon groups. A strilzin,- fact is the high aromatic hydrocarbon content ( heavy benzol, xylenes). There are 3 fi,-,ur,-s, 2 tables, and 9 references, 8 of which are Soviet. ASSOCIATION: Kafedra khimicheskoy teklinologii t 'opliva Dneprop,-ArovskoUo khimilco-tol-linologicheskogo instituta im. F. E. Dzerzhinskogo (Ch 'ai r c; Chemical Technology of -Fuels of the Dnepropetrovsk Institute Technology imeni P. -1. Dzerzhinskiy) SUBMITI'ED; June 20, 1958 Card 2/2 DALIP V.I.j, doktor tekhn. nauk; ZAMRA, V.A., inzh. Investigation of the composition of Us tar of essicoked Aleksandrov brown coal and products of its catal3rtic cracking. Kompl, vyk. pal.--onerg. roe. Ukr. no.1:209-221 159. (MIRA 16:7) 1. Dnepropetrovskiy khimiko-tokhnologicheakiy in,-qtitut im. Dzerzhinskogo. (coal tar) (Coal--Carbonization) I'lalull,,v Pvgra 'fAklLd;~TLA, Vadim Ih Nenediklcvic -uk.. KLE"ENY, A ch, kand. lek--aDdrOvi tekhn . nauk, ratsenzent gyjv Te,~Lnika~ o jj~, 17 , 9) 281 P. KLIMKO, Aleksandr Petrovich, kand. tekhn. nauk; V*A*j kand. khim. nauk., retsenzent. I - [Separation of natural hydrocarbon gases] Razdelenie pri- rodnykh uglevodorodnykh gazov. Kievj Tekhni a. 1964. 379 p. (MIRA 17:11) .1ACCESSION NRs AP4043279 5/0065/64/000/008/0021/0026 AUT11ORt Zakupra, Ve As; Lebedevo Ye. V.; Manz&# 1. A. TITLE: The effect of chemical treatment on the structure And adsorption property of silica.gel3 with different trade marks SOURCE: Khimlys i tekhnologlyn topliv I masel, no. 8,'1964, 21-26 TOPIC TAGSt silica gel, indusirial silica gel, silica get separation., effectivenesep displacement chromatograpliyo silica gel chemical treatment, hydrocarbon group separationg chromatographic hydrocarbon analysis ABSTRACT: The affect of chemical treatment (with 11C1 and 11202) Of industrial silica gets ASH, KSH, ASK, and of-silica gels with a Riven.-- pore radius KSH-6, KSS-4, KSK-2, on the effectiveness o1 their sepa-;j'.., ration of various synthetic mixtures of paraffinicg mono-olefinicl and aromatic hydrocarbons was studied by means of displacement chromatography@ The use of displacement chromatography for analytical determination of the group composition of cracking or dehydrogenation products has made it possible to decrease the total volume of the J.. CO 5 ACCESSION NR: AP4043279 mixture to be studied as a result of a decrease In the volume of the desorption fraction used in identification. Thus, a decrease In the volume of the mixture to be ar-lyzed decreases the consumption of silica gets* It to noted that this method is advantageousfor a seri'ei of determinations, since the sixe of the apparatus dimensions and the time needed for analysis are also decreased. The characteristics 1'. of the individual hydrocarbon fractions separated are given in Table I of the Enclosures To determine the effect of chemical treatment oti silica gels on the effectiveness of separation of various hydro- carbon mixtures, silica gels with various porous structure (treated and untreated chemically) were used. It-was found that the beat properties for separating benzene,.n-heptane and 2-heptene (mixture ii 1),and isopropyl benxenes n-octane.and I-octene (mixture 2) were possessed by ASH, KSH, and KSS-4 silica gels which had been treated chemically. For separation of a-mothyinaphthalene, n-h xadecane, and 1-hexadecene (mixture 3),the most effective agents w:re KSS-4 and ASK silica gels which also had been chemically treated. KSH-6 silica get clearly showed the effect of chemical treatment# and it separation effectiveness for uixtures of I and 2 approached that o ar At L"', ACCESSION NRt AP4043279 ASMj-KSHq and KSS-4. The activity datermin;tto" of th* silica gals used in the separation of benzene showed a decrease of 4 to 3 units for fine~,porous silica gets which had been chemically treated. This decrease in activity is explained by a'decrease in the specific surface on which the process of absorption of benzene depends. A ~sharper decrease in the specific surface (from 590 to 470 M2/g) as a %result of chemical treatment occurred in ASH silica gel, From the differential curve of the distiibution of pore 'sizes or the effective, irsdil of the silica gets used#'Lt was concluded that the effective .spore radius of chemically treated KSS-4 silica gal is 21 to 27 A greater than that of the untreated get. For ASH silica gal with a :larger pore size, the change is characterized by an increase in the inumber.of large pores. It was concluded that the separating ability Of silica gels Increases after chemical treatment, with the exceptiate of KSK-2 silica galwhich consists of large pares and has decreased ~abillty to separate mixtures of high-molecular particles. The most :effective allies got with mediuvi pore size was KSS-4, -Thus, it was ;established that chemical treatment leads to changes in the porous ize ab'd decreasing .:'structure of silica gets by Increasing the pore a the specific surfacess OrIge arts hass 5 figures and~2 tables* 3/ 5 ,d Al. ACCESSION WRI AP4043279 ASSOCIATIONs UkrOllsiproneft, SUBMITTED1, 00 SUB CODRI HTS 00 I-ACCESSION NRt -AP4043279 ENCLOSUREt 91 Table I& Characteristics of individual starting hydrocarbons mpound. oiling Point 9C* (760 mm of [it) efractive Index an Density Synthetic mixture of Hydrocarbons 2 by volume 'Benzene 80,0-80,5 1.5010 0,8790 33.5 n-Ileptane 97,5--07,9 0.6833- 33.2 No. I 2-Reptane imported, not 1.4094 0.7106 31.3 distilled Isopropyl benzene 149*9-151,7 104908 0o8633 3394 n-Octand 124.3-125.0 1.3972 0.7027 330 Moe 2 I-Octane Imported# not 114089 0,7150 33.3 distilled a-Hethylnapthalano 68.9-70.3 1.6148 1.0232 37.7 (4 a a pm. cm. ) n-Hexad,scana 108,3-108.5 1.4345 0.7740 31.3 No. 3 (3.5 an P". co. I-Nexadecene Imported, not 1.4412 0.7811 31.0 1 distilled I I I Card *Individual hydrocarbons were distilled In a fractionation col-uns with an effectiveness of 20-22 theoretical plates 50 SKLYAR, V.T.; LEBEDE7, Ye-Y.; ZAKUPWvj Y.A.- Dehydrocracking of parafriz.,s over sulfide catnlysts. Nefte- kbimiia 4 no.2:200-208 Mr-Ap'64 (MIM 17&'S) Thermocatalytic --sion of paraffins ov(,,i- oxir' catalysts. lbid.,.209-214 ~ - - --i- 1. Gosudarstvennyy naucluio-issledavatellskiy i proyektnlry insti- tut neftyanoy i neftechimicheskoy promyshlennosti "Ukrniigiproneft", Kiyev. ACCESSION NR: AP4032515 8/0204/64/004/002/0209/0214 AUDIOR: Sklyar,, Va T.; lebedev, Ye, Vo; Zakupra,, Ve Ae TITIE: Thermocatalytic transformation of paraffins on oxide catalysts SOURCE: Neftekhimiyao v. 4. no. 2,, 1964, 2o9-214 TOPIC TAGS! paraffin dehydrocrackin(Sl olefin production, cA olefin productiont thermocatalytic cracking; oxide cato4st, MoO, sub 3 -NiO, Al sub 2 0 sub 3 catalyst,, WO Bub 3 Hig Al sub 2 0 sub 3 catalyst, Cr sub 2 0 sub 3 /Fe sub 2 0 sub 3 catalyDt,, inomerizationo disproportionation, aromatization, condensation# catalyst .i-r-19enerationp economics, conversion rate ABSTRACT: Liquid olefins were obtained in 35-45% yield from paraffins by dehydro- cracking with oxide catalysts (mOOKMO-A12031 WO NVO-A1203) Cr20 IFe 0 ) at temperatures of 550-590C. The par&ffin crude, obLined from diesel 0H ~y complex- ing with carbamidev typically contained 0.060. aromatics, and 40 wt4 C16 C n-paraffins. At 550C increasing the feed rate reduced the yield; at 590C$ tk1j, reverse obtains and high yields were obtained at a space velocitY of 3 hours To obtain a relatively high at-olefin-containing product the conversion should be Card-, 1/2 ACCMSIOK NH: AM32515 Ilimited to 30-40% at high temperatures and apace velocitiess simultaneously recirculating the unconverted portion of the crude and inert diluents. Side reactions such as isomerization, disproportionation of hydrogen, aromatization Iand condensation are more prevalent with these oxide than vith sulfide catalysts* Howeverp the former are cheaper and ma be regenerated more easily. Orig. art.. has: 1 table and 4 figures. ASSOCIATION; Gosuda'rstvenny*y nauchno-isoledovatellskiy i proyektay*y inatitut neftyanoy i neftekhi-icheakoy promW%hlennosti 'Urnilgiproneft'" g. Kiyev. (State Scientific Research wA Planning Institute of the Petroleum ana Petro- ,chemical LAustry) ..... .. SURCETTED: 24Apr63 ENCL: 00 SUB OWE; FF# OG NO MW SOV: 002 MUM 000 c(W'i- 2/2 5(2) SO-7/3 2-24- - 2-1 AUTHORS: Dal V. 1. , Zakupra, V. A. , Ruban , 1. 'LT. - T I TLE: Determination of Sulfu~rn products of Carbon Treatment Usin6 the Double Combustion Method (Opredeleniye sery v produktakh pererabotki uglya metodom dvoynogo sozhzheniya) PERIODICAL: Zavodskaya Laboratoriya, 1958, Vol 24, "Ir 12, PP 1445-1446 (USSR) ABSTRACT: The method of double combustion was suggested by Volynskiy Chudakova (Ref 1). In the work reported here an iodine soluti,.:; containing starch was used instead of the soda solution for adsorbing the SO2 gas. The absorber was also modified (Figi"-e), and among other changes the glass filter was replaced by a perforated plastic lamella. Instead of the gas burner a small electric furnace was used, The product of a catalytic crackin,, 1z (over 2000), the neutral res*'aous fraction of semicoking (200- ))O0 ), a cracking fraction (200-3000), a Diesel oil, the resinous fraction of a catalytic cracking product (over 20001), concentrates of various aromatic hydrocarbons, and a coal tar Card 112 were analyzed (Table). It was observed that with a sulfur c0".- SO V132-24 -1 12- 11 1/4-_ Determination of Sulfur in Products of Carbon Treatment Using the Doubie Combustion Method tent of more than 3% the titration of the 302 with iodine is more difficult. Wh-n this is the case the weighed sample taken must be smaller and the duration of the analysis must be lengthened. Using the iodine solution the analytic method is simplified and the analysis is carried out more quickly. There are 1 figure, 1 tableg and 1 Soviet reference. ASSOCIATION: Dnepropetrovskiy khimiko-tekhnologicheskiy institut (Dnepropetrovsk Chemical-Technological Institute) Card 2/2 ZAKUPRA, V.A., kand.tekhn.nauk Apparatus for rapid chromatopyaphic adsorption fractionation; two- stage chromato-graphic column. IIauch.zap.UkrniiproePta ro.4;14I_ 149 '61. (Mjqjj 15:1) (Chromatographic analysis) (Coal-Analysis) (Petroleum--Analysis) ZAKUPRA, V A.; LERFIEV , Ye.V . ., , I A.,, Frln-'IrUi I a 'L1,-, autlyt, .': i-I I RAKOV A; T. P; Effect of chemical treatmer.*. on the structure and properties of various brands of silica gels. Khtm. i tekh. topl i masel 9 no.8321-26 Ag 164. (MIRk 17310) 1. UkrNIlgiproneftt. L 6 2 0 L2 =6 5F-11 71E G-4 A I -ACCESSI0ff-11R:, AMIM49 -UR/0296/65/=)/010/0045/00-*~.5, AUTHOPS- Golont, L. Yo.; Turnakova, R. 114. Gabyahevj V. G.; Zakurdayev, A. D. TIM: Device for coupling a drift resonator with magnified spatial interaction and a rectangular waveguide., Class 21,11o. 171033 SOURCE; Byulleten( izobrGton5,v.' tL-vqrnyk-h -1965t 45 znzx1zOV, no, lot TOPIC TAGS waveguide coupler resonator ABSTRACT: -This AuthorCertificate presents a device for coupling a drift reso- nator with magnified spatial interaction and-a rectangular waveawLde throvgh a coupling window in the resonator wall. To insure the required amount Of COuDling, the devica is in the forn, of a-trian,-,alar metallic plate (see Fir,.. I on the Enclo-! GUM). Its wide aida is connoolund to the, WrLda ,mll of the ractangtartr waveguidol and the apa~~-is~connacted to'the delay systemlof the drift resonator. A rectan- .-g ar groove. s~cut in the ~ida ~jn of the waveguide under the p2ate coupler. .,Orig. art. has: 1 diagram* I !-ASSOCIATION: Gosudarstve=07 kamitat po elektronnoy tekhnika SSSH (State-Commit- tea for Electronic Technology, SSSR) SUBMT710; 18APr64 VICL: 01 SUB CODE: EC In Pa. SOV: 000 MIER: 000 C!~r L09j"AWIDE., G.A.; VEDERNIKOV., A.A.; Prinimali uchastiye: SHARONOV, G.~vi.b I ZAKURDAYEV, A.G.; MOKROVA, V.P.; ROZHKOV, I.M. CArhnn oxidation during the finlahing period of the oxygon blcw'Lag of ar open-hearth furnace bath. [Sbor. trud.) TSNIICHM no.29,. b 163. (KIRA 1734N1 AKINFIYEV, V.I.; ZA~AYE _A.G.; SHARONOV, G.Ye.; SOROKIN, A.A.; CHMLA, L.A. Mechanism and the kinetics of processes taking place in the bath of a basic open-hearth furnace in scrap and hot metal pract;OgL- [Sbor. trud.) TSNIICHM no.29:73-102 163. (MIRA 17:4) 1. TS~ntraltnyy nauchno-inaledovatellskiy institut chernoy metallurgii (for Akinfiyev, Zakurdaye'v, Sharonow). 2. Dneprovskiy wtallurgichankiy savod imeni Dzerzhinskogo (for Sorokin, Chavela). ROZHKOVI I.M.; ZAKURDAYEV, A.G. Determining the movent of the dbarg6 meltine, the earl-xin eontent at the time of malting, and the .metal towporature. Izv. VY80 ucheb. zav.; chern. met. 6 no-11j42-46 163. (MIRA 17:3) 1. TSentrallnyv nauchno-Igsledovatallskly inc-fAtut chornoy motallurgii. GNOTEIP, L.A.; MORDAM, A.K. Design of Inductive pickupa and meaauring networks for them. Vop. g1dr. no. 12:84-111 163. (MIRA 17:5) L 05901-67 NP ACC AT60163143 W ijF(c"' -am SOURCE CODE: UR/3183/65/000/001/01-15/0120 AUTHOR: Birul Ya. A. K. (Doctor of technical sciences); Mikhovich, S. I. (Candidate of technical scienceej; Zakurdayev, 1. Ye. (Engineer) ORG: None TITLE: Automobile tirem-to-road adhesion during the fall-winter period SOURCE: Kharkov. Avtomobillno-dorozhnyy institut. Avtomobillnyy transport; mezhvedom- stvennyy respublikanskiy nauchno-tekhhlcheskly sbornlK, no=,-Ty" , 3a7-Mr TOPIC TAGS: automobile industry, road, highway vehicle data, motor vehicle, adhesion ABSTRACT: Automobile tire adhesion to road surface is characterized by an adhesion factor which has a significant effect on safe maximum automobile speed and determines the economic efficiency of vehicle transport. The adhesion factor is a function of surface type and degree of roughness, wear and condition. This factor is not constant for any period of time but varies from season to season and year to year depending on cAnatic conditions. It is highest during summer months and falls sharply in winter. The most dangerous period for travelling is fall and winter. The adhesion factor drops from summer to winter from 0-75 to 0.40. The minimum values for this factor have been determined for many regions of the SSSR and run from 0.4 to 0.6. The authors discuss a method developed at the Kharkov Automobile Highway Institute for de- L 05901-67 ~~C_d_N& AT6ol6343 termining the adhesion factor. This method is based on braking distance measurements. An expression is given for calculating the longitudinal adhesion factor using this method. Experimental verification of the Mo:etical data was done on the KhADI Mobile Laboratory based on the GAZ-51 truckI ing the M-20 automobile as the test vehicle. The results show that the adhesion factor is highest (0.8-0.9) inwarm weather for a dry asphalt surface and decreases to 0.45-0-55 for wet or dirty surfaces During winter months the adhesion factor is 0.20-0.25 for snov and 0.14-0.18 for ice. All of these data are for the same road section'. The effect of air temperature on the adhesion factor is considered. The authors recommend that since the minImum safe.ad- hesion factor is 0.4, the road service crews should systematically measure the exist- ing factors for various roads and develop effective means for maintaining a factor which ensures safe travel. Orig. art. has: 2 tables, 3 formulas.: CODE: 13/ SUBM DATE: None/ ORIG REF: oo4 . 6~/7 kh ZAKUPDAYEV, Leonid Vasillyevich; BOGATOVA, V.S., red. ----(Y',otion-picture films, their characteristics and P~oces- sing] Kinoplenki, ikh kharaktoristiki i bbrabotka. Mo- skva, Izd-vo "Iskusstvo," 1964. 109 p. ~ WIRA 17;7) ZAKURDAYEV,X. - MEMOOMORAft-kV Patriotism and perseverance of Soviet seamen. Blok.agit.vod. transp. no.16:11-18 Ag 155. (MM 8:9) 1. Sekretar, partlynoy organizateli tankeris "Tuapsew (Formosa,--wreedow of the seas) A L 10 r Q A i U If jI I I ~A 00 UL W tt,. 00 1! V-P o0 -00 Of A 00 C, M.A.. 00 All DIL 1910, -14--AM II.L., PlItIc. -00 ros CAN tw &Wkd to ctdw-ftut go, but imly with the ski 00 Al! 14 swim itid 6 inrwrawJ wvtml % hV flit'r. 0* 00 r" 111fix" F. *411 1 1 Wa 00 V. -00 00 me 0 40 a 40 c0 00 fat 1900 0 00 Sao Fit, get, A 5 S L A At 41'i.- 1- if. -~v 1 5' 1 V A L 4 04 a to is X A* Out I. It ft It 19 ft 1!14 10000 000009000000 ego!* go$ 0 0 0 0 0 q 0 a 0 0 0 * I 01 Vo 0 0 a 0 0 0 0 0 o 0 o 0 6 0 0 0 0 c0 0 0 0 0 0 0 0 0 o 0 0 0 0 0 0 0 o :% ZAKURDAYEV P. D. I IMMIN, N. I. 30370 Opyt raboty na nystryeryvno dyeyistvuyushchyey zustrakta,'OnnoY ustanovkye s odmkratnym pryedvarit ye llnym slyemom masla. Pisbch. Prom-otl SSSR, Vyp. 13, 1949, S. 27-31. SO: Istopis' No. 34 ZAK-LT!G'AY---,V, P.D. Processing undecorticAted cottonseed In a vom-tyLpe extra-ation Maal--zhir.prom. 17 no.10:1.3-15 152. 01. Z~q.A 1. 0 1, KmDotkinskiy maslookstraktBionnyy znved. (cottonseed) ZAKURDAYSV, P.D. - ~ .......... ", .. ... Standard oilseed storage. Kial.-zhir. pron. 23 no.3.-9-10 157. (MIRA 10:4) 1. Kropotkinakly melookstruktaianuyy sayod, (Ollsseds-Storag*) !~A P-2-NOW

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