SCIENTIFIC ABSTRACT ZELENTSOV, V.V. - ZELENTSOVA, S.P.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
• Original Classification: S
• Document Page Count: 60
• Document Creation Date: November 2, 2016
• Document Release Date: March 15, 2001
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

AUTHORS:
TITLE:
PERIODICAL;
ABSTRACT:
Card 113
-_Z 2-1 e n-tag_v.,._ 11. VSavcich, 1. A., SIOV12o-122-1-2114.4
1--t- 1-1 Member, Academy of Sciences, USSR
Spitsyn,
On the 2roblem of Stereochemistry of Intracomplex Compounds
of Vanadyl (K voprosu o stereokhimii vnutrikompletcsnykh
soyedineniy vanadila)
Doklady Akademii nauk SSSR, 1956, Vol'122, Ur 1,
pp 80 - 81 (USSR)
Some problems as mentioned in the title concerning the
stereochemistry of vanadyl compounds with azomethyl
derivatives of the aromatic o-oxy-aldehydes are
discussed in this paper. Althouah the magnetic moment
of the complex.compounds of vanadyl does not depend
upon the coordination number of the central atom
it is possible to draw some conclusions on t-h-e mentioned
stereochemiatry by comparing this moment with the
results of analyses. The crystalline intracomplex
vanadyl compounds which were synthetized by the authors
were analyzed after having been dried until a constant
weight was reached and their magnetic susceptibility

On- the -.?roblem of - Stereoch-em-istry of'Intiacomplex SOV/2o-122-1-21/44
Compounds of Vanadyl
~waa determined.'The chemical analysis proves that
~.they contain no-solvents'(Table 1). As table 2
aho,,Y3 the magnetic momen'to of the oynthotized com-
potuids are between 1,76 and 1,80 mv. If the oxy~on
atom takez as a rule a single place in the coordination
system the coordination number of vanadium is not a i x
but f i v e in those compounds. Thic is in contrast
to reference 2. The a3sumption that the vanadium ion
lies in the base of a tetragonal pyramid is more likely
to be right. This is proved by the fact thatl'in'vanadyl-
o-oxy-quinolinda(Ref 4) the pyridine molecule in
connected with the central ion as regards the coordination.
The free pair of electrons of the nitrogen atom takes
the free 4P-orbit in the pyridine molecule. The square
pyramid grows steadily until it is an octahedron.
Based upon the mentioned facts the autilors are of
opinion that the initially mentioned vanadyl compounds
have the structure of a square pyramid. Thanks to the
2
d sp hybridization the d-bindings exist. Apart from
Card 2/3 this a 3d-orbit of vanadium takes part in -the formation

On the Problem of StereocheLListry of Intracomplex SOVII2o-122-1-21/44
Compounds of Vanadyl
of a solid 7r-binding with an oxygen atom. The structure
of thooe compounds lo explained by means of the forraulae
A and B. There are 2 tables and 6' references, I of which
is Soviet.
SUBMITTED-: May 27P 1958
Card 313

5M SOV/20.-128-3-27/56
AUTHORS: Aminov, T. G., 1.
TITLE: Magnetic Susceptibility of Some-Ozal0e.Complexeis of Quadri-
valent Uranium
PERIODICAL: Doklady Akademii nauk SSSRI 1959,:Vol 1289 Nr 31 PP 533-535
(USSR)
ABSTRACT: The'' investigation of the problem mentioned.-In the-title
facilitates the answer to the question as-to.the-electronic
configuration of quadrivalent uranium..In.its.iont 2 nonpaired
electrons may occupy the pathe 6d or 5f. Theng.their ground
state
determined - according to Hund's rules - by the
I
terms 102 and 3H49 while their effective magnetio.moments
will amount to 1.63 and 3.58 magnetons of Bohr, respectively,
if the interaction of Russell-Saunders takes place. As the
electrons of level 6d are more intensely subjected to the
influence of electric fields of neighboring atomag the orbital
component is almost completely suppressed in most cases, and
moment in this case is only determined by the
the magnetic
-
spin, afid imounts.tD peff ~ 2.83 PB& The presen! paper gives
Card 1/3 investigation results of the magnetic susceptibility of 3

oxalate complexes of U (IV):
K4 ~ (C204)41-5H 2Of Ba 2[U(0204)41 -6H20 and Cd 2[U(C2o4)21 -7H2 0.
,tlity of these substances was first investigated
The Otxacept!
by A# A. Oriilborg - and T. K. Petrzhak (Ref I) t but only at
room temperature and without correction for the diam4gnotlem
of the cation and oxalate ion. The authors studied thin ouv-
ceptibility over a wider temperature range. The knowledge of
the Weiss constant, and the consideration of all diamagnotic
corrections, make possible a more accurate computation of
the effective magnetic momenta of U (IV) in the above-mentioned
salts. Table 1 gives their analysis. The magnetic susceptibility
was determined by Guils method. A special device was used.mak-
ing possible the investigation over a -temperature range from
room temperature up to the boiling point of liquid nitrogen.
Mohr's salt was used as a standard substance. The measurement
results of the susceptibility of the above complexes are
given in table 2 and figure 1. Figure I shows that all com- 0
pounds investigated follow the law of Curie-Weiss above 195 K-
At lower temperatures, considerable deviations occur which
Card 2/3 are different for,the individual compounds (similar to Refs 3,4)-

SOV/2-OA28.-3-2-7/58
Magnetic Susceptibility of Some Oxa'late C ompl axe a.- of --Quadr:Lval ant .,Uranium
They are due to magnetic anomalies at low.tomperatures. With
the falling temperatures,, the susceptibility starts increasing
more slowly than it would have to according.to.formula
X. -I- Table.2 shown the ji and the Weiss constants of the
T+A" off
said complexes. V. B. Tevdokimov helped by giving raluable
advice* There are 1~figurej 2 tablesp.and-4 references, 1
of which is Soviet.
ASSOCIATION: Moskovskiy fiziko-tekhnicheski7-inati-tut
(Moscow Physico-technical Institute)
PRESENTED: April 21, 1959, by V. I. Spitsyn, Academician
SUBMITTED: February 24, 1959
Card 3/3

TRAILINA, Te.P.; SAVICH, I-A- ZVYA TSOV, V V
Synthesis of Imner-complex, cozpounds of some cations with Mannich
bases. Mrarv neorg. khim. 5 no.8:1902-1904 Ag 160. (KM 13:9)
(Mannich bases) (complex compounds)

r777
~157-202 00(4),
3/020/60/130/03/018/065
B011/B016
AUTHORS: ..zolentsov, V. V.t Savich, 1. A., Spitayn, Vikt. I.,
IMCIV-316 M-61 dff
111ITLE: Inner Complex Compounds of flexavailent UraniJ With Azomethine
Derivatives
PERIODICAL: Doklady Akademii nauk S33R, 1960, Vol 130, Nr 3, PP 549-551
(USSR)
A133TRAM ~The present re port deals with the otereoohemlBtr~r of uranyl
compounds with Schiff's b~taes. The compounds mentioned in this
'paper may be divided into three groups according to the type of
the ligand. The authors used three types of Schiff's bases
which had been obtained from ethylene diamine (A), aromatic
amine (B) as well as from 2-amino-pyridine (V) (see scheme).
The analysis revealed that the uranyls of type 1 never contain
more than 1 molecule of the solvent (Table 1). The molecule
0
can be removed only by prolonped heating at 160-180 . The na-
ture of the complex and the difficult elimination of the Bol-
vent molecule suggest that a donor-acceptor-bond may be formed.,
Curd 1/4 Accordingly, the coordination number of uranium in such compounds

in 7 and will bo 6 after elimination of the solvent-molecule.
In the second,type of the uranyl oomplexeu7the case in quite a
difforont onei they contain 2 pyridine moleculeg which otoinot
be removed even by prolongod heating tit 160-100 . At 200-220 0
the complexes are destroyed. Also in this case a donor-acoep-
tor-bond is probably formed. The coordination number of the
hexavalont uranium in ouch complexes apparently equals 8.
2- Sal icylal -aminopyridino (contrary to oalicylal-aniline) readily
forms a complex with uranyl even in a neutral medium. An tho
former differs from the latter only by the occurrence of
heterocyclic nitrogen, ouch a considerable increase in the
capability of complex formation may be attributed to hetero-
cyclic nitrogen. It was, howevert not possible to produce a
complex of uranium with 3-salicylal-aminopyridine. Accordingly,
tho Ptubility of tho oomplax depends mainly on the position of
tho hotorocyolia nitrogort with roopoot to tbo azomothine-group.
It was confirmed by analysis that complexou of this type ountain
no molecules of the solvent. flerefrom t;,e authorsconcludo that
in the complex compounds of uranyl with azomethint,4-derivatives
Card 2/4 of the 2-aminopyridine series, a coordination-saturation of

67913
Inner Complex Compounds of Hexavalent Uranium With 3/020/60/130/03/018/065
Azomethine Derivatives BO11/BO16
.,Card 3/4
hexavalent uranium takes place. This is possible only if the
heterocyclic nitrogen is coordinated with the central atom.
The coordination number of uranium in these compounds is, most
likely, equal to 0. Thus, uraniumf according to the properties
of the Schiff's base, shown a variable coordination number.
Taking into account that the uranyl ion has a linear structure,
it follows that, from among all possible structural models of
the hexavalent uranium complexes with the coordination numbers
7 and 6, ouch would have to be given preference, in which
the ligand atoma oombinod with uranium are placed in a plane
vartical to the direction 0-- U 0. 8inco the high stability
2+
of UO is due to the participation of the 5 f-orbits of
uranium in the bindings with oxygen (Ref 8), the structure of
the complexes.for.the coordination numbers 5, 7 and 8 will cor-
respond to a tetragonal bi-pyramid (50 6d278) 1, a pentagonal
b.i-pyramid Of 36d3 75) 11 and a hexagonal bi-pyramid
(50 16d3787P),III (a,b) (Scheme). There are 1 table and 8 ref-

a a X I UP 0 am RON W-M 0-~-
67913
Liner Complex Compounds of Hexavalent Uranium -With Sj/020/60/130/0,3/01$V'C65
Azom(thine Derivatives ..B011/B016
erences, 2 of which are Soviet.

ASSOCIATIONS Moskovskiy gosudarstvennyy univer8itet Im. M. V. Lomonosova,
(Moscow State University imeni-M. V. Lomonouov)
SUBMITTED: October 8_, 1959
Card 4/4

UORM
811901611003101610141019
B1,2401 10
AUTHORS: Zelentsov, V. V., Pai Wen-mingf Savich, I. A.1 spitayn, V. 1.
TITLE: Chelate polymers of uranyl
PERIODICAL: VyBokomolekulyarnyye soyedineniya, V- 3, no. 10, 1961,
1535-1543
TEXT: The present paper describes the synthesis and some properties of
polychelate-(Or coordination-) compounds of uranyl with poly-Schiff's
bases vhich had been synthesized from 3,31-methyle.ne-bia-5-bromo salicyl,
aldehyde. (BSA) and some diamines. The chelate polymers synthesized can
be illustrated by the general formula
Card 1/ 11
7

3
28 k003101010141019
6/1 9
Y
Chelate polymers of uranyl B1 24
B1 10
X.- x
I

011C

f Lffs-
CHO
X-R-N
0 0 0
,
tjos uo,
Oil off
OTIC-o' I-CF12- CIT lic CIl,- Clio
O'k,
X-, X- X
-X C1 it fir a 11, 112~
As compared to 5,51-methylone-bia-salicyl aldehyde (MSA), the -3131-methyl-
ene-bis-5-chloro salicyl aldehyde (CSA) and the 3,31-methylene-bis-5-
.Card 2/11

28185
Chelate polymers of uranyl
S/1 90/61/003/010/014/019
B120110
bromo salicyl aldehyde (BSA) react much fasteri with considerably higher
yields, and without resin formation. The synthesis of OSA and BSA proceeds
under heating of a solution of the respective aldehyde in a mixture of
concentrated 112SO4and glacial acetic acid with paraformaldohyde. Th 0
preparatioYmiwere purified by recrystallizin- from glacial acetic acid-
The poly-Schiff's bases weresynthosized by reactine of equimolecular.
quantities of the respective bis-aldehydee with diamines in their
methanolic-benzene solution heated to boiling temperature. They cre
microcrystalline, yellow to light-brown powders unsoluble in usual solvents;
some properties of these substances are given in Table 1. For synthesizing
the chelate polymers of uranyl, the reaction of uranyl acetate with the
corresponding dialdehydes and diamines (molar ratio 1 : I : 1) in benzene-
alcoholic solution heated to boiling temperature is mcst advanta,-,eous. In
this way, six:chelate polymers.of uranyl.were syntheeizedq the composition
propertieEl of whioh 'are-given in Table 2. The formulas aesumed-
on the basis of results of ultimate analysis .~re confirmed by the infrared
absorption spectra. All chelate polymers of urallyl are almost insoluble
in usual solvents; in pyridine and tetrahydrofuran, they are poorly uolublq.
Up 'to 270-3000C, they are atable., and with houting (10 11r) to 200C tin
Card 3/11

28185
B/190/61/003/010/014/019
Chelate polymers of uranyl B124/3110
considerable lose in weiLht occura The di,~zrtvattves of CSA are somewhat
more resistant to heat than those of BSA; the heat resistance of poly-
ahelatea of iiranyl decreaues in the sequence o-phenylene diamirxe> p-
phenylene diamine~-ethylene diamine, The density of compounds synthesized
frora BSA is lower than that of compounds synthesized from CSA. ", I 1 11 h
equal dialdehyde it decreases in the sequence ethylene diaminw, > o-pheniylen,~
diamine> p-phenylene diamine~ All synthesized polychelates of hexavalent
uranium are paramagnetic,, The synthesis of 5-chloro salicyl aldehyde,
5-bromo salicyl aldehyde, BSA, CSA) poly-Schiff's bases, and uranyl
polychelates is described~. There are 2 tables and 12 references, 2 SovLet
and 10 non-Soviat. The two most recent references to Eng-liah-
language publications read as followe: C S. I-Jarvel) 11, Ta-7ko-y, J. Amel.,
Chem. Soc., 8-0, 832, 1956; C: S.~ Marvel, 11 V- Bonsi6~us.ry, J. Amer Chem.
$oc 81 2668, 1959, C ~ S.. Marvel '11 . TarkUy, J i Amer ~ Chem . Soc , 71~?~,
60w. 17)!~,j
ASSUIATION: 1~~oskovskiy ~-osudaarstvennyy universitet im, .111. V Lozmonc)sova
'6L'oscow Sta~te University imeni M- 'L Loriono-sov)
3 U B11; I TIT "-;,o ' Novov*er 21 960
Card 4/11

ZELENTSOV, V.V.; TRAILINA, Ye.P.; GLUSHKO, Yu.V.;- SAVICH, I.K.; SPITSYN,
~
ZELN
T~M
Inner-complex uranyl c-ompounds with derivatives of 8-hydroxyquJno--
Inn(
-line of the type of Mannich bases. Zhur.noorg.khim. 6 no.5:1063-
linc
io65, my 61. (MIM 14-4)
(Uranyl coMourpds)

FM
TRAILINA9 Ye.P.-, ZELENTSOVO VIV.--SAVIGHt I.A.; SPITSYNO Vikt.l.
Solubility products of inner-complex compo'inds of copper, nickel,
and uranium ~iith 8-hydroxyquinoline.. Zhur.neorr.lMm. 6 no.g:
2048--2051 s 161. (MIRA 14:9)
(Organometallic compounds)

TRAILINA; Ye.P.; -.WMiTSCLY~S,V; SAVICH, I.A.; BYLYNA, E.A.;
YBVDOKIMVI V.D.
MAgnetic susceptibility of the chelate compoun4s of divalant copper,
nickel# and cobalt with Mannich bases, Zhur, fi z. Aim, 3 5
no. 4:960-962 Ap 161. WIRA 14: 5)
1. Mookovskiy gosudarstvennyy universitet im. M,V. Lomonosova.
(Chqlates-Magnetic properties)

. ..........
V.v., Y'AYAREVICH,
'fsvll
filly
of
jhemlc'--l data On inncx:-Iompler~ iper'(11) arld cob"t (11)
. Part 31-C01
Be-Li nime -A9
-CYJ&IMI. 7hur. atrukt- khJlm. 6 no. 4*.653 JI
1931)
Q5
r(.y In"Ititlit khImiclieskikh
Inntitut.
i moskovskl
Osobo c-bistA-h
slal:mlf,~ed Ileceml)3r 22, 19

---
~1111--,-,-~'W.-----~~~

is,
HALUMMOV; V.T.; ZEUNTSOVp V.Y,; VOLKOV' M.N.; SHOSTAKOVSKlY, S.M.
Cart-ain features of the infrared absorptim apectra of vanadyl
compounds with carboxylic acida. Dokl. AN' SSSR 159 no.4a882-884
0
D 1644 411RA 18a)
1. Moskmkiy Miko-teUmioheskly institut. Ilredstavleno
akademikom V.I. Spits~mym.

NUNN
ZELENTSOV,,,Ir~,y~q,,.PLINNIKOV, V. T.
Magnetic susceptibility of vanadyl compounds with carboxylia
acids. Dokl. AN SSSR 155 no. 2:395-397 Mr 164. (MMA 17:5)
Mos.kovakiy fiziko-tekhnichoskiy Institut. Predotavleno
akademikom, V. 1. Spitsynym.

ZELENTSOV V.I.
Stersochemistry of inner compl,3x compounds of copper and'vanadyl
exhibiting anomalous magnetic properties. Zhur.neorg.khim. 7
rio.6sl299-1304 Je 162. (K= 15:6)
1. Moskovskiy fiziko-teldmicheakiy institut.-
(Copper compounds-Magnetic properties) (Vanadium compounds)

BREKHOVSKM So 14.;-VIKTOIWA Y411 No WNI," -Vs~ Va)o ZELENTSOVAjr So As
"Effect of..Qome Oxwe on oillcon-oxygen aceleton of oxygeneous glaBOOGO

tZELENTSGV.,lV~V....;_,YOLROVj M,N.; ALLENOV, V.M.; AMINOV, T.G.
Magnatle ausceptibIlIty of coppor benzoat*4 Zhur, nearg. khlm.
10 ne.2064-565 F 165s (MIRA 18111)
1. Yoskovakiy Miko-teklinic-heakly inutitut, Submitted June
A 1964.

ZBUWSOVA, G.A.
,~n body of the bronchi, Vest,ato.-rin. 20 nofW102 Jl-Ag'58
(MIRA ll-*7)
1. -Iz kliniki boleznev ukha, gorla i nosa (dir. prof. A,A. Atkarokaya)
Gorlkovskogo meditainakogo institutas
(BRONGIII-7wlaw BODIES)
~i7 ~'w

PLYT:41 '1114, V. G. 77-,'IFL4T:3f' 'A, M.
A.P.; YARNINA, G.
'Production of n--Isrt-bLt-j1 phenol by alkylasticr. of -,4,snol wilth.
isobutylere in the Msence of hydroge,.% fluoride. F.-Ca..
41 no. 32-.887-891 9 165

I, t) 9'-- 0 - 6 7 a.;'T
i ACC kNR% -kT36035674 SOURCE CODE: UR/0413 66/000 /0' 9
sey ze v M.
Kara I.; lentso a
............
none
T I T 1, E, :llkmhod of Tlznuf act~i ring rh!~niu.m w-:L,r.e-, Class 7, No. 186379
iSOURCF: Izobre',eniya, proaPjshlen:q)-!e obraztsy, tovarnyye znakL, no. 19, 1966, 13
~TOPIC TAGS: rheaium wire, wire technology, wire manuracture
'XL3S'MGT: This Author Certificate introduces a merhod for renufacturing rhenium wire
iwhich includes annealing in vacuum or protective atmosphere and drawing. To obtain
!wire up to 0.01 in diameter, iq-)rove wire qualicy a:td increase the yield, the annealing
lis carried out at 1400-1500C after each 25-30% reduction with wire moving at a rate
of 1-8 mhmia.
;)U4 C~)PF. 1.3/ SUBM D,,.TE: 271,11ar641 ATD PRESS; 5105
Card 1 1 UDC: 669.849:621.778.04

An experimental study of contact heat wcchange
70EIKTODTCAL; noiocaifnay~a tetdiiii-Im Y', no.:- Ij, - 1963, ~7, -40
rotckced evanorators
Ms
conei-ansers and de-vujokt~wd
fl-a--ratus v-aq a can-
per zon6 c7i ii-a
e Ste=
da to 2mve-
apparatus
Contact heat exchange in condensers was also proposed to Lmprzove
of rez":-i~,era~~on equipment. T,*h-is scq,--ne pezmitted elimination of tube heat exchangere
0f,,2

Ali study
-YCU-LU ~L=reased th!4-, cooliM
-OTI
Condjt-~, rs
noot
prf~ no 'Knox S.

1 ,I I '. .-. I . -1., . '. . ~- - , z , , ". ..J .~ , ~ ,, , - :
, .. ... -~l , - I - -I-
.1dam ~VQWUAM -. i , l`,.,t,-l!%.L~- .~-- ~!--.~-J-il,-~f t., . -

i

USSR/Fitting Out of Laboratories Instrumente.
Their Theory)' Constru6tion,,and Use.
Abs Jour Ree Zhur Khimiya, No 3, 1957, 8746
Author Aerov, M.E., and Zelentsova, N.I.
Inst
Title Apparatus for-the Continuous,Control of Liquid Purity
on,~the Basis of the Difference in the Distillation
Temperatures of the Light and Heavy Fractions.
Orig Pub Zavod. labi,7atoriya, 1956, 22, No 6, 739-740
Abstract The apparatus consists of two continuously operated
aeries-connected semimicro-rectification. columns . Each
column consists of a rectification section 320 = long
and 10 mm. in diameter: the lower portion of the column
is connected to the pot and the upper portion to the
distill-ate receiver. The withdrawal of the distillate
and of the pot liquid is controlled by the imer5ion
depth of wires placed In capillary tubes. The cQlu=
Card 1/2. _4~

0 - . .- - ~ -1 -

10 20
S/844/62/000/000/114/129
D207/D307
AUTHORS: Brekhovskikh, S. I.I.,--Vereshchinskiy, I*V., Griah~ra, A.
D., Zelentsoval U. A*, Revinap Ik. A. aad Tykachinokiy,
I. Do
.-TITLE: Electron paramagnetic resonance in irradiated glasses of
varioug Compositions
SCURCE: Trudy II Vsesoyuznogo coveshchaniya po radiatsionnoy khi-';~
mii. Ed. by L. S. Polak. Moscow, Iod-vo AN SSSP,# 19629
660-667
TEXT: The purpose of the work was to prepare Ia glass for making
test tubes and ampouics.used in EPR studies of irradiated substan-
ces; such glass must not.given an apppreciable BPR signal after be-
ing subjected to an ionizing radiation. The basic glass composition
was 3SiO 240-5A1 203' 0.75CaO.O.2MgO,-which was varied by-additions
of Na20, K20, Li 200 BaOt:Ceo 21- or Fe2039 by altering the propor-
tions of CaO or HgO, and by replacing 20 wt.% SiO with the same
Card 1/3

3/844/62/000/000/114/120,
Electron paramagnetic resonance D207/D-307.
amount of B 0 31- Samples were prepared from quartz sand and from
materials oi purel.and 'analytically pure' grades, in corundum
crucibles heated to 1450 - 157000. The glasses were irradiated with
1800 kev electrons at the rate of 10 21 ev.cm-2 hour-1 at room tem-
17 3.sec-1 at 77 - 320 0 K.
perature or with 80 kev x rays (10 ev.cm-
The spectra were recorded with an ap aratus based on )Y.O-,Z (EPR-2)
of the Ins titut. k1limiclieukoy fiziki Nnstitute of Charaical Physics).
It was found that in a0mu cases thora was no correlation between
coloring and generation of paramagnetic centers by electrons and
x rays. The addition CeO reduced the EPIR signal inten-
2
sity of'the irradiated glasses, while the other additives either
raised.the original signal intensity (Al 203 or alkali oxides to-
gether with B 0 ).or produced an additional peak (B 0 alone or
2 3 2 3
BaO). AiLnealing of irradiated glasses reauced the conccntration of
U
paramagnetic centers produced by second irradiation. Using this in-
form.ation a glass of unstated composition, named W, was prepared,
.--which pvc no noticeable ..,PR signal after irradiation and was,
Card 213
. . .......

S/844/62/000/000/114/129
Electron paramagnetic resomance ... D207 D307
therefore,-buitable for-making test-tubes used in radiation chemia-
try. The work 'on BPR and x ray irradiation was carried out in the
.Laboratoriya radiatsionnoy khimii (Radiation-Chemiatry Laboratory),
,.directed by Doctor of Chemical 6ciences N. A. Bakh, who took a
direct dart in the discussion of the results. There are 8 figures
and 2 tables.
ASSOCIATION:-. -Vkjcaoyuznyy naVelitio-iosloZtoVc~~tel",-skiy,,.ili stituf,etekla
_41
SO entif-~O_ eqea'rcK-'Jnstitute'Ior- Glass
01114ilion
-tu,t-f izid ieskoj` (Institute of
iiiimii AN ~86SR
. .... n6ti
sical Chemistry, AS USSR
Phy
Inatitut elektrolihimii
AN SSSR,(Institute of Electr'ochemistry, AS U;SSR)
~Card 3/3

'ACCESSION NR3
-6/dial/64/006/004
AP40241 /0981/0905
IA~MORS: -Volkovs D. L; Taraeovq B. V.1 Zelentoo", 8, A;
!TITLEt mapetio properves or glass containing additiona Qf manpueeep cobalt, ands
i nickel
1SOURGEt Fizika tvordogo tela, v. 69 no. 4o- 1964P 981-985
-~TOPIC TAGS: glass, magnatio.suaceptibility, temperature dependencep Curie lawp
'C4rie Weiss law
.'iABSTRAGT: The temperature de endence of the magnetic susceptibility of glass 00n-1.
taining up to 1341 Mn) 14 7 0
Co, and 14'5% Cc was measured. The initial glass
'(without addition of Mho Cot or Ni ions)-was diamagnetiat with a oulloeptibility of
-6
1-0-35*10 , praoti-ijally independent of tomperaturo.. With the addition of the
:indicated iona, the glasses became paramagnetic and strongly temperature dependent.
'The reciprocal of the susceptibility proved to depend Unearly on the temperature
'for all compos itlona of glass teaited# but it was found not-to be zero at absolute
I ' Thin means -that- the, Tolation do a
,zero. oa ~ot imply follow thn.Curio law, but is
.rather expressed by the Curie-Yleiss lawt where
_0 k is the mwocptibility,~ i
Cord J/

'JACCESSION BRI AP4028417
IC the Curio,constant, T the 0,solute topperaturet and-Olthe.Weiso.constant. a
observed linear Idependence was-iamd to hold only.at.low teinperatures. At high
iemp6iatiliee -,-the relationship is destroyed, and the-law ceases to hold, the changon
in magne-ly-io suscoptibility bocoaing irrovarnible. Hoating and cooling lead to
different susceptibility values. This irreversible c7haraoter holds for glasses
Icontaihing'any of the investigated ions, and this:suggests that*suoh'bohavior is due
solely to ohangeo in the framework of the glans itoolf. Orig. art, haul 4 figuroa#
,11 tablo# and I formaU,
JASSOCIATIONt Mookovakiy gom%darutvenny*y univeruitotim. M...Ve Lomonosova (Mollcow
Ste-to
University)
SWAITTED I IOJ=63 ENOM 001
6M COD41 M, NO REY SM 003
DrAM i 001
Card 2 2

VOLVICYP D.I.; TARASOV, B.V.; ZE11,11TSOM, S.A.
IC propertlet; of wl th admIxtures of'
Magne
r-obalt, and nickel. Fiz. tver. tela 0 noo 4:981~-985 A- '64.
1' :6)
1. Foskovskiy gosudarstvennyy universitet imeni Lomonosova.

WO-2
5
Ld arc IY7~7~~ 0 1*, appear in
620I.-~4-ri e- yN~~ orpUb
U M ---- -- Mn 5 - .-
'bud c
th6~91*tia-A-s--a~r-e-' fo-fy4ddiadofii ~Iilefir-st -.an be crik-d-tothe F-center-which -
-represents. a Inloxis 1~ of I rekdeAto.-the-Position-
y
of it a
rOAL v
dri-bfik-migrattng seco a ctrou near it anti
IW~f lftii7tocal unt u W ry ele the more intense
C6rd 1/2:

66
12884.
ACC NRs Anom%
the absorption band. All glasses containing el ements of groups I and 11 as the third component
have similar spectra, ivith smaller absorption at 400 nqi for glasses with Mg arid Ca. The
ptim in the ing region Indicates, in all probability, the presence W the glass of oxygen
absor 60
vaca .nci6 ~fid the formation-of free ox -ents of group M differ appreciably
ygen atorum. , Elem
'th bstan
momehemicalV than those of groups I a~d 11 -, er fore their sliectra, su tially differ from
6ne'~anoth 116~ef e-nit-6--bf g-r-oup Fi-,arr-increaae-of radiation -optical resistance is observed
er
ent&--'7
vivith a decrease of ion railius~6&~ for thell"refthree elementE
of group V the radiatton-optical resistance Increases by a'1466,6~ -of 3-3-oh-r6placing SrO(4.do)
by Z?rOZ(4d2) and Nb205 (40), which is associated with a decrease oi the ion radius from Sr to
qpqtaining elements of group V1 are governed by the same rule. Orig. art. has:
-figure ------
3
SUB CODE: 11, 18 SUBM DATE: 22May65 ORIG REV.- 002/OT_*__ff_ RE~,f- 601-

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