SCIENTIFIC ABSTRACT ZEMELMAN, V.B. - ZEMLICKA, J.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001964420003-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 19, 2001
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


I.,
I

ZJWNKOV, Boris Serge 'vich; MKSHINA, L., red.; YEGOROVA. I., tekhn.red,
(memorable Rlaces of Moscow; pagan from the life of man of science
and oulturaj Pamiatnye menta Moskvy; stranitsy zhizni deiatelei.
nauki i kulltixry, Moskva, Hook.reboohii, 1959. 509 P.
(MIRA 12:12)
(Hosaow-Guide books)

M A.-, master-pavar
.-teklinolog
6 z 0 a 00 it. no.8.28--30 Ag
(MIRA
(for Berg). 2.
Zanestitell zav
0 to oil 9 *1 1, aratov (for Shirol

N..Kh,,, Mwovi I.V, RAMIOV, I.S. ISHULEV, I.P.;,;IBSTXRqV, L.Ye.
STEPAIJOV
Improve, and-'aevelop, C'ommm~ ca-tion facilities in the economic
regions. Vest,sviazi 17 no.8-.15-18 Ag 157- (MIRA,ro:10)
1.1fachallnik otdela alektronvyazi Sverdlovskogo oblastnogo
upravleniya (for Chern7ak). 2. Nachallnik Sverdlovskogo telegrafa.
(for Zemero,r) 3.Nachallnik Sverdlovsko7 mezhdugorodnoy ieletonnoy
Otantaii (for Klebanov), 4.2amestitell naLehallnilm Sver-41ovskogo
upravleniya svyazi (for Naumov). 5,Nachallnik oik~la p9chtovor
ev3razi Sverdlovskogo upravleniya svyazi (for Shmele:V)*'6.Nacha;lnik
Sverdlovsko7 direktaii radiotranslyatsionnykh sete7' (for Reaterdv).
7.Nachallnilc Ordzhohikidzeveko~ kontari avyazi g, Sverdlovoka (for
Stepanov).
.(Bverdlovsk--Telecommunication--Congressee)

lift
ZEVIEROV, 'Nikolay Iosifovich; AERZIOVICH, G.O.,, red.; KOLBICHEV, V.I.,
-tek~lm. F~.
(Development of telecor=unicatious in Chelyabinsk Province in
tbe seven year plan]Razvitie sviazi Cheliabinskoi oblasti v
semi-letke. Cheliabinsk, Cheliabinskoe knizhnoe izd-vo.. 1960. 21 p.
(MIRA 15:12)
(Chelyabins,k~Provin6e-Teleco=unication)

Acute &astroonteritis of toxinfectious origin. Zdrav.Kazakh.
17 no.8:28-32 '57. (14IFA 12:6)
1. Iz kliniki propedevtiki vmitronnikh bolesney.Karagandin-
SkOgO gOBudarstvennogo moditainGkogo instituta.
(GLSTROWMITIS)

ZEM, Sj A.A.. prof. (Iraragntids)
Clinical picture of Dneumoconinsis in Knrngnnda miners.
KlIn.med. 36 no.6tlo~-111 Je '58 (1-1111A 11;7)
1. 1z kliniki propedevtiki vnutrennikh bolezne7 (znv* 1)rof.
A.A. Zemets) KarngAndinakogo moditsinakago institute,
(PIMIM0001-TIOSIS. enideniol.
in Russia. in miners (Rus))

60-63 LWP(q)/EWT(m)/BDS AFFTC/ASD
L187 JD
ACCESSIOIFNR.- AT3002462 R/P-501/63/008/001/0033./0042
A9
AUTHOR: Prot~popescu, M.; Zemirche,'S.,- Fetresou,,,N.j Trite, V. (Rumanian orth.)
TITLE: Blectrical resistivity Wind~al-a function of the degree of PuAty'
(Translation from Rumanian into Russian; original published in the journal
Studii si cercetari de metalurgie,, Acad. R.P.R'11p 1962.9 3.)
SOURCE: Academia Republicii Populare Romine. Revue Roumaine de metallurgie.~:*
v, 8. no, 1, 1963, 31-42
TOPIC TAGS: Semiconductor material
electrical resistivity,, electrical conduc-~.'
tivity, indium, cementation, electro3.ysis., vacuum distillation, transport
phenomena,, zone refining., impurity.
ABSTRACT: The relationship between:the resistivity of indium and the concentra-
tion of impurities was investigated in order to establish a quick and easy method
1. of purity assay for camples too pure for chemical or spectral analysis. Indium
of extreme purity is needed for the semiconductor industry. Indium. of 99.998%
purity was obtained by applyIng the methods of cementation, electrolysis of
hydroc loric acid solutions, -vacuum distillation and repeated zone refi-n-Ing with'
1 Card 1/2

ZEMIT~, A. P. In Latvian
ZEMITN', A. P. -- 'Totermination of Requirement for.LiminG and Lime Doses for Soils
Rich in Organic Matter." Latvian Agricultural Academy, 1951. In Latvian (Diaserta-
tion for the Degree of Candidate of Agricultural:5clences)
SO: -Izvestiya Ak. Nauk Latvi7Bkoy 58 No. 9. Sept.. 1955

- - - --------
OU163
Zia
7
.47
8-762
-T~ htoqq-&~ TW/g4p(j)/T T-1P(C) WIRM
Xq~ NRI A 60-15673 SOURCE CODE.- uR/04i3/66/ooo/oo9/0o76/oo76
IMNTOR: Lazaryants, E. G.; Aleshin, A. M ; Gromova, V. A.;
Ye. P.; Kosmodemlyqnskiy, L. V.; Romanava, R. G.; Tr itskiv.
e Kop
Xlov
p Taa-~ 11d, V. L.; Shikhaloval K.P.; Shushkina, Ye# .; Kostin, D4 Lu-"
none
TITIE: Preparation of divinyl-alpha-methylatyrene rubberj~'Class 3&9o
No. 181294X/.1
SOURCE: Izobreteniyas promyshiennyyz obraztsy, tovarnyye znakij no. 9,
19661 76
TOPIC TAGSt rubber, methyletyrene rubber., alpha methylatyrene., divinyl
ABSTRACT: This Author Certificate introduces a method of preparing
divinyl-alpha-methylstyrene rubber by emulsion copolymerizationlof
divinyl with-alpha-methylstyrene at 20C and abolie in thr presend6 of
persulfate initiators and emulsifiers. To increase the polymerization
rate and Improve the conditlons for~the granular coagulation of latex$
commercial grades of sodium salts of the synthetic fatty acids C :LO-0i6
.rd 1/2

L 44194-66
ACC NR' Ap6015673
are suggested as eimilsifiers in the following composition M.. 0 5-1;
10,
16-17; C -17; C
all* 112-14; C12J Y 15 C 9-10;
14' 2.5
a 7-8; below C and above C 15-20. (Translation)
16 - 10 [LD]
SUB CODE: Il/ SUBM DATE: 12Mar62/
Cord 2/2 is

USSR Cultivated Plants. Plants for Technical Use. m
Oil Plants. Sugar Plants.
Abs Jour
Ref Zhur Biologiyal No 61 19590 No. 24980
Author Zemit, V. E.
Inst Yar -cTa-VT-7gricultura1 Institute
Titlo On tho Problom of Variability of the Character-
latic-Ovorall Height of Long Fiber
U'Dolounoiz"] Flax Stalks
Orig Pub Tre Yaroslavsk. s.-kh,* in-ta, 1957p 4j 145-
159
Abstract Cultivation of the plants was conducted under
conditions of box sowing in a vegetative
little house. The changeability of the
stalk's overall height was studied in, the
parental plants as well as in the fl-r-st
and second seed generation. A repetitive
Card,1/3
125

USSR / Cultivated Plants. Plants for Technical Use.
Oil Plants. Sugar Plants.
Abs Jour Ref Zhur Biologiya, No 6v 1959, No. 2498o
cultivation of flax under equal conditions
by seeds, taken from the experimental plants.,
leads to the equalization of the plantsl
growth along the goneral height of the stalk,
This takes place at the expense of reducing
the general.height of the stalk in the
generation of tall grasses$ and of increasing
the general height of the stalk In the
generation of undersized plants. A prolonged
effect of good or bad conditions of the flax
cultivation may lead to the appearance of
differentiated ecotype forms in the variety
and in the subsequent generations. Unevenness
of the aE;ricultural engineering background
decreases the harvest and Impairs its quality,
Card 2/3.

lo
USSR Cultivated Plants. Plants for Technical Use. M
Oil Plants. Sugar Plants.
Abs'Jour Ref Zhur Biologiya, No 6, 1959, No. 24980
and also causes a prolonged or permanent
onangu in the flax nature. The growing.
heterogeneity of the stalk stand in old
seed batches of selective varieties,
existing for a lone timo in Industrial
sowingst permits the production of an
effective mass selection with the applica-
tion of pulling or a two-fold threshing.
A massive improving selection amid the
sowings of selective flax varieties produced
positive results, and it should be used on
seed plots of long fiber ["dolgunetz"] flax.
P. N.,Kizima
Card 3/3
126

MITAN. V.L. gvardiL mayor meditsinskoy alushby
Signs for designating temporary shelters for wounded and disabled.
Voent-med. Our. no.10:76 0 155, (MIRA 9:10)
(RUSSIA-AW-TRANSPORfATIM OF SICK AND,WOUNDED)

BARBALIS, P.;-~~,T-T~P,,,A.; NEILPI-IDE, A., red.
[improvement and fertilization of soils] Augsnu iela-
bosana un meslosana. Riga Latvijas Valsts izd-ba,
1964. 237 P. [In Latvianj (MIRA 18:2)

Country USSR
Category Soil Science. Fertilizers. Mineral Ferti-
lizers. j
'Abs Jour : RvhBiol., No 6, 1959, No 24648
Author 3 Zemite, A.
Inst : I-MMvponw-
Title SoTj equ r"ements of the Livanskiy FOY=
(LatvSSR) in Calcium Fertilizers.
Orig Pub Pochva i urozhay. Rigag 1956, 51 61-66
Abstract No abstract.
Card 1/1
50

-arodermatitis. Cesk.
ice v Bratislaw, veduci
ITIS in inf & child)
ld)

Z1724KOVA. IfLj.; KAZA,'.Frr'.1-,'FJYA, T.P,
Characteristics of the trtmk peots of Siberiari fir In the
Vest('In Sayan Mountain;3. [Trudy) STI 3501-13 163
(MIRA 18:2)

p

SLUSARCZYKJ, Stanislim, inz.- KRAVJTT, Antoni, inz.; ZIMA, Adam,.#2.;
14ICIRILL011SK: ) Teofil., inz.; TOAMSZEWS"I,
inz.
Increased 61.10. =-4. power and work zi-f-m-mY of UIZ 50 M4
power unit4., Gosp paliw 11 Special issue do.(95):57 Ja'63-
1. ElektrotrM!;, Jaworzno IL

SOKOL, F.;LIBIMDTA, H.;ZD(rA, J.
Properties of infectious ribonacleic acid derived from'brains
of mice lufect6& with tick-borne encephalitis virus. Acts, virol.
Rngl. id. Praha 4 noo-2:65-74 Mr 160
1. Institute of Virology, Czechoslovak Academy of Sciences,
Bratislava.
(RIBOMUCLEIG ACID chem.)
(MIN ohem. )
(003PRALITIS IPIDWIC exper.
M"MUM

~ow'

BR) V,; ZEM[Aj, J.
-take and aerobic glycolysis o
ysis 0 human cens persistentl7
with tick-borne encephalitis rus. Acta virol. 6 no.3:
Ute of Virology Czechoslovak cademy of Sciencep,, Bratislava.
(MEPH&LITIS tFIDEMIC jr.1 (TISSUE CULTURE)
U

MIM RNEKI B.;
perouleatus
63.
of Sciences,

mipzaw
W15" -"-`777777-----
ZEMLA, Stefan
Stocktaking problems of the current state and modernization of
old-fashioned metallurgy. Problemy proj hut maszyn 12 no.lls
347-348 N 161,.
1. Biprohut,, Gliwice.
F-M
Ma

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Ci& And NIX w.is dead, ill mra% mul its grmij, I far )-uft,
are piviented ill taloular isn't gf-ApIlie Ilivy Cwt I".
;91 1011111AI: A~ fAt it, thl' :1 l1will
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%IN Ill fill- gluillarlil Nlfbl%% puklumd I,y thecila".J. plmll~.

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16, -4
V,
th
e iddiOn a,iwki* pubstapme mTV t
y Of
--dl motmUm al (M.or Ilb In I
YA NO
4> >HCI>UAOg CWO >PM)g.
KA
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14
1
i~vlllll -"dbl "I
3r, ;g.
&so 0,* 0

n-Grigorl4iP.Xich; MZVOVA, Tamara Akjl,.o a;
"12,!LEGLYADOV,_ _J~qnstap~-i vn
KO~NfMEIKOV, K.M.., red.
(Efficient ways of introducing the multiple machining method
based on the standardization of parts and billets] Effek+.I-v-
nye puti vnedrenlia metoda gr-uppovoi obral*tki na osnove uni-
fikatsii detalei i. zagotovok. Leningrad, 1965. 42 p.
(MIRA 18:5)
A-

PHEYNMAN, Remualld Petrovich; ZEMMLYADOV.Konstantin Grigorlyqvich;
NOVIKOVA, L.K., red. na-va-,--ow
GVIRTS, V.L., tekhn.-red.
(Improvement ofthe production structure of a machiner7
Plant] Sovershenstvoiranie proinodAvennolatruktur7 mashino-
stroitellnog,D zavoda. Leningrad, Ob-vo po rasprostraneniiu
politicheskikh i nauchn. znanii RSFSR, 1963~ 42 p. (Leningrad-
skii dom nau,chno-tokhnicheskoi propagandy. Otmen peredovym opy-
tom. Seriia: Mekhanizatsiia inzhenernogo i upravlencheskogo
truda, no.l),. (MIRA 16:7)
(Machinez7 industry-Management)
-.00,

VEMILER, 1,,aks Saulovicl,,* ZD-rILJV.J',,N. M.A., Ted.
[Electrostatic devices] Blektroqtntichoskie pribox-y. Vlo-
skva, Ener giia, 1961~. 13,1+ p. pribc-
ry no.7) (MIRA 17:8)

ZEMLM, B. arkbitoktor
Cbango tho'lnethod.of inotalling door blockn in partitiona. Ila
strol.Mosk, 2 no,6:31 Ja '59. (AIRA 12:8)
(Doors)
"r "T
-M.777

ZEMZR, Josef
Standardization of technological processes in the consumer
goods industry. Sklar a keramik 14 no.5.-150-151 My 164.
1. Sdruzeni podniku jablonecke bizuterie, Jablonee nad
Nisou.

ZIMEIRP Josef
Improvement of the product:Lon procuzi3 by the enterprise level
standardization. Normalizace 12 no*lOt274 0 16,1.
1. Sdruzeni podniku jablonocke bizuterJe,, Jablonec nad Maw.

EXCERPTA VIEDICA Sec 9 Vol 13/6 Surgery June 59
3269. THE CLINICAL PICTURE OF THE PRIMARY PHLEGMON OF THE
STOMACH (Russian text) G. - KHIRURGIYA 1958, 5
(70-76) Tables I Illus. I -------
Five cases are reported and 32 case histories from the literature are analysed.
The general toxic symptoms are pronounced and the patients look seriously ill.
They moan or cry from pains in the stomach. Respiration is embarassed. The
tongue is dry and the fever ri es up to 40* C. Even on insignificant strain of mus-
cles in the epigastric area anpd seemingly mild changes in the abdominal cavity.
the pulse rate is increased. This incoordination of the gravity of the general can-
dition with local manifestations is characteristic of phleSmonof the stomach. Re-
section of the stomach should be performed as early an possible. If resection is
not poso b e the gastric wall should be injected with antibiotics.
V1

axiaA, J.
Goll C!,, Ov-m 29 nc,7:1734-1735
il 164.
2. lnatitixt.~.,ct iVganle Cnem!st-ry ani Biochemistry,, Czac hoularvak
of Scieaces., Iagu e
ml -Ml N

ZEULICK4: J. CZEC11OSLOVAKTA
no academic degree indicated
Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Science,
Prague.
Prague, Collection of Czechoslovak Chemical Commudeations, vol 27., No 10,
Oct 62, pp 2464-2467.
Ann

CZECHOSLOVAKIA
ZEML10KAs J; SORMs F
Institute of Organic Chemistry and Biochemistry, Czecho-
slovak Academy of Sciencess Prague (for both)
Frague, Collection of Czeeho3lovak Chemical Comm-gniogtions,
No 2.. February 196f:757~7-59~0
"Nucleic acid components and their analogues. Part 89:
Synthesis of 2*030-o-isopropylidene-o?-,5,:cyclo-6-aza-
uridine and 2-( -D-ribofuranos-yl)-3-amino 4,5-dihydro-
1.2,04-triazine-3-one (6-a'zaisocytidine).

ZEISICKA) J.
Technology of the pi doiqrh in zqtRtionary mixing
machines. p. 132.
TECHNIKA VUYUPU, a Wnisterstvo uotravinarskeho
prun7slu a vykupu z- uzeni mlyrnu a pelcaren3
Paraha, Czechoslovii W 195Q.
HDn" List of Eas EEAI), LC Vol. 0,, no. 2,
Feb. ig6o.
Uncl.
Et

ZEMLICKA., J.; KRUPICKA, J.; ARNOLD) ZI
Self-condensation of triformy3methane to 1,,3,,5-triformylbenzene,
Coll Cz chem 27 no.10-.2464-2467 0 162.
1* Institute.of Organic Chemistry and Biochemistry.. Czechoslovak
Academy of Sciences., Prague.

M, C YA, J. CZECHOSLOVAKIA
no academic degree indicated
Institute of Organic Chemintry and Biochemistry., Czechoslovak Acadeqr of
Science, Prague
Prague, Collection of Czechoslovak Chemical Communications, vol 27., 110 10j,
Oct 62j pp 21t%-2107-
IfFhosphates Derived from 3-Hydroxysulpholane and 3-Hydrovsulphol-2-EE
as Phosphory-lating Agents"
Go-author:
SURT, J. same as above

NOUN,, diven Na-.Wo
Countrys Czechoslovakia
Academic Degrees: [not g-lvenj
Institute of-Organio ChemistL7 and Biocheuiistr7o
Affiliations

Prague dne* don of CzMh om
C Chemija C
minic"
DA
Vol 16, NO lis HOV#Mr 19 01s xqq p.40~1
Data$ NSYrMetio Reactions of Dimtby1formataide. X. Synthesis
and Reactions of Some Triforvwl Deriva"s of Aceton6
and Metbyl Etbyl Ketone*"
A~hors:
MILICKA, J
Also "ol 26, No 11, pp 2852-2864
NXI. Po3,vforrq1&tjon of Ketones of Other Types
wA the Problem of the Reaction CoursO."

ZEMLICKA S14RT, J.; SORM, F.
Nucleic acid componenets and their analogo. Pt. 48. Coll
Cz Chem 29 no. 3:635~~ Mr 164.
19 Institute of Organic Chemistry and Biochemistry, Czechoslovak
Academy of Sciences, Prague.

MUM, J.; SOM4, F.
Preparatio- of 2-chloroethene-l-sulfanyl ureide. Coll Cz Chem
29 no. 3:837-8.39 Mr 164.
1. Institute of Organic Chemistry and Blo.-hemistry, Czechoslovak.
Academy of Sciences, Prague,

Country
Cjato53r-=
i
Abs, Jour,
Author
Institilt,
Titlo
.0rig. Pub,
: Czechoslovakia G-2
: Organia Chemistry, Synthetio- &axao Chemistry
or
: Rof, Zjjur,-Khimiy% . 6, 1959 19357
No
: Arnold, Z.; Zemlicka J
Synthetic Reactions of Dimethylformamide. II.
Interaction of Ketals with Dimethylformamide
and Phosgene.
Chem. listy, 1958, 52, No ~, 458-467
Abstract Study of formylation of diethyl-ketals RC(OCII-~l
4CH2R, [acetophenone (I), propiophenone (II), acetone (III
pinacoline (TV), cyclopentanone (V) cyclohexanone (VI)]
with dimethylformamide (VII) and C6612 (VIII). On the basis
of investigations of the products of formylation of ketals
the assumption is made that the reaction takes place aver
the stage of an intermediate quaternary salt IC2H50CR--CR,CH=
=N(CH3)23+X- (IX), the decomposition of which occurs, de-
pending upon the nature of R and R, and of-the reactants
used, awrlinfl to different schemes: IX 94 RC(OC H )--CRI HO
W; I ~H3 2N L(CH3)2NCR=CRICH=N(CH3)23+cl- (XI5 C
Card: 1/7

Country Czechoslovakia
C at ofr o ry
Abs. Jour.
Author
Inotitut.
Titio
G-2
19357
Orig 'Pub.
Abotract (XI) OH (CH -(C-H-3 ME.. RC 0
-CR I =C1-21 (CH32 _ Xj)2NCR=CRICHO (M) EH3
(X I I 04L,
H By the action of ( T-Nir the
X is converted to XII. Attempts to formylate diethyl ketal
of isobutyrophenone (BP 1150/10 mm, n2OD 1,1+823) and diethyl
ether of pinacone (XIV) were unsuccessful. All ketals were I
synthesized from ketones and HC(OC H ) Diethyl k-etal of lv~,
BP 66-670/23 mm n20D 1.1+123. To 0!2~ m'he VII and 0.125 mol
VIII in 160 ml hchlorethane added at 00 0.05 mole ketal of
I, heated 3 hours at 400, decomposed with 0,2 mole CH3COONa
and ice; distillation of CH ClCH Cl~layer yieldedjt-chloro-
cinnamic aldehyde, yield 5X, B~2 5 -700 (bath temperature)/
/0.2 mm; aqueous layer saturated with K2CO3 and extracted
Card: 2/7

G-2

19357

Extract evaporated in
_idue extraction with
d 25.7$9 IBP 1300/0,2 mm,
0
)-
aqueous
/0.12 mm
di
h
I
c
lor-
n
dissolved

_
XI, R = C H RO- H,
picrate MI C
1121(~N5
It
f
l
a
ke 1 of
ormylation o
oil separated X -H = C6H51
h
ti
f X
B
ea
min.
ng o
y
,
)
2NH in C6H6 for
of (CH3

A

Country Czechoslovakia G-2
Catogory
Abs. Jour. 19357
Author
InBtitUt.
Title
OriS'Pub.
Abstract 1.5 hours was synthesized XII R C051 R1=
= CH3 , yield 53.4%, BP 50'0/0.08 mmIMP 80-hlO (from ether).
Formylation of ketal of III gave mixture (yield 4.6%, BP
120-140*/10 mm) of XII R = CH Rl- H (XIIa) and XIII, R
= CH ~ R'= H (XIIIa)(iAentiftea"by ;aper chromatography) and
56% 11, R -_ CH3s R'= H MP 193-1970 (decomposes; from pyridim)
-PC C H19N5071 MP l00-iOlO.i perchlorate CaHj N2C104 W)t
MP 1~90. Hydrolysis of XV with aqueous KOH at 250 yielded
(72.8*) mixture of Ma and XIIIa, while treatment of XV
with aqueous KC1 and hydrolysis of resulting chloride in
moderate vacuum gave XIIIa, yield 55.4%, MP 640 (from ether)
PC, MP 1400. Ma was synthesized from CH3CCCH=CHC1 (0-3 mdle~
Card, )+/7

Country Czechoslovakia G-2
catogory=
xlibc,. Jour, 19357
Author
Instit'It.
Tit10
.0rig. Pub.
j.ution Of (CH3)2NH
Abotract and 300 ml 2.3 N so' in
toluene (at 0*) yield 77.5~~j BP 111-1120/7 mm, Formylation
H91 RI= H yield
of ketal of IV at 500 gave X R = tert-C4
82$ BP 105-1100/9 mm 1n20D J.4705; semicarbazone ~SC), MP
16311650 (from 5C% alcohol) and small amount of XIIII R =
= tert-C4H~I RI= R Mp 38.5Z (from ether at - 750), subli-
mates at 3 -40 /0.1 mm. Formylation of ketal of V gave
2-dimethylamino-cyc:lopenten-l-alj yield 47.6%t BP 117-1210/
/'l mm, Mp 87-87-50 (from ether)(sublimates-at 75--800/0.1 mm).
From ketal of VI was obtained 2--ethoxy-cyclohexene-l-all
yield 59%, BP 140-1600/11 mm~ MP 360 (from ether at 750)
Card: 5/7
MORE M

Country Czechoslovakia
Catogory
Abs. Jour.
Author
In6titut.
Titlc
1,
0
Orig Pub.
Abstract (sublimates at 30-350/0.3. mm), n2OD 1.5100t SC,
HP 207-207.50 (from 50$ alcohol). To 0*2 mole K in 100 ml
11. uid NH added 0,05 mole pinacone, replaced NH3 by C H6
and boilea for 1+.5 hours with 0..1. mole (C2H3)2S0U and then
for 3 hours with 'J1.55 g Ba(OH12 and 200 ml water; obtained
72.8$ XIVI BP 65-676/20 mm, n20D 1.41'28. From 0.1 mole C6H5-
-CQCBrfCH3)2, Hr,(OCZH ) and Zn in CGH6 (boiling 10 hours)
4,ze
was synt, d Q It C8~~CH )2CH(OC2H3)2 yield 14.7%,
.VT),
BP 10/12 min n268 .4940.30' e
f .5 g XVI tr ated with 20 ml 8Q~
H2801, cooling with ice for 30 minutes, decomposed with ice
pree pitate sulimated aZ 1450/0-1 MM) to get 06H5COC(CII3)2CI'
yield 100$1 MP 158..158.50 (from 75$ alcohol) , Pyrolysis of
Card: 6/7

Country Czechoslovakia G-2
fibs, Jour, 19357
Autaor
Institlit,
Title
Orig. '06tib.
Abstract of keta.11 Of C6H5COCH(CH3 )2 in the presence of
p-CH C H SO H was qbtained,0L -ethoxy-.Pj~-dimeth,.,rlstyrene,
BP W-iCN3 mm, n?-OD 1.5169. C O_MM,,- 4
1958, 39539. -- J. Kucera. cation I seo RZhKhim,
Card: 7/7

Synthedc reactions of dismethyff"WiWdo. JU. N
of j4hlorarlayj aldekydes!l Z. Arnold . "iLo
Zemlikka (Cm15;j5-y. -Aimfl- V&J, tut). - L-dwzlf"
Comm tins. 24. 2r( a-RUISOXIn Ggman) - -
-t cf. -C.A. 53, Me,* 1102M.~-The repa. 00 CICII.- CRFI-ja
R - if a," me (it), Et (IUM IN (IV), AVY). phcllc~
MI, NCOXM4010 *a4 QC , ': M 00PA
-(Vltl) was givirn. The Jklilorotivinyl sitilthyded were uu.;
[&Ve a P40S. renc-i
stable even at 0' In scaled ampul.s. thty j
tion with 2,4-(OiNNCcffjN1INII, and a nag. reaction wltb~
YeCli: the Cl atom reacted readily withMeINH WitU thC
lormalloin of the conts-ponding "Imcthylambio conjpds.':,
which gave is chamcteristic coWation with FeCh, exce"i
(about 60 g-) COCI, was introduced with sCitibc and coollng-.!
with NaCl-ke mixt. hriw 18.8 g. anhyd.~CHACHON 7W
salt and stWng was corifluaic4i o0 m-n, Filterbig an the,,
plit., washing with MI% evArg. the futtateg 4n vdcxs (lath'
tfmp. belativ 40"), and distg. gave 13,0 g. 1, ba 37-41 *, sit
1.4823. Slinilafly, the JICOCH~CHCHICHo. Na salt
gave 55% CICHCHCH:CHCH0, m. 57. (ti.
7dolicune).
Treating a suspension of 8.11) S. HoCH:CAfeCorh in loo
d nil. Cill. with 23 ml. 4,35N Nfe3bill In (411j.,keeldn, tho
mixt. I hr. at room temp., evapg., adding again 23 ml.i and
distc. the next day gave 6,64 g. MrjVCj[,- Clie Coph (jz),
ba.: 127-130', tn. 45.5-7' (EttO at -151). Heating 13
-hrs. in an autodave on a steam bath 4.5 9. CICPb:C-
McCUO with 50 ml. 4.38M'Me,WII in C,1111, filterlsig oil
the Plitd- Nfc3NH2CI tvapg. in racuoi dissolving the resi-
due in 200 mi. H-0
tztg. the soln. with petr. ether. satil.
the aq. layer witil K',COj, extg. with C4111. dr)ing the cxts.
with K,CO,.'and d6tt. gave 3.1 j. -M4%,YCPk: CAfecilo.
W.. 145-150* (bath terap.). I COC13 (0.0,.,5 nx4e) in CIICI,
was added dropwise In 5 min. with stirring and cooling Into
0.01 mole I&INCH MICCHO in 5 Ina. CHC11 and the mixt,
WIN
--ii-Ft-w-um- v6F- T-dua;ci of Up).
::v" Sio. 46 aii. (e
gralig. is; oscaa gave 4n ti=tablc cry3t. residue
Hcmt:CHCIICI, whit decriuspd. with Ithring acid'-
cooling (ke) by the addh. of 25 ral. 11,0 and 20 mi 90'
Ritc. the aq. layer wlt~ FtO, N.I.X the 9;~i .U:. 'le
wn$j%Ing With &q. NaHC0j, and HtO,*drying
MISO.), aucl dkill. pve-68% ll,-b* 53-M'. isilt mwo. fL-At-(
9,1 Ul MIM. lin 60-s", %, 1,4745;
Me U I'.m 25-6 MI,
ra. 32-'31'(". ether sit "15"W'Va A V'3:
ti, 0 900-6 (Lath t=p.); VIII (24 ). b4-1-Q(~-3*_(bMth
ji~mpj. In She prqm. of III 'Toand IV (79%). tin
1001, a160 1,4719, 0.011 mote POC4 In CHCls was also used
Instead of COCh. p-bitC41I.SOXI with UeNCH:CEt-
CHO In CA sobt. In a trAe ratio 1: 1 gave only 255o' III.
Keeping 10 mg. VIII 2 clays with 1 0. 4MN Me,NH N
:-C4H* Pyle IX. Rf 0,05 (by th1`OMtMPPhY On It 13aper Im-
ptitguatied with HCONMci and develoinactit w 1h cYdo-
MIAMI). A surprising stability of 1he unsubMtui salk
IjMeiN:CHCH:CI1CIjCI (m, not given) towascis hydrolysti
is mentioned in cmrtitrast to the behavior of the substitute
desivs. IV,- Yjvparatlaa of A-Chlaravinyl ANOW1111 11011a
cubotcyl tompatinds. W. 2=5-92I.-Reatctions Of RCO-
CIIR' with HCOMfet txnd POCI, in a molar raito 1:3:-
2.5 cave CICR: CRICHO (R. Bit, rwetlon time. bath temp.,
yield. b.p., and nj? given: Ife, IT, 43 or 30 min., W* err 35-
40-. 39%. b., W-65- (bath. temp.). 1.4790, Aft, Nit 11).
'35 min., 35A0', 67%, bu 53-6% -.4915: D. Me, 30 mm.,
3&40', 77%. 111., 67% 1.487 1; Ph. 11 (11), 2 hrs,, 40-45'
A!%O, b, 00-103o, IAICA (semic=bazone, tn. 20EI--74
(1401111; Ph. Ate (111), 3 firs., 1445". 01%. bi.s 117%
1=3 6emitarbazene m. (RR' =) (CM01 (IV).
I hr, - 30 min., 20* or 35-10% (14%. bit.%% 1.5162; (RR'
(C!13~. 20 min.. 2CHO". $41,S, bit 87,* 1.5226. (RRA s-
C110s. 4011116,. 3"04 65"" 'bit 05-8', 1.6-127; (RR'
-i Mi
M104. 45 tuln.. 35-40 , ba 135-40- (bath temp.
1,6247. Similarly, only 281~,D CICII:CEtCHO, bia,
pd,komllrCHO. I'hokcione(O.05tatilm
yvas pre

7-
JV

Almold, Zi, ai~d ~e~li&a,
(6
lit ry-16 inim with ttkrint aind k e-coolins laid the reazent:
(prcpd. by treating In o'46 min. at 04 liz IT& roci, WiW Mote urt-13LICONfe into~a TCAM!,jifepd. from.0:205 ir'otc -
11 g. HCONAIrl and stlirring 30 van at rowl temp.), The,
-
i MeiNH and 0.125 insole COC13 (loc. cit.), heating the mixt. CZ
1.5 or 3.5 birs. to 70' or 55% mp.i decompl. with 0.2 mole
mixt. I
15 It 30-90 min. In a bath a
20-46! aild siteompt . -
with Ito gn"e. The product Is Isolated by e0q. wills RhO";
'
- anhyd. NaCiAe and 100 it. fee, sepg. the tayus, exti. the I

combining the exts
washing with 11
layer with (CILCI)
8
washin
g the "tz.
wlth
aq~ MUM 4 NajC03 or NaOll':
' .,
,
s,
,
%sid distg. gave 80'70 CIC(kyl-liu)-CH.
drying (MgSOj
,
;ai;
resp. toremove any hydroxinnethyleseketove RCOCR
jQ% 1U. Reactions of the HCONMer-
"LarlyiphCORtgavc . . . . . . .
-
'
&tillute-satd' ivlth MCI. The p"uct'extd. with Rtj%~ ~COQ~rtag=t with
PhCOP&Iva grid CACMICH2 failed
auddistil. . Only- traces of the isolintsic CJCRt ;CHCHO (y) %
-
'
,
-
-
d
d
I : Reaction of 11 with excess 4N MesNH in Cells gave Mer
NCPh.CJICII.-N1Mes1CI - Weram, - ns. -- GO-11 (EtOll)). - -
!
t
w
ere
t
from
-Treating V
. In the prepn.~of
WCOEt.
with 4,38N AlesNH In C4H& and keeping tlv! misit, 3 days and tram of Me~NCI?h:CHCHO. Rr 0.41 by paper

at room texrip. gave MeIDICILCH00131 (V1;),(Rj 0.33 by chromatography with C1fKOBu,%r-HsO. Heating I hr.
a stcarn bath in an autoclave 5 X.- VIU with 23 A. 4MR,
paper chrorsatography, in iso-Pr30-HIO), the product of,

tea7angemellt'. V1, b2', W.6-101% was Stio p"pd. fTom
McmNlf in C411i, cooling, fifterins off the MctNH:CI, wash-
. I i
ve 45% hfeeNCH:CHCOBu-
ing whis CJii
and distg.
CICII-CHCOSt and MeNft In III CsUrWCH.. 1. bu ,
5* (Et
tert
b
115% rn
at - IV)
IT Will]
V
38
Treatin
68' (bath temp.). nlr 1.4917i was prepd. (yi,!Id 687o) from.:
;
M
Ch1
NCU
COM
VIII
u
C
C
II .
.
,
.
,
s
g
MetNII in CA at rcan temp. gave 2-dimethylaminol. I
et
:
e
d
O
arIy_Au-
4
6. jUm
r (
)
"
*
cyclopentrnecarboxald6yde (RI 0.00) and 2-dimeth)l-
-62
thentIrV. big 68
, x1f 1.4
&48, was prepd.(yidd 18%) front
VlajidCOCh. Addipir with agitation in 10tain. at 0" 0.05.
tititinouiethylviecyclopetitancrt-.e (Rj. 0.26) as shown by
PUPer chromatography In C114013u)r-UsO. The Dean
1
I
L inetlind (CA. 24, 4507) was used to prep. V
.04
I, R/ (
4.).
G-11
.'Pr
tit
0)
.
,
1
I
p
%